# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_added_by_encifer
_database_code_depnum_ccdc_archive 'CCDC 1057307'
_audit_update_record             
;
2016-02-04 deposited with the CCDC.
2016-02-22 downloaded from the CCDC.
;

# start Validation Reply Form
_vrf_PLAT029_mp21c               
;
PROBLEM: _diffrn_measured_fraction_theta_full Low .......      0.794 Note  
RESPONSE: The quality of the crystal was not optimal (very platy) 
and it was weakly diffracting. Although recrystallization and data 
collection for different crystals was attempted repeatedly, but this
 structure represents the best of the all. However, this will always
 be a problem with area detector data that is not truncated.
;

# end Validation Reply Form

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H22 F6 N4 O2 P Rh'
_chemical_formula_weight         754.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/c  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.299(4)
_cell_length_b                   13.785(3)
_cell_length_c                   27.191(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 101.13(3)
_cell_angle_gamma                90.00
_cell_volume                     6362(2)
_cell_formula_units_Z            8
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    42999
_cell_measurement_theta_min      5.2
_cell_measurement_theta_max      59.0

_exptl_crystal_description       irregular
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.575
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3024
_exptl_absorpt_coefficient_mu    0.660
_exptl_absorpt_correction_type   Numerical
_exptl_absorpt_correction_T_min  0.6575
_exptl_absorpt_correction_T_max  0.9633
_exptl_absorpt_process_details   '(X-SHAPE and X-RED; Stoe & Cie, 2005)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Stoe IPDS-II'
_diffrn_measurement_method       'rotation method'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            8901
_diffrn_reflns_av_R_equivalents  0.0912
_diffrn_reflns_av_sigmaI/netI    0.0875
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         2.73
_diffrn_reflns_theta_max         25.00
_reflns_number_total             8901
_reflns_number_gt                4973
_reflns_threshold_expression     >2σ(I)

_computing_data_collection       'X-AREA (Stoe & Cie, 2005)'
_computing_cell_refinement       'X-AREA (Stoe & Cie, 2005)'
_computing_data_reduction        'X-AREA (Stoe & Cie, 2005)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2σ(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1158P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8901
_refine_ls_number_parameters     892
_refine_ls_number_restraints     15
_refine_ls_R_factor_all          0.1206
_refine_ls_R_factor_gt           0.0732
_refine_ls_wR_factor_ref         0.2023
_refine_ls_wR_factor_gt          0.1852
_refine_ls_goodness_of_fit_ref   0.967
_refine_ls_restrained_S_all      0.967
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
F7 F 0.275(2) 0.1353(15) 0.0491(17) 0.21(3) Uani 0.56(4) 1 d PD A 1
F8 F 0.265(2) 0.2213(19) 0.1215(9) 0.158(15) Uani 0.56(4) 1 d PD A 1
F11 F 0.1435(13) 0.1522(19) 0.0275(7) 0.153(15) Uani 0.56(4) 1 d PD A 1
F12 F 0.1410(11) 0.2245(18) 0.0984(7) 0.104(9) Uani 0.56(4) 1 d PD A 1
F7' F 0.2971(13) 0.174(3) 0.0914(14) 0.131(15) Uani 0.44(4) 1 d P A 2
F8' F 0.204(4) 0.243(3) 0.1213(14) 0.25(3) Uani 0.44(4) 1 d PD A 2
F11' F 0.219(2) 0.110(3) 0.0302(9) 0.158(19) Uani 0.44(4) 1 d PD A 2
F12' F 0.1160(4) 0.175(3) 0.059(2) 0.19(3) Uani 0.44(4) 1 d PD A 2
C1 C 0.5478(7) 0.6519(9) 0.0650(6) 0.081(4) Uani 1 1 d . . .
H1 H 0.5182 0.5980 0.0703 0.097 Uiso 1 1 calc R . .
C2 C 0.5764(7) 0.6573(12) 0.0199(7) 0.099(5) Uani 1 1 d . . .
H2 H 0.5674 0.6086 -0.0042 0.119 Uiso 1 1 calc R . .
C3 C 0.6177(7) 0.7382(12) 0.0142(6) 0.095(5) Uani 1 1 d . . .
H3 H 0.6356 0.7471 -0.0156 0.114 Uiso 1 1 calc R . .
C4 C 0.6342(8) 0.8076(10) 0.0507(7) 0.098(5) Uani 1 1 d . . .
