# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound1
_database_code_depnum_ccdc_archive 'CCDC 1046018'
_audit_update_record             
;
2015-01-28 deposited with the CCDC.
2015-05-22 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C80 H70 Ag15 K2 Mo24 N40 O82 P2'
_chemical_formula_weight         6964.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.554(5)
_cell_length_b                   14.649(5)
_cell_length_c                   20.459(7)
_cell_angle_alpha                83.042(7)
_cell_angle_beta                 77.036(7)
_cell_angle_gamma                64.534(6)
_cell_volume                     3836(2)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.015
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3267
_exptl_absorpt_coefficient_mu    3.929
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.539
_exptl_absorpt_correction_T_max  0.577
_exptl_absorpt_process_details   'SADABS, Sheldrick, 1996'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            20778
_diffrn_reflns_av_R_equivalents  0.0829
_diffrn_reflns_av_sigmaI/netI    0.1732
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.58
_diffrn_reflns_theta_max         24.71
_reflns_number_total             13071
_reflns_number_gt                6470
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 2001)'
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT+ (Bruker, 1999)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (1998)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1203P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         13071
_refine_ls_number_parameters     1069
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.1832
_refine_ls_R_factor_gt           0.0916
_refine_ls_wR_factor_ref         0.2481
_refine_ls_wR_factor_gt          0.2020
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_restrained_S_all      1.001
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 1.0000 -1.5000 0.5000 0.0257(19) Uani 1 2 d S . .
P2 P 1.5000 -1.5000 0.0000 0.034(2) Uani 1 2 d S . .
Mo1 Mo 0.79922(18) -1.29333(17) 0.59622(12) 0.0422(6) Uani 1 1 d . . .
Mo2 Mo 1.26196(17) -1.53332(17) 0.47409(13) 0.0434(6) Uani 1 1 d . . .
Mo3 Mo 1.06643(19) -1.35317(17) 0.59111(12) 0.0415(6) Uani 1 1 d . . .
Mo4 Mo 1.12745(17) -1.45320(16) 0.33793(11) 0.0357(6) Uani 1 1 d . . .
Mo5 Mo 0.85389(17) -1.38232(16) 0.37105(11) 0.0348(5) Uani 1 1 d . . .
Mo6 Mo 0.95501(17) -1.24582(15) 0.44586(11) 0.0329(5) Uani 1 1 d . . .
Mo7 Mo 1.7427(2) -1.4782(2) -0.04797(13) 0.0557(8) Uani 1 1 d . . .
Mo8 Mo 1.2847(2) -1.30993(18) 0.09764(12) 0.0476(7) Uani 1 1 d . . .
Mo9 Mo 1.7179(2) -1.66822(18) 0.07312(12) 0.0432(6) Uani 1 1 d . . .
Mo10 Mo 1.53526(18) -1.30619(18) 0.06612(12) 0.0418(6) Uani 1 1 d . . .
Mo11 Mo 1.48471(18) -1.70763(18) 0.10601(11) 0.0403(6) Uani 1 1 d . . .
Mo12 Mo 1.48919(17) -1.49713(16) 0.17567(10) 0.0335(5) Uani 1 1 d . . .
O1' O 0.987(2) -1.4272(18) 0.4439(12) 0.016(6) Uiso 0.50 1 d P . .
O1 O 1.107(2) -1.536(2) 0.4446(13) 0.023(7) Uiso 0.50 1 d P . .
O1W O 1.004(3) -1.494(3) 0.198(2) 0.199(18) Uani 1 1 d . . .
O2' O 0.968(2) -1.3903(19) 0.5215(13) 0.021(6) Uiso 0.50 1 d P . .
O2 O 0.9154(19) -1.4991(18) 0.4622(12) 0.012(6) Uiso 0.50 1 d P . .
O3 O 0.721(2) -1.3397(14) 0.5641(12) 0.091(9) Uani 1 1 d . . .
O4 O 1.1983(19) -1.4206(13) 0.5234(11) 0.086(8) Uani 1 1 d . . .
O5 O 1.1785(18) -1.5885(14) 0.3376(12) 0.084(8) Uani 1 1 d . . .
O6 O 0.7109(15) -1.2026(14) 0.6434(9) 0.059(5) Uani 1 1 d . . .
O7 O 1.0627(16) -1.3172(14) 0.3805(9) 0.061(5) Uiso 1 1 d . . .
O8 O 0.9977(15) -1.4244(14) 0.3219(10) 0.059(5) Uani 1 1 d U . .
O9 O 1.1009(14) -1.2816(13) 0.6297(9) 0.052(5) Uiso 1 1 d . . .
O10 O 0.8339(15) -1.2265(18) 0.5216(8) 0.069(6) Uani 1 1 d . . .
O11 O 1.1820(15) -1.4207(15) 0.2642(9) 0.061(6) Uani 1 1 d . . .
O12 O 1.2277(17) -1.4727(15) 0.3954(11) 0.070(6) Uani 1 1 d U . .
O13 O 0.8982(18) -1.5303(14) 0.3604(12) 0.091(9) Uani 1 1 d . . .
O14 O 1.0328(16) -1.2661(19) 0.5105(9) 0.079(7) Uani 1 1 d . . .
O15 O 0.9253(14) -1.3042(17) 0.6240(8) 0.064(6) Uani 1 1 d . . .
O16 O 1.3882(14) -1.5570(13) 0.4618(8) 0.046(5) Uiso 1 1 d . . .
O17 O 0.8616(13) -1.2731(15) 0.3987(9) 0.056(5) Uani 1 1 d . . .
O18 O 0.9326(16) -1.1279(14) 0.4220(12) 0.072(6) Uani 1 1 d . . .
O19 O 0.7533(18) -1.3877(13) 0.4405(10) 0.077(7) Uani 1 1 d . . .
O20 O 0.7949(15) -1.3381(12) 0.3084(9) 0.051(5) Uani 1 1 d . . .
O21' O 1.459(2) -1.585(2) 0.0157(16) 0.032(8) Uani 0.50 1 d P . .
O21 O 1.370(2) -1.4331(19) 0.0138(13) 0.020(6) Uiso 0.50 1 d P . .
O22' O 1.526(2) -1.5567(19) 0.0637(13) 0.020(6) Uiso 0.50 1 d P . .
O22 O 1.480(2) -1.441(2) 0.0598(14) 0.028(7) Uiso 0.50 1 d P . .
O23 O 1.774(2) -1.586(2) -0.1019(14) 0.115(9) Uani 1 1 d U . .
O24 O 1.768(3) -1.579(2) 0.0272(10) 0.126(12) Uani 1 1 d . . .
O25 O 1.255(2) -1.2745(17) 0.0169(11) 0.085(7) Uani 1 1 d U . .
O26 O 1.4920(15) -1.747(2) 0.0234(10) 0.099(10) Uani 1 1 d . . .
O27 O 1.5390(15) -1.3907(14) 0.1406(11) 0.073(7) Uani 1 1 d . . .
O28 O 1.4894(18) -1.499(2) 0.2535(10) 0.085(7) Uani 1 1 d . . .
O29 O 1.5431(19) -1.2112(14) 0.0971(11) 0.079(7) Uani 1 1 d . . .
O30 O 1.8167(13) -1.7537(12) 0.1054(10) 0.056(6) Uani 1 1 d . . .
O31 O 1.6240(12) -1.7366(11) 0.0948(10) 0.051(5) Uani 1 1 d . . .
O32 O 1.3362(14) -1.617(2) 0.1039(9) 0.088(9) Uani 1 1 d . . .
O33 O 1.4601(15) -1.6035(14) 0.1706(12) 0.072(7) Uani 1 1 d . . .
O34 O 1.8544(12) -1.4679(13) -0.0690(8) 0.043(4) Uani 1 1 d . . .
O35 O 1.6680(14) -1.384(2) 0.0246(8) 0.084(8) Uani 1 1 d . . .
O36 O 1.3836(13) -1.2604(12) 0.0856(10) 0.059(6) Uani 1 1 d . . .
O37 O 1.469(2) -1.7987(16) 0.1577(10) 0.085(8) Uani 1 1 d . . .
O38 O 1.3596(13) -1.4020(12) 0.1679(11) 0.065(6) Uani 1 1 d . . .
O39 O 1.6355(13) -1.5842(13) 0.1450(10) 0.058(5) Uani 1 1 d . . .
O40 O 1.1827(13) -1.2265(14) 0.1476(8) 0.050(5) Uani 1 1 d . . .
Ag1 Ag 1.12897(16) -1.20786(17) 0.27448(11) 0.0506(6) Uani 1 1 d . . .
Ag2 Ag 0.99068(18) -0.60656(15) 0.05740(10) 0.0485(6) Uani 1 1 d . . .
Ag3 Ag 0.93286(17) -0.92099(14) 0.29500(12) 0.0491(6) Uani 1 1 d . . .
Ag4 Ag 0.70774(16) -0.69900(14) 0.31599(10) 0.0422(5) Uani 1 1 d . . .
Ag5 Ag 1.0000 -1.0000 0.5000 0.0475(8) Uani 1 2 d S . .
Ag6 Ag 0.74058(17) -0.46894(15) 0.21063(10) 0.0493(6) Uani 1 1 d . . .
Ag7 Ag 0.71362(15) -1.18890(15) 0.22248(10) 0.0418(5) Uani 1 1 d . . .
Ag8 Ag 0.57732(14) -0.62321(13) 0.48880(9) 0.0367(5) Uani 1 1 d . . .
K1 K 1.0145(5) -1.3331(4) 0.1879(3) 0.0497(17) Uani 1 1 d . . .
C1 C 0.855(2) -1.2759(19) 0.0777(13) 0.041(6) Uani 1 1 d . . .
C2 C 0.866(2) -1.1773(19) 0.0683(12) 0.046(7) Uani 1 1 d . . .
C3 C 0.969(3) -1.187(2) 0.0650(16) 0.077(11) Uani 1 1 d . . .
H3A H 1.0132 -1.2244 0.0248 0.092 Uiso 1 1 calc R . .
C4 C 0.981(3) -1.097(3) 0.0625(19) 0.091(12) Uani 1 1 d . . .
H4A H 1.0460 -1.0990 0.0600 0.109 Uiso 1 1 calc R . .
C5 C 0.897(3) -1.008(3) 0.064(2) 0.103(14) Uani 1 1 d . . .
H5A H 0.9100 -0.9503 0.0615 0.123 Uiso 1 1 calc R . .
C6 C 0.797(3) -0.991(2) 0.0676(18) 0.090(13) Uani 1 1 d . . .
H6A H 0.7413 -0.9270 0.0697 0.108 Uiso 1 1 calc R . .
C7 C 0.788(3) -1.085(2) 0.0683(17) 0.067(9) Uani 1 1 d . . .
C8 C 0.680(3) -1.067(3) 0.0694(19) 0.107(15) Uani 1 1 d . . .
H8A H 0.6756 -1.1309 0.0698 0.161 Uiso 1 1 calc R . .
H8B H 0.6575 -1.0280 0.0303 0.161 Uiso 1 1 calc R . .
H8C H 0.6358 -1.0311 0.1089 0.161 Uiso 1 1 calc R . .
C9 C 0.8076(18) -1.0436(16) 0.2744(11) 0.029(5) Uani 1 1 d . . .
C10 C 0.7128(18) -0.9475(18) 0.2929(12) 0.034(6) Uani 1 1 d . . .
C11 C 0.6926(18) -0.8633(18) 0.2515(11) 0.037(6) Uani 1 1 d . . .
H11A H 0.7379 -0.8682 0.2106 0.044 Uiso 1 1 calc R . .
C12 C 0.612(2) -0.7751(19) 0.2660(13) 0.039(6) Uani 1 1 d . . .
H12A H 0.5835 -0.7370 0.2271 0.047 Uiso 1 1 calc R . .
C13 C 0.540(2) -0.767(2) 0.3237(15) 0.052(8) Uani 1 1 d . . .
H13A H 0.4795 -0.7077 0.3327 0.063 Uiso 1 1 calc R . .
C14 C 0.5587(18) -0.852(2) 0.3697(14) 0.050(8) Uani 1 1 d . . .
H14A H 0.5124 -0.8471 0.4102 0.060 Uiso 1 1 calc R . .
C15 C 0.6475(19) -0.9452(17) 0.3544(11) 0.032(6) Uiso 1 1 d . . .
C16 C 0.671(2) -1.030(2) 0.4039(13) 0.051(8) Uani 1 1 d . . .
H16A H 0.7332 -1.0858 0.3853 0.076 Uiso 1 1 calc R . .
H16B H 0.6145 -1.0496 0.4154 0.076 Uiso 1 1 calc R . .
H16C H 0.6810 -1.0087 0.4435 0.076 Uiso 1 1 calc R . .
C17 C 0.7759(16) -0.8385(15) 0.5118(10) 0.022(5) Uani 1 1 d . . .
C18 C 0.7598(18) -0.8327(16) 0.5847(13) 0.038(7) Uani 1 1 d . . .
C19 C 0.7337(18) -0.7402(17) 0.6113(14) 0.040(7) Uani 1 1 d . . .
H19A H 0.7322 -0.6854 0.5826 0.048 Uiso 1 1 calc R . .
C20 C 0.7096(19) -0.728(2) 0.6809(13) 0.048(7) Uani 1 1 d . . .
H20A H 0.6910 -0.6654 0.6981 0.057 Uiso 1 1 calc R . .
C21 C 0.714(2) -0.812(2) 0.7254(13) 0.046(7) Uani 1 1 d U . .
H21A H 0.6943 -0.8049 0.7716 0.055 Uiso 1 1 calc R . .
C22 C 0.748(2) -0.905(2) 0.6961(14) 0.048(7) Uani 1 1 d U . .
H22A H 0.7567 -0.9618 0.7243 0.057 Uiso 1 1 calc R . .
C23 C 0.7690(19) -0.9176(19) 0.6293(13) 0.039(6) Uani 1 1 d U . .
C24 C 0.796(3) -1.0195(18) 0.6049(16) 0.077(11) Uani 1 1 d . . .
H24A H 0.7984 -1.0661 0.6425 0.115 Uiso 1 1 calc R . .
H24B H 0.8623 -1.0427 0.5753 0.115 Uiso 1 1 calc R . .
H24C H 0.7442 -1.0155 0.5812 0.115 Uiso 1 1 calc R . .
C25 C 0.5682(16) -0.3688(17) 0.3479(11) 0.028(5) Uani 1 1 d . . .
C26 C 0.5420(17) -0.2645(16) 0.3309(12) 0.032(6) Uani 1 1 d . . .
C27 C 0.5437(16) -0.2366(16) 0.2599(12) 0.029(6) Uani 1 1 d . . .
H27A H 0.5613 -0.2858 0.2290 0.035 Uiso 1 1 calc R . .
C28 C 0.5196(18) -0.1383(16) 0.2386(11) 0.030(6) Uiso 1 1 d . . .
H28A H 0.5166 -0.1200 0.1937 0.036 Uiso 1 1 calc R . .
C29 C 0.499(2) -0.0640(19) 0.2852(16) 0.056(8) Uani 1 1 d . . .
H29A H 0.4894 0.0014 0.2699 0.067 Uiso 1 1 calc R . .
C30 C 0.494(2) -0.0876(18) 0.3518(14) 0.043(7) Uani 1 1 d . . .
H30A H 0.4735 -0.0370 0.3822 0.051 Uiso 1 1 calc R . .
C31 C 0.5179(18) -0.1855(17) 0.3744(12) 0.034(6) Uani 1 1 d . . .
C32 C 0.520(2) -0.2029(18) 0.4474(13) 0.048(7) Uani 1 1 d . . .
H32A H 0.5008 -0.1397 0.4675 0.072 Uiso 1 1 calc R . .
H32B H 0.5892 -0.2484 0.4533 0.072 Uiso 1 1 calc R . .
H32C H 0.4727 -0.2319 0.4685 0.072 Uiso 1 1 calc R . .
C33 C 1.0067(17) -0.7740(16) 0.1827(11) 0.027(5) Uani 1 1 d . . .
C34 C 1.115(2) -0.8462(19) 0.1581(13) 0.041(6) Uani 1 1 d . . .
C35 C 1.198(2) -0.8279(19) 0.1673(14) 0.047(7) Uani 1 1 d . . .
C36 C 1.295(3) -0.903(3) 0.1459(17) 0.077(10) Uani 1 1 d . . .
H36A H 1.3527 -0.8945 0.1512 0.092 Uiso 1 1 calc R . .
C37 C 1.311(3) -0.989(3) 0.117(2) 0.093(14) Uani 1 1 d . . .
H37A H 1.3782 -1.0372 0.1050 0.112 Uiso 1 1 calc R . .
C38 C 1.230(3) -1.006(3) 0.107(2) 0.104(16) Uani 1 1 d . . .
H38A H 1.2432 -1.0635 0.0849 0.125 Uiso 1 1 calc R . .
C39 C 1.125(3) -0.933(2) 0.1292(15) 0.068(10) Uani 1 1 d . . .
H39A H 1.0682 -0.9433 0.1249 0.082 Uiso 1 1 calc R . .
C40 C 1.182(3) -0.736(3) 0.2017(18) 0.090(12) Uani 1 1 d . . .
H40A H 1.1096 -0.6938 0.2137 0.136 Uiso 1 1 calc R . .
H40B H 1.2157 -0.6983 0.1718 0.136 Uiso 1 1 calc R . .
H40C H 1.2120 -0.7561 0.2414 0.136 Uiso 1 1 calc R . .
N1 N 0.7920(15) -1.2934(14) 0.1313(10) 0.037(5) Uani 1 1 d . . .
N2 N 0.8110(15) -1.3896(15) 0.1299(11) 0.042(5) Uani 1 1 d . . .
N3 N 0.8797(15) -1.4281(14) 0.0759(9) 0.030(4) Uiso 1 1 d . . .
N4 N 0.9076(15) -1.3583(13) 0.0420(9) 0.029(5) Uani 1 1 d . . .
N5 N 0.9032(15) -1.0509(14) 0.2758(10) 0.036(5) Uani 1 1 d . . .
N6 N 0.9715(14) -1.1452(12) 0.2581(10) 0.030(5) Uani 1 1 d . . .
N7 N 0.9175(15) -1.1903(13) 0.2406(11) 0.040(5) Uani 1 1 d . . .
N8 N 0.8146(15) -1.1275(14) 0.2522(11) 0.041(5) Uani 1 1 d . . .
N9 N 0.7082(13) -0.7756(13) 0.4742(9) 0.026(4) Uani 1 1 d . . .
N10 N 0.7535(15) -0.8060(14) 0.4102(9) 0.031(5) Uiso 1 1 d . . .
N11 N 0.8435(14) -0.8828(14) 0.4085(10) 0.032(5) Uani 1 1 d . . .
N12 N 0.8591(14) -0.9057(13) 0.4728(10) 0.034(5) Uani 1 1 d . . .
N13 N 0.5315(14) -0.4067(13) 0.4081(8) 0.025(4) Uiso 1 1 d . . .
N14 N 0.5768(14) -0.5098(14) 0.4028(8) 0.029(5) Uani 1 1 d . . .
N15 N 0.6370(14) -0.5292(13) 0.3448(10) 0.032(5) Uani 1 1 d . . .
N16 N 0.6368(14) -0.4482(14) 0.3097(10) 0.031(5) Uani 1 1 d . . .
N17 N 0.9615(15) -0.6783(14) 0.1578(9) 0.031(5) Uani 1 1 d . . .
N18 N 0.8626(15) -0.6387(15) 0.1935(9) 0.035(5) Uani 1 1 d U . .
N19 N 0.8487(16) -0.7086(13) 0.2366(10) 0.037(5) Uani 1 1 d . . .
N20 N 0.9368(15) -0.7929(15) 0.2305(9) 0.035(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1' 1.46(2) . ?
P1 O1' 1.46(2) 2_726 ?
P1 O2' 1.56(3) 2_726 ?
P1 O2' 1.56(3) . ?
P1 O2 1.59(2) . ?
P1 O2 1.59(2) 2_726 ?
P1 O1 1.62(3) 2_726 ?
P1 O1 1.62(3) . ?
P2 O22' 1.49(2) . ?
