# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_comp5_b7_tr
_database_code_depnum_ccdc_archive 'CCDC 1538903'
_audit_update_record             
;
2017-08-16 deposited with the CCDC.
2017-08-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
'Complex of silver(I) tetrafluoroborate and hexafluorophosphate witn  tris(2-pyridyl)phosphine'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
;         
 C68 H60 Ag5 N16 P4, F6 P, 4(B F4), 2(C2 H3 N)
;
_chemical_formula_sum            'C72 H66 Ag5 B4 F22 N18 P5'
_chemical_formula_weight         2338.86

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.3371(6)
_cell_length_b                   14.4204(5)
_cell_length_c                   22.4241(9)
_cell_angle_alpha                84.0450(10)
_cell_angle_beta                 87.7610(10)
_cell_angle_gamma                69.1570(10)
_cell_volume                     4309.3(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9959
_cell_measurement_theta_min      2.37
_cell_measurement_theta_max      27.48

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.802
_exptl_crystal_F_000             2304
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.310
_shelx_estimated_absorpt_T_min   0.560
_shelx_estimated_absorpt_T_max   0.780
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7458
_exptl_absorpt_correction_T_max  0.8621
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            86869
_diffrn_reflns_av_unetI/netI     0.0301
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         3.002
_diffrn_reflns_theta_max         27.484
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             19682
_reflns_number_gt                15424
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0489P)²+11.2366P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19682
_refine_ls_number_parameters     1158
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0593
_refine_ls_R_factor_gt           0.0394
_refine_ls_wR_factor_ref         0.1135
_refine_ls_wR_factor_gt          0.0984
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_restrained_S_all      1.070
_refine_ls_shift/su_max          0.033
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.26409(2) 0.38440(2) 0.35208(2) 0.03172(8) Uani 1 1 d . . . . .
Ag2 Ag 0.31052(2) 0.22895(2) 0.25181(2) 0.02240(7) Uani 1 1 d . . . . .
Ag3 Ag 0.54545(2) 0.12565(2) 0.23801(2) 0.03159(8) Uani 1 1 d . . . . .
Ag4 Ag 0.21964(3) 0.33478(2) 0.12845(2) 0.03532(8) Uani 1 1 d . . . . .
Ag5 Ag 0.22164(2) 0.05941(2) 0.28999(2) 0.03044(8) Uani 1 1 d . . . . .
P1 P 0.12055(7) 0.31197(7) 0.26563(4) 0.0236(2) Uani 1 1 d . . . . .
P2 P 0.38636(7) 0.13757(7) 0.35271(4) 0.02209(19) Uani 1 1 d . . . . .
P3 P 0.38380(7) 0.36593(7) 0.21941(4) 0.0234(2) Uani 1 1 d . . . . .
P4 P 0.35294(7) 0.10134(7) 0.17227(4) 0.02325(19) Uani 1 1 d . . . . .
P6 P 0.19624(11) 0.73388(12) 0.01256(7) 0.0539(3) Uani 1 1 d . U . . .
B1 B 0.4222(4) -0.3525(4) 0.3887(2) 0.0381(11) Uani 1 1 d . . . . .
B2 B -0.1392(4) 0.1015(5) 0.3987(3) 0.0422(13) Uani 1 1 d . . . . .
B3 B -0.2627(3) 0.7848(3) 0.09790(19) 0.0262(9) Uani 1 1 d . . . . .
B4 B 0.8684(5) 0.6549(4) 0.3903(2) 0.0394(13) Uani 1 1 d . . . . .
N1 N 0.1223(3) 0.3525(3) 0.37940(15) 0.0305(7) Uani 1 1 d . . . . .
N2 N 0.4153(2) 0.2914(2) 0.39521(14) 0.0272(7) Uani 1 1 d . . . . .
N3 N 0.5373(2) -0.0040(2) 0.30423(15) 0.0289(7) Uani 1 1 d . . . . .
N4 N 0.5646(3) 0.2647(2) 0.26800(15) 0.0289(7) Uani 1 1 d . . . . .
N5 N 0.3664(3) 0.3580(2) 0.10168(15) 0.0297(7) Uani 1 1 d . . . . .
N6 N 0.1872(3) 0.1975(3) 0.10817(15) 0.0300(7) Uani 1 1 d . . . . .
N7 N 0.5269(3) 0.1196(2) 0.13779(15) 0.0286(7) Uani 1 1 d . . . . .
N8 N 0.3513(2) -0.0563(2) 0.24535(15) 0.0277(7) Uani 1 1 d . . . . .
N9 N 0.0780(2) 0.1547(2) 0.23866(15) 0.0279(7) Uani 1 1 d . . . . .
N10 N 0.2255(2) 0.0938(2) 0.38765(15) 0.0280(7) Uani 1 1 d . . . . .
N11 N 0.1513(3) -0.0800(3) 0.32602(19) 0.0448(10) Uani 1 1 d . . . . .
N12 N 0.1069(3) 0.4583(3) 0.17887(16) 0.0330(8) Uani 1 1 d . . . . .
N13 N 0.2521(2) 0.5090(2) 0.27762(15) 0.0277(7) Uani 1 1 d . . . . .
N14 N 0.7398(3) 0.0370(4) 0.2316(2) 0.0509(11) Uani 1 1 d . . . . .
N16 N 1.0304(5) -0.1090(4) 0.1672(3) 0.0765(16) Uani 1 1 d . . . . .
N18 N -0.3226(7) 0.4874(6) 0.1710(3) 0.114(3) Uani 1 1 d . . . . .
N19 N 0.2257(3) 0.5072(4) 0.4367(2) 0.0503(11) Uani 1 1 d . . . . .
N20 N 0.1303(4) 0.4266(4) 0.0342(2) 0.0589(12) Uani 1 1 d . . . . .
C1 C 0.0709(3) 0.3205(3) 0.34234(17) 0.0257(8) Uani 1 1 d . . . . .
C2 C 0.4587(3) 0.1917(3) 0.39410(16) 0.0246(8) Uani 1 1 d . . . . .
C3 C 0.4607(3) 0.3375(3) 0.42675(19) 0.0334(9) Uani 1 1 d . . . . .
H1 H 0.4316 0.4078 0.4275 0.040 Uiso 1 1 calc R U . . .
C4 C 0.5486(3) 0.2864(4) 0.45826(19) 0.0380(10) Uani 1 1 d . . . . .
H2 H 0.5778 0.3212 0.4808 0.046 Uiso 1 1 calc R U . . .
C5 C 0.5928(3) 0.1849(4) 0.45667(18) 0.0332(9) Uani 1 1 d . . . . .
H3 H 0.6530 0.1489 0.4779 0.040 Uiso 1 1 calc R U . . .
C6 C 0.5480(3) 0.1364(3) 0.42354(18) 0.0320(9) Uani 1 1 d . . . . .
H4 H 0.5775 0.0666 0.4210 0.038 Uiso 1 1 calc R U . . .
C7 C 0.4729(3) 0.0088(3) 0.35044(17) 0.0257(8) Uani 1 1 d . . . . .
C8 C 0.6485(3) 0.2526(3) 0.2968(2) 0.0366(10) Uani 1 1 d . . . . .
H5 H 0.6990 0.1883 0.3005 0.044 Uiso 1 1 calc R U . . .
C9 C 0.6653(3) 0.3291(3) 0.3216(2) 0.0386(10) Uani 1 1 d . . . . .
H6 H 0.7259 0.3174 0.3419 0.046 Uiso 1 1 calc R U . . .
C10 C 0.5922(3) 0.4233(3) 0.3163(2) 0.0367(10) Uani 1 1 d . . . . .
H7 H 0.6014 0.4771 0.3332 0.044 Uiso 1 1 calc R U . . .
C11 C 0.5057(3) 0.4372(3) 0.28590(19) 0.0313(9) Uani 1 1 d . . . . .
H8 H 0.4544 0.5010 0.2817 0.038 Uiso 1 1 calc R U . . .
C12 C 0.4940(3) 0.3573(3) 0.26160(17) 0.0262(8) Uani 1 1 d . . . . .
C13 C 0.4273(3) 0.3710(3) 0.14141(17) 0.0282(8) Uani 1 1 d . . . . .
C14 C 0.1096(3) 0.2077(4) 0.0736(2) 0.0382(10) Uani 1 1 d . . . . .
H31 H 0.0674 0.2730 0.0592 0.046 Uiso 1 1 calc R U . . .
C15 C 0.0879(4) 0.1266(4) 0.0577(2) 0.0451(12) Uani 1 1 d . . . . .
H30 H 0.0308 0.1366 0.0342 0.054 Uiso 1 1 calc R U . . .
C16 C 0.1506(4) 0.0320(4) 0.0766(2) 0.0439(11) Uani 1 1 d . . . . .
H9 H 0.1384 -0.0245 0.0656 0.053 Uiso 1 1 calc R U . . .
C17 C 0.2322(3) 0.0200(3) 0.11208(19) 0.0340(9) Uani 1 1 d . . . . .
H29 H 0.2764 -0.0447 0.1259 0.041 Uiso 1 1 calc R U . . .
C18 C 0.2479(3) 0.1043(3) 0.12695(16) 0.0262(8) Uani 1 1 d . . . . .
C19 C 0.4443(3) 0.1120(3) 0.11487(17) 0.0259(8) Uani 1 1 d . . . . .
C20 C 0.5991(3) 0.1248(3) 0.0999(2) 0.0374(10) Uani 1 1 d . . . . .
H10 H 0.6577 0.1292 0.1159 0.045 Uiso 1 1 calc R U . . .
C21 C 0.5931(4) 0.1240(3) 0.0384(2) 0.0399(10) Uani 1 1 d . . . . .
H11 H 0.6459 0.1286 0.0128 0.048 Uiso 1 1 calc R U . . .
C22 C 0.5088(4) 0.1165(4) 0.0154(2) 0.0402(11) Uani 1 1 d . . . . .
H13 H 0.5030 0.1153 -0.0265 0.048 Uiso 1 1 calc R U . . .
C23 C 0.4320(3) 0.1107(3) 0.05389(17) 0.0318(9) Uani 1 1 d . . . . .
H12 H 0.3730 0.1059 0.0388 0.038 Uiso 1 1 calc R U . . .
C24 C 0.4022(3) -0.0319(3) 0.19818(17) 0.0266(8) Uani 1 1 d . . . . .
C25 C 0.0421(3) 0.2549(3) 0.23177(17) 0.0261(8) Uani 1 1 d . . . . .
C26 C -0.0487(3) 0.3101(3) 0.20371(19) 0.0337(9) Uani 1 1 d . . . . .
H17 H -0.0719 0.3809 0.1995 0.040 Uiso 1 1 calc R U . . .
C27 C -0.1043(3) 0.2598(3) 0.18221(19) 0.0351(9) Uani 1 1 d . . . . .
H16 H -0.1664 0.2952 0.1628 0.042 Uiso 1 1 calc R U . . .
C28 C -0.0680(4) 0.1577(4) 0.1894(2) 0.0409(11) Uani 1 1 d . . . . .
H15 H -0.1049 0.1215 0.1749 0.049 Uiso 1 1 calc R U . . .
C29 C 0.0222(3) 0.1076(3) 0.2177(2) 0.0355(9) Uani 1 1 d . . . . .
H14 H 0.0458 0.0368 0.2226 0.043 Uiso 1 1 calc R U . . .
C30 C 0.2968(3) 0.1225(3) 0.40960(17) 0.0260(8) Uani 1 1 d . . . . .
C31 C 0.3008(3) 0.1355(3) 0.46959(18) 0.0350(9) Uani 1 1 d . . . . .
H21 H 0.3508 0.1571 0.4835 0.042 Uiso 1 1 calc R U . . .
C32 C 0.2323(4) 0.1170(4) 0.5090(2) 0.0442(12) Uani 1 1 d . . . . .
H20 H 0.2351 0.1238 0.5505 0.053 Uiso 1 1 calc R U . . .
C33 C 0.1581(4) 0.0878(3) 0.4866(2) 0.0412(11) Uani 1 1 d . . . . .
H19 H 0.1089 0.0755 0.5125 0.049 Uiso 1 1 calc R U . . .
C34 C 0.1582(3) 0.0772(3) 0.4260(2) 0.0357(10) Uani 1 1 d . . . . .
H18 H 0.1080 0.0572 0.4110 0.043 Uiso 1 1 calc R U . . .
C35 C 0.1402(4) -0.1321(3) 0.3655(2) 0.0397(10) Uani 1 1 d . . . . .
C36 C 0.1261(5) -0.1987(5) 0.4147(3) 0.0668(17) Uani 1 1 d . . . . .
H22 H 0.0617 -0.2067 0.4104 0.100 Uiso 1 1 calc R U . . .
H24 H 0.1272 -0.1708 0.4526 0.100 Uiso 1 1 calc R U . . .
H23 H 0.1799 -0.2637 0.4146 0.100 Uiso 1 1 calc R U . . .
C37 C 0.3737(3) -0.1539(3) 0.2631(2) 0.0353(9) Uani 1 1 d . . . . .
H28 H 0.3392 -0.1723 0.2966 0.042 Uiso 1 1 calc R U . . .
C38 C 0.4450(4) -0.2285(3) 0.2346(2) 0.0429(11) Uani 1 1 d . . . . .
H27 H 0.4576 -0.2967 0.2477 0.051 Uiso 1 1 calc R U . . .
C39 C 0.4976(4) -0.2025(3) 0.1866(2) 0.0393(10) Uani 1 1 d . . . . .
H26 H 0.5469 -0.2523 0.1664 0.047 Uiso 1 1 calc R U . . .
C40 C 0.4767(3) -0.1021(3) 0.16886(19) 0.0337(9) Uani 1 1 d . . . . .
H25 H 0.5131 -0.0819 0.1370 0.040 Uiso 1 1 calc R U . . .
C41 C 0.0686(3) 0.4423(3) 0.23282(19) 0.0307(9) Uani 1 1 d . . . . .
C42 C -0.0033(3) 0.5171(3) 0.2610(2) 0.0395(10) Uani 1 1 d . . . . .
H35 H -0.0275 0.5039 0.2998 0.047 Uiso 1 1 calc R U . . .
C43 C -0.0389(4) 0.6123(3) 0.2306(3) 0.0517(14) Uani 1 1 d . . . . .
H34 H -0.0892 0.6652 0.2480 0.062 Uiso 1 1 calc R U . . .
C44 C -0.0003(4) 0.6288(4) 0.1749(3) 0.0539(14) Uani 1 1 d . . . . .
H33 H -0.0237 0.6931 0.1534 0.065 Uiso 1 1 calc R U . . .
C45 C 0.0727(4) 0.5505(4) 0.1509(2) 0.0453(12) Uani 1 1 d . . . . .
H32 H 0.1000 0.5627 0.1128 0.054 Uiso 1 1 calc R U . . .
C46 C 0.1322(4) 0.4599(4) -0.0127(2) 0.0443(11) Uani 1 1 d . . . . .
C47 C 0.3913(4) 0.3638(3) 0.04344(19) 0.0398(10) Uani 1 1 d . . . . .
H36 H 0.3487 0.3551 0.0148 0.048 Uiso 1 1 calc R U . . .
C48 C 0.4763(4) 0.3818(4) 0.0234(2) 0.0475(13) Uani 1 1 d . . . . .
H37 H 0.4918 0.3848 -0.0182 0.057 Uiso 1 1 calc R U . . .
C49 C 0.5389(4) 0.3955(3) 0.0651(2) 0.0419(11) Uani 1 1 d . . . . .
H39 H 0.5975 0.4084 0.0525 0.050 Uiso 1 1 calc R U . . .
C50 C 0.5136(3) 0.3899(3) 0.1246(2) 0.0353(9) Uani 1 1 d . . . . .
H38 H 0.5547 0.3988 0.1540 0.042 Uiso 1 1 calc R U . . .
C51 C 0.3036(3) 0.4960(3) 0.22565(18) 0.0263(8) Uani 1 1 d . . . . .
C52 C 0.1947(3) 0.6021(3) 0.2878(2) 0.0354(9) Uani 1 1 d . . . . .
H43 H 0.1585 0.6124 0.3244 0.042 Uiso 1 1 calc R U . . .
C53 C 0.1860(4) 0.6839(3) 0.2473(2) 0.0390(10) Uani 1 1 d . . . . .
H42 H 0.1445 0.7488 0.2561 0.047 Uiso 1 1 calc R U . . .
C54 C 0.2383(4) 0.6698(3) 0.1941(2) 0.0380(10) Uani 1 1 d . . . . .
H40 H 0.2334 0.7250 0.1657 0.046 Uiso 1 1 calc R U . . .
C55 C 0.2980(3) 0.5742(3) 0.1828(2) 0.0349(9) Uani 1 1 d . . . . .
H41 H 0.3345 0.5625 0.1464 0.042 Uiso 1 1 calc R U . . .
C56 C 0.8055(4) -0.0163(4) 0.2582(2) 0.0453(11) Uani 1 1 d . . . . .
C57 C 0.8915(5) -0.0855(5) 0.2919(3) 0.0733(19) Uani 1 1 d . . . . .
H46 H 0.8687 -0.1228 0.3247 0.110 Uiso 1 1 calc R U . . .
H44 H 0.9280 -0.0481 0.3085 0.110 Uiso 1 1 calc R U . . .
H45 H 0.9356 -0.1320 0.2652 0.110 Uiso 1 1 calc R U . . .
C58 C 0.6034(3) -0.0951(3) 0.3002(2) 0.0402(10) Uani 1 1 d . . . . .
H50 H 0.6490 -0.1052 0.2675 0.048 Uiso 1 1 calc R U . . .
C59 C 0.6096(4) -0.1764(3) 0.3409(2) 0.0442(12) Uani 1 1 d . . . . .
H47 H 0.6579 -0.2403 0.3361 0.053 Uiso 1 1 calc R U . . .
C60 C 0.5441(4) -0.1620(3) 0.3885(2) 0.0390(10) Uani 1 1 d . . . . .
H48 H 0.5477 -0.2156 0.4179 0.047 Uiso 1 1 calc R U . . .
C61 C 0.4729(3) -0.0687(3) 0.3928(2) 0.0357(10) Uani 1 1 d . . . . .
H49 H 0.4249 -0.0577 0.4242 0.043 Uiso 1 1 calc R U . . .
C62 C -0.0119(3) 0.2976(3) 0.3612(2) 0.0347(9) Uani 1 1 d . . . . .
H54 H -0.0460 0.2740 0.3344 0.042 Uiso 1 1 calc R U . . .
C63 C -0.0442(3) 0.3093(4) 0.4195(2) 0.0416(11) Uani 1 1 d . . . . .
H53 H -0.1005 0.2932 0.4335 0.050 Uiso 1 1 calc R U . . .
C64 C 0.0061(4) 0.3447(4) 0.4573(2) 0.0437(11) Uani 1 1 d . . . . .
H52 H -0.0155 0.3546 0.4975 0.052 Uiso 1 1 calc R U . . .
C65 C 0.0891(3) 0.3656(4) 0.4353(2) 0.0385(10) Uani 1 1 d . . . . .
H51 H 0.1236 0.3903 0.4613 0.046 Uiso 1 1 calc R U . . .
C68 C 0.8887(7) -0.0521(7) 0.0913(3) 0.105(3) Uani 1 1 d . . . . .
H57 H 0.8249 -0.0306 0.1129 0.158 Uiso 1 1 calc R U . . .
H58 H 0.8921 -0.1067 0.0677 0.158 Uiso 1 1 calc R U . . .
H59 H 0.8940 0.0040 0.0645 0.158 Uiso 1 1 calc R U . . .
C69 C 0.9691(5) -0.0856(4) 0.1335(3) 0.0588(15) Uani 1 1 d . . . . .
C72 C -0.3079(5) 0.5324(5) 0.2054(3) 0.0629(16) Uani 1 1 d . . . . .
C73 C -0.2876(5) 0.5884(5) 0.2491(3) 0.0719(18) Uani 1 1 d . . . . .
H61 H -0.2344 0.5440 0.2759 0.108 Uiso 1 1 calc R U . . .
H60 H -0.3481 0.6184 0.2725 0.108 Uiso 1 1 calc R U . . .
H62 H -0.2663 0.6411 0.2288 0.108 Uiso 1 1 calc R U . . .
C74 C 0.2550(4) 0.5119(4) 0.4819(2) 0.0419(11) Uani 1 1 d . . . . .
C75 C 0.2939(5) 0.5194(5) 0.5390(2) 0.0626(16) Uani 1 1 d . . . . .
H75A H 0.3646 0.4771 0.5419 0.094 Uiso 1 1 calc R U . . .
H75B H 0.2566 0.4973 0.5715 0.094 Uiso 1 1 calc R U . . .
H75C H 0.2868 0.5888 0.5423 0.094 Uiso 1 1 calc R U . . .
C76 C 0.1332(5) 0.5050(5) -0.0737(3) 0.0699(18) Uani 1 1 d . . . . .
H76A H 0.0645 0.5389 -0.0878 0.105 Uiso 1 1 calc R U . . .
H76B H 0.1688 0.4531 -0.0998 0.105 Uiso 1 1 calc R U . . .
H76C H 0.1669 0.5535 -0.0744 0.105 Uiso 1 1 calc R U . . .
F1 F 0.8198(6) 0.6050(8) 0.3545(3) 0.117(3) Uani 0.748(11) 1 d . . P A 1
F2 F 0.8647(10) 0.7231(9) 0.3696(6) 0.204(7) Uani 0.748(11) 1 d . . P A 1
F3 F 0.7938(12) 0.6804(14) 0.4382(8) 0.089(4) Uani 0.748(11) 1 d . . P A 1
F22 F 0.9439(7) 0.5862(6) 0.4133(5) 0.201(6) Uani 0.748(11) 1 d . . P A 1
F1' F 0.8334(8) 0.7146(8) 0.3289(5) 0.036(3) Uiso 0.252(11) 1 d . . P A 2
F2' F 0.9117(12) 0.7431(13) 0.4063(7) 0.071(5) Uiso 0.252(11) 1 d . . P A 2
F3' F 0.8693(14) 0.5595(12) 0.3744(7) 0.065(5) Uiso 0.252(11) 1 d . . P A 2
F22' F 0.771(3) 0.678(3) 0.437(2) 0.050(6) Uiso 0.252(11) 1 d . . P A 2
F4 F -0.1229(3) 0.1470(3) 0.34395(14) 0.0627(9) Uani 1 1 d . . . . .
F5 F -0.1793(3) 0.1734(4) 0.43795(18) 0.0874(13) Uani 1 1 d . . . . .
F6 F -0.2087(2) 0.0562(2) 0.39129(14) 0.0527(7) Uani 1 1 d . . . . .
F7 F -0.0513(2) 0.0318(3) 0.4198(2) 0.0948(15) Uani 1 1 d . . . . .
F8 F 0.2631(4) 0.6190(3) 0.0244(3) 0.1208(19) Uani 1 1 d . . . . .
F9 F 0.1279(4) 0.8510(3) 0.0044(2) 0.0996(14) Uani 1 1 d . . . . .
F10 F 0.2692(4) 0.7596(5) 0.0530(2) 0.1146(19) Uani 1 1 d . . . . .
F11 F 0.1313(13) 0.7036(10) -0.0300(7) 0.321(7) Uani 1 1 d . U . . .
F12 F 0.1095(5) 0.7185(5) 0.0483(4) 0.155(3) Uani 1 1 d . . . . .
F13 F 0.2290(5) 0.7464(5) -0.0536(2) 0.134(2) Uani 1 1 d . . . . .
F14 F -0.1760(4) 0.7531(4) 0.0684(3) 0.1184(18) Uani 1 1 d . . . . .
F15 F -0.3278(4) 0.7278(4) 0.0860(2) 0.1097(16) Uani 1 1 d . . . . .
F16 F -0.2564(4) 0.7820(6) 0.1571(2) 0.146(2) Uani 1 1 d . . . . .
F17 F -0.3268(3) 0.8807(3) 0.0753(2) 0.0983(14) Uani 1 1 d . . . . .
F18 F 0.3747(2) -0.2596(2) 0.40865(13) 0.0519(7) Uani 1 1 d . . . . .
F19 F 0.3676(3) -0.3657(3) 0.34303(15) 0.0664(9) Uani 1 1 d . . . . .
F20 F 0.4363(3) -0.4273(2) 0.43529(14) 0.0626(9) Uani 1 1 d . . . . .
F21 F 0.5164(2) -0.3590(2) 0.36609(16) 0.0584(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N13 2.286(3) . ?
Ag1 N1 2.286(3) . ?
Ag1 N2 2.294(3) . ?
Ag1 Ag2 3.2234(4) . ?
Ag2 P2 2.5674(10) . ?
Ag2 P1 2.5765(10) . ?
Ag2 P3 2.5793(10) . ?
Ag2 P4 2.5957(10) . ?
Ag2 Ag4 3.1096(4) . ?
Ag2 Ag5 3.1672(4) . ?
Ag2 Ag3 3.1786(4) . ?
Ag3 N7 2.287(3) . ?
Ag3 N4 2.288(3) . ?
Ag3 N3 2.298(3) . ?
Ag3 N14 2.626(5) . ?
Ag4 N6 2.281(3) . ?
Ag4 N5 2.293(4) . ?
Ag4 N12 2.300(4) . ?
Ag4 N20 2.507(4) . ?
Ag5 N8 2.288(3) . ?
Ag5 N9 2.301(3) . ?
Ag5 N10 2.302(3) . ?
Ag5 N11 2.599(4) . ?
P1 C1 1.835(4) . ?
P1 C25 1.837(4) . ?
P1 C41 1.840(4) . ?
P2 C30 1.827(4) . ?
P2 C2 1.830(4) . ?
P2 C7 1.834(4) . ?
P3 C12 1.833(4) . ?
P3 C51 1.835(4) . ?
P3 C13 1.837(4) . ?
P4 C24 1.834(4) . ?
P4 C19 1.835(4) . ?
P4 C18 1.835(4) . ?
P6 F12 1.523(5) . ?
P6 F13 1.552(5) . ?
P6 F11 1.554(12) . ?
P6 F10 1.572(4) . ?
P6 F8 1.592(5) . ?
P6 F9 1.618(4) . ?
B1 F19 1.381(6) . ?
B1 F18 1.382(6) . ?
B1 F20 1.386(6) . ?
B1 F21 1.400(6) . ?
B2 F7 1.368(6) . ?
B2 F5 1.381(7) . ?
B2 F4 1.382(6) . ?
B2 F6 1.393(6) . ?
B3 F16 1.329(7) . ?
B3 F14 1.338(6) . ?
B3 F17 1.414(6) . ?
B3 F15 1.492(7) . ?
B4 F2 1.027(12) . ?
B4 F22 1.262(8) . ?
B4 F3' 1.452(17) . ?
B4 F3 1.465(19) . ?
B4 F1 1.473(8) . ?
B4 F1' 1.546(12) . ?
B4 F2' 1.674(18) . ?
B4 F22' 1.68(5) . ?
N1 C65 1.332(5) . ?
N1 C1 1.348(5) . ?
N2 C3 1.344(5) . ?
N2 C2 1.350(5) . ?
N3 C58 1.328(6) . ?
N3 C7 1.344(5) . ?
N4 C8 1.335(5) . ?
N4 C12 1.355(5) . ?
N5 C47 1.342(5) . ?
N5 C13 1.344(5) . ?
N6 C14 1.338(5) . ?
N6 C18 1.348(5) . ?
N7 C20 1.330(5) . ?
N7 C19 1.353(5) . ?
N8 C24 1.349(5) . ?
N8 C37 1.348(5) . ?
N9 C25 1.344(5) . ?
N9 C29 1.345(5) . ?
N10 C34 1.336(5) . ?
N10 C30 1.356(5) . ?
N11 C35 1.144(6) . ?
N12 C45 1.338(6) . ?
N12 C41 1.341(5) . ?
N13 C52 1.340(5) . ?
N13 C51 1.349(5) . ?
N14 C56 1.125(7) . ?
N16 C69 1.116(8) . ?
N18 C72 1.128(9) . ?
N19 C74 1.130(6) . ?
N20 C46 1.114(6) . ?
C1 C62 1.381(6) . ?
C2 C6 1.393(6) . ?
C3 C4 1.390(6) . ?
C3 H1 0.9500 . ?
C4 C5 1.375(7) . ?
C4 H2 0.9500 . ?
C5 C6 1.387(6) . ?
C5 H3 0.9500 . ?
C6 H4 0.9500 . ?
C7 C61 1.390(5) . ?
C8 C9 1.382(6) . ?
C8 H5 0.9500 . ?
C9 C10 1.385(7) . ?
C9 H6 0.9500 . ?
C10 C11 1.380(6) . ?
C10 H7 0.9500 . ?
C11 C12 1.387(5) . ?
C11 H8 0.9500 . ?
C13 C50 1.388(6) . ?
C14 C15 1.395(7) . ?
C14 H31 0.9500 . ?
C15 C16 1.374(7) . ?
C15 H30 0.9500 . ?
C16 C17 1.390(6) . ?
C16 H9 0.9500 . ?
C17 C18 1.388(6) . ?
C17 H29 0.9500 . ?
C19 C23 1.388(5) . ?
C20 C21 1.387(6) . ?
C20 H10 0.9500 . ?
C21 C22 1.375(7) . ?
C21 H11 0.9500 . ?
C22 C23 1.392(6) . ?
C22 H13 0.9500 . ?
C23 H12 0.9500 . ?
C24 C40 1.382(6) . ?
C25 C26 1.395(5) . ?
C26 C27 1.381(6) . ?
C26 H17 0.9500 . ?
C27 C28 1.369(7) . ?
C27 H16 0.9500 . ?
C28 C29 1.378(6) . ?
C28 H15 0.9500 . ?
C29 H14 0.9500 . ?
C30 C31 1.384(6) . ?
C31 C32 1.374(6) . ?
C31 H21 0.9500 . ?
C32 C33 1.402(7) . ?
C32 H20 0.9500 . ?
C33 C34 1.383(7) . ?
C33 H19 0.9500 . ?
C34 H18 0.9500 . ?
C35 C36 1.442(7) . ?
C36 H22 0.9800 . ?
C36 H24 0.9800 . ?
C36 H23 0.9800 . ?
C37 C38 1.386(7) . ?
C37 H28 0.9500 . ?
C38 C39 1.386(7) . ?
C38 H27 0.9500 . ?
C39 C40 1.388(6) . ?
C39 H26 0.9500 . ?
C40 H25 0.9500 . ?
C41 C42 1.388(6) . ?
C42 C43 1.395(6) . ?
C42 H35 0.9500 . ?
C43 C44 1.378(8) . ?
C43 H34 0.9500 . ?
C44 C45 1.379(8) . ?
C44 H33 0.9500 . ?
C45 H32 0.9500 . ?
C46 C76 1.453(7) . ?
C47 C48 1.384(7) . ?
C47 H36 0.9500 . ?
C48 C49 1.396(8) . ?
C48 H37 0.9500 . ?
C49 C50 1.371(6) . ?
C49 H39 0.9500 . ?
C50 H38 0.9500 . ?
C51 C55 1.385(5) . ?
C52 C53 1.383(6) . ?
C52 H43 0.9500 . ?
C53 C54 1.378(7) . ?
C53 H42 0.9500 . ?
C54 C55 1.383(6) . ?
C54 H40 0.9500 . ?
C55 H41 0.9500 . ?
C56 C57 1.459(8) . ?
C57 H46 0.9800 . ?
C57 H44 0.9800 . ?
C57 H45 0.9800 . ?
C58 C59 1.388(7) . ?
C58 H50 0.9500 . ?
C59 C60 1.375(7) . ?
C59 H47 0.9500 . ?
C60 C61 1.379(6) . ?
C60 H48 0.9500 . ?
C61 H49 0.9500 . ?
C62 C63 1.376(6) . ?
C62 H54 0.9500 . ?
C63 C64 1.378(7) . ?
C63 H53 0.9500 . ?
C64 C65 1.387(6) . ?
C64 H52 0.9500 . ?
C65 H51 0.9500 . ?
C68 C69 1.433(10) . ?
C68 H57 0.9800 . ?
C68 H58 0.9800 . ?
C68 H59 0.9800 . ?
C72 C73 1.432(10) . ?
C73 H61 0.9800 . ?
C73 H60 0.9800 . ?
C73 H62 0.9800 . ?
C74 C75 1.445(7) . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
F11 F13 1.764(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N13 Ag1 N1 117.91(12) . . ?
N13 Ag1 N2 120.55(12) . . ?
N1 Ag1 N2 121.50(12) . . ?
N13 Ag1 Ag2 89.10(8) . . ?
N1 Ag1 Ag2 90.22(9) . . ?
N2 Ag1 Ag2 88.83(8) . . ?
P2 Ag2 P1 108.39(3) . . ?
P2 Ag2 P3 109.48(3) . . ?
P1 Ag2 P3 108.65(3) . . ?
P2 Ag2 P4 108.88(3) . . ?
P1 Ag2 P4 111.52(3) . . ?
P3 Ag2 P4 109.89(3) . . ?
P2 Ag2 Ag4 178.65(2) . . ?
P1 Ag2 Ag4 72.05(2) . . ?
P3 Ag2 Ag4 71.45(2) . . ?
P4 Ag2 Ag4 69.80(2) . . ?
P2 Ag2 Ag5 70.92(2) . . ?
P1 Ag2 Ag5 71.74(2) . . ?
P3 Ag2 Ag5 179.23(3) . . ?
P4 Ag2 Ag5 69.34(2) . . ?
Ag4 Ag2 Ag5 108.140(12) . . ?
P2 Ag2 Ag3 70.33(2) . . ?
P1 Ag2 Ag3 178.69(2) . . ?
P3 Ag2 Ag3 71.72(2) . . ?
P4 Ag2 Ag3 69.37(2) . . ?
Ag4 Ag2 Ag3 109.233(12) . . ?
Ag5 Ag2 Ag3 107.909(12) . . ?
P2 Ag2 Ag1 69.90(2) . . ?
P1 Ag2 Ag1 69.99(2) . . ?
P3 Ag2 Ag1 69.82(2) . . ?
P4 Ag2 Ag1 178.39(3) . . ?
Ag4 Ag2 Ag1 111.427(12) . . ?
Ag5 Ag2 Ag1 110.945(11) . . ?
Ag3 Ag2 Ag1 109.107(11) . . ?
N7 Ag3 N4 118.06(12) . . ?
N7 Ag3 N3 118.97(12) . . ?
N4 Ag3 N3 122.92(12) . . ?
N7 Ag3 N14 92.05(13) . . ?
N4 Ag3 N14 90.75(13) . . ?
N3 Ag3 N14 89.60(14) . . ?
N7 Ag3 Ag2 90.19(9) . . ?
N4 Ag3 Ag2 89.23(9) . . ?
N3 Ag3 Ag2 88.28(8) . . ?
N14 Ag3 Ag2 177.47(11) . . ?
N6 Ag4 N5 122.68(12) . . ?
N6 Ag4 N12 121.66(12) . . ?
N5 Ag4 N12 115.65(12) . . ?
N6 Ag4 N20 89.48(14) . . ?
N5 Ag4 N20 94.43(15) . . ?
N12 Ag4 N20 86.95(15) . . ?
N6 Ag4 Ag2 90.62(8) . . ?
N5 Ag4 Ag2 90.24(8) . . ?
N12 Ag4 Ag2 88.22(8) . . ?
N20 Ag4 Ag2 174.39(12) . . ?
N8 Ag5 N9 121.92(12) . . ?
N8 Ag5 N10 123.33(12) . . ?
N9 Ag5 N10 114.73(12) . . ?
N8 Ag5 N11 88.98(12) . . ?
N9 Ag5 N11 92.89(12) . . ?
N10 Ag5 N11 90.00(13) . . ?
N8 Ag5 Ag2 91.65(8) . . ?
N9 Ag5 Ag2 88.81(8) . . ?
N10 Ag5 Ag2 87.65(8) . . ?
N11 Ag5 Ag2 177.53(10) . . ?
C1 P1 C25 101.26(18) . . ?
C1 P1 C41 102.26(19) . . ?
C25 P1 C41 102.22(18) . . ?
C1 P1 Ag2 118.04(12) . . ?
C25 P1 Ag2 116.44(13) . . ?
C41 P1 Ag2 114.28(14) . . ?
C30 P2 C2 101.52(17) . . ?
C30 P2 C7 101.72(18) . . ?
C2 P2 C7 101.90(17) . . ?
C30 P2 Ag2 115.38(13) . . ?
C2 P2 Ag2 117.94(12) . . ?
C7 P2 Ag2 115.92(13) . . ?
C12 P3 C51 101.38(18) . . ?
C12 P3 C13 102.32(18) . . ?
C51 P3 C13 101.92(18) . . ?
C12 P3 Ag2 114.89(12) . . ?
C51 P3 Ag2 117.89(13) . . ?
C13 P3 Ag2 116.09(13) . . ?
C24 P4 C19 102.24(18) . . ?
C24 P4 C18 99.48(18) . . ?
C19 P4 C18 102.31(18) . . ?
C24 P4 Ag2 118.35(13) . . ?
C19 P4 Ag2 115.92(12) . . ?
C18 P4 Ag2 115.89(13) . . ?
F12 P6 F13 139.4(4) . . ?
F12 P6 F11 71.3(7) . . ?
F13 P6 F11 69.2(7) . . ?
F12 P6 F10 112.2(4) . . ?
F13 P6 F10 107.7(3) . . ?
F11 P6 F10 175.6(7) . . ?
F12 P6 F8 91.9(3) . . ?
F13 P6 F8 95.8(3) . . ?
F11 P6 F8 88.1(6) . . ?
F10 P6 F8 89.1(3) . . ?
F12 P6 F9 86.5(3) . . ?
F13 P6 F9 87.1(3) . . ?
F11 P6 F9 94.0(5) . . ?
F10 P6 F9 89.0(3) . . ?
F8 P6 F9 176.9(3) . . ?
F19 B1 F18 109.7(4) . . ?
F19 B1 F20 111.0(4) . . ?
F18 B1 F20 111.1(4) . . ?
F19 B1 F21 108.1(4) . . ?
F18 B1 F21 109.4(4) . . ?
F20 B1 F21 107.5(4) . . ?
F7 B2 F5 111.3(5) . . ?
F7 B2 F4 109.5(4) . . ?
F5 B2 F4 108.9(5) . . ?
F7 B2 F6 110.2(5) . . ?
F5 B2 F6 107.9(4) . . ?
F4 B2 F6 109.0(4) . . ?
F16 B3 F14 116.0(5) . . ?
F16 B3 F17 108.9(5) . . ?
F14 B3 F17 113.4(4) . . ?
F16 B3 F15 107.0(4) . . ?
F14 B3 F15 111.7(4) . . ?
F17 B3 F15 98.2(4) . . ?
F2 B4 F22 127.8(13) . . ?
F2 B4 F3 103.5(10) . . ?
F22 B4 F3 106.2(10) . . ?
F2 B4 F1 111.8(11) . . ?
F22 B4 F1 105.2(7) . . ?
F3 B4 F1 98.2(8) . . ?
F3' B4 F1' 97.1(8) . . ?
F3' B4 F2' 159.2(10) . . ?
F1' B4 F2' 88.6(8) . . ?
F3' B4 F22' 97.3(17) . . ?
F1' B4 F22' 109.3(16) . . ?
F2' B4 F22' 99.6(16) . . ?
C65 N1 C1 118.1(4) . . ?
C65 N1 Ag1 118.1(3) . . ?
C1 N1 Ag1 123.8(3) . . ?
C3 N2 C2 117.8(4) . . ?
C3 N2 Ag1 118.2(3) . . ?
C2 N2 Ag1 123.9(2) . . ?
C58 N3 C7 117.3(4) . . ?
C58 N3 Ag3 119.6(3) . . ?
C7 N3 Ag3 122.9(3) . . ?
C8 N4 C12 118.0(3) . . ?
C8 N4 Ag3 117.6(3) . . ?
C12 N4 Ag3 124.3(3) . . ?
C47 N5 C13 117.6(4) . . ?
C47 N5 Ag4 119.2(3) . . ?
C13 N5 Ag4 123.1(3) . . ?
C14 N6 C18 118.0(4) . . ?
C14 N6 Ag4 120.0(3) . . ?
C18 N6 Ag4 121.9(3) . . ?
C20 N7 C19 118.0(4) . . ?
C20 N7 Ag3 119.4(3) . . ?
C19 N7 Ag3 122.6(3) . . ?
C24 N8 C37 117.5(4) . . ?
C24 N8 Ag5 122.8(3) . . ?
C37 N8 Ag5 119.5(3) . . ?
C25 N9 C29 117.3(3) . . ?
C25 N9 Ag5 124.6(3) . . ?
