# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1404736'
_audit_update_record             
;
2015-06-03 deposited with the CCDC.
2015-11-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        '[Os(bpy)2(dppcb)Pd(bpy)](PF6)4'
_chemical_name_common            ?
_chemical_melting_point          '> 573'
_chemical_formula_moiety         '2(C82 H68 N6 Os P4 Pd), 8(F6 P), 5(C2 H3 N)'
_chemical_formula_sum            'C174 H151 F48 N17 Os2 P16 Pd2'
_chemical_formula_weight         4480.91

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.0903(2)
_cell_length_b                   17.9570(3)
_cell_length_c                   20.4371(3)
_cell_angle_alpha                72.7270(8)
_cell_angle_beta                 88.1416(9)
_cell_angle_gamma                89.5445(8)
_cell_volume                     4935.17(13)
_cell_formula_units_Z            1
_cell_measurement_temperature    243(2)
_cell_measurement_reflns_used    200095
_cell_measurement_theta_min      0.998
_cell_measurement_theta_max      27.485

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2230
_exptl_absorpt_coefficient_mu    1.690
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.475
_exptl_absorpt_correction_T_max  0.765
_exptl_absorpt_process_details   'Otwinowski et al, 1997'

_diffrn_ambient_temperature      243(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Kappa CCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         3
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  120
_diffrn_standards_decay_%        0
_diffrn_reflns_number            40080
_diffrn_reflns_av_R_equivalents  0.0243
_diffrn_reflns_av_sigmaI/netI    0.0488
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.99
_diffrn_reflns_theta_max         27.52
_reflns_number_total             22745
_reflns_number_gt                17732
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Kappa CCD'
_computing_cell_refinement       'Denzo and Scalepack'
_computing_data_reduction        'Denzo and Scalepack'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2015 (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL-NT V6.1'
_computing_publication_material  'SHELXTL-NT V6.1'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0749P)²+4.4469P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         22419
_refine_ls_number_parameters     1192
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0532
_refine_ls_R_factor_gt           0.0437
_refine_ls_wR_factor_ref         0.1424
_refine_ls_wR_factor_gt          0.1241
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_diffrn_measured_fraction_theta_full 1.00

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.702842(12) 0.452564(10) 0.817365(9) 0.03194(7) Uani 1 1 d . . .
Pd1 Pd 0.80968(2) 0.14497(2) 0.646953(17) 0.03136(9) Uani 1 1 d . . .
P1 P 0.63822(8) 0.42246(7) 0.72589(6) 0.0325(2) Uani 1 1 d . . .
P2 P 0.77194(8) 0.32994(7) 0.84474(6) 0.0301(2) Uani 1 1 d . . .
P3 P 0.76522(8) 0.13124(7) 0.75742(6) 0.0302(2) Uani 1 1 d . . .
P4 P 0.69454(8) 0.23625(7) 0.62525(6) 0.0309(2) Uani 1 1 d . . .
C1 C 0.7160(3) 0.3457(3) 0.7055(2) 0.0314(9) Uani 1 1 d . . .
H1 H 0.7576 0.3688 0.6646 0.038 Uiso 1 1 calc R . .
C2 C 0.7746(3) 0.2947(2) 0.7663(2) 0.0278(8) Uani 1 1 d . . .
H2 H 0.8407 0.2884 0.7510 0.033 Uiso 1 1 calc R . .
C3 C 0.7129(3) 0.2227(3) 0.7671(2) 0.0299(9) Uani 1 1 d . . .
H3 H 0.6661 0.2109 0.8060 0.036 Uiso 1 1 calc R . .
C4 C 0.6655(3) 0.2709(3) 0.6999(2) 0.0318(9) Uani 1 1 d . . .
H4 H 0.5959 0.2742 0.7070 0.038 Uiso 1 1 calc R . .
N1 N 0.8071(3) 0.5106(2) 0.7440(2) 0.0376(9) Uani 1 1 d . . .
N2 N 0.6562(3) 0.5707(2) 0.7880(2) 0.0407(9) Uani 1 1 d . . .
C101 C 0.8807(4) 0.4783(3) 0.7179(3) 0.0433(11) Uani 1 1 d . . .
H101 H 0.8890 0.4240 0.7351 0.052 Uiso 1 1 calc R . .
C102 C 0.9438(5) 0.5191(4) 0.6681(4) 0.0609(16) Uani 1 1 d . . .
H102 H 0.9940 0.4936 0.6521 0.073 Uiso 1 1 calc R . .
C103 C 0.9318(5) 0.6003(4) 0.6413(4) 0.0704(19) Uani 1 1 d . . .
H103 H 0.9724 0.6302 0.6060 0.084 Uiso 1 1 calc R . .
C104 C 0.8601(5) 0.6343(4) 0.6679(3) 0.0622(16) Uani 1 1 d . . .
H104 H 0.8525 0.6887 0.6522 0.075 Uiso 1 1 calc R . .
C105 C 0.7980(4) 0.5898(3) 0.7179(3) 0.0445(12) Uani 1 1 d . . .
C106 C 0.7151(4) 0.6218(3) 0.7452(3) 0.0482(13) Uani 1 1 d . . .
C107 C 0.6942(6) 0.7023(4) 0.7249(4) 0.0692(19) Uani 1 1 d . . .
H107 H 0.7373 0.7383 0.6965 0.083 Uiso 1 1 calc R . .
C108 C 0.6114(7) 0.7273(4) 0.7466(5) 0.089(3) Uani 1 1 d . . .
H108 H 0.5961 0.7806 0.7323 0.107 Uiso 1 1 calc R . .
C109 C 0.5496(6) 0.6743(4) 0.7896(5) 0.082(2) Uani 1 1 d . . .
H109 H 0.4917 0.6907 0.8049 0.098 Uiso 1 1 calc R . .
C110 C 0.5749(4) 0.5967(4) 0.8096(3) 0.0559(14) Uani 1 1 d . . .
H110 H 0.5337 0.5605 0.8397 0.067 Uiso 1 1 calc R . .
N3 N 0.5984(3) 0.4260(2) 0.8962(2) 0.0417(9) Uani 1 1 d . . .
N4 N 0.7689(3) 0.4792(2) 0.8991(2) 0.0357(8) Uani 1 1 d . . .
C201 C 0.8547(4) 0.5139(3) 0.8943(3) 0.0444(12) Uani 1 1 d . . .
H201 H 0.8877 0.5295 0.8517 0.053 Uiso 1 1 calc R . .
C202 C 0.8954(4) 0.5270(4) 0.9510(3) 0.0556(14) Uani 1 1 d . . .
H202 H 0.9543 0.5526 0.9464 0.067 Uiso 1 1 calc R . .
C203 C 0.8500(5) 0.5028(4) 1.0126(4) 0.0679(18) Uani 1 1 d . . .
H203 H 0.8779 0.5105 1.0512 0.081 Uiso 1 1 calc R . .
C204 C 0.7623(5) 0.4666(4) 1.0193(3) 0.0599(16) Uani 1 1 d . . .
H204 H 0.7304 0.4489 1.0622 0.072 Uiso 1 1 calc R . .
C205 C 0.7225(4) 0.4571(3) 0.9605(3) 0.0440(12) Uani 1 1 d . . .
C206 C 0.6274(4) 0.4264(3) 0.9594(3) 0.0458(12) Uani 1 1 d . . .
C207 C 0.5654(5) 0.4040(4) 1.0167(3) 0.0668(17) Uani 1 1 d . . .
H207 H 0.5868 0.4029 1.0600 0.080 Uiso 1 1 calc R . .
C208 C 0.4736(5) 0.3839(5) 1.0098(4) 0.074(2) Uani 1 1 d . . .
H208 H 0.4323 0.3670 1.0483 0.089 Uiso 1 1 calc R . .
C209 C 0.4433(4) 0.3886(4) 0.9466(4) 0.0620(16) Uani 1 1 d . . .
H209 H 0.3800 0.3766 0.9407 0.074 Uiso 1 1 calc R . .
C210 C 0.5053(4) 0.4109(4) 0.8909(3) 0.0528(14) Uani 1 1 d . . .
H210 H 0.4820 0.4161 0.8471 0.063 Uiso 1 1 calc R . .
N5 N 0.8602(3) 0.1587(2) 0.5456(2) 0.0407(9) Uani 1 1 d . . .
N6 N 0.9145(3) 0.0577(3) 0.6633(2) 0.0421(9) Uani 1 1 d . . .
C301 C 0.8247(5) 0.2014(4) 0.4871(3) 0.0528(14) Uani 1 1 d . . .
H301 H 0.7643 0.2237 0.4879 0.063 Uiso 1 1 calc R . .
C302 C 0.8731(5) 0.2142(4) 0.4250(3) 0.0651(17) Uani 1 1 d . . .
H302 H 0.8458 0.2443 0.3843 0.078 Uiso 1 1 calc R . .
C303 C 0.9608(6) 0.1827(5) 0.4233(4) 0.078(2) Uani 1 1 d . . .
H303 H 0.9954 0.1918 0.3815 0.093 Uiso 1 1 calc R . .
C304 C 0.9988(5) 0.1370(4) 0.4838(4) 0.0697(18) Uani 1 1 d . . .
H304 H 1.0600 0.1158 0.4837 0.084 Uiso 1 1 calc R . .
C305 C 0.9458(4) 0.1232(3) 0.5439(3) 0.0493(13) Uani 1 1 d . . .
C306 C 0.9739(4) 0.0669(3) 0.6087(3) 0.0501(13) Uani 1 1 d . . .
C307 C 1.0536(5) 0.0183(5) 0.6134(4) 0.075(2) Uani 1 1 d . . .
H307 H 1.0974 0.0269 0.5762 0.090 Uiso 1 1 calc R . .
C308 C 1.0679(6) -0.0415(5) 0.6720(4) 0.082(2) Uani 1 1 d . . .
H308 H 1.1203 -0.0750 0.6750 0.098 Uiso 1 1 calc R . .
C309 C 1.0047(6) -0.0517(4) 0.7260(4) 0.073(2) Uani 1 1 d . . .
H309 H 1.0122 -0.0925 0.7668 0.088 Uiso 1 1 calc R . .
C310 C 0.9298(5) -0.0010(3) 0.7193(3) 0.0558(14) Uani 1 1 d . . .
H310 H 0.8867 -0.0082 0.7568 0.067 Uiso 1 1 calc R . .
C11 C 0.6405(4) 0.5067(3) 0.6489(3) 0.0422(11) Uani 1 1 d . . .
C12 C 0.7080(5) 0.5181(3) 0.5960(3) 0.0556(14) Uani 1 1 d . . .
H12 H 0.7507 0.4780 0.5950 0.067 Uiso 1 1 calc R . .
C13 C 0.7127(7) 0.5893(4) 0.5442(4) 0.082(2) Uani 1 1 d . . .
H13 H 0.7595 0.5967 0.5090 0.099 Uiso 1 1 calc R . .
C14 C 0.6513(8) 0.6475(5) 0.5438(4) 0.089(3) Uani 1 1 d . . .
H14 H 0.6559 0.6952 0.5088 0.107 Uiso 1 1 calc R . .
C15 C 0.5820(7) 0.6370(4) 0.5947(4) 0.080(2) Uani 1 1 d . . .
H15 H 0.5382 0.6770 0.5937 0.096 Uiso 1 1 calc R . .
C16 C 0.5765(5) 0.5667(3) 0.6483(3) 0.0566(15) Uani 1 1 d . . .
H16 H 0.5299 0.5600 0.6836 0.068 Uiso 1 1 calc R . .
C21 C 0.5183(3) 0.3833(3) 0.7246(3) 0.0404(11) Uani 1 1 d . . .
C22 C 0.4855(4) 0.3210(4) 0.7785(3) 0.0490(13) Uani 1 1 d . . .
H22 H 0.5238 0.3011 0.8166 0.059 Uiso 1 1 calc R . .
C23 C 0.3987(4) 0.2877(5) 0.7776(4) 0.0687(18) Uani 1 1 d . . .
H23 H 0.3783 0.2453 0.8147 0.082 Uiso 1 1 calc R . .
C24 C 0.3416(4) 0.3160(5) 0.7228(4) 0.073(2) Uani 1 1 d . . .
H24 H 0.2811 0.2942 0.7230 0.087 Uiso 1 1 calc R . .
C25 C 0.3722(5) 0.3753(4) 0.6683(5) 0.073(2) Uani 1 1 d . . .
H25 H 0.3329 0.3934 0.6305 0.088 Uiso 1 1 calc R . .
C26 C 0.4605(4) 0.4102(4) 0.6669(4) 0.0569(15) Uani 1 1 d . . .
H26 H 0.4814 0.4508 0.6284 0.068 Uiso 1 1 calc R . .
C31 C 0.7261(3) 0.2444(3) 0.9122(2) 0.0355(10) Uani 1 1 d . . .
C32 C 0.7848(4) 0.1807(3) 0.9390(3) 0.0431(11) Uani 1 1 d . . .
H32 H 0.8491 0.1832 0.9248 0.052 Uiso 1 1 calc R . .
C33 C 0.7501(5) 0.1142(3) 0.9862(3) 0.0547(14) Uani 1 1 d . . .
H33 H 0.7910 0.0717 1.0034 0.066 Uiso 1 1 calc R . .
C34 C 0.6560(5) 0.1089(4) 1.0087(3) 0.0608(16) Uani 1 1 d . . .
H34 H 0.6329 0.0631 1.0409 0.073 Uiso 1 1 calc R . .
C35 C 0.5965(4) 0.1715(4) 0.9834(3) 0.0571(15) Uani 1 1 d . . .
H35 H 0.5326 0.1685 0.9987 0.069 Uiso 1 1 calc R . .
C36 C 0.6307(4) 0.2389(3) 0.9355(3) 0.0455(12) Uani 1 1 d . . .
H36 H 0.5896 0.2812 0.9185 0.055 Uiso 1 1 calc R . .
C41 C 0.8950(3) 0.3268(3) 0.8730(2) 0.0364(10) Uani 1 1 d . . .
C42 C 0.9760(3) 0.3220(3) 0.8336(3) 0.0444(12) Uani 1 1 d . . .
H42 H 0.9705 0.3210 0.7881 0.053 Uiso 1 1 calc R . .
C43 C 1.0654(4) 0.3185(4) 0.8619(4) 0.0628(17) Uani 1 1 d . . .
H43 H 1.1196 0.3137 0.8353 0.075 Uiso 1 1 calc R . .
C44 C 1.0759(5) 0.3217(4) 0.9267(4) 0.0660(18) Uani 1 1 d . . .
H44 H 1.1367 0.3208 0.9445 0.079 Uiso 1 1 calc R . .
C45 C 0.9969(5) 0.3264(4) 0.9658(4) 0.0620(17) Uani 1 1 d . . .
H45 H 1.0038 0.3280 1.0109 0.074 Uiso 1 1 calc R . .
C46 C 0.9059(4) 0.3288(3) 0.9399(3) 0.0452(12) Uani 1 1 d . . .
H46 H 0.8523 0.3317 0.9677 0.054 Uiso 1 1 calc R . .
C51 C 0.8614(3) 0.0993(3) 0.8155(2) 0.0345(10) Uani 1 1 d . . .
C52 C 0.9468(3) 0.1409(3) 0.7992(3) 0.0404(11) Uani 1 1 d . . .
H52 H 0.9523 0.1847 0.7603 0.048 Uiso 1 1 calc R . .
C53 C 1.0229(4) 0.1167(4) 0.8411(3) 0.0581(15) Uani 1 1 d . . .
H53 H 1.0797 0.1455 0.8316 0.070 Uiso 1 1 calc R . .
C54 C 1.0168(5) 0.0513(5) 0.8964(3) 0.0691(19) Uani 1 1 d . . .
H54 H 1.0697 0.0350 0.9239 0.083 Uiso 1 1 calc R . .
C55 C 0.9343(5) 0.0095(4) 0.9118(3) 0.0616(16) Uani 1 1 d . . .
H55 H 0.9309 -0.0357 0.9496 0.074 Uiso 1 1 calc R . .
C56 C 0.8547(4) 0.0335(3) 0.8717(3) 0.0453(12) Uani 1 1 d . . .
H56 H 0.7976 0.0052 0.8827 0.054 Uiso 1 1 calc R . .
C61 C 0.6682(3) 0.0626(3) 0.7859(3) 0.0363(10) Uani 1 1 d . . .
C62 C 0.6465(4) 0.0126(3) 0.7482(3) 0.0526(14) Uani 1 1 d . . .
H62 H 0.6823 0.0142 0.7082 0.063 Uiso 1 1 calc R . .
C63 C 0.5717(6) -0.0396(4) 0.7697(5) 0.083(2) Uani 1 1 d . . .
H63 H 0.5573 -0.0742 0.7448 0.099 Uiso 1 1 calc R . .
C64 C 0.5188(6) -0.0406(5) 0.8276(5) 0.085(2) Uani 1 1 d . . .
H64 H 0.4673 -0.0752 0.8415 0.102 Uiso 1 1 calc R . .
C65 C 0.5406(5) 0.0085(4) 0.8653(4) 0.076(2) Uani 1 1 d . . .
H65 H 0.5050 0.0062 0.9056 0.091 Uiso 1 1 calc R . .
C66 C 0.6138(4) 0.0606(4) 0.8446(3) 0.0571(15) Uani 1 1 d . . .
H66 H 0.6273 0.0950 0.8699 0.068 Uiso 1 1 calc R . .
C71 C 0.5844(3) 0.1952(3) 0.6070(2) 0.0364(10) Uani 1 1 d . . .
C72 C 0.5892(5) 0.1349(4) 0.5785(4) 0.0629(17) Uani 1 1 d . . .
H72 H 0.6485 0.1151 0.5693 0.076 Uiso 1 1 calc R . .
C73 C 0.5050(6) 0.1031(5) 0.5632(4) 0.080(2) Uani 1 1 d . . .
H73 H 0.5078 0.0619 0.5436 0.096 Uiso 1 1 calc R . .
C74 C 0.4201(5) 0.1315(5) 0.5767(4) 0.074(2) Uani 1 1 d . . .
H74 H 0.3642 0.1097 0.5665 0.089 Uiso 1 1 calc R . .
C75 C 0.4140(4) 0.1914(4) 0.6049(3) 0.0625(16) Uani 1 1 d . . .
H75 H 0.3544 0.2106 0.6141 0.075 Uiso 1 1 calc R . .
C76 C 0.4961(4) 0.2238(4) 0.6198(3) 0.0549(14) Uani 1 1 d . . .
H76 H 0.4922 0.2654 0.6389 0.066 Uiso 1 1 calc R . .
C81 C 0.7222(3) 0.3222(3) 0.5541(2) 0.0348(10) Uani 1 1 d . . .
C82 C 0.8151(4) 0.3503(3) 0.5458(3) 0.0442(12) Uani 1 1 d . . .
H82 H 0.8612 0.3251 0.5769 0.053 Uiso 1 1 calc R . .
C83 C 0.8397(4) 0.4151(4) 0.4918(3) 0.0565(15) Uani 1 1 d . . .
H83 H 0.9021 0.4347 0.4866 0.068 Uiso 1 1 calc R . .
C84 C 0.7722(5) 0.4506(4) 0.4460(3) 0.0699(19) Uani 1 1 d . . .
H84 H 0.7885 0.4951 0.4096 0.084 Uiso 1 1 calc R . .
C85 C 0.6807(6) 0.4220(4) 0.4525(4) 0.076(2) Uani 1 1 d . . .
H85 H 0.6356 0.4460 0.4201 0.091 Uiso 1 1 calc R . .
C86 C 0.6555(4) 0.3577(3) 0.5071(3) 0.0527(14) Uani 1 1 d . . .
H86 H 0.5931 0.3384 0.5120 0.063 Uiso 1 1 calc R . .
P5 P 0.07866(10) 0.31370(11) 0.63184(8) 0.0564(4) Uani 1 1 d . . .
F1 F -0.0233(3) 0.3283(3) 0.6633(2) 0.0809(12) Uani 1 1 d . . .
F2 F 0.1055(3) 0.2590(3) 0.7039(2) 0.1015(17) Uani 1 1 d . . .
F3 F 0.1797(3) 0.3023(4) 0.6017(3) 0.113(2) Uani 1 1 d . . .
F4 F 0.1216(4) 0.3827(3) 0.6565(4) 0.127(2) Uani 1 1 d . . .
F5 F 0.0509(4) 0.3729(5) 0.5631(3) 0.170(4) Uani 1 1 d . . .
F6 F 0.0330(4) 0.2483(5) 0.6101(5) 0.168(4) Uani 1 1 d . . .
P6 P 0.73483(15) 0.91741(12) 0.57893(11) 0.0716(5) Uani 1 1 d . . .
F7 F 0.7582(4) 0.8151(4) 0.1133(3) 0.133(2) Uani 1 1 d . . .
F8 F 0.6200(4) 0.8667(5) 0.0776(4) 0.144(3) Uani 1 1 d . . .
F9 F 0.8096(5) 0.8446(5) 0.0041(4) 0.157(3) Uani 1 1 d . . .
F10 F 0.6848(8) 0.7761(5) 0.0411(6) 0.229(5) Uani 1 1 d . . .
F11 F 0.7567(6) 0.9340(4) 0.0453(6) 0.198(4) Uani 1 1 d . . .
F12 F 0.6751(7) 0.9032(8) -0.0259(5) 0.257(7) Uani 1 1 d . . .
P7 P 0.71337(15) 0.85521(12) 0.04091(11) 0.0756(5) Uani 1 1 d . . .
F13 F 0.0797(7) 0.6695(5) 0.7222(4) 0.171(3) Uani 1 1 d . . .
F14 F 0.0326(8) 0.5982(6) 0.8118(5) 0.220(5) Uani 1 1 d . . .
F15 F 0.1515(9) 0.6613(6) 0.8194(8) 0.253(7) Uani 1 1 d . . .
F16 F 0.0912(11) 0.7689(5) 0.7638(7) 0.256(6) Uani 1 1 d . . .
F17 F -0.0411(7) 0.7108(12) 0.7699(10) 0.360(12) Uani 1 1 d . . .
F18 F 0.0370(9) 0.7070(13) 0.8568(6) 0.328(10) Uani 1 1 d . . .
P8 P 0.05511(18) 0.68827(17) 0.79209(12) 0.0923(7) Uani 1 1 d . . .
F19 F 0.7418(8) 0.9980(5) 0.5945(5) 0.157(3) Uani 0.87 1 d P . .
F20 F 0.6441(6) 0.9597(6) 0.5411(6) 0.175(4) Uani 0.89 1 d P . .
F21 F 0.7677(5) 0.9244(7) 0.5051(3) 0.155(4) Uani 0.83 1 d P . .
F22 F 0.6736(9) 0.8454(5) 0.5801(5) 0.205(5) Uani 0.96 1 d P . .
F23 F 0.8147(6) 0.8634(7) 0.6124(4) 0.195(5) Uani 0.97 1 d P . .
F24 F 0.6974(11) 0.8982(6) 0.6549(5) 0.200(6) Uani 0.80 1 d P . .
F25 F 0.8304(10) 0.9668(9) 0.5613(9) 0.203(7) Uani 0.68 1 d P . .
N7 N 0.7343(6) 0.6679(6) 0.9127(6) 0.119(3) Uani 1 1 d . . .
C91 C 0.7641(8) 0.7281(7) 0.8874(6) 0.102(3) Uani 1 1 d . . .
C92 C 0.8045(11) 0.8053(7) 0.8539(7) 0.148(5) Uani 1 1 d . . .
H92A H 0.8417 0.8039 0.8135 0.221 Uiso 1 1 calc R . .
H92B H 0.8449 0.8203 0.8854 0.221 Uiso 1 1 calc R . .
H92C H 0.7536 0.8430 0.8406 0.221 Uiso 1 1 calc R . .
N8 N 0.3463(8) 0.5454(9) 0.8215(7) 0.181(6) Uani 1 1 d . . .
C93 C 0.2927(9) 0.5399(13) 0.7834(7) 0.181(8) Uani 1 1 d . . .
C94 C 0.2192(14) 0.5195(13) 0.7449(10) 0.232(11) Uani 1 1 d . . .
H94A H 0.2337 0.4695 0.7378 0.348 Uiso 1 1 calc R . .
H94B H 0.2152 0.5591 0.7009 0.348 Uiso 1 1 calc R . .
H94C H 0.1589 0.5161 0.7700 0.348 Uiso 1 1 calc R . .
N9 N 0.390(3) -0.2128(17) 0.833(2) 0.24(2) Uani 0.50 1 d P . .
C95 C 0.318(2) -0.2163(14) 0.8542(17) 0.123(10) Uani 0.50 1 d P . .
C96 C 0.240(2) -0.210(3) 0.8831(18) 0.22(2) Uani 0.50 1 d P . .
H96A H 0.2337 -0.2514 0.9262 0.326 Uiso 0.50 1 calc PR . .
H96B H 0.1886 -0.2144 0.8537 0.326 Uiso 0.50 1 calc PR . .
H96C H 0.2364 -0.1599 0.8917 0.326 Uiso 0.50 1 calc PR . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 N3 2.095(4) . ?
Os1 N1 2.109(4) . ?
Os1 N4 2.113(4) . ?
Os1 N2 2.131(4) . ?
Os1 P1 2.3096(13) . ?
Os1 P2 2.3193(14) . ?
Pd1 N6 2.105(4) . ?
Pd1 N5 2.113(4) . ?
Pd1 P4 2.2557(14) . ?
Pd1 P3 2.2651(13) . ?
P1 C11 1.830(5) . ?
P1 C21 1.839(5) . ?
P1 C1 1.888(5) . ?
P2 C31 1.838(5) . ?
P2 C41 1.840(5) . ?
P2 C2 1.889(4) . ?
P3 C51 1.807(5) . ?
P3 C61 1.811(5) . ?
P3 C3 1.856(5) . ?
P4 C81 1.813(5) . ?
P4 C71 1.819(5) . ?
P4 C4 1.845(5) . ?
C1 C4 1.559(6) . ?
C1 C2 1.562(6) . ?
C1 H1 0.9900 . ?
C2 C3 1.560(6) . ?
C2 H2 0.9900 . ?
C3 C4 1.557(6) . ?
C3 H3 0.9900 . ?
C4 H4 0.9900 . ?
N1 C101 1.356(7) . ?
N1 C105 1.368(6) . ?
N2 C106 1.337(7) . ?
N2 C110 1.343(7) . ?
C101 C102 1.368(8) . ?
C101 H101 0.9400 . ?
C102 C103 1.409(9) . ?
C102 H102 0.9400 . ?
C103 C104 1.355(10) . ?
C103 H103 0.9400 . ?
C104 C105 1.385(8) . ?
C104 H104 0.9400 . ?
C105 C106 1.464(8) . ?
C106 C107 1.412(8) . ?
C107 C108 1.354(11) . ?
C107 H107 0.9400 . ?
C108 C109 1.381(11) . ?
C108 H108 0.9400 . ?
C109 C110 1.378(9) . ?
C109 H109 0.9400 . ?
C110 H110 0.9400 . ?
N3 C210 1.356(7) . ?
N3 C206 1.370(7) . ?
N4 C205 1.347(7) . ?
N4 C201 1.353(6) . ?
C201 C202 1.391(8) . ?
C201 H201 0.9400 . ?
C202 C203 1.344(9) . ?
C202 H202 0.9400 . ?
C203 C204 1.385(10) . ?
C203 H203 0.9400 . ?
C204 C205 1.399(8) . ?
C204 H204 0.9400 . ?
C205 C206 1.456(8) . ?
C206 C207 1.398(8) . ?
C207 C208 1.368(10) . ?
C207 H207 0.9400 . ?
C208 C209 1.352(10) . ?
C208 H208 0.9400 . ?
C209 C210 1.374(8) . ?
C209 H209 0.9400 . ?
C210 H210 0.9400 . ?
N5 C301 1.325(7) . ?
N5 C305 1.363(7) . ?
N6 C310 1.329(7) . ?
N6 C306 1.344(7) . ?
C301 C302 1.379(8) . ?
C301 H301 0.9400 . ?
C302 C303 1.358(10) . ?
C302 H302 0.9400 . ?
C303 C304 1.386(11) . ?
C303 H303 0.9400 . ?
C304 C305 1.376(8) . ?
C304 H304 0.9400 . ?
C305 C306 1.471(8) . ?
C306 C307 1.405(8) . ?
C307 C308 1.370(11) . ?
C307 H307 0.9400 . ?
C308 C309 1.365(11) . ?
C308 H308 0.9400 . ?
C309 C310 1.371(9) . ?
C309 H309 0.9400 . ?
C310 H310 0.9400 . ?
C11 C12 1.384(8) . ?
C11 C16 1.397(8) . ?
C12 C13 1.397(8) . ?
C12 H12 0.9400 . ?
C13 C14 1.351(12) . ?
C13 H13 0.9400 . ?
C14 C15 1.375(13) . ?
C14 H14 0.9400 . ?
