# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Pt(SiH2Me)2(dcpe)_complex_3
_database_code_depnum_ccdc_archive 'CCDC 1439201'
_audit_update_record             
;
2015-11-26 deposited with the CCDC.
2016-02-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H58 P2 Pt Si2, C6 H6'
_chemical_formula_sum            'C34 H64 P2 Pt Si2'
_chemical_formula_weight         786.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.2140(4)
_cell_length_b                   14.0280(5)
_cell_length_c                   23.0967(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3633.3(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9935
_cell_measurement_theta_min      2.49
_cell_measurement_theta_max      26.75

_exptl_crystal_description       rod
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.437
_exptl_crystal_F_000             1616
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    4.037
_shelx_estimated_absorpt_T_min   0.564
_shelx_estimated_absorpt_T_max   0.855
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5767
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_process_details   'Bruker APEX2'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            20086
_diffrn_reflns_av_unetI/netI     0.0459
_diffrn_reflns_av_R_equivalents  0.0336
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.284
_diffrn_reflns_theta_max         26.754
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.987
_reflns_number_total             7646
_reflns_number_gt                7258
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.773
_reflns_Friedel_fraction_max     0.974
_reflns_Friedel_fraction_full    0.972

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0060P)²+0.5286P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 3037 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.010(4)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         7646
_refine_ls_number_parameters     370
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0257
_refine_ls_R_factor_gt           0.0229
_refine_ls_wR_factor_ref         0.0463
_refine_ls_wR_factor_gt          0.0456
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_restrained_S_all      0.998
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.64049(2) 0.69842(2) 0.67136(2) 0.00964(5) Uani 1 1 d . . . . .
P1 P 0.70974(11) 0.54593(9) 0.68977(5) 0.0104(3) Uani 1 1 d . . . . .
Si1 Si 0.82210(12) 0.77996(10) 0.68933(6) 0.0151(3) Uani 1 1 d D . . . .
C1 C 0.5787(4) 0.4673(3) 0.6978(2) 0.0132(10) Uani 1 1 d . . . . .
H1A H 0.6014 0.4016 0.6868 0.016 Uiso 1 1 calc R U . . .
H1B H 0.5542 0.4664 0.7390 0.016 Uiso 1 1 calc R U . . .
P2 P 0.45438(11) 0.62994(9) 0.65802(5) 0.0113(3) Uani 1 1 d . . . . .
Si2 Si 0.57217(12) 0.85683(9) 0.66585(6) 0.0144(3) Uani 1 1 d D . . . .
C2 C 0.4726(4) 0.4992(3) 0.6606(2) 0.0133(11) Uani 1 1 d . . . . .
H2A H 0.3988 0.4704 0.6763 0.016 Uiso 1 1 calc R U . . .
H2B H 0.4836 0.4749 0.6207 0.016 Uiso 1 1 calc R U . . .
C3 C 0.8048(4) 0.4800(4) 0.6385(2) 0.0134(10) Uani 1 1 d . . . . .
H3 H 0.8094 0.4127 0.6526 0.016 Uiso 1 1 calc R U . . .
C4 C 0.7481(6) 0.4772(4) 0.5779(2) 0.0258(14) Uani 1 1 d . . . . .
H4A H 0.6674 0.4491 0.5806 0.031 Uiso 1 1 calc R U . . .
H4B H 0.7400 0.5431 0.5630 0.031 Uiso 1 1 calc R U . . .
C5 C 0.8236(5) 0.4185(5) 0.5358(2) 0.0307(15) Uani 1 1 d . . . . .
H5A H 0.8242 0.3511 0.5483 0.037 Uiso 1 1 calc R U . . .
H5B H 0.7874 0.4214 0.4967 0.037 Uiso 1 1 calc R U . . .
C6 C 0.9514(6) 0.4557(5) 0.5330(2) 0.0341(15) Uani 1 1 d . . . . .
H6A H 0.9516 0.5207 0.5163 0.041 Uiso 1 1 calc R U . . .
H6B H 0.9992 0.4140 0.5073 0.041 Uiso 1 1 calc R U . . .
C7 C 1.0075(5) 0.4581(5) 0.5929(2) 0.0302(15) Uani 1 1 d . . . . .
H7A H 1.0146 0.3923 0.6079 0.036 Uiso 1 1 calc R U . . .
H7B H 1.0886 0.4855 0.5902 0.036 Uiso 1 1 calc R U . . .
C8 C 0.9328(5) 0.5174(4) 0.6345(2) 0.0253(13) Uani 1 1 d . . . . .
H8A H 0.9316 0.5845 0.6212 0.030 Uiso 1 1 calc R U . . .
H8B H 0.9699 0.5159 0.6734 0.030 Uiso 1 1 calc R U . . .
C9 C 0.7878(4) 0.5350(4) 0.76028(19) 0.0131(10) Uani 1 1 d . . . . .
H9 H 0.8642 0.5711 0.7563 0.016 Uiso 1 1 calc R U . . .
C10 C 0.8218(5) 0.4335(4) 0.7777(2) 0.0154(11) Uani 1 1 d . . . . .
H10A H 0.7487 0.3944 0.7818 0.018 Uiso 1 1 calc R U . . .
H10B H 0.8716 0.4046 0.7469 0.018 Uiso 1 1 calc R U . . .
H102 H 0.831(4) 0.869(2) 0.6590(18) 0.016(14) Uiso 1 1 d D . . . .
H101 H 0.929(3) 0.731(3) 0.6721(19) 0.012(12) Uiso 1 1 d D . . . .
C11 C 0.8910(4) 0.4333(4) 0.8351(2) 0.0200(11) Uani 1 1 d . . . . .
H11A H 0.9685 0.4658 0.8295 0.024 Uiso 1 1 calc R U . . .
H11B H 0.9074 0.3666 0.8468 0.024 Uiso 1 1 calc R U . . .
C12 C 0.8218(5) 0.4832(4) 0.8831(2) 0.0209(12) Uani 1 1 d . . . . .
H12A H 0.7483 0.4468 0.8918 0.025 Uiso 1 1 calc R U . . .
H12B H 0.8709 0.4854 0.9187 0.025 Uiso 1 1 calc R U . . .
C13 C 0.7888(5) 0.5846(4) 0.8649(2) 0.0186(11) Uani 1 1 d . . . . .
H13A H 0.8624 0.6225 0.8596 0.022 Uiso 1 1 calc R U . . .
H13B H 0.7411 0.6150 0.8960 0.022 Uiso 1 1 calc R U . . .
C14 C 0.7170(4) 0.5844(4) 0.80854(18) 0.0129(10) Uani 1 1 d . . . . .
H14A H 0.6405 0.5506 0.8146 0.015 Uiso 1 1 calc R U . . .
H14B H 0.6989 0.6508 0.7970 0.015 Uiso 1 1 calc R U . . .
C15 C 0.3750(5) 0.6466(4) 0.58840(19) 0.0161(11) Uani 1 1 d . . . . .
H15 H 0.3154 0.5940 0.5843 0.019 Uiso 1 1 calc R U . . .
C16 C 0.4644(5) 0.6388(4) 0.5379(2) 0.0201(12) Uani 1 1 d . . . . .
H16A H 0.5269 0.6881 0.5424 0.024 Uiso 1 1 calc R U . . .
H16B H 0.5035 0.5756 0.5391 0.024 Uiso 1 1 calc R U . . .
C17 C 0.4028(5) 0.6517(4) 0.4795(2) 0.0264(13) Uani 1 1 d . . . . .
H17A H 0.3466 0.5983 0.4731 0.032 Uiso 1 1 calc R U . . .
H17B H 0.4632 0.6500 0.4483 0.032 Uiso 1 1 calc R U . . .
C18 C 0.3347(6) 0.7460(4) 0.4768(2) 0.0295(15) Uani 1 1 d . . . . .
H18A H 0.2919 0.7504 0.4394 0.035 Uiso 1 1 calc R U . . .
H18B H 0.3919 0.7997 0.4789 0.035 Uiso 1 1 calc R U . . .
C19 C 0.2450(5) 0.7539(4) 0.5266(2) 0.0264(14) Uani 1 1 d . . . . .
H19A H 0.2053 0.8169 0.5252 0.032 Uiso 1 1 calc R U . . .
H19B H 0.1831 0.7041 0.5223 0.032 Uiso 1 1 calc R U . . .
C20 C 0.3077(5) 0.7420(4) 0.5852(2) 0.0212(12) Uani 1 1 d . . . . .
H20A H 0.2479 0.7449 0.6166 0.025 Uiso 1 1 calc R U . . .
H20B H 0.3647 0.7951 0.5909 0.025 Uiso 1 1 calc R U . . .
H202 H 0.448(3) 0.863(3) 0.6784(19) 0.007(12) Uiso 1 1 d D . . . .
H201 H 0.616(6) 0.923(4) 0.707(2) 0.046(19) Uiso 1 1 d D . . . .
C21 C 0.3430(4) 0.6597(4) 0.71424(18) 0.0133(10) Uani 1 1 d . . . . .
H21 H 0.3221 0.7283 0.7083 0.016 Uiso 1 1 calc R U . . .
C22 C 0.2258(5) 0.6046(4) 0.7110(2) 0.0223(12) Uani 1 1 d . . . . .
H22A H 0.1904 0.6127 0.6721 0.027 Uiso 1 1 calc R U . . .
H22B H 0.2416 0.5359 0.7170 0.027 Uiso 1 1 calc R U . . .
C23 C 0.1381(5) 0.6395(4) 0.7566(2) 0.0268(12) Uani 1 1 d . . . . .
H23A H 0.1174 0.7069 0.7487 0.032 Uiso 1 1 calc R U . . .
H23B H 0.0640 0.6014 0.7543 0.032 Uiso 1 1 calc R U . . .
C24 C 0.1899(5) 0.6315(4) 0.8170(2) 0.0225(12) Uani 1 1 d . . . . .
H24A H 0.2033 0.5636 0.8265 0.027 Uiso 1 1 calc R U . . .
H24B H 0.1325 0.6578 0.8454 0.027 Uiso 1 1 calc R U . . .
C25 C 0.3076(4) 0.6858(4) 0.8212(2) 0.0222(11) Uani 1 1 d . . . . .
H25A H 0.2922 0.7548 0.8163 0.027 Uiso 1 1 calc R U . . .
H25B H 0.3423 0.6761 0.8602 0.027 Uiso 1 1 calc R U . . .
C26 C 0.3971(4) 0.6528(4) 0.7754(2) 0.0165(11) Uani 1 1 d . . . . .
H26A H 0.4207 0.5861 0.7833 0.020 Uiso 1 1 calc R U . . .
H26B H 0.4696 0.6930 0.7774 0.020 Uiso 1 1 calc R U . . .
C27 C 0.8489(5) 0.8141(4) 0.76810(19) 0.0234(11) Uani 1 1 d . . . . .
H27A H 0.9121 0.8621 0.7702 0.035 Uiso 1 1 calc R U . . .
H27B H 0.8729 0.7574 0.7900 0.035 Uiso 1 1 calc R U . . .
H27C H 0.7753 0.8402 0.7846 0.035 Uiso 1 1 calc R U . . .
C28 C 0.5944(5) 0.9243(4) 0.5960(2) 0.0271(13) Uani 1 1 d . . . . .
H28A H 0.5530 0.8911 0.5645 0.041 Uiso 1 1 calc R U . . .
H28B H 0.6798 0.9279 0.5871 0.041 Uiso 1 1 calc R U . . .
H28C H 0.5620 0.9888 0.6000 0.041 Uiso 1 1 calc R U . . .
C29 C 0.5781(6) 0.7780(4) 0.9211(2) 0.0300(14) Uani 1 1 d . . . . .
H29 H 0.5698 0.7419 0.8866 0.036 Uiso 1 1 calc R U . . .
C30 C 0.6837(6) 0.8230(4) 0.9332(3) 0.0350(16) Uani 1 1 d . . . . .
H30 H 0.7487 0.8178 0.9070 0.042 Uiso 1 1 calc R U . . .
C31 C 0.6960(6) 0.8761(4) 0.9836(3) 0.0358(15) Uani 1 1 d . . . . .
H31 H 0.7692 0.9071 0.9922 0.043 Uiso 1 1 calc R U . . .
C32 C 0.6008(6) 0.8832(5) 1.0212(3) 0.0381(17) Uani 1 1 d . . . . .
H32 H 0.6077 0.9208 1.0552 0.046 Uiso 1 1 calc R U . . .
C33 C 0.4963(6) 0.8362(5) 1.0095(3) 0.0357(16) Uani 1 1 d . . . . .
H33 H 0.4322 0.8389 1.0363 0.043 Uiso 1 1 calc R U . . .
C34 C 0.4840(5) 0.7853(4) 0.9593(2) 0.0311(14) Uani 1 1 d . . . . .
H34 H 0.4104 0.7549 0.9506 0.037 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.3152(13) . ?
Pt1 P2 2.3181(12) . ?
Pt1 Si2 2.3539(13) . ?
Pt1 Si1 2.3724(14) . ?
P1 C3 1.842(5) . ?
P1 C1 1.846(5) . ?
P1 C9 1.855(5) . ?
Si1 C27 1.905(5) . ?
Si1 H102 1.43(3) . ?
Si1 H101 1.44(3) . ?
C1 C2 1.535(6) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
P2 C2 1.847(5) . ?
P2 C15 1.853(5) . ?
P2 C21 1.849(5) . ?
Si2 C28 1.887(5) . ?
Si2 H202 1.43(3) . ?
Si2 H201 1.42(3) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C8 1.531(7) . ?
C3 C4 1.537(7) . ?
C3 H3 1.0000 . ?
C4 C5 1.530(7) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.526(9) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 C7 1.520(8) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 C8 1.522(7) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C14 1.534(6) . ?
C9 C10 1.528(7) . ?
C9 H9 1.0000 . ?
C10 C11 1.537(6) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.525(7) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 C13 1.528(7) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.531(6) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C20 1.538(7) . ?
C15 C16 1.542(7) . ?
C15 H15 1.0000 . ?
C16 C17 1.525(7) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.530(8) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.533(8) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C20 1.533(7) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.526(7) . ?
C21 C26 1.539(6) . ?
C21 H21 1.0000 . ?
C22 C23 1.523(7) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.515(7) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.527(7) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.531(7) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 C30 1.370(9) . ?
C29 C34 1.379(8) . ?
C29 H29 0.9500 . ?
C30 C31 1.390(9) . ?
C30 H30 0.9500 . ?
C31 C32 1.378(9) . ?
C31 H31 0.9500 . ?
C32 C33 1.372(9) . ?
C32 H32 0.9500 . ?
C33 C34 1.369(8) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 86.76(4) . . ?
P1 Pt1 Si2 172.46(4) . . ?
P2 Pt1 Si2 95.22(5) . . ?
P1 Pt1 Si1 97.21(5) . . ?
P2 Pt1 Si1 174.84(5) . . ?
Si2 Pt1 Si1 80.43(5) . . ?
C3 P1 C1 103.0(2) . . ?
C3 P1 C9 104.5(2) . . ?
C1 P1 C9 103.7(2) . . ?
C3 P1 Pt1 122.66(17) . . ?
C1 P1 Pt1 107.66(16) . . ?
C9 P1 Pt1 113.32(17) . . ?
C27 Si1 Pt1 115.05(18) . . ?
C27 Si1 H102 103.7(18) . . ?
Pt1 Si1 H102 113.3(19) . . ?
C27 Si1 H101 104.6(18) . . ?
Pt1 Si1 H101 115.9(18) . . ?
H102 Si1 H101 103(3) . . ?
C2 C1 P1 112.8(3) . . ?
C2 C1 H1A 109.0 . . ?
P1 C1 H1A 109.0 . . ?
C2 C1 H1B 109.0 . . ?
P1 C1 H1B 109.0 . . ?
H1A C1 H1B 107.8 . . ?
C2 P2 C15 101.9(2) . . ?
C2 P2 C21 106.0(2) . . ?
C15 P2 C21 104.9(2) . . ?
C2 P2 Pt1 107.93(16) . . ?
C15 P2 Pt1 119.71(17) . . ?
C21 P2 Pt1 114.92(16) . . ?
C28 Si2 Pt1 118.45(19) . . ?
C28 Si2 H202 105.6(18) . . ?
Pt1 Si2 H202 111.6(18) . . ?
C28 Si2 H201 102(2) . . ?
Pt1 Si2 H201 118(3) . . ?
H202 Si2 H201 99(3) . . ?
C1 C2 P2 113.1(3) . . ?
C1 C2 H2A 109.0 . . ?
P2 C2 H2A 109.0 . . ?
C1 C2 H2B 109.0 . . ?
P2 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?
C8 C3 C4 110.0(4) . . ?
C8 C3 P1 114.2(4) . . ?
C4 C3 P1 111.0(4) . . ?
C8 C3 H3 107.1 . . ?
C4 C3 H3 107.1 . . ?
P1 C3 H3 107.1 . . ?
C5 C4 C3 111.4(5) . . ?
C5 C4 H4A 109.4 . . ?
C3 C4 H4A 109.4 . . ?
C5 C4 H4B 109.4 . . ?
C3 C4 H4B 109.4 . . ?
H4A C4 H4B 108.0 . . ?
C6 C5 C4 111.2(5) . . ?
C6 C5 H5A 109.4 . . ?
C4 C5 H5A 109.4 . . ?
C6 C5 H5B 109.4 . . ?
C4 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
C5 C6 C7 111.0(5) . . ?
C5 C6 H6A 109.4 . . ?
C7 C6 H6A 109.4 . . ?
C5 C6 H6B 109.4 . . ?
C7 C6 H6B 109.4 . . ?
H6A C6 H6B 108.0 . . ?
C8 C7 C6 111.1(5) . . ?
C8 C7 H7A 109.4 . . ?
C6 C7 H7A 109.4 . . ?
C8 C7 H7B 109.4 . . ?
C6 C7 H7B 109.4 . . ?
H7A C7 H7B 108.0 . . ?
C7 C8 C3 111.5(4) . . ?
C7 C8 H8A 109.3 . . ?
C3 C8 H8A 109.3 . . ?
C7 C8 H8B 109.3 . . ?
C3 C8 H8B 109.3 . . ?
H8A C8 H8B 108.0 . . ?
C14 C9 C10 111.1(4) . . ?
C14 C9 P1 110.9(3) . . ?
C10 C9 P1 115.2(3) . . ?
C14 C9 H9 106.4 . . ?
C10 C9 H9 106.4 . . ?
P1 C9 H9 106.4 . . ?
C11 C10 C9 110.8(4) . . ?
C11 C10 H10A 109.5 . . ?
C9 C10 H10A 109.5 . . ?
C11 C10 H10B 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 108.1 . . ?
C10 C11 C12 111.7(4) . . ?
C10 C11 H11A 109.3 . . ?
C12 C11 H11A 109.3 . . ?
C10 C11 H11B 109.3 . . ?
C12 C11 H11B 109.3 . . ?
H11A C11 H11B 107.9 . . ?
C13 C12 C11 110.5(4) . . ?
C13 C12 H12A 109.5 . . ?
C11 C12 H12A 109.5 . . ?
C13 C12 H12B 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 108.1 . . ?
C12 C13 C14 111.1(4) . . ?
C12 C13 H13A 109.4 . . ?
C14 C13 H13A 109.4 . . ?
C12 C13 H13B 109.4 . . ?
C14 C13 H13B 109.4 . . ?
H13A C13 H13B 108.0 . . ?
C9 C14 C13 110.3(4) . . ?
C9 C14 H14A 109.6 . . ?
C13 C14 H14A 109.6 . . ?
C9 C14 H14B 109.6 . . ?
C13 C14 H14B 109.6 . . ?
H14A C14 H14B 108.1 . . ?
C20 C15 C16 110.1(4) . . ?
C20 C15 P2 112.8(3) . . ?
C16 C15 P2 109.6(3) . . ?
C20 C15 H15 108.1 . . ?
C16 C15 H15 108.1 . . ?
P2 C15 H15 108.1 . . ?
C17 C16 C15 111.4(4) . . ?
C17 C16 H16A 109.3 . . ?
C15 C16 H16A 109.3 . . ?
C17 C16 H16B 109.3 . . ?
C15 C16 H16B 109.3 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 111.5(4) . . ?
C16 C17 H17A 109.3 . . ?
C18 C17 H17A 109.3 . . ?
C16 C17 H17B 109.3 . . ?
C18 C17 H17B 109.3 . . ?
H17A C17 H17B 108.0 . . ?
C17 C18 C19 111.0(4) . . ?
C17 C18 H18A 109.4 . . ?
C19 C18 H18A 109.4 . . ?
C17 C18 H18B 109.4 . . ?
C19 C18 H18B 109.4 . . ?
H18A C18 H18B 108.0 . . ?
C20 C19 C18 110.7(5) . . ?
C20 C19 H19A 109.5 . . ?
C18 C19 H19A 109.5 . . ?
C20 C19 H19B 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 108.1 . . ?
C19 C20 C15 111.2(4) . . ?
C19 C20 H20A 109.4 . . ?
C15 C20 H20A 109.4 . . ?
C19 C20 H20B 109.4 . . ?
C15 C20 H20B 109.4 . . ?
H20A C20 H20B 108.0 . . ?
C22 C21 C26 110.7(4) . . ?
C22 C21 P2 115.7(3) . . ?
C26 C21 P2 111.3(3) . . ?
C22 C21 H21 106.2 . . ?
C26 C21 H21 106.2 . . ?
P2 C21 H21 106.2 . . ?
C23 C22 C21 111.1(4) . . ?
C23 C22 H22A 109.4 . . ?
C21 C22 H22A 109.4 . . ?
C23 C22 H22B 109.4 . . ?
C21 C22 H22B 109.4 . . ?
H22A C22 H22B 108.0 . . ?
C24 C23 C22 111.5(5) . . ?
C24 C23 H23A 109.3 . . ?
C22 C23 H23A 109.3 . . ?
C24 C23 H23B 109.3 . . ?
C22 C23 H23B 109.3 . . ?
H23A C23 H23B 108.0 . . ?
C23 C24 C25 110.6(4) . . ?
C23 C24 H24A 109.5 . . ?
C25 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C25 C24 H24B 109.5 . . ?
H24A C24 H24B 108.1 . . ?
C26 C25 C24 111.9(4) . . ?
C26 C25 H25A 109.2 . . ?
C24 C25 H25A 109.2 . . ?
C26 C25 H25B 109.2 . . ?
C24 C25 H25B 109.2 . . ?
H25A C25 H25B 107.9 . . ?
C25 C26 C21 110.9(4) . . ?
C25 C26 H26A 109.5 . . ?
C21 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26A C26 H26B 108.0 . . ?
Si1 C27 H27A 109.5 . . ?
Si1 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si1 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
Si2 C28 H28A 109.5 . . ?
Si2 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
Si2 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 C34 119.8(5) . . ?
C30 C29 H29 120.1 . . ?
C34 C29 H29 120.1 . . ?
C29 C30 C31 120.2(6) . . ?
C29 C30 H30 119.9 . . ?
C31 C30 H30 119.9 . . ?
C32 C31 C30 119.3(6) . . ?
C32 C31 H31 120.4 . . ?
C30 C31 H31 120.4 . . ?
C33 C32 C31 120.2(6) . . ?
C33 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?
C32 C33 C34 120.2(6) . . ?
C32 C33 H33 119.9 . . ?
C34 C33 H33 119.9 . . ?
C29 C34 C33 120.2(6) . . ?
C29 C34 H34 119.9 . . ?
C33 C34 H34 119.9 . . ?

