# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 1485799'
_audit_update_record             
;
2016-10-16 deposited with the CCDC.
2016-10-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C46 H104 Eu2 N12 Si4'
_chemical_formula_sum            'C46 H104 Eu2 N12 Si4'
_chemical_formula_weight         1241.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.5784(13)
_cell_length_b                   13.6097(10)
_cell_length_c                   19.0544(10)
_cell_angle_alpha                71.442(10)
_cell_angle_beta                 75.023(9)
_cell_angle_gamma                83.412(12)
_cell_volume                     3222.7(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    12797
_cell_measurement_theta_min      3.0
_cell_measurement_theta_max      27.5

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.280
_exptl_crystal_F_000             1292
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    2.040
_shelx_estimated_absorpt_T_min   0.496
_shelx_estimated_absorpt_T_max   0.822
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.499
_exptl_absorpt_correction_T_max  0.820
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 14.63
_diffrn_reflns_number            25276
_diffrn_reflns_av_unetI/netI     0.0967
_diffrn_reflns_av_R_equivalents  0.0631
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.021
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 0.994
_reflns_number_total             11276
_reflns_number_gt                7766
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       CrystalClear
_computing_cell_refinement       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0574P)²+12.7943P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11276
_refine_ls_number_parameters     682
_refine_ls_number_restraints     283
_refine_ls_R_factor_all          0.1289
_refine_ls_R_factor_gt           0.0851
_refine_ls_wR_factor_ref         0.1836
_refine_ls_wR_factor_gt          0.1607
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_restrained_S_all      1.134
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.39555(4) 0.64843(4) 0.25784(3) 0.04635(19) Uani 1 1 d . . . . .
Eu2 Eu 0.55305(4) 0.84131(4) 0.26613(3) 0.04825(19) Uani 1 1 d . . . . .
Si1 Si 0.7619(3) 0.6196(3) 0.0402(2) 0.0683(10) Uani 1 1 d . . . . .
Si2 Si 0.7912(4) 1.1742(3) 0.1600(3) 0.1062(15) Uani 1 1 d D U . . .
Si3 Si 0.2054(3) 0.9236(3) 0.4283(2) 0.0713(11) Uani 1 1 d . . . . .
N1 N 0.5128(7) 0.7000(7) 0.1237(5) 0.048(2) Uani 1 1 d . . . . .
N2 N 0.5966(6) 0.6835(6) 0.2153(5) 0.042(2) Uani 1 1 d . . . . .
N3 N 0.6769(8) 0.9437(7) 0.2921(5) 0.061(3) Uani 1 1 d . . . . .
N4 N 0.6893(7) 0.9518(6) 0.1689(5) 0.054(2) Uani 1 1 d . . . . .
N5 N 0.6986(7) 0.7048(6) 0.0882(5) 0.048(2) Uani 1 1 d . . . . .
N6 N 0.8120(7) 1.0468(6) 0.1924(7) 0.074(2) Uani 1 1 d D U . . .
N7 N 0.3966(7) 0.7289(6) 0.3678(5) 0.046(2) Uani 1 1 d . . . . .
N8 N 0.2350(6) 0.8265(6) 0.3859(5) 0.051(2) Uani 1 1 d . . . . .
N9 N 0.3187(7) 0.4741(7) 0.2933(6) 0.070(3) Uani 1 1 d . . . . .
N10 N 0.2064(7) 0.6044(7) 0.3114(7) 0.071(3) Uani 1 1 d . . . . .
N11 N 0.3625(7) 0.8535(7) 0.2656(5) 0.052(2) Uani 1 1 d . . . . .
C1 C 0.5993(9) 0.6958(7) 0.1411(5) 0.043(3) Uani 1 1 d . . . . .
C2 C 0.7254(8) 0.9802(7) 0.2192(7) 0.052(3) Uani 1 1 d D . . . .
C3 C 0.7577(8) 0.7895(8) 0.0887(6) 0.053(3) Uani 1 1 d . . . . .
H3A H 0.8268 0.7864 0.0570 0.064 Uiso 1 1 calc R U . . .
H3B H 0.7634 0.7790 0.1409 0.064 Uiso 1 1 calc R U . . .
C4 C 0.7089(9) 0.8965(8) 0.0593(6) 0.055(3) Uani 1 1 d . . . . .
H4A H 0.7285 0.9192 0.0035 0.066 Uiso 1 1 calc R U . . .
H4B H 0.6346 0.8916 0.0749 0.066 Uiso 1 1 calc R U . . .
C5 C 0.7401(10) 0.9777(9) 0.0884(7) 0.066(3) Uani 1 1 d . . . . .
H5A H 0.8143 0.9754 0.0815 0.079 Uiso 1 1 calc R U . . .
H5B H 0.7184 1.0474 0.0609 0.079 Uiso 1 1 calc R U . . .
C6 C 0.5065(10) 0.7232(10) 0.0434(7) 0.065(3) Uani 1 1 d . . . . .
H6 H 0.5723 0.7031 0.0134 0.078 Uiso 1 1 calc R U . . .
C7 C 0.4827(12) 0.8331(11) 0.0086(7) 0.083(4) Uani 1 1 d . . . . .
H7A H 0.4136 0.8504 0.0324 0.125 Uiso 1 1 calc R U . . .
H7B H 0.4890 0.8462 -0.0455 0.125 Uiso 1 1 calc R U . . .
H7C H 0.5299 0.8754 0.0157 0.125 Uiso 1 1 calc R U . . .
C8 C 0.4245(17) 0.6590(15) 0.0432(10) 0.144(9) Uani 1 1 d . . . . .
H8A H 0.4407 0.5862 0.0657 0.216 Uiso 1 1 calc R U . . .
H8B H 0.4198 0.6707 -0.0088 0.216 Uiso 1 1 calc R U . . .
H8C H 0.3599 0.6784 0.0726 0.216 Uiso 1 1 calc R U . . .
C9 C 0.6812(8) 0.6174(8) 0.2485(6) 0.051(3) Uani 1 1 d . . . . .
H9 H 0.7452 0.6243 0.2083 0.061 Uiso 1 1 calc R U . . .
C10 C 0.6972(10) 0.6522(10) 0.3139(7) 0.065(3) Uani 1 1 d . . . . .
H10A H 0.7304 0.7182 0.2932 0.097 Uiso 1 1 calc R U . . .
H10B H 0.7397 0.6007 0.3422 0.097 Uiso 1 1 calc R U . . .
H10C H 0.6317 0.6597 0.3477 0.097 Uiso 1 1 calc R U . . .
C11 C 0.6506(11) 0.5049(9) 0.2794(8) 0.074(4) Uani 1 1 d . . . . .
H11A H 0.5891 0.4981 0.3199 0.111 Uiso 1 1 calc R U . . .
H11B H 0.7052 0.4617 0.2992 0.111 Uiso 1 1 calc R U . . .
H11C H 0.6379 0.4832 0.2388 0.111 Uiso 1 1 calc R U . . .
C12 C 0.7036(10) 0.9765(10) 0.3503(7) 0.064(3) Uani 1 1 d . . . . .
H12 H 0.7567 1.0290 0.3261 0.076 Uiso 1 1 calc R U . . .
C13 C 0.7428(14) 0.8849(12) 0.4058(9) 0.106(6) Uani 1 1 d . . . . .
H13A H 0.6917 0.8323 0.4280 0.160 Uiso 1 1 calc R U . . .
H13B H 0.7572 0.9067 0.4457 0.160 Uiso 1 1 calc R U . . .
H13C H 0.8048 0.8565 0.3794 0.160 Uiso 1 1 calc R U . . .
C14 C 0.6079(12) 1.0238(13) 0.3920(9) 0.103(5) Uani 1 1 d . . . . .
H14A H 0.5895 1.0894 0.3581 0.154 Uiso 1 1 calc R U . . .
H14B H 0.6211 1.0353 0.4364 0.154 Uiso 1 1 calc R U . . .
H14C H 0.5523 0.9768 0.4079 0.154 Uiso 1 1 calc R U . . .
C15 C 0.8004(15) 0.6890(13) -0.0642(8) 0.126(7) Uani 1 1 d . . . . .
H15A H 0.7418 0.6980 -0.0863 0.188 Uiso 1 1 calc R U . . .
H15B H 0.8536 0.6486 -0.0887 0.188 Uiso 1 1 calc R U . . .
H15C H 0.8256 0.7564 -0.0718 0.188 Uiso 1 1 calc R U . . .
C16 C 0.8799(12) 0.5682(13) 0.0708(11) 0.118(7) Uani 1 1 d . . . . .
H16A H 0.9288 0.6227 0.0523 0.178 Uiso 1 1 calc R U . . .
H16B H 0.9082 0.5115 0.0503 0.178 Uiso 1 1 calc R U . . .
H16C H 0.8652 0.5432 0.1260 0.178 Uiso 1 1 calc R U . . .
C17 C 0.6797(12) 0.5087(10) 0.0594(9) 0.097(5) Uani 1 1 d . . . . .
H17A H 0.6502 0.4826 0.1137 0.145 Uiso 1 1 calc R U . . .
H17B H 0.7206 0.4539 0.0420 0.145 Uiso 1 1 calc R U . . .
H17C H 0.6256 0.5319 0.0325 0.145 Uiso 1 1 calc R U . . .
C18 C 0.9199(8) 1.0014(8) 0.1928(9) 0.066(3) Uani 1 1 d D U . . .
H18 H 0.9465 1.0227 0.1368 0.079 Uiso 1 1 calc R U . . .
C19 C 0.9966(12) 1.0515(14) 0.2095(14) 0.149(6) Uani 1 1 d D U . . .
H19A H 1.0639 1.0349 0.1820 0.224 Uiso 1 1 calc R U . . .
H19B H 0.9931 1.0269 0.2638 0.224 Uiso 1 1 calc R U . . .
H19C H 0.9840 1.1260 0.1940 0.224 Uiso 1 1 calc R U . . .
C20 C 0.9283(11) 0.8808(9) 0.2050(11) 0.106(5) Uani 1 1 d D U . . .
H20A H 0.8866 0.8455 0.2546 0.159 Uiso 1 1 calc R U . . .
H20B H 0.9988 0.8567 0.2023 0.159 Uiso 1 1 calc R U . . .
H20C H 0.9046 0.8662 0.1656 0.159 Uiso 1 1 calc R U . . .
C21 C 0.8707(16) 1.2338(15) 0.0625(10) 0.166(7) Uani 1 1 d D U . . .
H21A H 0.9241 1.1845 0.0493 0.248 Uiso 1 1 calc R U . . .
H21B H 0.9011 1.2956 0.0613 0.248 Uiso 1 1 calc R U . . .
H21C H 0.8281 1.2522 0.0261 0.248 Uiso 1 1 calc R U . . .
C22 C 0.8222(15) 1.2487(12) 0.2168(11) 0.141(5) Uani 1 1 d D U . . .
H22A H 0.8112 1.3222 0.1930 0.212 Uiso 1 1 calc R U . . .
H22B H 0.8930 1.2348 0.2195 0.212 Uiso 1 1 calc R U . . .
H22C H 0.7786 1.2283 0.2679 0.212 Uiso 1 1 calc R U . . .
C23 C 0.6549(9) 1.1966(10) 0.1627(9) 0.092(4) Uani 1 1 d D U . . .
H23A H 0.6408 1.1815 0.1198 0.138 Uiso 1 1 calc R U . . .
H23B H 0.6358 1.2685 0.1597 0.138 Uiso 1 1 calc R U . . .
H23C H 0.6158 1.1518 0.2098 0.138 Uiso 1 1 calc R U . . .
C24 C 0.3334(8) 0.8030(8) 0.3412(6) 0.044(3) Uani 1 1 d . . . . .
C25 C 0.2237(9) 0.5045(9) 0.3139(7) 0.0626(12) Uani 1 1 d D U . . .
C26 C 0.1611(9) 0.7425(9) 0.4097(7) 0.062(3) Uani 1 1 d . . . . .
H26A H 0.1111 0.7475 0.4559 0.075 Uiso 1 1 calc R U . . .
H26B H 0.1979 0.6754 0.4226 0.075 Uiso 1 1 calc R U . . .
C27 C 0.1037(10) 0.7450(10) 0.3493(8) 0.074(4) Uani 1 1 d . . . . .
H27A H 0.0333 0.7700 0.3649 0.088 Uiso 1 1 calc R U . . .
H27B H 0.1357 0.7948 0.3009 0.088 Uiso 1 1 calc R U . . .
C28 C 0.1017(10) 0.6412(10) 0.3365(9) 0.087(5) Uani 1 1 d D . . . .
H28A H 0.0674 0.5911 0.3839 0.105 Uiso 1 1 calc R U . . .
H28B H 0.0638 0.6483 0.2977 0.105 Uiso 1 1 calc R U . . .
C29 C 0.3774(9) 0.6781(8) 0.4503(6) 0.056(3) Uani 1 1 d . . . . .
H29 H 0.3074 0.6974 0.4747 0.067 Uiso 1 1 calc R U . . .
C30 C 0.4527(11) 0.7122(11) 0.4832(7) 0.080(4) Uani 1 1 d . . . . .
H30A H 0.5211 0.6890 0.4623 0.119 Uiso 1 1 calc R U . . .
H30B H 0.4360 0.6822 0.5382 0.119 Uiso 1 1 calc R U . . .
H30C H 0.4495 0.7873 0.4704 0.119 Uiso 1 1 calc R U . . .
C31 C 0.3858(12) 0.5620(9) 0.4636(8) 0.084(4) Uani 1 1 d . . . . .
H31A H 0.3342 0.5419 0.4443 0.125 Uiso 1 1 calc R U . . .
H31B H 0.3755 0.5266 0.5178 0.125 Uiso 1 1 calc R U . . .
H31C H 0.4529 0.5432 0.4373 0.125 Uiso 1 1 calc R U . . .
C32 C 0.290(5) 0.927(6) 0.220(4) 0.090(7) Uani 0.5 1 d . . P A 1
H32 H 0.2273 0.9432 0.2549 0.108 Uiso 0.5 1 calc R U P A 1
C32' C 0.308(5) 0.939(6) 0.228(4) 0.090(7) Uani 0.5 1 d . . P A 2
H32' H 0.2450 0.9524 0.2645 0.108 Uiso 0.5 1 calc R U P A 2
C33 C 0.345(2) 1.023(3) 0.1738(18) 0.090(7) Uani 0.5 1 d . . P A 1
H33A H 0.4117 1.0052 0.1464 0.135 Uiso 0.5 1 calc R U P A 1
H33B H 0.3521 1.0613 0.2071 0.135 Uiso 0.5 1 calc R U P A 1
H33C H 0.3063 1.0652 0.1377 0.135 Uiso 0.5 1 calc R U P A 1
C33' C 0.383(2) 1.037(3) 0.2003(19) 0.090(7) Uani 0.5 1 d . . P A 2
H33D H 0.4052 1.0418 0.2436 0.135 Uiso 0.5 1 calc R U P A 2
H33E H 0.3469 1.1007 0.1791 0.135 Uiso 0.5 1 calc R U P A 2
H33F H 0.4425 1.0262 0.1618 0.135 Uiso 0.5 1 calc R U P A 2
C34 C 0.263(3) 0.864(2) 0.1701(19) 0.090(7) Uani 0.5 1 d . . P A 1
H34A H 0.2172 0.9058 0.1399 0.135 Uiso 0.5 1 calc R U P A 1
H34B H 0.2307 0.8004 0.2036 0.135 Uiso 0.5 1 calc R U P A 1
H34C H 0.3253 0.8473 0.1366 0.135 Uiso 0.5 1 calc R U P A 1
C34' C 0.278(3) 0.922(2) 0.161(2) 0.090(7) Uani 0.5 1 d . . P A 2
H34D H 0.2562 0.8513 0.1754 0.135 Uiso 0.5 1 calc R U P A 2
H34E H 0.3363 0.9332 0.1180 0.135 Uiso 0.5 1 calc R U P A 2
H34F H 0.2226 0.9701 0.1479 0.135 Uiso 0.5 1 calc R U P A 2
C35 C 0.3441(11) 0.3633(10) 0.2931(8) 0.077(4) Uani 1 1 d . . . . .
H35 H 0.2807 0.3242 0.3097 0.093 Uiso 1 1 calc R U . . .
C36 C 0.4150(13) 0.3115(10) 0.3444(10) 0.103(6) Uani 1 1 d . . . . .
H36A H 0.4794 0.3463 0.3250 0.155 Uiso 1 1 calc R U . . .
H36B H 0.4268 0.2393 0.3459 0.155 Uiso 1 1 calc R U . . .
H36C H 0.3845 0.3158 0.3954 0.155 Uiso 1 1 calc R U . . .
C37 C 0.3968(13) 0.3702(13) 0.2081(9) 0.107(6) Uani 1 1 d . . . . .
H37A H 0.3474 0.3956 0.1770 0.161 Uiso 1 1 calc R U . . .
H37B H 0.4228 0.3019 0.2050 0.161 Uiso 1 1 calc R U . . .
H37C H 0.4527 0.4173 0.1897 0.161 Uiso 1 1 calc R U . . .
C38 C 0.0865(11) 0.9941(10) 0.4040(10) 0.105(6) Uani 1 1 d . . . . .
H38A H 0.1007 1.0328 0.3503 0.157 Uiso 1 1 calc R U . . .
H38B H 0.0626 1.0416 0.4340 0.157 Uiso 1 1 calc R U . . .
H38C H 0.0344 0.9445 0.4152 0.157 Uiso 1 1 calc R U . . .
C39 C 0.1823(12) 0.8684(13) 0.5336(8) 0.105(6) Uani 1 1 d . . . . .
H39A H 0.1279 0.8196 0.5519 0.158 Uiso 1 1 calc R U . . .
H39B H 0.1630 0.9238 0.5568 0.158 Uiso 1 1 calc R U . . .