C15 C16 1.405(9) . ?
C15 H15 0.9400 . ?
C16 H16 0.9400 . ?
C21 C22 1.386(8) . ?
C21 C26 1.416(8) . ?
C22 C23 1.368(8) . ?
C22 H22 0.9400 . ?
C23 C24 1.368(11) . ?
C23 H23 0.9400 . ?
C24 C25 1.354(11) . ?
C24 H24 0.9400 . ?
C25 C26 1.394(9) . ?
C25 H25 0.9400 . ?
C26 H26 0.9400 . ?
C31 C32 1.390(7) . ?
C31 C36 1.407(7) . ?
C32 C33 1.374(7) . ?
C32 H32 0.9400 . ?
C33 C34 1.385(9) . ?
C33 H33 0.9400 . ?
C34 C35 1.379(9) . ?
C34 H34 0.9400 . ?
C35 C36 1.390(8) . ?
C35 H35 0.9400 . ?
C36 H36 0.9400 . ?
C41 C42 1.392(7) . ?
C41 C46 1.393(7) . ?
C42 C43 1.396(8) . ?
C42 H42 0.9400 . ?
C43 C44 1.357(10) . ?
C43 H43 0.9400 . ?
C44 C45 1.365(10) . ?
C44 H44 0.9400 . ?
C45 C46 1.397(8) . ?
C45 H45 0.9400 . ?
C46 H46 0.9400 . ?
C51 C56 1.382(7) . ?
C51 C52 1.400(7) . ?
C52 C53 1.379(8) . ?
C52 H52 0.9400 . ?
C53 C54 1.367(9) . ?
C53 H53 0.9400 . ?
C54 C55 1.366(10) . ?
C54 H54 0.9400 . ?
C55 C56 1.398(8) . ?
C55 H55 0.9400 . ?
C56 H56 0.9400 . ?
C61 C62 1.387(7) . ?
C61 C66 1.394(8) . ?
C62 C63 1.387(9) . ?
C62 H62 0.9400 . ?
C63 C64 1.372(11) . ?
C63 H63 0.9400 . ?
C64 C65 1.375(11) . ?
C64 H64 0.9400 . ?
C65 C66 1.367(8) . ?
C65 H65 0.9400 . ?
C66 H66 0.9400 . ?
C71 C72 1.373(8) . ?
C71 C76 1.388(8) . ?
C72 C73 1.405(9) . ?
C72 H72 0.9400 . ?
C73 C74 1.348(11) . ?
C73 H73 0.9400 . ?
C74 C75 1.364(10) . ?
C74 H74 0.9400 . ?
C75 C76 1.381(8) . ?
C75 H75 0.9400 . ?
C76 H76 0.9400 . ?
C81 C86 1.378(7) . ?
C81 C82 1.394(7) . ?
C82 C83 1.382(8) . ?
C82 H82 0.9400 . ?
C83 C84 1.372(10) . ?
C83 H83 0.9400 . ?
C84 C85 1.379(10) . ?
C84 H84 0.9400 . ?
C85 C86 1.385(8) . ?
C85 H85 0.9400 . ?
C86 H86 0.9400 . ?
P5 F6 1.527(6) . ?
P5 F5 1.549(6) . ?
P5 F2 1.564(5) . ?
P5 F3 1.569(4) . ?
P5 F4 1.600(6) . ?
P5 F1 1.607(4) . ?
P6 F23 1.521(7) . ?
P6 F21 1.534(7) . ?
P6 F22 1.554(8) . ?
P6 F24 1.562(8) . ?
P6 F19 1.576(8) . ?
P6 F20 1.584(8) . ?
P6 F25 1.590(11) . ?
F7 P7 1.589(6) . ?
F8 P7 1.536(6) . ?
F9 P7 1.568(6) . ?
F10 P7 1.479(7) . ?
F11 P7 1.574(8) . ?
F12 P7 1.496(7) . ?
F13 P8 1.590(8) . ?
F14 P8 1.579(9) . ?
F15 P8 1.507(9) . ?
F16 P8 1.479(9) . ?
F17 P8 1.460(9) . ?
F18 P8 1.473(9) . ?
F19 F25 1.579(16) . ?
N7 C91 1.129(12) . ?
C91 C92 1.462(15) . ?
C92 H92A 0.9700 . ?
C92 H92B 0.9700 . ?
C92 H92C 0.9700 . ?
N8 C93 1.126(17) . ?
C93 C94 1.43(2) . ?
C94 H94A 0.9700 . ?
C94 H94B 0.9700 . ?
C94 H94C 0.9700 . ?
N9 C95 1.09(4) . ?
C95 C96 1.25(4) . ?
C96 H96A 0.9728 . ?
C96 H96B 0.9742 . ?
C96 H96C 0.9737 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Os1 N1 163.39(16) . . ?
N3 Os1 N4 76.36(17) . . ?
N1 Os1 N4 93.69(15) . . ?
N3 Os1 N2 89.23(17) . . ?
N1 Os1 N2 76.64(16) . . ?
N4 Os1 N2 85.83(16) . . ?
N3 Os1 P1 106.25(13) . . ?
N1 Os1 P1 84.05(11) . . ?
N4 Os1 P1 177.10(11) . . ?
N2 Os1 P1 95.40(12) . . ?
N3 Os1 P2 96.68(12) . . ?
N1 Os1 P2 96.93(12) . . ?
N4 Os1 P2 91.97(11) . . ?
N2 Os1 P2 173.03(12) . . ?
P1 Os1 P2 86.50(5) . . ?
N6 Pd1 N5 78.80(17) . . ?
N6 Pd1 P4 177.10(12) . . ?
N5 Pd1 P4 99.26(12) . . ?
N6 Pd1 P3 99.10(12) . . ?
N5 Pd1 P3 176.31(12) . . ?
P4 Pd1 P3 82.95(5) . . ?
C11 P1 C21 101.9(2) . . ?
C11 P1 C1 106.5(2) . . ?
C21 P1 C1 102.3(2) . . ?
C11 P1 Os1 111.39(17) . . ?
C21 P1 Os1 125.67(17) . . ?
C1 P1 Os1 107.49(14) . . ?
C31 P2 C41 98.2(2) . . ?
C31 P2 C2 102.5(2) . . ?
C41 P2 C2 106.8(2) . . ?
C31 P2 Os1 124.28(16) . . ?
C41 P2 Os1 114.44(16) . . ?
C2 P2 Os1 108.89(14) . . ?
C51 P3 C61 108.2(2) . . ?
C51 P3 C3 110.3(2) . . ?
C61 P3 C3 102.4(2) . . ?
C51 P3 Pd1 112.67(16) . . ?
C61 P3 Pd1 111.51(17) . . ?
C3 P3 Pd1 111.26(15) . . ?
C81 P4 C71 107.8(2) . . ?
C81 P4 C4 106.5(2) . . ?
C71 P4 C4 105.1(2) . . ?
C81 P4 Pd1 114.38(16) . . ?
C71 P4 Pd1 110.25(16) . . ?
C4 P4 Pd1 112.32(15) . . ?
C4 C1 C2 90.0(3) . . ?
C4 C1 P1 116.9(3) . . ?
C2 C1 P1 115.5(3) . . ?
C4 C1 H1 111.0 . . ?
C2 C1 H1 111.0 . . ?
P1 C1 H1 111.0 . . ?
C3 C2 C1 89.2(3) . . ?
C3 C2 P2 118.8(3) . . ?
C1 C2 P2 114.6(3) . . ?
C3 C2 H2 110.8 . . ?
C1 C2 H2 110.8 . . ?
P2 C2 H2 110.8 . . ?
C4 C3 C2 90.2(3) . . ?
C4 C3 P3 111.1(3) . . ?
C2 C3 P3 122.5(3) . . ?
C4 C3 H3 110.4 . . ?
C2 C3 H3 110.4 . . ?
P3 C3 H3 110.4 . . ?
C3 C4 C1 89.4(3) . . ?
C3 C4 P4 113.9(3) . . ?
C1 C4 P4 118.7(3) . . ?
C3 C4 H4 111.0 . . ?
C1 C4 H4 111.0 . . ?
P4 C4 H4 111.0 . . ?
C101 N1 C105 115.9(4) . . ?
C101 N1 Os1 127.4(3) . . ?
C105 N1 Os1 116.6(3) . . ?
C106 N2 C110 119.1(5) . . ?
C106 N2 Os1 115.4(3) . . ?
C110 N2 Os1 125.6(4) . . ?
N1 C101 C102 124.5(5) . . ?
N1 C101 H101 117.7 . . ?
C102 C101 H101 117.7 . . ?
C101 C102 C103 118.3(6) . . ?
C101 C102 H102 120.8 . . ?
C103 C102 H102 120.8 . . ?
C104 C103 C102 118.3(6) . . ?
C104 C103 H103 120.9 . . ?
C102 C103 H103 120.9 . . ?
C103 C104 C105 120.7(6) . . ?
C103 C104 H104 119.6 . . ?
C105 C104 H104 119.6 . . ?
N1 C105 C104 122.2(5) . . ?
N1 C105 C106 114.1(5) . . ?
C104 C105 C106 123.6(5) . . ?
N2 C106 C107 120.5(5) . . ?
N2 C106 C105 116.9(5) . . ?
C107 C106 C105 122.4(5) . . ?
C108 C107 C106 119.5(7) . . ?
C108 C107 H107 120.2 . . ?
C106 C107 H107 120.2 . . ?
C107 C108 C109 119.8(6) . . ?
C107 C108 H108 120.1 . . ?
C109 C108 H108 120.1 . . ?
C110 C109 C108 118.3(7) . . ?
C110 C109 H109 120.8 . . ?
C108 C109 H109 120.8 . . ?
N2 C110 C109 122.7(6) . . ?
N2 C110 H110 118.7 . . ?
C109 C110 H110 118.6 . . ?
C210 N3 C206 116.8(5) . . ?
C210 N3 Os1 127.2(4) . . ?
C206 N3 Os1 115.9(3) . . ?
C205 N4 C201 118.6(4) . . ?
C205 N4 Os1 116.6(3) . . ?
C201 N4 Os1 124.7(3) . . ?
N4 C201 C202 121.5(5) . . ?
N4 C201 H201 119.2 . . ?
C202 C201 H201 119.2 . . ?
C203 C202 C201 119.6(6) . . ?
C203 C202 H202 120.2 . . ?
C201 C202 H202 120.2 . . ?
C202 C203 C204 120.3(6) . . ?
C202 C203 H203 119.9 . . ?
C204 C203 H203 119.8 . . ?
C203 C204 C205 118.2(6) . . ?
C203 C204 H204 120.9 . . ?
C205 C204 H204 120.9 . . ?
N4 C205 C204 121.7(5) . . ?
N4 C205 C206 114.6(4) . . ?
C204 C205 C206 123.6(5) . . ?
N3 C206 C207 120.7(5) . . ?
N3 C206 C205 115.2(4) . . ?
C207 C206 C205 123.9(5) . . ?
C208 C207 C206 120.2(6) . . ?
C208 C207 H207 119.9 . . ?
C206 C207 H207 119.9 . . ?
C209 C208 C207 119.0(6) . . ?
C209 C208 H208 120.5 . . ?
C207 C208 H208 120.5 . . ?
C208 C209 C210 119.9(6) . . ?
C208 C209 H209 120.0 . . ?
C210 C209 H209 120.0 . . ?
N3 C210 C209 122.9(6) . . ?
N3 C210 H210 118.5 . . ?
C209 C210 H210 118.5 . . ?
C301 N5 C305 118.7(5) . . ?
C301 N5 Pd1 129.0(4) . . ?
C305 N5 Pd1 112.0(3) . . ?
C310 N6 C306 118.4(5) . . ?
C310 N6 Pd1 128.9(4) . . ?
C306 N6 Pd1 112.7(4) . . ?
N5 C301 C302 122.4(6) . . ?
N5 C301 H301 118.8 . . ?
C302 C301 H301 118.8 . . ?
C303 C302 C301 119.2(6) . . ?
C303 C302 H302 120.4 . . ?
C301 C302 H302 120.4 . . ?
C302 C303 C304 119.3(6) . . ?
C302 C303 H303 120.3 . . ?
C304 C303 H303 120.4 . . ?
C305 C304 C303 119.1(7) . . ?
C305 C304 H304 120.4 . . ?
C303 C304 H304 120.4 . . ?
N5 C305 C304 120.9(6) . . ?
N5 C305 C306 116.0(5) . . ?
C304 C305 C306 123.0(6) . . ?
N6 C306 C307 119.9(6) . . ?
N6 C306 C305 116.9(5) . . ?
C307 C306 C305 122.9(6) . . ?
C308 C307 C306 120.3(7) . . ?
C308 C307 H307 119.8 . . ?
C306 C307 H307 119.8 . . ?
C309 C308 C307 118.8(6) . . ?
C309 C308 H308 120.6 . . ?
C307 C308 H308 120.6 . . ?
C308 C309 C310 118.4(7) . . ?
C308 C309 H309 120.8 . . ?
C310 C309 H309 120.8 . . ?
N6 C310 C309 124.1(6) . . ?
N6 C310 H310 117.9 . . ?
C309 C310 H310 118.0 . . ?
C12 C11 C16 118.8(5) . . ?
C12 C11 P1 124.1(4) . . ?
C16 C11 P1 116.6(4) . . ?
C11 C12 C13 120.1(7) . . ?
C11 C12 H12 119.9 . . ?
C13 C12 H12 119.9 . . ?
C14 C13 C12 121.2(8) . . ?
C14 C13 H13 119.4 . . ?
C12 C13 H13 119.4 . . ?
C13 C14 C15 119.9(7) . . ?
C13 C14 H14 120.1 . . ?
C15 C14 H14 120.1 . . ?
C14 C15 C16 120.3(7) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C11 C16 C15 119.7(7) . . ?
C11 C16 H16 120.2 . . ?
C15 C16 H16 120.2 . . ?
C22 C21 C26 117.9(5) . . ?
C22 C21 P1 120.1(4) . . ?
C26 C21 P1 121.8(4) . . ?
C23 C22 C21 121.7(6) . . ?
C23 C22 H22 119.2 . . ?
C21 C22 H22 119.2 . . ?
C22 C23 C24 120.1(7) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 H23 119.9 . . ?
C25 C24 C23 120.1(6) . . ?
C25 C24 H24 119.9 . . ?
C23 C24 H24 120.0 . . ?
C24 C25 C26 121.5(6) . . ?
C24 C25 H25 119.2 . . ?
C26 C25 H25 119.2 . . ?
C25 C26 C21 118.6(6) . . ?
C25 C26 H26 120.7 . . ?
C21 C26 H26 120.7 . . ?
C32 C31 C36 117.9(4) . . ?
C32 C31 P2 120.1(4) . . ?
C36 C31 P2 121.9(4) . . ?
C33 C32 C31 120.9(5) . . ?
C33 C32 H32 119.6 . . ?
C31 C32 H32 119.5 . . ?
C32 C33 C34 121.0(6) . . ?
C32 C33 H33 119.5 . . ?
C34 C33 H33 119.5 . . ?
C35 C34 C33 119.2(5) . . ?
C35 C34 H34 120.4 . . ?
C33 C34 H34 120.4 . . ?
C34 C35 C36 120.2(6) . . ?
C34 C35 H35 119.9 . . ?
C36 C35 H35 119.9 . . ?
C35 C36 C31 120.7(5) . . ?
C35 C36 H36 119.7 . . ?
C31 C36 H36 119.7 . . ?
C42 C41 C46 118.6(5) . . ?
C42 C41 P2 125.6(4) . . ?
C46 C41 P2 115.9(4) . . ?
C41 C42 C43 119.7(5) . . ?
C41 C42 H42 120.1 . . ?
C43 C42 H42 120.1 . . ?
C44 C43 C42 121.6(6) . . ?
C44 C43 H43 119.2 . . ?
C42 C43 H43 119.2 . . ?
C43 C44 C45 119.1(6) . . ?
C43 C44 H44 120.5 . . ?
C45 C44 H44 120.5 . . ?
C44 C45 C46 121.3(6) . . ?
C44 C45 H45 119.4 . . ?
C46 C45 H45 119.4 . . ?
C41 C46 C45 119.8(6) . . ?
C41 C46 H46 120.1 . . ?
C45 C46 H46 120.1 . . ?
C56 C51 C52 120.2(5) . . ?
C56 C51 P3 122.3(4) . . ?
C52 C51 P3 117.3(4) . . ?
C53 C52 C51 119.0(5) . . ?
C53 C52 H52 120.5 . . ?
C51 C52 H52 120.5 . . ?
C54 C53 C52 120.9(6) . . ?
C54 C53 H53 119.6 . . ?
C52 C53 H53 119.6 . . ?
C55 C54 C53 120.4(6) . . ?
C55 C54 H54 119.8 . . ?
C53 C54 H54 119.8 . . ?
C54 C55 C56 120.4(6) . . ?
C54 C55 H55 119.8 . . ?
C56 C55 H55 119.8 . . ?
C51 C56 C55 119.0(5) . . ?
C51 C56 H56 120.5 . . ?
C55 C56 H56 120.5 . . ?
C62 C61 C66 119.7(5) . . ?
C62 C61 P3 119.7(4) . . ?
C66 C61 P3 120.6(4) . . ?
C61 C62 C63 119.7(6) . . ?
C61 C62 H62 120.2 . . ?
C63 C62 H62 120.2 . . ?
C64 C63 C62 119.8(7) . . ?
C64 C63 H63 120.1 . . ?
C62 C63 H63 120.1 . . ?
C63 C64 C65 120.6(6) . . ?
C63 C64 H64 119.7 . . ?
C65 C64 H64 119.7 . . ?
C66 C65 C64 120.3(6) . . ?
C66 C65 H65 119.8 . . ?
C64 C65 H65 119.8 . . ?
C65 C66 C61 119.8(6) . . ?
C65 C66 H66 120.1 . . ?
C61 C66 H66 120.1 . . ?
C72 C71 C76 119.2(5) . . ?
C72 C71 P4 118.7(4) . . ?
C76 C71 P4 122.1(4) . . ?
C71 C72 C73 119.5(6) . . ?
C71 C72 H72 120.2 . . ?
C73 C72 H72 120.2 . . ?
C74 C73 C72 120.1(6) . . ?
C74 C73 H73 120.0 . . ?
C72 C73 H73 120.0 . . ?
C73 C74 C75 121.2(6) . . ?
C73 C74 H74 119.4 . . ?
C75 C74 H74 119.4 . . ?
C74 C75 C76 119.5(6) . . ?
C74 C75 H75 120.2 . . ?
C76 C75 H75 120.2 . . ?
C75 C76 C71 120.5(6) . . ?
C75 C76 H76 119.8 . . ?
C71 C76 H76 119.8 . . ?
C86 C81 C82 119.8(5) . . ?
C86 C81 P4 122.0(4) . . ?
C82 C81 P4 118.2(4) . . ?
C83 C82 C81 120.2(5) . . ?
C83 C82 H82 119.9 . . ?
C81 C82 H82 119.9 . . ?
C84 C83 C82 119.3(6) . . ?
C84 C83 H83 120.3 . . ?
C82 C83 H83 120.3 . . ?
C83 C84 C85 121.0(6) . . ?
C83 C84 H84 119.5 . . ?
C85 C84 H84 119.5 . . ?
C84 C85 C86 119.8(6) . . ?
C84 C85 H85 120.1 . . ?
C86 C85 H85 120.1 . . ?
C81 C86 C85 119.9(6) . . ?
C81 C86 H86 120.1 . . ?
C85 C86 H86 120.1 . . ?
F6 P5 F5 89.7(5) . . ?
F6 P5 F2 94.0(5) . . ?
F5 P5 F2 175.6(5) . . ?
F6 P5 F3 94.3(4) . . ?
F5 P5 F3 91.5(3) . . ?
F2 P5 F3 90.7(3) . . ?
F6 P5 F4 177.2(4) . . ?
F5 P5 F4 90.5(5) . . ?
F2 P5 F4 85.8(4) . . ?
F3 P5 F4 88.5(4) . . ?
F6 P5 F1 87.9(3) . . ?
F5 P5 F1 88.3(3) . . ?
F2 P5 F1 89.4(2) . . ?
F3 P5 F1 177.8(3) . . ?
F4 P5 F1 89.3(3) . . ?
F23 P6 F21 95.4(5) . . ?
F23 P6 F22 89.8(7) . . ?
F21 P6 F22 89.5(6) . . ?
F23 P6 F24 81.9(6) . . ?
F21 P6 F24 171.9(6) . . ?
F22 P6 F24 82.8(6) . . ?
F23 P6 F19 110.7(6) . . ?
F21 P6 F19 111.5(6) . . ?
F22 P6 F19 148.2(7) . . ?
F24 P6 F19 76.6(5) . . ?
F23 P6 F20 169.3(6) . . ?
F21 P6 F20 81.6(5) . . ?
F22 P6 F20 79.9(6) . . ?
F24 P6 F20 99.5(7) . . ?
F19 P6 F20 79.9(5) . . ?
F23 P6 F25 73.0(8) . . ?
F21 P6 F25 70.8(7) . . ?
F22 P6 F25 152.0(8) . . ?
F24 P6 F25 115.4(8) . . ?
F19 P6 F25 59.8(6) . . ?
F20 P6 F25 115.2(9) . . ?
F10 P7 F12 100.8(9) . . ?
F10 P7 F8 91.8(5) . . ?
F12 P7 F8 89.9(5) . . ?
F10 P7 F9 89.2(5) . . ?
F12 P7 F9 90.5(5) . . ?
F8 P7 F9 178.9(5) . . ?
F10 P7 F11 172.1(7) . . ?
F12 P7 F11 85.5(7) . . ?
F8 P7 F11 93.0(5) . . ?
F9 P7 F11 86.0(5) . . ?
F10 P7 F7 86.9(6) . . ?
F12 P7 F7 172.3(7) . . ?
F8 P7 F7 89.5(4) . . ?
F9 P7 F7 90.0(4) . . ?
F11 P7 F7 86.9(5) . . ?
F17 P8 F18 91.7(8) . . ?
F17 P8 F16 92.8(10) . . ?
F18 P8 F16 86.6(10) . . ?
F17 P8 F15 176.1(11) . . ?
F18 P8 F15 86.0(8) . . ?
F16 P8 F15 90.3(8) . . ?
F17 P8 F14 93.4(9) . . ?
F18 P8 F14 103.5(9) . . ?
F16 P8 F14 168.0(8) . . ?
F15 P8 F14 84.1(7) . . ?
F17 P8 F13 90.5(6) . . ?
F18 P8 F13 177.3(7) . . ?
F16 P8 F13 91.7(7) . . ?
F15 P8 F13 91.8(7) . . ?
F14 P8 F13 78.0(5) . . ?
P6 F19 F25 60.5(5) . . ?
F19 F25 P6 59.7(6) . . ?
N7 C91 C92 178.7(12) . . ?
C91 C92 H92A 109.5 . . ?
C91 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C91 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
N8 C93 C94 169(2) . . ?
C93 C94 H94A 109.5 . . ?
C93 C94 H94B 109.4 . . ?
H94A C94 H94B 109.5 . . ?
C93 C94 H94C 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
N9 C95 C96 169(3) . . ?
C95 C96 H96A 110.00 . . ?
C95 C96 H96B 109.00 . . ?
H96A C96 H96B 108.6 . . ?
C95 C96 H96C 110.4 . . ?
H96A C96 H96C 109.4 . . ?
H96B C96 H96C 109.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Os1 P1 C11 123.8(2) . . . . ?
N1 Os1 P1 C11 -42.9(2) . . . . ?
N2 Os1 P1 C11 33.1(2) . . . . ?
P2 Os1 P1 C11 -140.2(2) . . . . ?
N3 Os1 P1 C21 0.2(2) . . . . ?
N1 Os1 P1 C21 -166.5(2) . . . . ?
N2 Os1 P1 C21 -90.6(2) . . . . ?
P2 Os1 P1 C21 96.1(2) . . . . ?
N3 Os1 P1 C1 -119.87(19) . . . . ?
N1 Os1 P1 C1 73.43(19) . . . . ?
N2 Os1 P1 C1 149.36(19) . . . . ?
P2 Os1 P1 C1 -23.92(15) . . . . ?
N3 Os1 P2 C31 5.1(2) . . . . ?
N1 Os1 P2 C31 175.6(2) . . . . ?
N4 Os1 P2 C31 81.6(2) . . . . ?
P1 Os1 P2 C31 -100.87(19) . . . . ?
N3 Os1 P2 C41 -114.8(2) . . . . ?
N1 Os1 P2 C41 55.7(2) . . . . ?
N4 Os1 P2 C41 -38.3(2) . . . . ?
P1 Os1 P2 C41 139.23(18) . . . . ?
N3 Os1 P2 C2 125.77(19) . . . . ?
N1 Os1 P2 C2 -63.77(18) . . . . ?
N4 Os1 P2 C2 -157.73(18) . . . . ?
P1 Os1 P2 C2 19.80(15) . . . . ?
N6 Pd1 P3 C51 31.1(2) . . . . ?
P4 Pd1 P3 C51 -150.96(18) . . . . ?
N6 Pd1 P3 C61 -90.8(2) . . . . ?
P4 Pd1 P3 C61 87.16(17) . . . . ?
N6 Pd1 P3 C3 155.53(19) . . . . ?
P4 Pd1 P3 C3 -26.54(15) . . . . ?
N5 Pd1 P4 C81 -35.0(2) . . . . ?
P3 Pd1 P4 C81 141.97(17) . . . . ?
N5 Pd1 P4 C71 86.6(2) . . . . ?
P3 Pd1 P4 C71 -96.42(18) . . . . ?
N5 Pd1 P4 C4 -156.6(2) . . . . ?
P3 Pd1 P4 C4 20.42(16) . . . . ?
C11 P1 C1 C4 -111.7(3) . . . . ?
C21 P1 C1 C4 -5.2(4) . . . . ?
Os1 P1 C1 C4 128.8(3) . . . . ?
C11 P1 C1 C2 144.3(3) . . . . ?
C21 P1 C1 C2 -109.2(3) . . . . ?
Os1 P1 C1 C2 24.8(3) . . . . ?
C4 C1 C2 C3 -7.9(3) . . . . ?
P1 C1 C2 C3 112.2(3) . . . . ?
C4 C1 C2 P2 -129.5(3) . . . . ?
P1 C1 C2 P2 -9.4(4) . . . . ?
C31 P2 C2 C3 19.5(4) . . . . ?
C41 P2 C2 C3 122.1(3) . . . . ?
Os1 P2 C2 C3 -113.8(3) . . . . ?
C31 P2 C2 C1 123.1(3) . . . . ?
C41 P2 C2 C1 -134.3(3) . . . . ?
Os1 P2 C2 C1 -10.2(3) . . . . ?
C1 C2 C3 C4 7.9(3) . . . . ?
P2 C2 C3 C4 125.8(3) . . . . ?
C1 C2 C3 P3 123.3(3) . . . . ?
P2 C2 C3 P3 -118.8(3) . . . . ?
C51 P3 C3 C4 154.1(3) . . . . ?
C61 P3 C3 C4 -90.9(3) . . . . ?
Pd1 P3 C3 C4 28.4(3) . . . . ?
C51 P3 C3 C2 49.6(4) . . . . ?
C61 P3 C3 C2 164.6(3) . . . . ?
Pd1 P3 C3 C2 -76.1(3) . . . . ?
C2 C3 C4 C1 -7.9(3) . . . . ?
P3 C3 C4 C1 -133.2(3) . . . . ?
C2 C3 C4 P4 113.5(3) . . . . ?
P3 C3 C4 P4 -11.8(4) . . . . ?
C2 C1 C4 C3 7.9(3) . . . . ?
P1 C1 C4 C3 -110.9(3) . . . . ?
C2 C1 C4 P4 -109.3(3) . . . . ?
P1 C1 C4 P4 131.9(3) . . . . ?
C81 P4 C4 C3 -135.1(3) . . . . ?
C71 P4 C4 C3 110.7(3) . . . . ?
Pd1 P4 C4 C3 -9.2(3) . . . . ?
C81 P4 C4 C1 -31.8(4) . . . . ?
C71 P4 C4 C1 -145.9(3) . . . . ?
Pd1 P4 C4 C1 94.2(3) . . . . ?
N3 Os1 N1 C101 153.0(5) . . . . ?
N4 Os1 N1 C101 100.6(4) . . . . ?
N2 Os1 N1 C101 -174.6(4) . . . . ?
P1 Os1 N1 C101 -77.6(4) . . . . ?
P2 Os1 N1 C101 8.1(4) . . . . ?
N3 Os1 N1 C105 -29.4(7) . . . . ?
N4 Os1 N1 C105 -81.8(4) . . . . ?
N2 Os1 N1 C105 3.0(3) . . . . ?
P1 Os1 N1 C105 100.0(3) . . . . ?
P2 Os1 N1 C105 -174.2(3) . . . . ?
N3 Os1 N2 C106 165.9(4) . . . . ?