_refine_diff_density_max         1.483
_refine_diff_density_min         -0.608
_refine_diff_density_rms         0.090

_shelxl_version_number           2013-4

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Pt(SiMeCl2)2(dcpe)_complex_9
_database_code_depnum_ccdc_archive 'CCDC 1439202'
_audit_update_record             
;
2015-11-26 deposited with the CCDC.
2016-02-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C28 H54 Cl4 P2 Pt Si2, C6 H6'
_chemical_formula_sum            'C34 H60 Cl4 P2 Pt Si2'
_chemical_formula_weight         923.83

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.5338(8)
_cell_length_b                   18.0570(13)
_cell_length_c                   20.1236(14)
_cell_angle_alpha                85.305(2)
_cell_angle_beta                 73.897(2)
_cell_angle_gamma                83.984(2)
_cell_volume                     3998.3(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9873
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      25.16

_exptl_crystal_description       rod
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.535
_exptl_crystal_F_000             1872
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.230
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.040
_exptl_absorpt_coefficient_mu    3.940
_shelx_estimated_absorpt_T_min   0.464
_shelx_estimated_absorpt_T_max   0.858
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5681
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   'BRUKER APEX2'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'BRUKER D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            171341
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_av_R_equivalents  0.0485
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.248
_diffrn_reflns_theta_max         25.174
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             14241
_reflns_number_gt                12129
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0502P)²+58.6922P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14241
_refine_ls_number_parameters     738
_refine_ls_number_restraints     35
_refine_ls_R_factor_all          0.0620
_refine_ls_R_factor_gt           0.0514
_refine_ls_wR_factor_ref         0.1297
_refine_ls_wR_factor_gt          0.1229
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.072
_refine_ls_shift/su_max          0.064
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.72148(2) 0.24857(2) 0.23605(2) 0.01535(7) Uani 1 1 d . . . . .
Cl1 Cl 0.70963(19) 0.31252(12) 0.05397(11) 0.0386(5) Uiso 1 1 d D . . . .
Cl2 Cl 0.6141(3) 0.43447(17) 0.1657(2) 0.0501(8) Uiso 0.7371(2) 1 d D U P A 1
C2A C 0.662(2) 0.4364(7) 0.1692(18) 0.0501(8) Uiso 0.2703(2) 1 d D U P A 2
H2A1 H 0.6609 0.4457 0.2167 0.075 Uiso 0.2703(2) 1 calc R U P A 2
H2A2 H 0.5791 0.4382 0.1655 0.075 Uiso 0.2703(2) 1 calc R U P A 2
H2A3 H 0.7056 0.4746 0.1372 0.075 Uiso 0.2703(2) 1 calc R U P A 2
Cl3 Cl 0.9189(4) 0.3720(5) 0.1088(5) 0.0366(15) Uiso 0.2629(2) 1 d D U P A 1
C3A C 0.8856(7) 0.3871(6) 0.1092(7) 0.0366(15) Uiso 0.7297(2) 1 d D U P A 2
H3A1 H 0.8763 0.4232 0.0715 0.055 Uiso 0.7297(2) 1 calc R U P A 2
H3A2 H 0.9514 0.3490 0.0912 0.055 Uiso 0.7297(2) 1 calc R U P A 2
H3A3 H 0.9047 0.4129 0.1454 0.055 Uiso 0.7297(2) 1 calc R U P A 2
Cl4 Cl 0.7518(9) 0.4458(4) 0.2830(6) 0.0365(17) Uiso 0.2001(2) 1 d D U P B 1
C4A C 0.7759(8) 0.4250(4) 0.2981(6) 0.0365(17) Uiso 0.8087(2) 1 d D U P B 2
H4A1 H 0.7482 0.4570 0.3375 0.055 Uiso 0.8087(2) 1 calc R U P B 2
H4A2 H 0.7662 0.4532 0.2560 0.055 Uiso 0.8087(2) 1 calc R U P B 2
H4A3 H 0.8615 0.4077 0.2920 0.055 Uiso 0.8087(2) 1 calc R U P B 2
Cl5 Cl 0.7211(2) 0.31271(14) 0.41117(12) 0.0517(6) Uiso 1 1 d D U . . .
Si2 Si 0.68387(19) 0.34261(11) 0.31492(11) 0.0306(5) Uani 1 1 d D . . . .
Cl6 Cl 0.5014(2) 0.37887(16) 0.35260(15) 0.0479(7) Uiso 0.7999(2) 1 d D U P B 1
C6A C 0.5196(2) 0.37028(16) 0.34713(15) 0.0479(7) Uiso 0.1913(2) 1 d DR U P B 2
H6A1 H 0.5055 0.4027 0.3859 0.072 Uiso 0.1913(2) 1 calc R U P B 2
H6A2 H 0.4759 0.3256 0.3629 0.072 Uiso 0.1913(2) 1 calc R U P B 2
H6A3 H 0.4906 0.3972 0.3097 0.072 Uiso 0.1913(2) 1 calc R U P B 2
P1 P 0.69162(15) 0.15272(10) 0.32288(9) 0.0163(4) Uani 1 1 d . . . . .
P2 P 0.77310(15) 0.15100(9) 0.16062(9) 0.0144(3) Uani 1 1 d . . . . .
Si1 Si 0.74156(16) 0.34195(10) 0.14658(10) 0.0220(4) Uani 1 1 d D . . . .
C1 C 0.6916(6) 0.0662(4) 0.2811(3) 0.0173(14) Uani 1 1 d . . . . .
H1A H 0.7052 0.0226 0.3121 0.021 Uiso 1 1 calc R U . . .
H1B H 0.6124 0.0637 0.2717 0.021 Uiso 1 1 calc R U . . .
C2 C 0.7930(6) 0.0649(4) 0.2130(4) 0.0194(15) Uani 1 1 d . . . . .
H2A H 0.7895 0.0210 0.1874 0.023 Uiso 1 1 calc R U . . .
H2B H 0.8729 0.0613 0.2228 0.023 Uiso 1 1 calc R U . . .
C3 C 0.6603(6) 0.1341(4) 0.1160(4) 0.0171(14) Uani 1 1 d . . . . .
H3 H 0.6848 0.1605 0.0693 0.021 Uiso 1 1 calc R U . . .
C4 C 0.6513(6) 0.0524(4) 0.1031(4) 0.0193(15) Uani 1 1 d . . . . .
H4A H 0.7329 0.0287 0.0811 0.023 Uiso 1 1 calc R U . . .
H4B H 0.6184 0.0246 0.1478 0.023 Uiso 1 1 calc R U . . .
C5 C 0.5688(7) 0.0491(4) 0.0562(4) 0.0254(16) Uani 1 1 d . . . . .
H5A H 0.5636 -0.0036 0.0477 0.030 Uiso 1 1 calc R U . . .
H5B H 0.6034 0.0754 0.0110 0.030 Uiso 1 1 calc R U . . .
C6 C 0.4416(7) 0.0852(5) 0.0893(5) 0.0333(19) Uani 1 1 d . . . . .
H6A H 0.3908 0.0852 0.0570 0.040 Uiso 1 1 calc R U . . .
H6B H 0.4037 0.0558 0.1321 0.040 Uiso 1 1 calc R U . . .
C7 C 0.4479(7) 0.1649(5) 0.1067(5) 0.038(2) Uani 1 1 d . . . . .
H7A H 0.4765 0.1956 0.0632 0.046 Uiso 1 1 calc R U . . .
H7B H 0.3658 0.1860 0.1310 0.046 Uiso 1 1 calc R U . . .
C8 C 0.5324(6) 0.1687(4) 0.1519(4) 0.0228(16) Uani 1 1 d . . . . .
H8A H 0.5007 0.1414 0.1970 0.027 Uiso 1 1 calc R U . . .
H8B H 0.5365 0.2213 0.1608 0.027 Uiso 1 1 calc R U . . .
C9 C 0.9168(6) 0.1578(4) 0.0928(4) 0.0203(15) Uani 1 1 d . . . . .
H9 H 0.9064 0.2057 0.0656 0.024 Uiso 1 1 calc R U . . .
C10 C 0.9491(6) 0.0972(4) 0.0400(4) 0.0222(15) Uani 1 1 d . . . . .
H10E H 0.8817 0.0957 0.0186 0.027 Uiso 1 1 calc R U . . .
H10D H 0.9610 0.0479 0.0637 0.027 Uiso 1 1 calc R U . . .
C11 C 1.0652(6) 0.1134(4) -0.0164(4) 0.0243(16) Uani 1 1 d . . . . .
H11E H 1.0874 0.0726 -0.0487 0.029 Uiso 1 1 calc R U . . .
H11D H 1.0499 0.1602 -0.0432 0.029 Uiso 1 1 calc R U . . .
C12 C 1.1696(6) 0.1209(4) 0.0139(4) 0.0278(17) Uani 1 1 d . . . . .
H12E H 1.2418 0.1333 -0.0239 0.033 Uiso 1 1 calc R U . . .
H12D H 1.1898 0.0728 0.0371 0.033 Uiso 1 1 calc R U . . .
C13 C 1.1368(7) 0.1819(5) 0.0660(4) 0.0302(18) Uani 1 1 d . . . . .
H13E H 1.2047 0.1844 0.0867 0.036 Uiso 1 1 calc R U . . .
H13D H 1.1235 0.2308 0.0419 0.036 Uiso 1 1 calc R U . . .
C14 C 1.0225(6) 0.1659(4) 0.1232(4) 0.0246(16) Uani 1 1 d . . . . .
H14A H 1.0006 0.2071 0.1551 0.030 Uiso 1 1 calc R U . . .
H14B H 1.0384 0.1194 0.1500 0.030 Uiso 1 1 calc R U . . .
C15 C 0.8097(6) 0.1349(4) 0.3694(4) 0.0227(16) Uani 1 1 d . . . . .
H15 H 0.7784 0.1616 0.4134 0.027 Uiso 1 1 calc R U . . .
C16 C 0.9286(7) 0.1690(5) 0.3295(4) 0.0352(19) Uani 1 1 d . . . . .
H16A H 0.9678 0.1411 0.2875 0.042 Uiso 1 1 calc R U . . .
H16B H 0.9106 0.2216 0.3147 0.042 Uiso 1 1 calc R U . . .
C17 C 1.0137(9) 0.1651(6) 0.3756(6) 0.052(3) Uani 1 1 d . . . . .
H17A H 0.9768 0.1962 0.4157 0.063 Uiso 1 1 calc R U . . .
H17B H 1.0908 0.1853 0.3493 0.063 Uiso 1 1 calc R U . . .
C18 C 1.0390(8) 0.0850(6) 0.4014(6) 0.054(3) Uani 1 1 d . . . . .
H18A H 1.0903 0.0844 0.4336 0.064 Uiso 1 1 calc R U . . .
H18B H 1.0845 0.0555 0.3616 0.064 Uiso 1 1 calc R U . . .
C19 C 0.9223(8) 0.0489(5) 0.4385(4) 0.038(2) Uani 1 1 d . . . . .
H19A H 0.8806 0.0752 0.4810 0.046 Uiso 1 1 calc R U . . .
H19B H 0.9422 -0.0037 0.4522 0.046 Uiso 1 1 calc R U . . .
C20 C 0.8379(7) 0.0525(4) 0.3910(4) 0.0279(17) Uani 1 1 d . . . . .
H20A H 0.7619 0.0300 0.4158 0.033 Uiso 1 1 calc R U . . .
H20B H 0.8775 0.0242 0.3494 0.033 Uiso 1 1 calc R U . . .
C21 C 0.5461(6) 0.1621(4) 0.3899(4) 0.0217(15) Uani 1 1 d . . . . .
H21 H 0.5479 0.2077 0.4146 0.026 Uiso 1 1 calc R U . . .
C22 C 0.4390(7) 0.1779(5) 0.3580(4) 0.0292(18) Uani 1 1 d . . . . .
H22A H 0.4321 0.1341 0.3332 0.035 Uiso 1 1 calc R U . . .
H22B H 0.4536 0.2210 0.3239 0.035 Uiso 1 1 calc R U . . .
C23 C 0.3200(7) 0.1949(5) 0.4144(4) 0.036(2) Uani 1 1 d . . . . .
H23A H 0.3244 0.2409 0.4368 0.043 Uiso 1 1 calc R U . . .
H23B H 0.2517 0.2031 0.3931 0.043 Uiso 1 1 calc R U . . .
C24 C 0.2983(7) 0.1302(5) 0.4685(4) 0.035(2) Uani 1 1 d . . . . .
H24A H 0.2882 0.0850 0.4467 0.042 Uiso 1 1 calc R U . . .
H24B H 0.2228 0.1423 0.5052 0.042 Uiso 1 1 calc R U . . .
C25 C 0.4049(7) 0.1147(5) 0.5010(4) 0.0305(18) Uani 1 1 d . . . . .
H25A H 0.4109 0.1585 0.5260 0.037 Uiso 1 1 calc R U . . .
H25B H 0.3903 0.0715 0.5349 0.037 Uiso 1 1 calc R U . . .
C26 C 0.5231(6) 0.0985(4) 0.4457(4) 0.0249(16) Uani 1 1 d . . . . .
H26A H 0.5201 0.0517 0.4241 0.030 Uiso 1 1 calc R U . . .
H26B H 0.5909 0.0913 0.4675 0.030 Uiso 1 1 calc R U . . .
Pt2 Pt 0.29295(2) 0.75282(2) 0.26151(2) 0.01496(7) Uani 1 1 d . . . . .
Cl7 Cl 0.23370(16) 0.81101(10) 0.08740(9) 0.0251(4) Uiso 0.9426(3) 1 d D U P C
1
C7A C 0.26513(16) 0.81508(10) 0.09766(9) 0.0251(4) Uiso 0.1014(3) 1 d DR U P C
2
H7A1 H 0.3273 0.8337 0.0577 0.038 Uiso 0.1014(3) 1 calc R U P C 2
H7A2 H 0.1847 0.8343 0.0933 0.038 Uiso 0.1014(3) 1 calc R U P C 2
H7A3 H 0.2718 0.7604 0.0993 0.038 Uiso 0.1014(3) 1 calc R U P C 2
Cl8 Cl 0.46022(17) 0.87544(11) 0.12580(11) 0.0316(4) Uiso 0.9399(3) 1 d D U P C
1
C8A C 0.44491(17) 0.87277(11) 0.12999(11) 0.0316(4) Uiso 0.0228(3) 1 d DR U P C
2
H8A1 H 0.4755 0.8494 0.0855 0.047 Uiso 0.0228(3) 1 calc R U P C 2
H8A2 H 0.4983 0.8560 0.1596 0.047 Uiso 0.0228(3) 1 calc R U P C 2
H8A3 H 0.4429 0.9271 0.1222 0.047 Uiso 0.0228(3) 1 calc R U P C 2
Cl9 Cl 0.1642(11) 0.9406(5) 0.1965(10) 0.0291(16) Uiso 0.1176(3) 1 d D U P C 1
C9A C 0.1890(8) 0.9357(3) 0.1845(6) 0.0291(16) Uiso 0.8758(3) 1 d D U P C 2
