# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CCDC-1422328
_audit_block_doi                 10.5517/cc1jr1kw
_database_code_depnum_ccdc_archive 'CCDC 1422328'
_audit_update_record             
;
2016-03-16 deposited with the CCDC.
2016-03-22 downloaded from the CCDC.
;
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H28 Co N6 O6'
_chemical_formula_weight         771.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.7983(7)
_cell_length_b                   11.9044(7)
_cell_length_c                   14.4291(8)
_cell_angle_alpha                72.807(3)
_cell_angle_beta                 81.143(3)
_cell_angle_gamma                61.863(2)
_cell_volume                     1706.98(18)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9211
_cell_measurement_theta_min      2.47
_cell_measurement_theta_max      27.53

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.501
_exptl_crystal_F_000             794
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    0.565
_shelx_estimated_absorpt_T_min   0.827
_shelx_estimated_absorpt_T_max   0.895
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            28349
_diffrn_reflns_av_unetI/netI     0.0169
_diffrn_reflns_av_R_equivalents  0.0201
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         1.477
_diffrn_reflns_theta_max         27.647
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             7849
_reflns_number_gt                7169
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0494P)²+0.6414P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7849
_refine_ls_number_parameters     496
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0305
_refine_ls_wR_factor_ref         0.0866
_refine_ls_wR_factor_gt          0.0836
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_restrained_S_all      1.003
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.26403(2) 0.77857(2) 0.19249(2) 0.02407(6) Uani 1 1 d . . . . .
O1 O 0.23032(10) 0.92870(10) 0.06297(7) 0.0348(2) Uani 1 1 d . . . . .
O2 O 0.40510(14) 0.89829(12) -0.03091(11) 0.0651(4) Uani 1 1 d . . . . .
O3 O 0.46723(10) 0.65852(10) 0.17454(8) 0.0348(2) Uani 1 1 d . . . . .
O4 O 0.51919(13) 0.65834(11) 0.02000(9) 0.0540(3) Uani 1 1 d . . . . .
H4 H 0.4690 0.7369 0.0116 0.081 Uiso 1 1 calc R U . . .
O5 O 0.28490(10) 1.59566(9) 0.30653(7) 0.0316(2) Uani 1 1 d . . . . .
O6 O 0.24823(10) 1.62965(9) 0.15352(7) 0.0323(2) Uani 1 1 d . . . . .
N1 N 0.07921(14) 1.51725(12) -0.19188(10) 0.0394(3) Uani 1 1 d . . . . .
N2 N -0.03584(16) 1.73202(14) -0.19797(13) 0.0528(4) Uani 1 1 d . . . . .
N3 N 0.86907(12) 0.05563(12) 0.21055(9) 0.0339(3) Uani 1 1 d . . . . .
N4 N 1.06260(12) -0.11873(11) 0.22723(9) 0.0317(3) Uani 1 1 d . . . . .
N5 N 0.31511(13) 1.04272(11) 0.30411(9) 0.0310(3) Uani 1 1 d . . . . .
N6 N 0.31822(12) 0.87553(11) 0.26278(9) 0.0294(2) Uani 1 1 d . . . . .
C1 C 0.23597(14) 1.11177(13) -0.05667(10) 0.0311(3) Uani 1 1 d . . . . .
C2 C 0.10465(15) 1.19042(15) -0.05505(11) 0.0366(3) Uani 1 1 d . . . . .
H2A H 0.0511 1.1535 -0.0220 0.044 Uiso 1 1 calc R U . . .
C3 C 0.05165(15) 1.32353(15) -0.10208(12) 0.0390(3) Uani 1 1 d . . . . .
H3A H -0.0369 1.3753 -0.1018 0.047 Uiso 1 1 calc R U . . .
C4 C 0.13201(15) 1.37849(14) -0.14949(11) 0.0343(3) Uani 1 1 d . . . . .
C5 C 0.26321(16) 1.30041(16) -0.15462(14) 0.0442(4) Uani 1 1 d . . . . .
H5A H 0.3164 1.3371 -0.1888 0.053 Uiso 1 1 calc R U . . .
C6 C 0.31466(16) 1.16747(15) -0.10866(14) 0.0429(4) Uani 1 1 d . . . . .
H6A H 0.4028 1.1147 -0.1125 0.051 Uiso 1 1 calc R U . . .
C7 C 0.29431(15) 0.96796(14) -0.00383(11) 0.0334(3) Uani 1 1 d . . . . .