N1 Os1 N2 C106 -5.3(4) . . . . ?
N4 Os1 N2 C106 89.5(4) . . . . ?
P1 Os1 N2 C106 -87.8(4) . . . . ?
N3 Os1 N2 C110 -13.1(5) . . . . ?
N1 Os1 N2 C110 175.7(5) . . . . ?
N4 Os1 N2 C110 -89.5(5) . . . . ?
P1 Os1 N2 C110 93.2(5) . . . . ?
C105 N1 C101 C102 -0.5(8) . . . . ?
Os1 N1 C101 C102 177.1(5) . . . . ?
N1 C101 C102 C103 -0.5(10) . . . . ?
C101 C102 C103 C104 2.1(11) . . . . ?
C102 C103 C104 C105 -2.7(11) . . . . ?
C101 N1 C105 C104 -0.1(8) . . . . ?
Os1 N1 C105 C104 -178.0(5) . . . . ?
C101 N1 C105 C106 177.3(5) . . . . ?
Os1 N1 C105 C106 -0.6(6) . . . . ?
C103 C104 C105 N1 1.7(10) . . . . ?
C103 C104 C105 C106 -175.4(6) . . . . ?
C110 N2 C106 C107 2.3(9) . . . . ?
Os1 N2 C106 C107 -176.8(5) . . . . ?
C110 N2 C106 C105 -174.2(5) . . . . ?
Os1 N2 C106 C105 6.7(6) . . . . ?
N1 C105 C106 N2 -4.1(7) . . . . ?
C104 C105 C106 N2 173.2(6) . . . . ?
N1 C105 C106 C107 179.5(6) . . . . ?
C104 C105 C106 C107 -3.2(9) . . . . ?
N2 C106 C107 C108 -3.1(11) . . . . ?
C105 C106 C107 C108 173.2(7) . . . . ?
C106 C107 C108 C109 1.7(13) . . . . ?
C107 C108 C109 C110 0.4(14) . . . . ?
C106 N2 C110 C109 -0.1(10) . . . . ?
Os1 N2 C110 C109 178.8(6) . . . . ?
C108 C109 C110 N2 -1.2(12) . . . . ?
N1 Os1 N3 C210 113.5(6) . . . . ?
N4 Os1 N3 C210 167.9(5) . . . . ?
N2 Os1 N3 C210 82.0(5) . . . . ?
P1 Os1 N3 C210 -13.4(5) . . . . ?
P2 Os1 N3 C210 -101.7(5) . . . . ?
N1 Os1 N3 C206 -64.3(7) . . . . ?
N4 Os1 N3 C206 -9.8(4) . . . . ?
N2 Os1 N3 C206 -95.7(4) . . . . ?
P1 Os1 N3 C206 168.9(3) . . . . ?
P2 Os1 N3 C206 80.6(4) . . . . ?
N3 Os1 N4 C205 9.3(4) . . . . ?
N1 Os1 N4 C205 175.8(4) . . . . ?
N2 Os1 N4 C205 99.5(4) . . . . ?
P2 Os1 N4 C205 -87.1(4) . . . . ?
N3 Os1 N4 C201 -173.2(4) . . . . ?
N1 Os1 N4 C201 -6.7(4) . . . . ?
N2 Os1 N4 C201 -83.0(4) . . . . ?
P2 Os1 N4 C201 90.4(4) . . . . ?
C205 N4 C201 C202 0.0(8) . . . . ?
Os1 N4 C201 C202 -177.5(4) . . . . ?
N4 C201 C202 C203 1.9(9) . . . . ?
C201 C202 C203 C204 -1.4(11) . . . . ?
C202 C203 C204 C205 -0.8(11) . . . . ?
C201 N4 C205 C204 -2.3(8) . . . . ?
Os1 N4 C205 C204 175.4(5) . . . . ?
C201 N4 C205 C206 175.0(5) . . . . ?
Os1 N4 C205 C206 -7.3(6) . . . . ?
C203 C204 C205 N4 2.7(9) . . . . ?
C203 C204 C205 C206 -174.3(6) . . . . ?
C210 N3 C206 C207 6.7(8) . . . . ?
Os1 N3 C206 C207 -175.4(5) . . . . ?
C210 N3 C206 C205 -168.8(5) . . . . ?
Os1 N3 C206 C205 9.2(6) . . . . ?
N4 C205 C206 N3 -1.2(7) . . . . ?
C204 C205 C206 N3 176.0(5) . . . . ?
N4 C205 C206 C207 -176.5(6) . . . . ?
C204 C205 C206 C207 0.7(9) . . . . ?
N3 C206 C207 C208 -2.2(10) . . . . ?
C205 C206 C207 C208 172.8(6) . . . . ?
C206 C207 C208 C209 -2.3(11) . . . . ?
C207 C208 C209 C210 2.0(11) . . . . ?
C206 N3 C210 C209 -7.1(9) . . . . ?
Os1 N3 C210 C209 175.2(5) . . . . ?
C208 C209 C210 N3 2.8(10) . . . . ?
N6 Pd1 N5 C301 169.8(5) . . . . ?
P4 Pd1 N5 C301 -8.0(5) . . . . ?
N6 Pd1 N5 C305 -16.7(4) . . . . ?
P4 Pd1 N5 C305 165.5(3) . . . . ?
N5 Pd1 N6 C310 -166.7(5) . . . . ?
P3 Pd1 N6 C310 16.4(5) . . . . ?
N5 Pd1 N6 C306 15.8(4) . . . . ?
P3 Pd1 N6 C306 -161.2(4) . . . . ?
C305 N5 C301 C302 -3.2(9) . . . . ?
Pd1 N5 C301 C302 169.9(5) . . . . ?
N5 C301 C302 C303 -0.5(11) . . . . ?
C301 C302 C303 C304 1.4(12) . . . . ?
C302 C303 C304 C305 1.4(12) . . . . ?
C301 N5 C305 C304 6.1(9) . . . . ?
Pd1 N5 C305 C304 -168.1(5) . . . . ?
C301 N5 C305 C306 -170.4(5) . . . . ?
Pd1 N5 C305 C306 15.4(6) . . . . ?
C303 C304 C305 N5 -5.2(10) . . . . ?
C303 C304 C305 C306 171.0(7) . . . . ?
C310 N6 C306 C307 -4.3(9) . . . . ?
Pd1 N6 C306 C307 173.6(5) . . . . ?
C310 N6 C306 C305 169.6(5) . . . . ?
Pd1 N6 C306 C305 -12.5(6) . . . . ?
N5 C305 C306 N6 -2.0(8) . . . . ?
C304 C305 C306 N6 -178.4(6) . . . . ?
N5 C305 C306 C307 171.7(6) . . . . ?
C304 C305 C306 C307 -4.7(10) . . . . ?
N6 C306 C307 C308 4.1(11) . . . . ?
C305 C306 C307 C308 -169.4(7) . . . . ?
C306 C307 C308 C309 -1.6(13) . . . . ?
C307 C308 C309 C310 -0.5(13) . . . . ?
C306 N6 C310 C309 2.2(10) . . . . ?
Pd1 N6 C310 C309 -175.2(5) . . . . ?
C308 C309 C310 N6 0.2(12) . . . . ?
C21 P1 C11 C12 -124.0(5) . . . . ?
C1 P1 C11 C12 -17.2(5) . . . . ?
Os1 P1 C11 C12 99.7(5) . . . . ?
C21 P1 C11 C16 63.8(5) . . . . ?
C1 P1 C11 C16 170.6(4) . . . . ?
Os1 P1 C11 C16 -72.4(4) . . . . ?
C16 C11 C12 C13 1.5(9) . . . . ?
P1 C11 C12 C13 -170.5(5) . . . . ?
C11 C12 C13 C14 -1.1(12) . . . . ?
C12 C13 C14 C15 -0.6(13) . . . . ?
C13 C14 C15 C16 1.8(13) . . . . ?
C12 C11 C16 C15 -0.3(9) . . . . ?
P1 C11 C16 C15 172.3(5) . . . . ?
C14 C15 C16 C11 -1.3(11) . . . . ?
C11 P1 C21 C22 -175.2(4) . . . . ?
C1 P1 C21 C22 74.7(5) . . . . ?
Os1 P1 C21 C22 -47.6(5) . . . . ?
C11 P1 C21 C26 10.6(5) . . . . ?
C1 P1 C21 C26 -99.4(5) . . . . ?
Os1 P1 C21 C26 138.3(4) . . . . ?
C26 C21 C22 C23 -2.1(9) . . . . ?
P1 C21 C22 C23 -176.5(5) . . . . ?
C21 C22 C23 C24 -0.3(10) . . . . ?
C22 C23 C24 C25 2.2(12) . . . . ?
C23 C24 C25 C26 -1.5(12) . . . . ?
C24 C25 C26 C21 -1.1(11) . . . . ?
C22 C21 C26 C25 2.8(9) . . . . ?
P1 C21 C26 C25 177.0(5) . . . . ?
C41 P2 C31 C32 -33.7(4) . . . . ?
C2 P2 C31 C32 75.6(4) . . . . ?
Os1 P2 C31 C32 -160.9(3) . . . . ?
C41 P2 C31 C36 149.9(4) . . . . ?
C2 P2 C31 C36 -100.8(4) . . . . ?
Os1 P2 C31 C36 22.7(5) . . . . ?
C36 C31 C32 C33 0.9(8) . . . . ?
P2 C31 C32 C33 -175.6(4) . . . . ?
C31 C32 C33 C34 -0.5(9) . . . . ?
C32 C33 C34 C35 -0.2(10) . . . . ?
C33 C34 C35 C36 0.5(10) . . . . ?
C34 C35 C36 C31 -0.1(9) . . . . ?
C32 C31 C36 C35 -0.6(8) . . . . ?
P2 C31 C36 C35 175.9(4) . . . . ?
C31 P2 C41 C42 122.8(5) . . . . ?
C2 P2 C41 C42 17.0(5) . . . . ?
Os1 P2 C41 C42 -103.6(4) . . . . ?
C31 P2 C41 C46 -56.5(4) . . . . ?
C2 P2 C41 C46 -162.3(4) . . . . ?
Os1 P2 C41 C46 77.1(4) . . . . ?
C46 C41 C42 C43 0.6(8) . . . . ?
P2 C41 C42 C43 -178.7(4) . . . . ?
C41 C42 C43 C44 -1.7(10) . . . . ?
C42 C43 C44 C45 1.8(11) . . . . ?
C43 C44 C45 C46 -0.8(10) . . . . ?
C42 C41 C46 C45 0.5(8) . . . . ?
P2 C41 C46 C45 179.8(4) . . . . ?
C44 C45 C46 C41 -0.4(9) . . . . ?
C61 P3 C51 C56 -1.1(5) . . . . ?
C3 P3 C51 C56 110.2(4) . . . . ?
Pd1 P3 C51 C56 -124.8(4) . . . . ?
C61 P3 C51 C52 174.7(4) . . . . ?
C3 P3 C51 C52 -74.0(4) . . . . ?
Pd1 P3 C51 C52 51.0(4) . . . . ?
C56 C51 C52 C53 -2.0(8) . . . . ?
P3 C51 C52 C53 -177.9(4) . . . . ?
C51 C52 C53 C54 2.5(9) . . . . ?
C52 C53 C54 C55 -1.3(11) . . . . ?
C53 C54 C55 C56 -0.6(11) . . . . ?
C52 C51 C56 C55 0.2(8) . . . . ?
P3 C51 C56 C55 175.9(5) . . . . ?
C54 C55 C56 C51 1.1(10) . . . . ?
C51 P3 C61 C62 -108.8(5) . . . . ?
C3 P3 C61 C62 134.7(4) . . . . ?
Pd1 P3 C61 C62 15.6(5) . . . . ?
C51 P3 C61 C66 72.6(5) . . . . ?
C3 P3 C61 C66 -43.9(5) . . . . ?
Pd1 P3 C61 C66 -163.0(4) . . . . ?
C66 C61 C62 C63 -1.0(9) . . . . ?
P3 C61 C62 C63 -179.5(6) . . . . ?
C61 C62 C63 C64 1.0(12) . . . . ?
C62 C63 C64 C65 -1.5(14) . . . . ?
C63 C64 C65 C66 1.8(14) . . . . ?
C64 C65 C66 C61 -1.7(12) . . . . ?
C62 C61 C66 C65 1.3(10) . . . . ?
P3 C61 C66 C65 179.8(6) . . . . ?
C81 P4 C71 C72 96.8(5) . . . . ?
C4 P4 C71 C72 -149.9(5) . . . . ?
Pd1 P4 C71 C72 -28.7(5) . . . . ?
C81 P4 C71 C76 -82.0(5) . . . . ?
C4 P4 C71 C76 31.3(5) . . . . ?
Pd1 P4 C71 C76 152.5(4) . . . . ?
C76 C71 C72 C73 -0.3(10) . . . . ?
P4 C71 C72 C73 -179.2(6) . . . . ?
C71 C72 C73 C74 -0.2(12) . . . . ?
C72 C73 C74 C75 0.3(13) . . . . ?
C73 C74 C75 C76 0.1(12) . . . . ?
C74 C75 C76 C71 -0.6(10) . . . . ?
C72 C71 C76 C75 0.7(9) . . . . ?
P4 C71 C76 C75 179.5(5) . . . . ?
C71 P4 C81 C86 15.9(5) . . . . ?
C4 P4 C81 C86 -96.5(5) . . . . ?
Pd1 P4 C81 C86 138.9(4) . . . . ?
C71 P4 C81 C82 -161.2(4) . . . . ?
C4 P4 C81 C82 86.5(4) . . . . ?
Pd1 P4 C81 C82 -38.2(4) . . . . ?
C86 C81 C82 C83 2.1(8) . . . . ?
P4 C81 C82 C83 179.3(4) . . . . ?
C81 C82 C83 C84 -1.1(9) . . . . ?
C82 C83 C84 C85 -0.8(11) . . . . ?
C83 C84 C85 C86 1.7(13) . . . . ?
C82 C81 C86 C85 -1.2(9) . . . . ?
P4 C81 C86 C85 -178.2(5) . . . . ?
C84 C85 C86 C81 -0.7(11) . . . . ?
F23 P6 F19 F25 54.5(9) . . . . ?
F21 P6 F19 F25 -50.4(9) . . . . ?
F22 P6 F19 F25 -178.4(11) . . . . ?
F24 P6 F19 F25 130.4(11) . . . . ?
F20 P6 F19 F25 -127.2(10) . . . . ?
F23 P6 F25 F19 -127.2(8) . . . . ?
F21 P6 F25 F19 130.6(9) . . . . ?
F22 P6 F25 F19 178.2(13) . . . . ?
F24 P6 F25 F19 -55.1(10) . . . . ?
F20 P6 F25 F19 60.1(8) . . . . ?

_diffrn_reflns_theta_full        27.52
_diffrn_measured_fraction        0.997
_refine_diff_density_max         1.310
_refine_diff_density_min         -0.820
_refine_diff_density_rms         0.100
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Acetonitrile'
_chemical_properties_physical    'Light-sensitive, Photo-sensitive'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1404737'
_audit_update_record             
;
2015-06-03 deposited with the CCDC.
2015-11-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        '[Ru(bpy)2(dppcb)Pd(bpy)](SbF6)4'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'2(C82 H68 N6 P4 Pd Ru), 8(F6 Sb), 1.8(C H2 Cl2), 8.7(C Cl2)'
_chemical_formula_sum            'C174.50 H139.60 Cl21 F48 N12 P8 Pd2 Ru2 Sb8'
_chemical_formula_weight         5697.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.9389(2)
_cell_length_b                   18.0338(2)
_cell_length_c                   24.5740(4)
_cell_angle_alpha                74.4973(9)
_cell_angle_beta                 87.5735(8)
_cell_angle_gamma                77.9684(9)
_cell_volume                     5403.50(14)
_cell_formula_units_Z            1
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    149280
_cell_measurement_theta_min      0.998
_cell_measurement_theta_max      26.022

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.60
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.751
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2767.6
_exptl_absorpt_coefficient_mu    1.689
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.410
_exptl_absorpt_correction_T_max  0.739
_exptl_absorpt_process_details   'Otwinowski et al, 1997'

_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Kappa CCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         3
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  120
_diffrn_standards_decay_%        0
_diffrn_reflns_number            35291
_diffrn_reflns_av_R_equivalents  0.0364
_diffrn_reflns_av_sigmaI/netI    0.0541
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.61
_diffrn_reflns_theta_max         26.03
_reflns_number_total             21293
_reflns_number_gt                15033
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Kappa CCD'
_computing_cell_refinement       'Denzo and Scalepack'
_computing_data_reduction        'Denzo and Scalepack'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2015 (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL-NT V6.1'
_computing_publication_material  'SHELXTL-NT V6.1'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.01448P)²+3.9560P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         20136
_refine_ls_number_parameters     1384
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.0812
_refine_ls_R_factor_gt           0.0619
_refine_ls_wR_factor_ref         0.2395
_refine_ls_wR_factor_gt          0.1716
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_diffrn_measured_fraction_theta_full 1.00

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.75418(4) 0.70695(3) 0.74556(2) 0.04723(16) Uani 1 1 d . . .
Pd1 Pd 0.54803(4) 1.12705(3) 0.72445(2) 0.04612(15) Uani 1 1 d . . .
P1 P 0.59356(13) 0.77106(10) 0.77124(9) 0.0527(4) Uani 1 1 d . . .
P2 P 0.81843(12) 0.81543(9) 0.75302(9) 0.0518(4) Uani 1 1 d . . .
P3 P 0.67214(13) 1.04329(9) 0.78623(7) 0.0458(4) Uani 1 1 d . . .
P4 P 0.46115(12) 1.02674(9) 0.75115(7) 0.0449(3) Uani 1 1 d . . .
N1 N 0.6957(4) 0.7559(3) 0.6619(2) 0.0478(12) Uani 1 1 d . . .
N2 N 0.6946(5) 0.6141(3) 0.7281(3) 0.0637(17) Uani 1 1 d . . .
N3 N 0.8204(6) 0.6284(3) 0.8199(3) 0.0657(16) Uani 1 1 d . . .
N4 N 0.9003(4) 0.6534(3) 0.7178(3) 0.0543(14) Uani 1 1 d . . .
N5 N 0.4404(5) 1.2079(4) 0.6644(3) 0.0633(16) Uani 1 1 d . . .
N6 N 0.6206(5) 1.2248(3) 0.7009(3) 0.0643(16) Uani 1 1 d . . .
C1 C 0.5919(4) 0.8786(3) 0.7438(3) 0.0408(12) Uani 1 1 d . . .
H1 H 0.5567 0.9001 0.7062 0.049 Uiso 1 1 calc R . .
C2 C 0.7029(4) 0.9016(3) 0.7427(3) 0.0428(13) Uani 1 1 d . . .
H2 H 0.7108 0.9421 0.7075 0.051 Uiso 1 1 calc R . .
C3 C 0.6656(5) 0.9406(3) 0.7918(3) 0.0446(13) Uani 1 1 d . . .
H3 H 0.6952 0.9059 0.8285 0.054 Uiso 1 1 calc R . .
C4 C 0.5507(5) 0.9326(4) 0.7833(3) 0.0466(14) Uani 1 1 d . . .
H4 H 0.5217 0.9035 0.8186 0.056 Uiso 1 1 calc R . .
C101 C 0.6947(5) 0.8277(4) 0.6299(3) 0.0563(16) Uani 1 1 d . . .
H101 H 0.7194 0.8628 0.6459 0.068 Uiso 1 1 calc R . .
C102 C 0.6582(7) 0.8554(5) 0.5726(4) 0.072(2) Uani 1 1 d . . .
H102 H 0.6585 0.9071 0.5514 0.087 Uiso 1 1 calc R . .
C103 C 0.6236(8) 0.8046(6) 0.5500(4) 0.078(2) Uani 1 1 d . . .
H103 H 0.6011 0.8200 0.5120 0.094 Uiso 1 1 calc R . .
C104 C 0.6210(6) 0.7309(6) 0.5823(4) 0.073(2) Uani 1 1 d . . .
H104 H 0.5948 0.6961 0.5668 0.088 Uiso 1 1 calc R . .
C105 C 0.6572(5) 0.7063(4) 0.6388(4) 0.0584(18) Uani 1 1 d . . .
C106 C 0.6540(5) 0.6289(4) 0.6758(4) 0.0602(18) Uani 1 1 d . . .
C107 C 0.6074(7) 0.5741(5) 0.6602(5) 0.082(3) Uani 1 1 d . . .
H107 H 0.5789 0.5855 0.6236 0.098 Uiso 1 1 calc R . .
C108 C 0.6032(9) 0.5046(5) 0.6978(6) 0.093(3) Uani 1 1 d . . .
H108 H 0.5700 0.4683 0.6879 0.112 Uiso 1 1 calc R . .
C109 C 0.6478(8) 0.4879(5) 0.7502(5) 0.084(3) Uani 1 1 d . . .
H109 H 0.6472 0.4392 0.7762 0.100 Uiso 1 1 calc R . .
C110 C 0.6930(7) 0.5418(5) 0.7648(5) 0.080(3) Uani 1 1 d . . .
H110 H 0.7239 0.5292 0.8009 0.096 Uiso 1 1 calc R . .
C201 C 0.7705(10) 0.6093(5) 0.8696(4) 0.089(3) Uani 1 1 d . . .
H201 H 0.7016 0.6371 0.8732 0.106 Uiso 1 1 calc R . .
C202 C 0.8156(15) 0.5521(8) 0.9140(6) 0.130(5) Uani 1 1 d . . .
H202 H 0.7779 0.5397 0.9476 0.156 Uiso 1 1 calc R . .
C203 C 0.9168(16) 0.5115(8) 0.9104(7) 0.139(6) Uani 1 1 d . . .
H203 H 0.9516 0.4738 0.9419 0.167 Uiso 1 1 calc R . .
C204 C 0.9627(11) 0.5273(7) 0.8619(6) 0.108(4) Uani 1 1 d . . .
H204 H 1.0300 0.4972 0.8583 0.130 Uiso 1 1 calc R . .
C205 C 0.9182(7) 0.5862(5) 0.8147(4) 0.074(2) Uani 1 1 d . . .
C206 C 0.9655(6) 0.6020(4) 0.7597(4) 0.065(2) Uani 1 1 d . . .
C207 C 1.0675(7) 0.5668(5) 0.7456(5) 0.081(3) Uani 1 1 d . . .
H207 H 1.1125 0.5309 0.7741 0.097 Uiso 1 1 calc R . .
C208 C 1.1007(7) 0.5836(6) 0.6925(7) 0.094(3) Uani 1 1 d . . .
H208 H 1.1697 0.5614 0.6837 0.113 Uiso 1 1 calc R . .
C209 C 1.0339(7) 0.6331(6) 0.6513(5) 0.087(3) Uani 1 1 d . . .
H209 H 1.0549 0.6430 0.6134 0.104 Uiso 1 1 calc R . .
C210 C 0.9337(6) 0.6695(5) 0.6651(4) 0.0655(19) Uani 1 1 d . . .
H210 H 0.8894 0.7059 0.6366 0.079 Uiso 1 1 calc R . .
C301 C 0.3439(8) 1.2012(6) 0.6501(5) 0.085(3) Uani 1 1 d . . .
H301 H 0.3160 1.1578 0.6702 0.102 Uiso 1 1 calc R . .
C302 C 0.2857(12) 1.2567(9) 0.6068(7) 0.122(5) Uani 1 1 d . . .
H302 H 0.2155 1.2541 0.6007 0.147 Uiso 1 1 calc R . .
C303 C 0.3266(18) 1.3138(9) 0.5735(7) 0.140(6) Uani 1 1 d . . .
H303 H 0.2917 1.3474 0.5405 0.168 Uiso 1 1 calc R . .
C304 C 0.4225(17) 1.3211(7) 0.5900(6) 0.131(6) Uani 1 1 d . . .
H304 H 0.4513 1.3638 0.5694 0.157 Uiso 1 1 calc R . .
C305 C 0.4777(9) 1.2698(5) 0.6344(3) 0.075(2) Uani 1 1 d . . .
C306 C 0.5805(8) 1.2769(5) 0.6548(4) 0.077(2) Uani 1 1 d . . .
C307 C 0.6343(15) 1.3406(7) 0.6310(7) 0.128(6) Uani 1 1 d . . .
H307 H 0.6082 1.3783 0.5975 0.154 Uiso 1 1 calc R . .
C308 C 0.7209(16) 1.3466(10) 0.6560(9) 0.137(7) Uani 1 1 d . . .
H308 H 0.7569 1.3873 0.6399 0.164 Uiso 1 1 calc R . .
C309 C 0.7554(10) 1.2931(7) 0.7049(10) 0.128(6) Uani 1 1 d . . .
H309 H 0.8142 1.2973 0.7242 0.153 Uiso 1 1 calc R . .
C310 C 0.7056(7) 1.2344(5) 0.7255(6) 0.096(4) Uani 1 1 d . . .
H310 H 0.7315 1.1974 0.7593 0.115 Uiso 1 1 calc R . .
C11 C 0.4883(6) 0.7493(5) 0.7362(5) 0.071(2) Uani 1 1 d . . .
C12 C 0.4628(7) 0.6762(6) 0.7572(6) 0.096(4) Uani 1 1 d . . .
H12 H 0.4900 0.6427 0.7921 0.115 Uiso 1 1 calc R . .
C13 C 0.3912(10) 0.6535(10) 0.7227(12) 0.169(11) Uani 1 1 d . . .
H13 H 0.3738 0.6037 0.7358 0.203 Uiso 1 1 calc R . .
C14 C 0.3504(9) 0.6996(15) 0.6742(14) 0.194(14) Uani 1 1 d . . .
H14 H 0.3041 0.6831 0.6536 0.233 Uiso 1 1 calc R . .
C15 C 0.3755(7) 0.7702(9) 0.6544(7) 0.121(5) Uani 1 1 d . . .
H15 H 0.3474 0.8028 0.6194 0.145 Uiso 1 1 calc R . .
C16 C 0.4436(6) 0.7965(7) 0.6852(6) 0.093(4) Uani 1 1 d . . .
H16 H 0.4587 0.8469 0.6708 0.112 Uiso 1 1 calc R . .
C21 C 0.5385(8) 0.7648(4) 0.8417(4) 0.073(2) Uani 1 1 d . . .
C22 C 0.4340(9) 0.7635(5) 0.8524(5) 0.093(3) Uani 1 1 d . . .
H22 H 0.3896 0.7604 0.8242 0.111 Uiso 1 1 calc R . .
C23 C 0.3929(15) 0.7671(8) 0.9068(9) 0.131(6) Uani 1 1 d . . .
H23 H 0.3212 0.7662 0.9141 0.158 Uiso 1 1 calc R . .
C24 C 0.4544(19) 0.7715(8) 0.9475(7) 0.128(6) Uani 1 1 d . . .
H24 H 0.4258 0.7727 0.9831 0.153 Uiso 1 1 calc R . .
C25 C 0.5540(15) 0.7742(7) 0.9386(6) 0.113(4) Uani 1 1 d . . .
H25 H 0.5958 0.7782 0.9676 0.135 Uiso 1 1 calc R . .
C26 C 0.6002(10) 0.7713(5) 0.8846(4) 0.082(3) Uani 1 1 d . . .
H26 H 0.6718 0.7737 0.8784 0.098 Uiso 1 1 calc R . .
C31 C 0.9157(5) 0.8435(4) 0.6989(4) 0.0610(19) Uani 1 1 d . . .
C32 C 1.0164(6) 0.7936(5) 0.7086(7) 0.106(4) Uani 1 1 d . . .
H32 H 1.0325 0.7541 0.7426 0.128 Uiso 1 1 calc R . .
C33 C 1.0926(7) 0.8047(7) 0.6658(9) 0.134(7) Uani 1 1 d . . .
H33 H 1.1587 0.7699 0.6707 0.161 Uiso 1 1 calc R . .
C34 C 1.0736(8) 0.8625(8) 0.6193(7) 0.111(5) Uani 1 1 d . . .
H34 H 1.1255 0.8687 0.5914 0.133 Uiso 1 1 calc R . .
C35 C 0.9779(7) 0.9134(6) 0.6118(6) 0.090(3) Uani 1 1 d . . .
H35 H 0.9665 0.9564 0.5796 0.108 Uiso 1 1 calc R . .
C36 C 0.8984(5) 0.9040(4) 0.6494(4) 0.064(2) Uani 1 1 d . . .
H36 H 0.8320 0.9382 0.6419 0.076 Uiso 1 1 calc R . .
C41 C 0.8908(7) 0.8169(5) 0.8159(4) 0.074(2) Uani 1 1 d . . .
C42 C 0.9521(9) 0.8729(5) 0.8111(6) 0.108(5) Uani 1 1 d . . .
H42 H 0.9551 0.9103 0.7764 0.130 Uiso 1 1 calc R . .
