# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
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# Crystallographic Data Centre (CCDC).
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# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
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data_cg_bc_a183_0m
_database_code_depnum_ccdc_archive 'CCDC 1445337'
_audit_update_record             
;
2016-01-05 deposited with the CCDC.
2016-02-24 downloaded from the CCDC.
;
_audit_creation_date             2016-01-03
_audit_creation_method           
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C34 H37 N O2 P2 Ru), 2(C6 H6)'
_chemical_formula_sum            'C80 H86 N2 O4 P4 Ru2'
_chemical_formula_weight         1465.52
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x+, y+, z+'
'-x+, y+1/2, -z+1/2'
'-x+, -y+, -z+'
'x+, -y-1/2, z-1/2'

_cell_length_a                   13.3813(7)
_cell_length_b                   13.5583(7)
_cell_length_c                   20.6709(11)
_cell_angle_alpha                90
_cell_angle_beta                 104.397(3)
_cell_angle_gamma                90
_cell_volume                     3632.5(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9935
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      29.50
_cell_measurement_theta_min      3.14
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.554
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_correction_T_min  0.6087
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0939 before and 0.0546 after correction.
The Ratio of minimum to maximum transmission is 0.8161.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.340
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.09
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0457
_diffrn_reflns_av_unetI/netI     0.0317
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            58279
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.587
_diffrn_reflns_theta_min         3.234
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8839
_reflns_number_total             10160
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         4.231
_refine_diff_density_min         -0.935
_refine_diff_density_rms         0.126
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     420
_refine_ls_number_reflns         10160
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0585
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0814P)²+10.3227P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1572
_refine_ls_wR_factor_ref         0.1642
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C32) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C34)
\\sim Ueq, Uanis(C33) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.002
Uanis(C32) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.002
Uanis(C39) \\sim Ueq, Uanis(C40) \\sim Ueq, Uanis(C35) \\sim Ueq: with sigma of
0.007 and sigma for terminal atoms of 0.002
3.a Ternary CH refined with riding coordinates:
 N1(H1), C32(H32)
3.b Secondary CH2 refined with riding coordinates:
 C16(H16A,H16B), C17(H17A,H17B), C15(H15A,H15B), C14(H14A,H14B), C33(H33A,H33B)
3.c Aromatic/amide H refined with riding coordinates:
 C23(H23), C29(H29), C3(H3), C28(H28), C19(H19), C21(H21), C4(H4), C25(H25),
 C5(H5), C7(H7), C20(H20), C22(H22), C6(H6), C26(H26), C27(H27), C11(H11),
 C9(H9), C10(H10), C13(H13), C12(H12), C37(H37), C38(H38), C36(H36), C39(H39),
 C40(H40), C35(H35)
3.d Idealised Me refined as rotating group:
 C34(H34A,H34B,H34C)
3.e Idealised tetrahedral OH refined as rotating group:
 O2(H2)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.42861(2) 0.20139(2) 0.56721(2) 0.02052(9) Uani 1 1 d . . . . .
P2 P 0.59300(6) 0.19644(5) 0.63607(4) 0.02182(16) Uani 1 1 d . . . . .
P1 P 0.28730(7) 0.18858(6) 0.47723(4) 0.02604(17) Uani 1 1 d . . . . .
N1 N 0.5115(2) 0.19703(18) 0.48808(14) 0.0231(5) Uani 1 1 d . . . . .
H1 H 0.5204 0.2657 0.4758 0.028 Uiso 1 1 calc R . . . .
O1 O 0.3192(3) 0.1911(2) 0.67654(17) 0.0466(7) Uani 1 1 d . . . . .
C18 C 0.6406(3) 0.2956(2) 0.69571(17) 0.0263(6) Uani 1 1 d . . . . .
C16 C 0.6165(3) 0.1548(2) 0.51115(17) 0.0286(6) Uani 1 1 d . . . . .
H16A H 0.6544 0.1648 0.4773 0.034 Uiso 1 1 calc R . . . .
H16B H 0.6119 0.0844 0.5182 0.034 Uiso 1 1 calc R . . . .
C17 C 0.6731(3) 0.2041(2) 0.57583(17) 0.0280(6) Uani 1 1 d . . . . .
