# Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics.
# This journal is © the Owner Societies 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_c
_database_code_depnum_ccdc_archive 'CCDC 1052337'
_audit_update_record             
;
2015-03-05 deposited with the CCDC.
2015-05-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C74 H66 Eu2 F18 O22 S4'
_chemical_formula_weight         2081.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   22.453(2)
_cell_length_b                   23.9254(14)
_cell_length_c                   19.4634(17)
_cell_angle_alpha                90.00
_cell_angle_beta                 122.737(12)
_cell_angle_gamma                90.00
_cell_volume                     8794.9(13)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3486
_cell_measurement_theta_min      3.2628
_cell_measurement_theta_max      28.8286

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4152
_exptl_absorpt_coefficient_mu    1.613
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.785
_exptl_absorpt_correction_T_max  0.811
_exptl_absorpt_process_details   

;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            20047
_diffrn_reflns_av_R_equivalents  0.0326
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         3.27
_diffrn_reflns_theta_max         28.89
_reflns_number_total             9978
_reflns_number_gt                6298
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'CrysAlis PRO (Agilent, 2011)'
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2011)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2011)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0943P)²+38.4592P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9978
_refine_ls_number_parameters     550
_refine_ls_number_restraints     38
_refine_ls_R_factor_all          0.1087
_refine_ls_R_factor_gt           0.0659
_refine_ls_wR_factor_ref         0.2059
_refine_ls_wR_factor_gt          0.1658
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.027
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.243149(18) 0.090212(16) 0.78734(2) 0.05968(16) Uani 1 1 d . . .
O1 O 0.1618(3) 0.0340(3) 0.7992(4) 0.0949(19) Uani 1 1 d . . .
O2 O 0.3145(3) 0.0058(3) 0.8310(3) 0.096(2) Uani 1 1 d . . .
O3 O 0.2060(3) 0.0289(2) 0.6758(3) 0.0874(18) Uani 1 1 d . . .
O4 O -0.1213(3) 0.1785(3) 0.3285(3) 0.0941(19) Uani 1 1 d . . .
O5 O 0.2506(3) 0.1417(3) 0.6875(3) 0.0817(16) Uani 1 1 d . . .
O6 O 0.1702(3) 0.2043(3) 0.3363(3) 0.0930(19) Uani 1 1 d . . .
O7 O 0.2962(4) 0.0830(3) 0.9323(4) 0.0882(18) Uani 1 1 d . . .
O8 O 0.1293(2) 0.1260(2) 0.6848(3) 0.0643(12) Uani 1 1 d . . .
O9 O 0.3626(3) 0.1199(3) 0.8396(3) 0.0830(16) Uani 1 1 d . . .
O10 O 0.2236(3) 0.1781(2) 0.8293(3) 0.0772(15) Uani 1 1 d . . .
O11 O 0.0231(3) -0.0806(2) 0.3326(3) 0.0763(16) Uani 1 1 d . . .
C1 C 0.4738(8) 0.1182(12) 0.8578(8) 0.175(9) Uani 1 1 d . . .
C2 C 0.1892(7) 0.2645(5) 0.8513(7) 0.104(3) Uani 1 1 d . . .
C3 C 0.2800(4) -0.0499(4) 0.7154(5) 0.083(2) Uani 1 1 d . . .
H3A H 0.2917 -0.0821 0.6985 0.099 Uiso 1 1 calc R . .
C4 C 0.2197(4) -0.0173(3) 0.6568(4) 0.0668(19) Uani 1 1 d . . .
C5 C 0.3193(4) -0.0346(4) 0.7935(5) 0.080(2) Uani 1 1 d . . .
C6 C 0.2115(6) -0.0344(5) 0.9210(6) 0.122(4) Uani 1 1 d D . .
H6A H 0.2329 -0.0036 0.9580 0.182 Uiso 1 1 calc R . .
