# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2015

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_i:\sabine\sabine\haase\1320m
_database_code_depnum_ccdc_archive 'CCDC 1047297'
_audit_update_record             
;
2015-05-10 deposited with the CCDC.
2015-11-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H22 O5 V'
_chemical_formula_sum            'C30 H22 O5 V'
_chemical_formula_weight         513.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/n'
_symmetry_space_group_name_HALL  '-P 2yn'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.7159(9)
_cell_length_b                   15.199(1)
_cell_length_c                   12.9016(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.743(4)
_cell_angle_gamma                90.00
_cell_volume                     2476.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    1912
_cell_measurement_theta_min      3.12
_cell_measurement_theta_max      27.93

_exptl_crystal_description       rod
_exptl_crystal_colour            'dark green'
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.377
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1060
_exptl_absorpt_coefficient_mu    0.440
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9251
_exptl_absorpt_correction_T_max  0.9741
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd., 2009
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  
;  
Oxford Diffraction Xcalibur (TM) Single Crystal X-ray Diffractometer 
with Sapphire CCD Detector.
;
_diffrn_measurement_method       
;
Rotation method data acquisition using omega and phi scans.
;
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        0
_diffrn_reflns_number            9435
_diffrn_reflns_av_R_equivalents  0.0591
_diffrn_reflns_av_sigmaI/netI    0.1020
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.12
_diffrn_reflns_theta_max         25.19
_reflns_number_total             4443
_reflns_number_gt                2006
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrysAlis CCD (Oxford Diffraction Ltd., 2009)
;
_computing_cell_refinement       
;
CrysAlis RED (Oxford Diffraction Ltd., 2009)
;
_computing_data_reduction        
;
CrysAlis RED (Oxford Diffraction Ltd., 2009)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1100P)²+0.2857P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4443
_refine_ls_number_parameters     325
_refine_ls_number_restraints     19
_refine_ls_R_factor_all          0.1894
_refine_ls_R_factor_gt           0.0857
_refine_ls_wR_factor_ref         0.2386
_refine_ls_wR_factor_gt          0.1951
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.1388(5) 0.5227(4) 0.7331(5) 0.0657(18) Uani 1 1 d U . .
C2 C -0.1640(5) 0.4909(5) 0.6317(5) 0.074(2) Uani 1 1 d . . .
H2 H -0.2273 0.5093 0.5947 0.088 Uiso 1 1 calc R . .
C3 C -0.1009(5) 0.4339(5) 0.5824(5) 0.0675(18) Uani 1 1 d . . .
C4 C -0.1379(5) 0.3994(4) 0.4747(5) 0.0604(17) Uani 1 1 d . . .
C5 C -0.0616(6) 0.3695(4) 0.4168(6) 0.0758(19) Uani 1 1 d U . .
H4 H 0.0097 0.3731 0.4428 0.091 Uiso 1 1 calc R . .
C6 C -0.0925(8) 0.3331(5) 0.3170(6) 0.092(2) Uani 1 1 d U . .
H6 H -0.0424 0.3142 0.2748 0.111 Uiso 1 1 calc R . .
C7 C -0.2017(8) 0.3263(5) 0.2835(6) 0.093(2) Uani 1 1 d . . .
H7 H -0.2250 0.3006 0.2195 0.111 Uiso 1 1 calc R . .
C8 C -0.2706(7) 0.3566(6) 0.3434(6) 0.093(2) Uani 1 1 d . . .
H8 H -0.3425 0.3528 0.3200 0.112 Uiso 1 1 calc R . .
C9 C -0.2404(6) 0.3928(5) 0.4371(5) 0.078(2) Uani 1 1 d . . .
H9 H -0.2916 0.4136 0.4767 0.094 Uiso 1 1 calc R . .
C10 C -0.2128(5) 0.5844(4) 0.7812(5) 0.0655(17) Uani 1 1 d . . .
C11 C -0.3113(6) 0.6039(5) 0.7400(6) 0.094(2) Uani 1 1 d . . .
H11 H -0.3374 0.5786 0.6766 0.112 Uiso 1 1 calc R . .
