# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1436182'
_audit_update_record             
;
2015-11-10 deposited with the CCDC.
2015-12-22 downloaded from the CCDC.
;

_vrf_PLAT057_2                   
;
PROBLEM: Correction for Absorption Required   RT(exp) ...       1.26       
RESPONSE:correction in a multiscan-like manner,
         see: _exptl_special_details
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H24 Au Co F6 P2'
_chemical_formula_weight         816.33

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   17.1720(3)
_cell_length_b                   23.4197(2)
_cell_length_c                   15.6447(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 113.927(2)
_cell_angle_gamma                90.00
_cell_volume                     5751.03(16)
_cell_formula_units_Z            8
_cell_measurement_temperature    233(2)
_cell_measurement_reflns_used    20271
_cell_measurement_theta_min      1.0
_cell_measurement_theta_max      26.3

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.21
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.886
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3152
_exptl_absorpt_coefficient_mu    5.842
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
All data sets were measured with several scans to increase the number of
redundant reflections. In our experience this method of averaging redundant
reflections replaces in a good approximation semi-empirical absorptions
methods (absorption correction programs like SORTAV lead to no better data
sets).
;

_diffrn_ambient_temperature      233(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi- and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            17453
_diffrn_reflns_av_R_equivalents  0.0380
_diffrn_reflns_av_sigmaI/netI    0.0266
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.25
_diffrn_reflns_theta_max         25.00
_reflns_number_total             5016
_reflns_number_gt                4209
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       COLLECT
_computing_cell_refinement       ?
_computing_data_reduction        'DENZO and SCALEPACK'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Carbon atoms of cyclopentadienyl ring are positional disordered in ratio
 1:1 for C1-C5:C1A-C5A. These carbon positions were refined with isotropic
 displacement parameters. The two PF6-anion positions are nearby a two-fold
 rotation axis with P-atoms on the axis. The first is well ordered P2-F1-F3,
 the second shows an ordered part F4-F7 (with F6 and F7 on the axis) and a
 positional disordered part F8-F13. Both parts are in ratio of around 1:1.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0441P)²+22.5043P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5016
_refine_ls_number_parameters     412
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0335
_refine_ls_wR_factor_ref         0.0895
_refine_ls_wR_factor_gt          0.0846
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.085847(12) 0.249787(7) 0.850050(14) 0.04704(10) Uani 1 1 d . . .
Co1 Co -0.17799(4) 0.12325(3) 0.93695(5) 0.05260(19) Uani 1 1 d . . .
P1 P 0.17660(8) 0.31563(5) 0.83515(8) 0.0384(3) Uani 1 1 d . . .
C6 C -0.0804(4) 0.0713(3) 0.9495(4) 0.0664(16) Uani 1 1 d . A .
H6 H -0.0296 0.0670 1.0032 0.080 Uiso 1 1 calc . . .
C7 C -0.1551(5) 0.0391(3) 0.9283(6) 0.083(2) Uani 1 1 d . A .
H7 H -0.1622 0.0093 0.9646 0.099 Uiso 1 1 calc . . .
C8 C -0.2175(5) 0.0595(3) 0.8432(5) 0.082(2) Uani 1 1 d . A .
H8 H -0.2739 0.0464 0.8134 0.098 Uiso 1 1 calc . . .
C9 C -0.1795(4) 0.1032(3) 0.8110(4) 0.0653(15) Uani 1 1 d . A .
H9 H -0.2066 0.1238 0.7551 0.078 Uiso 1 1 calc . . .
C10 C -0.0941(3) 0.1113(2) 0.8764(4) 0.0511(12) Uani 1 1 d . A .
C11 C -0.0364(3) 0.1541(2) 0.8728(4) 0.0552(13) Uani 1 1 d . . .
C12 C 0.0104(3) 0.1905(2) 0.8678(4) 0.0555(13) Uani 1 1 d . A .
C101 C 0.2097(3) 0.36764(19) 0.9287(3) 0.0401(10) Uani 1 1 d . . .
C102 C 0.1463(3) 0.4003(3) 0.9397(4) 0.0590(14) Uani 1 1 d . . .
H102 H 0.0889 0.3951 0.8987 0.071 Uiso 1 1 calc . . .
C103 C 0.1678(4) 0.4399(3) 1.0105(4) 0.0723(17) Uani 1 1 d . . .
H103 H 0.1254 0.4630 1.0160 0.087 Uiso 1 1 calc . . .
C104 C 0.2514(4) 0.4457(2) 1.0735(4) 0.0629(15) Uani 1 1 d . . .
H104 H 0.2655 0.4723 1.1225 0.076 Uiso 1 1 calc . . .
C105 C 0.3139(4) 0.4130(2) 1.0650(4) 0.0581(14) Uani 1 1 d . . .
H105 H 0.3707 0.4171 1.1082 0.070 Uiso 1 1 calc . . .
C106 C 0.2933(3) 0.3737(2) 0.9923(3) 0.0484(11) Uani 1 1 d . . .
H106 H 0.3362 0.3513 0.9865 0.058 Uiso 1 1 calc . . .
C201 C 0.1334(3) 0.35659(19) 0.7269(3) 0.0384(10) Uani 1 1 d . . .
C202 C 0.0966(3) 0.3267(2) 0.6443(3) 0.0493(12) Uani 1 1 d . . .
H202 H 0.0925 0.2867 0.6453 0.059 Uiso 1 1 calc . . .
C203 C 0.0655(3) 0.3554(3) 0.5598(3) 0.0609(14) Uani 1 1 d . . .
H203 H 0.0408 0.3347 0.5038 0.073 Uiso 1 1 calc . . .
C204 C 0.0703(4) 0.4133(3) 0.5568(4) 0.0643(16) Uani 1 1 d . . .
H204 H 0.0499 0.4325 0.4991 0.077 Uiso 1 1 calc . . .
C205 C 0.1049(5) 0.4428(3) 0.6379(4) 0.0767(19) Uani 1 1 d . . .
H205 H 0.1071 0.4828 0.6362 0.092 Uiso 1 1 calc . . .
C206 C 0.1370(4) 0.4151(2) 0.7235(4) 0.0649(16) Uani 1 1 d . . .
H206 H 0.1612 0.4363 0.7791 0.078 Uiso 1 1 calc . . .
C301 C 0.2732(3) 0.28401(19) 0.8350(3) 0.0397(10) Uani 1 1 d . . .
C302 C 0.2939(3) 0.2279(2) 0.8647(4) 0.0523(12) Uani 1 1 d . . .
H302 H 0.2589 0.2069 0.8865 0.063 Uiso 1 1 calc . . .
C303 C 0.3661(4) 0.2030(2) 0.8622(4) 0.0651(15) Uani 1 1 d . . .
H303 H 0.3799 0.1651 0.8823 0.078 Uiso 1 1 calc . . .
C304 C 0.4173(4) 0.2331(3) 0.8308(4) 0.0627(15) Uani 1 1 d . . .
H304 H 0.4658 0.2157 0.8285 0.075 Uiso 1 1 calc . . .
C305 C 0.3983(4) 0.2886(3) 0.8027(4) 0.0649(15) Uani 1 1 d . . .
H305 H 0.4344 0.3093 0.7823 0.078 Uiso 1 1 calc . . .
C306 C 0.3262(3) 0.3144(2) 0.8039(4) 0.0550(13) Uani 1 1 d . . .
H306 H 0.3132 0.3524 0.7837 0.066 Uiso 1 1 calc . . .
C1 C -0.1388(12) 0.1735(10) 1.0513(16) 0.087(7) Uiso 0.50 1 d P A 1
H1 H -0.0827 0.1783 1.0959 0.104 Uiso 0.50 1 calc P B 1
C2 C -0.1978(13) 0.1340(7) 1.0553(11) 0.072(4) Uiso 0.50 1 d P A 1
H2 H -0.1882 0.1069 1.1029 0.086 Uiso 0.50 1 calc P C 1
C3 C -0.2721(10) 0.1415(6) 0.9783(13) 0.067(3) Uiso 0.50 1 d P A 1
H3 H -0.3222 0.1202 0.9639 0.081 Uiso 0.50 1 calc P D 1
C4 C -0.2616(14) 0.1853(9) 0.9251(12) 0.084(5) Uiso 0.50 1 d P A 1
H4 H -0.3038 0.1993 0.8692 0.101 Uiso 0.50 1 calc P E 1
C5 C -0.1790(18) 0.2051(8) 0.9675(18) 0.101(6) Uiso 0.50 1 d P A 1
H5 H -0.1541 0.2339 0.9451 0.122 Uiso 0.50 1 calc P F 1
C1A C -0.1517(13) 0.1594(8) 1.0648(11) 0.069(5) Uiso 0.50 1 d P A 2
H1A H -0.1087 0.1455 1.1202 0.083 Uiso 0.50 1 calc P G 2
C2A C -0.2366(16) 0.1433(9) 1.0253(17) 0.092(6) Uiso 0.50 1 d P A 2
H2A H -0.2620 0.1192 1.0547 0.110 Uiso 0.50 1 calc P H 2
C3A C -0.2803(10) 0.1673(9) 0.9361(13) 0.076(5) Uiso 0.50 1 d P A 2
H3A H -0.3360 0.1590 0.8931 0.091 Uiso 0.50 1 calc P I 2
C4A C -0.2220(10) 0.2072(5) 0.9244(9) 0.052(3) Uiso 0.50 1 d P A 2
H4A H -0.2338 0.2323 0.8738 0.063 Uiso 0.50 1 calc P J 2
C5A C -0.1436(8) 0.2019(5) 1.0030(10) 0.048(3) Uiso 0.50 1 d P A 2
H5A H -0.0940 0.2230 1.0132 0.058 Uiso 0.50 1 calc P K 2
P2 P 0.0000 0.57334(10) 0.7500 0.0578(5) Uani 1 2 d S . .