H17A H 0.6866 0.2727 0.5675 0.034 Uiso 1 1 calc R . . . .
H17B H 0.7386 0.1715 0.5937 0.034 Uiso 1 1 calc R . . . .
C30 C 0.4269(3) 0.3563(3) 0.56460(17) 0.0283(6) Uani 1 1 d . . . . .
C1 C 0.3598(3) 0.1957(2) 0.6339(2) 0.0305(7) Uani 1 1 d . . . . .
C24 C 0.6380(3) 0.0866(2) 0.68598(16) 0.0261(6) Uani 1 1 d . . . . .
C15 C 0.4531(3) 0.1470(3) 0.42656(16) 0.0294(6) Uani 1 1 d . . . . .
H15A H 0.4493 0.0768 0.4348 0.035 Uiso 1 1 calc R . . . .
H15B H 0.4883 0.1560 0.3912 0.035 Uiso 1 1 calc R . . . .
C23 C 0.6599(3) 0.2795(3) 0.76412(18) 0.0344(7) Uani 1 1 d . . . . .
H23 H 0.6519 0.2166 0.7801 0.041 Uiso 1 1 calc R . . . .
C2 C 0.2058(3) 0.0788(2) 0.46581(17) 0.0283(6) Uani 1 1 d . . . . .
C29 C 0.5673(3) 0.0224(2) 0.70269(16) 0.0289(6) Uani 1 1 d . . . . .
H29 H 0.4970 0.0334 0.6860 0.035 Uiso 1 1 calc R . . . .
C3 C 0.2047(3) 0.0177(3) 0.5194(2) 0.0331(7) Uani 1 1 d . . . . .
H3 H 0.2489 0.0307 0.5609 0.040 Uiso 1 1 calc R . . . .
C14 C 0.3457(3) 0.1895(3) 0.40522(18) 0.0329(7) Uani 1 1 d . . . . .
H14A H 0.3040 0.1505 0.3691 0.040 Uiso 1 1 calc R . . . .
H14B H 0.3486 0.2565 0.3893 0.040 Uiso 1 1 calc R . . . .
C28 C 0.6011(3) -0.0584(3) 0.74434(18) 0.0363(8) Uani 1 1 d . . . . .
H28 H 0.5533 -0.1000 0.7562 0.044 Uiso 1 1 calc R . . . .
C8 C 0.1895(3) 0.2856(3) 0.4589(2) 0.0357(8) Uani 1 1 d . . . . .
C19 C 0.6505(3) 0.3913(3) 0.6733(2) 0.0377(8) Uani 1 1 d . . . . .
H19 H 0.6355 0.4042 0.6277 0.045 Uiso 1 1 calc R . . . .
C21 C 0.7038(3) 0.4502(3) 0.7864(2) 0.0436(9) Uani 1 1 d . . . . .
H21 H 0.7262 0.5012 0.8166 0.052 Uiso 1 1 calc R . . . .
O2 O 0.5185(4) 0.5972(3) 0.5701(2) 0.0730(11) Uani 1 1 d . . . . .
H2 H 0.5338 0.5979 0.5341 0.109 Uiso 1 1 calc GR . . . .
C4 C 0.1383(3) -0.0627(3) 0.5120(2) 0.0410(9) Uani 1 1 d . . . . .
H4 H 0.1377 -0.1026 0.5485 0.049 Uiso 1 1 calc R . . . .
C25 C 0.7428(3) 0.0680(3) 0.71077(19) 0.0339(7) Uani 1 1 d . . . . .
H25 H 0.7910 0.1105 0.7004 0.041 Uiso 1 1 calc R . . . .
C5 C 0.0731(3) -0.0832(3) 0.4502(2) 0.0452(10) Uani 1 1 d . . . . .
H5 H 0.0287 -0.1370 0.4450 0.054 Uiso 1 1 calc R . . . .
C7 C 0.1385(3) 0.0576(3) 0.40372(19) 0.0388(8) Uani 1 1 d . . . . .
H7 H 0.1370 0.0984 0.3673 0.047 Uiso 1 1 calc R . . . .
