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Communication
Chem. Commun., 2009, 6774 - 6776, DOI: 10.1039/b907207a
A calixarene-based copper-centered redox switch as a data storage prototype
Ulrich Darbost, Vanessa Penin, Erwann Jeanneau, Caroline Félix, Francis Vocanson, Christophe Bucher, Guy Royal and Isabelle Bonnamour
A new copper redox molecular switch based on a calixarene possessing both imidazole- and quinoline-like fragments displays, through an exchange of ligands triggered by an electrochemical input, unexpected long-lasting stability of both the redox forms, as well as fast reversible cycling.
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