C8 C -0.00565(19) 1.61236(16) -0.14687(14) 0.0482(4) Uani 1 1 d . . . . .
H8A H -0.0389 1.5928 -0.0848 0.058 Uiso 1 1 calc R U . . .
C9 C 0.03185(17) 1.71771(16) -0.28453(14) 0.0447(4) Uani 1 1 d . . . . .
C10 C 0.0322(2) 1.81359(19) -0.36815(17) 0.0597(5) Uani 1 1 d . . . . .
H10A H -0.0168 1.9028 -0.3712 0.072 Uiso 1 1 calc R U . . .
C11 C 0.1065(3) 1.7726(2) -0.44533(17) 0.0696(6) Uani 1 1 d . . . . .
H11A H 0.1074 1.8353 -0.5017 0.083 Uiso 1 1 calc R U . . .
C12 C 0.1809(2) 1.6395(2) -0.44199(16) 0.0661(6) Uani 1 1 d . . . . .
H12A H 0.2305 1.6154 -0.4960 0.079 Uiso 1 1 calc R U . . .
C13 C 0.1825(2) 1.5424(2) -0.36021(15) 0.0521(4) Uani 1 1 d . . . . .
H13A H 0.2326 1.4535 -0.3575 0.062 Uiso 1 1 calc R U . . .
C14 C 0.10596(16) 1.58407(15) -0.28237(12) 0.0393(3) Uani 1 1 d . . . . .
C15 C 0.61491(13) 0.45789(13) 0.13649(11) 0.0303(3) Uani 1 1 d . . . . .
C16 C 0.68931(16) 0.39585(15) 0.06550(11) 0.0392(3) Uani 1 1 d . . . . .
H16A H 0.6843 0.4447 0.0013 0.047 Uiso 1 1 calc R U . . .
C17 C 0.77078(16) 0.26216(15) 0.08921(11) 0.0387(3) Uani 1 1 d . . . . .
H17A H 0.8197 0.2206 0.0414 0.046 Uiso 1 1 calc R U . . .
C18 C 0.77837(14) 0.19156(13) 0.18460(11) 0.0318(3) Uani 1 1 d . . . . .
C19 C 0.70346(15) 0.25127(15) 0.25638(11) 0.0361(3) Uani 1 1 d . . . . .
H19A H 0.7082 0.2021 0.3204 0.043 Uiso 1 1 calc R U . . .
C20 C 0.62166(14) 0.38462(14) 0.23177(11) 0.0341(3) Uani 1 1 d . . . . .
H20A H 0.5708 0.4255 0.2794 0.041 Uiso 1 1 calc R U . . .
C21 C 0.52661(14) 0.60148(14) 0.11102(11) 0.0314(3) Uani 1 1 d . . . . .
C22 C 0.99611(14) 0.00724(14) 0.18682(11) 0.0348(3) Uani 1 1 d . . . . .
H22A H 1.0326 0.0586 0.1458 0.042 Uiso 1 1 calc R U . . .
C23 C 0.97256(14) -0.15680(13) 0.28377(10) 0.0299(3) Uani 1 1 d . . . . .
C24 C 0.98757(16) -0.27780(15) 0.34441(12) 0.0386(3) Uani 1 1 d . . . . .
H24A H 1.0682 -0.3503 0.3548 0.046 Uiso 1 1 calc R U . . .
C25 C 0.87911(19) -0.28651(17) 0.38837(13) 0.0470(4) Uani 1 1 d . . . . .
H25A H 0.8871 -0.3665 0.4294 0.056 Uiso 1 1 calc R U . . .
C26 C 0.75731(18) -0.17907(18) 0.37342(14) 0.0484(4) Uani 1 1 d . . . . .
H26A H 0.6860 -0.1897 0.4031 0.058 Uiso 1 1 calc R U . . .
C27 C 0.74073(16) -0.05788(17) 0.31563(13) 0.0427(4) Uani 1 1 d . . . . .
H27A H 0.6599 0.0143 0.3057 0.051 Uiso 1 1 calc R U . . .
C28 C 0.85109(14) -0.04887(14) 0.27286(11) 0.0316(3) Uani 1 1 d . . . . .
C29 C 0.28316(14) 1.42065(12) 0.25865(10) 0.0280(3) Uani 1 1 d . . . . .
C30 C 0.34455(17) 1.34890(14) 0.19031(11) 0.0368(3) Uani 1 1 d . . . . .
H30A H 0.3766 1.3859 0.1331 0.044 Uiso 1 1 calc R U . . .