C12 C -0.3732(7) 0.6579(6) 0.7860(8) 0.107(3) Uani 1 1 d . . .
H12 H -0.4393 0.6725 0.7516 0.128 Uiso 1 1 calc R . .
C13 C -0.3430(8) 0.6924(5) 0.8823(8) 0.099(3) Uani 1 1 d . . .
H13 H -0.3886 0.7274 0.9158 0.119 Uiso 1 1 calc R . .
C14 C -0.2411(8) 0.6733(5) 0.9285(6) 0.097(2) Uani 1 1 d . . .
H14 H -0.2167 0.6958 0.9939 0.117 Uiso 1 1 calc R . .
C15 C -0.1754(5) 0.6194(5) 0.8751(6) 0.075(2) Uani 1 1 d . . .
H15 H -0.1063 0.6078 0.9041 0.090 Uiso 1 1 calc R . .
C16 C 0.2465(5) 0.5042(5) 0.8859(5) 0.0714(17) Uani 1 1 d U . .
C17 C 0.3166(5) 0.4662(5) 0.8254(5) 0.0756(18) Uani 1 1 d U . .
H17 H 0.3885 0.4701 0.8486 0.091 Uiso 1 1 calc R . .
C18 C 0.2867(5) 0.4225(5) 0.7322(5) 0.0705(16) Uani 1 1 d U . .
C19 C 0.3654(5) 0.3954(4) 0.6628(5) 0.0667(16) Uani 1 1 d U . .
C20 C 0.4692(6) 0.4187(7) 0.6790(6) 0.117(3) Uani 1 1 d . . .
H20 H 0.4939 0.4552 0.7344 0.140 Uiso 1 1 calc R . .
C21 C 0.5378(7) 0.3873(9) 0.6119(8) 0.152(5) Uani 1 1 d . . .
H21 H 0.6087 0.4035 0.6225 0.183 Uiso 1 1 calc R . .
C22 C 0.5049(7) 0.3350(7) 0.5335(7) 0.111(3) Uani 1 1 d . . .
H22 H 0.5528 0.3145 0.4899 0.133 Uiso 1 1 calc R . .
C23 C 0.4033(7) 0.3113(6) 0.5160(6) 0.103(3) Uani 1 1 d U . .
H23 H 0.3807 0.2741 0.4605 0.124 Uiso 1 1 calc R . .
C24 C 0.3322(6) 0.3417(5) 0.5799(5) 0.0814(19) Uani 1 1 d U . .
H24 H 0.2612 0.3259 0.5669 0.098 Uiso 1 1 calc R . .
C25 C 0.2866(5) 0.5647(4) 0.9726(5) 0.0663(16) Uani 1 1 d U . .
C26 C 0.3860(6) 0.5984(5) 0.9877(7) 0.101(3) Uani 1 1 d . . .
H26 H 0.4354 0.5831 0.9431 0.121 Uiso 1 1 calc R . .
C27 C 0.4129(7) 0.6541(7) 1.0673(9) 0.131(4) Uani 1 1 d . . .
H27 H 0.4813 0.6768 1.0761 0.157 Uiso 1 1 calc R . .
C28 C 0.3456(9) 0.6787(6) 1.1348(7) 0.112(3) Uani 1 1 d . . .
H28 H 0.3673 0.7171 1.1893 0.134 Uiso 1 1 calc R . .
C29 C 0.2444(8) 0.6462(5) 1.1220(7) 0.092(2) Uani 1 1 d . . .
H29 H 0.1967 0.6617 1.1682 0.111 Uiso 1 1 calc R . .
C30 C 0.2139(5) 0.5896(5) 1.0390(6) 0.076(2) Uani 1 1 d . . .
H30 H 0.1448 0.5686 1.0281 0.091 Uiso 1 1 calc R . .
O1 O -0.0537(3) 0.5030(3) 0.7900(3) 0.0627(12) Uani 1 1 d U . .
O2 O 0.1447(3) 0.4941(3) 0.8693(3) 0.0661(11) Uani 1 1 d U . .
