# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_amj017
_database_code_depnum_ccdc_archive 'CCDC 1843710'
_audit_update_record             
;
2018-05-16 deposited with the CCDC.
2018-07-26 downloaded from the CCDC.
;


_vrf_THETM01_amj017              
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.550
RESPONSE: The crystal used was small. Data was collected with a Cu 
Source on a dual
source instrument containing a Cu-IuS source and Mo-sealed tube 
source. The geometry of the
instrument restricts maximum angle that could be collected with the 
Cu source to 120 degrees
two-theta.
;
# end Validation Reply Form</FONT></PRE>




_audit_creation_date             2017-10-02
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5335)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H36 N O P Rh Sb'
_chemical_formula_sum            'C33 H36 N O P Rh Sb'
_chemical_formula_weight         718.26
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.0562 5.8946 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.5285(2)
_cell_length_b                   14.0615(3)
_cell_length_c                   20.1189(4)
_cell_angle_alpha                90
_cell_angle_beta                 92.0040(10)
_cell_angle_gamma                90
_cell_volume                     2976.71(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9940
_cell_measurement_temperature    110.0
_cell_measurement_theta_max      61.954
_cell_measurement_theta_min      3.836
_shelx_estimated_absorpt_T_max   0.856
_shelx_estimated_absorpt_T_min   0.781
_exptl_absorpt_coefficient_mu    12.382
_exptl_absorpt_correction_T_max  0.3766
_exptl_absorpt_correction_T_min  0.2557
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1292 before and 0.0713 after correction. The Ratio of minimum to maximum transmission is 0.6790. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1440
_exptl_crystal_size_max          0.021
_exptl_crystal_size_mid          0.015
_exptl_crystal_size_min          0.013
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1114
_diffrn_reflns_av_unetI/netI     0.0343
_diffrn_reflns_Laue_measured_fraction_full 0.980
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            56253
_diffrn_reflns_point_group_measured_fraction_full 0.980
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        54.985
_diffrn_reflns_theta_max         54.985
_diffrn_reflns_theta_min         3.836
_diffrn_ambient_temperature      110.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_special_details          ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3043
_reflns_number_total             3662
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.495
_refine_diff_density_min         -0.405
_refine_diff_density_rms         0.085
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         3662
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0416
_refine_ls_R_factor_gt           0.0299
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0388P)²+3.2014P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0673
_refine_ls_wR_factor_ref         0.0730
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C15(H15), C18(H18)
2.b Aromatic/amide H refined with riding coordinates:
 C10(H10), C22(H22), C12(H12), C24(H24), C23(H23), C32(H32), C3(H3), C9(H9),
 C5(H5), C26(H26), C6(H6), C30(H30), C28(H28), C31(H31), C25(H25), C29(H29)
2.c Idealised Me refined as rotating group:
 C14(H14A,H14B,H14C), C16(H16A,H16B,H16C), C7(H7A,H7B,H7C), C20(H20A,H20B,
 H20C), C19(H19A,H19B,H19C), C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.38293(3) 0.36654(2) 0.17139(2) 0.02322(12) Uani 1 1 d . . . . .
Rh1 Rh 0.57056(4) 0.27237(3) 0.22121(2) 0.02320(13) Uani 1 1 d . . . . .
P1 P 0.69515(12) 0.18846(10) 0.29393(7) 0.0248(3) Uani 1 1 d . . . . .
O1 O 0.6777(4) 0.1954(3) 0.0969(2) 0.0367(10) Uani 1 1 d . . . . .
N1 N 0.5163(4) 0.3373(3) 0.3101(2) 0.0232(10) Uani 1 1 d . . . . .
C13 C 0.3116(5) 0.3964(4) 0.2665(2) 0.0224(12) Uani 1 1 d . . . . .
C8 C 0.3941(5) 0.3718(3) 0.3205(3) 0.0241(12) Uani 1 1 d . . . . .
C27 C 0.2245(5) 0.2910(4) 0.1262(2) 0.0239(12) Uani 1 1 d . . . . .