H39C H 0.2441 0.8329 0.5469 0.158 Uiso 1 1 calc R U . . .
C40 C 0.3144(13) 1.0136(12) 0.3929(11) 0.125(8) Uani 1 1 d . . . . .
H40A H 0.3764 0.9744 0.4026 0.187 Uiso 1 1 calc R U . . .
H40B H 0.3000 1.0658 0.4193 0.187 Uiso 1 1 calc R U . . .
H40C H 0.3232 1.0470 0.3386 0.187 Uiso 1 1 calc R U . . .
C41 C 0.1080(12) 0.3763(10) 0.4275(8) 0.0650(14) Uani 0.798(5) 1 d D U P B 1
H41 H 0.0363 0.4010 0.4415 0.078 Uiso 0.798(5) 1 calc R U P B 1
C42 C 0.1612(13) 0.4076(12) 0.4766(8) 0.0668(18) Uani 0.798(5) 1 d D U P B 1
H42A H 0.2308 0.3797 0.4697 0.100 Uiso 0.798(5) 1 calc R U P B 1
H42B H 0.1256 0.3807 0.5296 0.100 Uiso 0.798(5) 1 calc R U P B 1
H42C H 0.1616 0.4827 0.4623 0.100 Uiso 0.798(5) 1 calc R U P B 1
C43 C 0.1031(12) 0.2619(10) 0.4465(9) 0.0662(19) Uani 0.798(5) 1 d D U P B 1
H43A H 0.0562 0.2462 0.4210 0.099 Uiso 0.798(5) 1 calc R U P B 1
H43B H 0.0793 0.2320 0.5011 0.099 Uiso 0.798(5) 1 calc R U P B 1
H43C H 0.1704 0.2329 0.4296 0.099 Uiso 0.798(5) 1 calc R U P B 1
C44 C 0.1159(12) 0.5251(11) 0.1897(8) 0.0653(19) Uani 0.798(5) 1 d D U P B 1
H44A H 0.1087 0.5930 0.1972 0.098 Uiso 0.798(5) 1 calc R U P B 1
H44B H 0.0743 0.5235 0.1556 0.098 Uiso 0.798(5) 1 calc R U P B 1
H44C H 0.1868 0.5110 0.1676 0.098 Uiso 0.798(5) 1 calc R U P B 1
C45 C 0.0846(12) 0.2944(9) 0.2663(9) 0.067(3) Uani 0.798(5) 1 d D U P B 1
H45A H 0.1561 0.2745 0.2521 0.100 Uiso 0.798(5) 1 calc R U P B 1
H45B H 0.0524 0.2992 0.2253 0.100 Uiso 0.798(5) 1 calc R U P B 1
H45C H 0.0512 0.2427 0.3121 0.100 Uiso 0.798(5) 1 calc R U P B 1
C46 C -0.0660(10) 0.4505(13) 0.3224(10) 0.076(3) Uani 0.798(5) 1 d D U P B 1
H46A H -0.0883 0.4039 0.3735 0.114 Uiso 0.798(5) 1 calc R U P B 1
H46B H -0.1053 0.4399 0.2897 0.114 Uiso 0.798(5) 1 calc R U P B 1
H46C H -0.0760 0.5217 0.3237 0.114 Uiso 0.798(5) 1 calc R U P B 1
N12 N 0.1427(9) 0.4293(9) 0.3455(6) 0.0628(11) Uani 0.798(5) 1 d D U P B 1
Si4 Si 0.0728(3) 0.4235(3) 0.2842(3) 0.0626(10) Uani 0.798(5) 1 d D U P B 1
C41' C 0.089(4) 0.493(4) 0.234(2) 0.0635(13) Uani 0.202(5) 1 d D U P B 2
H41' H 0.0337 0.5461 0.2419 0.076 Uiso 0.202(5) 1 calc R U P B 2
C42' C 0.158(5) 0.551(5) 0.160(3) 0.064(2) Uani 0.202(5) 1 d D U P B 2
H42D H 0.1886 0.5038 0.1315 0.097 Uiso 0.202(5) 1 calc R U P B 2
H42E H 0.2113 0.5824 0.1709 0.097 Uiso 0.202(5) 1 calc R U P B 2
H42F H 0.1188 0.6055 0.1308 0.097 Uiso 0.202(5) 1 calc R U P B 2
C43' C 0.031(4) 0.410(4) 0.227(3) 0.0644(16) Uani 0.202(5) 1 d D U P B 2
H43D H -0.0205 0.4419 0.1991 0.097 Uiso 0.202(5) 1 calc R U P B 2
H43E H -0.0018 0.3673 0.2777 0.097 Uiso 0.202(5) 1 calc R U P B 2
H43F H 0.0780 0.3672 0.2006 0.097 Uiso 0.202(5) 1 calc R U P B 2
C44' C -0.075(2) 0.434(4) 0.398(3) 0.069(2) Uani 0.202(5) 1 d D U P B 2
H44D H -0.1060 0.3952 0.3741 0.103 Uiso 0.202(5) 1 calc R U P B 2
H44E H -0.0851 0.5074 0.3739 0.103 Uiso 0.202(5) 1 calc R U P B 2
H44F H -0.1073 0.4161 0.4515 0.103 Uiso 0.202(5) 1 calc R U P B 2
C45' C 0.097(4) 0.397(3) 0.4755(18) 0.0655(17) Uani 0.202(5) 1 d D U P B 2
H45D H 0.0511 0.3527 0.5186 0.098 Uiso 0.202(5) 1 calc R U P B 2
H45E H 0.0901 0.4672 0.4797 0.098 Uiso 0.202(5) 1 calc R U P B 2
H45F H 0.1670 0.3713 0.4753 0.098 Uiso 0.202(5) 1 calc R U P B 2
C46' C 0.080(4) 0.257(2) 0.388(3) 0.0648(19) Uani 0.202(5) 1 d D U P B 2
H46D H 0.1463 0.2300 0.3968 0.097 Uiso 0.202(5) 1 calc R U P B 2
H46E H 0.0732 0.2506 0.3405 0.097 Uiso 0.202(5) 1 calc R U P B 2
H46F H 0.0270 0.2189 0.4297 0.097 Uiso 0.202(5) 1 calc R U P B 2
N12' N 0.130(2) 0.475(3) 0.3011(14) 0.0630(12) Uani 0.202(5) 1 d D U P B 2
Si4' Si 0.0659(13) 0.3990(13) 0.3839(10) 0.0637(12) Uani 0.202(5) 1 d D U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N9 2.521(8) . ?
Eu1 N1 2.564(8) . ?
Eu1 N10 2.571(9) . ?
Eu1 N7 2.659(8) . ?
Eu1 N2 2.692(8) . ?
Eu1 N11 2.820(9) . ?
Eu1 C24 2.947(9) . ?
Eu1 C25 2.975(10) . ?
Eu1 C1 3.055(11) . ?
Eu1 Eu2 3.6353(8) . ?
Eu2 N4 2.492(8) . ?
Eu2 N3 2.534(9) . ?
Eu2 N2 2.576(8) . ?
Eu2 N11 2.577(9) . ?
Eu2 N7 2.709(8) . ?
Eu2 C2 2.951(9) . ?
Eu2 C24 2.982(10) . ?
Si1 N5 1.722(8) . ?
Si1 C16 1.834(18) . ?
Si1 C17 1.865(13) . ?
Si1 C15 1.871(15) . ?
Si2 N6 1.663(9) . ?
Si2 C23 1.831(12) . ?
Si2 C22 1.846(14) . ?
Si2 C21 1.866(14) . ?
Si3 N8 1.717(8) . ?
Si3 C39 1.860(16) . ?
Si3 C38 1.868(16) . ?
Si3 C40 1.876(13) . ?
N1 C1 1.291(13) . ?
N1 C6 1.483(14) . ?
N2 C1 1.361(12) . ?
N2 C9 1.518(13) . ?
N3 C2 1.331(13) . ?
N3 C12 1.457(14) . ?
N4 C2 1.353(14) . ?
N4 C5 1.455(14) . ?
N5 C1 1.450(13) . ?
N5 C3 1.482(12) . ?
N6 C2 1.450(11) . ?
N6 C18 1.525(11) . ?
N7 C24 1.308(13) . ?
N7 C29 1.468(13) . ?
N8 C24 1.449(12) . ?
N8 C26 1.490(13) . ?
N9 C25 1.306(14) . ?
N9 C35 1.510(15) . ?
N10 C25 1.340(14) . ?
N10 C28 1.462(14) . ?
N11 C24 1.358(13) . ?
N11 C32' 1.40(7) . ?
N11 C32 1.55(6) . ?
C3 C4 1.525(15) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C4 C5 1.525(14) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C6 C7 1.466(17) . ?
C6 C8 1.494(19) . ?
C6 H6 0.9900 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 H7C 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 H8C 0.9700 . ?
C9 C11 1.520(14) . ?
C9 C10 1.539(15) . ?
C9 H9 0.9900 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 H10C 0.9700 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 H11C 0.9700 . ?
C12 C13 1.501(18) . ?
C12 C14 1.528(18) . ?
C12 H12 0.9900 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 H13C 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 H14C 0.9700 . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 H16C 0.9700 . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 H17C 0.9700 . ?
C18 C19 1.457(14) . ?
C18 C20 1.577(13) . ?
C18 H18 0.9900 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C21 H21C 0.9700 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C22 H22C 0.9700 . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
C25 N12 1.464(12) . ?
C25 N12' 1.477(19) . ?
C26 C27 1.538(17) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C27 C28 1.513(15) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C29 C30 1.510(16) . ?
C29 C31 1.515(15) . ?
C29 H29 0.9900 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C30 H30C 0.9700 . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C31 H31C 0.9700 . ?
C32 C33 1.48(7) . ?
C32 C34 1.59(7) . ?
C32 H32 0.9900 . ?
C32' C34' 1.52(7) . ?
C32' C33' 1.65(7) . ?
C32' H32' 0.9900 . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C33 H33C 0.9700 . ?
C33' H33D 0.9700 . ?
C33' H33E 0.9700 . ?
C33' H33F 0.9700 . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C34 H34C 0.9700 . ?
C34' H34D 0.9700 . ?
C34' H34E 0.9700 . ?
C34' H34F 0.9700 . ?
C35 C36 1.51(2) . ?
C35 C37 1.570(19) . ?
C35 H35 0.9900 . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C36 H36C 0.9700 . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C37 H37C 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C38 H38C 0.9700 . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C39 H39C 0.9700 . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C40 H40C 0.9700 . ?
C41 N12 1.471(14) . ?
C41 C43 1.488(14) . ?
C41 C42 1.500(15) . ?
C41 H41 0.9900 . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C42 H42C 0.9700 . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C43 H43C 0.9700 . ?
C44 Si4 1.885(13) . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C44 H44C 0.9700 . ?
C45 Si4 1.877(11) . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C45 H45C 0.9700 . ?
C46 Si4 1.875(12) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
C46 H46C 0.9700 . ?
N12 Si4 1.709(11) . ?
C41' N12' 1.46(2) . ?
C41' C43' 1.51(2) . ?
C41' C42' 1.51(2) . ?
C41' H41' 0.9900 . ?
C42' H42D 0.9700 . ?
C42' H42E 0.9700 . ?
C42' H42F 0.9700 . ?
C43' H43D 0.9700 . ?
C43' H43E 0.9700 . ?
C43' H43F 0.9700 . ?
C44' Si4' 1.893(19) . ?
C44' H44D 0.9700 . ?
C44' H44E 0.9700 . ?
C44' H44F 0.9700 . ?
C45' Si4' 1.895(19) . ?
C45' H45D 0.9700 . ?
C45' H45E 0.9700 . ?
C45' H45F 0.9700 . ?
C46' Si4' 1.893(18) . ?
C46' H46D 0.9700 . ?
C46' H46E 0.9700 . ?
C46' H46F 0.9700 . ?
N12' Si4' 1.665(14) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N9 Eu1 N1 113.0(3) . . ?
N9 Eu1 N10 52.5(3) . . ?
N1 Eu1 N10 134.3(3) . . ?
N9 Eu1 N7 118.9(3) . . ?
N1 Eu1 N7 125.3(3) . . ?
N10 Eu1 N7 92.6(3) . . ?
N9 Eu1 N2 125.3(3) . . ?
N1 Eu1 N2 50.9(3) . . ?
N10 Eu1 N2 174.4(3) . . ?
N7 Eu1 N2 84.2(3) . . ?
N9 Eu1 N11 146.0(3) . . ?
N1 Eu1 N11 94.3(3) . . ?
N10 Eu1 N11 93.9(3) . . ?
N7 Eu1 N11 48.4(3) . . ?
N2 Eu1 N11 87.5(2) . . ?
N9 Eu1 C24 126.1(3) . . ?
N1 Eu1 C24 119.8(3) . . ?
N10 Eu1 C24 81.9(3) . . ?
N7 Eu1 C24 26.3(3) . . ?
N2 Eu1 C24 97.1(3) . . ?
N11 Eu1 C24 27.1(3) . . ?
N9 Eu1 C25 25.8(3) . . ?
N1 Eu1 C25 126.6(3) . . ?
N10 Eu1 C25 26.7(3) . . ?
N7 Eu1 C25 107.9(3) . . ?
N2 Eu1 C25 151.0(3) . . ?
N11 Eu1 C25 120.5(3) . . ?
C24 Eu1 C25 105.2(3) . . ?
N9 Eu1 C1 120.0(3) . . ?
N1 Eu1 C1 24.6(3) . . ?
N10 Eu1 C1 158.4(3) . . ?
N7 Eu1 C1 107.4(3) . . ?
N2 Eu1 C1 26.4(2) . . ?
N11 Eu1 C1 93.3(2) . . ?
C24 Eu1 C1 112.5(3) . . ?
C25 Eu1 C1 142.1(3) . . ?
N9 Eu1 Eu2 157.6(3) . . ?
N1 Eu1 Eu2 77.32(19) . . ?
N10 Eu1 Eu2 134.45(18) . . ?
N7 Eu1 Eu2 47.97(18) . . ?
N2 Eu1 Eu2 45.05(17) . . ?
N11 Eu1 Eu2 44.88(19) . . ?
C24 Eu1 Eu2 52.61(19) . . ?
C25 Eu1 Eu2 155.7(2) . . ?
C1 Eu1 Eu2 61.47(18) . . ?
N4 Eu2 N3 53.9(3) . . ?
N4 Eu2 N2 95.7(3) . . ?
N3 Eu2 N2 126.8(3) . . ?
N4 Eu2 N11 126.3(3) . . ?
N3 Eu2 N11 137.6(3) . . ?
N2 Eu2 N11 95.4(3) . . ?
N4 Eu2 N7 176.6(3) . . ?
N3 Eu2 N7 127.6(3) . . ?
N2 Eu2 N7 85.5(2) . . ?
N11 Eu2 N7 50.4(3) . . ?
N4 Eu2 C2 27.1(3) . . ?
N3 Eu2 C2 26.7(3) . . ?
N2 Eu2 C2 112.9(3) . . ?
N11 Eu2 C2 138.7(3) . . ?
N7 Eu2 C2 154.3(3) . . ?
N4 Eu2 C24 150.6(3) . . ?
N3 Eu2 C24 129.6(3) . . ?
N2 Eu2 C24 98.8(3) . . ?
N11 Eu2 C24 27.0(3) . . ?
N7 Eu2 C24 26.0(3) . . ?
C2 Eu2 C24 148.1(3) . . ?
N4 Eu2 Eu1 132.5(2) . . ?
N3 Eu2 Eu1 167.9(2) . . ?
N2 Eu2 Eu1 47.70(19) . . ?
N11 Eu2 Eu1 50.6(2) . . ?
N7 Eu2 Eu1 46.79(17) . . ?
C2 Eu2 Eu1 158.0(2) . . ?
C24 Eu2 Eu1 51.75(18) . . ?
N5 Si1 C16 110.6(6) . . ?
N5 Si1 C17 110.1(6) . . ?
C16 Si1 C17 108.5(8) . . ?
N5 Si1 C15 109.8(6) . . ?
C16 Si1 C15 106.6(9) . . ?
C17 Si1 C15 111.2(8) . . ?
N6 Si2 C23 107.2(6) . . ?
N6 Si2 C22 114.5(8) . . ?
C23 Si2 C22 107.3(8) . . ?
N6 Si2 C21 113.0(8) . . ?
C23 Si2 C21 111.3(10) . . ?
C22 Si2 C21 103.3(10) . . ?
N8 Si3 C39 110.5(6) . . ?
N8 Si3 C38 108.5(6) . . ?
C39 Si3 C38 108.7(7) . . ?
N8 Si3 C40 109.2(5) . . ?
C39 Si3 C40 109.1(8) . . ?
C38 Si3 C40 110.9(8) . . ?
C1 N1 C6 121.2(9) . . ?
C1 N1 Eu1 99.5(6) . . ?
C6 N1 Eu1 139.1(7) . . ?
C1 N2 C9 117.6(8) . . ?
C1 N2 Eu2 119.5(6) . . ?
C9 N2 Eu2 109.6(6) . . ?
C1 N2 Eu1 91.9(6) . . ?
C9 N2 Eu1 127.9(6) . . ?
Eu2 N2 Eu1 87.3(2) . . ?
C2 N3 C12 120.7(9) . . ?
C2 N3 Eu2 94.4(6) . . ?
C12 N3 Eu2 144.8(7) . . ?
C2 N4 C5 122.3(9) . . ?
C2 N4 Eu2 95.7(6) . . ?
C5 N4 Eu2 141.4(7) . . ?
C1 N5 C3 112.7(7) . . ?
C1 N5 Si1 128.8(6) . . ?
C3 N5 Si1 117.4(7) . . ?
C2 N6 C18 121.0(8) . . ?
C2 N6 Si2 118.5(8) . . ?
C18 N6 Si2 120.5(7) . . ?