H9A1 H 0.2112 0.9670 0.1415 0.044 Uiso 0.8758(3) 1 calc R U P C 2
H9A2 H 0.2015 0.9615 0.2226 0.044 Uiso 0.8758(3) 1 calc R U P C 2
H9A3 H 0.1036 0.9260 0.1948 0.044 Uiso 0.8758(3) 1 calc R U P C 2
Cl10 Cl 0.31928(18) 0.82294(12) 0.42961(10) 0.0291(4) Uiso 0.9284(3) 1 d D U P
D 1
C10A C 0.3483(14) 0.839(4) 0.4063(7) 0.0291(4) Uiso 0.1262(3) 1 d D U P D 2
H10A H 0.4234 0.8067 0.3907 0.044 Uiso 0.1262(3) 1 calc R U P D 2
H10B H 0.2971 0.8165 0.4490 0.044 Uiso 0.1262(3) 1 calc R U P D 2
H10C H 0.3675 0.8880 0.4152 0.044 Uiso 0.1262(3) 1 calc R U P D 2
Cl11 Cl 0.0816(2) 0.88107(14) 0.37791(13) 0.0309(6) Uiso 0.7973(3) 1 d D U P D
1
C11A C 0.1043(10) 0.860(3) 0.3910(16) 0.0309(6) Uiso 0.1628(3) 1 d D U P D 2
H11A H 0.0993 0.8422 0.4389 0.046 Uiso 0.1628(3) 1 calc R U P D 2
H11B H 0.0547 0.8313 0.3720 0.046 Uiso 0.1628(3) 1 calc R U P D 2
H11C H 0.0743 0.9130 0.3900 0.046 Uiso 0.1628(3) 1 calc R U P D 2
Cl12 Cl 0.3561(7) 0.9454(3) 0.3019(4) 0.0301(12) Uiso 0.2743(3) 1 d D U P D 1
C12A C 0.3353(10) 0.9400(4) 0.3150(7) 0.0301(12) Uiso 0.7110(3) 1 d D U P D 2
H12A H 0.3225 0.9613 0.2710 0.045 Uiso 0.7110(3) 1 calc R U P D 2
H12B H 0.4224 0.9318 0.3106 0.045 Uiso 0.7110(3) 1 calc R U P D 2
H12C H 0.2976 0.9745 0.3516 0.045 Uiso 0.7110(3) 1 calc R U P D 2
P3 P 0.33399(16) 0.65453(10) 0.18636(9) 0.0170(4) Uani 1 1 d . . . . .
P4 P 0.29220(16) 0.65795(10) 0.34836(9) 0.0178(4) Uani 1 1 d . . . . .
Si3 Si 0.28586(15) 0.84520(10) 0.17417(9) 0.0193(4) Uani 1 1 d D . . . .
Si4 Si 0.26564(16) 0.84897(10) 0.33759(9) 0.0188(4) Uani 1 1 d D . . . .
C27 C 0.3732(6) 0.5702(4) 0.2368(4) 0.0209(15) Uani 1 1 d . . . . .
H27A H 0.3659 0.5251 0.2140 0.025 Uiso 1 1 calc R U . . .
H27B H 0.4581 0.5697 0.2389 0.025 Uiso 1 1 calc R U . . .
C28 C 0.2886(7) 0.5696(4) 0.3099(4) 0.0226(16) Uani 1 1 d . . . . .
H28A H 0.3145 0.5272 0.3384 0.027 Uiso 1 1 calc R U . . .
H28B H 0.2050 0.5636 0.3083 0.027 Uiso 1 1 calc R U . . .
C29 C 0.4258(7) 0.6464(4) 0.3846(4) 0.0255(16) Uani 1 1 d . . . . .
H29 H 0.4009 0.6712 0.4297 0.031 Uiso 1 1 calc R U . . .
C30 C 0.4699(7) 0.5654(4) 0.3999(4) 0.0299(18) Uani 1 1 d . . . . .
H30A H 0.4986 0.5392 0.3561 0.036 Uiso 1 1 calc R U . . .
H30B H 0.4020 0.5393 0.4308 0.036 Uiso 1 1 calc R U . . .
C31 C 0.5733(8) 0.5631(5) 0.4345(5) 0.040(2) Uani 1 1 d . . . . .
H31A H 0.5421 0.5853 0.4802 0.048 Uiso 1 1 calc R U . . .
H31B H 0.6030 0.5106 0.4424 0.048 Uiso 1 1 calc R U . . .
C32 C 0.6780(8) 0.6054(5) 0.3905(6) 0.049(2) Uani 1 1 d . . . . .
H32A H 0.7161 0.5797 0.3472 0.059 Uiso 1 1 calc R U . . .
H32B H 0.7399 0.6061 0.4160 0.059 Uiso 1 1 calc R U . . .
C33 C 0.6335(8) 0.6856(5) 0.3729(5) 0.042(2) Uani 1 1 d . . . . .
H33A H 0.6033 0.7128 0.4159 0.051 Uiso 1 1 calc R U . . .
H33B H 0.7020 0.7112 0.3420 0.051 Uiso 1 1 calc R U . . .
C34 C 0.5325(7) 0.6869(5) 0.3372(4) 0.0324(18) Uani 1 1 d . . . . .
H34A H 0.5636 0.6620 0.2929 0.039 Uiso 1 1 calc R U . . .
H34B H 0.5044 0.7392 0.3268 0.039 Uiso 1 1 calc R U . . .
C35 C 0.1556(7) 0.6633(4) 0.4218(4) 0.0229(16) Uani 1 1 d . . . . .
H35 H 0.1605 0.7065 0.4487 0.027 Uiso 1 1 calc R U . . .
C36 C 0.0426(7) 0.6802(4) 0.3954(4) 0.0274(17) Uani 1 1 d . . . . .
H36A H 0.0346 0.6382 0.3686 0.033 Uiso 1 1 calc R U . . .
H36B H 0.0518 0.7256 0.3639 0.033 Uiso 1 1 calc R U . . .
C37 C -0.0726(8) 0.6920(5) 0.4558(4) 0.036(2) Uani 1 1 d . . . . .
H37A H -0.0673 0.7362 0.4806 0.043 Uiso 1 1 calc R U . . .
H37B H -0.1443 0.7015 0.4374 0.043 Uiso 1 1 calc R U . . .
C38 C -0.0869(8) 0.6235(5) 0.5058(5) 0.040(2) Uani 1 1 d . . . . .
H38A H -0.1003 0.5805 0.4822 0.048 Uiso 1 1 calc R U . . .
H38B H -0.1586 0.6329 0.5457 0.048 Uiso 1 1 calc R U . . .
C39 C 0.0259(8) 0.6049(5) 0.5319(4) 0.038(2) Uani 1 1 d . . . . .
H39A H 0.0159 0.5589 0.5625 0.046 Uiso 1 1 calc R U . . .
H39B H 0.0340 0.6459 0.5597 0.046 Uiso 1 1 calc R U . . .
C40 C 0.1419(7) 0.5936(4) 0.4726(4) 0.0297(18) Uani 1 1 d . . . . .
H40A H 0.1385 0.5492 0.4476 0.036 Uiso 1 1 calc R U . . .
H40B H 0.2130 0.5850 0.4916 0.036 Uiso 1 1 calc R U . . .
C41 C 0.2095(6) 0.6313(4) 0.1526(4) 0.0217(15) Uani 1 1 d . . . . .
H41 H 0.2224 0.6569 0.1055 0.026 Uiso 1 1 calc R U . . .
C42 C 0.0847(7) 0.6626(4) 0.1954(4) 0.0273(17) Uani 1 1 d . . . . .
H42A H 0.0866 0.7163 0.2015 0.033 Uiso 1 1 calc R U . . .
H42B H 0.0649 0.6365 0.2419 0.033 Uiso 1 1 calc R U . . .
C43 C -0.0138(7) 0.6526(5) 0.1593(5) 0.039(2) Uani 1 1 d . . . . .
H43A H -0.0940 0.6710 0.1887 0.047 Uiso 1 1 calc R U . . .
H43B H 0.0019 0.6824 0.1146 0.047 Uiso 1 1 calc R U . . .
C44 C -0.0147(8) 0.5708(5) 0.1464(5) 0.040(2) Uani 1 1 d . . . . .
H44A H -0.0744 0.5660 0.1202 0.048 Uiso 1 1 calc R U . . .
H44B H -0.0405 0.5423 0.1914 0.048 Uiso 1 1 calc R U . . .
C45 C 0.1092(8) 0.5374(5) 0.1060(5) 0.036(2) Uani 1 1 d . . . . .
H45A H 0.1314 0.5620 0.0589 0.043 Uiso 1 1 calc R U . . .
H45B H 0.1057 0.4836 0.1013 0.043 Uiso 1 1 calc R U . . .
C46 C 0.2058(7) 0.5477(4) 0.1429(4) 0.0279(17) Uani 1 1 d . . . . .
H46A H 0.2860 0.5272 0.1152 0.033 Uiso 1 1 calc R U . . .
H46B H 0.1870 0.5201 0.1887 0.033 Uiso 1 1 calc R U . . .
C47 C 0.4675(6) 0.6643(4) 0.1122(4) 0.0226(16) Uani 1 1 d . . . . .
H47 H 0.4494 0.7103 0.0844 0.027 Uiso 1 1 calc R U . . .
C48 C 0.5781(7) 0.6773(5) 0.1364(4) 0.0327(19) Uani 1 1 d . . . . .
H48A H 0.5584 0.7212 0.1653 0.039 Uiso 1 1 calc R U . . .
H48B H 0.5974 0.6334 0.1655 0.039 Uiso 1 1 calc R U . . .
C49 C 0.6889(7) 0.6905(5) 0.0755(5) 0.036(2) Uani 1 1 d . . . . .
H49A H 0.6725 0.7368 0.0484 0.044 Uiso 1 1 calc R U . . .
H49B H 0.7591 0.6967 0.0931 0.044 Uiso 1 1 calc R U . . .
C50 C 0.7182(8) 0.6250(5) 0.0292(5) 0.048(3) Uani 1 1 d . . . . .
H50A H 0.7398 0.5794 0.0554 0.058 Uiso 1 1 calc R U . . .
H50B H 0.7887 0.6346 -0.0107 0.058 Uiso 1 1 calc R U . . .
C51 C 0.6096(8) 0.6133(5) 0.0030(4) 0.040(2) Uani 1 1 d . . . . .
H51A H 0.6299 0.5701 -0.0266 0.048 Uiso 1 1 calc R U . . .
H51B H 0.5916 0.6579 -0.0257 0.048 Uiso 1 1 calc R U . . .
C52 C 0.4973(7) 0.5996(4) 0.0629(4) 0.0276(17) Uani 1 1 d . . . . .
H52A H 0.5121 0.5522 0.0889 0.033 Uiso 1 1 calc R U . . .
H52B H 0.4275 0.5951 0.0444 0.033 Uiso 1 1 calc R U . . .
C53 C 0.2347(7) 0.1537(5) 0.8095(4) 0.0315(18) Uani 1 1 d . . . . .
H53 H 0.2416 0.1585 0.8549 0.038 Uiso 1 1 calc R U . . .
C54 C 0.3371(7) 0.1406(4) 0.7555(4) 0.0295(18) Uani 1 1 d . . . . .
H54 H 0.4151 0.1377 0.7633 0.035 Uiso 1 1 calc R U . . .
C55 C 0.3261(7) 0.1319(4) 0.6901(4) 0.0304(18) Uani 1 1 d . . . . .
H55 H 0.3964 0.1216 0.6531 0.036 Uiso 1 1 calc R U . . .
C56 C 0.2129(7) 0.1381(4) 0.6783(4) 0.0302(18) Uani 1 1 d . . . . .
H56 H 0.2055 0.1330 0.6331 0.036 Uiso 1 1 calc R U . . .
C57 C 0.1124(7) 0.1515(5) 0.7314(4) 0.0350(19) Uani 1 1 d . . . . .
H57 H 0.0346 0.1552 0.7232 0.042 Uiso 1 1 calc R U . . .
C58 C 0.1221(7) 0.1597(5) 0.7971(4) 0.036(2) Uani 1 1 d . . . . .
H58 H 0.0513 0.1696 0.8338 0.043 Uiso 1 1 calc R U . . .
C59 C 0.3112(8) 0.3447(7) 0.1841(7) 0.079(4) Uiso 1 1 d D . . . .
H59 H 0.3847 0.3403 0.1481 0.095 Uiso 1 1 calc R U . . .
C60 C 0.2032(6) 0.3331(6) 0.1697(5) 0.066(3) Uiso 1 1 d D . . . .
H60 H 0.2036 0.3209 0.1246 0.079 Uiso 1 1 calc R U . . .
C61 C 0.0945(9) 0.3394(8) 0.2219(4) 0.086(4) Uiso 1 1 d D . . . .
H61 H 0.0201 0.3321 0.2127 0.104 Uiso 1 1 calc R U . . .
C62 C 0.0970(8) 0.3565(9) 0.2878(5) 0.107(5) Uiso 1 1 d D . . . .
H62 H 0.0249 0.3610 0.3247 0.129 Uiso 1 1 calc R U . . .
C63 C 0.2093(7) 0.3668(8) 0.2976(6) 0.096(5) Uiso 1 1 d D . . . .
H63 H 0.2142 0.3781 0.3420 0.115 Uiso 1 1 calc R U . . .
C64 C 0.3143(10) 0.3607(8) 0.2429(6) 0.092(4) Uiso 1 1 d D . . . .
H64 H 0.3896 0.3689 0.2504 0.110 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.3374(17) . ?
Pt1 P2 2.3406(17) . ?
Pt1 Si1 2.3435(19) . ?
Pt1 Si2 2.344(2) . ?
Cl1 Si1 2.116(3) . ?
Cl2 Si1 2.092(3) . ?
C2A Si1 1.876(5) . ?
C2A H2A1 0.9800 . ?
C2A H2A2 0.9800 . ?
C2A H2A3 0.9800 . ?
Cl3 Si1 2.088(4) . ?
C3A Si1 1.865(5) . ?
C3A H3A1 0.9800 . ?
C3A H3A2 0.9800 . ?
C3A H3A3 0.9800 . ?
Cl4 Si2 2.080(5) . ?
C4A Si2 1.871(5) . ?
C4A H4A1 0.9800 . ?
C4A H4A2 0.9800 . ?
C4A H4A3 0.9800 . ?
Cl5 Si2 2.114(3) . ?
Si2 C6A 1.853(3) . ?
Si2 Cl6 2.083(3) . ?
C6A H6A1 0.9800 . ?
C6A H6A2 0.9800 . ?
C6A H6A3 0.9800 . ?
P1 C1 1.834(7) . ?
P1 C21 1.840(7) . ?
P1 C15 1.844(7) . ?
P2 C3 1.835(7) . ?
P2 C2 1.837(7) . ?
P2 C9 1.840(7) . ?
C1 C2 1.535(9) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.538(9) . ?
C3 C8 1.542(9) . ?
C3 H3 1.0000 . ?
C4 C5 1.524(10) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.533(11) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 C7 1.522(11) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 C8 1.517(10) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.533(10) . ?
C9 C14 1.533(9) . ?
C9 H9 1.0000 . ?
C10 C11 1.534(9) . ?
C10 H10E 0.9900 . ?
C10 H10D 0.9900 . ?
C11 C12 1.515(10) . ?
C11 H11E 0.9900 . ?
C11 H11D 0.9900 . ?
C12 C13 1.529(11) . ?
C12 H12E 0.9900 . ?
C12 H12D 0.9900 . ?
C13 C14 1.526(10) . ?
C13 H13E 0.9900 . ?
C13 H13D 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C20 1.543(11) . ?
C15 C16 1.546(11) . ?
C15 H15 1.0000 . ?
C16 C17 1.520(11) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.523(14) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.530(14) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C20 1.535(10) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C26 1.530(10) . ?
C21 C22 1.534(10) . ?
C21 H21 1.0000 . ?
C22 C23 1.540(10) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.522(12) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.536(11) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.520(10) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
Pt2 Si3 2.3345(18) . ?
Pt2 P4 2.3439(18) . ?
Pt2 Si4 2.3474(18) . ?
Pt2 P3 2.3510(17) . ?
Cl7 Si3 2.151(2) . ?
C7A Si3 1.758(2) . ?
C7A H7A1 0.9800 . ?
C7A H7A2 0.9800 . ?
C7A H7A3 0.9800 . ?
Cl8 Si3 2.085(2) . ?