C10 C 0.2200(5) 0.4148(4) 0.3916(3) 0.0263(13) Uani 1 1 d . . . . .
H10 H 0.189070 0.419546 0.435281 0.032 Uiso 1 1 calc R . . . .
C22 C 0.3444(5) 0.5826(4) 0.1586(3) 0.0278(13) Uani 1 1 d . . . . .
H22 H 0.341696 0.578919 0.205628 0.033 Uiso 1 1 calc R . . . .
C12 C 0.1893(5) 0.4307(4) 0.2756(3) 0.0248(12) Uani 1 1 d . . . . .
H12 H 0.136978 0.446193 0.237711 0.030 Uiso 1 1 calc R . . . .
C2 C 0.7065(5) 0.2724(4) 0.3628(3) 0.0258(12) Uani 1 1 d . . . . .
C24 C 0.3324(5) 0.6744(4) 0.0594(3) 0.0309(13) Uani 1 1 d . . . . .
H24 H 0.320856 0.734017 0.037909 0.037 Uiso 1 1 calc R . . . .
C23 C 0.3296(5) 0.6693(4) 0.1276(3) 0.0276(13) Uani 1 1 d . . . . .
H23 H 0.317577 0.725259 0.153091 0.033 Uiso 1 1 calc R . . . .
C32 C 0.2154(5) 0.1955(4) 0.1409(3) 0.0287(13) Uani 1 1 d . . . . .
H32 H 0.278150 0.165712 0.168886 0.034 Uiso 1 1 calc R . . . .
C21 C 0.3632(5) 0.5009(4) 0.1223(3) 0.0243(12) Uani 1 1 d . . . . .
C11 C 0.1421(5) 0.4429(4) 0.3380(3) 0.0253(12) Uani 1 1 d . . . . .
C3 C 0.8045(5) 0.2738(4) 0.4108(3) 0.0293(13) Uani 1 1 d . . . . .
H3 H 0.867732 0.225550 0.410615 0.035 Uiso 1 1 calc R . . . .
C9 C 0.3416(5) 0.3801(3) 0.3833(3) 0.0236(12) Uani 1 1 d . . . . .
H9 H 0.390977 0.361224 0.421449 0.028 Uiso 1 1 calc R . . . .
C1 C 0.6103(5) 0.3407(4) 0.3611(3) 0.0253(13) Uani 1 1 d . . . . .
C5 C 0.7182(5) 0.4143(4) 0.4561(3) 0.0323(14) Uani 1 1 d . . . . .
H5 H 0.722323 0.464540 0.487665 0.039 Uiso 1 1 calc R . . . .
C15 C 0.8583(5) 0.1554(4) 0.2743(3) 0.0286(13) Uani 1 1 d . . . . .
H15 H 0.903680 0.137005 0.316851 0.034 Uiso 1 1 calc R . . . .
C26 C 0.3678(5) 0.5071(4) 0.0534(3) 0.0298(13) Uani 1 1 d . . . . .
H26 H 0.382025 0.451425 0.027967 0.036 Uiso 1 1 calc R . . . .
C6 C 0.6202(5) 0.4129(4) 0.4090(3) 0.0267(12) Uani 1 1 d . . . . .
H6 H 0.558048 0.461906 0.409044 0.032 Uiso 1 1 calc R . . . .
C14 C 0.0104(5) 0.4826(4) 0.3470(3) 0.0319(13) Uani 1 1 d . . . . .
H14A H -0.006928 0.485345 0.394453 0.048 Uiso 1 1 calc GR . . . .
H14B H -0.052416 0.441581 0.324153 0.048 Uiso 1 1 calc GR . . . .
H14C H 0.005257 0.546813 0.328035 0.048 Uiso 1 1 calc GR . . . .
C4 C 0.8117(5) 0.3441(4) 0.4588(3) 0.0298(13) Uani 1 1 d . . . . .
