# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_aaa
_database_code_depnum_ccdc_archive 'CCDC 1437175'
_audit_update_record             
;
2015-11-16 deposited with the CCDC.
2016-03-28 downloaded from the CCDC.
;
_audit_creation_date             2015-11-14
_audit_creation_method           
;
  Olex2 1.2-ac2
  (compiled 2012.03.06 svn.r2239, GUI svn.r4109)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C40 H44 Cl2 Co3 N4 O4'
_chemical_formula_sum            'C40 H44 Cl2 Co3 N4 O4'
_chemical_formula_weight         892.48
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'

_cell_length_a                   8.327(2)
_cell_length_b                   9.764(3)
_cell_length_c                   13.148(4)
_cell_angle_alpha                75.049(4)
_cell_angle_beta                 78.964(4)
_cell_angle_gamma                68.160(4)
_cell_volume                     953.2(4)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    4439
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      26.35
_cell_measurement_theta_min      2.30
_exptl_absorpt_coefficient_mu    1.477
_exptl_absorpt_correction_T_max  0.8910
_exptl_absorpt_correction_T_min  0.6656
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.555
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             459
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0246
_diffrn_reflns_av_unetI/netI     0.0277
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10974
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.61
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         0
_reflns_number_gt                3277
_reflns_number_total             3881
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution    
'A short history of SHELX (Sheldrick, 2007)/Bruker'
_refine_diff_density_max         0.299
_refine_diff_density_min         -0.282
_refine_diff_density_rms         0.065
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     243
_refine_ls_number_reflns         3881
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0360
_refine_ls_R_factor_gt           0.0277
_refine_ls_restrained_S_all      1.087
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0512P)²+0.0255P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0821
_refine_ls_wR_factor_ref         0.0863
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.5000 0.5000 1.0000 0.02445(12) Uani 1 2 d S . .
Co2 Co 0.73651(4) 0.65730(3) 0.93421(2) 0.02587(10) Uani 1 1 d . . .
Cl1 Cl 0.58605(7) 0.23844(6) 0.99109(5) 0.03703(15) Uani 1 1 d . . .
O1 O 0.65451(19) 0.56195(17) 0.85808(11) 0.0299(3) Uani 1 1 d . . .
O2 O 0.74289(19) 0.48460(16) 1.03972(11) 0.0280(3) Uani 1 1 d . . .
N1 N 0.7218(2) 0.8263(2) 0.82392(14) 0.0312(4) Uani 1 1 d . . .
N2 N 0.8354(2) 0.7366(2) 1.01229(14) 0.0277(4) Uani 1 1 d . . .
C1 C 0.6499(3) 0.5937(2) 0.75414(17) 0.0290(5) Uani 1 1 d . . .
C2 C 0.6335(3) 0.4856(3) 0.70767(19) 0.0368(5) Uani 1 1 d . . .
H2 H 0.6229 0.3967 0.7507 0.044 Uiso 1 1 calc R . .
C3 C 0.6327(4) 0.5082(3) 0.6007(2) 0.0482(7) Uani 1 1 d . . .
H3 H 0.6242 0.4342 0.5716 0.058 Uiso 1 1 calc R . .
C4 C 0.6446(4) 0.6408(3) 0.5357(2) 0.0536(7) Uani 1 1 d . . .
H4 H 0.6443 0.6561 0.4630 0.064 Uiso 1 1 calc R . .
C5 C 0.6569(4) 0.7497(3) 0.5787(2) 0.0469(6) Uani 1 1 d . . .
H5 H 0.6633 0.8389 0.5340 0.056 Uiso 1 1 calc R . .
C6 C 0.6601(3) 0.7316(3) 0.68862(17) 0.0324(5) Uani 1 1 d . . .
C7 C 0.6757(3) 0.8512(3) 0.72991(18) 0.0332(5) Uani 1 1 d . . .
C8 C 0.6341(3) 1.0095(3) 0.6601(2) 0.0445(6) Uani 1 1 d . . .
H8A H 0.5506 1.0229 0.6129 0.053 Uiso 1 1 calc R . .
H8B H 0.5802 1.0832 0.7048 0.053 Uiso 1 1 calc R . .
C9 C 0.7944(4) 1.0394(4) 0.5942(2) 0.0630(8) Uani 1 1 d . . .
H9A H 0.8749 1.0320 0.6404 0.095 Uiso 1 1 calc R . .