P3 P 0.5000 0.53412(11) 1.2500 0.0850(9) Uani 1 2 d S . .
F1 F 0.0523(5) 0.5300(3) 0.8218(4) 0.161(3) Uani 1 1 d . . .
F2 F 0.0693(3) 0.5747(2) 0.7080(4) 0.1184(16) Uani 1 1 d . . .
F3 F 0.0478(4) 0.6239(2) 0.8196(4) 0.136(2) Uani 1 1 d . . .
F4 F 0.5000 0.6003(9) 1.2500 0.113(15) Uani 0.50 2 d SP L 1
F5 F 0.5000 0.4630(8) 1.2500 0.173(17) Uani 0.50 2 d SP M 1
F6 F 0.5997(18) 0.5329(16) 1.272(3) 0.178(12) Uani 0.50 1 d P L 1
F7 F 0.521(2) 0.5246(11) 1.3524(16) 0.168(13) Uani 0.50 1 d P L 1
F8 F 0.415(3) 0.532(2) 1.185(3) 0.116(18) Uani 0.25 1 d P . 2
F9 F 0.587(7) 0.538(3) 1.348(4) 0.17(4) Uani 0.25 1 d P . 2
F10 F 0.528(3) 0.571(2) 1.169(2) 0.162(17) Uani 0.25 1 d P . 2
F11 F 0.459(5) 0.529(4) 1.310(4) 0.29(4) Uani 0.25 1 d P . 2
F12 F 0.491(4) 0.592(2) 1.277(4) 0.20(3) Uani 0.25 1 d P . 2
F13 F 0.535(3) 0.4827(9) 1.225(3) 0.146(13) Uani 0.25 1 d P . 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C12 1.994(5) . ?
Au1 P1 2.2705(11) . ?
Au1 Au1 3.3175(4) 2_556 ?
Co1 C5 1.98(2) . ?
Co1 C4 1.998(17) . ?
Co1 C8 2.008(6) . ?
Co1 C9 2.015(5) . ?
Co1 C3 2.015(14) . ?
Co1 C6 2.015(6) . ?
Co1 C1 2.015(19) . ?
Co1 C7 2.024(7) . ?
Co1 C2 2.030(14) . ?
Co1 C3A 2.033(16) . ?
Co1 C10 2.039(5) . ?
Co1 C1A 2.048(16) . ?
P1 C101 1.809(4) . ?
P1 C301 1.818(5) . ?
P1 C201 1.822(4) . ?
C6 C7 1.406(9) . ?
C6 C10 1.421(7) . ?
C6 H6 0.9400 . ?
C7 C8 1.412(10) . ?
C7 H7 0.9400 . ?
C8 C9 1.411(9) . ?
C8 H8 0.9400 . ?
C9 C10 1.420(8) . ?
C9 H9 0.9400 . ?
C10 C11 1.426(7) . ?
C11 C12 1.197(7) . ?
C101 C106 1.382(7) . ?
C101 C102 1.397(7) . ?
C102 C103 1.376(7) . ?
C102 H102 0.9400 . ?
C103 C104 1.380(9) . ?
C103 H103 0.9400 . ?
C104 C105 1.368(8) . ?
C104 H104 0.9400 . ?
C105 C106 1.392(7) . ?
C105 H105 0.9400 . ?
C106 H106 0.9400 . ?
C201 C206 1.373(7) . ?
C201 C202 1.378(6) . ?
C202 C203 1.382(7) . ?
C202 H202 0.9400 . ?
C203 C204 1.359(9) . ?
C203 H203 0.9400 . ?
C204 C205 1.353(9) . ?
C204 H204 0.9400 . ?
C205 C206 1.385(7) . ?
C205 H205 0.9400 . ?
C206 H206 0.9400 . ?
C301 C306 1.389(7) . ?
C301 C302 1.392(7) . ?
C302 C303 1.384(8) . ?
C302 H302 0.9400 . ?
C303 C304 1.366(9) . ?
C303 H303 0.9400 . ?
C304 C305 1.368(9) . ?
C304 H304 0.9400 . ?
C305 C306 1.385(8) . ?
C305 H305 0.9400 . ?
C306 H306 0.9400 . ?
C1 C2 1.39(3) . ?
C1 C5 1.42(3) . ?
C1 H1 0.9400 . ?
C2 C3 1.36(2) . ?
C2 H2 0.9400 . ?
C3 C4 1.38(3) . ?
C3 H3 0.9400 . ?
C4 C5 1.38(3) . ?
C4 H4 0.9400 . ?
C5 H5 0.9400 . ?
C1A C2A 1.39(3) . ?
C1A C5A 1.43(2) . ?
C1A H1A 0.9400 . ?
C2A C3A 1.41(3) . ?
C2A H2A 0.9400 . ?
C3A C4A 1.43(2) . ?
C3A H3A 0.9400 . ?
C4A C5A 1.413(18) . ?
C4A H4A 0.9400 . ?
C5A H5A 0.9400 . ?
P2 F1 1.510(5) 2_556 ?
P2 F1 1.510(5) . ?
P2 F2 1.577(4) 2_556 ?
P2 F2 1.577(4) . ?
P2 F3 1.594(5) . ?
P2 F3 1.594(5) 2_556 ?
P3 F11 1.39(5) 2_657 ?
P3 F11 1.39(5) . ?
P3 F8 1.41(5) . ?
P3 F8 1.41(5) 2_657 ?
P3 F12 1.44(5) . ?
P3 F12 1.44(5) 2_657 ?
P3 F13 1.47(2) 2_657 ?
P3 F13 1.47(2) . ?
P3 F7 1.51(2) 2_657 ?
P3 F7 1.51(2) . ?
P3 F4 1.55(2) . ?
P3 F6 1.60(3) . ?
F8 F9 0.51(8) 2_657 ?
F8 F13 1.77(6) 2_657 ?
F9 F8 0.51(8) 2_657 ?
F10 F11 1.03(8) 2_657 ?
F10 F12 1.14(8) 2_657 ?
F11 F10 1.03(8) 2_657 ?
F11 F13 1.24(9) 2_657 ?
F11 F12 1.73(8) . ?
F12 F12 1.00(11) 2_657 ?
F12 F10 1.14(8) 2_657 ?
F13 F11 1.24(9) 2_657 ?
F13 F13 1.67(7) 2_657 ?
F13 F8 1.77(6) 2_657 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 Au1 P1 177.53(16) . . ?
C12 Au1 Au1 75.64(16) . 2_556 ?
P1 Au1 Au1 106.70(3) . 2_556 ?
C5 Co1 C4 40.7(8) . . ?
C5 Co1 C8 149.7(9) . . ?
C4 Co1 C8 117.1(6) . . ?
C5 Co1 C9 117.7(7) . . ?
C4 Co1 C9 110.8(5) . . ?
C8 Co1 C9 41.1(3) . . ?
C5 Co1 C3 68.3(7) . . ?
C4 Co1 C3 40.1(7) . . ?
C8 Co1 C3 108.3(5) . . ?
C9 Co1 C3 132.0(6) . . ?
C5 Co1 C6 130.6(8) . . ?
C4 Co1 C6 170.5(8) . . ?
C8 Co1 C6 69.1(3) . . ?
C9 Co1 C6 68.6(3) . . ?
C3 Co1 C6 147.2(6) . . ?
C5 Co1 C1 41.6(8) . . ?
C4 Co1 C1 68.1(8) . . ?
C8 Co1 C1 167.1(8) . . ?
C9 Co1 C1 150.6(7) . . ?
C3 Co1 C1 67.3(7) . . ?
C6 Co1 C1 107.6(6) . . ?
C5 Co1 C7 168.7(9) . . ?
C4 Co1 C7 148.6(8) . . ?
C8 Co1 C7 41.0(3) . . ?
