# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1884388'
_audit_update_record             
;
2018-12-11 deposited with the CCDC.
2019-01-16 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C62 H60 Dy4 N8 O22'
_chemical_formula_sum            'C62 H60 Dy4 N8 O22'
_chemical_formula_weight         1919.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   16.1040(16)
_cell_length_b                   11.3324(12)
_cell_length_c                   17.9653(19)
_cell_angle_alpha                90
_cell_angle_beta                 94.292(2)
_cell_angle_gamma                90
_cell_volume                     3269.4(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    4093
_cell_measurement_theta_min      2.43
_cell_measurement_theta_max      26.29

_exptl_crystal_description       block
_exptl_crystal_colour            'light brown'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.950
_exptl_crystal_F_000             1856
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    4.602
_shelx_estimated_absorpt_T_min   0.608
_shelx_estimated_absorpt_T_max   0.710
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.581
_exptl_absorpt_correction_T_max  0.692
_exptl_absorpt_process_details   'SADABS V2012/1(Bruker AXS Inc.)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            17623
_diffrn_reflns_av_unetI/netI     0.0527
_diffrn_reflns_av_R_equivalents  0.0404
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.638
_diffrn_reflns_theta_max         26.479
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             6669
_reflns_number_gt                4703
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker SMART APEX II'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0316P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         6669
_refine_ls_number_parameters     433
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0590
_refine_ls_R_factor_gt           0.0330
_refine_ls_wR_factor_ref         0.0748
_refine_ls_wR_factor_gt          0.0652
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_restrained_S_all      0.968
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.61019(2) 0.56424(2) 0.01121(2) 0.02697(8) Uani 1 1 d . . . . .
Dy2 Dy 0.49818(2) 0.57040(2) 0.16792(2) 0.02954(8) Uani 1 1 d . . . . .
N1 N 0.7230(3) 0.4195(4) 0.0516(2) 0.0321(10) Uani 1 1 d . . . . .
N2 N 0.4477(3) 0.7740(4) 0.1817(3) 0.0397(12) Uani 1 1 d . . . . .
N3 N 0.5781(3) 0.2339(5) 0.2896(3) 0.0505(14) Uani 1 1 d . . . . .
N4 N 0.7131(3) 0.7395(4) -0.0510(3) 0.0463(13) Uani 1 1 d . . . . .
O1 O 0.48643(19) 0.5590(3) -0.06446(18) 0.0275(8) Uani 1 1 d . . . . .
H1A H 0.4644 0.6371 -0.0787 0.033 Uiso 1 1 calc R U . . .
O2 O 0.6287(2) 0.4480(3) -0.09163(19) 0.0324(8) Uani 1 1 d . . . . .
O3 O 0.6402(2) 0.5631(3) 0.14141(18) 0.0325(8) Uani 1 1 d . . . . .
O4 O 0.6336(2) 0.4547(3) -0.23550(19) 0.0391(9) Uani 1 1 d . . . . .
O5 O 0.5367(2) 0.6217(4) 0.2822(2) 0.0417(10) Uani 1 1 d . . . . .
O6 O 0.5300(2) 0.6970(3) 0.07013(19) 0.0329(8) Uani 1 1 d . . . . .
O7 O 0.5717(3) 0.5593(5) 0.4210(2) 0.0708(14) Uani 1 1 d . . . . .
O8 O 0.5188(2) 0.3785(4) 0.2189(2) 0.0436(10) Uani 1 1 d . . . . .
O9 O 0.7340(3) 0.6839(4) 0.0075(3) 0.0669(14) Uani 1 1 d . . . . .
O10 O 0.6424(3) 0.7159(4) -0.0811(2) 0.0597(12) Uani 1 1 d . . . . .
O11 O 0.7580(3) 0.8136(4) -0.0764(3) 0.0740(15) Uani 1 1 d . . . . .
C1 C 0.7695(3) 0.3772(5) -0.0732(3) 0.0343(13) Uani 1 1 d . . . . .
C2 C 0.6995(3) 0.4135(4) -0.1183(3) 0.0310(12) Uani 1 1 d . . . . .
C3 C 0.7054(3) 0.4140(5) -0.1958(3) 0.0351(13) Uani 1 1 d . . . . .
C4 C 0.7743(4) 0.3729(5) -0.2286(3) 0.0445(15) Uani 1 1 d . . . . .
H4A H 0.7749 0.3710 -0.2803 0.053 Uiso 1 1 calc R U . . .
