# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3c
_database_code_depnum_ccdc_archive 'CCDC 1468913'
_audit_update_record             
;
2016-03-16 deposited with the CCDC.
2016-06-03 downloaded from the CCDC.
;
#===============================================================================


_audit_creation_method           SHELXL-2014
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C27 H47 B N5 Pt, C32 H12 B F24'
_chemical_formula_sum            'C59 H59 B2 F24 N5 Pt'
_chemical_formula_weight         1510.82
_chemical_compound_source        synthesis

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 2/c'
_space_group_name_Hall           '-C 2yc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.077 0.250 207 45 ' '
2 0.000 -0.077 0.750 207 45 ' '
3 0.262 0.049 0.148 9 1 ' '
4 0.738 0.049 0.352 9 1 ' '
5 0.266 0.065 0.666 10 0 ' '
6 0.734 0.065 0.834 10 0 ' '
7 0.500 0.423 0.750 207 45 ' '
8 0.500 0.577 0.250 207 45 ' '
9 0.234 0.435 0.334 9 0 ' '
10 0.766 0.435 0.166 9 0 ' '
11 0.238 0.451 0.852 8 1 ' '
12 0.762 0.451 0.648 8 0 ' '
13 0.239 0.564 0.355 7 0 ' '
14 0.761 0.564 0.145 7 0 ' '
15 0.234 0.579 0.832 8 0 ' '
16 0.766 0.579 0.668 8 0 ' '
17 0.266 0.921 0.168 8 0 ' '
18 0.734 0.921 0.332 8 0 ' '
19 0.261 0.936 0.645 6 0 ' '
20 0.739 0.936 0.855 6 0 ' '
_platon_squeeze_details          
;
;

_cell_length_a                   39.650(5)
_cell_length_b                   13.440(5)
_cell_length_c                   26.010(5)
_cell_angle_alpha                90.000
_cell_angle_beta                 111.476(5)
_cell_angle_gamma                90.000
_cell_volume                     12898(6)
_cell_formula_units_Z            8
_cell_measurement_temperature    273(2)
_cell_measurement_reflns_used    9977
_cell_measurement_theta_min      3.50
_cell_measurement_theta_max      59.06


_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_F_000             6016
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_min          0.17
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_max          0.27
_exptl_absorpt_coefficient_mu    5.064
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_correction_T_min  0.4927
_exptl_absorpt_correction_T_max  0.7516
_exptl_absorpt_process_details   'SADABS v.2008/1;(Sheldrick 2008)'


_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      273(2)
_diffrn_radiation_wavelength     1.5418
_diffrn_radiation_type           CuK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_reflns_number            17182
_diffrn_reflns_av_unetI/netI     0.0332
_diffrn_reflns_av_R_equivalents  0.0210
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_h_max       44
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.395
_diffrn_reflns_theta_max         59.061
_diffrn_reflns_theta_full        67.000
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measured_fraction_theta_full 0.779
_diffrn_reflns_Laue_measured_fraction_max 0.961
_diffrn_reflns_Laue_measured_fraction_full 0.779
_diffrn_reflns_point_group_measured_fraction_max 0.961
_diffrn_reflns_point_group_measured_fraction_full 0.779
_reflns_number_total             8952
_reflns_number_gt                8775
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    SIR-2004
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_molecular_graphics    'PLATON (Spek, 2008)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0411P)²+135.6565P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8952
_refine_ls_number_parameters     832
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0400
_refine_ls_R_factor_gt           0.0395
_refine_ls_wR_factor_ref         0.0981
_refine_ls_wR_factor_gt          0.0977
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_restrained_S_all      1.048
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.59761(13) 0.4716(3) 0.1839(2) 0.0208(10) Uani 1 1 d . . . . .
C2 C 0.55230(16) 0.3969(4) 0.1162(2) 0.0362(13) Uani 1 1 d . . . . .
H2 H 0.5359 0.3483 0.0967 0.043 Uiso 1 1 calc R U . . .
C3 C 0.55449(14) 0.4886(4) 0.0990(2) 0.0313(12) Uani 1 1 d . . . . .
H3 H 0.5402 0.5165 0.0653 0.038 Uiso 1 1 calc R U . . .
C4 C 0.5965(2) 0.6337(5) 0.1418(3) 0.068(3) Uani 1 1 d D . . . .
C5 C 0.62281(13) 0.6561(4) 0.1975(2) 0.0229(10) Uani 1 1 d . . . . .
H5A H 0.6121 0.7042 0.2148 0.027 Uiso 1 1 calc R U . . .
H5B H 0.6440 0.6868 0.1940 0.027 Uiso 1 1 calc R U . . .
C6 C 0.5752(3) 0.7032(5) 0.1060(3) 0.119(5) Uani 1 1 d D . . . .
H6A H 0.5881 0.7651 0.1109 0.179 Uiso 1 1 calc R U . . .
H6B H 0.5692 0.6805 0.0687 0.179 Uiso 1 1 calc R U . . .
H6C H 0.5534 0.7127 0.1132 0.179 Uiso 1 1 calc R U . . .
C7 C 0.6235(3) 0.6178(8) 0.1045(4) 0.085(3) Uani 1 1 d D . . . .
H7A H 0.6418 0.5694 0.1224 0.127 Uiso 1 1 calc R U . . .
H7B H 0.6091 0.5952 0.0681 0.127 Uiso 1 1 calc R U . . .
H7C H 0.6347 0.6800 0.1021 0.127 Uiso 1 1 calc R U . . .
C8 C 0.58560(19) 0.2907(4) 0.2003(3) 0.0517(18) Uani 1 1 d . . . . .
C9 C 0.5554(3) 0.2164(6) 0.1703(4) 0.104(4) Uani 1 1 d . . . . .
H9A H 0.5596 0.1550 0.1905 0.156 Uiso 1 1 calc R U . . .
H9B H 0.5324 0.2434 0.1677 0.156 Uiso 1 1 calc R U . . .
H9C H 0.5552 0.2044 0.1338 0.156 Uiso 1 1 calc R U . . .
