# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2016

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_1
_database_code_depnum_ccdc_archive 'CCDC 1472198'
_audit_update_record             
;
2016-09-19 deposited with the CCDC.
2016-10-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(N O3), C H2 Cl2'
_chemical_formula_sum            'C73 H58 Au2 Cl2 N2 O8 P4'
_chemical_formula_weight         1679.92

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   21.848(2)
_cell_length_b                   15.4782(16)
_cell_length_c                   19.843(2)
_cell_angle_alpha                90
_cell_angle_beta                 106.460(2)
_cell_angle_gamma                90
_cell_volume                     6435.1(11)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9739
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.968
_cell_measurement_theta_min      2.348
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?


_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.734
_exptl_crystal_F_000             3304
_exptl_crystal_description       block
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    4.797
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6639
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/4 (Bruker,2014) was used for absorption correction.
wR2(int) was 0.0653 before and 0.0564 after correction.
The Ratio of minimum to maximum transmission is 0.8903.
The λ/2 correction factor is 0.00150.
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            178161
_diffrn_reflns_av_unetI/netI     0.0330
_diffrn_reflns_av_R_equivalents  0.0694
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.972
_diffrn_reflns_theta_max         28.304
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             16016
_reflns_number_gt                13038
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_solution    'XT (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0153P)²+6.8809P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16016
_refine_ls_number_parameters     820
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0393
_refine_ls_R_factor_gt           0.0240
_refine_ls_wR_factor_ref         0.0455
_refine_ls_wR_factor_gt          0.0417
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_restrained_S_all      0.999
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.77691(2) 0.35002(2) 0.68332(2) 0.01106(3) Uani 1 1 d . . . . .
Au2 Au 0.73261(2) 0.45009(2) 0.82695(2) 0.01150(3) Uani 1 1 d . . . . .
P1 P 0.80526(3) 0.21649(4) 0.73838(4) 0.01016(14) Uani 1 1 d . . . . .
P2 P 0.83720(3) 0.47572(4) 0.89055(4) 0.01062(14) Uani 1 1 d . . . . .
P3 P 0.75209(3) 0.46892(4) 0.60827(4) 0.01054(14) Uani 1 1 d . . . . .
P4 P 0.62269(3) 0.44069(4) 0.78899(4) 0.01062(13) Uani 1 1 d . . . . .
C1 C 0.75962(12) 0.18481(17) 0.79831(14) 0.0112(5) Uani 1 1 d . . . . .
C2 C 0.71196(13) 0.12193(17) 0.78012(15) 0.0146(6) Uani 1 1 d . . . . .
H2 H 0.7060 0.0903 0.7377 0.018 Uiso 1 1 calc R U . . .
C3 C 0.67305(13) 0.10498(18) 0.82317(15) 0.0171(6) Uani 1 1 d . . . . .
H3 H 0.6414 0.0612 0.8107 0.021 Uiso 1 1 calc R U . . .
C4 C 0.68064(13) 0.15209(19) 0.88412(15) 0.0178(6) Uani 1 1 d . . . . .
H4 H 0.6532 0.1415 0.9128 0.021 Uiso 1 1 calc R U . . .
C5 C 0.72791(13) 0.21474(18) 0.90403(15) 0.0160(6) Uani 1 1 d . . . . .
H5 H 0.7329 0.2470 0.9460 0.019 Uiso 1 1 calc R U . . .
C6 C 0.76766(12) 0.22945(16) 0.86159(14) 0.0111(5) Uani 1 1 d . . . . .
C7 C 0.84642(13) 0.31161(18) 0.94624(14) 0.0124(6) Uani 1 1 d . . . . .
C8 C 0.86038(13) 0.39841(17) 0.96162(14) 0.0115(5) Uani 1 1 d . . . . .
C9 C 0.89630(13) 0.42044(19) 1.02993(15) 0.0165(6) Uani 1 1 d . . . . .
H9 H 0.9051 0.4794 1.0421 0.020 Uiso 1 1 calc R U . . .
C10 C 0.91888(14) 0.35707(19) 1.07962(14) 0.0178(6) Uani 1 1 d . . . . .
H10 H 0.9434 0.3724 1.1257 0.021 Uiso 1 1 calc R U . . .
C11 C 0.90574(14) 0.27067(19) 1.06218(15) 0.0193(6) Uani 1 1 d . . . . .
H11 H 0.9223 0.2272 1.0963 0.023 Uiso 1 1 calc R U . . .
C12 C 0.86877(13) 0.24712(19) 0.99569(14) 0.0162(6) Uani 1 1 d . . . . .
H12 H 0.8590 0.1882 0.9842 0.019 Uiso 1 1 calc R U . . .
O1 O 0.81471(9) 0.29236(11) 0.87633(9) 0.0115(4) Uani 1 1 d . . . . .
C13 C 0.76346(12) 0.57475(16) 0.64958(13) 0.0102(5) Uani 1 1 d . . . . .
C14 C 0.81151(13) 0.63162(17) 0.64426(14) 0.0136(6) Uani 1 1 d . . . . .
H14 H 0.8369 0.6183 0.6139 0.016 Uiso 1 1 calc R U . . .
C15 C 0.82247(13) 0.70754(18) 0.68310(15) 0.0164(6) Uani 1 1 d . . . . .
H15 H 0.8541 0.7470 0.6780 0.020 Uiso 1 1 calc R U . . .
C16 C 0.78713(14) 0.72556(18) 0.72929(15) 0.0181(6) Uani 1 1 d . . . . .
H16 H 0.7965 0.7758 0.7579 0.022 Uiso 1 1 calc R U . . .
C17 C 0.73813(13) 0.67112(17) 0.73437(14) 0.0147(6) Uani 1 1 d . . . . .
H17 H 0.7136 0.6839 0.7657 0.018 Uiso 1 1 calc R U . . .
C18 C 0.72574(12) 0.59781(17) 0.69274(14) 0.0111(5) Uani 1 1 d . . . . .
C19 C 0.61942(12) 0.57762(17) 0.69818(14) 0.0109(5) Uani 1 1 d . . . . .
C20 C 0.58797(12) 0.53721(16) 0.74149(13) 0.0108(5) Uani 1 1 d . . . . .
C21 C 0.52911(12) 0.57125(17) 0.74404(14) 0.0122(5) Uani 1 1 d . . . . .
H21 H 0.5062 0.5442 0.7724 0.015 Uiso 1 1 calc R U . . .
C22 C 0.50432(13) 0.64416(18) 0.70543(14) 0.0151(6) Uani 1 1 d . . . . .
H22 H 0.4648 0.6674 0.7079 0.018 Uiso 1 1 calc R U . . .
C23 C 0.53722(13) 0.68343(18) 0.66310(15) 0.0155(6) Uani 1 1 d . . . . .
H23 H 0.5200 0.7336 0.6370 0.019 Uiso 1 1 calc R U . . .
C24 C 0.59470(12) 0.65029(18) 0.65860(14) 0.0134(5) Uani 1 1 d . . . . .
H24 H 0.6168 0.6766 0.6291 0.016 Uiso 1 1 calc R U . . .
O2 O 0.67646(8) 0.54104(11) 0.69383(9) 0.0112(4) Uani 1 1 d . . . . .
C1A C 0.78860(13) 0.13146(17) 0.67292(14) 0.0123(5) Uani 1 1 d . . . . .
C2A C 0.74840(13) 0.14707(19) 0.60549(14) 0.0160(6) Uani 1 1 d . . . . .
H2A H 0.7331 0.2039 0.5924 0.019 Uiso 1 1 calc R U . . .
C3A C 0.73065(14) 0.0795(2) 0.55746(15) 0.0198(6) Uani 1 1 d . . . . .
H3A H 0.7036 0.0904 0.5116 0.024 Uiso 1 1 calc R U . . .
C4A C 0.75249(14) -0.0035(2) 0.57665(16) 0.0224(7) Uani 1 1 d . . . . .
H4A H 0.7389 -0.0501 0.5447 0.027 Uiso 1 1 calc R U . . .
C5A C 0.79426(14) -0.01837(19) 0.64278(16) 0.0197(6) Uani 1 1 d . . . . .
H5A H 0.8105 -0.0749 0.6550 0.024 Uiso 1 1 calc R U . . .
C6A C 0.81261(13) 0.04810(18) 0.69120(14) 0.0147(6) Uani 1 1 d . . . . .
H6A H 0.8412 0.0372 0.7363 0.018 Uiso 1 1 calc R U . . .
C1B C 0.88917(13) 0.20730(17) 0.78542(14) 0.0118(5) Uani 1 1 d . . . . .
C2B C 0.93307(13) 0.24493(18) 0.75579(14) 0.0143(6) Uani 1 1 d . . . . .
H2B H 0.9187 0.2759 0.7129 0.017 Uiso 1 1 calc R U . . .
C3B C 0.99796(13) 0.23746(18) 0.78864(15) 0.0181(6) Uani 1 1 d . . . . .
H3B H 1.0282 0.2616 0.7677 0.022 Uiso 1 1 calc R U . . .
C4B C 1.01827(13) 0.19430(18) 0.85242(16) 0.0179(6) Uani 1 1 d . . . . .
H4B H 1.0626 0.1905 0.8759 0.021 Uiso 1 1 calc R U . . .
C5B C 0.97468(13) 0.15686(19) 0.88212(15) 0.0184(6) Uani 1 1 d . . . . .
H5B H 0.9891 0.1278 0.9259 0.022 Uiso 1 1 calc R U . . .
C6B C 0.90983(13) 0.16170(17) 0.84803(14) 0.0151(6) Uani 1 1 d . . . . .
H6B H 0.8798 0.1340 0.8674 0.018 Uiso 1 1 calc R U . . .
C1C C 0.84509(13) 0.58349(17) 0.92800(14) 0.0137(6) Uani 1 1 d . . . . .
C2C C 0.90242(14) 0.62880(19) 0.94184(17) 0.0221(7) Uani 1 1 d . . . . .
H2C H 0.9391 0.6018 0.9345 0.026 Uiso 1 1 calc R U . . .
C3C C 0.90619(17) 0.7134(2) 0.96640(18) 0.0284(8) Uani 1 1 d . . . . .
H3C H 0.9449 0.7448 0.9743 0.034 Uiso 1 1 calc R U . . .
C4C C 0.85340(17) 0.7514(2) 0.97934(17) 0.0288(8) Uani 1 1 d . . . . .
H4C H 0.8563 0.8088 0.9970 0.035 Uiso 1 1 calc R U . . .
C5C C 0.79611(16) 0.7067(2) 0.96673(17) 0.0259(7) Uani 1 1 d . . . . .
H5C H 0.7602 0.7332 0.9762 0.031 Uiso 1 1 calc R U . . .
C6C C 0.79174(14) 0.62315(19) 0.94025(15) 0.0188(6) Uani 1 1 d . . . . .
H6C H 0.7524 0.5929 0.9304 0.023 Uiso 1 1 calc R U . . .
C1D C 0.90095(13) 0.46965(17) 0.84887(14) 0.0128(6) Uani 1 1 d . . . . .
C2D C 0.89553(14) 0.5224(2) 0.79043(15) 0.0200(6) Uani 1 1 d . . . . .
H2D H 0.8573 0.5537 0.7704 0.024 Uiso 1 1 calc R U . . .
C3D C 0.94630(15) 0.5287(2) 0.76174(16) 0.0249(7) Uani 1 1 d . . . . .
H3D H 0.9427 0.5645 0.7219 0.030 Uiso 1 1 calc R U . . .
C4D C 1.00198(15) 0.4836(2) 0.79038(17) 0.0245(7) Uani 1 1 d . . . . .
H4D H 1.0368 0.4891 0.7708 0.029 Uiso 1 1 calc R U . . .
C5D C 1.00712(14) 0.43024(19) 0.84761(17) 0.0232(7) Uani 1 1 d . . . . .
H5D H 1.0452 0.3983 0.8667 0.028 Uiso 1 1 calc R U . . .
C6D C 0.95700(13) 0.42297(18) 0.87739(16) 0.0167(6) Uani 1 1 d . . . . .
H6D H 0.9608 0.3865 0.9169 0.020 Uiso 1 1 calc R U . . .
C1E C 0.67185(13) 0.47060(17) 0.55010(14) 0.0129(6) Uani 1 1 d . . . . .
C2E C 0.64930(14) 0.54569(19) 0.51170(15) 0.0178(6) Uani 1 1 d . . . . .
H2E H 0.6755 0.5957 0.5176 0.021 Uiso 1 1 calc R U . . .
C3E C 0.58839(14) 0.5468(2) 0.46492(15) 0.0215(6) Uani 1 1 d . . . . .
H3E H 0.5733 0.5974 0.4382 0.026 Uiso 1 1 calc R U . . .
C4E C 0.54951(14) 0.4741(2) 0.45710(15) 0.0210(7) Uani 1 1 d . . . . .
H4E H 0.5083 0.4747 0.4242 0.025 Uiso 1 1 calc R U . . .
C5E C 0.57074(13) 0.40092(19) 0.49717(15) 0.0181(6) Uani 1 1 d . . . . .
H5E H 0.5434 0.3523 0.4932 0.022 Uiso 1 1 calc R U . . .
C6E C 0.63211(13) 0.39867(18) 0.54314(15) 0.0156(6) Uani 1 1 d . . . . .
H6E H 0.6469 0.3480 0.5698 0.019 Uiso 1 1 calc R U . . .
C1F C 0.80716(13) 0.47077(17) 0.55492(14) 0.0121(5) Uani 1 1 d . . . . .
C2F C 0.78945(14) 0.49734(18) 0.48467(14) 0.0155(6) Uani 1 1 d . . . . .
H2F H 0.7459 0.5078 0.4608 0.019 Uiso 1 1 calc R U . . .
C3F C 0.83613(14) 0.50832(18) 0.44997(15) 0.0176(6) Uani 1 1 d . . . . .
H3F H 0.8242 0.5257 0.4021 0.021 Uiso 1 1 calc R U . . .
C4F C 0.89955(14) 0.49422(18) 0.48457(16) 0.0195(6) Uani 1 1 d . . . . .
H4F H 0.9310 0.5037 0.4607 0.023 Uiso 1 1 calc R U . . .
C5F C 0.91785(14) 0.46634(18) 0.55387(16) 0.0177(6) Uani 1 1 d . . . . .
H5F H 0.9616 0.4561 0.5773 0.021 Uiso 1 1 calc R U . . .
C6F C 0.87145(13) 0.45359(18) 0.58861(15) 0.0146(6) Uani 1 1 d . . . . .
H6F H 0.8835 0.4330 0.6356 0.017 Uiso 1 1 calc R U . . .
C1G C 0.58397(12) 0.35291(17) 0.73214(13) 0.0121(5) Uani 1 1 d . . . . .
C2G C 0.51731(13) 0.34679(18) 0.71041(14) 0.0155(6) Uani 1 1 d . . . . .
H2G H 0.4922 0.3856 0.7285 0.019 Uiso 1 1 calc R U . . .
C3G C 0.48806(14) 0.28396(18) 0.66238(15) 0.0171(6) Uani 1 1 d . . . . .
H3G H 0.4428 0.2797 0.6477 0.020 Uiso 1 1 calc R U . . .
C4G C 0.52436(15) 0.22714(18) 0.63553(15) 0.0194(6) Uani 1 1 d . . . . .
H4G H 0.5040 0.1852 0.6017 0.023 Uiso 1 1 calc R U . . .
C5G C 0.59040(15) 0.23166(19) 0.65815(16) 0.0213(7) Uani 1 1 d . . . . .
H5G H 0.6153 0.1919 0.6406 0.026 Uiso 1 1 calc R U . . .
C6G C 0.62019(14) 0.29445(18) 0.70657(15) 0.0172(6) Uani 1 1 d . . . . .
H6G H 0.6655 0.2973 0.7222 0.021 Uiso 1 1 calc R U . . .
C1H C 0.59474(12) 0.43700(17) 0.86687(14) 0.0114(5) Uani 1 1 d . . . . .
C2H C 0.59542(13) 0.51217(18) 0.90625(14) 0.0152(6) Uani 1 1 d . . . . .
H2H H 0.6072 0.5658 0.8903 0.018 Uiso 1 1 calc R U . . .
C3H C 0.57887(14) 0.50805(19) 0.96872(15) 0.0175(6) Uani 1 1 d . . . . .
H3H H 0.5789 0.5591 0.9953 0.021 Uiso 1 1 calc R U . . .
C4H C 0.56237(13) 0.42978(19) 0.99242(15) 0.0185(6) Uani 1 1 d . . . . .
H4H H 0.5509 0.4274 1.0351 0.022 Uiso 1 1 calc R U . . .
C5H C 0.56250(13) 0.35481(19) 0.95423(15) 0.0180(6) Uani 1 1 d . . . . .
H5H H 0.5512 0.3013 0.9708 0.022 Uiso 1 1 calc R U . . .
C6H C 0.57922(13) 0.35802(18) 0.89163(14) 0.0156(6) Uani 1 1 d . . . . .
H6H H 0.5801 0.3066 0.8658 0.019 Uiso 1 1 calc R U . . .
N1 N 0.92946(12) 0.88717(16) 0.81734(13) 0.0197(5) Uani 1 1 d . . . . .
O3 O 0.89297(10) 0.86634(14) 0.75904(12) 0.0288(5) Uani 1 1 d . . . . .
O4 O 0.92433(11) 0.96054(15) 0.84158(12) 0.0328(6) Uani 1 1 d . . . . .
O5 O 0.97200(13) 0.83723(16) 0.84979(14) 0.0457(7) Uani 1 1 d . . . . .
N2 N 0.36869(12) 0.22262(15) 0.48311(13) 0.0197(5) Uani 1 1 d . . . . .
O6 O 0.36382(11) 0.21191(16) 0.54366(11) 0.0326(6) Uani 1 1 d . . . . .
O7 O 0.32089(10) 0.24155(17) 0.43386(12) 0.0350(6) Uani 1 1 d . . . . .
O8 O 0.42176(11) 0.21343(15) 0.47064(12) 0.0313(6) Uani 1 1 d . . . . .
C25 C 0.34790(18) 0.1146(2) 0.30527(19) 0.0361(9) Uani 1 1 d . . . . .
H25A H 0.3587 0.1673 0.3346 0.043 Uiso 1 1 calc R U . . .
H25B H 0.3069 0.0920 0.3099 0.043 Uiso 1 1 calc R U . . .
Cl1 Cl 0.33900(5) 0.14185(6) 0.21660(5) 0.0443(2) Uani 1 1 d . . . . .
Cl2 Cl 0.40776(5) 0.03694(7) 0.33587(5) 0.0423(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P3 2.3326(7) . ?
Au1 P1 2.3377(7) . ?
Au2 P4 2.3087(7) . ?
Au2 P2 2.3102(7) . ?
P1 C1B 1.812(3) . ?
P1 C1A 1.812(3) . ?
P1 C1 1.823(3) . ?
P2 C8 1.809(3) . ?
P2 C1D 1.812(3) . ?
P2 C1C 1.814(3) . ?
P3 C1E 1.805(3) . ?
P3 C1F 1.814(3) . ?
P3 C13 1.817(3) . ?
P4 C20 1.814(3) . ?
P4 C1G 1.815(3) . ?
P4 C1H 1.816(3) . ?
C1 C2 1.396(4) . ?
C1 C6 1.400(4) . ?
C2 C3 1.390(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.381(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.390(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.389(4) . ?
C5 H5 0.9500 . ?
C6 O1 1.385(3) . ?
C7 C12 1.388(4) . ?
C7 C8 1.392(4) . ?
C7 O1 1.396(3) . ?
C8 C9 1.402(4) . ?
C9 C10 1.379(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.391(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.386(4) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.393(4) . ?
C13 C14 1.397(4) . ?
C14 C15 1.388(4) . ?
C14 H14 0.9500 . ?
C15 C16 1.384(4) . ?
C15 H15 0.9500 . ?
C16 C17 1.388(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.384(4) . ?
C17 H17 0.9500 . ?
C18 O2 1.395(3) . ?
C19 C24 1.390(4) . ?
C19 C20 1.392(4) . ?
C19 O2 1.394(3) . ?
C20 C21 1.404(4) . ?
C21 C22 1.385(4) . ?
C21 H21 0.9500 . ?
C22 C23 1.391(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.382(4) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C1A C2A 1.398(4) . ?
C1A C6A 1.401(4) . ?
C2A C3A 1.394(4) . ?
C2A H2A 0.9500 . ?
C3A C4A 1.386(4) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.389(4) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.387(4) . ?
C5A H5A 0.9500 . ?
C6A H6A 0.9500 . ?
C1B C2B 1.387(4) . ?
C1B C6B 1.388(4) . ?
C2B C3B 1.387(4) . ?
C2B H2B 0.9500 . ?
C3B C4B 1.388(4) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.381(4) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.388(4) . ?
C5B H5B 0.9500 . ?
C6B H6B 0.9500 . ?
C1C C2C 1.393(4) . ?
C1C C6C 1.398(4) . ?
C2C C3C 1.391(4) . ?
C2C H2C 0.9500 . ?
C3C C4C 1.382(5) . ?
C3C H3C 0.9500 . ?
C4C C5C 1.389(5) . ?
C4C H4C 0.9500 . ?
C5C C6C 1.390(4) . ?
C5C H5C 0.9500 . ?
C6C H6C 0.9500 . ?
C1D C2D 1.395(4) . ?
C1D C6D 1.396(4) . ?
C2D C3D 1.386(4) . ?
C2D H2D 0.9500 . ?
C3D C4D 1.378(5) . ?
C3D H3D 0.9500 . ?
C4D C5D 1.383(5) . ?
C4D H4D 0.9500 . ?
C5D C6D 1.388(4) . ?
C5D H5D 0.9500 . ?
C6D H6D 0.9500 . ?
C1E C6E 1.395(4) . ?
C1E C2E 1.401(4) . ?
C2E C3E 1.390(4) . ?
C2E H2E 0.9500 . ?
C3E C4E 1.392(4) . ?
C3E H3E 0.9500 . ?
C4E C5E 1.386(4) . ?
C4E H4E 0.9500 . ?
C5E C6E 1.392(4) . ?
C5E H5E 0.9500 . ?
C6E H6E 0.9500 . ?
C1F C2F 1.399(4) . ?
C1F C6F 1.399(4) . ?
C2F C3F 1.393(4) . ?
C2F H2F 0.9500 . ?
C3F C4F 1.378(4) . ?
C3F H3F 0.9500 . ?
C4F C5F 1.388(4) . ?
C4F H4F 0.9500 . ?
C5F C6F 1.392(4) . ?
C5F H5F 0.9500 . ?
C6F H6F 0.9500 . ?
C1G C6G 1.389(4) . ?
C1G C2G 1.400(4) . ?
C2G C3G 1.385(4) . ?
C2G H2G 0.9500 . ?
C3G C4G 1.388(4) . ?
C3G H3G 0.9500 . ?
C4G C5G 1.386(4) . ?
C4G H4G 0.9500 . ?
C5G C6G 1.392(4) . ?
C5G H5G 0.9500 . ?
C6G H6G 0.9500 . ?
C1H C6H 1.395(4) . ?
C1H C2H 1.399(4) . ?
C2H C3H 1.388(4) . ?
C2H H2H 0.9500 . ?
C3H C4H 1.384(4) . ?
C3H H3H 0.9500 . ?
C4H C5H 1.386(4) . ?
C4H H4H 0.9500 . ?
C5H C6H 1.391(4) . ?
C5H H5H 0.9500 . ?
C6H H6H 0.9500 . ?
N1 O5 1.240(3) . ?
N1 O3 1.247(3) . ?
N1 O4 1.251(3) . ?
N2 O7 1.246(3) . ?
N2 O6 1.247(3) . ?
N2 O8 1.260(3) . ?
C25 Cl2 1.754(4) . ?
C25 Cl1 1.765(4) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P3 Au1 P1 168.16(2) . . ?
P4 Au2 P2 164.89(2) . . ?
C1B P1 C1A 106.31(12) . . ?
C1B P1 C1 107.66(12) . . ?
C1A P1 C1 103.67(12) . . ?
C1B P1 Au1 113.93(9) . . ?
C1A P1 Au1 109.53(9) . . ?
C1 P1 Au1 114.92(9) . . ?
C8 P2 C1D 103.87(12) . . ?
C8 P2 C1C 108.40(12) . . ?
C1D P2 C1C 103.80(13) . . ?
C8 P2 Au2 109.11(9) . . ?
C1D P2 Au2 120.72(9) . . ?
C1C P2 Au2 110.25(9) . . ?
C1E P3 C1F 108.12(13) . . ?
C1E P3 C13 105.02(12) . . ?
C1F P3 C13 102.74(12) . . ?
C1E P3 Au1 115.31(9) . . ?
C1F P3 Au1 108.21(9) . . ?
C13 P3 Au1 116.48(9) . . ?
C20 P4 C1G 103.94(12) . . ?
C20 P4 C1H 106.02(12) . . ?
C1G P4 C1H 107.19(12) . . ?
C20 P4 Au2 111.15(9) . . ?
C1G P4 Au2 120.57(9) . . ?
C1H P4 Au2 107.09(8) . . ?
C2 C1 C6 118.1(2) . . ?
C2 C1 P1 121.7(2) . . ?
C6 C1 P1 120.0(2) . . ?
C3 C2 C1 120.9(3) . . ?
C3 C2 H2 119.5 . . ?
C1 C2 H2 119.5 . . ?
C4 C3 C2 119.7(3) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C3 C4 C5 120.8(3) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
C6 C5 C4 118.9(3) . . ?
C6 C5 H5 120.5 . . ?
C4 C5 H5 120.5 . . ?
O1 C6 C5 122.8(2) . . ?
O1 C6 C1 115.7(2) . . ?
C5 C6 C1 121.4(2) . . ?
C12 C7 C8 121.9(3) . . ?
C12 C7 O1 121.7(2) . . ?
C8 C7 O1 116.1(2) . . ?
C7 C8 C9 118.3(2) . . ?
C7 C8 P2 118.2(2) . . ?
C9 C8 P2 123.3(2) . . ?
C10 C9 C8 120.5(3) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C9 C10 C11 119.9(3) . . ?
C9 C10 H10 120.0 . . ?
C11 C10 H10 120.0 . . ?
C12 C11 C10 120.9(3) . . ?
C12 C11 H11 119.6 . . ?
C10 C11 H11 119.6 . . ?
C11 C12 C7 118.5(3) . . ?
C11 C12 H12 120.8 . . ?
C7 C12 H12 120.8 . . ?
C6 O1 C7 119.3(2) . . ?
C18 C13 C14 118.2(2) . . ?
C18 C13 P3 118.6(2) . . ?
C14 C13 P3 122.9(2) . . ?
C15 C14 C13 120.4(3) . . ?
C15 C14 H14 119.8 . . ?
C13 C14 H14 119.8 . . ?
C16 C15 C14 119.8(3) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C15 C16 C17 120.8(3) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C18 C17 C16 118.6(3) . . ?
C18 C17 H17 120.7 . . ?
C16 C17 H17 120.7 . . ?
C17 C18 C13 121.8(2) . . ?
C17 C18 O2 121.9(2) . . ?
C13 C18 O2 116.2(2) . . ?
C24 C19 C20 122.1(2) . . ?
C24 C19 O2 120.3(2) . . ?
C20 C19 O2 117.5(2) . . ?
C19 C20 C21 118.1(2) . . ?
C19 C20 P4 119.0(2) . . ?
C21 C20 P4 122.9(2) . . ?
C22 C21 C20 120.3(3) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 120.1(3) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 H22 119.9 . . ?
C24 C23 C22 120.7(3) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C23 C24 C19 118.6(3) . . ?
C23 C24 H24 120.7 . . ?
C19 C24 H24 120.7 . . ?
C19 O2 C18 116.9(2) . . ?
C2A C1A C6A 119.6(2) . . ?
C2A C1A P1 120.3(2) . . ?
C6A C1A P1 119.9(2) . . ?
C3A C2A C1A 120.2(3) . . ?
C3A C2A H2A 119.9 . . ?
C1A C2A H2A 119.9 . . ?
C4A C3A C2A 120.0(3) . . ?
C4A C3A H3A 120.0 . . ?
C2A C3A H3A 120.0 . . ?
C3A C4A C5A 119.7(3) . . ?
C3A C4A H4A 120.1 . . ?
C5A C4A H4A 120.1 . . ?
C6A C5A C4A 121.0(3) . . ?
C6A C5A H5A 119.5 . . ?
C4A C5A H5A 119.5 . . ?
C5A C6A C1A 119.3(3) . . ?
C5A C6A H6A 120.3 . . ?
C1A C6A H6A 120.3 . . ?
C2B C1B C6B 120.3(3) . . ?
C2B C1B P1 118.0(2) . . ?
C6B C1B P1 121.7(2) . . ?
C3B C2B C1B 120.2(3) . . ?
C3B C2B H2B 119.9 . . ?
C1B C2B H2B 119.9 . . ?
C2B C3B C4B 119.3(3) . . ?
C2B C3B H3B 120.4 . . ?
C4B C3B H3B 120.4 . . ?
C5B C4B C3B 120.7(3) . . ?
C5B C4B H4B 119.7 . . ?
C3B C4B H4B 119.7 . . ?
C4B C5B C6B 120.1(3) . . ?
C4B C5B H5B 120.0 . . ?
C6B C5B H5B 120.0 . . ?
C1B C6B C5B 119.4(3) . . ?
C1B C6B H6B 120.3 . . ?
C5B C6B H6B 120.3 . . ?
C2C C1C C6C 119.5(3) . . ?
C2C C1C P2 121.3(2) . . ?
C6C C1C P2 119.2(2) . . ?
C3C C2C C1C 120.2(3) . . ?
C3C C2C H2C 119.9 . . ?
C1C C2C H2C 119.9 . . ?
C4C C3C C2C 119.8(3) . . ?
C4C C3C H3C 120.1 . . ?
C2C C3C H3C 120.1 . . ?
C3C C4C C5C 120.7(3) . . ?
C3C C4C H4C 119.6 . . ?
C5C C4C H4C 119.6 . . ?
C4C C5C C6C 119.6(3) . . ?
C4C C5C H5C 120.2 . . ?
C6C C5C H5C 120.2 . . ?
C5C C6C C1C 120.2(3) . . ?
C5C C6C H6C 119.9 . . ?
C1C C6C H6C 119.9 . . ?
C2D C1D C6D 119.8(3) . . ?
C2D C1D P2 117.0(2) . . ?
C6D C1D P2 122.8(2) . . ?
C3D C2D C1D 119.6(3) . . ?
C3D C2D H2D 120.2 . . ?
C1D C2D H2D 120.2 . . ?
C4D C3D C2D 120.7(3) . . ?
C4D C3D H3D 119.7 . . ?
C2D C3D H3D 119.7 . . ?
C3D C4D C5D 119.9(3) . . ?
C3D C4D H4D 120.1 . . ?
C5D C4D H4D 120.1 . . ?
C4D C5D C6D 120.5(3) . . ?
C4D C5D H5D 119.7 . . ?
C6D C5D H5D 119.7 . . ?
C5D C6D C1D 119.5(3) . . ?
C5D C6D H6D 120.2 . . ?
C1D C6D H6D 120.2 . . ?
C6E C1E C2E 119.7(3) . . ?
C6E C1E P3 121.1(2) . . ?
C2E C1E P3 119.2(2) . . ?
C3E C2E C1E 119.8(3) . . ?
C3E C2E H2E 120.1 . . ?
C1E C2E H2E 120.1 . . ?
C2E C3E C4E 120.2(3) . . ?
C2E C3E H3E 119.9 . . ?
C4E C3E H3E 119.9 . . ?
C5E C4E C3E 120.2(3) . . ?
C5E C4E H4E 119.9 . . ?
C3E C4E H4E 119.9 . . ?
C4E C5E C6E 120.0(3) . . ?
C4E C5E H5E 120.0 . . ?
C6E C5E H5E 120.0 . . ?
C5E C6E C1E 120.1(3) . . ?
C5E C6E H6E 119.9 . . ?
C1E C6E H6E 119.9 . . ?
C2F C1F C6F 119.3(2) . . ?
C2F C1F P3 123.0(2) . . ?
C6F C1F P3 117.4(2) . . ?
C3F C2F C1F 119.6(3) . . ?
C3F C2F H2F 120.2 . . ?
C1F C2F H2F 120.2 . . ?
C4F C3F C2F 120.5(3) . . ?
C4F C3F H3F 119.7 . . ?
C2F C3F H3F 119.7 . . ?
C3F C4F C5F 120.6(3) . . ?
C3F C4F H4F 119.7 . . ?
C5F C4F H4F 119.7 . . ?
C4F C5F C6F 119.3(3) . . ?
C4F C5F H5F 120.4 . . ?
C6F C5F H5F 120.4 . . ?
C5F C6F C1F 120.6(3) . . ?
C5F C6F H6F 119.7 . . ?
C1F C6F H6F 119.7 . . ?
C6G C1G C2G 119.6(3) . . ?
C6G C1G P4 120.1(2) . . ?
C2G C1G P4 120.2(2) . . ?
C3G C2G C1G 119.8(3) . . ?
C3G C2G H2G 120.1 . . ?
C1G C2G H2G 120.1 . . ?
C2G C3G C4G 120.5(3) . . ?
C2G C3G H3G 119.8 . . ?
C4G C3G H3G 119.8 . . ?
C5G C4G C3G 120.0(3) . . ?
C5G C4G H4G 120.0 . . ?
C3G C4G H4G 120.0 . . ?
C4G C5G C6G 120.0(3) . . ?
C4G C5G H5G 120.0 . . ?
C6G C5G H5G 120.0 . . ?
C1G C6G C5G 120.2(3) . . ?
C1G C6G H6G 119.9 . . ?
C5G C6G H6G 119.9 . . ?
C6H C1H C2H 119.8(3) . . ?
C6H C1H P4 120.1(2) . . ?
C2H C1H P4 119.7(2) . . ?
C3H C2H C1H 119.8(3) . . ?
C3H C2H H2H 120.1 . . ?
C1H C2H H2H 120.1 . . ?
C4H C3H C2H 120.2(3) . . ?
C4H C3H H3H 119.9 . . ?
C2H C3H H3H 119.9 . . ?
C3H C4H C5H 120.4(3) . . ?
C3H C4H H4H 119.8 . . ?
C5H C4H H4H 119.8 . . ?
C4H C5H C6H 120.0(3) . . ?
C4H C5H H5H 120.0 . . ?
C6H C5H H5H 120.0 . . ?
C5H C6H C1H 119.8(3) . . ?
C5H C6H H6H 120.1 . . ?
C1H C6H H6H 120.1 . . ?
O5 N1 O3 120.6(3) . . ?
O5 N1 O4 120.1(3) . . ?
O3 N1 O4 119.2(3) . . ?
O7 N2 O6 120.4(3) . . ?
O7 N2 O8 119.1(3) . . ?
O6 N2 O8 120.6(3) . . ?
Cl2 C25 Cl1 111.68(19) . . ?
Cl2 C25 H25A 109.3 . . ?
Cl1 C25 H25A 109.3 . . ?
Cl2 C25 H25B 109.3 . . ?
Cl1 C25 H25B 109.3 . . ?
H25A C25 H25B 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1B P1 C1 C2 -127.3(2) . . . . ?
C1A P1 C1 C2 -14.9(3) . . . . ?
Au1 P1 C1 C2 104.6(2) . . . . ?
C1B P1 C1 C6 58.9(2) . . . . ?
C1A P1 C1 C6 171.3(2) . . . . ?
Au1 P1 C1 C6 -69.2(2) . . . . ?
C6 C1 C2 C3 0.8(4) . . . . ?
P1 C1 C2 C3 -173.1(2) . . . . ?
C1 C2 C3 C4 1.3(4) . . . . ?
C2 C3 C4 C5 -1.8(4) . . . . ?
C3 C4 C5 C6 0.0(4) . . . . ?
C4 C5 C6 O1 178.0(2) . . . . ?
C4 C5 C6 C1 2.3(4) . . . . ?
C2 C1 C6 O1 -178.7(2) . . . . ?
P1 C1 C6 O1 -4.6(3) . . . . ?
C2 C1 C6 C5 -2.7(4) . . . . ?
P1 C1 C6 C5 171.4(2) . . . . ?
C12 C7 C8 C9 -2.2(4) . . . . ?
O1 C7 C8 C9 -175.4(2) . . . . ?
C12 C7 C8 P2 172.6(2) . . . . ?
O1 C7 C8 P2 -0.7(3) . . . . ?
C1D P2 C8 C7 -82.3(2) . . . . ?
C1C P2 C8 C7 167.7(2) . . . . ?
Au2 P2 C8 C7 47.6(2) . . . . ?
C1D P2 C8 C9 92.1(3) . . . . ?
C1C P2 C8 C9 -17.8(3) . . . . ?
Au2 P2 C8 C9 -137.9(2) . . . . ?
C7 C8 C9 C10 2.2(4) . . . . ?
P2 C8 C9 C10 -172.3(2) . . . . ?
C8 C9 C10 C11 -0.4(4) . . . . ?
C9 C10 C11 C12 -1.6(5) . . . . ?
C10 C11 C12 C7 1.6(4) . . . . ?
C8 C7 C12 C11 0.3(4) . . . . ?
O1 C7 C12 C11 173.2(3) . . . . ?
C5 C6 O1 C7 33.3(3) . . . . ?
C1 C6 O1 C7 -150.7(2) . . . . ?
C12 C7 O1 C6 45.3(4) . . . . ?
C8 C7 O1 C6 -141.4(2) . . . . ?
C1E P3 C13 C18 64.0(2) . . . . ?
C1F P3 C13 C18 177.0(2) . . . . ?
Au1 P3 C13 C18 -64.9(2) . . . . ?
C1E P3 C13 C14 -120.9(2) . . . . ?
C1F P3 C13 C14 -7.9(3) . . . . ?
Au1 P3 C13 C14 110.2(2) . . . . ?
C18 C13 C14 C15 2.2(4) . . . . ?
P3 C13 C14 C15 -172.9(2) . . . . ?
C13 C14 C15 C16 2.3(4) . . . . ?
C14 C15 C16 C17 -3.8(4) . . . . ?
C15 C16 C17 C18 0.7(4) . . . . ?
C16 C17 C18 C13 4.1(4) . . . . ?
C16 C17 C18 O2 -178.6(2) . . . . ?
C14 C13 C18 C17 -5.5(4) . . . . ?
P3 C13 C18 C17 169.8(2) . . . . ?
C14 C13 C18 O2 177.1(2) . . . . ?
P3 C13 C18 O2 -7.6(3) . . . . ?
C24 C19 C20 C21 0.7(4) . . . . ?
O2 C19 C20 C21 -177.3(2) . . . . ?
C24 C19 C20 P4 178.1(2) . . . . ?
O2 C19 C20 P4 0.0(3) . . . . ?
C1G P4 C20 C19 -94.1(2) . . . . ?
C1H P4 C20 C19 153.1(2) . . . . ?
Au2 P4 C20 C19 37.0(2) . . . . ?
C1G P4 C20 C21 83.1(2) . . . . ?
C1H P4 C20 C21 -29.7(3) . . . . ?
Au2 P4 C20 C21 -145.8(2) . . . . ?
C19 C20 C21 C22 -1.4(4) . . . . ?
P4 C20 C21 C22 -178.6(2) . . . . ?
C20 C21 C22 C23 0.9(4) . . . . ?
C21 C22 C23 C24 0.3(4) . . . . ?
C22 C23 C24 C19 -1.0(4) . . . . ?
C20 C19 C24 C23 0.5(4) . . . . ?
O2 C19 C24 C23 178.5(2) . . . . ?
C24 C19 O2 C18 42.3(3) . . . . ?
C20 C19 O2 C18 -139.6(2) . . . . ?
C17 C18 O2 C19 39.7(3) . . . . ?
C13 C18 O2 C19 -142.8(2) . . . . ?
C1B P1 C1A C2A -140.0(2) . . . . ?
C1 P1 C1A C2A 106.6(2) . . . . ?
Au1 P1 C1A C2A -16.5(2) . . . . ?
C1B P1 C1A C6A 44.3(2) . . . . ?
C1 P1 C1A C6A -69.1(2) . . . . ?
Au1 P1 C1A C6A 167.81(19) . . . . ?
C6A C1A C2A C3A 2.1(4) . . . . ?
P1 C1A C2A C3A -173.7(2) . . . . ?
C1A C2A C3A C4A 0.5(4) . . . . ?
C2A C3A C4A C5A -2.8(5) . . . . ?
C3A C4A C5A C6A 2.6(5) . . . . ?
C4A C5A C6A C1A -0.1(4) . . . . ?
C2A C1A C6A C5A -2.2(4) . . . . ?
P1 C1A C6A C5A 173.5(2) . . . . ?
C1A P1 C1B C2B 82.7(2) . . . . ?
C1 P1 C1B C2B -166.7(2) . . . . ?
Au1 P1 C1B C2B -38.0(2) . . . . ?
C1A P1 C1B C6B -95.1(2) . . . . ?
C1 P1 C1B C6B 15.5(3) . . . . ?
Au1 P1 C1B C6B 144.2(2) . . . . ?
C6B C1B C2B C3B -0.2(4) . . . . ?
P1 C1B C2B C3B -178.0(2) . . . . ?
C1B C2B C3B C4B -2.0(4) . . . . ?
C2B C3B C4B C5B 1.9(4) . . . . ?
C3B C4B C5B C6B 0.4(4) . . . . ?
C2B C1B C6B C5B 2.5(4) . . . . ?
P1 C1B C6B C5B -179.8(2) . . . . ?
C4B C5B C6B C1B -2.5(4) . . . . ?
C8 P2 C1C C2C 88.4(3) . . . . ?
C1D P2 C1C C2C -21.6(3) . . . . ?
Au2 P2 C1C C2C -152.2(2) . . . . ?
C8 P2 C1C C6C -94.4(2) . . . . ?
C1D P2 C1C C6C 155.6(2) . . . . ?
Au2 P2 C1C C6C 24.9(2) . . . . ?
C6C C1C C2C C3C -1.2(5) . . . . ?
P2 C1C C2C C3C 175.9(2) . . . . ?
C1C C2C C3C C4C 2.2(5) . . . . ?
C2C C3C C4C C5C -1.3(5) . . . . ?
C3C C4C C5C C6C -0.6(5) . . . . ?
C4C C5C C6C C1C 1.6(5) . . . . ?
C2C C1C C6C C5C -0.7(4) . . . . ?
P2 C1C C6C C5C -177.9(2) . . . . ?
C8 P2 C1D C2D 179.1(2) . . . . ?
C1C P2 C1D C2D -67.6(2) . . . . ?
Au2 P2 C1D C2D 56.5(2) . . . . ?
C8 P2 C1D C6D -8.4(3) . . . . ?
C1C P2 C1D C6D 104.9(2) . . . . ?
Au2 P2 C1D C6D -131.0(2) . . . . ?
C6D C1D C2D C3D -0.8(4) . . . . ?
P2 C1D C2D C3D 171.9(2) . . . . ?
C1D C2D C3D C4D 0.0(5) . . . . ?
C2D C3D C4D C5D 1.1(5) . . . . ?
C3D C4D C5D C6D -1.2(4) . . . . ?
C4D C5D C6D C1D 0.4(4) . . . . ?
C2D C1D C6D C5D 0.7(4) . . . . ?
P2 C1D C6D C5D -171.7(2) . . . . ?
C1F P3 C1E C6E 111.0(2) . . . . ?
C13 P3 C1E C6E -139.8(2) . . . . ?
Au1 P3 C1E C6E -10.2(3) . . . . ?
C1F P3 C1E C2E -69.3(2) . . . . ?
C13 P3 C1E C2E 39.8(3) . . . . ?
Au1 P3 C1E C2E 169.46(19) . . . . ?
C6E C1E C2E C3E -2.5(4) . . . . ?
P3 C1E C2E C3E 177.8(2) . . . . ?
C1E C2E C3E C4E 1.1(4) . . . . ?
C2E C3E C4E C5E 1.6(4) . . . . ?
C3E C4E C5E C6E -2.8(4) . . . . ?
C4E C5E C6E C1E 1.4(4) . . . . ?
C2E C1E C6E C5E 1.3(4) . . . . ?
P3 C1E C6E C5E -179.0(2) . . . . ?
C1E P3 C1F C2F 18.7(3) . . . . ?
C13 P3 C1F C2F -92.0(2) . . . . ?
Au1 P3 C1F C2F 144.3(2) . . . . ?
C1E P3 C1F C6F -168.3(2) . . . . ?
C13 P3 C1F C6F 81.0(2) . . . . ?
Au1 P3 C1F C6F -42.8(2) . . . . ?
C6F C1F C2F C3F -1.6(4) . . . . ?
P3 C1F C2F C3F 171.2(2) . . . . ?
C1F C2F C3F C4F -0.8(4) . . . . ?
C2F C3F C4F C5F 2.0(4) . . . . ?
C3F C4F C5F C6F -0.7(4) . . . . ?
C4F C5F C6F C1F -1.7(4) . . . . ?
C2F C1F C6F C5F 2.8(4) . . . . ?
P3 C1F C6F C5F -170.4(2) . . . . ?
C20 P4 C1G C6G 120.3(2) . . . . ?
C1H P4 C1G C6G -127.7(2) . . . . ?
Au2 P4 C1G C6G -5.0(3) . . . . ?
C20 P4 C1G C2G -55.9(2) . . . . ?
C1H P4 C1G C2G 56.1(2) . . . . ?
Au2 P4 C1G C2G 178.82(18) . . . . ?
C6G C1G C2G C3G -1.6(4) . . . . ?
P4 C1G C2G C3G 174.6(2) . . . . ?
C1G C2G C3G C4G -0.1(4) . . . . ?
C2G C3G C4G C5G 1.7(4) . . . . ?
C3G C4G C5G C6G -1.5(4) . . . . ?
C2G C1G C6G C5G 1.8(4) . . . . ?
P4 C1G C6G C5G -174.4(2) . . . . ?
C4G C5G C6G C1G -0.3(4) . . . . ?
C20 P4 C1H C6H 142.4(2) . . . . ?
C1G P4 C1H C6H 31.8(2) . . . . ?
Au2 P4 C1H C6H -98.9(2) . . . . ?
C20 P4 C1H C2H -44.5(2) . . . . ?
C1G P4 C1H C2H -155.1(2) . . . . ?
Au2 P4 C1H C2H 74.2(2) . . . . ?
C6H C1H C2H C3H -1.8(4) . . . . ?
P4 C1H C2H C3H -174.9(2) . . . . ?
C1H C2H C3H C4H 0.7(4) . . . . ?
C2H C3H C4H C5H 0.3(4) . . . . ?
C3H C4H C5H C6H -0.1(4) . . . . ?
C4H C5H C6H C1H -1.1(4) . . . . ?
C2H C1H C6H C5H 2.1(4) . . . . ?
P4 C1H C6H C5H 175.1(2) . . . . ?

