# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_BMM-7
_database_code_depnum_ccdc_archive 'CCDC 1496638'
_audit_update_record             
;
2016-07-29 deposited with the CCDC.
2016-09-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C28 H35 Eu N4 O12'
_chemical_formula_weight         771.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.4640(4)
_cell_length_b                   12.0162(5)
_cell_length_c                   13.1846(5)
_cell_angle_alpha                83.780(3)
_cell_angle_beta                 86.014(3)
_cell_angle_gamma                75.659(4)
_cell_volume                     1595.12(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    6929
_cell_measurement_theta_min      3.5920
_cell_measurement_theta_max      29.2580

_exptl_crystal_description       bulk
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             780
_exptl_absorpt_coefficient_mu    2.033
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8543
_exptl_absorpt_correction_T_max  0.9052
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            10687
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.32
_diffrn_reflns_theta_max         25.00
_reflns_number_total             5620
_reflns_number_gt                5158
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0244P)²+1.9393P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5620
_refine_ls_number_parameters     360
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0350
_refine_ls_R_factor_gt           0.0305
_refine_ls_wR_factor_ref         0.0697
_refine_ls_wR_factor_gt          0.0672
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.392681(17) 0.382137(14) -0.047577(13) 0.00679(7) Uani 1 1 d . . .
O9 O 0.2436(3) 0.4306(2) -0.1911(2) 0.0175(6) Uani 1 1 d . . .
O10 O 0.4659(3) 0.2323(2) -0.16468(19) 0.0158(6) Uani 1 1 d . . .
O2 O 0.1541(2) 0.3987(2) 0.02246(18) 0.0109(5) Uani 1 1 d . . .
O1 O 0.2899(2) 0.2273(2) 0.00797(19) 0.0126(6) Uani 1 1 d . . .
O7 O 0.3895(2) 0.3909(2) 0.13165(18) 0.0118(5) Uani 1 1 d . . .
O8 O 0.4547(2) 0.5496(2) 0.15731(18) 0.0112(5) Uani 1 1 d . . .
O3 O -0.3333(2) 0.4201(2) 0.04289(18) 0.0114(5) Uani 1 1 d . . .
O4 O -0.3993(2) 0.2656(2) 0.00839(18) 0.0111(5) Uani 1 1 d . . .
O6 O 0.3522(3) 0.1119(2) 0.4302(2) 0.0285(7) Uani 1 1 d . . .
H6A H 0.3302 0.0546 0.4621 0.034 Uiso 1 1 calc R . .
O5 O 0.3483(4) 0.1669(3) 0.5870(2) 0.0353(8) Uani 1 1 d . . .
N1 N 0.0637(3) 0.4949(3) -0.2874(2) 0.0183(7) Uani 1 1 d . . .
N2 N 0.4524(4) 0.0516(3) -0.1878(3) 0.0364(6) Uani 1 1 d U . .
C21 C 0.3810(5) -0.0244(4) -0.2247(4) 0.0364(6) Uani 1 1 d U . .
H21A H 0.2929 0.0202 -0.2440 0.055 Uiso 1 1 calc R . .
H21B H 0.3727 -0.0852 -0.1706 0.055 Uiso 1 1 calc R . .
H21C H 0.4293 -0.0593 -0.2843 0.055 Uiso 1 1 calc R . .
C9 C 0.4796(4) 0.4614(3) 0.4671(3) 0.0120(8) Uani 1 1 d . . .
C14 C 0.4709(4) 0.4894(3) 0.3615(3) 0.0117(8) Uani 1 1 d . . .
H14 H 0.4922 0.5585 0.3315 0.014 Uiso 1 1 calc R . .
C22 C 0.5865(5) -0.0020(4) -0.1600(4) 0.0364(6) Uani 1 1 d U . .
H22A H 0.6197 0.0506 -0.1228 0.055 Uiso 1 1 calc R . .
H22B H 0.6424 -0.0190 -0.2219 0.055 Uiso 1 1 calc R . .
H22C H 0.5884 -0.0738 -0.1165 0.055 Uiso 1 1 calc R . .
C17 C 0.1235(4) 0.4728(3) -0.2000(3) 0.0155(8) Uani 1 1 d . . .
H17 H 0.0708 0.4905 -0.1395 0.019 Uiso 1 1 calc R . .
C20 C 0.4062(4) 0.1627(3) -0.1894(3) 0.0154(8) Uani 1 1 d . . .
H20 H 0.3188 0.1934 -0.2114 0.019 Uiso 1 1 calc R . .
C18 C -0.0778(4) 0.5447(4) -0.2923(3) 0.0293(10) Uani 1 1 d . . .
H18A H -0.1152 0.5613 -0.2238 0.044 Uiso 1 1 calc R . .
H18B H -0.1198 0.4899 -0.3186 0.044 Uiso 1 1 calc R . .
H18C H -0.0936 0.6163 -0.3379 0.044 Uiso 1 1 calc R . .