C29 N9 Ag5 118.0(3) . . ?
C34 N10 C30 118.0(4) . . ?
C34 N10 Ag5 118.1(3) . . ?
C30 N10 Ag5 123.8(3) . . ?
C35 N11 Ag5 146.5(4) . . ?
C45 N12 C41 118.1(4) . . ?
C45 N12 Ag4 117.8(3) . . ?
C41 N12 Ag4 124.0(3) . . ?
C52 N13 C51 117.7(3) . . ?
C52 N13 Ag1 117.8(3) . . ?
C51 N13 Ag1 124.4(3) . . ?
C56 N14 Ag3 141.8(4) . . ?
C46 N20 Ag4 150.0(5) . . ?
N1 C1 C62 122.2(4) . . ?
N1 C1 P1 113.8(3) . . ?
C62 C1 P1 124.1(3) . . ?
N2 C2 C6 122.6(4) . . ?
N2 C2 P2 113.3(3) . . ?
C6 C2 P2 124.0(3) . . ?
N2 C3 C4 122.5(4) . . ?
N2 C3 H1 118.8 . . ?
C4 C3 H1 118.8 . . ?
C5 C4 C3 119.6(4) . . ?
C5 C4 H2 120.2 . . ?
C3 C4 H2 120.2 . . ?
C4 C5 C6 118.7(4) . . ?
C4 C5 H3 120.6 . . ?
C6 C5 H3 120.6 . . ?
C5 C6 C2 118.8(4) . . ?
C5 C6 H4 120.6 . . ?
C2 C6 H4 120.6 . . ?
N3 C7 C61 122.7(4) . . ?
N3 C7 P2 113.9(3) . . ?
C61 C7 P2 123.4(3) . . ?
N4 C8 C9 123.2(4) . . ?
N4 C8 H5 118.4 . . ?
C9 C8 H5 118.4 . . ?
C8 C9 C10 118.9(4) . . ?
C8 C9 H6 120.6 . . ?
C10 C9 H6 120.6 . . ?
C11 C10 C9 118.5(4) . . ?
C11 C10 H7 120.7 . . ?
C9 C10 H7 120.7 . . ?
C10 C11 C12 119.6(4) . . ?
C10 C11 H8 120.2 . . ?
C12 C11 H8 120.2 . . ?
N4 C12 C11 121.8(4) . . ?
N4 C12 P3 114.2(3) . . ?
C11 C12 P3 124.0(3) . . ?
N5 C13 C50 122.8(4) . . ?
N5 C13 P3 113.9(3) . . ?
C50 C13 P3 123.2(3) . . ?
N6 C14 C15 122.8(4) . . ?
N6 C14 H31 118.6 . . ?
C15 C14 H31 118.6 . . ?
C16 C15 C14 118.8(4) . . ?
C16 C15 H30 120.6 . . ?
C14 C15 H30 120.6 . . ?
C15 C16 C17 119.1(4) . . ?
C15 C16 H9 120.4 . . ?
C17 C16 H9 120.4 . . ?
C18 C17 C16 118.7(4) . . ?
C18 C17 H29 120.6 . . ?
C16 C17 H29 120.6 . . ?
N6 C18 C17 122.5(4) . . ?
N6 C18 P4 113.3(3) . . ?
C17 C18 P4 124.1(3) . . ?
N7 C19 C23 122.6(4) . . ?
N7 C19 P4 113.3(3) . . ?
C23 C19 P4 124.1(3) . . ?
N7 C20 C21 123.3(4) . . ?
N7 C20 H10 118.4 . . ?
C21 C20 H10 118.4 . . ?
C22 C21 C20 118.4(4) . . ?
C22 C21 H11 120.8 . . ?
C20 C21 H11 120.8 . . ?
C21 C22 C23 119.7(4) . . ?
C21 C22 H13 120.1 . . ?
C23 C22 H13 120.1 . . ?
C19 C23 C22 118.0(4) . . ?
C19 C23 H12 121.0 . . ?
C22 C23 H12 121.0 . . ?
N8 C24 C40 123.0(4) . . ?
N8 C24 P4 112.9(3) . . ?
C40 C24 P4 123.8(3) . . ?
N9 C25 C26 122.8(4) . . ?
N9 C25 P1 113.8(3) . . ?
C26 C25 P1 123.3(3) . . ?
C27 C26 C25 118.7(4) . . ?
C27 C26 H17 120.6 . . ?
C25 C26 H17 120.6 . . ?
C28 C27 C26 118.6(4) . . ?
C28 C27 H16 120.7 . . ?
C26 C27 H16 120.7 . . ?
C27 C28 C29 119.9(4) . . ?
C27 C28 H15 120.1 . . ?
C29 C28 H15 120.1 . . ?
N9 C29 C28 122.7(4) . . ?
N9 C29 H14 118.6 . . ?
C28 C29 H14 118.6 . . ?
N10 C30 C31 122.1(4) . . ?
N10 C30 P2 113.1(3) . . ?
C31 C30 P2 124.7(3) . . ?
C32 C31 C30 119.7(4) . . ?
C32 C31 H21 120.2 . . ?
C30 C31 H21 120.2 . . ?
C31 C32 C33 118.5(4) . . ?
C31 C32 H20 120.7 . . ?
C33 C32 H20 120.7 . . ?
C34 C33 C32 118.6(4) . . ?
C34 C33 H19 120.7 . . ?
C32 C33 H19 120.7 . . ?
N10 C34 C33 123.1(4) . . ?
N10 C34 H18 118.4 . . ?
C33 C34 H18 118.4 . . ?
N11 C35 C36 179.2(6) . . ?
C35 C36 H22 109.5 . . ?
C35 C36 H24 109.5 . . ?
H22 C36 H24 109.5 . . ?
C35 C36 H23 109.5 . . ?
H22 C36 H23 109.5 . . ?
H24 C36 H23 109.5 . . ?
N8 C37 C38 122.7(4) . . ?
N8 C37 H28 118.6 . . ?
C38 C37 H28 118.6 . . ?
C39 C38 C37 119.1(4) . . ?
C39 C38 H27 120.4 . . ?
C37 C38 H27 120.4 . . ?
C38 C39 C40 118.5(4) . . ?
C38 C39 H26 120.7 . . ?
C40 C39 H26 120.7 . . ?
C24 C40 C39 119.0(4) . . ?
C24 C40 H25 120.5 . . ?
C39 C40 H25 120.5 . . ?
N12 C41 C42 123.0(4) . . ?
N12 C41 P1 113.6(3) . . ?
C42 C41 P1 123.4(3) . . ?
C41 C42 C43 117.9(5) . . ?
C41 C42 H35 121.1 . . ?
C43 C42 H35 121.1 . . ?
C44 C43 C42 119.2(5) . . ?
C44 C43 H34 120.4 . . ?
C42 C43 H34 120.4 . . ?
C43 C44 C45 119.0(4) . . ?
C43 C44 H33 120.5 . . ?
C45 C44 H33 120.5 . . ?
N12 C45 C44 122.8(5) . . ?
N12 C45 H32 118.6 . . ?
C44 C45 H32 118.6 . . ?
N20 C46 C76 178.9(7) . . ?
N5 C47 C48 122.8(5) . . ?
N5 C47 H36 118.6 . . ?
C48 C47 H36 118.6 . . ?
C47 C48 C49 119.0(4) . . ?
C47 C48 H37 120.5 . . ?
C49 C48 H37 120.5 . . ?
C50 C49 C48 118.3(4) . . ?
C50 C49 H39 120.8 . . ?
C48 C49 H39 120.8 . . ?
C49 C50 C13 119.4(4) . . ?
C49 C50 H38 120.3 . . ?
C13 C50 H38 120.3 . . ?
N13 C51 C55 122.7(4) . . ?
N13 C51 P3 113.0(3) . . ?
C55 C51 P3 124.3(3) . . ?
N13 C52 C53 122.8(4) . . ?
N13 C52 H43 118.6 . . ?
C53 C52 H43 118.6 . . ?
C54 C53 C52 119.1(4) . . ?
C54 C53 H42 120.4 . . ?
C52 C53 H42 120.4 . . ?
C53 C54 C55 118.9(4) . . ?
C53 C54 H40 120.5 . . ?
C55 C54 H40 120.5 . . ?
C54 C55 C51 118.7(4) . . ?
C54 C55 H41 120.6 . . ?
C51 C55 H41 120.6 . . ?
N14 C56 C57 179.2(6) . . ?
C56 C57 H46 109.5 . . ?
C56 C57 H44 109.5 . . ?
H46 C57 H44 109.5 . . ?
C56 C57 H45 109.5 . . ?
H46 C57 H45 109.5 . . ?
H44 C57 H45 109.5 . . ?
N3 C58 C59 123.8(5) . . ?
N3 C58 H50 118.1 . . ?
C59 C58 H50 118.1 . . ?
C60 C59 C58 118.3(4) . . ?
C60 C59 H47 120.8 . . ?
C58 C59 H47 120.8 . . ?
C59 C60 C61 119.1(4) . . ?
C59 C60 H48 120.5 . . ?
C61 C60 H48 120.5 . . ?
C60 C61 C7 118.8(4) . . ?
C60 C61 H49 120.6 . . ?
C7 C61 H49 120.6 . . ?
C63 C62 C1 119.1(4) . . ?
C63 C62 H54 120.4 . . ?
C1 C62 H54 120.4 . . ?
C64 C63 C62 119.2(4) . . ?
C64 C63 H53 120.4 . . ?
C62 C63 H53 120.4 . . ?
C63 C64 C65 118.6(4) . . ?
C63 C64 H52 120.7 . . ?
C65 C64 H52 120.7 . . ?
N1 C65 C64 122.8(4) . . ?
N1 C65 H51 118.6 . . ?
C64 C65 H51 118.6 . . ?
C69 C68 H57 109.5 . . ?
C69 C68 H58 109.5 . . ?
H57 C68 H58 109.5 . . ?
C69 C68 H59 109.5 . . ?
H57 C68 H59 109.5 . . ?
H58 C68 H59 109.5 . . ?
N16 C69 C68 177.8(7) . . ?
N18 C72 C73 179.0(9) . . ?
C72 C73 H61 109.5 . . ?
C72 C73 H60 109.5 . . ?
H61 C73 H60 109.5 . . ?
C72 C73 H62 109.5 . . ?
H61 C73 H62 109.5 . . ?
H60 C73 H62 109.5 . . ?
N19 C74 C75 178.5(6) . . ?
C74 C75 H75A 109.5 . . ?
C74 C75 H75B 109.5 . . ?
H75A C75 H75B 109.5 . . ?
C74 C75 H75C 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
C46 C76 H76A 109.5 . . ?
C46 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C46 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
P6 F11 F13 55.3(5) . . ?
P6 F13 F11 55.4(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C65 N1 C1 C62 -2.5(6) . . . . ?
Ag1 N1 C1 C62 176.9(3) . . . . ?
C65 N1 C1 P1 176.9(3) . . . . ?
Ag1 N1 C1 P1 -3.7(4) . . . . ?
C25 P1 C1 N1 174.3(3) . . . . ?
C41 P1 C1 N1 -80.3(3) . . . . ?
Ag2 P1 C1 N1 46.0(3) . . . . ?
C25 P1 C1 C62 -6.3(4) . . . . ?
C41 P1 C1 C62 99.0(4) . . . . ?
Ag2 P1 C1 C62 -134.6(3) . . . . ?
C3 N2 C2 C6 -0.7(6) . . . . ?
Ag1 N2 C2 C6 -176.3(3) . . . . ?
C3 N2 C2 P2 177.2(3) . . . . ?
Ag1 N2 C2 P2 1.6(4) . . . . ?
C30 P2 C2 N2 -83.3(3) . . . . ?
C7 P2 C2 N2 172.0(3) . . . . ?
Ag2 P2 C2 N2 43.8(3) . . . . ?
C30 P2 C2 C6 94.6(4) . . . . ?
C7 P2 C2 C6 -10.1(4) . . . . ?
Ag2 P2 C2 C6 -138.3(3) . . . . ?
C2 N2 C3 C4 -0.8(6) . . . . ?
Ag1 N2 C3 C4 175.0(3) . . . . ?
N2 C3 C4 C5 1.3(6) . . . . ?
C3 C4 C5 C6 -0.2(6) . . . . ?
C4 C5 C6 C2 -1.3(6) . . . . ?
N2 C2 C6 C5 1.8(6) . . . . ?
P2 C2 C6 C5 -175.9(3) . . . . ?
C58 N3 C7 C61 -0.4(6) . . . . ?
Ag3 N3 C7 C61 -175.3(3) . . . . ?
C58 N3 C7 P2 178.9(3) . . . . ?
Ag3 N3 C7 P2 4.0(4) . . . . ?
C30 P2 C7 N3 168.9(3) . . . . ?
C2 P2 C7 N3 -86.5(3) . . . . ?
Ag2 P2 C7 N3 43.0(3) . . . . ?
C30 P2 C7 C61 -11.7(4) . . . . ?
C2 P2 C7 C61 92.9(4) . . . . ?
Ag2 P2 C7 C61 -137.7(3) . . . . ?
C12 N4 C8 C9 1.8(7) . . . . ?
Ag3 N4 C8 C9 -174.4(4) . . . . ?
N4 C8 C9 C10 -0.3(7) . . . . ?
C8 C9 C10 C11 -0.6(7) . . . . ?
C9 C10 C11 C12 0.0(6) . . . . ?
C8 N4 C12 C11 -2.4(6) . . . . ?
Ag3 N4 C12 C11 173.5(3) . . . . ?
C8 N4 C12 P3 178.3(3) . . . . ?
Ag3 N4 C12 P3 -5.8(4) . . . . ?
C10 C11 C12 N4 1.6(6) . . . . ?
C10 C11 C12 P3 -179.1(3) . . . . ?
C51 P3 C12 N4 175.5(3) . . . . ?
C13 P3 C12 N4 -79.4(3) . . . . ?
Ag2 P3 C12 N4 47.3(3) . . . . ?
C51 P3 C12 C11 -3.8(4) . . . . ?
C13 P3 C12 C11 101.3(4) . . . . ?
Ag2 P3 C12 C11 -132.0(3) . . . . ?
C47 N5 C13 C50 0.0(6) . . . . ?
Ag4 N5 C13 C50 -176.8(3) . . . . ?
C47 N5 C13 P3 178.0(3) . . . . ?
Ag4 N5 C13 P3 1.2(4) . . . . ?
C12 P3 C13 N5 167.7(3) . . . . ?
C51 P3 C13 N5 -87.7(3) . . . . ?
Ag2 P3 C13 N5 41.7(3) . . . . ?
C12 P3 C13 C50 -14.4(4) . . . . ?
C51 P3 C13 C50 90.2(4) . . . . ?
Ag2 P3 C13 C50 -140.3(3) . . . . ?
C18 N6 C14 C15 1.7(6) . . . . ?
Ag4 N6 C14 C15 177.6(4) . . . . ?
N6 C14 C15 C16 -2.3(7) . . . . ?
C14 C15 C16 C17 1.5(7) . . . . ?
C15 C16 C17 C18 -0.4(7) . . . . ?
C14 N6 C18 C17 -0.5(6) . . . . ?
Ag4 N6 C18 C17 -176.2(3) . . . . ?
C14 N6 C18 P4 178.4(3) . . . . ?
Ag4 N6 C18 P4 2.7(4) . . . . ?
C16 C17 C18 N6 -0.2(6) . . . . ?
C16 C17 C18 P4 -179.0(3) . . . . ?
C24 P4 C18 N6 171.1(3) . . . . ?
C19 P4 C18 N6 -84.0(3) . . . . ?
Ag2 P4 C18 N6 43.1(3) . . . . ?
C24 P4 C18 C17 -10.0(4) . . . . ?
C19 P4 C18 C17 94.9(4) . . . . ?
Ag2 P4 C18 C17 -138.0(3) . . . . ?
C20 N7 C19 C23 -0.9(6) . . . . ?
Ag3 N7 C19 C23 178.4(3) . . . . ?
C20 N7 C19 P4 178.1(3) . . . . ?
Ag3 N7 C19 P4 -2.6(4) . . . . ?
C24 P4 C19 N7 -82.4(3) . . . . ?
C18 P4 C19 N7 174.9(3) . . . . ?
Ag2 P4 C19 N7 47.8(3) . . . . ?
C24 P4 C19 C23 96.6(4) . . . . ?
C18 P4 C19 C23 -6.1(4) . . . . ?
Ag2 P4 C19 C23 -133.2(3) . . . . ?
C19 N7 C20 C21 0.9(6) . . . . ?
Ag3 N7 C20 C21 -178.4(3) . . . . ?
N7 C20 C21 C22 -0.7(7) . . . . ?
C20 C21 C22 C23 0.5(7) . . . . ?
N7 C19 C23 C22 0.7(6) . . . . ?
P4 C19 C23 C22 -178.2(3) . . . . ?
C21 C22 C23 C19 -0.5(6) . . . . ?
C37 N8 C24 C40 -1.5(6) . . . . ?
Ag5 N8 C24 C40 -176.1(3) . . . . ?
C37 N8 C24 P4 172.0(3) . . . . ?
Ag5 N8 C24 P4 -2.5(4) . . . . ?
C19 P4 C24 N8 174.1(3) . . . . ?
C18 P4 C24 N8 -81.0(3) . . . . ?
Ag2 P4 C24 N8 45.4(3) . . . . ?
C19 P4 C24 C40 -12.4(4) . . . . ?
C18 P4 C24 C40 92.5(4) . . . . ?
Ag2 P4 C24 C40 -141.1(3) . . . . ?
C29 N9 C25 C26 -0.6(6) . . . . ?
Ag5 N9 C25 C26 -175.6(3) . . . . ?
C29 N9 C25 P1 176.7(3) . . . . ?
Ag5 N9 C25 P1 1.7(4) . . . . ?
C1 P1 C25 N9 -88.0(3) . . . . ?
C41 P1 C25 N9 166.7(3) . . . . ?
Ag2 P1 C25 N9 41.4(3) . . . . ?
C1 P1 C25 C26 89.4(4) . . . . ?
C41 P1 C25 C26 -15.9(4) . . . . ?
Ag2 P1 C25 C26 -141.2(3) . . . . ?
N9 C25 C26 C27 0.2(6) . . . . ?
P1 C25 C26 C27 -176.9(3) . . . . ?
C25 C26 C27 C28 0.1(7) . . . . ?
C26 C27 C28 C29 0.1(7) . . . . ?
C25 N9 C29 C28 0.8(6) . . . . ?
Ag5 N9 C29 C28 176.2(4) . . . . ?
C27 C28 C29 N9 -0.6(7) . . . . ?
C34 N10 C30 C31 -0.5(6) . . . . ?
Ag5 N10 C30 C31 -175.2(3) . . . . ?
C34 N10 C30 P2 177.7(3) . . . . ?
Ag5 N10 C30 P2 3.0(4) . . . . ?
C2 P2 C30 N10 172.6(3) . . . . ?
C7 P2 C30 N10 -82.5(3) . . . . ?
Ag2 P2 C30 N10 43.8(3) . . . . ?
C2 P2 C30 C31 -9.2(4) . . . . ?
C7 P2 C30 C31 95.7(4) . . . . ?
Ag2 P2 C30 C31 -138.0(3) . . . . ?
N10 C30 C31 C32 1.4(7) . . . . ?
P2 C30 C31 C32 -176.6(4) . . . . ?
C30 C31 C32 C33 -1.7(7) . . . . ?
C31 C32 C33 C34 1.1(7) . . . . ?
C30 N10 C34 C33 -0.1(6) . . . . ?
Ag5 N10 C34 C33 174.9(3) . . . . ?
C32 C33 C34 N10 -0.2(7) . . . . ?
C24 N8 C37 C38 -0.8(6) . . . . ?
Ag5 N8 C37 C38 173.9(4) . . . . ?
N8 C37 C38 C39 1.6(7) . . . . ?
C37 C38 C39 C40 -0.1(7) . . . . ?
N8 C24 C40 C39 3.0(6) . . . . ?
P4 C24 C40 C39 -169.9(3) . . . . ?
C38 C39 C40 C24 -2.1(7) . . . . ?
C45 N12 C41 C42 -1.0(6) . . . . ?
Ag4 N12 C41 C42 -176.5(3) . . . . ?
C45 N12 C41 P1 179.0(3) . . . . ?
Ag4 N12 C41 P1 3.5(4) . . . . ?
C1 P1 C41 N12 170.3(3) . . . . ?
C25 P1 C41 N12 -85.1(3) . . . . ?
Ag2 P1 C41 N12 41.6(3) . . . . ?
C1 P1 C41 C42 -9.7(4) . . . . ?
C25 P1 C41 C42 94.9(4) . . . . ?
Ag2 P1 C41 C42 -138.4(3) . . . . ?
N12 C41 C42 C43 2.0(7) . . . . ?
P1 C41 C42 C43 -178.0(4) . . . . ?
C41 C42 C43 C44 -1.3(7) . . . . ?
C42 C43 C44 C45 -0.2(8) . . . . ?
C41 N12 C45 C44 -0.6(7) . . . . ?
Ag4 N12 C45 C44 175.1(4) . . . . ?
C43 C44 C45 N12 1.2(8) . . . . ?
C13 N5 C47 C48 0.3(6) . . . . ?
Ag4 N5 C47 C48 177.2(3) . . . . ?
N5 C47 C48 C49 -0.5(7) . . . . ?
C47 C48 C49 C50 0.4(7) . . . . ?
C48 C49 C50 C13 -0.1(7) . . . . ?
N5 C13 C50 C49 -0.1(6) . . . . ?
P3 C13 C50 C49 -177.9(3) . . . . ?
C52 N13 C51 C55 -1.0(6) . . . . ?
Ag1 N13 C51 C55 -176.7(3) . . . . ?
C52 N13 C51 P3 177.0(3) . . . . ?
Ag1 N13 C51 P3 1.3(4) . . . . ?
C12 P3 C51 N13 -82.6(3) . . . . ?
C13 P3 C51 N13 172.1(3) . . . . ?
Ag2 P3 C51 N13 43.7(3) . . . . ?
C12 P3 C51 C55 95.4(4) . . . . ?
C13 P3 C51 C55 -9.9(4) . . . . ?
Ag2 P3 C51 C55 -138.3(3) . . . . ?
C51 N13 C52 C53 0.6(6) . . . . ?
Ag1 N13 C52 C53 176.6(3) . . . . ?
N13 C52 C53 C54 -0.1(7) . . . . ?
C52 C53 C54 C55 0.0(7) . . . . ?
C53 C54 C55 C51 -0.4(7) . . . . ?
N13 C51 C55 C54 1.0(6) . . . . ?
P3 C51 C55 C54 -176.8(3) . . . . ?
C7 N3 C58 C59 -0.5(7) . . . . ?
Ag3 N3 C58 C59 174.6(4) . . . . ?
N3 C58 C59 C60 -0.3(7) . . . . ?
C58 C59 C60 C61 2.1(7) . . . . ?
C59 C60 C61 C7 -2.9(7) . . . . ?
N3 C7 C61 C60 2.2(6) . . . . ?
P2 C7 C61 C60 -177.1(3) . . . . ?
N1 C1 C62 C63 1.1(6) . . . . ?
P1 C1 C62 C63 -178.2(3) . . . . ?
C1 C62 C63 C64 0.8(7) . . . . ?
C62 C63 C64 C65 -1.1(7) . . . . ?
C1 N1 C65 C64 2.1(7) . . . . ?
Ag1 N1 C65 C64 -177.4(4) . . . . ?
C63 C64 C65 N1 -0.3(7) . . . . ?
F12 P6 F11 F13 170.4(5) . . . . ?
F8 P6 F11 F13 -96.9(4) . . . . ?
F9 P6 F11 F13 85.4(4) . . . . ?
F12 P6 F13 F11 -14.1(8) . . . . ?
F10 P6 F13 F11 176.6(6) . . . . ?
F8 P6 F13 F11 85.7(6) . . . . ?
F9 P6 F13 F11 -95.3(6) . . . . ?

_refine_diff_density_max         1.134
_refine_diff_density_min         -1.028
_refine_diff_density_rms         0.107

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_comp3_b7_sq
_database_code_depnum_ccdc_archive 'CCDC 1532341'
_audit_update_record             
;
2017-08-16 deposited with the CCDC.
2017-08-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
; 
 Complex of AgPF6 with tris(2-pyridyl)phosphine 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C62 H51 Ag5 N13 P4, 5(F6 P) [+ solvent]'
_chemical_formula_sum            'C62 H51 Ag5 F30 N13 P9'
_chemical_formula_weight         2366.24

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   18.482(2)
_cell_length_b                   22.800(3)
_cell_length_c                   24.670(4)
_cell_angle_alpha                90
_cell_angle_beta                 96.390(6)
_cell_angle_gamma                90
_cell_volume                     10331(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    8286
_cell_measurement_theta_min      2.98
_cell_measurement_theta_max      22.52

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_F_000             4616
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.700
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.020
_exptl_absorpt_coefficient_mu    1.163
_shelx_estimated_absorpt_T_min   0.497
_shelx_estimated_absorpt_T_max   0.977
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4258
_exptl_absorpt_correction_T_max  0.8620
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            43586
_diffrn_reflns_av_unetI/netI     0.1420
_diffrn_reflns_av_R_equivalents  0.0914
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.035
_diffrn_reflns_theta_max         25.026
_diffrn_reflns_theta_full        25.026
_diffrn_measured_fraction_theta_max 0.927
_diffrn_measured_fraction_theta_full 0.927
_diffrn_reflns_Laue_measured_fraction_max 0.927
_diffrn_reflns_Laue_measured_fraction_full 0.927
_diffrn_reflns_point_group_measured_fraction_max 0.927
_diffrn_reflns_point_group_measured_fraction_full 0.927
_reflns_number_total             16894
_reflns_number_gt                8007
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1011P)²+69.1385P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16894
_refine_ls_number_parameters     1073
_refine_ls_number_restraints     48
_refine_ls_R_factor_all          0.1770
_refine_ls_R_factor_gt           0.0804
_refine_ls_wR_factor_ref         0.2689
_refine_ls_wR_factor_gt          0.1962
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.034
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.23733(6) 0.39769(5) 0.48235(5) 0.0553(3) Uani 1 1 d . . . . .
Ag2 Ag 0.21826(5) 0.26461(4) 0.52180(4) 0.0386(3) Uani 1 1 d . . . . .
Ag3 Ag 0.13743(6) 0.19187(4) 0.42411(5) 0.0534(3) Uani 1 1 d . . . . .
Ag4 Ag 0.37275(6) 0.20627(5) 0.56330(5) 0.0599(4) Uani 1 1 d . . . . .
Ag5 Ag 0.11841(7) 0.26541(5) 0.61717(5) 0.0601(4) Uani 1 1 d . . . . .
P1 P 0.09264(18) 0.31157(14) 0.49003(15) 0.0404(8) Uani 1 1 d . . . . .
P2 P 0.20000(19) 0.15728(13) 0.55177(15) 0.0423(9) Uani 1 1 d . . . . .
P3 P 0.29936(19) 0.26647(13) 0.44273(15) 0.0409(8) Uani 1 1 d . . . . .
P4 P 0.28279(19) 0.32465(14) 0.60164(15) 0.0413(9) Uani 1 1 d . . . . .
P5 P -0.2298(6) 0.3611(3) 0.4049(3) 0.159(4) Uani 1 1 d D U . . .
P6 P 0.1638(3) -0.0745(2) 0.3538(3) 0.0934(17) Uani 1 1 d . . . . .
P7 P 0.0881(3) 0.5583(2) 0.2903(2) 0.0885(16) Uani 1 1 d . . . . .
P8 P 0.1340(3) 0.2125(2) 0.1792(3) 0.0965(18) Uani 1 1 d . . . . .
P9 P 0.1929(3) -0.0859(3) 0.6350(3) 0.111(2) Uani 1 1 d D U . . .
F3 F -0.1597(12) 0.3767(7) 0.4474(8) 0.225(10) Uani 1 1 d . . . . .
F4 F -0.2595(15) 0.3146(8) 0.4513(8) 0.250(10) Uani 1 1 d . U . . .
F11 F 0.0899(8) -0.1098(6) 0.3545(7) 0.160(6) Uani 1 1 d . . . . .
F10 F 0.1645(15) -0.0672(16) 0.4166(8) 0.318(19) Uani 1 1 d . . . . .
F7 F 0.2348(8) -0.0372(7) 0.3512(10) 0.231(11) Uani 1 1 d . . . . .
F8 F 0.1610(17) -0.0864(11) 0.2916(10) 0.309(17) Uani 1 1 d . . . . .
F9 F 0.1202(10) -0.0231(7) 0.3408(14) 0.303(17) Uani 1 1 d . . . . .
F18 F 0.1546(8) 0.6001(6) 0.2757(8) 0.167(6) Uani 1 1 d . . . . .
F17 F 0.1384(10) 0.5251(7) 0.3362(7) 0.202(8) Uani 1 1 d . . . . .
F16 F 0.0715(9) 0.6067(5) 0.3362(6) 0.142(5) Uani 1 1 d . . . . .
F15 F 0.1060(8) 0.5118(6) 0.2448(7) 0.166(6) Uani 1 1 d . . . . .
F14 F 0.0327(9) 0.5937(7) 0.2470(6) 0.173(6) Uani 1 1 d . . . . .
F13 F 0.0191(7) 0.5213(5) 0.3042(6) 0.139(5) Uani 1 1 d . . . . .
F23 F 0.0514(10) 0.2178(12) 0.1758(16) 0.333(19) Uani 1 1 d . . . . .
F22 F 0.2187(10) 0.2045(13) 0.1801(12) 0.293(14) Uani 1 1 d . . . . .
F21 F 0.1268(11) 0.2744(7) 0.2082(8) 0.208(9) Uani 1 1 d . . . . .
F20 F 0.143(2) 0.1874(11) 0.2359(10) 0.37(2) Uani 1 1 d . . . . .
F26 F 0.1231(9) -0.1261(9) 0.6326(9) 0.213(9) Uani 1 1 d . . . . .
F25 F 0.2656(11) -0.0503(9) 0.6378(11) 0.258(11) Uani 1 1 d . . . . .
C63 C 0.0758(7) 0.3839(5) 0.5196(5) 0.044(3) Uani 1 1 d . . . . .
N2 N 0.1338(6) 0.4200(4) 0.5212(5) 0.046(3) Uani 1 1 d . . . . .
N3 N 0.0934(6) 0.2791(4) 0.3872(5) 0.047(3) Uani 1 1 d . . . . .
N4 N 0.0804(6) 0.1362(4) 0.4854(5) 0.049(3) Uani 1 1 d . . . . .
C62 C 0.2596(7) 0.1020(5) 0.5261(5) 0.042(3) Uani 1 1 d . . . . .
N6 N 0.3279(6) 0.1186(4) 0.5269(5) 0.049(3) Uani 1 1 d . . . . .
N7 N 0.4274(6) 0.2678(5) 0.5057(5) 0.049(3) Uani 1 1 d . . . . .
N8 N 0.2433(6) 0.3640(5) 0.3953(5) 0.049(3) Uani 1 1 d . . . . .
N9 N 0.2500(6) 0.1631(4) 0.4006(5) 0.051(3) Uani 1 1 d . . . . .
N10 N 0.3551(6) 0.2345(5) 0.6500(5) 0.051(3) Uani 1 1 d . . . . .
N11 N 0.1620(6) 0.3576(4) 0.6459(5) 0.050(3) Uani 1 1 d . . . . .
N12 N 0.0184(6) 0.2465(4) 0.5532(5) 0.049(3) Uani 1 1 d . . . . .
C28 C 0.3603(7) 0.3715(5) 0.5855(6) 0.045(3) Uani 1 1 d . . . . .
N14 N 0.3436(7) 0.4046(5) 0.5418(5) 0.058(3) Uani 1 1 d . . . . .
C61 C 0.4248(8) 0.3738(6) 0.6172(7) 0.071(5) Uani 1 1 d . . . . .
H61A H 0.4347 0.3482 0.6464 0.085 Uiso 1 1 calc R U . . .
C1 C 0.1279(10) 0.4735(6) 0.5438(7) 0.068(5) Uani 1 1 d . . . . .
H4 H 0.1663 0.4997 0.5430 0.082 Uiso 1 1 calc R U . . .
C2 C 0.0680(11) 0.4911(6) 0.5678(7) 0.068(5) Uani 1 1 d . . . . .
H3 H 0.0677 0.5269 0.5858 0.082 Uiso 1 1 calc R U . . .
C3 C 0.0101(10) 0.4555(7) 0.5647(7) 0.070(5) Uani 1 1 d . . . . .
H2 H -0.0324 0.4683 0.5779 0.084 Uiso 1 1 calc R U . . .
C4 C 0.0122(8) 0.3983(6) 0.5416(6) 0.057(4) Uani 1 1 d . . . . .
H1 H -0.0267 0.3724 0.5413 0.069 Uiso 1 1 calc R U . . .
C5 C 0.0758(6) 0.3243(6) 0.4173(5) 0.041(3) Uani 1 1 d . . . . .
C6 C 0.1105(7) 0.1236(5) 0.5347(6) 0.043(3) Uani 1 1 d . . . . .
C7 C 0.4980(8) 0.2817(8) 0.5163(8) 0.076(5) Uani 1 1 d . . . . .
H15 H 0.5228 0.2639 0.5468 0.092 Uiso 1 1 calc R U . . .
C8 C 0.5367(11) 0.3173(8) 0.4889(9) 0.088(6) Uani 1 1 d . . . . .
H5 H 0.5858 0.3245 0.4995 0.105 Uiso 1 1 calc R U . . .
C9 C 0.4993(10) 0.3435(8) 0.4430(10) 0.094(6) Uani 1 1 d . . . . .
H6 H 0.5228 0.3705 0.4227 0.113 Uiso 1 1 calc R U . . .
C10 C 0.4271(8) 0.3294(7) 0.4278(7) 0.068(5) Uani 1 1 d . . . . .
H14 H 0.4021 0.3449 0.3962 0.081 Uiso 1 1 calc R U . . .
C11 C 0.3934(7) 0.2921(6) 0.4605(7) 0.053(4) Uani 1 1 d . . . . .
C12 C 0.2700(7) 0.3109(5) 0.3824(6) 0.039(3) Uani 1 1 d . . . . .
C13 C 0.2253(8) 0.4009(6) 0.3515(7) 0.060(4) Uani 1 1 d . . . . .
H7 H 0.2105 0.4386 0.3594 0.072 Uiso 1 1 calc R U . . .
C14 C 0.2269(8) 0.3878(7) 0.2993(6) 0.057(4) Uani 1 1 d . . . . .
H8 H 0.2124 0.4145 0.2717 0.068 Uiso 1 1 calc R U . . .
C15 C 0.2515(8) 0.3319(6) 0.2882(6) 0.053(4) Uani 1 1 d . . . . .
H9 H 0.2541 0.3202 0.2523 0.064 Uiso 1 1 calc R U . . .
C16 C 0.2721(9) 0.2938(6) 0.3308(6) 0.060(4) Uani 1 1 d . . . . .
H10 H 0.2876 0.2561 0.3235 0.072 Uiso 1 1 calc R U . . .
C17 C 0.3114(7) 0.1940(5) 0.4091(6) 0.044(3) Uani 1 1 d . . . . .
C18 C 0.2547(8) 0.1129(6) 0.3747(7) 0.063(5) Uani 1 1 d . . . . .
H13 H 0.2134 0.0892 0.3703 0.076 Uiso 1 1 calc R U . . .
C19 C 0.3158(10) 0.0930(7) 0.3538(8) 0.076(5) Uani 1 1 d . . . . .
H19A H 0.3155 0.0589 0.3331 0.091 Uiso 1 1 calc R U . . .
C20 C 0.3778(9) 0.1264(7) 0.3651(7) 0.074(5) Uani 1 1 d . . . . .
H12 H 0.4213 0.1140 0.3532 0.088 Uiso 1 1 calc R U . . .
C21 C 0.3762(8) 0.1770(6) 0.3935(7) 0.068(5) Uani 1 1 d . . . . .
H11 H 0.4181 0.1993 0.4019 0.081 Uiso 1 1 calc R U . . .
C22 C 0.3859(10) 0.2016(7) 0.6932(8) 0.080(5) Uani 1 1 d . . . . .
H32 H 0.4133 0.1689 0.6858 0.096 Uiso 1 1 calc R U . . .
C23 C 0.3782(12) 0.2142(9) 0.7460(7) 0.097(7) Uani 1 1 d . . . . .
H31 H 0.3971 0.1888 0.7735 0.116 Uiso 1 1 calc R U . . .
C24 C 0.3420(11) 0.2655(8) 0.7595(7) 0.088(6) Uani 1 1 d . . . . .
H30 H 0.3363 0.2753 0.7954 0.106 Uiso 1 1 calc R U . . .
C25 C 0.3155(9) 0.3002(6) 0.7163(6) 0.064(4) Uani 1 1 d . . . . .
H29 H 0.2926 0.3354 0.7231 0.076 Uiso 1 1 calc R U . . .
C26 C 0.3221(7) 0.2840(5) 0.6617(6) 0.047(4) Uani 1 1 d . . . . .
C27 C 0.2277(7) 0.3787(6) 0.6348(5) 0.044(3) Uani 1 1 d . . . . .
N5 N 0.1823(7) 0.1849(5) 0.6549(5) 0.062(3) Uani 1 1 d . . . . .
C29 C 0.2156(7) 0.1447(6) 0.6256(6) 0.047(3) Uani 1 1 d . . . . .
C30 C 0.2507(11) 0.0964(7) 0.6483(8) 0.090(6) Uani 1 1 d . . . . .
H18 H 0.2735 0.0693 0.6278 0.108 Uiso 1 1 calc R U . . .
C31 C 0.2499(13) 0.0906(9) 0.7054(8) 0.119(8) Uani 1 1 d D U . . .
H17 H 0.2693 0.0571 0.7229 0.143 Uiso 1 1 calc R U . . .
C32 C 0.2203(14) 0.1345(11) 0.7356(8) 0.121(9) Uani 1 1 d D U . . .
H32A H 0.2228 0.1311 0.7733 0.145 Uiso 1 1 calc R U . . .
C33 C 0.1890(12) 0.1805(8) 0.7115(7) 0.095(7) Uani 1 1 d . . . . .
H16 H 0.1712 0.2103 0.7321 0.115 Uiso 1 1 calc R U . . .
C34 C -0.0402(9) 0.2137(6) 0.5662(7) 0.065(5) Uani 1 1 d . . . . .
H22 H -0.0364 0.1947 0.5997 0.078 Uiso 1 1 calc R U . . .
C35 C -0.1026(9) 0.2079(8) 0.5328(10) 0.091(7) Uani 1 1 d . . . . .
H19 H -0.1422 0.1878 0.5437 0.109 Uiso 1 1 calc R U . . .
C36 C -0.1054(9) 0.2323(8) 0.4831(9) 0.088(6) Uani 1 1 d . . . . .
H20 H -0.1475 0.2287 0.4589 0.106 Uiso 1 1 calc R U . . .
C37 C -0.0483(8) 0.2616(7) 0.4679(8) 0.067(5) Uani 1 1 d . . . . .
H21 H -0.0501 0.2772 0.4330 0.080 Uiso 1 1 calc R U . . .
C38 C 0.0108(7) 0.2683(6) 0.5030(7) 0.050(4) Uani 1 1 d . . . . .
C39 C 0.1200(8) 0.3918(7) 0.6739(7) 0.064(4) Uani 1 1 d . . . . .
H26 H 0.0745 0.3780 0.6808 0.076 Uiso 1 1 calc R U . . .
C40 C 0.1415(9) 0.4450(7) 0.6923(7) 0.068(5) Uani 1 1 d . . . . .
H23 H 0.1119 0.4673 0.7125 0.082 Uiso 1 1 calc R U . . .
C41 C 0.2087(11) 0.4667(6) 0.6808(6) 0.074(5) Uani 1 1 d . . . . .
H24 H 0.2239 0.5036 0.6935 0.089 Uiso 1 1 calc R U . . .
C42 C 0.2536(8) 0.4336(5) 0.6504(6) 0.049(4) Uani 1 1 d . . . . .
H25 H 0.2979 0.4476 0.6413 0.058 Uiso 1 1 calc R U . . .
C43 C 0.3923(10) 0.4434(8) 0.5304(7) 0.082(6) Uani 1 1 d . . . . .
H28 H 0.3808 0.4679 0.5006 0.099 Uiso 1 1 calc R U . . .
C44 C 0.4582(10) 0.4496(8) 0.5596(8) 0.093(6) Uani 1 1 d . . . . .
H44A H 0.4918 0.4768 0.5496 0.112 Uiso 1 1 calc R U . . .