C20 C 0.6827(4) 0.4674(3) 0.7185(2) 0.0444(10) Uani 1 1 d . . . . .
H20 H 0.6901 0.5307 0.7030 0.053 Uiso 1 1 calc R . . . .
C22 C 0.6912(4) 0.3569(3) 0.8089(2) 0.0437(9) Uani 1 1 d . . . . .
H22 H 0.7037 0.3452 0.8545 0.052 Uiso 1 1 calc R . . . .
C6 C 0.0743(4) -0.0236(4) 0.3966(2) 0.0496(11) Uani 1 1 d . . . . .
H6 H 0.0314 -0.0383 0.3549 0.060 Uiso 1 1 calc R . . . .
C26 C 0.7760(3) -0.0136(3) 0.7508(2) 0.0411(9) Uani 1 1 d . . . . .
H26 H 0.8462 -0.0261 0.7664 0.049 Uiso 1 1 calc R . . . .
C31 C 0.4270(3) 0.4453(3) 0.5639(2) 0.0406(9) Uani 1 1 d . . . . .
C27 C 0.7052(4) -0.0764(3) 0.76785(19) 0.0412(9) Uani 1 1 d . . . . .
H27 H 0.7278 -0.1307 0.7951 0.049 Uiso 1 1 calc R . . . .
C11 C 0.0433(5) 0.4353(4) 0.4348(3) 0.0677(16) Uani 1 1 d . . . . .
H11 H -0.0064 0.4848 0.4259 0.081 Uiso 1 1 calc R . . . .
C34 C 0.2546(5) 0.5765(5) 0.5862(3) 0.0663(14) Uani 1 1 d . U . . .
H34A H 0.2239 0.6060 0.5437 0.099 Uiso 1 1 calc GR . . . .
H34B H 0.2219 0.6020 0.6192 0.099 Uiso 1 1 calc GR . . . .
H34C H 0.2456 0.5063 0.5831 0.099 Uiso 1 1 calc GR . . . .
C9 C 0.0946(4) 0.2709(4) 0.4706(3) 0.0515(11) Uani 1 1 d . . . . .
H9 H 0.0785 0.2103 0.4865 0.062 Uiso 1 1 calc R . . . .
C32 C 0.4274(5) 0.5545(3) 0.5628(4) 0.0710(17) Uani 1 1 d . U . . .
H32 H 0.3890 0.5719 0.5174 0.085 Uiso 1 1 calc R . . . .
C10 C 0.0211(5) 0.3471(5) 0.4587(3) 0.0685(16) Uani 1 1 d . U . . .
H10 H -0.0431 0.3370 0.4674 0.082 Uiso 1 1 calc R . . . .
C33 C 0.3692(5) 0.6007(4) 0.6064(3) 0.0606(13) Uani 1 1 d . U . . .
H33A H 0.3778 0.6717 0.6053 0.073 Uiso 1 1 calc R . . . .
H33B H 0.3976 0.5789 0.6520 0.073 Uiso 1 1 calc R . . . .
C13 C 0.2133(4) 0.3774(3) 0.4357(3) 0.0630(15) Uani 1 1 d . . . . .
H13 H 0.2782 0.3887 0.4285 0.076 Uiso 1 1 calc R . . . .
C12 C 0.1393(5) 0.4520(4) 0.4235(4) 0.0727(17) Uani 1 1 d . U . . .
H12 H 0.1546 0.5130 0.4078 0.087 Uiso 1 1 calc R . . . .
C37 C 0.0741(4) 0.2445(4) 0.1735(3) 0.0600(13) Uani 1 1 d . . . . .
H37 H 0.1160 0.2502 0.1439 0.072 Uiso 1 1 calc R . . . .
C38 C 0.1004(5) 0.2926(5) 0.2320(3) 0.0710(17) Uani 1 1 d . . . . .
H38 H 0.1592 0.3319 0.2424 0.085 Uiso 1 1 calc R . . . .
C36 C -0.0095(6) 0.1893(4) 0.1570(4) 0.0766(18) Uani 1 1 d . . . . .
H36 H -0.0283 0.1595 0.1152 0.092 Uiso 1 1 calc R . . . .
