# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1498976'
_audit_update_record             
;
2016-08-12 deposited with the CCDC.
2016-10-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C10 H14 Ag2 O6 P2'
_chemical_formula_weight         507.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   6.747(2)
_cell_length_b                   6.1736(16)
_cell_length_c                   15.970(5)
_cell_angle_alpha                90
_cell_angle_beta                 94.412(13)
_cell_angle_gamma                90
_cell_volume                     663.2(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    300(2)
_cell_measurement_reflns_used    3501
_cell_measurement_theta_min      3.028
_cell_measurement_theta_max      24.998

_exptl_crystal_description       plate
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.543
_exptl_crystal_F_000             492
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.06
_exptl_absorpt_coefficient_mu    3.214
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.467
_exptl_absorpt_correction_T_max  0.825
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      300(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            3501
_diffrn_reflns_av_unetI/netI     0.0308
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         3.028
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.958
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.958
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_point_group_measured_fraction_full 0.958
_reflns_number_total             1144
_reflns_number_gt                920
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_vrf_PLAT232_2                   
;
PROBLEM: Hirshfeld Test Diff (M-X)  Ag1-C4_a ..11.0 s.u.
RESPONSE: Moderate data quality and heavy atom effect.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0303P)²+3.1481P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1144
_refine_ls_number_parameters     92
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0477
_refine_ls_R_factor_gt           0.0329
_refine_ls_wR_factor_ref         0.0794
_refine_ls_wR_factor_gt          0.0737
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_restrained_S_all      1.060
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.09388(8) -0.39670(7) 0.18825(3) 0.0373(2) Uani 1 1 d . . . . .
O1 O 1.1663(5) 0.2619(6) 0.2424(2) 0.0238(9) Uani 1 1 d . . . . .
O2 O 1.4746(5) 0.2251(6) 0.1627(2) 0.0260(9) Uani 1 1 d . . . . .
H2A H 1.5332 0.2720 0.2058 0.039 Uiso 1 1 calc R U . . .
O3 O 1.3060(6) -0.1115(6) 0.2157(2) 0.0267(9) Uani 1 1 d . . . . .
P1 P 1.27351(19) 0.1182(2) 0.18427(8) 0.0167(3) Uani 1 1 d . . . . .
C1 C 1.3610(8) 0.2901(10) -0.0524(4) 0.0280(13) Uani 1 1 d . . . . .
H1A H 1.3261 0.1572 -0.0811 0.042 Uiso 1 1 calc R U . . .
H1B H 1.4509 0.2599 -0.0043 0.042 Uiso 1 1 calc R U . . .
H1C H 1.4238 0.3857 -0.0896 0.042 Uiso 1 1 calc R U . . .
C2 C 1.1764(7) 0.3956(8) -0.0244(3) 0.0189(11) Uani 1 1 d . . . . .
C3 C 1.0698(7) 0.3077(8) 0.0405(3) 0.0160(11) Uani 1 1 d . . . . .
C4 C 0.8983(8) 0.4141(8) 0.0634(3) 0.0188(11) Uani 1 1 d . . . . .
H4A H 0.8306 0.3557 0.1067 0.023 Uiso 1 1 calc R U . . .
C5 C 1.1322(8) 0.0967(8) 0.0834(3) 0.0209(12) Uani 1 1 d . . . . .
H5A H 1.2108 0.0153 0.0459 0.025 Uiso 1 1 calc R U . . .
H5B H 1.0133 0.0128 0.0910 0.025 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O3 2.290(4) . ?
Ag1 O1 2.316(4) 1_545 ?
Ag1 O1 2.360(4) 2_745 ?
Ag1 C4 2.584(5) 1_545 ?
O1 P1 1.508(4) . ?
O1 Ag1 2.316(4) 1_565 ?
O1 Ag1 2.360(4) 2_755 ?
O2 P1 1.571(4) . ?
O3 P1 1.515(4) . ?
P1 C5 1.812(5) . ?
C1 C2 1.504(7) . ?
C2 C4 1.405(7) 3_765 ?
C2 C3 1.414(7) . ?
C3 C4 1.404(7) . ?
C3 C5 1.517(7) . ?
C4 C2 1.405(7) 3_765 ?
C4 Ag1 2.584(5) 1_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ag1 O1 121.16(13) . 1_545 ?
O3 Ag1 O1 93.87(14) . 2_745 ?
O1 Ag1 O1 110.23(9) 1_545 2_745 ?
O3 Ag1 C4 140.35(15) . 1_545 ?
O1 Ag1 C4 87.55(15) 1_545 1_545 ?
O1 Ag1 C4 101.28(15) 2_745 1_545 ?
P1 O1 Ag1 113.8(2) . 1_565 ?
P1 O1 Ag1 117.0(2) . 2_755 ?
Ag1 O1 Ag1 114.19(15) 1_565 2_755 ?
P1 O3 Ag1 125.7(2) . . ?
O1 P1 O3 114.3(2) . . ?
O1 P1 O2 110.5(2) . . ?
O3 P1 O2 111.1(2) . . ?
O1 P1 C5 110.2(2) . . ?
O3 P1 C5 106.2(2) . . ?
O2 P1 C5 103.9(2) . . ?
C4 C2 C3 117.4(5) 3_765 . ?
C4 C2 C1 120.5(5) 3_765 . ?
C3 C2 C1 122.1(5) . . ?
C4 C3 C2 119.2(5) . . ?
C4 C3 C5 119.3(5) . . ?
C2 C3 C5 121.4(5) . . ?
C3 C4 C2 123.4(5) . 3_765 ?
C3 C4 Ag1 91.8(3) . 1_565 ?
C2 C4 Ag1 96.2(3) 3_765 1_565 ?
C3 C5 P1 116.6(3) . . ?

