# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_nyy14100904a
_audit_block_doi                 10.5517/cc1jvk20
_database_code_depnum_ccdc_archive 'CCDC 1425692'
_audit_update_record             
;
2015-12-07 deposited with the CCDC.
2015-12-16 downloaded from the CCDC.
;
_audit_creation_date             2015-08-31
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C24 H22 N2), Ag5 Br9'
_chemical_formula_sum            'C48 H44 Ag5 Br9 N4'
_chemical_formula_weight         1935.41
_chemical_melting_point          ?
_chemical_oxdiff_formula         C20H20N4Ag1Br1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.4312(4)
_cell_length_b                   11.1981(8)
_cell_length_c                   13.2196(10)
_cell_angle_alpha                73.325(6)
_cell_angle_beta                 78.580(6)
_cell_angle_gamma                66.409(6)
_cell_volume                     1349.53(17)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    3880
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      28.0840
_cell_measurement_theta_min      3.4470
_shelx_estimated_absorpt_T_max   0.344
_shelx_estimated_absorpt_T_min   0.282
_exptl_absorpt_coefficient_mu    8.481
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79619
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.381
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       bulk
_exptl_crystal_F_000             910
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_av_unetI/netI     0.0475
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.850
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            11957
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.850
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.111
_diffrn_reflns_theta_min         3.216
_diffrn_ambient_temperature      291.15
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.850
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -25.00   21.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  -99.0000  -30.0000 46

#__ type_ start__ end____ width___ exp.time_
  2 omega  -70.00  -34.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  133.0000  144.0000 36

#__ type_ start__ end____ width___ exp.time_
  3 omega   23.00   56.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  -99.0000  120.0000 33

#__ type_ start__ end____ width___ exp.time_
  4 omega   37.00   92.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  178.0000   30.0000 55

#__ type_ start__ end____ width___ exp.time_
  5 omega  -51.00   36.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  -37.0000   60.0000 87

#__ type_ start__ end____ width___ exp.time_
  6 omega  -32.00   88.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104    0.0000   90.0000 120

#__ type_ start__ end____ width___ exp.time_
  7 omega   -2.00   56.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104   57.0000  150.0000 58
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0336233000
_diffrn_orient_matrix_UB_12      0.0697525000
_diffrn_orient_matrix_UB_13      -0.0203876000
_diffrn_orient_matrix_UB_21      -0.0194199000
_diffrn_orient_matrix_UB_22      0.0096783000
_diffrn_orient_matrix_UB_23      0.0524297000
_diffrn_orient_matrix_UB_31      0.0636215000
_diffrn_orient_matrix_UB_32      0.0093801000
_diffrn_orient_matrix_UB_33      -0.0010153000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4360
_reflns_number_total             6172
_reflns_odcompleteness_completeness 99.76
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_refine_diff_density_max         1.368
_refine_diff_density_min         -1.364
_refine_diff_density_rms         0.127
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         6172
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0734
_refine_ls_R_factor_gt           0.0431
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0399P)²+0.4390P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0846
_refine_ls_wR_factor_ref         0.0976
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Others
 Fixed Sof: Ag3(0.5)
3.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C19(H19A,H19B)
3.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C11(H11), C12(H12),
 C13(H13), C14(H14), C15(H15), C16(H16), C17(H17), C20(H20), C21(H21), C23(H23),
  C24(H24)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.0886(7) 0.4138(6) 0.1473(6) 0.0684(19) Uani 1 1 d . . . . .
H1 H 0.1666 0.3751 0.1032 0.082 Uiso 1 1 calc R . . . .
C2 C 0.0406(8) 0.5517(7) 0.1429(6) 0.077(2) Uani 1 1 d . . . . .
H2 H 0.0876 0.6041 0.0964 0.093 Uiso 1 1 calc R . . . .
C3 C -0.0740(8) 0.6083(7) 0.2064(7) 0.075(2) Uani 1 1 d . . . . .
H3 H -0.1063 0.6997 0.2027 0.090 Uiso 1 1 calc R . . . .