C8A Si3 1.902(2) . ?
C8A H8A1 0.9800 . ?
C8A H8A2 0.9800 . ?
C8A H8A3 0.9800 . ?
Cl9 Si3 2.100(5) . ?
C9A Si3 1.872(4) . ?
C9A H9A1 0.9800 . ?
C9A H9A2 0.9800 . ?
C9A H9A3 0.9800 . ?
Cl10 Si4 2.113(2) . ?
C10A Si4 1.873(5) . ?
C10A H10A 0.9800 . ?
C10A H10B 0.9800 . ?
C10A H10C 0.9800 . ?
Cl11 Si4 2.089(3) . ?
C11A Si4 1.873(5) . ?
C11A H11A 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11C 0.9800 . ?
Cl12 Si4 2.097(4) . ?
C12A Si4 1.873(5) . ?
C12A H12A 0.9800 . ?
C12A H12B 0.9800 . ?
C12A H12C 0.9800 . ?
P3 C47 1.836(7) . ?
P3 C27 1.847(7) . ?
P3 C41 1.848(7) . ?
P4 C35 1.837(7) . ?
P4 C28 1.839(7) . ?
P4 C29 1.866(8) . ?
C27 C28 1.522(9) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.534(10) . ?
C29 C34 1.544(11) . ?
C29 H29 1.0000 . ?
C30 C31 1.535(11) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.522(13) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C33 1.531(12) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.526(11) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.532(11) . ?
C35 C40 1.546(10) . ?
C35 H35 1.0000 . ?
C36 C37 1.542(10) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 C38 1.523(12) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 C39 1.530(13) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C40 1.535(11) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C41 C42 1.535(10) . ?
C41 C46 1.544(10) . ?
C41 H41 1.0000 . ?
C42 C43 1.541(11) . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C43 C44 1.523(12) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 C45 1.523(12) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.535(11) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C47 C48 1.532(11) . ?
C47 C52 1.542(10) . ?
C47 H47 1.0000 . ?
C48 C49 1.530(10) . ?
C48 H48A 0.9900 . ?
C48 H48B 0.9900 . ?
C49 C50 1.517(12) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C50 C51 1.527(14) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C51 C52 1.532(10) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C53 C54 1.380(11) . ?
C53 C58 1.381(12) . ?
C53 H53 0.9500 . ?
C54 C55 1.380(11) . ?
C54 H54 0.9500 . ?
C55 C56 1.381(11) . ?
C55 H55 0.9500 . ?
C56 C57 1.357(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.378(12) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C64 1.252(16) . ?
C59 C60 1.394(5) . ?
C59 H59 0.9500 . ?
C60 C61 1.395(5) . ?
C60 H60 0.9500 . ?
C61 C62 1.395(5) . ?
C61 H61 0.9500 . ?
C62 C63 1.395(5) . ?
C62 H62 0.9500 . ?
C63 C64 1.394(5) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 84.30(6) . . ?
P1 Pt1 Si1 176.35(6) . . ?
P2 Pt1 Si1 94.00(6) . . ?
P1 Pt1 Si2 93.58(7) . . ?
P2 Pt1 Si2 175.22(7) . . ?
Si1 Pt1 Si2 88.36(7) . . ?
Si1 C2A H2A1 109.5 . . ?
Si1 C2A H2A2 109.5 . . ?
H2A1 C2A H2A2 109.5 . . ?
Si1 C2A H2A3 109.5 . . ?
H2A1 C2A H2A3 109.5 . . ?
H2A2 C2A H2A3 109.5 . . ?
Si1 C3A H3A1 109.5 . . ?
Si1 C3A H3A2 109.5 . . ?
H3A1 C3A H3A2 109.5 . . ?
Si1 C3A H3A3 109.5 . . ?
H3A1 C3A H3A3 109.5 . . ?
H3A2 C3A H3A3 109.5 . . ?
Si2 C4A H4A1 109.5 . . ?
Si2 C4A H4A2 109.5 . . ?
H4A1 C4A H4A2 109.5 . . ?
Si2 C4A H4A3 109.5 . . ?
H4A1 C4A H4A3 109.5 . . ?
H4A2 C4A H4A3 109.5 . . ?
C6A Si2 C4A 111.9(3) . . ?
Cl6 Si2 Cl4 98.6(3) . . ?
C6A Si2 Cl5 98.63(14) . . ?
C4A Si2 Cl5 93.1(4) . . ?
Cl6 Si2 Cl5 97.96(13) . . ?
Cl4 Si2 Cl5 105.9(3) . . ?
C6A Si2 Pt1 111.37(14) . . ?
C4A Si2 Pt1 121.7(4) . . ?
Cl6 Si2 Pt1 114.13(12) . . ?
Cl4 Si2 Pt1 119.9(3) . . ?
Cl5 Si2 Pt1 116.70(11) . . ?
Si2 C6A H6A1 109.5 . . ?
Si2 C6A H6A2 109.5 . . ?
H6A1 C6A H6A2 109.5 . . ?
Si2 C6A H6A3 109.5 . . ?
H6A1 C6A H6A3 109.5 . . ?
H6A2 C6A H6A3 109.5 . . ?
C1 P1 C21 105.7(3) . . ?
C1 P1 C15 105.8(3) . . ?
C21 P1 C15 106.2(3) . . ?
C1 P1 Pt1 107.2(2) . . ?
C21 P1 Pt1 115.2(2) . . ?
C15 P1 Pt1 115.9(2) . . ?
C3 P2 C2 105.7(3) . . ?
C3 P2 C9 106.0(3) . . ?
C2 P2 C9 106.0(3) . . ?
C3 P2 Pt1 116.5(2) . . ?
C2 P2 Pt1 107.0(2) . . ?
C9 P2 Pt1 114.8(2) . . ?
C3A Si1 C2A 88.8(9) . . ?
Cl3 Si1 Cl2 112.6(3) . . ?
C3A Si1 Cl1 99.4(5) . . ?
C2A Si1 Cl1 108.9(12) . . ?
Cl3 Si1 Cl1 100.3(3) . . ?
Cl2 Si1 Cl1 97.75(14) . . ?
C3A Si1 Pt1 122.1(4) . . ?
C2A Si1 Pt1 117.4(10) . . ?
Cl3 Si1 Pt1 112.6(3) . . ?
Cl2 Si1 Pt1 115.77(13) . . ?
Cl1 Si1 Pt1 116.11(10) . . ?
C2 C1 P1 108.7(5) . . ?
C2 C1 H1A 110.0 . . ?
P1 C1 H1A 110.0 . . ?
C2 C1 H1B 110.0 . . ?
P1 C1 H1B 110.0 . . ?
H1A C1 H1B 108.3 . . ?
C1 C2 P2 108.7(5) . . ?
C1 C2 H2A 110.0 . . ?
P2 C2 H2A 110.0 . . ?
C1 C2 H2B 110.0 . . ?
P2 C2 H2B 110.0 . . ?
H2A C2 H2B 108.3 . . ?
C4 C3 C8 108.4(5) . . ?
C4 C3 P2 116.5(5) . . ?
C8 C3 P2 112.5(5) . . ?
C4 C3 H3 106.2 . . ?
C8 C3 H3 106.2 . . ?
P2 C3 H3 106.2 . . ?
C5 C4 C3 109.7(6) . . ?
C5 C4 H4A 109.7 . . ?
C3 C4 H4A 109.7 . . ?
C5 C4 H4B 109.7 . . ?
C3 C4 H4B 109.7 . . ?
H4A C4 H4B 108.2 . . ?
C4 C5 C6 110.7(6) . . ?
C4 C5 H5A 109.5 . . ?
C6 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 108.1 . . ?
C7 C6 C5 110.5(6) . . ?
C7 C6 H6A 109.5 . . ?
C5 C6 H6A 109.5 . . ?
C7 C6 H6B 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
C8 C7 C6 111.8(7) . . ?
C8 C7 H7A 109.3 . . ?
C6 C7 H7A 109.3 . . ?
C8 C7 H7B 109.3 . . ?
C6 C7 H7B 109.3 . . ?
H7A C7 H7B 107.9 . . ?
C7 C8 C3 110.3(6) . . ?
C7 C8 H8A 109.6 . . ?
C3 C8 H8A 109.6 . . ?
C7 C8 H8B 109.6 . . ?
C3 C8 H8B 109.6 . . ?
H8A C8 H8B 108.1 . . ?
C10 C9 C14 111.3(6) . . ?
C10 C9 P2 115.9(5) . . ?
C14 C9 P2 112.0(5) . . ?
C10 C9 H9 105.6 . . ?
C14 C9 H9 105.6 . . ?
P2 C9 H9 105.6 . . ?
C9 C10 C11 110.0(6) . . ?
C9 C10 H10E 109.7 . . ?
C11 C10 H10E 109.7 . . ?
C9 C10 H10D 109.7 . . ?
C11 C10 H10D 109.7 . . ?
H10E C10 H10D 108.2 . . ?
C12 C11 C10 111.9(6) . . ?
C12 C11 H11E 109.2 . . ?
C10 C11 H11E 109.2 . . ?
C12 C11 H11D 109.2 . . ?
C10 C11 H11D 109.2 . . ?
H11E C11 H11D 107.9 . . ?
C11 C12 C13 110.8(6) . . ?
C11 C12 H12E 109.5 . . ?
C13 C12 H12E 109.5 . . ?
C11 C12 H12D 109.5 . . ?
C13 C12 H12D 109.5 . . ?
H12E C12 H12D 108.1 . . ?
C14 C13 C12 110.6(6) . . ?
C14 C13 H13E 109.5 . . ?
C12 C13 H13E 109.5 . . ?
C14 C13 H13D 109.5 . . ?
C12 C13 H13D 109.5 . . ?
H13E C13 H13D 108.1 . . ?
C13 C14 C9 111.0(6) . . ?
C13 C14 H14A 109.4 . . ?
C9 C14 H14A 109.4 . . ?
C13 C14 H14B 109.4 . . ?
C9 C14 H14B 109.4 . . ?
H14A C14 H14B 108.0 . . ?
C20 C15 C16 109.5(6) . . ?
C20 C15 P1 115.6(5) . . ?
C16 C15 P1 112.3(5) . . ?
C20 C15 H15 106.3 . . ?
C16 C15 H15 106.3 . . ?
P1 C15 H15 106.3 . . ?
C17 C16 C15 109.8(7) . . ?
C17 C16 H16A 109.7 . . ?
C15 C16 H16A 109.7 . . ?
C17 C16 H16B 109.7 . . ?
C15 C16 H16B 109.7 . . ?
H16A C16 H16B 108.2 . . ?
C16 C17 C18 110.8(8) . . ?
C16 C17 H17A 109.5 . . ?
C18 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C18 C17 H17B 109.5 . . ?
H17A C17 H17B 108.1 . . ?
C17 C18 C19 111.9(8) . . ?
C17 C18 H18A 109.2 . . ?
C19 C18 H18A 109.2 . . ?
C17 C18 H18B 109.2 . . ?
C19 C18 H18B 109.2 . . ?
H18A C18 H18B 107.9 . . ?
C18 C19 C20 110.5(7) . . ?
C18 C19 H19A 109.5 . . ?
C20 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C20 C19 H19B 109.5 . . ?
H19A C19 H19B 108.1 . . ?
C19 C20 C15 108.7(7) . . ?
C19 C20 H20A 110.0 . . ?
C15 C20 H20A 110.0 . . ?
C19 C20 H20B 110.0 . . ?
C15 C20 H20B 110.0 . . ?
H20A C20 H20B 108.3 . . ?
C26 C21 C22 110.8(6) . . ?
C26 C21 P1 115.9(5) . . ?
C22 C21 P1 111.7(5) . . ?
C26 C21 H21 105.9 . . ?
C22 C21 H21 105.9 . . ?
P1 C21 H21 105.9 . . ?
C21 C22 C23 110.8(6) . . ?
C21 C22 H22A 109.5 . . ?
C23 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C23 C22 H22B 109.5 . . ?
H22A C22 H22B 108.1 . . ?
C24 C23 C22 110.2(7) . . ?
C24 C23 H23A 109.6 . . ?
C22 C23 H23A 109.6 . . ?
C24 C23 H23B 109.6 . . ?
C22 C23 H23B 109.6 . . ?
H23A C23 H23B 108.1 . . ?
C23 C24 C25 110.7(7) . . ?
C23 C24 H24A 109.5 . . ?
C25 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C25 C24 H24B 109.5 . . ?
H24A C24 H24B 108.1 . . ?
C26 C25 C24 110.9(6) . . ?
C26 C25 H25A 109.5 . . ?
C24 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 108.0 . . ?
C25 C26 C21 111.3(6) . . ?
C25 C26 H26A 109.4 . . ?
C21 C26 H26A 109.4 . . ?
C25 C26 H26B 109.4 . . ?
C21 C26 H26B 109.4 . . ?
H26A C26 H26B 108.0 . . ?
Si3 Pt2 P4 177.36(6) . . ?
Si3 Pt2 Si4 87.50(6) . . ?
P4 Pt2 Si4 93.79(6) . . ?
Si3 Pt2 P3 94.08(6) . . ?
P4 Pt2 P3 84.78(6) . . ?
Si4 Pt2 P3 175.98(6) . . ?
Si3 C7A H7A1 109.5 . . ?
Si3 C7A H7A2 109.5 . . ?
H7A1 C7A H7A2 109.5 . . ?
Si3 C7A H7A3 109.5 . . ?
H7A1 C7A H7A3 109.5 . . ?
H7A2 C7A H7A3 109.5 . . ?
Si3 C8A H8A1 109.5 . . ?
Si3 C8A H8A2 109.5 . . ?
H8A1 C8A H8A2 109.5 . . ?
Si3 C8A H8A3 109.5 . . ?
H8A1 C8A H8A3 109.5 . . ?
H8A2 C8A H8A3 109.5 . . ?
Si3 C9A H9A1 109.5 . . ?
Si3 C9A H9A2 109.5 . . ?
H9A1 C9A H9A2 109.5 . . ?
Si3 C9A H9A3 109.5 . . ?
H9A1 C9A H9A3 109.5 . . ?
H9A2 C9A H9A3 109.5 . . ?
Si4 C10A H10A 109.5 . . ?
Si4 C10A H10B 109.5 . . ?
H10A C10A H10B 109.5 . . ?
Si4 C10A H10C 109.5 . . ?
H10A C10A H10C 109.5 . . ?
H10B C10A H10C 109.5 . . ?
Si4 C11A H11A 109.5 . . ?
Si4 C11A H11B 109.5 . . ?
H11A C11A H11B 109.5 . . ?
Si4 C11A H11C 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
Si4 C12A H12A 109.5 . . ?
Si4 C12A H12B 109.5 . . ?
H12A C12A H12B 109.5 . . ?
Si4 C12A H12C 109.5 . . ?
H12A C12A H12C 109.5 . . ?
H12B C12A H12C 109.5 . . ?
C47 P3 C27 105.0(3) . . ?
C47 P3 C41 107.5(3) . . ?
C27 P3 C41 105.8(3) . . ?
C47 P3 Pt2 113.9(2) . . ?
C27 P3 Pt2 106.1(2) . . ?
C41 P3 Pt2 117.5(2) . . ?
C35 P4 C28 104.5(3) . . ?
C35 P4 C29 107.4(3) . . ?
C28 P4 C29 106.5(3) . . ?
C35 P4 Pt2 114.0(2) . . ?
C28 P4 Pt2 106.9(2) . . ?
C29 P4 Pt2 116.6(2) . . ?
C7A Si3 C9A 101.7(4) . . ?
C7A Si3 C8A 93.52(12) . . ?
C9A Si3 C8A 104.5(3) . . ?
Cl8 Si3 Cl9 110.3(4) . . ?
Cl8 Si3 Cl7 100.95(10) . . ?
Cl9 Si3 Cl7 98.7(6) . . ?
C7A Si3 Pt2 116.02(11) . . ?
C9A Si3 Pt2 126.1(3) . . ?
C8A Si3 Pt2 109.63(10) . . ?
Cl8 Si3 Pt2 109.62(10) . . ?
Cl9 Si3 Pt2 119.7(5) . . ?
Cl7 Si3 Pt2 115.62(9) . . ?
C10A Si4 C12A 84(2) . . ?
C10A Si4 C11A 101.4(12) . . ?
C12A Si4 C11A 112.5(17) . . ?
Cl11 Si4 Cl12 108.3(2) . . ?