C9 Co1 C7 68.5(3) . . ?
C3 Co1 C7 115.5(5) . . ?
C6 Co1 C7 40.7(3) . . ?
C1 Co1 C7 128.6(7) . . ?
C5 Co1 C2 68.8(7) . . ?
C4 Co1 C2 67.3(7) . . ?
C8 Co1 C2 128.8(5) . . ?
C9 Co1 C2 168.6(6) . . ?
C3 Co1 C2 39.4(7) . . ?
C6 Co1 C2 115.3(5) . . ?
C1 Co1 C2 40.2(7) . . ?
C7 Co1 C2 106.9(5) . . ?
C5 Co1 C3A 54.4(8) . . ?
C4 Co1 C3A 16.9(7) . . ?
C8 Co1 C3A 109.7(5) . . ?
C9 Co1 C3A 116.3(6) . . ?
C3 Co1 C3A 24.7(5) . . ?
C6 Co1 C3A 171.7(7) . . ?
C1 Co1 C3A 71.7(7) . . ?
C7 Co1 C3A 133.2(7) . . ?
C2 Co1 C3A 58.6(7) . . ?
C5 Co1 C10 108.8(6) . . ?
C4 Co1 C10 132.4(7) . . ?
C8 Co1 C10 69.6(2) . . ?
C9 Co1 C10 41.0(2) . . ?
C3 Co1 C10 171.1(6) . . ?
C6 Co1 C10 41.0(2) . . ?
C1 Co1 C10 116.6(6) . . ?
C7 Co1 C10 69.0(2) . . ?
C2 Co1 C10 148.5(6) . . ?
C3A Co1 C10 146.9(7) . . ?
C5 Co1 C1A 51.9(8) . . ?
C4 Co1 C1A 69.8(7) . . ?
C8 Co1 C1A 153.7(7) . . ?
C9 Co1 C1A 164.2(7) . . ?
C3 Co1 C1A 59.1(6) . . ?
C6 Co1 C1A 108.0(5) . . ?
C1 Co1 C1A 13.8(7) . . ?
C7 Co1 C1A 119.7(6) . . ?
C2 Co1 C1A 27.0(5) . . ?
C3A Co1 C1A 69.1(7) . . ?
C10 Co1 C1A 126.4(6) . . ?
C101 P1 C301 106.7(2) . . ?
C101 P1 C201 105.8(2) . . ?
C301 P1 C201 103.9(2) . . ?
C101 P1 Au1 112.20(15) . . ?
C301 P1 Au1 112.86(15) . . ?
C201 P1 Au1 114.55(15) . . ?
C7 C6 C10 109.0(6) . . ?
C7 C6 Co1 70.0(4) . . ?
C10 C6 Co1 70.4(3) . . ?
C7 C6 H6 125.5 . . ?
C10 C6 H6 125.5 . . ?
Co1 C6 H6 125.7 . . ?
C6 C7 C8 108.2(5) . . ?
C6 C7 Co1 69.3(3) . . ?
C8 C7 Co1 68.9(4) . . ?
C6 C7 H7 125.9 . . ?
C8 C7 H7 125.9 . . ?
Co1 C7 H7 127.5 . . ?
C9 C8 C7 107.3(6) . . ?
C9 C8 Co1 69.7(3) . . ?
C7 C8 Co1 70.1(4) . . ?
C9 C8 H8 126.3 . . ?
C7 C8 H8 126.3 . . ?
Co1 C8 H8 125.4 . . ?
C8 C9 C10 109.4(5) . . ?
C8 C9 Co1 69.2(3) . . ?
C10 C9 Co1 70.4(3) . . ?
C8 C9 H9 125.3 . . ?
C10 C9 H9 125.3 . . ?
Co1 C9 H9 126.6 . . ?
C9 C10 C6 106.1(5) . . ?
C9 C10 C11 126.6(5) . . ?
C6 C10 C11 127.1(5) . . ?
C9 C10 Co1 68.6(3) . . ?
C6 C10 Co1 68.6(3) . . ?
C11 C10 Co1 123.7(4) . . ?
C12 C11 C10 178.3(6) . . ?
C11 C12 Au1 176.0(5) . . ?
C106 C101 C102 119.2(4) . . ?
C106 C101 P1 123.1(4) . . ?
C102 C101 P1 117.6(4) . . ?
C103 C102 C101 120.0(5) . . ?
C103 C102 H102 120.0 . . ?
C101 C102 H102 120.0 . . ?
C102 C103 C104 120.3(5) . . ?
C102 C103 H103 119.9 . . ?
C104 C103 H103 119.9 . . ?
C105 C104 C103 120.3(5) . . ?
C105 C104 H104 119.9 . . ?
C103 C104 H104 119.9 . . ?
C104 C105 C106 120.0(5) . . ?
C104 C105 H105 120.0 . . ?
C106 C105 H105 120.0 . . ?
C101 C106 C105 120.2(5) . . ?
C101 C106 H106 119.9 . . ?
C105 C106 H106 119.9 . . ?
C206 C201 C202 118.7(4) . . ?
C206 C201 P1 123.7(4) . . ?
C202 C201 P1 117.6(3) . . ?
C201 C202 C203 120.2(5) . . ?
C201 C202 H202 119.9 . . ?
C203 C202 H202 119.9 . . ?
C204 C203 C202 120.8(5) . . ?
C204 C203 H203 119.6 . . ?
C202 C203 H203 119.6 . . ?
C205 C204 C203 119.1(5) . . ?
C205 C204 H204 120.5 . . ?
C203 C204 H204 120.5 . . ?
C204 C205 C206 121.2(5) . . ?
C204 C205 H205 119.4 . . ?
C206 C205 H205 119.4 . . ?
C201 C206 C205 119.9(5) . . ?
C201 C206 H206 120.0 . . ?
C205 C206 H206 120.0 . . ?
C306 C301 C302 119.1(4) . . ?
C306 C301 P1 121.3(4) . . ?
C302 C301 P1 119.6(3) . . ?
C303 C302 C301 119.8(5) . . ?
C303 C302 H302 120.1 . . ?
C301 C302 H302 120.1 . . ?
C304 C303 C302 120.6(5) . . ?
C304 C303 H303 119.7 . . ?
C302 C303 H303 119.7 . . ?
C303 C304 C305 120.1(5) . . ?
C303 C304 H304 120.0 . . ?
C305 C304 H304 120.0 . . ?
C304 C305 C306 120.6(5) . . ?
C304 C305 H305 119.7 . . ?
C306 C305 H305 119.7 . . ?
C305 C306 C301 119.8(5) . . ?
C305 C306 H306 120.1 . . ?
C301 C306 H306 120.1 . . ?
C2 C1 C5 107.4(16) . . ?
C2 C1 Co1 70.4(10) . . ?
C5 C1 Co1 67.7(11) . . ?
C2 C1 H1 126.3 . . ?
C5 C1 H1 126.3 . . ?
Co1 C1 H1 127.0 . . ?
C3 C2 C1 108.2(14) . . ?
C3 C2 Co1 69.7(9) . . ?
C1 C2 Co1 69.3(9) . . ?
C3 C2 H2 125.9 . . ?
C1 C2 H2 125.9 . . ?
Co1 C2 H2 126.7 . . ?
C2 C3 C4 109.0(14) . . ?
C2 C3 Co1 70.9(9) . . ?
C4 C3 Co1 69.3(9) . . ?
C2 C3 H3 125.5 . . ?
C4 C3 H3 125.5 . . ?
Co1 C3 H3 125.9 . . ?
C3 C4 C5 108.7(16) . . ?
C3 C4 Co1 70.6(9) . . ?
C5 C4 Co1 68.8(11) . . ?
C3 C4 H4 125.7 . . ?
C5 C4 H4 125.7 . . ?
Co1 C4 H4 126.5 . . ?
C4 C5 C1 106.8(18) . . ?
C4 C5 Co1 70.5(11) . . ?
C1 C5 Co1 70.7(11) . . ?
C4 C5 H5 126.6 . . ?
C1 C5 H5 126.6 . . ?
Co1 C5 H5 123.8 . . ?
C2A C1A C5A 105.1(14) . . ?
C2A C1A Co1 71.1(10) . . ?
C5A C1A Co1 70.8(8) . . ?
C2A C1A H1A 127.5 . . ?
C5A C1A H1A 127.5 . . ?
Co1 C1A H1A 122.4 . . ?
C1A C2A C3A 112.0(18) . . ?
C1A C2A Co1 69.6(10) . . ?
C3A C2A Co1 68.6(10) . . ?
C1A C2A H2A 124.0 . . ?
C3A C2A H2A 124.0 . . ?
Co1 C2A H2A 129.7 . . ?
C2A C3A C4A 105.5(14) . . ?
C2A C3A Co1 71.3(11) . . ?
C4A C3A Co1 71.7(8) . . ?