H4 H 0.6661 0.8601 0.0465 0.118 Uiso 1 1 calc R . .
C5 C 0.6035(5) 0.7997(8) 0.0935(5) 0.061(3) Uani 1 1 d . . .
C6 C 0.6124(6) 0.8673(8) 0.1357(5) 0.070(4) Uani 1 1 d . . .
C7 C 0.6528(7) 0.9558(9) 0.1350(6) 0.086(4) Uani 1 1 d . . .
H7 H 0.6739 0.9749 0.1076 0.103 Uiso 1 1 calc R . .
C8 C 0.6593(9) 1.0132(10) 0.1776(8) 0.113(6) Uani 1 1 d . . .
H8 H 0.6862 1.0718 0.1783 0.136 Uiso 1 1 calc R . .
C9 C 0.6292(7) 0.9891(8) 0.2179(7) 0.096(5) Uani 1 1 d . . .
H9 H 0.6345 1.0307 0.2453 0.116 Uiso 1 1 calc R . .
C10 C 0.5901(6) 0.9018(8) 0.2180(5) 0.077(4) Uani 1 1 d . . .
H10 H 0.5705 0.8839 0.2463 0.092 Uiso 1 1 calc R . .
C11 C 0.5792(6) 0.8385(7) 0.1759(5) 0.060(3) Uani 1 1 d . . .
C12 C 0.4285(6) 0.7788(8) 0.2439(6) 0.074(3) Uani 1 1 d . . .
H12 H 0.3953 0.8106 0.2179 0.088 Uiso 1 1 calc R . .
C13 C 0.4147(7) 0.7875(9) 0.2927(7) 0.086(4) Uani 1 1 d . . .
H13 H 0.3737 0.8259 0.2992 0.103 Uiso 1 1 calc R . .
C14 C 0.4635(8) 0.7373(10) 0.3315(6) 0.082(4) Uani 1 1 d . . .
H14 H 0.4544 0.7388 0.3641 0.099 Uiso 1 1 calc R . .
C15 C 0.5270(8) 0.6845(8) 0.3193(6) 0.079(4) Uani 1 1 d . . .
H15 H 0.5622 0.6536 0.3446 0.095 Uiso 1 1 calc R . .
C16 C 0.5381(6) 0.6776(7) 0.2705(5) 0.064(3) Uani 1 1 d . . .
C17 C 0.5999(6) 0.6268(6) 0.2544(5) 0.060(3) Uani 1 1 d . . .
C18 C 0.6562(7) 0.5697(9) 0.2857(5) 0.082(4) Uani 1 1 d . . .
H18 H 0.6536 0.5632 0.3194 0.099 Uiso 1 1 calc R . .
C19 C 0.7145(7) 0.5234(8) 0.2675(7) 0.087(4) Uani 1 1 d . . .
H19 H 0.7527 0.4879 0.2888 0.105 Uiso 1 1 calc R . .
C20 C 0.7157(7) 0.5302(8) 0.2163(6) 0.078(4) Uani 1 1 d . . .
H20 H 0.7547 0.4977 0.2036 0.094 Uiso 1 1 calc R . .
C21 C 0.6599(6) 0.5847(7) 0.1842(5) 0.070(3) Uani 1 1 d . . .
H21 H 0.6602 0.5869 0.1501 0.084 Uiso 1 1 calc R . .
C22 C 0.6027(5) 0.6364(7) 0.2040(5) 0.054(3) Uani 1 1 d . . .
C23 C 0.3938(7) 0.8880(7) 0.1100(4) 0.070(3) Uani 1 1 d . . .
H23 H 0.4297 0.9377 0.1203 0.084 Uiso 1 1 calc R . .
C24 C 0.3194(8) 0.9089(8) 0.0809(5) 0.090(4) Uani 1 1 d . . .
H24 H 0.3079 0.9733 0.0723 0.108 Uiso 1 1 calc R . .
C25 C 0.2639(7) 0.8422(8) 0.0646(5) 0.090(4) Uani 1 1 d . . .
H25 H 0.2147 0.8592 0.0462 0.107 Uiso 1 1 calc R . .
C26 C 0.2840(6) 0.7463(7) 0.0767(4) 0.063(3) Uani 1 1 d . . .
C27 C 0.2415(7) 0.6499(8) 0.0680(5) 0.070(3) Uani 1 1 d . . .
C28 C 0.3004(6) 0.5755(7) 0.0948(4) 0.059(3) Uani 1 1 d . . .