C4 C -0.1428(7) 0.5314(8) 0.2762(6) 0.0700(19) Uani 1 1 d . . . . .
H4 H -0.2210 0.5705 0.3200 0.084 Uiso 1 1 calc R . . . .
C5 C -0.0961(6) 0.3968(7) 0.2812(5) 0.0555(15) Uani 1 1 d . . . . .
H5 H -0.1431 0.3451 0.3285 0.067 Uiso 1 1 calc R . . . .
C6 C 0.0206(6) 0.3370(6) 0.2165(5) 0.0496(14) Uani 1 1 d . . . . .
C7 C 0.0656(7) 0.1870(6) 0.2295(6) 0.0683(19) Uani 1 1 d . . . . .
H7A H 0.0824 0.1426 0.3029 0.082 Uiso 1 1 calc R . . . .
H7B H -0.0104 0.1685 0.2134 0.082 Uiso 1 1 calc R . . . .
C8 C 0.3181(7) 0.0898(6) 0.1962(5) 0.0584(16) Uani 1 1 d . . . . .
H8 H 0.3233 0.0961 0.2638 0.070 Uiso 1 1 calc R . . . .
C9 C 0.4385(6) 0.0388(6) 0.1350(5) 0.0516(15) Uani 1 1 d . . . . .
H9 H 0.5247 0.0104 0.1615 0.062 Uiso 1 1 calc R . . . .
C10 C 0.4350(5) 0.0283(5) 0.0338(4) 0.0369(11) Uani 1 1 d . . . . .
C11 C 0.3032(6) 0.0732(6) -0.0009(5) 0.0515(15) Uani 1 1 d . . . . .
H11 H 0.2951 0.0692 -0.0685 0.062 Uiso 1 1 calc R . . . .
C12 C 0.1851(6) 0.1233(6) 0.0632(5) 0.0552(15) Uani 1 1 d . . . . .
H12 H 0.0974 0.1529 0.0387 0.066 Uiso 1 1 calc R . . . .
N1 N 0.1933(5) 0.1307(5) 0.1610(4) 0.0531(13) Uani 1 1 d . . . . .
C13 C 0.3007(5) 0.7549(5) 0.0893(4) 0.0406(12) Uani 1 1 d . . . . .
H13 H 0.2048 0.8014 0.0846 0.049 Uiso 1 1 calc R . . . .
C14 C 0.3857(6) 0.7096(6) 0.0037(4) 0.0498(14) Uani 1 1 d . . . . .
H14 H 0.3467 0.7268 -0.0588 0.060 Uiso 1 1 calc R . . . .
C15 C 0.5269(6) 0.6395(6) 0.0094(4) 0.0510(15) Uani 1 1 d . . . . .
H15 H 0.5829 0.6074 -0.0483 0.061 Uiso 1 1 calc R . . . .
C16 C 0.5850(6) 0.6168(7) 0.1005(5) 0.0561(16) Uani 1 1 d . . . . .
H16 H 0.6814 0.5720 0.1036 0.067 Uiso 1 1 calc R . . . .
C17 C 0.5012(5) 0.6602(6) 0.1884(4) 0.0471(14) Uani 1 1 d . . . . .
H17 H 0.5405 0.6418 0.2510 0.057 Uiso 1 1 calc R . . . .
C18 C 0.3576(5) 0.7315(5) 0.1817(4) 0.0334(11) Uani 1 1 d . . . . .
C19 C 0.2678(5) 0.7813(5) 0.2752(4) 0.0391(12) Uani 1 1 d . . . . .
H19A H 0.2019 0.8713 0.2502 0.047 Uiso 1 1 calc R . . . .
H19B H 0.3272 0.7865 0.3204 0.047 Uiso 1 1 calc R . . . .
C20 C 0.0666(5) 0.7538(5) 0.3951(4) 0.0354(11) Uani 1 1 d . . . . .
H20 H 0.0328 0.8455 0.3904 0.042 Uiso 1 1 calc R . . . .
C21 C -0.0076(5) 0.6778(5) 0.4587(4) 0.0375(12) Uani 1 1 d . . . . .
H21 H -0.0909 0.7189 0.4972 0.045 Uiso 1 1 calc R . . . .