C16 C 0.9262(5) 0.2421(4) 0.2466(3) 0.0330(14) Uani 1 1 d . . . . .
H16A H 0.882699 0.262508 0.205180 0.050 Uiso 1 1 calc GR . . . .
H16B H 1.014382 0.225359 0.237757 0.050 Uiso 1 1 calc GR . . . .
H16C H 0.925072 0.293919 0.279127 0.050 Uiso 1 1 calc GR . . . .
C30 C 0.0215(5) 0.1874(4) 0.0753(3) 0.0365(15) Uani 1 1 d . . . . .
H30 H -0.049139 0.151733 0.058391 0.044 Uiso 1 1 calc R . . . .
C28 C 0.1338(5) 0.3350(4) 0.0857(3) 0.0326(14) Uani 1 1 d . . . . .
H28 H 0.141668 0.400524 0.075241 0.039 Uiso 1 1 calc R . . . .
C31 C 0.1137(5) 0.1435(4) 0.1146(3) 0.0351(15) Uani 1 1 d . . . . .
H31 H 0.107745 0.077371 0.123682 0.042 Uiso 1 1 calc R . . . .
C7 C 0.9196(5) 0.3463(4) 0.5100(3) 0.0368(14) Uani 1 1 d . . . . .
H7A H 0.957954 0.282970 0.513871 0.055 Uiso 1 1 calc GR . . . .
H7B H 0.887250 0.365354 0.553129 0.055 Uiso 1 1 calc GR . . . .
H7C H 0.983842 0.392131 0.496373 0.055 Uiso 1 1 calc GR . . . .
C25 C 0.3518(5) 0.5934(4) 0.0217(3) 0.0332(14) Uani 1 1 d . . . . .
H25 H 0.353962 0.597418 -0.025369 0.040 Uiso 1 1 calc R . . . .
C18 C 0.6225(5) 0.0792(4) 0.3277(3) 0.0320(13) Uani 1 1 d . . . . .
H18 H 0.614649 0.031763 0.290774 0.038 Uiso 1 1 calc R . . . .
C29 C 0.0309(5) 0.2831(4) 0.0604(3) 0.0350(14) Uani 1 1 d . . . . .
H29 H -0.032509 0.313078 0.032996 0.042 Uiso 1 1 calc R . . . .
C20 C 0.4882(5) 0.1030(4) 0.3495(3) 0.0400(15) Uani 1 1 d . . . . .
H20A H 0.492689 0.152664 0.383655 0.060 Uiso 1 1 calc GR . . . .
H20B H 0.448939 0.045851 0.367674 0.060 Uiso 1 1 calc GR . . . .
H20C H 0.436933 0.125638 0.311080 0.060 Uiso 1 1 calc GR . . . .
C19 C 0.7011(6) 0.0341(4) 0.3842(3) 0.0439(16) Uani 1 1 d . . . . .
H19A H 0.783776 0.014618 0.367854 0.066 Uiso 1 1 calc GR . . . .
H19B H 0.656349 -0.021734 0.400741 0.066 Uiso 1 1 calc GR . . . .
H19C H 0.713784 0.080288 0.420245 0.066 Uiso 1 1 calc GR . . . .
C17 C 0.8603(5) 0.0700(4) 0.2280(3) 0.0348(14) Uani 1 1 d . . . . .
H17A H 0.818532 0.015961 0.248879 0.052 Uiso 1 1 calc GR . . . .
H17B H 0.948544 0.053220 0.219232 0.052 Uiso 1 1 calc GR . . . .
H17C H 0.815210 0.085686 0.185975 0.052 Uiso 1 1 calc GR . . . .
C33 C 0.6340(5) 0.2230(4) 0.1446(3) 0.0280(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Rh1 2.5539(5) . ?
Sb1 C13 2.121(5) . ?
Sb1 C27 2.152(5) . ?
Sb1 C21 2.139(5) . ?
Rh1 P1 2.2626(14) . ?
Rh1 N1 2.105(4) . ?