O3 O -0.0116(3) 0.4082(3) 0.6232(3) 0.0665(12) Uani 1 1 d . . .
O4 O 0.1885(3) 0.4053(3) 0.6991(3) 0.0700(12) Uani 1 1 d U . .
O5 O 0.0379(3) 0.3321(3) 0.8242(3) 0.0813(14) Uani 1 1 d . . .
V1 V 0.05933(8) 0.42078(7) 0.76648(8) 0.0617(4) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.270(7) . ?
C1 C2 1.396(8) . ?
C1 C10 1.512(9) . ?
C2 C3 1.385(8) . ?
C2 H2 0.9300 . ?
C3 O3 1.257(7) . ?
C3 C4 1.508(9) . ?
C4 C9 1.340(9) . ?
C4 C5 1.370(9) . ?
C5 C6 1.415(10) . ?
C5 H4 0.9300 . ?
C6 C7 1.409(11) . ?
C6 H6 0.9300 . ?
C7 C8 1.317(10) . ?
C7 H7 0.9300 . ?
C8 C9 1.342(9) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C10 C11 1.335(9) . ?
C10 C15 1.357(8) . ?
C11 C12 1.325(10) . ?
C11 H11 0.9300 . ?
C12 C13 1.362(11) . ?
C12 H12 0.9300 . ?
C13 C14 1.392(11) . ?
C13 H13 0.9300 . ?
C14 C15 1.406(10) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C16 O2 1.296(7) . ?
C16 C17 1.379(8) . ?
C16 C25 1.491(9) . ?
C17 C18 1.388(8) . ?
C17 H17 0.9300 . ?
C18 O4 1.297(7) . ?
C18 C19 1.478(9) . ?
C19 C20 1.359(9) . ?
C19 C24 1.371(8) . ?
C20 C21 1.383(11) . ?
C20 H20 0.9300 . ?
C21 C22 1.315(11) . ?
C21 H21 0.9300 . ?
C22 C23 1.335(10) . ?
C22 H22 0.9300 . ?
C23 C24 1.375(10) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.357(9) . ?
C25 C30 1.384(9) . ?
C26 C27 1.344(11) . ?
C26 H26 0.9300 . ?
C27 C28 1.344(12) . ?
C27 H27 0.9300 . ?
C28 C29 1.370(11) . ?
C28 H28 0.9300 . ?
C29 C30 1.393(10) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
O1 V1 1.956(4) . ?
O2 V1 1.960(4) . ?
O3 V1 1.969(4) . ?
O4 V1 1.961(4) . ?
O5 V1 1.579(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C1 C2 123.1(6) . . ?
O1 C1 C10 116.0(6) . . ?
C2 C1 C10 120.9(6) . . ?
C3 C2 C1 124.4(6) . . ?
C3 C2 H2 117.8 . . ?
C1 C2 H2 117.8 . . ?
O3 C3 C2 123.1(6) . . ?
O3 C3 C4 116.5(6) . . ?
C2 C3 C4 120.4(6) . . ?
C9 C4 C5 119.9(6) . . ?
C9 C4 C3 123.0(6) . . ?
C5 C4 C3 117.0(6) . . ?
C4 C5 C6 119.1(7) . . ?
C4 C5 H4 120.4 . . ?
C6 C5 H4 120.4 . . ?
C7 C6 C5 117.8(7) . . ?
C7 C6 H6 121.1 . . ?
C5 C6 H6 121.1 . . ?
C8 C7 C6 119.7(8) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 122.0(8) . . ?
C7 C8 H8 119.0 . . ?
C9 C8 H8 119.0 . . ?
C8 C9 C4 121.4(7) . . ?
C8 C9 H9 119.3 . . ?
C4 C9 H9 119.3 . . ?
C11 C10 C15 118.8(7) . . ?
C11 C10 C1 125.1(7) . . ?
C15 C10 C1 116.1(6) . . ?
C12 C11 C10 122.6(8) . . ?
C12 C11 H11 118.7 . . ?
C10 C11 H11 118.7 . . ?
C11 C12 C13 121.9(8) . . ?
C11 C12 H12 119.1 . . ?