C22 C 0.0389(4) 0.5421(5) 0.4663(3) 0.0269(10) Uani 1 1 d . . . . .
C23 C 0.1656(5) 0.4860(5) 0.4085(4) 0.0442(13) Uani 1 1 d . . . . .
H23 H 0.2020 0.3944 0.4123 0.053 Uiso 1 1 calc R . . . .
C24 C 0.2370(5) 0.5642(5) 0.3462(4) 0.0386(12) Uani 1 1 d . . . . .
H24 H 0.3213 0.5253 0.3077 0.046 Uiso 1 1 calc R . . . .
N2 N 0.1871(4) 0.6963(4) 0.3399(3) 0.0284(8) Uani 1 1 d . . . . .
Ag1 Ag 0.72240(5) 0.04855(5) 0.31081(4) 0.05756(15) Uani 1 1 d . . . . .
Ag2 Ag 0.55512(5) 0.26458(5) 0.46602(4) 0.05826(15) Uani 1 1 d . . . . .
Ag3 Ag 0.46428(15) 0.02468(18) 0.47743(13) 0.0741(5) Uani 0.5 1 d . . . . .
Br1 Br 0.90969(5) -0.01381(6) 0.15671(4) 0.04790(16) Uani 1 1 d . . . . .
Br2 Br 0.47520(6) 0.25875(6) 0.28684(5) 0.05668(17) Uani 1 1 d . . . . .
Br3 Br 0.37999(6) 0.16337(5) 0.62445(4) 0.04456(15) Uani 1 1 d . . . . .
Br4 Br 0.5000 0.5000 0.5000 0.0771(3) Uani 1 2 d S T P . .
Br5 Br 0.79900(6) 0.05056(8) 0.49727(5) 0.0656(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 H1 0.9300 . ?
C1 C2 1.407(9) . ?
C1 C6 1.364(8) . ?
C2 H2 0.9300 . ?
C2 C3 1.356(10) . ?
C3 H3 0.9300 . ?
C3 C4 1.372(10) . ?
C4 H4 0.9300 . ?
C4 C5 1.372(9) . ?
C5 H5 0.9300 . ?
C5 C6 1.388(8) . ?
C6 C7 1.518(8) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 N1 1.473(7) . ?
C8 H8 0.9300 . ?
C8 C9 1.359(8) . ?
C8 N1 1.327(8) . ?
C9 H9 0.9300 . ?
C9 C10 1.385(7) . ?
C10 C10 1.481(10) 2_655 ?
C10 C11 1.385(7) . ?
C11 H11 0.9300 . ?
C11 C12 1.362(8) . ?
C12 H12 0.9300 . ?
C12 N1 1.340(8) . ?
C13 H13 0.9300 . ?
C13 C14 1.377(7) . ?
C13 C18 1.376(7) . ?
C14 H14 0.9300 . ?
C14 C15 1.369(8) . ?
C15 H15 0.9300 . ?
C15 C16 1.369(8) . ?
C16 H16 0.9300 . ?
C16 C17 1.390(8) . ?
C17 H17 0.9300 . ?
C17 C18 1.394(7) . ?
C18 C19 1.494(7) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 N2 1.495(6) . ?
C20 H20 0.9300 . ?
C20 C21 1.374(7) . ?
C20 N2 1.336(6) . ?
C21 H21 0.9300 . ?
C21 C22 1.378(7) . ?
C22 C22 1.478(9) 2_566 ?
C22 C23 1.391(6) . ?
C23 H23 0.9300 . ?
C23 C24 1.365(6) . ?
C24 H24 0.9300 . ?
C24 N2 1.341(6) . ?
Ag1 Ag2 3.3405(7) . ?
Ag1 Ag3 3.1721(19) . ?
Ag1 Ag3 3.1785(19) 2_656 ?
Ag1 Br1 2.5695(7) . ?
Ag1 Br2 2.7069(8) . ?
Ag1 Br3 2.8294(7) 2_656 ?
Ag1 Br5 2.7462(8) . ?
Ag2 Ag3 3.189(2) 2_656 ?