C10 C 0.6221(2) 0.2518(5) 0.2029(3) 0.068(2) Uani 1 1 d . . . . .
H10A H 0.6273 0.1903 0.2231 0.102 Uiso 1 1 calc R U . . .
H10B H 0.6214 0.2407 0.1661 0.102 Uiso 1 1 calc R U . . .
H10C H 0.6405 0.2997 0.2211 0.102 Uiso 1 1 calc R U . . .
C11 C 0.58422(19) 0.3101(5) 0.2566(3) 0.060(2) Uani 1 1 d . . . . .
H11A H 0.5886 0.2491 0.2772 0.089 Uiso 1 1 calc R U . . .
H11B H 0.6025 0.3579 0.2758 0.089 Uiso 1 1 calc R U . . .
H11C H 0.5608 0.3355 0.2526 0.089 Uiso 1 1 calc R U . . .
C12 C 0.67630(12) 0.6244(3) 0.30407(18) 0.0174(10) Uani 1 1 d . . . . .
C13 C 0.72567(14) 0.7181(5) 0.3479(2) 0.0388(14) Uani 1 1 d . . . . .
H13 H 0.7486 0.7459 0.3577 0.047 Uiso 1 1 calc R U . . .
C14 C 0.70209(15) 0.7360(4) 0.3717(2) 0.0371(14) Uani 1 1 d . . . . .
H14 H 0.7054 0.7794 0.4010 0.045 Uiso 1 1 calc R U . . .
C15 C 0.63939(13) 0.6768(4) 0.3634(2) 0.0250(11) Uani 1 1 d . . . . .
C16 C 0.60502(14) 0.7084(4) 0.3165(2) 0.0324(12) Uani 1 1 d . . . . .
H16A H 0.6080 0.7746 0.3049 0.049 Uiso 1 1 calc R U . . .
H16B H 0.6003 0.6634 0.2860 0.049 Uiso 1 1 calc R U . . .
H16C H 0.5850 0.7072 0.3289 0.049 Uiso 1 1 calc R U . . .
C17 C 0.63553(15) 0.5729(4) 0.3826(2) 0.0305(12) Uani 1 1 d . . . . .
H17A H 0.6152 0.5706 0.3943 0.046 Uiso 1 1 calc R U . . .
H17B H 0.6317 0.5269 0.3527 0.046 Uiso 1 1 calc R U . . .
H17C H 0.6572 0.5551 0.4129 0.046 Uiso 1 1 calc R U . . .
C18 C 0.64642(17) 0.7493(5) 0.4114(2) 0.0394(14) Uani 1 1 d . . . . .
H18A H 0.6489 0.8154 0.3993 0.059 Uiso 1 1 calc R U . . .
H18B H 0.6265 0.7472 0.4239 0.059 Uiso 1 1 calc R U . . .
H18C H 0.6683 0.7307 0.4411 0.059 Uiso 1 1 calc R U . . .
C19 C 0.73323(13) 0.6092(4) 0.2760(2) 0.0274(11) Uani 1 1 d . . . . .
C20 C 0.71222(14) 0.5488(4) 0.2253(2) 0.0294(12) Uani 1 1 d . . . . .
H20A H 0.7285 0.5248 0.2083 0.044 Uiso 1 1 calc R U . . .
H20B H 0.7009 0.4934 0.2358 0.044 Uiso 1 1 calc R U . . .
H20C H 0.6940 0.5899 0.1995 0.044 Uiso 1 1 calc R U . . .
C21 C 0.75062(17) 0.6968(5) 0.2574(3) 0.0442(15) Uani 1 1 d . . . . .
H21A H 0.7656 0.6722 0.2384 0.066 Uiso 1 1 calc R U . . .
H21B H 0.7320 0.7387 0.2331 0.066 Uiso 1 1 calc R U . . .
H21C H 0.7652 0.7344 0.2892 0.066 Uiso 1 1 calc R U . . .
C22 C 0.76218(16) 0.5437(5) 0.3170(2) 0.0436(16) Uani 1 1 d . . . . .
H22A H 0.7775 0.5162 0.2993 0.065 Uiso 1 1 calc R U . . .
H22B H 0.7765 0.5829 0.3481 0.065 Uiso 1 1 calc R U . . .
H22C H 0.7507 0.4907 0.3292 0.065 Uiso 1 1 calc R U . . .
C23 C 0.66057(15) 0.3125(4) 0.3918(2) 0.0329(13) Uani 1 1 d . . . . .
H23 H 0.6575 0.3769 0.4025 0.040 Uiso 1 1 calc R U . . .
C24 C 0.65178(15) 0.2344(5) 0.4177(2) 0.0379(14) Uani 1 1 d . . . . .
H24 H 0.6424 0.2457 0.4452 0.046 Uiso 1 1 calc R U . . .
C25 C 0.65673(14) 0.1397(5) 0.4033(2) 0.0378(14) Uani 1 1 d . . . . .
H25 H 0.6509 0.0858 0.4209 0.045 Uiso 1 1 calc R U . . .
C26 C 0.67033(16) 0.1247(4) 0.3624(2) 0.0358(13) Uani 1 1 d . . . . .
H26 H 0.6740 0.0606 0.3520 0.043 Uiso 1 1 calc R U . . .
C27 C 0.67845(15) 0.2067(4) 0.3370(2) 0.0293(12) Uani 1 1 d . . . . .
H27 H 0.6876 0.1971 0.3092 0.035 Uiso 1 1 calc R U . . .
C28 C 0.60909(12) 0.9907(3) 0.07834(18) 0.0139(9) Uani 1 1 d . . . . .
C29 C 0.57285(12) 0.9870(3) 0.07361(19) 0.0168(10) Uani 1 1 d . . . . .
H29 H 0.5548 0.9970 0.0391 0.020 Uiso 1 1 calc R U . . .
C30 C 0.56303(13) 0.9689(3) 0.1187(2) 0.0194(10) Uani 1 1 d . . . . .
C31 C 0.58890(13) 0.9526(3) 0.1707(2) 0.0200(10) Uani 1 1 d . . . . .