_refine_diff_density_max         1.363
_refine_diff_density_min         -1.092
_refine_diff_density_rms         0.121

_shelxl_version_number           2013-2

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1498977'
_audit_update_record             
;
2016-08-12 deposited with the CCDC.
2016-10-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C9 H12 Ag3 O9 P3'
_chemical_formula_weight         680.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.3751(9)
_cell_length_b                   9.2734(9)
_cell_length_c                   10.7848(13)
_cell_angle_alpha                86.327(4)
_cell_angle_beta                 89.491(4)
_cell_angle_gamma                63.771(3)
_cell_volume                     749.64(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8206
_cell_measurement_theta_min      3.199
_cell_measurement_theta_max      26.481

_exptl_crystal_description       plate
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.016
_exptl_crystal_F_000             648
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.05
_exptl_absorpt_coefficient_mu    4.246
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.360
_exptl_absorpt_correction_T_max  0.809
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8206
_diffrn_reflns_av_unetI/netI     0.0703
_diffrn_reflns_av_R_equivalents  0.0588
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         3.199
_diffrn_reflns_theta_max         26.481
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.950
_diffrn_measured_fraction_theta_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.950
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.950
_diffrn_reflns_point_group_measured_fraction_full 0.986
_reflns_number_total             2951
_reflns_number_gt                2013
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0229P)²+0.2057P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         2951
_refine_ls_number_parameters     217
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0799
_refine_ls_R_factor_gt           0.0386
_refine_ls_wR_factor_ref         0.0670
_refine_ls_wR_factor_gt          0.0580
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_restrained_S_all      1.006
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.57543(7) 0.60062(6) 0.05814(5) 0.03632(16) Uani 1 1 d . . . . .
Ag2 Ag 0.82462(7) 0.82030(6) 1.02540(5) 0.03481(16) Uani 1 1 d . . . . .
Ag3 Ag 0.83616(6) 0.14620(6) 0.88165(6) 0.03595(16) Uani 1 1 d . . . . .
O1 O 0.8175(5) 0.4022(4) 0.1910(4) 0.0207(10) Uani 1 1 d . . . . .
O2 O 0.6606(5) 0.2357(4) 0.1716(4) 0.0223(10) Uani 1 1 d . . . . .
H2B H 0.6684 0.1442 0.1784 0.033 Uiso 1 1 calc R U . . .
O3 O 0.9808(5) 0.1230(4) 0.1033(4) 0.0193(9) Uani 1 1 d . . . . .
O4 O 1.0153(5) 0.4276(4) 0.8280(4) 0.0311(12) Uani 1 1 d . . . . .
H4B H 1.0582 0.4918 0.8213 0.047 Uiso 1 1 calc R U . . .
O5 O 0.7492(5) 0.6853(4) 0.8742(4) 0.0248(10) Uani 1 1 d . . . . .