_refine_diff_density_max         0.672
_refine_diff_density_min         -0.650
_refine_diff_density_rms         0.111



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_2
_database_code_depnum_ccdc_archive 'CCDC 1472199'
_audit_update_record             
;
2016-09-19 deposited with the CCDC.
2016-10-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(C F3 O3 S), C H2 Cl2'
_chemical_formula_sum            'C75 H58 Au2 Cl2 F6 O8 P4 S2'
_chemical_formula_weight         1854.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   22.275(3)
_cell_length_b                   16.505(2)
_cell_length_c                   19.910(3)
_cell_angle_alpha                90
_cell_angle_beta                 105.095(2)
_cell_angle_gamma                90
_cell_volume                     7067.5(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9612
_cell_measurement_theta_max      28.093
_cell_measurement_theta_min      2.260

_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_description       prism
_exptl_crystal_F_000             3640
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.150
_exptl_absorpt_coefficient_mu    4.444
_shelx_estimated_absorpt_T_min   0.441
_shelx_estimated_absorpt_T_max   0.555
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6810
_exptl_absorpt_correction_type   multi-scan


_exptl_absorpt_process_details   
;
SADABS-2014/4 (Bruker,2014) was used for absorption correction.

;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            83647
_diffrn_reflns_av_unetI/netI     0.0387
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.947
_diffrn_reflns_theta_max         28.307
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             17549
_reflns_number_gt                13962
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0353P)²+27.1266P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17549
_refine_ls_number_parameters     896
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0513
_refine_ls_R_factor_gt           0.0336
_refine_ls_wR_factor_ref         0.0846
_refine_ls_wR_factor_gt          0.0752
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.28673(2) 0.35217(2) 0.20447(2) 0.01650(4) Uani 1 1 d . . . . .
Au2 Au 0.23699(2) 0.45060(2) 0.35171(2) 0.01652(4) Uani 1 1 d . . . . .
P1 P 0.25721(5) 0.46258(6) 0.12963(6) 0.0161(2) Uani 1 1 d . . . . .
P2 P 0.13045(5) 0.44049(7) 0.30699(6) 0.0187(2) Uani 1 1 d . . . . .
P3 P 0.31465(5) 0.22431(6) 0.25330(6) 0.0150(2) Uani 1 1 d . . . . .
P4 P 0.34047(5) 0.46918(6) 0.41033(6) 0.0148(2) Uani 1 1 d . . . . .
C1 C 0.26222(19) 0.5653(2) 0.1635(2) 0.0157(8) Uani 1 1 d . . . . .
C2 C 0.3070(2) 0.6202(3) 0.1538(2) 0.0195(9) Uani 1 1 d . . . . .
H2 H 0.3342 0.6051 0.1262 0.023 Uiso 1 1 calc R U . . .
C3 C 0.3122(2) 0.6960(3) 0.1838(2) 0.0238(10) Uani 1 1 d . . . . .
H3 H 0.3424 0.7329 0.1760 0.029 Uiso 1 1 calc R U . . .
C4 C 0.2741(2) 0.7188(3) 0.2249(3) 0.0270(10) Uani 1 1 d . . . . .
H4 H 0.2790 0.7705 0.2467 0.032 Uiso 1 1 calc R U . . .
C5 C 0.2283(2) 0.6663(3) 0.2346(2) 0.0241(10) Uani 1 1 d . . . . .
H5 H 0.2016 0.6820 0.2626 0.029 Uiso 1 1 calc R U . . .
C6 C 0.2221(2) 0.5911(3) 0.2032(2) 0.0207(9) Uani 1 1 d . . . . .
C7 C 0.1199(2) 0.5675(3) 0.2152(2) 0.0219(9) Uani 1 1 d . . . . .
C8 C 0.09341(19) 0.5308(3) 0.2630(2) 0.0205(9) Uani 1 1 d . . . . .
C9 C 0.0360(2) 0.5585(3) 0.2692(3) 0.0312(11) Uani 1 1 d . . . . .
H9 H 0.0175 0.5347 0.3024 0.037 Uiso 1 1 calc R U . . .
C10 C 0.0059(2) 0.6212(3) 0.2270(3) 0.0360(13) Uani 1 1 d . . . . .
H10 H -0.0333 0.6401 0.2311 0.043 Uiso 1 1 calc R U . . .
C11 C 0.0327(2) 0.6555(3) 0.1795(3) 0.0358(13) Uani 1 1 d . . . . .
H11 H 0.0118 0.6982 0.1509 0.043 Uiso 1 1 calc R U . . .
C12 C 0.0903(2) 0.6291(3) 0.1719(3) 0.0316(11) Uani 1 1 d . . . . .
H12 H 0.1084 0.6527 0.1383 0.038 Uiso 1 1 calc R U . . .
O1 O 0.17660(14) 0.53581(18) 0.20936(17) 0.0212(7) Uani 1 1 d . . . . .
C13 C 0.27117(18) 0.1917(2) 0.3146(2) 0.0150(8) Uani 1 1 d . . . . .
C14 C 0.22725(19) 0.1291(3) 0.2996(2) 0.0185(9) Uani 1 1 d . . . . .
H14 H 0.2227 0.0979 0.2585 0.022 Uiso 1 1 calc R U . . .
C15 C 0.1904(2) 0.1123(3) 0.3443(2) 0.0238(10) Uani 1 1 d . . . . .
H15 H 0.1612 0.0693 0.3341 0.029 Uiso 1 1 calc R U . . .
C16 C 0.1963(2) 0.1586(3) 0.4041(2) 0.0267(10) Uani 1 1 d . . . . .
H16 H 0.1698 0.1484 0.4337 0.032 Uiso 1 1 calc R U . . .
C17 C 0.2406(2) 0.2197(3) 0.4207(2) 0.0233(9) Uani 1 1 d . . . . .
H17 H 0.2451 0.2507 0.4619 0.028 Uiso 1 1 calc R U . . .
C18 C 0.27817(19) 0.2347(2) 0.3765(2) 0.0167(8) Uani 1 1 d . . . . .
C19 C 0.3567(2) 0.3104(3) 0.4565(2) 0.0174(8) Uani 1 1 d . . . . .
C20 C 0.36959(19) 0.3909(2) 0.4743(2) 0.0155(8) Uani 1 1 d . . . . .
C21 C 0.4063(2) 0.4080(3) 0.5414(2) 0.0215(9) Uani 1 1 d . . . . .
H21 H 0.4158 0.4627 0.5550 0.026 Uiso 1 1 calc R U . . .
C22 C 0.4290(2) 0.3463(3) 0.5883(2) 0.0243(10) Uani 1 1 d . . . . .
H22 H 0.4533 0.3588 0.6339 0.029 Uiso 1 1 calc R U . . .
C23 C 0.4162(2) 0.2659(3) 0.5686(2) 0.0252(10) Uani 1 1 d . . . . .
H23 H 0.4327 0.2235 0.6003 0.030 Uiso 1 1 calc R U . . .
C24 C 0.3794(2) 0.2476(3) 0.5028(2) 0.0237(9) Uani 1 1 d . . . . .
H24 H 0.3697 0.1929 0.4894 0.028 Uiso 1 1 calc R U . . .
O2 O 0.32229(14) 0.29572(17) 0.38807(15) 0.0185(6) Uani 1 1 d . . . . .
C1A C 0.3091(2) 0.4656(2) 0.0727(2) 0.0179(9) Uani 1 1 d . . . . .
C2A C 0.3723(2) 0.4487(3) 0.1013(2) 0.0179(8) Uani 1 1 d . . . . .
H2A H 0.3863 0.4287 0.1475 0.022 Uiso 1 1 calc R U . . .
C3A C 0.4147(2) 0.4616(3) 0.0616(3) 0.0228(9) Uani 1 1 d . . . . .
H3A H 0.4578 0.4519 0.0812 0.027 Uiso 1 1 calc R U . . .
C4A C 0.3938(2) 0.4885(3) -0.0067(3) 0.0264(10) Uani 1 1 d . . . . .
H4A H 0.4227 0.4972 -0.0336 0.032 Uiso 1 1 calc R U . . .
C5A C 0.3315(2) 0.5028(3) -0.0356(2) 0.0281(11) Uani 1 1 d . . . . .
H5A H 0.3176 0.5205 -0.0825 0.034 Uiso 1 1 calc R U . . .
C6A C 0.2887(2) 0.4914(3) 0.0037(2) 0.0245(10) Uani 1 1 d . . . . .
H6A H 0.2458 0.5011 -0.0164 0.029 Uiso 1 1 calc R U . . .
C1B C 0.17853(19) 0.4538(3) 0.0740(2) 0.0194(9) Uani 1 1 d . . . . .
C2B C 0.1480(2) 0.3797(3) 0.0663(3) 0.0249(10) Uani 1 1 d . . . . .
H2B H 0.1675 0.3342 0.0923 0.030 Uiso 1 1 calc R U . . .
C3B C 0.0894(2) 0.3715(4) 0.0210(3) 0.0356(13) Uani 1 1 d . . . . .
H3B H 0.0688 0.3206 0.0158 0.043 Uiso 1 1 calc R U . . .
C4B C 0.0611(2) 0.4378(4) -0.0163(3) 0.0390(14) Uani 1 1 d . . . . .
H4B H 0.0214 0.4320 -0.0483 0.047 Uiso 1 1 calc R U . . .
C5B C 0.0899(2) 0.5122(4) -0.0078(3) 0.0397(13) Uani 1 1 d . . . . .
H5B H 0.0694 0.5579 -0.0325 0.048 Uiso 1 1 calc R U . . .
C6B C 0.1492(2) 0.5205(3) 0.0373(3) 0.0294(11) Uani 1 1 d . . . . .
H6B H 0.1694 0.5717 0.0427 0.035 Uiso 1 1 calc R U . . .
C1C C 0.0942(2) 0.4248(3) 0.3775(2) 0.0239(10) Uani 1 1 d . . . . .
C2C C 0.0574(3) 0.3585(3) 0.3809(3) 0.0363(13) Uani 1 1 d . . . . .
H2C H 0.0501 0.3186 0.3453 0.044 Uiso 1 1 calc R U . . .
C3C C 0.0308(3) 0.3503(4) 0.4373(3) 0.0432(14) Uani 1 1 d . . . . .
H3C H 0.0057 0.3045 0.4400 0.052 Uiso 1 1 calc R U . . .
C4C C 0.0411(3) 0.4079(4) 0.4882(3) 0.0381(13) Uani 1 1 d . . . . .
H4C H 0.0226 0.4024 0.5258 0.046 Uiso 1 1 calc R U . . .
C5C C 0.0784(2) 0.4746(4) 0.4854(3) 0.0337(12) Uani 1 1 d . . . . .
H5C H 0.0857 0.5143 0.5212 0.040 Uiso 1 1 calc R U . . .
C6C C 0.1049(2) 0.4827(3) 0.4301(3) 0.0287(11) Uani 1 1 d . . . . .
H6C H 0.1305 0.5282 0.4280 0.034 Uiso 1 1 calc R U . . .
C1D C 0.1015(2) 0.3623(3) 0.2436(2) 0.0243(10) Uani 1 1 d . . . . .
C2D C 0.1380(2) 0.2958(3) 0.2389(2) 0.0220(9) Uani 1 1 d . . . . .
H2D H 0.1788 0.2919 0.2689 0.026 Uiso 1 1 calc R U . . .
C3D C 0.1156(2) 0.2345(3) 0.1908(2) 0.0244(10) Uani 1 1 d . . . . .
H3D H 0.1412 0.1893 0.1877 0.029 Uiso 1 1 calc R U . . .
C4D C 0.0564(2) 0.2397(3) 0.1478(3) 0.0375(13) Uani 1 1 d . . . . .
H4D H 0.0408 0.1978 0.1152 0.045 Uiso 1 1 calc R U . . .
C5D C 0.0198(3) 0.3058(5) 0.1520(5) 0.078(3) Uani 1 1 d . . . . .
H5D H -0.0211 0.3093 0.1223 0.094 Uiso 1 1 calc R U . . .
C6D C 0.0420(3) 0.3667(4) 0.1991(4) 0.064(2) Uani 1 1 d . . . . .
H6D H 0.0165 0.4122 0.2013 0.076 Uiso 1 1 calc R U . . .
C1E C 0.39567(19) 0.2071(2) 0.2966(2) 0.0163(8) Uani 1 1 d . . . . .
C2E C 0.41259(19) 0.1527(3) 0.3517(2) 0.0201(9) Uani 1 1 d . . . . .
H2E H 0.3814 0.1273 0.3691 0.024 Uiso 1 1 calc R U . . .
C3E C 0.4749(2) 0.1355(3) 0.3813(2) 0.0234(9) Uani 1 1 d . . . . .
H3E H 0.4865 0.0992 0.4195 0.028 Uiso 1 1 calc R U . . .
C4E C 0.5199(2) 0.1715(3) 0.3549(3) 0.0235(10) Uani 1 1 d . . . . .
H4E H 0.5624 0.1582 0.3741 0.028 Uiso 1 1 calc R U . . .
C5E C 0.5035(2) 0.2268(3) 0.3005(3) 0.0255(10) Uani 1 1 d . . . . .
H5E H 0.5348 0.2522 0.2834 0.031 Uiso 1 1 calc R U . . .
C6E C 0.4411(2) 0.2449(3) 0.2712(2) 0.0213(9) Uani 1 1 d . . . . .
H6E H 0.4296 0.2827 0.2341 0.026 Uiso 1 1 calc R U . . .
C1F C 0.29443(19) 0.1484(3) 0.1850(2) 0.0172(8) Uani 1 1 d . . . . .
C2F C 0.3161(2) 0.0690(3) 0.1980(2) 0.0220(9) Uani 1 1 d . . . . .
H2F H 0.3468 0.0561 0.2396 0.026 Uiso 1 1 calc R U . . .
C3F C 0.2924(2) 0.0090(3) 0.1493(3) 0.0256(10) Uani 1 1 d . . . . .
H3F H 0.3075 -0.0449 0.1574 0.031 Uiso 1 1 calc R U . . .
C4F C 0.2470(2) 0.0271(3) 0.0892(3) 0.0280(11) Uani 1 1 d . . . . .
H4F H 0.2295 -0.0147 0.0573 0.034 Uiso 1 1 calc R U . . .
C5F C 0.2271(2) 0.1061(3) 0.0755(2) 0.0270(10) Uani 1 1 d . . . . .
H5F H 0.1969 0.1188 0.0335 0.032 Uiso 1 1 calc R U . . .
C6F C 0.2511(2) 0.1672(3) 0.1231(2) 0.0229(9) Uani 1 1 d . . . . .
H6F H 0.2378 0.2217 0.1132 0.027 Uiso 1 1 calc R U . . .
C1G C 0.39525(19) 0.4760(3) 0.3577(2) 0.0172(8) Uani 1 1 d . . . . .
C2G C 0.4464(2) 0.4239(3) 0.3660(2) 0.0214(9) Uani 1 1 d . . . . .
H2G H 0.4509 0.3789 0.3966 0.026 Uiso 1 1 calc R U . . .
C3G C 0.4907(2) 0.4387(3) 0.3290(3) 0.0263(10) Uani 1 1 d . . . . .
H3G H 0.5257 0.4040 0.3348 0.032 Uiso 1 1 calc R U . . .
C4G C 0.4836(2) 0.5035(3) 0.2840(2) 0.0227(9) Uani 1 1 d . . . . .
H4G H 0.5139 0.5133 0.2590 0.027 Uiso 1 1 calc R U . . .
C5G C 0.4329(2) 0.5543(3) 0.2750(2) 0.0243(10) Uani 1 1 d . . . . .
H5G H 0.4285 0.5989 0.2440 0.029 Uiso 1 1 calc R U . . .
C6G C 0.3882(2) 0.5404(3) 0.3112(2) 0.0217(9) Uani 1 1 d . . . . .
H6G H 0.3529 0.5749 0.3041 0.026 Uiso 1 1 calc R U . . .
C1H C 0.35158(19) 0.5630(3) 0.4589(2) 0.0168(8) Uani 1 1 d . . . . .
C2H C 0.3029(2) 0.5952(3) 0.4811(3) 0.0256(10) Uani 1 1 d . . . . .
H2H H 0.2630 0.5706 0.4671 0.031 Uiso 1 1 calc R U . . .
C3H C 0.3116(2) 0.6626(3) 0.5233(3) 0.0370(13) Uani 1 1 d . . . . .
H3H H 0.2784 0.6828 0.5404 0.044 Uiso 1 1 calc R U . . .
C4H C 0.3688(2) 0.7005(3) 0.5408(3) 0.0337(12) Uani 1 1 d . . . . .
H4H H 0.3746 0.7479 0.5689 0.040 Uiso 1 1 calc R U . . .
C5H C 0.4177(2) 0.6700(3) 0.5177(2) 0.0240(10) Uani 1 1 d . . . . .
H5H H 0.4568 0.6967 0.5295 0.029 Uiso 1 1 calc R U . . .
C6H C 0.40975(19) 0.6006(3) 0.4775(2) 0.0187(9) Uani 1 1 d . . . . .
H6H H 0.4436 0.5787 0.4626 0.022 Uiso 1 1 calc R U . . .
C25 C 0.4035(3) 0.8130(3) 0.3732(3) 0.0312(11) Uani 1 1 d . . . . .
F1 F 0.43873(18) 0.82745(19) 0.43765(15) 0.0443(8) Uani 1 1 d . . . . .
F2 F 0.41120(18) 0.73633(17) 0.35727(16) 0.0453(9) Uani 1 1 d . . . . .
F3 F 0.34425(17) 0.8218(2) 0.37468(18) 0.0490(9) Uani 1 1 d . . . . .
S1 S 0.42421(5) 0.88182(7) 0.31130(6) 0.0220(2) Uani 1 1 d . . . . .
O3 O 0.41398(17) 0.96079(19) 0.33736(18) 0.0295(8) Uani 1 1 d . . . . .
O4 O 0.48878(16) 0.8616(2) 0.31829(18) 0.0316(8) Uani 1 1 d . . . . .
O5 O 0.38268(16) 0.8603(2) 0.24499(17) 0.0272(7) Uani 1 1 d . . . . .
C26 C -0.1649(3) 0.2671(4) 0.0548(3) 0.0397(3) Uani 1 1 d D . . . .
F4 F -0.13277(18) 0.3254(3) 0.0924(2) 0.0679(12) Uani 1 1 d . . . . .
F5 F -0.1890(2) 0.2199(3) 0.0932(2) 0.0800(15) Uani 1 1 d . . . . .
F6 F -0.2095(5) 0.2997(5) -0.0038(7) 0.342(10) Uani 1 1 d D . . . .
S2 S -0.12744(7) 0.21851(9) -0.00245(8) 0.0397(3) Uani 1 1 d . . . . .
O6 O -0.0955(5) 0.2698(5) -0.0298(4) 0.147(4) Uani 1 1 d . . . . .
O7 O -0.0733(3) 0.1800(4) 0.0561(4) 0.113(3) Uani 1 1 d . . . . .
O8 O -0.1627(2) 0.1513(3) -0.0319(3) 0.0647(14) Uani 1 1 d . . . . .
C27 C 0.1428(5) 0.5940(5) 0.6832(4) 0.076(3) Uani 1 1 d . . . A 1
H27A H 0.1884 0.5883 0.6917 0.091 Uiso 1 1 calc R U . A 1
H27B H 0.1273 0.6237 0.6388 0.091 Uiso 1 1 calc R U . A 1
Cl1 Cl 0.10906(7) 0.49670(10) 0.67454(8) 0.0468(4) Uani 1 1 d . . . A 1
Cl2A Cl 0.1277(3) 0.6483(2) 0.7472(3) 0.102(2) Uani 0.725(10) 1 d . . P A 1
Cl2B Cl 0.1914(10) 0.6062(8) 0.7720(5) 0.132(10) Uani 0.275(10) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3374(11) . ?
Au1 P3 2.3389(11) . ?
Au2 P2 2.3135(11) . ?
Au2 P4 2.3169(11) . ?
P1 C1 1.817(4) . ?
P1 C1A 1.818(4) . ?
P1 C1B 1.819(4) . ?
P2 C1D 1.804(5) . ?
P2 C1C 1.811(5) . ?
P2 C8 1.814(5) . ?
P3 C1E 1.808(4) . ?
P3 C1F 1.817(4) . ?
P3 C13 1.825(4) . ?
P4 C1G 1.808(4) . ?
P4 C1H 1.809(4) . ?
P4 C20 1.812(4) . ?
C1 C2 1.398(6) . ?
C1 C6 1.405(6) . ?
C2 C3 1.378(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.377(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.389(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.381(6) . ?
C5 H5 0.9500 . ?
C6 O1 1.393(5) . ?
C7 C8 1.383(7) . ?
C7 C12 1.384(7) . ?
C7 O1 1.400(5) . ?
C8 C9 1.394(6) . ?
C9 C10 1.390(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.367(8) . ?
C10 H10 0.9500 . ?
C11 C12 1.398(7) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.395(6) . ?
C13 C14 1.400(6) . ?
C14 C15 1.386(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.393(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.388(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.387(6) . ?
C17 H17 0.9500 . ?
C18 O2 1.384(5) . ?
C19 C20 1.386(6) . ?
C19 C24 1.392(6) . ?
C19 O2 1.399(5) . ?
C20 C21 1.402(6) . ?
C21 C22 1.385(6) . ?
C21 H21 0.9500 . ?
C22 C23 1.393(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.386(6) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C1A C6A 1.396(6) . ?
C1A C2A 1.403(6) . ?
C2A C3A 1.397(6) . ?
C2A H2A 0.9500 . ?
C3A C4A 1.391(7) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.376(7) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.395(7) . ?
C5A H5A 0.9500 . ?
C6A H6A 0.9500 . ?
C1B C6B 1.387(7) . ?
C1B C2B 1.388(6) . ?
C2B C3B 1.388(7) . ?
C2B H2B 0.9500 . ?
C3B C4B 1.379(8) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.375(8) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.397(7) . ?
C5B H5B 0.9500 . ?
C6B H6B 0.9500 . ?
C1C C2C 1.379(7) . ?
C1C C6C 1.392(7) . ?
C2C C3C 1.405(8) . ?
C2C H2C 0.9500 . ?
C3C C4C 1.365(9) . ?
C3C H3C 0.9500 . ?
C4C C5C 1.387(8) . ?
C4C H4C 0.9500 . ?
C5C C6C 1.386(7) . ?
C5C H5C 0.9500 . ?
C6C H6C 0.9500 . ?
C1D C2D 1.384(6) . ?
C1D C6D 1.389(7) . ?
C2D C3D 1.393(6) . ?
C2D H2D 0.9500 . ?
C3D C4D 1.375(7) . ?
C3D H3D 0.9500 . ?
C4D C5D 1.378(8) . ?
C4D H4D 0.9500 . ?
C5D C6D 1.376(8) . ?
C5D H5D 0.9500 . ?
C6D H6D 0.9500 . ?
C1E C6E 1.390(6) . ?
C1E C2E 1.392(6) . ?
C2E C3E 1.388(6) . ?
C2E H2E 0.9500 . ?
C3E C4E 1.382(7) . ?
C3E H3E 0.9500 . ?
C4E C5E 1.390(7) . ?
C4E H4E 0.9500 . ?
C5E C6E 1.394(6) . ?