H31 H 0.5823 0.9400 0.2009 0.024 Uiso 1 1 calc R U . . .
C32 C 0.62501(13) 0.9557(3) 0.17632(19) 0.0170(10) Uani 1 1 d . . . . .
C33 C 0.63461(13) 0.9749(3) 0.13114(19) 0.0163(10) Uani 1 1 d . . . . .
H33 H 0.6591 0.9774 0.1363 0.020 Uiso 1 1 calc R U . . .
C34 C 0.52327(13) 0.9655(4) 0.1095(2) 0.0248(11) Uani 1 1 d . . . . .
C35 C 0.65484(13) 0.9394(4) 0.23123(19) 0.0212(10) Uani 1 1 d . . . . .
C36 C 0.66090(12) 0.9808(3) 0.03279(17) 0.0140(9) Uani 1 1 d . . . . .
C37 C 0.68501(12) 1.0324(3) 0.01488(18) 0.0161(10) Uani 1 1 d . . . . .
H37 H 0.6790 1.0965 0.0010 0.019 Uiso 1 1 calc R U . . .
C38 C 0.71767(12) 0.9920(4) 0.01688(18) 0.0188(10) Uani 1 1 d . . . . .
C39 C 0.72785(12) 0.8969(4) 0.03664(19) 0.0202(10) Uani 1 1 d . . . . .
H39 H 0.7499 0.8702 0.0383 0.024 Uiso 1 1 calc R U . . .
C40 C 0.70417(12) 0.8424(3) 0.05392(18) 0.0193(10) Uani 1 1 d . . . . .
C41 C 0.67181(12) 0.8838(3) 0.05241(18) 0.0181(10) Uani 1 1 d . . . . .
H41 H 0.6567 0.8460 0.0648 0.022 Uiso 1 1 calc R U . . .
C42 C 0.74148(13) 1.0501(4) -0.0056(2) 0.0256(11) Uani 1 1 d . . . . .
C43 C 0.71352(14) 0.7383(4) 0.0739(2) 0.0266(11) Uani 1 1 d . . . . .
C44 C 0.61631(11) 1.1427(3) 0.02182(17) 0.0145(9) Uani 1 1 d . . . . .
C45 C 0.58391(12) 1.1911(3) -0.00716(19) 0.0183(10) Uani 1 1 d . . . . .
H45 H 0.5638 1.1531 -0.0271 0.022 Uiso 1 1 calc R U . . .
C46 C 0.58041(13) 1.2940(3) -0.00764(19) 0.0211(10) Uani 1 1 d . . . . .
C47 C 0.60979(14) 1.3538(4) 0.0213(2) 0.0249(11) Uani 1 1 d . . . . .
H47 H 0.6078 1.4227 0.0204 0.030 Uiso 1 1 calc R U . . .
C48 C 0.64202(12) 1.3077(3) 0.0514(2) 0.0222(10) Uani 1 1 d . . . . .
C49 C 0.64509(12) 1.2052(3) 0.05222(19) 0.0183(10) Uani 1 1 d . . . . .
H49 H 0.6671 1.1765 0.0738 0.022 Uiso 1 1 calc R U . . .
C50 C 0.67489(16) 1.3697(4) 0.0816(3) 0.0429(16) Uani 1 1 d . . . . .
C51 C 0.54442(14) 1.3404(4) -0.0407(2) 0.0320(12) Uani 1 1 d . . . . .
C52 C 0.59367(12) 0.9644(3) -0.03081(19) 0.0167(10) Uani 1 1 d . . . . .
C53 C 0.58527(12) 1.0040(3) -0.08389(19) 0.0176(10) Uani 1 1 d . . . . .
H53 H 0.5924 1.0688 -0.0874 0.021 Uiso 1 1 calc R U . . .
C54 C 0.56690(13) 0.9505(4) -0.13121(19) 0.0207(10) Uani 1 1 d . . . . .
C55 C 0.55598(13) 0.8536(4) -0.1284(2) 0.0235(11) Uani 1 1 d . . . . .
H55 H 0.5438 0.8175 -0.1603 0.028 Uiso 1 1 calc R U . . .
C56 C 0.56383(13) 0.8119(4) -0.0765(2) 0.0222(10) Uani 1 1 d . . . . .
C57 C 0.58195(12) 0.8669(3) -0.02902(18) 0.0181(10) Uani 1 1 d . . . . .
H57 H 0.5864 0.8375 0.0052 0.022 Uiso 1 1 calc R U . . .
C58 C 0.55445(16) 0.7060(4) -0.0706(2) 0.0328(13) Uani 1 1 d . . . . .
C59 C 0.56007(14) 0.9967(4) -0.1865(2) 0.0275(11) Uani 1 1 d . . . . .
B1 B 0.68387(16) 0.3925(5) 0.3232(3) 0.0276(13) Uani 1 1 d D . . . .
B2 B 0.61988(14) 1.0210(4) 0.0253(2) 0.0151(11) Uani 1 1 d . . . . .
N1 N 0.57878(12) 0.3863(3) 0.16842(18) 0.0330(11) Uani 1 1 d . . . . .
N2 N 0.58224(11) 0.5347(3) 0.14122(17) 0.0226(9) Uani 1 1 d . . . . .
N3 N 0.67143(10) 0.6786(3) 0.34519(16) 0.0226(9) Uani 1 1 d . . . . .
N4 N 0.71003(10) 0.6503(3) 0.30564(16) 0.0246(9) Uani 1 1 d . . . . .
N5 N 0.67349(10) 0.2993(3) 0.35128(16) 0.0229(9) Uani 1 1 d . . . . .
F1 F 0.50530(9) 1.0435(3) 0.08131(17) 0.0485(9) Uani 1 1 d . . . . .
F2 F 0.50702(8) 0.8874(3) 0.08018(18) 0.0584(11) Uani 1 1 d . . . . .
F3 F 0.51707(10) 0.9649(4) 0.15589(16) 0.0757(16) Uani 1 1 d . . . . .
F4 F 0.67327(8) 1.0249(2) 0.25096(12) 0.0335(7) Uani 1 1 d . . . . .