Rh1 C33 1.838(6) . ?
P1 C2 1.821(5) . ?
P1 C15 1.836(5) . ?
P1 C18 1.855(6) . ?
O1 C33 1.146(7) . ?
N1 C8 1.398(7) . ?
N1 C1 1.401(7) . ?
C13 C8 1.411(7) . ?
C13 C12 1.393(7) . ?
C8 C9 1.401(7) . ?
C27 C32 1.378(8) . ?
C27 C28 1.380(8) . ?
C10 H10 0.9500 . ?
C10 C11 1.389(7) . ?
C10 C9 1.385(7) . ?
C22 H22 0.9500 . ?
C22 C23 1.376(8) . ?
C22 C21 1.379(8) . ?
C12 H12 0.9500 . ?
C12 C11 1.377(7) . ?
C2 C3 1.388(8) . ?
C2 C1 1.395(8) . ?
C24 H24 0.9500 . ?
C24 C23 1.374(8) . ?
C24 C25 1.387(8) . ?
C23 H23 0.9500 . ?
C32 H32 0.9500 . ?
C32 C31 1.386(8) . ?
C21 C26 1.391(7) . ?
C11 C14 1.512(7) . ?
C3 H3 0.9500 . ?
C3 C4 1.383(8) . ?
C9 H9 0.9500 . ?
C1 C6 1.402(8) . ?
C5 H5 0.9500 . ?
C5 C6 1.376(8) . ?
C5 C4 1.394(8) . ?
C15 H15 1.0000 . ?
C15 C16 1.527(8) . ?
C15 C17 1.521(8) . ?
C26 H26 0.9500 . ?
C26 C25 1.378(8) . ?
C6 H6 0.9500 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C4 C7 1.507(8) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C30 H30 0.9500 . ?
C30 C31 1.377(9) . ?
C30 C29 1.383(8) . ?
C28 H28 0.9500 . ?
C28 C29 1.388(8) . ?
C31 H31 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C25 H25 0.9500 . ?
C18 H18 1.0000 . ?
C18 C20 1.532(8) . ?
C18 C19 1.520(8) . ?
C29 H29 0.9500 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 Sb1 Rh1 92.41(14) . . ?
C13 Sb1 C27 100.67(19) . . ?
C13 Sb1 C21 102.1(2) . . ?
C27 Sb1 Rh1 119.16(14) . . ?
C21 Sb1 Rh1 134.47(13) . . ?
C21 Sb1 C27 100.3(2) . . ?
P1 Rh1 Sb1 161.30(4) . . ?
N1 Rh1 Sb1 83.08(11) . . ?
N1 Rh1 P1 81.09(11) . . ?
C33 Rh1 Sb1 99.52(16) . . ?
C33 Rh1 P1 97.23(16) . . ?
C33 Rh1 N1 173.8(2) . . ?
C2 P1 Rh1 100.09(18) . . ?
C2 P1 C15 106.9(2) . . ?
C2 P1 C18 106.0(3) . . ?
C15 P1 Rh1 121.22(19) . . ?
C15 P1 C18 105.7(3) . . ?
C18 P1 Rh1 115.56(18) . . ?
C8 N1 Rh1 123.8(3) . . ?
C8 N1 C1 120.6(4) . . ?
C1 N1 Rh1 115.6(3) . . ?
C8 C13 Sb1 114.7(4) . . ?
C12 C13 Sb1 123.1(4) . . ?
C12 C13 C8 122.0(5) . . ?
N1 C8 C13 121.0(5) . . ?
N1 C8 C9 124.0(5) . . ?
C9 C8 C13 115.0(5) . . ?
C32 C27 Sb1 116.6(4) . . ?
C32 C27 C28 120.8(5) . . ?
C28 C27 Sb1 122.6(4) . . ?
C11 C10 H10 119.0 . . ?
C9 C10 H10 119.0 . . ?
C9 C10 C11 121.9(5) . . ?
C23 C22 H22 119.5 . . ?
C23 C22 C21 121.0(5) . . ?