C5E H5E 0.9500 . ?
C6E H6E 0.9500 . ?
C1F C6F 1.390(6) . ?
C1F C2F 1.397(6) . ?
C2F C3F 1.389(6) . ?
C2F H2F 0.9500 . ?
C3F C4F 1.385(7) . ?
C3F H3F 0.9500 . ?
C4F C5F 1.381(7) . ?
C4F H4F 0.9500 . ?
C5F C6F 1.391(6) . ?
C5F H5F 0.9500 . ?
C6F H6F 0.9500 . ?
C1G C6G 1.392(6) . ?
C1G C2G 1.402(6) . ?
C2G C3G 1.399(6) . ?
C2G H2G 0.9500 . ?
C3G C4G 1.377(7) . ?
C3G H3G 0.9500 . ?
C4G C5G 1.380(7) . ?
C4G H4G 0.9500 . ?
C5G C6G 1.392(6) . ?
C5G H5G 0.9500 . ?
C6G H6G 0.9500 . ?
C1H C2H 1.379(6) . ?
C1H C6H 1.397(6) . ?
C2H C3H 1.377(7) . ?
C2H H2H 0.9500 . ?
C3H C4H 1.381(7) . ?
C3H H3H 0.9500 . ?
C4H C5H 1.383(7) . ?
C4H H4H 0.9500 . ?
C5H C6H 1.382(6) . ?
C5H H5H 0.9500 . ?
C6H H6H 0.9500 . ?
C25 F2 1.326(6) . ?
C25 F3 1.337(6) . ?
C25 F1 1.340(6) . ?
C25 S1 1.821(5) . ?
S1 O3 1.443(3) . ?
S1 O5 1.445(3) . ?
S1 O4 1.448(4) . ?
C26 F5 1.301(7) . ?
C26 F4 1.312(6) . ?
C26 F6 1.426(8) . ?
C26 S2 1.771(6) . ?
S2 O6 1.311(6) . ?
S2 O8 1.397(4) . ?
S2 O7 1.576(7) . ?
C27 Cl2A 1.664(8) . ?
C27 Cl1 1.763(8) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P3 165.62(4) . . ?
P2 Au2 P4 171.77(4) . . ?
C1 P1 C1A 102.61(19) . . ?
C1 P1 C1B 104.8(2) . . ?
C1A P1 C1B 106.9(2) . . ?
C1 P1 Au1 120.73(14) . . ?
C1A P1 Au1 107.44(14) . . ?
C1B P1 Au1 113.13(15) . . ?
C1D P2 C1C 106.8(2) . . ?
C1D P2 C8 102.4(2) . . ?
C1C P2 C8 104.7(2) . . ?
C1D P2 Au2 117.74(15) . . ?
C1C P2 Au2 109.34(15) . . ?
C8 P2 Au2 114.74(15) . . ?
C1E P3 C1F 105.72(19) . . ?
C1E P3 C13 105.80(19) . . ?
C1F P3 C13 103.02(19) . . ?
C1E P3 Au1 117.64(14) . . ?
C1F P3 Au1 108.91(15) . . ?
C13 P3 Au1 114.45(14) . . ?
C1G P4 C1H 103.7(2) . . ?
C1G P4 C20 106.27(19) . . ?
C1H P4 C20 105.12(19) . . ?
C1G P4 Au2 116.71(14) . . ?
C1H P4 Au2 111.24(14) . . ?
C20 P4 Au2 112.77(14) . . ?
C2 C1 C6 117.6(4) . . ?
C2 C1 P1 122.1(3) . . ?
C6 C1 P1 120.3(3) . . ?
C3 C2 C1 120.7(4) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C4 C3 C2 120.7(4) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C3 C4 C5 120.0(4) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C6 C5 C4 119.3(4) . . ?
C6 C5 H5 120.4 . . ?
C4 C5 H5 120.4 . . ?
C5 C6 O1 122.6(4) . . ?
C5 C6 C1 121.6(4) . . ?
O1 C6 C1 115.8(4) . . ?
C8 C7 C12 122.1(4) . . ?
C8 C7 O1 116.7(4) . . ?
C12 C7 O1 121.2(4) . . ?
C7 C8 C9 118.8(4) . . ?
C7 C8 P2 118.1(3) . . ?
C9 C8 P2 122.6(4) . . ?
C10 C9 C8 120.0(5) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C11 C10 C9 119.8(5) . . ?
C11 C10 H10 120.1 . . ?
C9 C10 H10 120.1 . . ?
C10 C11 C12 121.7(5) . . ?
C10 C11 H11 119.2 . . ?
C12 C11 H11 119.2 . . ?
C7 C12 C11 117.6(5) . . ?
C7 C12 H12 121.2 . . ?
C11 C12 H12 121.2 . . ?
C6 O1 C7 117.1(3) . . ?
C18 C13 C14 118.3(4) . . ?
C18 C13 P3 118.9(3) . . ?
C14 C13 P3 122.6(3) . . ?
C15 C14 C13 120.6(4) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C14 C15 C16 120.0(4) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C17 C16 C15 120.3(4) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C18 C17 C16 119.2(4) . . ?
C18 C17 H17 120.4 . . ?
C16 C17 H17 120.4 . . ?
O2 C18 C17 123.0(4) . . ?
O2 C18 C13 115.4(4) . . ?
C17 C18 C13 121.5(4) . . ?
C20 C19 C24 122.0(4) . . ?
C20 C19 O2 116.1(4) . . ?
C24 C19 O2 121.8(4) . . ?
C19 C20 C21 117.9(4) . . ?
C19 C20 P4 119.4(3) . . ?
C21 C20 P4 122.7(3) . . ?
C22 C21 C20 120.9(4) . . ?
C22 C21 H21 119.5 . . ?
C20 C21 H21 119.5 . . ?
C21 C22 C23 119.9(4) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C24 C23 C22 120.2(4) . . ?
C24 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C23 C24 C19 119.1(4) . . ?
C23 C24 H24 120.4 . . ?
C19 C24 H24 120.4 . . ?
C18 O2 C19 118.3(3) . . ?
C6A C1A C2A 119.7(4) . . ?
C6A C1A P1 121.7(3) . . ?
C2A C1A P1 118.4(3) . . ?
C3A C2A C1A 119.7(4) . . ?
C3A C2A H2A 120.2 . . ?
C1A C2A H2A 120.2 . . ?
C4A C3A C2A 119.9(4) . . ?
C4A C3A H3A 120.1 . . ?
C2A C3A H3A 120.1 . . ?
C5A C4A C3A 120.5(4) . . ?
C5A C4A H4A 119.7 . . ?
C3A C4A H4A 119.7 . . ?
C4A C5A C6A 120.2(4) . . ?
C4A C5A H5A 119.9 . . ?
C6A C5A H5A 119.9 . . ?
C5A C6A C1A 120.0(4) . . ?
C5A C6A H6A 120.0 . . ?
C1A C6A H6A 120.0 . . ?
C6B C1B C2B 119.4(4) . . ?
C6B C1B P1 120.3(3) . . ?
C2B C1B P1 120.2(3) . . ?
C1B C2B C3B 120.6(5) . . ?
C1B C2B H2B 119.7 . . ?
C3B C2B H2B 119.7 . . ?
C4B C3B C2B 119.6(5) . . ?
C4B C3B H3B 120.2 . . ?
C2B C3B H3B 120.2 . . ?
C5B C4B C3B 120.6(5) . . ?
C5B C4B H4B 119.7 . . ?
C3B C4B H4B 119.7 . . ?
C4B C5B C6B 120.0(5) . . ?
C4B C5B H5B 120.0 . . ?
C6B C5B H5B 120.0 . . ?
C1B C6B C5B 119.8(5) . . ?
C1B C6B H6B 120.1 . . ?
C5B C6B H6B 120.1 . . ?
C2C C1C C6C 119.6(5) . . ?
C2C C1C P2 122.9(4) . . ?
C6C C1C P2 117.5(4) . . ?
C1C C2C C3C 119.7(5) . . ?
C1C C2C H2C 120.1 . . ?
C3C C2C H2C 120.1 . . ?
C4C C3C C2C 120.1(5) . . ?
C4C C3C H3C 120.0 . . ?
C2C C3C H3C 120.0 . . ?
C3C C4C C5C 120.7(5) . . ?
C3C C4C H4C 119.7 . . ?
C5C C4C H4C 119.7 . . ?
C6C C5C C4C 119.4(5) . . ?
C6C C5C H5C 120.3 . . ?
C4C C5C H5C 120.3 . . ?
C5C C6C C1C 120.5(5) . . ?
C5C C6C H6C 119.8 . . ?
C1C C6C H6C 119.8 . . ?
C2D C1D C6D 118.6(4) . . ?
C2D C1D P2 120.3(3) . . ?
C6D C1D P2 121.1(4) . . ?
C1D C2D C3D 120.7(4) . . ?
C1D C2D H2D 119.7 . . ?
C3D C2D H2D 119.7 . . ?
C4D C3D C2D 119.7(4) . . ?
C4D C3D H3D 120.1 . . ?
C2D C3D H3D 120.1 . . ?
C3D C4D C5D 119.9(5) . . ?
C3D C4D H4D 120.0 . . ?
C5D C4D H4D 120.0 . . ?
C6D C5D C4D 120.4(5) . . ?
C6D C5D H5D 119.8 . . ?
C4D C5D H5D 119.8 . . ?
C5D C6D C1D 120.6(5) . . ?
C5D C6D H6D 119.7 . . ?
C1D C6D H6D 119.7 . . ?
C6E C1E C2E 120.2(4) . . ?
C6E C1E P3 119.1(3) . . ?
C2E C1E P3 120.6(3) . . ?
C3E C2E C1E 120.1(4) . . ?
C3E C2E H2E 119.9 . . ?
C1E C2E H2E 119.9 . . ?
C4E C3E C2E 119.7(4) . . ?
C4E C3E H3E 120.2 . . ?
C2E C3E H3E 120.2 . . ?
C3E C4E C5E 120.6(4) . . ?
C3E C4E H4E 119.7 . . ?
C5E C4E H4E 119.7 . . ?
C4E C5E C6E 119.9(4) . . ?
C4E C5E H5E 120.1 . . ?
C6E C5E H5E 120.1 . . ?
C1E C6E C5E 119.5(4) . . ?
C1E C6E H6E 120.2 . . ?
C5E C6E H6E 120.2 . . ?
C6F C1F C2F 120.0(4) . . ?
C6F C1F P3 119.3(3) . . ?
C2F C1F P3 120.2(3) . . ?
C3F C2F C1F 119.3(4) . . ?
C3F C2F H2F 120.3 . . ?
C1F C2F H2F 120.3 . . ?
C4F C3F C2F 120.5(4) . . ?
C4F C3F H3F 119.7 . . ?
C2F C3F H3F 119.7 . . ?
C5F C4F C3F 119.9(4) . . ?
C5F C4F H4F 120.0 . . ?
C3F C4F H4F 120.0 . . ?
C4F C5F C6F 120.3(4) . . ?
C4F C5F H5F 119.9 . . ?
C6F C5F H5F 119.9 . . ?
C1F C6F C5F 119.8(4) . . ?
C1F C6F H6F 120.1 . . ?
C5F C6F H6F 120.1 . . ?
C6G C1G C2G 119.7(4) . . ?
C6G C1G P4 117.2(3) . . ?
C2G C1G P4 122.9(3) . . ?
C3G C2G C1G 119.5(4) . . ?
C3G C2G H2G 120.2 . . ?
C1G C2G H2G 120.2 . . ?
C4G C3G C2G 120.1(4) . . ?
C4G C3G H3G 119.9 . . ?
C2G C3G H3G 119.9 . . ?
C3G C4G C5G 120.5(4) . . ?
C3G C4G H4G 119.7 . . ?
C5G C4G H4G 119.7 . . ?
C4G C5G C6G 120.3(4) . . ?
C4G C5G H5G 119.9 . . ?
C6G C5G H5G 119.9 . . ?
C1G C6G C5G 119.9(4) . . ?
C1G C6G H6G 120.1 . . ?
C5G C6G H6G 120.1 . . ?
C2H C1H C6H 119.8(4) . . ?
C2H C1H P4 119.4(3) . . ?
C6H C1H P4 120.7(3) . . ?
C3H C2H C1H 120.6(4) . . ?
C3H C2H H2H 119.7 . . ?
C1H C2H H2H 119.7 . . ?
C2H C3H C4H 119.6(5) . . ?
C2H C3H H3H 120.2 . . ?
C4H C3H H3H 120.2 . . ?
C3H C4H C5H 120.4(5) . . ?
C3H C4H H4H 119.8 . . ?
C5H C4H H4H 119.8 . . ?
C6H C5H C4H 120.2(4) . . ?
C6H C5H H5H 119.9 . . ?
C4H C5H H5H 119.9 . . ?
C5H C6H C1H 119.4(4) . . ?
C5H C6H H6H 120.3 . . ?
C1H C6H H6H 120.3 . . ?
F2 C25 F3 107.4(4) . . ?
F2 C25 F1 108.6(4) . . ?
F3 C25 F1 107.1(4) . . ?
F2 C25 S1 111.3(4) . . ?
F3 C25 S1 111.8(4) . . ?
F1 C25 S1 110.4(3) . . ?
O3 S1 O5 115.3(2) . . ?
O3 S1 O4 114.8(2) . . ?
O5 S1 O4 114.5(2) . . ?
O3 S1 C25 103.2(2) . . ?
O5 S1 C25 104.5(2) . . ?
O4 S1 C25 102.2(2) . . ?
F5 C26 F4 110.5(5) . . ?
F5 C26 F6 113.6(7) . . ?
F4 C26 F6 110.6(6) . . ?
F5 C26 S2 116.2(4) . . ?
F4 C26 S2 114.9(4) . . ?
F6 C26 S2 89.4(8) . . ?
O6 S2 O8 130.2(4) . . ?
O6 S2 O7 100.1(6) . . ?
O8 S2 O7 103.2(3) . . ?
O6 S2 C26 111.8(4) . . ?
O8 S2 C26 108.8(3) . . ?
O7 S2 C26 96.0(4) . . ?
Cl2A C27 Cl1 113.5(4) . . ?
Cl2A C27 H27A 108.9 . . ?
Cl1 C27 H27A 108.9 . . ?
Cl2A C27 H27B 108.9 . . ?
Cl1 C27 H27B 108.9 . . ?
H27A C27 H27B 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1A P1 C1 C2 -11.0(4) . . . . ?
C1B P1 C1 C2 -122.5(4) . . . . ?
Au1 P1 C1 C2 108.4(3) . . . . ?
C1A P1 C1 C6 171.6(3) . . . . ?
C1B P1 C1 C6 60.0(4) . . . . ?
Au1 P1 C1 C6 -69.0(4) . . . . ?
C6 C1 C2 C3 1.6(6) . . . . ?
P1 C1 C2 C3 -175.9(3) . . . . ?
C1 C2 C3 C4 1.1(7) . . . . ?
C2 C3 C4 C5 -2.2(7) . . . . ?
C3 C4 C5 C6 0.6(7) . . . . ?
C4 C5 C6 O1 -178.8(4) . . . . ?
C4 C5 C6 C1 2.2(7) . . . . ?
C2 C1 C6 C5 -3.3(6) . . . . ?
P1 C1 C6 C5 174.3(3) . . . . ?
C2 C1 C6 O1 177.6(4) . . . . ?
P1 C1 C6 O1 -4.8(5) . . . . ?
C12 C7 C8 C9 -2.1(7) . . . . ?
O1 C7 C8 C9 -178.1(4) . . . . ?
C12 C7 C8 P2 170.4(4) . . . . ?
O1 C7 C8 P2 -5.6(5) . . . . ?
C1D P2 C8 C7 -81.3(4) . . . . ?
C1C P2 C8 C7 167.3(4) . . . . ?
Au2 P2 C8 C7 47.5(4) . . . . ?
C1D P2 C8 C9 90.9(4) . . . . ?
C1C P2 C8 C9 -20.5(5) . . . . ?
Au2 P2 C8 C9 -140.3(4) . . . . ?
C7 C8 C9 C10 1.1(7) . . . . ?
P2 C8 C9 C10 -171.0(4) . . . . ?
C8 C9 C10 C11 -0.1(8) . . . . ?
C9 C10 C11 C12 0.0(8) . . . . ?
C8 C7 C12 C11 1.9(7) . . . . ?
O1 C7 C12 C11 177.8(4) . . . . ?
C10 C11 C12 C7 -0.9(8) . . . . ?
C5 C6 O1 C7 32.6(6) . . . . ?
C1 C6 O1 C7 -148.3(4) . . . . ?
C8 C7 O1 C6 -138.3(4) . . . . ?
C12 C7 O1 C6 45.6(6) . . . . ?
C1E P3 C13 C18 66.1(4) . . . . ?
C1F P3 C13 C18 176.8(3) . . . . ?
Au1 P3 C13 C18 -65.1(3) . . . . ?
C1E P3 C13 C14 -119.1(4) . . . . ?
C1F P3 C13 C14 -8.4(4) . . . . ?
Au1 P3 C13 C14 109.7(3) . . . . ?
C18 C13 C14 C15 2.0(6) . . . . ?
P3 C13 C14 C15 -172.8(3) . . . . ?
C13 C14 C15 C16 0.9(7) . . . . ?
C14 C15 C16 C17 -2.5(7) . . . . ?
C15 C16 C17 C18 1.0(7) . . . . ?
C16 C17 C18 O2 178.2(4) . . . . ?
C16 C17 C18 C13 2.0(7) . . . . ?
C14 C13 C18 O2 -180.0(4) . . . . ?
P3 C13 C18 O2 -5.0(5) . . . . ?
C14 C13 C18 C17 -3.5(6) . . . . ?
P3 C13 C18 C17 171.5(3) . . . . ?
C24 C19 C20 C21 -0.3(6) . . . . ?
O2 C19 C20 C21 -177.3(4) . . . . ?
C24 C19 C20 P4 178.1(3) . . . . ?
O2 C19 C20 P4 1.2(5) . . . . ?
C1G P4 C20 C19 -83.1(4) . . . . ?
C1H P4 C20 C19 167.4(3) . . . . ?
Au2 P4 C20 C19 46.0(4) . . . . ?
C1G P4 C20 C21 95.3(4) . . . . ?
C1H P4 C20 C21 -14.3(4) . . . . ?
Au2 P4 C20 C21 -135.7(3) . . . . ?
C19 C20 C21 C22 0.0(7) . . . . ?
P4 C20 C21 C22 -178.4(4) . . . . ?
C20 C21 C22 C23 1.0(7) . . . . ?
C21 C22 C23 C24 -1.7(7) . . . . ?
C22 C23 C24 C19 1.4(7) . . . . ?
C20 C19 C24 C23 -0.4(7) . . . . ?
O2 C19 C24 C23 176.4(4) . . . . ?
C17 C18 O2 C19 38.7(6) . . . . ?
C13 C18 O2 C19 -145.0(4) . . . . ?
C20 C19 O2 C18 -141.9(4) . . . . ?
C24 C19 O2 C18 41.2(6) . . . . ?
C1 P1 C1A C6A -85.7(4) . . . . ?
C1B P1 C1A C6A 24.3(4) . . . . ?
Au1 P1 C1A C6A 146.0(3) . . . . ?
C1 P1 C1A C2A 88.1(4) . . . . ?
C1B P1 C1A C2A -161.8(3) . . . . ?
Au1 P1 C1A C2A -40.1(4) . . . . ?
C6A C1A C2A C3A 3.0(6) . . . . ?
P1 C1A C2A C3A -171.0(3) . . . . ?
C1A C2A C3A C4A -2.0(6) . . . . ?
C2A C3A C4A C5A 0.1(7) . . . . ?
C3A C4A C5A C6A 0.8(7) . . . . ?
C4A C5A C6A C1A 0.2(7) . . . . ?
C2A C1A C6A C5A -2.1(7) . . . . ?
P1 C1A C6A C5A 171.7(4) . . . . ?
C1 P1 C1B C6B 33.1(4) . . . . ?
C1A P1 C1B C6B -75.4(4) . . . . ?
Au1 P1 C1B C6B 166.5(3) . . . . ?
C1 P1 C1B C2B -148.9(4) . . . . ?
C1A P1 C1B C2B 102.7(4) . . . . ?
Au1 P1 C1B C2B -15.4(4) . . . . ?
C6B C1B C2B C3B 1.7(7) . . . . ?
P1 C1B C2B C3B -176.4(4) . . . . ?
C1B C2B C3B C4B -0.4(8) . . . . ?
C2B C3B C4B C5B -1.6(8) . . . . ?
C3B C4B C5B C6B 2.3(9) . . . . ?
C2B C1B C6B C5B -1.0(8) . . . . ?
P1 C1B C6B C5B 177.1(4) . . . . ?
C4B C5B C6B C1B -0.9(9) . . . . ?
C1D P2 C1C C2C 6.3(5) . . . . ?
C8 P2 C1C C2C 114.4(4) . . . . ?
Au2 P2 C1C C2C -122.2(4) . . . . ?
C1D P2 C1C C6C -174.0(4) . . . . ?
C8 P2 C1C C6C -65.8(4) . . . . ?
Au2 P2 C1C C6C 57.6(4) . . . . ?
C6C C1C C2C C3C 0.2(8) . . . . ?
P2 C1C C2C C3C 180.0(4) . . . . ?
C1C C2C C3C C4C 0.4(9) . . . . ?
C2C C3C C4C C5C -0.8(9) . . . . ?
C3C C4C C5C C6C 0.5(8) . . . . ?
C4C C5C C6C C1C 0.1(7) . . . . ?
C2C C1C C6C C5C -0.5(7) . . . . ?
P2 C1C C6C C5C 179.8(4) . . . . ?
C1C P2 C1D C2D -102.6(4) . . . . ?
C8 P2 C1D C2D 147.6(4) . . . . ?
Au2 P2 C1D C2D 20.7(5) . . . . ?
C1C P2 C1D C6D 76.5(6) . . . . ?
C8 P2 C1D C6D -33.2(6) . . . . ?
Au2 P2 C1D C6D -160.1(5) . . . . ?
C6D C1D C2D C3D -0.1(8) . . . . ?
P2 C1D C2D C3D 179.1(4) . . . . ?
C1D C2D C3D C4D -0.5(8) . . . . ?
C2D C3D C4D C5D 0.6(9) . . . . ?
C3D C4D C5D C6D 0.0(13) . . . . ?
C4D C5D C6D C1D -0.7(14) . . . . ?
C2D C1D C6D C5D 0.7(12) . . . . ?
P2 C1D C6D C5D -178.5(7) . . . . ?
C1F P3 C1E C6E 87.8(4) . . . . ?
C13 P3 C1E C6E -163.4(3) . . . . ?
Au1 P3 C1E C6E -34.1(4) . . . . ?
C1F P3 C1E C2E -87.9(4) . . . . ?
C13 P3 C1E C2E 20.9(4) . . . . ?
Au1 P3 C1E C2E 150.2(3) . . . . ?
C6E C1E C2E C3E -0.4(7) . . . . ?
P3 C1E C2E C3E 175.3(3) . . . . ?
C1E C2E C3E C4E -1.2(7) . . . . ?
C2E C3E C4E C5E 2.2(7) . . . . ?
C3E C4E C5E C6E -1.5(7) . . . . ?
C2E C1E C6E C5E 1.1(7) . . . . ?
P3 C1E C6E C5E -174.7(3) . . . . ?
C4E C5E C6E C1E -0.1(7) . . . . ?
C1E P3 C1F C6F -146.8(4) . . . . ?
C13 P3 C1F C6F 102.4(4) . . . . ?
Au1 P3 C1F C6F -19.5(4) . . . . ?
C1E P3 C1F C2F 41.3(4) . . . . ?
C13 P3 C1F C2F -69.5(4) . . . . ?
Au1 P3 C1F C2F 168.6(3) . . . . ?
C6F C1F C2F C3F -2.0(7) . . . . ?
P3 C1F C2F C3F 169.8(3) . . . . ?
C1F C2F C3F C4F -1.1(7) . . . . ?
C2F C3F C4F C5F 3.2(7) . . . . ?
C3F C4F C5F C6F -2.1(7) . . . . ?
C2F C1F C6F C5F 3.1(7) . . . . ?
P3 C1F C6F C5F -168.8(4) . . . . ?
C4F C5F C6F C1F -1.1(7) . . . . ?
C1H P4 C1G C6G -60.0(4) . . . . ?
C20 P4 C1G C6G -170.6(3) . . . . ?
Au2 P4 C1G C6G 62.7(4) . . . . ?
C1H P4 C1G C2G 114.6(4) . . . . ?
C20 P4 C1G C2G 4.0(4) . . . . ?
Au2 P4 C1G C2G -122.7(3) . . . . ?
C6G C1G C2G C3G 1.8(7) . . . . ?
P4 C1G C2G C3G -172.6(4) . . . . ?
C1G C2G C3G C4G -0.8(7) . . . . ?
C2G C3G C4G C5G -0.1(7) . . . . ?
C3G C4G C5G C6G -0.2(7) . . . . ?
C2G C1G C6G C5G -2.1(7) . . . . ?
P4 C1G C6G C5G 172.7(3) . . . . ?
C4G C5G C6G C1G 1.3(7) . . . . ?
C1G P4 C1H C2H 152.6(4) . . . . ?
C20 P4 C1H C2H -96.0(4) . . . . ?
Au2 P4 C1H C2H 26.3(4) . . . . ?
C1G P4 C1H C6H -31.2(4) . . . . ?
C20 P4 C1H C6H 80.2(4) . . . . ?
Au2 P4 C1H C6H -157.4(3) . . . . ?
C6H C1H C2H C3H -2.1(7) . . . . ?
P4 C1H C2H C3H 174.2(4) . . . . ?
C1H C2H C3H C4H 3.1(9) . . . . ?
C2H C3H C4H C5H -1.8(9) . . . . ?
C3H C4H C5H C6H -0.7(8) . . . . ?
C4H C5H C6H C1H 1.7(7) . . . . ?
C2H C1H C6H C5H -0.3(7) . . . . ?
P4 C1H C6H C5H -176.6(3) . . . . ?
F2 C25 S1 O3 -179.1(4) . . . . ?
F3 C25 S1 O3 60.7(4) . . . . ?
F1 C25 S1 O3 -58.4(4) . . . . ?
F2 C25 S1 O5 59.9(4) . . . . ?
F3 C25 S1 O5 -60.2(4) . . . . ?
F1 C25 S1 O5 -179.4(4) . . . . ?
F2 C25 S1 O4 -59.7(4) . . . . ?
F3 C25 S1 O4 -179.8(3) . . . . ?
F1 C25 S1 O4 61.0(4) . . . . ?
F5 C26 S2 O6 -168.9(7) . . . . ?
F4 C26 S2 O6 -37.6(8) . . . . ?
F6 C26 S2 O6 74.9(6) . . . . ?
F5 C26 S2 O8 40.7(6) . . . . ?
F4 C26 S2 O8 171.9(5) . . . . ?
F6 C26 S2 O8 -75.6(5) . . . . ?
F5 C26 S2 O7 -65.5(5) . . . . ?
F4 C26 S2 O7 65.8(5) . . . . ?
F6 C26 S2 O7 178.3(4) . . . . ?