C5 C 0.8426(4) 0.3346(6) -0.1838(4) 0.0524(17) Uani 1 1 d . . . . .
H5A H 0.8897 0.3070 -0.2052 0.063 Uiso 1 1 calc R U . . .
C6 C 0.8404(3) 0.3376(5) -0.1080(3) 0.0452(16) Uani 1 1 d . . . . .
H6A H 0.8870 0.3129 -0.0783 0.054 Uiso 1 1 calc R U . . .
C7 C 0.7753(3) 0.3772(5) 0.0086(3) 0.0419(15) Uani 1 1 d . . . . .
H7A H 0.8226 0.3423 0.0319 0.050 Uiso 1 1 calc R U . . .
C8 C 0.7398(3) 0.4104(5) 0.1305(3) 0.0355(13) Uani 1 1 d . . . . .
C9 C 0.7940(4) 0.3298(6) 0.1658(3) 0.0528(17) Uani 1 1 d . . . . .
H9A H 0.8208 0.2748 0.1375 0.063 Uiso 1 1 calc R U . . .
C10 C 0.8090(4) 0.3298(6) 0.2425(4) 0.0566(18) Uani 1 1 d . . . . .
H10A H 0.8454 0.2748 0.2654 0.068 Uiso 1 1 calc R U . . .
C11 C 0.7709(4) 0.4096(6) 0.2846(3) 0.0480(16) Uani 1 1 d . . . . .
H11A H 0.7822 0.4105 0.3361 0.058 Uiso 1 1 calc R U . . .
C12 C 0.7150(3) 0.4898(5) 0.2510(3) 0.0381(14) Uani 1 1 d . . . . .
H12A H 0.6894 0.5448 0.2802 0.046 Uiso 1 1 calc R U . . .
C13 C 0.6966(3) 0.4891(5) 0.1741(3) 0.0309(12) Uani 1 1 d . . . . .
C14 C 0.6420(4) 0.4979(6) -0.3090(3) 0.0537(17) Uani 1 1 d . . . . .
H14A H 0.5887 0.5232 -0.3306 0.081 Uiso 1 1 calc R U . . .
H14B H 0.6800 0.5632 -0.3069 0.081 Uiso 1 1 calc R U . . .
H14C H 0.6630 0.4362 -0.3391 0.081 Uiso 1 1 calc R U . . .
C15 C 0.4610(4) 0.7923(5) 0.3170(3) 0.0461(15) Uani 1 1 d . . . . .
C16 C 0.5086(3) 0.6894(5) 0.3340(3) 0.0384(14) Uani 1 1 d . . . . .
C17 C 0.5270(4) 0.6602(6) 0.4105(4) 0.0511(17) Uani 1 1 d . . . . .
C18 C 0.4977(4) 0.7289(7) 0.4659(4) 0.066(2) Uani 1 1 d . . . . .
H18A H 0.5085 0.7073 0.5157 0.079 Uiso 1 1 calc R U . . .
C19 C 0.4521(5) 0.8302(7) 0.4482(4) 0.068(2) Uani 1 1 d . . . . .
H19A H 0.4332 0.8767 0.4861 0.081 Uiso 1 1 calc R U . . .
C20 C 0.4349(4) 0.8622(6) 0.3755(4) 0.064(2) Uani 1 1 d . . . . .
H20A H 0.4053 0.9313 0.3645 0.076 Uiso 1 1 calc R U . . .
C21 C 0.4391(4) 0.8315(6) 0.2424(3) 0.0487(16) Uani 1 1 d . . . . .
H21A H 0.4163 0.9067 0.2372 0.058 Uiso 1 1 calc R U . . .
C22 C 0.4289(3) 0.8278(5) 0.1105(3) 0.0385(14) Uani 1 1 d . . . . .
C23 C 0.3687(4) 0.9147(6) 0.0945(4) 0.0563(18) Uani 1 1 d . . . . .
H23A H 0.3361 0.9405 0.1319 0.068 Uiso 1 1 calc R U . . .
C24 C 0.3572(4) 0.9619(6) 0.0251(4) 0.065(2) Uani 1 1 d . . . . .
H24A H 0.3173 1.0203 0.0152 0.078 Uiso 1 1 calc R U . . .
C25 C 0.4047(4) 0.9229(5) -0.0306(4) 0.0577(18) Uani 1 1 d . . . . .
H25A H 0.3970 0.9553 -0.0782 0.069 Uiso 1 1 calc R U . . .