C45 C 0.4741(10) 0.4134(8) 0.6058(9) 0.091(6) Uani 1 1 d . . . . .
H27 H 0.5180 0.4171 0.6279 0.109 Uiso 1 1 calc R U . . .
C46 C 0.3766(10) 0.0798(7) 0.5102(7) 0.073(5) Uani 1 1 d . . . . .
H36 H 0.4251 0.0904 0.5098 0.088 Uiso 1 1 calc R U . . .
C47 C 0.3531(11) 0.0246(7) 0.4938(7) 0.081(5) Uani 1 1 d . . . . .
H35 H 0.3871 -0.0015 0.4826 0.097 Uiso 1 1 calc R U . . .
C48 C 0.2834(11) 0.0063(7) 0.4931(8) 0.082(6) Uani 1 1 d . . . . .
H34 H 0.2689 -0.0315 0.4827 0.099 Uiso 1 1 calc R U . . .
C49 C 0.2366(8) 0.0465(5) 0.5084(7) 0.064(4) Uani 1 1 d . . . . .
H33 H 0.1876 0.0369 0.5071 0.076 Uiso 1 1 calc R U . . .
C50 C 0.0768(9) 0.0870(6) 0.5692(7) 0.062(4) Uani 1 1 d . . . . .
H38 H 0.1003 0.0782 0.6035 0.074 Uiso 1 1 calc R U . . .
N13 N 0.0688(9) 0.1353(7) 0.3465(7) 0.094(5) Uani 1 1 d . . . . .
C55 C 0.0349(12) 0.1129(9) 0.3116(8) 0.082(5) Uani 1 1 d . . . . .
C56 C -0.0085(14) 0.0791(13) 0.2699(10) 0.166(13) Uani 1 1 d . . . . .
H42 H -0.0064 0.0383 0.2796 0.249 Uiso 1 1 calc R U . . .
H44 H 0.0103 0.0843 0.2355 0.249 Uiso 1 1 calc R U . . .
H43 H -0.0582 0.0922 0.2671 0.249 Uiso 1 1 calc R U . . .
C57 C 0.0794(9) 0.2840(7) 0.3323(7) 0.064(4) Uani 1 1 d . . . . .
H45 H 0.0898 0.2518 0.3114 0.077 Uiso 1 1 calc R U . . .
C58 C 0.0514(9) 0.3320(7) 0.3056(8) 0.072(5) Uani 1 1 d . . . . .
H46 H 0.0449 0.3336 0.2677 0.086 Uiso 1 1 calc R U . . .
C59 C 0.0321(9) 0.3804(7) 0.3381(8) 0.074(5) Uani 1 1 d . . . . .
H48 H 0.0111 0.4140 0.3219 0.089 Uiso 1 1 calc R U . . .
C60 C 0.0454(8) 0.3759(6) 0.3942(7) 0.065(4) Uani 1 1 d . . . . .
H47 H 0.0343 0.4070 0.4163 0.078 Uiso 1 1 calc R U . . .
C53 C 0.0120(8) 0.1139(6) 0.4688(7) 0.062(4) Uani 1 1 d . . . . .
H53A H -0.0114 0.1237 0.4347 0.074 Uiso 1 1 calc R U . . .
C51 C 0.0101(9) 0.0640(6) 0.5536(8) 0.063(5) Uani 1 1 d . . . . .
H51A H -0.0132 0.0400 0.5768 0.075 Uiso 1 1 calc R U . . .
C52 C -0.0216(9) 0.0773(7) 0.5025(9) 0.078(5) Uani 1 1 d . . . . .
H52A H -0.0668 0.0614 0.4902 0.093 Uiso 1 1 calc R U . . .
F2 F -0.2969(13) 0.3452(9) 0.3592(7) 0.240(11) Uani 1 1 d . . . . .
F19 F 0.1393(18) 0.1530(8) 0.1515(13) 0.337(17) Uani 1 1 d . . . . .
F1 F -0.1813(13) 0.3097(8) 0.3787(8) 0.223(9) Uani 1 1 d . . . . .
F6 F -0.1922(15) 0.4027(9) 0.3600(9) 0.263(12) Uani 1 1 d . . . . .
F24 F 0.1353(14) 0.2445(11) 0.1181(8) 0.257(11) Uani 1 1 d . . . . .
F12 F 0.2109(13) -0.1271(13) 0.371(2) 0.44(3) Uani 1 1 d . . . . .
F5 F -0.2673(14) 0.4135(9) 0.4345(9) 0.300(12) Uani 1 1 d D U . . .
F27 F 0.1467(15) -0.0317(8) 0.6143(15) 0.39(2) Uani 1 1 d D . . . .
F28 F 0.2000(16) -0.0925(13) 0.6990(5) 0.286(11) Uani 1 1 d D U . . .
F29 F 0.1971(15) -0.1051(12) 0.5729(6) 0.282(11) Uani 1 1 d D U . . .
F30 F 0.2503(12) -0.1365(9) 0.6528(15) 0.300(12) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N8 2.296(11) . ?
Ag1 N2 2.291(11) . ?
Ag1 N14 2.322(12) . ?
Ag1 Ag2 3.2176(14) . ?
Ag2 P4 2.579(4) . ?
Ag2 P2 2.589(3) . ?
Ag2 P3 2.589(4) . ?
Ag2 P1 2.597(3) . ?
Ag2 Ag5 3.1476(16) . ?
Ag2 Ag3 3.1605(15) . ?
Ag2 Ag4 3.2123(15) . ?
Ag3 N3 2.299(10) . ?
Ag3 N9 2.315(11) . ?
Ag3 N4 2.316(11) . ?
Ag3 N13 2.530(18) . ?
Ag4 N10 2.292(11) . ?
Ag4 N6 2.308(11) . ?
Ag4 N7 2.308(12) . ?
Ag5 N5 2.320(12) . ?
Ag5 N11 2.332(11) . ?
Ag5 N12 2.332(12) . ?
P1 C5 1.810(13) . ?
P1 C63 1.844(13) . ?
P1 C38 1.863(13) . ?
P2 C6 1.830(14) . ?
P2 C62 1.832(13) . ?
P2 C29 1.833(14) . ?
P3 C12 1.832(13) . ?
P3 C11 1.840(14) . ?
P3 C17 1.873(13) . ?
P4 C26 1.829(13) . ?
P4 C27 1.845(12) . ?
P4 C28 1.864(13) . ?
P5 F5 1.599(9) . ?
P5 F2 1.622(19) . ?
P5 F1 1.65(2) . ?
P5 F3 1.612(18) . ?
P5 F4 1.69(2) . ?
P5 F6 1.67(2) . ?
P6 F9 1.438(15) . ?
P6 F12 1.51(2) . ?
P6 F8 1.55(2) . ?
P6 F10 1.56(2) . ?
P6 F11 1.589(13) . ?
P6 F7 1.570(13) . ?
P7 F17 1.575(14) . ?
P7 F13 1.598(13) . ?
P7 F14 1.612(14) . ?
P7 F15 1.606(14) . ?
P7 F16 1.634(13) . ?
P7 F18 1.627(14) . ?
P8 F20 1.50(2) . ?
P8 F19 1.53(2) . ?
P8 F22 1.57(2) . ?
P8 F23 1.523(19) . ?
P8 F21 1.594(14) . ?
P8 F24 1.68(2) . ?
P9 F30 1.597(10) . ?
P9 F27 1.556(9) . ?
P9 F29 1.603(10) . ?
P9 F26 1.578(16) . ?
P9 F25 1.564(16) . ?
P9 F28 1.579(9) . ?
C63 N2 1.349(16) . ?
C63 C4 1.388(18) . ?
N2 C1 1.349(16) . ?
N3 C5 1.333(16) . ?
N3 C57 1.354(18) . ?
N4 C6 1.313(17) . ?
N4 C53 1.381(17) . ?
C62 N6 1.317(16) . ?
C62 C49 1.390(18) . ?
N6 C46 1.357(18) . ?
N7 C7 1.340(18) . ?
N7 C11 1.337(18) . ?
N8 C12 1.356(15) . ?
N8 C13 1.381(18) . ?
N9 C18 1.319(15) . ?
N9 C17 1.334(16) . ?
N10 C26 1.330(15) . ?
N10 C22 1.373(19) . ?
N11 C39 1.343(16) . ?
N11 C27 1.363(17) . ?
N12 C38 1.328(18) . ?
N12 C34 1.383(17) . ?
C28 N14 1.325(17) . ?
C28 C61 1.352(19) . ?
N14 C43 1.315(18) . ?
C61 C45 1.33(2) . ?
C61 H61A 0.9300 . ?
C1 C2 1.37(2) . ?
C1 H4 0.9300 . ?
C2 C3 1.34(2) . ?
C2 H3 0.9300 . ?
C3 C4 1.42(2) . ?
C3 H2 0.9300 . ?
C4 H1 0.9300 . ?
C5 C60 1.397(17) . ?
C6 C50 1.386(19) . ?
C7 C8 1.32(2) . ?
C7 H15 0.9300 . ?
C8 C9 1.39(3) . ?
C8 H5 0.9300 . ?
C9 C10 1.38(2) . ?
C9 H6 0.9300 . ?
C10 C11 1.37(2) . ?
C10 H14 0.9300 . ?
C12 C16 1.336(18) . ?
C13 C14 1.32(2) . ?
C13 H7 0.9300 . ?
C14 C15 1.390(19) . ?
C14 H8 0.9300 . ?
C15 C16 1.386(19) . ?
C15 H9 0.9300 . ?
C16 H10 0.9300 . ?
C17 C21 1.355(18) . ?
C18 C19 1.37(2) . ?
C18 H13 0.9300 . ?
C19 C20 1.38(2) . ?
C19 H19A 0.9300 . ?
C20 C21 1.349(19) . ?
C20 H12 0.9300 . ?
C21 H11 0.9300 . ?
C22 C23 1.36(2) . ?
C22 H32 0.9300 . ?
C23 C24 1.41(2) . ?
C23 H31 0.9300 . ?
C24 C25 1.37(2) . ?
C24 H30 0.9300 . ?
C25 C26 1.414(19) . ?
C25 H29 0.9300 . ?
C27 C42 1.379(17) . ?
N5 C29 1.357(17) . ?
N5 C33 1.391(19) . ?
C29 C30 1.366(19) . ?
C30 C31 1.42(2) . ?
C30 H18 0.9300 . ?
C31 C32 1.397(10) . ?
C31 H17 0.9300 . ?
C32 C33 1.31(2) . ?
C32 H32A 0.9300 . ?
C33 H16 0.9300 . ?
C34 C35 1.35(2) . ?
C34 H22 0.9300 . ?
C35 C36 1.34(3) . ?
C35 H19 0.9300 . ?
C36 C37 1.34(2) . ?
C36 H20 0.9300 . ?
C37 C38 1.32(2) . ?
C37 H21 0.9300 . ?
C39 C40 1.34(2) . ?
C39 H26 0.9300 . ?
C40 C41 1.40(2) . ?
C40 H23 0.9300 . ?
C41 C42 1.40(2) . ?
C41 H24 0.9300 . ?
C42 H25 0.9300 . ?
C43 C44 1.35(2) . ?
C43 H28 0.9300 . ?
C44 C45 1.41(2) . ?
C44 H44A 0.9300 . ?
C45 H27 0.9300 . ?
C46 C47 1.38(2) . ?
C46 H36 0.9300 . ?
C47 C48 1.35(2) . ?
C47 H35 0.9300 . ?
C48 C49 1.34(2) . ?
C48 H34 0.9300 . ?
C49 H33 0.9300 . ?
C50 C51 1.36(2) . ?
C50 H38 0.9300 . ?
N13 C55 1.13(2) . ?
C55 C56 1.45(3) . ?
C56 H42 0.9600 . ?
C56 H44 0.9600 . ?
C56 H43 0.9600 . ?
C57 C58 1.35(2) . ?
C57 H45 0.9300 . ?
C58 C59 1.43(2) . ?
C58 H46 0.9300 . ?
C59 C60 1.38(2) . ?
C59 H48 0.9300 . ?
C60 H47 0.9300 . ?
C53 C52 1.37(2) . ?
C53 H53A 0.9300 . ?
C51 C52 1.36(2) . ?
C51 H51A 0.9300 . ?
C52 H52A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Ag1 N2 126.6(4) . . ?
N8 Ag1 N14 119.2(4) . . ?
N2 Ag1 N14 114.1(4) . . ?
N8 Ag1 Ag2 89.2(3) . . ?
N2 Ag1 Ag2 87.6(3) . . ?
N14 Ag1 Ag2 89.2(3) . . ?
P4 Ag2 P2 110.33(11) . . ?
P4 Ag2 P3 108.02(11) . . ?
P2 Ag2 P3 109.60(11) . . ?
P4 Ag2 P1 109.48(11) . . ?
P2 Ag2 P1 109.58(11) . . ?
P3 Ag2 P1 109.81(12) . . ?
P4 Ag2 Ag5 71.69(9) . . ?
P2 Ag2 Ag5 71.71(9) . . ?
P3 Ag2 Ag5 178.63(8) . . ?
P1 Ag2 Ag5 69.17(9) . . ?
P4 Ag2 Ag3 179.31(9) . . ?
P2 Ag2 Ag3 69.89(8) . . ?
P3 Ag2 Ag3 72.44(8) . . ?
P1 Ag2 Ag3 69.84(8) . . ?
Ag5 Ag2 Ag3 107.84(4) . . ?
P4 Ag2 Ag4 69.96(8) . . ?
P2 Ag2 Ag4 69.95(8) . . ?
P3 Ag2 Ag4 71.24(8) . . ?
P1 Ag2 Ag4 178.95(9) . . ?
Ag5 Ag2 Ag4 109.78(4) . . ?
Ag3 Ag2 Ag4 110.71(4) . . ?
P4 Ag2 Ag1 70.95(8) . . ?
P2 Ag2 Ag1 178.55(9) . . ?
P3 Ag2 Ag1 70.40(7) . . ?
P1 Ag2 Ag1 69.17(8) . . ?
Ag5 Ag2 Ag1 108.28(4) . . ?
Ag3 Ag2 Ag1 108.82(4) . . ?
Ag4 Ag2 Ag1 111.31(4) . . ?
N3 Ag3 N9 115.7(4) . . ?
N3 Ag3 N4 124.5(4) . . ?
N9 Ag3 N4 119.6(4) . . ?
N3 Ag3 N13 90.9(5) . . ?
N9 Ag3 N13 93.1(5) . . ?
N4 Ag3 N13 89.3(5) . . ?
N3 Ag3 Ag2 88.0(3) . . ?
N9 Ag3 Ag2 88.7(3) . . ?
N4 Ag3 Ag2 90.1(3) . . ?
N13 Ag3 Ag2 178.1(4) . . ?
N10 Ag4 N6 121.7(4) . . ?
N10 Ag4 N7 121.4(4) . . ?
N6 Ag4 N7 116.8(4) . . ?
N10 Ag4 Ag2 88.1(3) . . ?
N6 Ag4 Ag2 88.1(3) . . ?
N7 Ag4 Ag2 89.2(3) . . ?
N5 Ag5 N11 116.6(4) . . ?
N5 Ag5 N12 117.0(4) . . ?
N11 Ag5 N12 126.4(4) . . ?
N5 Ag5 Ag2 88.9(3) . . ?
N11 Ag5 Ag2 91.2(3) . . ?
N12 Ag5 Ag2 88.8(3) . . ?
C5 P1 C63 103.3(6) . . ?
C5 P1 C38 101.7(7) . . ?
C63 P1 C38 103.3(6) . . ?
C5 P1 Ag2 114.5(4) . . ?
C63 P1 Ag2 115.7(4) . . ?
C38 P1 Ag2 116.4(4) . . ?
C6 P2 C62 101.2(6) . . ?
C6 P2 C29 101.6(6) . . ?
C62 P2 C29 101.6(6) . . ?
C6 P2 Ag2 118.3(4) . . ?
C62 P2 Ag2 116.7(4) . . ?
C29 P2 Ag2 114.8(4) . . ?
C12 P3 C11 101.8(7) . . ?
C12 P3 C17 99.6(6) . . ?
C11 P3 C17 103.2(6) . . ?
C12 P3 Ag2 118.5(4) . . ?
C11 P3 Ag2 115.9(5) . . ?
C17 P3 Ag2 115.3(4) . . ?
C26 P4 C27 99.7(6) . . ?
C26 P4 C28 102.6(7) . . ?
C27 P4 C28 100.8(6) . . ?
C26 P4 Ag2 117.3(4) . . ?
C27 P4 Ag2 117.5(4) . . ?
C28 P4 Ag2 116.2(4) . . ?
F5 P5 F2 98.5(14) . . ?
F5 P5 F1 172.7(14) . . ?
F2 P5 F1 88.6(11) . . ?
F5 P5 F3 84.0(11) . . ?
F2 P5 F3 176.4(15) . . ?
F1 P5 F3 88.8(11) . . ?
F5 P5 F4 88.3(14) . . ?
F2 P5 F4 92.9(11) . . ?
F1 P5 F4 93.0(11) . . ?
F3 P5 F4 89.8(11) . . ?
F5 P5 F6 96.3(13) . . ?
F2 P5 F6 90.5(11) . . ?
F1 P5 F6 81.9(13) . . ?
F3 P5 F6 86.6(13) . . ?
F4 P5 F6 173.8(15) . . ?
F9 P6 F12 177(3) . . ?
F9 P6 F8 88.1(17) . . ?
F12 P6 F8 95(2) . . ?
F9 P6 F10 94.4(18) . . ?
F12 P6 F10 83(2) . . ?
F8 P6 F10 175.8(13) . . ?
F9 P6 F11 87.4(10) . . ?
F12 P6 F11 93.6(12) . . ?
F8 P6 F11 89.3(11) . . ?
F10 P6 F11 87.4(10) . . ?
F9 P6 F7 90.0(10) . . ?
F12 P6 F7 89.0(13) . . ?
F8 P6 F7 89.6(12) . . ?
F10 P6 F7 93.9(12) . . ?
F11 P6 F7 177.2(10) . . ?
F17 P7 F13 90.8(10) . . ?
F17 P7 F14 175.6(10) . . ?
F13 P7 F14 86.7(9) . . ?
F17 P7 F15 91.9(10) . . ?
F13 P7 F15 91.8(8) . . ?
F14 P7 F15 91.8(9) . . ?
F17 P7 F16 88.2(9) . . ?
F13 P7 F16 89.6(8) . . ?
F14 P7 F16 88.1(8) . . ?
F15 P7 F16 178.6(8) . . ?
F17 P7 F18 92.4(10) . . ?
F13 P7 F18 175.9(8) . . ?
F14 P7 F18 90.0(9) . . ?
F15 P7 F18 90.7(8) . . ?
F16 P7 F18 87.9(8) . . ?
F20 P8 F19 94.1(15) . . ?
F20 P8 F22 86.5(17) . . ?
F19 P8 F22 77.9(15) . . ?
F20 P8 F23 94.8(19) . . ?
F19 P8 F23 99.2(15) . . ?
F22 P8 F23 176.9(15) . . ?
F20 P8 F21 85.7(13) . . ?
F19 P8 F21 178.9(17) . . ?
F22 P8 F21 103.2(13) . . ?
F23 P8 F21 79.7(12) . . ?
F20 P8 F24 172.4(19) . . ?
F19 P8 F24 88.7(15) . . ?
F22 P8 F24 87.1(15) . . ?
F23 P8 F24 91.8(17) . . ?
F21 P8 F24 91.6(12) . . ?
F30 P9 F27 171.4(18) . . ?
F30 P9 F29 87.9(16) . . ?
F27 P9 F29 89.3(17) . . ?
F30 P9 F26 96.1(13) . . ?
F27 P9 F26 91.9(14) . . ?
F29 P9 F26 86.1(12) . . ?
F30 P9 F25 79.7(13) . . ?
F27 P9 F25 92.3(14) . . ?
F29 P9 F25 92.9(14) . . ?
F26 P9 F25 175.7(12) . . ?
F30 P9 F28 71.1(14) . . ?
F27 P9 F28 113(2) . . ?
F29 P9 F28 157.3(16) . . ?
F26 P9 F28 87.6(12) . . ?
F25 P9 F28 91.7(14) . . ?
N2 C63 C4 123.3(12) . . ?
N2 C63 P1 112.8(9) . . ?
C4 C63 P1 123.7(11) . . ?
C1 N2 C63 117.6(13) . . ?
C1 N2 Ag1 118.9(10) . . ?
C63 N2 Ag1 123.4(8) . . ?
C5 N3 C57 117.6(12) . . ?
C5 N3 Ag3 123.1(9) . . ?
C57 N3 Ag3 119.2(10) . . ?
C6 N4 C53 118.2(13) . . ?
C6 N4 Ag3 123.3(9) . . ?
C53 N4 Ag3 118.5(10) . . ?
N6 C62 C49 121.6(12) . . ?
N6 C62 P2 114.2(10) . . ?
C49 C62 P2 124.1(11) . . ?
C62 N6 C46 118.4(12) . . ?
C62 N6 Ag4 123.8(9) . . ?
C46 N6 Ag4 117.5(10) . . ?
C7 N7 C11 115.0(14) . . ?
C7 N7 Ag4 120.4(12) . . ?
C11 N7 Ag4 124.6(10) . . ?
C12 N8 C13 115.0(12) . . ?
C12 N8 Ag1 125.0(9) . . ?
C13 N8 Ag1 119.7(9) . . ?
C18 N9 C17 115.7(12) . . ?
C18 N9 Ag3 118.5(9) . . ?
C17 N9 Ag3 125.8(8) . . ?
C26 N10 C22 117.1(13) . . ?
C26 N10 Ag4 123.9(9) . . ?
C22 N10 Ag4 118.7(10) . . ?
C39 N11 C27 118.5(12) . . ?
C39 N11 Ag5 118.7(10) . . ?
C27 N11 Ag5 122.8(9) . . ?
C38 N12 C34 114.4(13) . . ?
C38 N12 Ag5 123.7(9) . . ?
C34 N12 Ag5 121.8(10) . . ?
N14 C28 C61 123.9(13) . . ?
N14 C28 P4 112.7(10) . . ?
C61 C28 P4 123.3(12) . . ?
C43 N14 C28 117.1(13) . . ?
C43 N14 Ag1 117.5(11) . . ?
C28 N14 Ag1 125.4(9) . . ?
C45 C61 C28 119.0(16) . . ?
C45 C61 H61A 120.5 . . ?
C28 C61 H61A 120.5 . . ?
N2 C1 C2 123.3(15) . . ?
N2 C1 H4 118.4 . . ?
C2 C1 H4 118.4 . . ?
C3 C2 C1 118.4(14) . . ?
C3 C2 H3 120.8 . . ?
C1 C2 H3 120.8 . . ?
C2 C3 C4 121.4(15) . . ?
C2 C3 H2 119.3 . . ?
C4 C3 H2 119.3 . . ?
C63 C4 C3 115.8(14) . . ?
C63 C4 H1 122.1 . . ?
C3 C4 H1 122.1 . . ?
N3 C5 C60 122.4(13) . . ?
N3 C5 P1 113.7(9) . . ?
C60 C5 P1 123.8(11) . . ?
N4 C6 C50 121.8(13) . . ?
N4 C6 P2 113.6(10) . . ?
C50 C6 P2 124.6(12) . . ?
C8 C7 N7 128.2(18) . . ?
C8 C7 H15 115.9 . . ?
N7 C7 H15 115.9 . . ?
C7 C8 C9 115.6(17) . . ?
C7 C8 H5 122.2 . . ?
C9 C8 H5 122.2 . . ?
C10 C9 C8 119.9(16) . . ?
C10 C9 H6 120.1 . . ?
C8 C9 H6 120.1 . . ?
C11 C10 C9 118.2(16) . . ?
C11 C10 H14 120.9 . . ?
C9 C10 H14 120.9 . . ?
C10 C11 N7 123.1(13) . . ?
C10 C11 P3 122.4(12) . . ?
N7 C11 P3 114.3(11) . . ?
C16 C12 N8 122.3(12) . . ?
C16 C12 P3 125.0(10) . . ?
N8 C12 P3 112.7(10) . . ?
C14 C13 N8 126.4(14) . . ?
C14 C13 H7 116.8 . . ?
N8 C13 H7 116.8 . . ?
C13 C14 C15 116.2(14) . . ?
C13 C14 H8 121.9 . . ?
C15 C14 H8 121.9 . . ?
C16 C15 C14 119.5(13) . . ?
C16 C15 H9 120.2 . . ?
C14 C15 H9 120.2 . . ?
C12 C16 C15 120.3(13) . . ?
C12 C16 H10 119.8 . . ?
C15 C16 H10 119.8 . . ?
N9 C17 C21 124.6(12) . . ?
N9 C17 P3 113.2(9) . . ?
C21 C17 P3 122.2(11) . . ?
N9 C18 C19 124.9(14) . . ?
N9 C18 H13 117.6 . . ?
C19 C18 H13 117.6 . . ?
C18 C19 C20 116.2(14) . . ?
C18 C19 H19A 121.9 . . ?
C20 C19 H19A 121.9 . . ?
C21 C20 C19 120.8(14) . . ?
C21 C20 H12 119.6 . . ?
C19 C20 H12 119.6 . . ?
C20 C21 C17 117.7(14) . . ?
C20 C21 H11 121.2 . . ?
C17 C21 H11 121.2 . . ?
C23 C22 N10 123.4(15) . . ?
C23 C22 H32 118.3 . . ?
N10 C22 H32 118.3 . . ?
C22 C23 C24 120.5(16) . . ?
C22 C23 H31 119.8 . . ?
C24 C23 H31 119.8 . . ?
C25 C24 C23 115.7(15) . . ?
C25 C24 H30 122.2 . . ?
C23 C24 H30 122.2 . . ?
C24 C25 C26 121.8(14) . . ?
C24 C25 H29 119.1 . . ?
C26 C25 H29 119.1 . . ?
N10 C26 C25 121.3(12) . . ?
N10 C26 P4 113.8(10) . . ?
C25 C26 P4 124.8(10) . . ?
C42 C27 N11 123.6(12) . . ?
C42 C27 P4 122.5(11) . . ?
N11 C27 P4 113.7(9) . . ?
C29 N5 C33 119.4(13) . . ?
C29 N5 Ag5 124.1(9) . . ?
C33 N5 Ag5 116.3(10) . . ?
N5 C29 C30 123.2(15) . . ?
N5 C29 P2 113.2(10) . . ?
C30 C29 P2 123.3(13) . . ?
C29 C30 C31 115.4(18) . . ?
C29 C30 H18 122.3 . . ?
C31 C30 H18 122.3 . . ?
C32 C31 C30 120.7(17) . . ?
C32 C31 H17 119.7 . . ?
C30 C31 H17 119.7 . . ?
C31 C32 C33 120.8(19) . . ?
C31 C32 H32A 119.6 . . ?
C33 C32 H32A 119.6 . . ?
C32 C33 N5 120.0(17) . . ?
C32 C33 H16 120.0 . . ?
N5 C33 H16 120.0 . . ?
C35 C34 N12 123.5(16) . . ?
C35 C34 H22 118.3 . . ?
N12 C34 H22 118.3 . . ?
C34 C35 C36 117.5(16) . . ?
C34 C35 H19 121.3 . . ?
C36 C35 H19 121.3 . . ?
C37 C36 C35 120.8(18) . . ?
C37 C36 H20 119.6 . . ?
C35 C36 H20 119.6 . . ?
C36 C37 C38 119.6(17) . . ?
C36 C37 H21 120.2 . . ?
C38 C37 H21 120.2 . . ?
N12 C38 C37 124.1(13) . . ?
N12 C38 P1 110.8(10) . . ?
C37 C38 P1 125.1(13) . . ?
C40 C39 N11 122.2(15) . . ?
C40 C39 H26 118.9 . . ?
N11 C39 H26 118.9 . . ?
C39 C40 C41 119.3(14) . . ?
C39 C40 H23 120.4 . . ?
C41 C40 H23 120.4 . . ?
C40 C41 C42 120.8(14) . . ?
C40 C41 H24 119.6 . . ?
C42 C41 H24 119.6 . . ?
C27 C42 C41 115.6(14) . . ?
C27 C42 H25 122.2 . . ?
C41 C42 H25 122.2 . . ?
N14 C43 C44 123.7(17) . . ?
N14 C43 H28 118.2 . . ?
C44 C43 H28 118.2 . . ?
C43 C44 C45 117.6(16) . . ?
C43 C44 H44A 121.2 . . ?
C45 C44 H44A 121.2 . . ?
C61 C45 C44 118.6(16) . . ?
C61 C45 H27 120.7 . . ?
C44 C45 H27 120.7 . . ?
C47 C46 N6 119.1(16) . . ?
C47 C46 H36 120.4 . . ?
N6 C46 H36 120.4 . . ?
C48 C47 C46 123.7(15) . . ?
C48 C47 H35 118.1 . . ?
C46 C47 H35 118.1 . . ?
C47 C48 C49 115.3(15) . . ?
C47 C48 H34 122.4 . . ?
C49 C48 H34 122.4 . . ?
C48 C49 C62 121.8(15) . . ?
C48 C49 H33 119.1 . . ?
C62 C49 H33 119.1 . . ?
C51 C50 C6 121.1(15) . . ?
C51 C50 H38 119.5 . . ?
C6 C50 H38 119.5 . . ?
C55 N13 Ag3 175.5(18) . . ?
N13 C55 C56 175(2) . . ?
C55 C56 H42 109.5 . . ?
C55 C56 H44 109.5 . . ?
H42 C56 H44 109.5 . . ?
C55 C56 H43 109.5 . . ?
H42 C56 H43 109.5 . . ?
H44 C56 H43 109.5 . . ?
C58 C57 N3 125.1(16) . . ?
C58 C57 H45 117.5 . . ?
N3 C57 H45 117.5 . . ?
C57 C58 C59 117.1(16) . . ?
C57 C58 H46 121.4 . . ?
C59 C58 H46 121.4 . . ?
C60 C59 C58 118.5(14) . . ?
C60 C59 H48 120.7 . . ?
C58 C59 H48 120.7 . . ?
C59 C60 C5 119.2(15) . . ?
C59 C60 H47 120.4 . . ?
C5 C60 H47 120.4 . . ?
C52 C53 N4 120.4(16) . . ?
C52 C53 H53A 119.8 . . ?
N4 C53 H53A 119.8 . . ?
C52 C51 C50 117.3(15) . . ?
C52 C51 H51A 121.4 . . ?
C50 C51 H51A 121.4 . . ?
C53 C52 C51 121.2(15) . . ?
C53 C52 H52A 119.4 . . ?
C51 C52 H52A 119.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 P1 C63 N2 -83.0(10) . . . . ?
C38 P1 C63 N2 171.4(10) . . . . ?
Ag2 P1 C63 N2 43.0(10) . . . . ?
C5 P1 C63 C4 101.5(12) . . . . ?
C38 P1 C63 C4 -4.1(13) . . . . ?
Ag2 P1 C63 C4 -132.5(10) . . . . ?
C4 C63 N2 C1 -2.4(19) . . . . ?
P1 C63 N2 C1 -177.9(10) . . . . ?
C4 C63 N2 Ag1 -177.8(10) . . . . ?
P1 C63 N2 Ag1 6.7(13) . . . . ?
C6 P2 C62 N6 171.8(10) . . . . ?
C29 P2 C62 N6 -83.7(10) . . . . ?
Ag2 P2 C62 N6 42.0(11) . . . . ?
C6 P2 C62 C49 -9.9(13) . . . . ?
C29 P2 C62 C49 94.6(13) . . . . ?
Ag2 P2 C62 C49 -139.7(11) . . . . ?
C49 C62 N6 C46 0(2) . . . . ?
P2 C62 N6 C46 178.0(11) . . . . ?
C49 C62 N6 Ag4 -173.9(10) . . . . ?
P2 C62 N6 Ag4 4.5(14) . . . . ?
C26 P4 C28 N14 179.0(10) . . . . ?
C27 P4 C28 N14 -78.4(11) . . . . ?
Ag2 P4 C28 N14 49.7(11) . . . . ?
C26 P4 C28 C61 -4.9(14) . . . . ?
C27 P4 C28 C61 97.7(13) . . . . ?
Ag2 P4 C28 C61 -134.2(12) . . . . ?
C61 C28 N14 C43 -3(2) . . . . ?
P4 C28 N14 C43 173.3(12) . . . . ?
C61 C28 N14 Ag1 175.2(11) . . . . ?
P4 C28 N14 Ag1 -8.7(14) . . . . ?
N14 C28 C61 C45 3(3) . . . . ?
P4 C28 C61 C45 -172.4(14) . . . . ?
C63 N2 C1 C2 4(2) . . . . ?
Ag1 N2 C1 C2 179.7(12) . . . . ?
N2 C1 C2 C3 -6(2) . . . . ?
C1 C2 C3 C4 6(2) . . . . ?
N2 C63 C4 C3 2(2) . . . . ?
P1 C63 C4 C3 177.4(11) . . . . ?
C2 C3 C4 C63 -4(2) . . . . ?
C57 N3 C5 C60 -2(2) . . . . ?
Ag3 N3 C5 C60 -176.5(10) . . . . ?
C57 N3 C5 P1 177.0(10) . . . . ?
Ag3 N3 C5 P1 2.1(13) . . . . ?
C63 P1 C5 N3 172.2(10) . . . . ?
C38 P1 C5 N3 -81.0(10) . . . . ?
Ag2 P1 C5 N3 45.5(11) . . . . ?
C63 P1 C5 C60 -9.3(13) . . . . ?
C38 P1 C5 C60 97.6(12) . . . . ?
Ag2 P1 C5 C60 -136.0(11) . . . . ?
C53 N4 C6 C50 2.8(19) . . . . ?
Ag3 N4 C6 C50 -175.8(10) . . . . ?
C53 N4 C6 P2 -178.7(9) . . . . ?
Ag3 N4 C6 P2 2.8(13) . . . . ?
C62 P2 C6 N4 -87.4(10) . . . . ?
C29 P2 C6 N4 168.1(10) . . . . ?
Ag2 P2 C6 N4 41.4(11) . . . . ?
C62 P2 C6 C50 91.1(12) . . . . ?
C29 P2 C6 C50 -13.4(13) . . . . ?
Ag2 P2 C6 C50 -140.1(10) . . . . ?
C11 N7 C7 C8 3(3) . . . . ?
Ag4 N7 C7 C8 -177.6(16) . . . . ?
N7 C7 C8 C9 0(3) . . . . ?
C7 C8 C9 C10 -3(3) . . . . ?
C8 C9 C10 C11 4(3) . . . . ?
C9 C10 C11 N7 -1(2) . . . . ?
C9 C10 C11 P3 -176.3(13) . . . . ?
C7 N7 C11 C10 -2(2) . . . . ?
Ag4 N7 C11 C10 178.6(11) . . . . ?
C7 N7 C11 P3 173.8(11) . . . . ?
Ag4 N7 C11 P3 -6.0(14) . . . . ?
C12 P3 C11 C10 -7.4(14) . . . . ?
C17 P3 C11 C10 95.6(13) . . . . ?
Ag2 P3 C11 C10 -137.4(12) . . . . ?
C12 P3 C11 N7 177.2(10) . . . . ?
C17 P3 C11 N7 -79.8(11) . . . . ?
Ag2 P3 C11 N7 47.2(10) . . . . ?
C13 N8 C12 C16 -5.9(19) . . . . ?
Ag1 N8 C12 C16 -179.9(10) . . . . ?
C13 N8 C12 P3 175.6(9) . . . . ?
Ag1 N8 C12 P3 1.6(13) . . . . ?
C11 P3 C12 C16 95.3(13) . . . . ?
C17 P3 C12 C16 -10.5(14) . . . . ?
Ag2 P3 C12 C16 -136.3(11) . . . . ?
C11 P3 C12 N8 -86.2(10) . . . . ?
C17 P3 C12 N8 167.9(9) . . . . ?
Ag2 P3 C12 N8 42.2(10) . . . . ?
C12 N8 C13 C14 5(2) . . . . ?
Ag1 N8 C13 C14 179.2(12) . . . . ?
N8 C13 C14 C15 -2(2) . . . . ?
C13 C14 C15 C16 0(2) . . . . ?
N8 C12 C16 C15 5(2) . . . . ?
P3 C12 C16 C15 -177.2(11) . . . . ?
C14 C15 C16 C12 -1(2) . . . . ?
C18 N9 C17 C21 -1(2) . . . . ?
Ag3 N9 C17 C21 -177.9(12) . . . . ?
C18 N9 C17 P3 176.9(11) . . . . ?
Ag3 N9 C17 P3 -0.4(15) . . . . ?
C12 P3 C17 N9 -85.5(11) . . . . ?
C11 P3 C17 N9 169.8(11) . . . . ?
Ag2 P3 C17 N9 42.5(12) . . . . ?
C12 P3 C17 C21 92.0(13) . . . . ?
C11 P3 C17 C21 -12.6(15) . . . . ?
Ag2 P3 C17 C21 -140.0(12) . . . . ?
C17 N9 C18 C19 -4(2) . . . . ?
Ag3 N9 C18 C19 173.5(14) . . . . ?
N9 C18 C19 C20 6(3) . . . . ?
C18 C19 C20 C21 -3(3) . . . . ?
C19 C20 C21 C17 -1(3) . . . . ?
N9 C17 C21 C20 3(3) . . . . ?
P3 C17 C21 C20 -174.1(13) . . . . ?
C26 N10 C22 C23 6(3) . . . . ?
Ag4 N10 C22 C23 -179.4(16) . . . . ?
N10 C22 C23 C24 -5(3) . . . . ?
C22 C23 C24 C25 0(3) . . . . ?
C23 C24 C25 C26 2(3) . . . . ?
C22 N10 C26 C25 -3(2) . . . . ?
Ag4 N10 C26 C25 -177.3(11) . . . . ?
C22 N10 C26 P4 -179.9(11) . . . . ?
Ag4 N10 C26 P4 6.1(15) . . . . ?
C24 C25 C26 N10 -1(2) . . . . ?
C24 C25 C26 P4 175.3(14) . . . . ?
C27 P4 C26 N10 168.6(11) . . . . ?
C28 P4 C26 N10 -88.0(11) . . . . ?
Ag2 P4 C26 N10 40.7(12) . . . . ?
C27 P4 C26 C25 -7.9(14) . . . . ?
C28 P4 C26 C25 95.6(14) . . . . ?
Ag2 P4 C26 C25 -135.8(12) . . . . ?
C39 N11 C27 C42 -0.4(19) . . . . ?
Ag5 N11 C27 C42 178.5(10) . . . . ?
C39 N11 C27 P4 174.8(10) . . . . ?
Ag5 N11 C27 P4 -6.3(13) . . . . ?
C26 P4 C27 C42 93.4(12) . . . . ?
C28 P4 C27 C42 -11.5(13) . . . . ?
Ag2 P4 C27 C42 -138.8(10) . . . . ?
C26 P4 C27 N11 -81.9(10) . . . . ?
C28 P4 C27 N11 173.2(10) . . . . ?
Ag2 P4 C27 N11 45.9(11) . . . . ?
C33 N5 C29 C30 6(2) . . . . ?
Ag5 N5 C29 C30 -177.5(12) . . . . ?
C33 N5 C29 P2 179.5(13) . . . . ?
Ag5 N5 C29 P2 -4.0(14) . . . . ?
C6 P2 C29 N5 -82.0(11) . . . . ?
C62 P2 C29 N5 173.8(10) . . . . ?
Ag2 P2 C29 N5 47.0(11) . . . . ?
C6 P2 C29 C30 91.5(14) . . . . ?
C62 P2 C29 C30 -12.7(15) . . . . ?
Ag2 P2 C29 C30 -139.6(12) . . . . ?
N5 C29 C30 C31 0(2) . . . . ?
P2 C29 C30 C31 -172.6(14) . . . . ?
C29 C30 C31 C32 -5(3) . . . . ?
C30 C31 C32 C33 4(4) . . . . ?
C31 C32 C33 N5 3(4) . . . . ?
C29 N5 C33 C32 -7(3) . . . . ?
Ag5 N5 C33 C32 175.8(19) . . . . ?
C38 N12 C34 C35 -5(2) . . . . ?
Ag5 N12 C34 C35 171.5(14) . . . . ?
N12 C34 C35 C36 4(3) . . . . ?
C34 C35 C36 C37 -1(3) . . . . ?
C35 C36 C37 C38 -2(3) . . . . ?
C34 N12 C38 C37 2(2) . . . . ?
Ag5 N12 C38 C37 -174.4(11) . . . . ?
C34 N12 C38 P1 179.9(9) . . . . ?