C29 C 0.3040(7) 0.4772(8) 0.0994(5) 0.069(3) Uani 1 1 d . . .
H29 H 0.2625 0.4383 0.0838 0.083 Uiso 1 1 calc R . .
C30 C 0.3710(7) 0.4371(8) 0.1277(5) 0.082(4) Uani 1 1 d . . .
H30 H 0.3732 0.3707 0.1339 0.098 Uiso 1 1 calc R . .
C31 C 0.4359(6) 0.4959(7) 0.1473(4) 0.066(3) Uani 1 1 d . . .
H31 H 0.4816 0.4662 0.1644 0.079 Uiso 1 1 calc R . .
C32 C 0.3684(5) 0.6271(6) 0.1170(4) 0.049(2) Uani 1 1 d . . .
C33 C 0.3568(5) 0.7293(6) 0.1060(4) 0.054(3) Uani 1 1 d . . .
C34 C 0.1562(6) 0.3492(7) 0.2023(5) 0.076(4) Uani 1 1 d . . .
H34 H 0.1541 0.3460 0.1679 0.091 Uiso 1 1 calc R . .
C35 C 0.2117(6) 0.2945(7) 0.2346(6) 0.086(5) Uani 1 1 d . . .
H35 H 0.2471 0.2553 0.2220 0.104 Uiso 1 1 calc R . .
C36 C 0.2138(6) 0.2988(8) 0.2860(6) 0.077(4) Uani 1 1 d . . .
H36 H 0.2489 0.2611 0.3083 0.092 Uiso 1 1 calc R . .
C37 C 0.1637(6) 0.3588(8) 0.3023(5) 0.079(4) Uani 1 1 d . . .
H37 H 0.1664 0.3643 0.3367 0.094 Uiso 1 1 calc R . .
C38 C 0.1077(5) 0.4135(6) 0.2704(5) 0.056(3) Uani 1 1 d . . .
C39 C 0.0490(5) 0.4801(6) 0.2850(5) 0.053(3) Uani 1 1 d . . .
C40 C 0.0373(7) 0.4930(7) 0.3335(5) 0.073(4) Uani 1 1 d . . .
H40 H 0.0701 0.4613 0.3597 0.088 Uiso 1 1 calc R . .
C41 C -0.0199(7) 0.5499(7) 0.3433(5) 0.071(3) Uani 1 1 d . . .
H41 H -0.0289 0.5539 0.3759 0.085 Uiso 1 1 calc R . .
C42 C -0.0662(7) 0.6034(8) 0.3056(6) 0.073(3) Uani 1 1 d . . .
H42 H -0.1047 0.6452 0.3129 0.087 Uiso 1 1 calc R . .
C43 C -0.0543(6) 0.5935(7) 0.2568(5) 0.068(3) Uani 1 1 d . . .
H43 H -0.0853 0.6291 0.2313 0.082 Uiso 1 1 calc R . .
C44 C 0.0034(5) 0.5311(6) 0.2452(4) 0.050(2) Uani 1 1 d . . .
C45 C -0.1376(6) 0.5663(8) 0.1205(4) 0.069(3) Uani 1 1 d . . .
H45 H -0.1587 0.5076 0.1284 0.083 Uiso 1 1 calc R . .
C46 C -0.1850(7) 0.6324(9) 0.0907(5) 0.078(4) Uani 1 1 d . . .
H46 H -0.2371 0.6169 0.0770 0.094 Uiso 1 1 calc R . .
C47 C -0.1555(9) 0.7195(9) 0.0814(5) 0.087(4) Uani 1 1 d . . .
H47 H -0.1878 0.7660 0.0631 0.105 Uiso 1 1 calc R . .
C48 C -0.0763(8) 0.7392(7) 0.0996(5) 0.077(4) Uani 1 1 d . . .
H48 H -0.0551 0.7978 0.0916 0.092 Uiso 1 1 calc R . .
C49 C -0.0285(7) 0.6729(7) 0.1293(4) 0.065(3) Uani 1 1 d . . .
C50 C 0.0541(6) 0.6849(7) 0.1522(4) 0.059(3) Uani 1 1 d . . .
C51 C 0.0964(9) 0.7692(8) 0.1485(6) 0.098(5) Uani 1 1 d . . .
H51 H 0.0714 0.8240 0.1329 0.118 Uiso 1 1 calc R . .
