# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2017

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1552465'
_audit_update_record             
;
2017-07-27 deposited with the CCDC.
2017-08-02 downloaded from the CCDC.
;
#=======================================================================

# 5. CHEMICAL DATA

_chemical_name_systematic        
; ?
;
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_iupac          ?
_chemical_formula_sum            'C9 H15 F1 Ge6.11 N O13.75 Si0.64'
_chemical_formula_weight         837.98
_chemical_melting_point          ?
_chemical_compound_source        ?
_chemical_absolute_configuration ?

#=======================================================================

# 6. CRYSTAL DATA

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'F m 2 m'
_symmetry_space_group_name_Hall  'F -2x;2y;-2z'
_symmetry_Int_Tables_number      42

loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y,-z
3 -x,y,z
4 x,y,-z
5 x,y+1/2,z+1/2
6 -x,y+1/2,-z+1/2
7 -x,y+1/2,z+1/2
8 x,y+1/2,-z+1/2
9 x+1/2,y,z+1/2
10 -x+1/2,y,-z+1/2
11 -x+1/2,y,z+1/2
12 x+1/2,y,-z+1/2
13 x+1/2,y+1/2,z
14 -x+1/2,y+1/2,-z
15 -x+1/2,y+1/2,z
16 x+1/2,y+1/2,-z

_cell_length_a                   13.9117(2)
_cell_length_b                   18.2980(3)
_cell_length_c                   32.7800(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     8344.4(2)

loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
_twin_individual_twin_matrix_11
_twin_individual_twin_matrix_12
_twin_individual_twin_matrix_13
_twin_individual_twin_matrix_21
_twin_individual_twin_matrix_22
_twin_individual_twin_matrix_23
_twin_individual_twin_matrix_31
_twin_individual_twin_matrix_32
_twin_individual_twin_matrix_33
? ? ? ? ? ? ? ? ? ? ?

_cell_formula_units_Z            16

_cell_measurement_reflns_used    1501
_cell_measurement_theta_min      0.6
_cell_measurement_theta_max      28
_cell_measurement_temperature    100
_cell_special_details            
; ?
;

_exptl_crystal_density_diffrn    2.668
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             ?

_exptl_absorpt_coefficient_mu    2.672
_exptl_crystal_description       powder
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_size_rad          ?
_exptl_crystal_colour            colorless
_exptl_absorpt_correction_type   ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
? ? ? ?

#=======================================================================

# 7. EXPERIMENTAL DATA

_exptl_special_details           ?

_diffrn_ambient_temperature      100
_diffrn_source                   ?
_diffrn_source_power             ?
_diffrn_source_voltage           ?
_diffrn_source_current           ?
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         synchrotron
_diffrn_radiation_wavelength     0.459255
_diffrn_radiation_monochromator  ?
_diffrn_measurement_device       ?
_diffrn_measurement_device_type  synchrotron
_diffrn_detector                 ?
_diffrn_detector_area_resol_mean ?
_diffrn_measurement_method       ?
_diffrn_measurement_specimen_support ?

_diffrn_reflns_number            ?
_diffrn_reflns_theta_min         ?
_diffrn_reflns_theta_max         ?
_diffrn_reflns_theta_full        ?
_diffrn_measured_fraction_theta_max ?
_diffrn_measured_fraction_theta_full ?
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_av_unetI/netI     ?
_diffrn_reflns_limit_h_min       ?
_diffrn_reflns_limit_h_max       ?
_diffrn_reflns_limit_k_min       ?
_diffrn_reflns_limit_k_max       ?
_diffrn_reflns_limit_l_min       ?
_diffrn_reflns_limit_l_max       ?
_diffrn_reflns_reduction_process ?

_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?