F5 F 0.64312(8) 0.9074(3) 0.27019(11) 0.0366(7) Uani 1 1 d . . . . .
F6 F 0.67959(7) 0.8751(2) 0.22877(11) 0.0286(6) Uani 1 1 d . . . . .
F7 F 0.7230(2) 0.7308(4) 0.1267(2) 0.130(3) Uani 1 1 d . . . . .
F8 F 0.74135(12) 0.7024(3) 0.0634(2) 0.0801(15) Uani 1 1 d . . . . .
F9 F 0.68756(12) 0.6775(3) 0.0526(3) 0.112(2) Uani 1 1 d . . . . .
F10 F 0.73054(9) 1.0416(2) -0.06057(13) 0.0405(8) Uani 1 1 d . . . . .
F11 F 0.74094(9) 1.1479(2) 0.00339(15) 0.0443(8) Uani 1 1 d . . . . .
F12 F 0.77587(8) 1.0209(3) 0.01434(16) 0.0525(10) Uani 1 1 d . . . . .
F13 F 0.68736(11) 1.3529(3) 0.13575(16) 0.0670(12) Uani 1 1 d . . . . .
F14 F 0.67134(13) 1.4633(3) 0.0713(3) 0.119(3) Uani 1 1 d . . . . .
F15 F 0.70386(10) 1.3415(3) 0.06824(19) 0.0701(12) Uani 1 1 d . . . . .
F16 F 0.54548(10) 1.4391(2) -0.04079(19) 0.0623(12) Uani 1 1 d . . . . .
F17 F 0.53219(10) 1.3101(3) -0.09244(14) 0.0567(10) Uani 1 1 d . . . . .
F18 F 0.51883(8) 1.3173(3) -0.02136(16) 0.0538(10) Uani 1 1 d . . . . .
F19 F 0.59088(10) 1.0098(4) -0.19520(16) 0.0745(14) Uani 1 1 d . . . . .
F20 F 0.54527(11) 1.0860(3) -0.19174(14) 0.0541(10) Uani 1 1 d . . . . .
F21 F 0.53864(13) 0.9439(3) -0.22803(14) 0.0666(12) Uani 1 1 d . . . . .
F22 F 0.53693(13) 0.6614(3) -0.11862(14) 0.0634(12) Uani 1 1 d . . . . .
F23 F 0.58339(10) 0.6511(2) -0.04301(18) 0.0564(10) Uani 1 1 d . . . . .
F24 F 0.53229(10) 0.6981(3) -0.04187(15) 0.0499(9) Uani 1 1 d . . . . .
Pt1 Pt 0.63906(2) 0.53499(2) 0.24820(2) 0.01485(9) Uani 1 1 d . . . . .
H1B H 0.6594(11) 0.423(5) 0.299(3) 0.06(2) Uiso 1 1 d D . . . .
H2B H 0.6969(14) 0.373(4) 0.298(2) 0.037(15) Uiso 1 1 d D . . . .
H3B H 0.6972(15) 0.443(4) 0.3522(19) 0.042(17) Uiso 1 1 d D . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.347(6) . ?
C1 N2 1.351(6) . ?
C1 Pt1 2.052(5) . ?
C2 C3 1.325(8) . ?
C2 N1 1.387(7) . ?
C2 H2 0.9300 . ?
C3 N2 1.384(7) . ?
C3 H3 0.9300 . ?
C4 C6 1.370(9) . ?
C4 N2 1.444(7) . ?
C4 C5 1.473(8) . ?
C4 C7 1.698(11) . ?
C5 Pt1 2.045(5) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 N1 1.498(7) . ?
C8 C11 1.509(11) . ?
C8 C10 1.515(11) . ?
C8 C9 1.535(9) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 N3 1.365(6) . ?
C12 N4 1.368(6) . ?
C12 Pt1 2.041(5) . ?
C13 C14 1.318(8) . ?
C13 N4 1.387(7) . ?
C13 H13 0.9300 . ?
C14 N3 1.391(7) . ?
C14 H14 0.9300 . ?
C15 C17 1.509(7) . ?
C15 N3 1.510(6) . ?
C15 C16 1.520(7) . ?
C15 C18 1.525(7) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 N4 1.504(6) . ?
C19 C20 1.513(7) . ?
C19 C22 1.527(8) . ?
C19 C21 1.529(8) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 N5 1.342(7) . ?
C23 C24 1.360(8) . ?
C23 H23 0.9300 . ?
C24 C25 1.362(9) . ?
C24 H24 0.9300 . ?
C25 C26 1.372(8) . ?
C25 H25 0.9300 . ?
C26 C27 1.383(8) . ?
C26 H26 0.9300 . ?
C27 N5 1.334(7) . ?
C27 H27 0.9300 . ?
C28 C33 1.392(7) . ?
C28 C29 1.398(6) . ?
C28 B2 1.639(7) . ?
C29 C30 1.385(7) . ?
C29 H29 0.9300 . ?
C30 C31 1.384(7) . ?
C30 C34 1.506(7) . ?
C31 C32 1.385(7) . ?
C31 H31 0.9300 . ?
C32 C33 1.386(7) . ?
C32 C35 1.500(7) . ?
C33 H33 0.9300 . ?
C34 F3 1.317(6) . ?
C34 F2 1.318(6) . ?
C34 F1 1.327(6) . ?
C35 F6 1.327(6) . ?
C35 F5 1.332(5) . ?
C35 F4 1.357(6) . ?
C36 C37 1.392(7) . ?
C36 C41 1.409(6) . ?
C36 B2 1.656(7) . ?
C37 C38 1.387(7) . ?
C37 H37 0.9300 . ?
C38 C39 1.382(7) . ?
C38 C42 1.499(7) . ?
C39 C40 1.389(7) . ?
C39 H39 0.9300 . ?
C40 C41 1.386(7) . ?
C40 C43 1.491(7) . ?
C41 H41 0.9300 . ?
C42 F12 1.328(6) . ?
C42 F11 1.336(6) . ?