C19 C 0.1367(4) 0.4662(4) -0.3835(3) 0.0293(11) Uani 1 1 d . . .
H19A H 0.2306 0.4353 -0.3707 0.044 Uiso 1 1 calc R . .
H19B H 0.1257 0.5358 -0.4314 0.044 Uiso 1 1 calc R . .
H19C H 0.1028 0.4083 -0.4128 0.044 Uiso 1 1 calc R . .
C7 C 0.1748(3) 0.2918(3) 0.0188(3) 0.0097(3) Uani 1 1 d . . .
C16 C 0.4251(3) 0.4550(3) 0.1870(3) 0.0112(8) Uani 1 1 d . . .
C3 C 0.0606(3) 0.2360(3) 0.0207(3) 0.0097(3) Uani 1 1 d . . .
C12 C 0.3988(4) 0.3175(3) 0.3409(3) 0.0120(8) Uani 1 1 d . . .
H12 H 0.3717 0.2693 0.2984 0.014 Uiso 1 1 calc R . .
C10 C 0.4460(4) 0.3589(3) 0.5076(3) 0.0148(8) Uani 1 1 d . . .
H10 H 0.4507 0.3372 0.5790 0.018 Uiso 1 1 calc R . .
C4 C -0.0682(3) 0.3019(3) 0.0251(3) 0.0097(3) Uani 1 1 d . . .
H4 H -0.0863 0.3827 0.0301 0.012 Uiso 1 1 calc R . .
C2 C 0.0871(4) 0.1182(3) 0.0119(3) 0.0097(3) Uani 1 1 d . . .
H2 H 0.1761 0.0744 0.0097 0.012 Uiso 1 1 calc R . .
C8 C -0.3116(3) 0.3162(3) 0.0253(3) 0.0097(3) Uani 1 1 d . . .
C6 C -0.1442(3) 0.1299(3) 0.0127(3) 0.0097(3) Uani 1 1 d . . .
H6 H -0.2156 0.0945 0.0106 0.012 Uiso 1 1 calc R . .
C13 C 0.4320(3) 0.4188(3) 0.2997(3) 0.0112(8) Uani 1 1 d . . .
C1 C -0.0144(3) 0.0626(3) 0.0062(3) 0.0097(3) Uani 1 1 d . . .
C5 C -0.1703(3) 0.2476(3) 0.0221(3) 0.0097(3) Uani 1 1 d . . .
C11 C 0.4063(4) 0.2885(3) 0.4458(3) 0.0143(8) Uani 1 1 d . . .
C15 C 0.3666(4) 0.1830(3) 0.4957(3) 0.0217(9) Uani 1 1 d . . .
O11 O 0.0211(4) 0.7433(3) 0.4779(3) 0.0464(9) Uani 1 1 d . . .
N3 N 0.1151(4) 0.7710(3) 0.3192(3) 0.0342(10) Uani 1 1 d . . .
C23 C 0.1173(5) 0.7472(4) 0.4207(3) 0.0313(11) Uani 1 1 d . . .
H23 H 0.2005 0.7322 0.4508 0.038 Uiso 1 1 calc R . .
C25 C 0.2353(6) 0.7778(6) 0.2587(4) 0.071(2) Uani 1 1 d . . .
H25A H 0.3078 0.7697 0.3043 0.107 Uiso 1 1 calc R . .
H25B H 0.2214 0.8526 0.2178 0.107 Uiso 1 1 calc R . .
H25C H 0.2576 0.7157 0.2133 0.107 Uiso 1 1 calc R . .
C24 C -0.0056(6) 0.7910(5) 0.2662(4) 0.0444(14) Uani 1 1 d . . .
H24A H -0.0791 0.7880 0.3158 0.067 Uiso 1 1 calc R . .
H24B H 0.0025 0.7315 0.2192 0.067 Uiso 1 1 calc R . .
H24C H -0.0222 0.8672 0.2274 0.067 Uiso 1 1 calc R . .
N12 N 0.1333(4) -0.1230(3) 0.6431(3) 0.0258(9) Uani 1 1 d . . .
C27 C 0.2174(5) -0.2364(4) 0.6712(4) 0.0324(11) Uani 1 1 d . . .
H27A H 0.1787 -0.2957 0.6494 0.049 Uiso 1 1 calc R . .
H27B H 0.2253 -0.2477 0.7455 0.049 Uiso 1 1 calc R . .
H27C H 0.3052 -0.2422 0.6378 0.049 Uiso 1 1 calc R . .
C28 C -0.0010(5) -0.0982(5) 0.6878(4) 0.0444(14) Uani 1 1 d . . .
H28A H -0.0474 -0.0193 0.6640 0.067 Uiso 1 1 calc R . .
H28B H 0.0018 -0.1058 0.7624 0.067 Uiso 1 1 calc R . .
H28C H -0.0476 -0.1528 0.6669 0.067 Uiso 1 1 calc R . .