_diffrn_radiation_probe          X-ray

#=======================================================================

_refine_special_details          
; ?                                                                         
;

_pd_proc_ls_profile_function     'Pearson VII peak type'
_pd_proc_ls_background_function  'Chebychev polynomial'
_pd_proc_ls_pref_orient_corr     
; ?                                                                         
;

_pd_proc_ls_prof_R_factor        0.09023
_pd_proc_ls_prof_wR_factor       0.11868
_pd_proc_ls_prof_wR_expected     0.04201
_refine_ls_R_I_factor            0.04481
_refine_ls_R_Fsqd_factor         ?
_refine_ls_R_factor_all          ?
_refine_ls_goodness_of_fit_all   2.825


_pd_calc_method                  'Rietveld Refinement'
_reflns_number_total             1501
_refine_ls_number_parameters     160

loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 0.0033 0.0016 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
H 0.0000 0.0000 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
F 0.0171 0.0103 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Ge 0.1547 1.8001 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
N 0.0061 0.0033 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
O 0.0106 0.0060 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Si 0.0817 0.0704 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'


#=======================================================================

# 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_site_symmetry_multiplicity
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.88870(14) 0.00937(12) 0.21210(6) Uiso 0.0193(5) 16 1 d . . .
Ge2 Ge 0.88141(16) 0.88495(11) 0.28173(6) Uiso 0.0193(5) 16 1 d . . .
Si3 Si 0.11129(15) 0.13208(11) 0.28164(6) Uiso 0.0193(5) 16 0.2214(6) d . . .
Ge3 Ge 0.11129(15) 0.13208(11) 0.28164(6) Uiso 0.0193(5) 16 0.779(2) d . . .
Si4 Si 0.25 0.74972(12) 0.25 Uiso 0.0193(5) 8 0.2038(10) d . . .
Ge4 Ge 0.25 0.74972(12) 0.25 Uiso 0.0193(5) 8 0.796(4) d . . .
Si5 Si 0.3886(3) 0.14779(12) 0 Uiso 0.0193(5) 8 0.1686(9) d . . .
Ge5 Ge 0.3886(3) 0.14779(12) 0 Uiso 0.0193(5) 8 0.498(3) d . . .
Si6 Si 0.6114(5) 0.89666(12) 0 Uiso 0.0193(5) 8 0.1837(10) d . . .
Ge6 Ge 0.6114(5) 0.89666(12) 0 Uiso 0.0193(5) 8 0.816(4) d . . .
Si7 Si 0.80236(13) 0.00509(12) 0.34299(7) Uiso 0.0193(5) 16 0.1384(4) d . . .
Ge7 Ge 0.80236(13) 0.00509(12) 0.34299(7) Uiso 0.0193(5) 16 0.862(2) d . . .
Ge8 Ge 0.88782(14) 0.01979(10) 0.43074(6) Uiso 0.0193(5) 16 1 d . . .
O1 O 0 0.6712(3) 0.21297(19) Uiso 0.0274(16) 8 1 d . . .
O2 O 0 0.3656(3) 0.2190(2) Uiso 0.0274(16) 8 1 d . . .
O3 O 0.8295(2) 0.8023(2) 0.27516(12) Uiso 0.0274(16) 16 1 d . . .
O4 O 0.1940(2) 0.1978(2) 0.28527(11) Uiso 0.0274(16) 16 1 d . . .
O5 O 0.8485(2) 0.9402(2) 0.24266(14) Uiso 0.0274(16) 16 1 d . . .
O6 O 0.1192(3) 0.09297(18) 0.23549(12) Uiso 0.0274(16) 16 1 d . . .
O7 O 0.8474(3) 0.9219(2) 0.32864(11) Uiso 0.0274(16) 16 1 d . . .
