# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx_sq
_database_code_depnum_ccdc_archive 'CCDC 1884067'
_audit_update_record             
;
2018-12-10 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C38 H22 Eu2 N2 O16'
_chemical_formula_weight         1066.49

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.2685(5)
_cell_length_b                   14.6954(11)
_cell_length_c                   19.3575(17)
_cell_angle_alpha                78.962(6)
_cell_angle_beta                 79.280(5)
_cell_angle_gamma                75.788(5)
_cell_volume                     1946.2(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    213(2)
_cell_measurement_reflns_used    6401
_cell_measurement_theta_min      3.2
_cell_measurement_theta_max      27.5

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.820
_exptl_crystal_F_000             1036
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.160
_exptl_absorpt_coefficient_mu    3.269
_shelx_estimated_absorpt_T_min   0.561
_shelx_estimated_absorpt_T_max   0.623
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5609
_exptl_absorpt_correction_T_max  0.6951
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      213(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'rotating anode'
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            21223
_diffrn_reflns_av_unetI/netI     0.0260
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.242
_diffrn_reflns_theta_max         25.008
_diffrn_reflns_theta_full        25.008
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.987
_reflns_number_total             6783
_reflns_number_gt                6100
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)'
_computing_cell_refinement       'CrystalClear-SM Expert 2.1 b42'
_computing_data_reduction        'CrystalClear-SM Expert 2.1 b42'
_computing_structure_solution    'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0461P)²+2.7481P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6783
_refine_ls_number_parameters     687
_refine_ls_number_restraints     2508
_refine_ls_R_factor_all          0.0208
_refine_ls_R_factor_gt           0.0184
_refine_ls_wR_factor_ref         0.0557
_refine_ls_wR_factor_gt          0.0542
_refine_ls_goodness_of_fit_ref   0.805
_refine_ls_restrained_S_all      0.754
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.06734(2) 0.74216(2) 0.21058(2) 0.01235(5) Uani 1 1 d . U . . .
Eu2 Eu 0.52000(2) 0.75818(2) 0.28950(2) 0.01240(5) Uani 1 1 d . U . . .
N1 N -0.0881(8) 0.1445(4) 0.0278(2) 0.0353(14) Uani 0.813(4) 1 d D U P A 1
N2 N 0.5879(10) 1.3554(4) 0.4714(3) 0.0374(16) Uani 0.770(4) 1 d D U P B 1
N1' N -0.045(5) 0.1399(19) 0.0265(9) 0.040(4) Uani 0.187(4) 1 d D U P A 2
N2' N 0.619(4) 1.3591(17) 0.4718(8) 0.040(3) Uani 0.230(4) 1 d D U P B 2
O1 O 0.0519(3) 0.57738(15) 0.20104(14) 0.0309(5) Uani 1 1 d . U . . .
O2 O -0.2283(3) 0.67471(13) 0.21213(10) 0.0163(4) Uani 1 1 d . U . . .
O3 O -0.6095(3) 0.65319(13) 0.24139(10) 0.0160(4) Uani 1 1 d . U . . .
O4 O -0.6437(3) 0.66299(16) 0.12991(11) 0.0247(5) Uani 1 1 d . U . . .
O5 O -0.4323(5) 0.3113(3) 0.1304(3) 0.0662(11) Uani 0.813(4) 1 d . U P A 1
O5' O -0.0241(19) 0.2713(10) 0.1634(9) 0.045(2) Uani 0.187(4) 1 d . U P A 2
O6 O 0.6494(3) 0.83850(16) 0.36975(12) 0.0260(5) Uani 1 1 d . U . . .
O7 O 0.7855(3) 0.84713(13) 0.25814(10) 0.0162(4) Uani 1 1 d . U . . .
O8 O 1.1585(3) 0.82574(13) 0.28785(11) 0.0169(4) Uani 1 1 d . U . . .
O9 O 1.3315(3) 0.92321(15) 0.29821(14) 0.0305(5) Uani 1 1 d . U . . .
O10 O 0.5131(5) 1.1911(3) 0.3654(3) 0.0642(11) Uani 0.770(4) 1 d . U P B 1
O10' O 0.9139(16) 1.2310(8) 0.3335(7) 0.046(2) Uani 0.230(4) 1 d . U P B 2
O11 O 0.0115(3) 0.66610(14) 0.33282(11) 0.0221(4) Uani 1 1 d . U . . .
O12 O -0.2814(3) 0.63665(15) 0.36144(11) 0.0239(5) Uani 1 1 d . U . . .
O13 O 0.5109(3) 0.83347(14) 0.16695(11) 0.0219(4) Uani 1 1 d . U . . .
O14 O 0.2156(3) 0.86458(15) 0.13912(11) 0.0240(5) Uani 1 1 d . U . . .
O15 O -0.0867(3) 0.80322(18) 0.10831(12) 0.0331(5) Uani 1 1 d . U . . .
H15A H -0.186298 0.780868 0.112615 0.050 Uiso 1 1 d R U . . .
H15C H -0.010157 0.786948 0.071675 0.050 Uiso 1 1 d R U . . .
O16 O 0.3242(3) 0.69725(18) 0.39176(12) 0.0335(6) Uani 1 1 d . U . . .
H16A H 0.380378 0.688879 0.428001 0.050 Uiso 1 1 d R U . . .
H16B H 0.217508 0.736647 0.397861 0.050 Uiso 1 1 d R U . . .
C1 C -0.1247(4) 0.5937(2) 0.20154(16) 0.0201(6) Uani 1 1 d . U . . .
C2 C -0.2133(4) 0.5191(2) 0.18718(19) 0.0266(7) Uani 1 1 d . U . . .
C3 C -0.0962(5) 0.4295(3) 0.1821(2) 0.0419(9) Uani 1 1 d . U . . .
H3 H 0.030822 0.417431 0.191196 0.050 Uiso 1 1 calc R U . . .
C4 C -0.1618(6) 0.3580(3) 0.1640(3) 0.0513(10) Uani 1 1 d . U . . .
H4 H -0.081304 0.297514 0.161813 0.062 Uiso 0.813(4) 1 calc R U P A 1
C5 C -0.3473(5) 0.3763(3) 0.1492(3) 0.0477(10) Uani 1 1 d . U . . .
H5 H -0.391871 0.328460 0.135552 0.057 Uiso 0.187(4) 1 calc R U P A 2
C6 C -0.4682(5) 0.4645(3) 0.1541(2) 0.0375(8) Uani 1 1 d . U . . .
H6 H -0.594175 0.476159 0.143968 0.045 Uiso 1 1 calc R U . . .
C7 C -0.4034(4) 0.5357(2) 0.17419(18) 0.0242(6) Uani 1 1 d . U . . .
C8 C -0.5560(4) 0.6248(2) 0.18029(16) 0.0188(6) Uani 1 1 d . U . . .