O12 O 0.2797(3) -0.0695(3) 0.5244(2) 0.0320(8) Uani 1 1 d . . .
C26 C 0.1729(5) -0.0497(4) 0.5724(3) 0.0268(10) Uani 1 1 d . . .
H26 H 0.1141 0.0236 0.5579 0.032 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.309(2) 2_565 ?
Eu1 O8 2.321(2) 2_665 ?
Eu1 O7 2.374(2) . ?
Eu1 O4 2.394(2) 1_655 ?
Eu1 O1 2.397(2) . ?
Eu1 O10 2.443(2) . ?
Eu1 O9 2.465(3) . ?
Eu1 O2 2.569(2) . ?
Eu1 C7 2.808(3) . ?
Eu1 C8 3.188(4) 1_655 ?
Eu1 Eu1 4.3537(4) 2_665 ?
O9 C17 1.242(5) . ?
O10 C20 1.242(4) . ?
O2 C7 1.254(4) . ?
O1 C7 1.269(4) . ?
O7 C16 1.251(4) . ?
O8 C16 1.265(4) . ?
O8 Eu1 2.321(2) 2_665 ?
O3 C8 1.257(4) . ?
O3 Eu1 2.309(2) 2_565 ?
O4 C8 1.263(4) . ?
O4 Eu1 2.394(2) 1_455 ?
O6 C15 1.319(5) . ?
O6 H6A 0.8400 . ?
O5 C15 1.208(5) . ?
N1 C17 1.320(5) . ?
N1 C18 1.456(5) . ?
N1 C19 1.462(5) . ?
N2 C20 1.301(5) . ?
N2 C22 1.446(6) . ?
N2 C21 1.453(6) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C9 C14 1.401(5) . ?
C9 C10 1.404(5) . ?
C9 C9 1.490(7) 2_666 ?
C14 C13 1.384(5) . ?
C14 H14 0.9500 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C17 H17 0.9500 . ?
C20 H20 0.9500 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C7 C3 1.506(5) . ?
C16 C13 1.505(5) . ?
C3 C4 1.385(5) . ?
C3 C2 1.390(5) . ?
C12 C13 1.392(5) . ?
C12 C11 1.392(5) . ?
C12 H12 0.9500 . ?
C10 C11 1.386(5) . ?
C10 H10 0.9500 . ?
C4 C5 1.387(5) . ?
C4 H4 0.9500 . ?
C2 C1 1.398(5) . ?
C2 H2 0.9500 . ?
C8 C5 1.504(5) . ?
C8 Eu1 3.188(4) 1_455 ?
C6 C5 1.390(5) . ?
C6 C1 1.400(5) . ?
C6 H6 0.9500 . ?
C1 C1 1.484(7) 2 ?
C11 C15 1.501(5) . ?
O11 C23 1.222(5) . ?
N3 C23 1.339(6) . ?
N3 C24 1.441(7) . ?
N3 C25 1.457(7) . ?
C23 H23 0.9500 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
N12 C26 1.329(5) . ?
N12 C27 1.453(6) . ?
N12 C28 1.458(6) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
O12 C26 1.229(5) . ?
C26 H26 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O8 75.03(8) 2_565 2_665 ?
O3 Eu1 O7 80.68(8) 2_565 . ?
O8 Eu1 O7 121.64(8) 2_665 . ?
O3 Eu1 O4 122.60(8) 2_565 1_655 ?
O8 Eu1 O4 76.50(8) 2_665 1_655 ?
O7 Eu1 O4 73.67(8) . 1_655 ?
O3 Eu1 O1 135.03(8) 2_565 . ?
O8 Eu1 O1 147.92(8) 2_665 . ?
O7 Eu1 O1 80.79(8) . . ?
O4 Eu1 O1 90.31(8) 1_655 . ?
O3 Eu1 O10 142.27(8) 2_565 . ?
O8 Eu1 O10 76.53(8) 2_665 . ?
O7 Eu1 O10 136.09(9) . . ?
O4 Eu1 O10 73.01(9) 1_655 . ?
O1 Eu1 O10 71.63(8) . . ?
O3 Eu1 O9 81.70(9) 2_565 . ?
O8 Eu1 O9 86.75(9) 2_665 . ?
O7 Eu1 O9 140.69(8) . . ?
O4 Eu1 O9 144.19(8) 1_655 . ?
O1 Eu1 O9 87.46(9) . . ?
O10 Eu1 O9 72.39(9) . . ?
O3 Eu1 O2 82.54(8) 2_565 . ?
O8 Eu1 O2 150.40(8) 2_665 . ?
O7 Eu1 O2 72.16(8) . . ?
O4 Eu1 O2 132.71(8) 1_655 . ?
O1 Eu1 O2 52.79(8) . . ?
O10 Eu1 O2 112.91(8) . . ?
O9 Eu1 O2 70.89(8) . . ?
O3 Eu1 C7 109.01(9) 2_565 . ?