Cl11 Si4 Cl10 100.91(12) . . ?
Cl12 Si4 Cl10 99.6(3) . . ?
C10A Si4 Pt2 119.1(19) . . ?
C12A Si4 Pt2 125.0(4) . . ?
C11A Si4 Pt2 110.4(14) . . ?
Cl11 Si4 Pt2 110.62(10) . . ?
Cl12 Si4 Pt2 118.5(2) . . ?
Cl10 Si4 Pt2 117.07(10) . . ?
C28 C27 P3 109.7(5) . . ?
C28 C27 H27A 109.7 . . ?
P3 C27 H27A 109.7 . . ?
C28 C27 H27B 109.7 . . ?
P3 C27 H27B 109.7 . . ?
H27A C27 H27B 108.2 . . ?
C27 C28 P4 109.1(5) . . ?
C27 C28 H28A 109.9 . . ?
P4 C28 H28A 109.9 . . ?
C27 C28 H28B 109.9 . . ?
P4 C28 H28B 109.9 . . ?
H28A C28 H28B 108.3 . . ?
C30 C29 C34 109.3(6) . . ?
C30 C29 P4 114.9(5) . . ?
C34 C29 P4 111.2(5) . . ?
C30 C29 H29 107.0 . . ?
C34 C29 H29 107.0 . . ?
P4 C29 H29 107.0 . . ?
C29 C30 C31 110.1(6) . . ?
C29 C30 H30A 109.6 . . ?
C31 C30 H30A 109.6 . . ?
C29 C30 H30B 109.6 . . ?
C31 C30 H30B 109.6 . . ?
H30A C30 H30B 108.2 . . ?
C32 C31 C30 111.8(7) . . ?
C32 C31 H31A 109.2 . . ?
C30 C31 H31A 109.2 . . ?
C32 C31 H31B 109.2 . . ?
C30 C31 H31B 109.2 . . ?
H31A C31 H31B 107.9 . . ?
C31 C32 C33 110.7(8) . . ?
C31 C32 H32A 109.5 . . ?
C33 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C33 C32 H32B 109.5 . . ?
H32A C32 H32B 108.1 . . ?
C34 C33 C32 111.1(7) . . ?
C34 C33 H33A 109.4 . . ?
C32 C33 H33A 109.4 . . ?
C34 C33 H33B 109.4 . . ?
C32 C33 H33B 109.4 . . ?
H33A C33 H33B 108.0 . . ?
C33 C34 C29 109.8(7) . . ?
C33 C34 H34A 109.7 . . ?
C29 C34 H34A 109.7 . . ?
C33 C34 H34B 109.7 . . ?
C29 C34 H34B 109.7 . . ?
H34A C34 H34B 108.2 . . ?
C36 C35 C40 110.3(6) . . ?
C36 C35 P4 110.0(5) . . ?
C40 C35 P4 114.7(5) . . ?
C36 C35 H35 107.2 . . ?
C40 C35 H35 107.2 . . ?
P4 C35 H35 107.2 . . ?
C35 C36 C37 111.2(7) . . ?
C35 C36 H36A 109.4 . . ?
C37 C36 H36A 109.4 . . ?
C35 C36 H36B 109.4 . . ?
C37 C36 H36B 109.4 . . ?
H36A C36 H36B 108.0 . . ?
C38 C37 C36 110.3(7) . . ?
C38 C37 H37A 109.6 . . ?
C36 C37 H37A 109.6 . . ?
C38 C37 H37B 109.6 . . ?
C36 C37 H37B 109.6 . . ?
H37A C37 H37B 108.1 . . ?
C37 C38 C39 110.7(7) . . ?
C37 C38 H38A 109.5 . . ?
C39 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
C39 C38 H38B 109.5 . . ?
H38A C38 H38B 108.1 . . ?
C38 C39 C40 112.4(7) . . ?
C38 C39 H39A 109.1 . . ?
C40 C39 H39A 109.1 . . ?
C38 C39 H39B 109.1 . . ?
C40 C39 H39B 109.1 . . ?
H39A C39 H39B 107.8 . . ?
C39 C40 C35 109.9(7) . . ?
C39 C40 H40A 109.7 . . ?
C35 C40 H40A 109.7 . . ?
C39 C40 H40B 109.7 . . ?
C35 C40 H40B 109.7 . . ?
H40A C40 H40B 108.2 . . ?
C42 C41 C46 109.3(6) . . ?
C42 C41 P3 112.6(5) . . ?
C46 C41 P3 115.6(5) . . ?
C42 C41 H41 106.2 . . ?
C46 C41 H41 106.2 . . ?
P3 C41 H41 106.2 . . ?
C41 C42 C43 110.7(6) . . ?
C41 C42 H42A 109.5 . . ?
C43 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C43 C42 H42B 109.5 . . ?
H42A C42 H42B 108.1 . . ?
C44 C43 C42 110.4(7) . . ?
C44 C43 H43A 109.6 . . ?
C42 C43 H43A 109.6 . . ?
C44 C43 H43B 109.6 . . ?
C42 C43 H43B 109.6 . . ?
H43A C43 H43B 108.1 . . ?
C43 C44 C45 112.2(7) . . ?
C43 C44 H44A 109.2 . . ?
C45 C44 H44A 109.2 . . ?
C43 C44 H44B 109.2 . . ?
C45 C44 H44B 109.2 . . ?
H44A C44 H44B 107.9 . . ?
C44 C45 C46 110.7(7) . . ?
C44 C45 H45A 109.5 . . ?
C46 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
C46 C45 H45B 109.5 . . ?
H45A C45 H45B 108.1 . . ?
C45 C46 C41 110.1(6) . . ?
C45 C46 H46A 109.6 . . ?
C41 C46 H46A 109.6 . . ?
C45 C46 H46B 109.6 . . ?
C41 C46 H46B 109.6 . . ?
H46A C46 H46B 108.2 . . ?
C48 C47 C52 110.8(6) . . ?
C48 C47 P3 110.8(5) . . ?
C52 C47 P3 114.7(5) . . ?
C48 C47 H47 106.7 . . ?
C52 C47 H47 106.7 . . ?
P3 C47 H47 106.7 . . ?
C49 C48 C47 111.9(7) . . ?
C49 C48 H48A 109.2 . . ?
C47 C48 H48A 109.2 . . ?
C49 C48 H48B 109.2 . . ?
C47 C48 H48B 109.2 . . ?
H48A C48 H48B 107.9 . . ?
C50 C49 C48 110.2(7) . . ?
C50 C49 H49A 109.6 . . ?
C48 C49 H49A 109.6 . . ?
C50 C49 H49B 109.6 . . ?
C48 C49 H49B 109.6 . . ?
H49A C49 H49B 108.1 . . ?
C49 C50 C51 110.4(7) . . ?
C49 C50 H50A 109.6 . . ?
C51 C50 H50A 109.6 . . ?
C49 C50 H50B 109.6 . . ?
C51 C50 H50B 109.6 . . ?
H50A C50 H50B 108.1 . . ?
C50 C51 C52 111.6(7) . . ?
C50 C51 H51A 109.3 . . ?
C52 C51 H51A 109.3 . . ?
C50 C51 H51B 109.3 . . ?
C52 C51 H51B 109.3 . . ?
H51A C51 H51B 108.0 . . ?
C51 C52 C47 110.5(6) . . ?
C51 C52 H52A 109.6 . . ?
C47 C52 H52A 109.6 . . ?
C51 C52 H52B 109.6 . . ?
C47 C52 H52B 109.6 . . ?
H52A C52 H52B 108.1 . . ?
C54 C53 C58 119.5(8) . . ?
C54 C53 H53 120.3 . . ?
C58 C53 H53 120.3 . . ?
C53 C54 C55 119.8(7) . . ?
C53 C54 H54 120.1 . . ?
C55 C54 H54 120.1 . . ?
C54 C55 C56 120.1(7) . . ?
C54 C55 H55 119.9 . . ?
C56 C55 H55 119.9 . . ?
C57 C56 C55 119.9(8) . . ?
C57 C56 H56 120.0 . . ?
C55 C56 H56 120.0 . . ?
C56 C57 C58 120.5(8) . . ?
C56 C57 H57 119.7 . . ?
C58 C57 H57 119.7 . . ?
C57 C58 C53 120.1(7) . . ?
C57 C58 H58 119.9 . . ?
C53 C58 H58 119.9 . . ?
C64 C59 C60 122.0(11) . . ?
C64 C59 H59 119.0 . . ?
C60 C59 H59 119.0 . . ?
C59 C60 C61 119.7(10) . . ?
C59 C60 H60 120.2 . . ?
C61 C60 H60 120.2 . . ?
C60 C61 C62 118.8(10) . . ?
C60 C61 H61 120.6 . . ?
C62 C61 H61 120.6 . . ?
C61 C62 C63 117.6(10) . . ?
C61 C62 H62 121.2 . . ?
C63 C62 H62 121.2 . . ?
C64 C63 C62 120.6(11) . . ?
C64 C63 H63 119.7 . . ?
C62 C63 H63 119.7 . . ?
C59 C64 C63 121.3(13) . . ?
C59 C64 H64 119.4 . . ?
C63 C64 H64 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C21 P1 C1 C2 165.2(5) . . . . ?
C15 P1 C1 C2 -82.4(5) . . . . ?
Pt1 P1 C1 C2 41.8(5) . . . . ?
P1 C1 C2 P2 -54.1(5) . . . . ?
C3 P2 C2 C1 -82.8(5) . . . . ?
C9 P2 C2 C1 164.9(5) . . . . ?
Pt1 P2 C2 C1 42.0(5) . . . . ?
C2 P2 C3 C4 -26.4(6) . . . . ?
C9 P2 C3 C4 85.9(5) . . . . ?
Pt1 P2 C3 C4 -145.1(4) . . . . ?
C2 P2 C3 C8 99.7(5) . . . . ?
C9 P2 C3 C8 -148.0(5) . . . . ?
Pt1 P2 C3 C8 -19.0(6) . . . . ?
C8 C3 C4 C5 60.8(7) . . . . ?
P2 C3 C4 C5 -171.1(5) . . . . ?
C3 C4 C5 C6 -59.6(8) . . . . ?
C4 C5 C6 C7 55.9(9) . . . . ?
C5 C6 C7 C8 -55.0(10) . . . . ?
C6 C7 C8 C3 57.3(9) . . . . ?
C4 C3 C8 C7 -59.5(8) . . . . ?
P2 C3 C8 C7 170.2(5) . . . . ?
C3 P2 C9 C10 -46.4(6) . . . . ?
C2 P2 C9 C10 65.7(6) . . . . ?
Pt1 P2 C9 C10 -176.4(5) . . . . ?
C3 P2 C9 C14 -175.5(5) . . . . ?
C2 P2 C9 C14 -63.5(6) . . . . ?
Pt1 P2 C9 C14 54.4(6) . . . . ?
C14 C9 C10 C11 -55.1(8) . . . . ?
P2 C9 C10 C11 175.5(5) . . . . ?
C9 C10 C11 C12 55.9(8) . . . . ?
C10 C11 C12 C13 -57.0(8) . . . . ?
C11 C12 C13 C14 56.8(9) . . . . ?
C12 C13 C14 C9 -56.4(9) . . . . ?
C10 C9 C14 C13 56.1(8) . . . . ?
P2 C9 C14 C13 -172.4(5) . . . . ?
C1 P1 C15 C20 -25.7(6) . . . . ?
C21 P1 C15 C20 86.3(6) . . . . ?
Pt1 P1 C15 C20 -144.4(5) . . . . ?
C1 P1 C15 C16 100.9(6) . . . . ?
C21 P1 C15 C16 -147.1(6) . . . . ?
Pt1 P1 C15 C16 -17.8(6) . . . . ?
C20 C15 C16 C17 -60.6(9) . . . . ?
P1 C15 C16 C17 169.7(6) . . . . ?
C15 C16 C17 C18 57.2(11) . . . . ?
C16 C17 C18 C19 -55.4(11) . . . . ?
C17 C18 C19 C20 56.2(10) . . . . ?
C18 C19 C20 C15 -58.4(9) . . . . ?
C16 C15 C20 C19 60.8(8) . . . . ?
P1 C15 C20 C19 -171.2(5) . . . . ?
C1 P1 C21 C26 59.7(6) . . . . ?
C15 P1 C21 C26 -52.4(6) . . . . ?
Pt1 P1 C21 C26 177.9(5) . . . . ?
C1 P1 C21 C22 -68.4(6) . . . . ?
C15 P1 C21 C22 179.5(5) . . . . ?
Pt1 P1 C21 C22 49.8(6) . . . . ?
C26 C21 C22 C23 56.0(9) . . . . ?
P1 C21 C22 C23 -173.2(6) . . . . ?
C21 C22 C23 C24 -57.2(9) . . . . ?
C22 C23 C24 C25 57.6(9) . . . . ?
C23 C24 C25 C26 -57.3(9) . . . . ?
C24 C25 C26 C21 56.1(9) . . . . ?
C22 C21 C26 C25 -55.6(8) . . . . ?
P1 C21 C26 C25 175.9(5) . . . . ?
C47 P3 C27 C28 162.3(5) . . . . ?
C41 P3 C27 C28 -84.1(5) . . . . ?
Pt2 P3 C27 C28 41.4(5) . . . . ?
P3 C27 C28 P4 -53.8(6) . . . . ?
C35 P4 C28 C27 162.5(5) . . . . ?
C29 P4 C28 C27 -84.0(6) . . . . ?
Pt2 P4 C28 C27 41.3(5) . . . . ?
C35 P4 C29 C30 89.7(6) . . . . ?
C28 P4 C29 C30 -21.9(6) . . . . ?
Pt2 P4 C29 C30 -141.0(5) . . . . ?
C35 P4 C29 C34 -145.5(5) . . . . ?
C28 P4 C29 C34 103.0(6) . . . . ?
Pt2 P4 C29 C34 -16.1(6) . . . . ?
C34 C29 C30 C31 58.5(9) . . . . ?
P4 C29 C30 C31 -175.7(6) . . . . ?
C29 C30 C31 C32 -56.7(9) . . . . ?
C30 C31 C32 C33 54.8(10) . . . . ?
C31 C32 C33 C34 -55.9(11) . . . . ?
C32 C33 C34 C29 58.6(10) . . . . ?
C30 C29 C34 C33 -59.8(9) . . . . ?
P4 C29 C34 C33 172.2(6) . . . . ?
C28 P4 C35 C36 -72.4(6) . . . . ?
C29 P4 C35 C36 174.7(5) . . . . ?
Pt2 P4 C35 C36 43.9(6) . . . . ?
C28 P4 C35 C40 52.6(6) . . . . ?
C29 P4 C35 C40 -60.3(6) . . . . ?
Pt2 P4 C35 C40 168.9(5) . . . . ?
C40 C35 C36 C37 57.6(8) . . . . ?
P4 C35 C36 C37 -174.9(5) . . . . ?
C35 C36 C37 C38 -57.7(9) . . . . ?
C36 C37 C38 C39 56.0(10) . . . . ?
C37 C38 C39 C40 -56.2(10) . . . . ?
C38 C39 C40 C35 55.7(9) . . . . ?
C36 C35 C40 C39 -55.8(8) . . . . ?
P4 C35 C40 C39 179.3(6) . . . . ?
C47 P3 C41 C42 -148.1(5) . . . . ?
C27 P3 C41 C42 100.1(5) . . . . ?
Pt2 P3 C41 C42 -18.1(6) . . . . ?
C47 P3 C41 C46 85.3(6) . . . . ?
C27 P3 C41 C46 -26.5(6) . . . . ?
Pt2 P3 C41 C46 -144.7(5) . . . . ?
C46 C41 C42 C43 -58.9(8) . . . . ?
P3 C41 C42 C43 171.2(5) . . . . ?
C41 C42 C43 C44 56.6(9) . . . . ?
C42 C43 C44 C45 -54.9(10) . . . . ?
C43 C44 C45 C46 55.7(10) . . . . ?
C44 C45 C46 C41 -57.4(9) . . . . ?
C42 C41 C46 C45 59.1(8) . . . . ?
P3 C41 C46 C45 -172.6(5) . . . . ?
C27 P3 C47 C48 -63.0(6) . . . . ?
C41 P3 C47 C48 -175.4(5) . . . . ?
Pt2 P3 C47 C48 52.6(6) . . . . ?
C27 P3 C47 C52 63.3(6) . . . . ?
C41 P3 C47 C52 -49.1(6) . . . . ?
Pt2 P3 C47 C52 179.0(5) . . . . ?
C52 C47 C48 C49 55.1(9) . . . . ?
P3 C47 C48 C49 -176.4(5) . . . . ?
C47 C48 C49 C50 -57.1(10) . . . . ?
C48 C49 C50 C51 57.8(10) . . . . ?
C49 C50 C51 C52 -58.3(10) . . . . ?
C50 C51 C52 C47 56.0(9) . . . . ?
C48 C47 C52 C51 -53.9(9) . . . . ?
P3 C47 C52 C51 179.8(6) . . . . ?
C58 C53 C54 C55 -1.6(12) . . . . ?
C53 C54 C55 C56 1.7(12) . . . . ?
C54 C55 C56 C57 -1.2(12) . . . . ?
C55 C56 C57 C58 0.6(13) . . . . ?
C56 C57 C58 C53 -0.6(14) . . . . ?
C54 C53 C58 C57 1.1(13) . . . . ?
C64 C59 C60 C61 0(2) . . . . ?
C59 C60 C61 C62 -1(2) . . . . ?
C60 C61 C62 C63 0(2) . . . . ?
C61 C62 C63 C64 1(2) . . . . ?
C60 C59 C64 C63 1(2) . . . . ?
C62 C63 C64 C59 -1(2) . . . . ?