C39 C 0.0399(7) 0.2835(6) 0.2763(4) 0.094(2) Uani 1 1 d . U . . .
H39 H 0.0561 0.3176 0.3166 0.112 Uiso 1 1 calc R . . . .
C40 C -0.0478(6) 0.2214(7) 0.2596(5) 0.094(2) Uani 1 1 d . U . . .
H40 H -0.0899 0.2123 0.2888 0.113 Uiso 1 1 calc R . . . .
C35 C -0.0674(7) 0.1766(7) 0.2009(5) 0.098(2) Uani 1 1 d . U . . .
H35 H -0.1238 0.1344 0.1896 0.118 Uiso 1 1 calc R . . . .
H H 0.419(6) 0.080(7) 0.563(4) 0.118 Uiso 1 1 d R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 P2 2.3049(9) . ?
Ru1 P1 2.3057(9) . ?
Ru1 N1 2.194(3) . ?
Ru1 C30 2.102(3) . ?
Ru1 C1 1.839(4) . ?
Ru1 H 1.65(9) . ?
P2 C18 1.828(3) . ?
P2 C17 1.837(3) . ?
P2 C24 1.826(3) . ?
P1 C2 1.825(3) . ?
P1 C14 1.845(4) . ?
P1 C8 1.827(4) . ?
N1 H1 0.9800 . ?
N1 C16 1.482(4) . ?
N1 C15 1.481(4) . ?
O1 C1 1.147(5) . ?
C18 C23 1.390(5) . ?
C18 C19 1.395(5) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C17 1.518(5) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C30 C31 1.206(5) . ?
C24 C29 1.390(5) . ?
C24 C25 1.392(5) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 C14 1.510(5) . ?
C23 H23 0.9300 . ?
C23 C22 1.393(5) . ?
C2 C3 1.387(5) . ?
C2 C7 1.402(5) . ?
C29 H29 0.9300 . ?
C29 C28 1.397(5) . ?
C3 H3 0.9300 . ?
C3 C4 1.390(5) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C28 H28 0.9300 . ?
C28 C27 1.379(6) . ?
C8 C9 1.366(6) . ?
C8 C13 1.399(6) . ?
C19 H19 0.9300 . ?
C19 C20 1.387(5) . ?
C21 H21 0.9300 . ?
C21 C20 1.381(6) . ?
C21 C22 1.371(6) . ?
O2 H2 0.8200 . ?
O2 C32 1.323(7) . ?
C4 H4 0.9300 . ?
C4 C5 1.383(6) . ?
C25 H25 0.9300 . ?
C25 C26 1.387(5) . ?
C5 H5 0.9300 . ?
C5 C6 1.375(7) . ?
C7 H7 0.9300 . ?
C7 C6 1.382(6) . ?
C20 H20 0.9300 . ?
C22 H22 0.9300 . ?
C6 H6 0.9300 . ?
C26 H26 0.9300 . ?
C26 C27 1.382(6) . ?
C31 C32 1.480(6) . ?
C27 H27 0.9300 . ?
C11 H11 0.9300 . ?
C11 C10 1.355(9) . ?
C11 C12 1.380(9) . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C34 C33 1.522(8) . ?
C9 H9 0.9300 . ?
C9 C10 1.406(6) . ?
C32 H32 0.9800 . ?
C32 C33 1.471(7) . ?
C10 H10 0.9300 . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C13 H13 0.9300 . ?
C13 C12 1.394(7) . ?
C12 H12 0.9300 . ?
C37 H37 0.9300 . ?
C37 C38 1.340(9) . ?
C37 C36 1.319(8) . ?
C38 H38 0.9300 . ?
C38 C39 1.371(11) . ?
C36 H36 0.9300 . ?
C36 C35 1.344(11) . ?
C39 H39 0.9300 . ?
C39 C40 1.415(12) . ?
C40 H40 0.9300 . ?
C40 C35 1.323(12) . ?
C35 H35 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Ru1 P1 164.01(3) . . ?
P2 Ru1 H 93(3) . . ?
P1 Ru1 H 81(3) . . ?
N1 Ru1 P2 82.98(8) . . ?
N1 Ru1 P1 82.05(8) . . ?
