# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1497452'
_audit_update_record             
;
2016-08-03 deposited with the CCDC.
2016-10-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ce7 Co2 Ge4'
_chemical_formula_weight         1389.06

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.3483(5)
_cell_length_b                   12.3288(5)
_cell_length_c                   12.3228(5)
_cell_angle_alpha                90
_cell_angle_beta                 109.413(5)
_cell_angle_gamma                90
_cell_volume                     1339.50(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    6.888
_exptl_crystal_F_000             2352
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    34.413
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            11821
_diffrn_reflns_av_unetI/netI     0.0296
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.408
_diffrn_reflns_theta_max         28.913
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.893
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.893
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.893
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             3161
_reflns_number_gt                2713
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0126P)²+5.6017P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.000291(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         3161
_refine_ls_number_parameters     119
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0379
_refine_ls_R_factor_gt           0.0289
_refine_ls_wR_factor_ref         0.0616
_refine_ls_wR_factor_gt          0.0590
_refine_ls_goodness_of_fit_ref   1.261
_refine_ls_restrained_S_all      1.261
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ce1 Ce 0.00192(6) 0.61790(4) 0.34073(4) 0.01185(12) Uani 1 1 d . . . . .
Ce2 Ce 0.00201(6) 0.39808(4) 0.10187(4) 0.01014(12) Uani 1 1 d . . . . .
Ce3 Ce 0.00010(6) 0.33970(4) 0.38182(4) 0.01195(12) Uani 1 1 d . . . . .
Ce4 Ce 0.64521(5) 0.49834(4) 0.16325(4) 0.00859(11) Uani 1 1 d . . . . .
Ce5 Ce 0.36215(6) 0.24683(4) 0.09212(4) 0.00904(12) Uani 1 1 d . . . . .
Ce6 Ce 0.63737(6) 0.25227(4) 0.41063(4) 0.00905(12) Uani 1 1 d . . . . .
Ce7 Ce 0.36754(6) 0.49830(4) 0.34559(4) 0.00961(12) Uani 1 1 d . . . . .
Ge1 Ge 0.25046(11) 0.00006(7) 0.06242(7) 0.00999(19) Uani 1 1 d . . . . .
Ge2 Ge 0.29657(10) 0.50042(8) 0.07496(7) 0.00978(19) Uani 1 1 d . . . . .
Ge3 Ge 0.72508(11) 0.25026(7) 0.17958(7) 0.0105(2) Uani 1 1 d . . . . .
Ge4 Ge 0.27264(11) 0.25196(7) 0.31628(7) 0.0099(2) Uani 1 1 d . . . . .
Co1 Co 0.13811(15) 0.61931(10) 0.15672(10) 0.0152(3) Uani 1 1 d . . . . .
Co2 Co 0.13492(14) 0.12166(10) 0.41428(10) 0.0145(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ce1 Co1 2.9465(13) . ?
Ce1 Co2 2.9734(12) 2 ?
Ce1 Ge3 3.1087(11) 2_655 ?
Ce1 Ge4 3.1244(11) 2 ?
Ce1 Ge1 3.2797(10) 4_566 ?
Ce1 Ge1 3.3125(10) 2 ?
Ce1 Ce3 3.4649(7) 3_566 ?
Ce1 Ce3 3.4678(7) . ?
Ce1 Ce2 3.5286(7) 2 ?
Ce1 Ce4 3.6370(7) 1_455 ?
Ce1 Ce7 3.7046(7) . ?
Ce1 Ce3 3.8685(7) 2 ?
Ce2 Co2 2.9759(13) 4_565 ?
Ce2 Co1 2.9905(14) . ?
Ce2 Co2 3.0179(14) 2 ?
Ce2 Co1 3.0234(13) 3_565 ?
Ce2 Ge2 3.1450(10) . ?
Ce2 Ge2 3.1721(10) 3_565 ?
Ce2 Ge4 3.4904(11) . ?
Ce2 Ce1 3.5286(7) 2_545 ?
Ce2 Ce3 3.5299(7) . ?
Ce2 Ce2 3.5436(9) 3_565 ?
Ce2 Ge3 3.5480(11) 1_455 ?
Ce2 Ce4 3.8604(7) 1_455 ?
Ce3 Co2 2.9393(14) . ?
Ce3 Co1 2.9783(14) 2_545 ?
Ce3 Ge4 3.1115(11) . ?
Ce3 Ge3 3.1269(11) 1_455 ?
Ce3 Ge1 3.2971(10) 4_566 ?
Ce3 Ge1 3.3071(10) 2 ?
Ce3 Ce1 3.4649(7) 3_566 ?
Ce3 Ce5 3.6713(7) 4_566 ?
Ce3 Ce6 3.6860(7) 1_455 ?
Ce3 Ce1 3.8685(7) 2_545 ?
Ce4 Co2 2.9589(13) 2_655 ?
Ce4 Ge2 3.0739(10) . ?
Ce4 Ge3 3.1388(10) . ?
Ce4 Ge2 3.1585(10) 3_665 ?
Ce4 Ge1 3.1918(10) 2_655 ?
Ce4 Ge4 3.2097(10) 2_655 ?
Ce4 Ce1 3.6370(7) 1_655 ?
Ce4 Ce2 3.8604(7) 1_655 ?
Ce4 Ce7 3.9576(7) . ?
Ce4 Ce5 3.9804(7) . ?
Ce4 Ce6 4.0011(7) 2_655 ?
Ce4 Ce3 4.0182(7) 1_655 ?
Ce5 Co2 2.9747(13) 4_565 ?
Ce5 Ge4 3.1418(10) . ?
Ce5 Ge2 3.1794(10) . ?
Ce5 Ge1 3.1978(10) . ?
Ce5 Ge3 3.2005(11) . ?
Ce5 Ge4 3.2193(10) 4_565 ?
Ce5 Ce3 3.6713(7) 4_565 ?
Ce5 Ce7 3.8824(7) 2_645 ?
Ce5 Ce6 3.9137(7) . ?
Ce5 Ce6 3.9302(7) 4_565 ?
Ce6 Co1 2.9899(14) 2_645 ?
Ce6 Ge3 3.1386(10) 4_566 ?
Ce6 Ge2 3.1594(10) 2_645 ?
Ce6 Ge1 3.2111(10) 2_655 ?
Ce6 Ge3 3.2142(10) . ?
Ce6 Ge4 3.2159(11) . ?
Ce6 Ce3 3.6860(7) 1_655 ?
Ce6 Ce7 3.8551(7) . ?
Ce6 Ce2 3.9076(7) 4_666 ?
Ce6 Ce5 3.9302(7) 4_566 ?
Ce6 Ce4 4.0012(7) 2_645 ?
Ce7 Co1 2.9873(13) . ?
Ce7 Ge4 3.1510(10) . ?
Ce7 Ge2 3.1767(10) . ?
Ce7 Ge1 3.2066(10) 4_566 ?
Ce7 Ge3 3.2120(10) 2_655 ?
Ce7 Ge1 3.3685(11) 2_655 ?
Ce7 Ce7 3.7884(10) 3_666 ?
Ce7 Ce5 3.8824(7) 2_655 ?
Ge1 Ce4 3.1918(10) 2_645 ?
Ge1 Ce7 3.2066(10) 4_565 ?
Ge1 Ce6 3.2111(10) 2_645 ?
Ge1 Ce1 3.2797(10) 4_565 ?
Ge1 Ce3 3.2970(10) 4_565 ?
Ge1 Ce3 3.3070(10) 2_545 ?
Ge1 Ce1 3.3125(10) 2_545 ?
Ge1 Ce7 3.3685(11) 2_645 ?
Ge2 Co1 2.5200(15) . ?
Ge2 Co2 2.5457(15) 4_565 ?
Ge2 Ce4 3.1584(10) 3_665 ?
Ge2 Ce6 3.1593(10) 2_655 ?
Ge2 Ce2 3.1721(10) 3_565 ?
Ge3 Co1 2.5684(15) 2_645 ?
Ge3 Ce1 3.1087(11) 2_645 ?
Ge3 Ce3 3.1269(11) 1_655 ?
Ge3 Ce6 3.1386(10) 4_565 ?
Ge3 Ce7 3.2120(10) 2_645 ?
Ge3 Ce2 3.5480(11) 1_655 ?
Ge4 Co2 2.5942(15) . ?
Ge4 Ce1 3.1244(11) 2_545 ?
Ge4 Ce4 3.2097(10) 2_645 ?
Ge4 Ce5 3.2193(10) 4_566 ?
Co1 Co2 2.4076(18) 2 ?
Co1 Ge3 2.5684(15) 2_655 ?
Co1 Ce3 2.9783(14) 2 ?
Co1 Ce6 2.9899(14) 2_655 ?
Co1 Ce2 3.0235(13) 3_565 ?
Co2 Co1 2.4075(18) 2_545 ?
Co2 Ge2 2.5457(15) 4_566 ?
Co2 Ce4 2.9589(13) 2_645 ?
Co2 Ce1 2.9735(12) 2_545 ?
Co2 Ce5 2.9748(13) 4_566 ?
Co2 Ce2 2.9759(13) 4_566 ?
Co2 Ce2 3.0178(14) 2_545 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Co1 Ce1 Co2 47.99(4) . 2 ?
Co1 Ce1 Ge3 50.11(3) . 2_655 ?
Co2 Ce1 Ge3 89.03(3) 2 2_655 ?
Co1 Ce1 Ge4 89.80(3) . 2 ?
Co2 Ce1 Ge4 50.28(3) 2 2 ?
Ge3 Ce1 Ge4 101.53(3) 2_655 2 ?
Co1 Ce1 Ge1 106.02(3) . 4_566 ?
Co2 Ce1 Ge1 145.49(3) 2 4_566 ?
Ge3 Ce1 Ge1 85.79(3) 2_655 4_566 ?
Ge4 Ce1 Ge1 163.55(3) 2 4_566 ?
Co1 Ce1 Ge1 145.24(3) . 2 ?
Co2 Ce1 Ge1 106.25(3) 2 2 ?
Ge3 Ce1 Ge1 164.02(3) 2_655 2 ?
Ge4 Ce1 Ge1 85.31(3) 2 2 ?
Ge1 Ce1 Ge1 84.13(3) 4_566 2 ?
Co1 Ce1 Ce3 154.68(3) . 3_566 ?
Co2 Ce1 Ce3 154.02(3) 2 3_566 ?
Ge3 Ce1 Ce3 105.91(2) 2_655 3_566 ?
Ge4 Ce1 Ce3 104.98(2) 2 3_566 ?
Ge1 Ce1 Ce3 58.647(19) 4_566 3_566 ?
Ge1 Ce1 Ce3 58.167(19) 2 3_566 ?
Co1 Ce1 Ce3 98.19(3) . . ?
Co2 Ce1 Ce3 98.54(3) 2 . ?
Ge3 Ce1 Ce3 125.10(2) 2_655 . ?
Ge4 Ce1 Ce3 124.80(2) 2 . ?
Ge1 Ce1 Ce3 58.42(2) 4_566 . ?
Ge1 Ce1 Ce3 58.33(2) 2 . ?
Ce3 Ce1 Ce3 90.186(15) 3_566 . ?
Co1 Ce1 Ce2 100.63(3) . 2 ?
Co2 Ce1 Ce2 99.62(3) 2 2 ?
Ge3 Ce1 Ce2 64.26(2) 2_655 2 ?
Ge4 Ce1 Ce2 62.94(2) 2 2 ?
Ge1 Ce1 Ce2 108.59(2) 4_566 2 ?
Ge1 Ce1 Ce2 107.52(2) 2 2 ?
Ce3 Ce1 Ce2 69.555(15) 3_566 2 ?
Ce3 Ce1 Ce2 159.727(19) . 2 ?
Co1 Ce1 Ce4 94.82(3) . 1_455 ?
Co2 Ce1 Ce4 52.01(3) 2 1_455 ?
Ge3 Ce1 Ce4 141.03(2) 2_655 1_455 ?
Ge4 Ce1 Ce4 56.06(2) 2 1_455 ?
Ge1 Ce1 Ce4 125.12(2) 4_566 1_455 ?
Ge1 Ce1 Ce4 54.439(19) 2 1_455 ?
Ce3 Ce1 Ce4 110.480(18) 3_566 1_455 ?
Ce3 Ce1 Ce4 68.835(15) . 1_455 ?
Ce2 Ce1 Ce4 116.662(18) 2 1_455 ?
Co1 Ce1 Ce7 51.86(3) . . ?
Co2 Ce1 Ce7 95.38(3) 2 . ?
Ge3 Ce1 Ce7 55.42(2) 2_655 . ?
Ge4 Ce1 Ce7 141.64(2) 2 . ?
Ge1 Ce1 Ce7 54.248(19) 4_566 . ?
Ge1 Ce1 Ce7 125.69(2) 2 . ?
Ce3 Ce1 Ce7 110.591(18) 3_566 . ?
Ce3 Ce1 Ce7 69.714(15) . . ?
Ce2 Ce1 Ce7 117.220(17) 2 . ?
Ce4 Ce1 Ce7 120.332(17) 1_455 . ?
Co1 Ce1 Ce3 49.60(3) . 2 ?
Co2 Ce1 Ce3 48.75(3) 2 2 ?
Ge3 Ce1 Ce3 51.87(2) 2_655 2 ?
Ge4 Ce1 Ce3 51.51(2) 2 2 ?
Ge1 Ce1 Ce3 137.66(2) 4_566 2 ?
Ge1 Ce1 Ce3 136.82(2) 2 2 ?
Ce3 Ce1 Ce3 126.337(15) 3_566 2 ?
Ce3 Ce1 Ce3 143.470(16) . 2 ?
Ce2 Ce1 Ce3 56.782(13) 2 2 ?
Ce4 Ce1 Ce3 94.171(16) 1_455 2 ?
Ce7 Ce1 Ce3 94.581(15) . 2 ?
Co2 Ce2 Co1 89.66(4) 4_565 . ?
Co2 Ce2 Co2 107.52(3) 4_565 2 ?
Co1 Ce2 Co2 47.24(4) . 2 ?
Co2 Ce2 Co1 47.31(3) 4_565 3_565 ?
Co1 Ce2 Co1 107.80(3) . 3_565 ?
Co2 Ce2 Co1 88.26(3) 2 3_565 ?
Co2 Ce2 Ge2 49.06(3) 4_565 . ?
Co1 Ce2 Ge2 48.42(3) . . ?
Co2 Ce2 Ge2 89.64(3) 2 . ?
Co1 Ce2 Ge2 90.29(3) 3_565 . ?
Co2 Ce2 Ge2 89.88(3) 4_565 3_565 ?
Co1 Ce2 Ge2 90.38(3) . 3_565 ?
Co2 Ce2 Ge2 48.49(3) 2 3_565 ?
Co1 Ce2 Ge2 47.93(3) 3_565 3_565 ?
Ge2 Ce2 Ge2 111.76(2) . 3_565 ?
Co2 Ce2 Ge4 99.27(3) 4_565 . ?
Co1 Ce2 Ge4 98.79(3) . . ?
Co2 Ce2 Ge4 134.92(3) 2 . ?
Co1 Ce2 Ge4 135.42(3) 3_565 . ?
Ge2 Ce2 Ge4 81.21(3) . . ?
Ge2 Ce2 Ge4 167.04(3) 3_565 . ?
Co2 Ce2 Ce1 96.34(3) 4_565 2_545 ?
Co1 Ce2 Ce1 151.59(3) . 2_545 ?
Co2 Ce2 Ce1 151.04(3) 2 2_545 ?
Co1 Ce2 Ce1 96.44(3) 3_565 2_545 ?
Ge2 Ce2 Ce1 118.80(2) . 2_545 ?
Ge2 Ce2 Ce1 117.29(2) 3_565 2_545 ?
Ge4 Ce2 Ce1 52.861(18) . 2_545 ?
Co2 Ce2 Ce3 151.83(3) 4_565 . ?
Co1 Ce2 Ce3 96.03(3) . . ?
Co2 Ce2 Ce3 96.36(3) 2 . ?
Co1 Ce2 Ce3 150.98(3) 3_565 . ?
Ge2 Ce2 Ce3 118.28(2) . . ?
Ge2 Ce2 Ce3 117.56(2) 3_565 . ?
Ge4 Ce2 Ce3 52.615(18) . . ?
Ce1 Ce2 Ce3 66.468(15) 2_545 . ?
Co2 Ce2 Ce2 54.31(3) 4_565 3_565 ?
Co1 Ce2 Ce2 54.33(3) . 3_565 ?
Co2 Ce2 Ce2 53.21(3) 2 3_565 ?
Co1 Ce2 Ce2 53.47(3) 3_565 3_565 ?
Ge2 Ce2 Ce2 56.24(2) . 3_565 ?
Ge2 Ce2 Ce2 55.51(2) 3_565 3_565 ?
Ge4 Ce2 Ce2 137.45(3) . 3_565 ?
Ce1 Ce2 Ce2 146.92(2) 2_545 3_565 ?
Ce3 Ce2 Ce2 146.58(2) . 3_565 ?
Co2 Ce2 Ge3 134.28(3) 4_565 1_455 ?
Co1 Ce2 Ge3 134.52(3) . 1_455 ?
Co2 Ce2 Ge3 98.94(3) 2 1_455 ?
