# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_140326_hx_10_34
_database_code_depnum_ccdc_archive 'CCDC 1013803'
_audit_update_record             
;
2014-07-13 deposited with the CCDC.
2015-06-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H34 O10'
_chemical_formula_sum            'C24 H34 O10'
_chemical_formula_weight         482.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'

_cell_length_a                   5.8507(10)
_cell_length_b                   14.177(2)
_cell_length_c                   30.834(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     2557.5(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3164
_cell_measurement_theta_min      3.0019
_cell_measurement_theta_max      29.5319

_exptl_crystal_description       needle
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.23
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.253
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1032
_exptl_absorpt_coefficient_mu    0.097
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9575
_exptl_absorpt_correction_T_max  0.9780
_exptl_absorpt_process_details   
;
CrysAlis PRO (Agilent Technologies, 2011) 
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.3592
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15536
_diffrn_reflns_av_R_equivalents  0.1325
_diffrn_reflns_av_sigmaI/netI    0.0705
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       4
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         25.35
_reflns_number_total             2706
_reflns_number_gt                2010
_reflns_threshold_expression     >2sigma(I)

_computing_cell_refinement       'CrysAlis PRO (Agilent Technologies, 2011)'
_computing_data_collection       'CrysAlis PRO'
_computing_data_reduction        'CrysAlis PRO'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  OLEX2
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1276P)²+0.5568P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.019(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   5(3)
_chemical_absolute_configuration unk
_refine_ls_number_reflns         2706
_refine_ls_number_parameters     313
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1020
_refine_ls_R_factor_gt           0.0800
_refine_ls_wR_factor_ref         0.2267
_refine_ls_wR_factor_gt          0.2036
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_restrained_S_all      1.094
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.7007(7) 0.6985(2) 0.11027(10) 0.0473(9) Uani 1 1 d . . .
O2 O 1.1256(11) 0.7980(6) 0.06461(16) 0.108(2) Uani 1 1 d . . .
O3 O 0.7892(8) 0.8703(3) 0.06500(12) 0.0590(11) Uani 1 1 d . . .
O4 O 0.6488(10) 0.9522(3) 0.20865(17) 0.0805(15) Uani 1 1 d . . .
O5 O 0.3767(7) 0.8630(2) 0.17843(11) 0.0511(10) Uani 1 1 d . . .
O6 O -0.0071(8) 0.6940(5) 0.22536(16) 0.0857(15) Uani 1 1 d . . .
O7 O 0.3784(6) 0.6936(3) 0.22827(10) 0.0474(9) Uani 1 1 d . . .
O8 O 0.6482(9) 0.4333(3) 0.19061(16) 0.0729(13) Uani 1 1 d . . .
O9 O 0.3594(7) 0.5317(2) 0.17341(11) 0.0496(9) Uani 1 1 d . . .
O10 O 0.6518(8) 0.5412(3) 0.09654(11) 0.0537(10) Uani 1 1 d . . .
C1 C 0.5957(11) 0.7861(3) 0.12223(16) 0.0455(12) Uani 1 1 d . . .
H1 H 0.4573 0.7955 0.1049 0.055 Uiso 1 1 calc R . .
C2 C 0.5327(10) 0.7854(3) 0.17019(15) 0.0439(12) Uani 1 1 d . . .
H2 H 0.6698 0.7910 0.1883 0.053 Uiso 1 1 calc R . .
C3 C 0.3973(10) 0.6967(3) 0.18210(14) 0.0427(11) Uani 1 1 d . . .
H3 H 0.2442 0.7004 0.1693 0.051 Uiso 1 1 calc R . .
C4 C 0.5172(10) 0.6089(3) 0.16565(15) 0.0422(12) Uani 1 1 d . . .
H4 H 0.6621 0.5988 0.1809 0.051 Uiso 1 1 calc R . .
C5 C 0.5549(11) 0.6196(3) 0.11698(16) 0.0471(13) Uani 1 1 d . . .
H5 H 0.4072 0.6328 0.1033 0.056 Uiso 1 1 calc R . .
C6 C 0.7686(12) 0.8612(4) 0.11099(17) 0.0540(14) Uani 1 1 d . . .
H6A H 0.7213 0.9210 0.1234 0.065 Uiso 1 1 calc R . .
H6B H 0.9158 0.8446 0.1233 0.065 Uiso 1 1 calc R . .
C7 C 0.9726(14) 0.8356(5) 0.04502(19) 0.0637(17) Uani 1 1 d . . .
C8 C 0.9645(17) 0.8465(6) -0.0027(2) 0.084(2) Uani 1 1 d . . .
H8A H 0.8083 0.8519 -0.0119 0.127 Uiso 1 1 calc R . .
H8B H 1.0330 0.7924 -0.0162 0.127 Uiso 1 1 calc R . .