N1 Ru1 H 89(3) . . ?
C30 Ru1 P2 92.73(9) . . ?
C30 Ru1 P1 93.04(10) . . ?
C30 Ru1 N1 90.70(11) . . ?
C30 Ru1 H 174(3) . . ?
C1 Ru1 P2 96.58(12) . . ?
C1 Ru1 P1 97.96(12) . . ?
C1 Ru1 N1 176.03(12) . . ?
C1 Ru1 C30 93.27(13) . . ?
C1 Ru1 H 87(3) . . ?
C18 P2 Ru1 120.94(11) . . ?
C18 P2 C17 104.54(16) . . ?
C17 P2 Ru1 101.99(12) . . ?
C24 P2 Ru1 120.16(11) . . ?
C24 P2 C18 102.01(15) . . ?
C24 P2 C17 105.28(15) . . ?
C2 P1 Ru1 120.63(12) . . ?
C2 P1 C14 105.08(16) . . ?
C2 P1 C8 100.73(17) . . ?
C14 P1 Ru1 102.92(12) . . ?
C8 P1 Ru1 120.98(13) . . ?
C8 P1 C14 104.61(18) . . ?
Ru1 N1 H1 106.5 . . ?
C16 N1 Ru1 112.66(19) . . ?
C16 N1 H1 106.5 . . ?
C15 N1 Ru1 113.3(2) . . ?
C15 N1 H1 106.5 . . ?
C15 N1 C16 110.8(3) . . ?
C23 C18 P2 121.0(3) . . ?
C23 C18 C19 118.4(3) . . ?
C19 C18 P2 120.4(3) . . ?
N1 C16 H16A 109.7 . . ?
N1 C16 H16B 109.7 . . ?
N1 C16 C17 109.8(3) . . ?
H16A C16 H16B 108.2 . . ?
C17 C16 H16A 109.7 . . ?
C17 C16 H16B 109.7 . . ?
P2 C17 H17A 109.9 . . ?
P2 C17 H17B 109.9 . . ?
C16 C17 P2 109.0(2) . . ?
C16 C17 H17A 109.9 . . ?
C16 C17 H17B 109.9 . . ?
H17A C17 H17B 108.3 . . ?
C31 C30 Ru1 179.0(4) . . ?
O1 C1 Ru1 178.2(4) . . ?
C29 C24 P2 120.1(3) . . ?
C29 C24 C25 118.7(3) . . ?
C25 C24 P2 121.1(3) . . ?
N1 C15 H15A 109.7 . . ?
N1 C15 H15B 109.7 . . ?
N1 C15 C14 109.7(3) . . ?
H15A C15 H15B 108.2 . . ?
C14 C15 H15A 109.7 . . ?
C14 C15 H15B 109.7 . . ?
C18 C23 H23 119.8 . . ?
C18 C23 C22 120.4(4) . . ?
C22 C23 H23 119.8 . . ?
C3 C2 P1 120.6(3) . . ?
C3 C2 C7 118.4(3) . . ?
C7 C2 P1 120.9(3) . . ?
C24 C29 H29 119.7 . . ?
C24 C29 C28 120.6(3) . . ?
C28 C29 H29 119.7 . . ?
C2 C3 H3 119.5 . . ?
C2 C3 C4 121.0(4) . . ?
C4 C3 H3 119.5 . . ?
P1 C14 H14A 109.9 . . ?
P1 C14 H14B 109.9 . . ?
C15 C14 P1 109.0(2) . . ?
C15 C14 H14A 109.9 . . ?
C15 C14 H14B 109.9 . . ?
H14A C14 H14B 108.3 . . ?
C29 C28 H28 120.0 . . ?
C27 C28 C29 120.0(4) . . ?
C27 C28 H28 120.0 . . ?
C9 C8 P1 120.5(3) . . ?
C9 C8 C13 119.4(4) . . ?
C13 C8 P1 120.0(3) . . ?
C18 C19 H19 119.8 . . ?
C20 C19 C18 120.4(4) . . ?
C20 C19 H19 119.8 . . ?
C20 C21 H21 120.4 . . ?
C22 C21 H21 120.4 . . ?