P2 O22' 1.49(2) 2_825 ?
P2 O22 1.49(3) 2_825 ?
P2 O22 1.49(3) . ?
P2 O21' 1.57(3) . ?
P2 O21' 1.57(3) 2_825 ?
P2 O21 1.69(3) 2_825 ?
P2 O21 1.69(3) . ?
Mo1 O6 1.624(18) . ?
Mo1 O10 1.81(2) . ?
Mo1 O3 1.818(19) . ?
Mo1 O15 1.978(17) . ?
Mo1 O5 2.02(2) 2_726 ?
Mo1 O1 2.42(3) 2_726 ?
Mo1 O2' 2.50(3) . ?
Mo2 O16 1.681(18) . ?
Mo2 O12 1.81(2) . ?
Mo2 O4 1.81(2) . ?
Mo2 O3 2.00(2) 2_726 ?
Mo2 O19 2.001(19) 2_726 ?
Mo2 O2 2.48(3) 2_726 ?
Mo2 O1 2.48(3) . ?
Mo3 O9 1.675(18) . ?
Mo3 O13 1.796(19) 2_726 ?
Mo3 O15 1.848(18) . ?
Mo3 O14 1.98(2) . ?
Mo3 O4 2.02(2) . ?
Mo3 O2 2.43(2) 2_726 ?
Mo3 O2' 2.48(3) . ?
Mo4 O11 1.658(18) . ?
Mo4 O5 1.794(18) . ?
Mo4 O8 1.847(18) . ?
Mo4 O12 1.980(18) . ?
Mo4 O7 2.013(19) . ?
Mo4 O1 2.39(3) . ?
Mo4 K1 3.701(6) . ?
Mo5 O20 1.617(16) . ?
Mo5 O17 1.815(18) . ?
Mo5 O19 1.818(19) . ?
Mo5 O8 1.967(19) . ?
Mo5 O13 2.002(19) . ?
Mo5 O2 2.42(2) . ?
Mo5 K1 4.111(7) . ?
Mo6 O18 1.647(17) . ?
Mo6 O7 1.824(19) . ?
Mo6 O14 1.845(18) . ?
Mo6 O10 2.010(18) . ?
Mo6 O17 2.022(17) . ?
Mo6 O2' 2.43(3) . ?
Mo6 O1' 2.50(2) . ?
Mo7 O34 1.654(15) . ?
Mo7 O32 1.85(2) 2_825 ?
Mo7 O23 1.87(3) . ?
Mo7 O35 1.94(2) . ?
Mo7 O24 1.98(2) . ?
Mo7 O21 2.44(3) 2_825 ?
Mo8 O40 1.674(18) . ?
Mo8 O25 1.76(2) . ?
Mo8 O36 1.831(18) . ?
Mo8 O38 2.01(2) . ?
Mo8 O23 2.03(3) 2_825 ?
Mo8 O21 2.37(3) . ?
Mo8 K1 4.090(8) . ?
Mo9 O30 1.658(16) . ?
Mo9 O24 1.83(2) . ?
Mo9 O39 1.868(19) . ?
Mo9 O31 1.967(17) . ?
Mo9 O25 2.00(2) 2_825 ?
Mo9 O21 2.40(3) 2_825 ?
Mo10 O29 1.653(18) . ?
Mo10 O27 1.84(2) . ?
Mo10 O35 1.833(19) . ?
Mo10 O26 1.96(2) 2_825 ?
Mo10 O36 1.969(17) . ?
Mo10 O21' 2.41(3) 2_825 ?
Mo10 O22 2.46(3) . ?
Mo11 O37 1.660(19) . ?
Mo11 O26 1.81(2) . ?
Mo11 O31 1.849(16) . ?
Mo11 O33 2.001(19) . ?
Mo11 O32 1.998(18) . ?
Mo11 O21' 2.39(3) . ?
Mo12 O28 1.59(2) . ?
Mo12 O33 1.801(18) . ?
Mo12 O38 1.829(17) . ?
Mo12 O39 1.953(18) . ?
Mo12 O27 1.99(2) . ?
Mo12 O22' 2.41(3) . ?
Mo12 O22 2.43(3) . ?
O1' O2' 1.66(3) . ?
O1' O2 1.73(3) . ?
O1' O1 1.79(4) . ?
O1 O2' 1.82(4) 2_726 ?
O1 Mo1 2.42(3) 2_726 ?
O1W K1 2.40(5) . ?
O2' O1 1.82(4) 2_726 ?
O2 Mo3 2.43(2) 2_726 ?
O2 Mo2 2.48(3) 2_726 ?
O3 Mo2 2.00(2) 2_726 ?
O5 Mo1 2.02(2) 2_726 ?
O8 K1 2.91(2) . ?
O11 K1 2.93(2) . ?
O13 Mo3 1.796(19) 2_726 ?
O19 Mo2 2.001(19) 2_726 ?
O21' O22 1.69(4) 2_825 ?
O21' O22' 1.72(4) . ?
O21' Mo10 2.41(3) 2_825 ?
O21 Mo9 2.40(2) 2_825 ?
O21 Mo7 2.44(3) 2_825 ?
O22' O22 1.53(4) . ?
O22 O21' 1.69(4) 2_825 ?
O23 Mo8 2.03(3) 2_825 ?
O23 K1 2.99(3) 2_825 ?
O25 Mo9 2.00(2) 2_825 ?
O26 Mo10 1.96(2) 2_825 ?
O32 Mo7 1.85(2) 2_825 ?
O40 Ag1 2.550(17) . ?
O40 K1 3.343(19) . ?
Ag1 N6 2.160(19) . ?
Ag1 C21 2.43(3) 2_736 ?
Ag1 C20 2.47(2) 2_736 ?
Ag1 K1 3.745(6) . ?
Ag2 N4 2.200(18) 2_735 ?
Ag2 N17 2.231(18) . ?
Ag2 N3 2.433(18) 1_565 ?
Ag3 N20 2.17(2) . ?
Ag3 N5 2.220(18) . ?
Ag3 N11 2.394(19) . ?
Ag4 N19 2.28(2) . ?
Ag4 N15 2.339(18) . ?
Ag4 N10 2.358(18) . ?
Ag4 C12 2.54(2) . ?
Ag5 N12 2.077(17) . ?
Ag5 N12 2.077(17) 2_736 ?
Ag6 N16 2.21(2) . ?
Ag6 N2 2.22(2) 1_565 ?
Ag6 N18 2.366(19) . ?
Ag7 N8 2.238(19) . ?
Ag7 N1 2.31(2) . ?
Ag7 C28 2.54(2) 1_545 ?
Ag7 K1 3.893(7) . ?
Ag8 N9 2.225(18) . ?
Ag8 N14 2.268(17) . ?
Ag8 N13 2.296(17) 2_646 ?
Ag8 Ag8 3.355(4) 2_646 ?
K1 N7 2.203(19) . ?
K1 O23 2.99(3) 2_825 ?
K1 N6 3.018(18) . ?
K1 C3 3.09(3) . ?
K1 N8 3.31(2) . ?
K1 C1 3.37(3) . ?
C1 N4 1.32(3) . ?
C1 N1 1.34(3) . ?
C1 C2 1.50(4) . ?
C2 C7 1.34(4) . ?
C2 C3 1.43(4) . ?
C3 C4 1.38(4) . ?
C3 H3A 0.9800 . ?
C4 C5 1.35(5) . ?
C4 H4A 0.9300 . ?
C5 C6 1.36(5) . ?
C5 H5A 0.9300 . ?
C6 C7 1.44(4) . ?
C6 H6A 0.9300 . ?
C7 C8 1.48(5) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 N8 1.32(3) . ?
C9 N5 1.36(3) . ?
C9 C10 1.50(3) . ?
C10 C11 1.37(3) . ?
C10 C15 1.39(3) . ?
C11 C12 1.33(3) . ?
C11 H11A 0.9300 . ?
C12 C13 1.38(4) . ?
C12 H12A 0.9800 . ?
C13 C14 1.44(4) . ?
C13 H13A 0.9300 . ?
C14 C15 1.42(3) . ?
C14 H14A 0.9300 . ?
C15 C16 1.47(3) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 N9 1.34(2) . ?
C17 N12 1.34(3) . ?
C17 C18 1.46(3) . ?
C18 C19 1.39(3) . ?
C18 C23 1.43(3) . ?
C19 C20 1.40(3) . ?
C19 H19A 0.9300 . ?
C20 C21 1.42(4) . ?
C20 Ag1 2.47(2) 2_736 ?
C20 H20A 0.9300 . ?
C21 C22 1.39(4) . ?
C21 Ag1 2.43(3) 2_736 ?
C21 H21A 0.9300 . ?
C22 C23 1.35(3) . ?
C22 H22A 0.9300 . ?
C23 C24 1.49(3) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 N16 1.35(3) . ?
C25 N13 1.38(3) . ?
C25 C26 1.43(3) . ?
C26 C31 1.42(3) . ?
C26 C27 1.46(3) . ?
C27 C28 1.37(3) . ?
C27 H27A 0.9300 . ?
C28 C29 1.43(3) . ?
C28 Ag7 2.54(2) 1_565 ?
C28 H28A 0.9300 . ?
C29 C30 1.36(4) . ?
C29 H29A 0.9300 . ?
C30 C31 1.37(3) . ?
C30 H30A 0.9300 . ?
C31 C32 1.49(3) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 N20 1.34(3) . ?
C33 N17 1.36(3) . ?
C33 C34 1.49(3) . ?
C34 C35 1.40(4) . ?
C34 C39 1.41(4) . ?
C35 C36 1.38(4) . ?
C35 C40 1.50(4) . ?
C36 C37 1.35(5) . ?
C36 H36A 0.9300 . ?
C37 C38 1.36(6) . ?
C37 H37A 0.9300 . ?
C38 C39 1.44(5) . ?
C38 H38A 0.9300 . ?
C39 H39A 0.9300 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
N1 N2 1.32(3) . ?
N2 N3 1.31(3) . ?
N2 Ag6 2.22(2) 1_545 ?
N3 N4 1.32(2) . ?
N3 Ag2 2.433(18) 1_545 ?
N4 Ag2 2.200(18) 2_735 ?
N5 N6 1.34(2) . ?
N6 N7 1.35(2) . ?
N7 N8 1.36(3) . ?
N9 N10 1.36(2) . ?
N10 N11 1.30(2) . ?
N11 N12 1.36(2) . ?
N13 N14 1.37(2) . ?
N13 Ag8 2.296(17) 2_646 ?
N14 N15 1.29(2) . ?
N15 N16 1.31(2) . ?
N17 N18 1.36(3) . ?
N18 N19 1.32(2) . ?
N19 N20 1.34(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1' P1 O1' 179.999(5) . 2_726 ?
O1' P1 O2' 113.0(13) . 2_726 ?
O1' P1 O2' 67.0(13) 2_726 2_726 ?
O1' P1 O2' 67.0(13) . . ?
O1' P1 O2' 113.0(13) 2_726 . ?
O2' P1 O2' 180.0(18) 2_726 . ?
O1' P1 O2 69.1(13) . . ?
O1' P1 O2 110.9(13) 2_726 . ?
O2' P1 O2 71.5(13) 2_726 . ?
O2' P1 O2 108.5(13) . . ?
O1' P1 O2 110.9(13) . 2_726 ?
O1' P1 O2 69.1(13) 2_726 2_726 ?
O2' P1 O2 108.5(13) 2_726 2_726 ?
O2' P1 O2 71.5(13) . 2_726 ?
O2 P1 O2 179.999(4) . 2_726 ?
O1' P1 O1 108.9(14) . 2_726 ?
O1' P1 O1 71.1(14) 2_726 2_726 ?
O2' P1 O1 110.2(14) 2_726 2_726 ?
O2' P1 O1 69.8(14) . 2_726 ?
O2 P1 O1 75.0(13) . 2_726 ?
O2 P1 O1 105.0(13) 2_726 2_726 ?
O1' P1 O1 71.1(14) . . ?
O1' P1 O1 108.9(14) 2_726 . ?
O2' P1 O1 69.8(14) 2_726 . ?
O2' P1 O1 110.2(14) . . ?
O2 P1 O1 105.0(13) . . ?
O2 P1 O1 75.0(13) 2_726 . ?
O1 P1 O1 179.999(5) 2_726 . ?
O22' P2 O22' 180(2) . 2_825 ?
O22' P2 O22 118.0(14) . 2_825 ?
O22' P2 O22 62.0(14) 2_825 2_825 ?
O22' P2 O22 62.0(14) . . ?
O22' P2 O22 118.0(14) 2_825 . ?
O22 P2 O22 180(2) 2_825 . ?
O22' P2 O21' 68.2(14) . . ?
O22' P2 O21' 111.8(14) 2_825 . ?
O22 P2 O21' 67.0(16) 2_825 . ?
O22 P2 O21' 113.0(16) . . ?
O22' P2 O21' 111.8(14) . 2_825 ?
O22' P2 O21' 68.2(14) 2_825 2_825 ?
O22 P2 O21' 113.0(16) 2_825 2_825 ?
O22 P2 O21' 67.0(16) . 2_825 ?
O21' P2 O21' 179.998(9) . 2_825 ?
O22' P2 O21 73.4(13) . 2_825 ?
O22' P2 O21 106.6(13) 2_825 2_825 ?
O22 P2 O21 77.3(14) 2_825 2_825 ?
O22 P2 O21 102.7(14) . 2_825 ?
O21' P2 O21 102.8(14) . 2_825 ?
O21' P2 O21 77.2(14) 2_825 2_825 ?
O22' P2 O21 106.6(13) . . ?
O22' P2 O21 73.4(13) 2_825 . ?
O22 P2 O21 102.7(14) 2_825 . ?
O22 P2 O21 77.3(14) . . ?
O21' P2 O21 77.2(14) . . ?
O21' P2 O21 102.8(14) 2_825 . ?
O21 P2 O21 179.998(2) 2_825 . ?
O6 Mo1 O10 103.0(10) . . ?
O6 Mo1 O3 101.5(11) . . ?
O10 Mo1 O3 98.8(9) . . ?
O6 Mo1 O15 100.4(9) . . ?
O10 Mo1 O15 87.2(8) . . ?
O3 Mo1 O15 155.3(10) . . ?
O6 Mo1 O5 100.0(10) . 2_726 ?
O10 Mo1 O5 155.3(10) . 2_726 ?
O3 Mo1 O5 85.3(8) . 2_726 ?
O15 Mo1 O5 79.8(8) . 2_726 ?
O6 Mo1 O1 156.7(10) . 2_726 ?
O10 Mo1 O1 98.5(10) . 2_726 ?
O3 Mo1 O1 66.0(10) . 2_726 ?
O15 Mo1 O1 89.5(9) . 2_726 ?
O5 Mo1 O1 60.8(9) 2_726 2_726 ?
O6 Mo1 O2' 158.6(10) . . ?
O10 Mo1 O2' 64.0(9) . . ?
O3 Mo1 O2' 97.4(11) . . ?
O15 Mo1 O2' 63.7(8) . . ?
O5 Mo1 O2' 91.4(9) 2_726 . ?
O1 Mo1 O2' 43.4(9) 2_726 . ?
O16 Mo2 O12 102.2(9) . . ?
O16 Mo2 O4 103.5(10) . . ?
O12 Mo2 O4 97.0(10) . . ?
O16 Mo2 O3 97.7(9) . 2_726 ?
O12 Mo2 O3 86.0(8) . 2_726 ?
O4 Mo2 O3 157.4(11) . 2_726 ?
O16 Mo2 O19 100.8(9) . 2_726 ?
O12 Mo2 O19 154.8(10) . 2_726 ?
O4 Mo2 O19 87.5(8) . 2_726 ?
O3 Mo2 O19 80.8(9) 2_726 2_726 ?
O16 Mo2 O2 157.6(8) . 2_726 ?
O12 Mo2 O2 98.2(9) . 2_726 ?
O4 Mo2 O2 64.5(9) . 2_726 ?
O3 Mo2 O2 92.8(10) 2_726 2_726 ?
O19 Mo2 O2 61.4(8) 2_726 2_726 ?
O16 Mo2 O1 154.8(9) . . ?
O12 Mo2 O1 63.1(9) . . ?
O4 Mo2 O1 98.8(10) . . ?
O3 Mo2 O1 62.6(9) 2_726 . ?
O19 Mo2 O1 91.8(10) 2_726 . ?
O2 Mo2 O1 46.4(8) 2_726 . ?
O9 Mo3 O13 103.8(11) . 2_726 ?
O9 Mo3 O15 102.1(9) . . ?
O13 Mo3 O15 96.6(10) 2_726 . ?
O9 Mo3 O14 99.0(9) . . ?
O13 Mo3 O14 155.5(11) 2_726 . ?
O15 Mo3 O14 87.2(8) . . ?
O9 Mo3 O4 100.2(9) . . ?
O13 Mo3 O4 88.3(8) 2_726 . ?
O15 Mo3 O4 155.2(9) . . ?
O14 Mo3 O4 78.9(9) . . ?
O9 Mo3 O2 157.9(9) . 2_726 ?
O13 Mo3 O2 63.1(10) 2_726 2_726 ?
O15 Mo3 O2 97.3(9) . 2_726 ?
O14 Mo3 O2 92.4(9) . 2_726 ?
O4 Mo3 O2 63.4(9) . 2_726 ?
O9 Mo3 O2' 157.0(9) . . ?
O13 Mo3 O2' 97.0(11) 2_726 . ?
O15 Mo3 O2' 65.5(8) . . ?
O14 Mo3 O2' 62.5(9) . . ?
O4 Mo3 O2' 89.9(10) . . ?
O2 Mo3 O2' 44.0(8) 2_726 . ?
O11 Mo4 O5 104.8(11) . . ?
O11 Mo4 O8 100.6(9) . . ?
O5 Mo4 O8 98.1(9) . . ?
O11 Mo4 O12 102.6(10) . . ?
O5 Mo4 O12 86.5(8) . . ?
O8 Mo4 O12 154.4(9) . . ?
O11 Mo4 O7 98.0(8) . . ?
O5 Mo4 O7 155.3(10) . . ?
O8 Mo4 O7 86.7(8) . . ?
O12 Mo4 O7 79.4(8) . . ?
O11 Mo4 O1 161.2(10) . . ?
O5 Mo4 O1 64.0(10) . . ?
O8 Mo4 O1 96.2(9) . . ?
O12 Mo4 O1 63.2(9) . . ?
O7 Mo4 O1 91.5(8) . . ?
O11 Mo4 K1 50.0(7) . . ?
O5 Mo4 K1 112.1(6) . . ?
O8 Mo4 K1 50.8(6) . . ?
O12 Mo4 K1 149.1(6) . . ?
O7 Mo4 K1 89.8(5) . . ?
O1 Mo4 K1 146.8(7) . . ?
O20 Mo5 O17 103.6(9) . . ?
O20 Mo5 O19 104.2(11) . . ?
O17 Mo5 O19 96.5(8) . . ?
O20 Mo5 O8 98.8(9) . . ?
O17 Mo5 O8 88.5(7) . . ?
O19 Mo5 O8 154.5(9) . . ?
O20 Mo5 O13 99.3(10) . . ?
O17 Mo5 O13 154.9(10) . . ?
O19 Mo5 O13 87.4(8) . . ?
O8 Mo5 O13 78.1(8) . . ?
O20 Mo5 O2 156.5(9) . . ?
O17 Mo5 O2 98.4(8) . . ?
O19 Mo5 O2 64.7(9) . . ?
O8 Mo5 O2 89.8(8) . . ?
O13 Mo5 O2 61.0(9) . . ?
O20 Mo5 K1 60.3(7) . . ?
O17 Mo5 K1 86.5(6) . . ?
O19 Mo5 K1 164.4(8) . . ?
O8 Mo5 K1 40.4(6) . . ?
O13 Mo5 K1 96.3(6) . . ?
O2 Mo5 K1 130.1(6) . . ?
O18 Mo6 O7 102.4(10) . . ?
O18 Mo6 O14 100.9(11) . . ?
O7 Mo6 O14 96.6(9) . . ?
O18 Mo6 O10 101.4(10) . . ?
O7 Mo6 O10 154.7(9) . . ?
O14 Mo6 O10 87.0(8) . . ?