C31 C 0.35841(17) 1.22220(14) 0.20679(12) 0.0381(3) Uani 1 1 d . . . . .
H31A H 0.4027 1.1725 0.1623 0.046 Uiso 1 1 calc R U . . .
C32 C 0.30537(14) 1.17126(13) 0.29023(11) 0.0301(3) Uani 1 1 d . . . . .
C33 C 0.24426(15) 1.24082(14) 0.35930(11) 0.0327(3) Uani 1 1 d . . . . .
H33A H 0.2095 1.2048 0.4154 0.039 Uiso 1 1 calc R U . . .
C34 C 0.23546(15) 1.36546(13) 0.34375(11) 0.0317(3) Uani 1 1 d . . . . .
H34A H 0.1973 1.4121 0.3908 0.038 Uiso 1 1 calc R U . . .
C35 C 0.27139(13) 1.55677(12) 0.23879(10) 0.0268(3) Uani 1 1 d . . . . .
C36 C 0.28715(15) 1.00151(13) 0.23647(11) 0.0316(3) Uani 1 1 d . . . . .
H36A H 0.2497 1.0570 0.1774 0.038 Uiso 1 1 calc R U . . .
C37 C 0.37436(14) 0.82858(13) 0.35334(10) 0.0283(3) Uani 1 1 d . . . . .
C38 C 0.43403(17) 0.70081(14) 0.41181(12) 0.0385(3) Uani 1 1 d . . . . .
H38A H 0.4398 0.6296 0.3935 0.046 Uiso 1 1 calc R U . . .
C39 C 0.48430(18) 0.68382(16) 0.49798(12) 0.0433(4) Uani 1 1 d . . . . .
H39A H 0.5261 0.5992 0.5378 0.052 Uiso 1 1 calc R U . . .
C40 C 0.47426(16) 0.78991(16) 0.52704(12) 0.0389(3) Uani 1 1 d . . . . .
H40A H 0.5068 0.7747 0.5867 0.047 Uiso 1 1 calc R U . . .
C41 C 0.41710(15) 0.91727(15) 0.46922(11) 0.0344(3) Uani 1 1 d . . . . .
H41A H 0.4104 0.9883 0.4883 0.041 Uiso 1 1 calc R U . . .
C42 C 0.37033(14) 0.93333(13) 0.38128(10) 0.0279(3) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N6 2.0875(11) . ?
Co1 O6 2.1040(10) 1_545 ?
Co1 O1 2.1045(10) . ?
Co1 N4 2.1562(12) 1_465 ?
Co1 O3 2.1571(10) . ?
Co1 O5 2.2384(10) 1_545 ?
Co1 C35 2.4867(12) 1_545 ?
O1 C7 1.2489(18) . ?
O2 C7 1.2494(19) . ?
O3 C21 1.2302(17) . ?
O4 C21 1.2824(19) . ?
O4 H4 0.8200 . ?
O5 C35 1.2571(17) . ?
O5 Co1 2.2383(10) 1_565 ?
O6 C35 1.2610(17) . ?
O6 Co1 2.1040(10) 1_565 ?
N1 C8 1.368(2) . ?
N1 C14 1.390(2) . ?
N1 C4 1.4283(18) . ?
N2 C8 1.297(2) . ?
N2 C9 1.385(3) . ?
N3 C22 1.3564(19) . ?
N3 C28 1.3891(18) . ?
N3 C18 1.4268(17) . ?
N4 C22 1.3109(18) . ?
N4 C23 1.4030(18) . ?
N4 Co1 2.1562(12) 1_645 ?
N5 C36 1.3553(18) . ?
N5 C42 1.3879(18) . ?
N5 C32 1.4335(15) . ?
N6 C36 1.3098(16) . ?
N6 C37 1.3943(19) . ?
C1 C2 1.382(2) . ?
C1 C6 1.392(2) . ?
C1 C7 1.5048(19) . ?
C2 C3 1.387(2) . ?
C2 H2A 0.9300 . ?
C3 C4 1.384(2) . ?
C3 H3A 0.9300 . ?
C4 C5 1.383(2) . ?
C5 C6 1.382(2) . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9300 . ?
C8 H8A 0.9300 . ?
C9 C10 1.395(3) . ?
C9 C14 1.401(2) . ?
C10 C11 1.365(4) . ?
C10 H10A 0.9300 . ?
C11 C12 1.393(4) . ?
C11 H11A 0.9300 . ?
C12 C13 1.381(3) . ?
C12 H12A 0.9300 . ?