O6 O 0.7332(5) 0.4182(4) 0.8920(4) 0.0200(9) Uani 1 1 d . . . . .
O7 O 0.6314(5) -0.0691(4) 0.7151(4) 0.0271(10) Uani 1 1 d . . . . .
H7C H 0.6648 -0.1439 0.7686 0.041 Uiso 1 1 calc R U . . .
O8 O 0.5480(5) 0.1485(4) 0.8679(4) 0.0239(10) Uani 1 1 d . . . . .
O9 O 0.3241(5) 0.0487(4) 0.8084(4) 0.0215(10) Uani 1 1 d . . . . .
P1 P 0.84896(19) 0.22874(17) 0.19495(15) 0.0151(3) Uani 1 1 d . . . . .
P2 P 0.80664(19) 0.52192(17) 0.82331(15) 0.0171(4) Uani 1 1 d . . . . .
P3 P 0.47840(19) 0.08393(17) 0.76716(15) 0.0162(3) Uani 1 1 d . . . . .
C1 C 0.8120(7) 0.2159(6) 0.4524(5) 0.0165(13) Uani 1 1 d . . . . .
C2 C 0.8370(7) 0.3343(6) 0.5111(5) 0.0186(14) Uani 1 1 d . . . . .
H2A H 0.9313 0.3569 0.4882 0.022 Uiso 1 1 calc R U . . .
C3 C 0.7248(7) 0.4179(6) 0.6021(5) 0.0183(14) Uani 1 1 d . . . . .
C4 C 0.5844(7) 0.3814(6) 0.6380(5) 0.0180(13) Uani 1 1 d . . . . .
H4A H 0.5067 0.4394 0.6983 0.022 Uiso 1 1 calc R U . . .
C5 C 0.5600(7) 0.2610(6) 0.5850(5) 0.0145(13) Uani 1 1 d . . . . .
C6 C 0.6744(7) 0.1792(6) 0.4919(6) 0.0188(14) Uani 1 1 d . . . . .
H6A H 0.6587 0.0981 0.4552 0.023 Uiso 1 1 calc R U . . .
C7 C 0.9268(7) 0.1315(7) 0.3469(5) 0.0211(14) Uani 1 1 d . . . . .
H7A H 0.9360 0.0234 0.3482 0.025 Uiso 1 1 calc R U . . .
H7B H 1.0455 0.1216 0.3610 0.025 Uiso 1 1 calc R U . . .
C8 C 0.7407(8) 0.5562(6) 0.6608(5) 0.0212(14) Uani 1 1 d . . . . .
H8A H 0.6265 0.6506 0.6514 0.025 Uiso 1 1 calc R U . . .
H8B H 0.8265 0.5807 0.6145 0.025 Uiso 1 1 calc R U . . .
C9 C 0.4115(7) 0.2208(7) 0.6308(6) 0.0203(14) Uani 1 1 d . . . . .
H9A H 0.3764 0.1728 0.5654 0.024 Uiso 1 1 calc R U . . .
H9B H 0.3089 0.3193 0.6496 0.024 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O8 2.283(4) 2_666 ?
Ag1 O1 2.442(4) . ?
Ag1 O6 2.488(4) 1_554 ?
Ag1 O6 2.714(4) 2_666 ?
Ag1 O5 2.725(4) 1_554 ?
Ag1 Ag1 3.0106(10) 2_665 ?
Ag1 Ag3 3.2891(8) 2_666 ?
Ag2 O9 2.267(4) 2_667 ?
Ag2 O3 2.341(4) 2_766 ?
Ag2 O5 2.367(4) . ?
Ag2 O4 2.535(4) 2_767 ?
Ag2 Ag3 3.1691(8) 2_767 ?
Ag2 Ag3 3.3469(8) 1_565 ?
Ag3 O3 2.275(3) 2_756 ?
Ag3 O6 2.287(4) . ?
Ag3 O8 2.410(4) . ?
Ag3 O3 2.642(4) 1_556 ?
Ag3 Ag2 3.1691(8) 2_767 ?
Ag3 Ag1 3.2892(8) 2_666 ?
Ag3 Ag2 3.3469(8) 1_545 ?
O1 P1 1.509(4) . ?
O2 P1 1.572(4) . ?
O3 P1 1.519(4) . ?
O3 Ag3 2.275(3) 2_756 ?
O3 Ag2 2.341(4) 2_766 ?
O3 Ag2 21.965(5) 1_556 ?
O4 P2 1.571(4) . ?
O4 Ag2 2.535(4) 2_767 ?
O5 P2 1.512(4) . ?
O6 P2 1.508(4) . ?
O6 Ag1 2.488(4) 1_556 ?
O7 P3 1.566(4) . ?
O8 P3 1.511(4) . ?
O8 Ag1 2.283(4) 2_666 ?
O9 P3 1.522(4) . ?
O9 Ag2 2.267(4) 2_667 ?
P1 C7 1.798(6) . ?
P2 C8 1.808(6) . ?
P3 C9 1.799(6) . ?
C1 C2 1.395(7) . ?
C1 C6 1.395(8) . ?
C1 C7 1.504(8) . ?
C2 C3 1.373(8) . ?
C3 C4 1.406(8) . ?
C3 C8 1.522(7) . ?
C4 C5 1.379(7) . ?
C5 C6 1.393(8) . ?
C5 C9 1.518(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Ag1 O1 113.09(13) 2_666 . ?
O8 Ag1 O6 150.14(13) 2_666 1_554 ?
O1 Ag1 O6 83.63(12) . 1_554 ?
O8 Ag1 O6 88.48(12) 2_666 2_666 ?
O1 Ag1 O6 110.36(12) . 2_666 ?
O6 Ag1 O6 109.42(10) 1_554 2_666 ?