C24 N7 C29 119.0(9) . . ?
C24 N7 Eu1 89.2(6) . . ?
C29 N7 Eu1 128.9(6) . . ?
C24 N7 Eu2 88.7(6) . . ?
C29 N7 Eu2 132.5(7) . . ?
Eu1 N7 Eu2 85.2(2) . . ?
C24 N8 C26 113.4(8) . . ?
C24 N8 Si3 127.2(7) . . ?
C26 N8 Si3 118.0(7) . . ?
C25 N9 C35 119.9(10) . . ?
C25 N9 Eu1 96.8(7) . . ?
C35 N9 Eu1 143.1(7) . . ?
C25 N10 C28 118.9(9) . . ?
C25 N10 Eu1 93.7(7) . . ?
C28 N10 Eu1 147.4(7) . . ?
C24 N11 C32' 123(3) . . ?
C24 N11 C32 123(3) . . ?
C24 N11 Eu2 93.3(6) . . ?
C32' N11 Eu2 128(3) . . ?
C32 N11 Eu2 138(3) . . ?
C24 N11 Eu1 81.7(6) . . ?
C32' N11 Eu1 132(3) . . ?
C32 N11 Eu1 118(3) . . ?
Eu2 N11 Eu1 84.6(2) . . ?
N1 C1 N2 116.9(9) . . ?
N1 C1 N5 125.6(9) . . ?
N2 C1 N5 117.5(9) . . ?
N1 C1 Eu1 55.9(5) . . ?
N2 C1 Eu1 61.7(5) . . ?
N5 C1 Eu1 173.1(6) . . ?
N3 C2 N4 116.1(8) . . ?
N3 C2 N6 124.0(10) . . ?
N4 C2 N6 120.0(11) . . ?
N3 C2 Eu2 58.9(5) . . ?
N4 C2 Eu2 57.2(5) . . ?
N6 C2 Eu2 176.9(8) . . ?
N5 C3 C4 112.6(10) . . ?
N5 C3 H3A 109.1 . . ?
C4 C3 H3A 109.1 . . ?
N5 C3 H3B 109.1 . . ?
C4 C3 H3B 109.1 . . ?
H3A C3 H3B 107.8 . . ?
C5 C4 C3 113.0(10) . . ?
C5 C4 H4A 109.0 . . ?
C3 C4 H4A 109.0 . . ?
C5 C4 H4B 109.0 . . ?
C3 C4 H4B 109.0 . . ?
H4A C4 H4B 107.8 . . ?
N4 C5 C4 106.0(8) . . ?
N4 C5 H5A 110.5 . . ?
C4 C5 H5A 110.5 . . ?
N4 C5 H5B 110.5 . . ?
C4 C5 H5B 110.5 . . ?
H5A C5 H5B 108.7 . . ?
C7 C6 N1 112.6(10) . . ?
C7 C6 C8 109.5(13) . . ?
N1 C6 C8 107.3(11) . . ?
C7 C6 H6 109.1 . . ?
N1 C6 H6 109.1 . . ?
C8 C6 H6 109.1 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C6 C8 H8A 109.5 . . ?
C6 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C6 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N2 C9 C11 108.8(9) . . ?
N2 C9 C10 109.9(9) . . ?
C11 C9 C10 109.0(10) . . ?
N2 C9 H9 109.7 . . ?
C11 C9 H9 109.7 . . ?
C10 C9 H9 109.7 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N3 C12 C13 110.0(11) . . ?
N3 C12 C14 108.3(11) . . ?
C13 C12 C14 109.8(13) . . ?
N3 C12 H12 109.6 . . ?
C13 C12 H12 109.6 . . ?
C14 C12 H12 109.6 . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si1 C15 H15A 109.5 . . ?
Si1 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si1 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si1 C16 H16A 109.5 . . ?
Si1 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si1 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si1 C17 H17A 109.5 . . ?
Si1 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si1 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 N6 123.0(11) . . ?
C19 C18 C20 120.3(12) . . ?
N6 C18 C20 112.9(8) . . ?
C19 C18 H18 96.5 . . ?
N6 C18 H18 96.5 . . ?
C20 C18 H18 96.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si2 C21 H21A 109.5 . . ?
Si2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si2 C22 H22A 109.5 . . ?
Si2 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si2 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si2 C23 H23A 109.5 . . ?
Si2 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si2 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N7 C24 N11 115.3(9) . . ?
N7 C24 N8 124.0(9) . . ?
N11 C24 N8 120.6(10) . . ?
N7 C24 Eu1 64.4(5) . . ?
N11 C24 Eu1 71.2(5) . . ?
N8 C24 Eu1 130.9(6) . . ?
N7 C24 Eu2 65.3(5) . . ?
N11 C24 Eu2 59.6(5) . . ?
N8 C24 Eu2 153.3(6) . . ?
Eu1 C24 Eu2 75.6(2) . . ?
N9 C25 N10 116.9(9) . . ?
N9 C25 N12 120.5(11) . . ?
N10 C25 N12 122.4(11) . . ?
N9 C25 N12' 130(2) . . ?
N10 C25 N12' 104(2) . . ?
N9 C25 Eu1 57.3(5) . . ?
N10 C25 Eu1 59.6(5) . . ?
N12 C25 Eu1 176.1(9) . . ?
N12' C25 Eu1 147.4(12) . . ?
N8 C26 C27 114.5(10) . . ?
N8 C26 H26A 108.6 . . ?
C27 C26 H26A 108.6 . . ?
N8 C26 H26B 108.6 . . ?
C27 C26 H26B 108.6 . . ?
H26A C26 H26B 107.6 . . ?
C28 C27 C26 114.1(12) . . ?
C28 C27 H27A 108.7 . . ?
C26 C27 H27A 108.7 . . ?
C28 C27 H27B 108.7 . . ?
C26 C27 H27B 108.7 . . ?
H27A C27 H27B 107.6 . . ?
N10 C28 C27 109.2(10) . . ?
N10 C28 H28A 109.8 . . ?
C27 C28 H28A 109.8 . . ?
N10 C28 H28B 109.8 . . ?
C27 C28 H28B 109.8 . . ?
H28A C28 H28B 108.3 . . ?
N7 C29 C30 110.4(9) . . ?
N7 C29 C31 107.8(9) . . ?
C30 C29 C31 111.3(11) . . ?
N7 C29 H29 109.1 . . ?
C30 C29 H29 109.1 . . ?
C31 C29 H29 109.1 . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C29 C31 H31A 109.5 . . ?
C29 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C29 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C33 C32 N11 108(4) . . ?
C33 C32 C34 114(5) . . ?
N11 C32 C34 105(5) . . ?
C33 C32 H32 110.1 . . ?
N11 C32 H32 110.1 . . ?
C34 C32 H32 110.1 . . ?
N11 C32' C34' 112(5) . . ?
N11 C32' C33' 105(3) . . ?
C34' C32' C33' 112(5) . . ?
N11 C32' H32' 109.2 . . ?
C34' C32' H32' 109.2 . . ?
C33' C32' H32' 109.2 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C32' C33' H33D 109.5 . . ?
C32' C33' H33E 109.5 . . ?
H33D C33' H33E 109.5 . . ?
C32' C33' H33F 109.5 . . ?
H33D C33' H33F 109.5 . . ?
H33E C33' H33F 109.5 . . ?
C32 C34 H34A 109.5 . . ?
C32 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C32 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C32' C34' H34D 109.5 . . ?
C32' C34' H34E 109.5 . . ?
H34D C34' H34E 109.5 . . ?
C32' C34' H34F 109.5 . . ?
H34D C34' H34F 109.5 . . ?
H34E C34' H34F 109.5 . . ?
C36 C35 N9 110.9(11) . . ?
C36 C35 C37 110.8(13) . . ?
N9 C35 C37 105.3(11) . . ?
C36 C35 H35 109.9 . . ?
N9 C35 H35 109.9 . . ?
C37 C35 H35 109.9 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C35 C37 H37A 109.5 . . ?
C35 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C35 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
Si3 C38 H38A 109.5 . . ?
Si3 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
Si3 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
Si3 C39 H39A 109.5 . . ?
Si3 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
Si3 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
Si3 C40 H40A 109.5 . . ?
Si3 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
Si3 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N12 C41 C43 113.7(11) . . ?
N12 C41 C42 114.3(11) . . ?
C43 C41 C42 113.0(13) . . ?
N12 C41 H41 104.9 . . ?
C43 C41 H41 104.9 . . ?
C42 C41 H41 104.9 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
Si4 C44 H44A 109.5 . . ?
Si4 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
Si4 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
Si4 C45 H45A 109.5 . . ?
Si4 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
Si4 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
Si4 C46 H46A 109.5 . . ?
Si4 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
Si4 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C25 N12 C41 123.2(10) . . ?
C25 N12 Si4 115.9(8) . . ?
C41 N12 Si4 119.8(9) . . ?
N12 Si4 C46 110.5(7) . . ?
N12 Si4 C45 113.4(7) . . ?
C46 Si4 C45 107.5(7) . . ?
N12 Si4 C44 109.5(6) . . ?
C46 Si4 C44 107.8(8) . . ?
C45 Si4 C44 107.8(7) . . ?
N12' C41' C43' 120(4) . . ?
N12' C41' C42' 114(4) . . ?
C43' C41' C42' 114(4) . . ?
N12' C41' H41' 101.8 . . ?
C43' C41' H41' 101.8 . . ?
C42' C41' H41' 101.8 . . ?
C41' C42' H42D 109.5 . . ?
C41' C42' H42E 109.5 . . ?
H42D C42' H42E 109.5 . . ?
C41' C42' H42F 109.5 . . ?
H42D C42' H42F 109.5 . . ?
H42E C42' H42F 109.5 . . ?
C41' C43' H43D 109.5 . . ?
C41' C43' H43E 109.5 . . ?
H43D C43' H43E 109.5 . . ?
C41' C43' H43F 109.5 . . ?
H43D C43' H43F 109.5 . . ?
H43E C43' H43F 109.5 . . ?
Si4' C44' H44D 109.5 . . ?
Si4' C44' H44E 109.5 . . ?
H44D C44' H44E 109.5 . . ?
Si4' C44' H44F 109.5 . . ?
H44D C44' H44F 109.5 . . ?
H44E C44' H44F 109.5 . . ?
Si4' C45' H45D 109.5 . . ?
Si4' C45' H45E 109.5 . . ?
H45D C45' H45E 109.5 . . ?
Si4' C45' H45F 109.5 . . ?
H45D C45' H45F 109.5 . . ?
H45E C45' H45F 109.5 . . ?
Si4' C46' H46D 109.5 . . ?
Si4' C46' H46E 109.5 . . ?
H46D C46' H46E 109.5 . . ?
Si4' C46' H46F 109.5 . . ?
H46D C46' H46F 109.5 . . ?
H46E C46' H46F 109.5 . . ?
C41' N12' C25 135(2) . . ?
C41' N12' Si4' 118(2) . . ?
C25 N12' Si4' 107.6(15) . . ?
N12' Si4' C46' 112(3) . . ?
N12' Si4' C44' 110(2) . . ?
C46' Si4' C44' 106.1(17) . . ?
N12' Si4' C45' 119.5(18) . . ?
C46' Si4' C45' 102.9(17) . . ?
C44' Si4' C45' 104.9(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C16 Si1 N5 C1 -115.9(10) . . . . ?
C17 Si1 N5 C1 4.0(12) . . . . ?
C15 Si1 N5 C1 126.8(11) . . . . ?
C16 Si1 N5 C3 51.3(10) . . . . ?
C17 Si1 N5 C3 171.2(9) . . . . ?
C15 Si1 N5 C3 -66.0(11) . . . . ?
C23 Si2 N6 C2 -3.2(12) . . . . ?
C22 Si2 N6 C2 115.8(11) . . . . ?
C21 Si2 N6 C2 -126.2(12) . . . . ?
C23 Si2 N6 C18 176.1(11) . . . . ?
C22 Si2 N6 C18 -65.0(13) . . . . ?
C21 Si2 N6 C18 53.0(14) . . . . ?
C39 Si3 N8 C24 -109.1(10) . . . . ?
C38 Si3 N8 C24 131.8(10) . . . . ?
C40 Si3 N8 C24 10.8(13) . . . . ?
C39 Si3 N8 C26 56.3(11) . . . . ?
C38 Si3 N8 C26 -62.7(10) . . . . ?
C40 Si3 N8 C26 176.3(11) . . . . ?
C6 N1 C1 N2 174.1(9) . . . . ?
Eu1 N1 C1 N2 -9.4(9) . . . . ?
C6 N1 C1 N5 -4.8(15) . . . . ?
Eu1 N1 C1 N5 171.7(8) . . . . ?
C6 N1 C1 Eu1 -176.5(11) . . . . ?
C9 N2 C1 N1 144.1(9) . . . . ?
Eu2 N2 C1 N1 -79.0(10) . . . . ?
Eu1 N2 C1 N1 8.9(9) . . . . ?
C9 N2 C1 N5 -37.0(12) . . . . ?
Eu2 N2 C1 N5 99.9(9) . . . . ?
Eu1 N2 C1 N5 -172.2(7) . . . . ?
C9 N2 C1 Eu1 135.2(8) . . . . ?
Eu2 N2 C1 Eu1 -87.9(5) . . . . ?
C3 N5 C1 N1 123.6(11) . . . . ?
Si1 N5 C1 N1 -68.7(13) . . . . ?
C3 N5 C1 N2 -55.3(12) . . . . ?
Si1 N5 C1 N2 112.5(10) . . . . ?
C12 N3 C2 N4 -174.7(11) . . . . ?
Eu2 N3 C2 N4 1.5(10) . . . . ?
C12 N3 C2 N6 5.2(17) . . . . ?
Eu2 N3 C2 N6 -178.6(9) . . . . ?
C12 N3 C2 Eu2 -176.2(13) . . . . ?
C5 N4 C2 N3 -174.2(10) . . . . ?
Eu2 N4 C2 N3 -1.5(11) . . . . ?
C5 N4 C2 N6 5.9(16) . . . . ?
Eu2 N4 C2 N6 178.5(8) . . . . ?
C5 N4 C2 Eu2 -172.7(12) . . . . ?
C18 N6 C2 N3 84.0(15) . . . . ?
Si2 N6 C2 N3 -96.8(13) . . . . ?
C18 N6 C2 N4 -96.1(14) . . . . ?
Si2 N6 C2 N4 83.1(12) . . . . ?
C1 N5 C3 C4 -65.8(11) . . . . ?
Si1 N5 C3 C4 125.0(8) . . . . ?
N5 C3 C4 C5 156.3(9) . . . . ?
C2 N4 C5 C4 155.3(10) . . . . ?
Eu2 N4 C5 C4 -13.0(18) . . . . ?
C3 C4 C5 N4 -71.1(12) . . . . ?
C1 N1 C6 C7 -96.3(13) . . . . ?
Eu1 N1 C6 C7 89.0(13) . . . . ?
C1 N1 C6 C8 143.2(13) . . . . ?
Eu1 N1 C6 C8 -31.5(18) . . . . ?
C1 N2 C9 C11 -87.7(11) . . . . ?
Eu2 N2 C9 C11 131.4(8) . . . . ?
Eu1 N2 C9 C11 29.2(12) . . . . ?
C1 N2 C9 C10 153.0(9) . . . . ?
Eu2 N2 C9 C10 12.2(10) . . . . ?
Eu1 N2 C9 C10 -90.1(9) . . . . ?
C2 N3 C12 C13 -117.5(14) . . . . ?
Eu2 N3 C12 C13 69.1(18) . . . . ?
C2 N3 C12 C14 122.6(13) . . . . ?
Eu2 N3 C12 C14 -50.8(19) . . . . ?
C2 N6 C18 C19 -143.9(16) . . . . ?
Si2 N6 C18 C19 37(2) . . . . ?
C2 N6 C18 C20 14.1(18) . . . . ?
Si2 N6 C18 C20 -165.1(11) . . . . ?
C29 N7 C24 N11 173.0(9) . . . . ?
Eu1 N7 C24 N11 -51.7(9) . . . . ?
Eu2 N7 C24 N11 33.6(9) . . . . ?
C29 N7 C24 N8 -11.7(15) . . . . ?
Eu1 N7 C24 N8 123.6(9) . . . . ?
Eu2 N7 C24 N8 -151.1(9) . . . . ?
C29 N7 C24 Eu1 -135.3(9) . . . . ?
Eu2 N7 C24 Eu1 85.3(2) . . . . ?
C29 N7 C24 Eu2 139.4(9) . . . . ?
Eu1 N7 C24 Eu2 -85.3(2) . . . . ?
C32' N11 C24 N7 -176(3) . . . . ?
C32 N11 C24 N7 167(3) . . . . ?
Eu2 N11 C24 N7 -35.7(9) . . . . ?
Eu1 N11 C24 N7 48.3(8) . . . . ?
C32' N11 C24 N8 8(4) . . . . ?
C32 N11 C24 N8 -8(4) . . . . ?
Eu2 N11 C24 N8 148.9(8) . . . . ?
Eu1 N11 C24 N8 -127.1(8) . . . . ?
C32' N11 C24 Eu1 135(3) . . . . ?
C32 N11 C24 Eu1 119(3) . . . . ?
Eu2 N11 C24 Eu1 -84.0(2) . . . . ?
C32' N11 C24 Eu2 -141(3) . . . . ?
C32 N11 C24 Eu2 -157(4) . . . . ?
Eu1 N11 C24 Eu2 84.0(2) . . . . ?
C26 N8 C24 N7 -66.2(14) . . . . ?
Si3 N8 C24 N7 99.8(11) . . . . ?
C26 N8 C24 N11 108.8(11) . . . . ?
Si3 N8 C24 N11 -85.2(12) . . . . ?
C26 N8 C24 Eu1 17.8(14) . . . . ?
Si3 N8 C24 Eu1 -176.2(5) . . . . ?