Ag5 N12 C38 P1 3.4(13) . . . . ?
C36 C37 C38 N12 1(2) . . . . ?
C36 C37 C38 P1 -176.1(13) . . . . ?
C5 P1 C38 N12 170.1(10) . . . . ?
C63 P1 C38 N12 -83.0(10) . . . . ?
Ag2 P1 C38 N12 45.0(11) . . . . ?
C5 P1 C38 C37 -12.1(15) . . . . ?
C63 P1 C38 C37 94.8(14) . . . . ?
Ag2 P1 C38 C37 -137.3(12) . . . . ?
C27 N11 C39 C40 -2(2) . . . . ?
Ag5 N11 C39 C40 179.3(13) . . . . ?
N11 C39 C40 C41 2(3) . . . . ?
C39 C40 C41 C42 0(2) . . . . ?
N11 C27 C42 C41 2(2) . . . . ?
P4 C27 C42 C41 -172.6(10) . . . . ?
C40 C41 C42 C27 -2(2) . . . . ?
C28 N14 C43 C44 2(3) . . . . ?
Ag1 N14 C43 C44 -176.0(16) . . . . ?
N14 C43 C44 C45 -2(3) . . . . ?
C28 C61 C45 C44 -3(3) . . . . ?
C43 C44 C45 C61 2(3) . . . . ?
C62 N6 C46 C47 -1(2) . . . . ?
Ag4 N6 C46 C47 173.0(13) . . . . ?
N6 C46 C47 C48 0(3) . . . . ?
C46 C47 C48 C49 2(3) . . . . ?
C47 C48 C49 C62 -3(3) . . . . ?
N6 C62 C49 C48 2(2) . . . . ?
P2 C62 C49 C48 -175.8(13) . . . . ?
N4 C6 C50 C51 -2(2) . . . . ?
P2 C6 C50 C51 179.7(11) . . . . ?
C5 N3 C57 C58 3(2) . . . . ?
Ag3 N3 C57 C58 177.8(13) . . . . ?
N3 C57 C58 C59 -3(2) . . . . ?
C57 C58 C59 C60 2(2) . . . . ?
C58 C59 C60 C5 -1(2) . . . . ?
N3 C5 C60 C59 1(2) . . . . ?
P1 C5 C60 C59 -177.5(12) . . . . ?
C6 N4 C53 C52 -3(2) . . . . ?
Ag3 N4 C53 C52 175.5(11) . . . . ?
C6 C50 C51 C52 1(2) . . . . ?
N4 C53 C52 C51 3(2) . . . . ?
C50 C51 C52 C53 -2(2) . . . . ?

_refine_diff_density_max         1.403
_refine_diff_density_min         -1.078
_refine_diff_density_rms         0.185



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_comp2_b6
_database_code_depnum_ccdc_archive 'CCDC 1472282'
_audit_update_record             
;
2017-08-16 deposited with the CCDC.
2017-08-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
;
 Complex of AgBF4 with tris(2-pyridyl)phosphine
;
_chemical_name_common            ?
_chemical_melting_point          503
_chemical_formula_moiety         
; 
 C69 H63 Ag5 N15 O P4, C67 H60 Ag5 N14 O P4, C2 N, 10(B F4), C3 H6 O
;
_chemical_formula_sum            'C141 H129 Ag10 B10 F40 N30 O3 P8'
_chemical_formula_weight         4486.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   23.685(3)
_cell_length_b                   22.865(2)
_cell_length_c                   30.599(3)
_cell_angle_alpha                90
_cell_angle_beta                 90.970(4)
_cell_angle_gamma                90
_cell_volume                     16568(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9446
_cell_measurement_theta_min      2.37
_cell_measurement_theta_max      27.43

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.799
_exptl_crystal_F_000             8836
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.337
_shelx_estimated_absorpt_T_min   0.690
_shelx_estimated_absorpt_T_max   0.776
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8066
_exptl_absorpt_correction_T_max  0.8621
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            245173
_diffrn_reflns_av_unetI/netI     0.0353
_diffrn_reflns_av_R_equivalents  0.0563
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_theta_min         2.557
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             37987
_reflns_number_gt                29640
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0342P)²+35.8610P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         37987
_refine_ls_number_parameters     2185
_refine_ls_number_restraints     22
_refine_ls_R_factor_all          0.0574
_refine_ls_R_factor_gt           0.0364
_refine_ls_wR_factor_ref         0.1001
_refine_ls_wR_factor_gt          0.0863
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_restrained_S_all      1.098
_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.17502(2) 0.49072(2) 0.18318(2) 0.03025(6) Uani 1 1 d . . . . .
Ag2 Ag 0.25017(2) 0.41500(2) 0.12108(2) 0.02138(6) Uani 1 1 d . . . . .
Ag3 Ag 0.17032(2) 0.32940(2) 0.06914(2) 0.03043(6) Uani 1 1 d . . . . .
Ag4 Ag 0.31118(2) 0.48993(2) 0.05244(2) 0.03103(7) Uani 1 1 d . . . . .
Ag5 Ag 0.33990(2) 0.34358(2) 0.17602(2) 0.03025(6) Uani 1 1 d . . . . .
P1 P 0.20162(4) 0.34965(4) 0.17728(3) 0.02136(17) Uani 1 1 d . . . . .
P2 P 0.17705(4) 0.47526(4) 0.07612(3) 0.02119(17) Uani 1 1 d . . . . .
P3 P 0.30701(4) 0.35002(4) 0.06852(3) 0.02301(18) Uani 1 1 d . . . . .
P4 P 0.31637(4) 0.48837(4) 0.16152(3) 0.02145(17) Uani 1 1 d . . . . .
N2A N 0.41551(18) 0.2785(2) 0.21037(15) 0.0597(12) Uani 1 1 d . . . . .
N1 N 0.19766(13) 0.42973(13) 0.24046(10) 0.0284(6) Uani 1 1 d . . . . .
N2 N 0.10968(12) 0.34067(13) 0.12689(10) 0.0261(6) Uani 1 1 d . . . . .
N3 N 0.16378(13) 0.39653(13) 0.01237(10) 0.0279(6) Uani 1 1 d . . . . .
N4 N 0.09812(12) 0.48453(13) 0.13744(10) 0.0265(6) Uani 1 1 d . . . . .
N5 N 0.24792(13) 0.56380(13) 0.06234(10) 0.0275(6) Uani 1 1 d . . . . .
N6 N 0.30288(13) 0.42074(14) -0.00075(10) 0.0297(7) Uani 1 1 d . . . . .
N7 N 0.23940(13) 0.25730(13) 0.07468(10) 0.0301(7) Uani 1 1 d . . . . .
N8 N 0.40041(12) 0.35546(13) 0.11821(10) 0.0279(6) Uani 1 1 d . . . . .
N10 N 0.34177(13) 0.41652(13) 0.22827(10) 0.0268(6) Uani 1 1 d . . . . .
N11 N 0.23582(12) 0.56887(13) 0.17355(10) 0.0266(6) Uani 1 1 d . . . . .
N12 N 0.38956(13) 0.50039(14) 0.09646(10) 0.0311(7) Uani 1 1 d . . . . .
N9 N 0.27902(13) 0.26516(13) 0.17990(10) 0.0291(7) Uani 1 1 d . . . . .
N1A N 0.1103(2) 0.25598(19) 0.03443(17) 0.0659(13) Uani 1 1 d . . . . .
C3A C 0.44479(19) 0.2757(2) 0.23970(16) 0.0439(10) Uani 1 1 d . . . . .
C1 C 0.20704(14) 0.37217(16) 0.23472(11) 0.0250(7) Uani 1 1 d . . . . .
C2 C 0.19739(17) 0.44968(19) 0.28135(13) 0.0378(9) Uani 1 1 d . . . . .
H4 H 0.1904 0.4901 0.2859 0.045 Uiso 1 1 calc R U . . .
C3 C 0.2068(2) 0.4146(2) 0.31735(14) 0.0470(11) Uani 1 1 d . . . . .
H3 H 0.2059 0.4305 0.3460 0.056 Uiso 1 1 calc R U . . .
C4 C 0.2175(2) 0.3560(2) 0.31115(14) 0.0458(11) Uani 1 1 d . . . . .
H2 H 0.2244 0.3309 0.3354 0.055 Uiso 1 1 calc R U . . .
C5 C 0.21794(17) 0.33447(18) 0.26899(13) 0.0352(9) Uani 1 1 d . . . . .
H1 H 0.2256 0.2943 0.2637 0.042 Uiso 1 1 calc R U . . .
C6 C 0.12509(14) 0.34542(15) 0.16918(12) 0.0251(7) Uani 1 1 d . . . . .
C7 C 0.16756(14) 0.45456(15) 0.01866(11) 0.0239(7) Uani 1 1 d . . . . .
C8 C 0.10349(14) 0.47727(14) 0.09381(12) 0.0247(7) Uani 1 1 d . . . . .
C9 C 0.04589(16) 0.48959(17) 0.15255(14) 0.0341(8) Uani 1 1 d . . . . .
H5 H 0.0413 0.4948 0.1831 0.041 Uiso 1 1 calc R U . . .
C10 C -0.00206(16) 0.48761(18) 0.12606(15) 0.0396(10) Uani 1 1 d . . . . .
H8 H -0.0385 0.4918 0.1383 0.048 Uiso 1 1 calc R U . . .
C11 C 0.00372(16) 0.47960(19) 0.08215(15) 0.0400(10) Uani 1 1 d . . . . .
H7 H -0.0286 0.4774 0.0634 0.048 Uiso 1 1 calc R U . . .
C12 C 0.05767(16) 0.47468(17) 0.06524(13) 0.0324(8) Uani 1 1 d . . . . .
H6 H 0.0629 0.4697 0.0348 0.039 Uiso 1 1 calc R U . . .
C13 C 0.19327(15) 0.55337(15) 0.07147(11) 0.0238(7) Uani 1 1 d . . . . .
C14 C 0.29974(15) 0.36353(17) 0.00970(12) 0.0284(8) Uani 1 1 d . . . . .
C15 C 0.29438(16) 0.27114(15) 0.07166(12) 0.0273(7) Uani 1 1 d . . . . .
C16 C 0.22577(19) 0.20019(17) 0.07591(14) 0.0394(9) Uani 1 1 d . . . . .
H9 H 0.1872 0.1896 0.0783 0.047 Uiso 1 1 calc R U . . .
C17 C 0.2657(2) 0.15652(18) 0.07390(16) 0.0493(12) Uani 1 1 d . . . . .
H12 H 0.2547 0.1166 0.0751 0.059 Uiso 1 1 calc R U . . .
C18 C 0.3224(2) 0.17131(19) 0.07016(17) 0.0510(12) Uani 1 1 d . . . . .
H10 H 0.3505 0.1419 0.0685 0.061 Uiso 1 1 calc R U . . .
C19 C 0.33656(19) 0.22953(18) 0.06899(15) 0.0407(10) Uani 1 1 d . . . . .
H11 H 0.3749 0.2411 0.0664 0.049 Uiso 1 1 calc R U . . .
C20 C 0.38404(15) 0.35429(16) 0.07614(12) 0.0279(8) Uani 1 1 d . . . . .
C22 C 0.22240(15) 0.27273(15) 0.18076(11) 0.0249(7) Uani 1 1 d . . . . .
C23 C 0.18475(17) 0.22679(17) 0.18540(14) 0.0352(9) Uani 1 1 d . . . . .
H16 H 0.1452 0.2336 0.1863 0.042 Uiso 1 1 calc R U . . .
C24 C 0.2064(2) 0.17068(18) 0.18869(17) 0.0474(11) Uani 1 1 d . . . . .
H15 H 0.1817 0.1382 0.1913 0.057 Uiso 1 1 calc R U . . .
C25 C 0.2641(2) 0.16234(19) 0.18818(18) 0.0525(13) Uani 1 1 d . . . . .
H13 H 0.2796 0.1242 0.1909 0.063 Uiso 1 1 calc R U . . .
C26 C 0.29884(19) 0.21015(18) 0.18374(15) 0.0420(10) Uani 1 1 d . . . . .
H14 H 0.3385 0.2041 0.1834 0.050 Uiso 1 1 calc R U . . .
C28 C 0.33170(14) 0.47323(15) 0.21954(11) 0.0247(7) Uani 1 1 d . . . . .
C29 C 0.29148(15) 0.56431(15) 0.16521(11) 0.0247(7) Uani 1 1 d . . . . .
C30 C 0.21513(17) 0.62227(17) 0.18034(13) 0.0345(9) Uani 1 1 d . . . . .
H20 H 0.1760 0.6260 0.1860 0.041 Uiso 1 1 calc R U . . .
C31 C 0.24762(19) 0.67239(17) 0.17958(15) 0.0411(10) Uani 1 1 d . . . . .
H21 H 0.2312 0.7096 0.1848 0.049 Uiso 1 1 calc R U . . .
C32 C 0.30425(19) 0.66753(17) 0.17107(15) 0.0406(10) Uani 1 1 d . . . . .
H23 H 0.3276 0.7013 0.1704 0.049 Uiso 1 1 calc R U . . .
C33 C 0.32684(17) 0.61233(17) 0.16342(13) 0.0339(8) Uani 1 1 d . . . . .
H22 H 0.3657 0.6078 0.1571 0.041 Uiso 1 1 calc R U . . .
C34 C 0.38797(15) 0.49679(15) 0.14027(12) 0.0259(7) Uani 1 1 d . . . . .
C35 C 0.44022(18) 0.5073(2) 0.07800(15) 0.0435(10) Uani 1 1 d . . . . .
H24 H 0.4419 0.5103 0.0471 0.052 Uiso 1 1 calc R U . . .
C36 C 0.49017(19) 0.5102(2) 0.10223(16) 0.0496(12) Uani 1 1 d . . . . .
H25 H 0.5252 0.5154 0.0881 0.059 Uiso 1 1 calc R U . . .
C37 C 0.48815(18) 0.5053(2) 0.14713(17) 0.0480(11) Uani 1 1 d . . . . .
H26 H 0.5218 0.5064 0.1644 0.058 Uiso 1 1 calc R U . . .
C38 C 0.43655(16) 0.49892(18) 0.16631(14) 0.0359(9) Uani 1 1 d . . . . .
H27 H 0.4341 0.4960 0.1972 0.043 Uiso 1 1 calc R U . . .
C39 C 0.33616(18) 0.51683(17) 0.25104(13) 0.0353(9) Uani 1 1 d . . . . .
H31 H 0.3285 0.5564 0.2437 0.042 Uiso 1 1 calc R U . . .
C40 C 0.3520(2) 0.50166(19) 0.29330(13) 0.0411(10) Uani 1 1 d . . . . .
H30 H 0.3553 0.5306 0.3155 0.049 Uiso 1 1 calc R U . . .
C41 C 0.36280(19) 0.44405(19) 0.30245(13) 0.0405(10) Uani 1 1 d . . . . .
H29 H 0.3741 0.4326 0.3311 0.049 Uiso 1 1 calc R U . . .
C42 C 0.35705(17) 0.40267(18) 0.26962(13) 0.0350(9) Uani 1 1 d . . . . .
H28 H 0.3642 0.3628 0.2765 0.042 Uiso 1 1 calc R U . . .
C43 C 0.45594(16) 0.35754(18) 0.12749(14) 0.0371(9) Uani 1 1 d . . . . .
H32 H 0.4681 0.3581 0.1572 0.045 Uiso 1 1 calc R U . . .
C44 C 0.49596(17) 0.3589(2) 0.09540(15) 0.0425(10) Uani 1 1 d . . . . .
H35 H 0.5349 0.3615 0.1030 0.051 Uiso 1 1 calc R U . . .
C45 C 0.47894(17) 0.3563(2) 0.05207(15) 0.0455(11) Uani 1 1 d . . . . .
H33 H 0.5060 0.3561 0.0295 0.055 Uiso 1 1 calc R U . . .
C46 C 0.42153(17) 0.35420(19) 0.04216(14) 0.0374(9) Uani 1 1 d . . . . .
H34 H 0.4084 0.3527 0.0127 0.045 Uiso 1 1 calc R U . . .
C47 C 0.29412(19) 0.3201(2) -0.02153(14) 0.0412(10) Uani 1 1 d . . . . .
H39 H 0.2908 0.2802 -0.0132 0.049 Uiso 1 1 calc R U . . .
C48 C 0.2934(2) 0.3361(2) -0.06520(14) 0.0522(12) Uani 1 1 d . . . . .
H38 H 0.2901 0.3073 -0.0874 0.063 Uiso 1 1 calc R U . . .
C49 C 0.2977(2) 0.3942(2) -0.07588(15) 0.0528(12) Uani 1 1 d . . . . .
H37 H 0.2976 0.4062 -0.1056 0.063 Uiso 1 1 calc R U . . .
C50 C 0.30210(19) 0.4349(2) -0.04286(14) 0.0425(10) Uani 1 1 d . . . . .
H36 H 0.3047 0.4751 -0.0505 0.051 Uiso 1 1 calc R U . . .
C51 C 0.26337(18) 0.61962(17) 0.05688(13) 0.0352(9) Uani 1 1 d . . . . .
H40 H 0.3016 0.6278 0.0501 0.042 Uiso 1 1 calc R U . . .
C52 C 0.22627(19) 0.66567(17) 0.06059(14) 0.0399(10) Uani 1 1 d . . . . .
H41 H 0.2391 0.7047 0.0569 0.048 Uiso 1 1 calc R U . . .
C53 C 0.17112(18) 0.65507(16) 0.06957(14) 0.0365(9) Uani 1 1 d . . . . .
H42 H 0.1450 0.6864 0.0719 0.044 Uiso 1 1 calc R U . . .
C54 C 0.15373(16) 0.59768(16) 0.07533(13) 0.0301(8) Uani 1 1 d . . . . .
H43 H 0.1155 0.5889 0.0818 0.036 Uiso 1 1 calc R U . . .
C55 C 0.16138(17) 0.49476(17) -0.01479(12) 0.0325(8) Uani 1 1 d . . . . .
H47 H 0.1646 0.5355 -0.0092 0.039 Uiso 1 1 calc R U . . .
C56 C 0.15028(18) 0.47434(19) -0.05681(13) 0.0374(9) Uani 1 1 d . . . . .
H46 H 0.1456 0.5008 -0.0805 0.045 Uiso 1 1 calc R U . . .
C57 C 0.14615(19) 0.4150(2) -0.06338(13) 0.0409(10) Uani 1 1 d . . . . .
H45 H 0.1391 0.3999 -0.0919 0.049 Uiso 1 1 calc R U . . .
C58 C 0.15234(18) 0.37737(18) -0.02823(13) 0.0374(9) Uani 1 1 d . . . . .
H44 H 0.1484 0.3365 -0.0330 0.045 Uiso 1 1 calc R U . . .
C2A C 0.08584(19) 0.2263(2) 0.01289(16) 0.0475(11) Uani 1 1 d . . . . .
C60 C 0.05442(16) 0.33813(17) 0.11692(13) 0.0323(8) Uani 1 1 d . . . . .
H53 H 0.0432 0.3338 0.0871 0.039 Uiso 1 1 calc R U . . .
C61 C 0.01314(16) 0.34147(18) 0.14813(15) 0.0381(9) Uani 1 1 d . . . . .
H50 H -0.0257 0.3411 0.1399 0.046 Uiso 1 1 calc R U . . .
C62 C 0.02946(17) 0.34535(19) 0.19180(15) 0.0400(10) Uani 1 1 d . . . . .
H51 H 0.0020 0.3465 0.2140 0.048 Uiso 1 1 calc R U . . .
C63 C 0.08642(16) 0.34751(17) 0.20244(13) 0.0326(8) Uani 1 1 d . . . . .
H52 H 0.0987 0.3504 0.2321 0.039 Uiso 1 1 calc R U . . .
C1A C 0.0537(3) 0.1875(4) -0.0153(2) 0.107(3) Uani 1 1 d . . . . .
H1AA H 0.0133 0.1927 -0.0099 0.160 Uiso 1 1 calc R U . . .
H1AB H 0.0644 0.1469 -0.0091 0.160 Uiso 1 1 calc R U . . .
H1AC H 0.0614 0.1967 -0.0459 0.160 Uiso 1 1 calc R U . . .
Ag6 Ag 0.84507(2) 0.02584(2) 0.08435(2) 0.03332(7) Uani 1 1 d . . . . .
Ag7 Ag 0.75083(2) 0.11163(2) 0.11518(2) 0.02276(6) Uani 1 1 d . . . . .
Ag8 Ag 0.65267(2) 0.03128(2) 0.14485(2) 0.03372(7) Uani 1 1 d . . . . .
Ag9 Ag 0.80089(2) 0.19111(2) 0.19147(2) 0.03149(7) Uani 1 1 d . . . . .
Ag10 Ag 0.70015(2) 0.18464(2) 0.03678(2) 0.02935(6) Uani 1 1 d . . . . .
P5 P 0.78757(4) 0.04934(4) 0.18013(3) 0.02372(18) Uani 1 1 d . . . . .
P6 P 0.67076(4) 0.17970(4) 0.14263(3) 0.02444(18) Uani 1 1 d . . . . .
P7 P 0.83219(4) 0.17440(4) 0.08557(3) 0.02326(18) Uani 1 1 d . . . . .
P8 P 0.71306(4) 0.04580(4) 0.05162(3) 0.02239(17) Uani 1 1 d . . . . .
N13 N 0.71789(13) -0.03961(13) 0.16091(10) 0.0287(7) Uani 1 1 d . . . . .
N14 N 0.76736(13) 0.12737(13) 0.24254(10) 0.0289(7) Uani 1 1 d . . . . .
N15 N 0.74022(14) 0.26472(14) 0.17050(11) 0.0342(7) Uani 1 1 d . . . . .
N16 N 0.61245(13) 0.19118(13) 0.06686(10) 0.0275(6) Uani 1 1 d . . . . .
N17 N 0.76100(13) 0.25858(13) 0.05750(10) 0.0282(6) Uani 1 1 d . . . . .
N18 N 0.87103(13) 0.09231(14) 0.03138(10) 0.0313(7) Uani 1 1 d . . . . .
N19 N 0.88848(13) 0.18808(13) 0.16173(10) 0.0283(6) Uani 1 1 d . . . . .
N20 N 0.73780(12) 0.12057(13) -0.01168(10) 0.0251(6) Uani 1 1 d . . . . .
N21 N 0.60696(12) 0.04694(13) 0.07924(10) 0.0288(7) Uani 1 1 d . . . . .
N22 N 0.78058(13) -0.04531(13) 0.06740(10) 0.0297(7) Uani 1 1 d . . . . .
N23 N 0.89217(13) 0.04541(13) 0.14903(11) 0.0303(7) Uani 1 1 d . . . . .
N24' N 0.63442(13) 0.09891(15) 0.19859(10) 0.0332(7) Uani 1 1 d . . . . .
N4A N 0.8364(2) 0.2533(2) 0.25496(15) 0.0622(12) Uani 1 1 d . . . . .
N3A N 0.56906(19) -0.0346(2) 0.16261(17) 0.0680(14) Uani 1 1 d . . . . .
C64 C 0.70183(18) -0.09576(17) 0.15733(14) 0.0376(9) Uani 1 1 d . . . . .
H105 H 0.6652 -0.1041 0.1458 0.045 Uiso 1 1 calc R U . . .
C65 C 0.7361(2) -0.14176(18) 0.16959(16) 0.0447(11) Uani 1 1 d . . . . .
H104 H 0.7235 -0.1809 0.1661 0.054 Uiso 1 1 calc R U . . .
C66 C 0.78929(19) -0.13036(18) 0.18712(15) 0.0406(10) Uani 1 1 d . . . . .
H103 H 0.8134 -0.1613 0.1964 0.049 Uiso 1 1 calc R U . . .
C67 C 0.80637(17) -0.07254(17) 0.19077(14) 0.0355(9) Uani 1 1 d . . . . .
H102 H 0.8427 -0.0632 0.2025 0.043 Uiso 1 1 calc R U . . .
C68 C 0.76984(15) -0.02850(16) 0.17716(12) 0.0271(7) Uani 1 1 d . . . . .
C69 C 0.76484(15) 0.06942(16) 0.23500(12) 0.0272(7) Uani 1 1 d . . . . .
C70 C 0.68879(16) 0.25687(16) 0.15243(12) 0.0290(8) Uani 1 1 d . . . . .
C71 C 0.64255(15) 0.15708(17) 0.19546(12) 0.0292(8) Uani 1 1 d . . . . .
C72 C 0.62886(17) 0.1957(2) 0.22868(14) 0.0414(10) Uani 1 1 d . . . . .
H57 H 0.6348 0.2365 0.2255 0.050 Uiso 1 1 calc R U . . .
C73 C 0.60626(19) 0.1731(3) 0.26667(14) 0.0520(13) Uani 1 1 d . . . . .
H56 H 0.5967 0.1983 0.2901 0.062 Uiso 1 1 calc R U . . .
C74 C 0.5979(2) 0.1137(3) 0.26997(15) 0.0567(14) Uani 1 1 d . . . . .
H54 H 0.5825 0.0974 0.2957 0.068 Uiso 1 1 calc R U . . .
C75 C 0.61199(18) 0.0782(2) 0.23544(14) 0.0460(11) Uani 1 1 d . . . . .
H55 H 0.6056 0.0373 0.2378 0.055 Uiso 1 1 calc R U . . .
C77 C 0.60469(15) 0.18686(16) 0.11033(12) 0.0272(7) Uani 1 1 d . . . . .
C78 C 0.81260(15) 0.25112(15) 0.07597(12) 0.0255(7) Uani 1 1 d . . . . .
C79 C 0.86225(14) 0.15072(16) 0.03365(12) 0.0269(7) Uani 1 1 d . . . . .
C80 C 0.89643(18) 0.0713(2) -0.00408(14) 0.0417(10) Uani 1 1 d . . . . .
H58 H 0.9034 0.0305 -0.0059 0.050 Uiso 1 1 calc R U . . .
C81 C 0.91283(19) 0.1068(2) -0.03806(14) 0.0473(11) Uani 1 1 d . . . . .
H59 H 0.9302 0.0903 -0.0629 0.057 Uiso 1 1 calc R U . . .
C82 C 0.90386(18) 0.1663(2) -0.03572(14) 0.0432(10) Uani 1 1 d . . . . .
H60 H 0.9152 0.1913 -0.0588 0.052 Uiso 1 1 calc R U . . .
C83 C 0.87799(17) 0.18893(19) 0.00095(13) 0.0358(9) Uani 1 1 d . . . . .
H61 H 0.8712 0.2297 0.0036 0.043 Uiso 1 1 calc R U . . .
C84 C 0.89716(15) 0.18234(15) 0.11874(12) 0.0268(7) Uani 1 1 d . . . . .
C85 C 0.93409(16) 0.19516(18) 0.18796(13) 0.0343(9) Uani 1 1 d . . . . .
H65 H 0.9286 0.1996 0.2185 0.041 Uiso 1 1 calc R U . . .
C86 C 0.98869(17) 0.19625(18) 0.17262(15) 0.0393(10) Uani 1 1 d . . . . .
H64 H 1.0198 0.2012 0.1922 0.047 Uiso 1 1 calc R U . . .
C87 C 0.99708(16) 0.19018(18) 0.12885(14) 0.0358(9) Uani 1 1 d . . . . .
H63 H 1.0342 0.1908 0.1175 0.043 Uiso 1 1 calc R U . . .
C88 C 0.95060(16) 0.18304(17) 0.10102(13) 0.0336(8) Uani 1 1 d . . . . .
H62 H 0.9554 0.1787 0.0704 0.040 Uiso 1 1 calc R U . . .
C89 C 0.84649(17) 0.29727(17) 0.08806(15) 0.0396(10) Uani 1 1 d . . . . .
H69 H 0.8827 0.2907 0.1009 0.048 Uiso 1 1 calc R U . . .
C90 C 0.8266(2) 0.35385(18) 0.08108(16) 0.0468(11) Uani 1 1 d . . . . .
H68 H 0.8492 0.3866 0.0891 0.056 Uiso 1 1 calc R U . . .
C91 C 0.77415(19) 0.36172(17) 0.06247(15) 0.0410(10) Uani 1 1 d . . . . .
H67 H 0.7597 0.4000 0.0576 0.049 Uiso 1 1 calc R U . . .
C92 C 0.74247(17) 0.31317(17) 0.05084(14) 0.0357(9) Uani 1 1 d . . . . .
H66 H 0.7063 0.3188 0.0377 0.043 Uiso 1 1 calc R U . . .
C93 C 0.75676(16) 0.13830(17) -0.05040(13) 0.0315(8) Uani 1 1 d . . . . .
H81 H 0.7554 0.1788 -0.0572 0.038 Uiso 1 1 calc R U . . .
C94 C 0.77834(17) 0.10006(18) -0.08103(13) 0.0346(9) Uani 1 1 d . . . . .
H70 H 0.7921 0.1142 -0.1080 0.041 Uiso 1 1 calc R U . . .
C95 C 0.77941(18) 0.04116(19) -0.07159(13) 0.0380(9) Uani 1 1 d . . . . .
H71 H 0.7933 0.0139 -0.0922 0.046 Uiso 1 1 calc R U . . .
C96 C 0.76004(17) 0.02235(17) -0.03182(12) 0.0325(8) Uani 1 1 d . . . . .
H80 H 0.7606 -0.0181 -0.0246 0.039 Uiso 1 1 calc R U . . .
C97 C 0.73982(14) 0.06305(15) -0.00256(11) 0.0250(7) Uani 1 1 d . . . . .
C98 C 0.63645(14) 0.04963(15) 0.04205(12) 0.0261(7) Uani 1 1 d . . . . .
C99 C 0.55054(16) 0.05064(17) 0.07641(14) 0.0346(9) Uani 1 1 d . . . . .
H72 H 0.5293 0.0478 0.1024 0.041 Uiso 1 1 calc R U . . .
C100 C 0.52205(17) 0.05849(18) 0.03683(15) 0.0388(9) Uani 1 1 d . . . . .
H75 H 0.4821 0.0622 0.0359 0.047 Uiso 1 1 calc R U . . .
C101 C 0.55236(17) 0.06080(18) -0.00087(14) 0.0388(9) Uani 1 1 d . . . . .
H74 H 0.5336 0.0657 -0.0283 0.047 Uiso 1 1 calc R U . . .
C102 C 0.61079(16) 0.05593(16) 0.00142(13) 0.0313(8) Uani 1 1 d . . . . .
H73 H 0.6326 0.0569 -0.0243 0.038 Uiso 1 1 calc R U . . .
C103 C 0.72741(15) -0.03282(15) 0.05438(12) 0.0257(7) Uani 1 1 d . . . . .
C104 C 0.79629(18) -0.10144(17) 0.06790(14) 0.0378(9) Uani 1 1 d . . . . .
H79 H 0.8337 -0.1108 0.0770 0.045 Uiso 1 1 calc R U . . .
C105 C 0.7602(2) -0.14661(18) 0.05565(16) 0.0446(11) Uani 1 1 d . . . . .
H78 H 0.7730 -0.1860 0.0561 0.053 Uiso 1 1 calc R U . . .
C106 C 0.70580(18) -0.13355(17) 0.04290(15) 0.0391(9) Uani 1 1 d . . . . .
H77 H 0.6802 -0.1638 0.0347 0.047 Uiso 1 1 calc R U . . .
C107 C 0.68883(17) -0.07515(16) 0.04215(13) 0.0330(8) Uani 1 1 d . . . . .
H76 H 0.6515 -0.0648 0.0334 0.040 Uiso 1 1 calc R U . . .
C108 C 0.56605(17) 0.19984(17) 0.04140(13) 0.0345(9) Uani 1 1 d . . . . .
H82 H 0.5708 0.2036 0.0108 0.041 Uiso 1 1 calc R U . . .
C109 C 0.51233(17) 0.20355(19) 0.05757(14) 0.0395(10) Uani 1 1 d . . . . .
H85 H 0.4809 0.2098 0.0385 0.047 Uiso 1 1 calc R U . . .
C110 C 0.50501(17) 0.1981(2) 0.10170(14) 0.0413(10) Uani 1 1 d . . . . .
H84 H 0.4683 0.1999 0.1136 0.050 Uiso 1 1 calc R U . . .
C111 C 0.55205(16) 0.19002(19) 0.12881(14) 0.0374(9) Uani 1 1 d . . . . .
H83 H 0.5480 0.1867 0.1595 0.045 Uiso 1 1 calc R U . . .
C112 C 0.65271(19) 0.30305(18) 0.14330(16) 0.0431(10) Uani 1 1 d . . . . .
H89 H 0.6169 0.2963 0.1298 0.052 Uiso 1 1 calc R U . . .
C113 C 0.6698(2) 0.35942(19) 0.15415(17) 0.0503(12) Uani 1 1 d . . . . .
H88 H 0.6457 0.3919 0.1485 0.060 Uiso 1 1 calc R U . . .
C114 C 0.7215(2) 0.36732(19) 0.17291(17) 0.0496(12) Uani 1 1 d . . . . .
H86 H 0.7340 0.4055 0.1807 0.060 Uiso 1 1 calc R U . . .
C115 C 0.7563(2) 0.31925(18) 0.18066(16) 0.0464(11) Uani 1 1 d . . . . .
H87 H 0.7925 0.3253 0.1936 0.056 Uiso 1 1 calc R U . . .
C9A C 0.8679(2) 0.2830(2) 0.27153(15) 0.0488(11) Uani 1 1 d . . . . .
C8A C 0.9089(2) 0.3220(3) 0.29234(19) 0.0647(15) Uani 1 1 d . . . . .
H93 H 0.9021 0.3622 0.2825 0.097 Uiso 1 1 calc R U . . .
H92 H 0.9471 0.3100 0.2844 0.097 Uiso 1 1 calc R U . . .
H91 H 0.9052 0.3199 0.3241 0.097 Uiso 1 1 calc R U . . .
C119 C 0.75190(17) 0.14662(19) 0.28176(13) 0.0353(9) Uani 1 1 d . . . . .
H97 H 0.7542 0.1874 0.2877 0.042 Uiso 1 1 calc R U . . .
C120 C 0.73283(17) 0.1099(2) 0.31403(13) 0.0388(9) Uani 1 1 d . . . . .
H96 H 0.7216 0.1254 0.3414 0.047 Uiso 1 1 calc R U . . .
C121 C 0.73020(19) 0.0510(2) 0.30635(14) 0.0435(10) Uani 1 1 d . . . . .
H95 H 0.7175 0.0250 0.3283 0.052 Uiso 1 1 calc R U . . .
C122 C 0.74647(17) 0.03012(18) 0.26585(13) 0.0351(9) Uani 1 1 d . . . . .
H94 H 0.7450 -0.0105 0.2595 0.042 Uiso 1 1 calc R U . . .
C123 C 0.86467(15) 0.04871(16) 0.18713(13) 0.0287(8) Uani 1 1 d . . . . .
C124 C 0.94891(17) 0.04612(18) 0.15031(15) 0.0386(9) Uani 1 1 d . . . . .
H98 H 0.9687 0.0443 0.1236 0.046 Uiso 1 1 calc R U . . .
C125 C 0.97950(18) 0.0493(2) 0.18902(17) 0.0481(11) Uani 1 1 d . . . . .
H101 H 1.0196 0.0498 0.1889 0.058 Uiso 1 1 calc R U . . .
C126 C 0.95133(19) 0.0519(2) 0.22758(17) 0.0524(12) Uani 1 1 d . . . . .
H100 H 0.9717 0.0535 0.2546 0.063 Uiso 1 1 calc R U . . .
C127 C 0.89272(18) 0.0521(2) 0.22694(14) 0.0411(10) Uani 1 1 d . . . . .
H99 H 0.8724 0.0546 0.2534 0.049 Uiso 1 1 calc R U . . .
C6A C 0.5321(2) -0.0660(3) 0.1551(2) 0.0686(17) Uani 1 1 d . . . . .
C5A C 0.4871(3) -0.1068(3) 0.1449(3) 0.095(2) Uani 1 1 d . . . . .
H109 H 0.5019 -0.1390 0.1273 0.142 Uiso 1 1 calc R U . . .
H108 H 0.4571 -0.0866 0.1284 0.142 Uiso 1 1 calc R U . . .
H107 H 0.4717 -0.1225 0.1720 0.142 Uiso 1 1 calc R U . . .
C4A C 0.4811(2) 0.2717(3) 0.27802(17) 0.0593(14) Uani 1 1 d . . . . .
H19 H 0.4721 0.3035 0.2982 0.089 Uiso 1 1 calc R U . . .
H18 H 0.5206 0.2749 0.2693 0.089 Uiso 1 1 calc R U . . .
H17 H 0.4751 0.2341 0.2925 0.089 Uiso 1 1 calc R U . . .
F1 F -0.00827(16) 0.3015(2) 0.44665(15) 0.1188(17) Uani 1 1 d . . . . .
F2 F -0.0917(2) 0.2754(3) 0.47493(16) 0.1306(19) Uani 1 1 d . . . . .
F3 F -0.06789(19) 0.3651(3) 0.4708(2) 0.149(2) Uani 1 1 d . . . . .
F4 F -0.09001(18) 0.3177(2) 0.40974(12) 0.1099(15) Uani 1 1 d . . . . .
F6 F 0.50012(17) 0.4108(2) 0.23880(15) 0.1028(13) Uani 1 1 d . . . . .
F7 F 0.58482(18) 0.43940(16) 0.21192(14) 0.0963(13) Uani 1 1 d . . . . .
F8 F 0.55139(15) 0.34806(18) 0.20198(13) 0.0888(12) Uani 1 1 d . . . . .
F9 F 0.58103(18) 0.3781(2) 0.26745(13) 0.127(2) Uani 1 1 d . . . . .
F10 F -0.12886(15) 0.68559(14) 0.13092(10) 0.0714(9) Uani 1 1 d . . . . .
F11 F -0.1528(3) 0.7484(2) 0.08002(14) 0.141(2) Uani 1 1 d . . . . .
F12 F -0.1206(2) 0.7805(2) 0.1432(2) 0.163(3) Uani 1 1 d . . . . .
F13 F -0.20525(16) 0.74219(15) 0.13889(15) 0.0951(13) Uani 1 1 d . . . . .
F3' F 0.49392(18) -0.2708(3) 0.22581(13) 0.143(2) Uani 1 1 d . . . . .
F15 F 0.45499(16) 0.1513(3) 0.55536(12) 0.135(2) Uani 1 1 d . . . . .
F16 F 0.51791(15) 0.13788(19) 0.50464(12) 0.0887(12) Uani 1 1 d . . . . .
F17 F 0.43815(17) 0.18863(17) 0.48787(14) 0.0936(12) Uani 1 1 d . . . . .
F18 F 0.4363(2) 0.0942(2) 0.49995(19) 0.148(2) Uani 1 1 d . . . . .
F19 F -0.10742(12) 0.36883(13) 0.18586(11) 0.0657(9) Uani 1 1 d . . . . .
F20 F -0.16303(12) 0.42583(14) 0.22690(11) 0.0661(9) Uani 1 1 d . . . . .
F21 F -0.13570(14) 0.45682(16) 0.15996(11) 0.0738(9) Uani 1 1 d . . . . .
F22 F -0.07172(13) 0.45114(15) 0.21534(11) 0.0720(9) Uani 1 1 d . . . . .
F25 F 0.1229(2) 0.46380(18) 0.39318(15) 0.1191(18) Uani 1 1 d . . . . .
F26 F 0.0752(2) 0.5486(4) 0.38370(18) 0.195(4) Uani 1 1 d . . . . .
F27 F 0.1427(2) 0.54158(15) 0.43149(13) 0.1095(16) Uani 1 1 d . . . . .
F28 F 0.16102(19) 0.54220(17) 0.36026(15) 0.1029(14) Uani 1 1 d . . . . .
F29 F 0.09132(19) 0.01441(16) 0.10378(14) 0.0934(12) Uani 1 1 d . . . . .
F30 F 0.05146(19) 0.0919(2) 0.07097(14) 0.1064(14) Uani 1 1 d . . . . .
F31 F 0.1406(2) 0.0707(2) 0.0589(2) 0.140(2) Uani 1 1 d . . . . .
F32 F 0.1120(2) 0.1040(2) 0.12536(18) 0.140(2) Uani 1 1 d . . . . .
F33 F 0.5730(2) 0.4521(2) 0.02365(17) 0.135(2) Uani 1 1 d . . . . .
F34 F 0.61166(14) 0.36541(16) 0.04463(14) 0.0848(11) Uani 1 1 d . . . . .
F35 F 0.6272(3) 0.4484(3) 0.07807(15) 0.140(2) Uani 1 1 d . . . . .
F36 F 0.66569(17) 0.43512(15) 0.01360(13) 0.0924(13) Uani 1 1 d . . . . .