C13 C14 1.385(3) . ?
C13 H13A 0.9300 . ?
C15 C20 1.384(2) . ?
C15 C16 1.387(2) . ?
C15 C21 1.4864(19) . ?
C16 C17 1.382(2) . ?
C16 H16A 0.9300 . ?
C17 C18 1.375(2) . ?
C17 H17A 0.9300 . ?
C18 C19 1.386(2) . ?
C19 C20 1.380(2) . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9300 . ?
C22 H22A 0.9300 . ?
C23 C24 1.391(2) . ?
C23 C28 1.394(2) . ?
C24 C25 1.374(2) . ?
C24 H24A 0.9300 . ?
C25 C26 1.395(3) . ?
C25 H25A 0.9300 . ?
C26 C27 1.374(2) . ?
C26 H26A 0.9300 . ?
C27 C28 1.390(2) . ?
C27 H27A 0.9300 . ?
C29 C34 1.384(2) . ?
C29 C30 1.3860(19) . ?
C29 C35 1.5009(16) . ?
C30 C31 1.3876(19) . ?
C30 H30A 0.9300 . ?
C31 C32 1.380(2) . ?
C31 H31A 0.9300 . ?
C32 C33 1.379(2) . ?
C33 C34 1.3884(18) . ?
C33 H33A 0.9300 . ?
C34 H34A 0.9300 . ?
C35 Co1 2.4867(12) 1_565 ?
C36 H36A 0.9300 . ?
C37 C38 1.3911(19) . ?
C37 C42 1.3983(18) . ?
C38 C39 1.380(2) . ?
C38 H38A 0.9300 . ?
C39 C40 1.393(2) . ?
C39 H39A 0.9300 . ?
C40 C41 1.382(2) . ?
C40 H40A 0.9300 . ?
C41 C42 1.387(2) . ?
C41 H41A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 Co1 O6 162.10(4) . 1_545 ?
N6 Co1 O1 91.46(5) . . ?
O6 Co1 O1 104.35(4) 1_545 . ?
N6 Co1 N4 93.93(5) . 1_465 ?
O6 Co1 N4 95.08(5) 1_545 1_465 ?
O1 Co1 N4 87.43(4) . 1_465 ?
N6 Co1 O3 85.84(4) . . ?
O6 Co1 O3 83.34(4) 1_545 . ?
O1 Co1 O3 99.59(4) . . ?
N4 Co1 O3 172.98(4) 1_465 . ?
N6 Co1 O5 103.62(4) . 1_545 ?
O6 Co1 O5 60.69(4) 1_545 1_545 ?
O1 Co1 O5 164.91(4) . 1_545 ?
N4 Co1 O5 91.79(4) 1_465 1_545 ?
O3 Co1 O5 81.46(4) . 1_545 ?
N6 Co1 C35 133.11(5) . 1_545 ?
O6 Co1 C35 30.46(4) 1_545 1_545 ?
O1 Co1 C35 134.81(5) . 1_545 ?
N4 Co1 C35 95.12(4) 1_465 1_545 ?
O3 Co1 C35 80.04(4) . 1_545 ?
O5 Co1 C35 30.28(4) 1_545 1_545 ?
C7 O1 Co1 138.20(10) . . ?
C21 O3 Co1 130.42(10) . . ?
C21 O4 H4 109.5 . . ?
C35 O5 Co1 85.86(8) . 1_565 ?
C35 O6 Co1 91.80(8) . 1_565 ?
C8 N1 C14 105.92(13) . . ?
C8 N1 C4 125.28(14) . . ?
C14 N1 C4 128.73(14) . . ?
C8 N2 C9 104.45(15) . . ?
C22 N3 C28 106.63(12) . . ?
C22 N3 C18 124.76(12) . . ?
C28 N3 C18 128.17(12) . . ?
C22 N4 C23 104.77(12) . . ?
C22 N4 Co1 120.55(10) . 1_645 ?
C23 N4 Co1 134.55(9) . 1_645 ?
C36 N5 C42 107.04(11) . . ?
C36 N5 C32 124.98(12) . . ?
C42 N5 C32 127.42(12) . . ?
C36 N6 C37 105.32(11) . . ?
C36 N6 Co1 125.56(10) . . ?
C37 N6 Co1 128.35(9) . . ?
C2 C1 C6 118.92(13) . . ?
C2 C1 C7 121.18(13) . . ?
C6 C1 C7 119.90(13) . . ?
C1 C2 C3 120.94(14) . . ?
C1 C2 H2A 119.5 . . ?