H6B H 0.2452 -0.0504 0.9107 0.182 Uiso 1 1 calc R . .
H6C H 0.1970 -0.0622 0.9446 0.182 Uiso 1 1 calc R . .
C7 C 0.0069(6) 0.2270(4) 0.5366(5) 0.111(4) Uani 1 1 d . . .
H7A H 0.0205 0.2597 0.5675 0.133 Uiso 1 1 calc R . .
C8 C -0.1590(6) 0.2280(4) 0.2875(5) 0.102(3) Uani 1 1 d . . .
H8A H -0.1266 0.2564 0.2914 0.122 Uiso 1 1 calc R . .
H8B H -0.1838 0.2424 0.3120 0.122 Uiso 1 1 calc R . .
C9 C 0.3069(4) 0.1673(4) 0.5469(5) 0.075(2) Uani 1 1 d . . .
H9A H 0.3557 0.1631 0.5804 0.091 Uiso 1 1 calc R . .
C10 C -0.0676(5) 0.1822(4) 0.4092(4) 0.076(2) Uani 1 1 d . . .
C11 C 0.1932(4) 0.1633(4) 0.5264(5) 0.074(2) Uani 1 1 d . . .
H11A H 0.1640 0.1560 0.5456 0.089 Uiso 1 1 calc R . .
C12 C -0.0464(7) 0.2300(4) 0.4566(6) 0.121(4) Uani 1 1 d . . .
H12A H -0.0685 0.2640 0.4339 0.145 Uiso 1 1 calc R . .
C13 C -0.0329(5) 0.1334(4) 0.4450(5) 0.081(2) Uani 1 1 d . . .
H13A H -0.0452 0.1009 0.4138 0.098 Uiso 1 1 calc R . .
C14 C 0.0622(5) -0.0215(4) 0.4423(5) 0.085(3) Uani 1 1 d . . .
H14A H 0.0215 -0.0004 0.4100 0.102 Uiso 1 1 calc R . .
C15 C 0.1630(5) 0.1795(4) 0.4472(5) 0.081(2) Uani 1 1 d . . .
H15A H 0.1143 0.1842 0.4137 0.097 Uiso 1 1 calc R . .
C16 C 0.1215(5) 0.2190(3) 0.7153(5) 0.074(2) Uani 1 1 d . . .
H16A H 0.0960 0.2522 0.6964 0.089 Uiso 1 1 calc R . .
C17 C 0.2776(5) 0.1830(4) 0.4675(5) 0.080(2) Uani 1 1 d . . .
H17A H 0.3066 0.1897 0.4479 0.096 Uiso 1 1 calc R . .
C18 C 0.3930(5) 0.1207(5) 0.8024(6) 0.091(3) Uani 1 1 d . . .
C19 C 0.1102(5) -0.0053(4) 0.5212(4) 0.081(2) Uani 1 1 d . . .
H19A H 0.1020 0.0272 0.5411 0.097 Uiso 1 1 calc R . .
C20 C 0.0200(4) 0.1317(3) 0.5266(5) 0.074(2) Uani 1 1 d . . .
H20A H 0.0416 0.0976 0.5499 0.089 Uiso 1 1 calc R . .
C21 C 0.3661(4) 0.1285(5) 0.7211(5) 0.092(3) Uani 1 1 d . . .
H21A H 0.3960 0.1253 0.7019 0.110 Uiso 1 1 calc R . .
C22 C 0.0418(4) 0.1785(3) 0.5741(4) 0.0611(17) Uani 1 1 d . . .
C23 C 0.2060(5) 0.1890(3) 0.4167(4) 0.074(2) Uani 1 1 d . . .
C24 C 0.0308(4) -0.1279(3) 0.2933(4) 0.0675(19) Uani 1 1 d . . .
H24A H 0.0313 -0.1621 0.3205 0.081 Uiso 1 1 calc R . .