C2A C3A H3A 127.2 . . ?
C4A C3A H3A 127.2 . . ?
Co1 C3A H3A 121.7 . . ?
C5A C4A C3A 107.4(11) . . ?
C5A C4A Co1 69.8(6) . . ?
C3A C4A Co1 67.6(8) . . ?
C5A C4A H4A 126.3 . . ?
C3A C4A H4A 126.3 . . ?
Co1 C4A H4A 127.9 . . ?
C4A C5A C1A 109.2(11) . . ?
C4A C5A Co1 70.5(6) . . ?
C1A C5A Co1 68.5(8) . . ?
C4A C5A H5A 125.4 . . ?
C1A C5A H5A 125.4 . . ?
Co1 C5A H5A 127.1 . . ?
F1 P2 F1 95.5(7) 2_556 . ?
F1 P2 F2 90.1(3) 2_556 2_556 ?
F1 P2 F2 91.5(3) . 2_556 ?
F1 P2 F2 91.5(3) 2_556 . ?
F1 P2 F2 90.1(3) . . ?
F2 P2 F2 177.7(4) 2_556 . ?
F1 P2 F3 173.9(4) 2_556 . ?
F1 P2 F3 90.3(4) . . ?
F2 P2 F3 88.1(3) 2_556 . ?
F2 P2 F3 90.2(3) . . ?
F1 P2 F3 90.3(4) 2_556 2_556 ?
F1 P2 F3 173.9(4) . 2_556 ?
F2 P2 F3 90.2(3) 2_556 2_556 ?
F2 P2 F3 88.1(3) . 2_556 ?
F3 P2 F3 83.9(5) . 2_556 ?
F11 P3 F11 170(8) 2_657 . ?
F11 P3 F8 100(3) 2_657 . ?
F11 P3 F8 80(3) . . ?
F11 P3 F8 80(3) 2_657 2_657 ?
F11 P3 F8 100(3) . 2_657 ?
F8 P3 F8 176(5) . 2_657 ?
F11 P3 F12 115(5) 2_657 . ?
F11 P3 F12 75(4) . . ?
F8 P3 F12 92(4) . . ?
F8 P3 F12 91(3) 2_657 . ?
F11 P3 F12 75(4) 2_657 2_657 ?
F11 P3 F12 115(5) . 2_657 ?
F8 P3 F12 91(3) . 2_657 ?
F8 P3 F12 92(4) 2_657 2_657 ?
F12 P3 F12 41(4) . 2_657 ?
F11 P3 F13 119(5) 2_657 2_657 ?
F11 P3 F13 51(3) . 2_657 ?
F8 P3 F13 76(3) . 2_657 ?
F8 P3 F13 101(3) 2_657 2_657 ?
F12 P3 F13 126(3) . 2_657 ?
F12 P3 F13 162(3) 2_657 2_657 ?
F11 P3 F13 51(3) 2_657 . ?
F11 P3 F13 119(5) . . ?
F8 P3 F13 101(3) . . ?
F8 P3 F13 76(3) 2_657 . ?
F12 P3 F13 162(3) . . ?
F12 P3 F13 126(3) 2_657 . ?
F13 P3 F13 70(3) 2_657 . ?
F11 P3 F7 40(3) 2_657 2_657 ?
F11 P3 F7 137.4(19) . 2_657 ?
F8 P3 F7 60(2) . 2_657 ?
F8 P3 F7 120(2) 2_657 2_657 ?
F12 P3 F7 116(3) . 2_657 ?
F12 P3 F7 81(2) 2_657 2_657 ?
F13 P3 F7 102.6(18) 2_657 2_657 ?
F13 P3 F7 62.7(17) . 2_657 ?
F11 P3 F7 137.4(19) 2_657 . ?
F11 P3 F7 40(3) . . ?
F8 P3 F7 120(2) . . ?
F8 P3 F7 60(2) 2_657 . ?
F12 P3 F7 81(2) . . ?
F12 P3 F7 116(3) 2_657 . ?
F13 P3 F7 62.7(17) 2_657 . ?
F13 P3 F7 102.6(18) . . ?
F7 P3 F7 163(2) 2_657 . ?
F11 P3 F4 95(4) 2_657 . ?
F11 P3 F4 95(4) . . ?
F8 P3 F4 92(2) . . ?
F8 P3 F4 92(2) 2_657 . ?
F12 P3 F4 20(2) . . ?
F12 P3 F4 20(2) 2_657 . ?
F13 P3 F4 145.2(13) 2_657 . ?
F13 P3 F4 145.2(13) . . ?
F7 P3 F4 98.5(10) 2_657 . ?
F7 P3 F4 98.5(10) . . ?
F11 P3 F6 50(3) 2_657 . ?
F11 P3 F6 130(3) . . ?
F8 P3 F6 150(2) . . ?
F8 P3 F6 30(2) 2_657 . ?
F12 P3 F6 101(3) . . ?
F12 P3 F6 81(3) 2_657 . ?
F13 P3 F6 116(2) 2_657 . ?
F13 P3 F6 62.1(19) . . ?
F7 P3 F6 90.3(12) 2_657 . ?
F7 P3 F6 89.4(11) . . ?
F4 P3 F6 91.0(14) . . ?
F9 F8 P3 110(10) 2_657 . ?
F9 F8 F13 141(10) 2_657 2_657 ?
P3 F8 F13 54(2) . 2_657 ?
F8 F9 P3 53(10) 2_657 . ?
F11 F10 F12 106(4) 2_657 2_657 ?
F11 F10 P3 53(3) 2_657 . ?
F12 F10 P3 55(3) 2_657 . ?
F10 F11 F13 158(7) 2_657 2_657 ?
F10 F11 P3 91(4) 2_657 . ?
F13 F11 P3 68(3) 2_657 . ?
F10 F11 F12 39(4) 2_657 . ?
F13 F11 F12 121(4) 2_657 . ?
P3 F11 F12 54(2) . . ?
F12 F12 F10 154(3) 2_657 2_657 ?
F12 F12 P3 70(2) 2_657 . ?
F10 F12 P3 85(4) 2_657 . ?
F12 F12 F11 120(4) 2_657 . ?
F10 F12 F11 35(3) 2_657 . ?
P3 F12 F11 51(3) . . ?
F11 F13 P3 61(2) 2_657 . ?
F11 F13 F13 115(3) 2_657 2_657 ?
P3 F13 F13 55.2(13) . 2_657 ?
F11 F13 F8 71(4) 2_657 2_657 ?
P3 F13 F8 50.5(18) . 2_657 ?
F13 F13 F8 80(3) 2_657 2_657 ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         1.597
_refine_diff_density_min         -1.408
_refine_diff_density_rms         0.094

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1436183'
_audit_update_record             
;
2015-11-10 deposited with the CCDC.
2015-12-22 downloaded from the CCDC.
;

_vrf_PLAT057_3                   
;
PROBLEM: Correction for Absorption Required   RT(exp) ...       1.66       
RESPONSE:correction in a multiscan-like manner,
         see: _exptl_special_details
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H18 Au Co2 F6 P'
_chemical_formula_weight         766.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.3787(6)
_cell_length_b                   13.9151(6)
_cell_length_c                   15.1660(7)
_cell_angle_alpha                117.297(3)
_cell_angle_beta                 92.968(4)
_cell_angle_gamma                106.865(3)
_cell_volume                     2343.68(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    233(2)
_cell_measurement_reflns_used    68650
_cell_measurement_theta_min      1.0
_cell_measurement_theta_max      26.0

_exptl_crystal_description       prism
_exptl_crystal_colour            brown
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.11
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.171
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1456
_exptl_absorpt_coefficient_mu    7.770
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
All data sets were measured with several scans to increase the number of
redundant reflections. In our experience this method of averaging redundant
reflections replaces in a good approximation semi-empirical absorptions
methods (absorption correction programs like SORTAV lead to no better data
sets).
;

_diffrn_ambient_temperature      233(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            16455
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_sigmaI/netI    0.0429
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.93
_diffrn_reflns_theta_max         25.50
_reflns_number_total             8596
_reflns_number_gt                7215
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       COLLECT
_computing_cell_refinement       'DENZO and SCALEPACK'
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Two Au-complexes into the asymmetric unit. One anion PF6 a in general
 position, two with P2 and P3 into a special position (symmetry center).
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0579P)²+4.8109P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8596
_refine_ls_number_parameters     616
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0387
_refine_ls_wR_factor_ref         0.1057
_refine_ls_wR_factor_gt          0.1001
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.08676(2) 0.23460(2) 0.47595(2) 0.04686(10) Uani 1 1 d . . .
Au2 Au 0.252609(18) 0.46128(2) 0.930091(19) 0.03926(9) Uani 1 1 d . . .
Co1 Co 0.29405(6) 0.09498(7) 0.74124(6) 0.03543(19) Uani 1 1 d . . .