O8 O 0.1318(2) 0.07232(18) 0.32069(12) Uiso 0.0274(16) 16 1 d . . .
O9 O 0 0.4912(4) 0.30531(12) Uiso 0.0274(16) 8 1 d . . .
O10 O 0.6846(2) 0.0120(5) 0.32970(10) Uiso 0.0274(16) 16 1 d . . .
O11 O 0.3241(5) 0.2234(5) 0 Uiso 0.0274(16) 8 0.6667 d . . .
O12 O 0.6944(3) 0.8312(3) 0 Uiso 0.0274(16) 8 1 d . . .
O13 O 0.8733(3) 0.9462(2) 0.45842(11) Uiso 0.0274(16) 16 1 d . . .
O14 O 0.1336(3) 0.0980(2) 0.45778(11) Uiso 0.0274(16) 16 1 d . . .
O15 O 0 0.6785(3) 0 Uiso 0.0274(16) 4 0.6667 d . . .
O16 O 0 0.3611(3) 0 Uiso 0.0274(16) 4 1 d . . .
O17 O 0 0.5221(5) 0.09006(16) Uiso 0.0274(16) 8 1 d . . .
O18 O 0.8052(3) 0.0144(5) 0.39376(9) Uiso 0.0274(16) 16 1 d . . .
F1 F 0 0.51979(10) 0 Uiso 0.110(14) 4 0.6667 d . . .
F2 F 0 0.5072(8) 0.22480(19) Uiso 0.110(14) 8 1 d . . .
Si9 Ge 0.28318(17) 0.74516(14) 0.01784(6) Uiso 0.0193(5) 16 0.3333 d . . .
O19 O 0.2827(7) 0.7448(9) 0.0707(3) Uiso 0.0274(16) 16 0.3333 d . . .
O20 F 0.3660(4) 0.6821(4) 0 Uiso 0.0274(16) 8 0.6667 d . . .
Ge10 Ge 0 0.6028(14) 0 Uiso 0.0193(5) 4 0.3333 d . . .
O21 O 0 0.722(7) 0 Uiso 0.0274(16) 4 0.3333 d . . .
O22 O 0 0.477(9) 0 Uiso 0.0274(16) 4 0.3333 d . . .
N1 N 0.5 0.1632(12) 0.39366(15) Uiso 0.146(7) 8 1 d . . .
N2 N 0.5 -0.2026(12) 0.39504(15) Uiso 0.146(7) 8 1 d . . .
C1 C 0.44489 0.2737(12) 0.35899(15) Uiso 0.146(7) 16 1 d . . .
C2 C 0.58777 0.2073(12) 0.38384(15) Uiso 0.146(7) 16 1 d . . .
C3 C 0.5 0.0945(12) 0.36831(15) Uiso 0.146(7) 8 1 d . . .
C4 C 0.41329 -0.2496(12) 0.38931(15) Uiso 0.146(7) 16 1 d . . .
C5 C 0.44473 -0.3265(12) 0.40213(15) Uiso 0.146(7) 16 1 d . . .
C6 C 0.5 -0.1404(12) 0.36498(15) Uiso 0.146(7) 8 1 d . . .
C7 C 0.5 0.1418(12) 0.43780(15) Uiso 0.146(7) 8 1 d . . .
C8 C 0.5 -0.1746(12) 0.43780(15) Uiso 0.146(7) 8 1 d . . .
C9 C 0.5 0.0589(12) 0.43780(15) Uiso 0.146(7) 8 1 d . . .
C10 C 0.41342 0.0213(12) 0.43780(15) Uiso 0.146(7) 16 1 d . . .
C11 C 0.41339 -0.0538(12) 0.43780(15) Uiso 0.146(7) 16 1 d . . .
C12 C 0.5 -0.0916(12) 0.43780(15) Uiso 0.146(7) 8 1 d . . .
H1a H 0.42137 0.3178(12) 0.37138(15) Uiso 0.175(9) 16 1 d . . .
H1b H 0.42136 0.2698(12) 0.33152(15) Uiso 0.175(9) 16 1 d . . .
H2a H 0.61833 0.2233(12) 0.40860(15) Uiso 0.175(9) 16 1 d . . .
H2b H 0.63191 0.1784(12) 0.36801(15) Uiso 0.175(9) 16 1 d . . .
H3a H 0.5 0.1073(12) 0.33990(15) Uiso 0.175(9) 8 1 d . . .
H3b H 0.44345 0.0661(12) 0.37436(15) Uiso 0.175(9) 16 1 d . . .
H4a H 0.39373 -0.2495(12) 0.36120(15) Uiso 0.175(9) 16 1 d . . .
H4b H 0.36164 -0.2328(12) 0.40641(15) Uiso 0.175(9) 16 1 d . . .
H5a H 0.42099 -0.3620(12) 0.38304(15) Uiso 0.175(9) 16 1 d . . .
H5b H 0.42113 -0.3372(12) 0.42906(15) Uiso 0.175(9) 16 1 d . . .
H6a H 0.5 -0.0947(12) 0.37954(15) Uiso 0.175(9) 8 1 d . . .
H6b H 0.44343 -0.1433(12) 0.34803(15) Uiso 0.175(9) 16 1 d . . .
H7 H 0.4432 0.1599(12) 0.45110(15) Uiso 0.175(9) 16 1 d . . .
H8 H 0.44354 -0.1919(12) 0.45171(15) Uiso 0.175(9) 16 1 d . . .
H10 H 0.35362 0.0477(12) 0.43780(15) Uiso 0.175(9) 16 1 d . . .
H11 H 0.35357 -0.0802(12) 0.43780(15) Uiso 0.175(9) 16 1 d . . .