Co1 Ce2 Ge3 98.55(3) 3_565 1_455 ?
Ge2 Ce2 Ge3 167.82(3) . 1_455 ?
Ge2 Ce2 Ge3 80.42(2) 3_565 1_455 ?
Ge4 Ce2 Ge3 86.61(2) . 1_455 ?
Ce1 Ce2 Ge3 52.116(18) 2_545 1_455 ?
Ce3 Ce2 Ge3 52.434(18) . 1_455 ?
Ce2 Ce2 Ge3 135.94(3) 3_565 1_455 ?
Co2 Ce2 Ce4 142.13(3) 4_565 1_455 ?
Co1 Ce2 Ce4 89.66(3) . 1_455 ?
Co2 Ce2 Ce4 49.10(3) 2 1_455 ?
Co1 Ce2 Ce4 97.43(3) 3_565 1_455 ?
Ge2 Ce2 Ce4 137.39(2) . 1_455 ?
Ge2 Ce2 Ce4 52.264(19) 3_565 1_455 ?
Ge4 Ce2 Ce4 118.23(2) . 1_455 ?
Ce1 Ce2 Ce4 101.942(16) 2_545 1_455 ?
Ce3 Ce2 Ce4 65.695(14) . 1_455 ?
Ce2 Ce2 Ce4 96.05(2) 3_565 1_455 ?
Ge3 Ce2 Ce4 49.915(18) 1_455 1_455 ?
Co2 Ce3 Co1 48.01(4) . 2_545 ?
Co2 Ce3 Ge4 50.68(3) . . ?
Co1 Ce3 Ge4 89.46(3) 2_545 . ?
Co2 Ce3 Ge3 89.30(3) . 1_455 ?
Co1 Ce3 Ge3 49.68(3) 2_545 1_455 ?
Ge4 Ce3 Ge3 101.41(3) . 1_455 ?
Co2 Ce3 Ge1 106.26(3) . 4_566 ?
Co1 Ce3 Ge1 145.82(3) 2_545 4_566 ?
Ge4 Ce3 Ge1 85.68(3) . 4_566 ?
Ge3 Ce3 Ge1 163.82(3) 1_455 4_566 ?
Co2 Ce3 Ge1 145.06(3) . 2 ?
Co1 Ce3 Ge1 106.19(3) 2_545 2 ?
Ge4 Ce3 Ge1 163.61(3) . 2 ?
Ge3 Ce3 Ge1 85.69(3) 1_455 2 ?
Ge1 Ce3 Ge1 83.94(3) 4_566 2 ?
Co2 Ce3 Ce1 98.42(3) . 3_566 ?
Co1 Ce3 Ce1 98.66(3) 2_545 3_566 ?
Ge4 Ce3 Ce1 125.60(2) . 3_566 ?
Ge3 Ce3 Ce1 124.54(2) 1_455 3_566 ?
Ge1 Ce3 Ce1 58.602(19) 4_566 3_566 ?
Ge1 Ce3 Ce1 57.879(19) 2 3_566 ?
Co2 Ce3 Ce1 154.38(3) . . ?
Co1 Ce3 Ce1 154.42(3) 2_545 . ?
Ge4 Ce3 Ce1 105.18(2) . . ?
Ge3 Ce3 Ce1 105.96(2) 1_455 . ?
Ge1 Ce3 Ce1 57.94(2) 4_566 . ?
Ge1 Ce3 Ce1 58.48(2) 2 . ?
Ce1 Ce3 Ce1 89.814(15) 3_566 . ?
Co2 Ce3 Ce2 100.27(3) . . ?
Co1 Ce3 Ce2 99.96(3) 2_545 . ?
Ge4 Ce3 Ce2 63.04(2) . . ?
Ge3 Ce3 Ce2 64.08(2) 1_455 . ?
Ge1 Ce3 Ce2 107.73(2) 4_566 . ?
Ge1 Ce3 Ce2 108.37(2) 2 . ?
Ce1 Ce3 Ce2 159.56(2) 3_566 . ?
Ce1 Ce3 Ce2 69.745(15) . . ?
Co2 Ce3 Ce5 52.06(3) . 4_566 ?
Co1 Ce3 Ce5 95.55(3) 2_545 4_566 ?
Ge4 Ce3 Ce5 55.94(2) . 4_566 ?
Ge3 Ce3 Ce5 141.35(2) 1_455 4_566 ?
Ge1 Ce3 Ce5 54.311(19) 4_566 4_566 ?
Ge1 Ce3 Ce5 125.27(2) 2 4_566 ?
Ce1 Ce3 Ce5 69.722(15) 3_566 4_566 ?
Ce1 Ce3 Ce5 110.020(17) . 4_566 ?
Ce2 Ce3 Ce5 116.497(18) . 4_566 ?
Co2 Ce3 Ce6 94.93(3) . 1_455 ?
Co1 Ce3 Ce6 52.00(3) 2_545 1_455 ?
Ge4 Ce3 Ce6 141.46(2) . 1_455 ?
Ge3 Ce3 Ce6 55.57(2) 1_455 1_455 ?
Ge1 Ce3 Ce6 125.42(2) 4_566 1_455 ?
Ge1 Ce3 Ce6 54.343(19) 2 1_455 ?
Ce1 Ce3 Ce6 69.034(15) 3_566 1_455 ?
Ce1 Ce3 Ce6 110.648(17) . 1_455 ?
Ce2 Ce3 Ce6 117.219(18) . 1_455 ?
Ce5 Ce3 Ce6 120.584(17) 4_566 1_455 ?
Co2 Ce3 Ce1 49.52(2) . 2_545 ?
Co1 Ce3 Ce1 48.88(3) 2_545 2_545 ?
Ge4 Ce3 Ce1 51.81(2) . 2_545 ?
Ge3 Ce3 Ce1 51.44(2) 1_455 2_545 ?
Ge1 Ce3 Ce1 137.49(2) 4_566 2_545 ?
Ge1 Ce3 Ce1 137.14(2) 2 2_545 ?
Ce1 Ce3 Ce1 143.690(16) 3_566 2_545 ?
Ce1 Ce3 Ce1 126.494(14) . 2_545 ?
Ce2 Ce3 Ce1 56.749(14) . 2_545 ?
Ce5 Ce3 Ce1 94.654(16) 4_566 2_545 ?
Ce6 Ce3 Ce1 94.224(16) 1_455 2_545 ?
Co2 Ce4 Ge2 130.54(3) 2_655 . ?
Co2 Ce4 Ge3 110.21(3) 2_655 . ?
Ge2 Ce4 Ge3 103.44(3) . . ?
Co2 Ce4 Ge2 49.05(3) 2_655 3_665 ?
Ge2 Ce4 Ge2 99.26(3) . 3_665 ?
Ge3 Ce4 Ge2 87.34(3) . 3_665 ?
Co2 Ce4 Ge1 109.76(3) 2_655 2_655 ?
Ge2 Ce4 Ge1 106.83(3) . 2_655 ?
Ge3 Ce4 Ge1 87.49(3) . 2_655 ?
Ge2 Ce4 Ge1 153.89(3) 3_665 2_655 ?
Co2 Ce4 Ge4 49.53(3) 2_655 2_655 ?
Ge2 Ce4 Ge4 102.57(3) . 2_655 ?
Ge3 Ce4 Ge4 153.98(3) . 2_655 ?
Ge2 Ce4 Ge4 87.57(3) 3_665 2_655 ?
Ge1 Ce4 Ge4 85.95(3) 2_655 2_655 ?
Co2 Ce4 Ce1 52.37(3) 2_655 1_655 ?
Ge2 Ce4 Ce1 149.52(2) . 1_655 ?
Ge3 Ce4 Ce1 101.85(2) . 1_655 ?
Ge2 Ce4 Ce1 98.63(2) 3_665 1_655 ?
Ge1 Ce4 Ce1 57.59(2) 2_655 1_655 ?
Ge4 Ce4 Ce1 53.86(2) 2_655 1_655 ?
Co2 Ce4 Ce2 50.44(3) 2_655 1_655 ?
Ge2 Ce4 Ce2 144.77(2) . 1_655 ?
Ge3 Ce4 Ce2 59.86(2) . 1_655 ?
Ge2 Ce4 Ce2 52.59(2) 3_665 1_655 ?
Ge1 Ce4 Ce2 103.29(2) 2_655 1_655 ?
Ge4 Ce4 Ce2 97.33(2) 2_655 1_655 ?
Ce1 Ce4 Ce2 64.429(14) 1_655 1_655 ?
Co2 Ce4 Ce7 147.19(3) 2_655 . ?
Ge2 Ce4 Ce7 51.877(19) . . ?
Ge3 Ce4 Ce7 98.65(2) . . ?
Ge2 Ce4 Ce7 151.14(2) 3_665 . ?
Ge1 Ce4 Ce7 54.96(2) 2_655 . ?
Ge4 Ce4 Ce7 98.07(2) 2_655 . ?
Ce1 Ce4 Ce7 107.572(16) 1_655 . ?
Ce2 Ce4 Ce7 152.086(17) 1_655 . ?
Co2 Ce4 Ce5 144.25(3) 2_655 . ?
Ge2 Ce4 Ce5 51.65(2) . . ?
Ge3 Ce4 Ce5 51.80(2) . . ?
Ge2 Ce4 Ce5 96.11(2) 3_665 . ?
Ge1 Ce4 Ce5 100.67(2) 2_655 . ?
Ge4 Ce4 Ce5 154.21(2) 2_655 . ?
Ce1 Ce4 Ce5 149.059(18) 1_655 . ?
Ce2 Ce4 Ce5 105.181(16) 1_655 . ?
Ce7 Ce4 Ce5 67.138(13) . . ?
Co2 Ce4 Ce6 90.08(3) 2_655 2_655 ?
Ge2 Ce4 Ce6 51.01(2) . 2_655 ?
Ge3 Ce4 Ce6 154.42(3) . 2_655 ?
Ge2 Ce4 Ce6 95.13(2) 3_665 2_655 ?
Ge1 Ce4 Ce6 100.49(2) 2_655 2_655 ?
Ge4 Ce4 Ce6 51.56(2) 2_655 2_655 ?
Ce1 Ce4 Ce6 102.929(16) 1_655 2_655 ?
Ce2 Ce4 Ce6 138.941(16) 1_655 2_655 ?
Ce7 Ce4 Ce6 67.745(13) . 2_655 ?
Ce5 Ce4 Ce6 102.658(16) . 2_655 ?
Co2 Ce4 Ce3 87.66(3) 2_655 1_655 ?
Ge2 Ce4 Ce3 141.57(2) . 1_655 ?
Ge3 Ce4 Ce3 49.98(2) . 1_655 ?
Ge2 Ce4 Ce3 105.45(2) 3_665 1_655 ?
Ge1 Ce4 Ce3 53.11(2) 2_655 1_655 ?
Ge4 Ce4 Ce3 107.39(2) 2_655 1_655 ?
Ce1 Ce4 Ce3 53.591(13) 1_655 1_655 ?
Ce2 Ce4 Ce3 53.190(12) 1_655 1_655 ?
Ce7 Ce4 Ce3 99.823(15) . 1_655 ?
Ce5 Ce4 Ce3 96.246(15) . 1_655 ?
Ce6 Ce4 Ce3 150.333(16) 2_655 1_655 ?
Co2 Ce5 Ge4 107.64(3) 4_565 . ?
Co2 Ce5 Ge2 48.73(3) 4_565 . ?
Ge4 Ce5 Ge2 86.38(2) . . ?
Co2 Ce5 Ge1 107.95(3) 4_565 . ?
Ge4 Ce5 Ge1 86.99(3) . . ?
Ge2 Ce5 Ge1 151.58(3) . . ?
Co2 Ce5 Ge3 131.17(3) 4_565 . ?
Ge4 Ce5 Ge3 105.42(3) . . ?
Ge2 Ce5 Ge3 99.72(3) . . ?
Ge1 Ce5 Ge3 108.69(3) . . ?
Co2 Ce5 Ge4 49.33(3) 4_565 4_565 ?
Ge4 Ce5 Ge4 151.22(4) . 4_565 ?
Ge2 Ce5 Ge4 87.05(2) . 4_565 ?
Ge1 Ce5 Ge4 85.59(2) . 4_565 ?
Ge3 Ce5 Ge4 103.29(3) . 4_565 ?
Co2 Ce5 Ce3 51.20(3) 4_565 4_565 ?
Ge4 Ce5 Ce3 100.02(2) . 4_565 ?
Ge2 Ce5 Ce3 97.28(2) . 4_565 ?
Ge1 Ce5 Ce3 56.87(2) . 4_565 ?
Ge3 Ce5 Ce3 150.10(2) . 4_565 ?
Ge4 Ce5 Ce3 53.20(2) 4_565 4_565 ?
Co2 Ce5 Ce7 146.54(3) 4_565 2_645 ?
Ge4 Ce5 Ce7 100.84(2) . 2_645 ?
Ge2 Ce5 Ce7 152.57(2) . 2_645 ?
Ge1 Ce5 Ce7 55.81(2) . 2_645 ?
Ge3 Ce5 Ce7 52.873(19) . 2_645 ?
Ge4 Ce5 Ce7 97.82(2) 4_565 2_645 ?
Ce3 Ce5 Ce7 107.276(16) 4_565 2_645 ?
Co2 Ce5 Ce2 49.25(2) 4_565 . ?
Ge4 Ce5 Ce2 58.43(2) . . ?
Ge2 Ce5 Ce2 51.699(19) . . ?
Ge1 Ce5 Ce2 101.94(2) . . ?
Ge3 Ce5 Ce2 144.66(2) . . ?
Ge4 Ce5 Ce2 96.12(2) 4_565 . ?
Ce3 Ce5 Ce2 63.659(14) 4_565 . ?
Ce7 Ce5 Ce2 152.425(17) 2_645 . ?
Co2 Ce5 Ce6 143.12(3) 4_565 . ?
Ge4 Ce5 Ce6 52.87(2) . . ?
Ge2 Ce5 Ce6 95.61(2) . . ?
Ge1 Ce5 Ce6 102.23(2) . . ?
Ge3 Ce5 Ce6 52.562(19) . . ?
Ge4 Ce5 Ce6 155.83(3) 4_565 . ?
Ce3 Ce5 Ce6 149.027(17) 4_565 . ?
Ce7 Ce5 Ce6 69.360(13) 2_645 . ?
Ce2 Ce5 Ce6 104.379(15) . . ?
Co2 Ce5 Ce6 91.23(3) 4_565 4_565 ?
Ge4 Ce5 Ce6 156.39(3) . 4_565 ?
Ge2 Ce5 Ce6 96.18(2) . 4_565 ?
Ge1 Ce5 Ce6 100.85(2) . 4_565 ?
Ge3 Ce5 Ce6 50.980(18) . 4_565 ?
Ge4 Ce5 Ce6 52.32(2) 4_565 4_565 ?
Ce3 Ce5 Ce6 102.911(15) 4_565 4_565 ?
Ce7 Ce5 Ce6 66.958(13) 2_645 4_565 ?
Ce2 Ce5 Ce6 138.948(16) . 4_565 ?
Ce6 Ce5 Ce6 103.542(17) . 4_565 ?
Co2 Ce5 Ce4 89.85(3) 4_565 . ?
Ge4 Ce5 Ce4 98.19(2) . . ?
Ge2 Ce5 Ce4 49.306(19) . . ?
Ge1 Ce5 Ce4 159.10(2) . . ?
Ge3 Ce5 Ce4 50.418(19) . . ?
Ge4 Ce5 Ce4 98.59(2) 4_565 . ?
Ce3 Ce5 Ce4 140.466(17) 4_565 . ?
Ce7 Ce5 Ce4 103.291(17) 2_645 . ?
Ce2 Ce5 Ce4 97.976(15) . . ?
Ce6 Ce5 Ce4 66.326(13) . . ?
Ce6 Ce5 Ce4 67.051(13) 4_565 . ?
Co1 Ce6 Ge3 109.06(3) 2_645 4_566 ?
Co1 Ce6 Ge2 48.29(3) 2_645 2_645 ?
Ge3 Ce6 Ge2 87.32(3) 4_566 2_645 ?
Co1 Ce6 Ge1 108.36(3) 2_645 2_655 ?
Ge3 Ce6 Ge1 86.48(2) 4_566 2_655 ?
Ge2 Ce6 Ge1 151.43(3) 2_645 2_655 ?
Co1 Ce6 Ge3 48.75(3) 2_645 . ?
Ge3 Ce6 Ge3 151.80(4) 4_566 . ?
Ge2 Ce6 Ge3 86.53(2) 2_645 . ?
Ge1 Ce6 Ge3 85.88(2) 2_655 . ?
Co1 Ce6 Ge4 131.05(3) 2_645 . ?
Ge3 Ce6 Ge4 104.79(3) 4_566 . ?
Ge2 Ce6 Ge4 100.55(3) 2_645 . ?
Ge1 Ce6 Ge4 108.00(3) 2_655 . ?
Ge3 Ce6 Ge4 103.40(3) . . ?
Co1 Ce6 Ce3 51.72(3) 2_645 1_655 ?
Ge3 Ce6 Ce3 100.30(2) 4_566 1_655 ?
Ge2 Ce6 Ce3 97.12(2) 2_645 1_655 ?
Ge1 Ce6 Ce3 56.80(2) 2_655 1_655 ?
Ge3 Ce6 Ce3 53.36(2) . 1_655 ?
Ge4 Ce6 Ce3 149.80(2) . 1_655 ?
Co1 Ce6 Ce7 147.66(3) 2_645 . ?
Ge3 Ce6 Ce7 98.66(2) 4_566 . ?
Ge2 Ce6 Ce7 152.52(2) 2_645 . ?
Ge1 Ce6 Ce7 56.05(2) 2_655 . ?
Ge3 Ce6 Ce7 99.43(2) . . ?
Ge4 Ce6 Ce7 51.971(19) . . ?
Ce3 Ce6 Ce7 108.008(16) 1_655 . ?
Co1 Ce6 Ce2 49.85(2) 2_645 4_666 ?
Ge3 Ce6 Ce2 59.28(2) 4_566 4_666 ?
Ge2 Ce6 Ce2 52.038(19) 2_645 4_666 ?
Ge1 Ce6 Ce2 101.51(2) 2_655 4_666 ?
Ge3 Ce6 Ce2 95.87(2) . 4_666 ?
Ge4 Ce6 Ce2 145.59(2) . 4_666 ?
Ce3 Ce6 Ce2 63.306(14) 1_655 4_666 ?
Ce7 Ce6 Ce2 151.399(17) . 4_666 ?
Co1 Ce6 Ce5 90.02(3) 2_645 . ?
Ge3 Ce6 Ce5 155.89(3) 4_566 . ?
Ge2 Ce6 Ce5 95.20(2) 2_645 . ?
Ge1 Ce6 Ce5 101.73(2) 2_655 . ?
Ge3 Ce6 Ce5 52.24(2) . . ?
Ge4 Ce6 Ce5 51.156(19) . . ?
Ce3 Ce6 Ce5 103.155(16) 1_655 . ?
Ce7 Ce6 Ce5 68.799(13) . . ?
Ce2 Ce6 Ce5 138.385(16) 4_666 . ?
Co1 Ce6 Ce5 144.32(3) 2_645 4_566 ?
Ge3 Ce6 Ce5 52.40(2) 4_566 4_566 ?
Ge2 Ce6 Ce5 97.10(2) 2_645 4_566 ?
Ge1 Ce6 Ce5 101.04(2) 2_655 4_566 ?
Ge3 Ce6 Ce5 155.79(3) . 4_566 ?
Ge4 Ce6 Ce5 52.396(18) . 4_566 ?
Ce3 Ce6 Ce5 148.338(17) 1_655 4_566 ?
Ce7 Ce6 Ce5 66.998(13) . 4_566 ?
Ce2 Ce6 Ce5 105.250(15) 4_666 4_566 ?
Ce5 Ce6 Ce5 103.547(17) . 4_566 ?
Co1 Ce6 Ce4 88.81(3) 2_645 2_645 ?
Ge3 Ce6 Ce4 98.83(2) 4_566 2_645 ?
Ge2 Ce6 Ce4 49.136(19) 2_645 2_645 ?
Ge1 Ce6 Ce4 159.41(2) 2_655 2_645 ?
Ge3 Ce6 Ce4 97.81(2) . 2_645 ?
Ge4 Ce6 Ce4 51.417(18) . 2_645 ?
Ce3 Ce6 Ce4 139.981(17) 1_655 2_645 ?