C21 C22 H22 119.5 . . ?
C13 C12 H12 119.1 . . ?
C11 C12 C13 121.8(5) . . ?
C11 C12 H12 119.1 . . ?
C3 C2 P1 124.4(4) . . ?
C3 C2 C1 121.9(5) . . ?
C1 C2 P1 113.5(4) . . ?
C23 C24 H24 119.6 . . ?
C23 C24 C25 120.8(5) . . ?
C25 C24 H24 119.6 . . ?
C22 C23 H23 120.3 . . ?
C24 C23 C22 119.4(5) . . ?
C24 C23 H23 120.3 . . ?
C27 C32 H32 120.3 . . ?
C27 C32 C31 119.4(5) . . ?
C31 C32 H32 120.3 . . ?
C22 C21 Sb1 120.3(4) . . ?
C22 C21 C26 119.0(5) . . ?
C26 C21 Sb1 120.7(4) . . ?
C10 C11 C14 122.1(5) . . ?
C12 C11 C10 116.8(5) . . ?
C12 C11 C14 121.1(5) . . ?
C2 C3 H3 119.4 . . ?
C4 C3 C2 121.1(5) . . ?
C4 C3 H3 119.4 . . ?
C8 C9 H9 118.9 . . ?
C10 C9 C8 122.3(5) . . ?
C10 C9 H9 118.9 . . ?
N1 C1 C6 124.2(5) . . ?
C2 C1 N1 119.2(5) . . ?
C2 C1 C6 116.4(5) . . ?
C6 C5 H5 119.0 . . ?
C6 C5 C4 121.9(5) . . ?
C4 C5 H5 119.0 . . ?
P1 C15 H15 107.7 . . ?
C16 C15 P1 109.3(4) . . ?
C16 C15 H15 107.7 . . ?
C17 C15 P1 111.4(4) . . ?
C17 C15 H15 107.7 . . ?
C17 C15 C16 113.0(5) . . ?
C21 C26 H26 119.7 . . ?
C25 C26 C21 120.5(5) . . ?
C25 C26 H26 119.7 . . ?
C1 C6 H6 119.4 . . ?
C5 C6 C1 121.3(5) . . ?
C5 C6 H6 119.4 . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C3 C4 C5 117.2(5) . . ?
C3 C4 C7 121.0(5) . . ?
C5 C4 C7 121.8(5) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C31 C30 H30 119.8 . . ?
C31 C30 C29 120.4(5) . . ?
C29 C30 H30 119.8 . . ?
C27 C28 H28 120.1 . . ?
C27 C28 C29 119.7(5) . . ?
C29 C28 H28 120.1 . . ?
C32 C31 H31 119.9 . . ?
C30 C31 C32 120.2(6) . . ?
C30 C31 H31 119.9 . . ?
C4 C7 H7A 109.5 . . ?
C4 C7 H7B 109.5 . . ?
C4 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C24 C25 H25 120.4 . . ?
C26 C25 C24 119.2(5) . . ?
C26 C25 H25 120.4 . . ?
P1 C18 H18 107.8 . . ?
C20 C18 P1 108.7(4) . . ?
C20 C18 H18 107.8 . . ?
C19 C18 P1 113.5(4) . . ?
C19 C18 H18 107.8 . . ?
C19 C18 C20 111.2(5) . . ?
C30 C29 C28 119.5(5) . . ?
C30 C29 H29 120.2 . . ?
C28 C29 H29 120.2 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O1 C33 Rh1 176.9(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Sb1 C13 C8 N1 4.6(6) . . . . ?
Sb1 C13 C8 C9 -172.3(3) . . . . ?
Sb1 C13 C12 C11 175.1(4) . . . . ?
Sb1 C27 C32 C31 178.5(4) . . . . ?
Sb1 C27 C28 C29 -177.2(4) . . . . ?
Sb1 C21 C26 C25 178.3(4) . . . . ?
Rh1 P1 C2 C3 -156.3(4) . . . . ?