H9B H 0.7599 1.1388 0.5505 0.095 Uiso 1 1 calc R . .
H9C H 0.8491 0.9664 0.5501 0.095 Uiso 1 1 calc R . .
C10 C 0.7329(3) 0.9470(3) 0.86722(19) 0.0393(6) Uani 1 1 d . . .
H10A H 0.6196 1.0004 0.8998 0.047 Uiso 1 1 calc R . .
H10B H 0.7705 1.0184 0.8108 0.047 Uiso 1 1 calc R . .
C11 C 0.8622(3) 0.8767(2) 0.94873(19) 0.0337(5) Uani 1 1 d . . .
H11A H 0.9800 0.8542 0.9138 0.040 Uiso 1 1 calc R . .
H11B H 0.8447 0.9462 0.9942 0.040 Uiso 1 1 calc R . .
C12 C 0.8876(3) 0.6814(2) 1.10596(18) 0.0290(5) Uani 1 1 d . . .
C13 C 0.9749(3) 0.7600(3) 1.1515(2) 0.0390(6) Uani 1 1 d . . .
H13A H 1.0364 0.8123 1.0941 0.047 Uiso 1 1 calc R . .
H13B H 1.0599 0.6850 1.1966 0.047 Uiso 1 1 calc R . .
C14 C 0.8457(4) 0.8729(3) 1.2156(2) 0.0558(7) Uani 1 1 d . . .
H14A H 0.7907 0.8206 1.2757 0.084 Uiso 1 1 calc R . .
H14B H 0.7589 0.9456 1.1720 0.084 Uiso 1 1 calc R . .
H14C H 0.9062 0.9235 1.2394 0.084 Uiso 1 1 calc R . .
C15 C 0.8606(3) 0.5424(2) 1.17144(18) 0.0299(5) Uani 1 1 d . . .
C16 C 0.9033(3) 0.4938(3) 1.27741(19) 0.0404(6) Uani 1 1 d . . .
H16 H 0.9508 0.5494 1.3027 0.048 Uiso 1 1 calc R . .
C17 C 0.8777(3) 0.3689(3) 1.3438(2) 0.0454(6) Uani 1 1 d . . .
H17 H 0.9055 0.3419 1.4131 0.054 Uiso 1 1 calc R . .
C18 C 0.8101(3) 0.2827(3) 1.30745(19) 0.0402(6) Uani 1 1 d . . .
H18 H 0.7932 0.1970 1.3520 0.048 Uiso 1 1 calc R . .
C19 C 0.7684(3) 0.3242(3) 1.20562(18) 0.0325(5) Uani 1 1 d . . .
H19 H 0.7251 0.2647 1.1814 0.039 Uiso 1 1 calc R . .
C20 C 0.7889(3) 0.4541(2) 1.13659(16) 0.0265(4) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 Co2 2.8105(6) 2_667 ?
Co1 Co2 2.8105(6) . ?
Co1 Cl1 2.4106(8) . ?
Co1 Cl1 2.4106(8) 2_667 ?
Co1 O1 2.1401(15) . ?
Co1 O1 2.1401(15) 2_667 ?
Co1 O2 2.1268(15) . ?
Co1 O2 2.1268(15) 2_667 ?
Co2 Cl1 2.5858(8) 2_667 ?
Co2 O1 1.8843(15) . ?
Co2 O2 1.8776(15) . ?
Co2 N1 1.8771(19) . ?
Co2 N2 1.8818(18) . ?
Cl1 Co2 2.5858(9) 2_667 ?
O1 C1 1.326(3) . ?
O2 C20 1.328(2) . ?
N1 C7 1.300(3) . ?
N1 C10 1.473(3) . ?
N2 C11 1.478(3) . ?
N2 C12 1.298(3) . ?
C1 C2 1.407(3) . ?
C1 C6 1.422(3) . ?
C2 H2 0.9300 . ?
C2 C3 1.367(3) . ?
C3 H3 0.9300 . ?
C3 C4 1.382(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.368(4) . ?
C5 H5 0.9300 . ?
C5 C6 1.415(3) . ?
C6 C7 1.463(3) . ?
C7 C8 1.531(3) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C9 1.528(4) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 C11 1.513(3) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.515(3) . ?
C12 C15 1.478(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 C14 1.528(4) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C16 1.420(3) . ?
C15 C20 1.415(3) . ?
C16 H16 0.9300 . ?
C16 C17 1.367(4) . ?
C17 H17 0.9300 . ?