C26 N8 C24 Eu2 -168.8(13) . . . . ?
Si3 N8 C24 Eu2 -3(2) . . . . ?
C35 N9 C25 N10 -178.8(12) . . . . ?
Eu1 N9 C25 N10 -2.4(13) . . . . ?
C35 N9 C25 N12 7.4(19) . . . . ?
Eu1 N9 C25 N12 -176.2(10) . . . . ?
C35 N9 C25 N12' -36(2) . . . . ?
Eu1 N9 C25 N12' 140.3(17) . . . . ?
C35 N9 C25 Eu1 -176.4(14) . . . . ?
C28 N10 C25 N9 -177.8(13) . . . . ?
Eu1 N10 C25 N9 2.3(12) . . . . ?
C28 N10 C25 N12 -4.2(19) . . . . ?
Eu1 N10 C25 N12 176.0(10) . . . . ?
C28 N10 C25 N12' 30.8(18) . . . . ?
Eu1 N10 C25 N12' -149.1(12) . . . . ?
C28 N10 C25 Eu1 179.8(14) . . . . ?
C24 N8 C26 C27 -83.5(12) . . . . ?
Si3 N8 C26 C27 109.1(10) . . . . ?
N8 C26 C27 C28 132.4(11) . . . . ?
C25 N10 C28 C27 164.6(12) . . . . ?
Eu1 N10 C28 C27 -16(3) . . . . ?
C26 C27 C28 N10 -59.8(16) . . . . ?
C24 N7 C29 C30 -106.8(12) . . . . ?
Eu1 N7 C29 C30 137.9(9) . . . . ?
Eu2 N7 C29 C30 11.4(14) . . . . ?
C24 N7 C29 C31 131.4(11) . . . . ?
Eu1 N7 C29 C31 16.1(14) . . . . ?
Eu2 N7 C29 C31 -110.4(10) . . . . ?
C24 N11 C32 C33 133(3) . . . . ?
Eu2 N11 C32 C33 -13(7) . . . . ?
Eu1 N11 C32 C33 -128(3) . . . . ?
C24 N11 C32 C34 -106(4) . . . . ?
Eu2 N11 C32 C34 109(4) . . . . ?
Eu1 N11 C32 C34 -7(5) . . . . ?
C24 N11 C32' C34' -124(4) . . . . ?
Eu2 N11 C32' C34' 109(4) . . . . ?
Eu1 N11 C32' C34' -13(7) . . . . ?
C24 N11 C32' C33' 114(4) . . . . ?
Eu2 N11 C32' C33' -12(6) . . . . ?
Eu1 N11 C32' C33' -135(3) . . . . ?
C25 N9 C35 C36 -121.6(14) . . . . ?
Eu1 N9 C35 C36 64.4(19) . . . . ?
C25 N9 C35 C37 118.5(14) . . . . ?
Eu1 N9 C35 C37 -56(2) . . . . ?
N9 C25 N12 C41 90.8(17) . . . . ?
N10 C25 N12 C41 -82.6(18) . . . . ?
N9 C25 N12 Si4 -101.2(13) . . . . ?
N10 C25 N12 Si4 85.4(14) . . . . ?
C43 C41 N12 C25 -130.4(14) . . . . ?
C42 C41 N12 C25 1(2) . . . . ?
C43 C41 N12 Si4 62.1(16) . . . . ?
C42 C41 N12 Si4 -166.3(11) . . . . ?
C25 N12 Si4 C46 -121.9(11) . . . . ?
C41 N12 Si4 C46 46.6(13) . . . . ?
C25 N12 Si4 C45 117.3(11) . . . . ?
C41 N12 Si4 C45 -74.3(12) . . . . ?
C25 N12 Si4 C44 -3.2(12) . . . . ?
C41 N12 Si4 C44 165.2(11) . . . . ?
C43' C41' N12' C25 144(5) . . . . ?
C42' C41' N12' C25 4(9) . . . . ?
C43' C41' N12' Si4' -33(7) . . . . ?
C42' C41' N12' Si4' -173(4) . . . . ?
N9 C25 N12' C41' -69(6) . . . . ?
N10 C25 N12' C41' 77(6) . . . . ?
Eu1 C25 N12' C41' 21(9) . . . . ?
N9 C25 N12' Si4' 107(2) . . . . ?
N10 C25 N12' Si4' -107(3) . . . . ?
Eu1 C25 N12' Si4' -162.3(14) . . . . ?
C41' N12' Si4' C46' 74(5) . . . . ?
C25 N12' Si4' C46' -103(3) . . . . ?
C41' N12' Si4' C44' -44(5) . . . . ?
C25 N12' Si4' C44' 139(3) . . . . ?
C41' N12' Si4' C45' -166(4) . . . . ?
C25 N12' Si4' C45' 17(4) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C29 H29 N8 0.99 2.34 2.843(15) 110.3 .
C12 H12 N6 0.99 2.40 2.887(17) 109.5 .
C29 H29 N8 0.99 2.34 2.843(15) 110.3 .
C35 H35 N12 0.99 2.32 2.807(19) 109.5 .

_refine_diff_density_max         1.270
_refine_diff_density_min         -1.021
_refine_diff_density_rms         0.132

# start Validation Reply Form

_vrf_PLAT910_shelxl              
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min)  17 Note,
RESPONSE: Because of beamstop theta-min limit set too high.
;

# end Validation Reply Form

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl
_database_code_depnum_ccdc_archive 'CCDC 1487480'
_audit_update_record             
;
2016-10-16 deposited with the CCDC.
2016-10-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C56 H88 Eu2 N12 O2, 2(C4 H8 O)'
_chemical_formula_sum            'C64 H104 Eu2 N12 O4'
_chemical_formula_weight         1409.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.834(4)
_cell_length_b                   14.323(4)
_cell_length_c                   19.638(7)
_cell_angle_alpha                90
_cell_angle_beta                 107.298(6)
_cell_angle_gamma                90
_cell_volume                     3447(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    15742
_cell_measurement_theta_min      3.0
_cell_measurement_theta_max      27.4

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.358
_exptl_crystal_F_000             1460
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.450
_exptl_crystal_size_min          0.440
_exptl_absorpt_coefficient_mu    1.855
_shelx_estimated_absorpt_T_min   0.457
_shelx_estimated_absorpt_T_max   0.496
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.429
_exptl_absorpt_correction_T_max  0.473
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 14.63
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            17190
_diffrn_reflns_av_unetI/netI     0.0557
_diffrn_reflns_av_R_equivalents  0.0447
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         3.045
_diffrn_reflns_theta_max         25.500
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             6356
_reflns_number_gt                5002
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       CrystalClear
_computing_cell_refinement       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0563P)²+1.7627P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6356
_refine_ls_number_parameters     361
_refine_ls_number_restraints     22
_refine_ls_R_factor_all          0.0648
_refine_ls_R_factor_gt           0.0471
_refine_ls_wR_factor_ref         0.1233
_refine_ls_wR_factor_gt          0.1115
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_restrained_S_all      1.083
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.38685(2) 0.06801(2) -0.00302(2) 0.04070(12) Uani 1 1 d . . . . .
O1 O 0.2749(5) 0.0790(3) 0.0911(3) 0.0803(16) Uani 1 1 d D . . . .
O2 O -0.0368(16) 0.5442(13) 0.1115(11) 0.165(5) Uiso 0.5 1 d D . P A 1
O2' O 0.0649(16) 0.5096(15) 0.1119(11) 0.165(5) Uiso 0.5 1 d D . P B 2
N1 N 0.5867(3) 0.1135(3) 0.0342(2) 0.0384(10) Uani 1 1 d . . . . .
N2 N 0.5740(4) 0.0100(3) 0.1164(2) 0.0502(12) Uani 1 1 d . . . . .
N3 N 0.6811(4) 0.1455(3) 0.1558(2) 0.0522(12) Uani 1 1 d D . . . .
H3 H 0.692(5) 0.115(4) 0.201(2) 0.078 Uiso 1 1 d D U . . .
N4 N 0.4189(3) 0.2294(3) -0.0378(2) 0.0417(10) Uani 1 1 d . . . . .
N5 N 0.2403(4) 0.1868(3) -0.0728(3) 0.0545(13) Uani 1 1 d . . . . .
N6 N 0.2803(4) 0.3475(3) -0.0552(3) 0.0640(15) Uani 1 1 d D . . . .
H6 H 0.203(2) 0.357(5) -0.065(4) 0.096 Uiso 1 1 d D U . . .
C1 C 0.6150(4) 0.0901(4) 0.1035(3) 0.0406(12) Uani 1 1 d . . . . .
C2 C 0.3101(5) 0.2553(4) -0.0573(3) 0.0462(13) Uani 1 1 d . . . . .
C3 C 0.6512(5) 0.1726(4) 0.0051(2) 0.0442(14) Uani 1 1 d . . . . .
C4 C 0.7627(5) 0.1534(4) 0.0241(3) 0.0519(14) Uani 1 1 d . . . . .
H4 H 0.7922 0.1081 0.0592 0.062 Uiso 1 1 calc R U . . .
C5 C 0.8319(5) 0.2006(4) -0.0083(3) 0.0568(15) Uani 1 1 d . . . . .
H5 H 0.9074 0.1890 0.0070 0.068 Uiso 1 1 calc R U . . .
C6 C 0.7896(5) 0.2624(5) -0.0612(3) 0.0591(16) Uani 1 1 d . . . . .
H6A H 0.8357 0.2925 -0.0837 0.071 Uiso 1 1 calc R U . . .
C7 C 0.6768(5) 0.2822(4) -0.0831(3) 0.0440(13) Uani 1 1 d . . . . .
C8 C 0.6350(6) 0.3446(4) -0.1407(3) 0.0572(16) Uani 1 1 d . . . . .
H8 H 0.6821 0.3722 -0.1635 0.069 Uiso 1 1 calc R U . . .
C9 C 0.5270(6) 0.3645(4) -0.1628(3) 0.0634(17) Uani 1 1 d . . . . .
H9 H 0.4998 0.4047 -0.2019 0.076 Uiso 1 1 calc R U . . .
C10 C 0.4550(5) 0.3271(4) -0.1293(3) 0.0490(14) Uani 1 1 d . . . . .
H10 H 0.3808 0.3432 -0.1463 0.059 Uiso 1 1 calc R U . . .
C11 C 0.4891(4) 0.2664(3) -0.0714(3) 0.0403(12) Uani 1 1 d . . . . .
C12 C 0.6046(4) 0.2393(3) -0.0490(3) 0.0372(12) Uani 1 1 d . . . . .
C13 C 0.5862(6) -0.0194(4) 0.1901(3) 0.0639(19) Uani 1 1 d . . . . .
H13 H 0.5900 0.0375 0.2193 0.077 Uiso 1 1 calc R U . . .
C14 C 0.6887(9) -0.0729(6) 0.2202(4) 0.106(3) Uani 1 1 d . . . . .
H14A H 0.6845 -0.1313 0.1945 0.159 Uiso 1 1 calc R U . . .
H14B H 0.6984 -0.0858 0.2702 0.159 Uiso 1 1 calc R U . . .
H14C H 0.7501 -0.0367 0.2156 0.159 Uiso 1 1 calc R U . . .
C15 C 0.4870(8) -0.0743(5) 0.1922(4) 0.092(3) Uani 1 1 d . . . . .
H15A H 0.4220 -0.0370 0.1723 0.139 Uiso 1 1 calc R U . . .
H15B H 0.4929 -0.0902 0.2412 0.139 Uiso 1 1 calc R U . . .
H15C H 0.4822 -0.1310 0.1645 0.139 Uiso 1 1 calc R U . . .
C16 C 0.6789(5) 0.2471(4) 0.1550(3) 0.0524(15) Uani 1 1 d . . . . .
H16 H 0.6990 0.2689 0.1127 0.063 Uiso 1 1 calc R U . . .
C17 C 0.7633(7) 0.2832(6) 0.2213(4) 0.101(3) Uani 1 1 d . . . . .
H17A H 0.7471 0.2595 0.2633 0.152 Uiso 1 1 calc R U . . .
H17B H 0.7616 0.3509 0.2215 0.152 Uiso 1 1 calc R U . . .
H17C H 0.8352 0.2622 0.2214 0.152 Uiso 1 1 calc R U . . .
C18 C 0.5687(6) 0.2845(5) 0.1504(4) 0.082(2) Uani 1 1 d . . . . .
H18A H 0.5157 0.2601 0.1080 0.123 Uiso 1 1 calc R U . . .
H18B H 0.5698 0.3521 0.1478 0.123 Uiso 1 1 calc R U . . .
H18C H 0.5488 0.2658 0.1923 0.123 Uiso 1 1 calc R U . . .
C19 C 0.1233(5) 0.2060(5) -0.0900(5) 0.077(2) Uani 1 1 d . . . . .
H19 H 0.1097 0.2518 -0.0558 0.092 Uiso 1 1 calc R U . . .
C20 C 0.0796(6) 0.2435(7) -0.1665(5) 0.111(3) Uani 1 1 d . . . . .
H20A H 0.1174 0.3009 -0.1707 0.166 Uiso 1 1 calc R U . . .
H20B H 0.0020 0.2559 -0.1775 0.166 Uiso 1 1 calc R U . . .
H20C H 0.0917 0.1976 -0.1996 0.166 Uiso 1 1 calc R U . . .
C21 C 0.0655(7) 0.1148(7) -0.0854(6) 0.124(4) Uani 1 1 d . . . . .
H21A H 0.0827 0.0692 -0.1169 0.186 Uiso 1 1 calc R U . . .
H21B H -0.0127 0.1251 -0.0995 0.186 Uiso 1 1 calc R U . . .
H21C H 0.0895 0.0917 -0.0368 0.186 Uiso 1 1 calc R U . . .
C22 C 0.3507(6) 0.4190(4) -0.0106(4) 0.0658(19) Uani 1 1 d . . . . .
H22 H 0.4278 0.4006 -0.0027 0.079 Uiso 1 1 calc R U . . .
C23 C 0.3327(7) 0.5125(5) -0.0476(6) 0.105(3) Uani 1 1 d . . . . .
H23A H 0.3353 0.5052 -0.0962 0.157 Uiso 1 1 calc R U . . .
H23B H 0.3894 0.5555 -0.0223 0.157 Uiso 1 1 calc R U . . .
H23C H 0.2620 0.5369 -0.0481 0.157 Uiso 1 1 calc R U . . .
C24 C 0.3297(8) 0.4246(5) 0.0612(5) 0.099(3) Uani 1 1 d . . . . .
H24A H 0.2546 0.4431 0.0545 0.149 Uiso 1 1 calc R U . . .
H24B H 0.3783 0.4703 0.0909 0.149 Uiso 1 1 calc R U . . .
H24C H 0.3426 0.3640 0.0842 0.149 Uiso 1 1 calc R U . . .
C25 C 0.1843(12) 0.0283(12) 0.1027(8) 0.0819(17) Uiso 0.5 1 d D . P C 1
H25A H 0.2044 -0.0373 0.1131 0.098 Uiso 0.5 1 calc R U P C 1
H25B H 0.1213 0.0309 0.0597 0.098 Uiso 0.5 1 calc R U P C 1
C25' C 0.2207(14) 0.0118(11) 0.1249(8) 0.0819(17) Uiso 0.5 1 d D . P C 2
H25C H 0.2629 -0.0461 0.1361 0.098 Uiso 0.5 1 calc R U P C 2
H25D H 0.1474 -0.0028 0.0936 0.098 Uiso 0.5 1 calc R U P C 2
C26 C 0.1565(14) 0.0707(10) 0.1627(9) 0.0819(17) Uiso 0.5 1 d D . P C 1
H26A H 0.1658 0.0254 0.2014 0.098 Uiso 0.5 1 calc R U P C 1
H26B H 0.0805 0.0920 0.1478 0.098 Uiso 0.5 1 calc R U P C 1
C26' C 0.2148(15) 0.0590(9) 0.1912(8) 0.0819(17) Uiso 0.5 1 d D . P C 2
H26C H 0.2847 0.0568 0.2290 0.098 Uiso 0.5 1 calc R U P C 2
H26D H 0.1571 0.0329 0.2089 0.098 Uiso 0.5 1 calc R U P C 2
C27 C 0.2333(13) 0.1527(11) 0.1872(8) 0.0819(17) Uiso 0.5 1 d D . P C 1
H27A H 0.1920 0.2106 0.1859 0.098 Uiso 0.5 1 calc R U P C 1
H27B H 0.2804 0.1427 0.2361 0.098 Uiso 0.5 1 calc R U P C 1
C27' C 0.1866(13) 0.1597(10) 0.1607(9) 0.0819(17) Uiso 0.5 1 d D . P C 2
H27C H 0.1094 0.1647 0.1332 0.098 Uiso 0.5 1 calc R U P C 2
H27D H 0.2032 0.2062 0.1990 0.098 Uiso 0.5 1 calc R U P C 2
C28 C 0.2994(13) 0.1581(10) 0.1370(8) 0.0819(17) Uiso 0.5 1 d D . P C 1
H28A H 0.2822 0.2156 0.1088 0.098 Uiso 0.5 1 calc R U P C 1
H28B H 0.3773 0.1587 0.1635 0.098 Uiso 0.5 1 calc R U P C 1
C28' C 0.2578(13) 0.1721(10) 0.1143(9) 0.0819(17) Uiso 0.5 1 d D . P C 2
H28C H 0.2222 0.2118 0.0733 0.098 Uiso 0.5 1 calc R U P C 2
H28D H 0.3274 0.2008 0.1408 0.098 Uiso 0.5 1 calc R U P C 2
C29 C 0.003(3) 0.509(2) 0.0555(16) 0.207(5) Uiso 0.5 1 d D . P A 1
H29A H 0.0723 0.5385 0.0563 0.248 Uiso 0.5 1 calc R U P A 1
H29B H -0.0502 0.5184 0.0086 0.248 Uiso 0.5 1 calc R U P A 1
C29' C 0.051(3) 0.408(2) 0.107(2) 0.207(5) Uiso 0.5 1 d D . P B 2
H29C H 0.1190 0.3762 0.1326 0.248 Uiso 0.5 1 calc R U P B 2
H29D H 0.0298 0.3877 0.0569 0.248 Uiso 0.5 1 calc R U P B 2
C30 C 0.018(3) 0.407(2) 0.0740(19) 0.207(5) Uiso 0.5 1 d D . P A 1
H30A H -0.0362 0.3697 0.0392 0.248 Uiso 0.5 1 calc R U P A 1
H30B H 0.0911 0.3866 0.0749 0.248 Uiso 0.5 1 calc R U P A 1
C30' C -0.037(3) 0.386(3) 0.140(2) 0.207(5) Uiso 0.5 1 d D . P B 2
H30C H -0.0212 0.3306 0.1703 0.248 Uiso 0.5 1 calc R U P B 2
H30D H -0.1092 0.3813 0.1048 0.248 Uiso 0.5 1 calc R U P B 2
C31 C 0.003(3) 0.399(3) 0.146(2) 0.207(5) Uiso 0.5 1 d D . P A 1
H31A H -0.0485 0.3475 0.1454 0.248 Uiso 0.5 1 calc R U P A 1
H31B H 0.0728 0.3818 0.1807 0.248 Uiso 0.5 1 calc R U P A 1
C31' C -0.019(4) 0.476(3) 0.181(2) 0.207(5) Uiso 0.5 1 d D . P B 2
H31C H -0.0039 0.4588 0.2313 0.248 Uiso 0.5 1 calc R U P B 2
H31D H -0.0901 0.5081 0.1677 0.248 Uiso 0.5 1 calc R U P B 2
C32 C -0.039(4) 0.485(3) 0.172(2) 0.207(5) Uiso 0.5 1 d D . P A 1
H32A H -0.1127 0.4770 0.1763 0.248 Uiso 0.5 1 calc R U P A 1
H32B H 0.0103 0.5076 0.2176 0.248 Uiso 0.5 1 calc R U P A 1
C32' C 0.065(3) 0.551(2) 0.1790(16) 0.207(5) Uiso 0.5 1 d D . P B 2
H32C H 0.0365 0.6149 0.1750 0.248 Uiso 0.5 1 calc R U P B 2
H32D H 0.1340 0.5454 0.2169 0.248 Uiso 0.5 1 calc R U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N4 2.479(4) . ?