C43 C 1.0088(11) 0.8741(6) 0.8573(7) 0.131(6) Uani 1 1 d . . .
H43 H 1.0490 0.9128 0.8540 0.158 Uiso 1 1 calc R . .
C44 C 1.0065(13) 0.8197(8) 0.9071(7) 0.134(6) Uani 1 1 d . . .
H44 H 1.0461 0.8204 0.9381 0.161 Uiso 1 1 calc R . .
C45 C 0.9481(12) 0.7647(9) 0.9125(6) 0.129(5) Uani 1 1 d . . .
H45 H 0.9465 0.7268 0.9471 0.155 Uiso 1 1 calc R . .
C46 C 0.8897(8) 0.7648(7) 0.8658(5) 0.091(3) Uani 1 1 d . . .
H46 H 0.8482 0.7267 0.8697 0.110 Uiso 1 1 calc R . .
C51 C 0.6426(6) 1.0518(4) 0.8570(3) 0.0553(16) Uani 1 1 d . . .
C52 C 0.5708(7) 1.1165(5) 0.8652(4) 0.069(2) Uani 1 1 d . . .
H52 H 0.5387 1.1560 0.8339 0.083 Uiso 1 1 calc R . .
C53 C 0.5461(9) 1.1233(7) 0.9193(5) 0.095(3) Uani 1 1 d . . .
H53 H 0.4990 1.1682 0.9244 0.114 Uiso 1 1 calc R . .
C54 C 0.5893(9) 1.0661(7) 0.9646(4) 0.091(3) Uani 1 1 d . . .
H54 H 0.5679 1.0696 1.0010 0.109 Uiso 1 1 calc R . .
C55 C 0.6656(10) 1.0011(7) 0.9584(4) 0.096(3) Uani 1 1 d . . .
H55 H 0.6997 0.9632 0.9900 0.115 Uiso 1 1 calc R . .
C56 C 0.6887(7) 0.9951(5) 0.9045(4) 0.071(2) Uani 1 1 d . . .
H56 H 0.7376 0.9510 0.8995 0.085 Uiso 1 1 calc R . .
C61 C 0.8048(5) 1.0568(4) 0.7690(3) 0.0508(15) Uani 1 1 d . . .
C62 C 0.8365(6) 1.0628(4) 0.7135(3) 0.0568(16) Uani 1 1 d . . .
H62 H 0.7898 1.0575 0.6872 0.068 Uiso 1 1 calc R . .
C63 C 0.9349(6) 1.0761(5) 0.6967(4) 0.0666(19) Uani 1 1 d . . .
H63 H 0.9572 1.0787 0.6594 0.080 Uiso 1 1 calc R . .
C64 C 1.0014(7) 1.0859(6) 0.7368(5) 0.078(2) Uani 1 1 d . . .
H64 H 1.0684 1.0965 0.7257 0.093 Uiso 1 1 calc R . .
C65 C 0.9723(6) 1.0805(5) 0.7902(5) 0.075(2) Uani 1 1 d . . .
H65 H 1.0191 1.0863 0.8163 0.090 Uiso 1 1 calc R . .
C66 C 0.8725(6) 1.0662(4) 0.8076(4) 0.0613(18) Uani 1 1 d . . .
H66 H 0.8516 1.0629 0.8451 0.074 Uiso 1 1 calc R . .
C71 C 0.3686(5) 1.0446(4) 0.8052(3) 0.0488(14) Uani 1 1 d . . .
C72 C 0.3339(7) 0.9856(6) 0.8443(4) 0.074(2) Uani 1 1 d . . .
H72 H 0.3608 0.9330 0.8442 0.089 Uiso 1 1 calc R . .
C73 C 0.2581(8) 1.0027(7) 0.8849(5) 0.089(3) Uani 1 1 d . . .
H73 H 0.2341 0.9621 0.9116 0.107 Uiso 1 1 calc R . .
C74 C 0.2204(8) 1.0799(8) 0.8842(5) 0.098(4) Uani 1 1 d . . .
H74 H 0.1712 1.0922 0.9113 0.118 Uiso 1 1 calc R . .
C75 C 0.2534(9) 1.1390(6) 0.8447(5) 0.086(3) Uani 1 1 d . . .
H75 H 0.2259 1.1916 0.8445 0.103 Uiso 1 1 calc R . .
C76 C 0.3255(7) 1.1223(5) 0.8057(4) 0.072(2) Uani 1 1 d . . .
H76 H 0.3469 1.1637 0.7786 0.086 Uiso 1 1 calc R . .
C81 C 0.3867(5) 1.0105(4) 0.6953(3) 0.0502(14) Uani 1 1 d . . .
C82 C 0.2899(6) 0.9905(6) 0.7050(4) 0.068(2) Uani 1 1 d . . .
H82 H 0.2602 0.9846 0.7411 0.082 Uiso 1 1 calc R . .
C83 C 0.2358(6) 0.9790(7) 0.6615(5) 0.088(3) Uani 1 1 d . . .
H83 H 0.1707 0.9630 0.6683 0.106 Uiso 1 1 calc R . .
C84 C 0.2770(7) 0.9910(7) 0.6091(4) 0.088(3) Uani 1 1 d . . .
H84 H 0.2377 0.9873 0.5790 0.105 Uiso 1 1 calc R . .
C85 C 0.3769(8) 1.0088(6) 0.5992(4) 0.077(2) Uani 1 1 d . . .
H85 H 0.4070 1.0133 0.5633 0.093 Uiso 1 1 calc R . .
C86 C 0.4310(6) 1.0198(5) 0.6421(3) 0.0585(16) Uani 1 1 d . . .
H86 H 0.4976 1.0335 0.6356 0.070 Uiso 1 1 calc R . .
Sb1 Sb 0.67966(6) 0.42436(6) 0.45382(3) 0.0992(3) Uani 1 1 d . . .
F1 F 0.6099(9) 0.4874(6) 0.5000(4) 0.157(4) Uani 1 1 d . . .
F2 F 0.7667(13) 0.3665(11) 0.5159(5) 0.270(10) Uani 1 1 d . . .
F3 F 0.5991(15) 0.4811(10) 0.3907(6) 0.243(8) Uani 1 1 d . . .
F4 F 0.7584(8) 0.3540(9) 0.4153(6) 0.192(5) Uani 1 1 d . . .
F5 F 0.5875(12) 0.3566(6) 0.4720(7) 0.214(7) Uani 1 1 d . . .
F6 F 0.7753(12) 0.4918(12) 0.4323(7) 0.232(7) Uani 1 1 d . . .
Sb2 Sb 0.36584(7) 0.37871(5) 0.78114(5) 0.0893(3) Uani 0.80 1 d P . .
F7 F 0.4015(16) 0.3047(14) 0.8521(13) 0.266(12) Uani 0.80 1 d P . .
F8 F 0.405(2) 0.4559(12) 0.8051(13) 0.280(14) Uani 0.80 1 d P . .
F9 F 0.2324(10) 0.4073(9) 0.8120(7) 0.205(8) Uani 0.80 1 d P . .
F10 F 0.3192(18) 0.3129(15) 0.7509(12) 0.274(12) Uani 0.80 1 d P . .
F11 F 0.4979(8) 0.3417(7) 0.7689(8) 0.174(6) Uani 0.80 1 d P . .
F12 F 0.3394(16) 0.4599(11) 0.7237(10) 0.233(9) Uani 0.80 1 d P . .
Sb3 Sb 0.68662(5) 0.11067(3) 0.54378(2) 0.06595(17) Uani 1 1 d . . .
F13 F 0.5542(9) 0.1682(6) 0.5597(4) 0.168(4) Uani 1 1 d . . .
F14 F 0.6755(4) 0.0338(4) 0.6129(2) 0.0895(16) Uani 1 1 d . . .
F15 F 0.6004(10) 0.0637(5) 0.5099(4) 0.158(4) Uani 1 1 d . . .
F16 F 0.7667(16) 0.1476(11) 0.5850(6) 0.296(12) Uani 1 1 d . . .
F17 F 0.6990(12) 0.1829(7) 0.4744(4) 0.200(6) Uani 1 1 d . . .
F18 F 0.8032(10) 0.0482(9) 0.5272(6) 0.259(10) Uani 1 1 d . . .
Sb4 Sb 1.0000 0.0000 0.0000 0.0981(5) Uani 0.70 2 d SP . .
F19 F 1.0858(12) 0.0706(14) 0.0031(7) 0.199(9) Uani 0.70 1 d P . .
F20 F 0.9775(10) 0.0470(13) -0.0761(5) 0.180(7) Uani 0.70 1 d P . .
F21 F 0.8836(11) 0.0704(9) 0.0178(6) 0.149(5) Uani 0.70 1 d P . .
Sb5 Sb 0.2058(3) 0.32414(19) 0.93561(14) 0.287(2) Uani 0.85 1 d PD . .
F22 F 0.124(2) 0.310(2) 0.9005(18) 0.316(18) Uani 0.73 1 d P . .
F23 F 0.1729(17) 0.3720(10) 0.9618(11) 0.127(8) Uani 0.57 1 d P . .
F24 F 0.194(2) 0.2158(8) 0.9661(6) 0.209(11) Uani 0.73 1 d P . .
F25 F 0.191(3) 0.414(3) 0.8775(15) 0.24(2) Uani 0.39 1 d P . .
F26 F 0.329(3) 0.289(2) 0.910(2) 0.35(2) Uani 0.73 1 d P . .
F27 F 0.198(4) 0.3744(16) 0.9739(11) 0.27(2) Uani 0.70 1 d P . .
F28 F 0.076(3) 0.351(3) 0.9601(17) 0.211(19) Uani 0.35 1 d P . .
F29 F 0.227(4) 0.232(3) 0.989(3) 0.62(4) Uani 0.90 1 d PDU . .
Cl1 Cl 0.0571(5) 0.2736(4) 0.7286(5) 0.209(4) Uani 0.90 1 d P . .
Cl2 Cl -0.0657(6) 0.4205(6) 0.7360(8) 0.336(9) Uani 0.90 1 d P . .
C5 C 0.054(2) 0.3576(14) 0.731(2) 0.30(3) Uani 0.90 1 d P . .
H5A H 0.0885 0.3829 0.6962 0.358 Uiso 0.90 1 calc PR . .
H5B H 0.0990 0.3548 0.7625 0.358 Uiso 0.90 1 calc PR . .
Cl3 Cl 0.600(5) 0.395(3) 0.9157(19) 0.88(6) Uani 0.86 1 d P . .
Cl3A Cl 0.830(9) 0.352(5) 0.904(5) 0.53(8) Uani 0.20 1 d P . .
Cl4 Cl 0.5288(9) 0.5489(6) 0.9192(7) 0.216(6) Uani 0.60 1 d P . .
Cl4A Cl 0.439(4) 0.418(2) 0.9642(11) 0.184(18) Uani 0.14 1 d P . .
C6 C 0.5343(10) 0.4497(6) 0.9311(6) 0.090(3) Uani 0.90 1 d P . .
Cl5 Cl 0.760(2) 0.2482(15) 0.8653(10) 0.445(15) Uani 0.80 1 d P . .
Cl5A Cl 0.7846(6) 0.2791(5) 0.9102(4) 0.084(2) Uani 0.45 1 d P . .
Cl6 Cl 0.792(2) 0.210(5) 0.9727(15) 0.50(6) Uani 0.28 1 d P . .
Cl6A Cl 0.875(4) 0.266(6) 0.925(2) 0.70(8) Uani 0.47 1 d P . .
C7 C 0.8307(19) 0.2681(14) 0.9100(9) 0.124(9) Uani 1 1 d . . .
Cl7 Cl 0.1926(4) 0.6687(4) 0.8343(2) 0.157(2) Uani 0.90 1 d P . .
Cl8 Cl 0.1622(16) 0.6013(15) 0.9455(6) 0.399(14) Uani 0.85 1 d PD . .
Cl8A Cl 0.2181(15) 0.6099(11) 0.9570(6) 0.128(6) Uani 0.25 1 d PD . .
C8 C 0.249(3) 0.597(3) 0.8913(14) 0.59(9) Uani 1 1 d D . .
Cl9 Cl 0.9292(13) 0.8650(13) 0.4601(10) 0.223(8) Uani 0.42 1 d P . .
Cl9A Cl 0.9099(9) 0.8039(9) 0.5054(6) 0.145(3) Uani 0.41 1 d P . .
Cl10 Cl 1.0133(6) 0.7526(6) 0.4107(4) 0.160(3) Uani 0.64 1 d P . .
Cl11 Cl 0.9437(18) 0.7095(12) 0.5022(10) 0.166(9) Uani 0.23 1 d P . .
C9 C 1.0297(15) 0.7682(14) 0.4725(10) 0.156(9) Uani 0.85 1 d P . .
Cl12 Cl 0.8791(13) 0.4911(11) 0.6369(10) 0.161(6) Uani 0.29 1 d P . .
Cl13 Cl 0.8692(14) 0.6101(11) 0.5389(8) 0.206(7) Uani 0.43 1 d P . .
Cl14 Cl 0.8780(8) 0.5340(6) 0.5581(4) 0.133(3) Uani 0.48 1 d P . .
C10 C 0.8153(14) 0.5418(13) 0.5778(11) 0.106(8) Uani 0.60 1 d P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N3 2.079(7) . ?
Ru1 N4 2.110(6) . ?
Ru1 N1 2.112(6) . ?
Ru1 N2 2.129(6) . ?
Ru1 P1 2.3089(19) . ?
Ru1 P2 2.3311(17) . ?
Pd1 N5 2.102(6) . ?
Pd1 N6 2.103(6) . ?
Pd1 P4 2.2623(18) . ?
Pd1 P3 2.2661(19) . ?
P1 C11 1.804(8) . ?
P1 C21 1.827(9) . ?
P1 C1 1.872(6) . ?
P2 C31 1.836(8) . ?
P2 C41 1.849(8) . ?
P2 C2 1.888(6) . ?
P3 C61 1.800(7) . ?
P3 C51 1.805(7) . ?
P3 C3 1.839(6) . ?
P4 C71 1.798(6) . ?
P4 C81 1.828(6) . ?
P4 C4 1.841(6) . ?
N1 C101 1.322(9) . ?
N1 C105 1.361(8) . ?
N2 C106 1.348(11) . ?
N2 C110 1.376(11) . ?
N3 C201 1.352(13) . ?
N3 C205 1.354(11) . ?
N4 C210 1.324(11) . ?
N4 C206 1.367(10) . ?
N5 C305 1.333(12) . ?
N5 C301 1.350(12) . ?
N6 C306 1.309(12) . ?
N6 C310 1.340(12) . ?
C1 C4 1.555(8) . ?
C1 C2 1.573(7) . ?
C1 H1 0.9900 . ?
C2 C3 1.565(9) . ?
C2 H2 0.9900 . ?
C3 C4 1.553(8) . ?
C3 H3 0.9900 . ?
C4 H4 0.9900 . ?
C101 C102 1.429(12) . ?
C101 H101 0.9400 . ?
C102 C103 1.346(13) . ?
C102 H102 0.9400 . ?
C103 C104 1.359(14) . ?
C103 H103 0.9400 . ?
C104 C105 1.408(13) . ?
C104 H104 0.9400 . ?
C105 C106 1.456(12) . ?
C106 C107 1.399(10) . ?
C107 C108 1.352(16) . ?
C107 H107 0.9400 . ?
C108 C109 1.365(17) . ?
C108 H108 0.9400 . ?
C109 C110 1.362(13) . ?
C109 H109 0.9400 . ?
C110 H110 0.9400 . ?
C201 C202 1.341(16) . ?
C201 H201 0.9400 . ?
C202 C203 1.37(2) . ?
C202 H202 0.9400 . ?
C203 C204 1.30(2) . ?
C203 H203 0.9400 . ?
C204 C205 1.395(14) . ?
C204 H204 0.9400 . ?
C205 C206 1.443(14) . ?
C206 C207 1.412(13) . ?
C207 C208 1.333(17) . ?
C207 H207 0.9400 . ?
C208 C209 1.357(16) . ?
C208 H208 0.9400 . ?
C209 C210 1.397(12) . ?
C209 H209 0.9400 . ?
C210 H210 0.9400 . ?
C301 C302 1.374(15) . ?
C301 H301 0.9400 . ?
C302 C303 1.32(2) . ?
C302 H302 0.9400 . ?
C303 C304 1.36(3) . ?
C303 H303 0.9400 . ?
C304 C305 1.345(17) . ?
C304 H304 0.9400 . ?
C305 C306 1.483(15) . ?
C306 C307 1.444(17) . ?
C307 C308 1.34(2) . ?
C307 H307 0.9400 . ?
C308 C309 1.35(3) . ?
C308 H308 0.9400 . ?
C309 C310 1.327(17) . ?
C309 H309 0.9400 . ?
C310 H310 0.9400 . ?
C11 C12 1.384(14) . ?
C11 C16 1.384(17) . ?
C12 C13 1.47(2) . ?
C12 H12 0.9400 . ?
C13 C14 1.32(4) . ?
C13 H13 0.9400 . ?
C14 C15 1.34(3) . ?
C14 H14 0.9400 . ?
C15 C16 1.413(12) . ?
C15 H15 0.9400 . ?
C16 H16 0.9400 . ?
C21 C22 1.369(14) . ?
C21 C26 1.394(15) . ?
C22 C23 1.43(2) . ?
C22 H22 0.9400 . ?
C23 C24 1.33(2) . ?
C23 H23 0.9400 . ?
C24 C25 1.31(2) . ?
C24 H24 0.9400 . ?
C25 C26 1.441(17) . ?
C25 H25 0.9400 . ?
C26 H26 0.9400 . ?
C31 C36 1.391(12) . ?
C31 C32 1.409(11) . ?
C32 C33 1.41(2) . ?
C32 H32 0.9400 . ?
C33 C34 1.32(2) . ?
C33 H33 0.9400 . ?
C34 C35 1.365(17) . ?
C34 H34 0.9400 . ?
C35 C36 1.359(13) . ?
C35 H35 0.9400 . ?
C36 H36 0.9400 . ?
C41 C46 1.331(16) . ?
C41 C42 1.389(14) . ?
C42 C43 1.384(15) . ?
C42 H42 0.9400 . ?
C43 C44 1.35(2) . ?
C43 H43 0.9400 . ?
C44 C45 1.34(2) . ?
C44 H44 0.9400 . ?
C45 C46 1.402(14) . ?
C45 H45 0.9400 . ?
C46 H46 0.9400 . ?
C51 C52 1.387(11) . ?
C51 C56 1.389(11) . ?
C52 C53 1.385(14) . ?
C52 H52 0.9400 . ?
C53 C54 1.347(16) . ?
C53 H53 0.9400 . ?
C54 C55 1.404(16) . ?
C54 H54 0.9400 . ?
C55 C56 1.374(14) . ?
C55 H55 0.9400 . ?
C56 H56 0.9400 . ?
C61 C66 1.383(9) . ?
C61 C62 1.389(11) . ?
C62 C63 1.372(11) . ?
C62 H62 0.9400 . ?
C63 C64 1.403(13) . ?
C63 H63 0.9400 . ?
C64 C65 1.334(15) . ?
C64 H64 0.9400 . ?
C65 C66 1.396(12) . ?
C65 H65 0.9400 . ?
C66 H66 0.9400 . ?
C71 C72 1.368(12) . ?
C71 C76 1.400(10) . ?
C72 C73 1.417(13) . ?
C72 H72 0.9400 . ?
C73 C74 1.371(17) . ?
C73 H73 0.9400 . ?
C74 C75 1.365(17) . ?
C74 H74 0.9400 . ?
C75 C76 1.356(14) . ?
C75 H75 0.9400 . ?
C76 H76 0.9400 . ?
C81 C82 1.369(10) . ?
C81 C86 1.387(11) . ?
C82 C83 1.386(11) . ?
C82 H82 0.9400 . ?
C83 C84 1.352(15) . ?
C83 H83 0.9400 . ?
C84 C85 1.391(14) . ?
C84 H84 0.9400 . ?
C85 C86 1.369(11) . ?
C85 H85 0.9400 . ?
C86 H86 0.9400 . ?
Sb1 F3 1.840(13) . ?
Sb1 F5 1.840(11) . ?
Sb1 F2 1.868(11) . ?
Sb1 F6 1.875(12) . ?
Sb1 F4 1.888(11) . ?
Sb1 F1 1.889(8) . ?
Sb2 F12 1.726(18) . ?
Sb2 F11 1.745(9) . ?
Sb2 F10 1.771(18) . ?
Sb2 F8 1.81(2) . ?
Sb2 F9 1.883(12) . ?
Sb2 F7 1.90(2) . ?
F7 F26 1.67(5) . ?
F9 F25 1.70(4) . ?
Sb3 F18 1.787(9) . ?
Sb3 F16 1.811(19) . ?
Sb3 F17 1.872(8) . ?
Sb3 F15 1.872(8) . ?
Sb3 F13 1.893(8) . ?
Sb3 F14 1.906(5) . ?
Sb4 F20 1.842(12) 2_755 ?
Sb4 F20 1.842(12) . ?
Sb4 F19 1.873(14) . ?
Sb4 F19 1.873(14) 2_755 ?
Sb4 F21 1.875(14) . ?
Sb4 F21 1.875(14) 2_755 ?
Sb5 F23 1.209(15) . ?
Sb5 F27 1.46(2) . ?
Sb5 F22 1.50(2) . ?
Sb5 F26 1.74(4) . ?
Sb5 F28 1.78(4) . ?
Sb5 F29 1.80(2) . ?
Sb5 F25 1.83(4) . ?
Sb5 F24 1.932(14) . ?
F23 F28 1.39(6) . ?
F24 F29 0.85(9) . ?
Cl1 C5 1.52(3) . ?
Cl2 C5 1.75(4) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ru1 N4 77.9(3) . . ?
N3 Ru1 N1 162.9(2) . . ?
N4 Ru1 N1 92.0(2) . . ?
N3 Ru1 N2 88.4(3) . . ?
N4 Ru1 N2 85.5(2) . . ?
N1 Ru1 N2 77.0(3) . . ?
N3 Ru1 P1 105.2(2) . . ?
N4 Ru1 P1 176.81(18) . . ?
N1 Ru1 P1 85.24(14) . . ?
N2 Ru1 P1 95.38(17) . . ?
N3 Ru1 P2 97.85(19) . . ?
N4 Ru1 P2 92.95(15) . . ?
N1 Ru1 P2 96.36(15) . . ?
N2 Ru1 P2 173.2(2) . . ?
P1 Ru1 P2 85.79(6) . . ?
N5 Pd1 N6 77.6(3) . . ?
N5 Pd1 P4 100.4(2) . . ?
N6 Pd1 P4 176.52(18) . . ?
N5 Pd1 P3 176.5(2) . . ?
N6 Pd1 P3 99.3(2) . . ?
P4 Pd1 P3 82.77(6) . . ?
C11 P1 C21 100.7(4) . . ?
C11 P1 C1 107.9(4) . . ?
C21 P1 C1 102.2(3) . . ?
C11 P1 Ru1 109.4(2) . . ?
C21 P1 Ru1 129.1(3) . . ?
C1 P1 Ru1 106.01(19) . . ?
C31 P2 C41 98.9(4) . . ?
C31 P2 C2 107.2(3) . . ?
C41 P2 C2 105.3(3) . . ?
C31 P2 Ru1 113.2(2) . . ?
C41 P2 Ru1 123.3(3) . . ?
C2 P2 Ru1 107.64(18) . . ?
C61 P3 C51 109.6(3) . . ?
C61 P3 C3 109.2(3) . . ?
C51 P3 C3 102.7(3) . . ?
C61 P3 Pd1 113.7(2) . . ?
C51 P3 Pd1 110.3(2) . . ?
C3 P3 Pd1 110.7(2) . . ?
C71 P4 C81 107.0(3) . . ?
C71 P4 C4 105.7(3) . . ?
C81 P4 C4 106.7(3) . . ?
C71 P4 Pd1 109.1(2) . . ?
C81 P4 Pd1 115.7(2) . . ?
C4 P4 Pd1 112.1(2) . . ?
C101 N1 C105 117.5(6) . . ?
C101 N1 Ru1 127.3(5) . . ?
C105 N1 Ru1 115.2(5) . . ?
C106 N2 C110 117.7(7) . . ?
C106 N2 Ru1 115.7(5) . . ?
C110 N2 Ru1 126.6(7) . . ?
C201 N3 C205 118.2(8) . . ?
C201 N3 Ru1 126.2(7) . . ?
C205 N3 Ru1 115.0(6) . . ?
C210 N4 C206 119.7(7) . . ?
C210 N4 Ru1 125.2(5) . . ?
C206 N4 Ru1 114.9(6) . . ?
C305 N5 C301 117.4(8) . . ?
C305 N5 Pd1 114.3(6) . . ?
C301 N5 Pd1 128.0(6) . . ?
C306 N6 C310 119.5(8) . . ?
C306 N6 Pd1 113.7(6) . . ?
C310 N6 Pd1 126.6(7) . . ?
C4 C1 C2 89.6(4) . . ?
C4 C1 P1 117.9(5) . . ?
C2 C1 P1 114.9(4) . . ?
C4 C1 H1 110.9 . . ?
C2 C1 H1 110.9 . . ?
P1 C1 H1 110.9 . . ?
C3 C2 C1 88.6(4) . . ?
C3 C2 P2 120.9(4) . . ?
C1 C2 P2 114.1(4) . . ?
C3 C2 H2 110.5 . . ?
C1 C2 H2 110.5 . . ?
P2 C2 H2 110.5 . . ?
C4 C3 C2 90.0(4) . . ?
C4 C3 P3 111.2(4) . . ?
C2 C3 P3 121.4(5) . . ?
C4 C3 H3 110.8 . . ?
C2 C3 H3 110.8 . . ?
P3 C3 H3 110.8 . . ?
C3 C4 C1 89.7(4) . . ?
C3 C4 P4 113.6(4) . . ?
C1 C4 P4 116.7(5) . . ?
C3 C4 H4 111.7 . . ?
C1 C4 H4 111.7 . . ?
P4 C4 H4 111.7 . . ?
N1 C101 C102 124.0(7) . . ?
N1 C101 H101 118.0 . . ?
C102 C101 H101 118.0 . . ?
C103 C102 C101 117.5(9) . . ?
C103 C102 H102 121.2 . . ?
C101 C102 H102 121.2 . . ?
C102 C103 C104 119.9(9) . . ?
C102 C103 H103 120.1 . . ?
C104 C103 H103 120.1 . . ?
C103 C104 C105 120.7(7) . . ?
C103 C104 H104 119.7 . . ?
C105 C104 H104 119.7 . . ?
N1 C105 C104 120.4(7) . . ?
N1 C105 C106 116.4(7) . . ?
C104 C105 C106 123.1(7) . . ?
N2 C106 C107 121.1(8) . . ?
N2 C106 C105 115.4(6) . . ?
C107 C106 C105 123.4(9) . . ?
C108 C107 C106 120.1(10) . . ?
C108 C107 H107 120.0 . . ?
C106 C107 H107 120.0 . . ?
C107 C108 C109 119.2(8) . . ?
C107 C108 H108 120.4 . . ?
C109 C108 H108 120.4 . . ?
C110 C109 C108 120.1(9) . . ?
C110 C109 H109 119.9 . . ?
C108 C109 H109 119.9 . . ?
C109 C110 N2 121.8(11) . . ?
C109 C110 H110 119.1 . . ?
N2 C110 H110 119.1 . . ?
C202 C201 N3 122.4(12) . . ?
C202 C201 H201 118.8 . . ?
N3 C201 H201 118.8 . . ?
C201 C202 C203 120.1(13) . . ?
C201 C202 H202 120.0 . . ?
C203 C202 H202 120.0 . . ?
C204 C203 C202 117.4(12) . . ?
C204 C203 H203 121.3 . . ?
C202 C203 H203 121.3 . . ?
C203 C204 C205 124.0(13) . . ?
C203 C204 H204 118.0 . . ?
C205 C204 H204 118.0 . . ?
N3 C205 C204 117.7(11) . . ?
N3 C205 C206 117.3(7) . . ?
C204 C205 C206 124.9(10) . . ?
N4 C206 C207 119.0(9) . . ?
N4 C206 C205 114.4(7) . . ?
C207 C206 C205 126.5(8) . . ?
C208 C207 C206 120.9(9) . . ?
C208 C207 H207 119.5 . . ?
C206 C207 H207 119.5 . . ?
C207 C208 C209 119.2(9) . . ?
C207 C208 H208 120.4 . . ?
C209 C208 H208 120.4 . . ?
C208 C209 C210 120.0(11) . . ?
C208 C209 H209 120.0 . . ?
C210 C209 H209 120.0 . . ?
N4 C210 C209 121.0(9) . . ?
N4 C210 H210 119.5 . . ?
C209 C210 H210 119.5 . . ?
N5 C301 C302 121.2(12) . . ?
N5 C301 H301 119.4 . . ?
C302 C301 H301 119.4 . . ?