Ce7 Ce6 Ce4 103.383(17) . 2_645 ?
Ce2 Ce6 Ce4 98.262(15) 4_666 2_645 ?
Ce5 Ce6 Ce4 66.055(13) . 2_645 ?
Ce5 Ce6 Ce4 67.923(13) 4_566 2_645 ?
Co1 Ce7 Ge4 106.87(3) . . ?
Co1 Ce7 Ge2 48.14(3) . . ?
Ge4 Ce7 Ge2 86.27(3) . . ?
Co1 Ce7 Ge1 106.89(3) . 4_566 ?
Ge4 Ce7 Ge1 86.59(3) . 4_566 ?
Ge2 Ce7 Ge1 149.85(3) . 4_566 ?
Co1 Ce7 Ge3 48.79(3) . 2_655 ?
Ge4 Ce7 Ge3 149.83(3) . 2_655 ?
Ge2 Ce7 Ge3 86.28(3) . 2_655 ?
Ge1 Ce7 Ge3 85.33(3) 4_566 2_655 ?
Co1 Ce7 Ge1 131.71(3) . 2_655 ?
Ge4 Ce7 Ge1 105.75(3) . 2_655 ?
Ge2 Ce7 Ge1 100.45(3) . 2_655 ?
Ge1 Ce7 Ge1 109.68(2) 4_566 2_655 ?
Ge3 Ce7 Ge1 104.35(3) 2_655 2_655 ?
Co1 Ce7 Ce1 50.88(3) . . ?
Ge4 Ce7 Ce1 99.13(2) . . ?
Ge2 Ce7 Ce1 96.32(2) . . ?
Ge1 Ce7 Ce1 56.10(2) 4_566 . ?
Ge3 Ce7 Ce1 52.83(2) 2_655 . ?
Ge1 Ce7 Ce1 150.70(2) 2_655 . ?
Co1 Ce7 Ce7 146.87(3) . 3_666 ?
Ge4 Ce7 Ce7 101.01(2) . 3_666 ?
Ge2 Ce7 Ce7 153.27(3) . 3_666 ?
Ge1 Ce7 Ce7 56.84(2) 4_566 3_666 ?
Ge3 Ce7 Ce7 98.72(2) 2_655 3_666 ?
Ge1 Ce7 Ce7 52.840(19) 2_655 3_666 ?
Ce1 Ce7 Ce7 107.66(2) . 3_666 ?
Co1 Ce7 Ce6 143.67(3) . . ?
Ge4 Ce7 Ce6 53.51(2) . . ?
Ge2 Ce7 Ce6 96.81(2) . . ?
Ge1 Ce7 Ce6 102.28(2) 4_566 . ?
Ge3 Ce7 Ce6 156.60(3) 2_655 . ?
Ge1 Ce7 Ce6 52.258(19) 2_655 . ?
Ce1 Ce7 Ce6 148.530(18) . . ?
Ce7 Ce7 Ce6 68.638(16) 3_666 . ?
Co1 Ce7 Ce5 90.66(3) . 2_655 ?
Ge4 Ce7 Ce5 157.41(3) . 2_655 ?
Ge2 Ce7 Ce5 95.52(2) . 2_655 ?
Ge1 Ce7 Ce5 102.14(2) 4_566 2_655 ?
Ge3 Ce7 Ce5 52.61(2) 2_655 2_655 ?
Ge1 Ce7 Ce5 51.746(19) 2_655 2_655 ?
Ce1 Ce7 Ce5 103.031(16) . 2_655 ?
Ce7 Ce7 Ce5 68.129(16) 3_666 2_655 ?
Ce6 Ce7 Ce5 104.003(16) . 2_655 ?
Co1 Ce7 Ce2 49.00(3) . . ?
Ge4 Ce7 Ce2 57.89(2) . . ?
Ge2 Ce7 Ce2 51.26(2) . . ?
Ge1 Ce7 Ce2 100.84(2) 4_566 . ?
Ge3 Ce7 Ce2 95.30(2) 2_655 . ?
Ge1 Ce7 Ce2 144.65(2) 2_655 . ?
Ce1 Ce7 Ce2 63.190(14) . . ?
Ce7 Ce7 Ce2 152.18(2) 3_666 . ?
Ce6 Ce7 Ce2 104.743(16) . . ?
Ce5 Ce7 Ce2 138.052(17) 2_655 . ?
Co1 Ce7 Ce4 89.67(3) . . ?
Ge4 Ce7 Ce4 98.50(2) . . ?
Ge2 Ce7 Ce4 49.575(19) . . ?
Ge1 Ce7 Ce4 160.56(2) 4_566 . ?
Ge3 Ce7 Ce4 98.73(2) 2_655 . ?
Ge1 Ce7 Ce4 50.881(18) 2_655 . ?
Ce1 Ce7 Ce4 140.040(17) . . ?
Ce7 Ce7 Ce4 103.72(2) 3_666 . ?
Ce6 Ce7 Ce4 67.098(13) . . ?
Ce5 Ce7 Ce4 66.770(13) 2_655 . ?
Ce2 Ce7 Ce4 97.707(15) . . ?
Ce4 Ge1 Ce5 84.95(2) 2_645 . ?
Ce4 Ge1 Ce7 144.47(3) 2_645 4_565 ?
Ce5 Ge1 Ce7 84.29(2) . 4_565 ?
Ce4 Ge1 Ce6 84.83(2) 2_645 2_645 ?
Ce5 Ge1 Ce6 144.13(3) . 2_645 ?
Ce7 Ge1 Ce6 84.37(2) 4_565 2_645 ?
Ce4 Ge1 Ce1 139.62(3) 2_645 4_565 ?
Ce5 Ge1 Ce1 129.13(3) . 4_565 ?
Ce7 Ge1 Ce1 69.65(2) 4_565 4_565 ?
Ce6 Ge1 Ce1 77.34(2) 2_645 4_565 ?
Ce4 Ge1 Ce3 128.12(3) 2_645 4_565 ?
Ce5 Ge1 Ce3 68.82(2) . 4_565 ?
Ce7 Ge1 Ce3 78.24(2) 4_565 4_565 ?
Ce6 Ge1 Ce3 140.71(3) 2_645 4_565 ?
Ce1 Ge1 Ce3 63.64(2) 4_565 4_565 ?
Ce4 Ge1 Ce3 76.36(2) 2_645 2_545 ?
Ce5 Ge1 Ce3 140.52(3) . 2_545 ?
Ce7 Ge1 Ce3 129.67(3) 4_565 2_545 ?
Ce6 Ge1 Ce3 68.86(2) 2_645 2_545 ?
Ce1 Ge1 Ce3 63.47(2) 4_565 2_545 ?
Ce3 Ge1 Ce3 96.06(3) 4_565 2_545 ?
Ce4 Ge1 Ce1 67.97(2) 2_645 2_545 ?
Ce5 Ge1 Ce1 77.65(2) . 2_545 ?
Ce7 Ge1 Ce1 141.14(3) 4_565 2_545 ?
Ce6 Ge1 Ce1 128.84(3) 2_645 2_545 ?
Ce1 Ge1 Ce1 95.87(3) 4_565 2_545 ?
Ce3 Ge1 Ce1 63.23(2) 4_565 2_545 ?
Ce3 Ge1 Ce1 63.18(2) 2_545 2_545 ?
Ce4 Ge1 Ce7 74.15(2) 2_645 2_645 ?
Ce5 Ge1 Ce7 72.44(2) . 2_645 ?
Ce7 Ge1 Ce7 70.31(2) 4_565 2_645 ?
Ce6 Ge1 Ce7 71.69(2) 2_645 2_645 ?
Ce1 Ge1 Ce7 130.98(3) 4_565 2_645 ?
Ce3 Ge1 Ce7 131.78(3) 4_565 2_645 ?
Ce3 Ge1 Ce7 132.15(3) 2_545 2_645 ?
Ce1 Ge1 Ce7 133.15(3) 2_545 2_645 ?
Co1 Ge2 Co2 112.27(5) . 4_565 ?
Co1 Ge2 Ce4 123.94(4) . . ?
Co2 Ge2 Ce4 123.77(4) 4_565 . ?
Co1 Ge2 Ce2 62.58(4) . . ?
Co2 Ge2 Ce2 62.01(3) 4_565 . ?
Ce4 Ge2 Ce2 145.27(3) . . ?
Co1 Ge2 Ce4 132.42(4) . 3_665 ?
Co2 Ge2 Ce4 61.39(3) 4_565 3_665 ?
Ce4 Ge2 Ce4 80.74(3) . 3_665 ?
Ce2 Ge2 Ce4 121.82(3) . 3_665 ?
Co1 Ge2 Ce6 62.34(4) . 2_655 ?
Co2 Ge2 Ce6 132.78(4) 4_565 2_655 ?
Ce4 Ge2 Ce6 79.85(3) . 2_655 ?
Ce2 Ge2 Ce6 123.37(3) . 2_655 ?
Ce4 Ge2 Ce6 87.51(3) 3_665 2_655 ?
Co1 Ge2 Ce2 62.95(3) . 3_565 ?
Co2 Ge2 Ce2 62.59(4) 4_565 3_565 ?
Ce4 Ge2 Ce2 146.49(3) . 3_565 ?
Ce2 Ge2 Ce2 68.24(2) . 3_565 ?
Ce4 Ge2 Ce2 75.15(2) 3_665 3_565 ?
Ce6 Ge2 Ce2 76.22(2) 2_655 3_565 ?
Co1 Ge2 Ce7 62.00(3) . . ?
Co2 Ge2 Ce7 132.42(4) 4_565 . ?
Ce4 Ge2 Ce7 78.55(2) . . ?
Ce2 Ge2 Ce7 76.75(2) . . ?
Ce4 Ge2 Ce7 159.29(4) 3_665 . ?
Ce6 Ge2 Ce7 88.87(3) 2_655 . ?
Ce2 Ge2 Ce7 123.60(3) 3_565 . ?
Co1 Ge2 Ce5 132.17(5) . . ?
Co2 Ge2 Ce5 61.43(4) 4_565 . ?
Ce4 Ge2 Ce5 79.05(3) . . ?
Ce2 Ge2 Ce5 75.80(2) . . ?
Ce4 Ge2 Ce5 88.72(3) 3_665 . ?
Ce6 Ge2 Ce5 158.90(4) 2_655 . ?
Ce2 Ge2 Ce5 122.67(3) 3_565 . ?
Ce7 Ge2 Ce5 87.35(3) . . ?
Co1 Ge3 Ce1 61.67(4) 2_645 2_645 ?
Co1 Ge3 Ce3 62.15(4) 2_645 1_655 ?
Ce1 Ge3 Ce3 76.69(3) 2_645 1_655 ?
Co1 Ge3 Ce6 135.25(4) 2_645 4_565 ?
Ce1 Ge3 Ce6 80.97(3) 2_645 4_565 ?
Ce3 Ge3 Ce6 134.60(3) 1_655 4_565 ?
Co1 Ge3 Ce4 135.12(4) 2_645 . ?
Ce1 Ge3 Ce4 133.67(3) 2_645 . ?
Ce3 Ge3 Ce4 79.78(2) 1_655 . ?
Ce6 Ge3 Ce4 88.22(3) 4_565 . ?
Co1 Ge3 Ce5 116.85(4) 2_645 . ?
Ce1 Ge3 Ce5 140.60(3) 2_645 . ?
Ce3 Ge3 Ce5 140.52(3) 1_655 . ?
Ce6 Ge3 Ce5 76.62(3) 4_565 . ?
Ce4 Ge3 Ce5 77.78(2) . . ?
Co1 Ge3 Ce7 61.04(3) 2_645 2_645 ?
Ce1 Ge3 Ce7 71.74(2) 2_645 2_645 ?
Ce3 Ge3 Ce7 122.81(3) 1_655 2_645 ?
Ce6 Ge3 Ce7 85.47(2) 4_565 2_645 ?
Ce4 Ge3 Ce7 152.30(4) . 2_645 ?
Ce5 Ge3 Ce7 74.52(2) . 2_645 ?
Co1 Ge3 Ce6 61.06(3) 2_645 . ?
Ce1 Ge3 Ce6 122.23(3) 2_645 . ?
Ce3 Ge3 Ce6 71.07(2) 1_655 . ?
Ce6 Ge3 Ce6 151.82(4) 4_565 . ?
Ce4 Ge3 Ce6 85.64(2) . . ?
Ce5 Ge3 Ce6 75.19(2) . . ?
Ce7 Ge3 Ce6 87.31(3) 2_645 . ?
Co1 Ge3 Ce2 108.50(4) 2_645 1_655 ?
Ce1 Ge3 Ce2 63.62(2) 2_645 1_655 ?
Ce3 Ge3 Ce2 63.48(2) 1_655 1_655 ?
Ce6 Ge3 Ce2 71.22(2) 4_565 1_655 ?
Ce4 Ge3 Ce2 70.22(2) . 1_655 ?
Ce5 Ge3 Ce2 134.65(3) . 1_655 ?
Ce7 Ge3 Ce2 131.92(3) 2_645 1_655 ?
Ce6 Ge3 Ce2 131.22(3) . 1_655 ?
Co2 Ge4 Ce3 61.22(4) . . ?
Co2 Ge4 Ce1 61.84(3) . 2_545 ?
Ce3 Ge4 Ce1 76.68(3) . 2_545 ?
Co2 Ge4 Ce5 135.66(4) . . ?
Ce3 Ge4 Ce5 135.69(3) . . ?
Ce1 Ge4 Ce5 81.31(2) 2_545 . ?
Co2 Ge4 Ce7 135.06(4) . . ?
Ce3 Ge4 Ce7 81.88(3) . . ?
Ce1 Ge4 Ce7 136.30(3) 2_545 . ?
Ce5 Ge4 Ce7 88.46(3) . . ?
Co2 Ge4 Ce4 60.20(3) . 2_645 ?
Ce3 Ge4 Ce4 120.90(3) . 2_645 ?
Ce1 Ge4 Ce4 70.07(2) 2_545 2_645 ?
Ce5 Ge4 Ce4 85.57(2) . 2_645 ?
Ce7 Ge4 Ce4 151.53(4) . 2_645 ?
Co2 Ge4 Ce6 117.58(4) . . ?
Ce3 Ge4 Ce6 140.08(3) . . ?
Ce1 Ge4 Ce6 141.13(3) 2_545 . ?
Ce5 Ge4 Ce6 75.98(2) . . ?
Ce7 Ge4 Ce6 74.52(2) . . ?
Ce4 Ge4 Ce6 77.03(2) 2_645 . ?
Co2 Ge4 Ce5 60.42(3) . 4_566 ?
Ce3 Ge4 Ce5 70.86(2) . 4_566 ?
Ce1 Ge4 Ce5 121.87(3) 2_545 4_566 ?
Ce5 Ge4 Ce5 151.25(4) . 4_566 ?
Ce7 Ge4 Ce5 84.84(2) . 4_566 ?
Ce4 Ge4 Ce5 87.14(2) 2_645 4_566 ?
Ce6 Ge4 Ce5 75.28(2) . 4_566 ?
Co2 Ge4 Ce2 108.96(4) . . ?
Ce3 Ge4 Ce2 64.35(2) . . ?
Ce1 Ge4 Ce2 64.20(2) 2_545 . ?
Ce5 Ge4 Ce2 71.50(2) . . ?
Ce7 Ge4 Ce2 72.24(2) . . ?
Ce4 Ge4 Ce2 131.04(3) 2_645 . ?
Ce6 Ge4 Ce2 133.45(3) . . ?
Ce5 Ge4 Ce2 131.72(3) 4_566 . ?
Co2 Co1 Ge2 123.70(6) 2 . ?
Co2 Co1 Ge3 117.96(6) 2 2_655 ?
Ge2 Co1 Ge3 118.31(6) . 2_655 ?
Co2 Co1 Ce1 66.59(4) 2 . ?
Ge2 Co1 Ce1 140.00(5) . . ?
Ge3 Co1 Ce1 68.23(4) 2_655 . ?
Co2 Co1 Ce3 65.15(4) 2 2 ?
Ge2 Co1 Ce3 138.45(5) . 2 ?
Ge3 Co1 Ce3 68.17(4) 2_655 2 ?
Ce1 Co1 Ce3 81.52(3) . 2 ?
Co2 Co1 Ce7 133.56(6) 2 . ?
Ge2 Co1 Ce7 69.86(4) . . ?
Ge3 Co1 Ce7 70.18(4) 2_655 . ?
Ce1 Co1 Ce7 77.26(3) . . ?
Ce3 Co1 Ce7 137.81(4) 2 . ?
Co2 Co1 Ce6 130.52(6) 2 2_655 ?
Ge2 Co1 Ce6 69.37(4) . 2_655 ?
Ge3 Co1 Ce6 70.19(4) 2_655 2_655 ?
Ce1 Co1 Ce6 137.70(5) . 2_655 ?
Ce3 Co1 Ce6 76.28(3) 2 2_655 ?
Ce7 Co1 Ce6 95.83(4) . 2_655 ?
Co2 Co1 Ce2 66.98(4) 2 . ?
Ge2 Co1 Ce2 69.00(4) . . ?
Ge3 Co1 Ce2 144.52(5) 2_655 . ?
Ce1 Co1 Ce2 84.74(4) . . ?
Ce3 Co1 Ce2 131.81(5) 2 . ?
Ce7 Co1 Ce2 82.07(3) . . ?
Ce6 Co1 Ce2 136.26(4) 2_655 . ?
Co2 Co1 Ce2 65.31(4) 2 3_565 ?
Ge2 Co1 Ce2 69.13(4) . 3_565 ?
Ge3 Co1 Ce2 143.18(5) 2_655 3_565 ?
Ce1 Co1 Ce2 131.61(5) . 3_565 ?
Ce3 Co1 Ce2 83.31(3) 2 3_565 ?
Ce7 Co1 Ce2 137.14(4) . 3_565 ?
Ce6 Co1 Ce2 81.05(3) 2_655 3_565 ?
Ce2 Co1 Ce2 72.20(3) . 3_565 ?
Co1 Co2 Ge2 123.99(6) 2_545 4_566 ?
Co1 Co2 Ge4 117.94(6) 2_545 . ?
Ge2 Co2 Ge4 118.04(6) 4_566 . ?
Co1 Co2 Ce3 66.84(4) 2_545 . ?
Ge2 Co2 Ce3 139.76(5) 4_566 . ?
Ge4 Co2 Ce3 68.10(4) . . ?
Co1 Co2 Ce4 130.00(6) 2_545 2_645 ?
Ge2 Co2 Ce4 69.57(4) 4_566 2_645 ?
Ge4 Co2 Ce4 70.27(4) . 2_645 ?
Ce3 Co2 Ce4 137.60(4) . 2_645 ?
Co1 Co2 Ce1 65.42(4) 2_545 2_545 ?
Ge2 Co2 Ce1 138.46(5) 4_566 2_545 ?
Ge4 Co2 Ce1 67.88(4) . 2_545 ?
Ce3 Co2 Ce1 81.73(3) . 2_545 ?
Ce4 Co2 Ce1 75.63(3) 2_645 2_545 ?
Co1 Co2 Ce5 133.27(6) 2_545 4_566 ?
Ge2 Co2 Ce5 69.84(4) 4_566 4_566 ?
Ge4 Co2 Ce5 70.25(4) . 4_566 ?
Ce3 Co2 Ce5 76.74(3) . 4_566 ?
Ce4 Co2 Ce5 96.62(4) 2_645 4_566 ?
Ce1 Co2 Ce5 137.57(5) 2_545 4_566 ?
Co1 Co2 Ce2 67.38(4) 2_545 4_566 ?
Ge2 Co2 Ce2 68.94(4) 4_566 4_566 ?
Ge4 Co2 Ce2 144.31(5) . 4_566 ?
Ce3 Co2 Ce2 84.82(3) . 4_566 ?
Ce4 Co2 Ce2 136.30(5) 2_645 4_566 ?
Ce1 Co2 Ce2 132.50(5) 2_545 4_566 ?
Ce5 Co2 Ce2 81.52(3) 4_566 4_566 ?
Co1 Co2 Ce2 65.78(4) 2_545 2_545 ?
Ge2 Co2 Ce2 68.92(4) 4_566 2_545 ?
Ge4 Co2 Ce2 143.15(5) . 2_545 ?
Ce3 Co2 Ce2 132.31(5) . 2_545 ?
Ce4 Co2 Ce2 80.46(3) 2_645 2_545 ?
Ce1 Co2 Ce2 83.80(3) 2_545 2_545 ?
Ce5 Co2 Ce2 136.87(4) 4_566 2_545 ?
Ce2 Co2 Ce2 72.48(3) 4_566 2_545 ?