C17 C18 1.385(4) . ?
C18 H18 0.9300 . ?
C18 C19 1.368(3) . ?
C19 H19 0.9300 . ?
C19 C20 1.403(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Co2 Co1 Co2 180.0 2_667 . ?
Cl1 Co1 Co2 121.22(2) . . ?
Cl1 Co1 Co2 58.78(2) 2_667 . ?
Cl1 Co1 Co2 58.78(2) . 2_667 ?
Cl1 Co1 Co2 121.22(2) 2_667 2_667 ?
Cl1 Co1 Cl1 180.00(3) . 2_667 ?
O1 Co1 Co2 42.08(4) . . ?
O1 Co1 Co2 137.92(4) 2_667 . ?
O1 Co1 Co2 42.08(4) 2_667 2_667 ?
O1 Co1 Co2 137.92(4) . 2_667 ?
O1 Co1 Cl1 84.00(4) 2_667 . ?
O1 Co1 Cl1 96.00(4) 2_667 2_667 ?
O1 Co1 Cl1 96.00(4) . . ?
O1 Co1 Cl1 84.00(4) . 2_667 ?
O1 Co1 O1 180.0 2_667 . ?
O2 Co1 Co2 138.09(4) . 2_667 ?
O2 Co1 Co2 41.91(4) 2_667 2_667 ?
O2 Co1 Co2 138.09(4) 2_667 . ?
O2 Co1 Co2 41.91(4) . . ?
O2 Co1 Cl1 95.63(4) 2_667 2_667 ?
O2 Co1 Cl1 95.63(4) . . ?
O2 Co1 Cl1 84.37(4) 2_667 . ?
O2 Co1 Cl1 84.37(4) . 2_667 ?
O2 Co1 O1 71.03(6) . . ?
O2 Co1 O1 108.97(6) 2_667 . ?
O2 Co1 O1 71.03(6) 2_667 2_667 ?
O2 Co1 O1 108.97(6) . 2_667 ?
O2 Co1 O2 180.0 2_667 . ?
Cl1 Co2 Co1 52.87(2) 2_667 . ?
O1 Co2 Co1 49.57(4) . . ?
O1 Co2 Cl1 84.56(5) . 2_667 ?
O2 Co2 Co1 49.17(4) . . ?
O2 Co2 Cl1 84.78(5) . 2_667 ?
O2 Co2 O1 82.43(6) . . ?
O2 Co2 N2 94.55(7) . . ?
N1 Co2 Co1 127.58(6) . . ?
N1 Co2 Cl1 94.15(6) . 2_667 ?
N1 Co2 O1 93.94(7) . . ?
N1 Co2 O2 176.29(7) . . ?
N1 Co2 N2 89.13(8) . . ?
N2 Co2 Co1 130.67(5) . . ?
N2 Co2 Cl1 99.28(6) . 2_667 ?
N2 Co2 O1 174.92(7) . . ?
Co1 Cl1 Co2 68.354(16) . 2_667 ?
Co2 O1 Co1 88.35(6) . . ?
C1 O1 Co1 139.05(13) . . ?
C1 O1 Co2 126.14(14) . . ?
Co2 O2 Co1 88.92(6) . . ?
C20 O2 Co1 126.53(13) . . ?
C20 O2 Co2 126.90(13) . . ?
C7 N1 Co2 128.28(16) . . ?
C7 N1 C10 122.0(2) . . ?
C10 N1 Co2 108.41(14) . . ?
C11 N2 Co2 110.54(14) . . ?
C12 N2 Co2 129.30(15) . . ?
C12 N2 C11 120.04(19) . . ?
O1 C1 C2 118.0(2) . . ?
O1 C1 C6 122.9(2) . . ?
C2 C1 C6 119.1(2) . . ?
C1 C2 H2 119.3 . . ?
C3 C2 C1 121.5(2) . . ?
C3 C2 H2 119.3 . . ?
C2 C3 H3 119.9 . . ?
C2 C3 C4 120.1(2) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 120.1 . . ?
C5 C4 C3 119.9(2) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 118.8 . . ?
C4 C5 C6 122.4(3) . . ?
C6 C5 H5 118.8 . . ?
C1 C6 C7 123.0(2) . . ?
C5 C6 C1 117.0(2) . . ?
C5 C6 C7 120.0(2) . . ?
N1 C7 C6 121.7(2) . . ?
N1 C7 C8 119.8(2) . . ?