O18 Mo6 O17 102.0(9) . . ?
O7 Mo6 O17 87.3(8) . . ?
O14 Mo6 O17 155.4(10) . . ?
O10 Mo6 O17 79.7(7) . . ?
O18 Mo6 O2' 158.5(10) . . ?
O7 Mo6 O2' 95.7(9) . . ?
O14 Mo6 O2' 65.1(10) . . ?
O10 Mo6 O2' 63.2(9) . . ?
O17 Mo6 O2' 90.4(9) . . ?
O18 Mo6 O1' 161.7(10) . . ?
O7 Mo6 O1' 66.2(9) . . ?
O14 Mo6 O1' 94.9(10) . . ?
O10 Mo6 O1' 88.6(9) . . ?
O17 Mo6 O1' 64.5(8) . . ?
O2' Mo6 O1' 39.5(8) . . ?
O34 Mo7 O32 102.4(9) . 2_825 ?
O34 Mo7 O23 99.0(11) . . ?
O32 Mo7 O23 93.5(12) 2_825 . ?
O34 Mo7 O35 102.7(9) . . ?
O32 Mo7 O35 88.4(9) 2_825 . ?
O23 Mo7 O35 157.3(12) . . ?
O34 Mo7 O24 101.6(11) . . ?
O32 Mo7 O24 155.6(12) 2_825 . ?
O23 Mo7 O24 86.5(11) . . ?
O35 Mo7 O24 82.6(10) . . ?
O34 Mo7 O21 155.9(9) . 2_825 ?
O32 Mo7 O21 96.9(10) 2_825 2_825 ?
O23 Mo7 O21 65.3(11) . 2_825 ?
O35 Mo7 O21 92.0(10) . 2_825 ?
O24 Mo7 O21 61.0(10) . 2_825 ?
O40 Mo8 O25 103.7(10) . . ?
O40 Mo8 O36 104.0(9) . . ?
O25 Mo8 O36 95.7(10) . . ?
O40 Mo8 O38 99.3(8) . . ?
O25 Mo8 O38 155.9(10) . . ?
O36 Mo8 O38 85.2(8) . . ?
O40 Mo8 O23 96.5(11) . 2_825 ?
O25 Mo8 O23 87.7(10) . 2_825 ?
O36 Mo8 O23 157.6(10) . 2_825 ?
O38 Mo8 O23 82.9(10) . 2_825 ?
O40 Mo8 O21 155.7(9) . . ?
O25 Mo8 O21 62.4(10) . . ?
O36 Mo8 O21 97.4(9) . . ?
O38 Mo8 O21 93.6(8) . . ?
O23 Mo8 O21 64.7(11) 2_825 . ?
O40 Mo8 K1 52.4(6) . . ?
O25 Mo8 K1 97.0(8) . . ?
O36 Mo8 K1 155.4(6) . . ?
O38 Mo8 K1 91.6(5) . . ?
O23 Mo8 K1 44.1(9) 2_825 . ?
O21 Mo8 K1 107.1(7) . . ?
O30 Mo9 O24 104.1(13) . . ?
O30 Mo9 O39 103.4(9) . . ?
O24 Mo9 O39 95.9(10) . . ?
O30 Mo9 O31 99.0(8) . . ?
O24 Mo9 O31 155.2(10) . . ?
O39 Mo9 O31 87.4(7) . . ?
O30 Mo9 O25 101.4(10) . 2_825 ?
O24 Mo9 O25 85.3(9) . 2_825 ?
O39 Mo9 O25 154.1(9) . 2_825 ?
O31 Mo9 O25 81.3(8) . 2_825 ?
O30 Mo9 O21 156.3(10) . 2_825 ?
O24 Mo9 O21 63.5(11) . 2_825 ?
O39 Mo9 O21 98.2(9) . 2_825 ?
O31 Mo9 O21 91.7(8) . 2_825 ?
O25 Mo9 O21 59.2(9) 2_825 2_825 ?
O29 Mo10 O27 100.8(10) . . ?
O29 Mo10 O35 105.0(12) . . ?
O27 Mo10 O35 94.5(9) . . ?
O29 Mo10 O26 102.2(11) . 2_825 ?
O27 Mo10 O26 155.8(11) . 2_825 ?
O35 Mo10 O26 86.8(8) . 2_825 ?
O29 Mo10 O36 99.5(10) . . ?
O27 Mo10 O36 87.5(8) . . ?
O35 Mo10 O36 154.6(9) . . ?
O26 Mo10 O36 81.4(8) 2_825 . ?
O29 Mo10 O21' 159.3(10) . 2_825 ?
O27 Mo10 O21' 99.0(10) . 2_825 ?
O35 Mo10 O21' 67.5(10) . 2_825 ?
O26 Mo10 O21' 59.2(11) 2_825 2_825 ?
O36 Mo10 O21' 87.1(9) . 2_825 ?
O29 Mo10 O22 158.9(11) . . ?
O27 Mo10 O22 64.3(10) . . ?
O35 Mo10 O22 91.5(11) . . ?
O26 Mo10 O22 91.6(11) 2_825 . ?
O36 Mo10 O22 66.5(8) . . ?
O21' Mo10 O22 40.6(10) 2_825 . ?
O37 Mo11 O26 104.4(12) . . ?
O37 Mo11 O31 104.7(11) . . ?
O26 Mo11 O31 95.9(9) . . ?
O37 Mo11 O33 101.6(10) . . ?
O26 Mo11 O33 152.4(11) . . ?
O31 Mo11 O33 86.5(8) . . ?
O37 Mo11 O32 99.5(12) . . ?
O26 Mo11 O32 86.4(9) . . ?
O31 Mo11 O32 154.3(10) . . ?
O33 Mo11 O32 80.2(9) . . ?
O37 Mo11 O21' 158.6(11) . . ?
O26 Mo11 O21' 61.2(12) . . ?
O31 Mo11 O21' 93.1(9) . . ?
O33 Mo11 O21' 91.3(9) . . ?
O32 Mo11 O21' 65.6(10) . . ?
O28 Mo12 O33 101.4(11) . . ?
O28 Mo12 O38 103.5(11) . . ?
O33 Mo12 O38 94.8(8) . . ?
O28 Mo12 O39 98.7(10) . . ?
O33 Mo12 O39 88.3(8) . . ?
O38 Mo12 O39 156.5(9) . . ?
O28 Mo12 O27 101.6(11) . . ?
O33 Mo12 O27 156.0(10) . . ?
O38 Mo12 O27 86.6(8) . . ?
O39 Mo12 O27 81.4(7) . . ?
O28 Mo12 O22' 159.7(11) . . ?
O33 Mo12 O22' 65.2(10) . . ?
O38 Mo12 O22' 93.2(9) . . ?
O39 Mo12 O22' 67.0(9) . . ?
O27 Mo12 O22' 90.8(9) . . ?
O28 Mo12 O22 162.5(12) . . ?
O33 Mo12 O22 94.9(10) . . ?
O38 Mo12 O22 68.6(9) . . ?
O39 Mo12 O22 88.0(9) . . ?
O27 Mo12 O22 63.2(10) . . ?
O22' Mo12 O22 36.9(9) . . ?
P1 O1' O2' 59.4(13) . . ?
P1 O1' O2 59.1(12) . . ?
O2' O1' O2 97.5(18) . . ?
P1 O1' O1 58.8(12) . . ?
O2' O1' O1 97.8(17) . . ?
O2 O1' O1 92.5(17) . . ?
P1 O1' Mo6 127.2(14) . . ?
O2' O1' Mo6 68.1(12) . . ?
O2 O1' Mo6 138.1(15) . . ?
O1 O1' Mo6 127.4(16) . . ?
P1 O1 O1' 50.2(11) . . ?
P1 O1 O2' 53.5(12) . 2_726 ?
O1' O1 O2' 88.2(17) . 2_726 ?
P1 O1 Mo4 124.1(14) . . ?
O1' O1 Mo4 74.1(12) . . ?
O2' O1 Mo4 131.7(16) 2_726 . ?
P1 O1 Mo1 123.6(14) . 2_726 ?
O1' O1 Mo1 141.2(17) . 2_726 ?
O2' O1 Mo1 70.5(12) 2_726 2_726 ?
Mo4 O1 Mo1 95.9(9) . 2_726 ?
P1 O1 Mo2 118.3(13) . . ?
O1' O1 Mo2 124.2(16) . . ?
O2' O1 Mo2 131.9(15) 2_726 . ?
Mo4 O1 Mo2 93.8(10) . . ?
Mo1 O1 Mo2 93.3(9) 2_726 . ?
P1 O2' O1' 53.6(12) . . ?
P1 O2' O1 56.8(12) . 2_726 ?
O1' O2' O1 91.9(17) . 2_726 ?
P1 O2' Mo6 125.7(14) . . ?
O1' O2' Mo6 72.4(12) . . ?
O1 O2' Mo6 138.8(16) 2_726 . ?
P1 O2' Mo3 121.3(14) . . ?
O1' O2' Mo3 137.6(17) . . ?
O1 O2' Mo3 121.2(14) 2_726 . ?
Mo6 O2' Mo3 93.3(9) . . ?
P1 O2' Mo1 122.6(15) . . ?
O1' O2' Mo1 127.6(16) . . ?
O1 O2' Mo1 66.1(12) 2_726 . ?
Mo6 O2' Mo1 93.2(9) . . ?
Mo3 O2' Mo1 92.0(9) . . ?
P1 O2 O1' 51.8(11) . . ?
P1 O2 Mo5 124.2(13) . . ?
O1' O2 Mo5 72.6(11) . . ?
P1 O2 Mo3 122.9(12) . 2_726 ?
O1' O2 Mo3 131.1(15) . 2_726 ?
Mo5 O2 Mo3 94.9(8) . 2_726 ?
P1 O2 Mo2 119.7(12) . 2_726 ?
O1' O2 Mo2 133.4(15) . 2_726 ?
Mo5 O2 Mo2 93.9(8) . 2_726 ?
Mo3 O2 Mo2 93.5(9) 2_726 2_726 ?
Mo1 O3 Mo2 138.1(13) . 2_726 ?
Mo2 O4 Mo3 138.2(12) . . ?
Mo4 O5 Mo1 139.0(14) . 2_726 ?
Mo6 O7 Mo4 139.8(12) . . ?
Mo4 O8 Mo5 139.4(11) . . ?
Mo4 O8 K1 99.8(8) . . ?
Mo5 O8 K1 113.5(8) . . ?
Mo1 O10 Mo6 139.2(12) . . ?
Mo4 O11 K1 104.2(9) . . ?
Mo2 O12 Mo4 139.8(12) . . ?
Mo3 O13 Mo5 140.3(15) 2_726 . ?
Mo6 O14 Mo3 138.6(13) . . ?
Mo3 O15 Mo1 138.6(10) . . ?
Mo5 O17 Mo6 137.5(11) . . ?
Mo5 O19 Mo2 139.7(13) . 2_726 ?
P2 O21' O22 54.2(14) . 2_825 ?
P2 O21' O22' 53.6(12) . . ?
O22 O21' O22' 97(2) 2_825 . ?
P2 O21' Mo11 127.8(15) . . ?
O22 O21' Mo11 141.8(19) 2_825 . ?
O22' O21' Mo11 74.2(13) . . ?
P2 O21' Mo10 125.2(17) . 2_825 ?
O22 O21' Mo10 71.1(14) 2_825 2_825 ?
O22' O21' Mo10 147.5(19) . 2_825 ?
Mo11 O21' Mo10 96.2(10) . 2_825 ?
P2 O21 Mo8 121.0(13) . . ?
P2 O21 Mo9 121.8(13) . 2_825 ?
Mo8 O21 Mo9 96.6(9) . 2_825 ?
P2 O21 Mo7 119.6(13) . 2_825 ?
Mo8 O21 Mo7 96.4(10) . 2_825 ?
Mo9 O21 Mo7 95.5(9) 2_825 2_825 ?
P2 O22' O22 58.9(14) . . ?
P2 O22' O21' 58.1(13) . . ?
O22 O22' O21' 103(2) . . ?
P2 O22' Mo12 130.5(15) . . ?
O22 O22' Mo12 72.0(14) . . ?
O21' O22' Mo12 135.7(19) . . ?
P2 O22 O22' 59.1(14) . . ?
P2 O22 O21' 58.9(14) . 2_825 ?
O22' O22 O21' 104(2) . 2_825 ?
P2 O22 Mo12 129.7(16) . . ?
O22' O22 Mo12 71.1(14) . . ?
O21' O22 Mo12 147.6(19) 2_825 . ?
P2 O22 Mo10 127.1(16) . . ?
O22' O22 Mo10 138(2) . . ?
O21' O22 Mo10 68.3(14) 2_825 . ?
Mo12 O22 Mo10 93.8(10) . . ?
Mo7 O23 Mo8 133.6(16) . 2_825 ?
Mo7 O23 K1 116.0(12) . 2_825 ?
Mo8 O23 K1 107.6(11) 2_825 2_825 ?
Mo9 O24 Mo7 139.9(16) . . ?
Mo8 O25 Mo9 141.6(14) . 2_825 ?
Mo11 O26 Mo10 142.6(17) . 2_825 ?
Mo10 O27 Mo12 137.7(13) . . ?
Mo11 O31 Mo9 140.2(9) . . ?
Mo7 O32 Mo11 139.5(11) 2_825 . ?
Mo12 O33 Mo11 140.6(14) . . ?
Mo10 O35 Mo7 140.7(11) . . ?
Mo8 O36 Mo10 140.8(10) . . ?
Mo12 O38 Mo8 139.5(11) . . ?
Mo9 O39 Mo12 138.0(10) . . ?
Mo8 O40 Ag1 133.5(9) . . ?
Mo8 O40 K1 104.2(8) . . ?
Ag1 O40 K1 77.6(5) . . ?
N6 Ag1 C21 150.1(8) . 2_736 ?
N6 Ag1 C20 167.5(8) . 2_736 ?
C21 Ag1 C20 33.8(8) 2_736 2_736 ?
N6 Ag1 O40 85.8(6) . . ?
C21 Ag1 O40 89.0(7) 2_736 . ?
C20 Ag1 O40 106.7(7) 2_736 . ?
N6 Ag1 K1 53.7(5) . . ?
C21 Ag1 K1 143.8(6) 2_736 . ?
C20 Ag1 K1 132.7(7) 2_736 . ?
O40 Ag1 K1 60.7(4) . . ?
N4 Ag2 N17 141.4(7) 2_735 . ?
N4 Ag2 N3 115.4(6) 2_735 1_565 ?
N17 Ag2 N3 102.8(6) . 1_565 ?
N20 Ag3 N5 130.5(7) . . ?
N20 Ag3 N11 115.9(7) . . ?
N5 Ag3 N11 102.3(7) . . ?
N19 Ag4 N15 101.0(6) . . ?
N19 Ag4 N10 112.4(7) . . ?
N15 Ag4 N10 110.5(7) . . ?
N19 Ag4 C12 106.6(8) . . ?
N15 Ag4 C12 123.4(7) . . ?
N10 Ag4 C12 103.0(8) . . ?
N12 Ag5 N12 179.998(2) . 2_736 ?
N16 Ag6 N2 143.1(7) . 1_565 ?
N16 Ag6 N18 112.5(7) . . ?
N2 Ag6 N18 100.9(7) 1_565 . ?
N8 Ag7 N1 114.4(7) . . ?
N8 Ag7 C28 135.9(7) . 1_545 ?
N1 Ag7 C28 106.9(7) . 1_545 ?
N8 Ag7 K1 58.2(5) . . ?
N1 Ag7 K1 62.0(5) . . ?
C28 Ag7 K1 165.3(5) 1_545 . ?
N9 Ag8 N14 115.4(6) . . ?
N9 Ag8 N13 117.1(6) . 2_646 ?
N14 Ag8 N13 127.2(6) . 2_646 ?
N9 Ag8 Ag8 167.0(4) . 2_646 ?
N14 Ag8 Ag8 60.0(4) . 2_646 ?
N13 Ag8 Ag8 67.5(4) 2_646 2_646 ?
N7 K1 O1W 132.1(12) . . ?
N7 K1 O8 83.8(7) . . ?
O1W K1 O8 63.0(10) . . ?
N7 K1 O11 100.3(7) . . ?
O1W K1 O11 88.4(10) . . ?
O8 K1 O11 55.1(5) . . ?
N7 K1 O23 133.6(8) . 2_825 ?
O1W K1 O23 93.1(11) . 2_825 ?
O8 K1 O23 115.6(7) . 2_825 ?
O11 K1 O23 66.3(6) . 2_825 ?
N7 K1 N6 24.0(6) . . ?
O1W K1 N6 146.5(11) . . ?
O8 K1 N6 85.4(5) . . ?
O11 K1 N6 81.7(5) . . ?
O23 K1 N6 111.6(6) 2_825 . ?
N7 K1 C3 80.8(9) . . ?
O1W K1 C3 123.7(11) . . ?
O8 K1 C3 162.8(9) . . ?
O11 K1 C3 135.7(8) . . ?
O23 K1 C3 81.0(9) 2_825 . ?
N6 K1 C3 83.7(7) . . ?
N7 K1 N8 16.8(6) . . ?
O1W K1 N8 121.1(11) . . ?
O8 K1 N8 86.6(6) . . ?
O11 K1 N8 114.8(5) . . ?
O23 K1 N8 145.5(6) 2_825 . ?
N6 K1 N8 40.6(5) . . ?
C3 K1 N8 76.5(8) . . ?
N7 K1 O40 82.0(6) . . ?
O1W K1 O40 142.4(11) . . ?
O8 K1 O40 116.3(5) . . ?
O11 K1 O40 67.2(5) . . ?
O23 K1 O40 51.6(6) 2_825 . ?
N6 K1 O40 60.5(5) . . ?
C3 K1 O40 69.2(7) . . ?
N8 K1 O40 95.6(5) . . ?
N7 K1 C1 92.4(7) . . ?
O1W K1 C1 84.2(10) . . ?
O8 K1 C1 128.8(6) . . ?
O11 K1 C1 167.3(6) . . ?
O23 K1 C1 103.6(7) 2_825 . ?
N6 K1 C1 110.1(6) . . ?
C3 K1 C1 44.7(8) . . ?
N8 K1 C1 77.9(6) . . ?
O40 K1 C1 113.6(5) . . ?
N7 K1 Mo4 91.2(6) . . ?
O1W K1 Mo4 76.6(10) . . ?
O8 K1 Mo4 29.5(4) . . ?
O11 K1 Mo4 25.7(4) . . ?
O23 K1 Mo4 90.0(6) 2_825 . ?
N6 K1 Mo4 80.8(4) . . ?
C3 K1 Mo4 157.9(6) . . ?
N8 K1 Mo4 101.2(4) . . ?
O40 K1 Mo4 89.3(3) . . ?
C1 K1 Mo4 157.1(5) . . ?
N7 K1 Ag1 58.5(5) . . ?
O1W K1 Ag1 135.6(10) . . ?
O8 K1 Ag1 78.9(4) . . ?
O11 K1 Ag1 49.6(4) . . ?
O23 K1 Ag1 83.2(5) 2_825 . ?
N6 K1 Ag1 35.2(4) . . ?
C3 K1 Ag1 99.5(6) . . ?
N8 K1 Ag1 75.3(3) . . ?
O40 K1 Ag1 41.7(3) . . ?
C1 K1 Ag1 139.7(5) . . ?
Mo4 K1 Ag1 59.20(10) . . ?
N4 C1 N1 110(2) . . ?
N4 C1 C2 129(2) . . ?
N1 C1 C2 121(2) . . ?
N4 C1 K1 97.7(15) . . ?
N1 C1 K1 83.0(14) . . ?
C2 C1 K1 84.4(15) . . ?
C7 C2 C3 120(3) . . ?
C7 C2 C1 126(3) . . ?
C3 C2 C1 115(2) . . ?
C4 C3 C2 116(3) . . ?
C4 C3 K1 120(2) . . ?
C2 C3 K1 96.6(18) . . ?
C4 C3 H3A 107.9 . . ?
C2 C3 H3A 107.9 . . ?
K1 C3 H3A 107.9 . . ?
C5 C4 C3 120(4) . . ?