C13 C12 H12 119.1 . . ?
C12 C13 C14 117.3(7) . . ?
C12 C13 H13 121.3 . . ?
C14 C13 H13 121.3 . . ?
C13 C14 C15 119.3(7) . . ?
C13 C14 H14 120.4 . . ?
C15 C14 H14 120.4 . . ?
C10 C15 C14 120.0(7) . . ?
C10 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
O2 C16 C17 123.8(6) . . ?
O2 C16 C25 116.4(6) . . ?
C17 C16 C25 119.7(6) . . ?
C16 C17 C18 124.1(6) . . ?
C16 C17 H17 117.9 . . ?
C18 C17 H17 117.9 . . ?
O4 C18 C17 122.5(6) . . ?
O4 C18 C19 116.0(6) . . ?
C17 C18 C19 121.5(5) . . ?
C20 C19 C24 118.7(7) . . ?
C20 C19 C18 123.3(7) . . ?
C24 C19 C18 118.0(6) . . ?
C19 C20 C21 119.1(8) . . ?
C19 C20 H20 120.5 . . ?
C21 C20 H20 120.5 . . ?
C22 C21 C20 121.5(9) . . ?
C22 C21 H21 119.2 . . ?
C20 C21 H21 119.2 . . ?
C21 C22 C23 120.5(8) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C22 C23 C24 120.0(8) . . ?
C22 C23 H23 120.0 . . ?
C24 C23 H23 120.0 . . ?
C19 C24 C23 120.3(7) . . ?
C19 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
C26 C25 C30 119.1(7) . . ?
C26 C25 C16 124.8(7) . . ?
C30 C25 C16 116.0(6) . . ?
C27 C26 C25 119.8(8) . . ?
C27 C26 H26 120.1 . . ?
C25 C26 H26 120.1 . . ?
C26 C27 C28 123.1(9) . . ?
C26 C27 H27 118.4 . . ?
C28 C27 H27 118.4 . . ?
C27 C28 C29 118.8(9) . . ?
C27 C28 H28 120.6 . . ?
C29 C28 H28 120.6 . . ?
C28 C29 C30 119.2(8) . . ?
C28 C29 H29 120.4 . . ?
C30 C29 H29 120.4 . . ?
C25 C30 C29 119.9(7) . . ?
C25 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C1 O1 V1 130.8(4) . . ?
C16 O2 V1 130.0(4) . . ?
C3 O3 V1 130.9(4) . . ?
C18 O4 V1 130.8(4) . . ?
O5 V1 O1 107.6(2) . . ?
O5 V1 O2 106.2(2) . . ?
O1 V1 O2 83.72(16) . . ?
O5 V1 O4 107.8(2) . . ?
O1 V1 O4 144.59(18) . . ?
O2 V1 O4 86.66(16) . . ?
O5 V1 O3 105.9(2) . . ?
O1 V1 O3 86.78(16) . . ?
O2 V1 O3 147.90(18) . . ?
O4 V1 O3 83.54(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C3 1.1(11) . . . . ?
C10 C1 C2 C3 -179.6(6) . . . . ?
C1 C2 C3 O3 -3.5(11) . . . . ?
C1 C2 C3 C4 176.7(6) . . . . ?
O3 C3 C4 C9 154.6(6) . . . . ?
C2 C3 C4 C9 -25.5(10) . . . . ?
O3 C3 C4 C5 -21.7(9) . . . . ?
C2 C3 C4 C5 158.2(6) . . . . ?
C9 C4 C5 C6 0.9(10) . . . . ?
C3 C4 C5 C6 177.4(6) . . . . ?
C4 C5 C6 C7 -2.4(10) . . . . ?
C5 C6 C7 C8 2.5(12) . . . . ?
C6 C7 C8 C9 -1.2(13) . . . . ?
C7 C8 C9 C4 -0.4(12) . . . . ?
C5 C4 C9 C8 0.5(11) . . . . ?
C3 C4 C9 C8 -175.7(7) . . . . ?
O1 C1 C10 C11 -170.9(7) . . . . ?
C2 C1 C10 C11 9.8(11) . . . . ?