_refine_diff_density_max         1.406
_refine_diff_density_min         -1.184
_refine_diff_density_rms         0.298

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 1497453'
_audit_update_record             
;
2016-08-03 deposited with the CCDC.
2016-10-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Co2 Ge4 La7'
_chemical_formula_weight         1380.59

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.4109(2)
_cell_length_b                   12.5208(4)
_cell_length_c                   12.5096(3)
_cell_angle_alpha                90
_cell_angle_beta                 109.680(2)
_cell_angle_gamma                90
_cell_volume                     1387.93(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    6.607
_exptl_crystal_F_000             2324
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    31.800
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            24102
_diffrn_reflns_av_unetI/netI     0.0415
_diffrn_reflns_av_R_equivalents  0.0759
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.816
_diffrn_reflns_theta_max         30.332
_diffrn_reflns_theta_full        25.240
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             4128
_reflns_number_gt                3107
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0677P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_extinction_coef       0.00147(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         4128
_refine_ls_number_parameters     119
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0502
_refine_ls_R_factor_gt           0.0409
_refine_ls_wR_factor_ref         0.0989
_refine_ls_wR_factor_gt          0.0967
_refine_ls_goodness_of_fit_ref   0.879
_refine_ls_restrained_S_all      0.879
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
La1 La 0.00232(5) 0.61664(3) 0.33979(4) 0.01780(11) Uani 1 1 d . . . . .
La2 La 0.00205(5) 0.39809(3) 0.10208(4) 0.01615(11) Uani 1 1 d . . . . .
La3 La -0.00029(5) 0.33878(4) 0.38254(4) 0.01777(11) Uani 1 1 d . . . . .
La4 La 0.64307(5) 0.49675(3) 0.16241(4) 0.01599(11) Uani 1 1 d . . . . .
La5 La 0.36203(5) 0.24669(3) 0.09390(4) 0.01594(11) Uani 1 1 d . . . . .
La6 La 0.63700(5) 0.25130(3) 0.41245(4) 0.01613(11) Uani 1 1 d . . . . .
La7 La 0.36813(5) 0.49684(3) 0.34522(4) 0.01664(11) Uani 1 1 d . . . . .
Ge1 Ge 0.25352(10) -0.00002(6) 0.06313(7) 0.01664(17) Uani 1 1 d . . . . .
Ge2 Ge 0.29454(10) 0.50025(7) 0.07429(8) 0.01737(17) Uani 1 1 d . . . . .
Ge3 Ge 0.72394(11) 0.24807(6) 0.18159(7) 0.01718(18) Uani 1 1 d . . . . .
Ge4 Ge 0.27313(11) 0.25005(6) 0.31827(7) 0.01692(17) Uani 1 1 d . . . . .
Co1 Co 0.13694(14) 0.61904(9) 0.15558(10) 0.0208(2) Uani 1 1 d . . . . .
Co2 Co 0.13393(14) 0.12109(9) 0.41413(10) 0.0207(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
La1 Co1 2.9804(12) . ?
La1 Co2 2.9990(12) 2 ?
La1 Ge3 3.1433(10) 2_655 ?
La1 Ge4 3.1570(10) 2 ?
La1 Ge1 3.3284(10) 4_566 ?
La1 Ge1 3.3726(10) 2 ?
La1 La3 3.5212(6) . ?
La1 La3 3.5244(6) 3_566 ?
La1 La2 3.6013(6) 2 ?
La1 La4 3.6817(7) 1_455 ?
La1 La7 3.7348(7) . ?
La1 La3 3.9289(6) 2 ?
La2 Co2 3.0152(12) 4_565 ?
La2 Co1 3.0234(12) . ?
La2 Co2 3.0495(12) 2 ?
La2 Co1 3.0506(12) 3_565 ?
La2 Ge2 3.1588(10) . ?
La2 Ge2 3.1829(10) 3_565 ?
La2 Ge4 3.5512(10) . ?
La2 La3 3.5935(6) . ?
La2 La1 3.6013(6) 2_545 ?
La2 La2 3.6014(8) 3_565 ?
La2 La4 3.9021(6) 1_455 ?
La2 La5 3.9133(6) . ?
La3 Co2 2.9741(12) . ?
La3 Co1 3.0064(13) 2_545 ?
La3 Ge4 3.1456(10) . ?
La3 Ge3 3.1545(10) 1_455 ?
La3 Ge1 3.3541(10) 4_566 ?
La3 Ge1 3.3623(10) 2 ?
La3 La1 3.5244(6) 3_566 ?
La3 La5 3.7000(7) 4_566 ?
La3 La6 3.7218(7) 1_455 ?
La3 La1 3.9290(6) 2_545 ?
La4 Co2 3.0163(12) 2_655 ?
La4 Ge2 3.0887(10) . ?
La4 Ge3 3.1952(9) . ?
La4 Ge2 3.2070(10) 3_665 ?
La4 Ge1 3.2382(10) 2_655 ?
La4 Ge4 3.2573(9) 2_655 ?
La4 La1 3.6816(7) 1_655 ?
La4 La2 3.9021(6) 1_655 ?
La4 La7 3.9887(7) . ?
La4 La5 4.0008(7) . ?
La4 La6 4.0397(7) 2_655 ?
La4 La4 4.0495(9) 3_665 ?
La5 Co2 3.0257(13) 4_565 ?
La5 Ge4 3.1878(9) . ?
La5 Ge3 3.2074(11) . ?
La5 Ge2 3.2308(9) . ?
La5 Ge1 3.2355(9) . ?
La5 Ge4 3.2630(10) 4_565 ?
La5 La3 3.7000(7) 4_565 ?
La5 La7 3.9386(6) 2_645 ?
La5 La6 3.9539(7) . ?
La5 La6 3.9757(7) 4_565 ?
La6 Co1 3.0350(12) 2_645 ?
La6 Ge3 3.1859(10) 4_566 ?
La6 Ge2 3.2017(9) 2_645 ?
La6 Ge4 3.2245(11) . ?
La6 Ge3 3.2562(9) . ?
La6 Ge1 3.2616(9) 2_655 ?
La6 La3 3.7218(7) 1_655 ?
La6 La7 3.8895(7) . ?
La6 La2 3.9293(7) 4_666 ?
La6 La5 3.9756(7) 4_566 ?
La6 La4 4.0397(7) 2_645 ?
La7 Co1 3.0375(13) . ?
La7 Ge4 3.2028(9) . ?
La7 Ge2 3.2230(10) . ?
La7 Ge3 3.2500(9) 2_655 ?
La7 Ge1 3.2521(10) 4_566 ?
La7 Ge1 3.3533(10) 2_655 ?
La7 La7 3.8326(9) 3_666 ?
La7 La5 3.9386(6) 2_655 ?
Ge1 La4 3.2383(10) 2_645 ?
Ge1 La7 3.2521(10) 4_565 ?
Ge1 La6 3.2615(9) 2_645 ?
Ge1 La1 3.3284(10) 4_565 ?
Ge1 La7 3.3532(10) 2_645 ?
Ge1 La3 3.3541(10) 4_565 ?
Ge1 La3 3.3624(10) 2_545 ?
Ge1 La1 3.3726(10) 2_545 ?
Ge2 Co1 2.5420(14) . ?
Ge2 Co2 2.5626(15) 4_565 ?
Ge2 La2 3.1829(10) 3_565 ?
Ge2 La6 3.2017(9) 2_655 ?
Ge2 La4 3.2069(10) 3_665 ?
Ge3 Co1 2.5840(14) 2_645 ?
Ge3 La1 3.1433(10) 2_645 ?
Ge3 La3 3.1545(10) 1_655 ?
Ge3 La6 3.1859(10) 4_565 ?
Ge3 La7 3.2499(9) 2_645 ?
Ge4 Co2 2.6113(14) . ?
Ge4 La1 3.1571(10) 2_545 ?
Ge4 La4 3.2574(9) 2_645 ?
Ge4 La5 3.2630(10) 4_566 ?
Co1 Co2 2.4005(17) 2 ?
Co1 Ge3 2.5840(14) 2_655 ?
Co1 La3 3.0063(12) 2 ?
Co1 La6 3.0350(12) 2_655 ?
Co1 La2 3.0506(12) 3_565 ?
Co2 Co1 2.4005(17) 2_545 ?
Co2 Ge2 2.5626(15) 4_566 ?
Co2 La1 2.9990(12) 2_545 ?
Co2 La2 3.0152(12) 4_566 ?
Co2 La4 3.0163(12) 2_645 ?
Co2 La5 3.0256(13) 4_566 ?
Co2 La2 3.0495(12) 2_545 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Co1 La1 Co2 47.34(3) . 2 ?
Co1 La1 Ge3 49.83(3) . 2_655 ?
Co2 La1 Ge3 88.31(3) 2 2_655 ?
Co1 La1 Ge4 89.06(3) . 2 ?
Co2 La1 Ge4 50.12(3) 2 2 ?
Ge3 La1 Ge4 101.15(3) 2_655 2 ?
Co1 La1 Ge1 106.66(3) . 4_566 ?
Co2 La1 Ge1 145.76(3) 2 4_566 ?
Ge3 La1 Ge1 86.00(3) 2_655 4_566 ?
Ge4 La1 Ge1 163.56(2) 2 4_566 ?
Co1 La1 Ge1 145.45(3) . 2 ?
Co2 La1 Ge1 106.68(3) 2 2 ?
Ge3 La1 Ge1 164.22(2) 2_655 2 ?
Ge4 La1 Ge1 85.39(2) 2 2 ?
Ge1 La1 Ge1 84.21(3) 4_566 2 ?
Co1 La1 La3 98.85(3) . . ?
Co2 La1 La3 99.02(3) 2 . ?
Ge3 La1 La3 125.31(2) 2_655 . ?
Ge4 La1 La3 124.86(2) 2 . ?
Ge1 La1 La3 58.558(18) 4_566 . ?
Ge1 La1 La3 58.336(17) 2 . ?
Co1 La1 La3 154.85(3) . 3_566 ?
Co2 La1 La3 153.98(3) 2 3_566 ?
Ge3 La1 La3 106.11(2) 2_655 3_566 ?
Ge4 La1 La3 104.93(2) 2 3_566 ?
Ge1 La1 La3 58.684(18) 4_566 3_566 ?
Ge1 La1 La3 58.147(18) 2 3_566 ?
La3 La1 La3 90.238(13) . 3_566 ?
Co1 La1 La2 100.54(3) . 2 ?
Co2 La1 La2 99.54(3) 2 2 ?
Ge3 La1 La2 64.551(18) 2_655 2 ?
Ge4 La1 La2 62.995(19) 2 2 ?
Ge1 La1 La2 108.24(2) 4_566 2 ?
Ge1 La1 La2 107.040(19) 2 2 ?
La3 La1 La2 159.230(17) . 2 ?
La3 La1 La2 69.012(13) 3_566 2 ?
Co1 La1 La4 94.66(3) . 1_455 ?
Co2 La1 La4 52.48(2) 2 1_455 ?
Ge3 La1 La4 140.78(2) 2_655 1_455 ?
Ge4 La1 La4 56.261(19) 2 1_455 ?
Ge1 La1 La4 125.14(2) 4_566 1_455 ?
Ge1 La1 La4 54.438(18) 2 1_455 ?
La3 La1 La4 68.701(13) . 1_455 ?
La3 La1 La4 110.482(15) 3_566 1_455 ?
La2 La1 La4 116.748(16) 2 1_455 ?
Co1 La1 La7 52.33(3) . . ?
Co2 La1 La7 95.13(3) 2 . ?
Ge3 La1 La7 55.595(19) 2_655 . ?
Ge4 La1 La7 141.38(2) 2 . ?
Ge1 La1 La7 54.463(18) 4_566 . ?
Ge1 La1 La7 125.80(2) 2 . ?
La3 La1 La7 69.753(13) . . ?
La3 La1 La7 110.890(16) 3_566 . ?
La2 La1 La7 117.546(16) 2 . ?
La4 La1 La7 120.063(15) 1_455 . ?
Co1 La1 La3 49.27(2) . 2 ?
Co2 La1 La3 48.60(2) 2 2 ?
Ge3 La1 La3 51.530(19) 2_655 2 ?
Ge4 La1 La3 51.305(18) 2 2 ?
Ge1 La1 La3 137.52(2) 4_566 2 ?
Ge1 La1 La3 136.69(2) 2 2 ?
La3 La1 La3 143.934(14) . 2 ?
La3 La1 La3 125.818(12) 3_566 2 ?
La2 La1 La3 56.807(12) 2 2 ?
La4 La1 La3 94.440(15) 1_455 2 ?
La7 La1 La3 94.698(14) . 2 ?
Co2 La2 Co1 89.60(3) 4_565 . ?
Co2 La2 Co2 107.14(3) 4_565 2 ?
Co1 La2 Co2 46.56(3) . 2 ?
Co2 La2 Co1 46.62(3) 4_565 3_565 ?
Co1 La2 Co1 107.27(3) . 3_565 ?
Co2 La2 Co1 88.46(3) 2 3_565 ?
Co2 La2 Ge2 48.98(3) 4_565 . ?
Co1 La2 Ge2 48.50(3) . . ?
Co2 La2 Ge2 89.06(3) 2 . ?
Co1 La2 Ge2 89.52(3) 3_565 . ?
Co2 La2 Ge2 89.23(3) 4_565 3_565 ?
Co1 La2 Ge2 89.56(3) . 3_565 ?
Co2 La2 Ge2 48.50(3) 2 3_565 ?
Co1 La2 Ge2 48.07(3) 3_565 3_565 ?
Ge2 La2 Ge2 110.79(2) . 3_565 ?
Co2 La2 Ge4 99.99(3) 4_565 . ?
Co1 La2 Ge4 99.71(3) . . ?
Co2 La2 Ge4 134.93(3) 2 . ?
Co1 La2 Ge4 135.27(3) 3_565 . ?
Ge2 La2 Ge4 82.30(2) . . ?
Ge2 La2 Ge4 166.90(2) 3_565 . ?
Co2 La2 La3 152.17(3) 4_565 . ?
Co1 La2 La3 96.50(2) . . ?
Co2 La2 La3 96.53(2) 2 . ?
Co1 La2 La3 151.12(3) 3_565 . ?
Ge2 La2 La3 118.89(2) . . ?
Ge2 La2 La3 117.85(2) 3_565 . ?
Ge4 La2 La3 52.237(17) . . ?
Co2 La2 La1 96.62(2) 4_565 2_545 ?
Co1 La2 La1 152.03(3) . 2_545 ?
Co2 La2 La1 151.20(3) 2 2_545 ?
Co1 La2 La1 96.58(2) 3_565 2_545 ?
Ge2 La2 La1 119.21(2) . 2_545 ?
Ge2 La2 La1 117.67(2) 3_565 2_545 ?
Ge4 La2 La1 52.379(16) . 2_545 ?
La3 La2 La1 66.197(13) . 2_545 ?
Co2 La2 La2 54.01(2) 4_565 3_565 ?
Co1 La2 La2 53.99(2) . 3_565 ?
Co2 La2 La2 53.13(2) 2 3_565 ?
Co1 La2 La2 53.29(2) 3_565 3_565 ?
Ge2 La2 La2 55.71(2) . 3_565 ?
Ge2 La2 La2 55.08(2) 3_565 3_565 ?
Ge4 La2 La2 138.02(2) . 3_565 ?
La3 La2 La2 146.79(2) . 3_565 ?
La1 La2 La2 146.98(2) 2_545 3_565 ?