Eu1 N1 2.535(4) . ?
Eu1 N5 2.603(5) . ?
Eu1 O1 2.662(4) . ?
Eu1 N2 2.669(4) 3_655 ?
Eu1 N1 2.715(4) 3_655 ?
Eu1 N2 2.934(5) . ?
Eu1 C2 2.946(6) . ?
Eu1 C1 2.999(5) 3_655 ?
Eu1 C1 3.067(5) . ?
Eu1 Eu1 3.4697(10) 3_655 ?
O1 C28 1.422(13) . ?
O1 C25 1.445(13) . ?
O1 C28' 1.446(13) . ?
O1 C25' 1.457(13) . ?
O2 C29 1.434(17) . ?
O2 C32 1.47(2) . ?
O2' C32' 1.446(18) . ?
O2' C29' 1.469(18) . ?
N1 C1 1.343(6) . ?
N1 C3 1.417(6) . ?
N1 Eu1 2.715(4) 3_655 ?
N2 C1 1.318(7) . ?
N2 C13 1.469(7) . ?
N2 Eu1 2.669(4) 3_655 ?
N3 C1 1.374(6) . ?
N3 C16 1.456(7) . ?
N3 H3 0.96(2) . ?
N4 C11 1.372(6) . ?
N4 C2 1.384(7) . ?
N5 C2 1.302(7) . ?
N5 C19 1.465(8) . ?
N6 C2 1.379(7) . ?
N6 C22 1.471(8) . ?
N6 H6 0.97(2) . ?
C1 Eu1 2.999(5) 3_655 ?
C3 C4 1.394(8) . ?
C3 C12 1.423(8) . ?
C4 C5 1.409(8) . ?
C4 H4 0.9400 . ?
C5 C6 1.351(9) . ?
C5 H5 0.9400 . ?
C6 C7 1.411(8) . ?
C6 H6A 0.9400 . ?
C7 C8 1.416(8) . ?
C7 C12 1.432(7) . ?
C8 C9 1.354(9) . ?
C8 H8 0.9400 . ?
C9 C10 1.390(8) . ?
C9 H9 0.9400 . ?
C10 C11 1.395(7) . ?
C10 H10 0.9400 . ?
C11 C12 1.468(7) . ?
C13 C14 1.485(11) . ?
C13 C15 1.509(10) . ?
C13 H13 0.9900 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 H14C 0.9700 . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C16 C18 1.490(9) . ?
C16 C17 1.515(9) . ?
C16 H16 0.9900 . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 H17C 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 H18C 0.9700 . ?
C19 C21 1.518(11) . ?
C19 C20 1.537(12) . ?
C19 H19 0.9900 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C21 H21C 0.9700 . ?
C22 C23 1.508(10) . ?
C22 C24 1.515(11) . ?
C22 H22 0.9900 . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C24 H24C 0.9700 . ?
C25 C26 1.461(15) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25' C26' 1.490(15) . ?
C25' H25C 0.9800 . ?
C25' H25D 0.9800 . ?
C26 C27 1.517(15) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26' C27' 1.563(15) . ?
C26' H26C 0.9800 . ?
C26' H26D 0.9800 . ?
C27 C28 1.482(15) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27' C28' 1.481(15) . ?
C27' H27C 0.9800 . ?
C27' H27D 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28' H28C 0.9800 . ?
C28' H28D 0.9800 . ?
C29 C30 1.499(19) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29' C30' 1.487(19) . ?
C29' H29C 0.9800 . ?
C29' H29D 0.9800 . ?
C30 C31 1.497(19) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30' C31' 1.509(19) . ?
C30' H30C 0.9800 . ?
C30' H30D 0.9800 . ?
C31 C32 1.494(19) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31' C32' 1.524(19) . ?
C31' H31C 0.9800 . ?
C31' H31D 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32' H32C 0.9800 . ?
C32' H32D 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Eu1 N1 66.62(13) . . ?
N4 Eu1 N5 53.02(14) . . ?
N1 Eu1 N5 119.63(14) . . ?
N4 Eu1 O1 107.67(14) . . ?
N1 Eu1 O1 119.57(15) . . ?
N5 Eu1 O1 82.67(17) . . ?
N4 Eu1 N2 94.19(14) . 3_655 ?
N1 Eu1 N2 85.56(14) . 3_655 ?
N5 Eu1 N2 96.89(15) . 3_655 ?
O1 Eu1 N2 151.47(14) . 3_655 ?
N4 Eu1 N1 142.09(14) . 3_655 ?
N1 Eu1 N1 97.34(12) . 3_655 ?
N5 Eu1 N1 128.77(13) . 3_655 ?
O1 Eu1 N1 110.03(13) . 3_655 ?
N2 Eu1 N1 49.01(13) 3_655 3_655 ?
N4 Eu1 N2 108.72(13) . . ?
N1 Eu1 N2 47.53(13) . . ?
N5 Eu1 N2 153.82(13) . . ?
O1 Eu1 N2 86.80(16) . . ?
N2 Eu1 N2 103.65(11) 3_655 . ?
N1 Eu1 N2 77.39(12) 3_655 . ?
N4 Eu1 C2 27.90(14) . . ?
N1 Eu1 C2 94.07(14) . . ?
N5 Eu1 C2 26.21(14) . . ?
O1 Eu1 C2 90.31(16) . . ?
N2 Eu1 C2 101.85(15) 3_655 . ?
N1 Eu1 C2 147.28(14) 3_655 . ?
N2 Eu1 C2 130.78(14) . . ?
N4 Eu1 C1 119.51(14) . 3_655 ?
N1 Eu1 C1 101.14(14) . 3_655 ?
N5 Eu1 C1 106.49(15) . 3_655 ?
O1 Eu1 C1 126.97(14) . 3_655 ?
N2 Eu1 C1 26.06(13) 3_655 3_655 ?
N1 Eu1 C1 26.59(13) 3_655 3_655 ?
N2 Eu1 C1 99.01(13) . 3_655 ?
C2 Eu1 C1 120.89(15) . 3_655 ?
N4 Eu1 C1 83.62(14) . . ?
N1 Eu1 C1 25.55(13) . . ?
N5 Eu1 C1 133.26(14) . . ?
O1 Eu1 C1 97.07(16) . . ?
N2 Eu1 C1 103.53(15) 3_655 . ?
N1 Eu1 C1 95.44(13) 3_655 . ?
N2 Eu1 C1 25.25(13) . . ?
C2 Eu1 C1 107.55(15) . . ?
C1 Eu1 C1 110.24(11) 3_655 . ?
N4 Eu1 Eu1 109.12(10) . 3_655 ?
N1 Eu1 Eu1 50.91(9) . 3_655 ?
N5 Eu1 Eu1 148.34(11) . 3_655 ?
O1 Eu1 Eu1 128.95(13) . 3_655 ?
N2 Eu1 Eu1 55.26(11) 3_655 3_655 ?
N1 Eu1 Eu1 46.43(9) 3_655 3_655 ?
N2 Eu1 Eu1 48.38(9) . 3_655 ?
C2 Eu1 Eu1 135.26(11) . 3_655 ?
C1 Eu1 Eu1 56.03(10) 3_655 3_655 ?
C1 Eu1 Eu1 54.20(10) . 3_655 ?
C28 O1 C25 109.7(9) . . ?
C28' O1 C25' 109.2(9) . . ?
C28 O1 Eu1 115.1(7) . . ?
C25 O1 Eu1 134.8(7) . . ?
C28' O1 Eu1 115.9(7) . . ?
C25' O1 Eu1 134.9(7) . . ?
C29 O2 C32 121(3) . . ?
C32' O2' C29' 116(2) . . ?
C1 N1 C3 122.9(4) . . ?
C1 N1 Eu1 100.0(3) . . ?
C3 N1 Eu1 134.4(3) . . ?
C1 N1 Eu1 88.6(3) . 3_655 ?
C3 N1 Eu1 110.7(3) . 3_655 ?
Eu1 N1 Eu1 82.66(12) . 3_655 ?
C1 N2 C13 120.4(5) . . ?
C1 N2 Eu1 91.1(3) . 3_655 ?
C13 N2 Eu1 135.2(4) . 3_655 ?
C1 N2 Eu1 83.0(3) . . ?
C13 N2 Eu1 133.7(4) . . ?
Eu1 N2 Eu1 76.35(11) 3_655 . ?
C1 N3 C16 124.3(5) . . ?
C1 N3 H3 109(4) . . ?
C16 N3 H3 117(4) . . ?
C11 N4 C2 121.1(5) . . ?
C11 N4 Eu1 132.7(3) . . ?
C2 N4 Eu1 95.2(3) . . ?
C2 N5 C19 119.9(5) . . ?
C2 N5 Eu1 91.7(3) . . ?
C19 N5 Eu1 140.8(4) . . ?
C2 N6 C22 123.9(5) . . ?
C2 N6 H6 114(5) . . ?
C22 N6 H6 115(5) . . ?
N2 C1 N1 114.2(4) . . ?
N2 C1 N3 123.6(5) . . ?
N1 C1 N3 122.3(5) . . ?
N2 C1 Eu1 62.9(3) . 3_655 ?
N1 C1 Eu1 64.8(3) . 3_655 ?
N3 C1 Eu1 144.1(4) . 3_655 ?
N2 C1 Eu1 71.7(3) . . ?
N1 C1 Eu1 54.5(3) . . ?
N3 C1 Eu1 145.3(4) . . ?
Eu1 C1 Eu1 69.77(11) 3_655 . ?
N5 C2 N6 123.5(5) . . ?
N5 C2 N4 115.4(5) . . ?
N6 C2 N4 120.9(5) . . ?
N5 C2 Eu1 62.0(3) . . ?
N6 C2 Eu1 158.0(4) . . ?
N4 C2 Eu1 56.9(3) . . ?
C4 C3 N1 116.7(5) . . ?
C4 C3 C12 120.2(5) . . ?
N1 C3 C12 122.4(5) . . ?
C3 C4 C5 121.3(6) . . ?
C3 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
C6 C5 C4 119.9(6) . . ?
C6 C5 H5 120.0 . . ?
C4 C5 H5 120.0 . . ?
C5 C6 C7 120.4(5) . . ?
C5 C6 H6A 119.8 . . ?
C7 C6 H6A 119.8 . . ?
C6 C7 C8 118.7(5) . . ?
C6 C7 C12 121.3(5) . . ?
C8 C7 C12 120.0(5) . . ?
C9 C8 C7 119.8(5) . . ?
C9 C8 H8 120.1 . . ?
C7 C8 H8 120.1 . . ?
C8 C9 C10 121.8(6) . . ?
C8 C9 H9 119.1 . . ?
C10 C9 H9 119.1 . . ?
C9 C10 C11 122.4(6) . . ?
C9 C10 H10 118.8 . . ?
C11 C10 H10 118.8 . . ?
N4 C11 C10 122.8(5) . . ?
N4 C11 C12 120.3(5) . . ?
C10 C11 C12 116.9(5) . . ?
C3 C12 C7 116.8(5) . . ?
C3 C12 C11 124.3(4) . . ?
C7 C12 C11 118.9(5) . . ?
N2 C13 C14 111.3(6) . . ?
N2 C13 C15 109.4(6) . . ?
C14 C13 C15 112.0(6) . . ?
N2 C13 H13 108.0 . . ?
C14 C13 H13 108.0 . . ?
C15 C13 H13 108.0 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N3 C16 C18 112.0(5) . . ?
N3 C16 C17 108.9(5) . . ?
C18 C16 C17 110.7(6) . . ?
N3 C16 H16 108.4 . . ?
C18 C16 H16 108.4 . . ?
C17 C16 H16 108.4 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N5 C19 C21 108.1(6) . . ?
N5 C19 C20 110.0(6) . . ?
C21 C19 C20 108.5(7) . . ?
N5 C19 H19 110.1 . . ?
C21 C19 H19 110.1 . . ?
C20 C19 H19 110.1 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
N6 C22 C23 110.6(6) . . ?
N6 C22 C24 110.0(6) . . ?
C23 C22 C24 111.0(6) . . ?
N6 C22 H22 108.4 . . ?
C23 C22 H22 108.4 . . ?
C24 C22 H22 108.4 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
O1 C25 C26 108.6(12) . . ?
O1 C25 H25A 110.0 . . ?
C26 C25 H25A 110.0 . . ?
O1 C25 H25B 110.0 . . ?
C26 C25 H25B 110.0 . . ?
H25A C25 H25B 108.4 . . ?
O1 C25' C26' 104.7(11) . . ?
O1 C25' H25C 110.8 . . ?
C26' C25' H25C 110.8 . . ?
O1 C25' H25D 110.8 . . ?
C26' C25' H25D 110.8 . . ?
H25C C25' H25D 108.9 . . ?
C25 C26 C27 106.7(12) . . ?
C25 C26 H26A 110.4 . . ?
C27 C26 H26A 110.4 . . ?
C25 C26 H26B 110.4 . . ?
C27 C26 H26B 110.4 . . ?
H26A C26 H26B 108.6 . . ?
C25' C26' C27' 98.6(12) . . ?
C25' C26' H26C 112.1 . . ?
C27' C26' H26C 112.1 . . ?
C25' C26' H26D 112.1 . . ?
C27' C26' H26D 112.1 . . ?
H26C C26' H26D 109.7 . . ?
C28 C27 C26 105.9(12) . . ?
C28 C27 H27A 110.5 . . ?
C26 C27 H27A 110.5 . . ?
C28 C27 H27B 110.5 . . ?
C26 C27 H27B 110.5 . . ?
H27A C27 H27B 108.7 . . ?
C28' C27' C26' 103.4(12) . . ?
C28' C27' H27C 111.1 . . ?
C26' C27' H27C 111.1 . . ?
C28' C27' H27D 111.1 . . ?
C26' C27' H27D 111.1 . . ?
H27C C27' H27D 109.0 . . ?
O1 C28 C27 108.5(11) . . ?
O1 C28 H28A 110.0 . . ?
C27 C28 H28A 110.0 . . ?
O1 C28 H28B 110.0 . . ?
C27 C28 H28B 110.0 . . ?
H28A C28 H28B 108.4 . . ?
O1 C28' C27' 105.2(11) . . ?
O1 C28' H28C 110.7 . . ?
C27' C28' H28C 110.7 . . ?
O1 C28' H28D 110.7 . . ?
C27' C28' H28D 110.7 . . ?
H28C C28' H28D 108.8 . . ?
O2 C29 C30 102(3) . . ?
O2 C29 H29A 111.4 . . ?
C30 C29 H29A 111.4 . . ?
O2 C29 H29B 111.4 . . ?
C30 C29 H29B 111.4 . . ?
H29A C29 H29B 109.3 . . ?
O2' C29' C30' 106(3) . . ?
O2' C29' H29C 110.6 . . ?
C30' C29' H29C 110.6 . . ?
O2' C29' H29D 110.6 . . ?
C30' C29' H29D 110.6 . . ?
H29C C29' H29D 108.7 . . ?
C31 C30 C29 106(3) . . ?
C31 C30 H30A 110.6 . . ?
C29 C30 H30A 110.6 . . ?
C31 C30 H30B 110.6 . . ?
C29 C30 H30B 110.6 . . ?
H30A C30 H30B 108.8 . . ?
C29' C30' C31' 92(3) . . ?
C29' C30' H30C 113.2 . . ?
C31' C30' H30C 113.2 . . ?