C3 C2 H2A 119.5 . . ?
C4 C3 C2 119.28(14) . . ?
C4 C3 H3A 120.4 . . ?
C2 C3 H3A 120.4 . . ?
C5 C4 C3 120.50(14) . . ?
C5 C4 N1 119.81(14) . . ?
C3 C4 N1 119.68(14) . . ?
C6 C5 C4 119.58(15) . . ?
C6 C5 H5A 120.2 . . ?
C4 C5 H5A 120.2 . . ?
C5 C6 C1 120.65(15) . . ?
C5 C6 H6A 119.7 . . ?
C1 C6 H6A 119.7 . . ?
O1 C7 O2 125.75(14) . . ?
O1 C7 C1 118.39(13) . . ?
O2 C7 C1 115.86(13) . . ?
N2 C8 N1 114.40(17) . . ?
N2 C8 H8A 122.8 . . ?
N1 C8 H8A 122.8 . . ?
N2 C9 C10 129.75(18) . . ?
N2 C9 C14 110.60(15) . . ?
C10 C9 C14 119.63(19) . . ?
C11 C10 C9 118.1(2) . . ?
C11 C10 H10A 121.0 . . ?
C9 C10 H10A 121.0 . . ?
C10 C11 C12 121.81(19) . . ?
C10 C11 H11A 119.1 . . ?
C12 C11 H11A 119.1 . . ?
C13 C12 C11 121.4(2) . . ?
C13 C12 H12A 119.3 . . ?
C11 C12 H12A 119.3 . . ?
C12 C13 C14 116.7(2) . . ?
C12 C13 H13A 121.6 . . ?
C14 C13 H13A 121.6 . . ?
C13 C14 N1 133.01(16) . . ?
C13 C14 C9 122.34(16) . . ?
N1 C14 C9 104.62(15) . . ?
C20 C15 C16 119.51(13) . . ?
C20 C15 C21 119.78(13) . . ?
C16 C15 C21 120.70(13) . . ?
C17 C16 C15 120.63(14) . . ?
C17 C16 H16A 119.7 . . ?
C15 C16 H16A 119.7 . . ?
C18 C17 C16 119.02(14) . . ?
C18 C17 H17A 120.5 . . ?
C16 C17 H17A 120.5 . . ?
C17 C18 C19 121.23(13) . . ?
C17 C18 N3 119.26(13) . . ?
C19 C18 N3 119.45(13) . . ?
C20 C19 C18 119.24(14) . . ?
C20 C19 H19A 120.4 . . ?
C18 C19 H19A 120.4 . . ?
C19 C20 C15 120.34(13) . . ?
C19 C20 H20A 119.8 . . ?
C15 C20 H20A 119.8 . . ?
O3 C21 O4 124.13(13) . . ?
O3 C21 C15 120.84(14) . . ?
O4 C21 C15 115.03(13) . . ?
N4 C22 N3 113.63(13) . . ?
N4 C22 H22A 123.2 . . ?
N3 C22 H22A 123.2 . . ?
C24 C23 C28 119.68(13) . . ?
C24 C23 N4 130.88(13) . . ?
C28 C23 N4 109.44(12) . . ?
C25 C24 C23 117.64(15) . . ?
C25 C24 H24A 121.2 . . ?
C23 C24 H24A 121.2 . . ?
C24 C25 C26 122.03(15) . . ?
C24 C25 H25A 119.0 . . ?
C26 C25 H25A 119.0 . . ?
C27 C26 C25 121.25(15) . . ?
C27 C26 H26A 119.4 . . ?
C25 C26 H26A 119.4 . . ?
C26 C27 C28 116.51(15) . . ?
C26 C27 H27A 121.7 . . ?
C28 C27 H27A 121.7 . . ?
N3 C28 C27 131.64(14) . . ?
N3 C28 C23 105.51(12) . . ?
C27 C28 C23 122.78(14) . . ?
C34 C29 C30 119.73(12) . . ?
C34 C29 C35 121.43(12) . . ?
C30 C29 C35 118.84(12) . . ?
C29 C30 C31 120.38(14) . . ?
C29 C30 H30A 119.8 . . ?
C31 C30 H30A 119.8 . . ?
C32 C31 C30 118.89(14) . . ?
C32 C31 H31A 120.6 . . ?
C30 C31 H31A 120.6 . . ?
C33 C32 C31 121.60(12) . . ?
C33 C32 N5 120.10(13) . . ?
C31 C32 N5 118.29(13) . . ?