C42 F10 1.338(6) . ?
C43 F9 1.271(7) . ?
C43 F7 1.288(7) . ?
C43 F8 1.321(6) . ?
C44 C45 1.390(7) . ?
C44 C49 1.404(6) . ?
C44 B2 1.641(6) . ?
C45 C46 1.390(7) . ?
C45 H45 0.9300 . ?
C46 C47 1.388(7) . ?
C46 C51 1.505(7) . ?
C47 C48 1.377(7) . ?
C47 H47 0.9300 . ?
C48 C49 1.383(7) . ?
C48 C50 1.503(7) . ?
C49 H49 0.9300 . ?
C50 F14 1.283(7) . ?
C50 F13 1.330(8) . ?
C50 F15 1.370(8) . ?
C51 F17 1.318(7) . ?
C51 F18 1.323(7) . ?
C51 F16 1.328(6) . ?
C52 C57 1.398(7) . ?
C52 C53 1.401(7) . ?
C52 B2 1.636(7) . ?
C53 C54 1.380(7) . ?
C53 H53 0.9300 . ?
C54 C55 1.383(7) . ?
C54 C59 1.498(7) . ?
C55 C56 1.387(7) . ?
C55 H55 0.9300 . ?
C56 C57 1.392(7) . ?
C56 C58 1.493(7) . ?
C57 H57 0.9300 . ?
C58 F22 1.330(6) . ?
C58 F23 1.332(7) . ?
C58 F24 1.350(6) . ?
C59 F21 1.312(6) . ?
C59 F20 1.321(7) . ?
C59 F19 1.333(6) . ?
B1 N5 1.579(7) . ?
B1 H1B 1.03(2) . ?
B1 H2B 1.02(2) . ?
B1 H3B 1.01(2) . ?
Pt1 H1B 1.96(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 N2 104.8(4) . . ?
N1 C1 Pt1 142.0(4) . . ?
N2 C1 Pt1 113.3(3) . . ?
C3 C2 N1 107.9(4) . . ?
C3 C2 H2 126.1 . . ?
N1 C2 H2 126.1 . . ?
C2 C3 N2 106.2(5) . . ?
C2 C3 H3 126.9 . . ?
N2 C3 H3 126.9 . . ?
C6 C4 N2 118.6(6) . . ?
C6 C4 C5 124.6(6) . . ?
N2 C4 C5 109.4(5) . . ?
C6 C4 C7 93.3(8) . . ?
N2 C4 C7 101.8(6) . . ?
C5 C4 C7 102.7(6) . . ?
C4 C5 Pt1 114.5(4) . . ?
C4 C5 H5A 108.6 . . ?
Pt1 C5 H5A 108.6 . . ?
C4 C5 H5B 108.6 . . ?
Pt1 C5 H5B 108.6 . . ?
H5A C5 H5B 107.6 . . ?
C4 C6 H6A 109.5 . . ?
C4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C4 C7 H7A 109.5 . . ?
C4 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C4 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N1 C8 C11 109.0(5) . . ?
N1 C8 C10 107.3(6) . . ?
C11 C8 C10 112.9(5) . . ?
N1 C8 C9 109.1(5) . . ?
C11 C8 C9 107.9(7) . . ?
C10 C8 C9 110.6(7) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C8 C11 H11A 109.5 . . ?
C8 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C8 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N3 C12 N4 105.0(4) . . ?
N3 C12 Pt1 126.8(3) . . ?
N4 C12 Pt1 128.0(3) . . ?
C14 C13 N4 107.7(5) . . ?
C14 C13 H13 126.2 . . ?
N4 C13 H13 126.2 . . ?
C13 C14 N3 107.9(4) . . ?
C13 C14 H14 126.1 . . ?
N3 C14 H14 126.1 . . ?
C17 C15 N3 108.5(4) . . ?
C17 C15 C16 110.7(5) . . ?
N3 C15 C16 110.7(4) . . ?
C17 C15 C18 109.3(4) . . ?
N3 C15 C18 108.9(4) . . ?
C16 C15 C18 108.7(4) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N4 C19 C20 113.5(4) . . ?
N4 C19 C22 107.4(4) . . ?
C20 C19 C22 109.4(5) . . ?
N4 C19 C21 108.1(4) . . ?
C20 C19 C21 107.8(4) . . ?
C22 C19 C21 110.7(5) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N5 C23 C24 121.9(5) . . ?
N5 C23 H23 119.0 . . ?
C24 C23 H23 119.0 . . ?
C23 C24 C25 119.7(5) . . ?
C23 C24 H24 120.1 . . ?
C25 C24 H24 120.1 . . ?
C24 C25 C26 119.2(5) . . ?
C24 C25 H25 120.4 . . ?
C26 C25 H25 120.4 . . ?
C25 C26 C27 118.7(5) . . ?
C25 C26 H26 120.6 . . ?
C27 C26 H26 120.6 . . ?
N5 C27 C26 121.7(5) . . ?
N5 C27 H27 119.1 . . ?
C26 C27 H27 119.1 . . ?
C33 C28 C29 115.7(4) . . ?
C33 C28 B2 123.3(4) . . ?
C29 C28 B2 120.8(4) . . ?
C30 C29 C28 122.0(4) . . ?
C30 C29 H29 119.0 . . ?
C28 C29 H29 119.0 . . ?
C31 C30 C29 121.2(4) . . ?
C31 C30 C34 120.6(4) . . ?
C29 C30 C34 118.2(4) . . ?
C30 C31 C32 117.8(4) . . ?
C30 C31 H31 121.1 . . ?
C32 C31 H31 121.1 . . ?
C31 C32 C33 120.7(4) . . ?
C31 C32 C35 121.4(4) . . ?
C33 C32 C35 118.0(4) . . ?
C32 C33 C28 122.6(4) . . ?
C32 C33 H33 118.7 . . ?
C28 C33 H33 118.7 . . ?
F3 C34 F2 108.0(4) . . ?
F3 C34 F1 105.5(4) . . ?
F2 C34 F1 105.1(4) . . ?
F3 C34 C30 113.0(4) . . ?