C26 C 0.4643(4) 0.8353(5) -0.0160(3) 0.0446(15) Uani 1 1 d . . . . .
H26A H 0.4971 0.8110 -0.0536 0.054 Uiso 1 1 calc R U . . .
C27 C 0.4751(3) 0.7845(4) 0.0534(3) 0.0328(12) Uani 1 1 d . . . . .
C28 C 0.6172(5) 0.5431(7) 0.4880(4) 0.090(3) Uani 1 1 d . . . . .
H28A H 0.6455 0.4685 0.4875 0.135 Uiso 1 1 calc R U . . .
H28B H 0.6574 0.6054 0.4955 0.135 Uiso 1 1 calc R U . . .
H28C H 0.5806 0.5439 0.5277 0.135 Uiso 1 1 calc R U . . .
C29 C 0.5527(3) 0.3410(5) 0.2777(3) 0.0442(15) Uani 1 1 d . . . . .
H29A H 0.5607 0.3942 0.3170 0.053 Uiso 1 1 calc R U . . .
C30 C 0.5693(5) 0.1474(7) 0.2294(4) 0.091(3) Uani 1 1 d . . . . .
H30A H 0.5910 0.0728 0.2471 0.137 Uiso 1 1 calc R U . . .
H30B H 0.5115 0.1389 0.2129 0.137 Uiso 1 1 calc R U . . .
H30C H 0.5997 0.1736 0.1885 0.137 Uiso 1 1 calc R U . . .
C31 C 0.6239(5) 0.1976(8) 0.3591(4) 0.089(3) Uani 1 1 d . . . . .
H31A H 0.6369 0.1151 0.3566 0.134 Uiso 1 1 calc R U . . .
H31B H 0.6746 0.2423 0.3661 0.134 Uiso 1 1 calc R U . . .
H31C H 0.5904 0.2117 0.4002 0.134 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O6 2.292(3) . ?
Dy1 O2 2.306(3) . ?
Dy1 O1 2.328(3) . ?
Dy1 O1 2.347(3) 3_665 ?
Dy1 O3 2.353(3) . ?
Dy1 O9 2.416(4) . ?
Dy1 O10 2.469(4) . ?
Dy1 N1 2.515(4) . ?
Dy1 N4 2.867(5) . ?
Dy1 Dy2 3.4562(4) . ?
Dy1 Dy1 3.8293(6) 3_665 ?
Dy1 Dy2 3.8587(4) 3_665 ?
Dy2 O5 2.179(4) . ?
Dy2 O6 2.354(3) . ?
Dy2 O3 2.373(3) . ?
Dy2 O8 2.374(4) . ?
Dy2 O2 2.382(3) 3_665 ?
Dy2 O1 2.395(3) 3_665 ?
Dy2 N2 2.465(4) . ?
Dy2 O4 2.538(3) 3_665 ?
Dy2 Dy1 3.8587(4) 3_665 ?
N1 C7 1.277(6) . ?
N1 C8 1.426(7) . ?
N2 C21 1.287(7) . ?
N2 C22 1.428(7) . ?
N3 C29 1.293(7) . ?
N3 C30 1.459(8) . ?
N3 C31 1.461(8) . ?
N4 O11 1.219(6) . ?
N4 O9 1.250(6) . ?
N4 O10 1.253(6) . ?
O1 Dy1 2.347(3) 3_665 ?
O1 Dy2 2.395(3) 3_665 ?
O1 H1A 0.9800 . ?
O2 C2 1.329(5) . ?
O2 Dy2 2.383(3) 3_665 ?
O3 C13 1.339(6) . ?
O4 C3 1.392(6) . ?
O4 C14 1.425(6) . ?
O4 Dy2 2.538(3) 3_665 ?
O5 C16 1.312(6) . ?
O6 C27 1.348(6) . ?
O7 C17 1.357(8) . ?
O7 C28 1.374(8) . ?
O8 C29 1.228(7) . ?
C1 C2 1.399(7) . ?
C1 C6 1.416(7) . ?
C1 C7 1.465(7) . ?
C2 C3 1.402(7) . ?
C3 C4 1.376(7) . ?
C4 C5 1.384(8) . ?
C4 H4A 0.9300 . ?
C5 C6 1.365(8) . ?
C5 H5A 0.9300 . ?
C6 H6A 0.9300 . ?
C7 H7A 0.9300 . ?
C8 C9 1.385(7) . ?