Ag2 Ag3 3.1441(19) . ?
Ag2 Br2 2.6878(8) . ?
Ag2 Br3 2.7907(7) . ?
Ag2 Br4 2.6166(5) . ?
Ag2 Br5 2.7118(8) . ?
Ag3 Ag1 3.1786(19) 2_656 ?
Ag3 Ag2 3.189(2) 2_656 ?
Ag3 Ag3 0.935(2) 2_656 ?
Ag3 Br3 2.6315(18) . ?
Ag3 Br3 2.6287(18) 2_656 ?
Br3 Ag1 2.8295(7) 2_656 ?
Br3 Ag3 2.6288(18) 2_656 ?
Br4 Ag2 2.6166(5) 2_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1 120.1 . . ?
C6 C1 H1 120.1 . . ?
C6 C1 C2 119.9(6) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 120.0(7) . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 119.8 . . ?
C2 C3 C4 120.3(7) . . ?
C4 C3 H3 119.8 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 119.9(7) . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 119.6 . . ?
C4 C5 C6 120.7(7) . . ?
C6 C5 H5 119.6 . . ?
C1 C6 C5 119.2(6) . . ?
C1 C6 C7 124.1(5) . . ?
C5 C6 C7 116.7(5) . . ?
C6 C7 H7A 108.9 . . ?
C6 C7 H7B 108.9 . . ?
H7A C7 H7B 107.7 . . ?
N1 C7 C6 113.2(5) . . ?
N1 C7 H7A 108.9 . . ?
N1 C7 H7B 108.9 . . ?
C9 C8 H8 119.5 . . ?
N1 C8 H8 119.5 . . ?
N1 C8 C9 121.0(6) . . ?
C8 C9 H9 119.4 . . ?
C8 C9 C10 121.2(5) . . ?
C10 C9 H9 119.4 . . ?
C9 C10 C10 122.0(5) . 2_655 ?
C9 C10 C11 116.3(5) . . ?
C11 C10 C10 121.7(6) . 2_655 ?
C10 C11 H11 119.7 . . ?
C12 C11 C10 120.6(5) . . ?
C12 C11 H11 119.7 . . ?
C11 C12 H12 119.5 . . ?
N1 C12 C11 121.0(5) . . ?
N1 C12 H12 119.5 . . ?
C8 N1 C7 119.1(6) . . ?
C8 N1 C12 119.9(5) . . ?
C12 N1 C7 121.0(5) . . ?
C14 C13 H13 120.0 . . ?
C18 C13 H13 120.0 . . ?
C18 C13 C14 120.0(5) . . ?
C13 C14 H14 119.5 . . ?
C15 C14 C13 120.9(5) . . ?
C15 C14 H14 119.5 . . ?
C14 C15 H15 120.2 . . ?
C14 C15 C16 119.6(5) . . ?
C16 C15 H15 120.2 . . ?
C15 C16 H16 119.7 . . ?
C15 C16 C17 120.5(5) . . ?
C17 C16 H16 119.7 . . ?
C16 C17 H17 120.3 . . ?
C16 C17 C18 119.4(5) . . ?
C18 C17 H17 120.3 . . ?
C13 C18 C17 119.5(5) . . ?
C13 C18 C19 121.0(5) . . ?
C17 C18 C19 119.5(5) . . ?
C18 C19 H19A 108.7 . . ?
C18 C19 H19B 108.7 . . ?
C18 C19 N2 114.3(4) . . ?
H19A C19 H19B 107.6 . . ?
N2 C19 H19A 108.7 . . ?
N2 C19 H19B 108.7 . . ?
C21 C20 H20 119.9 . . ?
N2 C20 H20 119.9 . . ?
N2 C20 C21 120.2(4) . . ?
C20 C21 H21 119.4 . . ?
C20 C21 C22 121.3(4) . . ?
C22 C21 H21 119.4 . . ?
C21 C22 C22 122.5(5) . 2_566 ?
C21 C22 C23 116.7(4) . . ?
C23 C22 C22 120.8(5) . 2_566 ?
C22 C23 H23 119.7 . . ?