C9 C -0.3134(6) 0.2270(3) 0.1129(3) 0.0454(11) Uani 0.813(4) 1 d D U P A 1
C10 C -0.1992(7) 0.2260(3) 0.0479(3) 0.0440(11) Uani 0.813(4) 1 d D U P A 1
H10 H -0.198280 0.283439 0.016614 0.053 Uiso 0.813(4) 1 calc R U P A 1
C11 C -0.0933(8) 0.0634(3) 0.0736(3) 0.0308(13) Uani 0.813(4) 1 d D U P A 1
H11 H -0.011631 0.006552 0.061729 0.037 Uiso 0.813(4) 1 calc R U P A 1
C13 C -0.2143(8) 0.0613(3) 0.1372(3) 0.0400(15) Uani 0.813(4) 1 d D U P A 1
H13 H -0.221412 0.002916 0.166290 0.048 Uiso 0.813(4) 1 calc R U P A 1
C14 C -0.3243(7) 0.1437(3) 0.1583(3) 0.0483(12) Uani 0.813(4) 1 d D U P A 1
H14 H -0.404718 0.143342 0.202321 0.058 Uiso 0.813(4) 1 calc R U P A 1
C15 C 0.7494(4) 0.8763(2) 0.31927(16) 0.0177(6) Uani 1 1 d . U . . .
C16 C 0.8076(4) 0.9655(2) 0.32456(17) 0.0235(6) Uani 1 1 d . U . . .
C17 C 0.6530(5) 1.0374(3) 0.3436(2) 0.0367(8) Uani 1 1 d . U . . .
H17 H 0.528417 1.025878 0.353735 0.044 Uiso 1 1 calc R U . . .
C18 C 0.6812(5) 1.1259(3) 0.3477(3) 0.0455(9) Uani 1 1 d . U . . .
H18 H 0.575653 1.174248 0.360538 0.055 Uiso 0.230(4) 1 calc R U P B 2
C19 C 0.8635(5) 1.1434(3) 0.3332(3) 0.0464(9) Uani 1 1 d . U . . .
H19 H 0.882215 1.203886 0.335043 0.056 Uiso 0.770(4) 1 calc R U P B 1
C20 C 1.0178(5) 1.0717(2) 0.3159(2) 0.0372(8) Uani 1 1 d . U . . .
H20 H 1.141913 1.083782 0.306629 0.045 Uiso 1 1 calc R U . . .
C21 C 0.9942(4) 0.9819(2) 0.31183(18) 0.0245(6) Uani 1 1 d . U . . .
C22 C 1.1719(4) 0.9069(2) 0.29774(16) 0.0187(6) Uani 1 1 d . U . . .
C23 C 0.5300(7) 1.2748(3) 0.3849(3) 0.0451(12) Uani 0.770(4) 1 d D U P B 1
C24 C 0.5790(7) 1.2744(3) 0.4504(3) 0.0419(11) Uani 0.770(4) 1 d D U P B 1
H24 H 0.606859 1.216522 0.481105 0.050 Uiso 0.770(4) 1 calc R U P B 1
C26 C 0.5463(8) 1.4373(4) 0.4267(3) 0.0297(15) Uani 0.770(4) 1 d D U P B 1
H26 H 0.558045 1.493828 0.439620 0.036 Uiso 0.770(4) 1 calc R U P B 1
C27 C 0.4869(10) 1.4408(4) 0.3625(3) 0.0423(18) Uani 0.770(4) 1 d D U P B 1
H27 H 0.451404 1.499610 0.333728 0.051 Uiso 0.770(4) 1 calc R U P B 1
C28 C 0.4797(8) 1.3587(3) 0.3408(3) 0.0480(12) Uani 0.770(4) 1 d D U P B 1
H28 H 0.441278 1.359830 0.296796 0.058 Uiso 0.770(4) 1 calc R U P B 1
C29 C -0.1132(4) 0.6261(2) 0.37255(15) 0.0181(6) Uani 1 1 d . U . . .
C30 C -0.0546(4) 0.5613(2) 0.43873(16) 0.0194(6) Uani 1 1 d . U . . .
C31 C -0.0580(5) 0.5982(2) 0.49990(17) 0.0276(7) Uani 1 1 d . U . . .
H31 H -0.096890 0.663980 0.500379 0.033 Uiso 1 1 d R U . . .
C32 C -0.1179(12) 0.7040(5) 0.5045(4) 0.0399(16) Uani 0.5 1 d . U P . .
C33 C -0.1137(15) 0.7376(6) 0.5642(5) 0.055(2) Uani 0.5 1 d . U P . .
C34 C 0.0024(5) 0.4643(2) 0.43815(18) 0.0283(7) Uani 1 1 d . U . . .
H34 H 0.003720 0.439587 0.396651 0.034 Uiso 1 1 d R U . . .
C35 C 0.3849(4) 0.87415(19) 0.12747(15) 0.0171(6) Uani 1 1 d . U . . .
C36 C 0.4450(4) 0.9390(2) 0.06133(15) 0.0188(6) Uani 1 1 d . U . . .
C37 C 0.4023(5) 1.0360(2) 0.06147(18) 0.0271(7) Uani 1 1 d . U . . .
H37 H 0.336261 1.060591 0.102781 0.033 Uiso 1 1 d R U . . .
C38 C 0.3014(12) 1.0797(5) 0.1277(4) 0.0400(17) Uani 0.5 1 d . U P . .
C39 C 0.2566(14) 1.1753(6) 0.1253(4) 0.053(2) Uani 0.5 1 d . U P . .
C40 C 0.5434(5) 0.9015(2) 0.00039(17) 0.0263(7) Uani 1 1 d . U . . .
H40 H 0.573154 0.835606 0.000190 0.032 Uiso 1 1 d R U . . .