C52 C 0.1773(9) 0.7707(10) 0.1687(6) 0.094(5) Uani 1 1 d . . .
H52 H 0.2061 0.8272 0.1670 0.113 Uiso 1 1 calc R . .
C53 C 0.2131(9) 0.6923(11) 0.1901(6) 0.099(5) Uani 1 1 d . . .
H53 H 0.2672 0.6937 0.2022 0.119 Uiso 1 1 calc R . .
C54 C 0.1707(6) 0.6071(8) 0.1949(5) 0.071(3) Uani 1 1 d . . .
H54 H 0.1968 0.5540 0.2116 0.085 Uiso 1 1 calc R . .
C55 C 0.0909(5) 0.6007(7) 0.1753(4) 0.055(3) Uani 1 1 d . . .
C56 C 0.0626(6) 0.4463(7) 0.0644(5) 0.065(3) Uani 1 1 d . . .
H56 H 0.0984 0.4973 0.0677 0.077 Uiso 1 1 calc R . .
C57 C 0.0494(7) 0.3942(8) 0.0189(5) 0.073(3) Uani 1 1 d . . .
H57 H 0.0753 0.4112 -0.0068 0.087 Uiso 1 1 calc R . .
C58 C -0.0032(7) 0.3167(9) 0.0135(5) 0.076(4) Uani 1 1 d . . .
H58 H -0.0140 0.2811 -0.0161 0.091 Uiso 1 1 calc R . .
C59 C -0.0388(6) 0.2942(7) 0.0532(5) 0.062(3) Uani 1 1 d . . .
C60 C -0.0951(7) 0.2193(8) 0.0651(6) 0.084(4) Uani 1 1 d . . .
C61 C -0.1097(6) 0.2410(8) 0.1167(5) 0.067(3) Uani 1 1 d . . .
C62 C -0.1540(7) 0.2000(8) 0.1474(6) 0.085(4) Uani 1 1 d . . .
H62 H -0.1849 0.1455 0.1377 0.102 Uiso 1 1 calc R . .
C63 C -0.1510(7) 0.2426(10) 0.1932(6) 0.086(4) Uani 1 1 d . . .
H63 H -0.1797 0.2165 0.2157 0.104 Uiso 1 1 calc R . .
C64 C -0.1050(7) 0.3253(8) 0.2062(5) 0.073(3) Uani 1 1 d . . .
H64 H -0.1043 0.3532 0.2375 0.088 Uiso 1 1 calc R . .
C65 C -0.0665(5) 0.3212(7) 0.1342(5) 0.052(3) Uani 1 1 d . . .
C66 C -0.0225(5) 0.3520(6) 0.0957(4) 0.052(3) Uani 1 1 d . . .
N1 N 0.5611(4) 0.7198(6) 0.1003(3) 0.055(2) Uani 1 1 d . . .
N2 N 0.4884(5) 0.7259(5) 0.2336(3) 0.060(2) Uani 1 1 d . . .
N3 N 0.4125(4) 0.7958(5) 0.1227(3) 0.053(2) Uani 1 1 d . . .
N4 N 0.4351(4) 0.5913(5) 0.1426(3) 0.048(2) Uani 1 1 d . . .
N5 N 0.1056(4) 0.4069(5) 0.2206(4) 0.055(2) Uani 1 1 d . . .
N6 N -0.0604(5) 0.5864(5) 0.1384(3) 0.057(2) Uani 1 1 d . . .
N7 N 0.0272(5) 0.4276(5) 0.1034(3) 0.053(2) Uani 1 1 d . . .
N8 N -0.0622(5) 0.3660(6) 0.1763(3) 0.053(2) Uani 1 1 d . . .
O1 O 0.1764(4) 0.6337(6) 0.0464(4) 0.093(3) Uani 1 1 d . . .
O2 O -0.1204(6) 0.1507(6) 0.0372(4) 0.106(3) Uani 1 1 d . . .
O3 O -0.0119(17) 0.4592(16) 0.4720(8) 0.156(11) Uani 0.50 1 d P . .
O4 O 0.8008(17) 0.9729(15) 0.0551(9) 0.158(11) Uani 0.50 1 d P . .
O5' O 0.422(2) 0.604(2) 0.4796(14) 0.212(13) Uiso 0.50 1 d P . .
O5 O 0.5016(13) 0.5809(15) 0.4420(9) 0.131(7) Uiso 0.50 1 d P . .