_refine_diff_density_max         4.647
_refine_diff_density_min         -3.000
_refine_diff_density_rms         0.172

_shelxl_version_number           2013-4


# start Validation Reply Form


_vrf_PLAT201_I                   
;
PROBLEM: Isotropic non-H Atoms in Main Residue(s) .......         12 Report
RESPONSE: In both independent molecules in the asymmetric unit all silicon 
bounded methyl groups show substitutional disorder with respect to the 
chloride substituents. In this disorder model of the crystal structure, 
along with distance restrains, the SUMP restrain have been applied in order 
to tie the three chlorine atoms of each silicon atom as two chlorine atoms. 
All atoms involved in disorder have been isotropically refined.
;
_vrf_PLAT971_I                   
;
PROBLEM: Check Calcd Residual Density  1.74A From     C16       4.66 eA-3  
RESPONSE: This residual electron density is not meaninfull. 
Higher residual electron density in this data set might be the  
result of extensive disorder as well as high 
absorption.
;
# end Validation Reply Form

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_PtI2(dcpe)_complex_11
_database_code_depnum_ccdc_archive 'CCDC 1439203'
_audit_update_record             
;
2015-11-26 deposited with the CCDC.
2016-02-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H48 I2 P2 Pt, C6 H6'
_chemical_formula_sum            'C32 H54 I2 P2 Pt'
_chemical_formula_weight         949.58

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_Int_Tables_number      14
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,1/2+y,1/2-z
-x,-y,-z
x,1/2-y,1/2+z

_cell_length_a                   12.1585(17)
_cell_length_b                   18.428(3)
_cell_length_c                   15.976(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.390(12)
_cell_angle_gamma                90.00
_cell_volume                     3509.1(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3710
_cell_measurement_theta_min      2.61
_cell_measurement_theta_max      28.40

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.797
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1840
_exptl_absorpt_coefficient_mu    5.868
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.2101
_exptl_absorpt_correction_T_max  0.4306
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
6 1 3 0.1180
-6 -3 -2 0.1410
0 -5 3 0.1560
0 5 -3 0.1050
0 -1 -1 0.0650
0 5 6 0.1110
-5 -4 5 0.1980
4 3 -5 0.2050

_exptl_absorpt_process_details   'STOE X-RED'

_exptl_special_details           
; 
 ? 
;

_diffrn_measurement_device       '2-circle goniometer'
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_detector                 'image plate (34 cm diameter)'
_diffrn_detector_type            STOE
_diffrn_detector_area_resol_mean 6.67
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_source_voltage           40
_diffrn_source_current           30
_diffrn_source_power             1.20
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_polarisn_norm  0
_diffrn_radiation_collimation    '0.5 mm diameter, monocapillary'
_diffrn_ambient_temperature      100(2)
_diffrn_measurement_method       'rotation method'
_diffrn_measurement_details      
; 540 frames, detector distance = 110 mm
;


_diffrn_reflns_number            88723
_diffrn_reflns_av_unetI/netI     0.0392
_diffrn_reflns_av_R_equivalents  0.0531
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         3.22
_diffrn_reflns_theta_max         28.00

