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CrystEngComm

Design and understanding of solid-state and crystalline materials




Communication

CrystEngComm, 2009, 11, 2264 - 2267, DOI: 10.1039/b910569g


Easy synthesis and characterization of single-crystalline hexagonal prism-shaped hematite -Fe2O3 in aqueous media

Nitin Kaduba Chaudhari, Hyoung Chan Kim, Derac Son and Jong-Sung Yu


A simple, mild and environmentally friendly one-pot aqueous synthesis route using urea devoid of surfactant and chelating agents is demonstrated for the first time to fabricate high yield crystalline uniform hexagonal prism-shaped weakly magnetic -Fe2O3 nanocrystals. As synthesized -Fe2O3 nanocrystals show ferromagnetic behavior with coercivity values of 0.8 and 0.2 T at 5 and 300 K, respectively. The urea and reaction temperature plays a crucial role, regulating the morphology and the size.

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