H8C H 1.0468 0.9022 -0.0110 0.127 Uiso 1 1 calc R . .
C9 C 0.4537(12) 0.9408(4) 0.19928(18) 0.0549(15) Uani 1 1 d . . .
C10 C 0.2596(14) 1.0065(5) 0.2075(2) 0.0689(18) Uani 1 1 d . . .
H10A H 0.1910 1.0241 0.1804 0.103 Uiso 1 1 calc R . .
H10B H 0.3150 1.0618 0.2220 0.103 Uiso 1 1 calc R . .
H10C H 0.1479 0.9757 0.2254 0.103 Uiso 1 1 calc R . .
C11 C 0.1654(11) 0.6930(4) 0.24649(18) 0.0526(13) Uani 1 1 d . . .
C12 C 0.1836(12) 0.6922(4) 0.29429(17) 0.0611(15) Uani 1 1 d . . .
H12A H 0.2672 0.6374 0.3034 0.092 Uiso 1 1 calc R . .
H12B H 0.0333 0.6908 0.3067 0.092 Uiso 1 1 calc R . .
H12C H 0.2622 0.7480 0.3038 0.092 Uiso 1 1 calc R . .
C13 C 0.4470(11) 0.4471(4) 0.18507(18) 0.0524(14) Uani 1 1 d . . .
C14 C 0.2576(15) 0.3756(5) 0.1900(2) 0.074(2) Uani 1 1 d . . .
H14A H 0.1218 0.4066 0.2001 0.111 Uiso 1 1 calc R . .
H14B H 0.3028 0.3284 0.2106 0.111 Uiso 1 1 calc R . .
H14C H 0.2278 0.3464 0.1625 0.111 Uiso 1 1 calc R . .
C15 C 0.8939(11) 0.5268(4) 0.10454(19) 0.0574(15) Uani 1 1 d . . .
H15A H 0.9263 0.5299 0.1354 0.069 Uiso 1 1 calc R . .
H15B H 0.9838 0.5746 0.0898 0.069 Uiso 1 1 calc R . .
C16 C 0.9478(13) 0.4313(4) 0.08715(18) 0.0606(16) Uani 1 1 d . . .
H16 H 0.8861 0.3789 0.1010 0.073 Uiso 1 1 calc R . .
C17 C 1.0773(14) 0.4180(4) 0.05346(19) 0.0632(17) Uani 1 1 d . . .
C18 C 1.2041(14) 0.4081(4) 0.01861(19) 0.0662(17) Uani 1 1 d . . .
H18 H 1.3611 0.4029 0.0227 0.079 Uiso 1 1 calc R . .
C19 C 1.1188(13) 0.4046(4) -0.0269(2) 0.0652(18) Uani 1 1 d . . .
H19 H 1.2130 0.4480 -0.0440 0.078 Uiso 1 1 calc R . .
C20 C 1.1460(17) 0.3069(5) -0.0466(2) 0.085(2) Uani 1 1 d . . .
H20A H 1.3058 0.2888 -0.0455 0.102 Uiso 1 1 calc R . .
H20B H 1.0600 0.2619 -0.0294 0.102 Uiso 1 1 calc R . .
C21 C 1.064(2) 0.3028(7) -0.0931(3) 0.109(3) Uani 1 1 d . . .
H21A H 1.0776 0.2386 -0.1037 0.131 Uiso 1 1 calc R . .
H21B H 1.1610 0.3426 -0.1109 0.131 Uiso 1 1 calc R . .
C22 C 0.8183(19) 0.3351(6) -0.0972(3) 0.091(3) Uani 1 1 d . . .
H22A H 0.7740 0.3355 -0.1275 0.109 Uiso 1 1 calc R . .
H22B H 0.7191 0.2914 -0.0819 0.109 Uiso 1 1 calc R . .
C23 C 0.7908(18) 0.4317(5) -0.0786(2) 0.088(2) Uani 1 1 d . . .
H23A H 0.6312 0.4498 -0.0800 0.106 Uiso 1 1 calc R . .
H23B H 0.8777 0.4762 -0.0959 0.106 Uiso 1 1 calc R . .
C24 C 0.8720(15) 0.4364(5) -0.0316(2) 0.081(2) Uani 1 1 d . . .
H24A H 0.8575 0.5006 -0.0212 0.097 Uiso 1 1 calc R . .
H24B H 0.7750 0.3966 -0.0138 0.097 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C5 1.422(6) . ?
O1 C1 1.433(6) . ?
O2 C7 1.204(9) . ?
O3 C7 1.332(9) . ?
O3 C6 1.429(6) . ?
O4 C9 1.188(9) . ?
O5 C9 1.354(7) . ?
O5 C2 1.451(6) . ?
O6 C11 1.202(8) . ?