C22 C21 C20 119.2(4) . . ?
C32 O2 H2 109.5 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 119.9(4) . . ?
C5 C4 H4 120.0 . . ?
C24 C25 H25 119.7 . . ?
C26 C25 C24 120.6(4) . . ?
C26 C25 H25 119.7 . . ?
C4 C5 H5 120.2 . . ?
C6 C5 C4 119.6(4) . . ?
C6 C5 H5 120.2 . . ?
C2 C7 H7 119.9 . . ?
C6 C7 C2 120.1(4) . . ?
C6 C7 H7 119.9 . . ?
C19 C20 H20 119.6 . . ?
C21 C20 C19 120.7(4) . . ?
C21 C20 H20 119.6 . . ?
C23 C22 H22 119.6 . . ?
C21 C22 C23 120.8(4) . . ?
C21 C22 H22 119.6 . . ?
C5 C6 C7 120.9(4) . . ?
C5 C6 H6 119.5 . . ?
C7 C6 H6 119.5 . . ?
C25 C26 H26 119.8 . . ?
C27 C26 C25 120.3(4) . . ?
C27 C26 H26 119.8 . . ?
C30 C31 C32 179.7(5) . . ?
C28 C27 C26 119.8(3) . . ?
C28 C27 H27 120.1 . . ?
C26 C27 H27 120.1 . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.3(5) . . ?
C12 C11 H11 119.9 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
C8 C9 H9 119.9 . . ?
C8 C9 C10 120.2(5) . . ?
C10 C9 H9 119.9 . . ?
O2 C32 C31 116.3(5) . . ?
O2 C32 H32 104.6 . . ?
O2 C32 C33 110.9(5) . . ?
C31 C32 H32 104.6 . . ?
C33 C32 C31 114.4(5) . . ?
C33 C32 H32 104.6 . . ?
C11 C10 C9 120.4(5) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C34 C33 H33A 109.0 . . ?
C34 C33 H33B 109.0 . . ?
C32 C33 C34 113.1(5) . . ?
C32 C33 H33A 109.0 . . ?
C32 C33 H33B 109.0 . . ?
H33A C33 H33B 107.8 . . ?
C8 C13 H13 120.1 . . ?
C12 C13 C8 119.7(5) . . ?
C12 C13 H13 120.1 . . ?
C11 C12 C13 120.0(5) . . ?
C11 C12 H12 120.0 . . ?
C13 C12 H12 120.0 . . ?
C38 C37 H37 119.2 . . ?
C36 C37 H37 119.2 . . ?
C36 C37 C38 121.7(7) . . ?
C37 C38 H38 120.2 . . ?
C37 C38 C39 119.5(6) . . ?
C39 C38 H38 120.2 . . ?
C37 C36 H36 120.3 . . ?
C37 C36 C35 119.4(7) . . ?
C35 C36 H36 120.3 . . ?
C38 C39 H39 120.6 . . ?
C38 C39 C40 118.8(7) . . ?
C40 C39 H39 120.6 . . ?
C39 C40 H40 121.3 . . ?
C35 C40 C39 117.3(7) . . ?
C35 C40 H40 121.3 . . ?
C36 C35 H35 118.5 . . ?
C40 C35 C36 123.1(8) . . ?
C40 C35 H35 118.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru1 P2 C18 C23 112.0(3) . . . . ?
Ru1 P2 C18 C19 -62.9(3) . . . . ?
Ru1 P2 C17 C16 -31.5(2) . . . . ?
Ru1 P2 C24 C29 -23.8(3) . . . . ?
Ru1 P2 C24 C25 159.4(2) . . . . ?
Ru1 P1 C2 C3 21.6(3) . . . . ?
Ru1 P1 C2 C7 -162.3(3) . . . . ?
Ru1 P1 C14 C15 28.5(3) . . . . ?
Ru1 P1 C8 C9 -107.2(4) . . . . ?
Ru1 P1 C8 C13 69.6(4) . . . . ?
Ru1 N1 C16 C17 -49.4(3) . . . . ?
Ru1 N1 C15 C14 50.7(3) . . . . ?
P2 C18 C23 C22 -176.7(3) . . . . ?