F2 C34 C30 112.2(4) . . ?
F1 C34 C30 112.5(4) . . ?
F6 C35 F5 107.2(4) . . ?
F6 C35 F4 105.3(4) . . ?
F5 C35 F4 106.0(4) . . ?
F6 C35 C32 112.8(4) . . ?
F5 C35 C32 113.5(4) . . ?
F4 C35 C32 111.4(4) . . ?
C37 C36 C41 115.1(4) . . ?
C37 C36 B2 124.3(4) . . ?
C41 C36 B2 120.2(4) . . ?
C38 C37 C36 122.6(4) . . ?
C38 C37 H37 118.7 . . ?
C36 C37 H37 118.7 . . ?
C39 C38 C37 121.2(4) . . ?
C39 C38 C42 119.1(4) . . ?
C37 C38 C42 119.6(4) . . ?
C38 C39 C40 117.9(4) . . ?
C38 C39 H39 121.0 . . ?
C40 C39 H39 121.0 . . ?
C41 C40 C39 120.5(4) . . ?
C41 C40 C43 119.7(4) . . ?
C39 C40 C43 119.7(4) . . ?
C40 C41 C36 122.7(4) . . ?
C40 C41 H41 118.7 . . ?
C36 C41 H41 118.7 . . ?
F12 C42 F11 107.6(4) . . ?
F12 C42 F10 106.1(4) . . ?
F11 C42 F10 104.6(4) . . ?
F12 C42 C38 113.4(4) . . ?
F11 C42 C38 113.0(4) . . ?
F10 C42 C38 111.6(4) . . ?
F9 C43 F7 106.7(6) . . ?
F9 C43 F8 106.3(5) . . ?
F7 C43 F8 104.5(5) . . ?
F9 C43 C40 113.1(4) . . ?
F7 C43 C40 112.5(4) . . ?
F8 C43 C40 113.0(4) . . ?
C45 C44 C49 115.1(4) . . ?
C45 C44 B2 122.7(4) . . ?
C49 C44 B2 122.0(4) . . ?
C46 C45 C44 122.7(4) . . ?
C46 C45 H45 118.6 . . ?
C44 C45 H45 118.6 . . ?
C47 C46 C45 120.6(4) . . ?
C47 C46 C51 120.2(4) . . ?
C45 C46 C51 119.2(4) . . ?
C48 C47 C46 117.9(4) . . ?
C48 C47 H47 121.0 . . ?
C46 C47 H47 121.0 . . ?
C47 C48 C49 121.0(4) . . ?
C47 C48 C50 119.6(4) . . ?
C49 C48 C50 119.3(4) . . ?
C48 C49 C44 122.6(4) . . ?
C48 C49 H49 118.7 . . ?
C44 C49 H49 118.7 . . ?
F14 C50 F13 110.9(6) . . ?
F14 C50 F15 104.9(6) . . ?
F13 C50 F15 101.6(5) . . ?
F14 C50 C48 115.3(5) . . ?
F13 C50 C48 112.0(5) . . ?
F15 C50 C48 111.2(5) . . ?
F17 C51 F18 105.6(5) . . ?
F17 C51 F16 107.8(5) . . ?
F18 C51 F16 105.4(5) . . ?
F17 C51 C46 111.8(4) . . ?
F18 C51 C46 112.6(4) . . ?
F16 C51 C46 113.0(4) . . ?
C57 C52 C53 115.3(4) . . ?
C57 C52 B2 121.1(4) . . ?
C53 C52 B2 123.1(4) . . ?
C54 C53 C52 122.6(4) . . ?
C54 C53 H53 118.7 . . ?
C52 C53 H53 118.7 . . ?
C53 C54 C55 121.1(4) . . ?
C53 C54 C59 119.5(4) . . ?
C55 C54 C59 119.4(4) . . ?
C54 C55 C56 117.9(4) . . ?
C54 C55 H55 121.0 . . ?
C56 C55 H55 121.0 . . ?
C55 C56 C57 120.6(4) . . ?
C55 C56 C58 120.7(4) . . ?
C57 C56 C58 118.7(4) . . ?
C56 C57 C52 122.5(4) . . ?
C56 C57 H57 118.7 . . ?
C52 C57 H57 118.7 . . ?
F22 C58 F23 107.8(5) . . ?
F22 C58 F24 105.2(4) . . ?
F23 C58 F24 105.4(4) . . ?
F22 C58 C56 113.4(4) . . ?
F23 C58 C56 112.7(4) . . ?
F24 C58 C56 111.8(4) . . ?
F21 C59 F20 106.1(4) . . ?
F21 C59 F19 106.9(5) . . ?
F20 C59 F19 105.3(5) . . ?
F21 C59 C54 113.6(4) . . ?
F20 C59 C54 113.1(4) . . ?
F19 C59 C54 111.3(4) . . ?
N5 B1 H1B 105(4) . . ?
N5 B1 H2B 112(3) . . ?
H1B B1 H2B 107(5) . . ?
N5 B1 H3B 110(4) . . ?
H1B B1 H3B 108(5) . . ?
H2B B1 H3B 115(5) . . ?
C52 B2 C28 111.0(4) . . ?
C52 B2 C44 113.6(4) . . ?
C28 B2 C44 104.5(4) . . ?
C52 B2 C36 103.3(4) . . ?
C28 B2 C36 111.6(4) . . ?
C44 B2 C36 113.1(4) . . ?
C1 N1 C2 110.0(4) . . ?
C1 N1 C8 126.6(4) . . ?
C2 N1 C8 123.3(4) . . ?
C1 N2 C3 111.1(4) . . ?
C1 N2 C4 120.8(4) . . ?
C3 N2 C4 128.0(4) . . ?
C12 N3 C14 109.6(4) . . ?
C12 N3 C15 127.9(4) . . ?
C14 N3 C15 122.4(4) . . ?
C12 N4 C13 109.8(4) . . ?
C12 N4 C19 131.7(4) . . ?
C13 N4 C19 117.9(4) . . ?
C27 N5 C23 118.7(4) . . ?