O1 C1 C10 C15 6.8(9) . . . . ?
C2 C1 C10 C15 -172.6(6) . . . . ?
C15 C10 C11 C12 1.7(12) . . . . ?
C1 C10 C11 C12 179.3(7) . . . . ?
C10 C11 C12 C13 -4.6(14) . . . . ?
C11 C12 C13 C14 3.9(13) . . . . ?
C12 C13 C14 C15 -0.5(12) . . . . ?
C11 C10 C15 C14 1.7(11) . . . . ?
C1 C10 C15 C14 -176.1(6) . . . . ?
C13 C14 C15 C10 -2.2(11) . . . . ?
O2 C16 C17 C18 8.9(11) . . . . ?
C25 C16 C17 C18 -167.7(6) . . . . ?
C16 C17 C18 O4 -7.6(11) . . . . ?
C16 C17 C18 C19 170.3(7) . . . . ?
O4 C18 C19 C20 171.0(7) . . . . ?
C17 C18 C19 C20 -7.0(11) . . . . ?
O4 C18 C19 C24 -11.1(9) . . . . ?
C17 C18 C19 C24 170.9(6) . . . . ?
C24 C19 C20 C21 -0.3(13) . . . . ?
C18 C19 C20 C21 177.6(9) . . . . ?
C19 C20 C21 C22 -0.5(18) . . . . ?
C20 C21 C22 C23 0.6(18) . . . . ?
C21 C22 C23 C24 0.2(15) . . . . ?
C20 C19 C24 C23 1.1(11) . . . . ?
C18 C19 C24 C23 -176.9(7) . . . . ?
C22 C23 C24 C19 -1.0(13) . . . . ?
O2 C16 C25 C26 -165.0(7) . . . . ?
C17 C16 C25 C26 11.9(10) . . . . ?
O2 C16 C25 C30 12.4(9) . . . . ?
C17 C16 C25 C30 -170.8(6) . . . . ?
C30 C25 C26 C27 1.1(12) . . . . ?
C16 C25 C26 C27 178.4(8) . . . . ?
C25 C26 C27 C28 0.3(15) . . . . ?
C26 C27 C28 C29 -0.5(16) . . . . ?
C27 C28 C29 C30 -0.7(13) . . . . ?
C26 C25 C30 C29 -2.3(10) . . . . ?
C16 C25 C30 C29 -179.8(6) . . . . ?
C28 C29 C30 C25 2.1(11) . . . . ?
C2 C1 O1 V1 -5.6(10) . . . . ?
C10 C1 O1 V1 175.0(4) . . . . ?
C17 C16 O2 V1 4.3(10) . . . . ?
C25 C16 O2 V1 -179.0(4) . . . . ?
C2 C3 O3 V1 10.3(10) . . . . ?
C4 C3 O3 V1 -169.9(4) . . . . ?
C17 C18 O4 V1 -6.8(10) . . . . ?
C19 C18 O4 V1 175.2(4) . . . . ?
C1 O1 V1 O5 -97.5(6) . . . . ?
C1 O1 V1 O2 157.5(6) . . . . ?
C1 O1 V1 O4 82.3(6) . . . . ?
C1 O1 V1 O3 8.2(6) . . . . ?
C16 O2 V1 O5 95.4(6) . . . . ?
C16 O2 V1 O1 -158.1(5) . . . . ?
C16 O2 V1 O4 -12.2(5) . . . . ?
C16 O2 V1 O3 -84.5(6) . . . . ?
C18 O4 V1 O5 -92.3(6) . . . . ?
C18 O4 V1 O1 87.9(6) . . . . ?
C18 O4 V1 O2 13.6(6) . . . . ?
C18 O4 V1 O3 163.0(6) . . . . ?
C3 O3 V1 O5 96.7(6) . . . . ?
C3 O3 V1 O1 -10.6(6) . . . . ?
C3 O3 V1 O2 -83.4(6) . . . . ?
C3 O3 V1 O4 -156.5(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.19
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         0.547
_refine_diff_density_min         -0.247
_refine_diff_density_rms         0.064