O8 Ag1 O5 93.21(13) 2_666 1_554 ?
O1 Ag1 O5 103.27(12) . 1_554 ?
O6 Ag1 O5 57.96(11) 1_554 1_554 ?
O6 Ag1 O5 142.57(11) 2_666 1_554 ?
O8 Ag1 Ag1 133.84(10) 2_666 2_665 ?
O1 Ag1 Ag1 102.82(9) . 2_665 ?
O6 Ag1 Ag1 58.22(8) 1_554 2_665 ?
O6 Ag1 Ag1 51.20(8) 2_666 2_665 ?
O5 Ag1 Ag1 106.11(8) 1_554 2_665 ?
O8 Ag1 Ag3 47.10(9) 2_666 2_666 ?
O1 Ag1 Ag3 131.89(10) . 2_666 ?
O6 Ag1 Ag3 137.36(8) 1_554 2_666 ?
O6 Ag1 Ag3 43.48(8) 2_666 2_666 ?
O5 Ag1 Ag3 118.98(8) 1_554 2_666 ?
Ag1 Ag1 Ag3 87.36(2) 2_665 2_666 ?
O9 Ag2 O3 128.43(12) 2_667 2_766 ?
O9 Ag2 O5 131.66(14) 2_667 . ?
O3 Ag2 O5 94.48(14) 2_766 . ?
O9 Ag2 O4 87.81(14) 2_667 2_767 ?
O3 Ag2 O4 112.78(13) 2_766 2_767 ?
O5 Ag2 O4 95.37(13) . 2_767 ?
O9 Ag2 Ag3 88.92(9) 2_667 2_767 ?
O3 Ag2 Ag3 54.86(9) 2_766 2_767 ?
O5 Ag2 Ag3 138.71(10) . 2_767 ?
O4 Ag2 Ag3 76.23(9) 2_767 2_767 ?
O9 Ag2 Ag3 94.50(9) 2_667 1_565 ?
O3 Ag2 Ag3 42.76(8) 2_766 1_565 ?
O5 Ag2 Ag3 107.62(10) . 1_565 ?
O4 Ag2 Ag3 146.29(9) 2_767 1_565 ?
Ag3 Ag2 Ag3 70.205(18) 2_767 1_565 ?
O3 Ag3 O6 161.37(12) 2_756 . ?
O3 Ag3 O8 101.38(13) 2_756 . ?
O6 Ag3 O8 96.31(12) . . ?
O3 Ag3 O3 80.90(13) 2_756 1_556 ?
O6 Ag3 O3 85.45(12) . 1_556 ?
O8 Ag3 O3 119.02(13) . 1_556 ?
O3 Ag3 Ag2 84.60(9) 2_756 2_767 ?
O6 Ag3 Ag2 76.81(9) . 2_767 ?
O8 Ag3 Ag2 163.69(10) . 2_767 ?
O3 Ag3 Ag2 46.43(8) 1_556 2_767 ?
O3 Ag3 Ag1 139.86(10) 2_756 2_666 ?
O6 Ag3 Ag1 54.74(9) . 2_666 ?
O8 Ag3 Ag1 43.96(9) . 2_666 ?
O3 Ag3 Ag1 98.34(8) 1_556 2_666 ?
Ag2 Ag3 Ag1 123.74(2) 2_767 2_666 ?
O3 Ag3 Ag2 44.32(10) 2_756 1_545 ?
O6 Ag3 Ag2 142.91(10) . 1_545 ?
O8 Ag3 Ag2 66.94(9) . 1_545 ?
O3 Ag3 Ag2 75.85(8) 1_556 1_545 ?
Ag2 Ag3 Ag2 109.795(19) 2_767 1_545 ?
Ag1 Ag3 Ag2 96.22(2) 2_666 1_545 ?
P1 O1 Ag1 118.4(2) . . ?
P1 O3 Ag3 130.3(2) . 2_756 ?
P1 O3 Ag2 128.9(2) . 2_766 ?
Ag3 O3 Ag2 92.92(13) 2_756 2_766 ?
P1 O3 Ag2 38.64(14) . 1_556 ?
Ag3 O3 Ag2 103.80(10) 2_756 1_556 ?
Ag2 O3 Ag2 116.20(9) 2_766 1_556 ?
P2 O4 Ag2 121.3(2) . 2_767 ?
P2 O5 Ag2 142.6(2) . . ?
P2 O6 Ag3 126.0(2) . . ?
P2 O6 Ag1 98.68(18) . 1_556 ?
Ag3 O6 Ag1 131.57(17) . 1_556 ?
P3 O8 Ag1 129.0(2) . 2_666 ?
P3 O8 Ag3 127.5(2) . . ?
Ag1 O8 Ag3 88.94(12) 2_666 . ?
P3 O9 Ag2 115.2(2) . 2_667 ?
O1 P1 O3 116.6(2) . . ?
O1 P1 O2 105.2(2) . . ?
O3 P1 O2 110.0(2) . . ?
O1 P1 C7 110.7(3) . . ?
O3 P1 C7 106.5(2) . . ?
O2 P1 C7 107.6(3) . . ?
O6 P2 O5 114.1(2) . . ?
O6 P2 O4 108.1(2) . . ?
O5 P2 O4 109.7(2) . . ?
O6 P2 C8 111.2(2) . . ?
O5 P2 C8 107.2(2) . . ?
O4 P2 C8 106.4(3) . . ?
O8 P3 O9 113.2(2) . . ?
O8 P3 O7 111.1(2) . . ?
O9 P3 O7 110.5(2) . . ?
O8 P3 C9 110.9(2) . . ?
O9 P3 C9 109.3(2) . . ?
O7 P3 C9 101.2(3) . . ?
C2 C1 C6 118.4(5) . . ?
C2 C1 C7 121.4(5) . . ?
C6 C1 C7 120.1(5) . . ?
C3 C2 C1 121.1(5) . . ?
C2 C3 C4 119.3(5) . . ?
C2 C3 C8 122.2(5) . . ?
C4 C3 C8 118.5(5) . . ?
C5 C4 C3 121.0(5) . . ?
C4 C5 C6 118.5(5) . . ?
C4 C5 C9 119.2(5) . . ?
C6 C5 C9 122.3(5) . . ?
C5 C6 C1 121.6(5) . . ?
C1 C7 P1 115.1(4) . . ?
C3 C8 P2 116.0(4) . . ?
C5 C9 P3 111.9(4) . . ?