Co2 La2 La4 141.87(3) 4_565 1_455 ?
Co1 La2 La4 89.65(2) . 1_455 ?
Co2 La2 La4 49.59(2) 2 1_455 ?
Co1 La2 La4 97.79(3) 3_565 1_455 ?
Ge2 La2 La4 137.42(2) . 1_455 ?
Ge2 La2 La4 52.642(18) 3_565 1_455 ?
Ge4 La2 La4 117.686(19) . 1_455 ?
La3 La2 La4 65.557(12) . 1_455 ?
La1 La2 La4 101.609(14) 2_545 1_455 ?
La2 La2 La4 96.294(17) 3_565 1_455 ?
Co2 La2 La5 49.74(2) 4_565 . ?
Co1 La2 La5 98.42(3) . . ?
Co2 La2 La5 142.13(3) 2 . ?
Co1 La2 La5 90.30(2) 3_565 . ?
Ge2 La2 La5 53.071(18) . . ?
Ge2 La2 La5 137.76(2) 3_565 . ?
Ge4 La2 La5 50.275(16) . . ?
La3 La2 La5 102.440(15) . . ?
La1 La2 La5 66.428(12) 2_545 . ?
La2 La2 La5 97.317(17) 3_565 . ?
La4 La2 La5 166.390(15) 1_455 . ?
Co2 La3 Co1 47.33(3) . 2_545 ?
Co2 La3 Ge4 50.42(3) . . ?
Co1 La3 Ge4 88.81(3) 2_545 . ?
Co2 La3 Ge3 88.54(3) . 1_455 ?
Co1 La3 Ge3 49.52(3) 2_545 1_455 ?
Ge4 La3 Ge3 101.15(3) . 1_455 ?
Co2 La3 Ge1 106.73(3) . 4_566 ?
Co1 La3 Ge1 145.82(3) 2_545 4_566 ?
Ge4 La3 Ge1 85.78(3) . 4_566 ?
Ge3 La3 Ge1 164.08(3) 1_455 4_566 ?
Co2 La3 Ge1 145.23(3) . 2 ?
Co1 La3 Ge1 106.67(3) 2_545 2 ?
Ge4 La3 Ge1 163.77(3) . 2 ?
Ge3 La3 Ge1 85.89(2) 1_455 2 ?
Ge1 La3 Ge1 83.97(3) 4_566 2 ?
Co2 La3 La1 154.33(3) . . ?
Co1 La3 La1 154.77(3) 2_545 . ?
Ge4 La3 La1 105.19(2) . . ?
Ge3 La3 La1 106.30(2) 1_455 . ?
Ge1 La3 La1 57.847(18) 4_566 . ?
Ge1 La3 La1 58.620(18) 2 . ?
Co2 La3 La1 99.04(3) . 3_566 ?
Co1 La3 La1 99.05(2) 2_545 3_566 ?
Ge4 La3 La1 125.75(2) . 3_566 ?
Ge3 La3 La1 124.50(2) 1_455 3_566 ?
Ge1 La3 La1 58.658(18) 4_566 3_566 ?
Ge1 La3 La1 57.745(18) 2 3_566 ?
La1 La3 La1 89.762(13) . 3_566 ?
Co2 La3 La2 100.20(2) . . ?
Co1 La3 La2 100.21(3) 2_545 . ?
Ge4 La3 La2 63.190(19) . . ?
Ge3 La3 La2 64.548(19) 1_455 . ?
Ge1 La3 La2 107.22(2) 4_566 . ?
Ge1 La3 La2 108.12(2) 2 . ?
La1 La3 La2 69.200(13) . . ?
La1 La3 La2 158.962(17) 3_566 . ?
Co2 La3 La5 52.56(3) . 4_566 ?
Co1 La3 La5 95.20(3) 2_545 4_566 ?
Ge4 La3 La5 56.234(19) . 4_566 ?
Ge3 La3 La5 141.10(2) 1_455 4_566 ?
Ge1 La3 La5 54.334(18) 4_566 4_566 ?
Ge1 La3 La5 125.07(2) 2 4_566 ?
La1 La3 La5 110.026(16) . 4_566 ?
La1 La3 La5 69.579(14) 3_566 4_566 ?
La2 La3 La5 116.762(16) . 4_566 ?
Co2 La3 La6 94.57(3) . 1_455 ?
Co1 La3 La6 52.32(2) 2_545 1_455 ?
Ge4 La3 La6 141.13(2) . 1_455 ?
Ge3 La3 La6 55.795(19) 1_455 1_455 ?
Ge1 La3 La6 125.36(2) 4_566 1_455 ?
Ge1 La3 La6 54.541(17) 2 1_455 ?
La1 La3 La6 111.075(15) . 1_455 ?
La1 La3 La6 68.778(13) 3_566 1_455 ?
La2 La3 La6 117.796(17) . 1_455 ?
La5 La3 La6 119.916(15) 4_566 1_455 ?
Co2 La3 La1 49.14(2) . 2_545 ?
Co1 La3 La1 48.70(2) 2_545 2_545 ?
Ge4 La3 La1 51.567(18) . 2_545 ?
Ge3 La3 La1 51.274(18) 1_455 2_545 ?
Ge1 La3 La1 137.35(2) 4_566 2_545 ?
Ge1 La3 La1 137.16(2) 2 2_545 ?
La1 La3 La1 126.196(12) . 2_545 ?
La1 La3 La1 144.040(14) 3_566 2_545 ?
La2 La3 La1 56.996(12) . 2_545 ?
La5 La3 La1 94.859(14) 4_566 2_545 ?
La6 La3 La1 94.406(14) 1_455 2_545 ?
Co2 La4 Ge2 130.40(3) 2_655 . ?
Co2 La4 Ge3 110.68(3) 2_655 . ?
Ge2 La4 Ge3 103.77(3) . . ?
Co2 La4 Ge2 48.51(3) 2_655 3_665 ?
Ge2 La4 Ge2 99.96(2) . 3_665 ?
Ge3 La4 Ge2 88.15(2) . 3_665 ?
Co2 La4 Ge1 109.71(3) 2_655 2_655 ?
Ge2 La4 Ge1 106.39(3) . 2_655 ?
Ge3 La4 Ge1 87.34(2) . 2_655 ?
Ge2 La4 Ge1 153.60(3) 3_665 2_655 ?
Co2 La4 Ge4 49.01(3) 2_655 2_655 ?
Ge2 La4 Ge4 102.37(3) . 2_655 ?
Ge3 La4 Ge4 153.85(3) . 2_655 ?
Ge2 La4 Ge4 86.68(2) 3_665 2_655 ?
Ge1 La4 Ge4 86.01(2) 2_655 2_655 ?
Co2 La4 La1 52.05(2) 2_655 1_655 ?
Ge2 La4 La1 149.16(2) . 1_655 ?
Ge3 La4 La1 101.82(2) . 1_655 ?
Ge2 La4 La1 97.77(2) 3_665 1_655 ?
Ge1 La4 La1 57.912(19) 2_655 1_655 ?
Ge4 La4 La1 53.705(19) 2_655 1_655 ?
Co2 La4 La2 50.34(2) 2_655 1_655 ?
Ge2 La4 La2 145.08(2) . 1_655 ?
Ge3 La4 La2 60.407(19) . 1_655 ?
Ge2 La4 La2 52.083(18) 3_665 1_655 ?
Ge1 La4 La2 103.79(2) 2_655 1_655 ?
Ge4 La4 La2 96.82(2) 2_655 1_655 ?
La1 La4 La2 64.310(12) 1_655 1_655 ?
Co2 La4 La7 146.81(3) 2_655 . ?
Ge2 La4 La7 52.317(19) . . ?
Ge3 La4 La7 98.12(2) . . ?
Ge2 La4 La7 152.27(2) 3_665 . ?
Ge1 La4 La7 54.089(18) 2_655 . ?
Ge4 La4 La7 98.327(19) 2_655 . ?
La1 La4 La7 107.197(15) 1_655 . ?
La2 La4 La7 151.886(16) 1_655 . ?
Co2 La4 La5 144.72(3) 2_655 . ?
Ge2 La4 La5 52.316(18) . . ?
Ge3 La4 La5 51.46(2) . . ?
Ge2 La4 La5 97.17(2) 3_665 . ?
Ge1 La4 La5 100.24(2) 2_655 . ?
Ge4 La4 La5 154.68(2) 2_655 . ?
La1 La4 La5 148.741(17) 1_655 . ?
La2 La4 La5 105.294(14) 1_655 . ?
La7 La4 La5 67.254(12) . . ?
Co2 La4 La6 89.35(3) 2_655 2_655 ?
Ge2 La4 La6 51.284(18) . 2_655 ?
Ge3 La4 La6 155.04(2) . 2_655 ?
Ge2 La4 La6 94.86(2) 3_665 2_655 ?
Ge1 La4 La6 100.11(2) 2_655 2_655 ?
Ge4 La4 La6 51.085(19) 2_655 2_655 ?
La1 La4 La6 102.303(14) 1_655 2_655 ?
La2 La4 La6 138.136(15) 1_655 2_655 ?
La7 La4 La6 68.538(12) . 2_655 ?
La5 La4 La6 103.599(16) . 2_655 ?
Co2 La4 La4 88.27(3) 2_655 3_665 ?
Ge2 La4 La4 51.260(19) . 3_665 ?
Ge3 La4 La4 98.98(2) . 3_665 ?
Ge2 La4 La4 48.697(19) 3_665 3_665 ?
Ge1 La4 La4 157.59(3) 2_655 3_665 ?
Ge4 La4 La4 96.75(2) 2_655 3_665 ?
La1 La4 La4 139.636(19) 1_655 3_665 ?
La2 La4 La4 97.976(16) 1_655 3_665 ?
La7 La4 La4 103.577(18) . 3_665 ?
La5 La4 La4 68.441(14) . 3_665 ?
La6 La4 La4 65.801(14) 2_655 3_665 ?
Co2 La5 Ge4 108.44(3) 4_565 . ?
Co2 La5 Ge3 131.08(3) 4_565 . ?
Ge4 La5 Ge3 105.20(3) . . ?
Co2 La5 Ge2 48.22(3) 4_565 . ?
Ge4 La5 Ge2 87.18(2) . . ?
Ge3 La5 Ge2 100.35(2) . . ?
Co2 La5 Ge1 108.51(3) 4_565 . ?
Ge4 La5 Ge1 87.22(2) . . ?
Ge3 La5 Ge1 107.58(2) . . ?
Ge2 La5 Ge1 152.01(3) . . ?
Co2 La5 Ge4 48.89(3) 4_565 4_565 ?
Ge4 La5 Ge4 151.68(4) . 4_565 ?
Ge3 La5 Ge4 103.07(3) . 4_565 ?
Ge2 La5 Ge4 86.19(2) . 4_565 ?
Ge1 La5 Ge4 85.87(2) . 4_565 ?
Co2 La5 La3 51.30(2) 4_565 4_565 ?
Ge4 La5 La3 100.43(2) . 4_565 ?
Ge3 La5 La3 149.64(2) . 4_565 ?
Ge2 La5 La3 96.87(2) . 4_565 ?
Ge1 La5 La3 57.375(19) . 4_565 ?
Ge4 La5 La3 53.264(19) 4_565 4_565 ?
Co2 La5 La2 49.51(2) 4_565 . ?
Ge4 La5 La2 58.961(19) . . ?
Ge3 La5 La2 144.82(2) . . ?
Ge2 La5 La2 51.405(18) . . ?
Ge1 La5 La2 102.96(2) . . ?
Ge4 La5 La2 96.05(2) 4_565 . ?
La3 La5 La2 63.975(13) 4_565 . ?
Co2 La5 La7 145.91(3) 4_565 2_645 ?
Ge4 La5 La7 100.58(2) . 2_645 ?
Ge3 La5 La7 52.907(17) . 2_645 ?
Ge2 La5 La7 153.21(2) . 2_645 ?
Ge1 La5 La7 54.675(19) . 2_645 ?
Ge4 La5 La7 97.669(19) 4_565 2_645 ?
La3 La5 La7 106.705(14) 4_565 2_645 ?
La2 La5 La7 152.520(15) . 2_645 ?
Co2 La5 La6 143.21(3) 4_565 . ?
Ge4 La5 La6 52.35(2) . . ?
Ge3 La5 La6 52.847(18) . . ?
Ge2 La5 La6 96.16(2) . . ?
Ge1 La5 La6 101.95(2) . . ?
Ge4 La5 La6 155.88(2) 4_565 . ?
La3 La5 La6 149.010(16) 4_565 . ?
La2 La5 La6 104.187(14) . . ?
La7 La5 La6 69.892(13) 2_645 . ?
Co2 La5 La6 90.43(2) 4_565 4_565 ?
Ge4 La5 La6 156.48(2) . 4_565 ?
Ge3 La5 La6 51.307(18) . 4_565 ?
Ge2 La5 La6 95.711(19) . 4_565 ?
Ge1 La5 La6 100.263(19) . 4_565 ?
Ge4 La5 La6 51.769(19) 4_565 4_565 ?
La3 La5 La6 102.369(14) 4_565 4_565 ?
La2 La5 La6 138.375(15) . 4_565 ?
La7 La5 La6 67.305(12) 2_645 4_565 ?
La6 La5 La6 104.148(16) . 4_565 ?
Co2 La5 La4 89.05(2) 4_565 . ?
Ge4 La5 La4 98.72(2) . . ?
Ge3 La5 La4 51.191(17) . . ?
Ge2 La5 La4 49.164(18) . . ?
Ge1 La5 La4 158.76(2) . . ?
Ge4 La5 La4 97.603(19) 4_565 . ?
La3 La5 La4 139.736(16) 4_565 . ?
La2 La5 La4 97.524(13) . . ?
La7 La5 La4 104.094(16) 2_645 . ?
La6 La5 La4 67.146(12) . . ?
La6 La5 La4 66.852(12) 4_565 . ?
Co1 La6 Ge3 110.05(3) 2_645 4_566 ?
Co1 La6 Ge2 48.01(3) 2_645 2_645 ?
Ge3 La6 Ge2 88.40(2) 4_566 2_645 ?
Co1 La6 Ge4 130.79(3) 2_645 . ?
Ge3 La6 Ge4 104.44(3) 4_566 . ?
Ge2 La6 Ge4 100.64(2) 2_645 . ?
Co1 La6 Ge3 48.34(3) 2_645 . ?
Ge3 La6 Ge3 152.31(4) 4_566 . ?
Ge2 La6 Ge3 85.84(2) 2_645 . ?
Ge4 La6 Ge3 103.24(3) . . ?
Co1 La6 Ge1 108.54(3) 2_645 2_655 ?
Ge3 La6 Ge1 86.45(2) 4_566 2_655 ?
Ge2 La6 Ge1 151.72(3) 2_645 2_655 ?
Ge4 La6 Ge1 107.58(2) . 2_655 ?
Ge3 La6 Ge1 85.94(2) . 2_655 ?
Co1 La6 La3 51.63(2) 2_645 1_655 ?
Ge3 La6 La3 100.82(2) 4_566 1_655 ?
Ge2 La6 La3 96.82(2) 2_645 1_655 ?
Ge4 La6 La3 149.52(2) . 1_655 ?
Ge3 La6 La3 53.245(19) . 1_655 ?
Ge1 La6 La3 57.108(18) 2_655 1_655 ?
Co1 La6 La7 146.83(3) 2_645 . ?
Ge3 La6 La7 98.24(2) 4_566 . ?
Ge2 La6 La7 153.14(2) 2_645 . ?
Ge4 La6 La7 52.507(17) . . ?
Ge3 La6 La7 99.06(2) . . ?
Ge1 La6 La7 55.086(18) 2_655 . ?
La3 La6 La7 107.309(14) 1_655 . ?
Co1 La6 La2 49.96(2) 2_645 4_666 ?
Ge3 La6 La2 60.132(19) 4_566 4_666 ?
Ge2 La6 La2 51.800(19) 2_645 4_666 ?
Ge4 La6 La2 145.41(2) . 4_666 ?
Ge3 La6 La2 95.73(2) . 4_666 ?
Ge1 La6 La2 102.33(2) 2_655 4_666 ?
La3 La6 La2 63.626(13) 1_655 4_666 ?
La7 La6 La2 151.602(16) . 4_666 ?
Co1 La6 La5 89.55(3) 2_645 . ?
Ge3 La6 La5 155.94(2) 4_566 . ?
Ge2 La6 La5 95.16(2) 2_645 . ?
Ge4 La6 La5 51.512(18) . . ?
Ge3 La6 La5 51.73(2) . . ?
Ge1 La6 La5 100.79(2) 2_655 . ?
La3 La6 La5 102.364(14) 1_655 . ?
La7 La6 La5 68.674(12) . . ?
La2 La6 La5 138.065(15) 4_666 . ?
Co1 La6 La5 144.69(3) 2_645 4_566 ?
Ge3 La6 La5 51.79(2) 4_566 4_566 ?
Ge2 La6 La5 97.755(19) 2_645 4_566 ?
Ge4 La6 La5 52.647(18) . 4_566 ?
Ge3 La6 La5 155.89(2) . 4_566 ?
Ge1 La6 La5 100.737(19) 2_655 4_566 ?
La3 La6 La5 148.307(16) 1_655 4_566 ?
La7 La6 La5 67.500(12) . 4_566 ?
La2 La6 La5 105.259(14) 4_666 4_566 ?
La5 La6 La5 104.159(16) . 4_566 ?
Co1 La6 La4 88.21(3) 2_645 2_645 ?
Ge3 La6 La4 99.34(2) 4_566 2_645 ?
