Issue 6, 2008
From the journal:

Chemical Communications

Aggregation-induced phosphorescent emission (AIPE) of iridium(iii) complexes†

Qiang Zhao,a   Lei Li,a   Fuyou Li,*a   Mengxiao Yu,a   Zhipan Liu,*a   Tao Yia  and  Chunhui Huang*a  

* Corresponding authors

a Department of Chemistry & Laboratory of Advanced Materials, Fudan University, Shanghai, P. R. China
E-mail: fyli@fudan.edu.cn, zpliu@fudan.edu.cn, chhuang@fudan.edu.cn
Fax: +86 21-55664621
Tel: +86 21-55664185

Abstract

A novel aggregation-induced phosphorescent emission (AIPE) was observed for iridium(III) complexes. This interesting phenomenon was attributed to the intermolecular packing, resulting in a switch from the non-emissive 3LX excited state to the emissive 3MLLCT transition, which is confirmed by X-ray diffraction studies as well as theoretical calculations.

Graphical abstract: Aggregation-induced phosphorescent emission (AIPE) of iridium(iii) complexes

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Article information

DOI
https://doi.org/10.1039/B712416C
Article type
Communication
Submitted
13 Aug 2007
Accepted
16 Nov 2007
First published
30 Nov 2007

Chem. Commun., 2008, 685-687

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Aggregation-induced phosphorescent emission (AIPE) of iridium(III) complexes

Q. Zhao, L. Li, F. Li, M. Yu, Z. Liu, T. Yi and C. Huang, Chem. Commun., 2008, 685 DOI: 10.1039/B712416C

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