C9' C -0.069(3) 0.2034(11) 0.1324(8) 0.042(3) Uani 0.187(4) 1 d D U P A 2
C10' C -0.014(3) 0.2075(12) 0.0605(9) 0.042(3) Uani 0.187(4) 1 d D U P A 2
H10' H 0.044805 0.256258 0.034468 0.051 Uiso 0.187(4) 1 calc R U P A 2
C11' C -0.132(5) 0.0696(17) 0.0652(11) 0.036(4) Uani 0.187(4) 1 d D U P A 2
H11' H -0.172215 0.029122 0.041715 0.043 Uiso 0.187(4) 1 calc R U P A 2
C13' C -0.160(4) 0.0580(13) 0.1381(11) 0.040(3) Uani 0.187(4) 1 d D U P A 2
H13' H -0.185554 0.000698 0.164819 0.047 Uiso 0.187(4) 1 calc R U P A 2
C14' C -0.151(3) 0.1309(12) 0.1717(9) 0.046(3) Uani 0.187(4) 1 d D U P A 2
H14' H -0.200092 0.131266 0.220164 0.056 Uiso 0.187(4) 1 calc R U P A 2
C23' C 0.7707(19) 1.2975(8) 0.3656(7) 0.039(2) Uani 0.230(4) 1 d D U P B 2
C24' C 0.755(2) 1.2934(9) 0.4378(7) 0.042(3) Uani 0.230(4) 1 d D U P B 2
H24' H 0.836769 1.245127 0.463968 0.051 Uiso 0.230(4) 1 calc R U P B 2
C26' C 0.503(3) 1.4300(14) 0.4330(10) 0.035(4) Uani 0.230(4) 1 d D U P B 2
H26' H 0.403856 1.472809 0.456401 0.041 Uiso 0.230(4) 1 calc R U P B 2
C27' C 0.530(4) 1.4391(15) 0.3603(10) 0.042(3) Uani 0.230(4) 1 d D U P B 2
H27' H 0.460968 1.492605 0.333514 0.050 Uiso 0.230(4) 1 calc R U P B 2
C28' C 0.657(2) 1.3700(10) 0.3267(7) 0.045(3) Uani 0.230(4) 1 d D U P B 2
H28' H 0.665655 1.372278 0.277398 0.054 Uiso 0.230(4) 1 calc R U P B 2
C32' C 0.0149(13) 0.4212(5) 0.3711(4) 0.0412(17) Uani 0.5 1 d . U P . .
C33' C 0.0664(15) 0.3249(6) 0.3727(5) 0.056(2) Uani 0.5 1 d . U P . .
C38' C 0.5948(11) 0.7957(5) -0.0036(4) 0.0384(16) Uani 0.5 1 d . U P . .
C39' C 0.6985(14) 0.7618(6) -0.0635(5) 0.052(2) Uani 0.5 1 d . U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O15 2.373(2) . ?
Eu1 O8 2.3783(19) 1_455 ?
Eu1 O7 2.3903(18) 1_455 ?
Eu1 O14 2.3993(19) . ?
Eu1 O11 2.4220(19) . ?
Eu1 O1 2.494(2) . ?
Eu1 O3 2.5095(18) 1_655 ?
Eu1 O4 2.545(2) 1_655 ?
Eu1 O2 2.5710(18) . ?
Eu1 C8 2.878(3) 1_655 ?
Eu1 C1 2.910(3) . ?
Eu1 Eu2 3.9500(3) . ?
Eu1 H15A 2.7733 . ?
Eu1 H15C 2.7720 . ?
Eu2 O16 2.376(2) . ?
Eu2 O2 2.3827(19) 1_655 ?
Eu2 O3 2.3922(18) 1_655 ?
Eu2 O12 2.3963(19) 1_655 ?
Eu2 O13 2.4235(19) . ?
Eu2 O9 2.495(2) 1_455 ?
Eu2 O7 2.5101(18) . ?
Eu2 O6 2.546(2) . ?
Eu2 O8 2.5748(19) 1_455 ?
Eu2 C15 2.878(3) . ?
Eu2 C22 2.910(3) 1_455 ?
Eu2 H16A 2.7757 . ?
Eu2 H16B 2.7760 . ?
N1 C11 1.346(5) . ?
N1 C10 1.351(6) . ?
N2 C26 1.345(6) . ?
N2 C24 1.349(7) . ?
N1' C11' 1.369(9) . ?
N1' C10' 1.373(9) . ?
N2' C24' 1.367(9) . ?
N2' C26' 1.368(9) . ?
O1 C1 1.245(4) . ?
O2 C1 1.273(3) . ?
O3 C8 1.289(4) . ?
O4 C8 1.232(4) . ?
O5 C9 1.387(5) . ?
O5 C5 1.391(5) . ?
O5' C9' 1.389(18) . ?
O5' C4 1.414(14) . ?
O6 C15 1.232(4) . ?
O7 C15 1.294(3) . ?
O8 C22 1.272(3) . ?
O9 C22 1.243(3) . ?
O10 C18 1.386(5) . ?
O10 C23 1.394(5) . ?
O10' C23' 1.384(15) . ?
O10' C19 1.424(11) . ?
O11 C29 1.261(3) . ?
O12 C29 1.247(3) . ?
O13 C35 1.264(3) . ?
O14 C35 1.247(3) . ?
O15 H15A 0.8501 . ?
O15 H15C 0.8501 . ?
O16 H16A 0.8501 . ?
O16 H16B 0.8499 . ?
C1 C2 1.492(4) . ?
C2 C3 1.391(4) . ?
C2 C7 1.405(4) . ?
C3 C4 1.380(5) . ?
C3 H3 0.9400 . ?
C4 C5 1.382(6) . ?
C4 H4 0.9400 . ?
C5 C6 1.384(5) . ?
C5 H5 0.9400 . ?
C6 C7 1.391(4) . ?
C6 H6 0.9400 . ?
C7 C8 1.502(4) . ?
C9 C14 1.373(6) . ?
C9 C10 1.374(6) . ?
C10 H10 0.9400 . ?
C11 C13 1.372(5) . ?
C11 H11 0.9400 . ?
C13 C14 1.365(6) . ?
C13 H13 0.9400 . ?
C14 H14 0.9400 . ?
C15 C16 1.501(4) . ?
C16 C17 1.388(4) . ?
C16 C21 1.404(4) . ?
C17 C18 1.385(5) . ?
C17 H17 0.9400 . ?
C18 C19 1.379(5) . ?
C18 H18 0.9400 . ?
C19 C20 1.376(5) . ?
C19 H19 0.9400 . ?
C20 C21 1.390(4) . ?
C20 H20 0.9400 . ?
C21 C22 1.498(4) . ?
C23 C28 1.370(6) . ?
C23 C24 1.378(6) . ?
C24 H24 0.9400 . ?
C26 C27 1.376(6) . ?
C26 H26 0.9400 . ?
C27 C28 1.368(7) . ?
C27 H27 0.9400 . ?
C28 H28 0.9400 . ?
C29 C30 1.505(4) . ?
C30 C34 1.386(4) . ?
C30 C31 1.387(5) . ?
C31 C34 1.421(4) 2_566 ?
C31 C32 1.524(7) . ?
C31 H31 0.9400 . ?
C32 C33 1.349(12) . ?
C32 H31 0.5878 . ?
C33 C33' 1.423(12) 2_566 ?
C34 C32' 1.528(8) . ?
C34 H34 0.9400 . ?
C35 C36 1.506(4) . ?
C36 C37 1.382(4) . ?
C36 C40 1.396(5) . ?
C37 C40 1.419(4) 2_675 ?
C37 C38 1.526(8) . ?
C37 H37 0.9400 . ?
C38 C39 1.356(11) . ?
C38 H37 0.5889 . ?
C39 C39' 1.404(12) 2_675 ?
C40 C38' 1.522(7) . ?