C29' C30' H30D 113.2 . . ?
C31' C30' H30D 113.2 . . ?
H30C C30' H30D 110.6 . . ?
C32 C31 C30 115(4) . . ?
C32 C31 H31A 108.6 . . ?
C30 C31 H31A 108.6 . . ?
C32 C31 H31B 108.6 . . ?
C30 C31 H31B 108.6 . . ?
H31A C31 H31B 107.6 . . ?
C30' C31' C32' 125(3) . . ?
C30' C31' H31C 106.0 . . ?
C32' C31' H31C 106.0 . . ?
C30' C31' H31D 106.0 . . ?
C32' C31' H31D 106.0 . . ?
H31C C31' H31D 106.3 . . ?
O2 C32 C31 96(3) . . ?
O2 C32 H32A 112.5 . . ?
C31 C32 H32A 112.5 . . ?
O2 C32 H32B 112.5 . . ?
C31 C32 H32B 112.5 . . ?
H32A C32 H32B 110.1 . . ?
O2' C32' C31' 86(2) . . ?
O2' C32' H32C 114.3 . . ?
C31' C32' H32C 114.3 . . ?
O2' C32' H32D 114.3 . . ?
C31' C32' H32D 114.3 . . ?
H32C C32' H32D 111.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 N2 C1 N1 -172.4(5) . . . . ?
Eu1 N2 C1 N1 41.1(5) 3_655 . . . ?
Eu1 N2 C1 N1 -35.1(4) . . . . ?
C13 N2 C1 N3 7.7(9) . . . . ?
Eu1 N2 C1 N3 -138.8(5) 3_655 . . . ?
Eu1 N2 C1 N3 145.1(5) . . . . ?
C13 N2 C1 Eu1 146.6(6) . . . 3_655 ?
Eu1 N2 C1 Eu1 -76.11(12) . . . 3_655 ?
C13 N2 C1 Eu1 -137.3(6) . . . . ?
Eu1 N2 C1 Eu1 76.11(12) 3_655 . . . ?
C3 N1 C1 N2 -154.2(5) . . . . ?
Eu1 N1 C1 N2 42.1(5) . . . . ?
Eu1 N1 C1 N2 -40.2(5) 3_655 . . . ?
C3 N1 C1 N3 25.7(8) . . . . ?
Eu1 N1 C1 N3 -138.1(5) . . . . ?
Eu1 N1 C1 N3 139.7(5) 3_655 . . . ?
C3 N1 C1 Eu1 -114.0(5) . . . 3_655 ?
Eu1 N1 C1 Eu1 82.29(15) . . . 3_655 ?
C3 N1 C1 Eu1 163.8(6) . . . . ?
Eu1 N1 C1 Eu1 -82.29(15) 3_655 . . . ?
C16 N3 C1 N2 -143.5(6) . . . . ?
C16 N3 C1 N1 36.6(8) . . . . ?
C16 N3 C1 Eu1 127.5(6) . . . 3_655 ?
C16 N3 C1 Eu1 -36.2(10) . . . . ?
C19 N5 C2 N6 0.5(9) . . . . ?
Eu1 N5 C2 N6 -155.2(6) . . . . ?
C19 N5 C2 N4 176.3(6) . . . . ?
Eu1 N5 C2 N4 20.6(5) . . . . ?
C19 N5 C2 Eu1 155.7(6) . . . . ?
C22 N6 C2 N5 152.7(6) . . . . ?
C22 N6 C2 N4 -22.8(9) . . . . ?
C22 N6 C2 Eu1 54.8(14) . . . . ?
C11 N4 C2 N5 126.5(6) . . . . ?
Eu1 N4 C2 N5 -21.7(5) . . . . ?
C11 N4 C2 N6 -57.6(7) . . . . ?
Eu1 N4 C2 N6 154.2(5) . . . . ?
C11 N4 C2 Eu1 148.2(5) . . . . ?
C1 N1 C3 C4 47.0(7) . . . . ?
Eu1 N1 C3 C4 -155.7(4) . . . . ?
Eu1 N1 C3 C4 -55.3(5) 3_655 . . . ?
C1 N1 C3 C12 -142.3(5) . . . . ?
Eu1 N1 C3 C12 15.0(7) . . . . ?
Eu1 N1 C3 C12 115.4(5) 3_655 . . . ?
N1 C3 C4 C5 172.4(5) . . . . ?
C12 C3 C4 C5 1.5(8) . . . . ?
C3 C4 C5 C6 -3.3(9) . . . . ?
C4 C5 C6 C7 1.8(9) . . . . ?
C5 C6 C7 C8 -177.5(6) . . . . ?
C5 C6 C7 C12 1.4(9) . . . . ?
C6 C7 C8 C9 179.8(6) . . . . ?
C12 C7 C8 C9 0.9(8) . . . . ?
C7 C8 C9 C10 1.6(9) . . . . ?
C8 C9 C10 C11 -0.5(9) . . . . ?
C2 N4 C11 C10 -4.0(8) . . . . ?
Eu1 N4 C11 C10 130.5(5) . . . . ?
C2 N4 C11 C12 178.9(4) . . . . ?
Eu1 N4 C11 C12 -46.7(7) . . . . ?
C9 C10 C11 N4 179.7(5) . . . . ?
C9 C10 C11 C12 -3.1(8) . . . . ?
C4 C3 C12 C7 1.6(7) . . . . ?
N1 C3 C12 C7 -168.7(4) . . . . ?
C4 C3 C12 C11 -178.2(5) . . . . ?
N1 C3 C12 C11 11.5(7) . . . . ?
C6 C7 C12 C3 -3.1(7) . . . . ?
C8 C7 C12 C3 175.8(5) . . . . ?
C6 C7 C12 C11 176.7(5) . . . . ?
C8 C7 C12 C11 -4.4(7) . . . . ?
N4 C11 C12 C3 2.5(7) . . . . ?
C10 C11 C12 C3 -174.8(5) . . . . ?
N4 C11 C12 C7 -177.3(4) . . . . ?
C10 C11 C12 C7 5.4(7) . . . . ?
C1 N2 C13 C14 -89.0(7) . . . . ?
Eu1 N2 C13 C14 39.6(9) 3_655 . . . ?
Eu1 N2 C13 C14 159.5(5) . . . . ?
C1 N2 C13 C15 146.7(6) . . . . ?
Eu1 N2 C13 C15 -84.7(7) 3_655 . . . ?
Eu1 N2 C13 C15 35.2(7) . . . . ?
C1 N3 C16 C18 57.3(8) . . . . ?
C1 N3 C16 C17 -180.0(6) . . . . ?
C2 N5 C19 C21 -164.5(7) . . . . ?
Eu1 N5 C19 C21 -24.9(10) . . . . ?
C2 N5 C19 C20 77.3(8) . . . . ?
Eu1 N5 C19 C20 -143.2(6) . . . . ?
C2 N6 C22 C23 146.0(7) . . . . ?
C2 N6 C22 C24 -91.0(8) . . . . ?
C28 O1 C25 C26 -5.7(17) . . . . ?
Eu1 O1 C25 C26 -177.8(9) . . . . ?
C28' O1 C25' C26' -25.0(15) . . . . ?
Eu1 O1 C25' C26' 157.6(8) . . . . ?
O1 C25 C26 C27 1.3(18) . . . . ?
O1 C25' C26' C27' 39.8(16) . . . . ?
C25 C26 C27 C28 3.3(19) . . . . ?
C25' C26' C27' C28' -41.5(17) . . . . ?
C25 O1 C28 C27 7.8(16) . . . . ?
Eu1 O1 C28 C27 -178.4(9) . . . . ?
C26 C27 C28 O1 -6.8(18) . . . . ?
C25' O1 C28' C27' -2.6(15) . . . . ?
Eu1 O1 C28' C27' 175.3(9) . . . . ?
C26' C27' C28' O1 27.8(17) . . . . ?
C32 O2 C29 C30 8(4) . . . . ?
C32' O2' C29' C30' 43(4) . . . . ?
O2 C29 C30 C31 -9(4) . . . . ?
O2' C29' C30' C31' -21(4) . . . . ?
C29 C30 C31 C32 9(5) . . . . ?
C29' C30' C31' C32' 0(6) . . . . ?
C29 O2 C32 C31 -3(5) . . . . ?
C30 C31 C32 O2 -4(5) . . . . ?
C29' O2' C32' C31' -35(4) . . . . ?
C30' C31' C32' O2' 20(5) . . . . ?

_refine_diff_density_max         1.222
_refine_diff_density_min         -1.004
_refine_diff_density_rms         0.106

# start Validation Reply Form

_vrf_PLAT413_shelxl              
;
PROBLEM: Short Inter XH3..XHn  H20B..H32C..    1.92 Ang,
RESPONSE: Because of disordered solvent molecule.
;
_vrf_PLAT414_shelxl              
;
PROBLEM: Intra D-H..H-X    H3..13   ..       1.83 Ang,
RESPONSE: Because of disordered isopropyl group.
;
# end Validation Reply Form

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_g160701a
_database_code_depnum_ccdc_archive 'CCDC 1494633'
_audit_update_record             
;
2016-10-16 deposited with the CCDC.
2016-10-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C31 H68 Cl Eu N6 O2 Si2, C4 H8 O'
_chemical_formula_sum            'C35 H76 Cl Eu N6 O3 Si2'
_chemical_formula_weight         872.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.6965(5)
_cell_length_b                   13.2218(4)
_cell_length_c                   23.7134(8)
_cell_angle_alpha                90
_cell_angle_beta                 92.135(3)
_cell_angle_gamma                90
_cell_volume                     4604.6(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    223(2)
_cell_measurement_reflns_used    8377
_cell_measurement_theta_min      3.1550
_cell_measurement_theta_max      27.8030

_exptl_crystal_description       block
_exptl_crystal_colour            'clear light orange'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.259
_exptl_crystal_F_000             1840
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.30
_exptl_absorpt_coefficient_mu    1.508
_shelx_estimated_absorpt_T_min   0.536
_shelx_estimated_absorpt_T_max   0.636
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.525
_exptl_absorpt_correction_T_max  0.626
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      223(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.4471
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            29154
_diffrn_reflns_av_unetI/netI     0.0433
_diffrn_reflns_av_R_equivalents  0.0460
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.774
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             8105
_reflns_number_gt                6297
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       CrystalClear
_computing_cell_refinement       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0908P)²+36.7570P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8105
_refine_ls_number_parameters     430
_refine_ls_number_restraints     63
_refine_ls_R_factor_all          0.0931
_refine_ls_R_factor_gt           0.0722
_refine_ls_wR_factor_ref         0.2072
_refine_ls_wR_factor_gt          0.1869
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_restrained_S_all      1.078
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.54651(3) 0.29222(3) 0.13357(2) 0.03757(17) Uani 1 1 d . . . . .
Cl1 Cl 0.45129(16) 0.2953(2) 0.03354(10) 0.0615(6) Uani 1 1 d . . . . .
N1 N 0.4001(5) 0.2985(6) 0.1826(3) 0.052(2) Uani 1 1 d . . . . .
N2 N 0.5303(5) 0.2860(6) 0.2325(3) 0.0522(19) Uani 1 1 d D U . . .
N3 N 0.6962(5) 0.2874(7) 0.1759(3) 0.059(2) Uani 1 1 d D . . . .
N4 N 0.6890(5) 0.2873(6) 0.0824(3) 0.0496(19) Uani 1 1 d . . . . .
N5 N 0.3926(6) 0.2976(8) 0.2842(3) 0.072(3) Uani 1 1 d . U . . .
N6 N 0.8371(5) 0.2621(7) 0.1286(4) 0.059(2) Uani 1 1 d . . . . .
O1 O 0.5393(5) 0.1059(5) 0.1278(3) 0.0610(18) Uani 1 1 d D . . . .
O2 O 0.5498(5) 0.4757(4) 0.1330(3) 0.0608(18) Uani 1 1 d D . . . .
Si1 Si 0.9166(2) 0.3541(3) 0.13918(15) 0.0731(9) Uani 1 1 d . . . . .
Si2 Si 0.3519(3) 0.2047(4) 0.3171(2) 0.1037(14) Uani 1 1 d D . . . .
C1 C 0.4399(6) 0.2921(7) 0.2327(4) 0.049(2) Uani 1 1 d . . . . .
C2 C 0.7413(6) 0.2802(7) 0.1292(4) 0.050(2) Uani 1 1 d . . . . .
C3 C 0.5861(10) 0.285(3) 0.2846(7) 0.043(14) Uani 0.5 1 d D . P A 1
H3A H 0.5577 0.2423 0.3126 0.052 Uiso 0.5 1 calc R U P A 1
H3B H 0.5904 0.3542 0.3000 0.052 Uiso 0.5 1 calc R U P A 1
C4 C 0.6813(13) 0.246(3) 0.2734(9) 0.074(7) Uani 0.5 1 d D . P A 1
H4A H 0.7154 0.2433 0.3097 0.089 Uiso 0.5 1 calc R U P A 1
H4B H 0.6748 0.1760 0.2600 0.089 Uiso 0.5 1 calc R U P A 1
C5 C 0.7401(19) 0.302(2) 0.2320(7) 0.053(8) Uani 0.5 1 d D . P A 1
H5A H 0.7435 0.3739 0.2415 0.063 Uiso 0.5 1 calc R U P A 1
H5B H 0.8020 0.2740 0.2330 0.063 Uiso 0.5 1 calc R U P A 1
C3A C 0.5897(16) 0.282(4) 0.2834(9) 0.07(2) Uani 0.5 1 d D U P A 2
H3A1 H 0.5947 0.2111 0.2958 0.089 Uiso 0.5 1 d R U P A 2
H3A2 H 0.5615 0.3201 0.3135 0.089 Uiso 0.5 1 d R U P A 2
C4A C 0.6849(12) 0.3232(17) 0.2750(8) 0.048(5) Uani 0.5 1 d D . P A 2
H4A1 H 0.7198 0.3230 0.3110 0.057 Uiso 0.5 1 calc R U P A 2
H4A2 H 0.6809 0.3931 0.2613 0.057 Uiso 0.5 1 calc R U P A 2
C5A C 0.7325(17) 0.2577(16) 0.2322(6) 0.040(6) Uani 0.5 1 d D . P A 2
H5A1 H 0.7985 0.2686 0.2350 0.048 Uiso 0.5 1 calc R U P A 2
H5A2 H 0.7203 0.1859 0.2391 0.048 Uiso 0.5 1 calc R U P A 2
C6 C 0.7261(7) 0.2915(9) 0.0265(4) 0.061(3) Uani 1 1 d . . . . .
H6 H 0.7931 0.2841 0.0298 0.073 Uiso 1 1 calc R U . . .
C7 C 0.7028(9) 0.3947(11) 0.0006(5) 0.090(4) Uani 1 1 d . . . . .
H7A H 0.6373 0.4038 -0.0009 0.134 Uiso 1 1 calc R U . . .
H7B H 0.7254 0.3981 -0.0372 0.134 Uiso 1 1 calc R U . . .
H7C H 0.7310 0.4475 0.0236 0.134 Uiso 1 1 calc R U . . .
C8 C 0.6873(9) 0.2083(11) -0.0105(5) 0.089(4) Uani 1 1 d . . . . .
H8A H 0.7018 0.1432 0.0064 0.133 Uiso 1 1 calc R U . . .
H8B H 0.7133 0.2122 -0.0475 0.133 Uiso 1 1 calc R U . . .
H8C H 0.6217 0.2158 -0.0144 0.133 Uiso 1 1 calc R U . . .
C9 C 0.8594(9) 0.1556(14) 0.1133(7) 0.107(5) Uani 1 1 d . . . . .
H9 H 0.8079 0.1342 0.0880 0.128 Uiso 1 1 calc R U . . .
C10 C 0.9415(11) 0.1445(12) 0.0781(8) 0.121(6) Uani 1 1 d . . . . .
H10A H 0.9353 0.1884 0.0454 0.182 Uiso 1 1 calc R U . . .
H10B H 0.9467 0.0749 0.0657 0.182 Uiso 1 1 calc R U . . .
H10C H 0.9957 0.1632 0.1003 0.182 Uiso 1 1 calc R U . . .
C11 C 0.8560(11) 0.0864(12) 0.1615(7) 0.108(5) Uani 1 1 d . . . . .
H11A H 0.9014 0.1063 0.1901 0.163 Uiso 1 1 calc R U . . .
H11B H 0.8683 0.0180 0.1491 0.163 Uiso 1 1 calc R U . . .
H11C H 0.7960 0.0891 0.1772 0.163 Uiso 1 1 calc R U . . .
C12 C 0.8568(9) 0.4691(10) 0.1636(6) 0.094(4) Uani 1 1 d . . . . .
H12A H 0.8130 0.4911 0.1346 0.141 Uiso 1 1 calc R U . . .
H12B H 0.9008 0.5225 0.1712 0.141 Uiso 1 1 calc R U . . .
H12C H 0.8255 0.4536 0.1978 0.141 Uiso 1 1 calc R U . . .
C13 C 1.0054(8) 0.3108(13) 0.1944(7) 0.108(5) Uani 1 1 d . . . . .
H13A H 0.9809 0.3170 0.2316 0.162 Uiso 1 1 calc R U . . .
H13B H 1.0594 0.3526 0.1922 0.162 Uiso 1 1 calc R U . . .
H13C H 1.0212 0.2408 0.1875 0.162 Uiso 1 1 calc R U . . .
C14 C 0.9719(10) 0.3947(12) 0.0736(6) 0.112(5) Uani 1 1 d . . . . .
H14A H 1.0043 0.3380 0.0579 0.169 Uiso 1 1 calc R U . . .
H14B H 1.0144 0.4491 0.0823 0.169 Uiso 1 1 calc R U . . .
H14C H 0.9258 0.4182 0.0463 0.169 Uiso 1 1 calc R U . . .