Co2 Co -0.12915(7) 0.42414(7) 0.27008(6) 0.0375(2) Uani 1 1 d . . .
Co3 Co 0.65623(7) 0.64598(7) 0.79175(7) 0.0407(2) Uani 1 1 d . . .
Co4 Co -0.21133(7) 0.15024(8) 0.77566(7) 0.0419(2) Uani 1 1 d . . .
P3 P 0.5000 0.0000 1.0000 0.0369(5) Uani 1 2 d S . .
C1 C 0.4166(6) 0.1020(7) 0.6706(6) 0.060(2) Uani 1 1 d . . .
H1 H 0.4109 0.0573 0.6004 0.072 Uiso 1 1 calc . . .
C2 C 0.4370(6) 0.0709(6) 0.7436(6) 0.0538(18) Uani 1 1 d . . .
H2 H 0.4475 0.0020 0.7306 0.065 Uiso 1 1 calc . . .
C3 C 0.4392(5) 0.1599(7) 0.8393(5) 0.0509(17) Uani 1 1 d . . .
H3 H 0.4519 0.1610 0.9014 0.061 Uiso 1 1 calc . . .
C4 C 0.4188(5) 0.2491(6) 0.8262(5) 0.0466(16) Uani 1 1 d . . .
H4 H 0.4146 0.3184 0.8773 0.056 Uiso 1 1 calc . . .
C5 C 0.4062(6) 0.2115(7) 0.7200(6) 0.060(2) Uani 1 1 d . . .
H5 H 0.3932 0.2526 0.6886 0.072 Uiso 1 1 calc . . .
C6 C 0.1632(5) -0.0328(6) 0.6317(5) 0.0477(16) Uani 1 1 d . . .
H6 H 0.1623 -0.0820 0.5635 0.057 Uiso 1 1 calc . . .
C7 C 0.1797(6) -0.0541(6) 0.7123(6) 0.0555(19) Uani 1 1 d . . .
H7 H 0.1922 -0.1193 0.7073 0.067 Uiso 1 1 calc . . .
C8 C 0.1742(6) 0.0386(7) 0.8016(6) 0.0541(19) Uani 1 1 d . . .
H8 H 0.1811 0.0453 0.8663 0.065 Uiso 1 1 calc . . .
C9 C 0.1568(5) 0.1192(6) 0.7783(5) 0.0470(16) Uani 1 1 d . . .
H9 H 0.1517 0.1902 0.8247 0.056 Uiso 1 1 calc . . .
C10 C 0.1481(5) 0.0745(6) 0.6697(5) 0.0445(15) Uani 1 1 d . . .
C11 C 0.1339(5) 0.1285(6) 0.6134(6) 0.0510(17) Uani 1 1 d . . .
C12 C 0.1171(5) 0.1684(6) 0.5609(5) 0.0488(17) Uani 1 1 d . . .
C21 C -0.2608(6) 0.2808(6) 0.2203(6) 0.0565(19) Uani 1 1 d . . .
H21 H -0.2658 0.2045 0.1759 0.068 Uiso 1 1 calc . . .
C22 C -0.2818(6) 0.3572(7) 0.1914(6) 0.059(2) Uani 1 1 d . . .
H22 H -0.3037 0.3404 0.1244 0.071 Uiso 1 1 calc . . .
C23 C -0.2642(6) 0.4632(7) 0.2802(6) 0.0578(19) Uani 1 1 d . . .
H23 H -0.2722 0.5294 0.2829 0.069 Uiso 1 1 calc . . .
C24 C -0.2328(6) 0.4521(6) 0.3637(5) 0.0522(17) Uani 1 1 d . . .
H24 H -0.2158 0.5101 0.4322 0.063 Uiso 1 1 calc . . .
C25 C -0.2307(6) 0.3391(6) 0.3280(6) 0.0535(18) Uani 1 1 d . . .
H25 H -0.2129 0.3087 0.3680 0.064 Uiso 1 1 calc . . .
C26 C -0.0129(5) 0.3748(6) 0.2001(5) 0.0472(16) Uani 1 1 d . . .
H26 H -0.0206 0.2999 0.1493 0.057 Uiso 1 1 calc . . .
C27 C -0.0315(6) 0.4597(7) 0.1826(6) 0.0534(18) Uani 1 1 d . . .
H27 H -0.0539 0.4515 0.1190 0.064 Uiso 1 1 calc . . .
C28 C -0.0104(5) 0.5591(6) 0.2780(6) 0.0510(17) Uani 1 1 d . . .
H28 H -0.0154 0.6296 0.2891 0.061 Uiso 1 1 calc . . .
C29 C 0.0194(5) 0.5350(6) 0.3538(5) 0.0482(16) Uani 1 1 d . . .
H29 H 0.0365 0.5863 0.4243 0.058 Uiso 1 1 calc . . .
C30 C 0.0192(5) 0.4192(6) 0.3060(5) 0.0419(15) Uani 1 1 d . . .
C31 C 0.0398(5) 0.3583(6) 0.3550(5) 0.0491(17) Uani 1 1 d . . .
C32 C 0.0564(5) 0.3058(6) 0.3954(5) 0.0480(16) Uani 1 1 d . . .
C41 C 0.5584(9) 0.6124(9) 0.6673(7) 0.083(3) Uani 1 1 d . . .
H41 H 0.5001 0.5436 0.6259 0.099 Uiso 1 1 calc . . .
C42 C 0.6663(9) 0.6360(9) 0.6554(7) 0.078(3) Uani 1 1 d . . .
H42 H 0.6926 0.5857 0.6047 0.094 Uiso 1 1 calc . . .
C43 C 0.7258(7) 0.7488(8) 0.7338(7) 0.068(2) Uani 1 1 d . . .
H43 H 0.7994 0.7876 0.7439 0.081 Uiso 1 1 calc . . .
C44 C 0.6584(8) 0.7933(7) 0.7934(7) 0.068(2) Uani 1 1 d . . .
H44 H 0.6783 0.8666 0.8517 0.082 Uiso 1 1 calc . . .
C45 C 0.5558(7) 0.7105(9) 0.7520(8) 0.075(3) Uani 1 1 d . . .
H45 H 0.4944 0.7194 0.7771 0.090 Uiso 1 1 calc . . .
C46 C 0.6264(6) 0.4989(5) 0.8007(6) 0.0504(17) Uani 1 1 d . . .
H46 H 0.5821 0.4242 0.7503 0.061 Uiso 1 1 calc . . .
C47 C 0.7355(6) 0.5495(7) 0.8075(6) 0.0584(19) Uani 1 1 d . . .
H47 H 0.7768 0.5149 0.7633 0.070 Uiso 1 1 calc . . .
C48 C 0.7728(5) 0.6629(7) 0.8934(6) 0.0538(18) Uani 1 1 d . . .
H48 H 0.8430 0.7166 0.9161 0.065 Uiso 1 1 calc . . .
C49 C 0.6858(6) 0.6800(6) 0.9381(5) 0.0490(17) Uani 1 1 d . . .
H49 H 0.6881 0.7479 0.9961 0.059 Uiso 1 1 calc . . .
C50 C 0.5930(5) 0.5781(5) 0.8816(5) 0.0422(15) Uani 1 1 d . . .
C51 C 0.4884(5) 0.5556(6) 0.9022(5) 0.0431(15) Uani 1 1 d . . .
C52 C 0.4013(5) 0.5265(6) 0.9195(5) 0.0410(14) Uani 1 1 d . . .
C61 C -0.1729(9) 0.0107(9) 0.6927(8) 0.086(3) Uani 1 1 d . . .
H61 H -0.1370 -0.0214 0.7205 0.103 Uiso 1 1 calc . . .
C62 C -0.2846(9) -0.0195(8) 0.6677(7) 0.084(3) Uani 1 1 d . . .
H62 H -0.3365 -0.0769 0.6739 0.101 Uiso 1 1 calc . . .
C63 C -0.3049(7) 0.0523(9) 0.6314(6) 0.073(3) Uani 1 1 d . . .
H63 H -0.3726 0.0512 0.6097 0.088 Uiso 1 1 calc . . .
C64 C -0.2045(7) 0.1260(8) 0.6338(6) 0.068(2) Uani 1 1 d . . .
H64 H -0.1935 0.1836 0.6153 0.081 Uiso 1 1 calc . . .
C65 C -0.1246(7) 0.0973(8) 0.6689(7) 0.072(3) Uani 1 1 d . . .
H65 H -0.0507 0.1306 0.6753 0.086 Uiso 1 1 calc . . .
C66 C -0.1632(7) 0.2019(8) 0.9240(6) 0.069(2) Uani 1 1 d . . .
H66 H -0.1336 0.1629 0.9486 0.082 Uiso 1 1 calc . . .