O8 Eu1 C7 159.79(10) 2_665 . ?
O7 Eu1 C7 78.45(9) . . ?
O4 Eu1 C7 114.58(9) 1_655 . ?
O1 Eu1 C7 26.75(9) . . ?
O10 Eu1 C7 90.27(9) . . ?
O9 Eu1 C7 74.57(9) . . ?
O2 Eu1 C7 26.49(9) . . ?
O3 Eu1 C8 102.47(9) 2_565 1_655 ?
O8 Eu1 C8 64.19(9) 2_665 1_655 ?
O7 Eu1 C8 70.82(8) . 1_655 ?
O4 Eu1 C8 20.48(8) 1_655 1_655 ?
O1 Eu1 C8 109.39(9) . 1_655 ?
O10 Eu1 C8 86.70(9) . 1_655 ?
O9 Eu1 C8 147.74(8) . 1_655 ?
O2 Eu1 C8 141.18(8) . 1_655 ?
C7 Eu1 C8 131.15(9) . 1_655 ?
O3 Eu1 Eu1 48.99(6) 2_565 2_665 ?
O8 Eu1 Eu1 58.67(6) 2_665 2_665 ?
O7 Eu1 Eu1 65.24(6) . 2_665 ?
O4 Eu1 Eu1 73.62(6) 1_655 2_665 ?
O1 Eu1 Eu1 145.18(6) . 2_665 ?
O10 Eu1 Eu1 128.86(6) . 2_665 ?
O9 Eu1 Eu1 123.55(6) . 2_665 ?
O2 Eu1 Eu1 118.23(5) . 2_665 ?
C7 Eu1 Eu1 139.10(7) . 2_665 ?
C8 Eu1 Eu1 53.54(6) 1_655 2_665 ?
C17 O9 Eu1 135.1(2) . . ?
C20 O10 Eu1 128.8(2) . . ?
C7 O2 Eu1 87.45(19) . . ?
C7 O1 Eu1 95.0(2) . . ?
C16 O7 Eu1 133.9(2) . . ?
C16 O8 Eu1 139.0(2) . 2_665 ?
C8 O3 Eu1 169.6(2) . 2_565 ?
C8 O4 Eu1 117.9(2) . 1_455 ?
C15 O6 H6A 109.5 . . ?
C17 N1 C18 121.9(3) . . ?
C17 N1 C19 121.0(3) . . ?
C18 N1 C19 117.1(3) . . ?
C20 N2 C22 120.8(4) . . ?
C20 N2 C21 123.2(4) . . ?
C22 N2 C21 115.6(4) . . ?
N2 C21 H21A 109.5 . . ?
N2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
N2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C14 C9 C10 117.0(3) . . ?
C14 C9 C9 121.0(4) . 2_666 ?
C10 C9 C9 122.0(4) . 2_666 ?
C13 C14 C9 121.5(3) . . ?
C13 C14 H14 119.3 . . ?
C9 C14 H14 119.3 . . ?
N2 C22 H22A 109.5 . . ?
N2 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N2 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
O9 C17 N1 124.7(4) . . ?
O9 C17 H17 117.6 . . ?
N1 C17 H17 117.6 . . ?
O10 C20 N2 125.9(4) . . ?
O10 C20 H20 117.1 . . ?
N2 C20 H20 117.1 . . ?
N1 C18 H18A 109.5 . . ?
N1 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N1 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N1 C19 H19A 109.5 . . ?
N1 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
N1 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
O2 C7 O1 122.6(3) . . ?
O2 C7 C3 120.2(3) . . ?
O1 C7 C3 117.1(3) . . ?
O2 C7 Eu1 66.05(17) . . ?
O1 C7 Eu1 58.23(17) . . ?
C3 C7 Eu1 162.4(2) . . ?
O7 C16 O8 126.0(3) . . ?
O7 C16 C13 117.9(3) . . ?
O8 C16 C13 116.0(3) . . ?
C4 C3 C2 120.7(3) . . ?
C4 C3 C7 120.6(3) . . ?
C2 C3 C7 118.6(3) . . ?
C13 C12 C11 118.3(3) . . ?
C13 C12 H12 120.8 . . ?
C11 C12 H12 120.8 . . ?
C11 C10 C9 121.5(3) . . ?
C11 C10 H10 119.3 . . ?
C9 C10 H10 119.3 . . ?
C3 C4 C5 118.6(3) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
C3 C2 C1 121.4(3) . . ?
C3 C2 H2 119.3 . . ?
C1 C2 H2 119.3 . . ?
O3 C8 O4 124.9(3) . . ?
O3 C8 C5 117.5(3) . . ?
O4 C8 C5 117.6(3) . . ?
O3 C8 Eu1 85.4(2) . 1_455 ?
O4 C8 Eu1 41.57(16) . 1_455 ?
C5 C8 Eu1 153.0(2) . 1_455 ?