Ge2 La6 La4 48.825(19) 2_645 2_645 ?
Ge4 La6 La4 51.813(17) . 2_645 ?
Ge3 La6 La4 97.11(2) . 2_645 ?
Ge1 La6 La4 159.35(2) 2_655 2_645 ?
La3 La6 La4 139.269(16) 1_655 2_645 ?
La7 La6 La4 104.320(16) . 2_645 ?
La2 La6 La4 97.695(13) 4_666 2_645 ?
La5 La6 La4 66.447(12) . 2_645 ?
La5 La6 La4 68.779(12) 4_566 2_645 ?
Co1 La7 Ge4 107.62(3) . . ?
Co1 La7 Ge2 47.80(3) . . ?
Ge4 La7 Ge2 87.05(2) . . ?
Co1 La7 Ge3 48.39(3) . 2_655 ?
Ge4 La7 Ge3 150.19(3) . 2_655 ?
Ge2 La7 Ge3 85.60(2) . 2_655 ?
Co1 La7 Ge1 107.22(3) . 4_566 ?
Ge4 La7 Ge1 86.58(2) . 4_566 ?
Ge2 La7 Ge1 150.09(3) . 4_566 ?
Ge3 La7 Ge1 85.55(2) 2_655 4_566 ?
Co1 La7 Ge1 131.29(3) . 2_655 ?
Ge4 La7 Ge1 105.90(2) . 2_655 ?
Ge2 La7 Ge1 100.76(2) . 2_655 ?
Ge3 La7 Ge1 103.85(2) 2_655 2_655 ?
Ge1 La7 Ge1 109.09(2) 4_566 2_655 ?
Co1 La7 La1 50.96(2) . . ?
Ge4 La7 La1 99.36(2) . . ?
Ge2 La7 La1 96.04(2) . . ?
Ge3 La7 La1 52.937(19) 2_655 . ?
Ge1 La7 La1 56.388(19) 4_566 . ?
Ge1 La7 La1 150.19(2) 2_655 . ?
Co1 La7 La7 145.95(3) . 3_666 ?
Ge4 La7 La7 100.90(2) . 3_666 ?
Ge2 La7 La7 154.02(3) . 3_666 ?
Ge3 La7 La7 98.26(2) 2_655 3_666 ?
Ge1 La7 La7 55.78(2) 4_566 3_666 ?
Ge1 La7 La7 53.312(19) 2_655 3_666 ?
La1 La7 La7 106.823(18) . 3_666 ?
Co1 La7 La6 144.07(3) . . ?
Ge4 La7 La6 53.01(2) . . ?
Ge2 La7 La6 97.56(2) . . ?
Ge3 La7 La6 156.75(2) 2_655 . ?
Ge1 La7 La6 101.75(2) 4_566 . ?
Ge1 La7 La6 52.900(17) 2_655 . ?
La1 La7 La6 148.205(16) . . ?
La7 La7 La6 69.211(15) 3_666 . ?
Co1 La7 La5 89.80(3) . 2_655 ?
Ge4 La7 La5 157.76(2) . 2_655 ?
Ge2 La7 La5 95.11(2) . 2_655 ?
Ge3 La7 La5 51.93(2) 2_655 2_655 ?
Ge1 La7 La5 101.68(2) 4_566 2_655 ?
Ge1 La7 La5 51.928(17) 2_655 2_655 ?
La1 La7 La5 102.407(14) . 2_655 ?
La7 La7 La5 68.423(15) 3_666 2_655 ?
La6 La7 La5 104.825(16) . 2_655 ?
Co1 La7 La2 49.19(2) . . ?
Ge4 La7 La2 58.440(19) . . ?
Ge2 La7 La2 51.049(18) . . ?
Ge3 La7 La2 95.19(2) 2_655 . ?
Ge1 La7 La2 101.53(2) 4_566 . ?
Ge1 La7 La2 144.84(2) 2_655 . ?
La1 La7 La2 63.382(12) . . ?
La7 La7 La2 152.24(2) 3_666 . ?
La6 La7 La2 104.736(14) . . ?
La5 La7 La2 137.402(16) 2_655 . ?
Co1 La7 La4 89.12(2) . . ?
Ge4 La7 La4 98.71(2) . . ?
Ge2 La7 La4 49.325(19) . . ?
Ge3 La7 La4 98.22(2) 2_655 . ?
Ge1 La7 La4 160.54(2) 4_566 . ?
Ge1 La7 La4 51.457(18) 2_655 . ?
La1 La7 La4 139.607(16) . . ?
La7 La7 La4 104.768(19) 3_666 . ?
La6 La7 La4 67.876(12) . . ?
La5 La7 La4 67.082(12) 2_655 . ?
La2 La7 La4 97.148(14) . . ?
La5 Ge1 La4 85.16(2) . 2_645 ?
La5 Ge1 La7 84.69(2) . 4_565 ?
La4 Ge1 La7 145.36(3) 2_645 4_565 ?
La5 Ge1 La6 145.41(3) . 2_645 ?
La4 Ge1 La6 85.19(2) 2_645 2_645 ?
La7 Ge1 La6 84.65(2) 4_565 2_645 ?
La5 Ge1 La1 128.70(3) . 4_565 ?
La4 Ge1 La1 139.41(3) 2_645 4_565 ?
La7 Ge1 La1 69.15(2) 4_565 4_565 ?
La6 Ge1 La1 76.85(2) 2_645 4_565 ?
La5 Ge1 La7 73.40(2) . 2_645 ?
La4 Ge1 La7 74.45(2) 2_645 2_645 ?
La7 Ge1 La7 70.91(2) 4_565 2_645 ?
La6 Ge1 La7 72.02(2) 2_645 2_645 ?
La1 Ge1 La7 130.85(3) 4_565 2_645 ?
La5 Ge1 La3 68.29(2) . 4_565 ?
La4 Ge1 La3 127.82(3) 2_645 4_565 ?
La7 Ge1 La3 77.88(2) 4_565 4_565 ?
La6 Ge1 La3 140.22(3) 2_645 4_565 ?
La1 Ge1 La3 63.59(2) 4_565 4_565 ?
La7 Ge1 La3 132.12(3) 2_645 4_565 ?
La5 Ge1 La3 139.98(3) . 2_545 ?
La4 Ge1 La3 76.03(2) 2_645 2_545 ?
La7 Ge1 La3 129.38(3) 4_565 2_545 ?
La6 Ge1 La3 68.351(19) 2_645 2_545 ?
La1 Ge1 La3 63.572(19) 4_565 2_545 ?
La7 Ge1 La3 131.85(3) 2_645 2_545 ?
La3 Ge1 La3 96.03(3) 4_565 2_545 ?
La5 Ge1 La1 77.21(2) . 2_545 ?
La4 Ge1 La1 67.65(2) 2_645 2_545 ?
La7 Ge1 La1 140.81(3) 4_565 2_545 ?
La6 Ge1 La1 128.39(3) 2_645 2_545 ?
La1 Ge1 La1 95.79(3) 4_565 2_545 ?
La7 Ge1 La1 133.36(3) 2_645 2_545 ?
La3 Ge1 La1 63.194(19) 4_565 2_545 ?
La3 Ge1 La1 63.043(19) 2_545 2_545 ?
Co1 Ge2 Co2 112.93(5) . 4_565 ?
Co1 Ge2 La4 123.92(4) . . ?
Co2 Ge2 La4 123.13(4) 4_565 . ?
Co1 Ge2 La2 62.97(3) . . ?
Co2 Ge2 La2 62.59(3) 4_565 . ?
La4 Ge2 La2 144.58(3) . . ?
Co1 Ge2 La2 63.24(3) . 3_565 ?
Co2 Ge2 La2 63.03(3) 4_565 3_565 ?
La4 Ge2 La2 146.20(3) . 3_565 ?
La2 Ge2 La2 69.21(2) . 3_565 ?
Co1 Ge2 La6 62.56(3) . 2_655 ?
Co2 Ge2 La6 132.69(4) 4_565 2_655 ?
La4 Ge2 La6 79.89(2) . 2_655 ?
La2 Ge2 La6 124.02(3) . 2_655 ?
La2 Ge2 La6 75.97(2) 3_565 2_655 ?
Co1 Ge2 La4 132.49(4) . 3_665 ?
Co2 Ge2 La4 61.85(3) 4_565 3_665 ?
La4 Ge2 La4 80.04(2) . 3_665 ?
La2 Ge2 La4 122.93(3) . 3_665 ?
La2 Ge2 La4 75.27(2) 3_565 3_665 ?
La6 Ge2 La4 86.57(2) 2_655 3_665 ?
Co1 Ge2 La7 62.28(3) . . ?
Co2 Ge2 La7 132.50(4) 4_565 . ?
La4 Ge2 La7 78.36(2) . . ?
La2 Ge2 La7 76.44(2) . . ?
La2 Ge2 La7 124.19(3) 3_565 . ?
La6 Ge2 La7 89.44(2) 2_655 . ?
La4 Ge2 La7 158.40(3) 3_665 . ?
Co1 Ge2 La5 132.13(4) . . ?
Co2 Ge2 La5 61.70(3) 4_565 . ?
La4 Ge2 La5 78.52(2) . . ?
La2 Ge2 La5 75.52(2) . . ?
La2 Ge2 La5 123.34(3) 3_565 . ?
La6 Ge2 La5 158.41(3) 2_655 . ?
La4 Ge2 La5 89.38(2) 3_665 . ?
La7 Ge2 La5 86.56(2) . . ?
Co1 Ge3 La1 61.81(3) 2_645 2_645 ?
Co1 Ge3 La3 62.25(3) 2_645 1_655 ?
La1 Ge3 La3 77.20(2) 2_645 1_655 ?
Co1 Ge3 La6 135.75(4) 2_645 4_565 ?
La1 Ge3 La6 80.65(2) 2_645 4_565 ?
La3 Ge3 La6 133.70(3) 1_655 4_565 ?
Co1 Ge3 La4 135.49(4) 2_645 . ?
La1 Ge3 La4 133.24(3) 2_645 . ?
La3 Ge3 La4 79.64(2) 1_655 . ?
La6 Ge3 La4 87.04(2) 4_565 . ?
Co1 Ge3 La5 117.64(4) 2_645 . ?
La1 Ge3 La5 140.75(3) 2_645 . ?
La3 Ge3 La5 140.21(3) 1_655 . ?
La6 Ge3 La5 76.90(2) 4_565 . ?
La4 Ge3 La5 77.34(2) . . ?
Co1 Ge3 La7 61.51(3) 2_645 2_645 ?
La1 Ge3 La7 71.47(2) 2_645 2_645 ?
La3 Ge3 La7 123.36(3) 1_655 2_645 ?
La6 Ge3 La7 85.91(2) 4_565 2_645 ?
La4 Ge3 La7 152.49(3) . 2_645 ?
La5 Ge3 La7 75.17(2) . 2_645 ?
Co1 Ge3 La6 61.35(3) 2_645 . ?
La1 Ge3 La6 122.68(3) 2_645 . ?
La3 Ge3 La6 70.96(2) 1_655 . ?
La6 Ge3 La6 152.31(4) 4_565 . ?
La4 Ge3 La6 85.98(2) . . ?
La5 Ge3 La6 75.42(2) . . ?
La7 Ge3 La6 88.03(2) 2_645 . ?
Co2 Ge4 La3 61.38(3) . . ?
Co2 Ge4 La1 61.80(3) . 2_545 ?
La3 Ge4 La1 77.13(2) . 2_545 ?
Co2 Ge4 La5 135.82(4) . . ?
La3 Ge4 La5 135.20(3) . . ?
La1 Ge4 La5 81.09(2) 2_545 . ?
Co2 Ge4 La7 135.53(4) . . ?
La3 Ge4 La7 81.70(2) . . ?
La1 Ge4 La7 135.86(3) 2_545 . ?
La5 Ge4 La7 87.63(2) . . ?
Co2 Ge4 La6 118.06(4) . . ?
La3 Ge4 La6 139.85(3) . . ?
La1 Ge4 La6 141.11(3) 2_545 . ?
La5 Ge4 La6 76.14(2) . . ?
La7 Ge4 La6 74.48(2) . . ?
Co2 Ge4 La4 60.68(3) . 2_645 ?
La3 Ge4 La4 121.56(3) . 2_645 ?
La1 Ge4 La4 70.03(2) 2_545 2_645 ?
La5 Ge4 La4 85.62(2) . 2_645 ?
La7 Ge4 La4 151.58(3) . 2_645 ?
La6 Ge4 La4 77.10(2) . 2_645 ?
Co2 Ge4 La5 60.81(3) . 4_566 ?
La3 Ge4 La5 70.50(2) . 4_566 ?
La1 Ge4 La5 122.19(3) 2_545 4_566 ?
La5 Ge4 La5 151.72(4) . 4_566 ?
La7 Ge4 La5 85.04(2) . 4_566 ?
La6 Ge4 La5 75.58(2) . 4_566 ?
La4 Ge4 La5 87.95(2) 2_645 4_566 ?
Co2 Ge4 La2 109.25(4) . . ?
La3 Ge4 La2 64.57(2) . . ?
La1 Ge4 La2 64.63(2) 2_545 . ?
La5 Ge4 La2 70.76(2) . . ?
La7 Ge4 La2 71.34(2) . . ?
La6 Ge4 La2 132.67(3) . . ?
La4 Ge4 La2 131.19(3) 2_645 . ?
La5 Ge4 La2 131.38(3) 4_566 . ?
Co2 Co1 Ge2 123.52(6) 2 . ?
Co2 Co1 Ge3 118.29(5) 2 2_655 ?
Ge2 Co1 Ge3 118.18(5) . 2_655 ?
Co2 Co1 La1 66.74(4) 2 . ?
Ge2 Co1 La1 139.52(5) . . ?
Ge3 Co1 La1 68.36(3) 2_655 . ?
Co2 Co1 La3 65.63(4) 2 2 ?
Ge2 Co1 La3 138.42(5) . 2 ?
Ge3 Co1 La3 68.22(3) 2_655 2 ?
La1 Co1 La3 82.03(3) . 2 ?
Co2 Co1 La2 67.29(4) 2 . ?
Ge2 Co1 La2 68.54(3) . . ?
Ge3 Co1 La2 144.10(5) 2_655 . ?
La1 Co1 La2 84.59(3) . . ?
La3 Co1 La2 132.61(4) 2 . ?
Co2 Co1 La6 130.63(6) 2 2_655 ?
Ge2 Co1 La6 69.43(3) . 2_655 ?
Ge3 Co1 La6 70.31(3) 2_655 2_655 ?
La1 Co1 La6 137.98(4) . 2_655 ?
La3 Co1 La6 76.06(3) 2 2_655 ?
La2 Co1 La6 135.96(4) . 2_655 ?
Co2 Co1 La7 133.06(5) 2 . ?
Ge2 Co1 La7 69.93(4) . . ?
Ge3 Co1 La7 70.11(4) 2_655 . ?
La1 Co1 La7 76.72(3) . . ?
La3 Co1 La7 137.78(4) 2 . ?
La2 Co1 La7 81.31(3) . . ?
La6 Co1 La7 96.23(4) 2_655 . ?
Co2 Co1 La2 65.91(4) 2 3_565 ?
Ge2 Co1 La2 68.69(3) . 3_565 ?
Ge3 Co1 La2 143.13(5) 2_655 3_565 ?
La1 Co1 La2 132.34(4) . 3_565 ?
La3 Co1 La2 83.60(3) 2 3_565 ?
La2 Co1 La2 72.73(3) . 3_565 ?
La6 Co1 La2 80.43(3) 2_655 3_565 ?
La7 Co1 La2 136.82(4) . 3_565 ?
Co1 Co2 Ge2 123.52(6) 2_545 4_566 ?
Co1 Co2 Ge4 118.38(6) 2_545 . ?
Ge2 Co2 Ge4 118.07(5) 4_566 . ?
Co1 Co2 La3 67.04(4) 2_545 . ?
Ge2 Co2 La3 139.42(5) 4_566 . ?
Ge4 Co2 La3 68.20(3) . . ?
Co1 Co2 La1 65.93(4) 2_545 2_545 ?
Ge2 Co2 La1 138.27(5) 4_566 2_545 ?
Ge4 Co2 La1 68.08(3) . 2_545 ?
La3 Co2 La1 82.26(3) . 2_545 ?
Co1 Co2 La2 67.47(4) 2_545 4_566 ?
Ge2 Co2 La2 68.43(3) 4_566 4_566 ?
Ge4 Co2 La2 144.02(5) . 4_566 ?
La3 Co2 La2 84.76(3) . 4_566 ?
La1 Co2 La2 133.08(4) 2_545 4_566 ?
Co1 Co2 La4 130.27(6) 2_545 2_645 ?
Ge2 Co2 La4 69.63(3) 4_566 2_645 ?
Ge4 Co2 La4 70.31(3) . 2_645 ?
La3 Co2 La4 137.78(4) . 2_645 ?
La1 Co2 La4 75.47(3) 2_545 2_645 ?
La2 Co2 La4 136.01(4) 4_566 2_645 ?
Co1 Co2 La5 132.58(5) 2_545 4_566 ?
Ge2 Co2 La5 70.08(4) 4_566 4_566 ?
Ge4 Co2 La5 70.30(3) . 4_566 ?
La3 Co2 La5 76.15(3) . 4_566 ?
La1 Co2 La5 137.79(4) 2_545 4_566 ?
La2 Co2 La5 80.75(3) 4_566 4_566 ?
La4 Co2 La5 97.07(4) 2_645 4_566 ?
Co1 Co2 La2 66.14(4) 2_545 2_545 ?
Ge2 Co2 La2 68.47(3) 4_566 2_545 ?
Ge4 Co2 La2 143.11(5) . 2_545 ?
La3 Co2 La2 132.87(4) . 2_545 ?
La1 Co2 La2 83.82(3) 2_545 2_545 ?
La2 Co2 La2 72.86(3) 4_566 2_545 ?
La4 Co2 La2 80.07(3) 2_645 2_545 ?
La5 Co2 La2 136.65(4) 4_566 2_545 ?