_refine_diff_density_max         3.223
_refine_diff_density_min         -3.025
_refine_diff_density_rms         0.139



#############################################################################
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_3
_database_code_depnum_ccdc_archive 'CCDC 1472200'
_audit_update_record             
;
2016-09-19 deposited with the CCDC.
2016-10-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(B F4), C H2 Cl2'
_chemical_formula_sum            'C73 H58 Au2 B2 Cl2 F8 O2 P4'
_chemical_formula_weight         1729.52

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   21.8263(18)
_cell_length_b                   16.0732(13)
_cell_length_c                   19.7116(16)
_cell_angle_alpha                90
_cell_angle_beta                 106.692(3)
_cell_angle_gamma                90
_cell_volume                     6623.8(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    7122
_cell_measurement_theta_max      22.378
_cell_measurement_theta_min      2.158

_exptl_crystal_description       block
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.734
_exptl_crystal_F_000             3384
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.310
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.180
_exptl_absorpt_coefficient_mu    4.672
_exptl_absorpt_correction_T_max  0.7448
_exptl_absorpt_correction_T_min  0.6393
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/4 (Bruker,2014/4) was used for absorption correction. 
wR2(int)was 0.0757 before and 0.0591 after correction. 
The Ratio of minimum to maximum 
transmission is 0.8584. 
The λ/2 correction factor is 0.00150.
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            54561
_diffrn_reflns_av_unetI/netI     0.0571
_diffrn_reflns_av_R_equivalents  0.0788
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         0.974
_diffrn_reflns_theta_max         22.765
_diffrn_reflns_theta_full        22.765
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             8922
_reflns_number_gt                6813
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0329P)²+20.0009P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8922
_refine_ls_number_parameters     839
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0596
_refine_ls_R_factor_gt           0.0363
_refine_ls_wR_factor_ref         0.0791
_refine_ls_wR_factor_gt          0.0716
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.21963(2) 0.35268(2) 0.30668(2) 0.01323(9) Uani 1 1 d . . . . .
Au2 Au 0.26694(2) 0.44708(2) 0.16706(2) 0.01486(9) Uani 1 1 d . . . . .
P1 P 0.24549(9) 0.46528(12) 0.38434(10) 0.0130(5) Uani 1 1 d . . . . .
P2 P 0.37726(9) 0.43870(12) 0.20839(10) 0.0139(5) Uani 1 1 d . . . . .
P3 P 0.19236(9) 0.22206(12) 0.25515(10) 0.0127(5) Uani 1 1 d . . . . .
P4 P 0.16198(9) 0.47225(12) 0.10266(10) 0.0132(5) Uani 1 1 d . . . . .
C1 C 0.2366(3) 0.5687(4) 0.3477(4) 0.0149(18) Uani 1 1 d . . . . .
C2 C 0.1894(3) 0.6252(5) 0.3548(4) 0.0195(19) Uani 1 1 d . . . . .
H2 H 0.1634 0.6115 0.3845 0.023 Uiso 1 1 calc R U . . .
C3 C 0.1803(3) 0.7003(5) 0.3191(4) 0.020(2) Uani 1 1 d . . . . .
H3 H 0.1502 0.7392 0.3268 0.024 Uiso 1 1 calc R U . . .
C4 C 0.2147(4) 0.7190(5) 0.2724(4) 0.022(2) Uani 1 1 d . . . . .
H4 H 0.2058 0.7686 0.2452 0.026 Uiso 1 1 calc R U . . .
C5 C 0.2622(4) 0.6660(5) 0.2650(4) 0.0188(19) Uani 1 1 d . . . . .
H5 H 0.2863 0.6792 0.2333 0.023 Uiso 1 1 calc R U . . .
C6 C 0.2741(3) 0.5934(5) 0.3043(4) 0.0145(18) Uani 1 1 d . . . . .
C1A C 0.1910(4) 0.4659(4) 0.4385(4) 0.0165(19) Uani 1 1 d . . . . .
C2A C 0.1265(3) 0.4466(4) 0.4056(4) 0.0163(18) Uani 1 1 d . . . . .
H1A H 0.1143 0.4254 0.3586 0.020 Uiso 1 1 calc R U . . .
C3A C 0.0805(4) 0.4579(5) 0.4403(4) 0.021(2) Uani 1 1 d . . . . .
H3A H 0.0369 0.4458 0.4172 0.026 Uiso 1 1 calc R U . . .
C4A C 0.0987(4) 0.4870(5) 0.5086(4) 0.022(2) Uani 1 1 d . . . . .
H4A H 0.0670 0.4961 0.5323 0.027 Uiso 1 1 calc R U . . .
C5A C 0.1623(4) 0.5035(5) 0.5439(4) 0.021(2) Uani 1 1 d . . . . .
H5A H 0.1744 0.5215 0.5918 0.025 Uiso 1 1 calc R U . . .
C6A C 0.2080(4) 0.4934(5) 0.5079(4) 0.0204(19) Uani 1 1 d . . . . .
H6A H 0.2516 0.5055 0.5313 0.024 Uiso 1 1 calc R U . . .
C1B C 0.3261(3) 0.4600(5) 0.4427(4) 0.0128(18) Uani 1 1 d . . . . .
C2B C 0.3517(4) 0.5285(5) 0.4848(4) 0.024(2) Uani 1 1 d . . . . .
H2B H 0.3271 0.5778 0.4821 0.029 Uiso 1 1 calc R U . . .
C3B C 0.4134(4) 0.5244(6) 0.5309(4) 0.028(2) Uani 1 1 d . . . . .
H3B H 0.4304 0.5706 0.5604 0.034 Uiso 1 1 calc R U . . .
C4B C 0.4495(4) 0.4549(6) 0.5340(4) 0.031(2) Uani 1 1 d . . . . .
H4B H 0.4913 0.4524 0.5661 0.037 Uiso 1 1 calc R U . . .
C5B C 0.4257(4) 0.3876(5) 0.4905(4) 0.023(2) Uani 1 1 d . . . . .
H5B H 0.4516 0.3398 0.4919 0.028 Uiso 1 1 calc R U . . .
C6B C 0.3642(4) 0.3897(5) 0.4450(4) 0.0165(19) Uani 1 1 d . . . . .
H6B H 0.3479 0.3434 0.4154 0.020 Uiso 1 1 calc R U . . .
C1C C 0.4072(3) 0.4324(5) 0.1318(4) 0.0134(18) Uani 1 1 d . . . . .
C2C C 0.4011(4) 0.5012(5) 0.0869(4) 0.020(2) Uani 1 1 d . . . . .
H2C H 0.3841 0.5518 0.0988 0.024 Uiso 1 1 calc R U . . .
C3C C 0.4194(4) 0.4966(5) 0.0259(4) 0.020(2) Uani 1 1 d . . . . .
H3C H 0.4161 0.5440 -0.0037 0.024 Uiso 1 1 calc R U . . .
C4C C 0.4427(4) 0.4224(5) 0.0078(4) 0.029(2) Uani 1 1 d . . . . .
H4C H 0.4548 0.4190 -0.0346 0.035 Uiso 1 1 calc R U . . .
C5C C 0.4484(4) 0.3540(5) 0.0501(4) 0.026(2) Uani 1 1 d . . . . .
H5C H 0.4651 0.3037 0.0374 0.031 Uiso 1 1 calc R U . . .
C6C C 0.4298(4) 0.3579(5) 0.1124(4) 0.0215(19) Uani 1 1 d . . . . .
H6C H 0.4325 0.3099 0.1412 0.026 Uiso 1 1 calc R U . . .
C1D C 0.4151(3) 0.3554(5) 0.2681(4) 0.0127(17) Uani 1 1 d . . . . .
C2D C 0.4814(4) 0.3531(5) 0.2972(4) 0.0209(19) Uani 1 1 d . . . . .
H2D H 0.5072 0.3944 0.2845 0.025 Uiso 1 1 calc R U . . .
C3D C 0.5098(4) 0.2916(5) 0.3442(4) 0.023(2) Uani 1 1 d . . . . .
H3D H 0.5549 0.2910 0.3639 0.028 Uiso 1 1 calc R U . . .
C4D C 0.4735(4) 0.2315(5) 0.3629(4) 0.024(2) Uani 1 1 d . . . . .
H4D H 0.4933 0.1900 0.3964 0.028 Uiso 1 1 calc R U . . .
C5D C 0.4071(4) 0.2313(5) 0.3326(4) 0.023(2) Uani 1 1 d . . . . .
H5D H 0.3820 0.1888 0.3448 0.028 Uiso 1 1 calc R U . . .
C6D C 0.3778(4) 0.2925(5) 0.2849(4) 0.0183(19) Uani 1 1 d . . . . .
H6D H 0.3328 0.2917 0.2638 0.022 Uiso 1 1 calc R U . . .
C1E C 0.1078(3) 0.2096(4) 0.2089(4) 0.0105(17) Uani 1 1 d . . . . .
C2E C 0.0868(4) 0.1631(5) 0.1483(4) 0.0197(19) Uani 1 1 d . . . . .
H2E H 0.1167 0.1372 0.1283 0.024 Uiso 1 1 calc R U . . .
C3E C 0.0216(4) 0.1542(5) 0.1164(4) 0.0219(19) Uani 1 1 d . . . . .
H3E H 0.0067 0.1229 0.0740 0.026 Uiso 1 1 calc R U . . .
C4E C -0.0215(4) 0.1910(5) 0.1466(4) 0.0192(19) Uani 1 1 d . . . . .
H4E H -0.0661 0.1852 0.1244 0.023 Uiso 1 1 calc R U . . .
C5E C -0.0006(4) 0.2360(5) 0.2085(4) 0.024(2) Uani 1 1 d . . . . .
H5E H -0.0304 0.2604 0.2294 0.028 Uiso 1 1 calc R U . . .
C6E C 0.0649(3) 0.2451(5) 0.2401(4) 0.0179(18) Uani 1 1 d . . . . .
H6E H 0.0800 0.2757 0.2829 0.021 Uiso 1 1 calc R U . . .
C1F C 0.2112(3) 0.1434(4) 0.3233(3) 0.0099(17) Uani 1 1 d . . . . .
C2F C 0.1873(4) 0.0620(5) 0.3089(4) 0.0184(19) Uani 1 1 d . . . . .
H2F H 0.1580 0.0491 0.2643 0.022 Uiso 1 1 calc R U . . .
C3F C 0.2068(4) 0.0010(5) 0.3596(4) 0.022(2) Uani 1 1 d . . . . .
H3F H 0.1906 -0.0540 0.3501 0.026 Uiso 1 1 calc R U . . .
C4F C 0.2505(4) 0.0197(5) 0.4254(4) 0.024(2) Uani 1 1 d . . . . .
H4F H 0.2657 -0.0232 0.4591 0.029 Uiso 1 1 calc R U . . .
C5F C 0.2711(4) 0.0989(5) 0.4410(4) 0.025(2) Uani 1 1 d . . . . .
H5F H 0.2986 0.1119 0.4866 0.030 Uiso 1 1 calc R U . . .
C6F C 0.2520(3) 0.1614(5) 0.3901(4) 0.0140(18) Uani 1 1 d . . . . .
H6F H 0.2671 0.2166 0.4011 0.017 Uiso 1 1 calc R U . . .
C1G C 0.1000(3) 0.4685(4) 0.1474(4) 0.0120(18) Uani 1 1 d . . . . .
C2G C 0.0454(3) 0.4202(4) 0.1245(4) 0.0167(19) Uani 1 1 d . . . . .
H2G H 0.0412 0.3821 0.0866 0.020 Uiso 1 1 calc R U . . .
C3G C -0.0034(4) 0.4274(5) 0.1570(4) 0.026(2) Uani 1 1 d . . . . .
H3G H -0.0410 0.3945 0.1410 0.031 Uiso 1 1 calc R U . . .
C4G C 0.0031(4) 0.4822(5) 0.2123(4) 0.024(2) Uani 1 1 d . . . . .
H4G H -0.0302 0.4872 0.2343 0.028 Uiso 1 1 calc R U . . .
C5G C 0.0579(4) 0.5302(5) 0.2360(4) 0.021(2) Uani 1 1 d . . . . .
H5G H 0.0621 0.5680 0.2741 0.025 Uiso 1 1 calc R U . . .
C6G C 0.1058(4) 0.5230(5) 0.2045(4) 0.020(2) Uani 1 1 d . . . . .
H6G H 0.1436 0.5553 0.2215 0.024 Uiso 1 1 calc R U . . .
C1H C 0.1535(4) 0.5766(5) 0.0656(4) 0.0160(18) Uani 1 1 d . . . . .
C2H C 0.2070(4) 0.6173(5) 0.0565(4) 0.023(2) Uani 1 1 d . . . . .
H2H H 0.2470 0.5893 0.0670 0.027 Uiso 1 1 calc R U . . .
C3H C 0.2019(5) 0.6984(6) 0.0322(5) 0.037(2) Uani 1 1 d . . . . .
H3H H 0.2381 0.7258 0.0251 0.044 Uiso 1 1 calc R U . . .
C4H C 0.1445(5) 0.7393(5) 0.0184(5) 0.036(2) Uani 1 1 d . . . . .
H4H H 0.1416 0.7956 0.0031 0.044 Uiso 1 1 calc R U . . .
C5H C 0.0910(4) 0.6996(5) 0.0265(4) 0.029(2) Uani 1 1 d . . . . .
H5H H 0.0513 0.7283 0.0166 0.035 Uiso 1 1 calc R U . . .
C6H C 0.0954(4) 0.6177(5) 0.0491(4) 0.022(2) Uani 1 1 d . . . . .
H6H H 0.0584 0.5896 0.0534 0.026 Uiso 1 1 calc R U . . .
C7 C 0.3800(3) 0.5741(4) 0.2971(4) 0.0127(18) Uani 1 1 d . . . . .
C8 C 0.4109(3) 0.5336(4) 0.2544(4) 0.0126(18) Uani 1 1 d . . . . .
C9 C 0.4701(3) 0.5657(5) 0.2505(4) 0.0171(19) Uani 1 1 d . . . . .
H9 H 0.4930 0.5381 0.2228 0.020 Uiso 1 1 calc R U . . .
C10 C 0.4944(4) 0.6373(5) 0.2869(4) 0.0188(19) Uani 1 1 d . . . . .
H10 H 0.5331 0.6606 0.2826 0.023 Uiso 1 1 calc R U . . .
C11 C 0.4621(4) 0.6754(5) 0.3301(4) 0.023(2) Uani 1 1 d . . . . .
H11 H 0.4796 0.7240 0.3559 0.027 Uiso 1 1 calc R U . . .
C12 C 0.4048(4) 0.6433(5) 0.3359(4) 0.0188(19) Uani 1 1 d . . . . .
H12 H 0.3832 0.6687 0.3661 0.023 Uiso 1 1 calc R U . . .
O1 O 0.3229(2) 0.5384(3) 0.3014(3) 0.0161(12) Uani 1 1 d . . . . .
C13 C 0.2363(3) 0.1900(4) 0.1942(4) 0.0127(18) Uani 1 1 d . . . . .
C14 C 0.2827(4) 0.1277(5) 0.2108(4) 0.0182(19) Uani 1 1 d . . . . .
H14 H 0.2885 0.0964 0.2531 0.022 Uiso 1 1 calc R U . . .
C15 C 0.3208(4) 0.1103(5) 0.1666(4) 0.023(2) Uani 1 1 d . . . . .
H15 H 0.3515 0.0668 0.1783 0.028 Uiso 1 1 calc R U . . .
C16 C 0.3134(4) 0.1568(5) 0.1056(4) 0.0210(19) Uani 1 1 d . . . . .
H16 H 0.3402 0.1465 0.0762 0.025 Uiso 1 1 calc R U . . .
C17 C 0.2669(4) 0.2182(5) 0.0874(4) 0.020(2) Uani 1 1 d . . . . .
H17 H 0.2616 0.2500 0.0454 0.024 Uiso 1 1 calc R U . . .
C18 C 0.2286(3) 0.2327(4) 0.1308(4) 0.0156(18) Uani 1 1 d . . . . .
C19 C 0.1482(3) 0.3137(5) 0.0474(4) 0.0136(18) Uani 1 1 d . . . . .
C20 C 0.1356(3) 0.3978(5) 0.0320(4) 0.0135(18) Uani 1 1 d . . . . .
C21 C 0.0983(3) 0.4191(5) -0.0360(4) 0.0172(19) Uani 1 1 d . . . . .
H21 H 0.0898 0.4760 -0.0482 0.021 Uiso 1 1 calc R U . . .
C22 C 0.0736(4) 0.3573(5) -0.0864(4) 0.0205(19) Uani 1 1 d . . . . .
H22 H 0.0485 0.3723 -0.1327 0.025 Uiso 1 1 calc R U . . .
C23 C 0.0854(4) 0.2755(5) -0.0691(4) 0.022(2) Uani 1 1 d . . . . .
H23 H 0.0673 0.2337 -0.1030 0.026 Uiso 1 1 calc R U . . .
C24 C 0.1239(4) 0.2525(5) -0.0020(4) 0.0203(19) Uani 1 1 d . . . . .
H24 H 0.1331 0.1956 0.0095 0.024 Uiso 1 1 calc R U . . .
O2 O 0.1821(2) 0.2946(3) 0.1173(2) 0.0166(12) Uani 1 1 d . . . . .
B1 B 0.3609(5) 0.7208(7) -0.0178(6) 0.034(3) Uani 1 1 d . . . . .
F1 F 0.3671(4) 0.6923(5) 0.0479(4) 0.100(3) Uani 1 1 d . . . . .
F2 F 0.3255(3) 0.7802(4) -0.0422(6) 0.145(4) Uani 1 1 d . . . . .
F3 F 0.4201(3) 0.7247(5) -0.0228(4) 0.099(3) Uani 1 1 d . . . . .
F4 F 0.3281(5) 0.6526(5) -0.0527(7) 0.184(5) Uani 1 1 d . . . . .
B2 B 0.0952(5) -0.1155(7) 0.1813(5) 0.029(3) Uani 1 1 d . . . . .
F5 F 0.0797(2) -0.0320(3) 0.1661(2) 0.0269(11) Uani 1 1 d . . . . .
F6 F 0.1467(4) -0.1361(5) 0.1603(4) 0.111(3) Uani 1 1 d . . . . .
F7 F 0.0434(4) -0.1633(4) 0.1495(4) 0.102(3) Uani 1 1 d . . . . .
F8 F 0.1090(2) -0.1287(3) 0.2536(2) 0.0327(12) Uani 1 1 d . . . . .
C25 C 0.3392(8) 0.6085(8) -0.2096(7) 0.111(6) Uani 1 1 d . . . . .
H25A H 0.2959 0.5889 -0.2108 0.133 Uiso 1 1 calc R U . . .
H25B H 0.3495 0.6568 -0.1771 0.133 Uiso 1 1 calc R U . . .
Cl1 Cl 0.39486(15) 0.5279(2) -0.17488(16) 0.0745(9) Uani 1 1 d . . . . .
Cl2 Cl 0.33779(18) 0.6414(2) -0.2944(2) 0.0965(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3326(19) . ?
Au1 P3 2.334(2) . ?
Au2 P4 2.3136(19) . ?
Au2 P2 2.3137(19) . ?
P1 C1 1.800(7) . ?
P1 C1B 1.807(7) . ?
P1 C1A 1.813(7) . ?
P2 C1C 1.812(7) . ?
P2 C1D 1.816(7) . ?
P2 C8 1.818(7) . ?
P3 C1F 1.805(7) . ?
P3 C13 1.813(7) . ?
P3 C1E 1.820(7) . ?
P4 C20 1.801(8) . ?
P4 C1G 1.815(7) . ?
P4 C1H 1.819(8) . ?
C1 C6 1.401(10) . ?
C1 C2 1.411(10) . ?
C2 C3 1.383(10) . ?
C2 H2 0.9500 . ?
C3 C4 1.378(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.380(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.384(10) . ?
C5 H5 0.9500 . ?
C6 O1 1.397(8) . ?
C1A C6A 1.383(10) . ?
C1A C2A 1.406(10) . ?
C2A C3A 1.378(10) . ?
C2A H1A 0.9500 . ?
C3A C4A 1.372(11) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.389(11) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.389(10) . ?
C5A H5A 0.9500 . ?
C6A H6A 0.9500 . ?
C1B C6B 1.395(10) . ?
C1B C2B 1.396(10) . ?
C2B C3B 1.393(11) . ?
C2B H2B 0.9500 . ?
C3B C4B 1.358(11) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.385(11) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.384(10) . ?
C5B H5B 0.9500 . ?
C6B H6B 0.9500 . ?
C1C C6C 1.389(10) . ?
C1C C2C 1.398(10) . ?
C2C C3C 1.374(10) . ?
C2C H2C 0.9500 . ?
C3C C4C 1.381(11) . ?
C3C H3C 0.9500 . ?
C4C C5C 1.364(11) . ?
C4C H4C 0.9500 . ?
C5C C6C 1.401(10) . ?
C5C H5C 0.9500 . ?
C6C H6C 0.9500 . ?
C1D C2D 1.396(10) . ?
C1D C6D 1.397(10) . ?
C2D C3D 1.374(10) . ?
C2D H2D 0.9500 . ?
C3D C4D 1.365(11) . ?
C3D H3D 0.9500 . ?
C4D C5D 1.401(11) . ?
C4D H4D 0.9500 . ?
C5D C6D 1.384(10) . ?
C5D H5D 0.9500 . ?
C6D H6D 0.9500 . ?
C1E C2E 1.370(10) . ?
C1E C6E 1.382(10) . ?
C2E C3E 1.388(10) . ?
C2E H2E 0.9500 . ?
C3E C4E 1.383(10) . ?
C3E H3E 0.9500 . ?
C4E C5E 1.379(10) . ?
C4E H4E 0.9500 . ?
C5E C6E 1.393(10) . ?
C5E H5E 0.9500 . ?
C6E H6E 0.9500 . ?
C1F C6F 1.391(9) . ?
C1F C2F 1.406(10) . ?
C2F C3F 1.378(10) . ?
C2F H2F 0.9500 . ?
C3F C4F 1.403(11) . ?
C3F H3F 0.9500 . ?
C4F C5F 1.355(11) . ?
C4F H4F 0.9500 . ?
C5F C6F 1.396(10) . ?
C5F H5F 0.9500 . ?
C6F H6F 0.9500 . ?
C1G C2G 1.384(10) . ?
C1G C6G 1.403(10) . ?
C2G C3G 1.397(10) . ?
C2G H2G 0.9500 . ?
C3G C4G 1.378(11) . ?
C3G H3G 0.9500 . ?
C4G C5G 1.387(11) . ?
C4G H4G 0.9500 . ?
C5G C6G 1.368(10) . ?
C5G H5G 0.9500 . ?
C6G H6G 0.9500 . ?
C1H C6H 1.383(10) . ?
C1H C2H 1.393(10) . ?
C2H C3H 1.382(11) . ?
C2H H2H 0.9500 . ?
C3H C4H 1.370(12) . ?
C3H H3H 0.9500 . ?
C4H C5H 1.380(12) . ?
C4H H4H 0.9500 . ?
C5H C6H 1.384(11) . ?
C5H H5H 0.9500 . ?
C6H H6H 0.9500 . ?
C7 C12 1.371(10) . ?
C7 C8 1.382(10) . ?
C7 O1 1.398(8) . ?
C8 C9 1.415(10) . ?
C9 C10 1.380(10) . ?
C9 H9 0.9500 . ?
C10 C11 1.392(10) . ?
C10 H10 0.9500 . ?
C11 C12 1.390(10) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.393(10) . ?
C13 C14 1.396(10) . ?
C14 C15 1.394(10) . ?
C14 H14 0.9500 . ?
C15 C16 1.385(11) . ?
C15 H15 0.9500 . ?
C16 C17 1.387(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.378(10) . ?
C17 H17 0.9500 . ?
C18 O2 1.392(8) . ?
C19 C24 1.378(10) . ?
C19 C20 1.394(10) . ?
C19 O2 1.398(8) . ?
C20 C21 1.397(10) . ?
C21 C22 1.399(10) . ?
C21 H21 0.9500 . ?
C22 C23 1.365(10) . ?
C22 H22 0.9500 . ?
C23 C24 1.398(10) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
B1 F2 1.236(12) . ?
B1 F3 1.324(12) . ?
B1 F1 1.344(12) . ?
B1 F4 1.380(13) . ?
B2 F6 1.346(11) . ?
B2 F7 1.361(12) . ?
B2 F8 1.387(11) . ?
B2 F5 1.395(11) . ?
C25 Cl2 1.744(12) . ?
C25 Cl1 1.774(13) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P3 165.25(7) . . ?
P4 Au2 P2 165.87(7) . . ?
C1 P1 C1B 105.7(3) . . ?
C1 P1 C1A 102.6(3) . . ?
C1B P1 C1A 108.0(3) . . ?
C1 P1 Au1 118.4(2) . . ?
C1B P1 Au1 112.9(2) . . ?
C1A P1 Au1 108.4(2) . . ?
C1C P2 C1D 107.0(3) . . ?
C1C P2 C8 105.8(3) . . ?
C1D P2 C8 104.6(3) . . ?
C1C P2 Au2 107.4(2) . . ?
C1D P2 Au2 120.3(2) . . ?
C8 P2 Au2 110.9(2) . . ?
C1F P3 C13 104.1(3) . . ?
C1F P3 C1E 106.1(3) . . ?
C13 P3 C1E 106.9(3) . . ?
C1F P3 Au1 109.3(2) . . ?
C13 P3 Au1 115.3(2) . . ?
C1E P3 Au1 114.4(2) . . ?
C20 P4 C1G 103.7(3) . . ?
C20 P4 C1H 109.2(3) . . ?
C1G P4 C1H 102.8(3) . . ?
C20 P4 Au2 110.7(2) . . ?
C1G P4 Au2 119.1(2) . . ?
C1H P4 Au2 110.6(3) . . ?
C6 C1 C2 116.8(7) . . ?
C6 C1 P1 119.5(5) . . ?
C2 C1 P1 123.5(6) . . ?
C3 C2 C1 120.8(7) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C4 C3 C2 120.3(7) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 120.4(7) . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C4 C5 C6 119.2(7) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
C5 C6 O1 122.3(7) . . ?
C5 C6 C1 122.1(7) . . ?
O1 C6 C1 115.5(6) . . ?
C6A C1A C2A 118.5(7) . . ?
C6A C1A P1 123.3(6) . . ?
C2A C1A P1 117.8(6) . . ?
C3A C2A C1A 121.1(7) . . ?
C3A C2A H1A 119.5 . . ?
C1A C2A H1A 119.5 . . ?
C4A C3A C2A 119.1(7) . . ?
C4A C3A H3A 120.5 . . ?
C2A C3A H3A 120.5 . . ?
C3A C4A C5A 121.5(7) . . ?
C3A C4A H4A 119.3 . . ?
C5A C4A H4A 119.3 . . ?
C4A C5A C6A 118.9(7) . . ?
C4A C5A H5A 120.5 . . ?
C6A C5A H5A 120.5 . . ?
C1A C6A C5A 120.9(7) . . ?
C1A C6A H6A 119.6 . . ?
C5A C6A H6A 119.6 . . ?
C6B C1B C2B 119.2(7) . . ?
C6B C1B P1 121.4(6) . . ?
C2B C1B P1 119.4(6) . . ?
C3B C2B C1B 119.8(8) . . ?
C3B C2B H2B 120.1 . . ?
C1B C2B H2B 120.1 . . ?
C4B C3B C2B 120.5(8) . . ?
C4B C3B H3B 119.7 . . ?
C2B C3B H3B 119.7 . . ?
C3B C4B C5B 120.3(8) . . ?
C3B C4B H4B 119.8 . . ?
C5B C4B H4B 119.8 . . ?
C6B C5B C4B 120.2(8) . . ?
C6B C5B H5B 119.9 . . ?
C4B C5B H5B 119.9 . . ?
C5B C6B C1B 119.9(7) . . ?
C5B C6B H6B 120.1 . . ?
C1B C6B H6B 120.1 . . ?
C6C C1C C2C 118.9(7) . . ?
C6C C1C P2 121.2(6) . . ?
C2C C1C P2 119.4(5) . . ?
C3C C2C C1C 120.8(7) . . ?
C3C C2C H2C 119.6 . . ?
C1C C2C H2C 119.6 . . ?
C2C C3C C4C 119.5(7) . . ?
C2C C3C H3C 120.3 . . ?
C4C C3C H3C 120.3 . . ?
C5C C4C C3C 121.0(8) . . ?
C5C C4C H4C 119.5 . . ?
C3C C4C H4C 119.5 . . ?
C4C C5C C6C 120.0(8) . . ?
C4C C5C H5C 120.0 . . ?
C6C C5C H5C 120.0 . . ?
C1C C6C C5C 119.7(7) . . ?
C1C C6C H6C 120.2 . . ?
C5C C6C H6C 120.2 . . ?
C2D C1D C6D 119.3(7) . . ?
C2D C1D P2 120.7(6) . . ?
C6D C1D P2 120.0(5) . . ?
C3D C2D C1D 120.6(7) . . ?
C3D C2D H2D 119.7 . . ?
C1D C2D H2D 119.7 . . ?
C4D C3D C2D 120.5(8) . . ?
C4D C3D H3D 119.7 . . ?
C2D C3D H3D 119.7 . . ?
C3D C4D C5D 119.7(8) . . ?
C3D C4D H4D 120.2 . . ?
C5D C4D H4D 120.2 . . ?
C6D C5D C4D 120.6(7) . . ?
C6D C5D H5D 119.7 . . ?
C4D C5D H5D 119.7 . . ?
C5D C6D C1D 119.2(7) . . ?
C5D C6D H6D 120.4 . . ?
C1D C6D H6D 120.4 . . ?
C2E C1E C6E 120.8(7) . . ?
C2E C1E P3 122.2(5) . . ?
C6E C1E P3 116.8(5) . . ?
C1E C2E C3E 119.6(7) . . ?
C1E C2E H2E 120.2 . . ?
C3E C2E H2E 120.2 . . ?
C4E C3E C2E 119.8(7) . . ?
C4E C3E H3E 120.1 . . ?
C2E C3E H3E 120.1 . . ?
C5E C4E C3E 120.8(7) . . ?
C5E C4E H4E 119.6 . . ?
C3E C4E H4E 119.6 . . ?
C4E C5E C6E 119.1(7) . . ?
C4E C5E H5E 120.4 . . ?
C6E C5E H5E 120.4 . . ?
C1E C6E C5E 119.8(7) . . ?
C1E C6E H6E 120.1 . . ?
C5E C6E H6E 120.1 . . ?
C6F C1F C2F 119.0(6) . . ?
C6F C1F P3 120.4(6) . . ?
C2F C1F P3 120.6(5) . . ?
C3F C2F C1F 119.7(7) . . ?
C3F C2F H2F 120.2 . . ?
C1F C2F H2F 120.2 . . ?
C2F C3F C4F 120.3(7) . . ?
C2F C3F H3F 119.9 . . ?
C4F C3F H3F 119.9 . . ?
C5F C4F C3F 120.3(7) . . ?
C5F C4F H4F 119.9 . . ?
C3F C4F H4F 119.9 . . ?
C4F C5F C6F 120.1(8) . . ?
C4F C5F H5F 120.0 . . ?
C6F C5F H5F 120.0 . . ?
C1F C6F C5F 120.5(7) . . ?
C1F C6F H6F 119.7 . . ?
C5F C6F H6F 119.7 . . ?
C2G C1G C6G 118.9(7) . . ?
C2G C1G P4 123.5(6) . . ?
C6G C1G P4 117.4(6) . . ?
C1G C2G C3G 120.2(7) . . ?
C1G C2G H2G 119.9 . . ?
C3G C2G H2G 119.9 . . ?
C4G C3G C2G 119.8(8) . . ?
C4G C3G H3G 120.1 . . ?
C2G C3G H3G 120.1 . . ?
C3G C4G C5G 120.3(7) . . ?
C3G C4G H4G 119.8 . . ?
C5G C4G H4G 119.8 . . ?
C6G C5G C4G 119.9(7) . . ?
C6G C5G H5G 120.0 . . ?
C4G C5G H5G 120.0 . . ?
C5G C6G C1G 120.8(7) . . ?
C5G C6G H6G 119.6 . . ?
C1G C6G H6G 119.6 . . ?
C6H C1H C2H 119.4(7) . . ?
C6H C1H P4 121.0(6) . . ?
C2H C1H P4 119.5(6) . . ?
C3H C2H C1H 120.0(8) . . ?
C3H C2H H2H 120.0 . . ?
C1H C2H H2H 120.0 . . ?
C4H C3H C2H 120.0(8) . . ?
C4H C3H H3H 120.0 . . ?
C2H C3H H3H 120.0 . . ?
C3H C4H C5H 120.7(8) . . ?
C3H C4H H4H 119.6 . . ?
C5H C4H H4H 119.6 . . ?
C4H C5H C6H 119.6(8) . . ?
C4H C5H H5H 120.2 . . ?
C6H C5H H5H 120.2 . . ?
C1H C6H C5H 120.3(8) . . ?
C1H C6H H6H 119.9 . . ?
C5H C6H H6H 119.9 . . ?
C12 C7 C8 122.7(7) . . ?
C12 C7 O1 120.9(6) . . ?
C8 C7 O1 116.3(6) . . ?
C7 C8 C9 118.3(6) . . ?
C7 C8 P2 120.1(5) . . ?
C9 C8 P2 121.5(5) . . ?
C10 C9 C8 119.7(7) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
C9 C10 C11 120.0(7) . . ?
C9 C10 H10 120.0 . . ?
C11 C10 H10 120.0 . . ?
C12 C11 C10 120.9(7) . . ?
C12 C11 H11 119.6 . . ?
C10 C11 H11 119.6 . . ?
C7 C12 C11 118.3(7) . . ?
C7 C12 H12 120.8 . . ?
C11 C12 H12 120.8 . . ?
C6 O1 C7 116.5(5) . . ?
C18 C13 C14 117.1(7) . . ?
C18 C13 P3 120.3(6) . . ?
C14 C13 P3 122.4(5) . . ?
C15 C14 C13 121.4(7) . . ?
C15 C14 H14 119.3 . . ?
C13 C14 H14 119.3 . . ?
C16 C15 C14 119.5(7) . . ?
C16 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
C15 C16 C17 120.3(7) . . ?
C15 C16 H16 119.9 . . ?
C17 C16 H16 119.9 . . ?
C18 C17 C16 119.2(7) . . ?
C18 C17 H17 120.4 . . ?
C16 C17 H17 120.4 . . ?
C17 C18 O2 122.8(7) . . ?
C17 C18 C13 122.4(7) . . ?
O2 C18 C13 114.7(6) . . ?
C24 C19 C20 121.8(7) . . ?
C24 C19 O2 121.7(7) . . ?
C20 C19 O2 116.3(6) . . ?
C19 C20 C21 118.1(7) . . ?
C19 C20 P4 118.5(5) . . ?
C21 C20 P4 123.2(6) . . ?
C20 C21 C22 120.5(7) . . ?
C20 C21 H21 119.8 . . ?
C22 C21 H21 119.8 . . ?
C23 C22 C21 120.0(7) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C24 120.7(7) . . ?
C22 C23 H23 119.6 . . ?
C24 C23 H23 119.6 . . ?
C19 C24 C23 118.9(7) . . ?
C19 C24 H24 120.5 . . ?
C23 C24 H24 120.5 . . ?
C18 O2 C19 119.8(5) . . ?
F2 B1 F3 116.6(9) . . ?
F2 B1 F1 121.1(11) . . ?
F3 B1 F1 105.0(9) . . ?
F2 B1 F4 104.0(10) . . ?
F3 B1 F4 112.3(11) . . ?
F1 B1 F4 96.0(9) . . ?
F6 B2 F7 112.1(9) . . ?
F6 B2 F8 108.9(8) . . ?
F7 B2 F8 107.1(8) . . ?
F6 B2 F5 110.0(8) . . ?
F7 B2 F5 109.0(8) . . ?
F8 B2 F5 109.6(8) . . ?
Cl2 C25 Cl1 114.4(7) . . ?
Cl2 C25 H25A 108.7 . . ?
Cl1 C25 H25A 108.7 . . ?
Cl2 C25 H25B 108.7 . . ?
Cl1 C25 H25B 108.7 . . ?
H25A C25 H25B 107.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1B P1 C1 C6 64.1(6) . . . . ?
C1A P1 C1 C6 177.2(6) . . . . ?
Au1 P1 C1 C6 -63.6(6) . . . . ?
C1B P1 C1 C2 -121.8(6) . . . . ?
C1A P1 C1 C2 -8.7(7) . . . . ?
Au1 P1 C1 C2 110.5(6) . . . . ?
C6 C1 C2 C3 1.3(11) . . . . ?
P1 C1 C2 C3 -172.8(6) . . . . ?
C1 C2 C3 C4 4.0(12) . . . . ?
C2 C3 C4 C5 -5.2(12) . . . . ?
C3 C4 C5 C6 0.9(12) . . . . ?
C4 C5 C6 O1 -177.7(7) . . . . ?
C4 C5 C6 C1 4.8(11) . . . . ?
C2 C1 C6 C5 -5.8(11) . . . . ?
P1 C1 C6 C5 168.7(6) . . . . ?
C2 C1 C6 O1 176.5(6) . . . . ?
P1 C1 C6 O1 -9.0(9) . . . . ?
C1 P1 C1A C6A -86.5(7) . . . . ?
C1B P1 C1A C6A 24.9(8) . . . . ?
Au1 P1 C1A C6A 147.6(6) . . . . ?
C1 P1 C1A C2A 86.0(6) . . . . ?
C1B P1 C1A C2A -162.6(6) . . . . ?
Au1 P1 C1A C2A -40.0(6) . . . . ?
C6A C1A C2A C3A 2.7(11) . . . . ?
P1 C1A C2A C3A -170.1(6) . . . . ?
C1A C2A C3A C4A -1.3(11) . . . . ?
C2A C3A C4A C5A -1.4(12) . . . . ?
C3A C4A C5A C6A 2.6(12) . . . . ?
C2A C1A C6A C5A -1.4(11) . . . . ?
P1 C1A C6A C5A 170.9(6) . . . . ?
C4A C5A C6A C1A -1.1(12) . . . . ?
C1 P1 C1B C6B -138.3(6) . . . . ?
C1A P1 C1B C6B 112.4(6) . . . . ?
Au1 P1 C1B C6B -7.4(6) . . . . ?
C1 P1 C1B C2B 39.7(7) . . . . ?
C1A P1 C1B C2B -69.6(7) . . . . ?
Au1 P1 C1B C2B 170.6(5) . . . . ?
C6B C1B C2B C3B -3.1(11) . . . . ?
P1 C1B C2B C3B 178.8(6) . . . . ?
C1B C2B C3B C4B 1.5(12) . . . . ?
C2B C3B C4B C5B 1.0(12) . . . . ?
C3B C4B C5B C6B -1.9(12) . . . . ?
C4B C5B C6B C1B 0.3(11) . . . . ?
C2B C1B C6B C5B 2.2(11) . . . . ?
P1 C1B C6B C5B -179.8(5) . . . . ?
C1D P2 C1C C6C 25.2(7) . . . . ?
C8 P2 C1C C6C 136.4(6) . . . . ?
Au2 P2 C1C C6C -105.2(6) . . . . ?
C1D P2 C1C C2C -161.9(6) . . . . ?
C8 P2 C1C C2C -50.8(7) . . . . ?
Au2 P2 C1C C2C 67.7(6) . . . . ?
C6C C1C C2C C3C -2.6(11) . . . . ?
P2 C1C C2C C3C -175.5(6) . . . . ?
C1C C2C C3C C4C 1.6(12) . . . . ?
C2C C3C C4C C5C -0.7(12) . . . . ?
C3C C4C C5C C6C 0.9(13) . . . . ?
C2C C1C C6C C5C 2.7(11) . . . . ?
P2 C1C C6C C5C 175.6(6) . . . . ?
C4C C5C C6C C1C -1.9(12) . . . . ?
C1C P2 C1D C2D 61.8(7) . . . . ?
C8 P2 C1D C2D -50.1(7) . . . . ?
Au2 P2 C1D C2D -175.5(5) . . . . ?
C1C P2 C1D C6D -117.7(6) . . . . ?
C8 P2 C1D C6D 130.3(6) . . . . ?
Au2 P2 C1D C6D 5.0(7) . . . . ?
C6D C1D C2D C3D -2.6(11) . . . . ?
P2 C1D C2D C3D 177.8(6) . . . . ?
C1D C2D C3D C4D 0.3(12) . . . . ?
C2D C3D C4D C5D 1.6(12) . . . . ?
C3D C4D C5D C6D -1.3(12) . . . . ?
C4D C5D C6D C1D -1.0(11) . . . . ?
C2D C1D C6D C5D 2.9(11) . . . . ?
P2 C1D C6D C5D -177.5(6) . . . . ?
C1F P3 C1E C2E -94.7(6) . . . . ?
C13 P3 C1E C2E 15.9(7) . . . . ?
Au1 P3 C1E C2E 144.7(6) . . . . ?
C1F P3 C1E C6E 81.5(6) . . . . ?
C13 P3 C1E C6E -167.9(6) . . . . ?
Au1 P3 C1E C6E -39.1(6) . . . . ?
C6E C1E C2E C3E 2.3(11) . . . . ?
P3 C1E C2E C3E 178.4(6) . . . . ?
C1E C2E C3E C4E -1.1(11) . . . . ?
C2E C3E C4E C5E -0.6(12) . . . . ?
C3E C4E C5E C6E 0.9(12) . . . . ?
C2E C1E C6E C5E -2.0(11) . . . . ?
P3 C1E C6E C5E -178.2(6) . . . . ?
C4E C5E C6E C1E 0.3(11) . . . . ?
C13 P3 C1F C6F 107.1(6) . . . . ?
C1E P3 C1F C6F -140.4(6) . . . . ?
Au1 P3 C1F C6F -16.6(6) . . . . ?
C13 P3 C1F C2F -69.9(6) . . . . ?
C1E P3 C1F C2F 42.7(6) . . . . ?
Au1 P3 C1F C2F 166.4(5) . . . . ?
C6F C1F C2F C3F -2.7(10) . . . . ?
P3 C1F C2F C3F 174.3(6) . . . . ?
C1F C2F C3F C4F -0.3(11) . . . . ?
C2F C3F C4F C5F 3.7(12) . . . . ?
C3F C4F C5F C6F -3.9(12) . . . . ?
C2F C1F C6F C5F 2.6(10) . . . . ?
P3 C1F C6F C5F -174.5(6) . . . . ?
C4F C5F C6F C1F 0.8(11) . . . . ?
C20 P4 C1G C2G -3.2(7) . . . . ?
C1H P4 C1G C2G 110.5(6) . . . . ?
Au2 P4 C1G C2G -126.8(5) . . . . ?
C20 P4 C1G C6G -177.7(6) . . . . ?
C1H P4 C1G C6G -63.9(6) . . . . ?
Au2 P4 C1G C6G 58.8(6) . . . . ?
C6G C1G C2G C3G 1.4(11) . . . . ?
P4 C1G C2G C3G -173.0(6) . . . . ?
C1G C2G C3G C4G -0.5(11) . . . . ?
C2G C3G C4G C5G -0.2(12) . . . . ?
C3G C4G C5G C6G -0.1(12) . . . . ?
C4G C5G C6G C1G 1.1(11) . . . . ?
C2G C1G C6G C5G -1.7(11) . . . . ?
P4 C1G C6G C5G 173.0(6) . . . . ?
C20 P4 C1H C6H 82.8(7) . . . . ?
C1G P4 C1H C6H -26.8(7) . . . . ?
Au2 P4 C1H C6H -155.0(5) . . . . ?
C20 P4 C1H C2H -100.1(7) . . . . ?
C1G P4 C1H C2H 150.3(6) . . . . ?
Au2 P4 C1H C2H 22.0(7) . . . . ?
C6H C1H C2H C3H 0.9(12) . . . . ?
P4 C1H C2H C3H -176.3(6) . . . . ?
C1H C2H C3H C4H 1.3(13) . . . . ?
C2H C3H C4H C5H -1.9(13) . . . . ?
C3H C4H C5H C6H 0.3(13) . . . . ?
C2H C1H C6H C5H -2.5(11) . . . . ?
P4 C1H C6H C5H 174.6(6) . . . . ?
C4H C5H C6H C1H 1.9(12) . . . . ?
C12 C7 C8 C9 -0.6(11) . . . . ?
O1 C7 C8 C9 -177.7(6) . . . . ?
C12 C7 C8 P2 176.5(6) . . . . ?
O1 C7 C8 P2 -0.6(9) . . . . ?
C1C P2 C8 C7 154.6(6) . . . . ?
C1D P2 C8 C7 -92.5(6) . . . . ?
Au2 P2 C8 C7 38.6(6) . . . . ?
C1C P2 C8 C9 -28.4(7) . . . . ?
C1D P2 C8 C9 84.5(6) . . . . ?
Au2 P2 C8 C9 -144.4(5) . . . . ?
C7 C8 C9 C10 -2.1(11) . . . . ?
P2 C8 C9 C10 -179.1(6) . . . . ?
C8 C9 C10 C11 3.0(11) . . . . ?
C9 C10 C11 C12 -1.4(11) . . . . ?
C8 C7 C12 C11 2.3(11) . . . . ?
O1 C7 C12 C11 179.2(6) . . . . ?
C10 C11 C12 C7 -1.3(11) . . . . ?
C5 C6 O1 C7 38.7(9) . . . . ?
C1 C6 O1 C7 -143.6(6) . . . . ?
C12 C7 O1 C6 40.5(9) . . . . ?
C8 C7 O1 C6 -142.4(6) . . . . ?
C1F P3 C13 C18 174.2(6) . . . . ?
C1E P3 C13 C18 62.3(7) . . . . ?
Au1 P3 C13 C18 -66.0(6) . . . . ?
C1F P3 C13 C14 -11.6(7) . . . . ?
C1E P3 C13 C14 -123.6(6) . . . . ?
Au1 P3 C13 C14 108.2(6) . . . . ?
C18 C13 C14 C15 1.5(11) . . . . ?
P3 C13 C14 C15 -172.9(6) . . . . ?
C13 C14 C15 C16 1.3(11) . . . . ?
C14 C15 C16 C17 -2.3(12) . . . . ?
C15 C16 C17 C18 0.4(11) . . . . ?
C16 C17 C18 O2 178.2(6) . . . . ?
C16 C17 C18 C13 2.6(11) . . . . ?
C14 C13 C18 C17 -3.5(11) . . . . ?
P3 C13 C18 C17 171.0(6) . . . . ?
C14 C13 C18 O2 -179.4(6) . . . . ?
P3 C13 C18 O2 -4.9(9) . . . . ?
C24 C19 C20 C21 -1.3(11) . . . . ?
O2 C19 C20 C21 -176.0(6) . . . . ?
C24 C19 C20 P4 173.2(6) . . . . ?
O2 C19 C20 P4 -1.4(9) . . . . ?
C1G P4 C20 C19 -81.7(6) . . . . ?
C1H P4 C20 C19 169.2(6) . . . . ?
Au2 P4 C20 C19 47.1(6) . . . . ?
C1G P4 C20 C21 92.5(6) . . . . ?
C1H P4 C20 C21 -16.6(7) . . . . ?
Au2 P4 C20 C21 -138.7(6) . . . . ?
C19 C20 C21 C22 1.2(11) . . . . ?
P4 C20 C21 C22 -173.0(6) . . . . ?
C20 C21 C22 C23 0.4(11) . . . . ?
C21 C22 C23 C24 -2.0(12) . . . . ?
C20 C19 C24 C23 -0.3(11) . . . . ?
O2 C19 C24 C23 174.1(6) . . . . ?
C22 C23 C24 C19 2.0(11) . . . . ?
C17 C18 O2 C19 34.7(10) . . . . ?
C13 C18 O2 C19 -149.3(6) . . . . ?
C24 C19 O2 C18 44.7(9) . . . . ?
C20 C19 O2 C18 -140.7(7) . . . . ?