C6 C7 C8 118.4(2) . . ?
C7 C8 H8A 108.9 . . ?
C7 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C9 C8 C7 113.2(2) . . ?
C9 C8 H8A 108.9 . . ?
C9 C8 H8B 108.9 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N1 C10 H10A 110.0 . . ?
N1 C10 H10B 110.0 . . ?
N1 C10 C11 108.61(19) . . ?
H10A C10 H10B 108.3 . . ?
C11 C10 H10A 110.0 . . ?
C11 C10 H10B 110.0 . . ?
N2 C11 C10 108.33(18) . . ?
N2 C11 H11A 110.0 . . ?
N2 C11 H11B 110.0 . . ?
C10 C11 H11A 110.0 . . ?
C10 C11 H11B 110.0 . . ?
H11A C11 H11B 108.4 . . ?
N2 C12 C13 120.5(2) . . ?
N2 C12 C15 121.03(19) . . ?
C15 C12 C13 118.4(2) . . ?
C12 C13 H13A 109.1 . . ?
C12 C13 H13B 109.1 . . ?
C12 C13 C14 112.7(2) . . ?
H13A C13 H13B 107.8 . . ?
C14 C13 H13A 109.1 . . ?
C14 C13 H13B 109.1 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 C12 119.4(2) . . ?
C20 C15 C12 124.2(2) . . ?
C20 C15 C16 116.4(2) . . ?
C15 C16 H16 118.6 . . ?
C17 C16 C15 122.9(2) . . ?
C17 C16 H16 118.6 . . ?
C16 C17 H17 120.1 . . ?
C16 C17 C18 119.7(2) . . ?
C18 C17 H17 120.1 . . ?
C17 C18 H18 120.2 . . ?
C19 C18 C17 119.6(2) . . ?
C19 C18 H18 120.2 . . ?
C18 C19 H19 119.0 . . ?
C18 C19 C20 122.0(2) . . ?
C20 C19 H19 119.0 . . ?
O2 C20 C15 123.58(19) . . ?
O2 C20 C19 116.97(19) . . ?
C19 C20 C15 119.4(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Co1 Co2 O1 C1 156.16(19) . . . . ?
Co1 Co2 O2 C20 -136.92(18) . . . . ?
Co1 Co2 N1 C7 -42.3(2) . . . . ?
Co1 Co2 N1 C10 124.90(14) . . . . ?
Co1 Co2 N2 C11 -146.27(11) . . . . ?
Co1 Co2 N2 C12 37.8(2) . . . . ?
Co1 O1 C1 C2 -56.3(3) . . . . ?
Co1 O1 C1 C6 123.4(2) . . . . ?
Co1 O2 C20 C15 -129.35(18) . . . . ?
Co1 O2 C20 C19 52.4(2) . . . . ?
Co2 Co1 Co2 Cl1 43(100) 2_667 . . 2_667 ?
Co2 Co1 Co2 O1 -76(100) 2_667 . . . ?
Co2 Co1 Co2 O2 164(100) 2_667 . . . ?
Co2 Co1 Co2 N1 -19(100) 2_667 . . . ?
Co2 Co1 Co2 N2 111(100) 2_667 . . . ?
Co2 Co1 Cl1 Co2 180.0 . . . 2_667 ?
Co2 Co1 O1 Co2 180.0 2_667 . . . ?
Co2 Co1 O1 C1 -150.1(2) . . . . ?
Co2 Co1 O1 C1 29.9(2) 2_667 . . . ?
Co2 Co1 O2 Co2 180.0 2_667 . . . ?
Co2 Co1 O2 C20 137.18(18) . . . . ?
Co2 Co1 O2 C20 -42.82(18) 2_667 . . . ?
Co2 O1 C1 C2 161.77(16) . . . . ?
Co2 O1 C1 C6 -18.5(3) . . . . ?
Co2 O2 C20 C15 -7.5(3) . . . . ?
Co2 O2 C20 C19 174.24(14) . . . . ?
Co2 N1 C7 C6 -12.6(3) . . . . ?
Co2 N1 C7 C8 166.68(16) . . . . ?
Co2 N1 C10 C11 37.6(2) . . . . ?
Co2 N2 C11 C10 25.6(2) . . . . ?
Co2 N2 C12 C13 176.01(15) . . . . ?
Co2 N2 C12 C15 -5.1(3) . . . . ?
Cl1 Co1 Co2 Cl1 180.0 . . . 2_667 ?