F37 F 0.31359(12) 0.27830(11) 0.37928(10) 0.0548(7) Uani 1 1 d . . . . .
F38 F 0.38638(14) 0.33504(14) 0.35831(10) 0.0692(9) Uani 1 1 d . . . . .
F39 F 0.34776(16) 0.27158(15) 0.31088(10) 0.0743(10) Uani 1 1 d . . . . .
F40 F 0.39895(17) 0.23996(18) 0.36901(14) 0.1044(15) Uani 1 1 d . . . . .
F2' F 0.41026(18) -0.3010(3) 0.24429(13) 0.152(3) Uani 1 1 d . . . . .
F1' F 0.43764(17) -0.3103(2) 0.17515(13) 0.1094(16) Uani 1 1 d . . . . .
F4' F 0.4145(4) -0.2287(4) 0.2016(3) 0.225(4) Uani 1 1 d . . . . .
B1 B -0.0641(3) 0.3129(4) 0.4496(2) 0.075(2) Uani 1 1 d . . . . .
B3 B 0.5550(3) 0.3942(3) 0.2300(2) 0.0573(15) Uani 1 1 d . . . . .
B4 B -0.1519(3) 0.7398(2) 0.1242(2) 0.0499(13) Uani 1 1 d . . . . .
B6 B 0.4615(3) 0.1444(3) 0.51255(19) 0.0546(15) Uani 1 1 d . . . . .
B7 B -0.1196(2) 0.4260(2) 0.1970(2) 0.0470(13) Uani 1 1 d . . . . .
B9 B 0.1242(3) 0.5252(3) 0.3917(2) 0.0572(15) Uani 1 1 d . . . . .
B10 B 0.0999(3) 0.0708(3) 0.0899(2) 0.0595(16) Uani 1 1 d . . . . .
B11 B 0.6187(3) 0.4234(3) 0.0368(2) 0.0558(15) Uani 1 1 d . . . . .
B12 B 0.3617(2) 0.2806(2) 0.35407(17) 0.0430(12) Uani 1 1 d . . . . .
B2 B 0.4407(3) -0.2817(5) 0.2131(2) 0.079(2) Uani 1 1 d . . . . .
O1C O 0.33479(15) -0.24822(17) 0.03232(12) 0.0595(9) Uani 1 1 d . . . . .
O2C O 0.12497(16) 0.55693(16) 0.24036(12) 0.0611(9) Uani 1 1 d . . . . .
N24 N 0.57260(19) 0.4465(2) 0.42320(17) 0.0624(12) Uani 1 1 d . . . . .
N5A N 0.0214(3) 0.6256(2) 0.1756(2) 0.0915(18) Uani 1 1 d . . . . .
C134 C 0.5500(2) 0.4189(2) 0.39718(18) 0.0512(12) Uani 1 1 d . . . . .
C135 C 0.5220(3) 0.3841(3) 0.3637(2) 0.0806(19) Uani 1 1 d . . . . .
H113 H 0.5181 0.4072 0.3368 0.121 Uiso 1 1 calc R U . . .
H112 H 0.4845 0.3726 0.3736 0.121 Uiso 1 1 calc R U . . .
H114 H 0.5444 0.3490 0.3579 0.121 Uiso 1 1 calc R U . . .
C3C C 0.4117(2) -0.3013(3) 0.0653(2) 0.0771(18) Uani 1 1 d . . . . .
H118 H 0.4007 -0.3334 0.0457 0.116 Uiso 1 1 calc R U . . .
H117 H 0.4106 -0.3149 0.0956 0.116 Uiso 1 1 calc R U . . .
H115 H 0.4500 -0.2884 0.0585 0.116 Uiso 1 1 calc R U . . .
C2C C 0.3718(2) -0.2517(3) 0.05916(17) 0.0590(15) Uani 1 1 d . . . . .
C6C C 0.0851(2) 0.5655(2) 0.26227(16) 0.0510(12) Uani 1 1 d . . . . .
C9AA C 0.0120(3) 0.6437(3) 0.1421(2) 0.0658(16) Uani 1 1 d . . . . .
C4C C 0.0630(3) 0.6173(3) 0.2824(2) 0.095(2) Uani 1 1 d . . . . .
H4A H 0.0836 0.6516 0.2721 0.142 Uiso 1 1 calc R U . . .
H4B H 0.0673 0.6142 0.3142 0.142 Uiso 1 1 calc R U . . .
H4C H 0.0229 0.6214 0.2747 0.142 Uiso 1 1 calc R U . . .
C5C C 0.0497(4) 0.5097(4) 0.2742(3) 0.120(3) Uani 1 1 d . . . . .
H5A H 0.0643 0.4757 0.2585 0.180 Uiso 1 1 calc R U . . .
H5B H 0.0100 0.5159 0.2659 0.180 Uiso 1 1 calc R U . . .
H5C H 0.0527 0.5026 0.3058 0.180 Uiso 1 1 calc R U . . .
C1C C 0.3803(3) -0.2001(3) 0.0914(2) 0.093(2) Uani 1 1 d . . . . .
H1CA H 0.3810 -0.2149 0.1215 0.139 Uiso 1 1 calc R U . . .
H1CB H 0.3492 -0.1721 0.0878 0.139 Uiso 1 1 calc R U . . .
H1CC H 0.4162 -0.1805 0.0854 0.139 Uiso 1 1 calc R U . . .
C10A C -0.0022(3) 0.6646(4) 0.0995(2) 0.103(3) Uani 1 1 d . . . . .
C13A C 0.5860(5) 0.6458(6) 0.1465(4) 0.200(6) Uani 1 1 d D U . . .
O1A O 0.6072(5) 0.6041(6) 0.1664(5) 0.287(8) Uani 1 1 d D . . . .
C14A C 0.5538(5) 0.6596(7) 0.1054(5) 0.345(16) Uani 1 1 d D . . . .
H14A H 0.5460 0.7016 0.1041 0.518 Uiso 1 1 calc R U . . .
H14B H 0.5761 0.6481 0.0801 0.518 Uiso 1 1 calc R U . . .
H14C H 0.5180 0.6380 0.1049 0.518 Uiso 1 1 calc R U . . .
C15A C 0.6283(5) 0.6948(6) 0.1554(5) 0.21382(12) Uani 1 1 d D U . . .
H15A H 0.6153 0.7307 0.1408 0.321 Uiso 1 1 calc R U . . .
H15B H 0.6315 0.7017 0.1870 0.321 Uiso 1 1 calc R U . . .
H15C H 0.6652 0.6837 0.1441 0.321 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.282(3) . ?
Ag1 N1 2.296(3) . ?
Ag1 N11 2.317(3) . ?
Ag1 Ag2 3.1450(4) . ?
Ag2 P1 2.5650(9) . ?
Ag2 P3 2.5845(9) . ?
Ag2 P2 2.5902(9) . ?
Ag2 P4 2.5959(9) . ?
Ag2 Ag4 3.0882(4) . ?
Ag2 Ag3 3.1354(4) . ?
Ag2 Ag5 3.1446(4) . ?
Ag3 N2 2.310(3) . ?
Ag3 N3 2.321(3) . ?
Ag3 N7 2.327(3) . ?
Ag3 N1A 2.433(4) . ?
Ag4 N6 2.276(3) . ?
Ag4 N5 2.281(3) . ?
Ag4 N12 2.288(3) . ?
Ag5 N9 2.305(3) . ?
Ag5 N10 2.310(3) . ?
Ag5 N8 2.311(3) . ?
Ag5 N2A 2.542(4) . ?
P1 C6 1.828(4) . ?
P1 C22 1.829(4) . ?
P1 C1 1.834(4) . ?
P2 C7 1.831(3) . ?
P2 C13 1.833(3) . ?
P2 C8 1.834(4) . ?
P3 C15 1.831(4) . ?
P3 C14 1.831(4) . ?
P3 C20 1.838(4) . ?
P4 C34 1.837(4) . ?
P4 C29 1.838(4) . ?
P4 C28 1.839(3) . ?
N2A C3A 1.127(6) . ?
N1 C2 1.332(5) . ?
N1 C1 1.347(5) . ?
N2 C60 1.340(5) . ?
N2 C6 1.343(5) . ?
N3 C58 1.341(5) . ?
N3 C7 1.344(4) . ?
N4 C9 1.333(5) . ?
N4 C8 1.353(5) . ?
N5 C51 1.339(5) . ?
N5 C13 1.350(5) . ?
N6 C50 1.329(5) . ?
N6 C14 1.349(5) . ?
N7 C15 1.345(5) . ?
N7 C16 1.346(5) . ?
N8 C20 1.338(5) . ?
N8 C43 1.342(5) . ?
N10 C28 1.344(4) . ?
N10 C42 1.348(5) . ?
N11 C30 1.333(5) . ?
N11 C29 1.351(5) . ?
N12 C35 1.344(5) . ?
N12 C34 1.344(5) . ?
N9 C26 1.347(5) . ?
N9 C22 1.353(5) . ?
N1A C2A 1.103(6) . ?
C3A C4A 1.445(7) . ?
C1 C5 1.378(5) . ?
C2 C3 1.378(6) . ?
C2 H4 0.9500 . ?
C3 C4 1.377(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.381(6) . ?
C4 H2 0.9500 . ?
C5 H1 0.9500 . ?
C6 C63 1.382(5) . ?
C7 C55 1.382(5) . ?
C8 C12 1.383(5) . ?
C9 C10 1.385(6) . ?
C9 H5 0.9500 . ?
C10 C11 1.365(6) . ?
C10 H8 0.9500 . ?
C11 C12 1.391(6) . ?
C11 H7 0.9500 . ?
C12 H6 0.9500 . ?
C13 C54 1.386(5) . ?
C14 C47 1.383(5) . ?
C15 C19 1.383(5) . ?
C16 C17 1.378(6) . ?
C16 H9 0.9500 . ?
C17 C18 1.390(7) . ?
C17 H12 0.9500 . ?
C18 C19 1.374(6) . ?
C18 H10 0.9500 . ?
C19 H11 0.9500 . ?
C20 C46 1.379(5) . ?
C22 C23 1.387(5) . ?
C23 C24 1.385(6) . ?
C23 H16 0.9500 . ?
C24 C25 1.379(7) . ?
C24 H15 0.9500 . ?
C25 C26 1.377(6) . ?
C25 H13 0.9500 . ?
C26 H14 0.9500 . ?
C28 C39 1.389(5) . ?
C29 C33 1.383(5) . ?
C30 C31 1.381(6) . ?
C30 H20 0.9500 . ?
C31 C32 1.375(6) . ?
C31 H21 0.9500 . ?
C32 C33 1.392(6) . ?
C32 H23 0.9500 . ?
C33 H22 0.9500 . ?
C34 C38 1.389(5) . ?
C35 C36 1.387(6) . ?
C35 H24 0.9500 . ?
C36 C37 1.380(7) . ?
C36 H25 0.9500 . ?
C37 C38 1.373(6) . ?
C37 H26 0.9500 . ?
C38 H27 0.9500 . ?
C39 C40 1.385(5) . ?
C39 H31 0.9500 . ?
C40 C41 1.370(6) . ?
C40 H30 0.9500 . ?
C41 C42 1.385(6) . ?
C41 H29 0.9500 . ?
C42 H28 0.9500 . ?
C43 C44 1.377(6) . ?
C43 H32 0.9500 . ?
C44 C45 1.380(6) . ?
C44 H35 0.9500 . ?
C45 C46 1.389(6) . ?
C45 H33 0.9500 . ?
C46 H34 0.9500 . ?
C47 C48 1.385(6) . ?
C47 H39 0.9500 . ?
C48 C49 1.373(7) . ?
C48 H38 0.9500 . ?
C49 C50 1.377(7) . ?
C49 H37 0.9500 . ?
C50 H36 0.9500 . ?
C51 C52 1.377(6) . ?
C51 H40 0.9500 . ?
C52 C53 1.361(6) . ?
C52 H41 0.9500 . ?
C53 C54 1.387(5) . ?
C53 H42 0.9500 . ?
C54 H43 0.9500 . ?
C55 C56 1.389(5) . ?
C55 H47 0.9500 . ?
C56 C57 1.375(6) . ?
C56 H46 0.9500 . ?
C57 C58 1.383(6) . ?
C57 H45 0.9500 . ?
C58 H44 0.9500 . ?
C2A C1A 1.445(7) . ?
C60 C61 1.381(6) . ?
C60 H53 0.9500 . ?
C61 C62 1.387(6) . ?
C61 H50 0.9500 . ?
C62 C63 1.383(5) . ?
C62 H51 0.9500 . ?
C63 H52 0.9500 . ?
C1A H1AA 0.9800 . ?
C1A H1AB 0.9800 . ?
C1A H1AC 0.9800 . ?
Ag6 N22 2.285(3) . ?
Ag6 N23 2.299(3) . ?
Ag6 N18 2.313(3) . ?
Ag6 Ag7 3.1288(5) . ?
Ag7 P7 2.5793(9) . ?
Ag7 P5 2.5840(9) . ?
Ag7 P6 2.6036(9) . ?
Ag7 P8 2.6057(9) . ?
Ag7 Ag8 3.1107(4) . ?
Ag7 Ag10 3.1440(4) . ?
Ag7 Ag9 3.1725(4) . ?
Ag8 N13 2.287(3) . ?
Ag8 N21 2.293(3) . ?
Ag8 N24' 2.303(3) . ?
Ag8 N3A 2.554(4) . ?
Ag9 N19 2.280(3) . ?
Ag9 N14 2.289(3) . ?
Ag9 N15 2.297(3) . ?
Ag9 N4A 2.539(4) . ?
Ag10 N20 2.277(3) . ?
Ag10 N16 2.291(3) . ?
Ag10 N17 2.304(3) . ?
P5 C68 1.830(4) . ?
P5 C69 1.830(4) . ?
P5 C123 1.835(4) . ?
P6 C71 1.834(4) . ?
P6 C70 1.839(4) . ?
P6 C77 1.844(4) . ?
P7 C79 1.834(4) . ?
P7 C78 1.837(4) . ?
P7 C84 1.838(4) . ?
P8 C97 1.828(4) . ?
P8 C103 1.831(4) . ?
P8 C98 1.835(3) . ?
N13 C68 1.344(5) . ?
N13 C64 1.343(5) . ?
N14 C119 1.335(5) . ?
N14 C69 1.346(5) . ?
N15 C115 1.338(5) . ?
N15 C70 1.341(5) . ?
N16 C77 1.350(5) . ?
N16 C108 1.351(5) . ?
N17 C92 1.338(5) . ?
N17 C78 1.348(5) . ?
N18 C80 1.339(5) . ?
N18 C79 1.354(5) . ?
N19 C84 1.341(5) . ?
N19 C85 1.345(5) . ?
N20 C93 1.337(5) . ?
N20 C97 1.345(4) . ?
N21 C99 1.340(5) . ?
N21 C98 1.347(5) . ?
N22 C104 1.336(5) . ?
N22 C103 1.345(5) . ?
N23 C124 1.344(5) . ?
N23 C123 1.347(5) . ?
N24' C75 1.341(5) . ?
N24' C71 1.348(5) . ?
N4A C9A 1.124(6) . ?
N3A C6A 1.150(7) . ?
C64 C65 1.377(6) . ?
C64 H105 0.9500 . ?
C65 C66 1.385(6) . ?
C65 H104 0.9500 . ?
C66 C67 1.386(6) . ?
C66 H103 0.9500 . ?
C67 C68 1.387(5) . ?
C67 H102 0.9500 . ?
C69 C122 1.379(5) . ?
C70 C112 1.384(5) . ?
C71 C72 1.389(5) . ?
C72 C73 1.388(7) . ?
C72 H57 0.9500 . ?
C73 C74 1.376(8) . ?
C73 H56 0.9500 . ?
C74 C75 1.379(7) . ?
C74 H54 0.9500 . ?
C75 H55 0.9500 . ?
C77 C111 1.380(5) . ?
C78 C89 1.373(5) . ?
C79 C83 1.384(5) . ?
C80 C81 1.380(6) . ?
C80 H58 0.9500 . ?
C81 C82 1.378(7) . ?
C81 H59 0.9500 . ?
C82 C83 1.388(6) . ?
C82 H60 0.9500 . ?
C83 H61 0.9500 . ?
C84 C88 1.386(5) . ?
C85 C86 1.383(6) . ?
C85 H65 0.9500 . ?
C86 C87 1.364(6) . ?
C86 H64 0.9500 . ?
C87 C88 1.390(5) . ?
C87 H63 0.9500 . ?
C88 H62 0.9500 . ?
C89 C90 1.392(6) . ?
C89 H69 0.9500 . ?
C90 C91 1.370(6) . ?
C90 H68 0.9500 . ?
C91 C92 1.383(6) . ?
C91 H67 0.9500 . ?
C92 H66 0.9500 . ?
C93 C94 1.386(6) . ?
C93 H81 0.9500 . ?
C94 C95 1.377(6) . ?
C94 H70 0.9500 . ?
C95 C96 1.377(6) . ?
C95 H71 0.9500 . ?
C96 C97 1.383(5) . ?
C96 H80 0.9500 . ?
C98 C102 1.382(5) . ?
C99 C100 1.388(6) . ?
C99 H72 0.9500 . ?
C100 C101 1.370(6) . ?
C100 H75 0.9500 . ?
C101 C102 1.389(6) . ?
C101 H74 0.9500 . ?
C102 H73 0.9500 . ?
C103 C107 1.379(5) . ?
C104 C105 1.388(6) . ?
C104 H79 0.9500 . ?
C105 C106 1.374(6) . ?
C105 H78 0.9500 . ?
C106 C107 1.394(5) . ?
C106 H77 0.9500 . ?
C107 H76 0.9500 . ?
C108 C109 1.375(6) . ?
C108 H82 0.9500 . ?
C109 C110 1.370(6) . ?
C109 H85 0.9500 . ?
C110 C111 1.390(5) . ?
C110 H84 0.9500 . ?
C111 H83 0.9500 . ?
C112 C113 1.390(6) . ?
C112 H89 0.9500 . ?
C113 C114 1.356(7) . ?
C113 H88 0.9500 . ?
C114 C115 1.391(6) . ?
C114 H86 0.9500 . ?
C115 H87 0.9500 . ?
C9A C8A 1.457(7) . ?
C8A H93 0.9800 . ?
C8A H92 0.9800 . ?
C8A H91 0.9800 . ?
C119 C120 1.378(6) . ?
C119 H97 0.9500 . ?
C120 C121 1.369(6) . ?
C120 H96 0.9500 . ?
C121 C122 1.389(6) . ?
C121 H95 0.9500 . ?
C122 H94 0.9500 . ?
C123 C127 1.380(5) . ?
C124 C125 1.380(6) . ?
C124 H98 0.9500 . ?
C125 C126 1.367(7) . ?
C125 H101 0.9500 . ?
C126 C127 1.388(6) . ?
C126 H100 0.9500 . ?
C127 H99 0.9500 . ?
C6A C5A 1.450(8) . ?
C5A H109 0.9800 . ?
C5A H108 0.9800 . ?
C5A H107 0.9800 . ?
C4A H19 0.9800 . ?
C4A H18 0.9800 . ?
C4A H17 0.9800 . ?
F1 B1 1.353(8) . ?
F2 B1 1.333(10) . ?
F3 B1 1.362(9) . ?
F4 B1 1.361(8) . ?
F6 B3 1.386(7) . ?
F7 B3 1.373(7) . ?
F8 B3 1.361(7) . ?
F9 B3 1.343(7) . ?
F10 B4 1.368(6) . ?
F11 B4 1.367(7) . ?
F12 B4 1.317(7) . ?
F13 B4 1.350(7) . ?
F3' B2 1.337(8) . ?
F15 B6 1.331(7) . ?
F16 B6 1.370(7) . ?
F17 B6 1.373(7) . ?
F18 B6 1.347(8) . ?
F19 B7 1.382(6) . ?
F20 B7 1.389(6) . ?
F21 B7 1.382(7) . ?
F22 B7 1.382(6) . ?
F25 B9 1.404(8) . ?
F26 B9 1.297(8) . ?
F27 B9 1.341(7) . ?
F28 B9 1.365(7) . ?
F29 B10 1.374(8) . ?
F30 B10 1.365(7) . ?
F31 B10 1.362(8) . ?
F32 B10 1.353(8) . ?
F33 B11 1.323(7) . ?
F34 B11 1.358(7) . ?
F35 B11 1.399(8) . ?
F36 B11 1.356(6) . ?
F37 B12 1.388(6) . ?
F38 B12 1.380(6) . ?
F39 B12 1.372(6) . ?
F40 B12 1.356(6) . ?
F2' B2 1.285(8) . ?
F1' B2 1.333(8) . ?
F4' B2 1.403(11) . ?
O1C C2C 1.193(6) . ?
O2C C6C 1.183(6) . ?
N24 C134 1.142(7) . ?
N5A C9AA 1.124(8) . ?
C134 C135 1.449(8) . ?
C135 H113 0.9800 . ?
C135 H112 0.9800 . ?
C135 H114 0.9800 . ?
C3C C2C 1.487(8) . ?
C3C H118 0.9800 . ?
C3C H117 0.9800 . ?
C3C H115 0.9800 . ?
C2C C1C 1.550(9) . ?
C6C C4C 1.439(7) . ?
C6C C5C 1.574(9) . ?
C9AA C10A 1.424(10) . ?
C4C H4A 0.9800 . ?
C4C H4B 0.9800 . ?
C4C H4C 0.9800 . ?
C5C H5A 0.9800 . ?
C5C H5B 0.9800 . ?
C5C H5C 0.9800 . ?
C1C H1CA 0.9800 . ?
C1C H1CB 0.9800 . ?
C1C H1CC 0.9800 . ?
C13A O1A 1.233(9) . ?
C13A C15A 1.525(9) . ?
C13A C14A 1.495(9) . ?
C14A C15A 2.453(9) . ?
C14A H14A 0.9800 . ?
C14A H14B 0.9800 . ?
C14A H14C 0.9800 . ?
C15A H15A 0.9800 . ?
C15A H15B 0.9800 . ?
C15A H15C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N1 127.16(11) . . ?
N4 Ag1 N11 117.46(10) . . ?
N1 Ag1 N11 115.33(11) . . ?
N4 Ag1 Ag2 92.82(8) . . ?
N1 Ag1 Ag2 89.98(8) . . ?
N11 Ag1 Ag2 89.33(7) . . ?
P1 Ag2 P3 109.05(3) . . ?
P1 Ag2 P2 111.27(3) . . ?
P3 Ag2 P2 109.02(3) . . ?
P1 Ag2 P4 109.32(3) . . ?
P3 Ag2 P4 110.57(3) . . ?
P2 Ag2 P4 107.60(3) . . ?
P1 Ag2 Ag4 177.97(2) . . ?
P3 Ag2 Ag4 68.97(2) . . ?
P2 Ag2 Ag4 70.12(2) . . ?
P4 Ag2 Ag4 71.33(2) . . ?
P1 Ag2 Ag3 72.71(2) . . ?
P3 Ag2 Ag3 69.01(2) . . ?
P2 Ag2 Ag3 70.78(2) . . ?
P4 Ag2 Ag3 177.86(2) . . ?
Ag4 Ag2 Ag3 106.668(13) . . ?
P1 Ag2 Ag5 69.25(2) . . ?
P3 Ag2 Ag5 71.32(2) . . ?
P2 Ag2 Ag5 179.14(2) . . ?
P4 Ag2 Ag5 71.54(2) . . ?
Ag4 Ag2 Ag5 109.381(13) . . ?
Ag3 Ag2 Ag5 110.073(13) . . ?
P1 Ag2 Ag1 69.56(2) . . ?
P3 Ag2 Ag1 176.90(2) . . ?
P2 Ag2 Ag1 69.39(2) . . ?
P4 Ag2 Ag1 72.52(2) . . ?
Ag4 Ag2 Ag1 112.435(13) . . ?
Ag3 Ag2 Ag1 107.889(13) . . ?
Ag5 Ag2 Ag1 110.311(13) . . ?
N2 Ag3 N3 117.66(10) . . ?
N2 Ag3 N7 117.96(11) . . ?
N3 Ag3 N7 124.12(11) . . ?
N2 Ag3 N1A 92.55(15) . . ?
N3 Ag3 N1A 95.65(14) . . ?
N7 Ag3 N1A 87.01(13) . . ?
N2 Ag3 Ag2 85.42(7) . . ?
N3 Ag3 Ag2 89.92(7) . . ?
N7 Ag3 Ag2 89.32(8) . . ?
N1A Ag3 Ag2 174.39(12) . . ?
N6 Ag4 N5 124.10(11) . . ?
N6 Ag4 N12 123.58(11) . . ?
N5 Ag4 N12 111.88(11) . . ?
N6 Ag4 Ag2 93.72(8) . . ?
N5 Ag4 Ag2 90.26(8) . . ?
N12 Ag4 Ag2 92.41(8) . . ?
N9 Ag5 N10 122.04(11) . . ?
N9 Ag5 N8 121.82(11) . . ?
N10 Ag5 N8 116.10(11) . . ?
N9 Ag5 N2A 87.73(12) . . ?
N10 Ag5 N2A 97.53(13) . . ?
N8 Ag5 N2A 86.76(13) . . ?
N9 Ag5 Ag2 90.79(7) . . ?
N10 Ag5 Ag2 90.01(7) . . ?
N8 Ag5 Ag2 87.26(7) . . ?
N2A Ag5 Ag2 171.90(12) . . ?
C6 P1 C22 102.84(16) . . ?
C6 P1 C1 101.42(16) . . ?
C22 P1 C1 101.52(16) . . ?
C6 P1 Ag2 113.24(12) . . ?
C22 P1 Ag2 118.42(12) . . ?
C1 P1 Ag2 117.01(12) . . ?
C7 P2 C13 101.53(16) . . ?
C7 P2 C8 100.85(16) . . ?
C13 P2 C8 101.53(16) . . ?
C7 P2 Ag2 116.27(11) . . ?
C13 P2 Ag2 114.86(11) . . ?
C8 P2 Ag2 119.11(12) . . ?
C15 P3 C14 101.82(17) . . ?
C15 P3 C20 102.02(17) . . ?
C14 P3 C20 101.08(17) . . ?
C15 P3 Ag2 116.52(12) . . ?
C14 P3 Ag2 118.24(12) . . ?
C20 P3 Ag2 114.64(12) . . ?
C34 P4 C29 102.82(16) . . ?
C34 P4 C28 101.13(16) . . ?
C29 P4 C28 100.19(16) . . ?
C34 P4 Ag2 116.93(12) . . ?
C29 P4 Ag2 116.62(11) . . ?
C28 P4 Ag2 116.51(12) . . ?
C3A N2A Ag5 141.5(4) . . ?
C2 N1 C1 117.4(3) . . ?
C2 N1 Ag1 120.3(3) . . ?
C1 N1 Ag1 122.0(2) . . ?
C60 N2 C6 118.1(3) . . ?
C60 N2 Ag3 116.0(2) . . ?
C6 N2 Ag3 125.7(2) . . ?
C58 N3 C7 117.9(3) . . ?
C58 N3 Ag3 119.2(3) . . ?
C7 N3 Ag3 122.8(2) . . ?
C9 N4 C8 117.1(3) . . ?
C9 N4 Ag1 121.2(3) . . ?
C8 N4 Ag1 121.7(2) . . ?
C51 N5 C13 117.3(3) . . ?
C51 N5 Ag4 120.5(3) . . ?
C13 N5 Ag4 122.1(2) . . ?
C50 N6 C14 117.8(3) . . ?
C50 N6 Ag4 121.5(3) . . ?
C14 N6 Ag4 120.6(2) . . ?
C15 N7 C16 117.6(3) . . ?
C15 N7 Ag3 120.6(2) . . ?
C16 N7 Ag3 121.4(3) . . ?
C20 N8 C43 118.1(3) . . ?
C20 N8 Ag5 124.1(2) . . ?
C43 N8 Ag5 117.4(3) . . ?
C28 N10 C42 117.2(3) . . ?
C28 N10 Ag5 123.9(2) . . ?
C42 N10 Ag5 118.8(2) . . ?
C30 N11 C29 117.6(3) . . ?
C30 N11 Ag1 117.1(3) . . ?
C29 N11 Ag1 125.1(2) . . ?
C35 N12 C34 117.8(3) . . ?
C35 N12 Ag4 119.1(3) . . ?
C34 N12 Ag4 123.0(2) . . ?
C26 N9 C22 117.5(3) . . ?
C26 N9 Ag5 120.9(3) . . ?
C22 N9 Ag5 121.5(2) . . ?
C2A N1A Ag3 169.2(5) . . ?
N2A C3A C4A 178.5(5) . . ?
N1 C1 C5 122.7(3) . . ?
N1 C1 P1 113.0(3) . . ?
C5 C1 P1 124.3(3) . . ?
N1 C2 C3 123.2(4) . . ?
N1 C2 H4 118.4 . . ?
C3 C2 H4 118.4 . . ?
C4 C3 C2 119.0(4) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 H3 120.5 . . ?
C3 C4 C5 118.7(4) . . ?
C3 C4 H2 120.7 . . ?
C5 C4 H2 120.7 . . ?
C1 C5 C4 118.9(4) . . ?
C1 C5 H1 120.5 . . ?
C4 C5 H1 120.5 . . ?
N2 C6 C63 122.7(3) . . ?
N2 C6 P1 112.8(3) . . ?
C63 C6 P1 124.5(3) . . ?
N3 C7 C55 123.0(3) . . ?
N3 C7 P2 113.6(3) . . ?
C55 C7 P2 123.3(3) . . ?
N4 C8 C12 122.9(3) . . ?
N4 C8 P2 113.6(3) . . ?
C12 C8 P2 123.5(3) . . ?
N4 C9 C10 123.4(4) . . ?
N4 C9 H5 118.3 . . ?
C10 C9 H5 118.3 . . ?
C11 C10 C9 119.0(4) . . ?
C11 C10 H8 120.5 . . ?
C9 C10 H8 120.5 . . ?
C10 C11 C12 119.0(4) . . ?
C10 C11 H7 120.5 . . ?
C12 C11 H7 120.5 . . ?
C8 C12 C11 118.5(4) . . ?
C8 C12 H6 120.8 . . ?
C11 C12 H6 120.8 . . ?
N5 C13 C54 122.7(3) . . ?
N5 C13 P2 113.0(3) . . ?
C54 C13 P2 124.3(3) . . ?
N6 C14 C47 122.5(4) . . ?
N6 C14 P3 113.1(3) . . ?
C47 C14 P3 124.4(3) . . ?
N7 C15 C19 122.9(3) . . ?
N7 C15 P3 113.2(3) . . ?
C19 C15 P3 123.8(3) . . ?
N7 C16 C17 122.5(4) . . ?
N7 C16 H9 118.8 . . ?
C17 C16 H9 118.8 . . ?
C16 C17 C18 119.5(4) . . ?
C16 C17 H12 120.3 . . ?
C18 C17 H12 120.3 . . ?
C19 C18 C17 118.4(4) . . ?
C19 C18 H10 120.8 . . ?
C17 C18 H10 120.8 . . ?
C18 C19 C15 119.2(4) . . ?
C18 C19 H11 120.4 . . ?
C15 C19 H11 120.4 . . ?
N8 C20 C46 123.1(3) . . ?
N8 C20 P3 113.2(3) . . ?
C46 C20 P3 123.7(3) . . ?
N9 C22 C23 123.0(3) . . ?
N9 C22 P1 112.8(2) . . ?
C23 C22 P1 124.2(3) . . ?
C24 C23 C22 118.1(4) . . ?
C24 C23 H16 121.0 . . ?
C22 C23 H16 121.0 . . ?
C25 C24 C23 119.6(4) . . ?
C25 C24 H15 120.2 . . ?
C23 C24 H15 120.2 . . ?
C26 C25 C24 119.0(4) . . ?
C26 C25 H13 120.5 . . ?
C24 C25 H13 120.5 . . ?
N9 C26 C25 122.8(4) . . ?
N9 C26 H14 118.6 . . ?
C25 C26 H14 118.6 . . ?
N10 C28 C39 122.9(3) . . ?
N10 C28 P4 113.9(3) . . ?
C39 C28 P4 123.1(3) . . ?
N11 C29 C33 122.7(3) . . ?
N11 C29 P4 113.6(2) . . ?
C33 C29 P4 123.5(3) . . ?
N11 C30 C31 123.4(4) . . ?
N11 C30 H20 118.3 . . ?
C31 C30 H20 118.3 . . ?
C32 C31 C30 118.8(4) . . ?
C32 C31 H21 120.6 . . ?
C30 C31 H21 120.6 . . ?
C31 C32 C33 118.9(4) . . ?
C31 C32 H23 120.5 . . ?
C33 C32 H23 120.5 . . ?
C29 C33 C32 118.6(4) . . ?
C29 C33 H22 120.7 . . ?
C32 C33 H22 120.7 . . ?
N12 C34 C38 122.2(3) . . ?
N12 C34 P4 113.7(3) . . ?
C38 C34 P4 124.1(3) . . ?
N12 C35 C36 122.7(4) . . ?
N12 C35 H24 118.6 . . ?
C36 C35 H24 118.6 . . ?
C37 C36 C35 119.0(4) . . ?
C37 C36 H25 120.5 . . ?
C35 C36 H25 120.5 . . ?
C38 C37 C36 118.7(4) . . ?
C38 C37 H26 120.6 . . ?
C36 C37 H26 120.6 . . ?
C37 C38 C34 119.5(4) . . ?
C37 C38 H27 120.2 . . ?
C34 C38 H27 120.2 . . ?
C40 C39 C28 119.0(4) . . ?
C40 C39 H31 120.5 . . ?
C28 C39 H31 120.5 . . ?
C41 C40 C39 118.6(4) . . ?
C41 C40 H30 120.7 . . ?
C39 C40 H30 120.7 . . ?
C40 C41 C42 119.5(4) . . ?
C40 C41 H29 120.2 . . ?
C42 C41 H29 120.2 . . ?
N10 C42 C41 122.8(4) . . ?
N10 C42 H28 118.6 . . ?
C41 C42 H28 118.6 . . ?
N8 C43 C44 122.3(4) . . ?
N8 C43 H32 118.9 . . ?
C44 C43 H32 118.9 . . ?
C43 C44 C45 119.4(4) . . ?
C43 C44 H35 120.3 . . ?
C45 C44 H35 120.3 . . ?
C44 C45 C46 118.7(4) . . ?
C44 C45 H33 120.7 . . ?
C46 C45 H33 120.7 . . ?
C20 C46 C45 118.4(4) . . ?
C20 C46 H34 120.8 . . ?
C45 C46 H34 120.8 . . ?
C14 C47 C48 118.4(4) . . ?
C14 C47 H39 120.8 . . ?
C48 C47 H39 120.8 . . ?
C49 C48 C47 119.1(4) . . ?
C49 C48 H38 120.5 . . ?
C47 C48 H38 120.5 . . ?
C48 C49 C50 119.0(4) . . ?
C48 C49 H37 120.5 . . ?
C50 C49 H37 120.5 . . ?
N6 C50 C49 123.1(4) . . ?
N6 C50 H36 118.4 . . ?
C49 C50 H36 118.4 . . ?
N5 C51 C52 122.8(4) . . ?
N5 C51 H40 118.6 . . ?
C52 C51 H40 118.6 . . ?
C53 C52 C51 119.8(4) . . ?
C53 C52 H41 120.1 . . ?
C51 C52 H41 120.1 . . ?
C52 C53 C54 118.8(4) . . ?
C52 C53 H42 120.6 . . ?
C54 C53 H42 120.6 . . ?
C13 C54 C53 118.6(4) . . ?
C13 C54 H43 120.7 . . ?
C53 C54 H43 120.7 . . ?
C7 C55 C56 118.6(4) . . ?
C7 C55 H47 120.7 . . ?
C56 C55 H47 120.7 . . ?
C57 C56 C55 118.6(4) . . ?
C57 C56 H46 120.7 . . ?
C55 C56 H46 120.7 . . ?
C56 C57 C58 119.6(4) . . ?
C56 C57 H45 120.2 . . ?
C58 C57 H45 120.2 . . ?
N3 C58 C57 122.3(4) . . ?
N3 C58 H44 118.8 . . ?
C57 C58 H44 118.8 . . ?
N1A C2A C1A 179.8(8) . . ?
N2 C60 C61 122.7(4) . . ?
N2 C60 H53 118.6 . . ?
C61 C60 H53 118.6 . . ?
C60 C61 C62 118.7(4) . . ?
C60 C61 H50 120.6 . . ?
C62 C61 H50 120.6 . . ?
C63 C62 C61 118.9(4) . . ?
C63 C62 H51 120.5 . . ?
C61 C62 H51 120.5 . . ?
C6 C63 C62 118.8(4) . . ?
C6 C63 H52 120.6 . . ?
C62 C63 H52 120.6 . . ?
C2A C1A H1AA 109.5 . . ?
C2A C1A H1AB 109.5 . . ?
H1AA C1A H1AB 109.5 . . ?
C2A C1A H1AC 109.5 . . ?
H1AA C1A H1AC 109.5 . . ?
H1AB C1A H1AC 109.5 . . ?
N22 Ag6 N23 130.29(11) . . ?
N22 Ag6 N18 119.56(11) . . ?
N23 Ag6 N18 110.15(11) . . ?
N22 Ag6 Ag7 92.14(8) . . ?
N23 Ag6 Ag7 87.52(8) . . ?
N18 Ag6 Ag7 89.93(8) . . ?
P7 Ag7 P5 109.46(3) . . ?
P7 Ag7 P6 109.47(3) . . ?
P5 Ag7 P6 108.60(3) . . ?
P7 Ag7 P8 107.96(3) . . ?
P5 Ag7 P8 111.26(3) . . ?
P6 Ag7 P8 110.08(3) . . ?
P7 Ag7 Ag8 176.08(2) . . ?
P5 Ag7 Ag8 72.15(2) . . ?
P6 Ag7 Ag8 72.94(2) . . ?
P8 Ag7 Ag8 68.15(2) . . ?
P7 Ag7 Ag6 72.66(2) . . ?
P5 Ag7 Ag6 69.74(2) . . ?
P6 Ag7 Ag6 177.75(2) . . ?
P8 Ag7 Ag6 69.55(2) . . ?
Ag8 Ag7 Ag6 104.966(13) . . ?
P7 Ag7 Ag10 73.40(2) . . ?
P5 Ag7 Ag10 177.14(2) . . ?
P6 Ag7 Ag10 70.00(2) . . ?
P8 Ag7 Ag10 67.38(2) . . ?
Ag8 Ag7 Ag10 104.990(12) . . ?
Ag6 Ag7 Ag10 111.593(12) . . ?
P7 Ag7 Ag9 70.59(2) . . ?
P5 Ag7 Ag9 68.47(2) . . ?
P6 Ag7 Ag9 71.66(2) . . ?
P8 Ag7 Ag9 178.13(2) . . ?
Ag8 Ag7 Ag9 113.291(13) . . ?
Ag6 Ag7 Ag9 108.743(12) . . ?
Ag10 Ag7 Ag9 112.978(13) . . ?
N13 Ag8 N21 127.31(11) . . ?
N13 Ag8 N24' 117.16(11) . . ?
N21 Ag8 N24' 115.39(11) . . ?
N13 Ag8 N3A 93.42(13) . . ?
N21 Ag8 N3A 85.53(13) . . ?
N24' Ag8 N3A 95.08(15) . . ?
N13 Ag8 Ag7 88.61(8) . . ?
N21 Ag8 Ag7 89.80(8) . . ?
N24' Ag8 Ag7 87.83(8) . . ?
N3A Ag8 Ag7 175.22(11) . . ?
N19 Ag9 N14 125.56(11) . . ?
N19 Ag9 N15 118.68(12) . . ?
N14 Ag9 N15 115.75(12) . . ?
N19 Ag9 N4A 91.76(13) . . ?
N14 Ag9 N4A 87.03(13) . . ?
N15 Ag9 N4A 90.06(14) . . ?
N19 Ag9 Ag7 91.15(8) . . ?
N14 Ag9 Ag7 90.46(8) . . ?
N15 Ag9 Ag7 89.42(8) . . ?
N4A Ag9 Ag7 176.92(11) . . ?
N20 Ag10 N16 132.17(10) . . ?
N20 Ag10 N17 113.65(11) . . ?
N16 Ag10 N17 114.13(11) . . ?
N20 Ag10 Ag7 90.38(7) . . ?
N16 Ag10 Ag7 93.74(8) . . ?
N17 Ag10 Ag7 87.17(8) . . ?
C68 P5 C69 102.63(17) . . ?
C68 P5 C123 103.01(17) . . ?