_refine_diff_density_max         2.753
_refine_diff_density_min         -1.148
_refine_diff_density_rms         0.134



#############################################################################
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_4
_database_code_depnum_ccdc_archive 'CCDC 1472201'
_audit_update_record             
;
2016-09-19 deposited with the CCDC.
2016-10-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(F6 P), C H2 Cl2'
_chemical_formula_sum            'C73 H58 Au2 Cl2 F12 O2 P6'
_chemical_formula_weight         1845.84

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   22.2139(17)
_cell_length_b                   16.1798(12)
_cell_length_c                   19.9656(15)
_cell_angle_alpha                90
_cell_angle_beta                 105.7400(10)
_cell_angle_gamma                90
_cell_volume                     6906.9(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9941
_cell_measurement_theta_min      2.289
_cell_measurement_theta_max      28.264

_exptl_crystal_description       block
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.775
_exptl_crystal_F_000             3608
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.11
_exptl_absorpt_coefficient_mu    4.539
_shelx_estimated_absorpt_T_min   0.549
_shelx_estimated_absorpt_T_max   0.635
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.510
_exptl_absorpt_correction_T_max  0.594
_exptl_absorpt_process_details   
;
SADABS-2014/4 (Bruker,2014) was used for absorption correction.
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            81807
_diffrn_reflns_av_unetI/netI     0.0433
_diffrn_reflns_av_R_equivalents  0.0512
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.952
_diffrn_reflns_theta_max         28.318
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             17176
_reflns_number_gt                13469
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_solution    'XT (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0256P)²+15.5385P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17176
_refine_ls_number_parameters     875
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0506
_refine_ls_R_factor_gt           0.0314
_refine_ls_wR_factor_ref         0.0685
_refine_ls_wR_factor_gt          0.0613
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.78499(2) 0.35109(2) 0.70184(2) 0.01374(4) Uani 1 1 d . . . . .
Au2 Au 0.73684(2) 0.45154(2) 0.84660(2) 0.01406(4) Uani 1 1 d . . . . .
P1 P 0.75534(4) 0.46221(6) 0.62521(5) 0.01328(19) Uani 1 1 d . . . . .
P2 P 0.62942(5) 0.44050(6) 0.80523(5) 0.0149(2) Uani 1 1 d . . . . .
P3 P 0.81303(5) 0.22220(6) 0.75403(5) 0.01263(19) Uani 1 1 d . . . . .
P4 P 0.84046(4) 0.47406(6) 0.90538(5) 0.01305(19) Uani 1 1 d . . . . .
C1 C 0.76259(17) 0.5665(2) 0.66044(19) 0.0140(7) Uani 1 1 d . . . . .
C2 C 0.80760(18) 0.6217(2) 0.6504(2) 0.0172(8) Uani 1 1 d . . . . .
H2 H 0.8328 0.6068 0.6207 0.021 Uiso 1 1 calc R U . . .
C3 C 0.81605(19) 0.6979(3) 0.6834(2) 0.0231(9) Uani 1 1 d . . . . .
H3 H 0.8458 0.7358 0.6750 0.028 Uiso 1 1 calc R U . . .
C4 C 0.7809(2) 0.7185(3) 0.7287(2) 0.0247(9) Uani 1 1 d . . . . .
H4 H 0.7885 0.7692 0.7535 0.030 Uiso 1 1 calc R U . . .
C5 C 0.73495(18) 0.6662(3) 0.7380(2) 0.0207(9) Uani 1 1 d . . . . .
H5 H 0.7104 0.6810 0.7683 0.025 Uiso 1 1 calc R U . . .
C6 C 0.72502(17) 0.5914(2) 0.70244(19) 0.0152(8) Uani 1 1 d . . . . .
C7 C 0.62250(18) 0.5706(2) 0.7143(2) 0.0162(8) Uani 1 1 d . . . . .
C8 C 0.59436(18) 0.5332(2) 0.76057(19) 0.0159(8) Uani 1 1 d . . . . .
C9 C 0.53671(19) 0.5642(3) 0.7654(2) 0.0228(9) Uani 1 1 d . . . . .
H9 H 0.5168 0.5401 0.7972 0.027 Uiso 1 1 calc R U . . .
C10 C 0.50879(19) 0.6296(3) 0.7243(2) 0.0248(10) Uani 1 1 d . . . . .
H10 H 0.4697 0.6503 0.7276 0.030 Uiso 1 1 calc R U . . .
C11 C 0.5376(2) 0.6652(3) 0.6783(2) 0.0284(10) Uani 1 1 d . . . . .
H11 H 0.5180 0.7102 0.6501 0.034 Uiso 1 1 calc R U . . .
C12 C 0.59476(19) 0.6363(3) 0.6724(2) 0.0218(9) Uani 1 1 d . . . . .
H12 H 0.6144 0.6608 0.6406 0.026 Uiso 1 1 calc R U . . .
O1 O 0.67852(12) 0.53658(16) 0.70837(14) 0.0176(6) Uani 1 1 d . . . . .
C13 C 0.76956(17) 0.1911(2) 0.81513(19) 0.0137(8) Uani 1 1 d . . . . .
C14 C 0.72415(18) 0.1293(2) 0.8001(2) 0.0174(8) Uani 1 1 d . . . . .
H14 H 0.7191 0.0971 0.7592 0.021 Uiso 1 1 calc R U . . .
C15 C 0.68603(19) 0.1138(3) 0.8438(2) 0.0219(9) Uani 1 1 d . . . . .
H15 H 0.6557 0.0710 0.8331 0.026 Uiso 1 1 calc R U . . .
C16 C 0.69270(19) 0.1613(3) 0.9027(2) 0.0224(9) Uani 1 1 d . . . . .
H16 H 0.6659 0.1519 0.9318 0.027 Uiso 1 1 calc R U . . .
C17 C 0.73812(19) 0.2225(2) 0.9201(2) 0.0196(8) Uani 1 1 d . . . . .
H17 H 0.7428 0.2546 0.9610 0.024 Uiso 1 1 calc R U . . .
C18 C 0.77643(17) 0.2361(2) 0.87678(19) 0.0148(8) Uani 1 1 d . . . . .
C19 C 0.85414(18) 0.3153(2) 0.95800(19) 0.0158(8) Uani 1 1 d . . . . .
C20 C 0.86763(17) 0.3986(2) 0.97369(19) 0.0144(8) Uani 1 1 d . . . . .
C21 C 0.90355(18) 0.4192(3) 1.04044(19) 0.0175(8) Uani 1 1 d . . . . .
H21 H 0.9125 0.4756 1.0526 0.021 Uiso 1 1 calc R U . . .
C22 C 0.9262(2) 0.3574(3) 1.0891(2) 0.0228(9) Uani 1 1 d . . . . .
H22 H 0.9507 0.3717 1.1345 0.027 Uiso 1 1 calc R U . . .
C23 C 0.9132(2) 0.2750(3) 1.0718(2) 0.0245(9) Uani 1 1 d . . . . .
H23 H 0.9293 0.2331 1.1052 0.029 Uiso 1 1 calc R U . . .
C24 C 0.87690(19) 0.2535(3) 1.0062(2) 0.0208(8) Uani 1 1 d . . . . .
H24 H 0.8677 0.1972 0.9943 0.025 Uiso 1 1 calc R U . . .
O2 O 0.82185(12) 0.29757(16) 0.88918(13) 0.0161(6) Uani 1 1 d . . . . .
C1A C 0.80688(17) 0.4645(2) 0.56822(19) 0.0141(8) Uani 1 1 d . . . . .
C2A C 0.87019(18) 0.4481(2) 0.5970(2) 0.0176(8) Uani 1 1 d . . . . .
H2A H 0.8843 0.4277 0.6432 0.021 Uiso 1 1 calc R U . . .
C3A C 0.91287(19) 0.4615(2) 0.5584(2) 0.0219(9) Uani 1 1 d . . . . .
H3A H 0.9561 0.4513 0.5785 0.026 Uiso 1 1 calc R U . . .
C4A C 0.8920(2) 0.4898(3) 0.4905(2) 0.0248(10) Uani 1 1 d . . . . .
H4A H 0.9211 0.4994 0.4642 0.030 Uiso 1 1 calc R U . . .
C5A C 0.8288(2) 0.5041(3) 0.4608(2) 0.0261(10) Uani 1 1 d . . . . .
H5A H 0.8147 0.5220 0.4138 0.031 Uiso 1 1 calc R U . . .
C6A C 0.7863(2) 0.4922(3) 0.4995(2) 0.0224(9) Uani 1 1 d . . . . .
H6A H 0.7431 0.5030 0.4793 0.027 Uiso 1 1 calc R U . . .
C1B C 0.67593(18) 0.4533(3) 0.5700(2) 0.0183(8) Uani 1 1 d . . . . .
C2B C 0.6471(2) 0.5207(3) 0.5298(2) 0.0251(9) Uani 1 1 d . . . . .
H2B H 0.6681 0.5723 0.5334 0.030 Uiso 1 1 calc R U . . .
C3B C 0.5879(2) 0.5117(3) 0.4847(2) 0.0301(11) Uani 1 1 d . . . . .
H3B H 0.5686 0.5569 0.4566 0.036 Uiso 1 1 calc R U . . .
C4B C 0.5566(2) 0.4372(3) 0.4806(2) 0.0302(11) Uani 1 1 d . . . . .
H4B H 0.5163 0.4312 0.4492 0.036 Uiso 1 1 calc R U . . .
C5B C 0.5837(2) 0.3716(3) 0.5219(2) 0.0297(11) Uani 1 1 d . . . . .
H5B H 0.5615 0.3211 0.5200 0.036 Uiso 1 1 calc R U . . .
C6B C 0.64359(19) 0.3795(3) 0.5663(2) 0.0204(9) Uani 1 1 d . . . . .
H6B H 0.6624 0.3340 0.5944 0.025 Uiso 1 1 calc R U . . .
C1C C 0.59611(18) 0.4281(2) 0.8784(2) 0.0175(8) Uani 1 1 d . . . . .
C2C C 0.5627(2) 0.3584(3) 0.8865(2) 0.0263(10) Uani 1 1 d . . . . .
H2C H 0.5557 0.3154 0.8527 0.032 Uiso 1 1 calc R U . . .
C3C C 0.5394(2) 0.3515(3) 0.9444(2) 0.0299(10) Uani 1 1 d . . . . .
H3C H 0.5162 0.3040 0.9501 0.036 Uiso 1 1 calc R U . . .
C4C C 0.5500(2) 0.4134(3) 0.9934(2) 0.0267(10) Uani 1 1 d . . . . .
H4C H 0.5340 0.4085 1.0327 0.032 Uiso 1 1 calc R U . . .
C5C C 0.5838(2) 0.4827(3) 0.9857(2) 0.0254(9) Uani 1 1 d . . . . .
H5C H 0.5910 0.5252 1.0198 0.030 Uiso 1 1 calc R U . . .
C6C C 0.6074(2) 0.4905(3) 0.9284(2) 0.0221(9) Uani 1 1 d . . . . .
H6C H 0.6309 0.5379 0.9233 0.027 Uiso 1 1 calc R U . . .
C1D C 0.59686(18) 0.3596(2) 0.7438(2) 0.0172(8) Uani 1 1 d . . . . .
C2D C 0.63437(19) 0.2957(2) 0.7330(2) 0.0193(8) Uani 1 1 d . . . . .
H2D H 0.6772 0.2939 0.7585 0.023 Uiso 1 1 calc R U . . .
C3D C 0.6099(2) 0.2338(3) 0.6848(2) 0.0239(9) Uani 1 1 d . . . . .
H3D H 0.6359 0.1903 0.6770 0.029 Uiso 1 1 calc R U . . .
C4D C 0.5474(2) 0.2361(3) 0.6485(2) 0.0275(10) Uani 1 1 d . . . . .
H4D H 0.5305 0.1941 0.6154 0.033 Uiso 1 1 calc R U . . .
C5D C 0.5091(2) 0.2989(3) 0.6597(2) 0.0316(11) Uani 1 1 d . . . . .
H5D H 0.4660 0.2991 0.6351 0.038 Uiso 1 1 calc R U . . .
C6D C 0.5334(2) 0.3615(3) 0.7067(2) 0.0273(10) Uani 1 1 d . . . . .
H6D H 0.5072 0.4053 0.7138 0.033 Uiso 1 1 calc R U . . .
C1E C 0.89534(17) 0.2077(2) 0.79818(19) 0.0128(7) Uani 1 1 d . . . . .
C2E C 0.91434(18) 0.1604(2) 0.8587(2) 0.0186(8) Uani 1 1 d . . . . .
H2E H 0.8841 0.1375 0.8791 0.022 Uiso 1 1 calc R U . . .
C3E C 0.97753(19) 0.1471(3) 0.8891(2) 0.0217(9) Uani 1 1 d . . . . .
H3E H 0.9908 0.1162 0.9310 0.026 Uiso 1 1 calc R U . . .
C4E C 1.02112(19) 0.1791(3) 0.8580(2) 0.0216(9) Uani 1 1 d . . . . .
H4E H 1.0644 0.1693 0.8783 0.026 Uiso 1 1 calc R U . . .
C5E C 1.00205(19) 0.2252(3) 0.7975(2) 0.0222(9) Uani 1 1 d . . . . .
H5E H 1.0323 0.2467 0.7763 0.027 Uiso 1 1 calc R U . . .
C6E C 0.93940(18) 0.2400(3) 0.7678(2) 0.0188(8) Uani 1 1 d . . . . .
H6E H 0.9264 0.2723 0.7267 0.023 Uiso 1 1 calc R U . . .
C1F C 0.79429(17) 0.1430(2) 0.68675(19) 0.0153(8) Uani 1 1 d . . . . .
C2F C 0.81738(19) 0.0627(2) 0.7009(2) 0.0199(8) Uani 1 1 d . . . . .
H2F H 0.8455 0.0500 0.7448 0.024 Uiso 1 1 calc R U . . .
C3F C 0.7991(2) 0.0017(3) 0.6509(2) 0.0263(10) Uani 1 1 d . . . . .
H3F H 0.8150 -0.0528 0.6603 0.032 Uiso 1 1 calc R U . . .
C4F C 0.7576(2) 0.0200(3) 0.5870(2) 0.0277(10) Uani 1 1 d . . . . .
H4F H 0.7441 -0.0225 0.5534 0.033 Uiso 1 1 calc R U . . .
C5F C 0.7358(2) 0.0991(3) 0.5721(2) 0.0261(10) Uani 1 1 d . . . . .
H5F H 0.7084 0.1116 0.5278 0.031 Uiso 1 1 calc R U . . .
C6F C 0.75387(19) 0.1610(3) 0.6218(2) 0.0201(8) Uani 1 1 d . . . . .
H6F H 0.7386 0.2156 0.6115 0.024 Uiso 1 1 calc R U . . .
C1G C 0.89798(17) 0.4712(2) 0.85592(19) 0.0148(8) Uani 1 1 d . . . . .
C2G C 0.9501(2) 0.4203(3) 0.8734(2) 0.0221(9) Uani 1 1 d . . . . .
H2G H 0.9543 0.3800 0.9090 0.027 Uiso 1 1 calc R U . . .
C3G C 0.9963(2) 0.4282(3) 0.8386(2) 0.0260(10) Uani 1 1 d . . . . .
H3G H 1.0322 0.3935 0.8506 0.031 Uiso 1 1 calc R U . . .
C4G C 0.9900(2) 0.4867(3) 0.7864(2) 0.0257(10) Uani 1 1 d . . . . .
H4G H 1.0217 0.4924 0.7628 0.031 Uiso 1 1 calc R U . . .
C5G C 0.9381(2) 0.5361(3) 0.7688(2) 0.0273(10) Uani 1 1 d . . . . .
H5G H 0.9337 0.5755 0.7326 0.033 Uiso 1 1 calc R U . . .
C6G C 0.8919(2) 0.5298(3) 0.8030(2) 0.0232(9) Uani 1 1 d . . . . .
H6G H 0.8562 0.5648 0.7905 0.028 Uiso 1 1 calc R U . . .
C1H C 0.85139(18) 0.5761(2) 0.94428(19) 0.0151(8) Uani 1 1 d . . . . .
C2H C 0.7996(2) 0.6209(3) 0.9513(2) 0.0237(9) Uani 1 1 d . . . . .
H2H H 0.7595 0.5957 0.9400 0.028 Uiso 1 1 calc R U . . .
C3H C 0.8067(2) 0.7017(3) 0.9748(3) 0.0322(11) Uani 1 1 d . . . . .
H3H H 0.7715 0.7319 0.9798 0.039 Uiso 1 1 calc R U . . .
C4H C 0.8655(2) 0.7385(3) 0.9910(2) 0.0278(10) Uani 1 1 d . . . . .
H4H H 0.8702 0.7945 1.0059 0.033 Uiso 1 1 calc R U . . .
C5H C 0.9173(2) 0.6940(3) 0.9855(2) 0.0219(9) Uani 1 1 d . . . . .
H5H H 0.9574 0.7190 0.9975 0.026 Uiso 1 1 calc R U . . .
C6H C 0.91037(19) 0.6132(3) 0.9625(2) 0.0203(9) Uani 1 1 d . . . . .
H6H H 0.9459 0.5826 0.9591 0.024 Uiso 1 1 calc R U . . .
P5 P 0.92123(5) 0.86152(7) 0.83340(5) 0.0188(2) Uani 1 1 d . . . . .
F1 F 0.89309(11) 0.86565(15) 0.74982(12) 0.0254(5) Uani 1 1 d . . . . .
F2 F 0.99092(11) 0.85898(14) 0.82355(12) 0.0220(5) Uani 1 1 d . . . . .
F3 F 0.94989(12) 0.85882(15) 0.91633(12) 0.0274(6) Uani 1 1 d . . . . .
F4 F 0.85179(12) 0.86541(17) 0.84236(14) 0.0342(6) Uani 1 1 d . . . . .
F5 F 0.92482(11) 0.96116(14) 0.83586(13) 0.0259(5) Uani 1 1 d . . . . .
F6 F 0.91833(12) 0.76304(15) 0.83031(13) 0.0288(6) Uani 1 1 d . . . . .
P6 P 0.37311(5) 0.22523(7) 0.48924(6) 0.0219(2) Uani 1 1 d . . . . .
F7 F 0.32229(13) 0.27640(18) 0.43360(16) 0.0451(8) Uani 1 1 d . . . . .
F8 F 0.39065(14) 0.1746(2) 0.42844(16) 0.0516(9) Uani 1 1 d . . . . .
F9 F 0.42526(13) 0.17411(16) 0.54467(15) 0.0386(7) Uani 1 1 d . . . . .
F10 F 0.35710(14) 0.2757(2) 0.55053(16) 0.0487(8) Uani 1 1 d . . . . .
F11 F 0.42541(12) 0.29266(17) 0.48643(15) 0.0388(7) Uani 1 1 d . . . . .
F12 F 0.32222(12) 0.15676(16) 0.49184(15) 0.0380(7) Uani 1 1 d . . . . .
C25 C 0.3392(6) 0.0984(6) 0.2798(4) 0.119(4) Uani 1 1 d . . . . .
H25A H 0.3492 0.1439 0.3142 0.143 Uiso 1 1 calc R U . . .
H25B H 0.2955 0.0813 0.2756 0.143 Uiso 1 1 calc R U . . .
Cl1 Cl 0.34279(14) 0.13853(16) 0.19720(13) 0.1125(9) Uani 1 1 d . . . . .
Cl2 Cl 0.38712(10) 0.01680(14) 0.31244(11) 0.0830(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3367(10) . ?
Au1 P3 2.3390(10) . ?
Au2 P2 2.3105(10) . ?
Au2 P4 2.3115(10) . ?
P1 C1B 1.815(4) . ?
P1 C1 1.818(4) . ?
P1 C1A 1.820(4) . ?
P2 C1D 1.805(4) . ?
P2 C8 1.809(4) . ?
P2 C1C 1.819(4) . ?
P3 C1E 1.817(4) . ?
P3 C13 1.820(4) . ?
P3 C1F 1.820(4) . ?
P4 C20 1.808(4) . ?
P4 C1H 1.813(4) . ?
P4 C1G 1.815(4) . ?
C1 C6 1.394(5) . ?
C1 C2 1.395(5) . ?
C2 C3 1.386(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.388(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.376(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.390(5) . ?
C5 H5 0.9500 . ?
C6 O1 1.391(4) . ?
C7 C8 1.388(5) . ?
C7 C12 1.388(5) . ?
C7 O1 1.394(4) . ?
C8 C9 1.403(5) . ?
C9 C10 1.381(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.379(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.387(6) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.394(5) . ?
C13 C18 1.402(5) . ?
C14 C15 1.394(5) . ?
C14 H14 0.9500 . ?
C15 C16 1.379(6) . ?
C15 H15 0.9500 . ?
C16 C17 1.389(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.385(5) . ?
C17 H17 0.9500 . ?
C18 O2 1.390(5) . ?
C19 C24 1.384(5) . ?
C19 O2 1.396(4) . ?
C19 C20 1.398(5) . ?
C20 C21 1.396(5) . ?
C21 C22 1.390(6) . ?
C21 H21 0.9500 . ?
C22 C23 1.389(6) . ?
C22 H22 0.9500 . ?
C23 C24 1.384(6) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C1A C2A 1.393(5) . ?
C1A C6A 1.397(5) . ?
C2A C3A 1.392(5) . ?
C2A H2A 0.9500 . ?
C3A C4A 1.385(6) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.387(6) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.387(6) . ?
C5A H5A 0.9500 . ?
C6A H6A 0.9500 . ?
C1B C6B 1.386(6) . ?
C1B C2B 1.401(6) . ?
C2B C3B 1.386(6) . ?
C2B H2B 0.9500 . ?
C3B C4B 1.383(7) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.378(7) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.390(6) . ?
C5B H5B 0.9500 . ?
C6B H6B 0.9500 . ?
C1C C2C 1.384(6) . ?
C1C C6C 1.393(6) . ?
C2C C3C 1.394(6) . ?
C2C H2C 0.9500 . ?
C3C C4C 1.374(6) . ?
C3C H3C 0.9500 . ?
C4C C5C 1.381(6) . ?
C4C H4C 0.9500 . ?
C5C C6C 1.387(6) . ?
C5C H5C 0.9500 . ?
C6C H6C 0.9500 . ?
C1D C2D 1.382(5) . ?
C1D C6D 1.405(6) . ?
C2D C3D 1.393(6) . ?
C2D H2D 0.9500 . ?
C3D C4D 1.382(6) . ?
C3D H3D 0.9500 . ?
C4D C5D 1.381(6) . ?
C4D H4D 0.9500 . ?
C5D C6D 1.387(6) . ?