H24B H 0.0748 -0.1254 0.2953 0.081 Uiso 1 1 calc R . .
C25 C 0.0735(4) -0.0688(3) 0.4104(4) 0.0623(17) Uani 1 1 d . . .
C26 C 0.1344(4) -0.1004(3) 0.4593(4) 0.0663(19) Uani 1 1 d . . .
H26A H 0.1434 -0.1320 0.4384 0.080 Uiso 1 1 calc R . .
C27 C 0.1007(4) 0.1730(3) 0.6616(4) 0.0611(17) Uani 1 1 d . . .
C28 C 0.2936(5) 0.1414(3) 0.6655(5) 0.071(2) Uani 1 1 d . . .
C29 C 0.1810(4) -0.0844(3) 0.5388(5) 0.069(2) Uani 1 1 d . . .
H29A H 0.2208 -0.1064 0.5715 0.082 Uiso 1 1 calc R . .
C30 C 0.2653(4) 0.1573(4) 0.5790(4) 0.0682(19) Uani 1 1 d . . .
C31 C 0.1713(4) -0.0367(3) 0.5723(4) 0.0647(18) Uani 1 1 d . . .
C32 C 0.1785(4) 0.2160(3) 0.7951(5) 0.0690(19) Uani 1 1 d . . .
C33 C 0.3830(9) -0.0741(6) 0.8511(8) 0.146(7) Uani 1 1 d . . .
C34 C 0.2106(6) 0.2130(4) 0.2997(5) 0.096(3) Uani 1 1 d . . .
H34A H 0.2362 0.1793 0.3034 0.115 Uiso 1 1 calc R . .
H34B H 0.2446 0.2430 0.3274 0.115 Uiso 1 1 calc R . .
C35 C 0.3979(8) 0.1458(6) 1.0284(10) 0.176(7) Uani 1 1 d D . .
H35A H 0.3778 0.1826 1.0138 0.264 Uiso 1 1 calc R . .
H35B H 0.4152 0.1355 0.9946 0.264 Uiso 1 1 calc R . .
H35C H 0.4363 0.1455 1.0847 0.264 Uiso 1 1 calc R . .
C36 C 0.0983(10) -0.0615(9) 0.7690(13) 0.251(10) Uani 1 1 d DU . .
H36A H 0.0577 -0.0483 0.7188 0.376 Uiso 1 1 calc R . .
H36B H 0.0834 -0.0875 0.7943 0.376 Uiso 1 1 calc R . .
H36C H 0.1303 -0.0798 0.7578 0.376 Uiso 1 1 calc R . .
C37' C 0.38(2) 0.041(17) 1.07(2) 0.34(4) Uani 0.50 1 d PD . .
H37A H 0.3779 0.0018 1.0609 0.509 Uiso 0.50 1 calc PR . .
H37B H 0.3482 0.0538 1.0820 0.509 Uiso 0.50 1 calc PR . .
H37C H 0.4300 0.0467 1.1230 0.509 Uiso 0.50 1 calc PR . .
C37 C 0.392(19) 0.050(17) 1.07(2) 0.34(4) Uani 0.50 1 d PD . .
H37D H 0.3691 0.0232 1.0840 0.509 Uiso 0.50 1 calc PR . .
H37E H 0.4317 0.0661 1.1192 0.509 Uiso 0.50 1 calc PR . .
H37F H 0.4091 0.0327 1.0394 0.509 Uiso 0.50 1 calc PR . .
F1 F 0.3666(7) -0.0981(6) 0.9019(12) 0.294(10) Uani 1 1 d . . .
F2 F 0.4352(4) -0.0519(4) 0.9041(7) 0.212(5) Uani 1 1 d . . .
F3 F 0.2542(6) 0.2796(4) 0.8968(7) 0.212(5) Uani 1 1 d . . .
F4 F 0.1534(6) 0.3076(3) 0.8186(5) 0.203(5) Uani 1 1 d . . .