F1 F 0.3739(7) 0.6500(14) -0.0053(3) 0.232(7) Uani 1 1 d D . .
F2 F 0.4132(5) 0.6096(13) -0.0769(5) 0.230(7) Uani 1 1 d D . .
F3 F 0.3347(8) 0.7289(8) -0.0914(7) 0.261(9) Uani 1 1 d D . .
F4 F 0.3203(13) 0.5272(8) -0.0420(9) 0.345(14) Uani 1 1 d D . .
F5 F 0.2573(6) 0.6776(13) -0.0458(5) 0.263(9) Uani 1 1 d D . .
F6 F 0.2816(8) 0.5956(14) -0.1118(4) 0.251(8) Uani 1 1 d D . .
F9 F 0.2140(5) 0.2747(5) 0.0446(4) 0.134(4) Uani 1 1 d D A .
F10 F 0.2057(5) 0.0825(5) 0.1050(4) 0.154(5) Uani 1 1 d D A .
P1 P 0.3325(3) 0.6324(4) -0.06112(19) 0.1203(16) Uani 1 1 d D . .
P2 P 0.2082(2) 0.1785(2) 0.07450(14) 0.0818(11) Uani 1 1 d D . .
Rh1 Rh 0.51739(4) 0.71776(5) 0.16458(3) 0.0529(3) Uani 1 1 d . . .
Rh2 Rh 0.01961(4) 0.49059(5) 0.17795(3) 0.0487(2) Uani 1 1 d . . .


_geom_special_details            
;
 All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell s.u.'s are taken
 into account individually in the estimation of s.u.'s in distances, angles
 and torsion angles; correlations between s.u.'s in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F7 P2 1.570(2) . ?
F8 P2 1.570(2) . ?
F11 P2 1.570(2) . ?
F12 P2 1.570(2) . ?
F7' P2 1.52(2) . ?
F8' P2 1.570(2) . ?
F11' P2 1.570(2) . ?
F12' P2 1.570(2) . ?
C1 N1 1.329(16) . ?
C1 C2 1.409(19) . ?
C2 C3 1.350(18) . ?
C3 C4 1.37(2) . ?
C4 C5 1.374(19) . ?
C5 N1 1.355(12) . ?
C5 C6 1.463(17) . ?
C6 C11 1.386(16) . ?
C6 C7 1.409(15) . ?
C7 C8 1.39(2) . ?
C8 C9 1.34(2) . ?
C9 C10 1.382(15) . ?
C10 C11 1.424(16) . ?
C11 Rh1 1.970(10) . ?
C12 N2 1.339(14) . ?
C12 C13 1.398(18) . ?
C13 C14 1.400(18) . ?
C14 C15 1.411(17) . ?
C15 C16 1.378(16) . ?
C16 N2 1.363(13) . ?
C16 C17 1.415(16) . ?
C17 C22 1.388(14) . ?
C17 C18 1.403(15) . ?
C18 C19 1.364(18) . ?
C19 C20 1.399(18) . ?
C20 C21 1.392(15) . ?
C21 C22 1.408(15) . ?
C22 Rh1 1.993(10) . ?
C23 N3 1.342(11) . ?
C23 C24 1.403(15) . ?
C24 C25 1.341(16) . ?
C25 C26 1.390(14) . ?
C26 C33 1.375(13) . ?
C26 C27 1.515(14) . ?
C27 O1 1.186(12) . ?
C27 C28 1.527(14) . ?
C28 C29 1.362(13) . ?
C28 C32 1.408(12) . ?
C29 C30 1.377(15) . ?
C30 C31 1.404(15) . ?
C31 N4 1.321(11) . ?
C32 N4 1.323(11) . ?
C32 C33 1.446(12) . ?
C33 N3 1.344(11) . ?
C34 N5 1.347(12) . ?
C34 C35 1.391(16) . ?
C35 C36 1.392(17) . ?
C36 C37 1.333(16) . ?
C37 C38 1.392(14) . ?
C38 N5 1.351(13) . ?
C38 C39 1.480(13) . ?
C39 C40 1.383(15) . ?
C39 C44 1.399(14) . ?
C40 C41 1.329(15) . ?
C41 C42 1.386(16) . ?
C42 C43 1.389(15) . ?
C43 C44 1.399(13) . ?
C44 Rh2 1.984(10) . ?
C45 N6 1.360(13) . ?
C45 C46 1.379(15) . ?
C46 C47 1.347(16) . ?