P2 C18 C19 C20 177.4(3) . . . . ?
P2 C24 C29 C28 -175.9(3) . . . . ?
P2 C24 C25 C26 177.4(3) . . . . ?
P1 C2 C3 C4 176.1(3) . . . . ?
P1 C2 C7 C6 -177.4(3) . . . . ?
P1 C8 C9 C10 177.6(4) . . . . ?
P1 C8 C13 C12 -178.2(5) . . . . ?
N1 C16 C17 P2 53.0(3) . . . . ?
N1 C15 C14 P1 -51.0(3) . . . . ?
C18 P2 C17 C16 -158.2(2) . . . . ?
C18 P2 C24 C29 113.2(3) . . . . ?
C18 P2 C24 C25 -63.6(3) . . . . ?
C18 C23 C22 C21 -0.2(7) . . . . ?
C18 C19 C20 C21 -1.1(7) . . . . ?
C16 N1 C15 C14 178.5(3) . . . . ?
C17 P2 C18 C23 -134.1(3) . . . . ?
C17 P2 C18 C19 51.1(3) . . . . ?
C17 P2 C24 C29 -137.9(3) . . . . ?
C17 P2 C24 C25 45.3(3) . . . . ?
C24 P2 C18 C23 -24.6(3) . . . . ?
C24 P2 C18 C19 160.5(3) . . . . ?
C24 P2 C17 C16 94.7(2) . . . . ?
C24 C29 C28 C27 -1.7(5) . . . . ?
C24 C25 C26 C27 -1.3(6) . . . . ?
C15 N1 C16 C17 -177.5(3) . . . . ?
C23 C18 C19 C20 2.4(6) . . . . ?
C2 P1 C14 C15 -98.6(3) . . . . ?
C2 P1 C8 C9 28.7(4) . . . . ?
C2 P1 C8 C13 -154.5(4) . . . . ?
C2 C3 C4 C5 0.8(6) . . . . ?
C2 C7 C6 C5 1.9(7) . . . . ?
C29 C24 C25 C26 0.6(5) . . . . ?
C29 C28 C27 C26 0.9(6) . . . . ?
C3 C2 C7 C6 -1.2(6) . . . . ?
C3 C4 C5 C6 -0.1(6) . . . . ?
C14 P1 C2 C3 136.9(3) . . . . ?
C14 P1 C2 C7 -47.0(3) . . . . ?
C14 P1 C8 C9 137.6(4) . . . . ?
C14 P1 C8 C13 -45.6(4) . . . . ?
C8 P1 C2 C3 -114.6(3) . . . . ?
C8 P1 C2 C7 61.5(3) . . . . ?
C8 P1 C14 C15 155.7(2) . . . . ?
C8 C9 C10 C11 0.8(9) . . . . ?
C8 C13 C12 C11 0.5(10) . . . . ?
C19 C18 C23 C22 -1.8(6) . . . . ?
O2 C32 C33 C34 163.1(5) . . . . ?
C4 C5 C6 C7 -1.2(7) . . . . ?
C25 C24 C29 C28 0.9(5) . . . . ?
C25 C26 C27 C28 0.6(6) . . . . ?
C7 C2 C3 C4 -0.1(5) . . . . ?
C20 C21 C22 C23 1.5(7) . . . . ?
C22 C21 C20 C19 -0.9(7) . . . . ?
C31 C32 C33 C34 -63.0(7) . . . . ?
C9 C8 C13 C12 -1.4(8) . . . . ?
C10 C11 C12 C13 1.1(10) . . . . ?
C13 C8 C9 C10 0.8(8) . . . . ?
C12 C11 C10 C9 -1.8(10) . . . . ?
C37 C38 C39 C40 1.5(11) . . . . ?
C37 C36 C35 C40 3.7(13) . . . . ?
C38 C37 C36 C35 -3.5(10) . . . . ?
C38 C39 C40 C35 -1.3(12) . . . . ?
C36 C37 C38 C39 0.9(10) . . . . ?
C39 C40 C35 C36 -1.3(14) . . . . ?

_shelx_SHELXL_version_number     2015/1
_olex2_submission_special_instructions 'No special instructions were received'