C303 C302 C301 121.2(14) . . ?
C303 C302 H302 119.4 . . ?
C301 C302 H302 119.4 . . ?
C302 C303 C304 116.0(12) . . ?
C302 C303 H303 122.0 . . ?
C304 C303 H303 122.0 . . ?
C305 C304 C303 122.8(15) . . ?
C305 C304 H304 118.6 . . ?
C303 C304 H304 118.6 . . ?
N5 C305 C304 120.6(13) . . ?
N5 C305 C306 114.8(7) . . ?
C304 C305 C306 124.6(12) . . ?
N6 C306 C307 117.6(12) . . ?
N6 C306 C305 116.9(8) . . ?
C307 C306 C305 125.1(11) . . ?
C308 C307 C306 120.9(15) . . ?
C308 C307 H307 119.6 . . ?
C306 C307 H307 119.6 . . ?
C307 C308 C309 118.6(13) . . ?
C307 C308 H308 120.7 . . ?
C309 C308 H308 120.7 . . ?
C310 C309 C308 119.4(16) . . ?
C310 C309 H309 120.3 . . ?
C308 C309 H309 120.3 . . ?
C309 C310 N6 123.9(14) . . ?
C309 C310 H310 118.0 . . ?
N6 C310 H310 118.0 . . ?
C12 C11 C16 118.5(9) . . ?
C12 C11 P1 117.5(9) . . ?
C16 C11 P1 123.2(7) . . ?
C11 C12 C13 117.0(15) . . ?
C11 C12 H12 121.5 . . ?
C13 C12 H12 121.5 . . ?
C14 C13 C12 123.0(16) . . ?
C14 C13 H13 118.5 . . ?
C12 C13 H13 118.5 . . ?
C13 C14 C15 119.4(13) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
C14 C15 C16 121.1(17) . . ?
C14 C15 H15 119.5 . . ?
C16 C15 H15 119.5 . . ?
C11 C16 C15 121.0(12) . . ?
C11 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C22 C21 C26 117.7(9) . . ?
C22 C21 P1 122.2(9) . . ?
C26 C21 P1 119.6(7) . . ?
C21 C22 C23 119.7(14) . . ?
C21 C22 H22 120.2 . . ?
C23 C22 H22 120.2 . . ?
C24 C23 C22 121.2(15) . . ?
C24 C23 H23 119.4 . . ?
C22 C23 H23 119.4 . . ?
C25 C24 C23 120.9(14) . . ?
C25 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C24 C25 C26 120.6(15) . . ?
C24 C25 H25 119.7 . . ?
C26 C25 H25 119.7 . . ?
C21 C26 C25 119.8(12) . . ?
C21 C26 H26 120.1 . . ?
C25 C26 H26 120.1 . . ?
C36 C31 C32 118.4(8) . . ?
C36 C31 P2 127.2(5) . . ?
C32 C31 P2 114.2(8) . . ?
C31 C32 C33 118.2(12) . . ?
C31 C32 H32 120.9 . . ?
C33 C32 H32 120.9 . . ?
C34 C33 C32 121.8(9) . . ?
C34 C33 H33 119.1 . . ?
C32 C33 H33 119.1 . . ?
C33 C34 C35 119.5(10) . . ?
C33 C34 H34 120.3 . . ?
C35 C34 H34 120.3 . . ?
C36 C35 C34 122.3(12) . . ?
C36 C35 H35 118.9 . . ?
C34 C35 H35 118.9 . . ?
C35 C36 C31 119.7(8) . . ?
C35 C36 H36 120.2 . . ?
C31 C36 H36 120.2 . . ?
C46 C41 C42 117.7(9) . . ?
C46 C41 P2 123.0(7) . . ?
C42 C41 P2 119.2(9) . . ?
C43 C42 C41 120.3(12) . . ?
C43 C42 H42 119.9 . . ?
C41 C42 H42 119.9 . . ?
C44 C43 C42 120.3(11) . . ?
C44 C43 H43 119.9 . . ?
C42 C43 H43 119.9 . . ?
C45 C44 C43 120.4(10) . . ?
C45 C44 H44 119.8 . . ?
C43 C44 H44 119.8 . . ?
C44 C45 C46 118.9(15) . . ?
C44 C45 H45 120.6 . . ?
C46 C45 H45 120.6 . . ?
C41 C46 C45 122.5(12) . . ?
C41 C46 H46 118.8 . . ?
C45 C46 H46 118.8 . . ?
C52 C51 C56 117.9(7) . . ?
C52 C51 P3 119.7(6) . . ?
C56 C51 P3 122.3(6) . . ?
C53 C52 C51 120.4(9) . . ?
C53 C52 H52 119.8 . . ?
C51 C52 H52 119.8 . . ?
C54 C53 C52 120.3(9) . . ?
C54 C53 H53 119.8 . . ?
C52 C53 H53 119.8 . . ?
C53 C54 C55 121.2(9) . . ?
C53 C54 H54 119.4 . . ?
C55 C54 H54 119.4 . . ?
C56 C55 C54 117.5(10) . . ?
C56 C55 H55 121.2 . . ?
C54 C55 H55 121.2 . . ?
C55 C56 C51 122.4(9) . . ?
C55 C56 H56 118.8 . . ?
C51 C56 H56 118.8 . . ?
C66 C61 C62 119.6(7) . . ?
C66 C61 P3 122.7(6) . . ?
C62 C61 P3 117.7(5) . . ?
C63 C62 C61 121.1(7) . . ?
C63 C62 H62 119.5 . . ?
C61 C62 H62 119.5 . . ?
C62 C63 C64 117.9(8) . . ?
C62 C63 H63 121.1 . . ?
C64 C63 H63 121.1 . . ?
C65 C64 C63 122.0(8) . . ?
C65 C64 H64 119.0 . . ?
C63 C64 H64 119.0 . . ?
C64 C65 C66 120.2(7) . . ?
C64 C65 H65 119.9 . . ?
C66 C65 H65 119.9 . . ?
C61 C66 C65 119.3(8) . . ?
C61 C66 H66 120.3 . . ?
C65 C66 H66 120.3 . . ?
C72 C71 C76 118.1(7) . . ?
C72 C71 P4 122.9(5) . . ?
C76 C71 P4 118.9(6) . . ?
C71 C72 C73 120.9(9) . . ?
C71 C72 H72 119.5 . . ?
C73 C72 H72 119.5 . . ?
C74 C73 C72 118.3(11) . . ?
C74 C73 H73 120.8 . . ?
C72 C73 H73 120.8 . . ?
C75 C74 C73 121.0(9) . . ?
C75 C74 H74 119.5 . . ?
C73 C74 H74 119.5 . . ?
C76 C75 C74 120.4(9) . . ?
C76 C75 H75 119.8 . . ?
C74 C75 H75 119.8 . . ?
C75 C76 C71 121.2(9) . . ?
C75 C76 H76 119.4 . . ?
C71 C76 H76 119.4 . . ?
C82 C81 C86 120.6(6) . . ?
C82 C81 P4 121.6(6) . . ?
C86 C81 P4 117.9(5) . . ?
C81 C82 C83 119.8(8) . . ?
C81 C82 H82 120.1 . . ?
C83 C82 H82 120.1 . . ?
C84 C83 C82 119.6(8) . . ?
C84 C83 H83 120.2 . . ?
C82 C83 H83 120.2 . . ?
C83 C84 C85 120.9(7) . . ?
C83 C84 H84 119.6 . . ?
C85 C84 H84 119.6 . . ?
C86 C85 C84 119.6(9) . . ?
C86 C85 H85 120.2 . . ?
C84 C85 H85 120.2 . . ?
C85 C86 C81 119.3(7) . . ?
C85 C86 H86 120.3 . . ?
C81 C86 H86 120.3 . . ?
F3 Sb1 F5 90.0(8) . . ?
F3 Sb1 F2 177.5(9) . . ?
F5 Sb1 F2 91.6(9) . . ?
F3 Sb1 F6 88.9(8) . . ?
F5 Sb1 F6 177.4(6) . . ?
F2 Sb1 F6 89.4(9) . . ?
F3 Sb1 F4 92.6(8) . . ?
F5 Sb1 F4 86.8(5) . . ?
F2 Sb1 F4 85.5(6) . . ?
F6 Sb1 F4 90.8(7) . . ?
F3 Sb1 F1 94.1(8) . . ?
F5 Sb1 F1 92.8(5) . . ?
F2 Sb1 F1 87.8(5) . . ?
F6 Sb1 F1 89.7(6) . . ?
F4 Sb1 F1 173.3(6) . . ?
F12 Sb2 F11 100.2(9) . . ?
F12 Sb2 F10 97.1(14) . . ?
F11 Sb2 F10 93.2(8) . . ?
F12 Sb2 F8 76.1(13) . . ?
F11 Sb2 F8 90.1(8) . . ?
F10 Sb2 F8 172.8(15) . . ?
F12 Sb2 F9 91.6(8) . . ?
F11 Sb2 F9 166.7(8) . . ?
F10 Sb2 F9 91.3(10) . . ?
F8 Sb2 F9 86.9(9) . . ?
F12 Sb2 F7 168.0(14) . . ?
F11 Sb2 F7 80.8(9) . . ?
F10 Sb2 F7 94.9(14) . . ?
F8 Sb2 F7 92.0(15) . . ?
F9 Sb2 F7 86.4(8) . . ?
F26 F7 Sb2 128.9(16) . . ?
F25 F9 Sb2 133.7(16) . . ?
F18 Sb3 F16 89.4(11) . . ?
F18 Sb3 F17 88.3(6) . . ?
F16 Sb3 F17 96.9(7) . . ?
F18 Sb3 F15 91.5(8) . . ?
F16 Sb3 F15 172.7(5) . . ?
F17 Sb3 F15 90.4(6) . . ?
F18 Sb3 F13 173.2(8) . . ?
F16 Sb3 F13 96.8(9) . . ?
F17 Sb3 F13 93.7(5) . . ?
F15 Sb3 F13 82.0(6) . . ?
F18 Sb3 F14 90.0(5) . . ?
F16 Sb3 F14 84.6(4) . . ?
F17 Sb3 F14 177.7(5) . . ?
F15 Sb3 F14 88.1(4) . . ?
F13 Sb3 F14 87.8(4) . . ?
F20 Sb4 F20 179.998(1) 2_755 . ?
F20 Sb4 F19 90.4(8) 2_755 . ?
F20 Sb4 F19 89.6(8) . . ?
F20 Sb4 F19 89.6(8) 2_755 2_755 ?
F20 Sb4 F19 90.4(8) . 2_755 ?
F19 Sb4 F19 179.998(1) . 2_755 ?
F20 Sb4 F21 88.9(7) 2_755 . ?
F20 Sb4 F21 91.1(7) . . ?
F19 Sb4 F21 89.0(7) . . ?
F19 Sb4 F21 91.0(7) 2_755 . ?
F20 Sb4 F21 91.1(7) 2_755 2_755 ?
F20 Sb4 F21 88.9(7) . 2_755 ?
F19 Sb4 F21 91.0(7) . 2_755 ?
F19 Sb4 F21 89.0(7) 2_755 2_755 ?
F21 Sb4 F21 179.998(1) . 2_755 ?
F23 Sb5 F27 17(2) . . ?
F23 Sb5 F22 114.4(16) . . ?
F27 Sb5 F22 132(2) . . ?
F23 Sb5 F26 135.0(19) . . ?
F27 Sb5 F26 120(2) . . ?
F22 Sb5 F26 107(2) . . ?
F23 Sb5 F28 51(2) . . ?
F27 Sb5 F28 66(2) . . ?
F22 Sb5 F28 68(2) . . ?
F26 Sb5 F28 174(3) . . ?
F23 Sb5 F29 104(3) . . ?
F27 Sb5 F29 97(3) . . ?
F22 Sb5 F29 99(3) . . ?
F26 Sb5 F29 86(2) . . ?
F28 Sb5 F29 91(2) . . ?
F23 Sb5 F25 81.0(17) . . ?
F27 Sb5 F25 87.4(18) . . ?
F22 Sb5 F25 80(2) . . ?
F26 Sb5 F25 90(2) . . ?
F28 Sb5 F25 92.8(17) . . ?
F29 Sb5 F25 175(3) . . ?
F23 Sb5 F24 120.2(14) . . ?
F27 Sb5 F24 118.8(11) . . ?
F22 Sb5 F24 73.6(17) . . ?
F26 Sb5 F24 87.1(19) . . ?
F28 Sb5 F24 87.7(19) . . ?
F29 Sb5 F24 26(3) . . ?
F25 Sb5 F24 151.2(17) . . ?
Sb5 F23 F28 86(2) . . ?
F29 F24 Sb5 68.2(18) . . ?
F9 F25 Sb5 120(2) . . ?
F7 F26 Sb5 141(3) . . ?
F24 F29 Sb5 86(3) . . ?
Cl1 C5 Cl2 120.5(14) . . ?
Cl1 C5 H5A 106.00 . . ?
Cl2 C5 H5A 107.2 . . ?
Cl1 C5 H5B 107.2 . . ?
Cl2 C5 H5B 107.2 . . ?
H5A C5 H5B 106.8 . . ?
Cl6A Cl3A Cl5A 47(4) . . ?
Cl3 C6 Cl4A 111(2) . . ?
Cl3 C6 Cl4 132.5(17) . . ?
Cl4A C6 Cl4 116.1(18) . . ?
C7 Cl5A Cl5 97(3) . . ?
Cl6A Cl5A Cl5 118(5) . . ?
C7 Cl5A Cl3A 75(6) . . ?
Cl6A Cl5A Cl3A 66(6) . . ?
Cl5 Cl5A Cl3A 127(5) . . ?
C7 Cl5A Cl6 85(3) . . ?
Cl6A Cl5A Cl6 75(3) . . ?
Cl5 Cl5A Cl6 110(3) . . ?
Cl3A Cl5A Cl6 121(6) . . ?
C7 Cl6A Cl3A 75(6) . . ?
Cl5A Cl6A Cl3A 67(4) . . ?
C7 Cl6A Cl6 73(7) . . ?
Cl5A Cl6A Cl6 65(4) . . ?
Cl3A Cl6A Cl6 115(5) . . ?
Cl3A Cl6A Cl5 87(5) . . ?
Cl6 Cl6A Cl5 77(4) . . ?
Cl5A C7 Cl6A 140(8) . . ?
Cl5A C7 Cl3A 82(5) . . ?
Cl6A C7 Cl3A 78(9) . . ?
Cl5A C7 Cl5 62(2) . . ?
Cl6A C7 Cl5 157(8) . . ?
Cl3A C7 Cl5 117(6) . . ?
Cl5A C7 Cl6 76(4) . . ?
Cl6A C7 Cl6 85(6) . . ?
Cl3A C7 Cl6 120(5) . . ?
Cl5 C7 Cl6 100(3) . . ?
Cl8A Cl8 C8 75.4(17) . . ?
Cl8 Cl8A C8 76.0(16) . . ?
Cl7 C8 Cl8A 118(3) . . ?
Cl7 C8 Cl8 106(2) . . ?
Cl9A Cl9 C9 63.7(11) . . ?
Cl9 Cl9A Cl11 120.7(15) . . ?
Cl9 Cl9A C9 72.1(11) . . ?
Cl11 Cl9A C9 58.4(12) . . ?
C9 Cl10 Cl11 45.7(9) . . ?
Cl9A Cl11 C9 63.9(13) . . ?
Cl9A Cl11 Cl13 130.4(18) . . ?
C9 Cl11 Cl13 164.9(18) . . ?
Cl9A Cl11 Cl10 89.4(10) . . ?
Cl13 Cl11 Cl10 130.9(12) . . ?
Cl10 C9 Cl11 90.4(15) . . ?
Cl10 C9 Cl9A 114.9(11) . . ?
Cl11 C9 Cl9A 57.7(12) . . ?
Cl10 C9 Cl9 96.4(12) . . ?
Cl11 C9 Cl9 96.0(14) . . ?
Cl14 Cl13 Cl11 148.8(15) . . ?
C10 Cl13 Cl11 168.3(15) . . ?
C10 Cl14 Cl13 90(2) . . ?
C10 Cl14 Cl12 60.8(17) . . ?
Cl13 Cl14 Cl12 118.0(12) . . ?
Cl14 C10 Cl13 54.4(14) . . ?
Cl14 C10 Cl12 89.5(18) . . ?
Cl13 C10 Cl12 115.5(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Ru1 P1 C11 -116.6(4) . . . . ?
N1 Ru1 P1 C11 49.6(4) . . . . ?
N2 Ru1 P1 C11 -26.9(4) . . . . ?
P2 Ru1 P1 C11 146.4(4) . . . . ?
N3 Ru1 P1 C21 6.1(4) . . . . ?
N1 Ru1 P1 C21 172.4(4) . . . . ?
N2 Ru1 P1 C21 95.9(4) . . . . ?
P2 Ru1 P1 C21 -90.9(4) . . . . ?
N3 Ru1 P1 C1 127.3(3) . . . . ?
N1 Ru1 P1 C1 -66.4(3) . . . . ?
N2 Ru1 P1 C1 -142.9(3) . . . . ?
P2 Ru1 P1 C1 30.3(2) . . . . ?
N3 Ru1 P2 C31 112.7(3) . . . . ?
N4 Ru1 P2 C31 34.6(3) . . . . ?
N1 Ru1 P2 C31 -57.8(3) . . . . ?
P1 Ru1 P2 C31 -142.5(3) . . . . ?
N3 Ru1 P2 C41 -6.3(4) . . . . ?
N4 Ru1 P2 C41 -84.4(4) . . . . ?
N1 Ru1 P2 C41 -176.8(4) . . . . ?
P1 Ru1 P2 C41 98.5(4) . . . . ?
N3 Ru1 P2 C2 -129.0(3) . . . . ?
N4 Ru1 P2 C2 152.8(3) . . . . ?
N1 Ru1 P2 C2 60.5(3) . . . . ?
P1 Ru1 P2 C2 -24.2(2) . . . . ?
N6 Pd1 P3 C61 -31.6(3) . . . . ?
P4 Pd1 P3 C61 151.2(2) . . . . ?
N6 Pd1 P3 C51 92.0(3) . . . . ?
P4 Pd1 P3 C51 -85.2(3) . . . . ?
N6 Pd1 P3 C3 -155.0(3) . . . . ?
P4 Pd1 P3 C3 27.8(2) . . . . ?
N5 Pd1 P4 C71 -84.6(3) . . . . ?
P3 Pd1 P4 C71 97.0(2) . . . . ?
N5 Pd1 P4 C81 36.1(3) . . . . ?
P3 Pd1 P4 C81 -142.3(2) . . . . ?
N5 Pd1 P4 C4 158.8(3) . . . . ?
P3 Pd1 P4 C4 -19.6(2) . . . . ?
N3 Ru1 N1 C101 -149.9(8) . . . . ?
N4 Ru1 N1 C101 -96.9(5) . . . . ?
N2 Ru1 N1 C101 178.2(6) . . . . ?
P1 Ru1 N1 C101 81.5(5) . . . . ?
P2 Ru1 N1 C101 -3.7(5) . . . . ?
N3 Ru1 N1 C105 28.6(10) . . . . ?
N4 Ru1 N1 C105 81.6(4) . . . . ?
N2 Ru1 N1 C105 -3.3(4) . . . . ?
P1 Ru1 N1 C105 -100.0(4) . . . . ?
P2 Ru1 N1 C105 174.8(4) . . . . ?
N3 Ru1 N2 C106 -169.4(5) . . . . ?
N4 Ru1 N2 C106 -91.4(5) . . . . ?
N1 Ru1 N2 C106 1.7(5) . . . . ?
P1 Ru1 N2 C106 85.5(5) . . . . ?
N3 Ru1 N2 C110 11.0(7) . . . . ?
N4 Ru1 N2 C110 89.0(7) . . . . ?
N1 Ru1 N2 C110 -177.9(7) . . . . ?
P1 Ru1 N2 C110 -94.0(6) . . . . ?
N4 Ru1 N3 C201 -169.5(8) . . . . ?
N1 Ru1 N3 C201 -114.8(10) . . . . ?
N2 Ru1 N3 C201 -83.8(8) . . . . ?
P1 Ru1 N3 C201 11.4(8) . . . . ?
P2 Ru1 N3 C201 99.1(7) . . . . ?
N4 Ru1 N3 C205 1.5(5) . . . . ?
N1 Ru1 N3 C205 56.2(11) . . . . ?
N2 Ru1 N3 C205 87.2(6) . . . . ?
P1 Ru1 N3 C205 -177.6(5) . . . . ?
P2 Ru1 N3 C205 -89.9(5) . . . . ?
N3 Ru1 N4 C210 179.5(6) . . . . ?
N1 Ru1 N4 C210 13.4(6) . . . . ?
N2 Ru1 N4 C210 90.2(6) . . . . ?
P2 Ru1 N4 C210 -83.1(6) . . . . ?
N3 Ru1 N4 C206 -4.8(5) . . . . ?
N1 Ru1 N4 C206 -170.9(5) . . . . ?
N2 Ru1 N4 C206 -94.0(5) . . . . ?
P2 Ru1 N4 C206 92.6(4) . . . . ?
N6 Pd1 N5 C305 12.7(5) . . . . ?
P4 Pd1 N5 C305 -170.3(5) . . . . ?
N6 Pd1 N5 C301 -173.1(8) . . . . ?
P4 Pd1 N5 C301 4.0(7) . . . . ?
N5 Pd1 N6 C306 -14.4(6) . . . . ?
P3 Pd1 N6 C306 163.8(5) . . . . ?
N5 Pd1 N6 C310 171.2(8) . . . . ?
P3 Pd1 N6 C310 -10.7(8) . . . . ?
C11 P1 C1 C4 106.8(5) . . . . ?
C21 P1 C1 C4 1.1(5) . . . . ?
Ru1 P1 C1 C4 -136.1(4) . . . . ?
C11 P1 C1 C2 -149.4(5) . . . . ?
C21 P1 C1 C2 104.9(5) . . . . ?
Ru1 P1 C1 C2 -32.3(5) . . . . ?
C4 C1 C2 C3 11.0(5) . . . . ?
P1 C1 C2 C3 -109.9(4) . . . . ?
C4 C1 C2 P2 134.5(5) . . . . ?
P1 C1 C2 P2 13.5(6) . . . . ?
C31 P2 C2 C3 -123.0(5) . . . . ?
C41 P2 C2 C3 -18.3(6) . . . . ?
Ru1 P2 C2 C3 115.0(4) . . . . ?
C31 P2 C2 C1 133.4(5) . . . . ?
C41 P2 C2 C1 -121.9(5) . . . . ?
Ru1 P2 C2 C1 11.3(5) . . . . ?
C1 C2 C3 C4 -11.0(5) . . . . ?
P2 C2 C3 C4 -128.5(5) . . . . ?
C1 C2 C3 P3 -126.1(5) . . . . ?
P2 C2 C3 P3 116.4(5) . . . . ?
C61 P3 C3 C4 -157.8(5) . . . . ?
C51 P3 C3 C4 85.8(5) . . . . ?
Pd1 P3 C3 C4 -31.9(5) . . . . ?
C61 P3 C3 C2 -54.1(5) . . . . ?
C51 P3 C3 C2 -170.5(5) . . . . ?
Pd1 P3 C3 C2 71.8(5) . . . . ?
C2 C3 C4 C1 11.1(5) . . . . ?
P3 C3 C4 C1 135.1(4) . . . . ?
C2 C3 C4 P4 -108.1(5) . . . . ?
P3 C3 C4 P4 16.0(6) . . . . ?
C2 C1 C4 C3 -11.1(5) . . . . ?
P1 C1 C4 C3 107.2(5) . . . . ?
C2 C1 C4 P4 105.4(5) . . . . ?
P1 C1 C4 P4 -136.4(4) . . . . ?
C71 P4 C4 C3 -112.6(5) . . . . ?
C81 P4 C4 C3 133.7(5) . . . . ?
Pd1 P4 C4 C3 6.1(5) . . . . ?
C71 P4 C4 C1 145.1(5) . . . . ?
C81 P4 C4 C1 31.5(5) . . . . ?
Pd1 P4 C4 C1 -96.2(4) . . . . ?
C105 N1 C101 C102 -1.6(10) . . . . ?
Ru1 N1 C101 C102 176.9(6) . . . . ?
N1 C101 C102 C103 -0.4(12) . . . . ?
C101 C102 C103 C104 2.1(14) . . . . ?
C102 C103 C104 C105 -1.9(14) . . . . ?
C101 N1 C105 C104 1.9(9) . . . . ?
Ru1 N1 C105 C104 -176.8(5) . . . . ?
C101 N1 C105 C106 -176.8(6) . . . . ?
Ru1 N1 C105 C106 4.5(7) . . . . ?
C103 C104 C105 N1 -0.2(12) . . . . ?
C103 C104 C105 C106 178.4(8) . . . . ?
C110 N2 C106 C107 3.0(10) . . . . ?
Ru1 N2 C106 C107 -176.6(6) . . . . ?
C110 N2 C106 C105 179.8(6) . . . . ?
Ru1 N2 C106 C105 0.2(8) . . . . ?
N1 C105 C106 N2 -3.1(9) . . . . ?
C104 C105 C106 N2 178.2(7) . . . . ?
N1 C105 C106 C107 173.5(7) . . . . ?
C104 C105 C106 C107 -5.1(11) . . . . ?
N2 C106 C107 C108 -0.5(12) . . . . ?
C105 C106 C107 C108 -177.0(8) . . . . ?
C106 C107 C108 C109 -2.0(15) . . . . ?
C107 C108 C109 C110 2.0(16) . . . . ?
C108 C109 C110 N2 0.6(15) . . . . ?
C106 N2 C110 C109 -3.0(12) . . . . ?
Ru1 N2 C110 C109 176.5(7) . . . . ?
C205 N3 C201 C202 2.2(16) . . . . ?
Ru1 N3 C201 C202 172.9(11) . . . . ?
N3 C201 C202 C203 1(2) . . . . ?
C201 C202 C203 C204 -5(3) . . . . ?
C202 C203 C204 C205 5(2) . . . . ?
C201 N3 C205 C204 -2.3(13) . . . . ?
Ru1 N3 C205 C204 -174.1(8) . . . . ?
C201 N3 C205 C206 173.7(8) . . . . ?
Ru1 N3 C205 C206 1.9(9) . . . . ?
C203 C204 C205 N3 -1.1(19) . . . . ?
C203 C204 C205 C206 -176.8(13) . . . . ?
C210 N4 C206 C207 -0.4(10) . . . . ?
Ru1 N4 C206 C207 -176.4(6) . . . . ?
C210 N4 C206 C205 -176.9(7) . . . . ?
Ru1 N4 C206 C205 7.1(7) . . . . ?
N3 C205 C206 N4 -6.0(10) . . . . ?
C204 C205 C206 N4 169.6(9) . . . . ?
N3 C205 C206 C207 177.8(8) . . . . ?
C204 C205 C206 C207 -6.6(14) . . . . ?
N4 C206 C207 C208 0.8(13) . . . . ?
C205 C206 C207 C208 176.8(9) . . . . ?
C206 C207 C208 C209 -2.5(15) . . . . ?
C207 C208 C209 C210 3.8(15) . . . . ?
C206 N4 C210 C209 1.7(11) . . . . ?
Ru1 N4 C210 C209 177.3(6) . . . . ?
C208 C209 C210 N4 -3.5(14) . . . . ?
C305 N5 C301 C302 -0.9(14) . . . . ?
Pd1 N5 C301 C302 -175.0(9) . . . . ?
N5 C301 C302 C303 8(2) . . . . ?
C301 C302 C303 C304 -10(2) . . . . ?
C302 C303 C304 C305 6(2) . . . . ?
C301 N5 C305 C304 -3.2(13) . . . . ?
Pd1 N5 C305 C304 171.7(8) . . . . ?
C301 N5 C305 C306 175.8(7) . . . . ?
Pd1 N5 C305 C306 -9.3(8) . . . . ?
C303 C304 C305 N5 0.8(19) . . . . ?
C303 C304 C305 C306 -178.1(13) . . . . ?
C310 N6 C306 C307 3.2(12) . . . . ?
Pd1 N6 C306 C307 -171.7(7) . . . . ?
C310 N6 C306 C305 -171.0(8) . . . . ?
Pd1 N6 C306 C305 14.1(9) . . . . ?
N5 C305 C306 N6 -3.3(10) . . . . ?
C304 C305 C306 N6 175.6(10) . . . . ?
N5 C305 C306 C307 -177.0(9) . . . . ?
C304 C305 C306 C307 1.9(15) . . . . ?
N6 C306 C307 C308 -1.2(16) . . . . ?
C305 C306 C307 C308 172.4(11) . . . . ?
C306 C307 C308 C309 -2(2) . . . . ?
C307 C308 C309 C310 3(2) . . . . ?
C308 C309 C310 N6 -1(2) . . . . ?
C306 N6 C310 C309 -2.3(16) . . . . ?