C5D H5D 0.9500 . ?
C6D H6D 0.9500 . ?
C1E C6E 1.386(5) . ?
C1E C2E 1.396(5) . ?
C2E C3E 1.387(6) . ?
C2E H2E 0.9500 . ?
C3E C4E 1.385(6) . ?
C3E H3E 0.9500 . ?
C4E C5E 1.386(6) . ?
C4E H4E 0.9500 . ?
C5E C6E 1.378(6) . ?
C5E H5E 0.9500 . ?
C6E H6E 0.9500 . ?
C1F C6F 1.393(5) . ?
C1F C2F 1.397(5) . ?
C2F C3F 1.386(6) . ?
C2F H2F 0.9500 . ?
C3F C4F 1.388(6) . ?
C3F H3F 0.9500 . ?
C4F C5F 1.372(6) . ?
C4F H4F 0.9500 . ?
C5F C6F 1.390(6) . ?
C5F H5F 0.9500 . ?
C6F H6F 0.9500 . ?
C1G C2G 1.387(6) . ?
C1G C6G 1.398(5) . ?
C2G C3G 1.393(6) . ?
C2G H2G 0.9500 . ?
C3G C4G 1.387(6) . ?
C3G H3G 0.9500 . ?
C4G C5G 1.370(6) . ?
C4G H4G 0.9500 . ?
C5G C6G 1.381(6) . ?
C5G H5G 0.9500 . ?
C6G H6G 0.9500 . ?
C1H C6H 1.396(5) . ?
C1H C2H 1.398(5) . ?
C2H C3H 1.383(6) . ?
C2H H2H 0.9500 . ?
C3H C4H 1.392(6) . ?
C3H H3H 0.9500 . ?
C4H C5H 1.387(6) . ?
C4H H4H 0.9500 . ?
C5H C6H 1.380(6) . ?
C5H H5H 0.9500 . ?
C6H H6H 0.9500 . ?
P5 F6 1.595(3) . ?
P5 F4 1.602(3) . ?
P5 F3 1.605(3) . ?
P5 F2 1.613(2) . ?
P5 F5 1.614(3) . ?
P5 F1 1.617(3) . ?
P6 F7 1.585(3) . ?
P6 F10 1.590(3) . ?
P6 F12 1.594(3) . ?
P6 F8 1.597(3) . ?
P6 F9 1.598(3) . ?
P6 F11 1.606(3) . ?
C25 Cl2 1.711(10) . ?
C25 Cl1 1.794(8) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 P3 166.26(3) . . ?
P2 Au2 P4 169.52(3) . . ?
C1B P1 C1 106.16(18) . . ?
C1B P1 C1A 107.12(18) . . ?
C1 P1 C1A 102.58(17) . . ?
C1B P1 Au1 113.06(14) . . ?
C1 P1 Au1 118.74(12) . . ?
C1A P1 Au1 108.17(12) . . ?
C1D P2 C8 103.10(18) . . ?
C1D P2 C1C 106.88(18) . . ?
C8 P2 C1C 105.81(18) . . ?
C1D P2 Au2 118.91(13) . . ?
C8 P2 Au2 112.14(13) . . ?
C1C P2 Au2 109.09(13) . . ?
C1E P3 C13 106.63(17) . . ?
C1E P3 C1F 105.40(17) . . ?
C13 P3 C1F 104.09(17) . . ?
C1E P3 Au1 116.29(13) . . ?
C13 P3 Au1 114.79(12) . . ?
C1F P3 Au1 108.58(13) . . ?
C20 P4 C1H 108.26(18) . . ?
C20 P4 C1G 104.67(18) . . ?
C1H P4 C1G 102.93(18) . . ?
C20 P4 Au2 111.06(13) . . ?
C1H P4 Au2 111.12(13) . . ?
C1G P4 Au2 118.09(13) . . ?
C6 C1 C2 118.1(3) . . ?
C6 C1 P1 119.8(3) . . ?
C2 C1 P1 122.0(3) . . ?
C3 C2 C1 120.8(4) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C2 C3 C4 119.7(4) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
C5 C4 C3 120.6(4) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C4 C5 C6 119.2(4) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
C5 C6 O1 122.0(3) . . ?
C5 C6 C1 121.4(4) . . ?
O1 C6 C1 116.5(3) . . ?
C8 C7 C12 121.9(4) . . ?
C8 C7 O1 117.2(3) . . ?
C12 C7 O1 120.8(3) . . ?
C7 C8 C9 118.3(4) . . ?
C7 C8 P2 118.6(3) . . ?
C9 C8 P2 122.8(3) . . ?
C10 C9 C8 120.3(4) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C11 C10 C9 120.1(4) . . ?
C11 C10 H10 119.9 . . ?
C9 C10 H10 119.9 . . ?
C10 C11 C12 121.1(4) . . ?
C10 C11 H11 119.5 . . ?
C12 C11 H11 119.5 . . ?
C11 C12 C7 118.3(4) . . ?
C11 C12 H12 120.8 . . ?
C7 C12 H12 120.8 . . ?
C6 O1 C7 117.1(3) . . ?
C14 C13 C18 117.5(3) . . ?
C14 C13 P3 122.6(3) . . ?
C18 C13 P3 119.6(3) . . ?
C15 C14 C13 121.4(4) . . ?
C15 C14 H14 119.3 . . ?
C13 C14 H14 119.3 . . ?
C16 C15 C14 119.4(4) . . ?
C16 C15 H15 120.3 . . ?
C14 C15 H15 120.3 . . ?
C15 C16 C17 120.8(4) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C18 C17 C16 119.0(4) . . ?
C18 C17 H17 120.5 . . ?
C16 C17 H17 120.5 . . ?
C17 C18 O2 122.8(3) . . ?
C17 C18 C13 121.7(4) . . ?
O2 C18 C13 115.4(3) . . ?
C24 C19 O2 122.0(3) . . ?
C24 C19 C20 121.7(4) . . ?
O2 C19 C20 116.1(3) . . ?
C21 C20 C19 118.5(3) . . ?
C21 C20 P4 123.1(3) . . ?
C19 C20 P4 118.3(3) . . ?
C22 C21 C20 120.0(4) . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C23 C22 C21 120.4(4) . . ?
C23 C22 H22 119.8 . . ?
C21 C22 H22 119.8 . . ?
C24 C23 C22 120.3(4) . . ?
C24 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C19 C24 C23 119.1(4) . . ?
C19 C24 H24 120.4 . . ?
C23 C24 H24 120.4 . . ?
C18 O2 C19 118.4(3) . . ?
C2A C1A C6A 119.4(4) . . ?
C2A C1A P1 118.3(3) . . ?
C6A C1A P1 121.8(3) . . ?
C3A C2A C1A 120.3(4) . . ?
C3A C2A H2A 119.8 . . ?
C1A C2A H2A 119.8 . . ?
C4A C3A C2A 119.7(4) . . ?
C4A C3A H3A 120.1 . . ?
C2A C3A H3A 120.1 . . ?
C3A C4A C5A 120.4(4) . . ?
C3A C4A H4A 119.8 . . ?
C5A C4A H4A 119.8 . . ?
C4A C5A C6A 120.1(4) . . ?
C4A C5A H5A 120.0 . . ?
C6A C5A H5A 120.0 . . ?
C5A C6A C1A 120.1(4) . . ?
C5A C6A H6A 120.0 . . ?
C1A C6A H6A 120.0 . . ?
C6B C1B C2B 119.4(4) . . ?
C6B C1B P1 120.3(3) . . ?
C2B C1B P1 120.3(3) . . ?
C3B C2B C1B 119.7(4) . . ?
C3B C2B H2B 120.1 . . ?
C1B C2B H2B 120.1 . . ?
C4B C3B C2B 120.2(4) . . ?
C4B C3B H3B 119.9 . . ?
C2B C3B H3B 119.9 . . ?
C5B C4B C3B 120.4(4) . . ?
C5B C4B H4B 119.8 . . ?
C3B C4B H4B 119.8 . . ?
C4B C5B C6B 119.9(4) . . ?
C4B C5B H5B 120.1 . . ?
C6B C5B H5B 120.1 . . ?
C1B C6B C5B 120.3(4) . . ?
C1B C6B H6B 119.8 . . ?
C5B C6B H6B 119.8 . . ?
C2C C1C C6C 120.3(4) . . ?
C2C C1C P2 122.1(3) . . ?
C6C C1C P2 117.6(3) . . ?
C1C C2C C3C 119.5(4) . . ?
C1C C2C H2C 120.2 . . ?
C3C C2C H2C 120.2 . . ?
C4C C3C C2C 120.1(4) . . ?
C4C C3C H3C 119.9 . . ?
C2C C3C H3C 119.9 . . ?
C3C C4C C5C 120.4(4) . . ?
C3C C4C H4C 119.8 . . ?
C5C C4C H4C 119.8 . . ?
C4C C5C C6C 120.2(4) . . ?
C4C C5C H5C 119.9 . . ?
C6C C5C H5C 119.9 . . ?
C5C C6C C1C 119.4(4) . . ?
C5C C6C H6C 120.3 . . ?
C1C C6C H6C 120.3 . . ?
C2D C1D C6D 119.7(4) . . ?
C2D C1D P2 120.1(3) . . ?
C6D C1D P2 120.2(3) . . ?
C1D C2D C3D 120.5(4) . . ?
C1D C2D H2D 119.8 . . ?
C3D C2D H2D 119.8 . . ?
C4D C3D C2D 119.5(4) . . ?
C4D C3D H3D 120.3 . . ?
C2D C3D H3D 120.3 . . ?
C5D C4D C3D 120.7(4) . . ?
C5D C4D H4D 119.7 . . ?
C3D C4D H4D 119.7 . . ?
C4D C5D C6D 120.2(4) . . ?
C4D C5D H5D 119.9 . . ?
C6D C5D H5D 119.9 . . ?
C5D C6D C1D 119.4(4) . . ?
C5D C6D H6D 120.3 . . ?
C1D C6D H6D 120.3 . . ?
C6E C1E C2E 120.1(3) . . ?
C6E C1E P3 118.4(3) . . ?
C2E C1E P3 121.3(3) . . ?
C3E C2E C1E 119.7(4) . . ?
C3E C2E H2E 120.1 . . ?
C1E C2E H2E 120.1 . . ?
C4E C3E C2E 119.6(4) . . ?
C4E C3E H3E 120.2 . . ?
C2E C3E H3E 120.2 . . ?
C3E C4E C5E 120.5(4) . . ?
C3E C4E H4E 119.8 . . ?
C5E C4E H4E 119.8 . . ?
C6E C5E C4E 120.2(4) . . ?
C6E C5E H5E 119.9 . . ?
C4E C5E H5E 119.9 . . ?
C5E C6E C1E 119.8(4) . . ?
C5E C6E H6E 120.1 . . ?
C1E C6E H6E 120.1 . . ?
C6F C1F C2F 119.4(4) . . ?
C6F C1F P3 120.1(3) . . ?
C2F C1F P3 120.4(3) . . ?
C3F C2F C1F 119.8(4) . . ?
C3F C2F H2F 120.1 . . ?
C1F C2F H2F 120.1 . . ?
C2F C3F C4F 120.2(4) . . ?
C2F C3F H3F 119.9 . . ?
C4F C3F H3F 119.9 . . ?
C5F C4F C3F 120.3(4) . . ?
C5F C4F H4F 119.8 . . ?
C3F C4F H4F 119.8 . . ?
C4F C5F C6F 120.0(4) . . ?
C4F C5F H5F 120.0 . . ?
C6F C5F H5F 120.0 . . ?
C5F C6F C1F 120.2(4) . . ?
C5F C6F H6F 119.9 . . ?
C1F C6F H6F 119.9 . . ?
C2G C1G C6G 119.7(4) . . ?
C2G C1G P4 122.8(3) . . ?
C6G C1G P4 117.1(3) . . ?
C1G C2G C3G 119.9(4) . . ?
C1G C2G H2G 120.1 . . ?
C3G C2G H2G 120.1 . . ?
C4G C3G C2G 120.0(4) . . ?
C4G C3G H3G 120.0 . . ?
C2G C3G H3G 120.0 . . ?
C5G C4G C3G 119.8(4) . . ?
C5G C4G H4G 120.1 . . ?
C3G C4G H4G 120.1 . . ?
C4G C5G C6G 121.2(4) . . ?
C4G C5G H5G 119.4 . . ?
C6G C5G H5G 119.4 . . ?
C5G C6G C1G 119.4(4) . . ?
C5G C6G H6G 120.3 . . ?
C1G C6G H6G 120.3 . . ?
C6H C1H C2H 119.4(4) . . ?
C6H C1H P4 120.7(3) . . ?
C2H C1H P4 119.8(3) . . ?
C3H C2H C1H 120.2(4) . . ?
C3H C2H H2H 119.9 . . ?
C1H C2H H2H 119.9 . . ?
C2H C3H C4H 119.8(4) . . ?
C2H C3H H3H 120.1 . . ?
C4H C3H H3H 120.1 . . ?
C5H C4H C3H 120.4(4) . . ?
C5H C4H H4H 119.8 . . ?
C3H C4H H4H 119.8 . . ?
C6H C5H C4H 119.9(4) . . ?
C6H C5H H5H 120.0 . . ?
C4H C5H H5H 120.0 . . ?
C5H C6H C1H 120.3(4) . . ?
C5H C6H H6H 119.8 . . ?
C1H C6H H6H 119.8 . . ?
F6 P5 F4 90.77(14) . . ?
F6 P5 F3 90.76(14) . . ?
F4 P5 F3 90.58(14) . . ?
F6 P5 F2 90.00(13) . . ?
F4 P5 F2 179.03(16) . . ?
F3 P5 F2 89.99(13) . . ?
F6 P5 F5 179.21(15) . . ?
F4 P5 F5 89.92(14) . . ?
F3 P5 F5 89.61(13) . . ?
F2 P5 F5 89.31(13) . . ?
F6 P5 F1 90.07(13) . . ?
F4 P5 F1 89.96(14) . . ?
F3 P5 F1 179.00(15) . . ?
F2 P5 F1 89.46(13) . . ?
F5 P5 F1 89.55(13) . . ?
F7 P6 F10 90.32(18) . . ?
F7 P6 F12 90.53(15) . . ?
F10 P6 F12 91.32(17) . . ?
F7 P6 F8 90.53(18) . . ?
F10 P6 F8 178.86(18) . . ?
F12 P6 F8 89.43(17) . . ?
F7 P6 F9 179.00(18) . . ?
F10 P6 F9 90.24(17) . . ?
F12 P6 F9 90.29(15) . . ?
F8 P6 F9 88.89(17) . . ?
F7 P6 F11 90.30(15) . . ?
F10 P6 F11 89.60(17) . . ?
F12 P6 F11 178.76(17) . . ?
F8 P6 F11 89.64(17) . . ?
F9 P6 F11 88.88(15) . . ?
Cl2 C25 Cl1 116.8(6) . . ?
Cl2 C25 H25A 108.1 . . ?
Cl1 C25 H25A 108.1 . . ?
Cl2 C25 H25B 108.1 . . ?
Cl1 C25 H25B 108.1 . . ?
H25A C25 H25B 107.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1B P1 C1 C6 62.0(3) . . . . ?
C1A P1 C1 C6 174.2(3) . . . . ?
Au1 P1 C1 C6 -66.6(3) . . . . ?
C1B P1 C1 C2 -122.1(3) . . . . ?
C1A P1 C1 C2 -9.8(4) . . . . ?
Au1 P1 C1 C2 109.3(3) . . . . ?
C6 C1 C2 C3 2.2(6) . . . . ?
P1 C1 C2 C3 -173.8(3) . . . . ?
C1 C2 C3 C4 2.2(6) . . . . ?
C2 C3 C4 C5 -4.0(6) . . . . ?
C3 C4 C5 C6 1.3(6) . . . . ?
C4 C5 C6 O1 -178.6(4) . . . . ?
C4 C5 C6 C1 3.3(6) . . . . ?
C2 C1 C6 C5 -5.0(6) . . . . ?
P1 C1 C6 C5 171.1(3) . . . . ?
C2 C1 C6 O1 176.8(3) . . . . ?
P1 C1 C6 O1 -7.1(5) . . . . ?
C12 C7 C8 C9 -1.1(6) . . . . ?
O1 C7 C8 C9 -177.5(3) . . . . ?
C12 C7 C8 P2 172.7(3) . . . . ?
O1 C7 C8 P2 -3.7(5) . . . . ?
C1D P2 C8 C7 -85.0(3) . . . . ?
C1C P2 C8 C7 162.9(3) . . . . ?
Au2 P2 C8 C7 44.1(3) . . . . ?
C1D P2 C8 C9 88.5(4) . . . . ?
C1C P2 C8 C9 -23.6(4) . . . . ?
Au2 P2 C8 C9 -142.4(3) . . . . ?
C7 C8 C9 C10 0.8(6) . . . . ?
P2 C8 C9 C10 -172.7(3) . . . . ?
C8 C9 C10 C11 -0.3(7) . . . . ?
C9 C10 C11 C12 0.0(7) . . . . ?
C10 C11 C12 C7 -0.2(7) . . . . ?
C8 C7 C12 C11 0.8(6) . . . . ?
O1 C7 C12 C11 177.1(4) . . . . ?
C5 C6 O1 C7 36.4(5) . . . . ?
C1 C6 O1 C7 -145.4(3) . . . . ?
C8 C7 O1 C6 -139.9(4) . . . . ?
C12 C7 O1 C6 43.6(5) . . . . ?
C1E P3 C13 C14 -122.3(3) . . . . ?
C1F P3 C13 C14 -11.2(4) . . . . ?
Au1 P3 C13 C14 107.3(3) . . . . ?
C1E P3 C13 C18 64.7(3) . . . . ?
C1F P3 C13 C18 175.9(3) . . . . ?
Au1 P3 C13 C18 -65.6(3) . . . . ?
C18 C13 C14 C15 1.3(6) . . . . ?
P3 C13 C14 C15 -171.7(3) . . . . ?
C13 C14 C15 C16 0.9(6) . . . . ?
C14 C15 C16 C17 -1.9(6) . . . . ?
C15 C16 C17 C18 0.7(6) . . . . ?
C16 C17 C18 O2 178.2(3) . . . . ?
C16 C17 C18 C13 1.6(6) . . . . ?
C14 C13 C18 C17 -2.6(6) . . . . ?
P3 C13 C18 C17 170.7(3) . . . . ?
C14 C13 C18 O2 -179.4(3) . . . . ?
P3 C13 C18 O2 -6.1(4) . . . . ?
C24 C19 C20 C21 -1.8(6) . . . . ?
O2 C19 C20 C21 -175.7(3) . . . . ?
C24 C19 C20 P4 175.6(3) . . . . ?
O2 C19 C20 P4 1.8(5) . . . . ?
C1H P4 C20 C21 -13.4(4) . . . . ?
C1G P4 C20 C21 95.9(3) . . . . ?
Au2 P4 C20 C21 -135.6(3) . . . . ?
C1H P4 C20 C19 169.3(3) . . . . ?
C1G P4 C20 C19 -81.4(3) . . . . ?
Au2 P4 C20 C19 47.0(3) . . . . ?
C19 C20 C21 C22 1.4(6) . . . . ?
P4 C20 C21 C22 -175.9(3) . . . . ?
C20 C21 C22 C23 -0.1(6) . . . . ?
C21 C22 C23 C24 -0.8(7) . . . . ?
O2 C19 C24 C23 174.4(4) . . . . ?
C20 C19 C24 C23 0.9(6) . . . . ?
C22 C23 C24 C19 0.4(6) . . . . ?
C17 C18 O2 C19 35.6(5) . . . . ?
C13 C18 O2 C19 -147.6(3) . . . . ?
C24 C19 O2 C18 44.3(5) . . . . ?
C20 C19 O2 C18 -141.9(3) . . . . ?
C1B P1 C1A C2A -162.4(3) . . . . ?
C1 P1 C1A C2A 86.0(3) . . . . ?
Au1 P1 C1A C2A -40.3(3) . . . . ?
C1B P1 C1A C6A 25.8(4) . . . . ?
C1 P1 C1A C6A -85.8(3) . . . . ?
Au1 P1 C1A C6A 148.0(3) . . . . ?
C6A C1A C2A C3A 1.9(6) . . . . ?
P1 C1A C2A C3A -170.1(3) . . . . ?
C1A C2A C3A C4A -1.2(6) . . . . ?
C2A C3A C4A C5A -0.6(6) . . . . ?
C3A C4A C5A C6A 1.7(7) . . . . ?
C4A C5A C6A C1A -1.0(7) . . . . ?
C2A C1A C6A C5A -0.7(6) . . . . ?
P1 C1A C6A C5A 170.9(3) . . . . ?
C1 P1 C1B C6B -143.9(3) . . . . ?
C1A P1 C1B C6B 107.0(3) . . . . ?
Au1 P1 C1B C6B -12.0(4) . . . . ?
C1 P1 C1B C2B 37.1(4) . . . . ?
C1A P1 C1B C2B -72.0(4) . . . . ?
Au1 P1 C1B C2B 169.0(3) . . . . ?
C6B C1B C2B C3B -2.8(6) . . . . ?
P1 C1B C2B C3B 176.2(3) . . . . ?
C1B C2B C3B C4B 1.5(7) . . . . ?
C2B C3B C4B C5B 0.9(7) . . . . ?
C3B C4B C5B C6B -2.0(7) . . . . ?
C2B C1B C6B C5B 1.6(6) . . . . ?
P1 C1B C6B C5B -177.4(3) . . . . ?
C4B C5B C6B C1B 0.8(6) . . . . ?
C1D P2 C1C C2C 11.3(4) . . . . ?
C8 P2 C1C C2C 120.7(4) . . . . ?
Au2 P2 C1C C2C -118.5(3) . . . . ?
C1D P2 C1C C6C -171.2(3) . . . . ?
C8 P2 C1C C6C -61.8(4) . . . . ?
Au2 P2 C1C C6C 59.1(3) . . . . ?
C6C C1C C2C C3C 1.1(6) . . . . ?
P2 C1C C2C C3C 178.6(3) . . . . ?
C1C C2C C3C C4C -0.5(7) . . . . ?
C2C C3C C4C C5C -0.1(7) . . . . ?
C3C C4C C5C C6C 0.1(7) . . . . ?
C4C C5C C6C C1C 0.5(7) . . . . ?
C2C C1C C6C C5C -1.1(6) . . . . ?
P2 C1C C6C C5C -178.8(3) . . . . ?
C8 P2 C1D C2D 138.1(3) . . . . ?
C1C P2 C1D C2D -110.6(3) . . . . ?
Au2 P2 C1D C2D 13.3(4) . . . . ?
C8 P2 C1D C6D -41.7(4) . . . . ?
C1C P2 C1D C6D 69.5(4) . . . . ?
Au2 P2 C1D C6D -166.5(3) . . . . ?
C6D C1D C2D C3D 0.9(6) . . . . ?
P2 C1D C2D C3D -178.9(3) . . . . ?
C1D C2D C3D C4D -0.8(6) . . . . ?
C2D C3D C4D C5D -0.3(7) . . . . ?
C3D C4D C5D C6D 1.4(7) . . . . ?
C4D C5D C6D C1D -1.3(7) . . . . ?
C2D C1D C6D C5D 0.1(7) . . . . ?
P2 C1D C6D C5D 179.9(4) . . . . ?
C13 P3 C1E C6E -169.0(3) . . . . ?
C1F P3 C1E C6E 80.8(3) . . . . ?
Au1 P3 C1E C6E -39.5(3) . . . . ?
C13 P3 C1E C2E 15.3(4) . . . . ?
C1F P3 C1E C2E -94.9(3) . . . . ?
Au1 P3 C1E C2E 144.8(3) . . . . ?
C6E C1E C2E C3E 1.1(6) . . . . ?
P3 C1E C2E C3E 176.7(3) . . . . ?
C1E C2E C3E C4E -1.6(6) . . . . ?
C2E C3E C4E C5E 1.0(6) . . . . ?
C3E C4E C5E C6E 0.3(6) . . . . ?
C4E C5E C6E C1E -0.9(6) . . . . ?
C2E C1E C6E C5E 0.2(6) . . . . ?
P3 C1E C6E C5E -175.5(3) . . . . ?
C1E P3 C1F C6F -141.8(3) . . . . ?
C13 P3 C1F C6F 106.2(3) . . . . ?
Au1 P3 C1F C6F -16.5(3) . . . . ?
C1E P3 C1F C2F 41.9(4) . . . . ?
C13 P3 C1F C2F -70.2(3) . . . . ?
Au1 P3 C1F C2F 167.1(3) . . . . ?
C6F C1F C2F C3F -1.1(6) . . . . ?
P3 C1F C2F C3F 175.3(3) . . . . ?
C1F C2F C3F C4F -0.5(6) . . . . ?
C2F C3F C4F C5F 2.0(7) . . . . ?
C3F C4F C5F C6F -1.9(7) . . . . ?
C4F C5F C6F C1F 0.4(6) . . . . ?
C2F C1F C6F C5F 1.2(6) . . . . ?
P3 C1F C6F C5F -175.2(3) . . . . ?
C20 P4 C1G C2G -1.1(4) . . . . ?
C1H P4 C1G C2G 112.0(3) . . . . ?
Au2 P4 C1G C2G -125.2(3) . . . . ?
C20 P4 C1G C6G -174.1(3) . . . . ?
C1H P4 C1G C6G -61.0(3) . . . . ?
Au2 P4 C1G C6G 61.8(3) . . . . ?
C6G C1G C2G C3G 0.7(6) . . . . ?
P4 C1G C2G C3G -172.2(3) . . . . ?
C1G C2G C3G C4G -0.3(6) . . . . ?
C2G C3G C4G C5G -0.5(6) . . . . ?
C3G C4G C5G C6G 0.9(7) . . . . ?
C4G C5G C6G C1G -0.6(7) . . . . ?
C2G C1G C6G C5G -0.2(6) . . . . ?
P4 C1G C6G C5G 173.0(3) . . . . ?
C20 P4 C1H C6H 78.4(4) . . . . ?
C1G P4 C1H C6H -32.0(4) . . . . ?
Au2 P4 C1H C6H -159.4(3) . . . . ?
C20 P4 C1H C2H -106.5(3) . . . . ?
C1G P4 C1H C2H 143.1(3) . . . . ?
Au2 P4 C1H C2H 15.8(4) . . . . ?
C6H C1H C2H C3H 1.3(6) . . . . ?
P4 C1H C2H C3H -173.9(4) . . . . ?
C1H C2H C3H C4H 0.4(7) . . . . ?
C2H C3H C4H C5H -1.7(7) . . . . ?
C3H C4H C5H C6H 1.3(7) . . . . ?
C4H C5H C6H C1H 0.5(6) . . . . ?
C2H C1H C6H C5H -1.8(6) . . . . ?
P4 C1H C6H C5H 173.4(3) . . . . ?