#=======================================================================

# 10. MOLECULAR GEOMETRY


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ge1 O5 . 1_545 1.709(5) ?
Ge1 O6 . 3_655 1.715(4) ?
Ge1 O9 . 6_645 1.683(3) ?
Ge1 O10 . 10_655 1.709(4) ?
Ge2 O2 . 6_655 1.688(2) ?
Ge2 O3 . . 1.690(4) ?
Ge2 O5 . . 1.694(5) ?
Ge2 O7 . . 1.745(4) ?
Si3 O1 . 6_545 1.714(3) ?
Si3 O4 . . 1.669(4) ?
Si3 O6 . . 1.677(4) ?
Si3 O8 . . 1.708(4) ?
Ge3 O1 . 6_545 1.714(3) ?
Ge3 O4 . . 1.669(4) ?
Ge3 O6 . . 1.677(4) ?
Ge3 O8 . . 1.708(4) ?
Si4 O3 . 3_655 1.682(4) ?
Si4 O3 . 12_455 1.682(4) ?
Si4 O4 . 15_555 1.687(4) ?
Si4 O4 . 8_555 1.687(4) ?
Ge4 O3 . 3_655 1.682(4) ?
Ge4 O3 . 12_455 1.682(4) ?
Ge4 O4 . 15_555 1.687(4) ?
Ge4 O4 . 8_555 1.687(4) ?
Si5 O11 . . 1.648(9) ?
Si5 O14 . 10_555 1.685(4) ?
Si5 O14 . 11_554 1.685(4) ?
Si5 O15 . 13_545 1.649(5) ?
Ge5 O11 . . 1.648(9) ?
Ge5 O14 . 10_555 1.685(4) ?
Ge5 O14 . 11_554 1.685(4) ?
Ge5 O15 . 13_545 1.649(5) ?
Si6 O12 . . 1.663(7) ?
Si6 O13 . 10_655 1.651(4) ?
Si6 O13 . 11_654 1.651(4) ?
Si6 O16 . 13_555 1.681(7) ?
Ge6 O12 . . 1.663(7) ?
Ge6 O13 . 10_655 1.651(4) ?
Ge6 O13 . 11_654 1.651(4) ?
Ge6 O16 . 13_555 1.681(7) ?
Si7 O7 . 1_545 1.711(4) ?
Si7 O8 . 3_655 1.699(4) ?
Si7 O10 . . 1.699(3) ?
Si7 O18 . . 1.673(4) ?
Ge7 O7 . 1_545 1.711(4) ?
Ge7 O8 . 3_655 1.699(4) ?
Ge7 O10 . . 1.699(3) ?
Ge7 O18 . . 1.673(4) ?
Ge8 O13 . 1_545 1.636(4) ?
Ge8 O14 . 3_655 1.710(4) ?
Ge8 O17 . 6_645 1.704(3) ?
Ge8 O18 . . 1.674(4) ?
Si9 O11 . 14_555 1.651(7) ?
Si9 O12 . 2_655 1.709(6) ?
Si9 O19 . . 1.734(9) ?
Si9 O20 . . 1.732(7) ?
Ge10 O14 . 5_554 2.319(4) ?
Ge10 O14 . 6_555 2.319(4) ?
Ge10 O14 . 7_554 2.319(4) ?
Ge10 O14 . 8_555 2.319(4) ?
Ge10 O21 . . 2.19(14) ?
Ge10 O22 . . 2.31(16) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O5 Ge1 O6 1_545 . 3_655 112.2(2) ?
O5 Ge1 O9 1_545 . 6_645 110.7(3) ?
O5 Ge1 O10 1_545 . 10_655 107.2(3) ?
O6 Ge1 O9 3_655 . 6_645 112.8(3) ?