C5 C4 H4A 120.0 . . ?
C3 C4 H4A 120.0 . . ?
C6 C5 C4 128(4) . . ?
C6 C5 H5A 115.9 . . ?
C4 C5 H5A 115.9 . . ?
C5 C6 C7 110(3) . . ?
C5 C6 H6A 124.9 . . ?
C7 C6 H6A 124.9 . . ?
C2 C7 C6 126(3) . . ?
C2 C7 C8 124(3) . . ?
C6 C7 C8 111(3) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N8 C9 N5 110(2) . . ?
N8 C9 C10 129(2) . . ?
N5 C9 C10 121(2) . . ?
C11 C10 C15 121(2) . . ?
C11 C10 C9 121(2) . . ?
C15 C10 C9 118(2) . . ?
C12 C11 C10 124(2) . . ?
C12 C11 H11A 118.0 . . ?
C10 C11 H11A 118.0 . . ?
C11 C12 C13 120(3) . . ?
C11 C12 Ag4 96.1(16) . . ?
C13 C12 Ag4 94.4(16) . . ?
C11 C12 H12A 114.4 . . ?
C13 C12 H12A 114.4 . . ?
Ag4 C12 H12A 114.4 . . ?
C12 C13 C14 118(2) . . ?
C12 C13 H13A 120.9 . . ?
C14 C13 H13A 120.9 . . ?
C15 C14 C13 121(2) . . ?
C15 C14 H14A 119.5 . . ?
C13 C14 H14A 119.5 . . ?
C10 C15 C14 116(2) . . ?
C10 C15 C16 123(2) . . ?
C14 C15 C16 121(2) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N9 C17 N12 110.0(19) . . ?
N9 C17 C18 124.0(19) . . ?
N12 C17 C18 125.9(19) . . ?
C19 C18 C23 119(2) . . ?
C19 C18 C17 118(2) . . ?
C23 C18 C17 123(2) . . ?
C18 C19 C20 121(2) . . ?
C18 C19 H19A 119.6 . . ?
C20 C19 H19A 119.6 . . ?
C19 C20 C21 120(3) . . ?
C19 C20 Ag1 109.7(17) . 2_736 ?
C21 C20 Ag1 71.7(15) . 2_736 ?
C19 C20 H20A 119.9 . . ?
C21 C20 H20A 119.9 . . ?
Ag1 C20 H20A 88.7 2_736 . ?
C22 C21 C20 117(2) . . ?
C22 C21 Ag1 104.8(17) . 2_736 ?
C20 C21 Ag1 74.5(15) . 2_736 ?
C22 C21 H21A 121.6 . . ?
C20 C21 H21A 121.6 . . ?
Ag1 C21 H21A 90.7 2_736 . ?
C23 C22 C21 124(3) . . ?
C23 C22 H22A 118.1 . . ?
C21 C22 H22A 118.1 . . ?
C22 C23 C18 119(2) . . ?
C22 C23 C24 118(2) . . ?
C18 C23 C24 122(2) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N16 C25 N13 107.9(19) . . ?
N16 C25 C26 126(2) . . ?
N13 C25 C26 126(2) . . ?
C31 C26 C25 128(2) . . ?
C31 C26 C27 116(2) . . ?
C25 C26 C27 116(2) . . ?
C28 C27 C26 120(2) . . ?
C28 C27 H27A 119.9 . . ?
C26 C27 H27A 119.9 . . ?
C27 C28 C29 120(2) . . ?
C27 C28 Ag7 84.7(13) . 1_565 ?
C29 C28 Ag7 90.8(16) . 1_565 ?
C27 C28 H28A 120.1 . . ?
C29 C28 H28A 120.1 . . ?
Ag7 C28 H28A 94.5 1_565 . ?
C30 C29 C28 121(2) . . ?
C30 C29 H29A 119.7 . . ?
C28 C29 H29A 119.7 . . ?
C29 C30 C31 120(2) . . ?
C29 C30 H30A 119.8 . . ?
C31 C30 H30A 119.8 . . ?
C30 C31 C26 122(2) . . ?
C30 C31 C32 115(2) . . ?
C26 C31 C32 123(2) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N20 C33 N17 109.1(19) . . ?
N20 C33 C34 126(2) . . ?
N17 C33 C34 125(2) . . ?
C35 C34 C39 125(3) . . ?
C35 C34 C33 120(2) . . ?
C39 C34 C33 115(2) . . ?
C36 C35 C34 115(3) . . ?
C36 C35 C40 123(3) . . ?
C34 C35 C40 122(2) . . ?
C37 C36 C35 123(4) . . ?
C37 C36 H36A 118.3 . . ?
C35 C36 H36A 118.3 . . ?
C36 C37 C38 122(4) . . ?
C36 C37 H37A 119.1 . . ?
C38 C37 H37A 119.1 . . ?
C37 C38 C39 119(4) . . ?
C37 C38 H38A 120.4 . . ?
C39 C38 H38A 120.4 . . ?
C34 C39 C38 116(3) . . ?
C34 C39 H39A 122.2 . . ?
C38 C39 H39A 122.2 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N2 N1 C1 106(2) . . ?
N2 N1 Ag7 127.5(16) . . ?
C1 N1 Ag7 123.3(17) . . ?
N3 N2 N1 109(2) . . ?
N3 N2 Ag6 127.7(15) . 1_545 ?
N1 N2 Ag6 123.6(16) . 1_545 ?
N2 N3 N4 110.0(18) . . ?
N2 N3 Ag2 126.4(15) . 1_545 ?
N4 N3 Ag2 120.1(14) . 1_545 ?
C1 N4 N3 105.5(18) . . ?
C1 N4 Ag2 134.9(16) . 2_735 ?
N3 N4 Ag2 119.3(13) . 2_735 ?
N6 N5 C9 107.3(18) . . ?
N6 N5 Ag3 129.1(14) . . ?
C9 N5 Ag3 123.3(15) . . ?
N5 N6 N7 106.6(17) . . ?
N5 N6 Ag1 122.2(14) . . ?
N7 N6 Ag1 130.4(13) . . ?
N5 N6 K1 146.6(14) . . ?
N7 N6 K1 41.7(10) . . ?
Ag1 N6 K1 91.1(6) . . ?
N6 N7 N8 109.7(16) . . ?
N6 N7 K1 114.2(14) . . ?
N8 N7 K1 135.4(14) . . ?
C9 N8 N7 105.8(18) . . ?
C9 N8 Ag7 139.6(16) . . ?
N7 N8 Ag7 114.3(13) . . ?
C9 N8 K1 132.8(15) . . ?
N7 N8 K1 27.9(9) . . ?
Ag7 N8 K1 86.8(6) . . ?
C17 N9 N10 104.9(17) . . ?
C17 N9 Ag8 134.4(15) . . ?
N10 N9 Ag8 117.8(13) . . ?
N11 N10 N9 110.8(17) . . ?
N11 N10 Ag4 122.9(14) . . ?
N9 N10 Ag4 122.5(13) . . ?
N10 N11 N12 107.6(17) . . ?
N10 N11 Ag3 110.5(13) . . ?
N12 N11 Ag3 141.2(13) . . ?
C17 N12 N11 106.6(16) . . ?
C17 N12 Ag5 126.5(15) . . ?
N11 N12 Ag5 125.0(14) . . ?
N14 N13 C25 105.9(16) . . ?
N14 N13 Ag8 105.2(12) . 2_646 ?
C25 N13 Ag8 148.8(14) . 2_646 ?
N15 N14 N13 106.8(16) . . ?
N15 N14 Ag8 125.9(14) . . ?
N13 N14 Ag8 125.6(12) . . ?
N14 N15 N16 113.5(18) . . ?
N14 N15 Ag4 114.2(14) . . ?
N16 N15 Ag4 131.7(16) . . ?
N15 N16 C25 105.8(19) . . ?
N15 N16 Ag6 117.9(15) . . ?
C25 N16 Ag6 136.2(16) . . ?
C33 N17 N18 105.8(18) . . ?
C33 N17 Ag2 132.3(15) . . ?
N18 N17 Ag2 116.7(14) . . ?
N19 N18 N17 108.7(18) . . ?
N19 N18 Ag6 117.8(14) . . ?
N17 N18 Ag6 131.0(15) . . ?
N18 N19 N20 109.2(19) . . ?
N18 N19 Ag4 129.9(15) . . ?
N20 N19 Ag4 120.8(14) . . ?
C33 N20 N19 107.2(18) . . ?
C33 N20 Ag3 136.5(16) . . ?
N19 N20 Ag3 116.3(14) . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        24.71
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.579
_refine_diff_density_min         -1.662
_refine_diff_density_rms         0.333
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound2
_database_code_depnum_ccdc_archive 'CCDC 1046019'
_audit_update_record             
;
2015-01-28 deposited with the CCDC.
2015-05-22 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H28 Ag7 N16 O42 P W12'
_chemical_formula_weight         4300.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.083(5)
_cell_length_b                   12.283(5)
_cell_length_c                   12.941(5)
_cell_angle_alpha                73.276(6)
_cell_angle_beta                 76.471(7)
_cell_angle_gamma                86.012(7)
_cell_volume                     1788.4(12)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.993
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1900.0
_exptl_absorpt_coefficient_mu    21.192
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.047
_exptl_absorpt_correction_T_max  0.051
_exptl_absorpt_process_details   'SADABS, Sheldrick, 1996'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            9067
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_sigmaI/netI    0.0583
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.69
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6311
_reflns_number_gt                5026
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 2001)'
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT+ (Bruker, 1999)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (1998)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0651P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6232
_refine_ls_number_parameters     512
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0583
_refine_ls_R_factor_gt           0.0442
_refine_ls_wR_factor_ref         0.1117
_refine_ls_wR_factor_gt          0.1059
_refine_ls_goodness_of_fit_ref   0.991
_refine_ls_restrained_S_all      0.991
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.5000 1.5000 -0.5000 0.0184(9) Uani 1 2 d S . .
W1 W 0.31297(5) 1.33952(5) -0.57850(5) 0.03338(16) Uani 1 1 d . . .
W2 W 0.60941(5) 1.26706(5) -0.60685(4) 0.03367(16) Uani 1 1 d . . .
W3 W 0.20483(4) 1.57819(5) -0.47983(4) 0.02856(15) Uani 1 1 d . . .
W4 W 0.42591(5) 1.21385(5) -0.33877(5) 0.03649(17) Uani 1 1 d . . .
W5 W 0.60370(5) 1.37894(5) -0.25480(4) 0.03049(15) Uani 1 1 d . . .
W6 W 0.30804(5) 1.44839(5) -0.23502(4) 0.03116(15) Uani 1 1 d . . .
O1' O 0.4011(14) 1.5101(16) -0.5513(13) 0.032(4) Uani 0.50 1 d P . .
O1 O 0.5261(13) 1.5791(13) -0.6210(13) 0.022(4) Uani 0.50 1 d PU . .
O1W O 0.9247(14) 1.5462(17) -1.2192(12) 0.111(6) Uani 1 1 d . . .
O2' O 0.4713(13) 1.3787(14) -0.5047(13) 0.023(4) Uiso 0.50 1 d P . .
O2 O 0.6053(13) 1.4561(14) -0.5672(12) 0.024(4) Uani 0.50 1 d P . .
O3 O 0.3230(9) 1.2439(14) -0.4380(9) 0.090(6) Uani 1 1 d . . .
O4 O 0.7324(12) 1.3028(10) -0.5528(9) 0.068(4) Uani 1 1 d . . .
O5 O 0.6550(11) 1.3236(10) -0.1399(8) 0.065(4) Uani 1 1 d . . .
O6 O 0.4532(9) 1.4216(10) -0.1942(13) 0.073(4) Uani 1 1 d . . .
O7 O 0.2049(12) 1.4915(9) -0.3309(9) 0.070(4) Uani 1 1 d . . .
O8 O 0.4625(10) 1.2834(13) -0.6351(9) 0.084(5) Uani 1 1 d . . .
O9 O 0.5406(9) 1.1888(14) -0.4569(8) 0.088(5) Uani 1 1 d . . .
O10 O 0.7320(11) 1.3598(9) -0.3691(9) 0.059(3) Uani 1 1 d . . .
O11 O 0.5380(9) 1.2523(11) -0.2729(14) 0.085(5) Uani 1 1 d . . .
O12 O 0.3235(9) 1.3007(11) -0.2562(13) 0.078(5) Uani 1 1 d . . .
O13 O 0.2255(10) 1.2645(11) -0.6184(10) 0.067(4) Uani 1 1 d . . .
O14 O 0.6615(9) 1.1566(9) -0.6562(9) 0.050(3) Uani 1 1 d . . .
O15 O 0.6599(12) 1.3935(9) -0.7329(9) 0.069(4) Uani 1 1 d . . .
O16 O 0.2113(11) 1.4324(9) -0.5099(8) 0.057(3) Uani 1 1 d . . .
O17 O 0.0653(9) 1.6136(11) -0.4688(11) 0.071(4) Uani 1 1 d . . .
O18 O 0.3499(11) 1.4675(9) -0.7058(9) 0.061(3) Uani 1 1 d . . .
O19 O 0.3910(9) 1.0786(8) -0.2635(8) 0.045(3) Uani 1 1 d . . .
O20 O 0.2169(9) 1.4257(10) -0.1105(8) 0.052(3) Uani 1 1 d . . .
Ag1 Ag 0.0000 0.5000 0.0000 0.0628(6) Uani 1 2 d S . .
Ag2 Ag 0.13499(9) 0.28204(11) 0.11857(11) 0.0534(4) Uani 1 1 d . . .
Ag3 Ag 0.33416(8) 0.56564(9) -0.00742(9) 0.0356(3) Uani 1 1 d . . .
Ag4 Ag 0.37406(8) 0.88401(9) -0.16848(10) 0.0368(3) Uani 1 1 d . . .
C1 C 0.3083(15) 0.0400(15) 0.1055(15) 0.058(5) Uani 1 1 d . . .
C2 C 0.2498(17) -0.0648(16) 0.1356(19) 0.068(6) Uani 1 1 d . . .
H2A H 0.2347 -0.0943 0.0817 0.082 Uiso 1 1 calc R . .
C3 C 0.2179(17) -0.1187(17) 0.240(2) 0.072(6) Uani 1 1 d . . .
H3A H 0.1823 -0.1887 0.2587 0.086 Uiso 1 1 calc R . .
C4 C 0.2327(15) -0.0804(16) 0.3199(17) 0.068(6) Uani 1 1 d . . .
H4A H 0.2052 -0.1223 0.3929 0.082 Uiso 1 1 calc R . .
C5 C 0.2932(16) 0.0299(14) 0.2967(15) 0.065(5) Uani 1 1 d . . .
H5A H 0.3091 0.0579 0.3513 0.078 Uiso 1 1 calc R . .
C6 C 0.3232(11) 0.0862(11) 0.1817(13) 0.037(3) Uani 1 1 d . . .
C7 C 0.3734(10) 0.2049(10) 0.1440(10) 0.025(3) Uani 1 1 d . . .
C8 C 0.350(3) 0.092(2) -0.0149(19) 0.139(13) Uani 1 1 d . . .
H8A H 0.3883 0.1618 -0.0271 0.209 Uiso 1 1 calc R . .
H8B H 0.2863 0.1072 -0.0500 0.209 Uiso 1 1 calc R . .
H8C H 0.4014 0.0406 -0.0458 0.209 Uiso 1 1 calc R . .
C9 C 0.0868(11) 0.9635(13) -0.1873(14) 0.044(4) Uani 1 1 d . . .
C10 C 0.0679(12) 0.9972(17) -0.2944(15) 0.058(5) Uani 1 1 d . . .
C11 C 0.0615(13) 1.1125(18) -0.3440(18) 0.079(8) Uani 1 1 d . . .
H11A H 0.0498 1.1388 -0.4156 0.094 Uiso 1 1 calc R . .
C12 C 0.0736(17) 1.1934(19) -0.282(3) 0.120(13) Uani 1 1 d . . .
H12A H 0.0725 1.2715 -0.3146 0.144 Uiso 1 1 calc R . .
C13 C 0.0856(16) 1.1525(16) -0.183(3) 0.095(9) Uani 1 1 d . . .
H13A H 0.0869 1.2029 -0.1419 0.113 Uiso 1 1 calc R . .
C14 C 0.0965(13) 1.0412(15) -0.1346(17) 0.062(5) Uani 1 1 d . . .
H14A H 0.1110 1.0174 -0.0640 0.074 Uiso 1 1 calc R . .
C15 C 0.1045(9) 0.8399(11) -0.1321(10) 0.028(3) Uani 1 1 d . . .
C16 C 0.0553(19) 0.914(2) -0.3544(15) 0.095(9) Uani 1 1 d . . .
H16A H 0.0433 0.9542 -0.4265 0.142 Uiso 1 1 calc R . .
H16B H -0.0086 0.8658 -0.3137 0.142 Uiso 1 1 calc R . .
H16C H 0.1232 0.8689 -0.3620 0.142 Uiso 1 1 calc R . .
N1 N 0.4830(8) 0.2321(9) 0.1301(10) 0.031(3) Uani 1 1 d . . .
N2 N 0.4854(9) 0.3465(9) 0.0889(9) 0.032(3) Uani 1 1 d . . .
N3 N 0.3825(8) 0.3844(9) 0.0794(8) 0.023(2) Uani 1 1 d . . .
N4 N 0.3122(8) 0.2956(9) 0.1133(8) 0.030(3) Uani 1 1 d . . .
N5 N 0.0316(10) 0.7540(10) -0.1057(11) 0.041(3) Uani 1 1 d . . .
N6 N 0.0880(9) 0.6576(9) -0.0542(10) 0.035(3) Uani 1 1 d . . .
N7 N 0.1864(9) 0.6891(9) -0.0493(9) 0.033(3) Uani 1 1 d . . .
N8 N 0.1999(8) 0.8006(9) -0.0961(9) 0.028(2) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1' 1.479(17) . ?
P1 O1' 1.479(17) 2_684 ?
P1 O2 1.523(15) 2_684 ?
P1 O2 1.523(15) . ?
P1 O1 1.559(15) . ?
P1 O1 1.559(15) 2_684 ?
P1 O2' 1.574(17) . ?
P1 O2' 1.574(17) 2_684 ?
W1 O13 1.702(11) . ?
W1 O16 1.864(10) . ?
W1 O3 1.886(11) . ?
W1 O18 1.910(10) . ?
W1 O8 1.942(12) . ?
W1 O2' 2.460(16) . ?
W2 O14 1.685(10) . ?
W2 O8 1.881(13) . ?
W2 O15 1.911(10) . ?
W2 O4 1.909(12) . ?
W2 O9 1.914(10) . ?
W2 O2' 2.471(16) . ?
W2 O2 2.514(17) . ?
W3 O17 1.695(11) . ?
W3 O10 1.874(10) 2_684 ?
W3 O4 1.884(12) 2_684 ?
W3 O7 1.916(10) . ?
W3 O16 1.932(10) . ?
W3 O2 2.487(16) 2_684 ?
W3 O1' 2.514(15) . ?
W4 O19 1.692(10) . ?
W4 O9 1.890(11) . ?
W4 O11 1.910(12) . ?
W4 O12 1.915(11) . ?
W4 O3 1.934(12) . ?
W4 O2' 2.473(16) . ?
W4 O1 2.525(16) 2_684 ?
W5 O5 1.688(10) . ?
W5 O11 1.890(11) . ?
W5 O18 1.895(11) 2_684 ?
W5 O6 1.906(11) . ?
W5 O10 1.930(11) . ?
W5 O1 2.429(15) 2_684 ?
W5 O1' 2.499(16) 2_684 ?
W6 O20 1.685(10) . ?
W6 O12 1.902(11) . ?
W6 O7 1.904(11) . ?
W6 O15 1.913(11) 2_684 ?
W6 O6 1.928(11) . ?
W6 O1 2.474(15) 2_684 ?
W6 O2 2.493(15) 2_684 ?
O1' O2 1.68(2) 2_684 ?
O1' O1 1.71(2) . ?
O1' O2' 1.78(2) . ?
O1' W5 2.499(16) 2_684 ?
O1 O2 1.79(2) . ?