C27 N5 B1 121.4(4) . . ?
C23 N5 B1 119.9(4) . . ?
C12 Pt1 C5 88.02(18) . . ?
C12 Pt1 C1 168.38(18) . . ?
C5 Pt1 C1 80.52(19) . . ?
C12 Pt1 H1B 88(2) . . ?
C5 Pt1 H1B 174.5(18) . . ?
C1 Pt1 H1B 104(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 N2 -0.6(7) . . . . ?
C6 C4 C5 Pt1 162.9(9) . . . . ?
N2 C4 C5 Pt1 13.6(8) . . . . ?
C7 C4 C5 Pt1 -93.9(5) . . . . ?
N4 C13 C14 N3 0.8(7) . . . . ?
N5 C23 C24 C25 1.3(8) . . . . ?
C23 C24 C25 C26 -0.4(8) . . . . ?
C24 C25 C26 C27 -0.3(8) . . . . ?
C25 C26 C27 N5 0.2(8) . . . . ?
C33 C28 C29 C30 0.1(6) . . . . ?
B2 C28 C29 C30 -175.1(4) . . . . ?
C28 C29 C30 C31 -0.7(7) . . . . ?
C28 C29 C30 C34 -179.5(4) . . . . ?
C29 C30 C31 C32 0.5(7) . . . . ?
C34 C30 C31 C32 179.3(4) . . . . ?
C30 C31 C32 C33 0.2(6) . . . . ?
C30 C31 C32 C35 179.6(4) . . . . ?
C31 C32 C33 C28 -0.8(7) . . . . ?
C35 C32 C33 C28 179.7(4) . . . . ?
C29 C28 C33 C32 0.7(6) . . . . ?
B2 C28 C33 C32 175.7(4) . . . . ?
C31 C30 C34 F3 12.1(7) . . . . ?
C29 C30 C34 F3 -169.1(5) . . . . ?
C31 C30 C34 F2 -110.3(5) . . . . ?
C29 C30 C34 F2 68.5(6) . . . . ?
C31 C30 C34 F1 131.4(5) . . . . ?
C29 C30 C34 F1 -49.7(6) . . . . ?
C31 C32 C35 F6 132.0(4) . . . . ?
C33 C32 C35 F6 -48.5(6) . . . . ?
C31 C32 C35 F5 9.8(6) . . . . ?
C33 C32 C35 F5 -170.8(4) . . . . ?
C31 C32 C35 F4 -109.7(5) . . . . ?
C33 C32 C35 F4 69.7(5) . . . . ?
C41 C36 C37 C38 -0.9(6) . . . . ?
B2 C36 C37 C38 -173.4(4) . . . . ?
C36 C37 C38 C39 0.5(7) . . . . ?
C36 C37 C38 C42 177.1(4) . . . . ?
C37 C38 C39 C40 0.7(7) . . . . ?
C42 C38 C39 C40 -175.9(4) . . . . ?
C38 C39 C40 C41 -1.5(7) . . . . ?
C38 C39 C40 C43 178.1(4) . . . . ?
C39 C40 C41 C36 1.1(7) . . . . ?
C43 C40 C41 C36 -178.4(4) . . . . ?
C37 C36 C41 C40 0.1(6) . . . . ?
B2 C36 C41 C40 172.9(4) . . . . ?
C39 C38 C42 F12 -24.4(6) . . . . ?
C37 C38 C42 F12 159.0(4) . . . . ?
C39 C38 C42 F11 -147.2(4) . . . . ?
C37 C38 C42 F11 36.2(6) . . . . ?
C39 C38 C42 F10 95.3(5) . . . . ?
C37 C38 C42 F10 -81.4(5) . . . . ?
C41 C40 C43 F9 47.1(7) . . . . ?
C39 C40 C43 F9 -132.4(6) . . . . ?
C41 C40 C43 F7 -73.9(7) . . . . ?
C39 C40 C43 F7 106.5(6) . . . . ?
C41 C40 C43 F8 168.0(5) . . . . ?
C39 C40 C43 F8 -11.6(7) . . . . ?
C49 C44 C45 C46 2.0(6) . . . . ?
B2 C44 C45 C46 176.4(4) . . . . ?
C44 C45 C46 C47 0.2(7) . . . . ?
C44 C45 C46 C51 179.3(4) . . . . ?
C45 C46 C47 C48 -1.6(7) . . . . ?
C51 C46 C47 C48 179.3(5) . . . . ?
C46 C47 C48 C49 0.6(7) . . . . ?
C46 C47 C48 C50 177.7(5) . . . . ?
C47 C48 C49 C44 1.7(8) . . . . ?
C50 C48 C49 C44 -175.3(5) . . . . ?
C45 C44 C49 C48 -2.9(7) . . . . ?
B2 C44 C49 C48 -177.4(4) . . . . ?
C47 C48 C50 F14 -8.2(9) . . . . ?
C49 C48 C50 F14 168.9(7) . . . . ?
C47 C48 C50 F13 119.8(5) . . . . ?
C49 C48 C50 F13 -63.1(7) . . . . ?
C47 C48 C50 F15 -127.4(5) . . . . ?
C49 C48 C50 F15 49.7(7) . . . . ?
C47 C46 C51 F17 125.7(5) . . . . ?
C45 C46 C51 F17 -53.5(7) . . . . ?
C47 C46 C51 F18 -115.6(5) . . . . ?
C45 C46 C51 F18 65.3(6) . . . . ?
C47 C46 C51 F16 3.8(7) . . . . ?
C45 C46 C51 F16 -175.4(5) . . . . ?
C57 C52 C53 C54 -0.3(6) . . . . ?
B2 C52 C53 C54 171.8(4) . . . . ?
C52 C53 C54 C55 -0.5(7) . . . . ?
C52 C53 C54 C59 -177.8(4) . . . . ?
C53 C54 C55 C56 0.5(7) . . . . ?
C59 C54 C55 C56 177.8(4) . . . . ?
C54 C55 C56 C57 0.4(7) . . . . ?
C54 C55 C56 C58 -177.0(5) . . . . ?