C15 C 0.3012(7) 0.3030(10) 0.1721(5) 0.073(3) Uani 1 1 d . . . . .
H15 H 0.2706 0.3071 0.2085 0.088 Uiso 1 1 calc R U . . .
C16 C 0.2702(9) 0.2090(12) 0.1412(7) 0.113(6) Uani 1 1 d . . . . .
H16A H 0.2943 0.2090 0.1036 0.170 Uiso 1 1 calc R U . . .
H16B H 0.2042 0.2076 0.1383 0.170 Uiso 1 1 calc R U . . .
H16C H 0.2922 0.1498 0.1616 0.170 Uiso 1 1 calc R U . . .
C17 C 0.2760(8) 0.3955(11) 0.1363(6) 0.097(5) Uani 1 1 d . . . . .
H17A H 0.2989 0.4560 0.1551 0.146 Uiso 1 1 calc R U . . .
H17B H 0.2103 0.3998 0.1314 0.146 Uiso 1 1 calc R U . . .
H17C H 0.3028 0.3894 0.0997 0.146 Uiso 1 1 calc R U . . .
C18 C 0.3545(9) 0.3885(9) 0.3146(5) 0.093(2) Uani 1 1 d D U . . .
H18 H 0.2872 0.3878 0.3106 0.111 Uiso 1 1 calc R U . . .
C19 C 0.3961(9) 0.4882(9) 0.2774(6) 0.093(2) Uani 1 1 d D . . . .
H19A H 0.4619 0.4829 0.2762 0.139 Uiso 1 1 calc R U . . .
H19B H 0.3801 0.5511 0.2956 0.139 Uiso 1 1 calc R U . . .
H19C H 0.3700 0.4871 0.2392 0.139 Uiso 1 1 calc R U . . .
C20 C 0.3843(9) 0.4088(10) 0.3785(5) 0.093(2) Uani 1 1 d D . . . .
H20A H 0.3862 0.3450 0.3988 0.139 Uiso 1 1 d DR U . . .
H20B H 0.3412 0.4539 0.3956 0.139 Uiso 1 1 d R U . . .
H20C H 0.4444 0.4394 0.3801 0.139 Uiso 1 1 d R U . . .
C21 C 0.2242(13) 0.229(3) 0.319(2) 0.121(5) Uani 0.5 1 d D . P B 1
H21A H 0.1957 0.1735 0.3392 0.181 Uiso 0.5 1 calc R U P B 1
H21B H 0.2136 0.2917 0.3389 0.181 Uiso 0.5 1 calc R U P B 1
H21C H 0.1985 0.2327 0.2812 0.181 Uiso 0.5 1 calc R U P B 1
C22 C 0.400(2) 0.2544(16) 0.3882(9) 0.121(5) Uani 0.5 1 d D . P B 1
H22A H 0.3832 0.2077 0.4177 0.181 Uiso 0.5 1 d DR U P B 1
H22B H 0.4655 0.2590 0.3873 0.181 Uiso 0.5 1 d R U P B 1
H22C H 0.3746 0.3206 0.3959 0.181 Uiso 0.5 1 d R U P B 1
C23 C 0.401(4) 0.095(4) 0.278(3) 0.121(5) Uani 0.5 1 d D . P B 1
H23A H 0.3801 0.0325 0.2951 0.181 Uiso 0.5 1 calc R U P B 1
H23B H 0.3803 0.0979 0.2391 0.181 Uiso 0.5 1 calc R U P B 1
H23C H 0.4665 0.0983 0.2813 0.181 Uiso 0.5 1 calc R U P B 1
C21A C 0.2252(13) 0.188(3) 0.321(2) 0.121(5) Uani 0.5 1 d D . P B 2
H21D H 0.2124 0.1272 0.3425 0.181 Uiso 0.5 1 d R U P B 2
H21E H 0.1991 0.2459 0.3391 0.181 Uiso 0.5 1 d R U P B 2
H21F H 0.1987 0.1807 0.2830 0.181 Uiso 0.5 1 d R U P B 2
C22A C 0.398(2) 0.174(3) 0.3885(9) 0.121(5) Uani 0.5 1 d D . P B 2
H22D H 0.3665 0.1158 0.4029 0.181 Uiso 0.5 1 d R U P B 2
H22E H 0.4626 0.1591 0.3867 0.181 Uiso 0.5 1 d R U P B 2
H22F H 0.3897 0.2314 0.4133 0.181 Uiso 0.5 1 d R U P B 2
C23A C 0.381(4) 0.092(4) 0.275(3) 0.121(5) Uani 0.5 1 d D . P B 2
H23D H 0.3575 0.0314 0.2924 0.181 Uiso 0.5 1 d R U P B 2
H23E H 0.3531 0.0981 0.2369 0.181 Uiso 0.5 1 d R U P B 2
H23F H 0.4463 0.0864 0.2721 0.181 Uiso 0.5 1 d R U P B 2
C24 C 0.594(4) 0.048(2) 0.165(2) 0.121(5) Uani 0.5 1 d D . P C 1
H24A H 0.5836 0.0686 0.2043 0.145 Uiso 0.5 1 calc R U P C 1
H24B H 0.6582 0.0577 0.1578 0.145 Uiso 0.5 1 calc R U P C 1
C25 C 0.568(3) -0.062(2) 0.1574(16) 0.121(5) Uani 0.5 1 d D . P C 1
H25A H 0.6226 -0.1039 0.1531 0.145 Uiso 0.5 1 calc R U P C 1
H25B H 0.5348 -0.0871 0.1895 0.145 Uiso 0.5 1 calc R U P C 1
C26 C 0.509(3) -0.0628(19) 0.1043(15) 0.121(5) Uani 0.5 1 d D . P C 1
H26A H 0.4554 -0.1052 0.1096 0.145 Uiso 0.5 1 calc R U P C 1
H26B H 0.5430 -0.0909 0.0731 0.145 Uiso 0.5 1 calc R U P C 1
C27 C 0.480(2) 0.0456(16) 0.0906(13) 0.121(5) Uani 0.5 1 d D . P C 1
H27A H 0.4892 0.0617 0.0509 0.145 Uiso 0.5 1 calc R U P C 1
H27B H 0.4157 0.0564 0.0987 0.145 Uiso 0.5 1 calc R U P C 1
C24A C 0.571(4) 0.0344(19) 0.167(2) 0.121(5) Uani 0.5 1 d D . P C 2
H24C H 0.5451 0.0471 0.2042 0.145 Uiso 0.5 1 calc R U P C 2
H24D H 0.6374 0.0363 0.1714 0.145 Uiso 0.5 1 calc R U P C 2
C25A C 0.539(3) -0.067(2) 0.1439(15) 0.121(5) Uani 0.5 1 d D . P C 2
H25C H 0.5909 -0.1124 0.1395 0.145 Uiso 0.5 1 calc R U P C 2
H25D H 0.4967 -0.0990 0.1696 0.145 Uiso 0.5 1 calc R U P C 2
C26A C 0.492(3) -0.048(2) 0.0879(14) 0.121(5) Uani 0.5 1 d D . P C 2
H26C H 0.5090 -0.0979 0.0597 0.145 Uiso 0.5 1 calc R U P C 2
H26D H 0.4255 -0.0473 0.0907 0.145 Uiso 0.5 1 calc R U P C 2
C27A C 0.528(3) 0.0547(19) 0.0746(9) 0.121(5) Uani 0.5 1 d D . P C 2
H27C H 0.5859 0.0494 0.0560 0.145 Uiso 0.5 1 calc R U P C 2
H27D H 0.4845 0.0913 0.0496 0.145 Uiso 0.5 1 calc R U P C 2
C28 C 0.5301(18) 0.5438(18) 0.0865(9) 0.075(4) Uani 0.5 1 d D . P D 1
H28A H 0.4731 0.5244 0.0666 0.090 Uiso 0.5 1 calc R U P D 1
H28B H 0.5792 0.5420 0.0597 0.090 Uiso 0.5 1 calc R U P D 1
C29 C 0.522(2) 0.648(2) 0.1112(10) 0.075(4) Uani 0.5 1 d D . P D 1
H29A H 0.5615 0.6960 0.0923 0.090 Uiso 0.5 1 calc R U P D 1
H29B H 0.4588 0.6726 0.1073 0.090 Uiso 0.5 1 calc R U P D 1
C30 C 0.5503(19) 0.637(2) 0.1725(9) 0.075(4) Uani 0.5 1 d D . P D 1
H30A H 0.4978 0.6451 0.1964 0.090 Uiso 0.5 1 calc R U P D 1
H30B H 0.5959 0.6886 0.1834 0.090 Uiso 0.5 1 calc R U P D 1
C31 C 0.590(2) 0.5329(19) 0.1787(10) 0.075(4) Uani 0.5 1 d D . P D 1
H31A H 0.6565 0.5349 0.1762 0.090 Uiso 0.5 1 calc R U P D 1
H31B H 0.5751 0.5032 0.2150 0.090 Uiso 0.5 1 calc R U P D 1
C28A C 0.4873(16) 0.5365(18) 0.0982(11) 0.075(4) Uani 0.5 1 d D . P D 2
H28C H 0.4247 0.5117 0.1007 0.090 Uiso 0.5 1 calc R U P D 2
H28D H 0.5042 0.5349 0.0586 0.090 Uiso 0.5 1 calc R U P D 2
C29A C 0.4960(17) 0.641(2) 0.1215(12) 0.075(4) Uani 0.5 1 d D . P D 2
H29C H 0.4455 0.6549 0.1462 0.090 Uiso 0.5 1 calc R U P D 2
H29D H 0.4945 0.6902 0.0908 0.090 Uiso 0.5 1 calc R U P D 2
C30A C 0.5854(16) 0.6467(19) 0.1545(11) 0.075(4) Uani 0.5 1 d D . P D 2
H30C H 0.6316 0.6811 0.1328 0.090 Uiso 0.5 1 calc R U P D 2
H30D H 0.5786 0.6825 0.1903 0.090 Uiso 0.5 1 calc R U P D 2
C31A C 0.610(2) 0.5390(18) 0.1643(11) 0.075(4) Uani 0.5 1 d D . P D 2
H31C H 0.6722 0.5270 0.1531 0.090 Uiso 0.5 1 calc R U P D 2
H31D H 0.6063 0.5233 0.2046 0.090 Uiso 0.5 1 calc R U P D 2
O3 O 0.745(3) 0.755(5) 0.057(2) 0.30(2) Uiso 0.5 1 d D . P E 1
C32 C 0.754(4) 0.859(5) 0.042(4) 0.30(2) Uiso 0.5 1 d D . P E 1
H32A H 0.7305 0.9022 0.0712 0.361 Uiso 0.5 1 calc R U P E 1
H32B H 0.7198 0.8727 0.0063 0.361 Uiso 0.5 1 calc R U P E 1
C33 C 0.856(5) 0.880(4) 0.035(3) 0.30(2) Uiso 0.5 1 d D . P E 1
H33A H 0.8803 0.9235 0.0650 0.361 Uiso 0.5 1 calc R U P E 1
H33B H 0.8660 0.9128 -0.0017 0.361 Uiso 0.5 1 calc R U P E 1
C34 C 0.902(3) 0.775(6) 0.037(3) 0.30(2) Uiso 0.5 1 d D . P E 1
H34A H 0.9390 0.7665 0.0720 0.361 Uiso 0.5 1 calc R U P E 1
H34B H 0.9408 0.7645 0.0047 0.361 Uiso 0.5 1 calc R U P E 1
C35 C 0.821(5) 0.700(4) 0.035(3) 0.30(2) Uiso 0.5 1 d D . P E 1
H35A H 0.8070 0.6779 -0.0038 0.361 Uiso 0.5 1 calc R U P E 1
H35B H 0.8348 0.6403 0.0583 0.361 Uiso 0.5 1 calc R U P E 1
O3A O 0.748(2) 0.828(3) 0.0805(13) 0.179(8) Uiso 0.5 1 d D . P F 2
C32A C 0.769(3) 0.898(3) 0.038(2) 0.179(8) Uiso 0.5 1 d D . P F 2
H32C H 0.7905 0.9615 0.0546 0.214 Uiso 0.5 1 calc R U P F 2
H32D H 0.7150 0.9117 0.0137 0.214 Uiso 0.5 1 calc R U P F 2
C33A C 0.844(3) 0.852(3) 0.0020(17) 0.179(8) Uiso 0.5 1 d D . P F 2
H33C H 0.9036 0.8825 0.0117 0.214 Uiso 0.5 1 calc R U P F 2
H33D H 0.8305 0.8616 -0.0384 0.214 Uiso 0.5 1 calc R U P F 2
C34A C 0.845(3) 0.738(3) 0.017(2) 0.179(8) Uiso 0.5 1 d D . P F 2
H34C H 0.8210 0.6978 -0.0148 0.214 Uiso 0.5 1 calc R U P F 2
H34D H 0.9066 0.7153 0.0274 0.214 Uiso 0.5 1 calc R U P F 2
C35A C 0.783(4) 0.730(3) 0.068(2) 0.179(8) Uiso 0.5 1 d D . P F 2
H35C H 0.7319 0.6836 0.0583 0.214 Uiso 0.5 1 calc R U P F 2
H35D H 0.8170 0.7022 0.1003 0.214 Uiso 0.5 1 calc R U P F 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N2 2.368(7) . ?
Eu1 N3 2.385(7) . ?
Eu1 O2 2.426(6) . ?
Eu1 N4 2.460(7) . ?
Eu1 O1 2.470(7) . ?
Eu1 N1 2.486(7) . ?
Eu1 Cl1 2.709(2) . ?
Eu1 C1 2.873(9) . ?
Eu1 C2 2.873(9) . ?
N1 C1 1.306(12) . ?
N1 C15 1.467(12) . ?
N2 C1 1.331(11) . ?
N2 C3 1.458(14) . ?
N2 C3A 1.463(15) . ?
N3 C2 1.317(11) . ?
N3 C5 1.469(15) . ?
N3 C5A 1.471(14) . ?
N4 C2 1.329(11) . ?
N4 C6 1.454(11) . ?
N5 C1 1.430(12) . ?
N5 C18 1.519(14) . ?
N5 Si2 1.584(10) . ?
N6 C2 1.428(11) . ?
N6 C9 1.493(19) . ?
N6 Si1 1.700(9) . ?
O1 C24A 1.397(18) . ?
O1 C24 1.403(18) . ?
O1 C27A 1.435(17) . ?
O1 C27 1.456(17) . ?
O2 C31A 1.406(17) . ?
O2 C31 1.431(17) . ?
O2 C28 1.445(16) . ?
O2 C28A 1.455(16) . ?
Si1 C12 1.859(13) . ?
Si1 C14 1.860(13) . ?
Si1 C13 1.901(12) . ?
Si2 C22A 1.846(18) . ?
Si2 C23A 1.860(18) . ?
Si2 C23 1.869(18) . ?
Si2 C21A 1.881(18) . ?
Si2 C21 1.905(18) . ?
Si2 C22 1.920(18) . ?
C3 C4 1.526(17) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C4 C5 1.523(17) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C3A C4A 1.523(19) . ?
C3A H3A1 0.9800 . ?
C3A H3A2 0.9800 . ?
C4A C5A 1.525(17) . ?
C4A H4A1 0.9800 . ?
C4A H4A2 0.9800 . ?
C5A H5A1 0.9800 . ?
C5A H5A2 0.9800 . ?
C6 C8 1.506(16) . ?
C6 C7 1.528(16) . ?
C6 H6 0.9900 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 H7C 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 H8C 0.9700 . ?
C9 C11 1.47(2) . ?
C9 C10 1.501(18) . ?
C9 H9 0.9900 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 H10C 0.9700 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 H11C 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 H13C 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 H14C 0.9700 . ?
C15 C16 1.505(19) . ?
C15 C17 1.527(18) . ?
C15 H15 0.9900 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 H16C 0.9700 . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 H17C 0.9700 . ?
C18 C20 1.584(14) . ?
C18 C19 1.712(14) . ?
C18 H18 0.9900 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 H19C 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C20 H22C 1.2463 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C21 H21C 0.9700 . ?
C22 H20A 1.2421 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C22 H22C 0.9700 . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 H23C 0.9700 . ?
C21A H21D 0.9700 . ?
C21A H21E 0.9700 . ?
C21A H21F 0.9700 . ?
C22A H22D 0.9700 . ?
C22A H22E 0.9700 . ?
C22A H22F 0.9700 . ?
C23A H23D 0.9700 . ?
C23A H23E 0.9700 . ?
C23A H23F 0.9700 . ?
C24 C25 1.509(18) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C25 C26 1.504(18) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C26 C27 1.528(19) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C24A C25A 1.520(18) . ?
C24A H24C 0.9800 . ?
C24A H24D 0.9800 . ?
C25A C26A 1.496(18) . ?
C25A H25C 0.9800 . ?
C25A H25D 0.9800 . ?
C26A C27A 1.492(19) . ?
C26A H26C 0.9800 . ?
C26A H26D 0.9800 . ?
C27A H27C 0.9800 . ?
C27A H27D 0.9800 . ?
C28 C29 1.507(17) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C29 C30 1.505(18) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C30 C31 1.505(17) . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C28A C29A 1.487(17) . ?
C28A H28C 0.9800 . ?
C28A H28D 0.9800 . ?
C29A C30A 1.506(19) . ?
C29A H29C 0.9800 . ?
C29A H29D 0.9800 . ?
C30A C31A 1.484(17) . ?
C30A H30C 0.9800 . ?
C30A H30D 0.9800 . ?
C31A H31C 0.9800 . ?
C31A H31D 0.9800 . ?
O3 C32 1.432(19) . ?
O3 C35 1.437(19) . ?
C32 C33 1.538(18) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C33 C34 1.547(18) . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C34 C35 1.549(19) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
O3A C32A 1.419(17) . ?
O3A C35A 1.429(17) . ?