C24 C23 C22 120.7(5) . . ?
C24 C23 H23 119.7 . . ?
C23 C24 H24 119.6 . . ?
N2 C24 C23 120.7(4) . . ?
N2 C24 H24 119.6 . . ?
C20 N2 C19 118.6(4) . . ?
C20 N2 C24 120.5(4) . . ?
C24 N2 C19 120.9(4) . . ?
Ag3 Ag1 Ag2 58.50(4) 2_656 . ?
Ag3 Ag1 Ag2 57.66(3) . . ?
Ag3 Ag1 Ag3 16.93(4) . 2_656 ?
Br1 Ag1 Ag2 147.34(2) . . ?
Br1 Ag1 Ag3 152.50(4) . 2_656 ?
Br1 Ag1 Ag3 154.62(4) . . ?
Br1 Ag1 Br2 123.80(3) . . ?
Br1 Ag1 Br3 103.95(2) . 2_656 ?
Br1 Ag1 Br5 120.27(2) . . ?
Br2 Ag1 Ag2 51.484(17) . . ?
Br2 Ag1 Ag3 77.42(3) . 2_656 ?
Br2 Ag1 Ag3 62.90(3) . . ?
Br2 Ag1 Br3 99.29(2) . 2_656 ?
Br2 Ag1 Br5 103.26(2) . . ?
Br3 Ag1 Ag2 108.70(2) 2_656 . ?
Br3 Ag1 Ag3 51.57(4) 2_656 . ?
Br3 Ag1 Ag3 51.55(4) 2_656 2_656 ?
Br5 Ag1 Ag2 51.798(18) . . ?
Br5 Ag1 Ag3 76.58(3) . . ?
Br5 Ag1 Ag3 62.90(3) . 2_656 ?
Br5 Ag1 Br3 102.07(3) . 2_656 ?
Ag3 Ag2 Ag1 58.21(3) 2_656 . ?
Ag3 Ag2 Ag1 58.48(3) . . ?
Ag3 Ag2 Ag3 16.96(4) . 2_656 ?
Br2 Ag2 Ag1 51.999(18) . . ?
Br2 Ag2 Ag3 63.49(3) . . ?
Br2 Ag2 Ag3 77.50(3) . 2_656 ?
Br2 Ag2 Br3 103.07(2) . . ?
Br2 Ag2 Br5 104.70(2) . . ?
Br3 Ag2 Ag1 109.34(2) . . ?
Br3 Ag2 Ag3 51.64(3) . 2_656 ?
Br3 Ag2 Ag3 52.23(4) . . ?
Br4 Ag2 Ag1 147.60(2) . . ?
Br4 Ag2 Ag3 150.85(3) . . ?
Br4 Ag2 Ag3 154.18(4) . 2_656 ?
Br4 Ag2 Br2 117.30(2) . . ?
Br4 Ag2 Br3 102.87(2) . . ?
Br4 Ag2 Br5 126.06(2) . . ?
Br5 Ag2 Ag1 52.732(18) . . ?
Br5 Ag2 Ag3 77.54(3) . . ?
Br5 Ag2 Ag3 63.08(3) . 2_656 ?
Br5 Ag2 Br3 98.64(3) . . ?
Ag1 Ag3 Ag1 163.07(4) . 2_656 ?
Ag1 Ag3 Ag2 113.16(5) . 2_656 ?
Ag1 Ag3 Ag2 63.29(4) 2_656 2_656 ?
Ag2 Ag3 Ag1 63.86(4) . . ?
Ag2 Ag3 Ag1 114.21(5) . 2_656 ?
Ag2 Ag3 Ag2 163.04(4) . 2_656 ?
Ag3 Ag3 Ag1 81.1(2) 2_656 2_656 ?
Ag3 Ag3 Ag1 81.9(2) 2_656 . ?
Ag3 Ag3 Ag2 84.2(2) 2_656 . ?
Ag3 Ag3 Ag2 78.8(2) 2_656 2_656 ?
Ag3 Ag3 Br3 79.9(2) 2_656 2_656 ?
Ag3 Ag3 Br3 79.6(2) 2_656 . ?