C5 C6 C1 121.1(3) . . ?
C5 C6 H6 119.4 . . ?
C1 C6 H6 119.4 . . ?
C14 C13 C12 121.0(3) . . ?
C14 C13 C16 118.3(3) . . ?
C12 C13 C16 120.8(3) . . ?
C2 C1 C6 117.3(3) . . ?
C2 C1 C1 121.3(4) . 2 ?
C6 C1 C1 121.5(4) . 2 ?
C4 C5 C6 120.9(3) . . ?
C4 C5 C8 120.4(3) . . ?
C6 C5 C8 118.7(3) . . ?
C10 C11 C12 120.7(3) . . ?
C10 C11 C15 118.2(3) . . ?
C12 C11 C15 121.1(3) . . ?
O5 C15 O6 124.0(4) . . ?
O5 C15 C11 122.5(4) . . ?
O6 C15 C11 113.5(3) . . ?
C23 N3 C24 121.4(4) . . ?
C23 N3 C25 120.8(5) . . ?
C24 N3 C25 117.8(4) . . ?
O11 C23 N3 125.4(5) . . ?
O11 C23 H23 117.3 . . ?
N3 C23 H23 117.3 . . ?
N3 C25 H25A 109.5 . . ?
N3 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
N3 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N3 C24 H24A 109.5 . . ?
N3 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
N3 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 N12 C27 121.3(4) . . ?
C26 N12 C28 121.4(4) . . ?
C27 N12 C28 117.0(4) . . ?
N12 C27 H27A 109.5 . . ?
N12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N12 C28 H28A 109.5 . . ?
N12 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
N12 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
O12 C26 N12 125.0(4) . . ?
O12 C26 H26 117.5 . . ?
N12 C26 H26 117.5 . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.360
_refine_diff_density_min         -2.484
_refine_diff_density_rms         0.116
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_BMM-7-Squeezed
_database_code_depnum_ccdc_archive 'CCDC 1496639'
_audit_update_record             
;
2016-07-29 deposited with the CCDC.
2016-09-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H20 Eu N2 O10'
_chemical_formula_weight         624.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.4702(4)
_cell_length_b                   12.0131(5)
_cell_length_c                   13.1765(6)
_cell_angle_alpha                83.827(4)
_cell_angle_beta                 85.920(4)
_cell_angle_gamma                75.686(4)
_cell_volume                     1594.86(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    6929
_cell_measurement_theta_min      3.5920
_cell_measurement_theta_max      29.2580

_exptl_crystal_description       bulk
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.300
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             618
_exptl_absorpt_coefficient_mu    14.469
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  0.5953
_exptl_absorpt_correction_T_max  0.6707
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11070
_diffrn_reflns_av_R_equivalents  0.0312
_diffrn_reflns_av_sigmaI/netI    0.0422
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.38
_diffrn_reflns_theta_max         64.98
_reflns_number_total             5420
_reflns_number_gt                5127
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0380P)²+1.2350P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5420
_refine_ls_number_parameters     320
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0292
_refine_ls_R_factor_gt           0.0278
_refine_ls_wR_factor_ref         0.0731
_refine_ls_wR_factor_gt          0.0725
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

# SQUEEZE RESULTS (APPEND TO CIF)
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.000 0.500 0.000 569.5 124.9
_platon_squeeze_details          
;
;

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.392782(16) 0.882203(14) 0.452224(13) 0.00364(7) Uani 1 1 d . . .
O5 O 0.5462(2) 0.95002(19) 0.34285(17) 0.0095(5) Uani 1 1 d . . .
O6 O 0.6106(2) 1.10937(19) 0.36839(16) 0.0102(5) Uani 1 1 d . . .
O2 O 0.1540(2) 0.89927(18) 0.52222(17) 0.0099(5) Uani 1 1 d . . .
O3 O -0.3332(2) 0.92010(18) 0.54321(17) 0.0112(5) Uani 1 1 d . . .
O1 O 0.2899(2) 0.72722(18) 0.50723(18) 0.0110(5) Uani 1 1 d . . .
O10 O 0.4664(2) 0.7325(2) 0.33462(18) 0.0152(5) Uani 1 1 d . . .
O9 O 0.2431(2) 0.9304(2) 0.30775(18) 0.0152(5) Uani 1 1 d . . .
O8 O 0.6480(3) 1.3891(2) 0.06973(19) 0.0252(6) Uani 1 1 d . . .
O7 O 0.6517(3) 1.3334(2) -0.0873(2) 0.0324(7) Uani 1 1 d . . .
C17 C 0.1243(4) 0.9729(3) 0.3003(3) 0.0143(7) Uani 1 1 d . . .
H17 H 0.0723 0.9910 0.3612 0.017 Uiso 1 1 calc R . .
C7 C 0.1747(3) 0.7912(3) 0.5183(2) 0.0085(7) Uani 1 1 d . . .