O1 W5 2.429(15) 2_684 ?
O1 W6 2.474(15) 2_684 ?
O1 W4 2.525(16) 2_684 ?
O2 O1' 1.68(2) 2_684 ?
O2 W3 2.487(16) 2_684 ?
O2 W6 2.493(15) 2_684 ?
O4 W3 1.884(12) 2_684 ?
O10 W3 1.874(10) 2_684 ?
O14 Ag4 2.591(10) 2_674 ?
O15 W6 1.913(11) 2_684 ?
O18 W5 1.895(11) 2_684 ?
O19 Ag4 2.350(10) . ?
Ag1 N6 2.127(10) . ?
Ag1 N6 2.127(10) 2_565 ?
Ag1 Ag2 3.2220(14) . ?
Ag1 Ag2 3.2221(14) 2_565 ?
Ag2 N4 2.143(10) . ?
Ag2 N5 2.144(12) 2_565 ?
Ag3 N3 2.290(10) . ?
Ag3 N7 2.320(10) . ?
Ag3 N2 2.372(11) 2_665 ?
Ag4 N1 2.217(10) 2_665 ?
Ag4 N8 2.276(10) . ?
Ag4 O14 2.591(10) 2_674 ?
C1 C6 1.32(2) . ?
C1 C2 1.42(2) . ?
C1 C8 1.48(3) . ?
C2 C3 1.30(3) . ?
C2 H2A 0.9300 . ?
C3 C4 1.31(3) . ?
C3 H3A 0.9300 . ?
C4 C5 1.50(3) . ?
C4 H4A 0.9300 . ?
C5 C6 1.42(2) . ?
C5 H5A 0.9300 . ?
C6 C7 1.519(18) . ?
C7 N4 1.309(15) . ?
C7 N1 1.347(15) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C14 1.35(2) . ?
C9 C10 1.40(2) . ?
C9 C15 1.505(19) . ?
C10 C11 1.38(2) . ?
C10 C16 1.48(3) . ?
C11 C12 1.48(4) . ?
C11 H11A 0.9300 . ?
C12 C13 1.27(4) . ?
C12 H12A 0.9300 . ?
C13 C14 1.34(2) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 N5 1.337(17) . ?
C15 N8 1.350(15) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
N1 N2 1.351(14) . ?
N1 Ag4 2.217(10) 2_665 ?
N2 N3 1.318(13) . ?
N2 Ag3 2.372(11) 2_665 ?
N3 N4 1.335(14) . ?
N5 N6 1.399(15) . ?
N5 Ag2 2.144(12) 2_565 ?
N6 N7 1.297(14) . ?
N7 N8 1.333(14) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1' P1 O1' 180.0(10) . 2_684 ?
O1' P1 O2 68.2(8) . 2_684 ?
O1' P1 O2 111.8(8) 2_684 2_684 ?
O1' P1 O2 111.8(8) . . ?
O1' P1 O2 68.2(8) 2_684 . ?
O2 P1 O2 179.998(3) 2_684 . ?
O1' P1 O1 68.3(9) . . ?
O1' P1 O1 111.7(9) 2_684 . ?
O2 P1 O1 109.2(8) 2_684 . ?
O2 P1 O1 70.8(8) . . ?
O1' P1 O1 111.7(9) . 2_684 ?
O1' P1 O1 68.3(9) 2_684 2_684 ?
O2 P1 O1 70.8(8) 2_684 2_684 ?
O2 P1 O1 109.2(8) . 2_684 ?
O1 P1 O1 180.0(11) . 2_684 ?
O1' P1 O2' 71.4(9) . . ?
O1' P1 O2' 108.6(9) 2_684 . ?
O2 P1 O2' 107.7(9) 2_684 . ?
O2 P1 O2' 72.3(9) . . ?
O1 P1 O2' 107.6(8) . . ?
O1 P1 O2' 72.4(8) 2_684 . ?
O1' P1 O2' 108.6(9) . 2_684 ?
O1' P1 O2' 71.4(9) 2_684 2_684 ?
O2 P1 O2' 72.3(9) 2_684 2_684 ?
O2 P1 O2' 107.7(9) . 2_684 ?
O1 P1 O2' 72.4(8) . 2_684 ?
O1 P1 O2' 107.6(8) 2_684 2_684 ?
O2' P1 O2' 180.0(3) . 2_684 ?
O13 W1 O16 102.6(6) . . ?
O13 W1 O3 102.2(7) . . ?
O16 W1 O3 89.4(5) . . ?
O13 W1 O18 101.7(6) . . ?
O16 W1 O18 88.2(4) . . ?
O3 W1 O18 156.0(6) . . ?
O13 W1 O8 102.2(7) . . ?
O16 W1 O8 155.1(6) . . ?
O3 W1 O8 87.2(4) . . ?
O18 W1 O8 84.9(5) . . ?
O13 W1 O2' 159.0(6) . . ?
O16 W1 O2' 93.5(5) . . ?
O3 W1 O2' 64.2(6) . . ?
O18 W1 O2' 92.1(6) . . ?
O8 W1 O2' 62.9(6) . . ?
O14 W2 O8 102.1(6) . . ?
O14 W2 O15 101.7(6) . . ?
O8 W2 O15 89.9(5) . . ?
O14 W2 O4 102.6(5) . . ?
O8 W2 O4 155.3(7) . . ?
O15 W2 O4 85.8(5) . . ?
O14 W2 O9 100.6(6) . . ?
O8 W2 O9 87.5(5) . . ?
O15 W2 O9 157.6(7) . . ?
O4 W2 O9 87.4(6) . . ?
O14 W2 O2' 158.1(5) . . ?
O8 W2 O2' 63.3(6) . . ?
O15 W2 O2' 94.8(6) . . ?
O4 W2 O2' 92.8(6) . . ?
O9 W2 O2' 64.3(6) . . ?
O14 W2 O2 158.8(5) . . ?
O8 W2 O2 94.2(6) . . ?
O15 W2 O2 64.5(5) . . ?
O4 W2 O2 62.1(5) . . ?
O9 W2 O2 93.5(6) . . ?
O2' W2 O2 43.0(5) . . ?
O17 W3 O10 103.0(6) . 2_684 ?
O17 W3 O4 103.8(6) . 2_684 ?
O10 W3 O4 90.3(5) 2_684 2_684 ?
O17 W3 O7 101.2(6) . . ?
O10 W3 O7 155.7(6) 2_684 . ?
O4 W3 O7 86.4(5) 2_684 . ?
O17 W3 O16 102.7(6) . . ?
O10 W3 O16 87.1(4) 2_684 . ?
O4 W3 O16 153.3(6) 2_684 . ?
O7 W3 O16 85.2(5) . . ?
O17 W3 O2 159.6(6) . 2_684 ?
O10 W3 O2 92.8(5) 2_684 2_684 ?
O4 W3 O2 62.9(6) 2_684 2_684 ?
O7 W3 O2 64.3(5) . 2_684 ?
O16 W3 O2 90.6(6) . 2_684 ?
O17 W3 O1' 161.0(6) . . ?
O10 W3 O1' 63.8(5) 2_684 . ?
O4 W3 O1' 90.4(6) 2_684 . ?
O7 W3 O1' 92.1(6) . . ?
O16 W3 O1' 64.6(6) . . ?
O2 W3 O1' 39.3(5) 2_684 . ?
O19 W4 O9 100.8(6) . . ?
O19 W4 O11 103.4(6) . . ?
O9 W4 O11 90.7(6) . . ?
O19 W4 O12 102.4(6) . . ?
O9 W4 O12 156.7(6) . . ?
O11 W4 O12 85.3(5) . . ?
O19 W4 O3 101.4(6) . . ?
O9 W4 O3 87.4(5) . . ?
O11 W4 O3 155.1(7) . . ?
O12 W4 O3 86.6(6) . . ?
O19 W4 O2' 158.1(5) . . ?
O9 W4 O2' 64.5(6) . . ?
O11 W4 O2' 93.5(6) . . ?
O12 W4 O2' 92.7(6) . . ?
O3 W4 O2' 63.3(6) . . ?
O19 W4 O1 158.5(5) . 2_684 ?
O9 W4 O1 94.8(6) . 2_684 ?
O11 W4 O1 61.4(5) . 2_684 ?
O12 W4 O1 63.2(5) . 2_684 ?
O3 W4 O1 93.9(6) . 2_684 ?
O2' W4 O1 43.5(5) . 2_684 ?
O5 W5 O11 103.5(7) . . ?
O5 W5 O18 101.0(6) . 2_684 ?
O11 W5 O18 155.5(6) . 2_684 ?
O5 W5 O6 101.8(6) . . ?
O11 W5 O6 87.1(5) . . ?
O18 W5 O6 89.7(5) 2_684 . ?
O5 W5 O10 101.5(6) . . ?
O11 W5 O10 87.0(5) . . ?
O18 W5 O10 86.4(5) 2_684 . ?
O6 W5 O10 156.7(6) . . ?
O5 W5 O1 160.3(6) . 2_684 ?
O11 W5 O1 63.7(6) . 2_684 ?
O18 W5 O1 93.1(6) 2_684 2_684 ?
O6 W5 O1 64.3(6) . 2_684 ?
O10 W5 O1 93.0(5) . 2_684 ?
O5 W5 O1' 159.2(6) . 2_684 ?
O11 W5 O1' 90.7(7) . 2_684 ?
O18 W5 O1' 65.3(6) 2_684 2_684 ?
O6 W5 O1' 94.1(6) . 2_684 ?
O10 W5 O1' 63.6(5) . 2_684 ?
O1 W5 O1' 40.5(6) 2_684 2_684 ?
O20 W6 O12 102.3(6) . . ?
O20 W6 O7 100.7(6) . . ?
O12 W6 O7 90.9(5) . . ?
O20 W6 O15 100.8(6) . 2_684 ?
O12 W6 O15 156.7(6) . 2_684 ?
O7 W6 O15 87.5(5) . 2_684 ?
O20 W6 O6 101.9(6) . . ?
O12 W6 O6 86.6(5) . . ?
O7 W6 O6 157.3(6) . . ?
O15 W6 O6 86.0(5) 2_684 . ?
O20 W6 O1 159.3(5) . 2_684 ?
O12 W6 O1 64.5(6) . 2_684 ?
O7 W6 O1 95.6(6) . 2_684 ?
O15 W6 O1 92.5(6) 2_684 2_684 ?
O6 W6 O1 63.0(5) . 2_684 ?
O20 W6 O2 158.6(5) . 2_684 ?
O12 W6 O2 93.4(6) . 2_684 ?
O7 W6 O2 64.3(5) . 2_684 ?
O15 W6 O2 65.0(5) 2_684 2_684 ?
O6 W6 O2 93.4(6) . 2_684 ?
O1 W6 O2 42.1(5) 2_684 2_684 ?
P1 O1' O2 57.2(8) . 2_684 ?
P1 O1' O1 58.1(8) . . ?
O2 O1' O1 95.7(12) 2_684 . ?
P1 O1' O2' 56.8(8) . . ?
O2 O1' O2' 92.4(11) 2_684 . ?
O1 O1' O2' 92.8(10) . . ?
P1 O1' W5 125.6(10) . 2_684 ?
O2 O1' W5 134.7(11) 2_684 2_684 ?
O1 O1' W5 67.5(7) . 2_684 ?
O2' O1' W5 128.6(9) . 2_684 ?
P1 O1' W3 126.6(8) . . ?
O2 O1' W3 69.4(7) 2_684 . ?
O1 O1' W3 132.9(11) . . ?
O2' O1' W3 130.7(10) . . ?
W5 O1' W3 91.2(5) 2_684 . ?
P1 O1 O1' 53.6(7) . . ?
P1 O1 O2 53.7(6) . . ?
O1' O1 O2 90.7(11) . . ?
P1 O1 W5 125.5(9) . 2_684 ?
O1' O1 W5 71.9(8) . 2_684 ?
O2 O1 W5 134.0(10) . 2_684 ?
P1 O1 W6 123.1(7) . 2_684 ?
O1' O1 W6 136.3(10) . 2_684 ?
O2 O1 W6 69.5(7) . 2_684 ?
W5 O1 W6 93.8(5) 2_684 2_684 ?
P1 O1 W4 120.9(8) . 2_684 ?
O1' O1 W4 128.9(9) . 2_684 ?
O2 O1 W4 128.9(10) . 2_684 ?
W5 O1 W4 92.8(5) 2_684 2_684 ?
W6 O1 W4 91.8(5) 2_684 2_684 ?
P1 O2' O1' 51.8(8) . . ?
P1 O2' W1 124.1(8) . . ?
O1' O2' W1 72.3(8) . . ?
P1 O2' W2 122.3(8) . . ?
O1' O2' W2 131.4(9) . . ?
W1 O2' W2 93.4(5) . . ?
P1 O2' W4 123.2(8) . . ?
O1' O2' W4 133.6(9) . . ?
W1 O2' W4 93.0(5) . . ?
W2 O2' W4 92.1(5) . . ?
P1 O2 O1' 54.6(7) . 2_684 ?
P1 O2 O1 55.6(7) . . ?
O1' O2 O1 92.9(11) 2_684 . ?
P1 O2 W3 125.9(8) . 2_684 ?
O1' O2 W3 71.2(8) 2_684 2_684 ?
O1 O2 W3 135.1(11) . 2_684 ?
P1 O2 W6 123.9(8) . 2_684 ?
O1' O2 W6 133.0(11) 2_684 2_684 ?
O1 O2 W6 68.4(7) . 2_684 ?
W3 O2 W6 91.9(5) 2_684 2_684 ?
P1 O2 W2 122.4(9) . . ?
O1' O2 W2 131.4(10) 2_684 . ?
O1 O2 W2 126.9(9) . . ?
W3 O2 W2 91.9(5) 2_684 . ?
W6 O2 W2 91.3(5) 2_684 . ?
W1 O3 W4 139.0(8) . . ?
W3 O4 W2 142.6(7) 2_684 . ?
W5 O6 W6 138.2(8) . . ?
W6 O7 W3 139.0(8) . . ?
W2 O8 W1 139.7(9) . . ?
W4 O9 W2 138.7(8) . . ?
W3 O10 W5 140.7(7) 2_684 . ?
W5 O11 W4 141.6(8) . . ?
W6 O12 W4 140.4(7) . . ?
W2 O14 Ag4 126.2(5) . 2_674 ?
W2 O15 W6 138.8(7) . 2_684 ?
W1 O16 W3 140.6(7) . . ?
W5 O18 W1 140.2(7) 2_684 . ?
W4 O19 Ag4 170.7(6) . . ?
N6 Ag1 N6 180.000(1) . 2_565 ?
N6 Ag1 Ag2 115.9(3) . . ?
N6 Ag1 Ag2 64.1(3) 2_565 . ?
N6 Ag1 Ag2 64.1(3) . 2_565 ?
N6 Ag1 Ag2 115.9(3) 2_565 2_565 ?
Ag2 Ag1 Ag2 180.0 . 2_565 ?
N4 Ag2 N5 169.1(5) . 2_565 ?
N4 Ag2 Ag1 119.8(3) . . ?
N5 Ag2 Ag1 65.3(3) 2_565 . ?
N3 Ag3 N7 145.8(4) . . ?
N3 Ag3 N2 102.3(3) . 2_665 ?
N7 Ag3 N2 111.9(4) . 2_665 ?
N1 Ag4 N8 113.6(4) 2_665 . ?
N1 Ag4 O19 125.5(4) 2_665 . ?
N8 Ag4 O19 120.8(4) . . ?
N1 Ag4 O14 102.9(4) 2_665 2_674 ?
N8 Ag4 O14 80.7(4) . 2_674 ?
O19 Ag4 O14 89.4(3) . 2_674 ?
C6 C1 C2 121.0(17) . . ?
C6 C1 C8 123.5(19) . . ?
C2 C1 C8 115.5(19) . . ?
C3 C2 C1 119(2) . . ?
C3 C2 H2A 120.7 . . ?
C1 C2 H2A 120.7 . . ?
C2 C3 C4 124(2) . . ?
C2 C3 H3A 118.1 . . ?
C4 C3 H3A 118.1 . . ?
C3 C4 C5 121.5(18) . . ?
C3 C4 H4A 119.2 . . ?
C5 C4 H4A 119.2 . . ?
C6 C5 C4 111.9(18) . . ?
C6 C5 H5A 124.1 . . ?
C4 C5 H5A 124.1 . . ?
C1 C6 C5 122.7(16) . . ?
C1 C6 C7 118.3(14) . . ?
C5 C6 C7 119.0(15) . . ?
N4 C7 N1 111.2(11) . . ?
N4 C7 C6 121.8(11) . . ?
N1 C7 C6 126.9(11) . . ?
C1 C8 H8A 109.5 . . ?
C1 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C1 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C14 C9 C10 120.8(17) . . ?
C14 C9 C15 119.0(15) . . ?
C10 C9 C15 120.1(15) . . ?
C11 C10 C9 117(2) . . ?
C11 C10 C16 120.3(18) . . ?
C9 C10 C16 122.3(16) . . ?
C10 C11 C12 119(2) . . ?
C10 C11 H11A 120.3 . . ?
C12 C11 H11A 120.3 . . ?
C13 C12 C11 118(2) . . ?
C13 C12 H12A 121.2 . . ?
C11 C12 H12A 121.2 . . ?
C12 C13 C14 124(3) . . ?
C12 C13 H13A 117.9 . . ?
C14 C13 H13A 117.9 . . ?
C13 C14 C9 121(2) . . ?
C13 C14 H14A 119.7 . . ?
C9 C14 H14A 119.7 . . ?
N5 C15 N8 109.3(11) . . ?
N5 C15 C9 128.0(11) . . ?
N8 C15 C9 122.6(11) . . ?
C10 C16 H16A 109.5 . . ?
C10 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C10 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C7 N1 N2 104.1(9) . . ?
C7 N1 Ag4 127.9(8) . 2_665 ?
N2 N1 Ag4 128.0(8) . 2_665 ?
N3 N2 N1 109.5(10) . . ?
N3 N2 Ag3 130.7(8) . 2_665 ?
N1 N2 Ag3 117.6(7) . 2_665 ?
N2 N3 N4 108.4(9) . . ?
N2 N3 Ag3 126.7(8) . . ?
N4 N3 Ag3 124.1(7) . . ?
C7 N4 N3 106.7(10) . . ?
C7 N4 Ag2 120.9(9) . . ?
N3 N4 Ag2 132.4(7) . . ?
C15 N5 N6 105.4(10) . . ?
C15 N5 Ag2 141.3(9) . 2_565 ?
N6 N5 Ag2 113.2(8) . 2_565 ?
N7 N6 N5 108.1(10) . . ?
N7 N6 Ag1 134.6(8) . . ?
N5 N6 Ag1 117.3(8) . . ?
N6 N7 N8 110.1(10) . . ?
N6 N7 Ag3 124.5(8) . . ?
N8 N7 Ag3 123.7(8) . . ?
N7 N8 C15 107.0(10) . . ?
N7 N8 Ag4 122.8(7) . . ?
C15 N8 Ag4 124.7(8) . . ?

_diffrn_measured_fraction_theta_max 0.987
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.987
_refine_diff_density_max         2.287
_refine_diff_density_min         -3.296
_refine_diff_density_rms         0.321
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_compound3
_database_code_depnum_ccdc_archive 'CCDC 1046020'
_audit_update_record             
;
2015-01-28 deposited with the CCDC.
2015-05-22 downloaded from the CCDC.
;


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C64 H56 Ag10 N32 O41 P W12'
_chemical_formula_weight         5245.28

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   24.980(3)
_cell_length_b                   19.327(3)
_cell_length_c                   21.407(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.019(2)
_cell_angle_gamma                90.00
_cell_volume                     10278(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.19
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.390
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             9460
_exptl_absorpt_coefficient_mu    15.331
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.048
_exptl_absorpt_correction_T_max  0.054
_exptl_absorpt_process_details   'SADABS, Sheldrick, 1996'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            72948
_diffrn_reflns_av_R_equivalents  0.0631
_diffrn_reflns_av_sigmaI/netI    0.0780
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         1.59
_diffrn_reflns_theta_max         27.93
_reflns_number_total             24598
_reflns_number_gt                15683
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 2001)'
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT+ (Bruker, 1999)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (1998)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0473P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         24598
_refine_ls_number_parameters     1413
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0899
_refine_ls_R_factor_gt           0.0428
_refine_ls_wR_factor_ref         0.1084
_refine_ls_wR_factor_gt          0.0936
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_restrained_S_all      1.017
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -0.74001(9) 0.47869(13) -1.25010(11) 0.0101(5) Uani 1 1 d . . .