F5 F 0.1744(6) 0.2484(4) 0.9056(5) 0.176(4) Uani 1 1 d . . .
F6 F 0.3936(8) -0.1120(7) 0.8221(6) 0.315(10) Uani 1 1 d U . .
F7 F 0.4897(6) 0.0660(6) 0.8839(14) 0.329(11) Uani 1 1 d U . .
F8 F 0.5008(4) 0.1363(8) 0.9272(7) 0.251(7) Uani 1 1 d U . .
F9 F 0.5084(4) 0.1281(11) 0.8347(7) 0.360(11) Uani 1 1 d U . .
S1' S 0.1752(3) -0.0327(2) 0.8166(3) 0.0874(9) Uani 0.50 1 d PD . .
S1 S 0.1369(3) -0.0107(2) 0.8281(3) 0.0874(9) Uani 0.50 1 d PD . .
S2' S 0.3798(3) 0.0760(3) 0.9982(3) 0.0998(12) Uani 0.50 1 d PD . .
S2 S 0.3360(3) 0.1004(3) 1.0147(3) 0.0998(12) Uani 0.50 1 d PD . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.367(5) . ?
Eu1 O1 2.378(6) . ?
Eu1 O10 2.381(5) . ?
Eu1 O5 2.382(6) . ?
Eu1 O8 2.394(5) . ?
Eu1 O7 2.403(6) . ?
Eu1 O9 2.405(6) . ?
Eu1 O2 2.427(6) . ?
Eu1 S1' 3.499(5) . ?
O1 S1 1.453(8) . ?
O1 S1' 1.626(8) . ?
O2 C5 1.251(9) . ?
O3 C4 1.256(9) . ?
O4 C10 1.371(9) . ?
O4 C8 1.422(10) . ?
O5 C28 1.250(9) . ?
O6 C23 1.366(9) . ?
O6 C34 1.440(11) . ?
O7 S2 1.412(7) . ?
O7 S2' 1.611(8) . ?
O8 C27 1.252(8) . ?
O9 C18 1.233(10) . ?
O10 C32 1.251(9) . ?
O11 C25 1.341(8) . ?
O11 C24 1.427(9) . ?
C1 F9 1.113(16) . ?
C1 F8 1.222(19) . ?
C1 F7 1.32(3) . ?
C1 C18 1.531(16) . ?
C2 F4 1.249(12) . ?
C2 F3 1.284(14) . ?
C2 F5 1.326(14) . ?
C2 C32 1.522(12) . ?
C3 C5 1.331(11) . ?
C3 C4 1.439(10) . ?
C4 C31 1.472(10) . ?
C5 C33 1.567(12) . ?
C6 S1 1.767(10) . ?
C7 C12 1.360(12) . ?
C7 C22 1.370(11) . ?
C8 C34 1.491(12) 2 ?
C9 C17 1.364(11) . ?
C9 C30 1.396(11) . ?
C10 C13 1.369(11) . ?
C10 C12 1.381(12) . ?
C11 C15 1.362(11) . ?
C11 C30 1.379(11) . ?
C13 C20 1.377(11) . ?
C14 C19 1.371(11) . ?
C14 C25 1.379(11) . ?
C15 C23 1.398(12) . ?
C16 C32 1.380(11) . ?
C16 C27 1.414(10) . ?
C17 C23 1.366(12) . ?
C18 C21 1.368(12) . ?
C19 C31 1.400(10) . ?
C20 C22 1.364(11) . ?
C21 C28 1.419(11) . ?
C22 C27 1.493(10) . ?
C24 C24 1.494(14) 2 ?
C25 C26 1.393(10) . ?
C26 C29 1.373(10) . ?
C28 C30 1.492(10) . ?
C29 C31 1.389(10) . ?
C33 F6 1.158(14) . ?
C33 F2 1.188(15) . ?
C33 F1 1.35(2) . ?