N1 N 0.0640(3) 0.9951(3) 0.2125(2) 0.0174(6) Uani 1 1 d . . .
C11 C 0.5687(3) 1.0806(3) 0.2005(2) 0.0093(7) Uani 1 1 d . . .
C15 C 0.5759(3) 1.0441(3) 0.3134(2) 0.0084(7) Uani 1 1 d . . .
C9 C 0.5205(3) 1.0380(3) 0.0332(3) 0.0116(7) Uani 1 1 d . . .
C12 C 0.6012(3) 1.1819(3) 0.1592(2) 0.0112(7) Uani 1 1 d . . .
H12 H 0.6280 1.2300 0.2019 0.013 Uiso 1 1 calc R . .
N2 N 0.4526(3) 0.5514(3) 0.3114(2) 0.0241(7) Uani 1 1 d . . .
C3 C 0.0605(3) 0.7361(3) 0.5206(2) 0.0090(7) Uani 1 1 d . . .
C14 C 0.5542(4) 1.1412(3) -0.0076(3) 0.0146(7) Uani 1 1 d . . .
H14 H 0.5498 1.1627 -0.0790 0.018 Uiso 1 1 calc R . .
C10 C 0.5288(3) 1.0107(3) 0.1383(3) 0.0112(7) Uani 1 1 d . . .
H10 H 0.5065 0.9420 0.1683 0.013 Uiso 1 1 calc R . .
C21 C 0.3801(5) 0.4764(3) 0.2753(3) 0.0271(9) Uani 1 1 d . . .
H21A H 0.2908 0.5208 0.2594 0.041 Uiso 1 1 calc R . .
H21B H 0.3750 0.4138 0.3285 0.041 Uiso 1 1 calc R . .
H21C H 0.4254 0.4437 0.2137 0.041 Uiso 1 1 calc R . .
C20 C 0.4063(4) 0.6630(3) 0.3098(3) 0.0145(7) Uani 1 1 d . . .
H20 H 0.3190 0.6937 0.2879 0.017 Uiso 1 1 calc R . .
C13 C 0.5938(3) 1.2121(3) 0.0543(3) 0.0130(7) Uani 1 1 d . . .
C16 C 0.6337(4) 1.3172(3) 0.0041(3) 0.0188(8) Uani 1 1 d . . .
C18 C 0.1360(4) 0.9665(4) 0.1163(3) 0.0280(9) Uani 1 1 d . . .
H18A H 0.2306 0.9396 0.1280 0.042 Uiso 1 1 calc R . .
H18B H 0.1208 1.0352 0.0672 0.042 Uiso 1 1 calc R . .
H18C H 0.1052 0.9055 0.0892 0.042 Uiso 1 1 calc R . .
C19 C -0.0773(4) 1.0435(4) 0.2084(3) 0.0279(9) Uani 1 1 d . . .
H19A H -0.1142 1.0615 0.2768 0.042 Uiso 1 1 calc R . .
H19B H -0.1190 0.9875 0.1838 0.042 Uiso 1 1 calc R . .
H19C H -0.0942 1.1143 0.1617 0.042 Uiso 1 1 calc R . .
O4 O -0.3987(2) 0.76483(18) 0.50828(17) 0.0102(5) Uani 1 1 d . . .
C5 C -0.1713(3) 0.7473(3) 0.5222(2) 0.0072(6) Uani 1 1 d . . .
C4 C -0.0687(3) 0.8025(3) 0.5251(2) 0.0092(7) Uani 1 1 d . . .
H4 H -0.0869 0.8832 0.5300 0.011 Uiso 1 1 calc R . .
C8 C -0.3121(3) 0.8156(3) 0.5250(2) 0.0085(7) Uani 1 1 d . . .
C2 C 0.0861(3) 0.6186(3) 0.5114(2) 0.0096(7) Uani 1 1 d . . .
H2 H 0.1751 0.5750 0.5085 0.012 Uiso 1 1 calc R . .
C1 C -0.0141(3) 0.5630(3) 0.5064(2) 0.0093(7) Uani 1 1 d . . .
C6 C -0.1440(3) 0.6298(3) 0.5129(2) 0.0080(6) Uani 1 1 d . . .
H6 H -0.2149 0.5938 0.5109 0.010 Uiso 1 1 calc R . .
C22 C 0.5864(7) 0.4973(5) 0.3405(6) 0.084(3) Uani 1 1 d . . .
H22A H 0.6449 0.4872 0.2790 0.126 Uiso 1 1 calc R . .
H22B H 0.5888 0.4218 0.3779 0.126 Uiso 1 1 calc R . .
H22C H 0.6159 0.5462 0.3842 0.126 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.308(2) 2_576 ?
Eu1 O5 2.321(2) . ?
Eu1 O6 2.374(2) 2_676 ?
Eu1 O1 2.397(2) . ?
Eu1 O4 2.405(2) 1_655 ?
Eu1 O10 2.444(2) . ?
Eu1 O9 2.481(2) . ?