Rh1 P1 C2 C1 19.9(4) . . . . ?
Rh1 P1 C15 C16 46.6(4) . . . . ?
Rh1 P1 C15 C17 -78.9(4) . . . . ?
Rh1 P1 C18 C20 -46.6(4) . . . . ?
Rh1 P1 C18 C19 -170.8(4) . . . . ?
Rh1 N1 C8 C13 -22.8(7) . . . . ?
Rh1 N1 C8 C9 153.8(4) . . . . ?
Rh1 N1 C1 C2 -26.3(6) . . . . ?
Rh1 N1 C1 C6 149.2(4) . . . . ?
P1 C2 C3 C4 175.2(4) . . . . ?
P1 C2 C1 N1 1.7(6) . . . . ?
P1 C2 C1 C6 -174.1(4) . . . . ?
N1 C8 C9 C10 179.9(5) . . . . ?
N1 C1 C6 C5 -177.1(5) . . . . ?
C13 C8 C9 C10 -3.3(7) . . . . ?
C13 C12 C11 C10 -3.1(7) . . . . ?
C13 C12 C11 C14 178.4(5) . . . . ?
C8 N1 C1 C2 151.1(5) . . . . ?
C8 N1 C1 C6 -33.5(7) . . . . ?
C8 C13 C12 C11 0.2(8) . . . . ?
C27 C32 C31 C30 -1.4(8) . . . . ?
C27 C28 C29 C30 -0.9(8) . . . . ?
C22 C21 C26 C25 -1.0(8) . . . . ?
C12 C13 C8 N1 179.9(5) . . . . ?
C12 C13 C8 C9 3.0(7) . . . . ?
C2 P1 C15 C16 -66.9(4) . . . . ?
C2 P1 C15 C17 167.6(4) . . . . ?
C2 P1 C18 C20 63.2(4) . . . . ?
C2 P1 C18 C19 -61.0(5) . . . . ?
C2 C3 C4 C5 -1.3(8) . . . . ?
C2 C3 C4 C7 -178.8(5) . . . . ?
C2 C1 C6 C5 -1.6(8) . . . . ?
C23 C22 C21 Sb1 -179.0(4) . . . . ?
C23 C22 C21 C26 0.3(8) . . . . ?
C23 C24 C25 C26 0.3(8) . . . . ?
C32 C27 C28 C29 1.1(8) . . . . ?
C21 C22 C23 C24 0.6(8) . . . . ?
C21 C26 C25 C24 0.7(8) . . . . ?
C11 C10 C9 C8 0.6(8) . . . . ?
C3 C2 C1 N1 177.9(5) . . . . ?
C3 C2 C1 C6 2.2(8) . . . . ?
C9 C10 C11 C12 2.7(7) . . . . ?
C9 C10 C11 C14 -178.7(5) . . . . ?
C1 N1 C8 C13 160.1(5) . . . . ?
C1 N1 C8 C9 -23.3(7) . . . . ?
C1 C2 C3 C4 -0.7(8) . . . . ?
C15 P1 C2 C3 -29.1(5) . . . . ?
C15 P1 C2 C1 147.1(4) . . . . ?
C15 P1 C18 C20 176.4(4) . . . . ?
C15 P1 C18 C19 52.2(5) . . . . ?
C6 C5 C4 C3 1.9(8) . . . . ?
C6 C5 C4 C7 179.4(5) . . . . ?
C4 C5 C6 C1 -0.4(8) . . . . ?
C28 C27 C32 C31 0.1(8) . . . . ?
C31 C30 C29 C28 -0.5(8) . . . . ?
C25 C24 C23 C22 -1.0(8) . . . . ?
C18 P1 C2 C3 83.3(5) . . . . ?
C18 P1 C2 C1 -100.5(4) . . . . ?
C18 P1 C15 C16 -179.4(4) . . . . ?
C18 P1 C15 C17 55.0(5) . . . . ?
C29 C30 C31 C32 1.7(8) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