C40 H40 0.9400 . ?
C9' C10' 1.369(10) . ?
C9' C14' 1.380(10) . ?
C10' H10' 0.9400 . ?
C11' C13' 1.370(9) . ?
C11' H11' 0.9400 . ?
C13' C14' 1.375(9) . ?
C13' H13' 0.9400 . ?
C14' H14' 0.9400 . ?
C23' C28' 1.370(8) . ?
C23' C24' 1.372(8) . ?
C24' H24' 0.9400 . ?
C26' C27' 1.370(9) . ?
C26' H26' 0.9400 . ?
C27' C28' 1.369(9) . ?
C27' H27' 0.9400 . ?
C28' H28' 0.9400 . ?
C32' C33' 1.368(11) . ?
C32' H34 0.5910 . ?
C38' C39' 1.369(11) . ?
C38' H40 0.5841 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Eu1 O8 129.07(8) . 1_455 ?
O15 Eu1 O7 78.65(8) . 1_455 ?
O8 Eu1 O7 72.07(6) 1_455 1_455 ?
O15 Eu1 O14 70.92(7) . . ?
O8 Eu1 O14 71.70(7) 1_455 . ?
O7 Eu1 O14 95.83(7) 1_455 . ?
O15 Eu1 O11 142.00(7) . . ?
O8 Eu1 O11 69.59(7) 1_455 . ?
O7 Eu1 O11 77.78(7) 1_455 . ?
O14 Eu1 O11 140.85(7) . . ?
O15 Eu1 O1 90.73(8) . . ?
O8 Eu1 O1 139.98(7) 1_455 . ?
O7 Eu1 O1 119.44(7) 1_455 . ?
O14 Eu1 O1 136.52(8) . . ?
O11 Eu1 O1 75.68(8) . . ?
O15 Eu1 O3 139.07(7) . 1_655 ?
O8 Eu1 O3 72.14(6) 1_455 1_655 ?
O7 Eu1 O3 140.25(6) 1_455 1_655 ?
O14 Eu1 O3 88.92(6) . 1_655 ?
O11 Eu1 O3 74.02(6) . 1_655 ?
O1 Eu1 O3 79.80(6) . 1_655 ?
O15 Eu1 O4 88.07(8) . 1_655 ?
O8 Eu1 O4 111.70(7) 1_455 1_655 ?
O7 Eu1 O4 164.59(7) 1_455 1_655 ?
O14 Eu1 O4 72.20(7) . 1_655 ?
O11 Eu1 O4 117.63(7) . 1_655 ?
O1 Eu1 O4 67.99(7) . 1_655 ?
O3 Eu1 O4 51.38(7) 1_655 1_655 ?
O15 Eu1 O2 66.61(7) . . ?
O8 Eu1 O2 134.37(7) 1_455 . ?
O7 Eu1 O2 70.62(6) 1_455 . ?
O14 Eu1 O2 137.12(6) . . ?
O11 Eu1 O2 77.61(6) . . ?
O1 Eu1 O2 51.02(6) . . ?
O3 Eu1 O2 127.88(6) 1_655 . ?
O4 Eu1 O2 111.30(7) 1_655 . ?
O15 Eu1 C8 113.36(9) . 1_655 ?
O8 Eu1 C8 94.85(7) 1_455 1_655 ?
O7 Eu1 C8 166.45(7) 1_455 1_655 ?
O14 Eu1 C8 82.96(7) . 1_655 ?
O11 Eu1 C8 94.59(8) . 1_655 ?
O1 Eu1 C8 68.36(7) . 1_655 ?
O3 Eu1 C8 26.57(7) 1_655 1_655 ?
O4 Eu1 C8 25.32(8) 1_655 1_655 ?
O2 Eu1 C8 119.08(7) . 1_655 ?
O15 Eu1 C1 76.68(8) . . ?
O8 Eu1 C1 145.69(8) 1_455 . ?
O7 Eu1 C1 95.83(7) 1_455 . ?
O14 Eu1 C1 142.50(8) . . ?
O11 Eu1 C1 76.56(8) . . ?
O1 Eu1 C1 25.16(7) . . ?
O3 Eu1 C1 104.09(7) 1_655 . ?
O4 Eu1 C1 88.59(7) 1_655 . ?
O2 Eu1 C1 25.93(7) . . ?
C8 Eu1 C1 93.20(8) 1_655 . ?
O15 Eu1 Eu2 140.14(5) . . ?
O8 Eu1 Eu2 38.87(4) 1_455 . ?
O7 Eu1 Eu2 110.90(4) 1_455 . ?
O14 Eu1 Eu2 69.65(5) . . ?
O11 Eu1 Eu2 76.69(5) . . ?
O1 Eu1 Eu2 114.24(5) . . ?
O3 Eu1 Eu2 35.31(4) 1_655 . ?
O4 Eu1 Eu2 74.65(5) 1_655 . ?
O2 Eu1 Eu2 153.17(4) . . ?
C8 Eu1 Eu2 55.99(6) 1_655 . ?
C1 Eu1 Eu2 136.70(6) . . ?
O15 Eu1 H15A 16.8 . . ?
O8 Eu1 H15A 137.4 1_455 . ?
O7 Eu1 H15A 73.6 1_455 . ?
O14 Eu1 H15A 87.5 . . ?
O11 Eu1 H15A 125.8 . . ?
O1 Eu1 H15A 79.8 . . ?
O3 Eu1 H15A 146.1 1_655 . ?
O4 Eu1 H15A 95.7 1_655 . ?
O2 Eu1 H15A 49.8 . . ?
C8 Eu1 H15A 119.7 1_655 . ?
C1 Eu1 H15A 62.1 . . ?
Eu2 Eu1 H15A 156.9 . . ?
O15 Eu1 H15C 16.8 . . ?
O8 Eu1 H15C 134.0 1_455 . ?
O7 Eu1 H15C 95.2 1_455 . ?
O14 Eu1 H15C 65.8 . . ?
O11 Eu1 H15C 152.4 . . ?
O1 Eu1 H15C 85.2 . . ?
O3 Eu1 H15C 122.3 1_655 . ?
O4 Eu1 H15C 71.3 1_655 . ?
O2 Eu1 H15C 74.9 . . ?
C8 Eu1 H15C 96.6 1_655 . ?
C1 Eu1 H15C 77.7 . . ?
Eu2 Eu1 H15C 130.0 . . ?
H15A Eu1 H15C 29.0 . . ?
O16 Eu2 O2 129.25(8) . 1_655 ?
O16 Eu2 O3 78.86(8) . 1_655 ?
O2 Eu2 O3 71.99(6) 1_655 1_655 ?
O16 Eu2 O12 70.98(7) . 1_655 ?
O2 Eu2 O12 71.98(7) 1_655 1_655 ?
O3 Eu2 O12 96.22(7) 1_655 1_655 ?