C47 C48 1.392(17) . ?
C48 C49 1.383(15) . ?
C49 N6 1.357(12) . ?
C49 C50 1.453(15) . ?
C50 C51 1.388(14) . ?
C50 C55 1.412(14) . ?
C51 C52 1.401(19) . ?
C52 C53 1.324(19) . ?
C53 C54 1.404(15) . ?
C54 C55 1.384(13) . ?
C55 Rh2 1.965(9) . ?
C56 N7 1.346(13) . ?
C56 C57 1.410(16) . ?
C57 C58 1.394(16) . ?
C58 C59 1.376(16) . ?
C59 C66 1.387(14) . ?
C59 C60 1.497(17) . ?
C60 O2 1.239(13) . ?
C60 C61 1.503(18) . ?
C61 C62 1.362(18) . ?
C61 C65 1.366(14) . ?
C62 C63 1.369(18) . ?
C63 C64 1.396(16) . ?
C64 N8 1.327(13) . ?
C65 N8 1.290(13) . ?
C65 C66 1.470(15) . ?
C66 N7 1.343(11) . ?
N1 Rh1 2.035(9) . ?
N2 Rh1 2.037(9) . ?
N3 Rh1 2.224(7) . ?
N4 Rh1 2.257(7) . ?
N5 Rh2 2.054(8) . ?
N6 Rh2 2.059(8) . ?
N7 Rh2 2.233(9) . ?
N8 Rh2 2.220(8) . ?
F1 P1 1.567(2) . ?
F2 P1 1.569(2) . ?
F3 P1 1.569(2) . ?
F4 P1 1.568(2) . ?
F5 P1 1.569(2) . ?
F6 P1 1.568(2) . ?
F9 P2 1.569(2) . ?
F10 P2 1.568(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 123.4(13) . . ?
C3 C2 C1 115.2(15) . . ?
C2 C3 C4 122.3(17) . . ?
C3 C4 C5 119.9(14) . . ?
N1 C5 C4 119.2(12) . . ?
N1 C5 C6 112.9(11) . . ?
C4 C5 C6 127.9(12) . . ?
C11 C6 C7 122.7(12) . . ?
C11 C6 C5 116.0(10) . . ?
C7 C6 C5 121.3(13) . . ?
C8 C7 C6 116.3(14) . . ?
C9 C8 C7 123.9(14) . . ?
C8 C9 C10 119.1(15) . . ?
C9 C10 C11 121.3(14) . . ?
C6 C11 C10 116.7(11) . . ?
C6 C11 Rh1 114.5(9) . . ?
C10 C11 Rh1 128.8(10) . . ?
N2 C12 C13 121.7(12) . . ?
C12 C13 C14 118.9(12) . . ?
C13 C14 C15 117.5(14) . . ?
C16 C15 C14 121.4(14) . . ?
N2 C16 C15 119.3(11) . . ?
N2 C16 C17 114.9(12) . . ?
C15 C16 C17 125.8(11) . . ?
C22 C17 C18 119.9(11) . . ?
C22 C17 C16 115.5(10) . . ?
C18 C17 C16 124.6(13) . . ?
C19 C18 C17 121.2(14) . . ?
C18 C19 C20 118.9(12) . . ?
C21 C20 C19 121.2(12) . . ?
C20 C21 C22 119.2(12) . . ?
C17 C22 C21 119.4(10) . . ?
C17 C22 Rh1 115.0(7) . . ?
C21 C22 Rh1 125.5(9) . . ?
N3 C23 C24 119.3(10) . . ?
C25 C24 C23 124.4(10) . . ?
C24 C25 C26 116.3(10) . . ?
C33 C26 C25 117.3(9) . . ?
C33 C26 C27 107.7(8) . . ?
C25 C26 C27 134.9(10) . . ?
O1 C27 C26 128.9(11) . . ?
O1 C27 C28 126.3(10) . . ?
C26 C27 C28 104.8(8) . . ?
C29 C28 C32 116.3(9) . . ?
C29 C28 C27 136.6(9) . . ?
C32 C28 C27 106.9(8) . . ?
C28 C29 C30 118.0(10) . . ?
C29 C30 C31 120.4(10) . . ?
N4 C31 C30 123.0(10) . . ?
N4 C32 C28 127.6(8) . . ?
N4 C32 C33 123.0(8) . . ?
C28 C32 C33 109.4(8) . . ?
N3 C33 C26 126.7(9) . . ?