_refine_diff_density_max         0.887
_refine_diff_density_min         -0.906
_refine_diff_density_rms         0.172

_shelxl_version_number           2013-2

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_4
_database_code_depnum_ccdc_archive 'CCDC 1498978'
_audit_update_record             
;
2016-08-12 deposited with the CCDC.
2016-10-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C35 H40 Ag2 N4 O10 P3'
_chemical_formula_weight         985.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.4999(7)
_cell_length_b                   12.1860(8)
_cell_length_c                   15.1329(9)
_cell_angle_alpha                97.139(2)
_cell_angle_beta                 103.613(2)
_cell_angle_gamma                99.718(2)
_cell_volume                     1827.5(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    289(2)
_cell_measurement_reflns_used    14209
_cell_measurement_theta_min      3.035
_cell_measurement_theta_max      25.00

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.791
_exptl_crystal_F_000             994
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.06
_exptl_absorpt_coefficient_mu    1.267
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.913
_exptl_absorpt_correction_T_max  0.927
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      289(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14209
_diffrn_reflns_av_unetI/netI     0.0401
_diffrn_reflns_av_R_equivalents  0.0289
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         3.035
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measured_fraction_theta_full 0.955
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_Laue_measured_fraction_full 0.955
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_point_group_measured_fraction_full 0.955
_reflns_number_total             6327
_reflns_number_gt                4471
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_vrf_PLAT232_4                   
;
PROBLEM: Hirshfeld Test Diff (M-X)  Ag1--O2 ..12.0 s.u. 
RESPONSE: Moderate data quality and heavy atom effect.
;
_vrf_PLAT417_4                   
;
PROBLEM: Short Inter D-H..H-D  H1W..  H1W.. 2.03 Ang. 
RESPONSE: Moderate data quality.
;
_vrf_PLAT910_4                   
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min)14 Note. 
RESPONSE: Theta min = 3.035 deg. The theta value of the missing reflections 
 are less than 3.035 deg. and therefore reflections 
 were excluded. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0401P)²+5.3700P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6327
_refine_ls_number_parameters     490
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0747
_refine_ls_R_factor_gt           0.0458
_refine_ls_wR_factor_ref         0.1157
_refine_ls_wR_factor_gt          0.0999
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.66646(6) 0.06826(4) 0.11353(4) 0.06541(19) Uani 1 1 d . . . . .
Ag2 Ag 0.77062(5) 0.27916(4) 0.27710(3) 0.05431(16) Uani 1 1 d . . . . .
N1 N 0.7585(4) -0.0340(4) 0.2096(3) 0.0378(10) Uani 1 1 d . . . . .
N2 N 1.1129(4) -0.2093(3) 0.6101(3) 0.0343(10) Uani 1 1 d . . . . .
N3 N 0.5609(4) 0.1606(4) 0.0143(3) 0.0380(10) Uani 1 1 d . . . . .
N4 N 0.3177(4) 0.5975(4) -0.2008(3) 0.0389(10) Uani 1 1 d . . . . .
O1 O 1.0969(4) 0.1623(3) 0.1863(3) 0.0564(11) Uani 1 1 d . . . . .
H1B H 1.1764 0.1828 0.1890 0.085 Uiso 1 1 calc R U . . .
O2 O 0.8796(4) 0.1982(4) 0.0975(3) 0.0665(13) Uani 1 1 d . . . . .
O3 O 1.0217(4) 0.3431(3) 0.2283(3) 0.0541(11) Uani 1 1 d . . . . .
H3A H 1.0977 0.3816 0.2484 0.081 Uiso 1 1 calc R U . . .
O4 O 0.4656(4) 0.5721(3) 0.3967(3) 0.0475(10) Uani 1 1 d . . . . .
H4A H 0.5190 0.5800 0.4473 0.071 Uiso 1 1 calc R U . . .
O5 O 0.3541(4) 0.3973(3) 0.4437(3) 0.0458(9) Uani 1 1 d . . . . .
O6 O 0.2450(4) 0.4695(4) 0.2993(3) 0.0572(11) Uani 1 1 d . . . . .
O7 O 0.3366(4) 0.1939(4) 0.2061(3) 0.0569(12) Uani 1 1 d . . . . .
O8 O 0.5469(4) 0.1213(4) 0.2658(3) 0.0678(14) Uani 1 1 d . . . . .
O9 O 0.4950(5) 0.2754(4) 0.3592(3) 0.0671(13) Uani 1 1 d . . . . .
H9B H 0.4344 0.2990 0.3761 0.101 Uiso 1 1 calc R U . . .
P1 P 1.01951(13) 0.25028(12) 0.14876(10) 0.0360(3) Uani 1 1 d . . . . .
P2 P 0.32881(15) 0.49682(12) 0.39731(9) 0.0381(3) Uani 1 1 d . . . . .
P3 P 0.43221(14) 0.16021(14) 0.28270(11) 0.0438(4) Uani 1 1 d . . . . .