C69 P5 C123 101.68(17) . . ?
C68 P5 Ag7 115.08(12) . . ?
C69 P5 Ag7 117.83(12) . . ?
C123 P5 Ag7 114.55(12) . . ?
C71 P6 C70 102.35(17) . . ?
C71 P6 C77 100.31(16) . . ?
C70 P6 C77 101.23(17) . . ?
C71 P6 Ag7 113.21(12) . . ?
C70 P6 Ag7 117.24(12) . . ?
C77 P6 Ag7 119.76(12) . . ?
C79 P7 C78 104.13(17) . . ?
C79 P7 C84 100.01(16) . . ?
C78 P7 C84 101.59(16) . . ?
C79 P7 Ag7 116.32(12) . . ?
C78 P7 Ag7 113.54(12) . . ?
C84 P7 Ag7 118.97(12) . . ?
C97 P8 C103 100.76(16) . . ?
C97 P8 C98 101.67(16) . . ?
C103 P8 C98 103.68(16) . . ?
C97 P8 Ag7 115.61(11) . . ?
C103 P8 Ag7 118.13(12) . . ?
C98 P8 Ag7 114.68(12) . . ?
C68 N13 C64 117.9(3) . . ?
C68 N13 Ag8 123.8(2) . . ?
C64 N13 Ag8 118.1(3) . . ?
C119 N14 C69 117.8(3) . . ?
C119 N14 Ag9 120.5(3) . . ?
C69 N14 Ag9 121.6(2) . . ?
C115 N15 C70 118.2(3) . . ?
C115 N15 Ag9 116.3(3) . . ?
C70 N15 Ag9 125.2(2) . . ?
C77 N16 C108 117.1(3) . . ?
C77 N16 Ag10 122.1(2) . . ?
C108 N16 Ag10 120.8(3) . . ?
C92 N17 C78 118.3(3) . . ?
C92 N17 Ag10 116.1(2) . . ?
C78 N17 Ag10 125.5(2) . . ?
C80 N18 C79 117.8(4) . . ?
C80 N18 Ag6 117.4(3) . . ?
C79 N18 Ag6 124.7(2) . . ?
C84 N19 C85 117.5(3) . . ?
C84 N19 Ag9 123.4(2) . . ?
C85 N19 Ag9 119.0(3) . . ?
C93 N20 C97 118.0(3) . . ?
C93 N20 Ag10 121.5(2) . . ?
C97 N20 Ag10 120.4(2) . . ?
C99 N21 C98 118.2(3) . . ?
C99 N21 Ag8 121.5(3) . . ?
C98 N21 Ag8 120.2(2) . . ?
C104 N22 C103 117.8(3) . . ?
C104 N22 Ag6 119.8(3) . . ?
C103 N22 Ag6 122.3(2) . . ?
C124 N23 C123 118.2(3) . . ?
C124 N23 Ag6 119.9(3) . . ?
C123 N23 Ag6 121.4(2) . . ?
C75 N24' C71 117.9(4) . . ?
C75 N24' Ag8 116.4(3) . . ?
C71 N24' Ag8 125.7(2) . . ?
C9A N4A Ag9 153.2(4) . . ?
C6A N3A Ag8 156.2(5) . . ?
N13 C64 C65 122.9(4) . . ?
N13 C64 H105 118.6 . . ?
C65 C64 H105 118.6 . . ?
C64 C65 C66 119.3(4) . . ?
C64 C65 H104 120.3 . . ?
C66 C65 H104 120.3 . . ?
C65 C66 C67 118.2(4) . . ?
C65 C66 H103 120.9 . . ?
C67 C66 H103 120.9 . . ?
C66 C67 C68 119.2(4) . . ?
C66 C67 H102 120.4 . . ?
C68 C67 H102 120.4 . . ?
N13 C68 C67 122.5(3) . . ?
N13 C68 P5 114.2(3) . . ?
C67 C68 P5 123.3(3) . . ?
N14 C69 C122 122.5(4) . . ?
N14 C69 P5 113.0(3) . . ?
C122 C69 P5 124.4(3) . . ?
N15 C70 C112 122.3(4) . . ?
N15 C70 P6 113.7(3) . . ?
C112 C70 P6 123.9(3) . . ?
N24' C71 C72 122.7(4) . . ?
N24' C71 P6 113.3(3) . . ?
C72 C71 P6 124.0(3) . . ?
C71 C72 C73 118.3(5) . . ?
C71 C72 H57 120.8 . . ?
C73 C72 H57 120.8 . . ?
C74 C73 C72 119.2(4) . . ?
C74 C73 H56 120.4 . . ?
C72 C73 H56 120.4 . . ?
C73 C74 C75 119.2(4) . . ?
C73 C74 H54 120.4 . . ?
C75 C74 H54 120.4 . . ?
N24' C75 C74 122.7(5) . . ?
N24' C75 H55 118.6 . . ?
C74 C75 H55 118.6 . . ?
N16 C77 C111 122.6(3) . . ?
N16 C77 P6 114.0(3) . . ?
C111 C77 P6 123.3(3) . . ?
N17 C78 C89 122.5(3) . . ?
N17 C78 P7 114.4(2) . . ?
C89 C78 P7 123.1(3) . . ?
N18 C79 C83 122.8(4) . . ?
N18 C79 P7 113.5(3) . . ?
C83 C79 P7 123.6(3) . . ?
N18 C80 C81 122.4(4) . . ?
N18 C80 H58 118.8 . . ?
C81 C80 H58 118.8 . . ?
C82 C81 C80 119.7(4) . . ?
C82 C81 H59 120.2 . . ?
C80 C81 H59 120.2 . . ?
C81 C82 C83 118.7(4) . . ?
C81 C82 H60 120.6 . . ?
C83 C82 H60 120.6 . . ?
C79 C83 C82 118.5(4) . . ?
C79 C83 H61 120.8 . . ?
C82 C83 H61 120.8 . . ?
N19 C84 C88 122.6(3) . . ?
N19 C84 P7 114.2(3) . . ?
C88 C84 P7 123.2(3) . . ?
N19 C85 C86 123.1(4) . . ?
N19 C85 H65 118.5 . . ?
C86 C85 H65 118.5 . . ?
C87 C86 C85 118.9(4) . . ?
C87 C86 H64 120.5 . . ?
C85 C86 H64 120.5 . . ?
C86 C87 C88 119.1(4) . . ?
C86 C87 H63 120.4 . . ?
C88 C87 H63 120.4 . . ?
C84 C88 C87 118.8(4) . . ?
C84 C88 H62 120.6 . . ?
C87 C88 H62 120.6 . . ?
C78 C89 C90 118.6(4) . . ?
C78 C89 H69 120.7 . . ?
C90 C89 H69 120.7 . . ?
C91 C90 C89 119.2(4) . . ?
C91 C90 H68 120.4 . . ?
C89 C90 H68 120.4 . . ?
C90 C91 C92 119.1(4) . . ?
C90 C91 H67 120.5 . . ?
C92 C91 H67 120.5 . . ?
N17 C92 C91 122.3(4) . . ?
N17 C92 H66 118.8 . . ?
C91 C92 H66 118.8 . . ?
N20 C93 C94 122.8(4) . . ?
N20 C93 H81 118.6 . . ?
C94 C93 H81 118.6 . . ?
C95 C94 C93 118.7(4) . . ?
C95 C94 H70 120.6 . . ?
C93 C94 H70 120.6 . . ?
C94 C95 C96 119.1(4) . . ?
C94 C95 H71 120.5 . . ?
C96 C95 H71 120.5 . . ?
C95 C96 C97 119.1(4) . . ?
C95 C96 H80 120.4 . . ?
C97 C96 H80 120.4 . . ?
N20 C97 C96 122.4(3) . . ?
N20 C97 P8 112.8(3) . . ?
C96 C97 P8 124.8(3) . . ?
N21 C98 C102 122.6(3) . . ?
N21 C98 P8 112.9(3) . . ?
C102 C98 P8 124.5(3) . . ?
N21 C99 C100 122.3(4) . . ?
N21 C99 H72 118.9 . . ?
C100 C99 H72 118.9 . . ?
C101 C100 C99 119.1(4) . . ?
C101 C100 H75 120.5 . . ?
C99 C100 H75 120.5 . . ?
C100 C101 C102 119.4(4) . . ?
C100 C101 H74 120.3 . . ?
C102 C101 H74 120.3 . . ?
C98 C102 C101 118.4(4) . . ?
C98 C102 H73 120.8 . . ?
C101 C102 H73 120.8 . . ?
N22 C103 C107 123.0(3) . . ?
N22 C103 P8 113.2(3) . . ?
C107 C103 P8 123.7(3) . . ?
N22 C104 C105 122.8(4) . . ?
N22 C104 H79 118.6 . . ?
C105 C104 H79 118.6 . . ?
C106 C105 C104 119.0(4) . . ?
C106 C105 H78 120.5 . . ?
C104 C105 H78 120.5 . . ?
C105 C106 C107 118.8(4) . . ?
C105 C106 H77 120.6 . . ?
C107 C106 H77 120.6 . . ?
C103 C107 C106 118.6(4) . . ?
C103 C107 H76 120.7 . . ?
C106 C107 H76 120.7 . . ?
N16 C108 C109 123.4(4) . . ?
N16 C108 H82 118.3 . . ?
C109 C108 H82 118.3 . . ?
C110 C109 C108 118.8(4) . . ?
C110 C109 H85 120.6 . . ?
C108 C109 H85 120.6 . . ?
C109 C110 C111 119.1(4) . . ?
C109 C110 H84 120.4 . . ?
C111 C110 H84 120.4 . . ?
C77 C111 C110 118.9(4) . . ?
C77 C111 H83 120.6 . . ?
C110 C111 H83 120.6 . . ?
C70 C112 C113 118.9(4) . . ?
C70 C112 H89 120.6 . . ?
C113 C112 H89 120.6 . . ?
C114 C113 C112 118.8(4) . . ?
C114 C113 H88 120.6 . . ?
C112 C113 H88 120.6 . . ?
C113 C114 C115 119.6(4) . . ?
C113 C114 H86 120.2 . . ?
C115 C114 H86 120.2 . . ?
N15 C115 C114 122.1(4) . . ?
N15 C115 H87 118.9 . . ?
C114 C115 H87 118.9 . . ?
N4A C9A C8A 179.1(6) . . ?
C9A C8A H93 109.5 . . ?
C9A C8A H92 109.5 . . ?
H93 C8A H92 109.5 . . ?
C9A C8A H91 109.5 . . ?
H93 C8A H91 109.5 . . ?
H92 C8A H91 109.5 . . ?
N14 C119 C120 122.8(4) . . ?
N14 C119 H97 118.6 . . ?
C120 C119 H97 118.6 . . ?
C121 C120 C119 119.4(4) . . ?
C121 C120 H96 120.3 . . ?
C119 C120 H96 120.3 . . ?
C120 C121 C122 118.7(4) . . ?
C120 C121 H95 120.7 . . ?
C122 C121 H95 120.7 . . ?
C69 C122 C121 118.8(4) . . ?
C69 C122 H94 120.6 . . ?
C121 C122 H94 120.6 . . ?
N23 C123 C127 122.3(4) . . ?
N23 C123 P5 113.2(3) . . ?
C127 C123 P5 124.5(3) . . ?
N23 C124 C125 122.4(4) . . ?
N23 C124 H98 118.8 . . ?
C125 C124 H98 118.8 . . ?
C126 C125 C124 119.1(4) . . ?
C126 C125 H101 120.4 . . ?
C124 C125 H101 120.4 . . ?
C125 C126 C127 119.4(4) . . ?
C125 C126 H100 120.3 . . ?
C127 C126 H100 120.3 . . ?
C123 C127 C126 118.6(4) . . ?
C123 C127 H99 120.7 . . ?
C126 C127 H99 120.7 . . ?
N3A C6A C5A 177.9(8) . . ?
C6A C5A H109 109.5 . . ?
C6A C5A H108 109.5 . . ?
H109 C5A H108 109.5 . . ?
C6A C5A H107 109.5 . . ?
H109 C5A H107 109.5 . . ?
H108 C5A H107 109.5 . . ?
C3A C4A H19 109.5 . . ?
C3A C4A H18 109.5 . . ?
H19 C4A H18 109.5 . . ?
C3A C4A H17 109.5 . . ?
H19 C4A H17 109.5 . . ?
H18 C4A H17 109.5 . . ?
F2 B1 F1 113.8(7) . . ?
F2 B1 F4 110.8(7) . . ?
F1 B1 F4 112.4(6) . . ?
F2 B1 F3 104.5(6) . . ?
F1 B1 F3 105.8(7) . . ?
F4 B1 F3 108.9(7) . . ?
F9 B3 F8 110.4(6) . . ?
F9 B3 F7 108.6(5) . . ?
F8 B3 F7 110.9(5) . . ?
F9 B3 F6 109.1(5) . . ?
F8 B3 F6 106.6(5) . . ?
F7 B3 F6 111.2(6) . . ?
F12 B4 F13 110.4(5) . . ?
F12 B4 F11 109.5(6) . . ?
F13 B4 F11 108.9(5) . . ?
F12 B4 F10 110.8(5) . . ?
F13 B4 F10 111.1(5) . . ?
F11 B4 F10 106.1(4) . . ?
F15 B6 F18 108.9(6) . . ?
F15 B6 F16 108.4(4) . . ?
F18 B6 F16 106.5(6) . . ?
F15 B6 F17 113.7(6) . . ?
F18 B6 F17 107.4(5) . . ?
F16 B6 F17 111.6(5) . . ?
F21 B7 F19 109.6(4) . . ?
F21 B7 F22 109.5(4) . . ?
F19 B7 F22 108.7(4) . . ?
F21 B7 F20 110.2(4) . . ?
F19 B7 F20 108.6(4) . . ?
F22 B7 F20 110.2(4) . . ?
F26 B9 F27 109.5(6) . . ?
F26 B9 F28 109.3(6) . . ?
F27 B9 F28 110.9(5) . . ?
F26 B9 F25 113.5(6) . . ?
F27 B9 F25 104.9(5) . . ?
F28 B9 F25 108.8(5) . . ?
F32 B10 F31 114.6(6) . . ?
F32 B10 F30 107.8(5) . . ?
F31 B10 F30 107.8(6) . . ?
F32 B10 F29 108.0(6) . . ?
F31 B10 F29 108.9(5) . . ?
F30 B10 F29 109.6(6) . . ?
F33 B11 F34 115.8(6) . . ?
F33 B11 F36 114.7(5) . . ?
F34 B11 F36 113.0(5) . . ?
F33 B11 F35 100.1(6) . . ?
F34 B11 F35 104.8(5) . . ?
F36 B11 F35 106.5(6) . . ?
F40 B12 F39 111.5(5) . . ?
F40 B12 F38 108.3(5) . . ?
F39 B12 F38 108.7(4) . . ?
F40 B12 F37 108.8(4) . . ?
F39 B12 F37 110.1(4) . . ?
F38 B12 F37 109.4(4) . . ?
F2' B2 F1' 117.1(7) . . ?
F2' B2 F3' 112.6(6) . . ?
F1' B2 F3' 112.5(7) . . ?
F2' B2 F4' 103.4(8) . . ?
F1' B2 F4' 101.0(6) . . ?
F3' B2 F4' 108.8(8) . . ?
N24 C134 C135 179.1(6) . . ?
C134 C135 H113 109.5 . . ?
C134 C135 H112 109.5 . . ?
H113 C135 H112 109.5 . . ?
C134 C135 H114 109.5 . . ?
H113 C135 H114 109.5 . . ?
H112 C135 H114 109.5 . . ?
C2C C3C H118 109.5 . . ?
C2C C3C H117 109.5 . . ?
H118 C3C H117 109.5 . . ?
C2C C3C H115 109.5 . . ?
H118 C3C H115 109.5 . . ?
H117 C3C H115 109.5 . . ?
O1C C2C C3C 126.5(6) . . ?
O1C C2C C1C 118.3(6) . . ?
C3C C2C C1C 115.2(5) . . ?
O2C C6C C4C 132.8(6) . . ?
O2C C6C C5C 115.5(6) . . ?
C4C C6C C5C 111.6(6) . . ?
N5A C9AA C10A 177.1(8) . . ?
C6C C4C H4A 109.5 . . ?
C6C C4C H4B 109.5 . . ?
H4A C4C H4B 109.5 . . ?
C6C C4C H4C 109.5 . . ?
H4A C4C H4C 109.5 . . ?
H4B C4C H4C 109.5 . . ?
C6C C5C H5A 109.5 . . ?
C6C C5C H5B 109.5 . . ?
H5A C5C H5B 109.5 . . ?
C6C C5C H5C 109.5 . . ?
H5A C5C H5C 109.5 . . ?
H5B C5C H5C 109.5 . . ?
C2C C1C H1CA 109.5 . . ?
C2C C1C H1CB 109.5 . . ?
H1CA C1C H1CB 109.5 . . ?
C2C C1C H1CC 109.5 . . ?
H1CA C1C H1CC 109.5 . . ?
H1CB C1C H1CC 109.5 . . ?
O1A C13A C15A 102.7(12) . . ?
O1A C13A C14A 140.9(15) . . ?
C15A C13A C14A 108.6(8) . . ?
C13A C14A C15A 36.1(4) . . ?
C13A C14A H14A 109.5 . . ?
C15A C14A H14A 80.5 . . ?
C13A C14A H14B 109.5 . . ?
C15A C14A H14B 100.8 . . ?
H14A C14A H14B 109.5 . . ?
C13A C14A H14C 109.5 . . ?
C15A C14A H14C 141.8 . . ?
H14A C14A H14C 109.5 . . ?
H14B C14A H14C 109.5 . . ?
C13A C15A C14A 35.3(4) . . ?
C13A C15A H15A 109.5 . . ?
C14A C15A H15A 76.9 . . ?
C13A C15A H15B 109.5 . . ?
C14A C15A H15B 135.3 . . ?
H15A C15A H15B 109.5 . . ?
C13A C15A H15C 109.5 . . ?
C14A C15A H15C 109.4 . . ?
H15A C15A H15C 109.5 . . ?
H15B C15A H15C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N1 C1 C5 -2.1(5) . . . . ?
Ag1 N1 C1 C5 -176.7(3) . . . . ?
C2 N1 C1 P1 176.1(3) . . . . ?
Ag1 N1 C1 P1 1.5(4) . . . . ?
C6 P1 C1 N1 -78.9(3) . . . . ?
C22 P1 C1 N1 175.3(3) . . . . ?
Ag2 P1 C1 N1 44.8(3) . . . . ?
C6 P1 C1 C5 99.3(3) . . . . ?
C22 P1 C1 C5 -6.5(4) . . . . ?
Ag2 P1 C1 C5 -137.0(3) . . . . ?
C1 N1 C2 C3 0.7(6) . . . . ?
Ag1 N1 C2 C3 175.4(3) . . . . ?
N1 C2 C3 C4 0.6(7) . . . . ?
C2 C3 C4 C5 -0.5(7) . . . . ?
N1 C1 C5 C4 2.2(6) . . . . ?
P1 C1 C5 C4 -175.9(3) . . . . ?
C3 C4 C5 C1 -0.8(7) . . . . ?
C60 N2 C6 C63 0.3(5) . . . . ?
Ag3 N2 C6 C63 -174.8(3) . . . . ?
C60 N2 C6 P1 -179.0(3) . . . . ?
Ag3 N2 C6 P1 5.9(4) . . . . ?
C22 P1 C6 N2 -87.5(3) . . . . ?
C1 P1 C6 N2 167.7(3) . . . . ?
Ag2 P1 C6 N2 41.5(3) . . . . ?
C22 P1 C6 C63 93.2(3) . . . . ?
C1 P1 C6 C63 -11.5(4) . . . . ?
Ag2 P1 C6 C63 -137.8(3) . . . . ?
C58 N3 C7 C55 -1.4(5) . . . . ?
Ag3 N3 C7 C55 -177.3(3) . . . . ?
C58 N3 C7 P2 174.9(3) . . . . ?
Ag3 N3 C7 P2 -1.0(4) . . . . ?
C13 P2 C7 N3 170.1(3) . . . . ?
C8 P2 C7 N3 -85.6(3) . . . . ?
Ag2 P2 C7 N3 44.8(3) . . . . ?
C13 P2 C7 C55 -13.6(3) . . . . ?
C8 P2 C7 C55 90.7(3) . . . . ?
Ag2 P2 C7 C55 -139.0(3) . . . . ?
C9 N4 C8 C12 -0.4(5) . . . . ?
Ag1 N4 C8 C12 -178.5(3) . . . . ?
C9 N4 C8 P2 176.5(3) . . . . ?
Ag1 N4 C8 P2 -1.7(3) . . . . ?
C7 P2 C8 N4 172.1(3) . . . . ?
C13 P2 C8 N4 -83.6(3) . . . . ?
Ag2 P2 C8 N4 43.6(3) . . . . ?
C7 P2 C8 C12 -11.1(3) . . . . ?
C13 P2 C8 C12 93.2(3) . . . . ?
Ag2 P2 C8 C12 -139.6(3) . . . . ?
C8 N4 C9 C10 0.2(6) . . . . ?
Ag1 N4 C9 C10 178.4(3) . . . . ?
N4 C9 C10 C11 0.6(6) . . . . ?
C9 C10 C11 C12 -1.1(6) . . . . ?
N4 C8 C12 C11 -0.2(6) . . . . ?
P2 C8 C12 C11 -176.7(3) . . . . ?
C10 C11 C12 C8 0.9(6) . . . . ?
C51 N5 C13 C54 -0.1(5) . . . . ?
Ag4 N5 C13 C54 -176.6(3) . . . . ?
C51 N5 C13 P2 177.8(3) . . . . ?
Ag4 N5 C13 P2 1.4(3) . . . . ?
C7 P2 C13 N5 -81.8(3) . . . . ?
C8 P2 C13 N5 174.5(3) . . . . ?
Ag2 P2 C13 N5 44.5(3) . . . . ?
C7 P2 C13 C54 96.1(3) . . . . ?
C8 P2 C13 C54 -7.6(3) . . . . ?
Ag2 P2 C13 C54 -137.6(3) . . . . ?
C50 N6 C14 C47 -1.9(6) . . . . ?
Ag4 N6 C14 C47 179.4(3) . . . . ?
C50 N6 C14 P3 175.3(3) . . . . ?
Ag4 N6 C14 P3 -3.3(4) . . . . ?
C15 P3 C14 N6 175.0(3) . . . . ?
C20 P3 C14 N6 -80.1(3) . . . . ?
Ag2 P3 C14 N6 45.9(3) . . . . ?
C15 P3 C14 C47 -7.8(4) . . . . ?
C20 P3 C14 C47 97.2(4) . . . . ?
Ag2 P3 C14 C47 -136.9(3) . . . . ?
C16 N7 C15 C19 1.2(6) . . . . ?
Ag3 N7 C15 C19 -171.3(3) . . . . ?
C16 N7 C15 P3 178.2(3) . . . . ?
Ag3 N7 C15 P3 5.6(4) . . . . ?
C14 P3 C15 N7 -86.9(3) . . . . ?
C20 P3 C15 N7 168.9(3) . . . . ?
Ag2 P3 C15 N7 43.2(3) . . . . ?
C14 P3 C15 C19 90.0(4) . . . . ?
C20 P3 C15 C19 -14.2(4) . . . . ?
Ag2 P3 C15 C19 -139.8(3) . . . . ?
C15 N7 C16 C17 -0.5(6) . . . . ?
Ag3 N7 C16 C17 172.0(3) . . . . ?
N7 C16 C17 C18 -0.4(7) . . . . ?
C16 C17 C18 C19 0.6(7) . . . . ?
C17 C18 C19 C15 0.2(7) . . . . ?
N7 C15 C19 C18 -1.1(7) . . . . ?
P3 C15 C19 C18 -177.7(4) . . . . ?
C43 N8 C20 C46 1.1(6) . . . . ?
Ag5 N8 C20 C46 -171.7(3) . . . . ?
C43 N8 C20 P3 178.9(3) . . . . ?
Ag5 N8 C20 P3 6.1(4) . . . . ?
C15 P3 C20 N8 -85.7(3) . . . . ?
C14 P3 C20 N8 169.5(3) . . . . ?
Ag2 P3 C20 N8 41.2(3) . . . . ?
C15 P3 C20 C46 92.1(4) . . . . ?
C14 P3 C20 C46 -12.7(4) . . . . ?
Ag2 P3 C20 C46 -141.0(3) . . . . ?
C26 N9 C22 C23 0.1(6) . . . . ?
Ag5 N9 C22 C23 -176.5(3) . . . . ?
C26 N9 C22 P1 177.9(3) . . . . ?
Ag5 N9 C22 P1 1.3(4) . . . . ?
C6 P1 C22 N9 170.1(3) . . . . ?
C1 P1 C22 N9 -85.2(3) . . . . ?
Ag2 P1 C22 N9 44.4(3) . . . . ?
C6 P1 C22 C23 -12.1(4) . . . . ?
C1 P1 C22 C23 92.6(3) . . . . ?
Ag2 P1 C22 C23 -137.8(3) . . . . ?
N9 C22 C23 C24 -0.9(6) . . . . ?
P1 C22 C23 C24 -178.5(3) . . . . ?
C22 C23 C24 C25 1.3(7) . . . . ?
C23 C24 C25 C26 -1.0(8) . . . . ?
C22 N9 C26 C25 0.3(6) . . . . ?
Ag5 N9 C26 C25 176.9(4) . . . . ?
C24 C25 C26 N9 0.1(8) . . . . ?
C42 N10 C28 C39 -0.3(5) . . . . ?
Ag5 N10 C28 C39 -176.3(3) . . . . ?
C42 N10 C28 P4 175.7(3) . . . . ?
Ag5 N10 C28 P4 -0.3(4) . . . . ?
C34 P4 C28 N10 -85.6(3) . . . . ?
C29 P4 C28 N10 169.0(3) . . . . ?
Ag2 P4 C28 N10 42.3(3) . . . . ?
C34 P4 C28 C39 90.4(3) . . . . ?
C29 P4 C28 C39 -15.0(4) . . . . ?
Ag2 P4 C28 C39 -141.8(3) . . . . ?
C30 N11 C29 C33 -0.2(5) . . . . ?
Ag1 N11 C29 C33 -174.4(3) . . . . ?
C30 N11 C29 P4 174.6(3) . . . . ?
Ag1 N11 C29 P4 0.4(4) . . . . ?
C34 P4 C29 N11 169.9(3) . . . . ?
C28 P4 C29 N11 -86.1(3) . . . . ?
Ag2 P4 C29 N11 40.6(3) . . . . ?
C34 P4 C29 C33 -15.4(4) . . . . ?
C28 P4 C29 C33 88.6(3) . . . . ?
Ag2 P4 C29 C33 -144.7(3) . . . . ?
C29 N11 C30 C31 -0.5(6) . . . . ?
Ag1 N11 C30 C31 174.1(3) . . . . ?
N11 C30 C31 C32 0.5(7) . . . . ?
C30 C31 C32 C33 0.2(7) . . . . ?
N11 C29 C33 C32 0.8(6) . . . . ?
P4 C29 C33 C32 -173.4(3) . . . . ?
C31 C32 C33 C29 -0.8(6) . . . . ?
C35 N12 C34 C38 -1.2(6) . . . . ?
Ag4 N12 C34 C38 175.1(3) . . . . ?
C35 N12 C34 P4 179.3(3) . . . . ?
Ag4 N12 C34 P4 -4.4(4) . . . . ?
C29 P4 C34 N12 -85.4(3) . . . . ?
C28 P4 C34 N12 171.3(3) . . . . ?
Ag2 P4 C34 N12 43.7(3) . . . . ?
C29 P4 C34 C38 95.0(3) . . . . ?
C28 P4 C34 C38 -8.3(4) . . . . ?
Ag2 P4 C34 C38 -135.9(3) . . . . ?
C34 N12 C35 C36 0.6(6) . . . . ?
Ag4 N12 C35 C36 -175.8(4) . . . . ?
N12 C35 C36 C37 0.6(8) . . . . ?
C35 C36 C37 C38 -1.3(7) . . . . ?
C36 C37 C38 C34 0.8(7) . . . . ?
N12 C34 C38 C37 0.5(6) . . . . ?
P4 C34 C38 C37 180.0(3) . . . . ?
N10 C28 C39 C40 0.4(6) . . . . ?
P4 C28 C39 C40 -175.2(3) . . . . ?
C28 C39 C40 C41 0.1(7) . . . . ?
C39 C40 C41 C42 -0.7(7) . . . . ?
C28 N10 C42 C41 -0.3(6) . . . . ?
Ag5 N10 C42 C41 175.8(3) . . . . ?
C40 C41 C42 N10 0.8(7) . . . . ?
C20 N8 C43 C44 0.4(6) . . . . ?
Ag5 N8 C43 C44 173.7(3) . . . . ?
N8 C43 C44 C45 -1.9(7) . . . . ?
C43 C44 C45 C46 1.8(7) . . . . ?
N8 C20 C46 C45 -1.0(6) . . . . ?
P3 C20 C46 C45 -178.6(3) . . . . ?
C44 C45 C46 C20 -0.4(7) . . . . ?
N6 C14 C47 C48 2.0(6) . . . . ?
P3 C14 C47 C48 -175.0(3) . . . . ?
C14 C47 C48 C49 -0.7(7) . . . . ?
C47 C48 C49 C50 -0.5(8) . . . . ?
C14 N6 C50 C49 0.6(6) . . . . ?
Ag4 N6 C50 C49 179.3(4) . . . . ?
C48 C49 C50 N6 0.6(7) . . . . ?
C13 N5 C51 C52 0.6(6) . . . . ?
Ag4 N5 C51 C52 177.1(3) . . . . ?
N5 C51 C52 C53 -1.0(7) . . . . ?
C51 C52 C53 C54 0.8(6) . . . . ?
N5 C13 C54 C53 0.0(6) . . . . ?
P2 C13 C54 C53 -177.7(3) . . . . ?
C52 C53 C54 C13 -0.3(6) . . . . ?
N3 C7 C55 C56 0.5(6) . . . . ?
P2 C7 C55 C56 -175.3(3) . . . . ?
C7 C55 C56 C57 -0.3(6) . . . . ?
C55 C56 C57 C58 0.8(7) . . . . ?
C7 N3 C58 C57 2.0(6) . . . . ?
Ag3 N3 C58 C57 178.0(3) . . . . ?
C56 C57 C58 N3 -1.7(7) . . . . ?
C6 N2 C60 C61 1.5(5) . . . . ?
Ag3 N2 C60 C61 177.0(3) . . . . ?
N2 C60 C61 C62 -2.6(6) . . . . ?
C60 C61 C62 C63 1.9(6) . . . . ?
N2 C6 C63 C62 -0.8(6) . . . . ?
P1 C6 C63 C62 178.4(3) . . . . ?
C61 C62 C63 C6 -0.3(6) . . . . ?
C68 N13 C64 C65 0.1(6) . . . . ?
Ag8 N13 C64 C65 -174.5(3) . . . . ?
N13 C64 C65 C66 1.1(7) . . . . ?
C64 C65 C66 C67 -1.4(7) . . . . ?
C65 C66 C67 C68 0.4(6) . . . . ?
C64 N13 C68 C67 -1.1(6) . . . . ?
Ag8 N13 C68 C67 173.2(3) . . . . ?
C64 N13 C68 P5 179.5(3) . . . . ?
Ag8 N13 C68 P5 -6.3(4) . . . . ?
C66 C67 C68 N13 0.8(6) . . . . ?
C66 C67 C68 P5 -179.8(3) . . . . ?
C69 P5 C68 N13 91.0(3) . . . . ?
C123 P5 C68 N13 -163.7(3) . . . . ?
Ag7 P5 C68 N13 -38.3(3) . . . . ?
C69 P5 C68 C67 -88.5(3) . . . . ?
C123 P5 C68 C67 16.9(4) . . . . ?
Ag7 P5 C68 C67 142.3(3) . . . . ?
C119 N14 C69 C122 0.8(5) . . . . ?
Ag9 N14 C69 C122 177.9(3) . . . . ?
C119 N14 C69 P5 -179.7(3) . . . . ?
Ag9 N14 C69 P5 -2.6(4) . . . . ?
C68 P5 C69 N14 -172.1(3) . . . . ?
C123 P5 C69 N14 81.5(3) . . . . ?
Ag7 P5 C69 N14 -44.6(3) . . . . ?
C68 P5 C69 C122 7.4(4) . . . . ?
C123 P5 C69 C122 -98.9(3) . . . . ?
Ag7 P5 C69 C122 135.0(3) . . . . ?
C115 N15 C70 C112 1.3(6) . . . . ?
Ag9 N15 C70 C112 175.4(3) . . . . ?
C115 N15 C70 P6 -177.1(3) . . . . ?
Ag9 N15 C70 P6 -3.0(4) . . . . ?
C71 P6 C70 N15 85.5(3) . . . . ?
C77 P6 C70 N15 -171.2(3) . . . . ?
Ag7 P6 C70 N15 -39.0(3) . . . . ?
C71 P6 C70 C112 -92.9(4) . . . . ?
C77 P6 C70 C112 10.4(4) . . . . ?
Ag7 P6 C70 C112 142.6(3) . . . . ?
C75 N24' C71 C72 0.2(6) . . . . ?
Ag8 N24' C71 C72 177.8(3) . . . . ?
C75 N24' C71 P6 -177.7(3) . . . . ?
Ag8 N24' C71 P6 -0.1(4) . . . . ?
C70 P6 C71 N24' -170.1(3) . . . . ?
C77 P6 C71 N24' 85.8(3) . . . . ?
Ag7 P6 C71 N24' -43.0(3) . . . . ?
C70 P6 C71 C72 12.0(4) . . . . ?
C77 P6 C71 C72 -92.1(3) . . . . ?
Ag7 P6 C71 C72 139.1(3) . . . . ?
N24' C71 C72 C73 0.4(6) . . . . ?
P6 C71 C72 C73 178.1(3) . . . . ?
C71 C72 C73 C74 -0.5(6) . . . . ?
C72 C73 C74 C75 -0.1(7) . . . . ?
C71 N24' C75 C74 -0.9(6) . . . . ?
Ag8 N24' C75 C74 -178.7(3) . . . . ?
C73 C74 C75 N24' 0.8(7) . . . . ?
C108 N16 C77 C111 1.0(6) . . . . ?
Ag10 N16 C77 C111 -179.2(3) . . . . ?
C108 N16 C77 P6 -176.4(3) . . . . ?
Ag10 N16 C77 P6 3.4(4) . . . . ?
C71 P6 C77 N16 -166.6(3) . . . . ?
C70 P6 C77 N16 88.5(3) . . . . ?
Ag7 P6 C77 N16 -42.1(3) . . . . ?
C71 P6 C77 C111 16.0(4) . . . . ?
C70 P6 C77 C111 -88.9(4) . . . . ?
Ag7 P6 C77 C111 140.4(3) . . . . ?
C92 N17 C78 C89 0.0(6) . . . . ?
Ag10 N17 C78 C89 -179.1(3) . . . . ?
C92 N17 C78 P7 177.6(3) . . . . ?
Ag10 N17 C78 P7 -1.6(4) . . . . ?
C79 P7 C78 N17 85.8(3) . . . . ?
C84 P7 C78 N17 -170.6(3) . . . . ?
Ag7 P7 C78 N17 -41.6(3) . . . . ?
C79 P7 C78 C89 -96.6(4) . . . . ?
C84 P7 C78 C89 7.0(4) . . . . ?
Ag7 P7 C78 C89 135.9(3) . . . . ?
C80 N18 C79 C83 0.5(5) . . . . ?
Ag6 N18 C79 C83 -179.3(3) . . . . ?
C80 N18 C79 P7 -175.6(3) . . . . ?
Ag6 N18 C79 P7 4.6(4) . . . . ?
C78 P7 C79 N18 -169.8(3) . . . . ?
C84 P7 C79 N18 85.5(3) . . . . ?
Ag7 P7 C79 N18 -44.0(3) . . . . ?
C78 P7 C79 C83 14.2(4) . . . . ?
C84 P7 C79 C83 -90.5(3) . . . . ?
Ag7 P7 C79 C83 140.0(3) . . . . ?
C79 N18 C80 C81 -1.0(6) . . . . ?
Ag6 N18 C80 C81 178.8(3) . . . . ?
N18 C80 C81 C82 1.0(7) . . . . ?
C80 C81 C82 C83 -0.4(7) . . . . ?
N18 C79 C83 C82 0.0(6) . . . . ?
P7 C79 C83 C82 175.7(3) . . . . ?
C81 C82 C83 C79 0.0(6) . . . . ?
C85 N19 C84 C88 0.5(5) . . . . ?
Ag9 N19 C84 C88 177.2(3) . . . . ?
C85 N19 C84 P7 -178.8(3) . . . . ?
Ag9 N19 C84 P7 -2.1(4) . . . . ?
C79 P7 C84 N19 -167.1(3) . . . . ?
C78 P7 C84 N19 86.1(3) . . . . ?
Ag7 P7 C84 N19 -39.4(3) . . . . ?
C79 P7 C84 C88 13.6(4) . . . . ?
C78 P7 C84 C88 -93.2(3) . . . . ?
Ag7 P7 C84 C88 141.3(3) . . . . ?
C84 N19 C85 C86 -0.5(6) . . . . ?
Ag9 N19 C85 C86 -177.4(3) . . . . ?
N19 C85 C86 C87 0.3(6) . . . . ?
C85 C86 C87 C88 -0.1(6) . . . . ?
N19 C84 C88 C87 -0.2(6) . . . . ?
P7 C84 C88 C87 179.0(3) . . . . ?
C86 C87 C88 C84 0.0(6) . . . . ?
N17 C78 C89 C90 0.2(6) . . . . ?
P7 C78 C89 C90 -177.1(3) . . . . ?
C78 C89 C90 C91 0.0(7) . . . . ?
C89 C90 C91 C92 -0.4(7) . . . . ?
C78 N17 C92 C91 -0.4(6) . . . . ?
Ag10 N17 C92 C91 178.8(3) . . . . ?
C90 C91 C92 N17 0.7(7) . . . . ?
C97 N20 C93 C94 -0.2(5) . . . . ?
Ag10 N20 C93 C94 -178.1(3) . . . . ?
N20 C93 C94 C95 1.2(6) . . . . ?
C93 C94 C95 C96 -1.2(6) . . . . ?
C94 C95 C96 C97 0.3(6) . . . . ?
C93 N20 C97 C96 -0.7(5) . . . . ?
Ag10 N20 C97 C96 177.1(3) . . . . ?
C93 N20 C97 P8 179.5(3) . . . . ?
Ag10 N20 C97 P8 -2.7(3) . . . . ?
C95 C96 C97 N20 0.7(6) . . . . ?
C95 C96 C97 P8 -179.6(3) . . . . ?
C103 P8 C97 N20 -175.6(3) . . . . ?
C98 P8 C97 N20 77.9(3) . . . . ?
Ag7 P8 C97 N20 -47.0(3) . . . . ?
C103 P8 C97 C96 4.7(4) . . . . ?
C98 P8 C97 C96 -101.9(3) . . . . ?
Ag7 P8 C97 C96 133.2(3) . . . . ?
C99 N21 C98 C102 -0.1(5) . . . . ?
Ag8 N21 C98 C102 176.6(3) . . . . ?
C99 N21 C98 P8 178.6(3) . . . . ?
Ag8 N21 C98 P8 -4.8(3) . . . . ?
C97 P8 C98 N21 -170.7(3) . . . . ?
C103 P8 C98 N21 85.1(3) . . . . ?
Ag7 P8 C98 N21 -45.2(3) . . . . ?
C97 P8 C98 C102 7.9(4) . . . . ?
C103 P8 C98 C102 -96.3(3) . . . . ?
Ag7 P8 C98 C102 133.4(3) . . . . ?
C98 N21 C99 C100 -1.6(6) . . . . ?
Ag8 N21 C99 C100 -178.2(3) . . . . ?
N21 C99 C100 C101 2.0(6) . . . . ?
C99 C100 C101 C102 -0.7(6) . . . . ?
N21 C98 C102 C101 1.3(6) . . . . ?
P8 C98 C102 C101 -177.2(3) . . . . ?
C100 C101 C102 C98 -0.8(6) . . . . ?
C104 N22 C103 C107 0.7(6) . . . . ?
Ag6 N22 C103 C107 177.0(3) . . . . ?
C104 N22 C103 P8 -176.0(3) . . . . ?
Ag6 N22 C103 P8 0.3(4) . . . . ?
C97 P8 C103 N22 83.9(3) . . . . ?
C98 P8 C103 N22 -171.2(3) . . . . ?