C8 C13 1.405(7) . ?
C9 C10 1.382(8) . ?
C9 H9A 0.9300 . ?
C10 C11 1.354(8) . ?
C10 H10A 0.9300 . ?
C11 C12 1.386(8) . ?
C11 H11A 0.9300 . ?
C12 C13 1.391(7) . ?
C12 H12A 0.9300 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C20 1.405(8) . ?
C15 C16 1.417(8) . ?
C15 C21 1.430(8) . ?
C16 C17 1.423(8) . ?
C17 C18 1.376(9) . ?
C18 C19 1.387(10) . ?
C18 H18A 0.9300 . ?
C19 C20 1.363(9) . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9300 . ?
C21 H21A 0.9300 . ?
C22 C23 1.396(8) . ?
C22 C27 1.401(7) . ?
C23 C24 1.357(9) . ?
C23 H23A 0.9300 . ?
C24 C25 1.377(9) . ?
C24 H24A 0.9300 . ?
C25 C26 1.391(8) . ?
C25 H25A 0.9300 . ?
C26 C27 1.372(7) . ?
C26 H26A 0.9300 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9300 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Dy1 O2 148.81(12) . . ?
O6 Dy1 O1 78.41(12) . . ?
O2 Dy1 O1 70.96(11) . . ?
O6 Dy1 O1 77.79(12) . 3_665 ?
O2 Dy1 O1 96.66(11) . 3_665 ?
O1 Dy1 O1 70.00(13) . 3_665 ?
O6 Dy1 O3 68.02(12) . . ?
O2 Dy1 O3 139.82(12) . . ?
O1 Dy1 O3 133.14(11) . . ?
O1 Dy1 O3 71.63(11) 3_665 . ?
O6 Dy1 O9 97.98(15) . . ?
O2 Dy1 O9 98.19(15) . . ?
O1 Dy1 O9 132.10(13) . . ?
O1 Dy1 O9 156.73(13) 3_665 . ?
O3 Dy1 O9 85.51(14) . . ?
O6 Dy1 O10 90.42(14) . . ?
O2 Dy1 O10 79.25(14) . . ?
O1 Dy1 O10 80.76(13) . . ?
O1 Dy1 O10 150.05(13) 3_665 . ?
O3 Dy1 O10 129.30(14) . . ?
O9 Dy1 O10 51.38(14) . . ?
O6 Dy1 N1 135.63(13) . . ?
O2 Dy1 N1 74.02(13) . . ?
O1 Dy1 N1 136.09(13) . . ?
O1 Dy1 N1 88.92(12) 3_665 . ?
O3 Dy1 N1 67.61(13) . . ?
O9 Dy1 N1 78.13(15) . . ?
O10 Dy1 N1 117.66(14) . . ?
O6 Dy1 N4 95.03(13) . . ?
O2 Dy1 N4 88.30(13) . . ?
O1 Dy1 N4 106.56(14) . . ?
O1 Dy1 N4 172.46(13) 3_665 . ?
O3 Dy1 N4 108.03(14) . . ?
O9 Dy1 N4 25.58(14) . . ?
O10 Dy1 N4 25.80(13) . . ?
N1 Dy1 N4 97.93(14) . . ?
O6 Dy1 Dy2 42.62(8) . . ?
O2 Dy1 Dy2 140.41(8) . . ?
O1 Dy1 Dy2 90.00(8) . . ?
O1 Dy1 Dy2 43.75(8) 3_665 . ?
O3 Dy1 Dy2 43.23(8) . . ?
O9 Dy1 Dy2 119.54(12) . . ?
O10 Dy1 Dy2 132.95(11) . . ?
N1 Dy1 Dy2 100.84(10) . . ?
N4 Dy1 Dy2 130.98(10) . . ?
O6 Dy1 Dy1 75.42(9) . 3_665 ?
O2 Dy1 Dy1 82.69(8) . 3_665 ?
O1 Dy1 Dy1 35.17(8) . 3_665 ?
O1 Dy1 Dy1 34.83(8) 3_665 3_665 ?
O3 Dy1 Dy1 102.85(8) . 3_665 ?
O9 Dy1 Dy1 166.08(11) . 3_665 ?
O10 Dy1 Dy1 115.69(11) . 3_665 ?
N1 Dy1 Dy1 115.24(10) . 3_665 ?
N4 Dy1 Dy1 141.33(12) . 3_665 ?
Dy2 Dy1 Dy1 63.720(9) . 3_665 ?