Pd1 N6 C310 C309 171.8(10) . . . . ?
C21 P1 C11 C12 -62.0(7) . . . . ?
C1 P1 C11 C12 -168.7(6) . . . . ?
Ru1 P1 C11 C12 76.5(7) . . . . ?
C21 P1 C11 C16 128.0(7) . . . . ?
C1 P1 C11 C16 21.2(7) . . . . ?
Ru1 P1 C11 C16 -93.6(6) . . . . ?
C16 C11 C12 C13 1.4(12) . . . . ?
P1 C11 C12 C13 -169.1(7) . . . . ?
C11 C12 C13 C14 -1.2(18) . . . . ?
C12 C13 C14 C15 1(2) . . . . ?
C13 C14 C15 C16 -1(2) . . . . ?
C12 C11 C16 C15 -1.7(12) . . . . ?
P1 C11 C16 C15 168.3(7) . . . . ?
C14 C15 C16 C11 1.5(15) . . . . ?
C11 P1 C21 C22 -13.8(8) . . . . ?
C1 P1 C21 C22 97.3(7) . . . . ?
Ru1 P1 C21 C22 -139.9(6) . . . . ?
C11 P1 C21 C26 174.4(7) . . . . ?
C1 P1 C21 C26 -74.4(7) . . . . ?
Ru1 P1 C21 C26 48.3(8) . . . . ?
C26 C21 C22 C23 -1.4(14) . . . . ?
P1 C21 C22 C23 -173.3(8) . . . . ?
C21 C22 C23 C24 0.0(19) . . . . ?
C22 C23 C24 C25 1(2) . . . . ?
C23 C24 C25 C26 -1(2) . . . . ?
C22 C21 C26 C25 1.7(13) . . . . ?
P1 C21 C26 C25 173.8(7) . . . . ?
C24 C25 C26 C21 -0.5(17) . . . . ?
C41 P2 C31 C36 -127.5(7) . . . . ?
C2 P2 C31 C36 -18.3(7) . . . . ?
Ru1 P2 C31 C36 100.2(6) . . . . ?
C41 P2 C31 C32 56.8(8) . . . . ?
C2 P2 C31 C32 166.0(7) . . . . ?
Ru1 P2 C31 C32 -75.5(7) . . . . ?
C36 C31 C32 C33 -3.8(14) . . . . ?
P2 C31 C32 C33 172.3(9) . . . . ?
C31 C32 C33 C34 4(2) . . . . ?
C32 C33 C34 C35 0(2) . . . . ?
C33 C34 C35 C36 -4.0(19) . . . . ?
C34 C35 C36 C31 3.8(15) . . . . ?
C32 C31 C36 C35 0.2(12) . . . . ?
P2 C31 C36 C35 -175.4(7) . . . . ?
C31 P2 C41 C46 -142.0(9) . . . . ?
C2 P2 C41 C46 107.3(8) . . . . ?
Ru1 P2 C41 C46 -16.5(10) . . . . ?
C31 P2 C41 C42 35.8(9) . . . . ?
C2 P2 C41 C42 -74.9(9) . . . . ?
Ru1 P2 C41 C42 161.3(7) . . . . ?
C46 C41 C42 C43 -0.6(18) . . . . ?
P2 C41 C42 C43 -178.6(11) . . . . ?
C41 C42 C43 C44 1(2) . . . . ?
C42 C43 C44 C45 -1(3) . . . . ?
C43 C44 C45 C46 0(2) . . . . ?
C42 C41 C46 C45 -0.4(17) . . . . ?
P2 C41 C46 C45 177.5(10) . . . . ?
C44 C45 C46 C41 1(2) . . . . ?
C61 P3 C51 C52 109.9(7) . . . . ?
C3 P3 C51 C52 -134.1(6) . . . . ?
Pd1 P3 C51 C52 -16.0(7) . . . . ?
C61 P3 C51 C56 -70.6(7) . . . . ?
C3 P3 C51 C56 45.5(7) . . . . ?
Pd1 P3 C51 C56 163.5(6) . . . . ?
C56 C51 C52 C53 -0.5(13) . . . . ?
P3 C51 C52 C53 179.1(8) . . . . ?
C51 C52 C53 C54 -1.9(17) . . . . ?
C52 C53 C54 C55 4.6(19) . . . . ?
C53 C54 C55 C56 -4.9(18) . . . . ?
C54 C55 C56 C51 2.5(16) . . . . ?
C52 C51 C56 C55 0.1(14) . . . . ?
P3 C51 C56 C55 -179.4(8) . . . . ?
C51 P3 C61 C66 4.4(7) . . . . ?
C3 P3 C61 C66 -107.4(6) . . . . ?
Pd1 P3 C61 C66 128.4(5) . . . . ?
C51 P3 C61 C62 -171.6(5) . . . . ?
C3 P3 C61 C62 76.6(6) . . . . ?
Pd1 P3 C61 C62 -47.6(5) . . . . ?
C66 C61 C62 C63 1.4(10) . . . . ?
P3 C61 C62 C63 177.5(6) . . . . ?
C61 C62 C63 C64 -1.8(11) . . . . ?
C62 C63 C64 C65 1.7(13) . . . . ?
C63 C64 C65 C66 -1.2(14) . . . . ?
C62 C61 C66 C65 -0.8(11) . . . . ?
P3 C61 C66 C65 -176.7(6) . . . . ?
C64 C65 C66 C61 0.7(13) . . . . ?
C81 P4 C71 C72 79.5(7) . . . . ?
C4 P4 C71 C72 -34.0(7) . . . . ?
Pd1 P4 C71 C72 -154.6(6) . . . . ?
C81 P4 C71 C76 -97.0(6) . . . . ?
C4 P4 C71 C76 149.5(6) . . . . ?
Pd1 P4 C71 C76 28.9(6) . . . . ?
C76 C71 C72 C73 -1.2(12) . . . . ?
P4 C71 C72 C73 -177.8(7) . . . . ?
C71 C72 C73 C74 -0.2(15) . . . . ?
C72 C73 C74 C75 1.4(16) . . . . ?
C73 C74 C75 C76 -1.0(17) . . . . ?
C74 C75 C76 C71 -0.6(15) . . . . ?
C72 C71 C76 C75 1.7(13) . . . . ?
P4 C71 C76 C75 178.3(7) . . . . ?
C71 P4 C81 C82 -19.2(7) . . . . ?
C4 P4 C81 C82 93.6(7) . . . . ?
Pd1 P4 C81 C82 -141.0(6) . . . . ?
C71 P4 C81 C86 160.2(6) . . . . ?
C4 P4 C81 C86 -87.0(6) . . . . ?
Pd1 P4 C81 C86 38.5(6) . . . . ?
C86 C81 C82 C83 0.3(13) . . . . ?
P4 C81 C82 C83 179.7(8) . . . . ?
C81 C82 C83 C84 -2.9(16) . . . . ?
C82 C83 C84 C85 5.0(17) . . . . ?
C83 C84 C85 C86 -4.6(16) . . . . ?
C84 C85 C86 C81 2.0(14) . . . . ?
C82 C81 C86 C85 0.1(12) . . . . ?
P4 C81 C86 C85 -179.4(7) . . . . ?
F12 Sb2 F7 F26 79(5) . . . . ?
F11 Sb2 F7 F26 174(3) . . . . ?
F10 Sb2 F7 F26 -93(3) . . . . ?
F8 Sb2 F7 F26 85(3) . . . . ?
F9 Sb2 F7 F26 -2(3) . . . . ?
F12 Sb2 F9 F25 -133(3) . . . . ?
F11 Sb2 F9 F25 20(5) . . . . ?
F10 Sb2 F9 F25 130(3) . . . . ?
F8 Sb2 F9 F25 -57(3) . . . . ?
F7 Sb2 F9 F25 35(3) . . . . ?
F27 Sb5 F23 F28 -148(8) . . . . ?
F22 Sb5 F23 F28 26(3) . . . . ?
F26 Sb5 F23 F28 -178(3) . . . . ?
F29 Sb5 F23 F28 -80(3) . . . . ?
F25 Sb5 F23 F28 101(2) . . . . ?
F24 Sb5 F23 F28 -58(2) . . . . ?
F23 Sb5 F24 F29 -56(6) . . . . ?
F27 Sb5 F24 F29 -36(6) . . . . ?
F22 Sb5 F24 F29 -165(6) . . . . ?
F26 Sb5 F24 F29 86(6) . . . . ?
F28 Sb5 F24 F29 -98(6) . . . . ?
F25 Sb5 F24 F29 171(5) . . . . ?
Sb2 F9 F25 Sb5 -66(5) . . . . ?
F23 Sb5 F25 F9 175(3) . . . . ?
F27 Sb5 F25 F9 159(3) . . . . ?
F22 Sb5 F25 F9 -68(3) . . . . ?
F26 Sb5 F25 F9 39(3) . . . . ?
F28 Sb5 F25 F9 -135(3) . . . . ?
F24 Sb5 F25 F9 -44(5) . . . . ?
Sb2 F7 F26 Sb5 -2(7) . . . . ?
F23 Sb5 F26 F7 -93(5) . . . . ?
F27 Sb5 F26 F7 -103(5) . . . . ?
F22 Sb5 F26 F7 63(5) . . . . ?
F29 Sb5 F26 F7 161(6) . . . . ?
F25 Sb5 F26 F7 -16(5) . . . . ?
F24 Sb5 F26 F7 135(5) . . . . ?
F27 Sb5 F28 F23 10(2) . . . . ?
F22 Sb5 F28 F23 -154(3) . . . . ?
F29 Sb5 F28 F23 107(3) . . . . ?
F25 Sb5 F28 F23 -76(2) . . . . ?
F24 Sb5 F28 F23 132.8(18) . . . . ?
F23 Sb5 F29 F24 132(5) . . . . ?
F27 Sb5 F29 F24 148(5) . . . . ?
F22 Sb5 F29 F24 14(6) . . . . ?
F26 Sb5 F29 F24 -92(5) . . . . ?
F28 Sb5 F29 F24 82(5) . . . . ?
Cl4A Cl3 C6 Cl4 -176(5) . . . . ?
Cl3 Cl4A C6 Cl4 177(4) . . . . ?
Cl6A Cl5 Cl5A C7 3(6) . . . . ?
C7 Cl5 Cl5A Cl6A -3(6) . . . . ?
C7 Cl5 Cl5A Cl3A 76(7) . . . . ?
Cl6A Cl5 Cl5A Cl3A 80(6) . . . . ?
C7 Cl5 Cl5A Cl6 -87(3) . . . . ?
Cl6A Cl5 Cl5A Cl6 -84(4) . . . . ?
Cl6A Cl3A Cl5A C7 -20(4) . . . . ?
C7 Cl3A Cl5A Cl6A 20(4) . . . . ?
C7 Cl3A Cl5A Cl5 -87(5) . . . . ?
Cl6A Cl3A Cl5A Cl5 -108(6) . . . . ?
C7 Cl3A Cl5A Cl6 74(4) . . . . ?
Cl6A Cl3A Cl5A Cl6 54(5) . . . . ?
Cl6A Cl5A Cl6 C7 -19(6) . . . . ?
Cl5 Cl5A Cl6 C7 95(3) . . . . ?
Cl3A Cl5A Cl6 C7 -69(5) . . . . ?
C7 Cl5A Cl6 Cl6A 19(6) . . . . ?
Cl5 Cl5A Cl6 Cl6A 115(5) . . . . ?
Cl3A Cl5A Cl6 Cl6A -50(6) . . . . ?
Cl5 Cl5A Cl6A C7 8(16) . . . . ?
Cl3A Cl5A Cl6A C7 -112(15) . . . . ?
Cl6 Cl5A Cl6A C7 114(16) . . . . ?
C7 Cl5A Cl6A Cl3A 112(15) . . . . ?
Cl5 Cl5A Cl6A Cl3A 121(6) . . . . ?
Cl6 Cl5A Cl6A Cl3A -134(6) . . . . ?
C7 Cl5A Cl6A Cl6 -114(16) . . . . ?
Cl5 Cl5A Cl6A Cl6 -105(3) . . . . ?
Cl3A Cl5A Cl6A Cl6 134(6) . . . . ?
C7 Cl5A Cl6A Cl5 -8(16) . . . . ?
Cl3A Cl5A Cl6A Cl5 -121(6) . . . . ?
Cl6 Cl5A Cl6A Cl5 105(3) . . . . ?
Cl5A Cl3A Cl6A C7 17(4) . . . . ?
C7 Cl3A Cl6A Cl5A -17(4) . . . . ?
C7 Cl3A Cl6A Cl6 -63(7) . . . . ?
Cl5A Cl3A Cl6A Cl6 -46(6) . . . . ?
C7 Cl3A Cl6A Cl5 11(4) . . . . ?
Cl5A Cl3A Cl6A Cl5 29(2) . . . . ?
Cl5A Cl6 Cl6A C7 -17(4) . . . . ?
C7 Cl6 Cl6A Cl5A 17(4) . . . . ?
Cl5A Cl6 Cl6A Cl3A 47(6) . . . . ?
C7 Cl6 Cl6A Cl3A 64(6) . . . . ?
Cl5A Cl6 Cl6A Cl5 -34(3) . . . . ?
C7 Cl6 Cl6A Cl5 -16(7) . . . . ?
Cl5A Cl5 Cl6A C7 -9(16) . . . . ?
C7 Cl5 Cl6A Cl5A 9(17) . . . . ?
Cl5A Cl5 Cl6A Cl3A -53(5) . . . . ?
Cl5A Cl5 Cl6A Cl6 63(4) . . . . ?
C7 Cl5 Cl6A Cl6 73(19) . . . . ?
Cl5 Cl5A C7 Cl6A -173(15) . . . . ?
Cl3A Cl5A C7 Cl6A 61(15) . . . . ?
Cl6 Cl5A C7 Cl6A -63(15) . . . . ?
Cl6A Cl5A C7 Cl3A -61(15) . . . . ?
Cl5 Cl5A C7 Cl3A 127(5) . . . . ?
Cl6 Cl5A C7 Cl3A -124(6) . . . . ?
Cl6A Cl5A C7 Cl5 173(15) . . . . ?
Cl3A Cl5A C7 Cl5 -127(5) . . . . ?
Cl6 Cl5A C7 Cl5 110(3) . . . . ?
Cl6A Cl5A C7 Cl6 63(15) . . . . ?
Cl5 Cl5A C7 Cl6 -110(3) . . . . ?
Cl3A Cl5A C7 Cl6 124(6) . . . . ?
Cl3A Cl6A C7 Cl5A -62(13) . . . . ?
Cl6 Cl6A C7 Cl5A 60(13) . . . . ?
Cl5 Cl6A C7 Cl5A 163(31) . . . . ?
Cl5A Cl6A C7 Cl3A 62(14) . . . . ?
Cl6 Cl6A C7 Cl3A 122(5) . . . . ?
Cl5 Cl6A C7 Cl3A -135(19) . . . . ?
Cl5A Cl6A C7 Cl5 -163(31) . . . . ?
Cl3A Cl6A C7 Cl5 135(19) . . . . ?
Cl6 Cl6A C7 Cl5 -103(18) . . . . ?
Cl5A Cl6A C7 Cl6 -60(13) . . . . ?
Cl3A Cl6A C7 Cl6 -122(5) . . . . ?
Cl5 Cl6A C7 Cl6 103(18) . . . . ?
Cl6A Cl3A C7 Cl5A 145(7) . . . . ?
Cl5A Cl3A C7 Cl6A -145(7) . . . . ?
Cl6A Cl3A C7 Cl5 -162(6) . . . . ?
Cl5A Cl3A C7 Cl5 53(3) . . . . ?
Cl6A Cl3A C7 Cl6 77(6) . . . . ?
Cl5A Cl3A C7 Cl6 -68(5) . . . . ?
Cl6A Cl5 C7 Cl5A -168(21) . . . . ?
Cl5A Cl5 C7 Cl6A 168(22) . . . . ?
Cl5A Cl5 C7 Cl3A -64(5) . . . . ?
Cl5A Cl5 C7 Cl6 68(4) . . . . ?
Cl6A Cl5 C7 Cl6 -100(20) . . . . ?
Cl6A Cl6 C7 Cl5A -145(10) . . . . ?
Cl5A Cl6 C7 Cl6A 145(10) . . . . ?
Cl5A Cl6 C7 Cl3A 72(7) . . . . ?
Cl6A Cl6 C7 Cl3A -73(9) . . . . ?
Cl5A Cl6 C7 Cl5 -57(3) . . . . ?
Cl6A Cl6 C7 Cl5 157(9) . . . . ?
Cl8 Cl8A C8 Cl7 71(3) . . . . ?
Cl8A Cl8 C8 Cl7 -120(3) . . . . ?
C9 Cl9 Cl9A Cl11 -33.6(15) . . . . ?
Cl9 Cl9A Cl11 C9 38.2(16) . . . . ?
Cl9 Cl9A Cl11 Cl13 -147.3(15) . . . . ?
C9 Cl9A Cl11 Cl13 174.5(17) . . . . ?
Cl9 Cl9A Cl11 Cl10 1.1(15) . . . . ?
C9 Cl9A Cl11 Cl10 -37.1(9) . . . . ?
C9 Cl10 Cl11 Cl9A 51.4(13) . . . . ?
C9 Cl10 Cl11 Cl13 -160.5(19) . . . . ?
Cl11 Cl10 C9 Cl9A -54.1(12) . . . . ?
Cl11 Cl10 C9 Cl9 -96.1(14) . . . . ?
Cl9A Cl11 C9 Cl10 -119.6(11) . . . . ?
Cl13 Cl11 C9 Cl10 77(6) . . . . ?
Cl13 Cl11 C9 Cl9A -164(6) . . . . ?
Cl10 Cl11 C9 Cl9A 119.6(11) . . . . ?
Cl9A Cl11 C9 Cl9 -23.1(11) . . . . ?
Cl13 Cl11 C9 Cl9 173(6) . . . . ?
Cl10 Cl11 C9 Cl9 96.5(12) . . . . ?
Cl9 Cl9A C9 Cl10 -72.5(16) . . . . ?
Cl11 Cl9A C9 Cl10 73.5(15) . . . . ?
Cl9 Cl9A C9 Cl11 -146.0(16) . . . . ?
Cl11 Cl9A C9 Cl9 146.0(16) . . . . ?
Cl9A Cl9 C9 Cl10 119.5(14) . . . . ?
Cl9A Cl9 C9 Cl11 28.3(14) . . . . ?
Cl9A Cl11 Cl13 Cl14 -154(2) . . . . ?
C9 Cl11 Cl13 Cl14 7(7) . . . . ?
Cl10 Cl11 Cl13 Cl14 70(2) . . . . ?
Cl9A Cl11 Cl13 C10 -51(7) . . . . ?
C9 Cl11 Cl13 C10 110(9) . . . . ?
Cl10 Cl11 Cl13 C10 173(6) . . . . ?
Cl11 Cl13 Cl14 C10 160(3) . . . . ?
C10 Cl13 Cl14 Cl12 -56.7(19) . . . . ?
Cl11 Cl13 Cl14 Cl12 103(3) . . . . ?
C10 Cl12 Cl14 Cl13 73(2) . . . . ?
Cl12 Cl14 C10 Cl13 122.3(11) . . . . ?
Cl13 Cl14 C10 Cl12 -122.3(11) . . . . ?
Cl11 Cl13 C10 Cl14 -119(6) . . . . ?
Cl14 Cl13 C10 Cl12 69.3(16) . . . . ?
Cl11 Cl13 C10 Cl12 -50(7) . . . . ?
Cl14 Cl12 C10 Cl13 -49.5(13) . . . . ?

_diffrn_reflns_theta_full        26.03
_diffrn_measured_fraction        0.996
_refine_diff_density_max         1.120
_refine_diff_density_min         -1.070
_refine_diff_density_rms         0.110
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 1404738'
_audit_update_record             
;
2015-06-03 deposited with the CCDC.
2015-11-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        '[Ru(bpy)2(dppcb)Pt(bpy)](BF4)4'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C82 H68 N6 P4 Pt Ru, 4(B F4), 1.4(O)'
_chemical_formula_sum            'C82 H68 B4 F16 N6 O1.40 P4 Pt Ru'
_chemical_formula_weight         1927.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.6388(7)
_cell_length_b                   17.0603(8)
_cell_length_c                   17.5445(8)
_cell_angle_alpha                90.007(2)
_cell_angle_beta                 110.103(2)
_cell_angle_gamma                107.555(2)
_cell_volume                     4162.8(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    243(2)
_cell_measurement_reflns_used    181293
_cell_measurement_theta_min      0.998
_cell_measurement_theta_max      26.373

_exptl_crystal_description       prism
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.538
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1918.4
_exptl_absorpt_coefficient_mu    2.022
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.750
_exptl_absorpt_correction_T_max  0.885
_exptl_absorpt_process_details   'Otwinowski et al, 1997'

_diffrn_ambient_temperature      243(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Kappa CCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         3
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  120
_diffrn_standards_decay_%        0
_diffrn_reflns_number            30330
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_sigmaI/netI    0.1146
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.87
_diffrn_reflns_theta_max         26.56
_reflns_number_total             17362
_reflns_number_gt                10642
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Kappa CCD'
_computing_cell_refinement       'Denzo and Scalepack'
_computing_data_reduction        'Denzo and Scalepack'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-2015 (Sheldrick, 2015)'
_computing_molecular_graphics    'SHELXTL-NT V6.1'
_computing_publication_material  'SHELXTL-NT V6.1'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0835P)²+3.4456P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16479
_refine_ls_number_parameters     1054
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0753
_refine_ls_R_factor_gt           0.0481
_refine_ls_wR_factor_ref         0.1764
_refine_ls_wR_factor_gt          0.1253
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_restrained_S_all      1.021
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_diffrn_measured_fraction_theta_full 1.00

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.26889(4) 0.78519(4) 0.25247(4) 0.03655(16) Uani 1 1 d . . .
Pt1 Pt 0.74348(2) 0.74454(2) 0.313115(19) 0.04215(12) Uani 1 1 d . . .
P1 P 0.32636(14) 0.67493(12) 0.28171(12) 0.0366(4) Uani 1 1 d . . .
P2 P 0.38826(14) 0.83415(12) 0.19731(11) 0.0351(4) Uani 1 1 d . . .
P3 P 0.63592(14) 0.76003(13) 0.19524(12) 0.0384(5) Uani 1 1 d . . .
P4 P 0.61628(15) 0.64969(13) 0.32655(12) 0.0399(5) Uani 1 1 d . . .
C1 C 0.4581(5) 0.7166(4) 0.3013(5) 0.0372(17) Uani 1 1 d . . .
H1 H 0.4957 0.7319 0.3605 0.045 Uiso 1 1 calc R . .
C2 C 0.4874(5) 0.7902(4) 0.2517(4) 0.0342(16) Uani 1 1 d . . .
H2 H 0.5454 0.8345 0.2872 0.041 Uiso 1 1 calc R . .
C3 C 0.5154(5) 0.7319(4) 0.2024(4) 0.0352(16) Uani 1 1 d . . .
H3 H 0.4649 0.7122 0.1475 0.042 Uiso 1 1 calc R . .
C4 C 0.5022(5) 0.6654(4) 0.2618(4) 0.0348(16) Uani 1 1 d . . .
H4 H 0.4536 0.6124 0.2320 0.042 Uiso 1 1 calc R . .
N1 N 0.3555(5) 0.8329(4) 0.3750(4) 0.0392(15) Uani 1 1 d . . .
N2 N 0.1698(5) 0.7508(4) 0.3139(5) 0.0466(17) Uani 1 1 d . . .
C101 C 0.4520(7) 0.8723(5) 0.4066(5) 0.050(2) Uani 1 1 d . . .
H101 H 0.4853 0.8826 0.3702 0.059 Uiso 1 1 calc R . .
C102 C 0.5045(7) 0.8983(6) 0.4889(5) 0.053(2) Uani 1 1 d . . .
H102 H 0.5711 0.9258 0.5077 0.064 Uiso 1 1 calc R . .
C103 C 0.4566(9) 0.8826(7) 0.5414(6) 0.081(3) Uani 1 1 d . . .
H103 H 0.4901 0.8984 0.5978 0.097 Uiso 1 1 calc R . .
C104 C 0.3584(8) 0.8434(7) 0.5120(6) 0.069(3) Uani 1 1 d . . .
H104 H 0.3248 0.8334 0.5482 0.083 Uiso 1 1 calc R . .
C105 C 0.3092(6) 0.8187(5) 0.4290(5) 0.049(2) Uani 1 1 d . . .
C106 C 0.2060(7) 0.7747(5) 0.3940(6) 0.056(2) Uani 1 1 d . . .
C107 C 0.1469(10) 0.7558(7) 0.4418(7) 0.079(3) Uani 1 1 d . . .
H107 H 0.1728 0.7738 0.4981 0.094 Uiso 1 1 calc R . .
C108 C 0.0527(9) 0.7114(8) 0.4051(9) 0.090(4) Uani 1 1 d . . .
H108 H 0.0131 0.6972 0.4362 0.108 Uiso 1 1 calc R . .
C109 C 0.0148(8) 0.6872(7) 0.3226(8) 0.081(3) Uani 1 1 d . . .
H109 H -0.0505 0.6565 0.2966 0.097 Uiso 1 1 calc R . .
C110 C 0.0745(7) 0.7087(6) 0.2790(7) 0.064(3) Uani 1 1 d . . .
H110 H 0.0481 0.6937 0.2222 0.077 Uiso 1 1 calc R . .
N3 N 0.1560(5) 0.7455(4) 0.1402(4) 0.0452(16) Uani 1 1 d . . .
N4 N 0.2248(5) 0.8902(4) 0.2285(4) 0.0467(17) Uani 1 1 d . . .
C201 C 0.1135(6) 0.6686(6) 0.1018(5) 0.054(2) Uani 1 1 d . . .
H201 H 0.1321 0.6253 0.1284 0.064 Uiso 1 1 calc R . .
C202 C 0.0429(7) 0.6500(7) 0.0244(7) 0.073(3) Uani 1 1 d . . .
H202 H 0.0149 0.5950 -0.0007 0.087 Uiso 1 1 calc R . .
C203 C 0.0145(8) 0.7113(8) -0.0151(7) 0.086(3) Uani 1 1 d . . .
H203 H -0.0295 0.7004 -0.0692 0.103 Uiso 1 1 calc R . .
C204 C 0.0514(8) 0.7895(8) 0.0256(7) 0.085(3) Uani 1 1 d . . .
H204 H 0.0291 0.8319 0.0005 0.102 Uiso 1 1 calc R . .
C205 C 0.1220(6) 0.8070(6) 0.1041(6) 0.053(2) Uani 1 1 d . . .
C206 C 0.1596(6) 0.8870(5) 0.1537(6) 0.050(2) Uani 1 1 d . . .
C207 C 0.1307(8) 0.9550(7) 0.1284(7) 0.073(3) Uani 1 1 d . . .
H207 H 0.0868 0.9526 0.0754 0.088 Uiso 1 1 calc R . .
C208 C 0.1670(9) 1.0259(7) 0.1818(8) 0.075(3) Uani 1 1 d . . .
H208 H 0.1481 1.0724 0.1653 0.090 Uiso 1 1 calc R . .
C209 C 0.2286(9) 1.0287(6) 0.2567(8) 0.075(3) Uani 1 1 d . . .
H209 H 0.2521 1.0764 0.2942 0.090 Uiso 1 1 calc R . .
C210 C 0.2588(8) 0.9586(6) 0.2795(6) 0.062(2) Uani 1 1 d . . .
H210 H 0.3039 0.9610 0.3320 0.075 Uiso 1 1 calc R . .
N5 N 0.8484(5) 0.7494(6) 0.4267(4) 0.060(2) Uani 1 1 d . . .
N6 N 0.8657(4) 0.8307(5) 0.3051(4) 0.0488(17) Uani 1 1 d . . .
C301 C 0.8432(8) 0.6977(9) 0.4831(7) 0.085(4) Uani 1 1 d . . .
H301 H 0.7945 0.6460 0.4691 0.102 Uiso 1 1 calc R . .
C302 C 0.9114(11) 0.7207(14) 0.5649(8) 0.122(6) Uani 1 1 d . . .
H302 H 0.9079 0.6841 0.6046 0.146 Uiso 1 1 calc R . .
C303 C 0.9831(10) 0.7977(14) 0.5855(9) 0.118(6) Uani 1 1 d . . .
H303 H 1.0260 0.8158 0.6396 0.142 Uiso 1 1 calc R . .
C304 C 0.9883(9) 0.8445(11) 0.5255(8) 0.098(4) Uani 1 1 d . . .
H304 H 1.0383 0.8952 0.5372 0.117 Uiso 1 1 calc R . .
C305 C 0.9236(6) 0.8213(7) 0.4477(6) 0.064(3) Uani 1 1 d . . .
C306 C 0.9323(6) 0.8655(7) 0.3781(6) 0.064(3) Uani 1 1 d . . .