O6 Ge1 O10 3_655 . 10_655 107.2(3) ?
O9 Ge1 O10 6_645 . 10_655 106.4(2) ?
O2 Ge2 O3 6_655 . . 103.2(2) ?
O2 Ge2 O5 6_655 . . 112.2(3) ?
O2 Ge2 O7 6_655 . . 111.0(3) ?
O3 Ge2 O5 . . . 108.8(2) ?
O3 Ge2 O7 . . . 110.1(2) ?
O5 Ge2 O7 . . . 111.2(2) ?
O1 Si3 O4 6_545 . . 108.3(2) ?
O1 Si3 O6 6_545 . . 109.3(3) ?
O1 Si3 O8 6_545 . . 109.9(3) ?
O4 Si3 O6 . . . 109.1(2) ?
O4 Si3 O8 . . . 107.0(2) ?
O6 Si3 O8 . . . 113.1(2) ?
O1 Ge3 O4 6_545 . . 108.3(2) ?
O1 Ge3 O6 6_545 . . 109.3(3) ?
O1 Ge3 O8 6_545 . . 109.9(3) ?
O4 Ge3 O6 . . . 109.1(2) ?
O4 Ge3 O8 . . . 107.0(2) ?
O6 Ge3 O8 . . . 113.1(2) ?
O3 Si4 O3 3_655 . 12_455 110.3(2) ?
O3 Si4 O4 3_655 . 15_555 106.84(18) ?
O3 Si4 O4 3_655 . 8_555 110.73(16) ?
O3 Si4 O4 12_455 . 15_555 110.73(16) ?
O3 Si4 O4 12_455 . 8_555 106.84(18) ?
O4 Si4 O4 15_555 . 8_555 111.5(2) ?
O3 Ge4 O3 3_655 . 12_455 110.3(2) ?
O3 Ge4 O4 3_655 . 15_555 106.84(18) ?
O3 Ge4 O4 3_655 . 8_555 110.73(16) ?
O3 Ge4 O4 12_455 . 15_555 110.73(16) ?
O3 Ge4 O4 12_455 . 8_555 106.84(18) ?
O4 Ge4 O4 15_555 . 8_555 111.5(2) ?
O11 Si5 O14 . . 10_555 110.7(2) ?
O11 Si5 O14 . . 11_554 110.7(2) ?
O11 Si5 O15 . . 13_545 103.1(4) ?
O14 Si5 O14 10_555 . 11_554 110.4(2) ?
O14 Si5 O15 10_555 . 13_545 110.9(2) ?
O14 Si5 O15 11_554 . 13_545 110.9(2) ?
O11 Ge5 O14 . . 10_555 110.7(2) ?
O11 Ge5 O14 . . 11_554 110.7(2) ?
O11 Ge5 O15 . . 13_545 103.1(4) ?
O14 Ge5 O14 10_555 . 11_554 110.4(2) ?
O14 Ge5 O15 10_555 . 13_545 110.9(2) ?
O14 Ge5 O15 11_554 . 13_545 110.9(2) ?
O12 Si6 O13 . . 10_655 107.9(3) ?
O12 Si6 O13 . . 11_654 107.9(3) ?
O12 Si6 O16 . . 13_555 111.2(3) ?
O13 Si6 O13 10_655 . 11_654 111.3(2) ?
O13 Si6 O16 10_655 . 13_555 109.3(3) ?
O13 Si6 O16 11_654 . 13_555 109.3(3) ?
O12 Ge6 O13 . . 10_655 107.9(3) ?
O12 Ge6 O13 . . 11_654 107.9(3) ?
O12 Ge6 O16 . . 13_555 111.2(3) ?
O13 Ge6 O13 10_655 . 11_654 111.3(2) ?
O13 Ge6 O16 10_655 . 13_555 109.3(3) ?
O13 Ge6 O16 11_654 . 13_555 109.3(3) ?