_reflns_number_total             8448
_reflns_number_gt                6821
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'STOE X-AREA'
_computing_cell_refinement       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_solution    'SIR 97'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0534P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8448
_refine_ls_number_parameters     334
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0265
_refine_ls_wR_factor_ref         0.0747
_refine_ls_wR_factor_gt          0.0731
_refine_ls_goodness_of_fit_ref   0.906
_refine_ls_restrained_S_all      0.906
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3182(3) 0.6608(2) 0.9155(3) 0.0132(8) Uani 1 1 d . . .
H1A H 0.2948 0.6638 0.9700 0.016 Uiso 1 1 calc R . .
H1B H 0.3024 0.6121 0.8934 0.016 Uiso 1 1 calc R . .
C2 C 0.4444(3) 0.6744(2) 0.9293(3) 0.0132(8) Uani 1 1 d . . .
H2A H 0.4838 0.6295 0.9471 0.016 Uiso 1 1 calc R . .
H2B H 0.4655 0.7095 0.9749 0.016 Uiso 1 1 calc R . .
C3 C 0.1904(3) 0.7944(2) 0.9108(3) 0.0140(8) Uani 1 1 d . . .
H3 H 0.1657 0.7683 0.9573 0.017 Uiso 1 1 calc R . .
C4 C 0.2885(4) 0.8437(3) 0.9517(3) 0.0187(9) Uani 1 1 d . . .
H4A H 0.3491 0.8141 0.9825 0.022 Uiso 1 1 calc R . .
H4B H 0.3163 0.8695 0.9071 0.022 Uiso 1 1 calc R . .
C5 C 0.2526(4) 0.8983(3) 1.0127(3) 0.0236(10) Uani 1 1 d . . .
H5A H 0.2336 0.8728 1.0610 0.028 Uiso 1 1 calc R . .
H5B H 0.3147 0.9307 1.0342 0.028 Uiso 1 1 calc R . .
C6 C 0.1518(4) 0.9428(3) 0.9688(3) 0.0234(10) Uani 1 1 d . . .
H6A H 0.1730 0.9726 0.9245 0.028 Uiso 1 1 calc R . .
H6B H 0.1281 0.9749 1.0101 0.028 Uiso 1 1 calc R . .
C7 C 0.0549(4) 0.8932(3) 0.9297(4) 0.0262(11) Uani 1 1 d . . .
H7A H -0.0077 0.9223 0.9008 0.031 Uiso 1 1 calc R . .
H7B H 0.0303 0.8659 0.9746 0.031 Uiso 1 1 calc R . .
C8 C 0.0913(4) 0.8408(3) 0.8661(3) 0.0191(9) Uani 1 1 d . . .
H8A H 0.1131 0.8681 0.8200 0.023 Uiso 1 1 calc R . .
H8B H 0.0289 0.8096 0.8418 0.023 Uiso 1 1 calc R . .
C9 C 0.1097(3) 0.6766(2) 0.7927(3) 0.0145(8) Uani 1 1 d . . .
H9 H 0.0599 0.7115 0.7576 0.017 Uiso 1 1 calc R . .
C10 C 0.0443(4) 0.6452(3) 0.8577(3) 0.0209(9) Uani 1 1 d . . .
H10A H 0.0912 0.6109 0.8947 0.025 Uiso 1 1 calc R . .
H10B H 0.0242 0.6839 0.8929 0.025 Uiso 1 1 calc R . .
C11 C -0.0622(4) 0.6069(3) 0.8108(3) 0.0251(10) Uani 1 1 d . . .
H11A H -0.1004 0.5851 0.8524 0.030 Uiso 1 1 calc R . .
H11B H -0.1123 0.6425 0.7787 0.030 Uiso 1 1 calc R . .
C12 C -0.0367(4) 0.5490(3) 0.7507(3) 0.0270(11) Uani 1 1 d . . .
H12A H 0.0071 0.5108 0.7833 0.032 Uiso 1 1 calc R . .
H12B H -0.1063 0.5279 0.7204 0.032 Uiso 1 1 calc R . .
C13 C 0.0277(4) 0.5801(3) 0.6871(3) 0.0260(11) Uani 1 1 d . . .
H13A H -0.0189 0.6150 0.6509 0.031 Uiso 1 1 calc R . .
H13B H 0.0464 0.5415 0.6511 0.031 Uiso 1 1 calc R . .
C14 C 0.1350(4) 0.6171(3) 0.7330(3) 0.0205(9) Uani 1 1 d . . .
H14A H 0.1738 0.6379 0.6912 0.025 Uiso 1 1 calc R . .
H14B H 0.1841 0.5812 0.7656 0.025 Uiso 1 1 calc R . .
C15 C 0.6163(3) 0.7608(3) 0.8740(3) 0.0144(8) Uani 1 1 d . . .
H15 H 0.6484 0.7747 0.8247 0.017 Uiso 1 1 calc R . .
C16 C 0.7065(4) 0.7173(3) 0.9344(3) 0.0195(9) Uani 1 1 d . . .
H16A H 0.6768 0.7015 0.9835 0.023 Uiso 1 1 calc R . .
H16B H 0.7258 0.6745 0.9051 0.023 Uiso 1 1 calc R . .
C17 C 0.8114(4) 0.7626(3) 0.9645(3) 0.0226(9) Uani 1 1 d . . .
H17A H 0.8453 0.7744 0.9161 0.027 Uiso 1 1 calc R . .
H17B H 0.8653 0.7347 1.0048 0.027 Uiso 1 1 calc R . .
C18 C 0.7833(4) 0.8330(3) 1.0074(3) 0.0235(10) Uani 1 1 d . . .
H18A H 0.7560 0.8213 1.0588 0.028 Uiso 1 1 calc R . .
H18B H 0.8507 0.8620 1.0235 0.028 Uiso 1 1 calc R . .
C19 C 0.6944(4) 0.8764(3) 0.9471(3) 0.0220(10) Uani 1 1 d . . .
H19A H 0.6752 0.9193 0.9763 0.026 Uiso 1 1 calc R . .
H19B H 0.7245 0.8922 0.8982 0.026 Uiso 1 1 calc R . .
C20 C 0.5892(4) 0.8311(2) 0.9167(3) 0.0157(8) Uani 1 1 d . . .
H20A H 0.5356 0.8591 0.8764 0.019 Uiso 1 1 calc R . .
H20B H 0.5551 0.8195 0.9650 0.019 Uiso 1 1 calc R . .
C21 C 0.5371(4) 0.6264(2) 0.7840(3) 0.0158(8) Uani 1 1 d . . .
H21 H 0.5803 0.5976 0.8307 0.019 Uiso 1 1 calc R . .
C22 C 0.4367(4) 0.5801(3) 0.7427(3) 0.0211(10) Uani 1 1 d . . .
H22A H 0.3920 0.5686 0.7850 0.025 Uiso 1 1 calc R . .
H22B H 0.3900 0.6076 0.6973 0.025 Uiso 1 1 calc R . .
C23 C 0.4746(4) 0.5100(3) 0.7063(4) 0.0317(12) Uani 1 1 d . . .
H23A H 0.5127 0.4797 0.7527 0.038 Uiso 1 1 calc R . .
H23B H 0.4092 0.4837 0.6767 0.038 Uiso 1 1 calc R . .
C24 C 0.5528(4) 0.5243(3) 0.6448(4) 0.0298(12) Uani 1 1 d . . .
H24A H 0.5786 0.4785 0.6257 0.036 Uiso 1 1 calc R . .
H24B H 0.5127 0.5502 0.5952 0.036 Uiso 1 1 calc R . .
C25 C 0.6523(4) 0.5687(3) 0.6881(3) 0.0242(10) Uani 1 1 d . . .
H25A H 0.7008 0.5784 0.6480 0.029 Uiso 1 1 calc R . .
H25B H 0.6951 0.5413 0.7355 0.029 Uiso 1 1 calc R . .
C26 C 0.6140(4) 0.6402(3) 0.7209(3) 0.0207(9) Uani 1 1 d . . .
H26A H 0.5743 0.6686 0.6732 0.025 Uiso 1 1 calc R . .
H26B H 0.6789 0.6678 0.7487 0.025 Uiso 1 1 calc R . .
C100 C 0.3055(5) 0.4937(3) 1.0054(4) 0.0375(14) Uani 1 1 d . . .
H100 H 0.3573 0.5216 1.0426 0.045 Uiso 1 1 calc R . .
C101 C 0.1978(5) 0.4855(3) 1.0203(4) 0.0353(13) Uani 1 1 d . . .
H101 H 0.1764 0.5083 1.0665 0.042 Uiso 1 1 calc R . .
C102 C 0.1219(5) 0.4425(3) 0.9648(4) 0.0343(13) Uani 1 1 d . . .
H102 H 0.0497 0.4358 0.9746 0.041 Uiso 1 1 calc R . .
C103 C 0.1529(5) 0.4099(3) 0.8958(4) 0.0344(13) Uani 1 1 d . . .
H103 H 0.1022 0.3810 0.8591 0.041 Uiso 1 1 calc R . .
C104 C 0.2609(5) 0.4205(4) 0.8813(4) 0.0412(15) Uani 1 1 d . . .
H104 H 0.2820 0.3999 0.8338 0.049 Uiso 1 1 calc R . .
C105 C 0.3360(5) 0.4615(3) 0.9372(4) 0.0354(13) Uani 1 1 d . . .
H105 H 0.4088 0.4673 0.9282 0.042 Uiso 1 1 calc R . .
I1 I 0.47791(3) 0.822184(19) 0.65805(2) 0.02413(8) Uani 1 1 d . . .
I2 I 0.16771(3) 0.82137(2) 0.64429(2) 0.02800(8) Uani 1 1 d . . .
P1 P 0.23633(9) 0.72590(6) 0.84121(7) 0.0115(2) Uani 1 1 d . . .
P2 P 0.48870(8) 0.70827(6) 0.83285(7) 0.01104(19) Uani 1 1 d . . .
Pt1 Pt 0.343737(13) 0.766336(9) 0.751643(10) 0.01100(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.527(6) . ?
C1 P1 1.836(4) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 P2 1.838(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C8 1.534(6) . ?
C3 C4 1.539(6) . ?
C3 P1 1.840(4) . ?
C3 H3 0.9800 . ?
C4 C5 1.524(6) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.525(7) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.524(7) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.530(7) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C14 1.525(6) . ?
C9 C10 1.539(6) . ?
C9 P1 1.824(4) . ?
C9 H9 0.9800 . ?
C10 C11 1.534(6) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.508(7) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.512(7) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.525(6) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C20 1.530(6) . ?
C15 C16 1.536(6) . ?
C15 P2 1.836(4) . ?
C15 H15 0.9800 . ?
C16 C17 1.521(6) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.536(7) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 C19 1.525(7) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.525(6) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C26 1.525(6) . ?
C21 C22 1.528(6) . ?
C21 P2 1.847(4) . ?
C21 H21 0.9800 . ?
C22 C23 1.527(7) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.518(8) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 C25 1.511(7) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.526(6) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C100 C105 1.356(9) . ?
C100 C101 1.384(9) . ?
C100 H100 0.9300 . ?
C101 C102 1.394(9) . ?
C101 H101 0.9300 . ?
C102 C103 1.371(9) . ?
C102 H102 0.9300 . ?
C103 C104 1.392(8) . ?
C103 H103 0.9300 . ?
C104 C105 1.372(10) . ?
C104 H104 0.9300 . ?
C105 H105 0.9300 . ?
I1 Pt1 2.6306(5) . ?
I2 Pt1 2.6647(5) . ?
P1 Pt1 2.2463(11) . ?