C34 C8 1.491(12) 2 ?
C35 S2 1.668(12) . ?
C36 S1 1.573(15) . ?
C37' S2' 1.65(2) . ?
C37 S2 1.65(2) . ?
S1' S1 1.129(6) . ?
S2' S2 1.323(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O1 80.2(2) . . ?
O3 Eu1 O10 145.40(18) . . ?
O1 Eu1 O10 99.9(2) . . ?
O3 Eu1 O5 73.6(2) . . ?
O1 Eu1 O5 140.2(2) . . ?
O10 Eu1 O5 86.0(2) . . ?
O3 Eu1 O8 76.61(17) . . ?
O1 Eu1 O8 75.72(18) . . ?
O10 Eu1 O8 70.07(18) . . ?
O5 Eu1 O8 69.47(18) . . ?
O3 Eu1 O7 137.51(19) . . ?
O1 Eu1 O7 76.4(2) . . ?
O10 Eu1 O7 74.1(2) . . ?
O5 Eu1 O7 141.8(2) . . ?
O8 Eu1 O7 129.2(2) . . ?
O3 Eu1 O9 109.3(2) . . ?
O1 Eu1 O9 149.94(19) . . ?
O10 Eu1 O9 88.0(2) . . ?
O5 Eu1 O9 68.77(19) . . ?
O8 Eu1 O9 133.71(19) . . ?
O7 Eu1 O9 78.1(2) . . ?
O3 Eu1 O2 69.15(18) . . ?
O1 Eu1 O2 83.8(2) . . ?
O10 Eu1 O2 145.45(19) . . ?
O5 Eu1 O2 113.0(2) . . ?
O8 Eu1 O2 142.55(18) . . ?
O7 Eu1 O2 73.5(2) . . ?
O9 Eu1 O2 73.9(2) . . ?
O3 Eu1 S1' 70.11(19) . . ?
O1 Eu1 S1' 23.57(18) . . ?
O10 Eu1 S1' 120.61(17) . . ?
O5 Eu1 S1' 142.84(18) . . ?
O8 Eu1 S1' 94.21(15) . . ?
O7 Eu1 S1' 74.40(17) . . ?
O9 Eu1 S1' 131.60(17) . . ?
O2 Eu1 S1' 60.5(2) . . ?
S1 O1 S1' 42.6(3) . . ?
S1 O1 Eu1 158.4(4) . . ?
S1' O1 Eu1 120.6(4) . . ?
C5 O2 Eu1 133.5(5) . . ?
C4 O3 Eu1 142.6(5) . . ?
C10 O4 C8 118.4(7) . . ?
C28 O5 Eu1 133.2(5) . . ?
C23 O6 C34 117.9(7) . . ?
S2 O7 S2' 51.4(4) . . ?
S2 O7 Eu1 156.9(5) . . ?
S2' O7 Eu1 124.5(4) . . ?
C27 O8 Eu1 136.9(5) . . ?
C18 O9 Eu1 126.8(6) . . ?
C32 O10 Eu1 134.8(5) . . ?
C25 O11 C24 120.0(6) . . ?
F9 C1 F8 110(2) . . ?
F9 C1 F7 104.6(19) . . ?
F8 C1 F7 92.3(14) . . ?
F9 C1 C18 121.8(11) . . ?
F8 C1 C18 117.1(12) . . ?
F7 C1 C18 106(2) . . ?
F4 C2 F3 107.3(11) . . ?
F4 C2 F5 106.1(12) . . ?
F3 C2 F5 102.2(11) . . ?
F4 C2 C32 117.1(9) . . ?
F3 C2 C32 112.9(11) . . ?
F5 C2 C32 110.0(9) . . ?
C5 C3 C4 121.0(7) . . ?
O3 C4 C3 121.2(7) . . ?
O3 C4 C31 117.1(6) . . ?
C3 C4 C31 121.7(7) . . ?