O7 C11 1.367(7) . ?
O7 C3 1.429(6) . ?
O8 C13 1.205(8) . ?
O9 C13 1.354(7) . ?
O9 C4 1.452(6) . ?
O10 C5 1.398(6) . ?
O10 C15 1.452(8) . ?
C1 C6 1.509(8) . ?
C1 C2 1.524(7) . ?
C1 H1 0.9800 . ?
C2 C3 1.531(7) . ?
C2 H2 0.9800 . ?
C3 C4 1.516(7) . ?
C3 H3 0.9800 . ?
C4 C5 1.524(7) . ?
C4 H4 0.9800 . ?
C5 H5 0.9800 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.481(9) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C10 1.490(9) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 C12 1.478(8) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 C14 1.509(9) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C16 1.491(8) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 C17 1.299(9) . ?
C16 H16 0.9300 . ?
C17 C18 1.313(9) . ?
C18 C19 1.491(9) . ?
C18 H18 0.9300 . ?
C19 C24 1.519(11) . ?
C19 C20 1.520(9) . ?
C19 H19 0.9800 . ?
C20 C21 1.513(11) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.516(14) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.493(11) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.527(11) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 O1 C1 112.7(4) . . ?
C7 O3 C6 119.5(5) . . ?
C9 O5 C2 119.4(5) . . ?
C11 O7 C3 118.7(4) . . ?
C13 O9 C4 118.1(5) . . ?
C5 O10 C15 115.5(4) . . ?
O1 C1 C6 105.3(5) . . ?
O1 C1 C2 110.4(3) . . ?
C6 C1 C2 112.9(4) . . ?
O1 C1 H1 109.4 . . ?
C6 C1 H1 109.4 . . ?
C2 C1 H1 109.4 . . ?
O5 C2 C1 108.5(4) . . ?
O5 C2 C3 104.7(4) . . ?
C1 C2 C3 111.3(4) . . ?
O5 C2 H2 110.7 . . ?
C1 C2 H2 110.7 . . ?
C3 C2 H2 110.7 . . ?
O7 C3 C4 110.1(4) . . ?
O7 C3 C2 107.7(4) . . ?
C4 C3 C2 110.8(4) . . ?
O7 C3 H3 109.4 . . ?
C4 C3 H3 109.4 . . ?
C2 C3 H3 109.4 . . ?
O9 C4 C3 105.6(4) . . ?
O9 C4 C5 109.2(4) . . ?
C3 C4 C5 108.3(4) . . ?
O9 C4 H4 111.1 . . ?
C3 C4 H4 111.1 . . ?
C5 C4 H4 111.1 . . ?
O10 C5 O1 108.5(4) . . ?
O10 C5 C4 115.1(4) . . ?
O1 C5 C4 107.9(4) . . ?
O10 C5 H5 108.4 . . ?
O1 C5 H5 108.4 . . ?
C4 C5 H5 108.4 . . ?
O3 C6 C1 110.4(5) . . ?
O3 C6 H6A 109.6 . . ?
C1 C6 H6A 109.6 . . ?
O3 C6 H6B 109.6 . . ?
C1 C6 H6B 109.6 . . ?
H6A C6 H6B 108.1 . . ?
O2 C7 O3 122.0(6) . . ?
O2 C7 C8 124.7(8) . . ?
O3 C7 C8 113.3(7) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O4 C9 O5 123.1(6) . . ?
O4 C9 C10 127.3(6) . . ?
O5 C9 C10 109.7(6) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O6 C11 O7 122.9(5) . . ?
O6 C11 C12 127.0(6) . . ?
O7 C11 C12 110.1(5) . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
O8 C13 O9 123.4(6) . . ?
O8 C13 C14 126.5(6) . . ?
O9 C13 C14 110.1(6) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
O10 C15 C16 105.9(5) . . ?
O10 C15 H15A 110.6 . . ?
C16 C15 H15A 110.6 . . ?
O10 C15 H15B 110.6 . . ?
C16 C15 H15B 110.6 . . ?
H15A C15 H15B 108.7 . . ?
C17 C16 C15 122.8(6) . . ?
C17 C16 H16 118.6 . . ?
C15 C16 H16 118.6 . . ?
C16 C17 C18 177.4(7) . . ?
C17 C18 C19 125.8(7) . . ?
C17 C18 H18 117.1 . . ?
C19 C18 H18 117.1 . . ?
C18 C19 C24 113.5(6) . . ?
C18 C19 C20 111.8(5) . . ?
C24 C19 C20 109.4(7) . . ?
C18 C19 H19 107.3 . . ?
C24 C19 H19 107.3 . . ?
C20 C19 H19 107.3 . . ?
C21 C20 C19 112.4(6) . . ?
C21 C20 H20A 109.1 . . ?