_refine_diff_density_max         5.045
_refine_diff_density_min         -2.669
_refine_diff_density_rms         0.674

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1506882'
_audit_update_record             
;
2016-10-20 deposited with the CCDC.
2016-10-24 downloaded from the CCDC.
;
#=======================================================================

# 5. CHEMICAL DATA

_chemical_name_systematic        
; ?
;
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac          ?
_chemical_formula_sum            'Co2 Ge4 Pr7'
_chemical_formula_weight         1394.6
_chemical_melting_point          ?
_chemical_compound_source        ?
_chemical_absolute_configuration .

#=======================================================================

# 6. CRYSTAL DATA

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ycb'
_symmetry_Int_Tables_number      14

loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y+1/2,-z+1/2
3 -x,-y,-z
4 x,-y+1/2,z+1/2

_cell_length_a                   9.2373(4)
_cell_length_b                   12.2352(6)
_cell_length_c                   12.2392(6)
_cell_angle_alpha                90
_cell_angle_beta                 109.505(4)
_cell_angle_gamma                90
_cell_volume                     1303.89(11)

loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
_twin_individual_twin_matrix_11
_twin_individual_twin_matrix_12
_twin_individual_twin_matrix_13
_twin_individual_twin_matrix_21
_twin_individual_twin_matrix_22
_twin_individual_twin_matrix_23
_twin_individual_twin_matrix_31
_twin_individual_twin_matrix_32
_twin_individual_twin_matrix_33
1 0.928(4) 1 0 0 0 1 0 0 0 1
2 0.072(4) -1 0 0 0 -1 0 -0.5 0 1

_cell_formula_units_Z            4

_cell_measurement_reflns_used    3894
_cell_measurement_theta_min      2.41
_cell_measurement_theta_max      28.99
_cell_measurement_temperature    293
_cell_special_details            
; ?
;

_exptl_crystal_density_diffrn    7.1041
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             2380

_exptl_absorpt_coefficient_mu    37.07
_exptl_crystal_description       ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_size_rad          ?
_exptl_crystal_colour            ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_correction_T_min  0.473
_exptl_absorpt_correction_T_max  1
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
? ? ? ?

#=======================================================================

# 7. EXPERIMENTAL DATA

_exptl_special_details           ?

_diffrn_ambient_temperature      293
_diffrn_source                   ?
_diffrn_source_power             ?
_diffrn_source_voltage           ?
_diffrn_source_current           ?
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_wavelength     0.7107
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_detector                 ?
_diffrn_detector_area_resol_mean 16.1829
_diffrn_measurement_method       'ω scans'
_diffrn_measurement_specimen_support ?

_diffrn_reflns_number            15137
_diffrn_reflns_theta_min         2.43
_diffrn_reflns_theta_max         29.05
_diffrn_reflns_theta_full        27.93
_diffrn_measured_fraction_theta_max 0.91
_diffrn_measured_fraction_theta_full 0.98
_diffrn_reflns_av_R_equivalents  0.0501
_diffrn_reflns_av_unetI/netI     ?
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_reduction_process ?

_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?

_diffrn_radiation_probe          X-ray

_diffrn_reflns_av_sigmaI/netI    0.0419

#=======================================================================

# 8. REFINEMENT DATA

_refine_special_details          
; ?
;

_reflns_number_total             3188
_reflns_number_gt                2283
_reflns_threshold_expression     I>3σ(I)

_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_gt           0.0307
_refine_ls_wR_factor_gt          0.0839
_refine_ls_R_factor_all          0.0506
_refine_ls_wR_factor_ref         0.0924
_refine_ls_goodness_of_fit_ref   1.37
_refine_ls_goodness_of_fit_gt    1.48
_refine_ls_restrained_S_gt       ?
_refine_ls_restrained_S_all      ?
_refine_ls_number_reflns         3188
_refine_ls_number_parameters     120
_refine_ls_number_restraints     0
_refine_ls_number_constraints    0
_refine_ls_weighting_scheme      sigma
_refine_ls_weighting_details     w=1/(σ²(I)+0.0004I²)
_refine_ls_hydrogen_treatment    ?
_refine_ls_shift/su_max          0.0486
_refine_ls_shift/su_mean         0.0084
_refine_diff_density_max         1.85
_refine_diff_density_min         -1.66
_refine_ls_extinction_method     
'B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)'
_refine_ls_extinction_coef       244(12)
_refine_ls_abs_structure_details ?
_refine_ls_abs_structure_Flack   ?
_refine_ls_abs_structure_Rogers  ?

loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co 0.3494 0.9721 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Ge 0.1547 1.8001 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Pr -0.2180 2.8214 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'

_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_structure_solution    ?
_computing_structure_refinement  ?
_computing_molecular_graphics    ?
_computing_publication_material  ?

loop_
_restr_distance_atom_site_label_1
_restr_distance_site_symmetry_1
_restr_distance_atom_site_label_2
_restr_distance_site_symmetry_2
_restr_distance_target
_restr_distance_target_weight_param
? ? ? ? ? ?

loop_
_restr_angle_atom_site_label_1
_restr_angle_site_symmetry_1
_restr_angle_atom_site_label_2
_restr_angle_site_symmetry_2
_restr_angle_atom_site_label_3
_restr_angle_site_symmetry_3
_restr_angle_target
_restr_angle_target_weight_param
? ? ? ? ? ? ? ?

loop_
_restr_torsion_atom_site_label_1
_restr_torsion_site_symmetry_1
_restr_torsion_atom_site_label_2
_restr_torsion_site_symmetry_2
_restr_torsion_atom_site_label_3
_restr_torsion_site_symmetry_3
_restr_torsion_atom_site_label_4
_restr_torsion_site_symmetry_4
_restr_torsion_angle_target
_restr_torsion_weight_param
? ? ? ? ? ? ? ? ? ?

loop_
_restr_equal_distance_atom_site_label_1
_restr_equal_distance_site_symmetry_1
_restr_equal_distance_atom_site_label_2
_restr_equal_distance_site_symmetry_2
_restr_equal_distance_class_class_id
_restr_equal_distance_class_target_weight_param
? ? ? ? ? ?

loop_
_restr_equal_angle_atom_site_label_1
_restr_equal_angle_site_symmetry_1
_restr_equal_angle_atom_site_label_2
_restr_equal_angle_site_symmetry_2
_restr_equal_angle_atom_site_label_3
_restr_equal_angle_site_symmetry_3
_restr_equal_angle_class_class_id
_restr_equal_angle_class_target_weight_param
? ? ? ? ? ? ? ?

loop_
_restr_equal_torsion_atom_site_label_1
_restr_equal_torsion_site_symmetry_1
_restr_equal_torsion_atom_site_label_2
_restr_equal_torsion_site_symmetry_2
_restr_equal_torsion_atom_site_label_3
_restr_equal_torsion_site_symmetry_3
_restr_equal_torsion_atom_site_label_4
_restr_equal_torsion_site_symmetry_4
_restr_equal_torsion_class_class_id
_restr_equal_torsion_class_target_weight_param
? ? ? ? ? ? ? ? ? ?