W1 W -0.829205(19) 0.44359(3) -1.13470(2) 0.02897(12) Uani 1 1 d . . .
W2 W -0.623749(18) 0.37393(3) -1.25807(2) 0.02624(11) Uani 1 1 d . . .
W3 W -0.763959(18) 0.62260(3) -1.35379(2) 0.02540(11) Uani 1 1 d . . .
W4 W -0.749686(18) 0.58727(3) -1.11749(2) 0.02595(11) Uani 1 1 d . . .
W5 W -0.821923(18) 0.32804(3) -1.27117(2) 0.02469(11) Uani 1 1 d . . .
W6 W -0.738466(18) 0.36770(3) -1.38223(2) 0.02410(11) Uani 1 1 d . . .
W7 W -0.708007(19) 0.33725(3) -1.14638(2) 0.02832(12) Uani 1 1 d . . .
W8 W -0.659418(17) 0.63041(2) -1.23747(2) 0.02382(10) Uani 1 1 d . . .
W9 W -0.652211(18) 0.52293(3) -1.36366(2) 0.02515(11) Uani 1 1 d . . .
W10 W -0.628641(17) 0.48134(2) -1.13225(2) 0.02310(10) Uani 1 1 d . . .
W11 W -0.849919(17) 0.46700(3) -1.36881(2) 0.02255(10) Uani 1 1 d . . .
W12 W -0.854782(18) 0.58264(3) -1.23253(2) 0.02659(11) Uani 1 1 d . . .
O1 O -0.7764(3) 0.5096(4) -1.2046(3) 0.0218(16) Uani 1 1 d . . .
O1W O 0.0359(3) 0.4105(6) -0.2619(4) 0.053(3) Uani 1 1 d . . .
O2 O -0.7148(3) 0.5367(4) -1.2843(3) 0.0205(16) Uani 1 1 d . . .
O3 O -0.6953(3) 0.4363(4) -1.2139(3) 0.0201(16) Uani 1 1 d . . .
O4 O -0.7726(3) 0.4319(4) -1.2971(3) 0.0173(15) Uani 1 1 d . . .
O5 O -0.6088(3) 0.5278(5) -1.4190(3) 0.040(2) Uani 1 1 d . . .
O6 O -0.7058(4) 0.2681(5) -1.0988(4) 0.045(2) Uani 1 1 d . . .
O7 O -0.7389(3) 0.6406(5) -1.0548(4) 0.038(2) Uani 1 1 d . . .
O8 O -0.6213(3) 0.7000(4) -1.2169(4) 0.035(2) Uani 1 1 d . . .
O9 O -0.5703(3) 0.3280(5) -1.2775(4) 0.038(2) Uani 1 1 d . . .
O10 O -0.8104(3) 0.6252(4) -1.2875(3) 0.0259(17) Uani 1 1 d . . .
O11 O -0.6799(3) 0.3479(4) -1.3199(3) 0.0265(18) Uani 1 1 d . . .
O12 O -0.6258(3) 0.5957(4) -1.3086(3) 0.0248(17) Uani 1 1 d . . .
O13 O -0.7819(3) 0.3064(4) -1.3394(3) 0.0270(18) Uani 1 1 d . . .
O14 O -0.7066(3) 0.5875(4) -1.3964(3) 0.0277(18) Uani 1 1 d . . .
O15 O -0.7598(3) 0.3111(4) -1.2141(3) 0.0277(18) Uani 1 1 d . . .
O16 O -0.6567(3) 0.3978(4) -1.1018(3) 0.0262(18) Uani 1 1 d . . .
O17 O -0.8041(3) 0.4127(4) -1.4143(3) 0.0268(18) Uani 1 1 d . . .
O18 O -0.7641(3) 0.3919(4) -1.1186(3) 0.0283(18) Uani 1 1 d . . .
O19 O -0.7110(3) 0.6704(4) -1.2997(4) 0.0300(19) Uani 1 1 d . . .
O20 O -0.8436(3) 0.3858(4) -1.2056(3) 0.0267(18) Uani 1 1 d . . .
O21 O -0.8750(3) 0.5137(5) -1.1753(3) 0.0306(19) Uani 1 1 d . . .
O22 O -0.8144(3) 0.6240(4) -1.1618(3) 0.0288(19) Uani 1 1 d . . .
O23 O -0.9098(3) 0.6338(5) -1.2407(4) 0.040(2) Uani 1 1 d . . .
O24 O -0.6522(3) 0.3138(4) -1.1991(4) 0.0316(19) Uani 1 1 d . . .
O25 O -0.5917(3) 0.4264(4) -1.1884(3) 0.0261(18) Uani 1 1 d . . .
O26 O -0.8685(3) 0.3828(4) -1.3288(3) 0.0224(17) Uani 1 1 d . . .
O27 O -0.8697(3) 0.5166(4) -1.2981(3) 0.0282(18) Uani 1 1 d . . .
O28 O -0.8067(3) 0.5455(4) -1.3826(3) 0.0222(16) Uani 1 1 d . . .
O29 O -0.7937(3) 0.5176(4) -1.0866(3) 0.0314(19) Uani 1 1 d . . .
O30 O -0.6263(3) 0.5586(4) -1.1886(3) 0.0217(16) Uani 1 1 d . . .
O31 O -0.6996(3) 0.4510(4) -1.3935(3) 0.0247(17) Uani 1 1 d . . .
O32 O -0.6212(3) 0.4566(4) -1.3073(3) 0.0246(17) Uani 1 1 d . . .
O33 O -0.6891(3) 0.5283(4) -1.1047(3) 0.0255(17) Uani 1 1 d . . .
O34 O -0.7249(3) 0.3191(5) -1.4436(3) 0.038(2) Uani 1 1 d . . .
O35 O -0.7103(3) 0.6313(4) -1.1790(3) 0.0270(18) Uani 1 1 d . . .
O36 O -0.8689(3) 0.4097(5) -1.0842(4) 0.039(2) Uani 1 1 d . . .
O37 O -0.9040(3) 0.4792(4) -1.4214(3) 0.032(2) Uani 1 1 d . . .
O38 O -0.7891(3) 0.6871(4) -1.4030(4) 0.041(2) Uani 1 1 d . . .
O39 O -0.5794(3) 0.4992(4) -1.0750(3) 0.0300(19) Uani 1 1 d . . .
O40 O -0.8601(3) 0.2564(5) -1.2656(4) 0.042(2) Uani 1 1 d . . .
Ag1 Ag -0.01057(4) 0.20635(5) -0.72355(4) 0.0388(2) Uani 1 1 d . . .
Ag2 Ag 0.05897(5) 0.51842(6) -0.76549(5) 0.0474(3) Uani 1 1 d . . .
Ag3 Ag -0.26666(4) 0.32836(7) -1.07470(5) 0.0514(3) Uani 1 1 d . . .
Ag4 Ag -0.40656(4) 0.21858(6) -1.12524(5) 0.0474(3) Uani 1 1 d . . .
Ag5A Ag 0.02115(8) 0.56395(9) -1.06042(7) 0.0281(4) Uani 0.50 1 d P . .
Ag5C Ag -0.02958(16) 0.5872(2) -1.06353(14) 0.0330(9) Uani 0.25 1 d P . .
Ag6 Ag -0.46281(4) 0.28686(5) -1.28454(4) 0.0288(2) Uani 1 1 d . . .
Ag7 Ag -0.44675(4) 0.48102(5) -1.26947(4) 0.0389(2) Uani 1 1 d . . .
Ag8 Ag -0.50875(5) 0.56715(5) -1.43398(4) 0.0432(3) Uani 1 1 d . . .
Ag9 Ag 0.19452(6) 0.71268(7) -0.55199(7) 0.0871(5) Uani 1 1 d . . .
Ag10 Ag -0.07831(4) 0.29205(6) -0.87751(6) 0.0574(3) Uani 1 1 d . . .
C1 C -0.4860(4) 0.6336(6) -1.2362(4) 0.018(2) Uani 1 1 d . . .
C2 C -0.4672(4) 0.6259(6) -1.1704(5) 0.024(3) Uani 1 1 d . . .
C3 C -0.4413(4) 0.6803(6) -1.1379(5) 0.027(3) Uani 1 1 d . . .
H3A H -0.4373 0.7219 -1.1588 0.032 Uiso 1 1 calc R . .
C4 C -0.4214(4) 0.6747(7) -1.0756(5) 0.032(3) Uani 1 1 d . . .
C5 C -0.4289(5) 0.6133(8) -1.0456(5) 0.037(3) Uani 1 1 d . . .
H5A H -0.4146 0.6082 -1.0040 0.044 Uiso 1 1 calc R . .
C6 C -0.4569(5) 0.5590(7) -1.0747(6) 0.041(3) Uani 1 1 d . . .
H6A H -0.4630 0.5189 -1.0525 0.050 Uiso 1 1 calc R . .
C7 C -0.4759(5) 0.5649(6) -1.1377(5) 0.031(3) Uani 1 1 d . . .
H7A H -0.4944 0.5283 -1.1582 0.037 Uiso 1 1 calc R . .
C8 C -0.3909(5) 0.7341(8) -1.0424(6) 0.049(4) Uani 1 1 d . . .
H8A H -0.3799 0.7213 -0.9997 0.074 Uiso 1 1 calc R . .
H8B H -0.4138 0.7740 -1.0431 0.074 Uiso 1 1 calc R . .
H8C H -0.3598 0.7445 -1.0634 0.074 Uiso 1 1 calc R . .
C9 C -0.4701(4) 0.3435(6) -1.4330(5) 0.021(2) Uani 1 1 d . . .
C10 C -0.4609(4) 0.2769(6) -1.4622(5) 0.023(2) Uani 1 1 d . . .
C11 C -0.4234(5) 0.2319(6) -1.4325(5) 0.032(3) Uani 1 1 d . . .
H11A H -0.4054 0.2433 -1.3937 0.039 Uiso 1 1 calc R . .
C12 C -0.4125(6) 0.1683(7) -1.4618(6) 0.044(3) Uani 1 1 d . . .
H12A H -0.3863 0.1388 -1.4429 0.053 Uiso 1 1 calc R . .
C13 C -0.4399(5) 0.1505(8) -1.5165(7) 0.048(4) Uani 1 1 d . . .
H13A H -0.4327 0.1082 -1.5345 0.057 Uiso 1 1 calc R . .
C14 C -0.4786(5) 0.1932(7) -1.5469(5) 0.035(3) Uani 1 1 d . . .
C15 C -0.4885(4) 0.2571(7) -1.5195(5) 0.028(3) Uani 1 1 d . . .
H15A H -0.5139 0.2869 -1.5398 0.033 Uiso 1 1 calc R . .
C16 C -0.5138(6) 0.1691(8) -1.6050(6) 0.057(5) Uani 1 1 d . . .
H16A H -0.5016 0.1247 -1.6177 0.086 Uiso 1 1 calc R . .
H16B H -0.5116 0.2018 -1.6383 0.086 Uiso 1 1 calc R . .
H16C H -0.5504 0.1656 -1.5956 0.086 Uiso 1 1 calc R . .
C17 C -0.3587(4) 0.4255(6) -1.1528(5) 0.023(2) Uani 1 1 d . . .
C18 C -0.3350(4) 0.4904(6) -1.1268(5) 0.030(3) Uani 1 1 d . . .
C19 C -0.3357(5) 0.5489(7) -1.1653(6) 0.035(3) Uani 1 1 d . . .
H19A H -0.3525 0.5471 -1.2062 0.042 Uiso 1 1 calc R . .
C20 C -0.3110(5) 0.6107(8) -1.1421(6) 0.044(4) Uani 1 1 d . . .
C21 C -0.2882(5) 0.6102(8) -1.0802(8) 0.060(5) Uani 1 1 d . . .
H21A H -0.2720 0.6504 -1.0635 0.071 Uiso 1 1 calc R . .
C22 C -0.2884(5) 0.5530(8) -1.0428(7) 0.047(4) Uani 1 1 d . . .
H22A H -0.2728 0.5551 -1.0014 0.056 Uiso 1 1 calc R . .
C23 C -0.3113(5) 0.4931(7) -1.0654(6) 0.040(3) Uani 1 1 d . . .
H23A H -0.3111 0.4541 -1.0399 0.048 Uiso 1 1 calc R . .
C24 C -0.3128(7) 0.6714(8) -1.1857(8) 0.076(6) Uani 1 1 d . . .
H24A H -0.2953 0.7102 -1.1643 0.113 Uiso 1 1 calc R . .
H24B H -0.3496 0.6830 -1.1991 0.113 Uiso 1 1 calc R . .
H24C H -0.2946 0.6599 -1.2216 0.113 Uiso 1 1 calc R . .
C25 C -0.1508(5) 0.4037(8) -1.0352(5) 0.035(3) Uani 1 1 d . . .
C26 C -0.1557(5) 0.4608(9) -1.0798(6) 0.051(4) Uani 1 1 d . . .
C27 C -0.1403(6) 0.5306(9) -1.0619(6) 0.050(4) Uani 1 1 d . . .
H27A H -0.1259 0.5388 -1.0207 0.060 Uiso 1 1 calc R . .
C28 C -0.1458(7) 0.5842(9) -1.1018(7) 0.062(5) Uani 1 1 d . . .
C29 C -0.1659(7) 0.5695(13) -1.1640(9) 0.091(7) Uani 1 1 d . . .
H29A H -0.1708 0.6052 -1.1932 0.110 Uiso 1 1 calc R . .
C30 C -0.1787(8) 0.5008(15) -1.1826(8) 0.108(9) Uani 1 1 d . . .
H30A H -0.1891 0.4906 -1.2246 0.130 Uiso 1 1 calc R . .
C31 C -0.1757(7) 0.4503(11) -1.1391(7) 0.073(5) Uani 1 1 d . . .
H31A H -0.1882 0.4064 -1.1509 0.088 Uiso 1 1 calc R . .
C32 C -0.1323(9) 0.6575(11) -1.0837(9) 0.104(7) Uani 1 1 d . . .
H32A H -0.1186 0.6593 -1.0401 0.156 Uiso 1 1 calc R . .
H32B H -0.1641 0.6855 -1.0904 0.156 Uiso 1 1 calc R . .
H32C H -0.1056 0.6747 -1.1088 0.156 Uiso 1 1 calc R . .
C33 C -0.0148(5) 0.3417(7) -1.0746(5) 0.031(3) Uani 1 1 d . . .
C34 C -0.0277(5) 0.2720(7) -1.0513(6) 0.033(3) Uani 1 1 d . . .
C35 C -0.0044(5) 0.2498(7) -0.9921(6) 0.036(3) Uani 1 1 d . . .
H35A H 0.0198 0.2777 -0.9677 0.043 Uiso 1 1 calc R . .
C36 C -0.0187(6) 0.1844(8) -0.9707(6) 0.046(4) Uani 1 1 d . . .
C37 C -0.0567(6) 0.1462(8) -1.0078(8) 0.061(5) Uani 1 1 d . . .
H37A H -0.0670 0.1033 -0.9934 0.074 Uiso 1 1 calc R . .
C38 C -0.0799(6) 0.1696(9) -1.0656(9) 0.069(5) Uani 1 1 d . . .
H38A H -0.1049 0.1427 -1.0899 0.083 Uiso 1 1 calc R . .
C39 C -0.0655(5) 0.2321(8) -1.0861(7) 0.052(4) Uani 1 1 d . . .
H39A H -0.0814 0.2486 -1.1244 0.062 Uiso 1 1 calc R . .
C40 C 0.0112(6) 0.1572(8) -0.9088(6) 0.059(4) Uani 1 1 d . . .
H40A H -0.0023 0.1122 -0.8997 0.089 Uiso 1 1 calc R . .
H40B H 0.0056 0.1884 -0.8752 0.089 Uiso 1 1 calc R . .
H40C H 0.0490 0.1541 -0.9131 0.089 Uiso 1 1 calc R . .
C41 C 0.0329(4) 0.3614(6) -0.7423(4) 0.022(2) Uani 1 1 d . . .
C42 C 0.0500(5) 0.3695(6) -0.6746(5) 0.031(3) Uani 1 1 d . . .
C43 C 0.0342(6) 0.4260(8) -0.6421(6) 0.052(4) Uani 1 1 d . . .
H43A H 0.0111 0.4589 -0.6619 0.062 Uiso 1 1 calc R . .
C44 C 0.0537(8) 0.4329(10) -0.5787(8) 0.075(6) Uani 1 1 d . . .
H44A H 0.0439 0.4711 -0.5560 0.090 Uiso 1 1 calc R . .
C45 C 0.0868(8) 0.3844(10) -0.5502(7) 0.072(6) Uani 1 1 d . . .
H45A H 0.0987 0.3896 -0.5078 0.086 Uiso 1 1 calc R . .
C46 C 0.1024(6) 0.3303(9) -0.5803(6) 0.055(4) Uani 1 1 d . . .
C47 C 0.0822(5) 0.3206(7) -0.6435(5) 0.041(3) Uani 1 1 d . . .
H47A H 0.0908 0.2805 -0.6643 0.049 Uiso 1 1 calc R . .
C48 C 0.1393(8) 0.2782(10) -0.5452(8) 0.100(8) Uani 1 1 d . . .
H48A H 0.1485 0.2938 -0.5029 0.151 Uiso 1 1 calc R . .
H48B H 0.1715 0.2735 -0.5657 0.151 Uiso 1 1 calc R . .
H48C H 0.1214 0.2343 -0.5448 0.151 Uiso 1 1 calc R . .
C49 C 0.1368(4) 0.5929(7) -0.6496(6) 0.031(3) Uani 1 1 d . . .
C50 C 0.1672(5) 0.5348(7) -0.6197(5) 0.032(3) Uani 1 1 d . . .
C51 C 0.1911(5) 0.5392(7) -0.5596(5) 0.040(3) Uani 1 1 d . . .
H51A H 0.1856 0.5781 -0.5356 0.048 Uiso 1 1 calc R . .
C52 C 0.2228(6) 0.4871(8) -0.5345(6) 0.045(4) Uani 1 1 d . . .
H52A H 0.2393 0.4906 -0.4936 0.053 Uiso 1 1 calc R . .
C53 C 0.2305(6) 0.4287(8) -0.5699(7) 0.053(4) Uani 1 1 d . . .
H53A H 0.2523 0.3932 -0.5524 0.063 Uiso 1 1 calc R . .
C54 C 0.2069(5) 0.4223(8) -0.6299(6) 0.043(3) Uani 1 1 d . . .
C55 C 0.1751(5) 0.4744(7) -0.6540(5) 0.032(3) Uani 1 1 d . . .
H55A H 0.1579 0.4701 -0.6945 0.039 Uiso 1 1 calc R . .
C56 C 0.2177(7) 0.3620(10) -0.6685(7) 0.075(6) Uani 1 1 d . . .
H56A H 0.1981 0.3666 -0.7093 0.112 Uiso 1 1 calc R . .
H56B H 0.2064 0.3207 -0.6488 0.112 Uiso 1 1 calc R . .
H56C H 0.2555 0.3595 -0.6727 0.112 Uiso 1 1 calc R . .
C57 C -0.3179(8) 0.1524(10) -0.9572(7) 0.073(6) Uani 1 1 d . . .
C58 C -0.3027(8) 0.1284(11) -0.8899(7) 0.132(9) Uiso 1 1 d G . .
C59 C -0.2738(7) 0.1679(8) -0.8438(11) 0.171(12) Uiso 1 1 d G . .
H59A H -0.2610 0.2114 -0.8537 0.205 Uiso 1 1 calc R . .
C60 C -0.2639(7) 0.1426(10) -0.7829(9) 0.164(12) Uiso 1 1 d GD . .
C61 C -0.2829(7) 0.0776(10) -0.7682(6) 0.160(11) Uiso 1 1 d G . .