C32A C33A 1.539(17) . ?
C32A H32C 0.9800 . ?
C32A H32D 0.9800 . ?
C33A C34A 1.541(18) . ?
C33A H33C 0.9800 . ?
C33A H33D 0.9800 . ?
C34A C35A 1.538(17) . ?
C34A H34C 0.9800 . ?
C34A H34D 0.9800 . ?
C35A H35C 0.9800 . ?
C35A H35D 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Eu1 N3 73.0(3) . . ?
N2 Eu1 O2 92.5(3) . . ?
N3 Eu1 O2 90.6(3) . . ?
N2 Eu1 N4 127.3(2) . . ?
N3 Eu1 N4 54.4(2) . . ?
O2 Eu1 N4 90.4(3) . . ?
N2 Eu1 O1 90.9(2) . . ?
N3 Eu1 O1 91.9(3) . . ?
O2 Eu1 O1 176.3(2) . . ?
N4 Eu1 O1 88.9(3) . . ?
N2 Eu1 N1 54.3(2) . . ?
N3 Eu1 N1 127.2(2) . . ?
O2 Eu1 N1 89.3(3) . . ?
N4 Eu1 N1 178.3(2) . . ?
O1 Eu1 N1 91.3(3) . . ?
N2 Eu1 Cl1 143.15(18) . . ?
N3 Eu1 Cl1 143.85(19) . . ?
O2 Eu1 Cl1 89.41(15) . . ?
N4 Eu1 Cl1 89.42(17) . . ?
O1 Eu1 Cl1 86.95(16) . . ?
N1 Eu1 Cl1 88.94(17) . . ?
N2 Eu1 C1 27.3(2) . . ?
N3 Eu1 C1 100.2(3) . . ?
O2 Eu1 C1 91.0(2) . . ?
N4 Eu1 C1 154.7(2) . . ?
O1 Eu1 C1 91.2(2) . . ?
N1 Eu1 C1 27.0(2) . . ?
Cl1 Eu1 C1 115.90(19) . . ?
N2 Eu1 C2 99.9(2) . . ?
N3 Eu1 C2 27.0(3) . . ?
O2 Eu1 C2 92.0(3) . . ?
N4 Eu1 C2 27.5(2) . . ?
O1 Eu1 C2 89.0(2) . . ?
N1 Eu1 C2 154.2(2) . . ?
Cl1 Eu1 C2 116.87(19) . . ?
C1 Eu1 C2 127.2(3) . . ?
C1 N1 C15 124.4(8) . . ?
C1 N1 Eu1 93.2(5) . . ?
C15 N1 Eu1 142.3(6) . . ?
C1 N2 C3 121.8(9) . . ?
C1 N2 C3A 124.3(13) . . ?
C1 N2 Eu1 98.0(5) . . ?
C3 N2 Eu1 140.0(8) . . ?
C3A N2 Eu1 137.7(12) . . ?
C2 N3 C5 123.6(13) . . ?
C2 N3 C5A 124.5(12) . . ?
C2 N3 Eu1 97.6(5) . . ?
C5 N3 Eu1 138.2(13) . . ?
C5A N3 Eu1 133.4(11) . . ?
C2 N4 C6 122.6(7) . . ?
C2 N4 Eu1 93.8(5) . . ?
C6 N4 Eu1 143.5(6) . . ?
C1 N5 C18 130.2(9) . . ?
C1 N5 Si2 125.9(8) . . ?
C18 N5 Si2 103.2(7) . . ?
C2 N6 C9 112.7(9) . . ?
C2 N6 Si1 123.5(7) . . ?
C9 N6 Si1 123.7(7) . . ?
C24A O1 C27A 107(2) . . ?
C24 O1 C27 113.5(17) . . ?
C24A O1 Eu1 128.7(14) . . ?
C24 O1 Eu1 119.3(13) . . ?
C27A O1 Eu1 121.5(11) . . ?
C27 O1 Eu1 127.1(11) . . ?
C31 O2 C28 108.3(14) . . ?
C31A O2 C28A 109.9(13) . . ?
C31A O2 Eu1 127.2(12) . . ?
C31 O2 Eu1 122.1(11) . . ?
C28 O2 Eu1 128.6(11) . . ?
C28A O2 Eu1 122.9(11) . . ?
N6 Si1 C12 107.5(5) . . ?
N6 Si1 C14 113.7(6) . . ?
C12 Si1 C14 104.5(7) . . ?
N6 Si1 C13 109.7(6) . . ?
C12 Si1 C13 110.6(7) . . ?
C14 Si1 C13 110.6(7) . . ?
N5 Si2 C22A 119.2(11) . . ?
N5 Si2 C23A 105(3) . . ?
C22A Si2 C23A 104(3) . . ?
N5 Si2 C23 102(3) . . ?
N5 Si2 C21A 120.7(11) . . ?
C22A Si2 C21A 105.1(18) . . ?
C23A Si2 C21A 100(2) . . ?
N5 Si2 C21 106.0(11) . . ?
C23 Si2 C21 123(2) . . ?
N5 Si2 C22 92.0(8) . . ?
C23 Si2 C22 124(2) . . ?
C21 Si2 C22 104(2) . . ?
N1 C1 N2 114.5(8) . . ?
N1 C1 N5 123.8(8) . . ?
N2 C1 N5 121.6(8) . . ?
N1 C1 Eu1 59.8(5) . . ?
N2 C1 Eu1 54.7(4) . . ?
N5 C1 Eu1 175.1(7) . . ?
N3 C2 N4 113.8(8) . . ?
N3 C2 N6 123.2(8) . . ?
N4 C2 N6 123.0(8) . . ?
N3 C2 Eu1 55.3(4) . . ?
N4 C2 Eu1 58.7(4) . . ?
N6 C2 Eu1 173.3(7) . . ?
N2 C3 C4 110.1(16) . . ?
N2 C3 H3A 109.6 . . ?
C4 C3 H3A 109.6 . . ?
N2 C3 H3B 109.6 . . ?
C4 C3 H3B 109.6 . . ?
H3A C3 H3B 108.1 . . ?
C5 C4 C3 119(3) . . ?
C5 C4 H4A 107.5 . . ?
C3 C4 H4A 107.5 . . ?
C5 C4 H4B 107.5 . . ?
C3 C4 H4B 107.5 . . ?
H4A C4 H4B 107.0 . . ?
N3 C5 C4 106.3(14) . . ?
N3 C5 H5A 110.5 . . ?
C4 C5 H5A 110.5 . . ?
N3 C5 H5B 110.5 . . ?
C4 C5 H5B 110.5 . . ?
H5A C5 H5B 108.7 . . ?
N2 C3A C4A 113.6(17) . . ?
N2 C3A H3A1 108.8 . . ?
C4A C3A H3A1 108.9 . . ?
N2 C3A H3A2 109.0 . . ?
C4A C3A H3A2 108.8 . . ?
H3A1 C3A H3A2 107.7 . . ?
C3A C4A C5A 109(3) . . ?
C3A C4A H4A1 109.8 . . ?
C5A C4A H4A1 109.8 . . ?
C3A C4A H4A2 109.8 . . ?
C5A C4A H4A2 109.8 . . ?
H4A1 C4A H4A2 108.3 . . ?
N3 C5A C4A 106.9(15) . . ?
N3 C5A H5A1 110.3 . . ?
C4A C5A H5A1 110.3 . . ?
N3 C5A H5A2 110.3 . . ?
C4A C5A H5A2 110.3 . . ?
H5A1 C5A H5A2 108.6 . . ?
N4 C6 C8 110.9(9) . . ?
N4 C6 C7 108.3(9) . . ?
C8 C6 C7 110.2(10) . . ?
N4 C6 H6 109.2 . . ?
C8 C6 H6 109.2 . . ?
C7 C6 H6 109.2 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C6 C8 H8A 109.5 . . ?
C6 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C6 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C11 C9 N6 112.6(12) . . ?
C11 C9 C10 115.2(14) . . ?
N6 C9 C10 114.6(14) . . ?
C11 C9 H9 104.3 . . ?
N6 C9 H9 104.3 . . ?
C10 C9 H9 104.3 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si1 C12 H12A 109.5 . . ?
Si1 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si1 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si1 C13 H13A 109.5 . . ?
Si1 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si1 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si1 C14 H14A 109.5 . . ?
Si1 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si1 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N1 C15 C16 109.2(10) . . ?
N1 C15 C17 110.2(10) . . ?
C16 C15 C17 109.1(11) . . ?
N1 C15 H15 109.4 . . ?
C16 C15 H15 109.4 . . ?
C17 C15 H15 109.4 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N5 C18 C20 119.6(11) . . ?
N5 C18 C19 102.7(8) . . ?
C20 C18 C19 105.8(9) . . ?
N5 C18 H18 109.4 . . ?
C20 C18 H18 109.4 . . ?
C19 C18 H18 109.4 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.2 . . ?
C18 C20 H20B 110.0 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.2 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C18 C20 H22C 97.3 . . ?
H20A C20 H22C 12.9 . . ?
H20B C20 H22C 110.6 . . ?
H20C C20 H22C 119.5 . . ?
Si2 C21 H21A 109.5 . . ?
Si2 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si2 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si2 C22 H20A 116.8 . . ?
Si2 C22 H22A 108.8 . . ?
H20A C22 H22A 115.1 . . ?
Si2 C22 H22B 109.5 . . ?
H20A C22 H22B 96.3 . . ?
H22A C22 H22B 109.5 . . ?
Si2 C22 H22C 110.1 . . ?
H20A C22 H22C 13.2 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si2 C23 H23A 109.5 . . ?
Si2 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Si2 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si2 C21A H21D 109.6 . . ?
Si2 C21A H21E 109.5 . . ?
H21D C21A H21E 109.5 . . ?
Si2 C21A H21F 109.2 . . ?
H21D C21A H21F 109.5 . . ?
H21E C21A H21F 109.5 . . ?
Si2 C22A H22D 109.4 . . ?
Si2 C22A H22E 109.4 . . ?
H22D C22A H22E 109.5 . . ?
Si2 C22A H22F 109.6 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?
Si2 C23A H23D 109.4 . . ?
Si2 C23A H23E 109.4 . . ?
H23D C23A H23E 109.5 . . ?
Si2 C23A H23F 109.6 . . ?
H23D C23A H23F 109.5 . . ?
H23E C23A H23F 109.5 . . ?
O1 C24 C25 108(2) . . ?
O1 C24 H24A 110.0 . . ?
C25 C24 H24A 110.0 . . ?
O1 C24 H24B 110.0 . . ?
C25 C24 H24B 110.0 . . ?
H24A C24 H24B 108.4 . . ?
C26 C25 C24 104(2) . . ?
C26 C25 H25A 110.9 . . ?
C24 C25 H25A 110.9 . . ?
C26 C25 H25B 110.9 . . ?
C24 C25 H25B 110.9 . . ?
H25A C25 H25B 109.0 . . ?
C25 C26 C27 109(2) . . ?
C25 C26 H26A 109.9 . . ?
C27 C26 H26A 109.9 . . ?
C25 C26 H26B 109.9 . . ?
C27 C26 H26B 109.9 . . ?
H26A C26 H26B 108.3 . . ?
O1 C27 C26 103.1(19) . . ?
O1 C27 H27A 111.1 . . ?
C26 C27 H27A 111.1 . . ?
O1 C27 H27B 111.1 . . ?
C26 C27 H27B 111.1 . . ?
H27A C27 H27B 109.1 . . ?
O1 C24A C25A 105(2) . . ?
O1 C24A H24C 110.7 . . ?
C25A C24A H24C 110.7 . . ?
O1 C24A H24D 110.7 . . ?
C25A C24A H24D 110.7 . . ?
H24C C24A H24D 108.8 . . ?
C26A C25A C24A 107(2) . . ?
C26A C25A H25C 110.2 . . ?
C24A C25A H25C 110.2 . . ?
C26A C25A H25D 110.2 . . ?
C24A C25A H25D 110.2 . . ?
H25C C25A H25D 108.5 . . ?
C27A C26A C25A 101(2) . . ?
C27A C26A H26C 111.6 . . ?
C25A C26A H26C 111.6 . . ?
C27A C26A H26D 111.6 . . ?
C25A C26A H26D 111.6 . . ?
H26C C26A H26D 109.4 . . ?
O1 C27A C26A 106(2) . . ?
O1 C27A H27C 110.5 . . ?
C26A C27A H27C 110.5 . . ?
O1 C27A H27D 110.5 . . ?
C26A C27A H27D 110.5 . . ?
H27C C27A H27D 108.7 . . ?
O2 C28 C29 107.0(18) . . ?
O2 C28 H28A 110.3 . . ?
C29 C28 H28A 110.3 . . ?
O2 C28 H28B 110.3 . . ?
C29 C28 H28B 110.3 . . ?
H28A C28 H28B 108.6 . . ?
C30 C29 C28 105(2) . . ?
C30 C29 H29A 110.7 . . ?
C28 C29 H29A 110.7 . . ?
C30 C29 H29B 110.7 . . ?
C28 C29 H29B 110.7 . . ?
H29A C29 H29B 108.8 . . ?
C29 C30 C31 106(2) . . ?
C29 C30 H30A 110.5 . . ?
C31 C30 H30A 110.5 . . ?
C29 C30 H30B 110.5 . . ?
C31 C30 H30B 110.5 . . ?
H30A C30 H30B 108.7 . . ?
O2 C31 C30 105.3(19) . . ?
O2 C31 H31A 110.7 . . ?
C30 C31 H31A 110.7 . . ?
O2 C31 H31B 110.7 . . ?
C30 C31 H31B 110.7 . . ?
H31A C31 H31B 108.8 . . ?
O2 C28A C29A 104.9(18) . . ?
O2 C28A H28C 110.8 . . ?
C29A C28A H28C 110.8 . . ?
O2 C28A H28D 110.8 . . ?
C29A C28A H28D 110.8 . . ?
H28C C28A H28D 108.8 . . ?
C28A C29A C30A 108(2) . . ?
C28A C29A H29C 110.2 . . ?
C30A C29A H29C 110.2 . . ?
C28A C29A H29D 110.2 . . ?
C30A C29A H29D 110.2 . . ?
H29C C29A H29D 108.5 . . ?
C31A C30A C29A 103(2) . . ?
C31A C30A H30C 111.1 . . ?
C29A C30A H30C 111.1 . . ?
C31A C30A H30D 111.1 . . ?
C29A C30A H30D 111.1 . . ?
H30C C30A H30D 109.1 . . ?
O2 C31A C30A 110(2) . . ?
O2 C31A H31C 109.6 . . ?
C30A C31A H31C 109.6 . . ?
O2 C31A H31D 109.6 . . ?
C30A C31A H31D 109.6 . . ?
H31C C31A H31D 108.1 . . ?
C32 O3 C35 108.2(18) . . ?
O3 C32 C33 107.6(15) . . ?
O3 C32 H32A 110.2 . . ?
C33 C32 H32A 110.2 . . ?
O3 C32 H32B 110.2 . . ?
C33 C32 H32B 110.2 . . ?
H32A C32 H32B 108.5 . . ?
C32 C33 C34 105.0(10) . . ?
C32 C33 H33A 110.8 . . ?
C34 C33 H33A 110.7 . . ?
C32 C33 H33B 110.8 . . ?
C34 C33 H33B 110.7 . . ?
H33A C33 H33B 108.8 . . ?
C33 C34 C35 103.7(14) . . ?
C33 C34 H34A 111.0 . . ?
C35 C34 H34A 111.0 . . ?
C33 C34 H34B 111.0 . . ?
C35 C34 H34B 111.0 . . ?
H34A C34 H34B 109.0 . . ?
O3 C35 C34 106.0(17) . . ?
O3 C35 H35A 110.5 . . ?
C34 C35 H35A 110.6 . . ?
O3 C35 H35B 110.5 . . ?
C34 C35 H35B 110.6 . . ?
H35A C35 H35B 108.7 . . ?
C32A O3A C35A 110.5(12) . . ?
O3A C32A C33A 108.4(12) . . ?
O3A C32A H32C 110.0 . . ?
C33A C32A H32C 110.0 . . ?
O3A C32A H32D 110.0 . . ?
C33A C32A H32D 110.0 . . ?
H32C C32A H32D 108.4 . . ?
C32A C33A C34A 104.8(11) . . ?
C32A C33A H33C 110.8 . . ?
C34A C33A H33C 110.8 . . ?
C32A C33A H33D 110.8 . . ?
C34A C33A H33D 110.8 . . ?
H33C C33A H33D 108.9 . . ?
C35A C34A C33A 104.8(10) . . ?
C35A C34A H34C 110.8 . . ?
C33A C34A H34C 110.8 . . ?
C35A C34A H34D 110.8 . . ?
C33A C34A H34D 110.8 . . ?
H34C C34A H34D 108.9 . . ?
O3A C35A C34A 108.9(11) . . ?
O3A C35A H35C 109.9 . . ?
C34A C35A H35C 109.9 . . ?
O3A C35A H35D 109.9 . . ?
C34A C35A H35D 109.9 . . ?
H35C C35A H35D 108.3 . . ?

_refine_diff_density_max         3.813
_refine_diff_density_min         -2.131
_refine_diff_density_rms         0.143

# start Validation Reply Form
_vrf_PLAT412_g160701a            
;
PROBLEM: Short Intra XH3 .. XHn     H20A   ..  H22F    ..       1.54 Ang.
RESPONSE: Because of disordered solvent molecule. 
;
_vrf_PLAT971_g160701a            
;
PROBLEM: Check Calcd Residual Density  0.17A From     C18       3.81 eA-3
RESPONSE: Because of disordered solvent molecule.
;
_vrf_PLAT971_I_g160701a          
;
PROBLEM: Check Calcd Residual Density  1.26A From     N6       2.74 eA-3
RESPONSE: Because of disordered solvent molecule.
;
# end Validation Reply Form