#=======================================================================

# 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_site_symmetry_multiplicity
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pr1 Pr 0.00214(9) 0.61890(6) 0.34144(6) Uani 0.0102(2) 4 1 d . . .
Pr2 Pr 0.00213(9) 0.39885(6) 0.10105(6) Uani 0.0088(2) 4 1 d . . .
Pr3 Pr 0.00023(9) 0.34028(6) 0.38051(6) Uani 0.0104(2) 4 1 d . . .
Pr4 Pr 0.64485(8) 0.49790(7) 0.16284(6) Uani 0.0082(2) 4 1 d . . .
Pr5 Pr 0.36195(9) 0.24672(6) 0.09173(6) Uani 0.0088(3) 4 1 d . . .
Pr6 Pr 0.63737(9) 0.25194(6) 0.41116(6) Uani 0.0089(3) 4 1 d . . .
Pr7 Pr 0.36739(8) 0.49843(7) 0.34545(7) Uani 0.0093(2) 4 1 d . . .
Ge1 Ge 0.25103(15) -0.00013(12) 0.06261(12) Uani 0.0093(4) 4 1 d . . .
Ge2 Ge 0.29821(15) 0.50068(12) 0.07541(12) Uani 0.0092(4) 4 1 d . . .
Ge3 Ge 0.72337(18) 0.25033(11) 0.17950(13) Uani 0.0096(5) 4 1 d . . .
Ge4 Ge 0.27465(18) 0.25223(11) 0.31589(13) Uani 0.0095(5) 4 1 d . . .
Co1 Co 0.1366(2) 0.62021(15) 0.15668(16) Uani 0.0129(6) 4 1 d . . .
Co2 Co 0.1348(2) 0.12231(16) 0.41313(16) Uani 0.0131(6) 4 1 d . . .


loop_
_jana_atom_site_ADP_C_label
_jana_atom_site_ADP_C_type_symbol
_jana_atom_site_ADP_C_111
_jana_atom_site_ADP_C_112
_jana_atom_site_ADP_C_113
_jana_atom_site_ADP_C_122
_jana_atom_site_ADP_C_123
_jana_atom_site_ADP_C_133
_jana_atom_site_ADP_C_222
_jana_atom_site_ADP_C_223
_jana_atom_site_ADP_C_233
_jana_atom_site_ADP_C_333
? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_D_label
_jana_atom_site_ADP_D_type_symbol
_jana_atom_site_ADP_D_1111
_jana_atom_site_ADP_D_1112
_jana_atom_site_ADP_D_1113
_jana_atom_site_ADP_D_1122
_jana_atom_site_ADP_D_1123
_jana_atom_site_ADP_D_1133
_jana_atom_site_ADP_D_1222
_jana_atom_site_ADP_D_1223
_jana_atom_site_ADP_D_1233
_jana_atom_site_ADP_D_1333
_jana_atom_site_ADP_D_2222
_jana_atom_site_ADP_D_2223
_jana_atom_site_ADP_D_2233
_jana_atom_site_ADP_D_2333
_jana_atom_site_ADP_D_3333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_E_label
_jana_atom_site_ADP_E_type_symbol
_jana_atom_site_ADP_E_11111
_jana_atom_site_ADP_E_11112
_jana_atom_site_ADP_E_11113
_jana_atom_site_ADP_E_11122
_jana_atom_site_ADP_E_11123
_jana_atom_site_ADP_E_11133
_jana_atom_site_ADP_E_11222
_jana_atom_site_ADP_E_11223
_jana_atom_site_ADP_E_11233
_jana_atom_site_ADP_E_11333
_jana_atom_site_ADP_E_12222
_jana_atom_site_ADP_E_12223
_jana_atom_site_ADP_E_12233
_jana_atom_site_ADP_E_12333
_jana_atom_site_ADP_E_13333
_jana_atom_site_ADP_E_22222
_jana_atom_site_ADP_E_22223
_jana_atom_site_ADP_E_22233
_jana_atom_site_ADP_E_22333
_jana_atom_site_ADP_E_23333
_jana_atom_site_ADP_E_33333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?

loop_
_jana_atom_site_ADP_F_label
_jana_atom_site_ADP_F_type_symbol
_jana_atom_site_ADP_F_111111
_jana_atom_site_ADP_F_111112
_jana_atom_site_ADP_F_111113
_jana_atom_site_ADP_F_111122
_jana_atom_site_ADP_F_111123
_jana_atom_site_ADP_F_111133
_jana_atom_site_ADP_F_111222
_jana_atom_site_ADP_F_111223
_jana_atom_site_ADP_F_111233
_jana_atom_site_ADP_F_111333
_jana_atom_site_ADP_F_112222
_jana_atom_site_ADP_F_112223
_jana_atom_site_ADP_F_112233
_jana_atom_site_ADP_F_112333
_jana_atom_site_ADP_F_113333
_jana_atom_site_ADP_F_122222
_jana_atom_site_ADP_F_122223
_jana_atom_site_ADP_F_122233
_jana_atom_site_ADP_F_122333
_jana_atom_site_ADP_F_123333
_jana_atom_site_ADP_F_133333
_jana_atom_site_ADP_F_222222
_jana_atom_site_ADP_F_222223
_jana_atom_site_ADP_F_222233
_jana_atom_site_ADP_F_222333
_jana_atom_site_ADP_F_223333
_jana_atom_site_ADP_F_233333
_jana_atom_site_ADP_F_333333
? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?


#=======================================================================

# 10. MOLECULAR GEOMETRY


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pr1 Pr2 . 2_555 3.4997(11) ?
Pr1 Pr3 . . 3.4433(11) ?
Pr1 Pr3 . 3_566 3.4468(12) ?
Pr1 Pr4 . 1_455 3.6118(10) ?
Pr1 Pr7 . . 3.6671(12) ?
Pr1 Ge3 . 2_655 3.0845(18) ?
Pr1 Ge4 . 2_555 3.1014(15) ?
Pr1 Co1 . . 2.921(2) ?
Pr1 Co2 . 2_555 2.9458(19) ?
Pr2 Pr2 . 3_565 3.4902(11) ?
Pr2 Pr3 . . 3.5004(12) ?
Pr2 Pr4 . 1_455 3.8209(12) ?
Pr2 Ge2 . . 3.1151(18) ?
Pr2 Ge2 . 3_565 3.1419(14) ?
Pr2 Co1 . . 2.963(2) ?
Pr2 Co1 . 3_565 2.9913(19) ?
Pr2 Co2 . 2_555 2.993(2) ?
Pr2 Co2 . 4_554 2.957(2) ?
Pr3 Pr5 . 4_555 3.6349(10) ?
Pr3 Pr6 . 1_455 3.6583(12) ?
Pr3 Ge3 . 1_455 3.0988(15) ?
Pr3 Ge4 . . 3.0904(19) ?
Pr3 Co1 . 2_545 2.945(2) ?
Pr3 Co2 . . 2.913(2) ?
Pr4 Ge1 . 2_655 3.1715(17) ?
Pr4 Ge2 . . 3.0185(15) ?
Pr4 Ge2 . 3_665 3.1312(19) ?
Pr4 Ge3 . . 3.1055(16) ?
Pr4 Ge4 . 2_655 3.1898(16) ?
Pr4 Co2 . 2_655 2.931(2) ?
Pr5 Ge1 . . 3.1709(17) ?
Pr5 Ge2 . . 3.1565(17) ?
Pr5 Ge3 . . 3.1475(17) ?
Pr5 Ge4 . . 3.108(2) ?
Pr5 Co2 . 4_554 2.9472(18) ?
Pr6 Ge1 . 2_655 3.1854(17) ?
Pr6 Ge2 . 2_645 3.1252(17) ?
Pr6 Ge3 . . 3.190(2) ?
Pr6 Ge3 . 4_555 3.1106(17) ?
Pr6 Ge4 . . 3.1587(17) ?
Pr6 Co1 . 2_645 2.967(2) ?
Pr7 Pr7 . 3_666 3.7585(11) ?
Pr7 Ge1 . 4_555 3.1824(19) ?
Pr7 Ge2 . . 3.1499(17) ?
Pr7 Ge3 . 2_655 3.1818(16) ?
Pr7 Ge4 . . 3.1196(16) ?
Pr7 Co1 . . 2.9688(18) ?
Ge2 Co1 . . 2.520(3) ?
Ge2 Co2 . 4_554 2.547(2) ?
Ge3 Co1 . 2_645 2.549(2) ?
Ge4 Co2 . . 2.576(3) ?
Co1 Co2 . 2_555 2.363(3) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
? ? ? ? ? ? ? ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
? ? ? ? ? ? ? ? ? ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
? ? ? ? ? ? ? ? ? ? ?


####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1506883'
_audit_update_record             
;
2016-10-20 deposited with the CCDC.
2016-10-24 downloaded from the CCDC.
;

_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Eos'
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.6 (release 27-01-2011 CrysAlis171 .NET)
(compiled Jan 27 2011,13:34:29)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.6 (release 27-01-2011 CrysAlis171 .NET)
(compiled Jan 27 2011,13:34:29)
;
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.6 (release 27-01-2011 CrysAlis171 .NET)
(compiled Jan 27 2011,13:34:29)
;
_computing_structure_solution    ?
_computing_structure_refinement  ?
_computing_molecular_graphics    ?
_computing_publication_material  ?
_chemical_formula_sum            'Co2 Ge4 Nd7'
_chemical_formula_weight         1417.9
_chemical_absolute_configuration .
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ycb'
_symmetry_Int_Tables_number      14
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y+1/2,-z+1/2
3 -x,-y,-z
4 x,-y+1/2,z+1/2
_cell_length_a                   9.1859(5)
_cell_length_b                   12.2022(6)
_cell_length_c                   12.2000(8)
_cell_angle_alpha                90
_cell_angle_beta                 109.478(7)
_cell_angle_gamma                90
_cell_volume                     1289.21(14)
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
_twin_individual_twin_matrix_11
_twin_individual_twin_matrix_12
_twin_individual_twin_matrix_13
_twin_individual_twin_matrix_21
_twin_individual_twin_matrix_22
_twin_individual_twin_matrix_23
_twin_individual_twin_matrix_31
_twin_individual_twin_matrix_32
_twin_individual_twin_matrix_33
1 0.491(2) 1 0 0 0 1 0 0 0 1
2 0.1777(15) 1 0 0 -0.25 0 1 0.25 -1 0
3 0.0645(7) 1 0 0 0 -1 0 0.5 0 -1
4 0.2670(15) 1 0 0 0.25 0 -1 0.25 1 0
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4320
_cell_measurement_theta_max      28.82
_cell_measurement_theta_min      2.88
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.296
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.6 (release 27-01-2011 CrysAlis171 .NET)
(compiled Jan 27 2011,13:34:29)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    7.3052
_exptl_crystal_F_000             1204
_exptl_absorpt_coefficient_mu    39.23
_cell_measurement_temperature    293
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          X-ray
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_detector_area_resol_mean 16.1367
_diffrn_measurement_method       'ω scans'
_diffrn_reflns_number            23501
_diffrn_reflns_theta_min         2.88
_diffrn_reflns_theta_max         28.89
_diffrn_reflns_theta_full        28.01
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.93
_diffrn_reflns_av_R_equivalents  0.047
_diffrn_reflns_av_sigmaI/netI    0.0531
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_reflns_number_total             6741
_reflns_number_gt                3901
_reflns_threshold_expression     I>3σ(I)
_refine_ls_R_factor_gt           0.0360
_refine_ls_wR_factor_gt          0.0902
_refine_ls_R_factor_all          0.0747
_refine_ls_wR_factor_ref         0.1087
_refine_ls_goodness_of_fit_ref   1.18
_refine_ls_goodness_of_fit_gt    1.29
_refine_ls_number_reflns         6741
_refine_ls_number_parameters     122
_refine_ls_weighting_scheme      sigma
_refine_ls_weighting_details     w=1/(σ²(I)+0.0004I²)
_refine_ls_shift/su_max          0.0428
_refine_ls_shift/su_mean         0.0059
_refine_diff_density_max         1.47
_refine_diff_density_min         -1.07
_refine_ls_extinction_method     
'B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)'
_refine_ls_number_constraints    0
_refine_ls_number_restraints     0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_extinction_coef       240(30)
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co 0.3494 0.9721 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Ge 0.1547 1.8001 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Nd -0.1943 3.0179 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_site_symmetry_multiplicity
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Nd1 Nd 0.00194(11) 0.61979(6) 0.34163(7) Uani 0.0097(3) 4 0.5 d . . .
Nd2 Nd 0.00196(11) 0.39938(7) 0.10064(7) Uani 0.0090(3) 4 0.5 d . . .
Nd3 Nd -0.00005(11) 0.34043(6) 0.37934(7) Uani 0.0101(3) 4 0.5 d . . .
Nd4 Nd 0.64474(7) 0.49782(8) 0.16282(9) Uani 0.0081(4) 4 0.5 d . . .
Nd5 Nd 0.36154(10) 0.24697(7) 0.09172(9) Uani 0.0085(5) 4 0.5 d . . .
Nd6 Nd 0.63757(10) 0.25180(7) 0.41102(9) Uani 0.0085(5) 4 0.5 d . . .
Nd7 Nd 0.36679(7) 0.49827(8) 0.34496(9) Uani 0.0087(4) 4 0.5 d . . .
Ge1 Ge 0.25176(13) -0.00004(16) 0.06263(17) Uani 0.0094(7) 4 0.5 d . . .
Ge2 Ge 0.29872(13) 0.50071(16) 0.07508(18) Uani 0.0091(7) 4 0.5 d . . .
Ge3 Ge 0.7227(2) 0.25060(14) 0.17877(17) Uani 0.0093(8) 4 0.5 d . . .
Ge4 Ge 0.2760(2) 0.25269(14) 0.31560(17) Uani 0.0089(8) 4 0.5 d . . .
Co1 Co 0.1373(2) 0.62056(18) 0.15735(18) Uani 0.0124(8) 4 0.5 d . . .
Co2 Co 0.1348(2) 0.12245(18) 0.41274(18) Uani 0.0123(7) 4 0.5 d . . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Nd1 Nd2 . 2_555 3.4861(12) ?
Nd1 Nd3 . . 3.4406(11) ?
Nd1 Nd3 . 2_555 3.8060(12) ?
Nd1 Nd3 . 3_566 3.4443(14) ?
Nd1 Nd4 . 1_455 3.6010(12) ?
Nd1 Nd7 . . 3.6527(13) ?
Nd1 Ge3 . 2_655 3.071(2) ?
Nd1 Ge4 . 2_555 3.0920(19) ?
Nd1 Co1 . . 2.909(3) ?
Nd1 Co2 . 2_555 2.934(2) ?
Nd2 Nd2 . 3_565 3.4645(13) ?
Nd2 Nd3 . . 3.4815(14) ?
Nd2 Nd4 . 1_455 3.8008(14) ?
Nd2 Ge2 . . 3.1022(19) ?
Nd2 Ge2 . 3_565 3.1245(17) ?
Nd2 Co1 . . 2.955(2) ?
Nd2 Co1 . 3_565 2.986(2) ?
Nd2 Co2 . 2_555 2.979(2) ?
Nd2 Co2 . 4_554 2.946(3) ?
Nd3 Nd5 . 4_555 3.6254(13) ?
Nd3 Nd6 . 1_455 3.6412(15) ?
Nd3 Ge3 . 1_455 3.0854(19) ?
Nd3 Ge4 . . 3.081(2) ?
Nd3 Co1 . 2_545 2.935(2) ?
Nd3 Co2 . . 2.905(2) ?
Nd4 Ge1 . 2_655 3.162(2) ?
Nd4 Ge2 . . 2.9968(13) ?
Nd4 Ge2 . 3_665 3.114(2) ?
Nd4 Ge3 . . 3.091(2) ?
Nd4 Ge4 . 2_655 3.185(2) ?
Nd4 Co2 . 2_655 2.917(3) ?
Nd5 Ge1 . . 3.161(2) ?
Nd5 Ge2 . . 3.144(2) ?
Nd5 Ge3 . . 3.128(2) ?
Nd5 Ge4 . . 3.085(3) ?
Nd5 Co2 . 4_554 2.935(2) ?
Nd6 Nd7 . . 3.8137(13) ?
Nd6 Ge1 . 2_655 3.176(2) ?
Nd6 Ge2 . 2_645 3.113(2) ?
Nd6 Ge3 . . 3.181(3) ?
Nd6 Ge3 . 4_555 3.095(2) ?
Nd6 Ge4 . . 3.132(2) ?
Nd6 Co1 . 2_645 2.948(3) ?
Nd7 Nd7 . 3_666 3.7587(14) ?
Nd7 Ge1 . 4_555 3.169(2) ?
Nd7 Ge2 . . 3.140(2) ?
Nd7 Ge3 . 2_655 3.175(2) ?
Nd7 Ge4 . . 3.099(2) ?
Nd7 Co1 . . 2.948(2) ?
Ge2 Co1 . . 2.518(3) ?
Ge2 Co2 . 4_554 2.542(3) ?
Ge3 Co1 . 2_645 2.541(3) ?
Ge4 Co2 . . 2.576(3) ?
Co1 Co2 . 2_555 2.356(3) ?