C32 C33 C34 118.92(13) . . ?
C32 C33 H33A 120.5 . . ?
C34 C33 H33A 120.5 . . ?
C29 C34 C33 120.37(13) . . ?
C29 C34 H34A 119.8 . . ?
C33 C34 H34A 119.8 . . ?
O5 C35 O6 121.49(12) . . ?
O5 C35 C29 119.90(12) . . ?
O6 C35 C29 118.61(12) . . ?
O5 C35 Co1 63.86(7) . 1_565 ?
O6 C35 Co1 57.74(6) . 1_565 ?
C29 C35 Co1 174.82(10) . 1_565 ?
N6 C36 N5 113.09(13) . . ?
N6 C36 H36A 123.5 . . ?
N5 C36 H36A 123.5 . . ?
C38 C37 N6 130.48(13) . . ?
C38 C37 C42 120.07(14) . . ?
N6 C37 C42 109.38(11) . . ?
C39 C38 C37 117.43(14) . . ?
C39 C38 H38A 121.3 . . ?
C37 C38 H38A 121.3 . . ?
C38 C39 C40 121.86(14) . . ?
C38 C39 H39A 119.1 . . ?
C40 C39 H39A 119.1 . . ?
C41 C40 C39 121.51(15) . . ?
C41 C40 H40A 119.2 . . ?
C39 C40 H40A 119.2 . . ?
C40 C41 C42 116.39(14) . . ?
C40 C41 H41A 121.8 . . ?
C42 C41 H41A 121.8 . . ?
C41 C42 N5 132.25(12) . . ?
C41 C42 C37 122.62(13) . . ?
N5 C42 C37 105.12(12) . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O4 H4 O2 0.82 1.65 2.4389(16) 161.3 .

_refine_diff_density_max         0.287
_refine_diff_density_min         -0.293
_refine_diff_density_rms         0.055

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CCDC-1443010
_database_code_depnum_ccdc_archive 'CCDC 1443010'
_audit_update_record             
;
2016-03-16 deposited with the CCDC.
2016-03-22 downloaded from the CCDC.
;
_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C30 H24 Co N4 O6'
_chemical_formula_weight         595.46

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      trigonal
_space_group_IT_number           152
_space_group_name_H-M_alt        'P 31 2 1'
_space_group_name_Hall           'P 31 2"'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z+1/3'
'-x+y, -x, z+2/3'
'y, x, -z'
'x-y, -y, -z+2/3'
'-x, -x+y, -z+1/3'

_cell_length_a                   12.9013(4)
_cell_length_b                   12.9013(4)
_cell_length_c                   15.3095(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     2206.78(19)
_cell_formula_units_Z            3
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    5906
_cell_measurement_theta_min      2.26
_cell_measurement_theta_max      26.68

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.344
_exptl_crystal_F_000             921
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.090
_exptl_absorpt_coefficient_mu    0.631
_shelx_estimated_absorpt_T_min   0.895
_shelx_estimated_absorpt_T_max   0.945
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            13132
_diffrn_reflns_av_unetI/netI     0.0241
_diffrn_reflns_av_R_equivalents  0.0209
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.823
_diffrn_reflns_theta_max         27.455
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             3324
_reflns_number_gt                2861
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.762
_reflns_Friedel_fraction_max     0.982
_reflns_Friedel_fraction_full    1.000

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0618P)²+0.1068P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
; 
 Flack x determined using 1110 quotients [(I+)-(I-)]/[(I+)+(I-)] 
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). 
;
_refine_ls_abs_structure_Flack   -0.005(6)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         3324
_refine_ls_number_parameters     186
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0396
_refine_ls_R_factor_gt           0.0286
_refine_ls_wR_factor_ref         0.0919
_refine_ls_wR_factor_gt          0.0771
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_restrained_S_all      1.009
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.61464(4) 0.61464(4) 0.0000 0.04178(16) Uani 1 2 d S T P . .
O1 O 0.0884(2) 0.4289(2) 0.54646(11) 0.0526(5) Uani 1 1 d . . . . .
O2 O 0.2382(2) 0.3965(3) 0.57411(14) 0.0743(8) Uani 1 1 d . . . . .
N2 N 0.4474(2) 0.5644(2) 0.05518(14) 0.0499(6) Uani 1 1 d . . . . .
C8 C 0.4373(3) 0.5774(3) 0.13908(17) 0.0532(8) Uani 1 1 d . . . . .
H8A H 0.5021 0.6251 0.1749 0.064 Uiso 1 1 calc R U . . .