Cl1 Co1 Co2 O1 60.73(6) . . . . ?
Cl1 Co1 Co2 O1 -119.27(6) 2_667 . . . ?
Cl1 Co1 Co2 O2 -59.77(6) . . . . ?
Cl1 Co1 Co2 O2 120.23(6) 2_667 . . . ?
Cl1 Co1 Co2 N1 117.93(7) . . . . ?
Cl1 Co1 Co2 N1 -62.07(7) 2_667 . . . ?
Cl1 Co1 Co2 N2 67.41(7) 2_667 . . . ?
Cl1 Co1 Co2 N2 -112.59(7) . . . . ?
Cl1 Co1 Cl1 Co2 -24(100) 2_667 . . 2_667 ?
Cl1 Co1 O1 Co2 -131.40(5) . . . . ?
Cl1 Co1 O1 Co2 48.60(5) 2_667 . . . ?
Cl1 Co1 O1 C1 -101.5(2) 2_667 . . . ?
Cl1 Co1 O1 C1 78.5(2) . . . . ?
Cl1 Co1 O2 Co2 132.06(5) . . . . ?
Cl1 Co1 O2 Co2 -47.94(5) 2_667 . . . ?
Cl1 Co1 O2 C20 89.24(16) 2_667 . . . ?
Cl1 Co1 O2 C20 -90.76(16) . . . . ?
Cl1 Co2 O1 Co1 -44.32(4) 2_667 . . . ?
Cl1 Co2 O1 C1 111.84(16) 2_667 . . . ?
Cl1 Co2 O2 Co1 43.76(4) 2_667 . . . ?
Cl1 Co2 O2 C20 -93.16(16) 2_667 . . . ?
Cl1 Co2 N1 C7 -87.2(2) 2_667 . . . ?
Cl1 Co2 N1 C10 79.97(15) 2_667 . . . ?
Cl1 Co2 N2 C11 -98.04(13) 2_667 . . . ?
Cl1 Co2 N2 C12 86.08(19) 2_667 . . . ?
O1 Co1 Co2 Cl1 -60.73(6) 2_667 . . 2_667 ?
O1 Co1 Co2 Cl1 119.27(6) . . . 2_667 ?
O1 Co1 Co2 O1 180.000(1) 2_667 . . . ?
O1 Co1 Co2 O2 -120.50(9) . . . . ?
O1 Co1 Co2 O2 59.50(9) 2_667 . . . ?
O1 Co1 Co2 N1 57.19(9) . . . . ?
O1 Co1 Co2 N1 -122.81(9) 2_667 . . . ?
O1 Co1 Co2 N2 6.68(9) 2_667 . . . ?
O1 Co1 Co2 N2 -173.32(9) . . . . ?
O1 Co1 Cl1 Co2 36.00(4) 2_667 . . 2_667 ?
O1 Co1 Cl1 Co2 -144.00(4) . . . 2_667 ?
O1 Co1 O1 Co2 112(100) 2_667 . . . ?
O1 Co1 O1 C1 -38(100) 2_667 . . . ?
O1 Co1 O2 Co2 -142.37(5) 2_667 . . . ?
O1 Co1 O2 Co2 37.63(5) . . . . ?
O1 Co1 O2 C20 174.82(17) . . . . ?
O1 Co1 O2 C20 -5.18(17) 2_667 . . . ?
O1 Co2 O2 Co1 -41.42(6) . . . . ?
O1 Co2 O2 C20 -178.34(16) . . . . ?
O1 Co2 N1 C7 -2.4(2) . . . . ?
O1 Co2 N1 C10 164.78(15) . . . . ?
O1 Co2 N2 C11 123.2(7) . . . . ?
O1 Co2 N2 C12 -52.7(8) . . . . ?
O1 C1 C2 C3 -178.2(2) . . . . ?
O1 C1 C6 C5 178.9(2) . . . . ?
O1 C1 C6 C7 -0.3(3) . . . . ?
O2 Co1 Co2 Cl1 -120.23(6) . . . 2_667 ?
O2 Co1 Co2 Cl1 59.77(6) 2_667 . . 2_667 ?
O2 Co1 Co2 O1 120.50(9) . . . . ?
O2 Co1 Co2 O1 -59.50(9) 2_667 . . . ?
O2 Co1 Co2 O2 180.0 2_667 . . . ?
O2 Co1 Co2 N1 -2.31(9) 2_667 . . . ?
O2 Co1 Co2 N1 177.69(9) . . . . ?