_refine_diff_density_max         2.227
_refine_diff_density_min         -1.546
_refine_diff_density_rms         0.133



#############################################################################
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_complex_5
_database_code_depnum_ccdc_archive 'CCDC 1472202'
_audit_update_record             
;
2016-09-19 deposited with the CCDC.
2016-10-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(F6 Sb), C H2 Cl2'
_chemical_formula_sum            'C73 H58 Au2 Cl2 F12 O2 P4 Sb2'
_chemical_formula_weight         2027.40

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   22.6394(16)
_cell_length_b                   16.3498(11)
_cell_length_c                   20.1213(14)
_cell_angle_alpha                90
_cell_angle_beta                 105.2300(10)
_cell_angle_gamma                90
_cell_volume                     7186.3(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9110
_cell_measurement_theta_min      2.243
_cell_measurement_theta_max      28.364

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.874
_exptl_crystal_F_000             3896
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    5.054
_shelx_estimated_absorpt_T_min   0.342
_shelx_estimated_absorpt_T_max   0.606
_exptl_absorpt_correction_T_min  0.332
_exptl_absorpt_correction_T_max  0.576
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/4 (Bruker,2014) was used for absorption correction.
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            170498
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_av_R_equivalents  0.0413
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         0.932
_diffrn_reflns_theta_max         28.395
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             17976
_reflns_number_gt                15013
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_solution    'XT (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0342P)²+27.8667P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17976
_refine_ls_number_parameters     884
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0302
_refine_ls_wR_factor_ref         0.0767
_refine_ls_wR_factor_gt          0.0699
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.21290(2) 0.34995(2) 0.79435(2) 0.01622(4) Uani 1 1 d . . . . .
Au2 Au 0.25901(2) 0.45270(2) 0.65047(2) 0.01836(4) Uani 1 1 d . . . . .
P1 P 0.18443(5) 0.22263(6) 0.74254(5) 0.01563(18) Uani 1 1 d . . . . .
P2 P 0.15711(5) 0.47363(6) 0.59414(5) 0.01631(19) Uani 1 1 d . . . . .
P3 P 0.24335(5) 0.45877(6) 0.87097(5) 0.01620(19) Uani 1 1 d . . . . .
P4 P 0.36403(5) 0.44098(6) 0.69114(5) 0.0203(2) Uani 1 1 d . . . . .
C1 C 0.22760(19) 0.1915(2) 0.68204(19) 0.0177(7) Uani 1 1 d . . . . .
C2 C 0.2711(2) 0.1286(3) 0.6965(2) 0.0218(8) Uani 1 1 d . . . . .
H2 H 0.2753 0.0960 0.7366 0.026 Uiso 1 1 calc R U . . .
C3 C 0.3083(2) 0.1136(3) 0.6529(2) 0.0275(9) Uani 1 1 d . . . . .
H3 H 0.3370 0.0700 0.6625 0.033 Uiso 1 1 calc R U . . .
C4 C 0.3036(2) 0.1620(3) 0.5954(2) 0.0291(10) Uani 1 1 d . . . . .
H4 H 0.3303 0.1529 0.5668 0.035 Uiso 1 1 calc R U . . .
C5 C 0.2602(2) 0.2237(3) 0.5790(2) 0.0250(9) Uani 1 1 d . . . . .
H5 H 0.2570 0.2566 0.5393 0.030 Uiso 1 1 calc R U . . .
C6 C 0.22125(18) 0.2369(2) 0.62135(19) 0.0183(8) Uani 1 1 d . . . . .
C7 C 0.14576(19) 0.3160(2) 0.54204(19) 0.0194(8) Uani 1 1 d . . . . .
C8 C 0.13118(19) 0.3981(2) 0.52693(19) 0.0181(8) Uani 1 1 d . . . . .
C9 C 0.09586(19) 0.4181(3) 0.4609(2) 0.0217(8) Uani 1 1 d . . . . .
H9 H 0.0858 0.4737 0.4493 0.026 Uiso 1 1 calc R U . . .
C10 C 0.0754(2) 0.3574(3) 0.4123(2) 0.0267(9) Uani 1 1 d . . . . .
H10 H 0.0515 0.3716 0.3675 0.032 Uiso 1 1 calc R U . . .
C11 C 0.0895(2) 0.2759(3) 0.4285(2) 0.0263(9) Uani 1 1 d . . . . .
H11 H 0.0748 0.2346 0.3951 0.032 Uiso 1 1 calc R U . . .
C12 C 0.1252(2) 0.2549(3) 0.4936(2) 0.0234(8) Uani 1 1 d . . . . .
H12 H 0.1355 0.1993 0.5048 0.028 Uiso 1 1 calc R U . . .
O1 O 0.17812(14) 0.29851(16) 0.60977(13) 0.0200(6) Uani 1 1 d . . . . .
C13 C 0.23668(18) 0.5624(2) 0.83756(19) 0.0179(8) Uani 1 1 d . . . . .
C14 C 0.1923(2) 0.6166(2) 0.8480(2) 0.0219(8) Uani 1 1 d . . . . .
H14 H 0.1669 0.6006 0.8766 0.026 Uiso 1 1 calc R U . . .
C15 C 0.1846(2) 0.6932(3) 0.8175(2) 0.0274(9) Uani 1 1 d . . . . .
H15 H 0.1551 0.7301 0.8263 0.033 Uiso 1 1 calc R U . . .
C16 C 0.2205(2) 0.7160(3) 0.7738(2) 0.0328(10) Uani 1 1 d . . . . .
H16 H 0.2140 0.7674 0.7510 0.039 Uiso 1 1 calc R U . . .
C17 C 0.2654(2) 0.6640(3) 0.7636(2) 0.0291(10) Uani 1 1 d . . . . .
H17 H 0.2900 0.6795 0.7340 0.035 Uiso 1 1 calc R U . . .
C18 C 0.2744(2) 0.5893(3) 0.7969(2) 0.0227(8) Uani 1 1 d . . . . .
C19 C 0.3741(2) 0.5690(3) 0.7820(2) 0.0247(9) Uani 1 1 d . . . . .
C20 C 0.3994(2) 0.5328(3) 0.7336(2) 0.0238(9) Uani 1 1 d . . . . .
C21 C 0.4546(2) 0.5640(3) 0.7250(3) 0.0358(11) Uani 1 1 d . . . . .
H21 H 0.4724 0.5407 0.6915 0.043 Uiso 1 1 calc R U . . .
C22 C 0.4831(3) 0.6287(4) 0.7651(3) 0.0478(15) Uani 1 1 d . . . . .
H22 H 0.5201 0.6505 0.7586 0.057 Uiso 1 1 calc R U . . .
C23 C 0.4576(3) 0.6619(4) 0.8147(3) 0.0467(15) Uani 1 1 d . . . . .
H23 H 0.4782 0.7049 0.8434 0.056 Uiso 1 1 calc R U . . .
C24 C 0.4024(2) 0.6329(3) 0.8229(3) 0.0362(11) Uani 1 1 d . . . . .
H24 H 0.3844 0.6567 0.8560 0.043 Uiso 1 1 calc R U . . .
O2 O 0.32002(14) 0.53522(18) 0.79008(15) 0.0236(6) Uani 1 1 d . . . . .
C1A C 0.20220(19) 0.1448(2) 0.80962(19) 0.0186(8) Uani 1 1 d . . . . .
C2A C 0.2419(2) 0.1627(3) 0.8735(2) 0.0237(9) Uani 1 1 d . . . . .
H2A H 0.2575 0.2166 0.8831 0.028 Uiso 1 1 calc R U . . .
C3A C 0.2590(2) 0.1021(3) 0.9234(2) 0.0306(10) Uani 1 1 d . . . . .
H3A H 0.2864 0.1143 0.9668 0.037 Uiso 1 1 calc R U . . .
C4A C 0.2358(2) 0.0240(3) 0.9094(2) 0.0313(10) Uani 1 1 d . . . . .
H4A H 0.2475 -0.0175 0.9434 0.038 Uiso 1 1 calc R U . . .
C5A C 0.1959(2) 0.0056(3) 0.8467(2) 0.0303(10) Uani 1 1 d . . . . .
H5A H 0.1802 -0.0484 0.8377 0.036 Uiso 1 1 calc R U . . .
C6A C 0.1784(2) 0.0661(3) 0.7962(2) 0.0244(9) Uani 1 1 d . . . . .
H6A H 0.1506 0.0536 0.7532 0.029 Uiso 1 1 calc R U . . .
C1B C 0.10466(18) 0.2074(2) 0.69902(19) 0.0168(7) Uani 1 1 d . . . . .
C2B C 0.06085(19) 0.2380(3) 0.7301(2) 0.0224(8) Uani 1 1 d . . . . .
H2B H 0.0731 0.2703 0.7706 0.027 Uiso 1 1 calc R U . . .
C3B C -0.0007(2) 0.2209(3) 0.7014(2) 0.0265(9) Uani 1 1 d . . . . .
H3B H -0.0304 0.2400 0.7234 0.032 Uiso 1 1 calc R U . . .
C4B C -0.0190(2) 0.1762(3) 0.6413(2) 0.0236(8) Uani 1 1 d . . . . .
H4B H -0.0612 0.1652 0.6217 0.028 Uiso 1 1 calc R U . . .
C5B C 0.0244(2) 0.1471(3) 0.6091(2) 0.0235(8) Uani 1 1 d . . . . .
H5B H 0.0119 0.1174 0.5672 0.028 Uiso 1 1 calc R U . . .
C6B C 0.08599(19) 0.1619(2) 0.6387(2) 0.0198(8) Uani 1 1 d . . . . .
H6B H 0.1157 0.1407 0.6177 0.024 Uiso 1 1 calc R U . . .
C1C C 0.14489(19) 0.5741(2) 0.5542(2) 0.0193(8) Uani 1 1 d . . . . .
C2C C 0.0865(2) 0.6082(3) 0.5350(2) 0.0243(9) Uani 1 1 d . . . . .
H2C H 0.0522 0.5775 0.5396 0.029 Uiso 1 1 calc R U . . .
C3C C 0.0786(2) 0.6870(3) 0.5090(2) 0.0278(9) Uani 1 1 d . . . . .
H3C H 0.0387 0.7103 0.4955 0.033 Uiso 1 1 calc R U . . .
C4C C 0.1282(2) 0.7317(3) 0.5027(3) 0.0339(11) Uani 1 1 d . . . . .
H4C H 0.1226 0.7863 0.4862 0.041 Uiso 1 1 calc R U . . .
C5C C 0.1863(3) 0.6979(3) 0.5201(3) 0.0392(12) Uani 1 1 d . . . . .
H5C H 0.2202 0.7286 0.5143 0.047 Uiso 1 1 calc R U . . .
C6C C 0.1946(2) 0.6185(3) 0.5462(2) 0.0280(9) Uani 1 1 d . . . . .
H6C H 0.2343 0.5950 0.5584 0.034 Uiso 1 1 calc R U . . .
C1D C 0.10129(18) 0.4712(2) 0.64452(19) 0.0186(8) Uani 1 1 d . . . . .
C2D C 0.1072(2) 0.5305(3) 0.6957(2) 0.0259(9) Uani 1 1 d . . . . .
H2D H 0.1420 0.5654 0.7068 0.031 Uiso 1 1 calc R U . . .
C3D C 0.0618(2) 0.5381(3) 0.7306(2) 0.0294(10) Uani 1 1 d . . . . .
H3D H 0.0657 0.5781 0.7657 0.035 Uiso 1 1 calc R U . . .
C4D C 0.0111(2) 0.4876(3) 0.7141(2) 0.0272(9) Uani 1 1 d . . . . .
H4D H -0.0200 0.4936 0.7376 0.033 Uiso 1 1 calc R U . . .
C5D C 0.0055(2) 0.4287(3) 0.6639(3) 0.0309(10) Uani 1 1 d . . . . .
H5D H -0.0294 0.3940 0.6530 0.037 Uiso 1 1 calc R U . . .
C6D C 0.0506(2) 0.4197(3) 0.6289(2) 0.0258(9) Uani 1 1 d . . . . .
H6D H 0.0468 0.3786 0.5946 0.031 Uiso 1 1 calc R U . . .
C1E C 0.32101(19) 0.4485(3) 0.9248(2) 0.0201(8) Uani 1 1 d . . . . .
C2E C 0.3504(2) 0.3732(3) 0.9302(2) 0.0241(9) Uani 1 1 d . . . . .
H2E H 0.3306 0.3279 0.9040 0.029 Uiso 1 1 calc R U . . .
C3E C 0.4091(2) 0.3642(3) 0.9742(2) 0.0340(11) Uani 1 1 d . . . . .
H3E H 0.4293 0.3128 0.9778 0.041 Uiso 1 1 calc R U . . .
C4E C 0.4375(2) 0.4295(4) 1.0121(3) 0.0379(12) Uani 1 1 d . . . . .
H4E H 0.4773 0.4229 1.0421 0.045 Uiso 1 1 calc R U . . .
C5E C 0.4091(2) 0.5046(4) 1.0073(3) 0.0413(12) Uani 1 1 d . . . . .
H5E H 0.4291 0.5493 1.0342 0.050 Uiso 1 1 calc R U . . .
C6E C 0.3507(2) 0.5147(3) 0.9626(2) 0.0308(10) Uani 1 1 d . . . . .
H6E H 0.3313 0.5667 0.9582 0.037 Uiso 1 1 calc R U . . .
C1F C 0.19355(19) 0.4613(2) 0.9284(2) 0.0189(8) Uani 1 1 d . . . . .
C2F C 0.2144(2) 0.4878(3) 0.9966(2) 0.0278(9) Uani 1 1 d . . . . .
H2F H 0.2568 0.4974 1.0161 0.033 Uiso 1 1 calc R U . . .
C3F C 0.1729(2) 0.5000(3) 1.0359(2) 0.0341(11) Uani 1 1 d . . . . .
H3F H 0.1872 0.5176 1.0824 0.041 Uiso 1 1 calc R U . . .
C4F C 0.1112(2) 0.4869(3) 1.0080(2) 0.0311(10) Uani 1 1 d . . . . .
H4F H 0.0832 0.4966 1.0349 0.037 Uiso 1 1 calc R U . . .
C5F C 0.0899(2) 0.4596(3) 0.9408(2) 0.0274(9) Uani 1 1 d . . . . .
H5F H 0.0474 0.4505 0.9218 0.033 Uiso 1 1 calc R U . . .
C6F C 0.1310(2) 0.4456(2) 0.9009(2) 0.0229(8) Uani 1 1 d . . . . .
H6F H 0.1165 0.4255 0.8553 0.028 Uiso 1 1 calc R U . . .
C1G C 0.3942(2) 0.3625(3) 0.7543(2) 0.0256(9) Uani 1 1 d . . . . .
C2G C 0.3587(2) 0.2955(3) 0.7606(2) 0.0239(9) Uani 1 1 d . . . . .
H2G H 0.3177 0.2918 0.7329 0.029 Uiso 1 1 calc R U . . .
C3G C 0.3827(2) 0.2337(3) 0.8073(2) 0.0283(9) Uani 1 1 d . . . . .
H3G H 0.3578 0.1882 0.8118 0.034 Uiso 1 1 calc R U . . .
C4G C 0.4422(2) 0.2379(3) 0.8472(2) 0.0362(11) Uani 1 1 d . . . . .
H4G H 0.4587 0.1953 0.8787 0.043 Uiso 1 1 calc R U . . .
C5G C 0.4781(3) 0.3050(4) 0.8409(3) 0.0501(15) Uani 1 1 d . . . . .
H5G H 0.5192 0.3080 0.8683 0.060 Uiso 1 1 calc R U . . .
C6G C 0.4545(2) 0.3675(4) 0.7954(3) 0.0442(14) Uani 1 1 d . . . . .
H6G H 0.4791 0.4135 0.7919 0.053 Uiso 1 1 calc R U . . .
C1H C 0.39869(19) 0.4239(3) 0.6204(2) 0.0207(8) Uani 1 1 d . . . . .
C2H C 0.3859(2) 0.4807(3) 0.5668(2) 0.0287(9) Uani 1 1 d . . . . .
H2H H 0.3593 0.5253 0.5676 0.034 Uiso 1 1 calc R U . . .
C3H C 0.4122(2) 0.4720(3) 0.5123(2) 0.0306(10) Uani 1 1 d . . . . .
H3H H 0.4037 0.5107 0.4759 0.037 Uiso 1 1 calc R U . . .
C4H C 0.4508(2) 0.4068(3) 0.5110(3) 0.0329(10) Uani 1 1 d . . . . .
H4H H 0.4696 0.4015 0.4742 0.040 Uiso 1 1 calc R U . . .
C5H C 0.4620(3) 0.3494(3) 0.5630(3) 0.0410(12) Uani 1 1 d . . . . .
H5H H 0.4877 0.3040 0.5614 0.049 Uiso 1 1 calc R U . . .
C6H C 0.4357(2) 0.3576(3) 0.6180(3) 0.0358(11) Uani 1 1 d . . . . .
H6H H 0.4432 0.3178 0.6536 0.043 Uiso 1 1 calc R U . . .
Sb1 Sb 0.07783(2) 0.85483(2) 0.66298(2) 0.02430(6) Uani 1 1 d . . . . .
F1 F 0.07805(15) 0.74066(15) 0.66595(14) 0.0388(7) Uani 1 1 d . . . . .
F2 F 0.11013(13) 0.85803(16) 0.75941(13) 0.0298(6) Uani 1 1 d . . . . .
F3 F 0.07666(13) 0.96999(15) 0.66185(14) 0.0323(6) Uani 1 1 d . . . . .
F4 F 0.04319(15) 0.85564(16) 0.56716(13) 0.0363(7) Uani 1 1 d . . . . .
F5 F 0.15703(15) 0.8566(2) 0.65113(18) 0.0481(8) Uani 1 1 d . . . . .
F6 F -0.00128(12) 0.85497(16) 0.67648(13) 0.0290(6) Uani 1 1 d . . . . .
Sb2 Sb 0.62461(2) 0.22344(2) 1.00253(2) 0.03198(7) Uani 1 1 d . . . . .
F7 F 0.6134(3) 0.1592(4) 1.0758(3) 0.111(2) Uani 1 1 d . . . . .
F8 F 0.68502(19) 0.2853(2) 1.0603(3) 0.0886(17) Uani 1 1 d . . . . .
F9 F 0.6296(2) 0.2900(4) 0.9318(2) 0.106(2) Uani 1 1 d . . . . .
F10 F 0.56246(13) 0.16302(18) 0.94400(18) 0.0441(8) Uani 1 1 d . . . . .
F11 F 0.68188(17) 0.1497(3) 0.9922(4) 0.121(3) Uani 1 1 d . . . . .
F12 F 0.56356(18) 0.2931(3) 1.0177(3) 0.0804(14) Uani 1 1 d . . . . .
C25 C 0.6487(7) 0.4233(8) 0.7434(10) 0.290(15) Uani 1 1 d . . . A 1
H25A H 0.6663 0.3907 0.7117 0.348 Uiso 1 1 calc R U . A 1
H25B H 0.6836 0.4571 0.7690 0.348 Uiso 1 1 calc R U . A 1
Cl1 Cl 0.6512(3) 0.3628(3) 0.7939(3) 0.228(3) Uani 1 1 d . . . A 1
Cl2A Cl 0.61190(18) 0.4968(2) 0.68519(16) 0.0883(14) Uani 0.687(8) 1 d . . P A
1
Cl2B Cl 0.5874(7) 0.4388(12) 0.7138(11) 0.231(10) Uani 0.313(8) 1 d . . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P3 2.3366(10) . ?
Au1 P1 2.3414(10) . ?
Au2 P4 2.3103(11) . ?
Au2 P2 2.3131(10) . ?
P1 C1B 1.805(4) . ?
P1 C1A 1.821(4) . ?
P1 C1 1.822(4) . ?
P2 C8 1.812(4) . ?
P2 C1D 1.816(4) . ?
P2 C1C 1.817(4) . ?
P3 C1E 1.814(4) . ?
P3 C13 1.814(4) . ?
P3 C1F 1.815(4) . ?
P4 C20 1.807(4) . ?
P4 C1G 1.809(4) . ?
P4 C1H 1.819(4) . ?
C1 C2 1.401(6) . ?
C1 C6 1.404(5) . ?
C2 C3 1.388(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.382(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.386(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.395(6) . ?
C5 H5 0.9500 . ?
C6 O1 1.379(5) . ?
C7 C12 1.389(5) . ?
C7 C8 1.396(5) . ?
C7 O1 1.397(4) . ?
C8 C9 1.398(5) . ?
C9 C10 1.385(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.389(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.389(6) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.396(6) . ?
C13 C18 1.401(6) . ?
C14 C15 1.387(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.395(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.382(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.381(6) . ?
C17 H17 0.9500 . ?
C18 O2 1.393(5) . ?
C19 C24 1.380(6) . ?
C19 C20 1.385(6) . ?
C19 O2 1.391(5) . ?
C20 C21 1.402(6) . ?
C21 C22 1.384(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.389(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.386(7) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C1A C2A 1.393(6) . ?
C1A C6A 1.394(6) . ?
C2A C3A 1.391(6) . ?
C2A H2A 0.9500 . ?
C3A C4A 1.381(7) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.380(7) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.398(6) . ?
C5A H5A 0.9500 . ?
C6A H6A 0.9500 . ?
C1B C6B 1.391(5) . ?
C1B C2B 1.396(5) . ?
C2B C3B 1.389(6) . ?
C2B H2B 0.9500 . ?
C3B C4B 1.381(6) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.393(6) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.386(6) . ?
C5B H5B 0.9500 . ?
C6B H6B 0.9500 . ?
C1C C6C 1.385(6) . ?
C1C C2C 1.393(6) . ?
C2C C3C 1.385(6) . ?
C2C H2C 0.9500 . ?
C3C C4C 1.374(7) . ?
C3C H3C 0.9500 . ?
C4C C5C 1.384(7) . ?
C4C H4C 0.9500 . ?
C5C C6C 1.394(6) . ?
C5C H5C 0.9500 . ?
C6C H6C 0.9500 . ?
C1D C6D 1.391(6) . ?
C1D C2D 1.396(6) . ?
C2D C3D 1.394(6) . ?
C2D H2D 0.9500 . ?
C3D C4D 1.381(7) . ?
C3D H3D 0.9500 . ?
C4D C5D 1.378(7) . ?
C4D H4D 0.9500 . ?
C5D C6D 1.392(6) . ?
C5D H5D 0.9500 . ?
C6D H6D 0.9500 . ?
C1E C2E 1.390(6) . ?
C1E C6E 1.390(6) . ?