C67 C -0.2752(6) 0.1824(9) 0.8984(6) 0.082(3) Uani 1 1 d . . .
H67 H -0.3318 0.1285 0.9044 0.099 Uiso 1 1 calc . . .
C68 C -0.2859(6) 0.2569(8) 0.8633(7) 0.075(3) Uani 1 1 d . . .
H68 H -0.3503 0.2626 0.8423 0.090 Uiso 1 1 calc . . .
C69 C -0.1836(6) 0.3206(6) 0.8652(6) 0.0560(19) Uani 1 1 d . . .
H69 H -0.1680 0.3753 0.8432 0.067 Uiso 1 1 calc . . .
C70 C -0.1061(5) 0.2918(6) 0.9049(5) 0.0484(17) Uani 1 1 d . . .
C71 C 0.0066(5) 0.3406(6) 0.9189(5) 0.0463(16) Uani 1 1 d . . .
C72 C 0.1004(5) 0.3885(5) 0.9291(5) 0.0402(14) Uani 1 1 d . . .
P1 P 0.61593(19) 0.25155(17) 0.51212(16) 0.0586(5) Uani 1 1 d . . .
P2 P 1.0000 1.0000 1.0000 0.0502(6) Uani 1 2 d S . .
F1 F 0.6664(5) 0.2878(5) 0.6264(4) 0.0949(18) Uani 1 1 d . . .
F2 F 0.5687(5) 0.2139(5) 0.4012(4) 0.1002(19) Uani 1 1 d . . .
F3 F 0.6793(6) 0.3757(4) 0.5320(5) 0.113(2) Uani 1 1 d . . .
F4 F 0.5522(5) 0.1269(4) 0.4948(5) 0.104(2) Uani 1 1 d . . .
F5 F 0.5212(5) 0.2949(6) 0.5528(5) 0.111(2) Uani 1 1 d . . .
F6 F 0.7125(5) 0.2101(5) 0.4758(4) 0.0902(16) Uani 1 1 d . . .
F7 F 1.0108(7) 1.0996(7) 1.1050(6) 0.186(5) Uani 1 1 d . . .
F8 F 1.1235(4) 1.0327(6) 1.0143(5) 0.112(2) Uani 1 1 d . . .
F9 F 0.9866(7) 0.9174(9) 1.0438(8) 0.170(4) Uani 1 1 d . . .
F10 F 0.5022(5) 0.0360(4) 1.1155(3) 0.0768(15) Uani 1 1 d . . .
F11 F 0.6218(4) 0.0142(5) 1.0192(4) 0.0833(15) Uani 1 1 d . . .
F12 F 0.5337(4) 0.1323(3) 1.0290(3) 0.0681(13) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C12 1.981(7) . ?
Au1 C32 1.982(7) . ?
Au2 C52 1.981(6) . ?
Au2 C72 1.990(6) . ?
Co1 C1 2.008(7) . ?
Co1 C7 2.023(7) . ?
Co1 C9 2.023(6) . ?
Co1 C8 2.025(7) . ?
Co1 C5 2.026(7) . ?
Co1 C2 2.037(7) . ?
Co1 C6 2.042(6) . ?
Co1 C4 2.052(6) . ?
Co1 C10 2.060(7) . ?
Co1 C3 2.062(7) . ?
Co2 C22 2.021(7) . ?
Co2 C21 2.023(7) . ?
Co2 C24 2.024(7) . ?
Co2 C29 2.026(6) . ?
Co2 C28 2.026(6) . ?
Co2 C23 2.027(8) . ?
Co2 C27 2.029(7) . ?
Co2 C26 2.034(7) . ?
Co2 C25 2.040(7) . ?
Co2 C30 2.060(7) . ?
Co3 C48 2.017(7) . ?
Co3 C41 2.018(9) . ?
Co3 C47 2.019(8) . ?
Co3 C45 2.022(8) . ?
Co3 C42 2.023(8) . ?
Co3 C44 2.031(8) . ?
Co3 C49 2.035(7) . ?
Co3 C46 2.037(7) . ?
Co3 C43 2.038(8) . ?
Co3 C50 2.074(6) . ?
Co4 C67 2.005(8) . ?
Co4 C61 2.006(10) . ?
Co4 C69 2.021(8) . ?
Co4 C66 2.023(8) . ?
Co4 C65 2.027(8) . ?
Co4 C64 2.031(7) . ?
Co4 C68 2.038(9) . ?
Co4 C62 2.040(9) . ?
Co4 C63 2.051(8) . ?
Co4 C70 2.066(7) . ?
P3 F11 1.578(5) . ?
P3 F11 1.578(5) 2_657 ?
P3 F10 1.582(4) 2_657 ?
P3 F10 1.582(4) . ?
P3 F12 1.595(4) 2_657 ?
P3 F12 1.595(4) . ?
C1 C2 1.401(11) . ?
C1 C5 1.411(12) . ?
C2 C3 1.403(10) . ?
C3 C4 1.441(10) . ?
C4 C5 1.430(11) . ?
C6 C7 1.405(10) . ?
C6 C10 1.414(10) . ?
C7 C8 1.401(11) . ?
C8 C9 1.395(10) . ?
C9 C10 1.452(10) . ?
C10 C11 1.409(10) . ?
C11 C12 1.205(10) . ?
C21 C22 1.411(11) . ?
C21 C25 1.420(10) . ?
C22 C23 1.410(11) . ?
C23 C24 1.403(11) . ?
C24 C25 1.418(11) . ?
C26 C27 1.407(10) . ?
C26 C30 1.417(9) . ?
C27 C28 1.408(11) . ?
C28 C29 1.407(10) . ?
C29 C30 1.431(10) . ?
C30 C31 1.427(10) . ?
C31 C32 1.205(10) . ?
C41 C45 1.392(14) . ?
C41 C42 1.424(14) . ?
C42 C43 1.406(13) . ?
C43 C44 1.382(12) . ?
C44 C45 1.391(13) . ?
C46 C47 1.399(10) . ?
C46 C50 1.423(10) . ?
C47 C48 1.423(11) . ?
C48 C49 1.402(11) . ?
C49 C50 1.428(9) . ?
C50 C51 1.426(9) . ?
C51 C52 1.203(9) . ?
C61 C65 1.405(14) . ?
C61 C62 1.409(15) . ?
C62 C63 1.422(14) . ?
C63 C64 1.421(12) . ?
C64 C65 1.403(13) . ?
C66 C70 1.428(10) . ?
C66 C67 1.440(13) . ?
C67 C68 1.402(14) . ?
C68 C69 1.389(11) . ?
C69 C70 1.412(11) . ?
C70 C71 1.421(9) . ?
C71 C72 1.200(9) . ?
P1 F2 1.548(6) . ?
P1 F3 1.562(5) . ?
P1 F4 1.583(5) . ?
P1 F6 1.588(6) . ?
P1 F5 1.592(6) . ?
P1 F1 1.610(6) . ?
P2 F7 1.521(6) 2_777 ?
P2 F7 1.521(6) . ?
P2 F9 1.545(7) . ?
P2 F9 1.545(7) 2_777 ?
P2 F8 1.555(6) 2_777 ?
P2 F8 1.555(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 Au1 C32 177.9(3) . . ?
C52 Au2 C72 175.6(3) . . ?
C1 Co1 C7 123.8(3) . . ?
C1 Co1 C9 155.5(3) . . ?
C7 Co1 C9 68.3(3) . . ?
C1 Co1 C8 161.6(4) . . ?
C7 Co1 C8 40.5(3) . . ?
C9 Co1 C8 40.3(3) . . ?
C1 Co1 C5 40.9(3) . . ?
C7 Co1 C5 160.7(4) . . ?
C9 Co1 C5 121.0(3) . . ?
C8 Co1 C5 156.8(4) . . ?
C1 Co1 C2 40.5(3) . . ?
C7 Co1 C2 107.4(3) . . ?
C9 Co1 C2 163.1(3) . . ?
C8 Co1 C2 126.0(3) . . ?
C5 Co1 C2 68.5(3) . . ?
C1 Co1 C6 105.9(3) . . ?
C7 Co1 C6 40.4(3) . . ?
C9 Co1 C6 68.5(3) . . ?
C8 Co1 C6 68.0(3) . . ?
C5 Co1 C6 123.9(3) . . ?
C2 Co1 C6 119.6(3) . . ?
C1 Co1 C4 69.0(3) . . ?
C7 Co1 C4 156.8(3) . . ?
C9 Co1 C4 108.5(3) . . ?
C8 Co1 C4 122.1(3) . . ?
C5 Co1 C4 41.0(3) . . ?
C2 Co1 C4 68.6(3) . . ?
C6 Co1 C4 161.8(3) . . ?
C1 Co1 C10 118.7(3) . . ?
C7 Co1 C10 68.4(3) . . ?