Eu1 O2 2.570(2) . ?
Eu1 C7 2.813(3) . ?
Eu1 C8 3.185(3) 1_655 ?
Eu1 Eu1 4.3528(4) 2_676 ?
O5 C15 1.260(4) . ?
O6 C15 1.254(4) . ?
O6 Eu1 2.374(2) 2_676 ?
O2 C7 1.268(4) . ?
O3 C8 1.266(4) . ?
O3 Eu1 2.308(2) 2_576 ?
O1 C7 1.268(4) . ?
O10 C20 1.244(4) . ?
O9 C17 1.229(4) . ?
O8 C16 1.325(4) . ?
O7 C16 1.208(4) . ?
C17 N1 1.328(4) . ?
C17 H17 0.9500 . ?
C7 C3 1.501(4) . ?
N1 C19 1.453(5) . ?
N1 C18 1.456(5) . ?
C11 C10 1.386(5) . ?
C11 C12 1.389(5) . ?
C11 C15 1.507(4) . ?
C9 C10 1.393(5) . ?
C9 C14 1.413(5) . ?
C9 C9 1.485(7) 2_675 ?
C12 C13 1.393(5) . ?
C12 H12 0.9500 . ?
N2 C20 1.306(5) . ?
N2 C21 1.449(5) . ?
N2 C22 1.451(6) . ?
C3 C2 1.387(5) . ?
C3 C4 1.391(5) . ?
C14 C13 1.391(5) . ?
C14 H14 0.9500 . ?
C10 H10 0.9500 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C20 H20 0.9500 . ?
C13 C16 1.499(5) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
O4 C8 1.254(4) . ?
O4 Eu1 2.405(2) 1_455 ?
C5 C6 1.386(4) . ?
C5 C4 1.399(5) . ?
C5 C8 1.499(4) . ?
C4 H4 0.9500 . ?
C8 Eu1 3.185(3) 1_455 ?
C2 C1 1.385(5) . ?
C2 H2 0.9500 . ?
C1 C6 1.399(5) . ?
C1 C1 1.496(6) 2_566 ?
C6 H6 0.9500 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O5 75.17(8) 2_576 . ?
O3 Eu1 O6 80.89(8) 2_576 2_676 ?
O5 Eu1 O6 121.54(8) . 2_676 ?
O3 Eu1 O1 135.06(8) 2_576 . ?
O5 Eu1 O1 147.74(8) . . ?
O6 Eu1 O1 80.86(8) 2_676 . ?
O3 Eu1 O4 122.86(8) 2_576 1_655 ?
O5 Eu1 O4 76.35(8) . 1_655 ?
O6 Eu1 O4 73.64(8) 2_676 1_655 ?
O1 Eu1 O4 90.23(7) . 1_655 ?
O3 Eu1 O10 142.10(8) 2_576 . ?
O5 Eu1 O10 76.41(8) . . ?
O6 Eu1 O10 136.04(8) 2_676 . ?
O1 Eu1 O10 71.60(8) . . ?
O4 Eu1 O10 72.92(8) 1_655 . ?
O3 Eu1 O9 81.71(8) 2_576 . ?
O5 Eu1 O9 87.02(8) . . ?
O6 Eu1 O9 140.77(8) 2_676 . ?
O1 Eu1 O9 87.22(8) . . ?
O4 Eu1 O9 144.04(8) 1_655 . ?
O10 Eu1 O9 72.26(8) . . ?
O3 Eu1 O2 82.36(7) 2_576 . ?
O5 Eu1 O2 150.48(7) . . ?
O6 Eu1 O2 72.21(7) 2_676 . ?
O1 Eu1 O2 52.97(7) . . ?
O4 Eu1 O2 132.77(7) 1_655 . ?
O10 Eu1 O2 113.05(7) . . ?
O9 Eu1 O2 70.81(7) . . ?
O3 Eu1 C7 109.09(9) 2_576 . ?
O5 Eu1 C7 159.82(8) . . ?
O6 Eu1 C7 78.55(8) 2_676 . ?
O1 Eu1 C7 26.67(8) . . ?
O4 Eu1 C7 114.44(8) 1_655 . ?
O10 Eu1 C7 90.19(9) . . ?
O9 Eu1 C7 74.42(8) . . ?
O2 Eu1 C7 26.76(8) . . ?
O3 Eu1 C8 102.76(8) 2_576 1_655 ?
O5 Eu1 C8 64.04(8) . 1_655 ?
O6 Eu1 C8 70.82(8) 2_676 1_655 ?
O1 Eu1 C8 109.30(8) . 1_655 ?
O4 Eu1 C8 20.45(8) 1_655 1_655 ?
O10 Eu1 C8 86.55(8) . 1_655 ?
O9 Eu1 C8 147.74(8) . 1_655 ?
O2 Eu1 C8 141.24(7) . 1_655 ?
C7 Eu1 C8 131.04(8) . 1_655 ?