H61A H -0.2762 0.0606 -0.7275 0.192 Uiso 1 1 calc R . .
C62 C -0.3118(6) 0.0380(7) -0.8143(8) 0.082(6) Uiso 1 1 d G . .
H62A H -0.3245 -0.0054 -0.8045 0.098 Uiso 1 1 calc R . .
C63 C -0.3217(6) 0.0634(10) -0.8752(7) 0.192(14) Uiso 1 1 d G . .
H63A H -0.3410 0.0370 -0.9061 0.231 Uiso 1 1 calc R . .
C64 C -0.2251(9) 0.1930(11) -0.7369(10) 0.135(10) Uani 1 1 d D . .
H64A H -0.2194 0.1729 -0.6958 0.203 Uiso 1 1 calc R . .
H64B H -0.2419 0.2375 -0.7344 0.203 Uiso 1 1 calc R . .
H64C H -0.1911 0.1984 -0.7536 0.203 Uiso 1 1 calc R . .
N1 N -0.5100(3) 0.6892(4) -1.2618(4) 0.0196(19) Uani 1 1 d . . .
N2 N -0.5211(3) 0.6752(5) -1.3236(4) 0.022(2) Uani 1 1 d . . .
N3 N -0.5032(4) 0.6142(5) -1.3350(4) 0.025(2) Uani 1 1 d . . .
N4 N -0.4812(4) 0.5854(5) -1.2808(4) 0.029(2) Uani 1 1 d . . .
N5 N -0.4798(4) 0.4032(5) -1.4648(4) 0.028(2) Uani 1 1 d . . .
N6 N -0.4826(4) 0.4513(5) -1.4190(4) 0.029(2) Uani 1 1 d . . .
N7 N -0.4743(4) 0.4223(5) -1.3646(4) 0.028(2) Uani 1 1 d . . .
N8 N -0.4662(3) 0.3535(5) -1.3706(4) 0.021(2) Uani 1 1 d . . .
N9 N -0.3984(4) 0.4177(5) -1.1992(4) 0.028(2) Uani 1 1 d . . .
N10 N -0.4060(4) 0.3489(5) -1.2062(4) 0.029(2) Uani 1 1 d . . .
N11 N -0.3723(4) 0.3153(5) -1.1663(4) 0.029(2) Uani 1 1 d . . .
N12 N -0.3411(4) 0.3620(5) -1.1319(4) 0.030(2) Uani 1 1 d . . .
N13 N -0.1805(4) 0.3487(7) -1.0401(5) 0.040(3) Uani 1 1 d . . .
N14 N -0.1617(4) 0.3083(6) -0.9922(5) 0.037(3) Uani 1 1 d . . .
N15 N -0.1217(4) 0.3408(6) -0.9600(4) 0.037(3) Uani 1 1 d . . .
N16 N -0.1131(4) 0.3995(6) -0.9856(5) 0.038(3) Uani 1 1 d . . .
N17 N 0.0004(4) 0.3962(5) -1.0392(4) 0.032(2) Uani 1 1 d . . .
N18 N 0.0053(4) 0.4486(5) -1.0815(5) 0.036(3) Uani 1 1 d . . .
N19 N -0.0047(4) 0.4250(6) -1.1375(4) 0.037(3) Uani 1 1 d . . .
N20 N -0.0169(4) 0.3566(5) -1.1359(4) 0.034(2) Uani 1 1 d . . .
N21 N 0.0342(4) 0.4109(6) -0.7836(4) 0.032(2) Uani 1 1 d . . .
N22 N 0.0149(4) 0.3830(6) -0.8386(4) 0.035(3) Uani 1 1 d . . .
N23 N 0.0035(4) 0.3181(5) -0.8298(4) 0.028(2) Uani 1 1 d . . .
N24 N 0.0147(3) 0.3022(5) -0.7676(4) 0.023(2) Uani 1 1 d . . .
N25 N 0.1428(4) 0.6566(6) -0.6262(5) 0.048(3) Uani 1 1 d . . .
N26 N 0.1093(4) 0.6971(6) -0.6641(5) 0.048(3) Uani 1 1 d . . .
N27 N 0.0854(4) 0.6582(6) -0.7092(5) 0.046(3) Uani 1 1 d . . .
N28 N 0.1020(4) 0.5941(5) -0.7007(4) 0.030(2) Uani 1 1 d . . .
N29 N -0.3596(5) 0.1485(6) -0.9997(5) 0.045(3) Uani 1 1 d . . .
N30 N -0.3512(4) 0.1964(5) -1.0414(4) 0.031(2) Uani 1 1 d . . .
N31 N -0.3065(4) 0.2263(6) -1.0251(5) 0.036(3) Uani 1 1 d . . .
N32 N -0.2835(5) 0.1992(8) -0.9716(6) 0.064(4) Uani 1 1 d . . .
Ag5B Ag 0.06928(13) 0.5207(2) -1.05673(15) 0.0276(8) Uiso 0.25 1 d P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O2 1.512(8) . ?
P1 O4 1.524(7) . ?
P1 O1 1.523(7) . ?
P1 O3 1.529(7) . ?
W1 O36 1.676(8) . ?
W1 O20 1.888(7) . ?
W1 O18 1.910(8) . ?
W1 O21 1.921(8) . ?
W1 O29 1.924(8) . ?
W1 O1 2.454(7) . ?
W2 O9 1.690(8) . ?
W2 O11 1.892(7) . ?
W2 O24 1.907(8) . ?
W2 O25 1.908(7) . ?
W2 O32 1.918(8) . ?
W2 O3 2.428(7) . ?
W3 O38 1.708(7) . ?
W3 O28 1.898(7) . ?
W3 O19 1.903(7) . ?
W3 O14 1.902(7) . ?
W3 O10 1.925(7) . ?
W3 O2 2.469(7) . ?
W4 O7 1.691(8) . ?
W4 O33 1.892(7) . ?
W4 O29 1.901(8) . ?
W4 O35 1.924(8) . ?
W4 O22 1.923(7) . ?
W4 O1 2.431(7) . ?
W5 O40 1.693(8) . ?
W5 O15 1.900(7) . ?
W5 O13 1.901(7) . ?
W5 O20 1.916(7) . ?
W5 O26 1.923(7) . ?
W5 O4 2.449(7) . ?
W6 O34 1.678(8) . ?
W6 O13 1.905(8) . ?
W6 O31 1.909(8) . ?
W6 O11 1.913(7) . ?
W6 O17 1.918(7) . ?
W6 O4 2.432(7) . ?
W7 O6 1.678(8) . ?
W7 O18 1.898(8) . ?
W7 O15 1.907(7) . ?
W7 O16 1.915(7) . ?
W7 O24 1.937(8) . ?
W7 O3 2.439(7) . ?
W8 O8 1.680(8) . ?
W8 O35 1.875(7) . ?
W8 O30 1.877(7) . ?
W8 O19 1.916(7) . ?
W8 O12 1.935(7) . ?
W8 O2 2.431(7) . ?
W9 O5 1.691(7) . ?
W9 O32 1.872(7) . ?
W9 O31 1.892(8) . ?
W9 O12 1.907(7) . ?
W9 O14 1.922(8) . ?
W9 O2 2.440(7) . ?
W10 O39 1.678(7) . ?
W10 O16 1.902(7) . ?
W10 O33 1.906(7) . ?
W10 O25 1.913(7) . ?
W10 O30 1.924(7) . ?
W10 O3 2.445(7) . ?
W11 O37 1.682(7) . ?
W11 O17 1.896(8) . ?
W11 O28 1.903(7) . ?
W11 O27 1.900(7) . ?
W11 O26 1.918(7) . ?
W11 O4 2.434(6) . ?
W12 O23 1.688(8) . ?
W12 O10 1.888(8) . ?
W12 O27 1.905(7) . ?
W12 O22 1.905(7) . ?
W12 O21 1.914(8) . ?
W12 O1 2.437(7) . ?
Ag1 N24 2.201(10) . ?
Ag1 N20 2.256(9) 4_566 ?
Ag1 N27 2.423(10) 2_543 ?
Ag2 N21 2.192(11) . ?
Ag2 N28 2.215(9) . ?
Ag2 N19 2.598(10) 3_563 ?
Ag3 N12 2.215(9) . ?
Ag3 N13 2.236(9) . ?
Ag3 N31 2.496(11) . ?
Ag4 N2 2.180(8) 2_442 ?
Ag4 N30 2.191(9) . ?
Ag4 N11 2.271(9) . ?
Ag5A Ag5C 1.339(4) . ?
Ag5A Ag5B 1.460(4) . ?
Ag5A N18 2.300(11) . ?
Ag5A N17 2.381(9) 3_563 ?
Ag5A N22 2.476(10) 3_563 ?
Ag5A N16 2.505(10) 3_563 ?
Ag5C N22 2.240(10) 3_563 ?
Ag5C N17 2.266(10) 3_563 ?
Ag5C Ag5B 2.774(5) . ?
Ag6 N8 2.242(8) . ?
Ag6 N1 2.270(9) 2_442 ?
Ag6 N10 2.401(9) . ?
Ag7 N4 2.197(10) . ?
Ag7 N9 2.199(9) . ?
Ag7 N7 2.370(9) . ?
Ag8 N5 2.231(9) 3_462 ?
Ag8 N3 2.296(8) . ?
Ag8 N6 2.346(10) . ?
Ag9 N25 2.222(10) . ?
Ag9 N32 2.242(14) 2_553 ?
Ag9 N14 2.269(11) 2_553 ?
Ag10 N15 2.186(10) . ?
Ag10 N26 2.214(11) 2_543 ?
Ag10 N23 2.243(9) . ?
C1 N1 1.320(13) . ?
C1 N4 1.347(13) . ?
C1 C2 1.446(13) . ?
C2 C3 1.383(15) . ?
C2 C7 1.398(16) . ?
C3 C4 1.378(15) . ?
C4 C5 1.372(18) . ?
C4 C8 1.513(17) . ?
C5 C6 1.372(19) . ?
C6 C7 1.386(15) . ?
C9 N8 1.343(12) . ?
C9 N5 1.348(14) . ?
C9 C10 1.461(15) . ?
C10 C11 1.383(15) . ?
C10 C15 1.395(14) . ?
C11 C12 1.419(17) . ?
C12 C13 1.336(18) . ?
C13 C14 1.380(19) . ?
C14 C15 1.401(17) . ?
C14 C16 1.519(16) . ?
C17 N9 1.337(12) . ?
C17 N12 1.361(14) . ?
C17 C18 1.472(15) . ?
C18 C23 1.385(15) . ?
C18 C19 1.397(16) . ?
C19 C20 1.409(17) . ?
C20 C21 1.388(19) . ?
C20 C24 1.50(2) . ?
C21 C22 1.37(2) . ?
C22 C23 1.359(18) . ?
C25 N13 1.295(17) . ?
C25 N16 1.346(14) . ?
C25 C26 1.46(2) . ?
C26 C31 1.331(19) . ?
C26 C27 1.44(2) . ?
C27 C28 1.34(2) . ?
C28 C29 1.40(2) . ?
C28 C32 1.50(3) . ?
C29 C30 1.41(3) . ?
C30 C31 1.35(3) . ?
C33 N17 1.330(15) . ?
C33 N20 1.339(14) . ?
C33 C34 1.484(17) . ?
C34 C39 1.377(17) . ?
C34 C35 1.404(16) . ?
C35 C36 1.402(19) . ?
C36 C37 1.38(2) . ?
C36 C40 1.544(17) . ?
C37 C38 1.39(2) . ?
C38 C39 1.35(2) . ?
C41 N21 1.304(14) . ?
C41 N24 1.325(14) . ?
C41 C42 1.477(14) . ?
C42 C43 1.375(18) . ?
C42 C47 1.369(17) . ?
C43 C44 1.401(19) . ?
C44 C45 1.35(2) . ?
C45 C46 1.31(2) . ?
C46 C47 1.406(17) . ?
C46 C48 1.51(2) . ?
C49 N28 1.324(13) . ?
C49 N25 1.333(15) . ?
C49 C50 1.465(16) . ?
C50 C51 1.364(15) . ?
C50 C55 1.403(17) . ?
C51 C52 1.356(18) . ?
C52 C53 1.38(2) . ?
C53 C54 1.360(17) . ?
C54 C55 1.353(17) . ?
C54 C56 1.47(2) . ?
C57 N32 1.31(2) . ?
C57 N29 1.31(2) . ?
C57 C58 1.523(18) . ?
C58 C59 1.3900 . ?
C58 C63 1.3900 . ?
C59 C60 1.3900 . ?
C60 C61 1.3900 . ?
C60 C64 1.631(16) . ?
C61 C62 1.3900 . ?
C62 C63 1.3900 . ?
N1 N2 1.350(11) . ?
N1 Ag6 2.270(9) 2_452 ?
N2 N3 1.294(12) . ?
N2 Ag4 2.180(8) 2_452 ?
N3 N4 1.351(12) . ?
N5 N6 1.357(12) . ?
N5 Ag8 2.231(9) 3_462 ?
N6 N7 1.289(11) . ?
N7 N8 1.352(13) . ?
N9 N10 1.350(13) . ?
N10 N11 1.308(12) . ?
N11 N12 1.357(12) . ?
N13 N14 1.334(14) . ?
N14 N15 1.313(13) . ?
N14 Ag9 2.269(11) 2_543 ?
N15 N16 1.288(15) . ?
N16 Ag5B 2.048(12) 3_563 ?
N16 Ag5A 2.505(10) 3_563 ?
N17 N18 1.374(14) . ?
N17 Ag5C 2.266(10) 3_563 ?
N17 Ag5A 2.381(9) 3_563 ?
N18 N19 1.283(12) . ?
N18 Ag5B 2.143(11) . ?
N19 N20 1.358(13) . ?
N19 Ag2 2.598(10) 3_563 ?
N20 Ag1 2.256(9) 4_565 ?
N21 N22 1.338(12) . ?
N22 N23 1.303(13) . ?
N22 Ag5C 2.240(10) 3_563 ?
N22 Ag5A 2.476(10) 3_563 ?
N23 N24 1.369(11) . ?
N25 N26 1.352(14) . ?
N26 N27 1.316(14) . ?
N26 Ag10 2.214(11) 2_553 ?
N27 N28 1.313(14) . ?
N27 Ag1 2.423(10) 2_553 ?
N29 N30 1.318(14) . ?
N30 N31 1.271(13) . ?
N31 N32 1.334(15) . ?
N32 Ag9 2.242(14) 2_543 ?
Ag5B N16 2.048(12) 3_563 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 P1 O4 110.0(4) . . ?
O2 P1 O1 109.0(4) . . ?
O4 P1 O1 110.0(4) . . ?
O2 P1 O3 108.9(4) . . ?
O4 P1 O3 109.1(4) . . ?
O1 P1 O3 109.8(4) . . ?
O36 W1 O20 102.2(4) . . ?
O36 W1 O18 103.3(4) . . ?
O20 W1 O18 85.6(3) . . ?
O36 W1 O21 101.7(4) . . ?
O20 W1 O21 89.9(3) . . ?
O18 W1 O21 155.0(3) . . ?
O36 W1 O29 102.5(4) . . ?
O20 W1 O29 155.3(3) . . ?
O18 W1 O29 87.5(3) . . ?
O21 W1 O29 86.4(3) . . ?
O36 W1 O1 171.6(4) . . ?
O20 W1 O1 83.5(3) . . ?
O18 W1 O1 83.1(3) . . ?
O21 W1 O1 72.0(3) . . ?
O29 W1 O1 72.1(3) . . ?
O9 W2 O11 103.5(4) . . ?
O9 W2 O24 101.6(4) . . ?
O11 W2 O24 90.0(3) . . ?
O9 W2 O25 101.2(3) . . ?
O11 W2 O25 155.1(3) . . ?
O24 W2 O25 87.9(3) . . ?
O9 W2 O32 103.2(4) . . ?
O11 W2 O32 84.4(3) . . ?
O24 W2 O32 155.1(3) . . ?
O25 W2 O32 87.2(3) . . ?
O9 W2 O3 171.4(3) . . ?
O11 W2 O3 83.2(3) . . ?
O24 W2 O3 72.8(3) . . ?
O25 W2 O3 72.4(3) . . ?
O32 W2 O3 82.5(3) . . ?
O38 W3 O28 102.4(4) . . ?
O38 W3 O19 102.0(4) . . ?
O28 W3 O19 155.5(3) . . ?
O38 W3 O14 102.2(4) . . ?
O28 W3 O14 89.5(3) . . ?
O19 W3 O14 87.4(3) . . ?
O38 W3 O10 102.9(4) . . ?
O28 W3 O10 84.1(3) . . ?
O19 W3 O10 88.5(3) . . ?
O14 W3 O10 154.8(3) . . ?
O38 W3 O2 171.8(3) . . ?
O28 W3 O2 84.0(3) . . ?
O19 W3 O2 71.9(3) . . ?
O14 W3 O2 72.3(3) . . ?
O10 W3 O2 82.8(3) . . ?
O7 W4 O33 101.2(3) . . ?
O7 W4 O29 101.9(4) . . ?
O33 W4 O29 90.4(3) . . ?
O7 W4 O35 102.9(4) . . ?
O33 W4 O35 84.6(3) . . ?
O29 W4 O35 155.2(3) . . ?
O7 W4 O22 102.8(4) . . ?
O33 W4 O22 155.9(3) . . ?
O29 W4 O22 86.9(3) . . ?
O35 W4 O22 87.9(3) . . ?
O7 W4 O1 173.1(3) . . ?
O33 W4 O1 83.7(3) . . ?
O29 W4 O1 73.0(3) . . ?
O35 W4 O1 82.3(3) . . ?
O22 W4 O1 72.6(3) . . ?
O40 W5 O15 104.0(4) . . ?
O40 W5 O13 102.7(4) . . ?
O15 W5 O13 89.8(3) . . ?
O40 W5 O20 102.7(4) . . ?
O15 W5 O20 84.5(3) . . ?
O13 W5 O20 154.6(3) . . ?
O40 W5 O26 100.8(3) . . ?
O15 W5 O26 155.0(3) . . ?
O13 W5 O26 87.7(3) . . ?
O20 W5 O26 87.2(3) . . ?
O40 W5 O4 170.7(3) . . ?
O15 W5 O4 83.7(3) . . ?
O13 W5 O4 71.9(3) . . ?
O20 W5 O4 82.9(3) . . ?
O26 W5 O4 71.8(3) . . ?
O34 W6 O13 101.6(4) . . ?
O34 W6 O31 103.1(4) . . ?
O13 W6 O31 155.3(3) . . ?
O34 W6 O11 103.4(3) . . ?
O13 W6 O11 88.4(3) . . ?
O31 W6 O11 83.9(3) . . ?
O34 W6 O17 102.0(3) . . ?
O13 W6 O17 86.9(3) . . ?
O31 W6 O17 90.0(3) . . ?
O11 W6 O17 154.6(3) . . ?
O34 W6 O4 171.0(3) . . ?
O13 W6 O4 72.2(3) . . ?
O31 W6 O4 83.5(3) . . ?
O11 W6 O4 83.2(3) . . ?
O17 W6 O4 71.5(3) . . ?
O6 W7 O18 103.3(4) . . ?
O6 W7 O15 103.1(4) . . ?
O18 W7 O15 85.5(3) . . ?
O6 W7 O16 102.0(3) . . ?
O18 W7 O16 88.9(3) . . ?
O15 W7 O16 155.0(3) . . ?
O6 W7 O24 100.8(4) . . ?
O18 W7 O24 155.8(3) . . ?
O15 W7 O24 88.1(3) . . ?
O16 W7 O24 87.1(3) . . ?
O6 W7 O3 170.7(3) . . ?
O18 W7 O3 84.0(3) . . ?
O15 W7 O3 83.0(3) . . ?
O16 W7 O3 72.2(3) . . ?
O24 W7 O3 72.1(3) . . ?
O8 W8 O35 102.9(4) . . ?
O8 W8 O30 104.0(3) . . ?
O35 W8 O30 85.7(3) . . ?
O8 W8 O19 100.4(4) . . ?
O35 W8 O19 90.4(3) . . ?
O30 W8 O19 155.5(3) . . ?