O16 Eu2 O13 141.97(7) . . ?
O2 Eu2 O13 69.28(7) 1_655 . ?
O3 Eu2 O13 77.41(7) 1_655 . ?
O12 Eu2 O13 140.81(7) 1_655 . ?
O16 Eu2 O9 90.90(8) . 1_455 ?
O2 Eu2 O9 139.60(7) 1_655 1_455 ?
O3 Eu2 O9 119.34(7) 1_655 1_455 ?
O12 Eu2 O9 136.47(8) 1_655 1_455 ?
O13 Eu2 O9 75.65(8) . 1_455 ?
O16 Eu2 O7 139.41(7) . . ?
O2 Eu2 O7 71.81(6) 1_655 . ?
O3 Eu2 O7 139.74(6) 1_655 . ?
O12 Eu2 O7 88.89(6) 1_655 . ?
O13 Eu2 O7 73.82(6) . . ?
O9 Eu2 O7 79.81(6) 1_455 . ?
O16 Eu2 O6 88.32(8) . . ?
O2 Eu2 O6 111.70(7) 1_655 . ?
O3 Eu2 O6 165.12(7) 1_655 . ?
O12 Eu2 O6 72.22(7) 1_655 . ?
O13 Eu2 O6 117.47(7) . . ?
O9 Eu2 O6 67.89(7) 1_455 . ?
O7 Eu2 O6 51.49(6) . . ?
O16 Eu2 O8 66.49(7) . 1_455 ?
O2 Eu2 O8 134.46(7) 1_655 1_455 ?
O3 Eu2 O8 70.76(6) 1_655 1_455 ?
O12 Eu2 O8 137.11(6) 1_655 1_455 ?
O13 Eu2 O8 77.79(6) . 1_455 ?
O9 Eu2 O8 50.96(6) 1_455 1_455 ?
O7 Eu2 O8 127.85(6) . 1_455 ?
O6 Eu2 O8 111.09(7) . 1_455 ?
O16 Eu2 C15 113.61(8) . . ?
O2 Eu2 C15 94.72(7) 1_655 . ?
O3 Eu2 C15 166.14(7) 1_655 . ?
O12 Eu2 C15 82.95(7) 1_655 . ?
O13 Eu2 C15 94.45(8) . . ?
O9 Eu2 C15 68.27(7) 1_455 . ?
O7 Eu2 C15 26.69(7) . . ?
O6 Eu2 C15 25.31(8) . . ?
O8 Eu2 C15 118.91(7) 1_455 . ?
O16 Eu2 C22 76.79(8) . 1_455 ?
O2 Eu2 C22 145.43(7) 1_655 1_455 ?
O3 Eu2 C22 95.86(7) 1_655 1_455 ?
O12 Eu2 C22 142.51(8) 1_655 1_455 ?
O13 Eu2 C22 76.57(8) . 1_455 ?
O9 Eu2 C22 25.12(7) 1_455 1_455 ?
O7 Eu2 C22 104.04(7) . 1_455 ?
O6 Eu2 C22 88.45(7) . 1_455 ?
O8 Eu2 C22 25.90(7) 1_455 1_455 ?
C15 Eu2 C22 93.06(8) . 1_455 ?
O16 Eu2 Eu1 77.45(6) . . ?
O2 Eu2 Eu1 100.63(5) 1_655 . ?
O3 Eu2 Eu1 37.33(4) 1_655 . ?
O12 Eu2 Eu1 128.56(5) 1_655 . ?
O13 Eu2 Eu1 65.67(5) . . ?
O9 Eu2 Eu1 82.02(5) 1_455 . ?
O7 Eu2 Eu1 138.53(4) . . ?
O6 Eu2 Eu1 146.51(5) . . ?
O8 Eu2 Eu1 35.42(4) 1_455 . ?
C15 Eu2 Eu1 147.92(5) . . ?
C22 Eu2 Eu1 58.98(6) 1_455 . ?
O16 Eu2 H16A 16.8 . . ?
O2 Eu2 H16A 126.3 1_655 . ?
O3 Eu2 H16A 92.2 1_655 . ?
O12 Eu2 H16A 58.9 1_655 . ?
O13 Eu2 H16A 157.9 . . ?
O9 Eu2 H16A 93.2 1_455 . ?
O7 Eu2 H16A 123.6 . . ?
O6 Eu2 H16A 73.9 . . ?
O8 Eu2 H16A 80.4 1_455 . ?
C15 Eu2 H16A 99.1 . . ?
C22 Eu2 H16A 85.3 1_455 . ?
Eu1 Eu2 H16A 94.2 . . ?
O16 Eu2 H16B 16.8 . . ?
O2 Eu2 H16B 143.7 1_655 . ?
O3 Eu2 H16B 81.7 1_655 . ?
O12 Eu2 H16B 86.9 1_655 . ?
O13 Eu2 H16B 129.1 . . ?
O9 Eu2 H16B 75.3 1_455 . ?
O7 Eu2 H16B 138.5 . . ?
O6 Eu2 H16B 88.2 . . ?
O8 Eu2 H16B 51.5 1_455 . ?
C15 Eu2 H16B 112.0 . . ?
C22 Eu2 H16B 60.0 1_455 . ?
Eu1 Eu2 H16B 69.6 . . ?
H16A Eu2 H16B 29.0 . . ?
C11 N1 C10 117.8(4) . . ?
C26 N2 C24 118.1(4) . . ?
C11' N1' C10' 119.3(8) . . ?
C24' N2' C26' 119.4(8) . . ?
C1 O1 Eu1 96.41(17) . . ?
C1 O2 Eu2 145.26(18) . 1_455 ?
C1 O2 Eu1 92.06(16) . . ?
Eu2 O2 Eu1 105.85(7) 1_455 . ?
C8 O3 Eu2 127.83(16) . 1_455 ?
C8 O3 Eu1 92.88(16) . 1_455 ?
Eu2 O3 Eu1 107.36(7) 1_455 1_455 ?
C8 O4 Eu1 92.63(17) . 1_455 ?
C9 O5 C5 117.4(3) . . ?
C9' O5' C4 115.4(13) . . ?
C15 O6 Eu2 92.60(17) . . ?
C15 O7 Eu1 127.94(16) . 1_655 ?
C15 O7 Eu2 92.71(16) . . ?
Eu1 O7 Eu2 107.55(7) 1_655 . ?
C22 O8 Eu1 144.90(18) . 1_655 ?
C22 O8 Eu2 91.95(16) . 1_655 ?
Eu1 O8 Eu2 105.71(7) 1_655 1_655 ?
C22 O9 Eu2 96.46(17) . 1_655 ?
C18 O10 C23 117.4(4) . . ?
C23' O10' C19 115.1(10) . . ?
C29 O11 Eu1 137.87(18) . . ?