Ag7 P8 C103 N22 -43.1(3) . . . . ?
C97 P8 C103 C107 -92.8(3) . . . . ?
C98 P8 C103 C107 12.1(4) . . . . ?
Ag7 P8 C103 C107 140.3(3) . . . . ?
C103 N22 C104 C105 0.0(6) . . . . ?
Ag6 N22 C104 C105 -176.4(3) . . . . ?
N22 C104 C105 C106 -0.8(7) . . . . ?
C104 C105 C106 C107 0.9(7) . . . . ?
N22 C103 C107 C106 -0.6(6) . . . . ?
P8 C103 C107 C106 175.7(3) . . . . ?
C105 C106 C107 C103 -0.2(6) . . . . ?
C77 N16 C108 C109 -0.9(6) . . . . ?
Ag10 N16 C108 C109 179.3(3) . . . . ?
N16 C108 C109 C110 -0.1(7) . . . . ?
C108 C109 C110 C111 1.0(7) . . . . ?
N16 C77 C111 C110 -0.2(6) . . . . ?
P6 C77 C111 C110 177.0(3) . . . . ?
C109 C110 C111 C77 -0.9(7) . . . . ?
N15 C70 C112 C113 -1.5(7) . . . . ?
P6 C70 C112 C113 176.8(4) . . . . ?
C70 C112 C113 C114 0.7(7) . . . . ?
C112 C113 C114 C115 0.3(8) . . . . ?
C70 N15 C115 C114 -0.3(7) . . . . ?
Ag9 N15 C115 C114 -174.9(4) . . . . ?
C113 C114 C115 N15 -0.5(8) . . . . ?
C69 N14 C119 C120 -1.1(6) . . . . ?
Ag9 N14 C119 C120 -178.3(3) . . . . ?
N14 C119 C120 C121 1.1(6) . . . . ?
C119 C120 C121 C122 -0.6(6) . . . . ?
N14 C69 C122 C121 -0.3(6) . . . . ?
P5 C69 C122 C121 -179.8(3) . . . . ?
C120 C121 C122 C69 0.2(6) . . . . ?
C124 N23 C123 C127 -0.7(6) . . . . ?
Ag6 N23 C123 C127 170.6(3) . . . . ?
C124 N23 C123 P5 178.4(3) . . . . ?
Ag6 N23 C123 P5 -10.3(4) . . . . ?
C68 P5 C123 N23 85.4(3) . . . . ?
C69 P5 C123 N23 -168.5(3) . . . . ?
Ag7 P5 C123 N23 -40.3(3) . . . . ?
C68 P5 C123 C127 -95.6(4) . . . . ?
C69 P5 C123 C127 10.5(4) . . . . ?
Ag7 P5 C123 C127 138.7(3) . . . . ?
C123 N23 C124 C125 0.8(6) . . . . ?
Ag6 N23 C124 C125 -170.6(3) . . . . ?
N23 C124 C125 C126 0.0(7) . . . . ?
C124 C125 C126 C127 -1.0(7) . . . . ?
N23 C123 C127 C126 -0.3(6) . . . . ?
P5 C123 C127 C126 -179.3(4) . . . . ?
C125 C126 C127 C123 1.2(7) . . . . ?
O1A C13A C14A C15A -142(3) . . . . ?
O1A C13A C15A C14A 156.3(19) . . . . ?

_refine_diff_density_max         1.393
_refine_diff_density_min         -1.537
_refine_diff_density_rms         0.100

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_comp1_b53
_database_code_depnum_ccdc_archive 'CCDC 1472281'
_audit_update_record             
;
2017-08-16 deposited with the CCDC.
2017-08-24 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
;
 Complex of AgOTf with tris(2-pyridyl)phosphine  
;
_chemical_name_common            ?
_chemical_melting_point          527-565
_chemical_formula_moiety         
;
 C64 H47 Ag5 F12 N12 O12 P4 S4, C F3 O3 S, 6(C3 H6 O)
;
_chemical_formula_sum            'C83 H83 Ag5 F15 N12 O21 P4 S5'
_chemical_formula_weight         2693.14

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   16.4246(7)
_cell_length_b                   22.9762(11)
_cell_length_c                   28.4848(11)
_cell_angle_alpha                90
_cell_angle_beta                 105.155(2)
_cell_angle_gamma                90
_cell_volume                     10375.6(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9413
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      29.93

_exptl_crystal_description       prism
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_F_000             5372
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.600
_exptl_crystal_size_mid          0.600
_exptl_crystal_size_min          0.400
_exptl_absorpt_coefficient_mu    1.187
_shelx_estimated_absorpt_T_min   0.536
_shelx_estimated_absorpt_T_max   0.648
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5930
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            93670
_diffrn_reflns_av_unetI/netI     0.0334
_diffrn_reflns_av_R_equivalents  0.0338
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         3.038
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_full        25.000
_diffrn_measured_fraction_theta_max 0.949
_diffrn_measured_fraction_theta_full 0.984
_diffrn_reflns_Laue_measured_fraction_max 0.949
_diffrn_reflns_Laue_measured_fraction_full 0.984
_diffrn_reflns_point_group_measured_fraction_max 0.949
_diffrn_reflns_point_group_measured_fraction_full 0.984
_reflns_number_total             22569
_reflns_number_gt                17200
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0058P)²+115.6130P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         22569
_refine_ls_number_parameters     1372
_refine_ls_number_restraints     67
_refine_ls_R_factor_all          0.0954
_refine_ls_R_factor_gt           0.0641
_refine_ls_wR_factor_ref         0.1457
_refine_ls_wR_factor_gt          0.1222
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_restrained_S_all      1.101
_refine_ls_shift/su_max          0.021
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.25143(3) 0.76499(2) 0.11008(2) 0.03745(12) Uani 1 1 d . . . . .
Ag2 Ag 1.06439(3) 0.75813(2) 0.12006(2) 0.02643(10) Uani 1 1 d . . . . .
Ag3 Ag 1.06379(3) 0.70509(2) 0.22247(2) 0.03599(12) Uani 1 1 d . . . . .
Ag4 Ag 1.00145(3) 0.88510(2) 0.11817(2) 0.03321(12) Uani 1 1 d . . . . .
Ag5 Ag 0.94525(3) 0.69178(2) 0.03266(2) 0.03733(12) Uani 1 1 d . . . . .
P4 P 1.11920(10) 0.65275(7) 0.12385(6) 0.0280(3) Uani 1 1 d . . . . .
P1 P 1.15832(9) 0.81755(7) 0.19067(6) 0.0278(3) Uani 1 1 d . . . . .
P2 P 0.91036(9) 0.75622(7) 0.12903(6) 0.0267(3) Uani 1 1 d . . . . .
P3 P 1.06952(9) 0.80367(7) 0.03719(6) 0.0267(3) Uani 1 1 d . . . . .
N12 N 1.1756(3) 0.6460(2) 0.22082(19) 0.0327(12) Uani 1 1 d . . . . .
N11 N 1.1386(3) 0.9165(2) 0.1400(2) 0.0327(12) Uani 1 1 d . . . . .
N8 N 0.9221(3) 0.8615(2) 0.17079(19) 0.0317(12) Uani 1 1 d . . . . .
N7 N 0.8328(3) 0.7485(2) 0.03391(18) 0.0298(11) Uani 1 1 d . . . . .
N5 N 1.0414(3) 0.7035(2) -0.01099(19) 0.0337(12) Uani 1 1 d . . . . .
N3 N 0.9378(3) 0.8722(2) 0.03654(19) 0.0294(11) Uani 1 1 d . . . . .
C73 C 0.8652(4) 0.9000(3) 0.0181(3) 0.0365(15) Uani 1 1 d . . . . .
H73A H 0.8424 0.9235 0.0390 0.044 Uiso 1 1 calc R U . . .
N1 N 1.2248(3) 0.8490(2) 0.0663(2) 0.0322(12) Uani 1 1 d . . . . .
C72 C 0.6871(4) 0.8082(3) 0.0359(3) 0.0359(15) Uani 1 1 d . . . . .
H72D H 0.6375 0.8292 0.0366 0.043 Uiso 1 1 calc R U . . .
C71 C 1.1604(4) 0.9678(3) 0.1254(3) 0.0386(15) Uani 1 1 d . . . . .
H71A H 1.1202 0.9884 0.1011 0.046 Uiso 1 1 calc R U . . .
C70 C 1.1940(4) 0.6283(3) 0.1799(2) 0.0296(13) Uani 1 1 d . . . . .
N2 N 1.0753(3) 0.7953(3) 0.2568(2) 0.0373(13) Uani 1 1 d . . . . .
C69 C 0.8880(4) 0.8088(3) 0.1725(2) 0.0283(13) Uani 1 1 d . . . . .
N4 N 0.9349(3) 0.6646(3) 0.1883(2) 0.0355(12) Uani 1 1 d . . . . .
C68 C 0.8226(4) 0.7706(3) 0.0755(2) 0.0273(12) Uani 1 1 d . . . . .
N6 N 0.9688(3) 0.6080(3) 0.0778(2) 0.0384(13) Uani 1 1 d . . . . .
C67 C 0.9708(4) 0.8403(3) 0.0066(2) 0.0270(12) Uani 1 1 d . . . . .
C66 C 1.1482(4) 0.8598(3) 0.0357(2) 0.0291(13) Uani 1 1 d . . . . .
N9 N 1.2959(3) 0.7560(2) 0.1931(2) 0.0335(12) Uani 1 1 d . . . . .
C65 C 1.2764(5) 0.6646(4) 0.0400(3) 0.0490(19) Uani 1 1 d . . . . .
C5 C 1.0421(5) 0.8055(4) 0.2944(3) 0.0508(19) Uani 1 1 d . . . . .
H5 H 1.0153 0.7746 0.3067 0.061 Uiso 1 1 calc R U . . .
C6 C 1.0458(6) 0.8602(5) 0.3158(3) 0.063(2) Uani 1 1 d . . . . .
H6 H 1.0223 0.8662 0.3425 0.075 Uiso 1 1 calc R U . . .
C7 C 1.0836(6) 0.9053(4) 0.2981(3) 0.065(3) Uani 1 1 d . . . . .
H7 H 1.0866 0.9430 0.3122 0.078 Uiso 1 1 calc R U . . .
C8 C 1.1172(5) 0.8948(3) 0.2592(3) 0.0463(18) Uani 1 1 d . . . . .
H8 H 1.1431 0.9254 0.2460 0.056 Uiso 1 1 calc R U . . .
C9 C 1.1130(4) 0.8395(3) 0.2398(2) 0.0337(14) Uani 1 1 d . . . . .
C10 C 1.1969(4) 0.8869(3) 0.1733(2) 0.0335(14) Uani 1 1 d . . . . .
C11 C 0.9046(5) 0.9029(3) 0.1995(3) 0.0412(16) Uani 1 1 d . . . . .
H11 H 0.9288 0.9403 0.1988 0.049 Uiso 1 1 calc R U . . .
C12 C 0.8525(5) 0.8940(4) 0.2306(3) 0.0454(18) Uani 1 1 d . . . . .
H12 H 0.8411 0.9246 0.2504 0.055 Uiso 1 1 calc R U . . .
C13 C 0.8180(4) 0.8390(4) 0.2318(3) 0.0436(18) Uani 1 1 d . . . . .
H13 H 0.7821 0.8312 0.2523 0.052 Uiso 1 1 calc R U . . .
C14 C 0.8367(4) 0.7962(3) 0.2028(2) 0.0376(15) Uani 1 1 d . . . . .
H14 H 0.8146 0.7581 0.2035 0.045 Uiso 1 1 calc R U . . .
C15 C 0.8780(4) 0.6870(3) 0.1509(2) 0.0289(13) Uani 1 1 d . . . . .
C16 C 0.9168(5) 0.6145(4) 0.2073(3) 0.0486(19) Uani 1 1 d . . . . .
H16 H 0.9569 0.5984 0.2345 0.058 Uiso 1 1 calc R U . . .
C17 C 0.8411(5) 0.5854(4) 0.1887(3) 0.057(2) Uani 1 1 d . . . . .
H17 H 0.8296 0.5498 0.2027 0.068 Uiso 1 1 calc R U . . .
C18 C 0.7830(5) 0.6090(4) 0.1494(3) 0.056(2) Uani 1 1 d . . . . .
H18 H 0.7309 0.5897 0.1357 0.067 Uiso 1 1 calc R U . . .
C19 C 0.8012(4) 0.6603(3) 0.1303(3) 0.0409(16) Uani 1 1 d . . . . .
H19 H 0.7619 0.6776 0.1034 0.049 Uiso 1 1 calc R U . . .
C20 C 0.9075(5) 0.5682(4) 0.0682(3) 0.057(2) Uani 1 1 d . . . . .
H20 H 0.8586 0.5758 0.0426 0.069 Uiso 1 1 calc R U . . .
C21 C 0.9112(6) 0.5177(4) 0.0930(3) 0.062(2) Uani 1 1 d . . . . .
H21 H 0.8660 0.4906 0.0847 0.075 Uiso 1 1 calc R U . . .
C22 C 0.9812(7) 0.5060(4) 0.1305(3) 0.067(3) Uani 1 1 d . . . . .
H22 H 0.9850 0.4708 0.1484 0.080 Uiso 1 1 calc R U . . .
C23 C 1.0461(5) 0.5464(3) 0.1417(3) 0.050(2) Uani 1 1 d . . . . .
H23 H 1.0950 0.5397 0.1677 0.061 Uiso 1 1 calc R U . . .
C24 C 1.0378(4) 0.5957(3) 0.1145(3) 0.0356(15) Uani 1 1 d . . . . .
C25 C 1.0849(4) 0.7533(3) -0.0096(2) 0.0323(14) Uani 1 1 d . . . . .
C26 C 0.8221(4) 0.8958(3) -0.0305(3) 0.0417(17) Uani 1 1 d . . . . .
H26 H 0.7696 0.9150 -0.0425 0.050 Uiso 1 1 calc R U . . .
C27 C 0.8563(5) 0.8633(4) -0.0610(3) 0.0478(19) Uani 1 1 d . . . . .
H27 H 0.8286 0.8606 -0.0947 0.057 Uiso 1 1 calc R U . . .
C28 C 0.9310(4) 0.8348(3) -0.0423(2) 0.0379(15) Uani 1 1 d . . . . .
H28 H 0.9551 0.8115 -0.0627 0.046 Uiso 1 1 calc R U . . .
C29 C 1.2864(4) 0.8868(3) 0.0655(3) 0.0417(16) Uani 1 1 d . . . . .
H29 H 1.3403 0.8806 0.0873 0.050 Uiso 1 1 calc R U . . .
C30 C 1.2759(5) 0.9342(3) 0.0347(3) 0.051(2) Uani 1 1 d . . . . .
H30 H 1.3219 0.9594 0.0350 0.061 Uiso 1 1 calc R U . . .
C31 C 1.1972(4) 0.9444(3) 0.0035(3) 0.0375(15) Uani 1 1 d . . . . .
H31 H 1.1880 0.9770 -0.0177 0.045 Uiso 1 1 calc R U . . .
C32 C 1.1328(4) 0.9066(3) 0.0039(3) 0.0378(15) Uani 1 1 d . . . . .
H32 H 1.0784 0.9124 -0.0174 0.045 Uiso 1 1 calc R U . . .
C33 C 1.1356(5) 0.7639(4) -0.0403(3) 0.0452(17) Uani 1 1 d . . . . .
H33 H 1.1652 0.7997 -0.0390 0.054 Uiso 1 1 calc R U . . .
C34 C 1.1421(6) 0.7205(5) -0.0733(3) 0.067(3) Uani 1 1 d . . . . .
H34 H 1.1773 0.7261 -0.0946 0.080 Uiso 1 1 calc R U . . .
C35 C 1.0979(5) 0.6702(4) -0.0748(3) 0.057(2) Uani 1 1 d . . . . .
H35 H 1.1015 0.6405 -0.0974 0.069 Uiso 1 1 calc R U . . .
C36 C 1.0481(5) 0.6628(4) -0.0435(3) 0.0475(18) Uani 1 1 d . . . . .
H36 H 1.0173 0.6276 -0.0449 0.057 Uiso 1 1 calc R U . . .
O1 O 0.8493(5) 0.6392(3) -0.0415(2) 0.083(2) Uani 1 1 d . . . . .
C45 C 0.7694(5) 0.7554(3) -0.0065(2) 0.0394(16) Uani 1 1 d . . . . .
H45 H 0.7753 0.7391 -0.0360 0.047 Uiso 1 1 calc R U . . .
C46 C 0.6963(4) 0.7848(3) -0.0070(3) 0.0415(17) Uani 1 1 d . . . . .
H46 H 0.6529 0.7890 -0.0363 0.050 Uiso 1 1 calc R U . . .
C47 C 0.7508(4) 0.8007(3) 0.0777(3) 0.0378(15) Uani 1 1 d . . . . .
H47 H 0.7455 0.8160 0.1078 0.045 Uiso 1 1 calc R U . . .
C48 C 1.2389(5) 0.9922(3) 0.1441(3) 0.0477(18) Uani 1 1 d . . . . .
H48 H 1.2518 1.0293 0.1332 0.057 Uiso 1 1 calc R U . . .
C49 C 1.2989(5) 0.9623(3) 0.1791(3) 0.053(2) Uani 1 1 d . . . . .
H49 H 1.3532 0.9784 0.1928 0.063 Uiso 1 1 calc R U . . .
C50 C 1.2772(4) 0.9087(3) 0.1932(3) 0.0454(18) Uani 1 1 d . . . . .
H50 H 1.3171 0.8866 0.2165 0.054 Uiso 1 1 calc R U . . .
C51 C 1.2561(4) 0.7813(3) 0.2233(2) 0.0330(14) Uani 1 1 d . . . . .
C52 C 1.3681(5) 0.7284(3) 0.2128(3) 0.051(2) Uani 1 1 d . . . . .
H52 H 1.3970 0.7106 0.1917 0.061 Uiso 1 1 calc R U . . .
C53 C 1.4030(5) 0.7246(4) 0.2621(3) 0.061(2) Uani 1 1 d . . . . .
H53 H 1.4542 0.7041 0.2747 0.073 Uiso 1 1 calc R U . . .
C54 C 1.3623(5) 0.7512(4) 0.2931(3) 0.059(2) Uani 1 1 d . . . . .
H54 H 1.3857 0.7503 0.3273 0.071 Uiso 1 1 calc R U . . .
C55 C 1.2866(5) 0.7791(4) 0.2732(3) 0.0470(18) Uani 1 1 d . . . . .
H55 H 1.2561 0.7966 0.2936 0.056 Uiso 1 1 calc R U . . .
C57 C 1.2255(4) 0.6278(3) 0.2637(3) 0.0423(17) Uani 1 1 d . . . . .
H57 H 1.2120 0.6392 0.2928 0.051 Uiso 1 1 calc R U . . .
C58 C 1.2959(4) 0.5931(4) 0.2669(3) 0.0493(19) Uani 1 1 d . . . . .
H58 H 1.3305 0.5815 0.2977 0.059 Uiso 1 1 calc R U . . .
C59 C 1.3147(4) 0.5758(3) 0.2246(3) 0.0450(18) Uani 1 1 d . . . . .
H59 H 1.3631 0.5525 0.2258 0.054 Uiso 1 1 calc R U . . .
C60 C 1.2627(4) 0.5925(3) 0.1809(3) 0.0413(16) Uani 1 1 d . . . . .
H60 H 1.2734 0.5797 0.1514 0.050 Uiso 1 1 calc R U . . .
C61 C 1.1754(4) 0.6344(3) 0.0781(2) 0.0341(14) Uani 1 1 d . . . . .
N10 N 1.2290(3) 0.6760(2) 0.0714(2) 0.0347(12) Uani 1 1 d . . . . .
C63 C 1.2708(6) 0.6128(4) 0.0155(3) 0.061(2) Uani 1 1 d . . . . .
H63 H 1.3054 0.6056 -0.0058 0.074 Uiso 1 1 calc R U . . .
C64 C 1.2141(6) 0.5711(4) 0.0223(3) 0.054(2) Uani 1 1 d . . . . .
H64 H 1.2080 0.5354 0.0049 0.065 Uiso 1 1 calc R U . . .
C62 C 1.1673(5) 0.5820(3) 0.0542(3) 0.0443(17) Uani 1 1 d . . . . .
H62 H 1.1292 0.5534 0.0600 0.053 Uiso 1 1 calc R U . . .
S1T S 1.47480(13) 0.79641(11) 0.12003(9) 0.0575(5) Uani 1 1 d . . . . .
C1T C 1.5694(5) 0.7585(5) 0.1543(4) 0.073(3) Uani 1 1 d . . . . .
O1T O 1.5035(5) 0.8270(4) 0.0843(3) 0.102(3) Uani 1 1 d . . . . .
O2T O 1.4530(4) 0.8328(4) 0.1561(3) 0.087(2) Uani 1 1 d . . . . .
O3T O 1.4146(4) 0.7523(3) 0.1043(2) 0.0748(19) Uani 1 1 d . . . . .
F1T F 1.6291(4) 0.7967(3) 0.1733(3) 0.118(3) Uani 1 1 d . . . . .
F2T F 1.5532(4) 0.7264(4) 0.1890(3) 0.125(3) Uani 1 1 d . . . . .
F3T F 1.6006(4) 0.7255(3) 0.1264(3) 0.123(3) Uani 1 1 d . . . . .
S2T S 0.98182(12) 1.03863(8) 0.14078(7) 0.0455(4) Uani 1 1 d . . . . .
O4T O 1.0266(3) 1.0189(3) 0.1883(2) 0.0606(16) Uani 1 1 d . . . . .
O5T O 1.0261(5) 1.0782(3) 0.1183(3) 0.091(2) Uani 1 1 d . . . . .
O6T O 0.9374(4) 0.9933(2) 0.1104(2) 0.0565(15) Uani 1 1 d . . . . .
C2T C 0.8987(6) 1.0833(4) 0.1527(4) 0.066(2) Uani 1 1 d . . . . .
F4T F 0.8521(4) 1.0536(3) 0.1760(3) 0.099(2) Uani 1 1 d . . . . .
F5T F 0.8479(4) 1.1039(3) 0.1120(2) 0.102(2) Uani 1 1 d . . . . .
F6T F 0.9292(5) 1.1274(3) 0.1815(3) 0.122(3) Uani 1 1 d . . . . .
S3T S 1.08682(12) 0.65481(11) 0.35549(7) 0.0534(5) Uani 1 1 d . . . . .
O7T O 1.0539(4) 0.6961(3) 0.3831(2) 0.0732(18) Uani 1 1 d . . . . .
O8T O 1.1761(4) 0.6457(4) 0.3698(2) 0.095(3) Uani 1 1 d . . . . .
O9T O 1.0514(4) 0.6582(3) 0.30386(19) 0.0679(19) Uani 1 1 d . . . . .
C3T C 1.0476(7) 0.5866(5) 0.3713(4) 0.073(3) Uani 1 1 d . . . . .
F7T F 0.9658(4) 0.5852(3) 0.3616(3) 0.094(2) Uani 1 1 d . . . . .
F8T F 1.0710(6) 0.5430(4) 0.3491(4) 0.148(4) Uani 1 1 d . . . . .
F9T F 1.0780(5) 0.5776(4) 0.4198(3) 0.119(3) Uani 1 1 d . . . . .
O1A O 0.5757(6) 0.4594(4) -0.1477(4) 0.114(3) Uani 1 1 d . . . . .
C1AA C 0.5101(7) 0.4373(5) -0.1494(4) 0.076(3) Uani 1 1 d . . . . .
C2A C 0.4955(10) 0.4107(7) -0.1039(5) 0.128(6) Uani 1 1 d . . . . .
H2AA H 0.5076 0.3689 -0.1034 0.193 Uiso 1 1 calc R U . . .
H2AB H 0.4366 0.4166 -0.1034 0.193 Uiso 1 1 calc R U . . .
H2AC H 0.5328 0.4292 -0.0752 0.193 Uiso 1 1 calc R U . . .
C3A C 0.4388(10) 0.4354(7) -0.1941(5) 0.122(5) Uani 1 1 d . . . . .
H3AA H 0.4532 0.4585 -0.2197 0.183 Uiso 1 1 calc R U . . .
H3AB H 0.3881 0.4515 -0.1870 0.183 Uiso 1 1 calc R U . . .
H3AC H 0.4282 0.3950 -0.2050 0.183 Uiso 1 1 calc R U . . .
O3A O 0.6859(6) 0.9596(4) 0.0345(3) 0.099(3) Uani 1 1 d . . . . .
C9A C 0.5629(8) 0.9622(7) 0.0608(6) 0.124(5) Uani 1 1 d . . . . .
H9AA H 0.5470 0.9995 0.0725 0.187 Uiso 1 1 calc R U . . .
H9AB H 0.5459 0.9304 0.0790 0.187 Uiso 1 1 calc R U . . .
H9AC H 0.5347 0.9579 0.0261 0.187 Uiso 1 1 calc R U . . .
C7A C 0.6542(6) 0.9605(4) 0.0678(4) 0.062(2) Uani 1 1 d . . . . .
C8A C 0.7035(10) 0.9560(8) 0.1180(5) 0.141(6) Uani 1 1 d . . . . .
H8AA H 0.6746 0.9304 0.1359 0.211 Uiso 1 1 calc R U . . .
H8AB H 0.7101 0.9948 0.1329 0.211 Uiso 1 1 calc R U . . .
H8AC H 0.7592 0.9400 0.1190 0.211 Uiso 1 1 calc R U . . .
O2A O 0.3113(7) 0.7930(7) -0.0358(8) 0.267(10) Uani 1 1 d D . . . .
C6A C 0.4453(10) 0.7517(7) -0.0269(7) 0.149(7) Uani 1 1 d D . . . .
H6AA H 0.4830 0.7542 0.0060 0.224 Uiso 1 1 calc R U . . .
H6AB H 0.4786 0.7546 -0.0508 0.224 Uiso 1 1 calc R U . . .
H6AC H 0.4154 0.7144 -0.0309 0.224 Uiso 1 1 calc R U . . .
C4A C 0.3839(7) 0.7996(6) -0.0344(5) 0.111(5) Uani 1 1 d D . . . .
C5A C 0.4184(10) 0.8585(6) -0.0339(5) 0.128(6) Uani 1 1 d D . . . .
H5AA H 0.3723 0.8861 -0.0462 0.192 Uiso 1 1 calc R U . . .
H5AB H 0.4575 0.8597 -0.0546 0.192 Uiso 1 1 calc R U . . .
H5AC H 0.4485 0.8690 -0.0005 0.192 Uiso 1 1 calc R U . . .
O5A O 0.9790(6) 0.5346(6) -0.2409(3) 0.133(4) Uani 1 1 d . . . . .
C15A C 1.0273(10) 0.6296(7) -0.2250(5) 0.125(6) Uani 1 1 d . . . . .
H1AA H 1.0072 0.6590 -0.2504 0.187 Uiso 1 1 calc R U . . .
H1AB H 1.0852 0.6389 -0.2068 0.187 Uiso 1 1 calc R U . . .
H1AC H 0.9908 0.6294 -0.2028 0.187 Uiso 1 1 calc R U . . .
C13A C 1.0256(8) 0.5731(7) -0.2472(4) 0.089(4) Uani 1 1 d . . . . .
C14A C 1.0844(8) 0.5623(6) -0.2780(5) 0.103(4) Uani 1 1 d . . . . .
H4AA H 1.0838 0.5209 -0.2862 0.154 Uiso 1 1 calc R U . . .
H4AB H 1.1416 0.5739 -0.2603 0.154 Uiso 1 1 calc R U . . .
H4AC H 1.0665 0.5852 -0.3080 0.154 Uiso 1 1 calc R U . . .
C12A C 1.1108(13) 0.9611(7) 0.4831(10) 0.212(11) Uani 1 1 d D . . . .
H7AA H 1.0524 0.9682 0.4840 0.318 Uiso 1 1 calc R U . . .
H7AB H 1.1161 0.9677 0.4500 0.318 Uiso 1 1 calc R U . . .
H7AC H 1.1485 0.9877 0.5056 0.318 Uiso 1 1 calc R U . . .
O4A O 1.1839(10) 0.8882(11) 0.5337(4) 0.306(14) Uani 1 1 d D . . . .
C10A C 1.1340(8) 0.9008(8) 0.4975(4) 0.124(6) Uani 1 1 d D U . . .
C11A C 1.1003(13) 0.8587(9) 0.4589(8) 0.222(11) Uani 1 1 d D U . . .
H1AD H 1.0942 0.8773 0.4272 0.333 Uiso 1 1 calc R U . . .
H1AE H 1.0451 0.8450 0.4614 0.333 Uiso 1 1 calc R U . . .
H1AF H 1.1390 0.8256 0.4621 0.333 Uiso 1 1 calc R U . . .
S4T S 0.7301(2) 0.42160(16) 0.14396(13) 0.0921(9) Uani 1 1 d D U . . .
O10T O 0.6977(13) 0.3627(4) 0.1533(7) 0.257(6) Uani 1 1 d D U . . .
O12T O 0.7908(7) 0.4195(6) 0.1201(5) 0.178(6) Uani 1 1 d D . . . .
O11T O 0.7289(6) 0.4573(5) 0.1837(3) 0.128(4) Uani 1 1 d D . . . .
C4T C 0.6300(6) 0.4266(6) 0.1051(4) 0.195(6) Uani 1 1 d D U . . .
F12T F 0.5713(6) 0.4297(7) 0.1251(4) 0.254(7) Uani 1 1 d D U . . .
F11T F 0.6168(8) 0.3909(7) 0.0706(4) 0.291(9) Uani 1 1 d D U . . .
F10T F 0.6474(13) 0.4777(6) 0.0911(7) 0.345(10) Uani 1 1 d D U . . .
O6A O 0.7607(7) 0.1913(5) 0.2549(4) 0.135(4) Uani 1 1 d D . . . .
C16A C 0.7419(8) 0.2005(8) 0.2117(5) 0.125(6) Uani 1 1 d D U . . .
C17A C 0.6616(12) 0.1997(12) 0.1749(8) 0.254(12) Uani 1 1 d D U . . .
H17D H 0.6408 0.1596 0.1698 0.381 Uiso 1 1 calc R U . . .
H17E H 0.6692 0.2152 0.1443 0.381 Uiso 1 1 calc R U . . .
H17F H 0.6206 0.2236 0.1857 0.381 Uiso 1 1 calc R U . . .
C18A C 0.8031(13) 0.2310(9) 0.1907(8) 0.202(11) Uani 1 1 d D . . . .
H18D H 0.7863 0.2719 0.1849 0.302 Uiso 1 1 calc R U . . .
H18E H 0.8043 0.2126 0.1599 0.302 Uiso 1 1 calc R U . . .
H18F H 0.8593 0.2289 0.2135 0.302 Uiso 1 1 calc R U . . .
S1 S 0.8404(3) 0.58782(18) -0.06260(16) 0.0479(12) Uani 0.490(6) 1 d . . P A 1
O2' O 0.9142(7) 0.5530(5) -0.0547(5) 0.057(3) Uani 0.490(6) 1 d . . P A 1
O3' O 0.7640(11) 0.5597(7) -0.0599(9) 0.115(7) Uani 0.490(6) 1 d . . P A 1
C4' C 0.8214(7) 0.5961(6) -0.1229(5) 0.126(6) Uani 0.490(6) 1 d D . P A 1
F4'A F 0.8801(10) 0.6265(9) -0.1374(6) 0.135(9) Uani 0.490(6) 1 d D . P A 1
F4'B F 0.7861(18) 0.5504(9) -0.1492(11) 0.183(16) Uani 0.490(6) 1 d D . P A 1
F4'C F 0.7567(10) 0.6363(8) -0.1375(6) 0.122(6) Uani 0.490(6) 1 d D . P A 1
S1' S 0.8144(4) 0.6475(3) -0.09144(19) 0.078(2) Uani 0.510(6) 1 d . . P A 2
O4' O 0.8688(16) 0.6872(9) -0.1058(8) 0.148(10) Uani 0.510(6) 1 d . . P A 2
O5' O 0.7327(13) 0.6636(10) -0.1138(9) 0.165(13) Uani 0.510(6) 1 d . . P A 2
C4" C 0.8214(7) 0.5961(6) -0.1229(5) 0.126(6) Uani 0.510(6) 1 d D . P A 2
F4"A F 0.8054(16) 0.5910(10) -0.1696(4) 0.131(8) Uani 0.510(6) 1 d D . P A 2
F4"B F 0.8972(11) 0.5684(12) -0.1084(11) 0.249(18) Uani 0.510(6) 1 d D . P A 2
F4"C F 0.782(2) 0.5478(10) -0.1133(10) 0.226(17) Uani 0.510(6) 1 d D . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.278(5) . ?
Ag1 N9 2.294(6) . ?
Ag1 N10 2.306(6) . ?
Ag1 Ag2 3.1623(7) . ?
Ag2 P4 2.5756(17) . ?
Ag2 P1 2.5822(16) . ?
Ag2 P3 2.6034(16) . ?
Ag2 P2 2.6088(16) . ?
Ag2 Ag4 3.0909(7) . ?
Ag2 Ag5 3.1311(7) . ?
Ag2 Ag3 3.1638(7) . ?
Ag3 N2 2.278(6) . ?
Ag3 N4 2.284(5) . ?
Ag3 N12 2.294(5) . ?
Ag4 N8 2.294(5) . ?
Ag4 N11 2.292(5) . ?
Ag4 N3 2.306(5) . ?
Ag5 N5 2.267(5) . ?
Ag5 N7 2.268(5) . ?
Ag5 N6 2.291(6) . ?
Ag5 O1 2.582(7) . ?
P4 C61 1.831(7) . ?
P4 C70 1.831(6) . ?
P4 C24 1.841(7) . ?
P1 C9 1.820(7) . ?
P1 C10 1.831(7) . ?
P1 C51 1.832(6) . ?
P2 C69 1.834(6) . ?
P2 C68 1.835(6) . ?
P2 C15 1.837(6) . ?
P3 C67 1.833(6) . ?
P3 C25 1.831(6) . ?
P3 C66 1.834(6) . ?
N12 C70 1.341(8) . ?
N12 C57 1.347(8) . ?
N11 C71 1.329(9) . ?
N11 C10 1.343(8) . ?
N8 C11 1.333(8) . ?
N8 C69 1.340(8) . ?
N7 C45 1.344(8) . ?
N7 C68 1.338(8) . ?
N5 C25 1.343(8) . ?
N5 C36 1.343(9) . ?
N3 C73 1.333(8) . ?
N3 C67 1.343(8) . ?
C73 C26 1.384(10) . ?
C73 H73A 0.9500 . ?
N1 C29 1.338(8) . ?
N1 C66 1.353(8) . ?
C72 C47 1.376(9) . ?
C72 C46 1.377(10) . ?
C72 H72D 0.9500 . ?
C71 C48 1.380(10) . ?
C71 H71A 0.9500 . ?
C70 C60 1.391(9) . ?
N2 C9 1.343(9) . ?
N2 C5 1.345(9) . ?
C69 C14 1.387(8) . ?
N4 C15 1.324(8) . ?
N4 C16 1.338(9) . ?
C68 C47 1.383(8) . ?
N6 C20 1.335(9) . ?
N6 C24 1.356(9) . ?
C67 C28 1.379(9) . ?
C66 C32 1.387(9) . ?
N9 C52 1.332(9) . ?
N9 C51 1.342(8) . ?
C65 N10 1.357(9) . ?
C65 C63 1.369(12) . ?
C5 C6 1.389(12) . ?
C5 H5 0.9500 . ?
C6 C7 1.371(13) . ?
C6 H6 0.9500 . ?
C7 C8 1.381(11) . ?
C7 H7 0.9500 . ?
C8 C9 1.381(10) . ?
C8 H8 0.9500 . ?
C10 C50 1.386(9) . ?
C11 C12 1.399(10) . ?
C11 H11 0.9500 . ?
C12 C13 1.389(11) . ?
C12 H12 0.9500 . ?
C13 C14 1.368(10) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 C19 1.388(9) . ?
C16 C17 1.390(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.378(11) . ?
C17 H17 0.9500 . ?
C18 C19 1.365(10) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C21 1.353(12) . ?
C20 H20 0.9500 . ?
C21 C22 1.375(13) . ?
C21 H21 0.9500 . ?
C22 C23 1.386(11) . ?
C22 H22 0.9500 . ?
C23 C24 1.360(10) . ?
C23 H23 0.9500 . ?
C25 C33 1.379(9) . ?
C26 C27 1.374(11) . ?
C26 H26 0.9500 . ?
C27 C28 1.368(9) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C30 1.381(10) . ?
C29 H29 0.9500 . ?
C30 C31 1.384(11) . ?
C30 H30 0.9500 . ?
C31 C32 1.370(9) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C34 1.392(11) . ?
C33 H33 0.9500 . ?
C34 C35 1.360(13) . ?
C34 H34 0.9500 . ?
C35 C36 1.368(11) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
O1 S1 1.315(8) . ?
O1 S1' 1.401(8) . ?
C45 C46 1.376(10) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C47 H47 0.9500 . ?
C48 C49 1.385(11) . ?
C48 H48 0.9500 . ?
C49 C50 1.370(10) . ?
C49 H49 0.9500 . ?
C50 H50 0.9500 . ?
C51 C55 1.379(10) . ?
C52 C53 1.376(12) . ?
C52 H52 0.9500 . ?
C53 C54 1.379(13) . ?
C53 H53 0.9500 . ?
C54 C55 1.381(10) . ?
C54 H54 0.9500 . ?
C55 H55 0.9500 . ?
C57 C58 1.388(10) . ?
C57 H57 0.9500 . ?
C58 C59 1.379(11) . ?
C58 H58 0.9500 . ?
C59 C60 1.368(10) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C61 N10 1.346(8) . ?
C61 C62 1.373(9) . ?
C63 C64 1.384(12) . ?
C63 H63 0.9500 . ?
C64 C62 1.357(11) . ?
C64 H64 0.9500 . ?
C62 H62 0.9500 . ?
S1T O3T 1.406(7) . ?
S1T O1T 1.415(7) . ?
S1T O2T 1.441(7) . ?
S1T C1T 1.826(10) . ?
C1T F3T 1.296(12) . ?
C1T F2T 1.315(12) . ?
C1T F1T 1.321(11) . ?
S2T O5T 1.418(7) . ?
S2T O6T 1.427(6) . ?
S2T O4T 1.435(6) . ?
S2T C2T 1.809(10) . ?
C2T F6T 1.316(11) . ?
C2T F4T 1.327(12) . ?
C2T F5T 1.325(11) . ?
S3T O7T 1.427(7) . ?
S3T O8T 1.431(6) . ?
S3T O9T 1.435(5) . ?
S3T C3T 1.797(12) . ?
C3T F8T 1.296(12) . ?
C3T F7T 1.298(11) . ?
C3T F9T 1.354(12) . ?
O1A C1AA 1.181(12) . ?
C1AA C3A 1.488(17) . ?
C1AA C2A 1.508(16) . ?
C2A H2AA 0.9800 . ?
C2A H2AB 0.9800 . ?
C2A H2AC 0.9800 . ?
C3A H3AA 0.9800 . ?
C3A H3AB 0.9800 . ?
C3A H3AC 0.9800 . ?
O3A C7A 1.195(11) . ?
C9A C7A 1.460(15) . ?
C9A H9AA 0.9800 . ?
C9A H9AB 0.9800 . ?
C9A H9AC 0.9800 . ?
C7A C8A 1.450(16) . ?
C8A H8AA 0.9800 . ?
C8A H8AB 0.9800 . ?
C8A H8AC 0.9800 . ?
O2A C4A 1.192(8) . ?
C6A C4A 1.469(9) . ?
C6A H6AA 0.9800 . ?
C6A H6AB 0.9800 . ?
C6A H6AC 0.9800 . ?
C4A C5A 1.466(9) . ?
C5A H5AA 0.9800 . ?
C5A H5AB 0.9800 . ?
C5A H5AC 0.9800 . ?
O5A C13A 1.212(15) . ?
C15A C13A 1.441(19) . ?
C15A H1AA 0.9800 . ?
C15A H1AB 0.9800 . ?
C15A H1AC 0.9800 . ?
C13A C14A 1.486(17) . ?
C14A H4AA 0.9800 . ?
C14A H4AB 0.9800 . ?
C14A H4AC 0.9800 . ?
C12A C10A 1.467(9) . ?
C12A H7AA 0.9800 . ?
C12A H7AB 0.9800 . ?
C12A H7AC 0.9800 . ?
O4A C10A 1.174(8) . ?
C10A C11A 1.460(9) . ?
C11A H1AD 0.9800 . ?