N1 N 0.3244(2) 0.5152(3) 0.16821(15) 0.0613(7) Uani 1 1 d . . . . .
C9 C 0.3324(3) 0.4862(3) 0.02644(16) 0.0494(7) Uani 1 1 d . . . . .
C7 C 0.1796(3) 0.4249(3) 0.52517(17) 0.0489(7) Uani 1 1 d . . . . .
C14 C 0.2541(3) 0.4537(4) 0.09670(19) 0.0654(10) Uani 1 1 d . . . . .
C4 C 0.2894(3) 0.4973(3) 0.25868(19) 0.0582(8) Uani 1 1 d . . . . .
C1 C 0.2216(3) 0.4556(3) 0.43149(17) 0.0508(7) Uani 1 1 d . . . . .
C6 C 0.1831(4) 0.5142(4) 0.3783(2) 0.0659(10) Uani 1 1 d . . . . .
H6A H 0.1332 0.5403 0.4009 0.079 Uiso 1 1 calc R U . . .
C10 C 0.2911(3) 0.4366(3) -0.05565(19) 0.0600(8) Uani 1 1 d . . . . .
H10A H 0.3424 0.4579 -0.1034 0.072 Uiso 1 1 calc R U . . .
C5 C 0.2167(4) 0.5359(4) 0.2910(2) 0.0688(10) Uani 1 1 d . . . . .
H5A H 0.1898 0.5761 0.2555 0.083 Uiso 1 1 calc R U . . .
C2 C 0.2956(5) 0.4195(5) 0.3979(2) 0.0983(18) Uani 1 1 d . . . . .
H2A H 0.3241 0.3810 0.4336 0.118 Uiso 1 1 calc R U . . .
C11 C 0.1704(4) 0.3543(4) -0.0632(3) 0.0850(13) Uani 1 1 d . . . . .
H11A H 0.1395 0.3198 -0.1172 0.102 Uiso 1 1 calc R U . . .
C13 C 0.1348(4) 0.3721(6) 0.0889(3) 0.1084(19) Uani 1 1 d . . . . .
H13A H 0.0828 0.3511 0.1362 0.130 Uiso 1 1 calc R U . . .
C3 C 0.3293(5) 0.4397(5) 0.3105(2) 0.1003(19) Uani 1 1 d . . . . .
H3A H 0.3792 0.4137 0.2878 0.120 Uiso 1 1 calc R U . . .
C12 C 0.0957(4) 0.3225(5) 0.0075(3) 0.115(2) Uani 1 1 d . . . . .
H12A H 0.0155 0.2653 0.0003 0.138 Uiso 1 1 calc R U . . .
O3 O 0.6904(2) 0.7981(2) 0.04391(13) 0.0618(6) Uani 1 1 d . . . . .
H3 H 0.6769 0.8325 0.0017 0.093 Uiso 1 1 d R U . . .
C15 C 0.8158(4) 0.8568(4) 0.0395(2) 0.0835(12) Uani 1 1 d . . . . .
H15A H 0.8469 0.8405 0.0922 0.100 Uiso 1 1 calc R U . . .
H15B H 0.8475 0.9426 0.0361 0.100 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 O1 2.0887(18) 5_665 ?
Co1 O1 2.0887(18) 2_664 ?
Co1 N2 2.095(2) 4 ?
Co1 N2 2.095(2) . ?
Co1 O3 2.167(2) 4 ?
Co1 O3 2.167(2) . ?
O1 C7 1.247(4) . ?
O1 Co1 2.0887(18) 3_565 ?
O2 C7 1.243(4) . ?
N2 C8 1.310(3) . ?
N2 C9 1.384(4) . ?
C8 N1 1.340(4) . ?
C8 H8A 0.9300 . ?
N1 C14 1.389(4) . ?
N1 C4 1.439(3) . ?
C9 C14 1.390(4) . ?
C9 C10 1.390(4) . ?
C7 C1 1.514(4) . ?
C14 C13 1.368(5) . ?
C4 C3 1.352(5) . ?
C4 C5 1.357(5) . ?
C1 C2 1.356(5) . ?
C1 C6 1.363(5) . ?
C6 C5 1.388(4) . ?
C6 H6A 0.9300 . ?
C10 C11 1.383(5) . ?
C10 H10A 0.9300 . ?
C5 H5A 0.9300 . ?
C2 C3 1.390(5) . ?
C2 H2A 0.9300 . ?
C11 C12 1.369(7) . ?