C29 O12 Eu2 132.26(18) . 1_455 ?
C35 O13 Eu2 137.45(18) . . ?
C35 O14 Eu1 131.84(18) . . ?
Eu1 O15 H15A 109.4 . . ?
Eu1 O15 H15C 109.3 . . ?
H15A O15 H15C 109.5 . . ?
Eu2 O16 H16A 109.3 . . ?
Eu2 O16 H16B 109.4 . . ?
H16A O16 H16B 109.5 . . ?
O1 C1 O2 120.2(3) . . ?
O1 C1 C2 119.6(3) . . ?
O2 C1 C2 120.2(2) . . ?
O1 C1 Eu1 58.42(15) . . ?
O2 C1 Eu1 62.01(14) . . ?
C2 C1 Eu1 172.8(2) . . ?
C3 C2 C7 118.4(3) . . ?
C3 C2 C1 117.6(3) . . ?
C7 C2 C1 123.8(3) . . ?
C4 C3 C2 121.7(3) . . ?
C4 C3 H3 119.1 . . ?
C2 C3 H3 119.1 . . ?
C3 C4 C5 119.2(3) . . ?
C3 C4 O5' 113.5(6) . . ?
C5 C4 O5' 127.3(6) . . ?
C3 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
C4 C5 C6 120.7(3) . . ?
C4 C5 O5 125.4(3) . . ?
C6 C5 O5 113.9(3) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C5 C6 C7 120.1(3) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 C2 119.9(3) . . ?
C6 C7 C8 112.9(3) . . ?
C2 C7 C8 127.2(3) . . ?
O4 C8 O3 120.7(3) . . ?
O4 C8 C7 120.0(3) . . ?
O3 C8 C7 118.8(3) . . ?
O4 C8 Eu1 62.05(15) . 1_455 ?
O3 C8 Eu1 60.55(13) . 1_455 ?
C7 C8 Eu1 158.37(19) . 1_455 ?
C14 C9 C10 120.5(4) . . ?
C14 C9 O5 119.3(4) . . ?
C10 C9 O5 119.9(4) . . ?
N1 C10 C9 121.5(4) . . ?
N1 C10 H10 119.2 . . ?
C9 C10 H10 119.2 . . ?
N1 C11 C13 122.0(4) . . ?
N1 C11 H11 119.0 . . ?
C13 C11 H11 119.0 . . ?
C14 C13 C11 120.3(4) . . ?
C14 C13 H13 119.8 . . ?
C11 C13 H13 119.8 . . ?
C13 C14 C9 117.7(4) . . ?
C13 C14 H14 121.1 . . ?
C9 C14 H14 121.1 . . ?
O6 C15 O7 120.8(3) . . ?
O6 C15 C16 120.2(3) . . ?
O7 C15 C16 118.5(3) . . ?
O6 C15 Eu2 62.09(15) . . ?
O7 C15 Eu2 60.59(13) . . ?
C16 C15 Eu2 158.38(19) . . ?
C17 C16 C21 119.7(3) . . ?
C17 C16 C15 113.1(3) . . ?
C21 C16 C15 127.3(3) . . ?
C18 C17 C16 120.4(3) . . ?
C18 C17 H17 119.8 . . ?
C16 C17 H17 119.8 . . ?
C19 C18 C17 120.2(3) . . ?
C19 C18 O10 125.9(3) . . ?
C17 C18 O10 113.8(3) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C20 C19 C18 119.6(3) . . ?
C20 C19 O10' 113.8(5) . . ?
C18 C19 O10' 126.6(5) . . ?
C20 C19 H19 120.2 . . ?
C18 C19 H19 120.2 . . ?
C19 C20 C21 121.5(3) . . ?
C19 C20 H20 119.3 . . ?
C21 C20 H20 119.3 . . ?
C20 C21 C16 118.6(3) . . ?
C20 C21 C22 117.4(3) . . ?
C16 C21 C22 123.9(3) . . ?
O9 C22 O8 120.3(3) . . ?
O9 C22 C21 119.7(2) . . ?
O8 C22 C21 120.0(2) . . ?
O9 C22 Eu2 58.42(15) . 1_655 ?
O8 C22 Eu2 62.15(14) . 1_655 ?
C21 C22 Eu2 172.7(2) . 1_655 ?
C28 C23 C24 120.4(4) . . ?
C28 C23 O10 118.7(4) . . ?
C24 C23 O10 120.6(4) . . ?
N2 C24 C23 121.3(4) . . ?
N2 C24 H24 119.3 . . ?
C23 C24 H24 119.3 . . ?
N2 C26 C27 122.1(5) . . ?
N2 C26 H26 119.0 . . ?
C27 C26 H26 119.0 . . ?
C28 C27 C26 119.9(5) . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 C28 C23 118.0(4) . . ?
C27 C28 H28 121.0 . . ?
C23 C28 H28 121.0 . . ?
O12 C29 O11 125.0(3) . . ?
O12 C29 C30 117.7(2) . . ?
O11 C29 C30 117.3(2) . . ?
C34 C30 C31 120.1(3) . . ?
C34 C30 C29 119.4(3) . . ?
C31 C30 C29 120.5(3) . . ?
C30 C31 C34 119.6(3) . 2_566 ?
C30 C31 C32 123.2(4) . . ?
C34 C31 C32 117.3(4) 2_566 . ?
C30 C31 H31 120.2 . . ?
C34 C31 H31 120.2 2_566 . ?
C32 C31 H31 3.0 . . ?
C33 C32 C31 121.6(6) . . ?
C33 C32 H31 126.4 . . ?
C31 C32 H31 4.8 . . ?
C32 C33 C33' 121.2(8) . 2_566 ?
C30 C34 C31 120.3(3) . 2_566 ?
C30 C34 C32' 121.7(4) . . ?
C31 C34 C32' 117.9(4) 2_566 . ?
C30 C34 H34 119.8 . . ?
C31 C34 H34 119.9 2_566 . ?
C32' C34 H34 2.9 . . ?
O14 C35 O13 125.0(2) . . ?
O14 C35 C36 117.8(2) . . ?
O13 C35 C36 117.1(2) . . ?
C37 C36 C40 120.2(3) . . ?
C37 C36 C35 119.5(3) . . ?
C40 C36 C35 120.3(3) . . ?
C36 C37 C40 120.4(3) . 2_675 ?
C36 C37 C38 122.0(4) . . ?
C40 C37 C38 117.5(4) 2_675 . ?
C36 C37 H37 119.7 . . ?
C40 C37 H37 119.9 2_675 . ?
C38 C37 H37 2.9 . . ?
C39 C38 C37 120.4(6) . . ?
C39 C38 H37 123.9 . . ?
C37 C38 H37 4.7 . . ?
C38 C39 C39' 122.6(7) . 2_675 ?
C36 C40 C37 119.3(3) . 2_675 ?