C9 Co1 C10 41.7(3) . . ?
C8 Co1 C10 68.7(3) . . ?
C5 Co1 C10 106.5(3) . . ?
C2 Co1 C10 153.7(3) . . ?
C6 Co1 C10 40.3(3) . . ?
C4 Co1 C10 125.5(3) . . ?
C1 Co1 C3 68.0(3) . . ?
C7 Co1 C3 121.3(3) . . ?
C9 Co1 C3 127.0(3) . . ?
C8 Co1 C3 109.7(3) . . ?
C5 Co1 C3 68.4(3) . . ?
C2 Co1 C3 40.0(3) . . ?
C6 Co1 C3 154.9(3) . . ?
C4 Co1 C3 41.0(3) . . ?
C10 Co1 C3 164.2(3) . . ?
C22 Co2 C21 40.8(3) . . ?
C22 Co2 C24 68.3(3) . . ?
C21 Co2 C24 68.5(3) . . ?
C22 Co2 C29 163.0(3) . . ?
C21 Co2 C29 154.8(3) . . ?
C24 Co2 C29 107.6(3) . . ?
C22 Co2 C28 125.9(3) . . ?
C21 Co2 C28 163.1(3) . . ?
C24 Co2 C28 120.4(3) . . ?
C29 Co2 C28 40.6(3) . . ?
C22 Co2 C23 40.8(3) . . ?
C21 Co2 C23 68.8(3) . . ?
C24 Co2 C23 40.5(3) . . ?
C29 Co2 C23 125.5(3) . . ?
C28 Co2 C23 107.9(3) . . ?
C22 Co2 C27 107.8(3) . . ?
C21 Co2 C27 125.6(3) . . ?
C24 Co2 C27 155.1(3) . . ?
C29 Co2 C27 68.5(3) . . ?
C28 Co2 C27 40.6(3) . . ?
C23 Co2 C27 120.4(3) . . ?
C22 Co2 C26 120.7(3) . . ?
C21 Co2 C26 107.9(3) . . ?
C24 Co2 C26 162.8(3) . . ?
C29 Co2 C26 68.0(3) . . ?
C28 Co2 C26 67.9(3) . . ?
C23 Co2 C26 155.5(3) . . ?
C27 Co2 C26 40.5(3) . . ?
C22 Co2 C25 68.7(3) . . ?
C21 Co2 C25 40.9(3) . . ?
C24 Co2 C25 40.8(3) . . ?
C29 Co2 C25 119.8(3) . . ?
C28 Co2 C25 154.9(3) . . ?
C23 Co2 C25 68.8(3) . . ?
C27 Co2 C25 162.8(3) . . ?
C26 Co2 C25 125.6(3) . . ?
C22 Co2 C30 154.8(3) . . ?
C21 Co2 C30 119.5(3) . . ?
C24 Co2 C30 125.4(3) . . ?
C29 Co2 C30 41.0(3) . . ?
C28 Co2 C30 68.7(3) . . ?
C23 Co2 C30 162.7(3) . . ?
C27 Co2 C30 68.8(3) . . ?
C26 Co2 C30 40.5(3) . . ?
C25 Co2 C30 106.8(3) . . ?
C48 Co3 C41 167.1(4) . . ?
C48 Co3 C47 41.3(3) . . ?
C41 Co3 C47 129.1(4) . . ?
C48 Co3 C45 150.3(4) . . ?
C41 Co3 C45 40.3(4) . . ?
C47 Co3 C45 168.0(4) . . ?
C48 Co3 C42 127.5(4) . . ?
C41 Co3 C42 41.3(4) . . ?
C47 Co3 C42 107.3(4) . . ?
C45 Co3 C42 68.1(4) . . ?
C48 Co3 C44 116.4(4) . . ?
C41 Co3 C44 68.2(4) . . ?
C47 Co3 C44 149.9(4) . . ?
C45 Co3 C44 40.1(4) . . ?
C42 Co3 C44 68.0(4) . . ?
C48 Co3 C49 40.5(3) . . ?
C41 Co3 C49 151.8(4) . . ?
C47 Co3 C49 68.5(3) . . ?
C45 Co3 C49 118.7(4) . . ?
C42 Co3 C49 165.6(4) . . ?
C44 Co3 C49 108.3(3) . . ?
C48 Co3 C46 68.4(3) . . ?
C41 Co3 C46 109.6(4) . . ?
C47 Co3 C46 40.4(3) . . ?
C45 Co3 C46 131.0(4) . . ?
C42 Co3 C46 118.4(4) . . ?
C44 Co3 C46 168.4(3) . . ?
C49 Co3 C46 67.9(3) . . ?
C48 Co3 C43 107.0(3) . . ?
C41 Co3 C43 68.3(4) . . ?
C47 Co3 C43 117.2(3) . . ?
C45 Co3 C43 67.0(4) . . ?
C42 Co3 C43 40.5(4) . . ?
C44 Co3 C43 39.7(4) . . ?
C49 Co3 C43 128.0(3) . . ?
C46 Co3 C43 151.2(3) . . ?
C48 Co3 C50 68.6(3) . . ?
C41 Co3 C50 118.7(4) . . ?
C47 Co3 C50 68.5(3) . . ?
C45 Co3 C50 110.0(3) . . ?
C42 Co3 C50 152.1(4) . . ?
C44 Co3 C50 129.6(3) . . ?
C49 Co3 C50 40.7(3) . . ?
C46 Co3 C50 40.5(3) . . ?
C43 Co3 C50 166.5(3) . . ?
C67 Co4 C61 126.4(5) . . ?
C67 Co4 C69 67.7(4) . . ?
C61 Co4 C69 155.9(4) . . ?
C67 Co4 C66 41.9(4) . . ?
C61 Co4 C66 107.8(4) . . ?
C69 Co4 C66 68.5(4) . . ?
C67 Co4 C65 163.3(5) . . ?
C61 Co4 C65 40.8(4) . . ?
C69 Co4 C65 120.3(4) . . ?
C66 Co4 C65 124.4(4) . . ?
C67 Co4 C64 155.5(4) . . ?
C61 Co4 C64 69.0(4) . . ?
C69 Co4 C64 106.0(4) . . ?
C66 Co4 C64 160.1(3) . . ?
C65 Co4 C64 40.5(4) . . ?
C67 Co4 C68 40.6(4) . . ?
C61 Co4 C68 163.1(4) . . ?
C69 Co4 C68 40.0(3) . . ?
C66 Co4 C68 69.4(4) . . ?
C65 Co4 C68 154.5(5) . . ?
C64 Co4 C68 119.4(4) . . ?
C67 Co4 C62 109.3(4) . . ?
C61 Co4 C62 40.7(4) . . ?
C69 Co4 C62 161.3(4) . . ?
C66 Co4 C62 122.6(4) . . ?
C65 Co4 C62 68.0(4) . . ?
C64 Co4 C62 68.6(4) . . ?
C68 Co4 C62 125.7(4) . . ?
C67 Co4 C63 121.6(4) . . ?
C61 Co4 C63 68.7(4) . . ?
C69 Co4 C63 123.7(4) . . ?
C66 Co4 C63 158.0(4) . . ?
C65 Co4 C63 67.9(4) . . ?
C64 Co4 C63 40.8(3) . . ?
C68 Co4 C63 107.3(4) . . ?
C62 Co4 C63 40.7(4) . . ?
C67 Co4 C70 68.8(3) . . ?
C61 Co4 C70 121.2(4) . . ?
C69 Co4 C70 40.4(3) . . ?
C66 Co4 C70 40.9(3) . . ?
C65 Co4 C70 107.1(3) . . ?
C64 Co4 C70 122.8(3) . . ?
C68 Co4 C70 68.3(3) . . ?
C62 Co4 C70 157.6(4) . . ?
C63 Co4 C70 159.8(4) . . ?
F11 P3 F11 180.000(1) . 2_657 ?
F11 P3 F10 91.0(3) . 2_657 ?
F11 P3 F10 89.0(3) 2_657 2_657 ?
F11 P3 F10 89.0(3) . . ?
F11 P3 F10 91.0(3) 2_657 . ?
F10 P3 F10 180.000(2) 2_657 . ?
F11 P3 F12 90.0(3) . 2_657 ?
F11 P3 F12 90.0(3) 2_657 2_657 ?
F10 P3 F12 89.9(2) 2_657 2_657 ?
F10 P3 F12 90.1(2) . 2_657 ?
F11 P3 F12 90.0(3) . . ?
F11 P3 F12 90.0(3) 2_657 . ?
F10 P3 F12 90.1(2) 2_657 . ?
F10 P3 F12 89.9(2) . . ?
F12 P3 F12 180.000(1) 2_657 . ?
C2 C1 C5 108.7(6) . . ?
C2 C1 Co1 70.8(4) . . ?
C5 C1 Co1 70.2(4) . . ?