N3 C33 C32 122.1(8) . . ?
C26 C33 C32 111.2(8) . . ?
N5 C34 C35 120.5(13) . . ?
C34 C35 C36 119.4(11) . . ?
C37 C36 C35 117.9(11) . . ?
C36 C37 C38 123.2(14) . . ?
N5 C38 C37 118.0(10) . . ?
N5 C38 C39 115.1(9) . . ?
C37 C38 C39 126.9(12) . . ?
C40 C39 C44 120.6(9) . . ?
C40 C39 C38 124.8(10) . . ?
C44 C39 C38 114.7(10) . . ?
C41 C40 C39 121.3(11) . . ?
C40 C41 C42 120.8(12) . . ?
C41 C42 C43 118.9(10) . . ?
C42 C43 C44 121.2(10) . . ?
C43 C44 C39 117.1(10) . . ?
C43 C44 Rh2 127.9(8) . . ?
C39 C44 Rh2 114.4(7) . . ?
N6 C45 C46 120.5(11) . . ?
C47 C46 C45 119.6(12) . . ?
C46 C47 C48 119.3(11) . . ?
C49 C48 C47 121.1(11) . . ?
N6 C49 C48 117.9(11) . . ?
N6 C49 C50 115.0(9) . . ?
C48 C49 C50 127.1(10) . . ?
C51 C50 C55 121.5(11) . . ?
C51 C50 C49 123.6(11) . . ?
C55 C50 C49 114.8(8) . . ?
C50 C51 C52 119.0(13) . . ?
C53 C52 C51 120.5(12) . . ?
C52 C53 C54 121.0(13) . . ?
C55 C54 C53 121.2(12) . . ?
C54 C55 C50 116.7(9) . . ?
C54 C55 Rh2 128.5(8) . . ?
C50 C55 Rh2 114.8(7) . . ?
N7 C56 C57 124.9(11) . . ?
C58 C57 C56 118.4(12) . . ?
C59 C58 C57 118.1(11) . . ?
C58 C59 C66 118.4(11) . . ?
C58 C59 C60 137.1(12) . . ?
C66 C59 C60 104.6(12) . . ?
O2 C60 C59 124.2(15) . . ?
O2 C60 C61 128.4(13) . . ?
C59 C60 C61 107.3(9) . . ?
C62 C61 C65 117.2(13) . . ?
C62 C61 C60 134.9(12) . . ?
C65 C61 C60 107.8(11) . . ?
C61 C62 C63 116.9(12) . . ?
C62 C63 C64 120.1(12) . . ?
N8 C64 C63 123.2(12) . . ?
N8 C65 C61 129.0(11) . . ?
N8 C65 C66 123.0(9) . . ?
C61 C65 C66 108.0(11) . . ?
N7 C66 C59 126.6(11) . . ?
N7 C66 C65 121.2(9) . . ?
C59 C66 C65 112.2(10) . . ?
C1 N1 C5 119.8(12) . . ?
C1 N1 Rh1 124.8(9) . . ?
C5 N1 Rh1 115.4(8) . . ?
C12 N2 C16 121.1(11) . . ?
C12 N2 Rh1 124.1(9) . . ?
C16 N2 Rh1 114.8(8) . . ?
C23 N3 C33 115.9(8) . . ?
C23 N3 Rh1 136.3(7) . . ?
C33 N3 Rh1 107.7(6) . . ?
C31 N4 C32 114.4(8) . . ?
C31 N4 Rh1 138.6(7) . . ?
C32 N4 Rh1 107.0(5) . . ?
C34 N5 C38 121.0(9) . . ?
C34 N5 Rh2 125.1(9) . . ?
C38 N5 Rh2 113.9(6) . . ?
C49 N6 C45 121.3(9) . . ?
C49 N6 Rh2 113.8(7) . . ?
C45 N6 Rh2 124.8(7) . . ?
C66 N7 C56 113.6(9) . . ?
C66 N7 Rh2 107.2(7) . . ?
C56 N7 Rh2 139.1(7) . . ?
C65 N8 C64 113.5(10) . . ?
C65 N8 Rh2 108.4(7) . . ?
C64 N8 Rh2 138.1(8) . . ?
F2 P1 F1 91.7(8) . . ?
F2 P1 F6 94.2(8) . . ?
F1 P1 F6 167.1(11) . . ?
F2 P1 F4 95.1(11) . . ?
F1 P1 F4 83.6(11) . . ?