C36 C40 C38' 123.0(4) . . ?
C37 C40 C38' 117.6(4) 2_675 . ?
C36 C40 H40 120.4 . . ?
C37 C40 H40 120.2 2_675 . ?
C38' C40 H40 2.6 . . ?
C10' C9' C14' 120.9(9) . . ?
C10' C9' O5' 116.3(13) . . ?
C14' C9' O5' 122.6(13) . . ?
C9' C10' N1' 119.7(9) . . ?
C9' C10' H10' 120.1 . . ?
N1' C10' H10' 120.1 . . ?
N1' C11' C13' 120.2(9) . . ?
N1' C11' H11' 119.9 . . ?
C13' C11' H11' 119.9 . . ?
C11' C13' C14' 119.4(8) . . ?
C11' C13' H13' 120.3 . . ?
C14' C13' H13' 120.3 . . ?
C13' C14' C9' 118.3(9) . . ?
C13' C14' H14' 120.9 . . ?
C9' C14' H14' 120.9 . . ?
C28' C23' C24' 120.1(7) . . ?
C28' C23' O10' 121.9(11) . . ?
C24' C23' O10' 117.9(11) . . ?
N2' C24' C23' 120.3(7) . . ?
N2' C24' H24' 119.9 . . ?
C23' C24' H24' 119.9 . . ?
N2' C26' C27' 120.4(8) . . ?
N2' C26' H26' 119.8 . . ?
C27' C26' H26' 119.8 . . ?
C28' C27' C26' 119.8(8) . . ?
C28' C27' H27' 120.1 . . ?
C26' C27' H27' 120.1 . . ?
C27' C28' C23' 119.6(7) . . ?
C27' C28' H28' 120.2 . . ?
C23' C28' H28' 120.2 . . ?
C33' C32' C34 120.4(7) . . ?
C33' C32' H34 123.2 . . ?
C34 C32' H34 4.6 . . ?
C32' C33' C33 121.4(8) . 2_566 ?
C39' C38' C40 121.0(6) . . ?
C39' C38' H40 125.2 . . ?
C40 C38' H40 4.2 . . ?
C38' C39' C39 120.5(7) . 2_675 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C1 O2 -6.0(3) . . . . ?
Eu1 O1 C1 C2 171.9(3) . . . . ?
Eu2 O2 C1 O1 -116.4(3) 1_455 . . . ?
Eu1 O2 C1 O1 5.8(3) . . . . ?
Eu2 O2 C1 C2 65.8(4) 1_455 . . . ?
Eu1 O2 C1 C2 -172.1(3) . . . . ?
Eu2 O2 C1 Eu1 -122.1(3) 1_455 . . . ?
O1 C1 C2 C3 7.5(5) . . . . ?
O2 C1 C2 C3 -174.6(3) . . . . ?
O1 C1 C2 C7 -168.4(3) . . . . ?
O2 C1 C2 C7 9.5(5) . . . . ?
C7 C2 C3 C4 0.7(6) . . . . ?
C1 C2 C3 C4 -175.4(4) . . . . ?
C2 C3 C4 C5 1.3(7) . . . . ?
C2 C3 C4 O5' -178.3(8) . . . . ?
C9' O5' C4 C3 -167.9(11) . . . . ?
C9' O5' C4 C5 12.4(18) . . . . ?
C3 C4 C5 C6 -1.7(8) . . . . ?
O5' C4 C5 C6 177.9(10) . . . . ?
C3 C4 C5 O5 -179.9(5) . . . . ?
C9 O5 C5 C4 -12.0(8) . . . . ?
C9 O5 C5 C6 169.7(4) . . . . ?
C4 C5 C6 C7 0.1(7) . . . . ?
O5 C5 C6 C7 178.4(4) . . . . ?
C5 C6 C7 C2 2.0(6) . . . . ?
C5 C6 C7 C8 -177.2(4) . . . . ?
C3 C2 C7 C6 -2.4(5) . . . . ?
C1 C2 C7 C6 173.4(3) . . . . ?
C3 C2 C7 C8 176.7(3) . . . . ?
C1 C2 C7 C8 -7.5(5) . . . . ?
Eu1 O4 C8 O3 -15.8(3) 1_455 . . . ?
Eu1 O4 C8 C7 155.3(2) 1_455 . . . ?
Eu2 O3 C8 O4 -98.7(3) 1_455 . . . ?
Eu1 O3 C8 O4 16.0(3) 1_455 . . . ?
Eu2 O3 C8 C7 90.1(3) 1_455 . . . ?
Eu1 O3 C8 C7 -155.2(2) 1_455 . . . ?
Eu2 O3 C8 Eu1 -114.65(18) 1_455 . . 1_455 ?
C6 C7 C8 O4 -53.8(4) . . . . ?
C2 C7 C8 O4 127.1(4) . . . . ?
C6 C7 C8 O3 117.5(3) . . . . ?
C2 C7 C8 O3 -61.6(4) . . . . ?
C6 C7 C8 Eu1 35.4(7) . . . 1_455 ?
C2 C7 C8 Eu1 -143.7(5) . . . 1_455 ?
C5 O5 C9 C14 109.9(6) . . . . ?
C5 O5 C9 C10 -76.1(7) . . . . ?
C11 N1 C10 C9 0.3(8) . . . . ?
C14 C9 C10 N1 -3.0(8) . . . . ?
O5 C9 C10 N1 -176.9(5) . . . . ?
C10 N1 C11 C13 3.6(9) . . . . ?
N1 C11 C13 C14 -4.8(10) . . . . ?
C11 C13 C14 C9 2.0(9) . . . . ?
C10 C9 C14 C13 1.8(8) . . . . ?
O5 C9 C14 C13 175.8(5) . . . . ?
Eu2 O6 C15 O7 -15.8(3) . . . . ?
Eu2 O6 C15 C16 155.4(2) . . . . ?
Eu1 O7 C15 O6 -98.8(3) 1_655 . . . ?
Eu2 O7 C15 O6 16.1(3) . . . . ?
Eu1 O7 C15 C16 89.9(3) 1_655 . . . ?
Eu2 O7 C15 C16 -155.3(2) . . . . ?
Eu1 O7 C15 Eu2 -114.82(18) 1_655 . . . ?
O6 C15 C16 C17 -54.1(4) . . . . ?
O7 C15 C16 C17 117.3(3) . . . . ?
Eu2 C15 C16 C17 35.8(7) . . . . ?
O6 C15 C16 C21 126.6(3) . . . . ?
O7 C15 C16 C21 -62.0(4) . . . . ?
Eu2 C15 C16 C21 -143.5(4) . . . . ?
C21 C16 C17 C18 2.2(6) . . . . ?
C15 C16 C17 C18 -177.1(4) . . . . ?
C16 C17 C18 C19 -0.2(7) . . . . ?