O2 Co1 Co2 N2 127.18(9) 2_667 . . . ?
O2 Co1 Co2 N2 -52.82(9) . . . . ?
O2 Co1 Cl1 Co2 144.56(4) . . . 2_667 ?
O2 Co1 Cl1 Co2 -35.44(4) 2_667 . . 2_667 ?
O2 Co1 O1 Co2 142.51(6) 2_667 . . . ?
O2 Co1 O1 Co2 -37.49(6) . . . . ?
O2 Co1 O1 C1 -7.6(2) 2_667 . . . ?
O2 Co1 O1 C1 172.4(2) . . . . ?
O2 Co1 O2 Co2 -47(100) 2_667 . . . ?
O2 Co1 O2 C20 90(100) 2_667 . . . ?
O2 Co2 O1 Co1 41.12(6) . . . . ?
O2 Co2 O1 C1 -162.72(17) . . . . ?
O2 Co2 N1 C7 -14.2(12) . . . . ?
O2 Co2 N1 C10 153.0(11) . . . . ?
O2 Co2 N2 C11 176.52(14) . . . . ?
O2 Co2 N2 C12 0.64(19) . . . . ?
N1 Co2 O1 Co1 -138.11(7) . . . . ?
N1 Co2 O1 C1 18.04(17) . . . . ?
N1 Co2 O2 Co1 -29.5(11) . . . . ?
N1 Co2 O2 C20 -166.5(11) . . . . ?
N1 Co2 N2 C11 -3.98(14) . . . . ?
N1 Co2 N2 C12 -179.86(19) . . . . ?
N1 C7 C8 C9 87.1(3) . . . . ?
N1 C10 C11 N2 -41.1(2) . . . . ?
N2 Co2 O1 Co1 94.9(7) . . . . ?
N2 Co2 O1 C1 -109.0(7) . . . . ?
N2 Co2 O2 Co1 142.69(6) . . . . ?
N2 Co2 O2 C20 5.76(17) . . . . ?
N2 Co2 N1 C7 173.5(2) . . . . ?
N2 Co2 N1 C10 -19.27(15) . . . . ?
N2 C12 C13 C14 91.2(3) . . . . ?
N2 C12 C15 C16 -173.6(2) . . . . ?
N2 C12 C15 C20 4.4(3) . . . . ?
C1 C2 C3 C4 -1.4(4) . . . . ?
C1 C6 C7 N1 16.4(3) . . . . ?
C1 C6 C7 C8 -162.8(2) . . . . ?
C2 C1 C6 C5 -1.4(3) . . . . ?
C2 C1 C6 C7 179.4(2) . . . . ?
C2 C3 C4 C5 -0.1(4) . . . . ?
C3 C4 C5 C6 0.8(4) . . . . ?
C4 C5 C6 C1 0.0(4) . . . . ?
C4 C5 C6 C7 179.2(3) . . . . ?
C5 C6 C7 N1 -162.8(2) . . . . ?
C5 C6 C7 C8 18.0(3) . . . . ?
C6 C1 C2 C3 2.1(3) . . . . ?
C6 C7 C8 C9 -93.6(3) . . . . ?
C7 N1 C10 C11 -154.2(2) . . . . ?
C10 N1 C7 C6 -178.2(2) . . . . ?
C10 N1 C7 C8 1.0(3) . . . . ?
C11 N2 C12 C13 0.5(3) . . . . ?
C11 N2 C12 C15 179.35(19) . . . . ?
C12 N2 C11 C10 -158.1(2) . . . . ?
C12 C15 C16 C17 178.1(2) . . . . ?
C12 C15 C20 O2 2.1(3) . . . . ?
C12 C15 C20 C19 -179.7(2) . . . . ?
C13 C12 C15 C16 5.3(3) . . . . ?
C13 C12 C15 C20 -176.7(2) . . . . ?
C15 C12 C13 C14 -87.8(3) . . . . ?
C15 C16 C17 C18 1.2(4) . . . . ?
C16 C15 C20 O2 -179.80(19) . . . . ?
C16 C15 C20 C19 -1.6(3) . . . . ?
C16 C17 C18 C19 -0.5(4) . . . . ?
C17 C18 C19 C20 -1.2(4) . . . . ?
C18 C19 C20 O2 -179.4(2) . . . . ?
C18 C19 C20 C15 2.3(3) . . . . ?
C20 C15 C16 C17 0.0(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