O2 C5 C3 131.7(7) . . ?
O2 C5 C33 112.5(8) . . ?
C3 C5 C33 115.8(8) . . ?
C12 C7 C22 123.3(9) . . ?
O4 C8 C34 107.4(8) . 2 ?
C17 C9 C30 121.7(8) . . ?
C13 C10 O4 115.7(8) . . ?
C13 C10 C12 118.1(8) . . ?
O4 C10 C12 126.2(7) . . ?
C15 C11 C30 122.3(8) . . ?
C7 C12 C10 119.6(8) . . ?
C10 C13 C20 120.8(8) . . ?
C19 C14 C25 120.9(7) . . ?
C11 C15 C23 119.5(8) . . ?
C32 C16 C27 121.7(7) . . ?
C9 C17 C23 120.4(8) . . ?
O9 C18 C21 130.1(8) . . ?
O9 C18 C1 114.0(8) . . ?
C21 C18 C1 115.7(9) . . ?
C14 C19 C31 121.2(7) . . ?
C22 C20 C13 121.8(7) . . ?
C18 C21 C28 121.2(8) . . ?
C20 C22 C7 116.3(7) . . ?
C20 C22 C27 118.2(6) . . ?
C7 C22 C27 125.5(7) . . ?
O6 C23 C17 126.1(8) . . ?
O6 C23 C15 114.7(8) . . ?
C17 C23 C15 119.2(7) . . ?
O11 C24 C24 107.4(5) . 2 ?
O11 C25 C14 115.7(6) . . ?
O11 C25 C26 125.0(7) . . ?
C14 C25 C26 119.3(7) . . ?
C29 C26 C25 119.1(7) . . ?
O8 C27 C16 122.3(7) . . ?
O8 C27 C22 117.1(7) . . ?
C16 C27 C22 120.6(6) . . ?
O5 C28 C21 121.3(7) . . ?
O5 C28 C30 116.7(7) . . ?
C21 C28 C30 121.9(8) . . ?
C26 C29 C31 122.8(7) . . ?
C11 C30 C9 116.8(7) . . ?
C11 C30 C28 118.4(7) . . ?
C9 C30 C28 124.7(7) . . ?
C29 C31 C19 116.8(7) . . ?
C29 C31 C4 125.1(7) . . ?
C19 C31 C4 118.2(7) . . ?
O10 C32 C16 129.0(7) . . ?
O10 C32 C2 113.7(8) . . ?
C16 C32 C2 117.3(8) . . ?
F6 C33 F2 113.9(18) . . ?
F6 C33 F1 103.3(17) . . ?
F2 C33 F1 94.9(14) . . ?
F6 C33 C5 118.1(11) . . ?
F2 C33 C5 116.3(11) . . ?
F1 C33 C5 105.9(15) . . ?
O6 C34 C8 106.8(8) . 2 ?
S1 S1' O1 60.5(4) . . ?
S1 S1' Eu1 94.9(4) . . ?
O1 S1' Eu1 35.8(3) . . ?
S1' S1 O1 76.9(5) . . ?
S1' S1 C36 70.9(8) . . ?
O1 S1 C36 117.5(10) . . ?
S1' S1 C6 69.5(5) . . ?
O1 S1 C6 106.4(5) . . ?
C36 S1 C6 110.0(10) . . ?
S2 S2' O7 56.5(4) . . ?
S2 S2' C37' 73(4) . . ?
O7 S2' C37' 104(10) . . ?
S2' S2 O7 72.1(4) . . ?
S2' S2 C37 55(4) . . ?
O7 S2 C37 109(10) . . ?
S2' S2 C35 70.3(6) . . ?
O7 S2 C35 109.6(7) . . ?
C37 S2 C35 95(10) . . ?

_diffrn_measured_fraction_theta_max 0.861
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.510
_refine_diff_density_min         -0.819
_refine_diff_density_rms         0.111
