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CrystEngComm, 2009, 11, 2032 - 2039, DOI: 10.1039/b905912a
Towards high Tc octacyanometalate-based networks
Barbara Sieklucka, Robert Podgajny, Dawid Pinkowicz, Beata Nowicka, Tomasz Korzeniak, Maria Ba
anda, Tadeusz Wasiuty
ski, Robert Peka, Magdalena Makarewicz, Mariusz Czapla, Micha Rams, Bartomiej Gawe and Wiesaw 
asocha
We present an overview of very recent advances in the engineering of magnetic networks based on octacyanometalates. The selected magnetic networks of CuIIWV, NiIIWV and MnIILNbIV (L – organic bridging linker) illustrate the possible strategies for tuning of the magnetic characteristics. The combination of magnetic ordering for 2D (two-dimensional) and 3D (three-dimensional) networks together with the solvent sensitivity of a cyano-bridged framework resulted in the development of a novel 3D {[MnII(imH)]2[NbIV(CN)8]} assembly with magnetic sponge character, characterized by Tc of 62 K, the highest ever observed for octacyanometalate-based networks.
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