Br3 Ag3 Ag1 119.16(6) . . ?
Br3 Ag3 Ag1 57.48(4) 2_656 . ?
Br3 Ag3 Ag1 57.36(4) . 2_656 ?
Br3 Ag3 Ag1 119.02(7) 2_656 2_656 ?
Br3 Ag3 Ag2 56.35(4) 2_656 2_656 ?
Br3 Ag3 Ag2 118.99(6) . 2_656 ?
Br3 Ag3 Ag2 120.66(6) 2_656 . ?
Br3 Ag3 Ag2 56.96(4) . . ?
Br3 Ag3 Br3 159.53(5) 2_656 . ?
Ag2 Br2 Ag1 76.52(2) . . ?
Ag2 Br3 Ag1 141.69(3) . 2_656 ?
Ag3 Br3 Ag1 70.96(4) 2_656 2_656 ?
Ag3 Br3 Ag1 71.08(5) . 2_656 ?
Ag3 Br3 Ag2 72.01(5) 2_656 . ?
Ag3 Br3 Ag2 70.81(4) . . ?
Ag3 Br3 Ag3 20.47(5) 2_656 . ?
Ag2 Br4 Ag2 180.0 . 2_666 ?
Ag2 Br5 Ag1 75.47(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 0.8(11) . . . . ?
C1 C6 C7 N1 1.1(10) . . . . ?
C2 C1 C6 C5 0.4(10) . . . . ?
C2 C1 C6 C7 -178.4(7) . . . . ?
C2 C3 C4 C5 -0.5(10) . . . . ?
C3 C4 C5 C6 0.1(9) . . . . ?
C4 C5 C6 C1 -0.1(9) . . . . ?
C4 C5 C6 C7 178.8(6) . . . . ?
C5 C6 C7 N1 -177.7(6) . . . . ?
C6 C1 C2 C3 -0.8(11) . . . . ?
C6 C7 N1 C8 88.4(7) . . . . ?
C6 C7 N1 C12 -90.0(7) . . . . ?
C8 C9 C10 C10 -179.4(6) . . . 2_655 ?
C8 C9 C10 C11 0.4(8) . . . . ?
C9 C8 N1 C7 -179.2(5) . . . . ?
C9 C8 N1 C12 -0.8(9) . . . . ?
C9 C10 C11 C12 -0.6(8) . . . . ?
C10 C10 C11 C12 179.2(6) 2_655 . . . ?
C10 C11 C12 N1 0.1(9) . . . . ?
C11 C12 N1 C7 179.0(5) . . . . ?
C11 C12 N1 C8 0.6(9) . . . . ?
N1 C8 C9 C10 0.3(9) . . . . ?
C13 C14 C15 C16 -1.6(9) . . . . ?
C13 C18 C19 N2 80.0(6) . . . . ?
C14 C13 C18 C17 -0.9(8) . . . . ?
C14 C13 C18 C19 179.2(5) . . . . ?
C14 C15 C16 C17 2.3(9) . . . . ?
C15 C16 C17 C18 -2.3(9) . . . . ?
C16 C17 C18 C13 1.6(8) . . . . ?
C16 C17 C18 C19 -178.5(5) . . . . ?
C17 C18 C19 N2 -99.9(5) . . . . ?
C18 C13 C14 C15 0.9(8) . . . . ?
C18 C19 N2 C20 -153.0(4) . . . . ?
C18 C19 N2 C24 29.6(7) . . . . ?
C20 C21 C22 C22 -179.7(5) . . . 2_566 ?
C20 C21 C22 C23 1.3(7) . . . . ?
C21 C20 N2 C19 -177.5(4) . . . . ?
C21 C20 N2 C24 -0.2(7) . . . . ?
C21 C22 C23 C24 -1.2(7) . . . . ?
C22 C22 C23 C24 179.9(5) 2_566 . . . ?
C22 C23 C24 N2 0.4(8) . . . . ?
C23 C24 N2 C19 177.6(5) . . . . ?
C23 C24 N2 C20 0.3(7) . . . . ?
N2 C20 C21 C22 -0.7(7) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