C307 C 1.0089(8) 0.9377(9) 0.3845(9) 0.093(4) Uani 1 1 d . . .
H307 H 1.0522 0.9654 0.4360 0.111 Uiso 1 1 calc R . .
C308 C 1.0194(9) 0.9673(9) 0.3139(11) 0.104(4) Uani 1 1 d . . .
H308 H 1.0704 1.0149 0.3165 0.125 Uiso 1 1 calc R . .
C309 C 0.9540(9) 0.9259(10) 0.2396(9) 0.094(4) Uani 1 1 d . . .
H309 H 0.9610 0.9442 0.1909 0.113 Uiso 1 1 calc R . .
C310 C 0.8799(7) 0.8590(7) 0.2370(7) 0.067(3) Uani 1 1 d . . .
H310 H 0.8364 0.8308 0.1858 0.081 Uiso 1 1 calc R . .
C11 C 0.2861(5) 0.5796(5) 0.2119(5) 0.0423(19) Uani 1 1 d . . .
C12 C 0.2666(7) 0.5001(5) 0.2373(6) 0.053(2) Uani 1 1 d . . .
H12 H 0.2724 0.4935 0.2919 0.064 Uiso 1 1 calc R . .
C13 C 0.2389(8) 0.4319(6) 0.1818(8) 0.072(3) Uani 1 1 d . . .
H13 H 0.2237 0.3785 0.1981 0.087 Uiso 1 1 calc R . .
C14 C 0.2335(8) 0.4415(8) 0.1031(8) 0.082(4) Uani 1 1 d . . .
H14 H 0.2163 0.3944 0.0664 0.099 Uiso 1 1 calc R . .
C15 C 0.2524(7) 0.5176(7) 0.0767(6) 0.068(3) Uani 1 1 d . . .
H15 H 0.2467 0.5233 0.0220 0.082 Uiso 1 1 calc R . .
C16 C 0.2806(6) 0.5872(6) 0.1328(5) 0.050(2) Uani 1 1 d . . .
H16 H 0.2961 0.6403 0.1158 0.060 Uiso 1 1 calc R . .
C21 C 0.3161(6) 0.6351(5) 0.3756(5) 0.046(2) Uani 1 1 d . . .
C22 C 0.2210(7) 0.5882(6) 0.3699(6) 0.063(2) Uani 1 1 d . . .
H22 H 0.1706 0.5737 0.3187 0.076 Uiso 1 1 calc R . .
C23 C 0.2035(10) 0.5642(8) 0.4400(9) 0.085(4) Uani 1 1 d . . .
H23 H 0.1413 0.5325 0.4364 0.101 Uiso 1 1 calc R . .
C24 C 0.2789(11) 0.5872(8) 0.5164(8) 0.086(4) Uani 1 1 d . . .
H24 H 0.2670 0.5711 0.5640 0.103 Uiso 1 1 calc R . .
C25 C 0.3677(10) 0.6321(7) 0.5214(6) 0.073(3) Uani 1 1 d . . .
H25 H 0.4177 0.6480 0.5727 0.088 Uiso 1 1 calc R . .
C26 C 0.3868(7) 0.6556(6) 0.4506(5) 0.055(2) Uani 1 1 d . . .
H26 H 0.4498 0.6860 0.4552 0.066 Uiso 1 1 calc R . .
C31 C 0.4432(6) 0.9478(5) 0.2138(5) 0.0378(17) Uani 1 1 d . . .
C32 C 0.3876(6) 0.9914(5) 0.1644(6) 0.050(2) Uani 1 1 d . . .
H32 H 0.3263 0.9620 0.1266 0.060 Uiso 1 1 calc R . .
C33 C 0.4202(8) 1.0769(6) 0.1693(7) 0.062(3) Uani 1 1 d . . .
H33 H 0.3814 1.1056 0.1359 0.074 Uiso 1 1 calc R . .
C34 C 0.5117(9) 1.1196(6) 0.2250(7) 0.065(3) Uani 1 1 d . . .
H34 H 0.5350 1.1777 0.2299 0.078 Uiso 1 1 calc R . .
C35 C 0.5673(8) 1.0773(6) 0.2721(6) 0.059(2) Uani 1 1 d . . .
H35 H 0.6298 1.1065 0.3079 0.070 Uiso 1 1 calc R . .
C36 C 0.5335(6) 0.9919(5) 0.2685(5) 0.048(2) Uani 1 1 d . . .
H36 H 0.5720 0.9640 0.3032 0.057 Uiso 1 1 calc R . .
C41 C 0.3729(5) 0.8208(5) 0.0895(4) 0.0349(16) Uani 1 1 d . . .
C42 C 0.2934(7) 0.7650(5) 0.0306(5) 0.052(2) Uani 1 1 d . . .
H42 H 0.2442 0.7308 0.0463 0.063 Uiso 1 1 calc R . .
C43 C 0.2842(7) 0.7579(6) -0.0518(5) 0.057(2) Uani 1 1 d . . .
H43 H 0.2287 0.7208 -0.0910 0.069 Uiso 1 1 calc R . .
C44 C 0.3569(7) 0.8054(6) -0.0741(5) 0.057(2) Uani 1 1 d . . .
H44 H 0.3523 0.7994 -0.1287 0.068 Uiso 1 1 calc R . .
C45 C 0.4362(7) 0.8617(7) -0.0186(5) 0.060(2) Uani 1 1 d . . .
H45 H 0.4856 0.8947 -0.0347 0.073 Uiso 1 1 calc R . .
C46 C 0.4429(6) 0.8694(5) 0.0633(5) 0.047(2) Uani 1 1 d . . .
H46 H 0.4969 0.9091 0.1013 0.057 Uiso 1 1 calc R . .
C51 C 0.6712(6) 0.8657(5) 0.1729(5) 0.046(2) Uani 1 1 d . . .
C52 C 0.7054(7) 0.9283(6) 0.2357(6) 0.061(2) Uani 1 1 d . . .
H52 H 0.7055 0.9159 0.2879 0.073 Uiso 1 1 calc R . .
C53 C 0.7395(8) 1.0095(6) 0.2217(9) 0.078(3) Uani 1 1 d . . .
H53 H 0.7624 1.0528 0.2641 0.094 Uiso 1 1 calc R . .
C54 C 0.7395(9) 1.0261(9) 0.1452(11) 0.097(4) Uani 1 1 d . . .
H54 H 0.7606 1.0814 0.1348 0.117 Uiso 1 1 calc R . .
C55 C 0.7093(9) 0.9635(10) 0.0838(9) 0.089(4) Uani 1 1 d . . .
H55 H 0.7127 0.9758 0.0325 0.106 Uiso 1 1 calc R . .
C56 C 0.6746(7) 0.8845(7) 0.0967(6) 0.065(3) Uani 1 1 d . . .
H56 H 0.6527 0.8417 0.0540 0.078 Uiso 1 1 calc R . .
C61 C 0.6167(7) 0.6903(6) 0.1089(5) 0.053(2) Uani 1 1 d . . .
C62 C 0.6795(8) 0.6453(6) 0.1156(6) 0.066(3) Uani 1 1 d . . .
H62 H 0.7322 0.6524 0.1645 0.079 Uiso 1 1 calc R . .
C63 C 0.6651(12) 0.5918(9) 0.0524(8) 0.108(5) Uani 1 1 d . . .
H63 H 0.7085 0.5626 0.0569 0.129 Uiso 1 1 calc R . .
C64 C 0.5878(12) 0.5799(10) -0.0177(9) 0.123(6) Uani 1 1 d . . .
H64 H 0.5768 0.5409 -0.0607 0.147 Uiso 1 1 calc R . .
C65 C 0.5264(10) 0.6237(9) -0.0263(7) 0.099(4) Uani 1 1 d . . .
H65 H 0.4752 0.6164 -0.0762 0.119 Uiso 1 1 calc R . .
C66 C 0.5376(7) 0.6786(7) 0.0366(5) 0.065(3) Uani 1 1 d . . .
H66 H 0.4934 0.7073 0.0311 0.078 Uiso 1 1 calc R . .
C71 C 0.6188(6) 0.6493(5) 0.4307(5) 0.0442(19) Uani 1 1 d . . .
C72 C 0.6025(7) 0.5758(6) 0.4675(6) 0.060(2) Uani 1 1 d . . .
H72 H 0.5825 0.5240 0.4370 0.072 Uiso 1 1 calc R . .
C73 C 0.6164(8) 0.5817(7) 0.5489(6) 0.075(3) Uani 1 1 d . . .
H73 H 0.6080 0.5330 0.5744 0.090 Uiso 1 1 calc R . .
C74 C 0.6415(9) 0.6539(8) 0.5935(6) 0.076(3) Uani 1 1 d . . .
H74 H 0.6478 0.6549 0.6488 0.091 Uiso 1 1 calc R . .
C75 C 0.6579(8) 0.7258(7) 0.5596(6) 0.070(3) Uani 1 1 d . . .
H75 H 0.6759 0.7764 0.5916 0.084 Uiso 1 1 calc R . .
C76 C 0.6481(6) 0.7250(6) 0.4774(5) 0.053(2) Uani 1 1 d . . .
H76 H 0.6611 0.7748 0.4540 0.063 Uiso 1 1 calc R . .
C81 C 0.6053(7) 0.5453(5) 0.2917(5) 0.046(2) Uani 1 1 d . . .
C82 C 0.6864(7) 0.5305(6) 0.2895(6) 0.059(2) Uani 1 1 d . . .
H82 H 0.7450 0.5740 0.3037 0.071 Uiso 1 1 calc R . .
C83 C 0.6811(10) 0.4509(8) 0.2659(7) 0.078(3) Uani 1 1 d . . .
H83 H 0.7361 0.4402 0.2644 0.094 Uiso 1 1 calc R . .
C84 C 0.5968(11) 0.3892(8) 0.2452(7) 0.079(3) Uani 1 1 d . . .
H84 H 0.5930 0.3358 0.2276 0.095 Uiso 1 1 calc R . .
C85 C 0.5153(9) 0.4030(6) 0.2496(6) 0.075(3) Uani 1 1 d . . .
H85 H 0.4578 0.3588 0.2371 0.090 Uiso 1 1 calc R . .
C86 C 0.5191(7) 0.4815(6) 0.2720(6) 0.059(2) Uani 1 1 d . . .
H86 H 0.4640 0.4917 0.2740 0.071 Uiso 1 1 calc R . .
B1 B 1.2512(8) 1.0432(7) 0.5290(7) 0.058(3) Uani 1 1 d . . .
F1 F 1.3353(4) 1.0943(4) 0.5857(3) 0.0718(15) Uani 1 1 d . . .
F2 F 1.1782(6) 1.0480(11) 0.5441(8) 0.202(8) Uani 0.90 1 d P . .
F3 F 1.2366(14) 0.9679(8) 0.5488(13) 0.146(8) Uani 0.55 1 d P . .
F4 F 1.2280(14) 1.0751(11) 0.4618(9) 0.222(10) Uani 0.85 1 d P . .
F4A F 1.2581(12) 1.000(2) 0.4765(18) 0.217(13) Uani 0.70 1 d P . .
B2 B 0.1946(13) 0.7392(10) 0.6769(11) 0.093(4) Uani 1 1 d . . .
F5 F 0.1988(7) 0.8078(6) 0.6391(6) 0.138(3) Uani 1 1 d . . .
F6 F 0.1269(9) 0.6748(6) 0.6233(7) 0.185(5) Uani 1 1 d . . .
F7 F 0.2801(9) 0.7322(7) 0.7085(12) 0.244(9) Uani 1 1 d . . .
F8 F 0.1654(10) 0.7637(10) 0.7375(7) 0.198(5) Uani 1 1 d . . .
B3 B 0.1767(17) 1.167(2) 0.0169(15) 0.139(9) Uani 1 1 d . . .
F9 F 0.2579(9) 1.1595(11) 0.0548(7) 0.206(6) Uani 1 1 d . . .
F10 F 0.1630(12) 1.1977(11) -0.0514(8) 0.228(7) Uani 1 1 d . . .
F11 F 0.1552(11) 1.2076(14) 0.0738(9) 0.228(8) Uani 1 1 d . . .
F12 F 0.1070(15) 1.0971(14) 0.0039(16) 0.314(14) Uani 1 1 d . . .
B4 B -0.080(3) 0.4911(18) 0.158(4) 0.30(4) Uani 1 1 d . . .
F13 F -0.1015(10) 0.5643(10) 0.1320(9) 0.211(6) Uani 1 1 d . . .
F14 F 0.0051(14) 0.5110(11) 0.1892(17) 0.307(13) Uani 1 1 d . . .
F15 F -0.143(3) 0.4346(14) 0.1166(17) 0.44(2) Uani 1 1 d . . .
F16 F -0.110(5) 0.492(5) 0.217(4) 0.77(9) Uani 1 1 d . . .
O1 O 0.7051(18) 0.7631(9) 0.7698(12) 0.194(10) Uani 0.70 1 d P . .
O2 O 0.9876(17) 0.6705(18) 0.7643(12) 0.198(10) Uani 0.70 1 d P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N3 2.084(7) . ?
Ru1 N4 2.100(6) . ?
Ru1 N1 2.110(6) . ?
Ru1 N2 2.123(7) . ?
Ru1 P1 2.305(2) . ?
Ru1 P2 2.328(2) . ?
Pt1 N6 2.079(7) . ?
Pt1 N5 2.083(7) . ?
Pt1 P4 2.239(2) . ?
Pt1 P3 2.248(2) . ?
P1 C21 1.822(8) . ?
P1 C11 1.842(8) . ?
P1 C1 1.870(7) . ?
P2 C41 1.828(7) . ?
P2 C31 1.845(8) . ?
P2 C2 1.887(7) . ?
P3 C51 1.805(9) . ?
P3 C61 1.808(8) . ?
P3 C3 1.847(7) . ?
P4 C71 1.814(8) . ?
P4 C81 1.822(8) . ?
P4 C4 1.855(7) . ?
C1 C4 1.553(10) . ?
C1 C2 1.572(10) . ?
C1 H1 0.9900 . ?
C2 C3 1.567(9) . ?
C2 H2 0.9900 . ?
C3 C4 1.557(10) . ?
C3 H3 0.9900 . ?
C4 H4 0.9900 . ?
N1 C105 1.357(10) . ?
N1 C101 1.360(11) . ?
N2 C106 1.331(11) . ?
N2 C110 1.357(12) . ?
C101 C102 1.386(12) . ?
C101 H101 0.9400 . ?
C102 C103 1.354(14) . ?
C102 H102 0.9400 . ?
C103 C104 1.382(15) . ?
C103 H103 0.9400 . ?
C104 C105 1.386(13) . ?
C104 H104 0.9400 . ?
C105 C106 1.460(13) . ?
C106 C107 1.420(13) . ?
C107 C108 1.354(16) . ?
C107 H107 0.9400 . ?
C108 C109 1.370(17) . ?
C108 H108 0.9400 . ?
C109 C110 1.369(14) . ?
C109 H109 0.9400 . ?
C110 H110 0.9400 . ?
N3 C201 1.335(11) . ?
N3 C205 1.375(11) . ?
N4 C210 1.321(11) . ?
N4 C206 1.346(11) . ?
C201 C202 1.387(13) . ?
C201 H201 0.9400 . ?
C202 C203 1.358(16) . ?
C202 H202 0.9400 . ?
C203 C204 1.368(16) . ?
C203 H203 0.9400 . ?
C204 C205 1.400(14) . ?
C204 H204 0.9400 . ?
C205 C206 1.460(13) . ?
C206 C207 1.387(12) . ?
C207 C208 1.372(16) . ?
C207 H207 0.9400 . ?
C208 C209 1.327(16) . ?
C208 H208 0.9400 . ?
C209 C210 1.423(14) . ?
C209 H209 0.9400 . ?
C210 H210 0.9400 . ?
N5 C301 1.332(13) . ?
N5 C305 1.362(13) . ?
N6 C306 1.336(12) . ?
N6 C310 1.352(12) . ?
C301 C302 1.431(18) . ?
C301 H301 0.9400 . ?
C302 C303 1.39(2) . ?
C302 H302 0.9400 . ?
C303 C304 1.33(2) . ?
C303 H303 0.9400 . ?
C304 C305 1.361(15) . ?
C304 H304 0.9400 . ?
C305 C306 1.460(15) . ?
C306 C307 1.408(16) . ?
C307 C308 1.381(19) . ?
C307 H307 0.9400 . ?
C308 C309 1.375(19) . ?
C308 H308 0.9400 . ?
C309 C310 1.347(16) . ?
C309 H309 0.9400 . ?
C310 H310 0.9400 . ?
C11 C16 1.369(12) . ?
C11 C12 1.406(12) . ?
C12 C13 1.377(13) . ?
C12 H12 0.9400 . ?
C13 C14 1.367(16) . ?
C13 H13 0.9400 . ?
C14 C15 1.360(16) . ?
C14 H14 0.9400 . ?
C15 C16 1.400(13) . ?
C15 H15 0.9400 . ?
C16 H16 0.9400 . ?
C21 C26 1.357(12) . ?
C21 C22 1.428(13) . ?
C22 C23 1.386(14) . ?
C22 H22 0.9400 . ?
C23 C24 1.405(18) . ?
C23 H23 0.9400 . ?
C24 C25 1.342(17) . ?
C24 H24 0.9400 . ?
C25 C26 1.406(13) . ?
C25 H25 0.9400 . ?
C26 H26 0.9400 . ?
C31 C36 1.381(12) . ?
C31 C32 1.391(11) . ?
C32 C33 1.385(13) . ?
C32 H32 0.9400 . ?
C33 C34 1.394(15) . ?
C33 H33 0.9400 . ?
C34 C35 1.358(14) . ?
C34 H34 0.9400 . ?
C35 C36 1.384(12) . ?
C35 H35 0.9400 . ?
C36 H36 0.9400 . ?
C41 C46 1.379(11) . ?
C41 C42 1.386(12) . ?
C42 C43 1.404(12) . ?
C42 H42 0.9400 . ?
C43 C44 1.361(13) . ?
C43 H43 0.9400 . ?
C44 C45 1.363(14) . ?
C44 H44 0.9400 . ?
C45 C46 1.406(11) . ?
C45 H45 0.9400 . ?
C46 H46 0.9400 . ?
C51 C52 1.376(13) . ?
C51 C56 1.390(13) . ?
C52 C53 1.380(14) . ?
C52 H52 0.9400 . ?
C53 C54 1.373(18) . ?
C53 H53 0.9400 . ?
C54 C55 1.367(19) . ?
C54 H54 0.9400 . ?
C55 C56 1.344(16) . ?
C55 H55 0.9400 . ?
C56 H56 0.9400 . ?
C61 C62 1.395(12) . ?
C61 C66 1.397(12) . ?
C62 C63 1.348(14) . ?
C62 H62 0.9400 . ?
C63 C64 1.358(19) . ?
C63 H63 0.9400 . ?
C64 C65 1.354(19) . ?
C64 H64 0.9400 . ?
C65 C66 1.377(14) . ?
C65 H65 0.9400 . ?
C66 H66 0.9400 . ?
C71 C76 1.391(12) . ?
C71 C72 1.405(12) . ?
C72 C73 1.368(13) . ?
C72 H72 0.9400 . ?
C73 C74 1.334(15) . ?
C73 H73 0.9400 . ?
C74 C75 1.356(15) . ?
C74 H74 0.9400 . ?
C75 C76 1.398(13) . ?
C75 H75 0.9400 . ?
C76 H76 0.9400 . ?
C81 C82 1.380(12) . ?
C81 C86 1.384(13) . ?
C82 C83 1.389(15) . ?
C82 H82 0.9400 . ?
C83 C84 1.346(17) . ?
C83 H83 0.9400 . ?
C84 C85 1.391(16) . ?
C84 H84 0.9400 . ?
C85 C86 1.374(13) . ?
C85 H85 0.9400 . ?
C86 H86 0.9400 . ?
B1 F4A 1.236(16) . ?
B1 F4 1.282(16) . ?
B1 F2 1.283(14) . ?
B1 F3 1.304(18) . ?
B1 F1 1.374(12) . ?
F3 F4A 1.48(3) . ?
F4 F4A 1.49(3) . ?
B2 F7 1.302(19) . ?
B2 F5 1.341(18) . ?
B2 F6 1.352(19) . ?
B2 F8 1.400(19) . ?
B3 F9 1.26(2) . ?
B3 F10 1.28(2) . ?
B3 F12 1.31(3) . ?
B3 F11 1.40(3) . ?
B4 F15 1.17(3) . ?
B4 F14 1.19(4) . ?
B4 F16 1.29(8) . ?
B4 F13 1.42(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ru1 N4 77.8(3) . . ?
N3 Ru1 N1 164.9(2) . . ?
N4 Ru1 N1 93.1(3) . . ?
N3 Ru1 N2 90.2(3) . . ?
N4 Ru1 N2 86.0(2) . . ?
N1 Ru1 N2 77.0(3) . . ?
N3 Ru1 P1 104.74(19) . . ?
N4 Ru1 P1 176.7(2) . . ?
N1 Ru1 P1 84.88(18) . . ?
N2 Ru1 P1 96.04(18) . . ?
N3 Ru1 P2 95.33(19) . . ?
N4 Ru1 P2 92.08(19) . . ?
N1 Ru1 P2 97.05(18) . . ?
N2 Ru1 P2 173.6(2) . . ?
P1 Ru1 P2 85.59(7) . . ?
N6 Pt1 N5 77.0(3) . . ?
N6 Pt1 P4 177.4(2) . . ?
N5 Pt1 P4 100.5(2) . . ?
N6 Pt1 P3 98.2(2) . . ?
N5 Pt1 P3 171.3(3) . . ?
P4 Pt1 P3 84.41(8) . . ?
C21 P1 C11 102.6(4) . . ?
C21 P1 C1 106.0(4) . . ?
C11 P1 C1 103.2(3) . . ?
C21 P1 Ru1 112.3(2) . . ?
C11 P1 Ru1 125.0(3) . . ?
C1 P1 Ru1 106.1(2) . . ?
C41 P2 C31 97.1(3) . . ?
C41 P2 C2 104.6(3) . . ?
C31 P2 C2 106.6(4) . . ?
C41 P2 Ru1 126.2(3) . . ?
C31 P2 Ru1 113.8(2) . . ?
C2 P2 Ru1 107.0(2) . . ?
C51 P3 C61 109.8(4) . . ?
C51 P3 C3 109.7(3) . . ?
C61 P3 C3 102.8(4) . . ?
C51 P3 Pt1 110.1(3) . . ?
C61 P3 Pt1 114.0(3) . . ?
C3 P3 Pt1 110.0(2) . . ?
C71 P4 C81 107.1(4) . . ?
C71 P4 C4 107.7(3) . . ?
C81 P4 C4 104.8(4) . . ?
C71 P4 Pt1 113.6(3) . . ?
C81 P4 Pt1 112.0(3) . . ?
C4 P4 Pt1 111.2(3) . . ?
C4 C1 C2 90.0(5) . . ?
C4 C1 P1 118.1(5) . . ?
C2 C1 P1 114.6(5) . . ?
C4 C1 H1 110.9 . . ?
C2 C1 H1 110.9 . . ?
P1 C1 H1 110.9 . . ?
C3 C2 C1 88.7(5) . . ?
C3 C2 P2 120.1(5) . . ?
C1 C2 P2 114.5(5) . . ?
C3 C2 H2 110.6 . . ?
C1 C2 H2 110.6 . . ?
P2 C2 H2 110.6 . . ?
C4 C3 C2 90.1(5) . . ?
C4 C3 P3 111.9(5) . . ?
C2 C3 P3 122.1(5) . . ?
C4 C3 H3 110.3 . . ?
C2 C3 H3 110.3 . . ?
P3 C3 H3 110.3 . . ?
C1 C4 C3 89.7(5) . . ?
C1 C4 P4 118.1(5) . . ?
C3 C4 P4 113.6(5) . . ?
C1 C4 H4 111.2 . . ?
C3 C4 H4 111.2 . . ?
P4 C4 H4 111.2 . . ?
C105 N1 C101 116.6(7) . . ?
C105 N1 Ru1 115.4(5) . . ?
C101 N1 Ru1 127.9(5) . . ?
C106 N2 C110 118.2(8) . . ?
C106 N2 Ru1 115.7(6) . . ?
C110 N2 Ru1 126.1(6) . . ?
N1 C101 C102 124.3(8) . . ?
N1 C101 H101 117.8 . . ?
C102 C101 H101 117.8 . . ?
C103 C102 C101 117.8(9) . . ?
C103 C102 H102 121.1 . . ?
C101 C102 H102 121.1 . . ?
C102 C103 C104 119.8(9) . . ?
C102 C103 H103 120.1 . . ?
C104 C103 H103 120.1 . . ?
C103 C104 C105 120.0(9) . . ?
C103 C104 H104 120.0 . . ?
C105 C104 H104 120.0 . . ?
N1 C105 C104 121.4(9) . . ?
N1 C105 C106 115.6(7) . . ?
C104 C105 C106 123.0(8) . . ?
N2 C106 C107 121.0(10) . . ?
N2 C106 C105 116.2(7) . . ?
C107 C106 C105 122.7(9) . . ?
C108 C107 C106 119.0(11) . . ?
C108 C107 H107 120.5 . . ?
C106 C107 H107 120.5 . . ?
C107 C108 C109 120.2(10) . . ?
C107 C108 H108 119.9 . . ?
C109 C108 H108 119.9 . . ?
C110 C109 C108 118.4(11) . . ?
C110 C109 H109 120.8 . . ?
C108 C109 H109 120.8 . . ?
N2 C110 C109 123.1(10) . . ?
N2 C110 H110 118.5 . . ?
C109 C110 H110 118.5 . . ?
C201 N3 C205 118.1(7) . . ?
C201 N3 Ru1 127.5(6) . . ?
C205 N3 Ru1 114.4(6) . . ?
C210 N4 C206 118.9(7) . . ?
C210 N4 Ru1 125.0(6) . . ?
C206 N4 Ru1 116.1(5) . . ?
N3 C201 C202 122.6(9) . . ?
N3 C201 H201 118.7 . . ?
C202 C201 H201 118.7 . . ?
C203 C202 C201 119.8(10) . . ?
C203 C202 H202 120.1 . . ?
C201 C202 H202 120.1 . . ?
C202 C203 C204 118.6(10) . . ?
C202 C203 H203 120.7 . . ?
C204 C203 H203 120.7 . . ?
C203 C204 C205 120.7(10) . . ?
C203 C204 H204 119.7 . . ?
C205 C204 H204 119.7 . . ?
N3 C205 C204 119.8(9) . . ?
N3 C205 C206 116.3(8) . . ?
C204 C205 C206 123.8(9) . . ?
N4 C206 C207 121.3(9) . . ?
N4 C206 C205 114.5(7) . . ?
C207 C206 C205 124.2(9) . . ?
C208 C207 C206 119.3(11) . . ?
C208 C207 H207 120.4 . . ?
C206 C207 H207 120.4 . . ?
C209 C208 C207 120.0(10) . . ?
C209 C208 H208 120.0 . . ?
C207 C208 H208 120.0 . . ?
C208 C209 C210 119.1(10) . . ?
C208 C209 H209 120.5 . . ?
C210 C209 H209 120.5 . . ?
N4 C210 C209 121.5(10) . . ?
N4 C210 H210 119.3 . . ?
C209 C210 H210 119.3 . . ?
C301 N5 C305 118.3(9) . . ?
C301 N5 Pt1 127.8(8) . . ?
C305 N5 Pt1 113.2(6) . . ?
C306 N6 C310 118.9(8) . . ?
C306 N6 Pt1 113.1(6) . . ?
C310 N6 Pt1 127.7(6) . . ?
N5 C301 C302 120.2(14) . . ?
N5 C301 H301 119.9 . . ?
C302 C301 H301 119.9 . . ?
C303 C302 C301 119.7(14) . . ?
C303 C302 H302 120.2 . . ?
C301 C302 H302 120.2 . . ?
C304 C303 C302 117.4(13) . . ?
C304 C303 H303 121.3 . . ?
C302 C303 H303 121.3 . . ?
C303 C304 C305 122.1(15) . . ?
C303 C304 H304 118.9 . . ?
C305 C304 H304 118.9 . . ?
C304 C305 N5 122.1(12) . . ?
C304 C305 C306 124.2(12) . . ?
N5 C305 C306 113.5(8) . . ?
N6 C306 C307 120.5(11) . . ?
N6 C306 C305 116.1(9) . . ?
C307 C306 C305 123.3(10) . . ?
C308 C307 C306 118.8(12) . . ?
C308 C307 H307 120.6 . . ?
C306 C307 H307 120.6 . . ?
C309 C308 C307 119.0(12) . . ?
C309 C308 H308 120.5 . . ?
C307 C308 H308 120.5 . . ?
C310 C309 C308 119.6(12) . . ?
C310 C309 H309 120.2 . . ?
C308 C309 H309 120.2 . . ?