O8 W8 O12 101.7(4) . . ?
O35 W8 O12 155.4(3) . . ?
O30 W8 O12 88.8(3) . . ?
O19 W8 O12 84.8(3) . . ?
O8 W8 O2 170.8(3) . . ?
O35 W8 O2 83.5(3) . . ?
O30 W8 O2 82.9(3) . . ?
O19 W8 O2 72.6(3) . . ?
O12 W8 O2 72.1(3) . . ?
O5 W9 O32 103.7(4) . . ?
O5 W9 O31 103.2(4) . . ?
O32 W9 O31 85.2(3) . . ?
O5 W9 O12 100.7(4) . . ?
O32 W9 O12 90.8(3) . . ?
O31 W9 O12 156.0(3) . . ?
O5 W9 O14 100.9(4) . . ?
O32 W9 O14 155.3(3) . . ?
O31 W9 O14 87.8(3) . . ?
O12 W9 O14 86.1(3) . . ?
O5 W9 O2 170.6(4) . . ?
O32 W9 O2 83.0(3) . . ?
O31 W9 O2 83.7(3) . . ?
O12 W9 O2 72.3(3) . . ?
O14 W9 O2 72.7(3) . . ?
O39 W10 O16 101.1(3) . . ?
O39 W10 O33 102.7(3) . . ?
O16 W10 O33 88.1(3) . . ?
O39 W10 O25 102.0(3) . . ?
O16 W10 O25 87.9(3) . . ?
O33 W10 O25 155.3(3) . . ?
O39 W10 O30 103.3(3) . . ?
O16 W10 O30 155.5(3) . . ?
O33 W10 O30 84.4(3) . . ?
O25 W10 O30 89.3(3) . . ?
O39 W10 O3 170.9(3) . . ?
O16 W10 O3 72.2(3) . . ?
O33 W10 O3 83.6(3) . . ?
O25 W10 O3 72.0(3) . . ?
O30 W10 O3 83.8(3) . . ?
O37 W11 O17 102.7(3) . . ?
O37 W11 O28 102.3(3) . . ?
O17 W11 O28 88.8(3) . . ?
O37 W11 O27 101.8(3) . . ?
O17 W11 O27 155.5(3) . . ?
O28 W11 O27 85.4(3) . . ?
O37 W11 O26 101.7(3) . . ?
O17 W11 O26 87.0(3) . . ?
O28 W11 O26 156.0(3) . . ?
O27 W11 O26 88.7(3) . . ?
O37 W11 O4 171.7(3) . . ?
O17 W11 O4 71.8(3) . . ?
O28 W11 O4 84.0(3) . . ?
O27 W11 O4 83.9(3) . . ?
O26 W11 O4 72.2(3) . . ?
O23 W12 O10 101.9(4) . . ?
O23 W12 O27 102.9(4) . . ?
O10 W12 O27 85.1(3) . . ?
O23 W12 O22 101.2(4) . . ?
O10 W12 O22 90.9(3) . . ?
O27 W12 O22 155.9(3) . . ?
O23 W12 O21 101.9(4) . . ?
O10 W12 O21 156.1(3) . . ?
O27 W12 O21 87.7(3) . . ?
O22 W12 O21 86.4(3) . . ?
O23 W12 O1 171.7(3) . . ?
O10 W12 O1 84.0(3) . . ?
O27 W12 O1 83.3(3) . . ?
O22 W12 O1 72.7(3) . . ?
O21 W12 O1 72.5(3) . . ?
P1 O1 W4 126.8(4) . . ?
P1 O1 W12 126.0(4) . . ?
W4 O1 W12 88.8(2) . . ?
P1 O1 W1 125.5(4) . . ?
W4 O1 W1 88.6(2) . . ?
W12 O1 W1 88.9(2) . . ?
P1 O2 W8 126.9(4) . . ?
P1 O2 W9 125.9(4) . . ?
W8 O2 W9 89.4(2) . . ?
P1 O2 W3 125.7(4) . . ?
W8 O2 W3 88.4(2) . . ?
W9 O2 W3 88.2(2) . . ?
P1 O3 W2 126.7(4) . . ?
P1 O3 W7 126.0(4) . . ?
W2 O3 W7 89.3(2) . . ?
P1 O3 W10 125.3(4) . . ?
W2 O3 W10 88.9(2) . . ?
W7 O3 W10 88.7(2) . . ?
P1 O4 W6 126.3(4) . . ?
P1 O4 W11 125.8(4) . . ?
W6 O4 W11 89.2(2) . . ?
P1 O4 W5 125.7(4) . . ?
W6 O4 W5 88.6(2) . . ?
W11 O4 W5 89.2(2) . . ?
W12 O10 W3 152.4(4) . . ?
W2 O11 W6 153.0(5) . . ?
W9 O12 W8 126.2(4) . . ?
W5 O13 W6 127.2(4) . . ?
W3 O14 W9 126.6(4) . . ?
W5 O15 W7 152.4(5) . . ?
W10 O16 W7 126.8(4) . . ?
W11 O17 W6 127.3(4) . . ?
W7 O18 W1 151.3(4) . . ?
W3 O19 W8 127.0(4) . . ?
W1 O20 W5 152.7(4) . . ?
W1 O21 W12 126.6(4) . . ?
W12 O22 W4 125.8(4) . . ?
W2 O24 W7 125.7(4) . . ?
W10 O25 W2 126.5(4) . . ?
W11 O26 W5 126.5(4) . . ?
W12 O27 W11 151.4(4) . . ?
W3 O28 W11 152.2(4) . . ?
W4 O29 W1 126.2(4) . . ?
W8 O30 W10 151.9(4) . . ?
W9 O31 W6 152.3(4) . . ?
W9 O32 W2 152.8(4) . . ?
W4 O33 W10 152.8(4) . . ?
W8 O35 W4 152.1(5) . . ?
N24 Ag1 N20 149.1(3) . 4_566 ?
N24 Ag1 N27 107.9(3) . 2_543 ?
N20 Ag1 N27 99.8(4) 4_566 2_543 ?
N21 Ag2 N28 147.8(3) . . ?
N21 Ag2 N19 98.3(3) . 3_563 ?
N28 Ag2 N19 113.6(3) . 3_563 ?
N12 Ag3 N13 148.7(4) . . ?
N12 Ag3 N31 96.8(3) . . ?
N13 Ag3 N31 114.3(4) . . ?
N2 Ag4 N30 139.1(4) 2_442 . ?
N2 Ag4 N11 116.6(3) 2_442 . ?
N30 Ag4 N11 104.3(3) . . ?
Ag5C Ag5A Ag5B 164.6(3) . . ?
Ag5C Ag5A N18 99.9(3) . . ?
Ag5B Ag5A N18 65.1(3) . . ?
Ag5C Ag5A N17 68.6(3) . 3_563 ?
Ag5B Ag5A N17 113.5(3) . 3_563 ?
N18 Ag5A N17 116.0(3) . 3_563 ?
Ag5C Ag5A N22 64.0(3) . 3_563 ?
Ag5B Ag5A N22 120.5(3) . 3_563 ?
N18 Ag5A N22 101.0(3) . 3_563 ?
N17 Ag5A N22 123.5(4) 3_563 3_563 ?
Ag5C Ag5A N16 138.5(3) . 3_563 ?
Ag5B Ag5A N16 54.8(3) . 3_563 ?
N18 Ag5A N16 118.8(4) . 3_563 ?
N17 Ag5A N16 80.8(3) 3_563 3_563 ?
N22 Ag5A N16 117.5(3) 3_563 3_563 ?
Ag5A Ag5C N22 83.5(3) . 3_563 ?
Ag5A Ag5C N17 78.0(3) . 3_563 ?
N22 Ag5C N17 143.5(4) 3_563 3_563 ?
Ag5A Ag5C Ag5B 8.04(14) . . ?
N22 Ag5C Ag5B 86.4(3) 3_563 . ?
N17 Ag5C Ag5B 79.7(3) 3_563 . ?
N8 Ag6 N1 148.2(3) . 2_442 ?
N8 Ag6 N10 104.8(3) . . ?
N1 Ag6 N10 107.0(3) 2_442 . ?
N4 Ag7 N9 140.1(3) . . ?
N4 Ag7 N7 105.7(3) . . ?
N9 Ag7 N7 114.2(3) . . ?
N5 Ag8 N3 141.6(3) 3_462 . ?
N5 Ag8 N6 112.6(3) 3_462 . ?
N3 Ag8 N6 105.3(3) . . ?
N25 Ag9 N32 126.4(5) . 2_553 ?
N25 Ag9 N14 119.1(4) . 2_553 ?
N32 Ag9 N14 113.2(5) 2_553 2_553 ?
N15 Ag10 N26 121.1(4) . 2_543 ?
N15 Ag10 N23 128.4(4) . . ?
N26 Ag10 N23 110.1(3) 2_543 . ?
N1 C1 N4 109.8(9) . . ?
N1 C1 C2 125.2(9) . . ?
N4 C1 C2 125.0(10) . . ?
C3 C2 C7 118.6(10) . . ?
C3 C2 C1 119.8(10) . . ?
C7 C2 C1 121.5(10) . . ?
C4 C3 C2 121.9(11) . . ?
C5 C4 C3 117.9(11) . . ?
C5 C4 C8 121.5(11) . . ?
C3 C4 C8 120.6(12) . . ?
C4 C5 C6 122.5(11) . . ?
C7 C6 C5 119.0(12) . . ?
C6 C7 C2 120.0(12) . . ?
N8 C9 N5 111.7(10) . . ?
N8 C9 C10 123.6(10) . . ?
N5 C9 C10 124.5(9) . . ?
C11 C10 C15 118.7(11) . . ?
C11 C10 C9 119.2(10) . . ?
C15 C10 C9 122.2(10) . . ?
C10 C11 C12 119.6(11) . . ?
C13 C12 C11 120.3(13) . . ?
C12 C13 C14 121.9(14) . . ?
C13 C14 C15 118.4(11) . . ?
C13 C14 C16 121.3(14) . . ?
C15 C14 C16 120.0(13) . . ?
C14 C15 C10 121.1(11) . . ?
N9 C17 N12 109.4(10) . . ?
N9 C17 C18 127.8(10) . . ?
N12 C17 C18 122.8(9) . . ?
C23 C18 C19 120.5(12) . . ?
C23 C18 C17 120.3(11) . . ?
C19 C18 C17 119.2(10) . . ?
C18 C19 C20 119.9(12) . . ?
C21 C20 C19 116.9(13) . . ?
C21 C20 C24 125.6(14) . . ?
C19 C20 C24 117.5(13) . . ?
C22 C21 C20 122.6(13) . . ?
C23 C22 C21 120.5(13) . . ?
C22 C23 C18 119.5(13) . . ?
N13 C25 N16 111.2(12) . . ?
N13 C25 C26 124.3(12) . . ?
N16 C25 C26 124.5(13) . . ?
C31 C26 C27 117.3(15) . . ?
C31 C26 C25 120.4(17) . . ?
C27 C26 C25 122.3(13) . . ?
C28 C27 C26 123.2(15) . . ?
C27 C28 C29 116.8(18) . . ?
C27 C28 C32 124.1(16) . . ?
C29 C28 C32 119.1(16) . . ?
C30 C29 C28 120.4(18) . . ?
C31 C30 C29 119.5(18) . . ?
C30 C31 C26 123(2) . . ?
N17 C33 N20 111.6(11) . . ?
N17 C33 C34 126.0(11) . . ?
N20 C33 C34 122.5(11) . . ?
C39 C34 C35 120.8(13) . . ?
C39 C34 C33 119.2(12) . . ?
C35 C34 C33 119.8(12) . . ?
C34 C35 C36 118.3(12) . . ?
C37 C36 C35 118.5(13) . . ?
C37 C36 C40 123.4(15) . . ?
C35 C36 C40 118.0(13) . . ?
C36 C37 C38 122.2(15) . . ?
C39 C38 C37 118.9(14) . . ?
C38 C39 C34 121.2(14) . . ?
N21 C41 N24 112.9(9) . . ?
N21 C41 C42 124.2(11) . . ?
N24 C41 C42 122.9(10) . . ?
C43 C42 C47 119.3(12) . . ?
C43 C42 C41 120.7(12) . . ?
C47 C42 C41 120.0(11) . . ?
C42 C43 C44 118.4(15) . . ?
C45 C44 C43 120.3(16) . . ?
C46 C45 C44 122.2(15) . . ?
C45 C46 C47 118.9(15) . . ?
C45 C46 C48 119.1(15) . . ?
C47 C46 C48 121.9(16) . . ?
C42 C47 C46 120.6(14) . . ?
N28 C49 N25 109.4(10) . . ?
N28 C49 C50 129.8(11) . . ?
N25 C49 C50 120.8(10) . . ?
C51 C50 C55 118.3(11) . . ?
C51 C50 C49 121.3(12) . . ?
C55 C50 C49 120.2(10) . . ?
C52 C51 C50 120.5(13) . . ?
C51 C52 C53 119.8(12) . . ?
C52 C53 C54 121.3(13) . . ?
C55 C54 C53 118.2(13) . . ?
C55 C54 C56 120.7(12) . . ?
C53 C54 C56 121.1(13) . . ?
C54 C55 C50 121.9(12) . . ?
N32 C57 N29 111.7(12) . . ?
N32 C57 C58 109.1(19) . . ?
N29 C57 C58 137.8(19) . . ?
C59 C58 C63 120.0 . . ?
C59 C58 C57 124.4(18) . . ?
C63 C58 C57 115.6(18) . . ?
C58 C59 C60 120.0 . . ?
C61 C60 C59 120.0 . . ?
C61 C60 C64 126.8(17) . . ?
C59 C60 C64 113.0(17) . . ?
C60 C61 C62 120.0 . . ?
C63 C62 C61 120.0 . . ?
C62 C63 C58 120.0 . . ?
C1 N1 N2 106.4(8) . . ?
C1 N1 Ag6 129.7(7) . 2_452 ?
N2 N1 Ag6 123.6(6) . 2_452 ?
N3 N2 N1 109.1(8) . . ?
N3 N2 Ag4 122.6(6) . 2_452 ?
N1 N2 Ag4 119.3(6) . 2_452 ?
N2 N3 N4 109.3(8) . . ?
N2 N3 Ag8 123.1(6) . . ?
N4 N3 Ag8 127.6(7) . . ?
C1 N4 N3 105.4(9) . . ?
C1 N4 Ag7 128.3(7) . . ?
N3 N4 Ag7 126.3(7) . . ?
C9 N5 N6 103.9(8) . . ?
C9 N5 Ag8 135.1(7) . 3_462 ?
N6 N5 Ag8 120.9(7) . 3_462 ?
N7 N6 N5 109.8(9) . . ?
N7 N6 Ag8 123.7(7) . . ?
N5 N6 Ag8 126.2(6) . . ?
N6 N7 N8 110.7(8) . . ?
N6 N7 Ag7 124.9(8) . . ?
N8 N7 Ag7 121.2(6) . . ?
C9 N8 N7 103.8(8) . . ?
C9 N8 Ag6 136.6(8) . . ?
N7 N8 Ag6 118.7(6) . . ?
C17 N9 N10 106.1(8) . . ?
C17 N9 Ag7 139.3(8) . . ?
N10 N9 Ag7 114.3(6) . . ?
N11 N10 N9 110.1(8) . . ?
N11 N10 Ag6 120.1(7) . . ?
N9 N10 Ag6 129.4(6) . . ?
N10 N11 N12 108.5(9) . . ?
N10 N11 Ag4 114.7(7) . . ?
N12 N11 Ag4 123.8(7) . . ?
N11 N12 C17 105.9(8) . . ?
N11 N12 Ag3 120.3(7) . . ?
C17 N12 Ag3 132.0(7) . . ?
C25 N13 N14 105.4(10) . . ?
C25 N13 Ag3 134.0(10) . . ?
N14 N13 Ag3 113.7(8) . . ?
N15 N14 N13 108.1(11) . . ?
N15 N14 Ag9 117.3(8) . 2_543 ?
N13 N14 Ag9 133.1(8) . 2_543 ?
N14 N15 N16 110.4(10) . . ?
N14 N15 Ag10 120.3(9) . . ?
N16 N15 Ag10 129.3(8) . . ?
N15 N16 C25 104.8(10) . . ?
N15 N16 Ag5B 125.5(8) . 3_563 ?
C25 N16 Ag5B 126.9(10) . 3_563 ?
N15 N16 Ag5A 105.5(7) . 3_563 ?
C25 N16 Ag5A 146.1(9) . 3_563 ?
Ag5B N16 Ag5A 35.7(2) 3_563 3_563 ?
C33 N17 N18 104.4(9) . . ?
C33 N17 Ag5C 135.2(9) . 3_563 ?
N18 N17 Ag5C 119.6(7) . 3_563 ?
C33 N17 Ag5A 133.5(8) . 3_563 ?
N18 N17 Ag5A 113.4(7) . 3_563 ?
Ag5C N17 Ag5A 33.39(17) 3_563 3_563 ?
N19 N18 N17 109.4(10) . . ?
N19 N18 Ag5B 122.0(8) . . ?
N17 N18 Ag5B 115.6(7) . . ?
N19 N18 Ag5A 122.8(8) . . ?
N17 N18 Ag5A 127.6(7) . . ?
Ag5B N18 Ag5A 38.2(2) . . ?
N18 N19 N20 110.2(9) . . ?
N18 N19 Ag2 129.1(8) . 3_563 ?
N20 N19 Ag2 109.3(7) . 3_563 ?
C33 N20 N19 104.4(9) . . ?
C33 N20 Ag1 134.5(8) . 4_565 ?
N19 N20 Ag1 117.9(7) . 4_565 ?
C41 N21 N22 105.6(10) . . ?
C41 N21 Ag2 127.0(8) . . ?
N22 N21 Ag2 127.3(8) . . ?
N23 N22 N21 109.0(9) . . ?
N23 N22 Ag5C 116.2(7) . 3_563 ?
N21 N22 Ag5C 129.8(8) . 3_563 ?
N23 N22 Ag5A 117.3(7) . 3_563 ?
N21 N22 Ag5A 131.7(8) . 3_563 ?
Ag5C N22 Ag5A 32.51(17) 3_563 3_563 ?
N22 N23 N24 109.3(9) . . ?
N22 N23 Ag10 110.7(7) . . ?
N24 N23 Ag10 118.5(7) . . ?
C41 N24 N23 103.3(9) . . ?
C41 N24 Ag1 130.8(7) . . ?
N23 N24 Ag1 124.6(7) . . ?
C49 N25 N26 105.8(10) . . ?
C49 N25 Ag9 138.9(8) . . ?
N26 N25 Ag9 115.1(8) . . ?
N27 N26 N25 108.3(11) . . ?
N27 N26 Ag10 128.1(8) . 2_553 ?
N25 N26 Ag10 117.3(8) . 2_553 ?
N28 N27 N26 109.0(10) . . ?
N28 N27 Ag1 131.0(7) . 2_553 ?
N26 N27 Ag1 118.6(9) . 2_553 ?
N27 N28 C49 107.5(9) . . ?
N27 N28 Ag2 114.3(7) . . ?
C49 N28 Ag2 137.7(8) . . ?
N30 N29 C57 105.0(13) . . ?
N31 N30 N29 109.4(10) . . ?
N31 N30 Ag4 126.6(8) . . ?
N29 N30 Ag4 124.0(8) . . ?
N30 N31 N32 110.1(12) . . ?
N30 N31 Ag3 128.3(8) . . ?
N32 N31 Ag3 121.3(9) . . ?
C57 N32 N31 103.8(12) . . ?
C57 N32 Ag9 133.5(11) . 2_543 ?
N31 N32 Ag9 118.4(11) . 2_543 ?
Ag5A Ag5B N16 89.5(4) . 3_563 ?
Ag5A Ag5B N18 76.7(3) . . ?
N16 Ag5B N18 161.7(4) 3_563 . ?
Ag5A Ag5B Ag5C 7.37(13) . . ?
N16 Ag5B Ag5C 96.1(3) 3_563 . ?
N18 Ag5B Ag5C 69.6(3) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.93
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         5.068
_refine_diff_density_min         -2.045
_refine_diff_density_rms         0.292

