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CrystEngComm

Design and understanding of solid-state and crystalline materials




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CrystEngComm, 2009, 11, 2254 - 2256, DOI: 10.1039/b903932e


A three-dimensional metal–organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies

Zhiyong Guo, Jiangbo Yu, Guanghua Li, Zhenjun Si, Huadong Guo and Hongjie Zhang


A novel metal–organic framework [Cu3(m-TATB)2Py(CH3OH)2] (1) constructed of a triazine-based trigonal-planar ligand, 3,3,3-s-triazine-2,4,6-triyltribenzoate (m-H3TATB), has been synthesized and structurally characterized. Compound 1 features three-dimensional (3D) channels and cavities together, and exhibits high carbon dioxide sorption at normal pressure.

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