C1 C2 C3 108.5(7) . . ?
C1 C2 Co1 68.6(4) . . ?
C3 C2 Co1 71.0(4) . . ?
C2 C3 C4 108.3(6) . . ?
C2 C3 Co1 69.0(4) . . ?
C4 C3 Co1 69.1(4) . . ?
C5 C4 C3 106.4(6) . . ?
C5 C4 Co1 68.5(4) . . ?
C3 C4 Co1 69.9(4) . . ?
C1 C5 C4 108.1(7) . . ?
C1 C5 Co1 68.9(4) . . ?
C4 C5 Co1 70.5(4) . . ?
C7 C6 C10 109.0(6) . . ?
C7 C6 Co1 69.0(4) . . ?
C10 C6 Co1 70.5(4) . . ?
C8 C7 C6 108.3(6) . . ?
C8 C7 Co1 69.9(4) . . ?
C6 C7 Co1 70.5(4) . . ?
C9 C8 C7 108.6(6) . . ?
C9 C8 Co1 69.7(4) . . ?
C7 C8 Co1 69.6(4) . . ?
C8 C9 C10 108.1(6) . . ?
C8 C9 Co1 70.0(4) . . ?
C10 C9 Co1 70.6(4) . . ?
C11 C10 C6 126.2(6) . . ?
C11 C10 C9 127.8(7) . . ?
C6 C10 C9 105.9(6) . . ?
C11 C10 Co1 124.9(5) . . ?
C6 C10 Co1 69.1(4) . . ?
C9 C10 Co1 67.8(4) . . ?
C12 C11 C10 176.1(8) . . ?
C11 C12 Au1 178.7(7) . . ?
C22 C21 C25 108.2(7) . . ?
C22 C21 Co2 69.5(4) . . ?
C25 C21 Co2 70.2(4) . . ?
C23 C22 C21 108.3(7) . . ?
C23 C22 Co2 69.8(4) . . ?
C21 C22 Co2 69.6(4) . . ?
C24 C23 C22 107.7(7) . . ?
C24 C23 Co2 69.6(4) . . ?
C22 C23 Co2 69.4(4) . . ?
C23 C24 C25 109.0(7) . . ?
C23 C24 Co2 69.9(4) . . ?
C25 C24 Co2 70.2(4) . . ?
C24 C25 C21 106.8(6) . . ?
C24 C25 Co2 69.0(4) . . ?
C21 C25 Co2 68.9(4) . . ?
C27 C26 C30 109.8(6) . . ?
C27 C26 Co2 69.5(4) . . ?
C30 C26 Co2 70.7(4) . . ?
C26 C27 C28 107.3(6) . . ?
C26 C27 Co2 69.9(4) . . ?
C28 C27 Co2 69.6(4) . . ?
C29 C28 C27 108.4(6) . . ?
C29 C28 Co2 69.7(4) . . ?
C27 C28 Co2 69.8(4) . . ?
C28 C29 C30 108.7(6) . . ?
C28 C29 Co2 69.7(4) . . ?
C30 C29 Co2 70.8(4) . . ?
C26 C30 C31 127.0(6) . . ?
C26 C30 C29 105.8(6) . . ?
C31 C30 C29 127.0(6) . . ?
C26 C30 Co2 68.8(4) . . ?
C31 C30 Co2 124.2(5) . . ?
C29 C30 Co2 68.2(4) . . ?
C32 C31 C30 179.3(8) . . ?
C31 C32 Au1 173.9(7) . . ?
C45 C41 C42 106.9(8) . . ?
C45 C41 Co3 70.0(5) . . ?
C42 C41 Co3 69.5(5) . . ?
C43 C42 C41 107.1(8) . . ?
C43 C42 Co3 70.3(5) . . ?
C41 C42 Co3 69.2(5) . . ?
C44 C43 C42 108.8(8) . . ?
C44 C43 Co3 69.8(5) . . ?
C42 C43 Co3 69.2(5) . . ?
C43 C44 C45 107.9(9) . . ?
C43 C44 Co3 70.4(5) . . ?
C45 C44 Co3 69.6(5) . . ?
C44 C45 C41 109.3(9) . . ?
C44 C45 Co3 70.3(5) . . ?
C41 C45 Co3 69.7(5) . . ?
C47 C46 C50 109.5(6) . . ?
C47 C46 Co3 69.1(4) . . ?
C50 C46 Co3 71.2(4) . . ?
C46 C47 C48 107.7(7) . . ?
C46 C47 Co3 70.5(4) . . ?
C48 C47 Co3 69.3(4) . . ?
C49 C48 C47 107.7(6) . . ?
C49 C48 Co3 70.5(4) . . ?
C47 C48 Co3 69.4(4) . . ?
C48 C49 C50 109.2(6) . . ?
C48 C49 Co3 69.0(4) . . ?
C50 C49 Co3 71.1(4) . . ?
C46 C50 C51 125.7(6) . . ?
C46 C50 C49 105.9(6) . . ?
C51 C50 C49 128.3(6) . . ?
C46 C50 Co3 68.4(4) . . ?
C51 C50 Co3 129.6(5) . . ?
C49 C50 Co3 68.2(4) . . ?
C52 C51 C50 173.1(7) . . ?
C51 C52 Au2 172.7(6) . . ?
C65 C61 C62 107.9(10) . . ?
C65 C61 Co4 70.4(5) . . ?
C62 C61 Co4 70.9(6) . . ?
C61 C62 C63 107.9(9) . . ?
C61 C62 Co4 68.3(5) . . ?
C63 C62 Co4 70.1(5) . . ?
C64 C63 C62 107.6(8) . . ?
C64 C63 Co4 68.9(4) . . ?
C62 C63 Co4 69.3(5) . . ?
C65 C64 C63 107.5(8) . . ?
C65 C64 Co4 69.6(5) . . ?
C63 C64 Co4 70.4(5) . . ?
C64 C65 C61 109.0(8) . . ?
C64 C65 Co4 69.9(5) . . ?
C61 C65 Co4 68.8(5) . . ?
C70 C66 C67 106.6(8) . . ?
C70 C66 Co4 71.2(4) . . ?
C67 C66 Co4 68.4(5) . . ?
C68 C67 C66 108.9(7) . . ?
C68 C67 Co4 71.0(5) . . ?
C66 C67 Co4 69.7(4) . . ?
C69 C68 C67 107.1(8) . . ?
C69 C68 Co4 69.4(5) . . ?
C67 C68 Co4 68.5(5) . . ?
C68 C69 C70 110.7(8) . . ?
C68 C69 Co4 70.6(5) . . ?
C70 C69 Co4 71.5(4) . . ?
C69 C70 C71 126.2(7) . . ?
C69 C70 C66 106.6(7) . . ?
C71 C70 C66 127.2(8) . . ?
C69 C70 Co4 68.1(4) . . ?
C71 C70 Co4 127.0(5) . . ?
C66 C70 Co4 68.0(4) . . ?
C72 C71 C70 174.6(8) . . ?
C71 C72 Au2 173.9(6) . . ?
F2 P1 F3 90.3(4) . . ?
F2 P1 F4 91.0(4) . . ?
F3 P1 F4 178.6(4) . . ?
F2 P1 F6 89.5(3) . . ?
F3 P1 F6 91.2(4) . . ?
F4 P1 F6 89.2(3) . . ?
F2 P1 F5 92.6(4) . . ?
F3 P1 F5 88.6(4) . . ?
F4 P1 F5 90.9(4) . . ?
F6 P1 F5 177.9(4) . . ?
F2 P1 F1 178.4(4) . . ?
F3 P1 F1 90.6(4) . . ?
F4 P1 F1 88.1(3) . . ?
F6 P1 F1 89.1(3) . . ?
F5 P1 F1 88.7(3) . . ?
F7 P2 F7 180.000(4) 2_777 . ?
F7 P2 F9 89.7(6) 2_777 . ?
F7 P2 F9 90.3(6) . . ?
F7 P2 F9 90.3(6) 2_777 2_777 ?
F7 P2 F9 89.7(6) . 2_777 ?
F9 P2 F9 180.000(5) . 2_777 ?
F7 P2 F8 91.9(4) 2_777 2_777 ?
F7 P2 F8 88.1(4) . 2_777 ?
F9 P2 F8 85.7(4) . 2_777 ?
F9 P2 F8 94.3(4) 2_777 2_777 ?
F7 P2 F8 88.1(4) 2_777 . ?
F7 P2 F8 91.9(4) . . ?
F9 P2 F8 94.3(4) . . ?
F9 P2 F8 85.7(4) 2_777 . ?
F8 P2 F8 180.000(2) 2_777 . ?

_diffrn_measured_fraction_theta_max 0.986
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.986
_refine_diff_density_max         1.716
_refine_diff_density_min         -1.918
_refine_diff_density_rms         0.143