C11A H1AE 0.9800 . ?
C11A H1AF 0.9800 . ?
S4T O12T 1.345(7) . ?
S4T O11T 1.402(7) . ?
S4T O10T 1.503(9) . ?
S4T C4T 1.728(9) . ?
C4T F12T 1.243(8) . ?
C4T F11T 1.256(9) . ?
C4T F10T 1.294(9) . ?
O6A C16A 1.207(9) . ?
C16A C17A 1.455(9) . ?
C16A C18A 1.474(9) . ?
C17A H17D 0.9800 . ?
C17A H17E 0.9800 . ?
C17A H17F 0.9800 . ?
C18A H18D 0.9800 . ?
C18A H18E 0.9800 . ?
C18A H18F 0.9800 . ?
S1 O2' 1.420(12) . ?
S1 O3' 1.432(14) . ?
S1 C4' 1.675(13) . ?
C4' F4'B 1.331(10) . ?
C4' F4'A 1.341(9) . ?
C4' F4'C 1.387(9) . ?
S1' O5' 1.377(17) . ?
S1' O4' 1.41(2) . ?
S1' C4" 1.505(13) . ?
C4" F4"A 1.293(9) . ?
C4" F4"C 1.347(10) . ?
C4" F4"B 1.362(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N9 127.16(19) . . ?
N1 Ag1 N10 120.41(19) . . ?
N9 Ag1 N10 112.38(19) . . ?
N1 Ag1 Ag2 92.25(13) . . ?
N9 Ag1 Ag2 87.60(13) . . ?
N10 Ag1 Ag2 87.77(13) . . ?
P4 Ag2 P1 109.47(5) . . ?
P4 Ag2 P3 108.79(5) . . ?
P1 Ag2 P3 109.84(5) . . ?
P4 Ag2 P2 108.50(5) . . ?
P1 Ag2 P2 109.25(5) . . ?
P3 Ag2 P2 110.96(5) . . ?
P4 Ag2 Ag4 178.54(4) . . ?
P1 Ag2 Ag4 69.11(4) . . ?
P3 Ag2 Ag4 72.23(4) . . ?
P2 Ag2 Ag4 71.89(4) . . ?
P4 Ag2 Ag5 73.42(4) . . ?
P1 Ag2 Ag5 177.12(4) . . ?
P3 Ag2 Ag5 68.68(4) . . ?
P2 Ag2 Ag5 69.47(4) . . ?
Ag4 Ag2 Ag5 108.006(19) . . ?
P4 Ag2 Ag1 73.35(4) . . ?
P1 Ag2 Ag1 69.33(4) . . ?
P3 Ag2 Ag1 68.65(4) . . ?
P2 Ag2 Ag1 178.06(4) . . ?
Ag4 Ag2 Ag1 106.246(18) . . ?
Ag5 Ag2 Ag1 111.883(19) . . ?
P4 Ag2 Ag3 71.61(4) . . ?
P1 Ag2 Ag3 68.32(4) . . ?
P3 Ag2 Ag3 178.07(4) . . ?
P2 Ag2 Ag3 70.51(4) . . ?
Ag4 Ag2 Ag3 107.333(19) . . ?
Ag5 Ag2 Ag3 113.179(19) . . ?
Ag1 Ag2 Ag3 109.834(18) . . ?
N2 Ag3 N4 121.1(2) . . ?
N2 Ag3 N12 124.77(19) . . ?
N4 Ag3 N12 114.1(2) . . ?
N2 Ag3 Ag2 91.45(14) . . ?
N4 Ag3 Ag2 89.46(14) . . ?
N12 Ag3 Ag2 90.78(13) . . ?
N8 Ag4 N11 125.67(19) . . ?
N8 Ag4 N3 116.32(18) . . ?
N11 Ag4 N3 117.96(18) . . ?
N8 Ag4 Ag2 90.61(14) . . ?
N11 Ag4 Ag2 89.54(13) . . ?
N3 Ag4 Ag2 87.58(13) . . ?
N5 Ag5 N7 128.82(19) . . ?
N5 Ag5 N6 111.6(2) . . ?
N7 Ag5 N6 119.50(19) . . ?
N5 Ag5 O1 88.3(2) . . ?
N7 Ag5 O1 87.5(2) . . ?
N6 Ag5 O1 92.5(2) . . ?
N5 Ag5 Ag2 89.88(13) . . ?
N7 Ag5 Ag2 92.87(13) . . ?
N6 Ag5 Ag2 89.07(14) . . ?
O1 Ag5 Ag2 177.95(19) . . ?
C61 P4 C70 101.6(3) . . ?
C61 P4 C24 102.4(3) . . ?
C70 P4 C24 101.7(3) . . ?
C61 P4 Ag2 115.0(2) . . ?
C70 P4 Ag2 118.2(2) . . ?
C24 P4 Ag2 115.5(2) . . ?
C9 P1 C10 102.0(3) . . ?
C9 P1 C51 102.5(3) . . ?
C10 P1 C51 102.4(3) . . ?
C9 P1 Ag2 117.7(2) . . ?
C10 P1 Ag2 115.4(2) . . ?
C51 P1 Ag2 114.8(2) . . ?
C69 P2 C68 101.0(3) . . ?
C69 P2 C15 102.4(3) . . ?
C68 P2 C15 101.8(3) . . ?
C69 P2 Ag2 115.16(19) . . ?
C68 P2 Ag2 119.1(2) . . ?
C15 P2 Ag2 114.9(2) . . ?
C67 P3 C25 102.5(3) . . ?
C67 P3 C66 102.0(3) . . ?
C25 P3 C66 101.3(3) . . ?
C67 P3 Ag2 112.44(19) . . ?
C25 P3 Ag2 116.7(2) . . ?
C66 P3 Ag2 119.6(2) . . ?
C70 N12 C57 118.1(6) . . ?
C70 N12 Ag3 124.1(4) . . ?
C57 N12 Ag3 117.8(5) . . ?
C71 N11 C10 118.0(6) . . ?
C71 N11 Ag4 121.3(4) . . ?
C10 N11 Ag4 120.1(4) . . ?
C11 N8 C69 117.6(6) . . ?
C11 N8 Ag4 118.9(5) . . ?
C69 N8 Ag4 123.4(4) . . ?
C45 N7 C68 117.6(6) . . ?
C45 N7 Ag5 120.4(4) . . ?
C68 N7 Ag5 121.5(4) . . ?
C25 N5 C36 118.4(6) . . ?
C25 N5 Ag5 121.8(4) . . ?
C36 N5 Ag5 119.4(5) . . ?
C73 N3 C67 118.7(6) . . ?
C73 N3 Ag4 117.3(4) . . ?
C67 N3 Ag4 124.0(4) . . ?
N3 C73 C26 122.0(7) . . ?
N3 C73 H73A 119.0 . . ?
C26 C73 H73A 119.0 . . ?
C29 N1 C66 116.7(6) . . ?
C29 N1 Ag1 121.4(4) . . ?
C66 N1 Ag1 121.4(4) . . ?
C47 C72 C46 118.9(6) . . ?
C47 C72 H72D 120.5 . . ?
C46 C72 H72D 120.5 . . ?
N11 C71 C48 122.7(7) . . ?
N11 C71 H71A 118.7 . . ?
C48 C71 H71A 118.7 . . ?
N12 C70 C60 121.9(6) . . ?
N12 C70 P4 114.4(4) . . ?
C60 C70 P4 123.7(5) . . ?
C9 N2 C5 118.5(7) . . ?
C9 N2 Ag3 121.8(4) . . ?
C5 N2 Ag3 119.7(5) . . ?
N8 C69 C14 122.5(6) . . ?
N8 C69 P2 114.4(4) . . ?
C14 C69 P2 123.0(5) . . ?
C15 N4 C16 118.4(6) . . ?
C15 N4 Ag3 124.4(4) . . ?
C16 N4 Ag3 117.3(5) . . ?
N7 C68 C47 122.5(6) . . ?
N7 C68 P2 114.5(4) . . ?
C47 C68 P2 123.0(5) . . ?
C20 N6 C24 116.7(6) . . ?
C20 N6 Ag5 116.9(5) . . ?
C24 N6 Ag5 126.4(4) . . ?
N3 C67 C28 121.8(6) . . ?
N3 C67 P3 113.7(4) . . ?
C28 C67 P3 124.4(5) . . ?
N1 C66 C32 122.9(6) . . ?
N1 C66 P3 113.5(4) . . ?
C32 C66 P3 123.5(5) . . ?
C52 N9 C51 117.8(6) . . ?
C52 N9 Ag1 119.0(5) . . ?
C51 N9 Ag1 123.0(4) . . ?
N10 C65 C63 121.9(7) . . ?
N2 C5 C6 121.7(8) . . ?
N2 C5 H5 119.1 . . ?
C6 C5 H5 119.1 . . ?
C7 C6 C5 119.7(8) . . ?
C7 C6 H6 120.1 . . ?
C5 C6 H6 120.1 . . ?
C6 C7 C8 118.4(8) . . ?
C6 C7 H7 120.8 . . ?
C8 C7 H7 120.8 . . ?
C7 C8 C9 119.6(8) . . ?
C7 C8 H8 120.2 . . ?
C9 C8 H8 120.2 . . ?
N2 C9 C8 122.1(7) . . ?
N2 C9 P1 112.8(5) . . ?
C8 C9 P1 125.1(6) . . ?
N11 C10 C50 122.2(6) . . ?
N11 C10 P1 113.5(5) . . ?
C50 C10 P1 124.4(5) . . ?
N8 C11 C12 123.4(7) . . ?
N8 C11 H11 118.3 . . ?
C12 C11 H11 118.3 . . ?
C13 C12 C11 118.0(7) . . ?
C13 C12 H12 121.0 . . ?
C11 C12 H12 121.0 . . ?
C14 C13 C12 118.8(6) . . ?
C14 C13 H13 120.6 . . ?
C12 C13 H13 120.6 . . ?
C13 C14 C69 119.7(7) . . ?
C13 C14 H14 120.2 . . ?
C69 C14 H14 120.2 . . ?
N4 C15 C19 122.8(6) . . ?
N4 C15 P2 113.8(4) . . ?
C19 C15 P2 123.4(5) . . ?
N4 C16 C17 122.1(7) . . ?
N4 C16 H16 119.0 . . ?
C17 C16 H16 119.0 . . ?
C18 C17 C16 118.8(7) . . ?
C18 C17 H17 120.6 . . ?
C16 C17 H17 120.6 . . ?
C19 C18 C17 119.1(7) . . ?
C19 C18 H18 120.5 . . ?
C17 C18 H18 120.5 . . ?
C18 C19 C15 118.9(7) . . ?
C18 C19 H19 120.6 . . ?
C15 C19 H19 120.6 . . ?
N6 C20 C21 123.6(8) . . ?
N6 C20 H20 118.2 . . ?
C21 C20 H20 118.2 . . ?
C20 C21 C22 119.1(8) . . ?
C20 C21 H21 120.4 . . ?
C22 C21 H21 120.4 . . ?
C21 C22 C23 119.1(7) . . ?
C21 C22 H22 120.5 . . ?
C23 C22 H22 120.5 . . ?
C24 C23 C22 118.0(8) . . ?
C24 C23 H23 121.0 . . ?
C22 C23 H23 121.0 . . ?
N6 C24 C23 123.6(6) . . ?
N6 C24 P4 113.1(5) . . ?
C23 C24 P4 123.4(6) . . ?
N5 C25 C33 122.5(6) . . ?
N5 C25 P3 112.7(4) . . ?
C33 C25 P3 124.8(6) . . ?
C27 C26 C73 119.0(6) . . ?
C27 C26 H26 120.5 . . ?
C73 C26 H26 120.5 . . ?
C28 C27 C26 119.0(7) . . ?
C28 C27 H27 120.5 . . ?
C26 C27 H27 120.5 . . ?
C27 C28 C67 119.4(7) . . ?
C27 C28 H28 120.3 . . ?
C67 C28 H28 120.3 . . ?
N1 C29 C30 123.6(7) . . ?
N1 C29 H29 118.2 . . ?
C30 C29 H29 118.2 . . ?
C29 C30 C31 118.8(7) . . ?
C29 C30 H30 120.6 . . ?
C31 C30 H30 120.6 . . ?
C32 C31 C30 118.8(6) . . ?
C32 C31 H31 120.6 . . ?
C30 C31 H31 120.6 . . ?
C31 C32 C66 119.1(6) . . ?
C31 C32 H32 120.4 . . ?
C66 C32 H32 120.4 . . ?
C25 C33 C34 117.8(8) . . ?
C25 C33 H33 121.1 . . ?
C34 C33 H33 121.1 . . ?
C35 C34 C33 119.8(7) . . ?
C35 C34 H34 120.1 . . ?
C33 C34 H34 120.1 . . ?
C34 C35 C36 119.3(8) . . ?
C34 C35 H35 120.4 . . ?
C36 C35 H35 120.4 . . ?
N5 C36 C35 122.3(8) . . ?
N5 C36 H36 118.9 . . ?
C35 C36 H36 118.9 . . ?
S1 O1 Ag5 140.0(5) . . ?
S1' O1 Ag5 140.2(6) . . ?
N7 C45 C46 123.1(6) . . ?
N7 C45 H45 118.4 . . ?
C46 C45 H45 118.4 . . ?
C45 C46 C72 118.7(6) . . ?
C45 C46 H46 120.6 . . ?
C72 C46 H46 120.6 . . ?
C72 C47 C68 119.1(6) . . ?
C72 C47 H47 120.4 . . ?
C68 C47 H47 120.4 . . ?
C71 C48 C49 119.6(7) . . ?
C71 C48 H48 120.2 . . ?
C49 C48 H48 120.2 . . ?
C50 C49 C48 117.7(7) . . ?
C50 C49 H49 121.1 . . ?
C48 C49 H49 121.1 . . ?
C49 C50 C10 119.8(7) . . ?
C49 C50 H50 120.1 . . ?
C10 C50 H50 120.1 . . ?
N9 C51 C55 122.6(6) . . ?
N9 C51 P1 112.4(5) . . ?
C55 C51 P1 125.0(6) . . ?
N9 C52 C53 123.2(8) . . ?
N9 C52 H52 118.4 . . ?
C53 C52 H52 118.4 . . ?
C52 C53 C54 118.9(7) . . ?
C52 C53 H53 120.5 . . ?
C54 C53 H53 120.5 . . ?
C55 C54 C53 118.6(7) . . ?
C55 C54 H54 120.7 . . ?
C53 C54 H54 120.7 . . ?
C51 C55 C54 119.0(8) . . ?
C51 C55 H55 120.5 . . ?
C54 C55 H55 120.5 . . ?
N12 C57 C58 122.6(7) . . ?
N12 C57 H57 118.7 . . ?
C58 C57 H57 118.7 . . ?
C59 C58 C57 118.7(7) . . ?
C59 C58 H58 120.6 . . ?
C57 C58 H58 120.6 . . ?
C60 C59 C58 119.0(6) . . ?
C60 C59 H59 120.5 . . ?
C58 C59 H59 120.5 . . ?
C59 C60 C70 119.7(7) . . ?
C59 C60 H60 120.2 . . ?
C70 C60 H60 120.2 . . ?
N10 C61 C62 122.3(6) . . ?
N10 C61 P4 114.1(5) . . ?
C62 C61 P4 123.6(5) . . ?
C61 N10 C65 117.8(6) . . ?
C61 N10 Ag1 126.2(4) . . ?
C65 N10 Ag1 116.0(5) . . ?
C65 C63 C64 119.2(7) . . ?
C65 C63 H63 120.4 . . ?
C64 C63 H63 120.4 . . ?
C62 C64 C63 119.1(7) . . ?
C62 C64 H64 120.5 . . ?
C63 C64 H64 120.5 . . ?
C64 C62 C61 119.6(7) . . ?
C64 C62 H62 120.2 . . ?
C61 C62 H62 120.2 . . ?
O3T S1T O1T 117.8(5) . . ?
O3T S1T O2T 111.2(4) . . ?
O1T S1T O2T 114.6(6) . . ?
O3T S1T C1T 104.8(5) . . ?
O1T S1T C1T 103.0(5) . . ?
O2T S1T C1T 103.3(5) . . ?
F3T C1T F2T 108.8(10) . . ?
F3T C1T F1T 105.6(8) . . ?
F2T C1T F1T 109.9(10) . . ?
F3T C1T S1T 111.6(9) . . ?
F2T C1T S1T 111.0(6) . . ?
F1T C1T S1T 109.7(8) . . ?
O5T S2T O6T 115.8(5) . . ?
O5T S2T O4T 115.5(4) . . ?
O6T S2T O4T 113.4(4) . . ?
O5T S2T C2T 102.8(5) . . ?
O6T S2T C2T 103.7(4) . . ?
O4T S2T C2T 103.2(4) . . ?
F6T C2T F4T 105.0(9) . . ?
F6T C2T F5T 108.7(9) . . ?
F4T C2T F5T 107.8(9) . . ?
F6T C2T S2T 111.8(7) . . ?
F4T C2T S2T 111.3(7) . . ?
F5T C2T S2T 111.9(7) . . ?
O7T S3T O8T 116.6(4) . . ?
O7T S3T O9T 114.7(4) . . ?
O8T S3T O9T 114.3(4) . . ?
O7T S3T C3T 103.3(4) . . ?
O8T S3T C3T 102.0(5) . . ?
O9T S3T C3T 103.2(5) . . ?
F8T C3T F7T 107.4(10) . . ?
F8T C3T F9T 107.7(10) . . ?
F7T C3T F9T 107.4(9) . . ?
F8T C3T S3T 112.3(8) . . ?
F7T C3T S3T 112.8(8) . . ?
F9T C3T S3T 109.1(8) . . ?
O1A C1AA C3A 123.5(12) . . ?
O1A C1AA C2A 119.3(12) . . ?
C3A C1AA C2A 117.2(11) . . ?
C1AA C2A H2AA 109.5 . . ?
C1AA C2A H2AB 109.5 . . ?
H2AA C2A H2AB 109.5 . . ?
C1AA C2A H2AC 109.5 . . ?
H2AA C2A H2AC 109.5 . . ?
H2AB C2A H2AC 109.5 . . ?
C1AA C3A H3AA 109.5 . . ?
C1AA C3A H3AB 109.5 . . ?
H3AA C3A H3AB 109.5 . . ?
C1AA C3A H3AC 109.5 . . ?
H3AA C3A H3AC 109.5 . . ?
H3AB C3A H3AC 109.5 . . ?
C7A C9A H9AA 109.5 . . ?
C7A C9A H9AB 109.5 . . ?
H9AA C9A H9AB 109.5 . . ?
C7A C9A H9AC 109.5 . . ?
H9AA C9A H9AC 109.5 . . ?
H9AB C9A H9AC 109.5 . . ?
O3A C7A C8A 122.2(11) . . ?
O3A C7A C9A 122.5(12) . . ?
C8A C7A C9A 115.2(11) . . ?
C7A C8A H8AA 109.5 . . ?
C7A C8A H8AB 109.5 . . ?
H8AA C8A H8AB 109.5 . . ?
C7A C8A H8AC 109.5 . . ?
H8AA C8A H8AC 109.5 . . ?
H8AB C8A H8AC 109.5 . . ?
C4A C6A H6AA 109.5 . . ?
C4A C6A H6AB 109.5 . . ?
H6AA C6A H6AB 109.5 . . ?
C4A C6A H6AC 109.5 . . ?
H6AA C6A H6AC 109.5 . . ?
H6AB C6A H6AC 109.5 . . ?
O2A C4A C6A 123.5(15) . . ?
O2A C4A C5A 119.9(14) . . ?
C6A C4A C5A 116.1(11) . . ?
C4A C5A H5AA 109.5 . . ?
C4A C5A H5AB 109.5 . . ?
H5AA C5A H5AB 109.5 . . ?
C4A C5A H5AC 109.5 . . ?
H5AA C5A H5AC 109.5 . . ?
H5AB C5A H5AC 109.5 . . ?
C13A C15A H1AA 109.5 . . ?
C13A C15A H1AB 109.5 . . ?
H1AA C15A H1AB 109.5 . . ?
C13A C15A H1AC 109.5 . . ?
H1AA C15A H1AC 109.5 . . ?
H1AB C15A H1AC 109.5 . . ?
O5A C13A C15A 122.2(14) . . ?
O5A C13A C14A 119.9(15) . . ?
C15A C13A C14A 117.8(14) . . ?
C13A C14A H4AA 109.5 . . ?
C13A C14A H4AB 109.5 . . ?
H4AA C14A H4AB 109.5 . . ?
C13A C14A H4AC 109.5 . . ?
H4AA C14A H4AC 109.5 . . ?
H4AB C14A H4AC 109.5 . . ?
C10A C12A H7AA 109.5 . . ?
C10A C12A H7AB 109.5 . . ?
H7AA C12A H7AB 109.5 . . ?
C10A C12A H7AC 109.5 . . ?
H7AA C12A H7AC 109.5 . . ?
H7AB C12A H7AC 109.5 . . ?
O4A C10A C11A 122.7(19) . . ?
O4A C10A C12A 123(2) . . ?
C11A C10A C12A 113.3(14) . . ?
C10A C11A H1AD 109.5 . . ?
C10A C11A H1AE 109.5 . . ?
H1AD C11A H1AE 109.5 . . ?
C10A C11A H1AF 109.5 . . ?
H1AD C11A H1AF 109.5 . . ?
H1AE C11A H1AF 109.5 . . ?
O12T S4T O11T 126.6(7) . . ?
O12T S4T O10T 113.6(9) . . ?
O11T S4T O10T 107.7(8) . . ?
O12T S4T C4T 112.7(8) . . ?
O11T S4T C4T 105.4(6) . . ?
O10T S4T C4T 81.5(9) . . ?
F12T C4T F11T 113.5(9) . . ?
F12T C4T F10T 110.5(10) . . ?
F11T C4T F10T 111.0(10) . . ?
F12T C4T S4T 115.6(9) . . ?
F11T C4T S4T 113.4(10) . . ?
F10T C4T S4T 90.5(12) . . ?
O6A C16A C17A 132.4(17) . . ?
O6A C16A C18A 118.5(15) . . ?
C17A C16A C18A 107.5(16) . . ?
C16A C17A H17D 109.5 . . ?
C16A C17A H17E 109.5 . . ?
H17D C17A H17E 109.5 . . ?
C16A C17A H17F 109.5 . . ?
H17D C17A H17F 109.5 . . ?
H17E C17A H17F 109.5 . . ?
C16A C18A H18D 109.5 . . ?
C16A C18A H18E 109.5 . . ?
H18D C18A H18E 109.5 . . ?
C16A C18A H18F 109.5 . . ?
H18D C18A H18F 109.5 . . ?
H18E C18A H18F 109.5 . . ?
O1 S1 O2' 116.3(6) . . ?
O1 S1 O3' 112.0(9) . . ?
O2' S1 O3' 117.4(9) . . ?
O1 S1 C4' 109.6(6) . . ?
O2' S1 C4' 98.6(7) . . ?
O3' S1 C4' 100.2(11) . . ?
F4'B C4' F4'A 119(3) . . ?
F4'B C4' F4'C 99.8(15) . . ?
F4'A C4' F4'C 96.8(13) . . ?
F4'B C4' S1 115.0(19) . . ?
F4'A C4' S1 114.8(10) . . ?
F4'C C4' S1 107.7(10) . . ?
O5' S1' O1 126.7(13) . . ?
O5' S1' O4' 107.8(17) . . ?
O1 S1' O4' 105.1(9) . . ?
O5' S1' C4" 98.8(9) . . ?
O1 S1' C4" 115.1(7) . . ?
O4' S1' C4" 100.5(13) . . ?
F4"A C4" F4"C 99.0(19) . . ?
F4"A C4" F4"B 101.2(18) . . ?
F4"C C4" F4"B 90(2) . . ?
F4"A C4" S1' 131.1(14) . . ?
F4"C C4" S1' 114.2(18) . . ?
F4"B C4" S1' 113.1(10) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C67 N3 C73 C26 1.7(10) . . . . ?
Ag4 N3 C73 C26 179.5(5) . . . . ?
C10 N11 C71 C48 -2.2(10) . . . . ?
Ag4 N11 C71 C48 169.0(6) . . . . ?
C57 N12 C70 C60 -0.4(10) . . . . ?
Ag3 N12 C70 C60 179.9(5) . . . . ?
C57 N12 C70 P4 177.3(5) . . . . ?
Ag3 N12 C70 P4 -2.4(7) . . . . ?
C61 P4 C70 N12 168.5(5) . . . . ?
C24 P4 C70 N12 -86.0(5) . . . . ?
Ag2 P4 C70 N12 41.6(5) . . . . ?
C61 P4 C70 C60 -13.8(6) . . . . ?
C24 P4 C70 C60 91.6(6) . . . . ?
Ag2 P4 C70 C60 -140.7(5) . . . . ?
C11 N8 C69 C14 -0.5(9) . . . . ?
Ag4 N8 C69 C14 -176.7(5) . . . . ?
C11 N8 C69 P2 176.4(5) . . . . ?
Ag4 N8 C69 P2 0.2(6) . . . . ?
C68 P2 C69 N8 -88.3(5) . . . . ?
C15 P2 C69 N8 166.9(5) . . . . ?
Ag2 P2 C69 N8 41.4(5) . . . . ?
C68 P2 C69 C14 88.6(6) . . . . ?
C15 P2 C69 C14 -16.3(6) . . . . ?
Ag2 P2 C69 C14 -141.7(5) . . . . ?
C45 N7 C68 C47 -1.3(9) . . . . ?
Ag5 N7 C68 C47 -173.8(5) . . . . ?
C45 N7 C68 P2 177.4(5) . . . . ?
Ag5 N7 C68 P2 4.8(6) . . . . ?
C69 P2 C68 N7 164.6(5) . . . . ?
C15 P2 C68 N7 -90.0(5) . . . . ?
Ag2 P2 C68 N7 37.5(5) . . . . ?
C69 P2 C68 C47 -16.7(6) . . . . ?
C15 P2 C68 C47 88.6(6) . . . . ?
Ag2 P2 C68 C47 -143.9(5) . . . . ?
C73 N3 C67 C28 -1.1(9) . . . . ?
Ag4 N3 C67 C28 -178.8(5) . . . . ?
C73 N3 C67 P3 -179.0(5) . . . . ?
Ag4 N3 C67 P3 3.4(6) . . . . ?
C25 P3 C67 N3 168.5(4) . . . . ?
C66 P3 C67 N3 -86.9(5) . . . . ?
Ag2 P3 C67 N3 42.4(5) . . . . ?
C25 P3 C67 C28 -9.3(6) . . . . ?
C66 P3 C67 C28 95.3(6) . . . . ?
Ag2 P3 C67 C28 -135.4(5) . . . . ?
C29 N1 C66 C32 1.4(10) . . . . ?
Ag1 N1 C66 C32 -171.3(5) . . . . ?
C29 N1 C66 P3 177.0(5) . . . . ?
Ag1 N1 C66 P3 4.3(6) . . . . ?
C67 P3 C66 N1 164.9(5) . . . . ?
C25 P3 C66 N1 -89.6(5) . . . . ?
Ag2 P3 C66 N1 40.2(5) . . . . ?
C67 P3 C66 C32 -19.6(6) . . . . ?
C25 P3 C66 C32 86.0(6) . . . . ?
Ag2 P3 C66 C32 -144.3(5) . . . . ?
C9 N2 C5 C6 0.1(11) . . . . ?
Ag3 N2 C5 C6 -178.5(6) . . . . ?
N2 C5 C6 C7 0.5(13) . . . . ?
C5 C6 C7 C8 -0.1(14) . . . . ?
C6 C7 C8 C9 -0.9(13) . . . . ?
C5 N2 C9 C8 -1.2(10) . . . . ?
Ag3 N2 C9 C8 177.4(5) . . . . ?
C5 N2 C9 P1 177.6(5) . . . . ?
Ag3 N2 C9 P1 -3.8(6) . . . . ?
C7 C8 C9 N2 1.6(11) . . . . ?
C7 C8 C9 P1 -177.0(6) . . . . ?
C10 P1 C9 N2 176.1(5) . . . . ?
C51 P1 C9 N2 -78.2(5) . . . . ?
Ag2 P1 C9 N2 48.8(5) . . . . ?
C10 P1 C9 C8 -5.2(7) . . . . ?
C51 P1 C9 C8 100.5(6) . . . . ?
Ag2 P1 C9 C8 -132.4(5) . . . . ?
C71 N11 C10 C50 1.4(10) . . . . ?
Ag4 N11 C10 C50 -169.9(6) . . . . ?
C71 N11 C10 P1 179.4(5) . . . . ?
Ag4 N11 C10 P1 8.1(7) . . . . ?
C9 P1 C10 N11 -87.5(5) . . . . ?
C51 P1 C10 N11 166.7(5) . . . . ?
Ag2 P1 C10 N11 41.2(6) . . . . ?
C9 P1 C10 C50 90.4(7) . . . . ?
C51 P1 C10 C50 -15.4(7) . . . . ?
Ag2 P1 C10 C50 -140.9(6) . . . . ?
C69 N8 C11 C12 -0.5(10) . . . . ?
Ag4 N8 C11 C12 175.9(6) . . . . ?
N8 C11 C12 C13 0.6(11) . . . . ?
C11 C12 C13 C14 0.3(11) . . . . ?
C12 C13 C14 C69 -1.2(11) . . . . ?
N8 C69 C14 C13 1.3(10) . . . . ?
P2 C69 C14 C13 -175.3(5) . . . . ?
C16 N4 C15 C19 -0.8(10) . . . . ?
Ag3 N4 C15 C19 178.2(5) . . . . ?
C16 N4 C15 P2 179.1(6) . . . . ?
Ag3 N4 C15 P2 -1.8(7) . . . . ?
C69 P2 C15 N4 -80.3(5) . . . . ?
C68 P2 C15 N4 175.5(5) . . . . ?
Ag2 P2 C15 N4 45.4(5) . . . . ?
C69 P2 C15 C19 99.7(6) . . . . ?
C68 P2 C15 C19 -4.5(6) . . . . ?
Ag2 P2 C15 C19 -134.7(5) . . . . ?
C15 N4 C16 C17 0.7(12) . . . . ?
Ag3 N4 C16 C17 -178.4(7) . . . . ?
N4 C16 C17 C18 -0.1(14) . . . . ?
C16 C17 C18 C19 -0.6(14) . . . . ?
C17 C18 C19 C15 0.5(13) . . . . ?
N4 C15 C19 C18 0.2(11) . . . . ?
P2 C15 C19 C18 -179.8(6) . . . . ?
C24 N6 C20 C21 0.4(13) . . . . ?
Ag5 N6 C20 C21 -177.6(7) . . . . ?
N6 C20 C21 C22 0.4(15) . . . . ?
C20 C21 C22 C23 -0.1(15) . . . . ?
C21 C22 C23 C24 -0.8(14) . . . . ?
C20 N6 C24 C23 -1.4(11) . . . . ?
Ag5 N6 C24 C23 176.3(6) . . . . ?
C20 N6 C24 P4 178.9(6) . . . . ?
Ag5 N6 C24 P4 -3.4(7) . . . . ?
C22 C23 C24 N6 1.6(12) . . . . ?
C22 C23 C24 P4 -178.7(7) . . . . ?
C61 P4 C24 N6 -83.1(5) . . . . ?
C70 P4 C24 N6 172.0(5) . . . . ?
Ag2 P4 C24 N6 42.6(5) . . . . ?
C61 P4 C24 C23 97.1(7) . . . . ?
C70 P4 C24 C23 -7.7(7) . . . . ?
Ag2 P4 C24 C23 -137.1(6) . . . . ?
C36 N5 C25 C33 0.3(10) . . . . ?
Ag5 N5 C25 C33 -171.7(5) . . . . ?
C36 N5 C25 P3 -179.4(5) . . . . ?
Ag5 N5 C25 P3 8.6(6) . . . . ?
C67 P3 C25 N5 -83.3(5) . . . . ?
C66 P3 C25 N5 171.6(5) . . . . ?
Ag2 P3 C25 N5 40.0(5) . . . . ?
C67 P3 C25 C33 97.1(6) . . . . ?
C66 P3 C25 C33 -8.1(7) . . . . ?
Ag2 P3 C25 C33 -139.6(6) . . . . ?
N3 C73 C26 C27 -2.0(11) . . . . ?
C73 C26 C27 C28 1.8(11) . . . . ?
C26 C27 C28 C67 -1.3(11) . . . . ?
N3 C67 C28 C27 0.9(10) . . . . ?
P3 C67 C28 C27 178.6(6) . . . . ?
C66 N1 C29 C30 -1.6(11) . . . . ?
Ag1 N1 C29 C30 171.1(6) . . . . ?
N1 C29 C30 C31 1.3(12) . . . . ?
C29 C30 C31 C32 -0.8(12) . . . . ?
C30 C31 C32 C66 0.6(11) . . . . ?
N1 C66 C32 C31 -0.9(10) . . . . ?
P3 C66 C32 C31 -176.1(5) . . . . ?
N5 C25 C33 C34 -1.0(11) . . . . ?
P3 C25 C33 C34 178.6(6) . . . . ?
C25 C33 C34 C35 1.2(13) . . . . ?
C33 C34 C35 C36 -0.6(14) . . . . ?
C25 N5 C36 C35 0.3(11) . . . . ?
Ag5 N5 C36 C35 172.5(6) . . . . ?
C34 C35 C36 N5 -0.2(13) . . . . ?
C68 N7 C45 C46 1.4(10) . . . . ?
Ag5 N7 C45 C46 174.0(5) . . . . ?
N7 C45 C46 C72 -0.4(11) . . . . ?
C47 C72 C46 C45 -0.7(10) . . . . ?
C46 C72 C47 C68 0.8(10) . . . . ?
N7 C68 C47 C72 0.2(10) . . . . ?
P2 C68 C47 C72 -178.3(5) . . . . ?
N11 C71 C48 C49 1.1(12) . . . . ?
C71 C48 C49 C50 0.7(12) . . . . ?
C48 C49 C50 C10 -1.4(13) . . . . ?
N11 C10 C50 C49 0.3(12) . . . . ?
P1 C10 C50 C49 -177.4(6) . . . . ?
C52 N9 C51 C55 -0.6(10) . . . . ?
Ag1 N9 C51 C55 -175.2(5) . . . . ?
C52 N9 C51 P1 179.7(5) . . . . ?
Ag1 N9 C51 P1 5.1(7) . . . . ?
C9 P1 C51 N9 173.5(5) . . . . ?
C10 P1 C51 N9 -81.1(5) . . . . ?
Ag2 P1 C51 N9 44.7(5) . . . . ?
C9 P1 C51 C55 -6.2(7) . . . . ?
C10 P1 C51 C55 99.2(7) . . . . ?
Ag2 P1 C51 C55 -135.0(6) . . . . ?
C51 N9 C52 C53 0.2(11) . . . . ?
Ag1 N9 C52 C53 175.1(6) . . . . ?
N9 C52 C53 C54 -0.9(13) . . . . ?
C52 C53 C54 C55 1.9(14) . . . . ?
N9 C51 C55 C54 1.6(12) . . . . ?
P1 C51 C55 C54 -178.7(6) . . . . ?
C53 C54 C55 C51 -2.3(13) . . . . ?
C70 N12 C57 C58 1.8(11) . . . . ?
Ag3 N12 C57 C58 -178.5(6) . . . . ?
N12 C57 C58 C59 -1.0(12) . . . . ?
C57 C58 C59 C60 -1.1(12) . . . . ?
C58 C59 C60 C70 2.4(11) . . . . ?
N12 C70 C60 C59 -1.7(11) . . . . ?
P4 C70 C60 C59 -179.2(6) . . . . ?
C70 P4 C61 N10 -86.5(5) . . . . ?
C24 P4 C61 N10 168.5(5) . . . . ?
Ag2 P4 C61 N10 42.4(5) . . . . ?
C70 P4 C61 C62 90.5(6) . . . . ?
C24 P4 C61 C62 -14.4(7) . . . . ?
Ag2 P4 C61 C62 -140.5(6) . . . . ?
C62 C61 N10 C65 -0.4(10) . . . . ?
P4 C61 N10 C65 176.7(5) . . . . ?
C62 C61 N10 Ag1 -178.5(5) . . . . ?
P4 C61 N10 Ag1 -1.4(7) . . . . ?
C63 C65 N10 C61 0.0(11) . . . . ?
C63 C65 N10 Ag1 178.3(7) . . . . ?
N10 C65 C63 C64 1.2(14) . . . . ?
C65 C63 C64 C62 -2.1(14) . . . . ?
C63 C64 C62 C61 1.7(13) . . . . ?
N10 C61 C62 C64 -0.4(11) . . . . ?
P4 C61 C62 C64 -177.3(6) . . . . ?
O3T S1T C1T F3T 66.8(8) . . . . ?
O1T S1T C1T F3T -57.0(9) . . . . ?
O2T S1T C1T F3T -176.6(7) . . . . ?
O3T S1T C1T F2T -54.8(10) . . . . ?
O1T S1T C1T F2T -178.6(9) . . . . ?
O2T S1T C1T F2T 61.8(10) . . . . ?
O3T S1T C1T F1T -176.5(8) . . . . ?
O1T S1T C1T F1T 59.7(9) . . . . ?
O2T S1T C1T F1T -59.9(9) . . . . ?
O5T S2T C2T F6T -60.2(9) . . . . ?
O6T S2T C2T F6T 178.8(8) . . . . ?
O4T S2T C2T F6T 60.3(9) . . . . ?
O5T S2T C2T F4T -177.3(7) . . . . ?
O6T S2T C2T F4T 61.7(8) . . . . ?
O4T S2T C2T F4T -56.8(8) . . . . ?
O5T S2T C2T F5T 61.9(9) . . . . ?
O6T S2T C2T F5T -59.0(8) . . . . ?
O4T S2T C2T F5T -177.6(7) . . . . ?
O7T S3T C3T F8T 179.6(8) . . . . ?
O8T S3T C3T F8T -59.0(10) . . . . ?
O9T S3T C3T F8T 59.8(9) . . . . ?
O7T S3T C3T F7T 58.1(8) . . . . ?
O8T S3T C3T F7T 179.5(7) . . . . ?
O9T S3T C3T F7T -61.7(8) . . . . ?
O7T S3T C3T F9T -61.1(8) . . . . ?
O8T S3T C3T F9T 60.3(8) . . . . ?
O9T S3T C3T F9T 179.1(7) . . . . ?
O12T S4T C4T F12T -179.0(11) . . . . ?
O11T S4T C4T F12T -37.1(12) . . . . ?
O10T S4T C4T F12T 69.0(12) . . . . ?
O12T S4T C4T F11T 47.4(13) . . . . ?
O11T S4T C4T F11T -170.8(10) . . . . ?
O10T S4T C4T F11T -64.7(11) . . . . ?
O12T S4T C4T F10T -65.9(11) . . . . ?
O11T S4T C4T F10T 75.9(10) . . . . ?
O10T S4T C4T F10T -178.0(11) . . . . ?
Ag5 O1 S1 O2' -25.7(12) . . . . ?
Ag5 O1 S1 O3' 113.3(13) . . . . ?
Ag5 O1 S1 C4' -136.5(8) . . . . ?
O1 S1 C4' F4'B -160.2(16) . . . . ?
O2' S1 C4' F4'B 77.8(17) . . . . ?
O3' S1 C4' F4'B -42.2(18) . . . . ?
O1 S1 C4' F4'A 56.6(13) . . . . ?
O2' S1 C4' F4'A -65.4(13) . . . . ?
O3' S1 C4' F4'A 174.6(13) . . . . ?
O1 S1 C4' F4'C -49.9(13) . . . . ?
O2' S1 C4' F4'C -171.9(12) . . . . ?
O3' S1 C4' F4'C 68.0(13) . . . . ?
Ag5 O1 S1' O5' -101.9(16) . . . . ?
Ag5 O1 S1' O4' 24.6(15) . . . . ?
Ag5 O1 S1' C4" 134.1(8) . . . . ?
O5' S1' C4" F4"A 52(3) . . . . ?
O1 S1' C4" F4"A -170.8(19) . . . . ?
O4' S1' C4" F4"A -59(2) . . . . ?
O5' S1' C4" F4"C -77(2) . . . . ?
O1 S1' C4" F4"C 61.0(18) . . . . ?
O4' S1' C4" F4"C 173.2(18) . . . . ?
O5' S1' C4" F4"B -178(3) . . . . ?
O1 S1' C4" F4"B -40(2) . . . . ?
O4' S1' C4" F4"B 72(2) . . . . ?

_refine_diff_density_max         2.220
_refine_diff_density_min         -1.394
_refine_diff_density_rms         0.143