C2E C3E 1.397(6) . ?
C2E H2E 0.9500 . ?
C3E C4E 1.370(8) . ?
C3E H3E 0.9500 . ?
C4E C5E 1.378(8) . ?
C4E H4E 0.9500 . ?
C5E C6E 1.400(7) . ?
C5E H5E 0.9500 . ?
C6E H6E 0.9500 . ?
C1F C2F 1.398(6) . ?
C1F C6F 1.402(6) . ?
C2F C3F 1.392(6) . ?
C2F H2F 0.9500 . ?
C3F C4F 1.379(7) . ?
C3F H3F 0.9500 . ?
C4F C5F 1.384(7) . ?
C4F H4F 0.9500 . ?
C5F C6F 1.397(6) . ?
C5F H5F 0.9500 . ?
C6F H6F 0.9500 . ?
C1G C2G 1.384(6) . ?
C1G C6G 1.400(7) . ?
C2G C3G 1.390(6) . ?
C2G H2G 0.9500 . ?
C3G C4G 1.378(7) . ?
C3G H3G 0.9500 . ?
C4G C5G 1.390(8) . ?
C4G H4G 0.9500 . ?
C5G C6G 1.383(7) . ?
C5G H5G 0.9500 . ?
C6G H6G 0.9500 . ?
C1H C6H 1.378(6) . ?
C1H C2H 1.394(6) . ?
C2H C3H 1.385(6) . ?
C2H H2H 0.9500 . ?
C3H C4H 1.383(7) . ?
C3H H3H 0.9500 . ?
C4H C5H 1.379(7) . ?
C4H H4H 0.9500 . ?
C5H C6H 1.394(7) . ?
C5H H5H 0.9500 . ?
C6H H6H 0.9500 . ?
Sb1 F1 1.868(3) . ?
Sb1 F5 1.870(3) . ?
Sb1 F6 1.881(3) . ?
Sb1 F4 1.881(3) . ?
Sb1 F3 1.883(2) . ?
Sb1 F2 1.886(3) . ?
Sb2 F9 1.819(4) . ?
Sb2 F11 1.822(4) . ?
Sb2 F8 1.846(3) . ?
Sb2 F10 1.863(3) . ?
Sb2 F12 1.877(4) . ?
Sb2 F7 1.880(5) . ?
C25 Cl1 1.409(12) . ?
C25 Cl2A 1.731(10) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P3 Au1 P1 165.87(3) . . ?
P4 Au2 P2 170.76(4) . . ?
C1B P1 C1A 105.16(18) . . ?
C1B P1 C1 106.34(18) . . ?
C1A P1 C1 104.32(18) . . ?
C1B P1 Au1 117.49(13) . . ?
C1A P1 Au1 108.04(13) . . ?
C1 P1 Au1 114.34(13) . . ?
C8 P2 C1D 105.36(19) . . ?
C8 P2 C1C 107.74(18) . . ?
C1D P2 C1C 102.67(18) . . ?
C8 P2 Au2 110.53(14) . . ?
C1D P2 Au2 118.27(13) . . ?
C1C P2 Au2 111.52(14) . . ?
C1E P3 C13 106.30(19) . . ?
C1E P3 C1F 106.80(18) . . ?
C13 P3 C1F 102.10(18) . . ?
C1E P3 Au1 113.26(14) . . ?
C13 P3 Au1 119.03(12) . . ?
C1F P3 Au1 108.21(14) . . ?
C20 P4 C1G 102.6(2) . . ?
C20 P4 C1H 105.62(19) . . ?
C1G P4 C1H 106.3(2) . . ?
C20 P4 Au2 112.69(15) . . ?
C1G P4 Au2 118.12(15) . . ?
C1H P4 Au2 110.54(14) . . ?
C2 C1 C6 118.3(4) . . ?
C2 C1 P1 122.5(3) . . ?
C6 C1 P1 118.9(3) . . ?
C3 C2 C1 120.5(4) . . ?
C3 C2 H2 119.7 . . ?
C1 C2 H2 119.7 . . ?
C4 C3 C2 120.1(4) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C3 C4 C5 120.6(4) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 H4 119.7 . . ?
C4 C5 C6 119.3(4) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
O1 C6 C5 122.9(4) . . ?
O1 C6 C1 116.1(3) . . ?
C5 C6 C1 120.9(4) . . ?
C12 C7 C8 121.5(4) . . ?
C12 C7 O1 122.0(4) . . ?
C8 C7 O1 116.3(3) . . ?
C7 C8 C9 118.4(4) . . ?
C7 C8 P2 118.8(3) . . ?
C9 C8 P2 122.8(3) . . ?
C10 C9 C8 120.3(4) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C9 C10 C11 120.5(4) . . ?
C9 C10 H10 119.8 . . ?
C11 C10 H10 119.8 . . ?
C12 C11 C10 120.0(4) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C7 C12 C11 119.2(4) . . ?
C7 C12 H12 120.4 . . ?
C11 C12 H12 120.4 . . ?
C6 O1 C7 118.8(3) . . ?
C14 C13 C18 117.6(4) . . ?
C14 C13 P3 122.0(3) . . ?
C18 C13 P3 120.4(3) . . ?
C15 C14 C13 121.2(4) . . ?
C15 C14 H14 119.4 . . ?
C13 C14 H14 119.4 . . ?
C14 C15 C16 119.6(4) . . ?
C14 C15 H15 120.2 . . ?
C16 C15 H15 120.2 . . ?
C17 C16 C15 120.2(4) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C18 C17 C16 119.5(4) . . ?
C18 C17 H17 120.3 . . ?
C16 C17 H17 120.3 . . ?
C17 C18 O2 122.2(4) . . ?
C17 C18 C13 121.7(4) . . ?
O2 C18 C13 116.1(4) . . ?
C24 C19 C20 122.0(4) . . ?
C24 C19 O2 121.1(4) . . ?
C20 C19 O2 116.9(4) . . ?
C19 C20 C21 118.6(4) . . ?
C19 C20 P4 118.3(3) . . ?
C21 C20 P4 122.8(3) . . ?
C22 C21 C20 120.0(4) . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C21 C22 C23 120.0(5) . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C24 C23 C22 120.6(5) . . ?
C24 C23 H23 119.7 . . ?
C22 C23 H23 119.7 . . ?
C19 C24 C23 118.7(5) . . ?
C19 C24 H24 120.6 . . ?
C23 C24 H24 120.6 . . ?
C19 O2 C18 117.2(3) . . ?
C2A C1A C6A 119.7(4) . . ?
C2A C1A P1 120.1(3) . . ?
C6A C1A P1 120.2(3) . . ?
C3A C2A C1A 120.4(4) . . ?
C3A C2A H2A 119.8 . . ?
C1A C2A H2A 119.8 . . ?
C4A C3A C2A 119.6(4) . . ?
C4A C3A H3A 120.2 . . ?
C2A C3A H3A 120.2 . . ?
C5A C4A C3A 120.7(4) . . ?
C5A C4A H4A 119.6 . . ?
C3A C4A H4A 119.6 . . ?
C4A C5A C6A 120.2(4) . . ?
C4A C5A H5A 119.9 . . ?
C6A C5A H5A 119.9 . . ?
C1A C6A C5A 119.5(4) . . ?
C1A C6A H6A 120.3 . . ?
C5A C6A H6A 120.3 . . ?
C6B C1B C2B 119.5(4) . . ?
C6B C1B P1 122.2(3) . . ?
C2B C1B P1 118.1(3) . . ?
C3B C2B C1B 119.7(4) . . ?
C3B C2B H2B 120.2 . . ?
C1B C2B H2B 120.2 . . ?
C4B C3B C2B 120.5(4) . . ?
C4B C3B H3B 119.8 . . ?
C2B C3B H3B 119.8 . . ?
C3B C4B C5B 120.1(4) . . ?
C3B C4B H4B 119.9 . . ?
C5B C4B H4B 119.9 . . ?
C6B C5B C4B 119.5(4) . . ?
C6B C5B H5B 120.2 . . ?
C4B C5B H5B 120.2 . . ?
C5B C6B C1B 120.6(4) . . ?
C5B C6B H6B 119.7 . . ?
C1B C6B H6B 119.7 . . ?
C6C C1C C2C 119.8(4) . . ?
C6C C1C P2 119.5(3) . . ?
C2C C1C P2 120.6(3) . . ?
C3C C2C C1C 119.9(4) . . ?
C3C C2C H2C 120.1 . . ?
C1C C2C H2C 120.1 . . ?
C4C C3C C2C 120.1(4) . . ?
C4C C3C H3C 120.0 . . ?
C2C C3C H3C 120.0 . . ?
C3C C4C C5C 120.7(4) . . ?
C3C C4C H4C 119.6 . . ?
C5C C4C H4C 119.6 . . ?
C4C C5C C6C 119.4(5) . . ?
C4C C5C H5C 120.3 . . ?
C6C C5C H5C 120.3 . . ?
C1C C6C C5C 120.0(4) . . ?
C1C C6C H6C 120.0 . . ?
C5C C6C H6C 120.0 . . ?
C6D C1D C2D 120.0(4) . . ?
C6D C1D P2 122.8(3) . . ?
C2D C1D P2 116.8(3) . . ?
C3D C2D C1D 119.5(4) . . ?
C3D C2D H2D 120.2 . . ?
C1D C2D H2D 120.2 . . ?
C4D C3D C2D 120.2(4) . . ?
C4D C3D H3D 119.9 . . ?
C2D C3D H3D 119.9 . . ?
C5D C4D C3D 120.3(4) . . ?
C5D C4D H4D 119.8 . . ?
C3D C4D H4D 119.8 . . ?
C4D C5D C6D 120.4(4) . . ?
C4D C5D H5D 119.8 . . ?
C6D C5D H5D 119.8 . . ?
C1D C6D C5D 119.6(4) . . ?
C1D C6D H6D 120.2 . . ?
C5D C6D H6D 120.2 . . ?
C2E C1E C6E 119.6(4) . . ?
C2E C1E P3 119.9(3) . . ?
C6E C1E P3 120.5(3) . . ?
C1E C2E C3E 120.0(4) . . ?
C1E C2E H2E 120.0 . . ?
C3E C2E H2E 120.0 . . ?
C4E C3E C2E 119.9(5) . . ?
C4E C3E H3E 120.0 . . ?
C2E C3E H3E 120.0 . . ?
C3E C4E C5E 120.9(5) . . ?
C3E C4E H4E 119.5 . . ?
C5E C4E H4E 119.5 . . ?
C4E C5E C6E 119.6(5) . . ?
C4E C5E H5E 120.2 . . ?
C6E C5E H5E 120.2 . . ?
C1E C6E C5E 120.0(5) . . ?
C1E C6E H6E 120.0 . . ?
C5E C6E H6E 120.0 . . ?
C2F C1F C6F 119.3(4) . . ?
C2F C1F P3 121.7(3) . . ?
C6F C1F P3 118.5(3) . . ?
C3F C2F C1F 119.9(4) . . ?
C3F C2F H2F 120.1 . . ?
C1F C2F H2F 120.1 . . ?
C4F C3F C2F 120.6(4) . . ?
C4F C3F H3F 119.7 . . ?
C2F C3F H3F 119.7 . . ?
C3F C4F C5F 120.2(4) . . ?
C3F C4F H4F 119.9 . . ?
C5F C4F H4F 119.9 . . ?
C4F C5F C6F 120.0(4) . . ?
C4F C5F H5F 120.0 . . ?
C6F C5F H5F 120.0 . . ?
C5F C6F C1F 120.0(4) . . ?
C5F C6F H6F 120.0 . . ?
C1F C6F H6F 120.0 . . ?
C2G C1G C6G 119.5(4) . . ?
C2G C1G P4 120.3(3) . . ?
C6G C1G P4 120.2(3) . . ?
C1G C2G C3G 120.3(4) . . ?
C1G C2G H2G 119.9 . . ?
C3G C2G H2G 119.9 . . ?
C4G C3G C2G 120.4(4) . . ?
C4G C3G H3G 119.8 . . ?
C2G C3G H3G 119.8 . . ?
C3G C4G C5G 119.5(4) . . ?
C3G C4G H4G 120.2 . . ?
C5G C4G H4G 120.2 . . ?
C6G C5G C4G 120.7(5) . . ?
C6G C5G H5G 119.7 . . ?
C4G C5G H5G 119.7 . . ?
C5G C6G C1G 119.7(5) . . ?
C5G C6G H6G 120.2 . . ?
C1G C6G H6G 120.2 . . ?
C6H C1H C2H 120.1(4) . . ?
C6H C1H P4 122.6(3) . . ?
C2H C1H P4 117.3(3) . . ?
C3H C2H C1H 119.9(4) . . ?
C3H C2H H2H 120.0 . . ?
C1H C2H H2H 120.0 . . ?
C4H C3H C2H 120.0(4) . . ?
C4H C3H H3H 120.0 . . ?
C2H C3H H3H 120.0 . . ?
C5H C4H C3H 120.0(4) . . ?
C5H C4H H4H 120.0 . . ?
C3H C4H H4H 120.0 . . ?
C4H C5H C6H 120.4(4) . . ?
C4H C5H H5H 119.8 . . ?
C6H C5H H5H 119.8 . . ?
C1H C6H C5H 119.5(4) . . ?
C1H C6H H6H 120.2 . . ?
C5H C6H H6H 120.2 . . ?
F1 Sb1 F5 91.42(14) . . ?
F1 Sb1 F6 89.50(13) . . ?
F5 Sb1 F6 178.67(14) . . ?
F1 Sb1 F4 92.11(12) . . ?
F5 Sb1 F4 91.42(14) . . ?
F6 Sb1 F4 89.52(12) . . ?
F1 Sb1 F3 178.54(12) . . ?
F5 Sb1 F3 89.66(13) . . ?
F6 Sb1 F3 89.40(12) . . ?
F4 Sb1 F3 88.84(12) . . ?
F1 Sb1 F2 89.87(12) . . ?
F5 Sb1 F2 90.29(14) . . ?
F6 Sb1 F2 88.74(11) . . ?
F4 Sb1 F2 177.35(12) . . ?
F3 Sb1 F2 89.15(12) . . ?
F9 Sb2 F11 96.6(3) . . ?
F9 Sb2 F8 88.7(2) . . ?
F11 Sb2 F8 90.13(18) . . ?
F9 Sb2 F10 90.82(18) . . ?
F11 Sb2 F10 91.09(16) . . ?
F8 Sb2 F10 178.73(15) . . ?
F9 Sb2 F12 87.9(3) . . ?
F11 Sb2 F12 175.3(3) . . ?
F8 Sb2 F12 91.19(18) . . ?
F10 Sb2 F12 87.62(16) . . ?
F9 Sb2 F7 175.2(3) . . ?
F11 Sb2 F7 88.1(3) . . ?
F8 Sb2 F7 92.5(2) . . ?
F10 Sb2 F7 88.0(2) . . ?
F12 Sb2 F7 87.4(3) . . ?
Cl1 C25 Cl2A 153.6(15) . . ?
Cl1 C25 H25A 98.1 . . ?
Cl2A C25 H25A 98.1 . . ?
Cl1 C25 H25B 98.1 . . ?
Cl2A C25 H25B 98.1 . . ?
H25A C25 H25B 103.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1B P1 C1 C2 -120.3(3) . . . . ?
C1A P1 C1 C2 -9.4(4) . . . . ?
Au1 P1 C1 C2 108.4(3) . . . . ?
C1B P1 C1 C6 65.7(3) . . . . ?
C1A P1 C1 C6 176.5(3) . . . . ?
Au1 P1 C1 C6 -65.7(3) . . . . ?
C6 C1 C2 C3 2.0(6) . . . . ?
P1 C1 C2 C3 -172.0(3) . . . . ?
C1 C2 C3 C4 1.5(7) . . . . ?
C2 C3 C4 C5 -2.7(7) . . . . ?
C3 C4 C5 C6 0.3(7) . . . . ?
C4 C5 C6 O1 178.0(4) . . . . ?
C4 C5 C6 C1 3.4(6) . . . . ?
C2 C1 C6 O1 -179.5(3) . . . . ?
P1 C1 C6 O1 -5.2(5) . . . . ?
C2 C1 C6 C5 -4.5(6) . . . . ?
P1 C1 C6 C5 169.8(3) . . . . ?
C12 C7 C8 C9 -1.0(6) . . . . ?
O1 C7 C8 C9 -176.5(4) . . . . ?
C12 C7 C8 P2 177.5(3) . . . . ?
O1 C7 C8 P2 2.0(5) . . . . ?
C1D P2 C8 C7 -82.4(4) . . . . ?
C1C P2 C8 C7 168.5(3) . . . . ?
Au2 P2 C8 C7 46.4(3) . . . . ?
C1D P2 C8 C9 96.0(4) . . . . ?
C1C P2 C8 C9 -13.1(4) . . . . ?
Au2 P2 C8 C9 -135.2(3) . . . . ?
C7 C8 C9 C10 0.8(6) . . . . ?
P2 C8 C9 C10 -177.6(3) . . . . ?
C8 C9 C10 C11 0.2(7) . . . . ?
C9 C10 C11 C12 -1.0(7) . . . . ?
C8 C7 C12 C11 0.2(6) . . . . ?
O1 C7 C12 C11 175.4(4) . . . . ?
C10 C11 C12 C7 0.9(7) . . . . ?
C5 C6 O1 C7 39.0(5) . . . . ?
C1 C6 O1 C7 -146.1(4) . . . . ?
C12 C7 O1 C6 39.8(5) . . . . ?
C8 C7 O1 C6 -144.8(4) . . . . ?
C1E P3 C13 C14 -123.0(3) . . . . ?
C1F P3 C13 C14 -11.2(4) . . . . ?
Au1 P3 C13 C14 107.8(3) . . . . ?
C1E P3 C13 C18 60.4(4) . . . . ?
C1F P3 C13 C18 172.2(3) . . . . ?
Au1 P3 C13 C18 -68.8(3) . . . . ?
C18 C13 C14 C15 2.0(6) . . . . ?
P3 C13 C14 C15 -174.7(3) . . . . ?
C13 C14 C15 C16 2.0(7) . . . . ?
C14 C15 C16 C17 -3.1(7) . . . . ?
C15 C16 C17 C18 0.2(7) . . . . ?
C16 C17 C18 O2 -178.3(4) . . . . ?
C16 C17 C18 C13 4.0(7) . . . . ?
C14 C13 C18 C17 -5.0(6) . . . . ?
P3 C13 C18 C17 171.8(3) . . . . ?
C14 C13 C18 O2 177.2(3) . . . . ?
P3 C13 C18 O2 -6.1(5) . . . . ?
C24 C19 C20 C21 -1.8(7) . . . . ?
O2 C19 C20 C21 -178.7(4) . . . . ?
C24 C19 C20 P4 171.8(4) . . . . ?
O2 C19 C20 P4 -5.1(6) . . . . ?
C1G P4 C20 C19 -80.3(4) . . . . ?
C1H P4 C20 C19 168.5(4) . . . . ?
Au2 P4 C20 C19 47.8(4) . . . . ?
C1G P4 C20 C21 93.0(4) . . . . ?
C1H P4 C20 C21 -18.1(5) . . . . ?
Au2 P4 C20 C21 -138.9(4) . . . . ?
C19 C20 C21 C22 1.0(8) . . . . ?
P4 C20 C21 C22 -172.3(5) . . . . ?
C20 C21 C22 C23 1.1(10) . . . . ?
C21 C22 C23 C24 -2.5(10) . . . . ?
C20 C19 C24 C23 0.4(8) . . . . ?
O2 C19 C24 C23 177.2(5) . . . . ?
C22 C23 C24 C19 1.8(9) . . . . ?
C24 C19 O2 C18 45.3(6) . . . . ?
C20 C19 O2 C18 -137.8(4) . . . . ?
C17 C18 O2 C19 33.4(6) . . . . ?
C13 C18 O2 C19 -148.7(4) . . . . ?
C1B P1 C1A C2A -142.9(3) . . . . ?
C1 P1 C1A C2A 105.3(3) . . . . ?
Au1 P1 C1A C2A -16.7(4) . . . . ?
C1B P1 C1A C6A 40.0(4) . . . . ?
C1 P1 C1A C6A -71.7(4) . . . . ?
Au1 P1 C1A C6A 166.3(3) . . . . ?
C6A C1A C2A C3A 1.4(6) . . . . ?
P1 C1A C2A C3A -175.6(3) . . . . ?
C1A C2A C3A C4A -0.6(7) . . . . ?
C2A C3A C4A C5A -0.1(7) . . . . ?
C3A C4A C5A C6A 0.1(8) . . . . ?
C2A C1A C6A C5A -1.4(6) . . . . ?
P1 C1A C6A C5A 175.6(3) . . . . ?
C4A C5A C6A C1A 0.7(7) . . . . ?
C1A P1 C1B C6B -96.4(3) . . . . ?
C1 P1 C1B C6B 13.9(4) . . . . ?
Au1 P1 C1B C6B 143.5(3) . . . . ?
C1A P1 C1B C2B 79.1(3) . . . . ?
C1 P1 C1B C2B -170.6(3) . . . . ?
Au1 P1 C1B C2B -41.0(3) . . . . ?
C6B C1B C2B C3B 1.6(6) . . . . ?
P1 C1B C2B C3B -174.0(3) . . . . ?
C1B C2B C3B C4B -2.1(6) . . . . ?
C2B C3B C4B C5B 0.7(7) . . . . ?
C3B C4B C5B C6B 1.4(6) . . . . ?
C4B C5B C6B C1B -1.9(6) . . . . ?
C2B C1B C6B C5B 0.4(6) . . . . ?
P1 C1B C6B C5B 175.9(3) . . . . ?
C8 P2 C1C C6C -106.4(4) . . . . ?
C1D P2 C1C C6C 142.7(3) . . . . ?
Au2 P2 C1C C6C 15.0(4) . . . . ?
C8 P2 C1C C2C 76.8(4) . . . . ?
C1D P2 C1C C2C -34.1(4) . . . . ?
Au2 P2 C1C C2C -161.7(3) . . . . ?
C6C C1C C2C C3C -1.2(6) . . . . ?
P2 C1C C2C C3C 175.6(3) . . . . ?
C1C C2C C3C C4C -0.5(6) . . . . ?
C2C C3C C4C C5C 2.0(7) . . . . ?
C3C C4C C5C C6C -1.8(8) . . . . ?
C2C C1C C6C C5C 1.3(7) . . . . ?
P2 C1C C6C C5C -175.5(4) . . . . ?
C4C C5C C6C C1C 0.2(8) . . . . ?
C8 P2 C1D C6D -0.7(4) . . . . ?
C1C P2 C1D C6D 112.0(4) . . . . ?
Au2 P2 C1D C6D -124.8(3) . . . . ?
C8 P2 C1D C2D -173.4(3) . . . . ?
C1C P2 C1D C2D -60.7(4) . . . . ?
Au2 P2 C1D C2D 62.5(3) . . . . ?
C6D C1D C2D C3D -0.6(6) . . . . ?
P2 C1D C2D C3D 172.3(3) . . . . ?
C1D C2D C3D C4D -0.4(7) . . . . ?
C2D C3D C4D C5D 0.9(7) . . . . ?
C3D C4D C5D C6D -0.3(7) . . . . ?
C2D C1D C6D C5D 1.1(6) . . . . ?
P2 C1D C6D C5D -171.4(3) . . . . ?
C4D C5D C6D C1D -0.6(7) . . . . ?
C13 P3 C1E C2E -148.3(3) . . . . ?
C1F P3 C1E C2E 103.3(3) . . . . ?
Au1 P3 C1E C2E -15.7(4) . . . . ?
C13 P3 C1E C6E 34.1(4) . . . . ?
C1F P3 C1E C6E -74.4(4) . . . . ?
Au1 P3 C1E C6E 166.6(3) . . . . ?
C6E C1E C2E C3E 0.8(6) . . . . ?
P3 C1E C2E C3E -176.9(3) . . . . ?
C1E C2E C3E C4E 0.3(7) . . . . ?
C2E C3E C4E C5E -0.3(8) . . . . ?
C3E C4E C5E C6E -0.6(8) . . . . ?
C2E C1E C6E C5E -1.8(7) . . . . ?
P3 C1E C6E C5E 175.9(4) . . . . ?
C4E C5E C6E C1E 1.7(8) . . . . ?
C1E P3 C1F C2F 25.7(4) . . . . ?
C13 P3 C1F C2F -85.7(4) . . . . ?
Au1 P3 C1F C2F 147.9(3) . . . . ?
C1E P3 C1F C6F -162.1(3) . . . . ?
C13 P3 C1F C6F 86.5(3) . . . . ?
Au1 P3 C1F C6F -39.9(3) . . . . ?
C6F C1F C2F C3F -1.4(6) . . . . ?
P3 C1F C2F C3F 170.7(4) . . . . ?
C1F C2F C3F C4F -0.5(7) . . . . ?
C2F C3F C4F C5F 1.4(7) . . . . ?
C3F C4F C5F C6F -0.2(7) . . . . ?
C4F C5F C6F C1F -1.7(6) . . . . ?
C2F C1F C6F C5F 2.5(6) . . . . ?
P3 C1F C6F C5F -169.9(3) . . . . ?
C20 P4 C1G C2G 146.1(4) . . . . ?
C1H P4 C1G C2G -103.2(4) . . . . ?
Au2 P4 C1G C2G 21.5(4) . . . . ?
C20 P4 C1G C6G -36.3(5) . . . . ?
C1H P4 C1G C6G 74.3(5) . . . . ?
Au2 P4 C1G C6G -160.9(4) . . . . ?
C6G C1G C2G C3G 0.0(7) . . . . ?
P4 C1G C2G C3G 177.5(3) . . . . ?
C1G C2G C3G C4G -0.8(7) . . . . ?
C2G C3G C4G C5G 0.7(8) . . . . ?
C3G C4G C5G C6G 0.2(9) . . . . ?
C4G C5G C6G C1G -1.0(10) . . . . ?
C2G C1G C6G C5G 0.9(9) . . . . ?
P4 C1G C6G C5G -176.7(5) . . . . ?
C20 P4 C1H C6H 113.8(4) . . . . ?
C1G P4 C1H C6H 5.2(5) . . . . ?
Au2 P4 C1H C6H -124.1(4) . . . . ?
C20 P4 C1H C2H -67.0(4) . . . . ?
C1G P4 C1H C2H -175.5(3) . . . . ?
Au2 P4 C1H C2H 55.2(4) . . . . ?
C6H C1H C2H C3H -2.3(7) . . . . ?
P4 C1H C2H C3H 178.4(4) . . . . ?
C1H C2H C3H C4H 0.3(7) . . . . ?
C2H C3H C4H C5H 1.6(8) . . . . ?
C3H C4H C5H C6H -1.5(8) . . . . ?
C2H C1H C6H C5H 2.3(8) . . . . ?
P4 C1H C6H C5H -178.4(4) . . . . ?
C4H C5H C6H C1H -0.5(8) . . . . ?

_refine_diff_density_max         3.787
_refine_diff_density_min         -2.838
_refine_diff_density_rms         0.134