C55 C56 C57 C52 -1.3(7) . . . . ?
C58 C56 C57 C52 176.1(5) . . . . ?
C53 C52 C57 C56 1.2(6) . . . . ?
B2 C52 C57 C56 -171.1(4) . . . . ?
C55 C56 C58 F22 -3.2(7) . . . . ?
C57 C56 C58 F22 179.4(5) . . . . ?
C55 C56 C58 F23 119.7(5) . . . . ?
C57 C56 C58 F23 -57.7(6) . . . . ?
C55 C56 C58 F24 -121.9(5) . . . . ?
C57 C56 C58 F24 60.8(6) . . . . ?
C53 C54 C59 F21 -172.0(5) . . . . ?
C55 C54 C59 F21 10.6(7) . . . . ?
C53 C54 C59 F20 -50.9(6) . . . . ?
C55 C54 C59 F20 131.7(5) . . . . ?
C53 C54 C59 F19 67.3(6) . . . . ?
C55 C54 C59 F19 -110.1(6) . . . . ?
C57 C52 B2 C28 -36.9(6) . . . . ?
C53 C52 B2 C28 151.5(4) . . . . ?
C57 C52 B2 C44 -154.3(4) . . . . ?
C53 C52 B2 C44 34.1(6) . . . . ?
C57 C52 B2 C36 82.8(5) . . . . ?
C53 C52 B2 C36 -88.8(5) . . . . ?
C33 C28 B2 C52 141.1(4) . . . . ?
C29 C28 B2 C52 -44.1(5) . . . . ?
C33 C28 B2 C44 -96.1(5) . . . . ?
C29 C28 B2 C44 78.7(5) . . . . ?
C33 C28 B2 C36 26.5(6) . . . . ?
C29 C28 B2 C36 -158.7(4) . . . . ?
C45 C44 B2 C52 33.7(6) . . . . ?
C49 C44 B2 C52 -152.3(4) . . . . ?
C45 C44 B2 C28 -87.5(5) . . . . ?
C49 C44 B2 C28 86.6(5) . . . . ?
C45 C44 B2 C36 151.0(4) . . . . ?
C49 C44 B2 C36 -34.9(6) . . . . ?
C37 C36 B2 C52 96.7(5) . . . . ?
C41 C36 B2 C52 -75.4(5) . . . . ?
C37 C36 B2 C28 -144.0(4) . . . . ?
C41 C36 B2 C28 43.9(5) . . . . ?
C37 C36 B2 C44 -26.5(6) . . . . ?
C41 C36 B2 C44 161.4(4) . . . . ?
N2 C1 N1 C2 0.7(6) . . . . ?
Pt1 C1 N1 C2 179.0(5) . . . . ?
N2 C1 N1 C8 177.9(6) . . . . ?
Pt1 C1 N1 C8 -3.9(10) . . . . ?
C3 C2 N1 C1 -0.1(7) . . . . ?
C3 C2 N1 C8 -177.3(6) . . . . ?
C11 C8 N1 C1 56.6(8) . . . . ?
C10 C8 N1 C1 -65.9(8) . . . . ?
C9 C8 N1 C1 174.2(7) . . . . ?
C11 C8 N1 C2 -126.6(6) . . . . ?
C10 C8 N1 C2 110.9(6) . . . . ?
C9 C8 N1 C2 -9.0(10) . . . . ?
N1 C1 N2 C3 -1.2(6) . . . . ?
Pt1 C1 N2 C3 -180.0(3) . . . . ?
N1 C1 N2 C4 -177.1(6) . . . . ?
Pt1 C1 N2 C4 4.1(7) . . . . ?
C2 C3 N2 C1 1.1(6) . . . . ?
C2 C3 N2 C4 176.8(6) . . . . ?
C6 C4 N2 C1 -163.0(9) . . . . ?
C5 C4 N2 C1 -11.7(9) . . . . ?
C7 C4 N2 C1 96.5(6) . . . . ?
C6 C4 N2 C3 21.8(13) . . . . ?
C5 C4 N2 C3 173.1(5) . . . . ?
C7 C4 N2 C3 -78.7(7) . . . . ?
N4 C12 N3 C14 -0.5(5) . . . . ?
Pt1 C12 N3 C14 -175.3(4) . . . . ?
N4 C12 N3 C15 -177.7(4) . . . . ?
Pt1 C12 N3 C15 7.5(7) . . . . ?
C13 C14 N3 C12 -0.2(7) . . . . ?
C13 C14 N3 C15 177.2(5) . . . . ?
C17 C15 N3 C12 60.5(6) . . . . ?
C16 C15 N3 C12 -61.2(6) . . . . ?
C18 C15 N3 C12 179.4(5) . . . . ?
C17 C15 N3 C14 -116.4(5) . . . . ?
C16 C15 N3 C14 121.9(5) . . . . ?
C18 C15 N3 C14 2.5(7) . . . . ?
N3 C12 N4 C13 1.0(5) . . . . ?
Pt1 C12 N4 C13 175.7(4) . . . . ?
N3 C12 N4 C19 171.9(5) . . . . ?
Pt1 C12 N4 C19 -13.4(7) . . . . ?
C14 C13 N4 C12 -1.2(7) . . . . ?
C14 C13 N4 C19 -173.5(5) . . . . ?
C20 C19 N4 C12 18.7(8) . . . . ?
C22 C19 N4 C12 -102.3(6) . . . . ?
C21 C19 N4 C12 138.2(5) . . . . ?
C20 C19 N4 C13 -171.0(5) . . . . ?
C22 C19 N4 C13 67.9(6) . . . . ?
C21 C19 N4 C13 -51.6(6) . . . . ?
C26 C27 N5 C23 0.6(8) . . . . ?
C26 C27 N5 B1 178.2(5) . . . . ?
C24 C23 N5 C27 -1.4(8) . . . . ?
C24 C23 N5 B1 -179.0(5) . . . . ?

_refine_diff_density_max         1.653
_refine_diff_density_min         -1.030
_refine_diff_density_rms         0.107

_shelxl_version_number           2014-3