P2 Pt1 2.2431(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 P1 112.8(3) . . ?
C2 C1 H1A 109.0 . . ?
P1 C1 H1A 109.0 . . ?
C2 C1 H1B 109.0 . . ?
P1 C1 H1B 109.0 . . ?
H1A C1 H1B 107.8 . . ?
C1 C2 P2 112.8(3) . . ?
C1 C2 H2A 109.0 . . ?
P2 C2 H2A 109.0 . . ?
C1 C2 H2B 109.0 . . ?
P2 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?
C8 C3 C4 109.8(4) . . ?
C8 C3 P1 113.9(3) . . ?
C4 C3 P1 111.0(3) . . ?
C8 C3 H3 107.2 . . ?
C4 C3 H3 107.2 . . ?
P1 C3 H3 107.2 . . ?
C5 C4 C3 111.5(4) . . ?
C5 C4 H4A 109.3 . . ?
C3 C4 H4A 109.3 . . ?
C5 C4 H4B 109.3 . . ?
C3 C4 H4B 109.3 . . ?
H4A C4 H4B 108.0 . . ?
C6 C5 C4 111.5(4) . . ?
C6 C5 H5A 109.3 . . ?
C4 C5 H5A 109.3 . . ?
C6 C5 H5B 109.3 . . ?
C4 C5 H5B 109.3 . . ?
H5A C5 H5B 108.0 . . ?
C5 C6 C7 110.6(4) . . ?
C5 C6 H6A 109.5 . . ?
C7 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C7 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
C6 C7 C8 110.5(4) . . ?
C6 C7 H7A 109.6 . . ?
C8 C7 H7A 109.6 . . ?
C6 C7 H7B 109.6 . . ?
C8 C7 H7B 109.6 . . ?
H7A C7 H7B 108.1 . . ?
C7 C8 C3 110.3(4) . . ?
C7 C8 H8A 109.6 . . ?
C3 C8 H8A 109.6 . . ?
C7 C8 H8B 109.6 . . ?
C3 C8 H8B 109.6 . . ?
H8A C8 H8B 108.1 . . ?
C14 C9 C10 110.3(4) . . ?
C14 C9 P1 111.5(3) . . ?
C10 C9 P1 114.0(3) . . ?
C14 C9 H9 106.9 . . ?
C10 C9 H9 106.9 . . ?
P1 C9 H9 106.9 . . ?
C11 C10 C9 110.0(4) . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10B 109.7 . . ?
C9 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C12 C11 C10 112.1(4) . . ?
C12 C11 H11A 109.2 . . ?
C10 C11 H11A 109.2 . . ?
C12 C11 H11B 109.2 . . ?
C10 C11 H11B 109.2 . . ?
H11A C11 H11B 107.9 . . ?
C13 C12 C11 111.0(4) . . ?
C13 C12 H12A 109.4 . . ?
C11 C12 H12A 109.4 . . ?
C13 C12 H12B 109.4 . . ?
C11 C12 H12B 109.4 . . ?
H12A C12 H12B 108.0 . . ?
C12 C13 C14 110.7(4) . . ?
C12 C13 H13A 109.5 . . ?
C14 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
C14 C13 H13B 109.5 . . ?
H13A C13 H13B 108.1 . . ?
C13 C14 C9 111.2(4) . . ?
C13 C14 H14A 109.4 . . ?
C9 C14 H14A 109.4 . . ?
C13 C14 H14B 109.4 . . ?
C9 C14 H14B 109.4 . . ?
H14A C14 H14B 108.0 . . ?
C20 C15 C16 110.6(4) . . ?
C20 C15 P2 111.4(3) . . ?
C16 C15 P2 113.4(3) . . ?
C20 C15 H15 107.0 . . ?
C16 C15 H15 107.0 . . ?
P2 C15 H15 107.0 . . ?
C17 C16 C15 111.3(4) . . ?
C17 C16 H16A 109.4 . . ?
C15 C16 H16A 109.4 . . ?
C17 C16 H16B 109.4 . . ?
C15 C16 H16B 109.4 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 111.0(4) . . ?
C16 C17 H17A 109.4 . . ?
C18 C17 H17A 109.4 . . ?
C16 C17 H17B 109.4 . . ?
C18 C17 H17B 109.4 . . ?
H17A C17 H17B 108.0 . . ?
C19 C18 C17 110.8(4) . . ?
C19 C18 H18A 109.5 . . ?
C17 C18 H18A 109.5 . . ?
C19 C18 H18B 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 108.1 . . ?
C20 C19 C18 111.0(4) . . ?
C20 C19 H19A 109.4 . . ?
C18 C19 H19A 109.4 . . ?
C20 C19 H19B 109.4 . . ?
C18 C19 H19B 109.4 . . ?
H19A C19 H19B 108.0 . . ?
C19 C20 C15 111.4(4) . . ?
C19 C20 H20A 109.3 . . ?
C15 C20 H20A 109.3 . . ?
C19 C20 H20B 109.3 . . ?
C15 C20 H20B 109.3 . . ?
H20A C20 H20B 108.0 . . ?
C26 C21 C22 110.5(4) . . ?
C26 C21 P2 115.5(3) . . ?
C22 C21 P2 110.1(3) . . ?
C26 C21 H21 106.8 . . ?
C22 C21 H21 106.8 . . ?
P2 C21 H21 106.8 . . ?
C23 C22 C21 111.2(4) . . ?
C23 C22 H22A 109.4 . . ?
C21 C22 H22A 109.4 . . ?
C23 C22 H22B 109.4 . . ?
C21 C22 H22B 109.4 . . ?
H22A C22 H22B 108.0 . . ?
C24 C23 C22 112.0(5) . . ?
C24 C23 H23A 109.2 . . ?
C22 C23 H23A 109.2 . . ?
C24 C23 H23B 109.2 . . ?
C22 C23 H23B 109.2 . . ?
H23A C23 H23B 107.9 . . ?
C25 C24 C23 110.2(4) . . ?
C25 C24 H24A 109.6 . . ?
C23 C24 H24A 109.6 . . ?
C25 C24 H24B 109.6 . . ?
C23 C24 H24B 109.6 . . ?
H24A C24 H24B 108.1 . . ?
C24 C25 C26 110.7(4) . . ?
C24 C25 H25A 109.5 . . ?
C26 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 108.1 . . ?
C25 C26 C21 110.6(4) . . ?
C25 C26 H26A 109.5 . . ?
C21 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26A C26 H26B 108.1 . . ?
C105 C100 C101 120.6(6) . . ?
C105 C100 H100 119.7 . . ?
C101 C100 H100 119.7 . . ?
C100 C101 C102 118.9(6) . . ?
C100 C101 H101 120.6 . . ?
C102 C101 H101 120.6 . . ?
C103 C102 C101 120.5(6) . . ?
C103 C102 H102 119.7 . . ?
C101 C102 H102 119.7 . . ?
C102 C103 C104 119.4(6) . . ?
C102 C103 H103 120.3 . . ?
C104 C103 H103 120.3 . . ?
C105 C104 C103 119.9(6) . . ?
C105 C104 H104 120.1 . . ?
C103 C104 H104 120.1 . . ?
C100 C105 C104 120.7(6) . . ?
C100 C105 H105 119.6 . . ?
C104 C105 H105 119.6 . . ?
C9 P1 C1 104.7(2) . . ?
C9 P1 C3 105.5(2) . . ?
C1 P1 C3 104.4(2) . . ?
C9 P1 Pt1 116.31(14) . . ?
C1 P1 Pt1 108.60(14) . . ?
C3 P1 Pt1 116.20(14) . . ?
C15 P2 C2 104.21(19) . . ?
C15 P2 C21 105.3(2) . . ?
C2 P2 C21 104.3(2) . . ?
C15 P2 Pt1 117.85(15) . . ?
C2 P2 Pt1 108.66(14) . . ?
C21 P2 Pt1 115.14(14) . . ?
P2 Pt1 P1 87.85(4) . . ?
P2 Pt1 I1 90.62(3) . . ?
P1 Pt1 I1 174.65(3) . . ?
P2 Pt1 I2 173.36(3) . . ?
P1 Pt1 I2 92.42(3) . . ?
I1 Pt1 I2 89.694(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 C2 P2 -34.3(4) . . . . ?
C8 C3 C4 C5 55.7(5) . . . . ?
P1 C3 C4 C5 -177.3(3) . . . . ?
C3 C4 C5 C6 -55.0(5) . . . . ?
C4 C5 C6 C7 55.6(5) . . . . ?
C5 C6 C7 C8 -57.7(6) . . . . ?
C6 C7 C8 C3 59.2(5) . . . . ?
C4 C3 C8 C7 -57.7(5) . . . . ?
P1 C3 C8 C7 177.0(3) . . . . ?
C14 C9 C10 C11 -55.5(5) . . . . ?
P1 C9 C10 C11 178.2(3) . . . . ?
C9 C10 C11 C12 55.7(6) . . . . ?
C10 C11 C12 C13 -56.3(6) . . . . ?
C11 C12 C13 C14 56.3(6) . . . . ?
C12 C13 C14 C9 -57.3(6) . . . . ?
C10 C9 C14 C13 57.0(5) . . . . ?
P1 C9 C14 C13 -175.4(3) . . . . ?
C20 C15 C16 C17 -55.6(5) . . . . ?
P2 C15 C16 C17 178.4(3) . . . . ?
C15 C16 C17 C18 56.2(5) . . . . ?
C16 C17 C18 C19 -56.4(5) . . . . ?
C17 C18 C19 C20 56.2(5) . . . . ?
C18 C19 C20 C15 -56.3(5) . . . . ?
C16 C15 C20 C19 55.6(5) . . . . ?
P2 C15 C20 C19 -177.3(3) . . . . ?
C26 C21 C22 C23 54.5(6) . . . . ?
P2 C21 C22 C23 -176.8(4) . . . . ?
C21 C22 C23 C24 -54.5(6) . . . . ?
C22 C23 C24 C25 55.9(6) . . . . ?
C23 C24 C25 C26 -57.9(6) . . . . ?
C24 C25 C26 C21 58.9(6) . . . . ?
C22 C21 C26 C25 -56.8(5) . . . . ?
P2 C21 C26 C25 177.5(3) . . . . ?
C105 C100 C101 C102 1.2(8) . . . . ?
C100 C101 C102 C103 -1.1(8) . . . . ?
C101 C102 C103 C104 -0.4(9) . . . . ?
C102 C103 C104 C105 1.9(9) . . . . ?
C101 C100 C105 C104 0.3(9) . . . . ?
C103 C104 C105 C100 -1.9(9) . . . . ?
C14 C9 P1 C1 -69.9(3) . . . . ?
C10 C9 P1 C1 55.7(4) . . . . ?
C14 C9 P1 C3 -179.7(3) . . . . ?
C10 C9 P1 C3 -54.1(4) . . . . ?
C14 C9 P1 Pt1 49.9(3) . . . . ?
C10 C9 P1 Pt1 175.5(3) . . . . ?
C2 C1 P1 C9 151.6(3) . . . . ?
C2 C1 P1 C3 -97.8(3) . . . . ?
C2 C1 P1 Pt1 26.8(3) . . . . ?
C8 C3 P1 C9 -51.6(4) . . . . ?
C4 C3 P1 C9 -176.2(3) . . . . ?
C8 C3 P1 C1 -161.6(3) . . . . ?
C4 C3 P1 C1 73.7(3) . . . . ?
C8 C3 P1 Pt1 78.8(3) . . . . ?
C4 C3 P1 Pt1 -45.8(3) . . . . ?
C20 C15 P2 C2 -70.6(3) . . . . ?
C16 C15 P2 C2 55.0(4) . . . . ?
C20 C15 P2 C21 179.9(3) . . . . ?
C16 C15 P2 C21 -54.5(4) . . . . ?
C20 C15 P2 Pt1 49.9(3) . . . . ?
C16 C15 P2 Pt1 175.4(3) . . . . ?
C1 C2 P2 C15 153.0(3) . . . . ?
C1 C2 P2 C21 -96.7(3) . . . . ?
C1 C2 P2 Pt1 26.6(3) . . . . ?
C26 C21 P2 C15 -50.8(4) . . . . ?
C22 C21 P2 C15 -176.8(3) . . . . ?
C26 C21 P2 C2 -160.2(3) . . . . ?
C22 C21 P2 C2 73.8(4) . . . . ?
C26 C21 P2 Pt1 80.8(3) . . . . ?
C22 C21 P2 Pt1 -45.2(4) . . . . ?
C15 P2 Pt1 P1 -126.10(16) . . . . ?
C2 P2 Pt1 P1 -7.97(15) . . . . ?
C21 P2 Pt1 P1 108.55(16) . . . . ?
C15 P2 Pt1 I1 48.77(16) . . . . ?
C2 P2 Pt1 I1 166.90(15) . . . . ?
C21 P2 Pt1 I1 -76.57(16) . . . . ?
C9 P1 Pt1 P2 -125.94(16) . . . . ?
C1 P1 Pt1 P2 -8.21(15) . . . . ?
C3 P1 Pt1 P2 108.99(16) . . . . ?
C9 P1 Pt1 I2 47.43(16) . . . . ?
C1 P1 Pt1 I2 165.15(15) . . . . ?
C3 P1 Pt1 I2 -77.65(15) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        28.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.440
_refine_diff_density_min         -2.227
_refine_diff_density_rms         0.186