F6 P1 F4 84.5(11) . . ?
F2 P1 F3 85.0(8) . . ?
F1 P1 F3 108.9(11) . . ?
F6 P1 F3 83.1(10) . . ?
F4 P1 F3 167.5(12) . . ?
F2 P1 F5 168.1(11) . . ?
F1 P1 F5 85.9(7) . . ?
F6 P1 F5 90.5(9) . . ?
F4 P1 F5 96.2(12) . . ?
F3 P1 F5 84.7(8) . . ?
F7' P2 F9 91.6(14) . . ?
F7' P2 F8 47.8(12) . . ?
F9 P2 F8 90.6(12) . . ?
F7' P2 F10 86.4(14) . . ?
F9 P2 F10 177.9(6) . . ?
F8 P2 F10 87.9(12) . . ?
F7' P2 F11' 87.0(18) . . ?
F9 P2 F11' 94.7(16) . . ?
F8 P2 F11' 134.7(17) . . ?
F10 P2 F11' 85.3(16) . . ?
F7' P2 F12 132.6(18) . . ?
F9 P2 F12 90.0(9) . . ?
F8 P2 F12 84.8(15) . . ?
F10 P2 F12 91.4(9) . . ?
F11' P2 F12 140.0(16) . . ?
F7' P2 F12' 175.2(18) . . ?
F9 P2 F12' 93.3(12) . . ?
F8 P2 F12' 132(3) . . ?
F10 P2 F12' 88.8(12) . . ?
F11' P2 F12' 92(3) . . ?
F12 P2 F12' 48(2) . . ?
F7' P2 F8' 89(2) . . ?
F9 P2 F8' 87(2) . . ?
F10 P2 F8' 92(2) . . ?
F11' P2 F8' 175(3) . . ?
F12' P2 F8' 92(2) . . ?
F7' P2 F7 48.1(15) . . ?
F9 P2 F7 88.1(8) . . ?
F8 P2 F7 95.8(18) . . ?
F10 P2 F7 90.6(9) . . ?
F12 P2 F7 178.0(14) . . ?
F12' P2 F7 132(3) . . ?
F8' P2 F7 136(2) . . ?
F7' P2 F11 139.3(18) . . ?
F9 P2 F11 83.2(11) . . ?
F8 P2 F11 170.4(15) . . ?
F10 P2 F11 98.5(12) . . ?
F11' P2 F11 53.6(13) . . ?
F12 P2 F11 87.8(11) . . ?
F8' P2 F11 131(2) . . ?
F7 P2 F11 91(2) . . ?
C11 Rh1 C22 93.9(4) . . ?
C11 Rh1 N1 80.9(5) . . ?
C22 Rh1 N1 96.3(4) . . ?
C11 Rh1 N2 91.9(4) . . ?
C22 Rh1 N2 79.9(4) . . ?
N1 Rh1 N2 171.6(3) . . ?
C11 Rh1 N3 92.1(3) . . ?
C22 Rh1 N3 173.4(3) . . ?
N1 Rh1 N3 87.5(3) . . ?
N2 Rh1 N3 97.1(3) . . ?
C11 Rh1 N4 171.7(4) . . ?
C22 Rh1 N4 94.1(3) . . ?
N1 Rh1 N4 95.9(3) . . ?
N2 Rh1 N4 91.8(3) . . ?
N3 Rh1 N4 80.1(3) . . ?
C55 Rh2 C44 91.0(4) . . ?
C55 Rh2 N5 93.6(4) . . ?
C44 Rh2 N5 81.6(4) . . ?
C55 Rh2 N6 81.3(4) . . ?
C44 Rh2 N6 95.8(4) . . ?
N5 Rh2 N6 174.3(3) . . ?
C55 Rh2 N8 176.8(4) . . ?
C44 Rh2 N8 91.9(4) . . ?
N5 Rh2 N8 88.1(3) . . ?
N6 Rh2 N8 97.1(3) . . ?
C55 Rh2 N7 96.9(4) . . ?
C44 Rh2 N7 172.1(3) . . ?
N5 Rh2 N7 97.5(3) . . ?
N6 Rh2 N7 85.8(3) . . ?
N8 Rh2 N7 80.2(3) . . ?

_diffrn_measured_fraction_theta_max 0.794
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.794
_refine_diff_density_max         1.291
_refine_diff_density_min         -1.171
_refine_diff_density_rms         0.090

