Design and understanding of solid-state and crystalline materials
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Paper
CrystEngComm, 2009, 11, 2371 - 2374, DOI: 10.1039/b905296h
2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer
Tae Hwan Noh, Youn Jung Choi, Yoon Kyong Ryu, Young-A Lee and Ok-Sang Jung
The reaction of AgPF6 in methanol with 1,3-dibromo-2,2-bis[(isonicotinoyloxy)methyl]propane (L) in dichloromethane affords an acentric diamondoid 3D silver(I) coordination polymer, [Ag(L)2]n(PF6)n with 2-fold interpenetration with alternating perpendicular
right-handed
and left-handed helical channel motifs induced by the bent ligand.
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