O7 Si7 O8 1_545 . 3_655 109.2(2) ?
O7 Si7 O10 1_545 . . 110.4(3) ?
O7 Si7 O18 1_545 . . 110.8(3) ?
O8 Si7 O10 3_655 . . 110.8(3) ?
O8 Si7 O18 3_655 . . 110.0(3) ?
O10 Si7 O18 . . . 105.7(2) ?
O7 Ge7 O8 1_545 . 3_655 109.2(2) ?
O7 Ge7 O10 1_545 . . 110.4(3) ?
O7 Ge7 O18 1_545 . . 110.8(3) ?
O8 Ge7 O10 3_655 . . 110.8(3) ?
O8 Ge7 O18 3_655 . . 110.0(3) ?
O10 Ge7 O18 . . . 105.7(2) ?
O13 Ge8 O14 1_545 . 3_655 112.3(2) ?
O13 Ge8 O17 1_545 . 6_645 110.8(3) ?
O13 Ge8 O18 1_545 . . 105.6(3) ?
O14 Ge8 O17 3_655 . 6_645 110.3(3) ?
O14 Ge8 O18 3_655 . . 107.8(3) ?
O17 Ge8 O18 6_645 . . 109.9(2) ?
O11 Si9 O12 14_555 . 2_655 105.5(3) ?
O11 Si9 O19 14_555 . . 110.5(4) ?
O11 Si9 O20 14_555 . . 108.7(3) ?
O12 Si9 O19 2_655 . . 110.2(5) ?
O12 Si9 O20 2_655 . . 112.1(3) ?
O19 Si9 O20 . . . 109.7(5) ?
O14 Ge10 O14 5_554 . 6_555 175.7(13) ?
O14 Ge10 O14 5_554 . 7_554 106.56(14) ?
O14 Ge10 O14 5_554 . 8_555 73.27(13) ?
O14 Ge10 O21 5_554 . . 92.1(6) ?
O14 Ge10 O22 5_554 . . 87.9(6) ?
O14 Ge10 O14 6_555 . 7_554 73.27(13) ?
O14 Ge10 O14 6_555 . 8_555 106.56(14) ?
O14 Ge10 O21 6_555 . . 92.1(6) ?
O14 Ge10 O22 6_555 . . 87.9(6) ?
O14 Ge10 O14 7_554 . 8_555 175.7(13) ?
O14 Ge10 O21 7_554 . . 92.1(6) ?
O14 Ge10 O22 7_554 . . 87.9(6) ?
O14 Ge10 O21 8_555 . . 92.1(6) ?
O14 Ge10 O22 8_555 . . 87.9(6) ?
O21 Ge10 O22 . . . 180.0(5) ?

# start Validation Reply Form
_vrf_PLAT341_I                   
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PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.01854 Ang.  
RESPONSE: ...
;
_vrf_PLAT430_I                   
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PROBLEM: Short Inter D...A Contact  O11    ..  O15     ..       2.58 Ang.  
RESPONSE: It is a typical O...O distance for TO4 tetrahedra.
;
_vrf_PLAT431_I                   
;
PROBLEM: Short Inter HL..A  Contact F2     ..  O2      ..       2.60 Ang.  
RESPONSE: The F2 atom is located in a cage. The F...O distance is a typical value.
;