C309 C310 N6 122.6(11) . . ?
C309 C310 H310 118.7 . . ?
N6 C310 H310 118.7 . . ?
C16 C11 C12 118.8(7) . . ?
C16 C11 P1 118.1(6) . . ?
C12 C11 P1 123.0(6) . . ?
C13 C12 C11 119.6(9) . . ?
C13 C12 H12 120.2 . . ?
C11 C12 H12 120.2 . . ?
C14 C13 C12 120.3(10) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C15 C14 C13 121.6(10) . . ?
C15 C14 H14 119.2 . . ?
C13 C14 H14 119.2 . . ?
C14 C15 C16 118.5(10) . . ?
C14 C15 H15 120.8 . . ?
C16 C15 H15 120.8 . . ?
C11 C16 C15 121.3(9) . . ?
C11 C16 H16 119.4 . . ?
C15 C16 H16 119.4 . . ?
C26 C21 C22 118.4(8) . . ?
C26 C21 P1 125.7(7) . . ?
C22 C21 P1 115.2(7) . . ?
C23 C22 C21 119.7(10) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
C22 C23 C24 120.0(11) . . ?
C22 C23 H23 120.0 . . ?
C24 C23 H23 120.0 . . ?
C25 C24 C23 120.0(10) . . ?
C25 C24 H24 120.0 . . ?
C23 C24 H24 120.0 . . ?
C24 C25 C26 120.6(11) . . ?
C24 C25 H25 119.7 . . ?
C26 C25 H25 119.7 . . ?
C21 C26 C25 121.3(10) . . ?
C21 C26 H26 119.3 . . ?
C25 C26 H26 119.3 . . ?
C36 C31 C32 118.4(7) . . ?
C36 C31 P2 126.2(6) . . ?
C32 C31 P2 115.4(6) . . ?
C33 C32 C31 121.7(9) . . ?
C33 C32 H32 119.1 . . ?
C31 C32 H32 119.1 . . ?
C32 C33 C34 118.5(9) . . ?
C32 C33 H33 120.8 . . ?
C34 C33 H33 120.8 . . ?
C35 C34 C33 120.1(9) . . ?
C35 C34 H34 119.9 . . ?
C33 C34 H34 119.9 . . ?
C34 C35 C36 121.2(10) . . ?
C34 C35 H35 119.4 . . ?
C36 C35 H35 119.4 . . ?
C31 C36 C35 120.1(8) . . ?
C31 C36 H36 120.0 . . ?
C35 C36 H36 120.0 . . ?
C46 C41 C42 116.6(7) . . ?
C46 C41 P2 119.2(6) . . ?
C42 C41 P2 124.2(6) . . ?
C41 C42 C43 122.1(8) . . ?
C41 C42 H42 119.0 . . ?
C43 C42 H42 119.0 . . ?
C44 C43 C42 118.9(8) . . ?
C44 C43 H43 120.5 . . ?
C42 C43 H43 120.5 . . ?
C43 C44 C45 121.2(8) . . ?
C43 C44 H44 119.4 . . ?
C45 C44 H44 119.4 . . ?
C44 C45 C46 119.0(9) . . ?
C44 C45 H45 120.5 . . ?
C46 C45 H45 120.5 . . ?
C41 C46 C45 122.1(8) . . ?
C41 C46 H46 118.9 . . ?
C45 C46 H46 118.9 . . ?
C52 C51 C56 119.7(9) . . ?
C52 C51 P3 118.5(7) . . ?
C56 C51 P3 121.5(7) . . ?
C51 C52 C53 119.7(10) . . ?
C51 C52 H52 120.1 . . ?
C53 C52 H52 120.1 . . ?
C54 C53 C52 119.2(12) . . ?
C54 C53 H53 120.4 . . ?
C52 C53 H53 120.4 . . ?
C55 C54 C53 120.9(11) . . ?
C55 C54 H54 119.6 . . ?
C53 C54 H54 119.6 . . ?
C56 C55 C54 120.2(12) . . ?
C56 C55 H55 119.9 . . ?
C54 C55 H55 119.9 . . ?
C55 C56 C51 120.2(11) . . ?
C55 C56 H56 119.9 . . ?
C51 C56 H56 119.9 . . ?
C62 C61 C66 119.6(8) . . ?
C62 C61 P3 119.6(7) . . ?
C66 C61 P3 120.8(7) . . ?
C63 C62 C61 120.4(11) . . ?
C63 C62 H62 119.8 . . ?
C61 C62 H62 119.8 . . ?
C62 C63 C64 120.1(11) . . ?
C62 C63 H63 119.9 . . ?
C64 C63 H63 119.9 . . ?
C65 C64 C63 120.7(10) . . ?
C65 C64 H64 119.6 . . ?
C63 C64 H64 119.6 . . ?
C64 C65 C66 121.4(12) . . ?
C64 C65 H65 119.3 . . ?
C66 C65 H65 119.3 . . ?
C65 C66 C61 117.8(10) . . ?
C65 C66 H66 121.1 . . ?
C61 C66 H66 121.1 . . ?
C76 C71 C72 119.6(8) . . ?
C76 C71 P4 118.2(7) . . ?
C72 C71 P4 121.8(7) . . ?
C73 C72 C71 118.2(9) . . ?
C73 C72 H72 120.9 . . ?
C71 C72 H72 120.9 . . ?
C74 C73 C72 122.6(10) . . ?
C74 C73 H73 118.7 . . ?
C72 C73 H73 118.7 . . ?
C73 C74 C75 120.4(9) . . ?
C73 C74 H74 119.8 . . ?
C75 C74 H74 119.8 . . ?
C74 C75 C76 120.3(9) . . ?
C74 C75 H75 119.9 . . ?
C76 C75 H75 119.9 . . ?
C71 C76 C75 118.8(9) . . ?
C71 C76 H76 120.6 . . ?
C75 C76 H76 120.6 . . ?
C82 C81 C86 120.8(8) . . ?
C82 C81 P4 118.2(7) . . ?
C86 C81 P4 121.0(6) . . ?
C81 C82 C83 119.5(10) . . ?
C81 C82 H82 120.2 . . ?
C83 C82 H82 120.2 . . ?
C84 C83 C82 119.7(10) . . ?
C84 C83 H83 120.1 . . ?
C82 C83 H83 120.1 . . ?
C83 C84 C85 121.1(10) . . ?
C83 C84 H84 119.5 . . ?
C85 C84 H84 119.5 . . ?
C86 C85 C84 120.0(11) . . ?
C86 C85 H85 120.0 . . ?
C84 C85 H85 120.0 . . ?
C85 C86 C81 118.9(9) . . ?
C85 C86 H86 120.6 . . ?
C81 C86 H86 120.6 . . ?
F4A B1 F4 72.8(18) . . ?
F4A B1 F2 131.8(13) . . ?
F4 B1 F2 93.0(16) . . ?
F4A B1 F3 71.3(18) . . ?
F4 B1 F3 134.9(14) . . ?
F2 B1 F3 91.0(17) . . ?
F4A B1 F1 117.3(12) . . ?
F4 B1 F1 111.3(11) . . ?
F2 B1 F1 110.8(9) . . ?
F3 B1 F1 109.0(11) . . ?
B1 F3 F4A 52.2(11) . . ?
B1 F4 F4A 52.2(11) . . ?
B1 F4A F3 56.5(12) . . ?
B1 F4A F4 55.0(12) . . ?
F3 F4A F4 106.7(15) . . ?
F7 B2 F5 110.0(16) . . ?
F7 B2 F6 115.7(14) . . ?
F5 B2 F6 107.8(14) . . ?
F7 B2 F8 111.2(17) . . ?
F5 B2 F8 96.8(13) . . ?
F6 B2 F8 113.6(16) . . ?
F9 B3 F10 118.5(19) . . ?
F9 B3 F12 112(3) . . ?
F10 B3 F12 107(3) . . ?
F9 B3 F11 106(2) . . ?
F10 B3 F11 114(2) . . ?
F12 B3 F11 97(2) . . ?
F15 B4 F14 138(6) . . ?
F15 B4 F16 98(5) . . ?
F14 B4 F16 105(6) . . ?
F15 B4 F13 108(3) . . ?
F14 B4 F13 106(3) . . ?
F16 B4 F13 92(6) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Ru1 P1 C21 -118.9(4) . . . . ?
N1 Ru1 P1 C21 49.3(4) . . . . ?
N2 Ru1 P1 C21 -27.1(4) . . . . ?
P2 Ru1 P1 C21 146.8(3) . . . . ?
N3 Ru1 P1 C11 6.2(4) . . . . ?
N1 Ru1 P1 C11 174.4(4) . . . . ?
N2 Ru1 P1 C11 98.1(4) . . . . ?
P2 Ru1 P1 C11 -88.1(3) . . . . ?
N3 Ru1 P1 C1 125.8(3) . . . . ?
N1 Ru1 P1 C1 -66.1(3) . . . . ?
N2 Ru1 P1 C1 -142.4(3) . . . . ?
P2 Ru1 P1 C1 31.4(3) . . . . ?
N3 Ru1 P2 C41 -7.7(3) . . . . ?
N4 Ru1 P2 C41 -85.6(3) . . . . ?
N1 Ru1 P2 C41 -179.0(3) . . . . ?
P1 Ru1 P2 C41 96.7(3) . . . . ?
N3 Ru1 P2 C31 111.6(3) . . . . ?
N4 Ru1 P2 C31 33.7(3) . . . . ?
N1 Ru1 P2 C31 -59.7(3) . . . . ?
P1 Ru1 P2 C31 -144.0(3) . . . . ?
N3 Ru1 P2 C2 -131.0(3) . . . . ?
N4 Ru1 P2 C2 151.1(3) . . . . ?
N1 Ru1 P2 C2 57.7(3) . . . . ?
P1 Ru1 P2 C2 -26.5(2) . . . . ?
N6 Pt1 P3 C51 -32.5(3) . . . . ?
P4 Pt1 P3 C51 148.1(3) . . . . ?
N6 Pt1 P3 C61 91.6(4) . . . . ?
P4 Pt1 P3 C61 -87.9(3) . . . . ?
N6 Pt1 P3 C3 -153.6(3) . . . . ?
P4 Pt1 P3 C3 26.9(3) . . . . ?
N5 Pt1 P4 C71 30.8(4) . . . . ?
P3 Pt1 P4 C71 -142.0(3) . . . . ?
N5 Pt1 P4 C81 -90.7(4) . . . . ?
P3 Pt1 P4 C81 96.6(3) . . . . ?
N5 Pt1 P4 C4 152.5(3) . . . . ?
P3 Pt1 P4 C4 -20.3(3) . . . . ?
C21 P1 C1 C4 105.0(6) . . . . ?
C11 P1 C1 C4 -2.4(6) . . . . ?
Ru1 P1 C1 C4 -135.4(5) . . . . ?
C21 P1 C1 C2 -150.8(5) . . . . ?
C11 P1 C1 C2 101.7(6) . . . . ?
Ru1 P1 C1 C2 -31.2(5) . . . . ?
C4 C1 C2 C3 8.9(5) . . . . ?
P1 C1 C2 C3 -112.3(5) . . . . ?
C4 C1 C2 P2 131.6(5) . . . . ?
P1 C1 C2 P2 10.4(7) . . . . ?
C41 P2 C2 C3 -17.3(7) . . . . ?
C31 P2 C2 C3 -119.4(6) . . . . ?
Ru1 P2 C2 C3 118.5(5) . . . . ?
C41 P2 C2 C1 -120.9(5) . . . . ?
C31 P2 C2 C1 137.0(5) . . . . ?
Ru1 P2 C2 C1 14.9(5) . . . . ?
C1 C2 C3 C4 -8.8(5) . . . . ?
P2 C2 C3 C4 -126.6(6) . . . . ?
C1 C2 C3 P3 -125.1(6) . . . . ?
P2 C2 C3 P3 117.1(6) . . . . ?
C51 P3 C3 C4 -150.7(5) . . . . ?
C61 P3 C3 C4 92.5(6) . . . . ?
Pt1 P3 C3 C4 -29.3(5) . . . . ?
C51 P3 C3 C2 -45.9(7) . . . . ?
C61 P3 C3 C2 -162.7(6) . . . . ?
Pt1 P3 C3 C2 75.5(6) . . . . ?
C2 C1 C4 C3 -8.9(5) . . . . ?
P1 C1 C4 C3 109.2(6) . . . . ?
C2 C1 C4 P4 107.9(6) . . . . ?
P1 C1 C4 P4 -134.0(5) . . . . ?
C2 C3 C4 C1 8.9(5) . . . . ?
P3 C3 C4 C1 133.9(5) . . . . ?
C2 C3 C4 P4 -111.9(5) . . . . ?
P3 C3 C4 P4 13.1(6) . . . . ?
C71 P4 C4 C1 30.1(7) . . . . ?
C81 P4 C4 C1 143.9(6) . . . . ?
Pt1 P4 C4 C1 -94.9(5) . . . . ?
C71 P4 C4 C3 133.3(5) . . . . ?
C81 P4 C4 C3 -112.9(5) . . . . ?
Pt1 P4 C4 C3 8.2(5) . . . . ?
N3 Ru1 N1 C105 33.5(13) . . . . ?
N4 Ru1 N1 C105 85.8(6) . . . . ?
N2 Ru1 N1 C105 0.6(5) . . . . ?
P1 Ru1 N1 C105 -96.8(5) . . . . ?
P2 Ru1 N1 C105 178.3(5) . . . . ?
N3 Ru1 N1 C101 -150.0(9) . . . . ?
N4 Ru1 N1 C101 -97.7(7) . . . . ?
N2 Ru1 N1 C101 177.1(7) . . . . ?
P1 Ru1 N1 C101 79.6(6) . . . . ?
P2 Ru1 N1 C101 -5.3(6) . . . . ?
N3 Ru1 N2 C106 -171.0(6) . . . . ?
N4 Ru1 N2 C106 -93.2(6) . . . . ?
N1 Ru1 N2 C106 0.9(5) . . . . ?
P1 Ru1 N2 C106 84.2(5) . . . . ?
N3 Ru1 N2 C110 7.7(7) . . . . ?
N4 Ru1 N2 C110 85.5(7) . . . . ?
N1 Ru1 N2 C110 179.6(7) . . . . ?
P1 Ru1 N2 C110 -97.1(7) . . . . ?
C105 N1 C101 C102 -0.2(12) . . . . ?
Ru1 N1 C101 C102 -176.6(6) . . . . ?
N1 C101 C102 C103 0.7(14) . . . . ?
C101 C102 C103 C104 -1.2(16) . . . . ?
C102 C103 C104 C105 1.3(17) . . . . ?
C101 N1 C105 C104 0.2(12) . . . . ?
Ru1 N1 C105 C104 177.1(7) . . . . ?
C101 N1 C105 C106 -178.7(7) . . . . ?
Ru1 N1 C105 C106 -1.8(9) . . . . ?
C103 C104 C105 N1 -0.7(15) . . . . ?
C103 C104 C105 C106 178.1(9) . . . . ?
C110 N2 C106 C107 0.9(12) . . . . ?
Ru1 N2 C106 C107 179.7(7) . . . . ?
C110 N2 C106 C105 179.1(8) . . . . ?
Ru1 N2 C106 C105 -2.1(9) . . . . ?
N1 C105 C106 N2 2.6(11) . . . . ?
C104 C105 C106 N2 -176.3(8) . . . . ?
N1 C105 C106 C107 -179.2(8) . . . . ?
C104 C105 C106 C107 1.9(14) . . . . ?
N2 C106 C107 C108 1.2(15) . . . . ?
C105 C106 C107 C108 -176.9(10) . . . . ?
C106 C107 C108 C109 -1.7(18) . . . . ?
C107 C108 C109 C110 0.2(19) . . . . ?
C106 N2 C110 C109 -2.5(14) . . . . ?
Ru1 N2 C110 C109 178.8(8) . . . . ?
C108 C109 C110 N2 2.0(17) . . . . ?
N4 Ru1 N3 C201 -169.8(7) . . . . ?
N1 Ru1 N3 C201 -115.9(10) . . . . ?
N2 Ru1 N3 C201 -83.9(7) . . . . ?
P1 Ru1 N3 C201 12.4(7) . . . . ?
P2 Ru1 N3 C201 99.3(7) . . . . ?
N4 Ru1 N3 C205 8.7(5) . . . . ?
N1 Ru1 N3 C205 62.6(12) . . . . ?
N2 Ru1 N3 C205 94.6(6) . . . . ?
P1 Ru1 N3 C205 -169.1(5) . . . . ?
P2 Ru1 N3 C205 -82.3(5) . . . . ?
N3 Ru1 N4 C210 174.5(7) . . . . ?
N1 Ru1 N4 C210 6.6(7) . . . . ?
N2 Ru1 N4 C210 83.4(7) . . . . ?
P2 Ru1 N4 C210 -90.5(7) . . . . ?
N3 Ru1 N4 C206 -8.3(6) . . . . ?
N1 Ru1 N4 C206 -176.1(6) . . . . ?
N2 Ru1 N4 C206 -99.4(6) . . . . ?
P2 Ru1 N4 C206 86.7(6) . . . . ?
C205 N3 C201 C202 6.0(13) . . . . ?
Ru1 N3 C201 C202 -175.6(7) . . . . ?
N3 C201 C202 C203 -0.3(16) . . . . ?
C201 C202 C203 C204 -5.0(18) . . . . ?
C202 C203 C204 C205 4.4(19) . . . . ?
C201 N3 C205 C204 -6.4(13) . . . . ?
Ru1 N3 C205 C204 175.0(8) . . . . ?
C201 N3 C205 C206 170.3(8) . . . . ?
Ru1 N3 C205 C206 -8.3(9) . . . . ?
C203 C204 C205 N3 1.3(16) . . . . ?
C203 C204 C205 C206 -175.2(10) . . . . ?
C210 N4 C206 C207 2.7(13) . . . . ?
Ru1 N4 C206 C207 -174.8(7) . . . . ?
C210 N4 C206 C205 -176.2(8) . . . . ?
Ru1 N4 C206 C205 6.4(9) . . . . ?
N3 C205 C206 N4 1.3(11) . . . . ?
C204 C205 C206 N4 177.9(9) . . . . ?
N3 C205 C206 C207 -177.5(8) . . . . ?
C204 C205 C206 C207 -0.9(15) . . . . ?
N4 C206 C207 C208 -2.3(14) . . . . ?
C205 C206 C207 C208 176.5(9) . . . . ?
C206 C207 C208 C209 -0.2(16) . . . . ?
C207 C208 C209 C210 2.2(17) . . . . ?
C206 N4 C210 C209 -0.6(13) . . . . ?
Ru1 N4 C210 C209 176.6(7) . . . . ?
C208 C209 C210 N4 -1.8(16) . . . . ?
N6 Pt1 N5 C301 -167.3(9) . . . . ?
P4 Pt1 N5 C301 11.8(9) . . . . ?
N6 Pt1 N5 C305 23.0(6) . . . . ?
P4 Pt1 N5 C305 -157.8(6) . . . . ?
N5 Pt1 N6 C306 -22.3(6) . . . . ?
P3 Pt1 N6 C306 150.3(6) . . . . ?
N5 Pt1 N6 C310 164.0(8) . . . . ?
P3 Pt1 N6 C310 -23.3(7) . . . . ?
C305 N5 C301 C302 4.5(15) . . . . ?
Pt1 N5 C301 C302 -164.7(8) . . . . ?
N5 C301 C302 C303 0.4(19) . . . . ?
C301 C302 C303 C304 -4(2) . . . . ?
C302 C303 C304 C305 4(2) . . . . ?
C303 C304 C305 N5 1.2(18) . . . . ?
C303 C304 C305 C306 -172.7(11) . . . . ?
C301 N5 C305 C304 -5.4(14) . . . . ?
Pt1 N5 C305 C304 165.3(8) . . . . ?
C301 N5 C305 C306 169.1(9) . . . . ?
Pt1 N5 C305 C306 -20.2(9) . . . . ?
C310 N6 C306 C307 9.0(13) . . . . ?
Pt1 N6 C306 C307 -165.3(8) . . . . ?
C310 N6 C306 C305 -167.1(8) . . . . ?
Pt1 N6 C306 C305 18.6(10) . . . . ?
C304 C305 C306 N6 175.4(10) . . . . ?
N5 C305 C306 N6 1.1(11) . . . . ?
C304 C305 C306 C307 -0.6(16) . . . . ?
N5 C305 C306 C307 -175.0(9) . . . . ?
N6 C306 C307 C308 -6.3(16) . . . . ?
C305 C306 C307 C308 169.5(11) . . . . ?
C306 C307 C308 C309 1(2) . . . . ?
C307 C308 C309 C310 2(2) . . . . ?
C308 C309 C310 N6 1.0(18) . . . . ?
C306 N6 C310 C309 -6.4(14) . . . . ?
Pt1 N6 C310 C309 166.9(8) . . . . ?
C21 P1 C11 C16 177.0(6) . . . . ?
C1 P1 C11 C16 -73.0(7) . . . . ?
Ru1 P1 C11 C16 47.9(7) . . . . ?
C21 P1 C11 C12 -7.0(8) . . . . ?
C1 P1 C11 C12 103.0(7) . . . . ?
Ru1 P1 C11 C12 -136.1(6) . . . . ?
C16 C11 C12 C13 -2.5(13) . . . . ?
P1 C11 C12 C13 -178.5(7) . . . . ?
C11 C12 C13 C14 2.2(15) . . . . ?
C12 C13 C14 C15 -1.9(17) . . . . ?
C13 C14 C15 C16 1.8(16) . . . . ?
C12 C11 C16 C15 2.6(12) . . . . ?
P1 C11 C16 C15 178.8(7) . . . . ?
C14 C15 C16 C11 -2.2(14) . . . . ?
C11 P1 C21 C26 127.2(7) . . . . ?
C1 P1 C21 C26 19.3(8) . . . . ?
Ru1 P1 C21 C26 -96.2(7) . . . . ?
C11 P1 C21 C22 -62.4(7) . . . . ?
C1 P1 C21 C22 -170.3(6) . . . . ?
Ru1 P1 C21 C22 74.2(7) . . . . ?
C26 C21 C22 C23 -0.7(13) . . . . ?
P1 C21 C22 C23 -171.8(8) . . . . ?
C21 C22 C23 C24 1.1(15) . . . . ?
C22 C23 C24 C25 -0.3(17) . . . . ?
C23 C24 C25 C26 -0.9(16) . . . . ?
C22 C21 C26 C25 -0.5(13) . . . . ?
P1 C21 C26 C25 169.6(7) . . . . ?
C24 C25 C26 C21 1.3(15) . . . . ?
C41 P2 C31 C36 -119.4(7) . . . . ?
C2 P2 C31 C36 -11.8(7) . . . . ?
Ru1 P2 C31 C36 105.8(6) . . . . ?
C41 P2 C31 C32 59.0(6) . . . . ?
C2 P2 C31 C32 166.5(5) . . . . ?
Ru1 P2 C31 C32 -75.8(6) . . . . ?
C36 C31 C32 C33 -0.6(12) . . . . ?
P2 C31 C32 C33 -179.1(7) . . . . ?
C31 C32 C33 C34 0.8(13) . . . . ?
C32 C33 C34 C35 0.8(14) . . . . ?
C33 C34 C35 C36 -2.5(13) . . . . ?
C32 C31 C36 C35 -1.0(11) . . . . ?
P2 C31 C36 C35 177.3(6) . . . . ?
C34 C35 C36 C31 2.6(13) . . . . ?
C31 P2 C41 C46 37.8(6) . . . . ?
C2 P2 C41 C46 -71.4(7) . . . . ?
Ru1 P2 C41 C46 164.3(5) . . . . ?
C31 P2 C41 C42 -141.0(7) . . . . ?
C2 P2 C41 C42 109.7(7) . . . . ?
Ru1 P2 C41 C42 -14.6(8) . . . . ?
C46 C41 C42 C43 0.1(12) . . . . ?
P2 C41 C42 C43 179.0(7) . . . . ?
C41 C42 C43 C44 2.1(13) . . . . ?
C42 C43 C44 C45 -2.5(14) . . . . ?
C43 C44 C45 C46 0.8(14) . . . . ?
C42 C41 C46 C45 -1.8(11) . . . . ?
P2 C41 C46 C45 179.2(6) . . . . ?
C44 C45 C46 C41 1.4(13) . . . . ?
C61 P3 C51 C52 -168.7(6) . . . . ?
C3 P3 C51 C52 79.0(7) . . . . ?
Pt1 P3 C51 C52 -42.3(7) . . . . ?
C61 P3 C51 C56 4.0(8) . . . . ?
C3 P3 C51 C56 -108.3(7) . . . . ?
Pt1 P3 C51 C56 130.4(7) . . . . ?
C56 C51 C52 C53 2.4(13) . . . . ?
P3 C51 C52 C53 175.2(7) . . . . ?
C51 C52 C53 C54 -0.6(15) . . . . ?
C52 C53 C54 C55 -2.2(17) . . . . ?
C53 C54 C55 C56 3.2(19) . . . . ?
C54 C55 C56 C51 -1.3(17) . . . . ?
C52 C51 C56 C55 -1.5(14) . . . . ?
P3 C51 C56 C55 -174.0(8) . . . . ?
C51 P3 C61 C62 111.8(8) . . . . ?
C3 P3 C61 C62 -131.5(8) . . . . ?
Pt1 P3 C61 C62 -12.4(9) . . . . ?
C51 P3 C61 C66 -70.7(9) . . . . ?
C3 P3 C61 C66 46.1(9) . . . . ?
Pt1 P3 C61 C66 165.2(7) . . . . ?
C66 C61 C62 C63 1.0(16) . . . . ?
P3 C61 C62 C63 178.6(10) . . . . ?
C61 C62 C63 C64 -1(2) . . . . ?
C62 C63 C64 C65 2(3) . . . . ?
C63 C64 C65 C66 -3(3) . . . . ?
C64 C65 C66 C61 2(2) . . . . ?
C62 C61 C66 C65 -1.5(16) . . . . ?
P3 C61 C66 C65 -179.0(9) . . . . ?
C81 P4 C71 C76 165.9(7) . . . . ?
C4 P4 C71 C76 -81.8(7) . . . . ?
Pt1 P4 C71 C76 41.8(7) . . . . ?
C81 P4 C71 C72 -7.0(8) . . . . ?
C4 P4 C71 C72 105.2(7) . . . . ?
Pt1 P4 C71 C72 -131.1(7) . . . . ?
C76 C71 C72 C73 -0.1(14) . . . . ?
P4 C71 C72 C73 172.7(8) . . . . ?
C71 C72 C73 C74 2.4(16) . . . . ?
C72 C73 C74 C75 -2.5(18) . . . . ?
C73 C74 C75 C76 0.4(17) . . . . ?
C72 C71 C76 C75 -1.8(13) . . . . ?
P4 C71 C76 C75 -174.9(7) . . . . ?
C74 C75 C76 C71 1.8(15) . . . . ?
C71 P4 C81 C82 -102.7(7) . . . . ?
C4 P4 C81 C82 143.1(7) . . . . ?
Pt1 P4 C81 C82 22.4(7) . . . . ?
C71 P4 C81 C86 74.1(8) . . . . ?
C4 P4 C81 C86 -40.1(8) . . . . ?
Pt1 P4 C81 C86 -160.8(6) . . . . ?
C86 C81 C82 C83 1.0(13) . . . . ?
P4 C81 C82 C83 177.8(7) . . . . ?
C81 C82 C83 C84 0.3(15) . . . . ?
C82 C83 C84 C85 -2.1(17) . . . . ?
C83 C84 C85 C86 2.7(16) . . . . ?
C84 C85 C86 C81 -1.4(15) . . . . ?
C82 C81 C86 C85 -0.4(14) . . . . ?
P4 C81 C86 C85 -177.1(7) . . . . ?
F4 B1 F3 F4A 39(2) . . . . ?
F2 B1 F3 F4A 134.3(14) . . . . ?
F1 B1 F3 F4A -113.3(13) . . . . ?
F2 B1 F4 F4A -133.1(15) . . . . ?
F3 B1 F4 F4A -39(2) . . . . ?
F1 B1 F4 F4A 113.2(14) . . . . ?
F4 B1 F4A F3 -152.2(15) . . . . ?
F2 B1 F4A F3 -74(3) . . . . ?
F1 B1 F4A F3 102.3(16) . . . . ?
F2 B1 F4A F4 78(3) . . . . ?
F3 B1 F4A F4 152.2(15) . . . . ?
F1 B1 F4A F4 -105.5(15) . . . . ?
B1 F3 F4A F4 -23.5(11) . . . . ?
B1 F4 F4A F3 24.0(12) . . . . ?

_diffrn_reflns_theta_full        26.56
_diffrn_measured_fraction        0.997
_refine_diff_density_max         1.000
_refine_diff_density_min         -0.890
_refine_diff_density_rms         0.100


#=============================================================================
#                         END of CIF
#=============================================================================