C1 C 0.6967(6) -0.0746(5) 0.2693(4) 0.0478(14) Uani 1 1 d . . . . .
H1A H 0.6056 -0.0758 0.2593 0.057 Uiso 1 1 calc R U . . .
C2 C 0.7597(6) -0.1148(5) 0.3448(4) 0.0463(14) Uani 1 1 d . . . . .
H2A H 0.7111 -0.1425 0.3843 0.056 Uiso 1 1 calc R U . . .
C3 C 0.8945(5) -0.1142(4) 0.3626(3) 0.0305(11) Uani 1 1 d . . . . .
C4 C 0.9696(5) -0.1471(4) 0.4489(3) 0.0286(11) Uani 1 1 d . . . . .
C5 C 0.9056(5) -0.2055(4) 0.5046(3) 0.0370(12) Uani 1 1 d . . . . .
H5A H 0.8127 -0.2255 0.4887 0.044 Uiso 1 1 calc R U . . .
C6 C 0.9787(6) -0.2340(4) 0.5832(4) 0.0396(13) Uani 1 1 d . . . . .
H6A H 0.9328 -0.2724 0.6196 0.048 Uiso 1 1 calc R U . . .
C7 C 1.1757(5) -0.1529(4) 0.5572(4) 0.0382(12) Uani 1 1 d . . . . .
H7A H 1.2688 -0.1340 0.5748 0.046 Uiso 1 1 calc R U . . .
C8 C 1.1090(5) -0.1215(4) 0.4778(4) 0.0389(13) Uani 1 1 d . . . . .
H8A H 1.1574 -0.0828 0.4430 0.047 Uiso 1 1 calc R U . . .
C9 C 0.9572(6) -0.0771(5) 0.2985(4) 0.0481(15) Uani 1 1 d . . . . .
H9A H 1.0473 -0.0782 0.3052 0.058 Uiso 1 1 calc R U . . .
C10 C 0.8860(6) -0.0381(5) 0.2238(4) 0.0514(16) Uani 1 1 d . . . . .
H10A H 0.9307 -0.0134 0.1814 0.062 Uiso 1 1 calc R U . . .
C11 C 0.6180(7) 0.2095(6) -0.0438(5) 0.064(2) Uani 1 1 d . . . . .
H11A H 0.6955 0.1882 -0.0530 0.077 Uiso 1 1 calc R U . . .
C12 C 0.5712(6) 0.2895(6) -0.0914(4) 0.0568(18) Uani 1 1 d . . . . .
H12A H 0.6151 0.3188 -0.1327 0.068 Uiso 1 1 calc R U . . .
C13 C 0.4594(5) 0.3262(4) -0.0781(3) 0.0330(11) Uani 1 1 d . . . . .
C14 C 0.4091(5) 0.4190(4) -0.1218(3) 0.0334(11) Uani 1 1 d . . . . .
C15 C 0.4609(6) 0.4645(5) -0.1884(4) 0.0500(16) Uani 1 1 d . . . . .
H15A H 0.5282 0.4360 -0.2080 0.060 Uiso 1 1 calc R U . . .
C16 C 0.4137(6) 0.5512(5) -0.2255(4) 0.0520(16) Uani 1 1 d . . . . .
H16A H 0.4504 0.5796 -0.2703 0.062 Uiso 1 1 calc R U . . .
C17 C 0.2677(5) 0.5543(5) -0.1367(4) 0.0425(13) Uani 1 1 d . . . . .
H17A H 0.2007 0.5846 -0.1182 0.051 Uiso 1 1 calc R U . . .
C18 C 0.3099(5) 0.4676(5) -0.0966(4) 0.0416(13) Uani 1 1 d . . . . .
H18A H 0.2715 0.4409 -0.0519 0.050 Uiso 1 1 calc R U . . .
C19 C 0.3990(7) 0.2725(5) -0.0194(5) 0.0597(19) Uani 1 1 d . . . . .
H19A H 0.3206 0.2910 -0.0094 0.072 Uiso 1 1 calc R U . . .
C20 C 0.4513(7) 0.1928(5) 0.0244(4) 0.0552(17) Uani 1 1 d . . . . .
H20A H 0.4068 0.1593 0.0637 0.066 Uiso 1 1 calc R U . . .
C21 C 0.9420(7) 0.2801(5) -0.1173(4) 0.0535(16) Uani 1 1 d . . . . .
H21A H 0.8752 0.2804 -0.1728 0.080 Uiso 1 1 calc R U . . .
H21B H 0.9098 0.2212 -0.0865 0.080 Uiso 1 1 calc R U . . .
H21C H 1.0225 0.2670 -0.1325 0.080 Uiso 1 1 calc R U . . .
C22 C 0.9708(5) 0.3920(4) -0.0551(3) 0.0345(12) Uani 1 1 d . . . . .
C23 C 1.0538(5) 0.4113(4) 0.0353(3) 0.0294(11) Uani 1 1 d . . . . .
C24 C 1.1122(5) 0.3183(4) 0.0774(4) 0.0360(12) Uani 1 1 d . . . . .
H24A H 1.2030 0.3501 0.1143 0.043 Uiso 1 1 calc R U . . .
H24B H 1.1170 0.2616 0.0280 0.043 Uiso 1 1 calc R U . . .
C25 C 1.0800(5) 0.5181(4) 0.0872(3) 0.0346(12) Uani 1 1 d . . . . .
H25A H 1.1348 0.5305 0.1471 0.041 Uiso 1 1 calc R U . . .
C26 C -0.0067(6) 0.6000(5) 0.3337(4) 0.0450(14) Uani 1 1 d . . . . .
H26A H 0.0611 0.6678 0.3466 0.068 Uiso 1 1 calc R U . . .
H26B H -0.0933 0.6180 0.3133 0.068 Uiso 1 1 calc R U . . .
H26C H 0.0075 0.5472 0.2862 0.068 Uiso 1 1 calc R U . . .
C27 C 0.0006(6) 0.5486(4) 0.4200(3) 0.0369(12) Uani 1 1 d . . . . .
C28 C 0.1224(5) 0.5417(4) 0.4797(3) 0.0357(12) Uani 1 1 d . . . . .
C29 C 0.2570(6) 0.5881(4) 0.4648(4) 0.0420(13) Uani 1 1 d . . . . .
H29A H 0.3201 0.6138 0.5249 0.050 Uiso 1 1 calc R U . . .
H29B H 0.2490 0.6542 0.4357 0.050 Uiso 1 1 calc R U . . .
C30 C 0.1172(5) 0.4934(4) 0.5582(3) 0.0332(11) Uani 1 1 d . . . . .
H30A H 0.1977 0.4892 0.5982 0.040 Uiso 1 1 calc R U . . .
C31 C 0.3767(6) -0.1637(5) 0.3315(4) 0.0508(15) Uani 1 1 d . . . . .
H31A H 0.4118 -0.2311 0.3377 0.076 Uiso 1 1 calc R U . . .
H31B H 0.3964 -0.1342 0.2792 0.076 Uiso 1 1 calc R U . . .
H31C H 0.2815 -0.1813 0.3229 0.076 Uiso 1 1 calc R U . . .
C32 C 0.4400(5) -0.0773(4) 0.4171(3) 0.0348(12) Uani 1 1 d . . . . .
C33 C 0.4207(5) 0.0340(4) 0.4237(3) 0.0328(11) Uani 1 1 d . . . . .
C34 C 0.3375(5) 0.0763(5) 0.3442(4) 0.0404(13) Uani 1 1 d . . . . .
H34A H 0.2807 0.1209 0.3678 0.049 Uiso 1 1 calc R U . . .
H34B H 0.2795 0.0116 0.3010 0.049 Uiso 1 1 calc R U . . .