C16 C17 C18 O10 178.3(4) . . . . ?
C23 O10 C18 C19 -14.5(8) . . . . ?
C23 O10 C18 C17 167.1(4) . . . . ?
C17 C18 C19 C20 -1.3(7) . . . . ?
O10 C18 C19 C20 -179.6(5) . . . . ?
C17 C18 C19 O10' 178.3(8) . . . . ?
C23' O10' C19 C20 -166.3(9) . . . . ?
C23' O10' C19 C18 14.1(15) . . . . ?
C18 C19 C20 C21 0.8(7) . . . . ?
O10' C19 C20 C21 -178.9(7) . . . . ?
C19 C20 C21 C16 1.1(6) . . . . ?
C19 C20 C21 C22 -175.8(4) . . . . ?
C17 C16 C21 C20 -2.6(5) . . . . ?
C15 C16 C21 C20 176.6(3) . . . . ?
C17 C16 C21 C22 174.0(3) . . . . ?
C15 C16 C21 C22 -6.7(5) . . . . ?
Eu2 O9 C22 O8 -5.7(3) 1_655 . . . ?
Eu2 O9 C22 C21 171.9(2) 1_655 . . . ?
Eu1 O8 C22 O9 -115.8(3) 1_655 . . . ?
Eu2 O8 C22 O9 5.5(3) 1_655 . . . ?
Eu1 O8 C22 C21 66.6(4) 1_655 . . . ?
Eu2 O8 C22 C21 -172.1(2) 1_655 . . . ?
Eu1 O8 C22 Eu2 -121.3(3) 1_655 . . 1_655 ?
C20 C21 C22 O9 8.1(5) . . . . ?
C16 C21 C22 O9 -168.6(3) . . . . ?
C20 C21 C22 O8 -174.4(3) . . . . ?
C16 C21 C22 O8 8.9(5) . . . . ?
C18 O10 C23 C28 112.0(6) . . . . ?
C18 O10 C23 C24 -74.0(7) . . . . ?
C26 N2 C24 C23 0.4(9) . . . . ?
C28 C23 C24 N2 -3.2(8) . . . . ?
O10 C23 C24 N2 -177.1(5) . . . . ?
C24 N2 C26 C27 3.1(10) . . . . ?
N2 C26 C27 C28 -3.9(11) . . . . ?
C26 C27 C28 C23 1.0(9) . . . . ?
C24 C23 C28 C27 2.5(8) . . . . ?
O10 C23 C28 C27 176.5(5) . . . . ?
Eu2 O12 C29 O11 -20.2(5) 1_455 . . . ?
Eu2 O12 C29 C30 159.2(2) 1_455 . . . ?
Eu1 O11 C29 O12 -20.3(5) . . . . ?
Eu1 O11 C29 C30 160.3(2) . . . . ?
O12 C29 C30 C34 83.2(4) . . . . ?
O11 C29 C30 C34 -97.3(3) . . . . ?
O12 C29 C30 C31 -96.6(3) . . . . ?
O11 C29 C30 C31 82.9(4) . . . . ?
C34 C30 C31 C34 0.1(5) . . . 2_566 ?
C29 C30 C31 C34 179.9(3) . . . 2_566 ?
C34 C30 C31 C32 179.7(5) . . . . ?
C29 C30 C31 C32 -0.5(6) . . . . ?
C30 C31 C32 C33 -177.9(7) . . . . ?
C34 C31 C32 C33 1.7(10) 2_566 . . . ?
C31 C32 C33 C33' -4.6(15) . . . 2_566 ?
C31 C30 C34 C31 -0.1(5) . . . 2_566 ?
C29 C30 C34 C31 -179.9(3) . . . 2_566 ?
C31 C30 C34 C32' -177.8(5) . . . . ?
C29 C30 C34 C32' 2.4(6) . . . . ?
Eu1 O14 C35 O13 -21.5(4) . . . . ?
Eu1 O14 C35 C36 158.5(2) . . . . ?
Eu2 O13 C35 O14 -20.4(5) . . . . ?
Eu2 O13 C35 C36 159.6(2) . . . . ?
O14 C35 C36 C37 81.1(4) . . . . ?
O13 C35 C36 C37 -99.0(3) . . . . ?
O14 C35 C36 C40 -99.1(3) . . . . ?
O13 C35 C36 C40 80.9(4) . . . . ?
C40 C36 C37 C40 0.5(5) . . . 2_675 ?
C35 C36 C37 C40 -179.6(3) . . . 2_675 ?
C40 C36 C37 C38 -177.8(5) . . . . ?
C35 C36 C37 C38 2.1(6) . . . . ?
C36 C37 C38 C39 -178.0(7) . . . . ?
C40 C37 C38 C39 3.6(10) 2_675 . . . ?
C37 C38 C39 C39' -0.8(15) . . . 2_675 ?
C37 C36 C40 C37 -0.5(5) . . . 2_675 ?
C35 C36 C40 C37 179.6(3) . . . 2_675 ?
C37 C36 C40 C38' -179.9(5) . . . . ?
C35 C36 C40 C38' 0.2(6) . . . . ?
C4 O5' C9' C10' 88(2) . . . . ?
C4 O5' C9' C14' -97(2) . . . . ?
C14' C9' C10' N1' 2(3) . . . . ?
O5' C9' C10' N1' 177(2) . . . . ?
C11' N1' C10' C9' 0(4) . . . . ?
C10' N1' C11' C13' -10(5) . . . . ?
N1' C11' C13' C14' 18(5) . . . . ?
C11' C13' C14' C9' -16(4) . . . . ?
C10' C9' C14' C13' 6(3) . . . . ?
O5' C9' C14' C13' -169(2) . . . . ?
C19 O10' C23' C28' -98.5(17) . . . . ?
C19 O10' C23' C24' 86.2(17) . . . . ?
C26' N2' C24' C23' -1(4) . . . . ?
C28' C23' C24' N2' 3(3) . . . . ?
O10' C23' C24' N2' 178(2) . . . . ?
C24' N2' C26' C27' -4(5) . . . . ?
N2' C26' C27' C28' 8(5) . . . . ?
C26' C27' C28' C23' -7(4) . . . . ?
C24' C23' C28' C27' 1(3) . . . . ?
O10' C23' C28' C27' -174(2) . . . . ?
C30 C34 C32' C33' -178.2(7) . . . . ?
C31 C34 C32' C33' 4.1(10) 2_566 . . . ?
C34 C32' C33' C33 -1.4(15) . . . 2_566 ?
C36 C40 C38' C39' -177.2(7) . . . . ?
C37 C40 C38' C39' 3.4(10) 2_675 . . . ?
C40 C38' C39' C39 -6.5(14) . . . 2_675 ?

_refine_diff_density_max         0.579
_refine_diff_density_min         -0.472
_refine_diff_density_rms         0.084