C11 H11A 0.9300 . ?
C13 C12 1.376(7) . ?
C13 H13A 0.9300 . ?
C3 H3A 0.9300 . ?
C12 H12A 0.9300 . ?
O3 C15 1.404(5) . ?
O3 H3 0.8499 . ?
C15 C15 1.518(8) 4 ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Co1 O1 179.51(14) 5_665 2_664 ?
O1 Co1 N2 93.62(9) 5_665 4 ?
O1 Co1 N2 86.71(9) 2_664 4 ?
O1 Co1 N2 86.71(9) 5_665 . ?
O1 Co1 N2 93.62(9) 2_664 . ?
N2 Co1 N2 95.96(15) 4 . ?
O1 Co1 O3 90.43(8) 5_665 4 ?
O1 Co1 O3 89.19(9) 2_664 4 ?
N2 Co1 O3 92.58(10) 4 4 ?
N2 Co1 O3 171.14(10) . 4 ?
O1 Co1 O3 89.19(9) 5_665 . ?
O1 Co1 O3 90.43(8) 2_664 . ?
N2 Co1 O3 171.14(10) 4 . ?
N2 Co1 O3 92.58(10) . . ?
O3 Co1 O3 78.98(14) 4 . ?
C7 O1 Co1 128.27(18) . 3_565 ?
C8 N2 C9 105.4(2) . . ?
C8 N2 Co1 120.6(2) . . ?
C9 N2 Co1 131.27(19) . . ?
N2 C8 N1 113.4(3) . . ?
N2 C8 H8A 123.3 . . ?
N1 C8 H8A 123.3 . . ?
C8 N1 C14 106.5(2) . . ?
C8 N1 C4 125.2(3) . . ?
C14 N1 C4 127.1(3) . . ?
N2 C9 C14 109.1(3) . . ?
N2 C9 C10 130.4(3) . . ?
C14 C9 C10 120.5(3) . . ?
O2 C7 O1 125.5(3) . . ?
O2 C7 C1 117.3(3) . . ?
O1 C7 C1 117.3(3) . . ?
C13 C14 C9 122.2(3) . . ?
C13 C14 N1 132.1(3) . . ?
C9 C14 N1 105.6(3) . . ?
C3 C4 C5 120.7(3) . . ?
C3 C4 N1 118.5(3) . . ?
C5 C4 N1 120.8(3) . . ?
C2 C1 C6 118.6(3) . . ?
C2 C1 C7 119.4(3) . . ?
C6 C1 C7 122.0(3) . . ?
C1 C6 C5 121.6(3) . . ?
C1 C6 H6A 119.2 . . ?
C5 C6 H6A 119.2 . . ?
C11 C10 C9 117.0(3) . . ?
C11 C10 H10A 121.5 . . ?
C9 C10 H10A 121.5 . . ?
C4 C5 C6 118.7(3) . . ?
C4 C5 H5A 120.6 . . ?
C6 C5 H5A 120.6 . . ?
C1 C2 C3 120.6(3) . . ?
C1 C2 H2A 119.7 . . ?
C3 C2 H2A 119.7 . . ?
C12 C11 C10 121.2(4) . . ?
C12 C11 H11A 119.4 . . ?
C10 C11 H11A 119.4 . . ?
C14 C13 C12 116.5(4) . . ?
C14 C13 H13A 121.7 . . ?
C12 C13 H13A 121.7 . . ?
C4 C3 C2 119.9(3) . . ?
C4 C3 H3A 120.1 . . ?
C2 C3 H3A 120.1 . . ?
C11 C12 C13 122.5(4) . . ?
C11 C12 H12A 118.7 . . ?
C13 C12 H12A 118.7 . . ?
C15 O3 Co1 110.1(2) . . ?
C15 O3 H3 99.4 . . ?
Co1 O3 H3 103.7 . . ?
O3 C15 C15 111.0(2) . 4 ?
O3 C15 H15A 109.4 . . ?
C15 C15 H15A 109.4 4 . ?
O3 C15 H15B 109.4 . . ?
C15 C15 H15B 109.4 4 . ?
H15A C15 H15B 108.0 . . ?

_refine_diff_density_max         0.354
_refine_diff_density_min         -0.233
_refine_diff_density_rms         0.127


# SQUEEZE RESULTS (Version = 201115)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.173 226 74 ' '
2 0.000 0.483 0.167 6 -1 ' '
3 0.483 0.000 0.833 6 -1 ' '
4 0.517 0.517 0.500 7 -1 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?