C35 C 0.4807(5) 0.1084(4) 0.5060(4) 0.0362(12) Uani 1 1 d . . . . .
H35A H 0.4676 0.1823 0.5101 0.043 Uiso 1 1 calc R U . . .
O1W O 0.1602(12) 0.0072(7) 0.0283(7) 0.220(6) Uani 1 1 d . . . . .
H1W H 0.0943 0.0278 -0.0050 0.265 Uiso 1 1 d R U . . .
H2W H 0.1616 -0.0560 -0.0019 0.265 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.190(4) . ?
Ag1 N3 2.192(4) . ?
Ag1 O2 2.594(4) . ?
Ag1 Ag2 3.1819(8) . ?
Ag2 N4 2.202(4) 2_665 ?
Ag2 N2 2.206(4) 2_756 ?
Ag2 O8 2.730(5) . ?
N1 C10 1.315(7) . ?
N1 C1 1.327(7) . ?
N2 C7 1.335(6) . ?
N2 C6 1.341(7) . ?
N2 Ag2 2.206(4) 2_756 ?
N3 C20 1.313(7) . ?
N3 C11 1.321(7) . ?
N4 C17 1.328(7) . ?
N4 C16 1.338(7) . ?
N4 Ag2 2.202(4) 2_665 ?
O1 P1 1.536(4) . ?
O2 P1 1.479(4) . ?
O3 P1 1.539(4) . ?
O4 P2 1.572(4) . ?
O5 P2 1.505(4) . ?
O6 P2 1.500(4) . ?
O7 P3 1.493(4) . ?
O8 P3 1.431(4) . ?
O9 P3 1.634(5) . ?
P1 C24 1.802(5) . ?
P2 C29 1.792(5) . ?
P3 C34 1.797(5) . ?
C1 C2 1.370(7) . ?
C2 C3 1.376(7) . ?
C3 C9 1.375(7) . ?
C3 C4 1.497(6) . ?
C4 C5 1.386(7) . ?
C4 C8 1.394(7) . ?
C5 C6 1.373(7) . ?
C7 C8 1.374(7) . ?
C9 C10 1.384(7) . ?
C11 C12 1.371(7) . ?
C12 C13 1.373(7) . ?
C13 C19 1.375(7) . ?
C13 C14 1.490(6) . ?
C14 C15 1.383(7) . ?
C14 C18 1.385(7) . ?
C15 C16 1.368(7) . ?
C17 C18 1.369(7) . ?
C19 C20 1.362(8) . ?
C21 C22 1.499(7) . ?
C22 C25 1.389(7) 2_765 ?
C22 C23 1.406(7) . ?
C23 C25 1.382(7) . ?
C23 C24 1.515(6) . ?
C25 C22 1.389(7) 2_765 ?
C26 C27 1.510(7) . ?
C27 C30 1.386(7) 2_566 ?
C27 C28 1.403(7) . ?
C28 C30 1.398(7) . ?
C28 C29 1.510(7) . ?
C30 C27 1.386(7) 2_566 ?
C31 C32 1.499(7) . ?
C32 C35 1.397(7) 2_656 ?
C32 C33 1.399(7) . ?
C33 C35 1.388(7) . ?
C33 C34 1.513(6) . ?
C35 C32 1.397(7) 2_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N3 175.73(16) . . ?
N1 Ag1 O2 99.97(15) . . ?
N3 Ag1 O2 84.01(14) . . ?
N1 Ag1 Ag2 87.99(12) . . ?
N3 Ag1 Ag2 94.92(12) . . ?
O2 Ag1 Ag2 68.68(12) . . ?
N4 Ag2 N2 160.02(16) 2_665 2_756 ?
N4 Ag2 O8 100.94(15) 2_665 . ?
N2 Ag2 O8 90.80(14) 2_756 . ?
N4 Ag2 Ag1 97.04(12) 2_665 . ?
N2 Ag2 Ag1 102.88(11) 2_756 . ?
O8 Ag2 Ag1 58.77(10) . . ?
C10 N1 C1 116.4(4) . . ?
C10 N1 Ag1 121.3(3) . . ?
C1 N1 Ag1 120.9(4) . . ?
C7 N2 C6 116.9(4) . . ?
C7 N2 Ag2 119.7(3) . 2_756 ?
C6 N2 Ag2 122.7(3) . 2_756 ?
C20 N3 C11 115.3(5) . . ?
C20 N3 Ag1 120.6(4) . . ?
C11 N3 Ag1 122.2(4) . . ?
C17 N4 C16 116.3(4) . . ?
C17 N4 Ag2 122.2(3) . 2_665 ?
C16 N4 Ag2 120.9(3) . 2_665 ?
P1 O2 Ag1 141.7(3) . . ?
P3 O8 Ag2 118.0(3) . . ?
O2 P1 O1 111.9(2) . . ?
O2 P1 O3 110.0(3) . . ?
O1 P1 O3 110.1(2) . . ?
O2 P1 C24 112.3(3) . . ?
O1 P1 C24 106.3(2) . . ?
O3 P1 C24 106.1(2) . . ?
O6 P2 O5 116.1(2) . . ?
O6 P2 O4 106.5(2) . . ?
O5 P2 O4 109.8(2) . . ?
O6 P2 C29 109.6(3) . . ?
O5 P2 C29 109.9(2) . . ?
O4 P2 C29 104.1(2) . . ?
O8 P3 O7 119.7(2) . . ?
O8 P3 O9 104.3(3) . . ?
O7 P3 O9 105.2(3) . . ?
O8 P3 C34 115.9(3) . . ?
O7 P3 C34 108.5(2) . . ?
O9 P3 C34 100.9(3) . . ?
N1 C1 C2 123.7(5) . . ?
C1 C2 C3 120.2(5) . . ?
C9 C3 C2 116.1(5) . . ?
C9 C3 C4 122.0(5) . . ?
C2 C3 C4 121.9(4) . . ?
C5 C4 C8 115.8(4) . . ?
C5 C4 C3 122.5(4) . . ?
C8 C4 C3 121.7(4) . . ?
C6 C5 C4 120.4(5) . . ?
N2 C6 C5 123.2(5) . . ?
N2 C7 C8 123.0(5) . . ?
C7 C8 C4 120.6(5) . . ?
C3 C9 C10 119.9(5) . . ?
N1 C10 C9 123.6(5) . . ?
N3 C11 C12 124.7(5) . . ?
C11 C12 C13 119.8(5) . . ?
C12 C13 C19 114.8(5) . . ?
C12 C13 C14 122.8(5) . . ?
C19 C13 C14 122.4(5) . . ?
C15 C14 C18 115.6(5) . . ?
C15 C14 C13 122.2(4) . . ?
C18 C14 C13 122.2(4) . . ?
C16 C15 C14 120.4(5) . . ?
N4 C16 C15 123.6(5) . . ?
N4 C17 C18 123.3(5) . . ?
C17 C18 C14 120.8(5) . . ?
C20 C19 C13 121.5(5) . . ?
N3 C20 C19 123.7(5) . . ?
C25 C22 C23 117.9(5) 2_765 . ?
C25 C22 C21 120.2(5) 2_765 . ?
C23 C22 C21 121.8(5) . . ?
C25 C23 C22 118.4(4) . . ?
C25 C23 C24 119.6(4) . . ?
C22 C23 C24 122.0(5) . . ?
C23 C24 P1 114.7(3) . . ?
C23 C25 C22 123.7(5) . 2_765 ?
C30 C27 C28 118.4(5) 2_566 . ?
C30 C27 C26 119.0(5) 2_566 . ?
C28 C27 C26 122.6(5) . . ?
C30 C28 C27 117.7(5) . . ?
C30 C28 C29 119.2(5) . . ?
C27 C28 C29 123.1(5) . . ?
C28 C29 P2 118.2(4) . . ?
C27 C30 C28 123.9(5) 2_566 . ?
C35 C32 C33 118.3(5) 2_656 . ?
C35 C32 C31 119.4(5) 2_656 . ?
C33 C32 C31 122.4(5) . . ?
C35 C33 C32 118.8(4) . . ?
C35 C33 C34 118.8(5) . . ?
C32 C33 C34 122.3(5) . . ?
C33 C34 P3 114.9(4) . . ?
C33 C35 C32 122.9(5) . 2_656 ?