C19 C20 H20A 109.1 . . ?
C21 C20 H20B 109.1 . . ?
C19 C20 H20B 109.1 . . ?
H20A C20 H20B 107.9 . . ?
C20 C21 C22 111.5(8) . . ?
C20 C21 H21A 109.3 . . ?
C22 C21 H21A 109.3 . . ?
C20 C21 H21B 109.3 . . ?
C22 C21 H21B 109.3 . . ?
H21A C21 H21B 108.0 . . ?
C23 C22 C21 110.3(9) . . ?
C23 C22 H22A 109.6 . . ?
C21 C22 H22A 109.6 . . ?
C23 C22 H22B 109.6 . . ?
C21 C22 H22B 109.6 . . ?
H22A C22 H22B 108.1 . . ?
C22 C23 C24 111.8(6) . . ?
C22 C23 H23A 109.3 . . ?
C24 C23 H23A 109.3 . . ?
C22 C23 H23B 109.3 . . ?
C24 C23 H23B 109.3 . . ?
H23A C23 H23B 107.9 . . ?
C19 C24 C23 111.9(6) . . ?
C19 C24 H24A 109.2 . . ?
C23 C24 H24A 109.2 . . ?
C19 C24 H24B 109.2 . . ?
C23 C24 H24B 109.2 . . ?
H24A C24 H24B 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 O1 C1 C6 -177.3(4) . . . . ?
C5 O1 C1 C2 60.5(6) . . . . ?
C9 O5 C2 C1 -105.4(5) . . . . ?
C9 O5 C2 C3 135.7(5) . . . . ?
O1 C1 C2 O5 -165.4(4) . . . . ?
C6 C1 C2 O5 77.0(6) . . . . ?
O1 C1 C2 C3 -50.7(6) . . . . ?
C6 C1 C2 C3 -168.2(5) . . . . ?
C11 O7 C3 C4 -118.2(5) . . . . ?
C11 O7 C3 C2 120.9(5) . . . . ?
O5 C2 C3 O7 -72.5(5) . . . . ?
C1 C2 C3 O7 170.5(4) . . . . ?
O5 C2 C3 C4 167.0(4) . . . . ?
C1 C2 C3 C4 50.0(6) . . . . ?
C13 O9 C4 C3 -144.0(4) . . . . ?
C13 O9 C4 C5 99.6(5) . . . . ?
O7 C3 C4 O9 68.6(5) . . . . ?
C2 C3 C4 O9 -172.3(4) . . . . ?
O7 C3 C4 C5 -174.4(4) . . . . ?
C2 C3 C4 C5 -55.4(5) . . . . ?
C15 O10 C5 O1 46.8(6) . . . . ?
C15 O10 C5 C4 -74.2(6) . . . . ?
C1 O1 C5 O10 168.1(4) . . . . ?
C1 O1 C5 C4 -66.6(5) . . . . ?
O9 C4 C5 O10 -61.6(6) . . . . ?
C3 C4 C5 O10 -176.2(5) . . . . ?
O9 C4 C5 O1 177.1(4) . . . . ?
C3 C4 C5 O1 62.5(6) . . . . ?
C7 O3 C6 C1 -105.2(6) . . . . ?
O1 C1 C6 O3 70.3(6) . . . . ?
C2 C1 C6 O3 -169.2(4) . . . . ?
C6 O3 C7 O2 -1.6(10) . . . . ?
C6 O3 C7 C8 177.3(6) . . . . ?
C2 O5 C9 O4 5.6(8) . . . . ?
C2 O5 C9 C10 -174.9(4) . . . . ?
C3 O7 C11 O6 0.8(9) . . . . ?
C3 O7 C11 C12 -178.4(4) . . . . ?
C4 O9 C13 O8 2.3(8) . . . . ?
C4 O9 C13 C14 -178.0(4) . . . . ?
C5 O10 C15 C16 169.3(4) . . . . ?
O10 C15 C16 C17 112.2(8) . . . . ?
C15 C16 C17 C18 -37(17) . . . . ?
C16 C17 C18 C19 -54(17) . . . . ?
C17 C18 C19 C24 13.6(8) . . . . ?
C17 C18 C19 C20 -110.7(8) . . . . ?
C18 C19 C20 C21 -178.9(8) . . . . ?
C24 C19 C20 C21 54.6(10) . . . . ?
C19 C20 C21 C22 -56.0(11) . . . . ?
C20 C21 C22 C23 55.6(10) . . . . ?
C21 C22 C23 C24 -55.8(10) . . . . ?
C18 C19 C24 C23 -179.9(6) . . . . ?
C20 C19 C24 C23 -54.4(8) . . . . ?
C22 C23 C24 C19 56.5(10) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.35
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         0.317
_refine_diff_density_min         -0.304
_refine_diff_density_rms         0.074