O3 Eu1 Eu1 49.14(6) 2_576 2_676 ?
O5 Eu1 Eu1 58.63(5) . 2_676 ?
O6 Eu1 Eu1 65.28(5) 2_676 2_676 ?
O1 Eu1 Eu1 145.29(6) . 2_676 ?
O4 Eu1 Eu1 73.73(5) 1_655 2_676 ?
O10 Eu1 Eu1 128.79(6) . 2_676 ?
O9 Eu1 Eu1 123.73(6) . 2_676 ?
O2 Eu1 Eu1 118.15(5) . 2_676 ?
C7 Eu1 Eu1 139.25(6) . 2_676 ?
C8 Eu1 Eu1 53.68(6) 1_655 2_676 ?
C15 O5 Eu1 139.0(2) . . ?
C15 O6 Eu1 133.5(2) . 2_676 ?
C7 O2 Eu1 87.37(18) . . ?
C8 O3 Eu1 169.0(2) . 2_576 ?
C7 O1 Eu1 95.30(18) . . ?
C20 O10 Eu1 128.6(2) . . ?
C17 O9 Eu1 134.2(2) . . ?
O9 C17 N1 124.0(3) . . ?
O9 C17 H17 118.0 . . ?
N1 C17 H17 118.0 . . ?
O1 C7 O2 122.2(3) . . ?
O1 C7 C3 117.7(3) . . ?
O2 C7 C3 120.0(3) . . ?
O1 C7 Eu1 58.03(16) . . ?
O2 C7 Eu1 65.87(17) . . ?
C3 C7 Eu1 162.9(2) . . ?
C17 N1 C19 121.7(3) . . ?
C17 N1 C18 121.3(3) . . ?
C19 N1 C18 117.0(3) . . ?
C10 C11 C12 120.5(3) . . ?
C10 C11 C15 118.5(3) . . ?
C12 C11 C15 121.0(3) . . ?
O6 C15 O5 126.6(3) . . ?
O6 C15 C11 117.4(3) . . ?
O5 C15 C11 116.0(3) . . ?
C10 C9 C14 116.8(3) . . ?
C10 C9 C9 121.7(4) . 2_675 ?
C14 C9 C9 121.5(4) . 2_675 ?
C11 C12 C13 119.1(3) . . ?
C11 C12 H12 120.4 . . ?
C13 C12 H12 120.4 . . ?
C20 N2 C21 122.7(3) . . ?
C20 N2 C22 121.0(4) . . ?
C21 N2 C22 116.0(4) . . ?
C2 C3 C4 120.4(3) . . ?
C2 C3 C7 118.7(3) . . ?
C4 C3 C7 120.7(3) . . ?
C13 C14 C9 121.6(3) . . ?
C13 C14 H14 119.2 . . ?
C9 C14 H14 119.2 . . ?
C11 C10 C9 121.9(3) . . ?
C11 C10 H10 119.0 . . ?
C9 C10 H10 119.0 . . ?
N2 C21 H21A 109.5 . . ?
N2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
N2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
O10 C20 N2 125.7(3) . . ?
O10 C20 H20 117.1 . . ?
N2 C20 H20 117.1 . . ?
C14 C13 C12 120.0(3) . . ?
C14 C13 C16 118.1(3) . . ?
C12 C13 C16 121.8(3) . . ?
O7 C16 O8 123.9(3) . . ?
O7 C16 C13 122.6(3) . . ?
O8 C16 C13 113.5(3) . . ?
N1 C18 H18A 109.5 . . ?
N1 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N1 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N1 C19 H19A 109.5 . . ?
N1 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
N1 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C8 O4 Eu1 117.5(2) . 1_455 ?
C6 C5 C4 120.5(3) . . ?
C6 C5 C8 119.2(3) . . ?
C4 C5 C8 120.2(3) . . ?
C3 C4 C5 118.3(3) . . ?
C3 C4 H4 120.8 . . ?
C5 C4 H4 120.8 . . ?
O4 C8 O3 125.6(3) . . ?
O4 C8 C5 117.4(3) . . ?
O3 C8 C5 117.0(3) . . ?
O4 C8 Eu1 42.05(15) . 1_455 ?
O3 C8 Eu1 85.62(18) . 1_455 ?
C5 C8 Eu1 153.4(2) . 1_455 ?
C1 C2 C3 122.0(3) . . ?
C1 C2 H2 119.0 . . ?
C3 C2 H2 119.0 . . ?
C2 C1 C6 117.4(3) . . ?
C2 C1 C1 121.8(4) . 2_566 ?
C6 C1 C1 120.8(4) . 2_566 ?
C5 C6 C1 121.4(3) . . ?
C5 C6 H6 119.3 . . ?
C1 C6 H6 119.3 . . ?
N2 C22 H22A 109.5 . . ?
N2 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N2 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        64.98
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.304
_refine_diff_density_min         -1.130
_refine_diff_density_rms         0.087