_refine_diff_density_max         1.385
_refine_diff_density_min         -1.323
_refine_diff_density_rms         0.090

_shelxl_version_number           2013-2

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3
_database_code_depnum_ccdc_archive 'CCDC 1498979'
_audit_update_record             
;
2016-08-12 deposited with the CCDC.
2016-10-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C14 H18 Ag2 N2 O6 P2'
_chemical_formula_weight         587.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.7570(14)
_cell_length_b                   4.6361(5)
_cell_length_c                   16.3047(18)
_cell_angle_alpha                90
_cell_angle_beta                 102.766(4)
_cell_angle_gamma                90
_cell_volume                     866.75(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    287(2)
_cell_measurement_reflns_used    4858
_cell_measurement_theta_min      3.43
_cell_measurement_theta_max      24.99

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.253
_exptl_crystal_F_000             576
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_exptl_absorpt_coefficient_mu    2.480
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.788
_exptl_absorpt_correction_T_max  0.820
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      287(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            4858
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_av_R_equivalents  0.0245
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         3.426
_diffrn_reflns_theta_max         24.990
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.965
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 0.965
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 0.965
_reflns_number_total             1520
_reflns_number_gt                1234
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0229P)²+1.6525P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1520
_refine_ls_number_parameters     119
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0387
_refine_ls_R_factor_gt           0.0261
_refine_ls_wR_factor_ref         0.0617
_refine_ls_wR_factor_gt          0.0565
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48666(2) 1.00448(8) 0.81603(2) 0.03998(13) Uani 1 1 d . . . . .
N1 N 0.4893(3) 0.6813(8) 0.93104(19) 0.0342(8) Uani 1 1 d . . . . .
O1 O 0.3157(2) 1.0596(5) 0.73237(16) 0.0330(7) Uani 1 1 d . . . . .
O2 O 0.3404(2) 0.6728(6) 0.62631(15) 0.0304(6) Uani 1 1 d . . . . .
O3 O 0.2285(2) 0.5711(5) 0.73814(16) 0.0306(6) Uani 1 1 d . . . . .
H3A H 0.2873 0.5059 0.7694 0.046 Uiso 1 1 calc R U . . .
P1 P 0.26452(8) 0.80419(19) 0.67850(6) 0.0210(2) Uani 1 1 d . . . . .
C1 C 0.1307(3) 0.9331(7) 0.6128(2) 0.0233(8) Uani 1 1 d . . . . .
H1A H 0.0822 1.0108 0.6485 0.028 Uiso 1 1 calc R U . . .
H1B H 0.1488 1.0900 0.5784 0.028 Uiso 1 1 calc R U . . .
C2 C 0.0612(3) 0.7070(7) 0.5555(2) 0.0206(7) Uani 1 1 d . . . . .
C3 C -0.0375(3) 0.5751(7) 0.5735(2) 0.0218(8) Uani 1 1 d . . . . .
C4 C -0.0817(4) 0.6476(10) 0.6515(2) 0.0382(10) Uani 1 1 d . . . . .
H4A H -0.1019 0.8484 0.6506 0.057 Uiso 1 1 calc R U . . .
H4B H -0.0218 0.6075 0.7006 0.057 Uiso 1 1 calc R U . . .
H4C H -0.1493 0.5330 0.6527 0.057 Uiso 1 1 calc R U . . .
C5 C 0.0962(3) 0.6282(8) 0.4830(2) 0.0219(8) Uani 1 1 d . . . . .
H5A H 0.1621 0.7156 0.4714 0.026 Uiso 1 1 calc R U . . .
C6 C 0.4133(3) 0.3245(9) 1.0084(2) 0.0358(9) Uani 1 1 d . . . . .
H6A H 0.3510 0.2057 1.0123 0.043 Uiso 1 1 calc R U . . .
C7 C 0.4045(3) 0.5054(9) 0.9401(2) 0.0338(9) Uani 1 1 d . . . . .
H7A H 0.3360 0.5036 0.8987 0.041 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.180(2) . ?
Ag1 O2 2.187(2) 2_656 ?
Ag1 N1 2.395(3) . ?
Ag1 Ag1 3.2260(5) 2_656 ?
Ag1 Ag1 3.2260(5) 2_646 ?
N1 C7 1.321(5) . ?
N1 C6 1.337(5) 3_667 ?
O1 P1 1.517(3) . ?
O2 P1 1.492(3) . ?
O2 Ag1 2.187(2) 2_646 ?
O3 P1 1.573(3) . ?
P1 C1 1.799(3) . ?
C1 C2 1.517(5) . ?
C2 C5 1.383(5) . ?
C2 C3 1.399(5) . ?
C3 C5 1.389(5) 3_566 ?
C3 C4 1.514(5) . ?
C5 C3 1.389(5) 3_566 ?
C6 N1 1.337(5) 3_667 ?
C6 C7 1.379(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 O2 150.24(10) . 2_656 ?
O1 Ag1 N1 114.45(11) . . ?
O2 Ag1 N1 92.10(10) 2_656 . ?
O1 Ag1 Ag1 73.17(7) . 2_656 ?
O2 Ag1 Ag1 79.18(7) 2_656 2_656 ?
N1 Ag1 Ag1 170.32(8) . 2_656 ?
O1 Ag1 Ag1 83.03(7) . 2_646 ?
O2 Ag1 Ag1 108.97(7) 2_656 2_646 ?
N1 Ag1 Ag1 94.97(8) . 2_646 ?
Ag1 Ag1 Ag1 91.871(18) 2_656 2_646 ?
C7 N1 C6 116.7(3) . 3_667 ?
C7 N1 Ag1 126.4(3) . . ?
C6 N1 Ag1 116.9(3) 3_667 . ?
P1 O1 Ag1 117.63(14) . . ?
P1 O2 Ag1 121.12(14) . 2_646 ?
O2 P1 O1 115.98(16) . . ?
O2 P1 O3 110.40(15) . . ?
O1 P1 O3 107.73(15) . . ?
O2 P1 C1 110.52(16) . . ?
O1 P1 C1 105.57(15) . . ?
O3 P1 C1 106.09(16) . . ?
C2 C1 P1 114.7(2) . . ?
C5 C2 C3 118.7(3) . . ?
C5 C2 C1 119.2(3) . . ?
C3 C2 C1 122.1(3) . . ?
C5 C3 C2 118.1(3) 3_566 . ?
C5 C3 C4 119.7(3) 3_566 . ?
C2 C3 C4 122.2(3) . . ?
C2 C5 C3 123.2(3) . 3_566 ?
N1 C6 C7 120.5(4) 3_667 . ?
N1 C7 C6 122.8(4) . . ?

_refine_diff_density_max         0.592
_refine_diff_density_min         -0.566
_refine_diff_density_rms         0.085

_shelxl_version_number           2013-2

