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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



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Dalton Trans., 2009, 2085 - 2087, DOI: 10.1039/b902678a

A non-classical copper carbonyl on a tri-alkene hydrocarbon support

Mauro Fianchini, Thomas R. Cundari, Nathan J. DeYonker and H. V. Rasika Dias

Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF5)] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF6] with a high CO stretching frequency (CO = 2160 cm-1), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.

Graphical abstract image for this article (ID: b902678a)