O6 Dy1 Dy2 114.16(9) . 3_665 ?
O2 Dy1 Dy2 35.26(8) . 3_665 ?
O1 Dy1 Dy2 35.78(8) . 3_665 ?
O1 Dy1 Dy2 80.35(8) 3_665 3_665 ?
O3 Dy1 Dy2 150.86(9) . 3_665 ?
O9 Dy1 Dy2 121.44(11) . 3_665 ?
O10 Dy1 Dy2 79.62(11) . 3_665 ?
N1 Dy1 Dy2 104.75(10) . 3_665 ?
N4 Dy1 Dy2 100.81(11) . 3_665 ?
Dy2 Dy1 Dy2 117.148(10) . 3_665 ?
Dy1 Dy1 Dy2 53.428(7) 3_665 3_665 ?
O5 Dy2 O6 118.59(14) . . ?
O5 Dy2 O3 89.31(12) . . ?
O6 Dy2 O3 66.71(11) . . ?
O5 Dy2 O8 81.88(14) . . ?
O6 Dy2 O8 144.54(12) . . ?
O3 Dy2 O8 86.37(12) . . ?
O5 Dy2 O2 137.45(12) . 3_665 ?
O6 Dy2 O2 81.33(12) . 3_665 ?
O3 Dy2 O2 132.81(11) . 3_665 ?
O8 Dy2 O2 103.34(13) . 3_665 ?
O5 Dy2 O1 148.87(13) . 3_665 ?
O6 Dy2 O1 75.68(11) . 3_665 ?
O3 Dy2 O1 70.46(11) . 3_665 ?
O8 Dy2 O1 73.69(12) . 3_665 ?
O2 Dy2 O1 68.52(11) 3_665 3_665 ?
O5 Dy2 N2 74.25(15) . . ?
O6 Dy2 N2 66.20(13) . . ?
O3 Dy2 N2 112.53(13) . . ?
O8 Dy2 N2 148.92(14) . . ?
O2 Dy2 N2 82.22(14) 3_665 . ?
O1 Dy2 N2 134.83(13) 3_665 . ?
O5 Dy2 O4 76.59(12) . 3_665 ?
O6 Dy2 O4 131.43(12) . 3_665 ?
O3 Dy2 O4 160.93(12) . 3_665 ?
O8 Dy2 O4 79.06(12) . 3_665 ?
O2 Dy2 O4 63.50(11) 3_665 3_665 ?
O1 Dy2 O4 116.20(11) 3_665 3_665 ?
N2 Dy2 O4 76.29(13) . 3_665 ?
O5 Dy2 Dy1 130.09(10) . . ?
O6 Dy2 Dy1 41.26(8) . . ?
O3 Dy2 Dy1 42.78(8) . . ?
O8 Dy2 Dy1 103.28(9) . . ?
O2 Dy2 Dy1 90.40(8) 3_665 . ?
O1 Dy2 Dy1 42.67(8) 3_665 . ?
N2 Dy2 Dy1 107.27(10) . . ?
O4 Dy2 Dy1 153.29(8) 3_665 . ?
O5 Dy2 Dy1 166.02(10) . 3_665 ?
O6 Dy2 Dy1 74.25(9) . 3_665 ?
O3 Dy2 Dy1 101.62(8) . 3_665 ?
O8 Dy2 Dy1 90.06(9) . 3_665 ?
O2 Dy2 Dy1 33.98(8) 3_665 3_665 ?
O1 Dy2 Dy1 34.64(8) 3_665 3_665 ?
N2 Dy2 Dy1 108.77(11) . 3_665 ?
O4 Dy2 Dy1 90.72(8) 3_665 3_665 ?
Dy1 Dy2 Dy1 62.851(10) . 3_665 ?
C7 N1 C8 119.4(4) . . ?
C7 N1 Dy1 124.4(4) . . ?
C8 N1 Dy1 114.3(3) . . ?
C21 N2 C22 120.9(5) . . ?
C21 N2 Dy2 128.0(4) . . ?
C22 N2 Dy2 111.1(3) . . ?
C29 N3 C30 119.8(6) . . ?
C29 N3 C31 122.6(6) . . ?
C30 N3 C31 117.3(6) . . ?
O11 N4 O9 122.2(6) . . ?
O11 N4 O10 122.1(6) . . ?
O9 N4 O10 115.7(5) . . ?
O11 N4 Dy1 178.8(5) . . ?
O9 N4 Dy1 56.6(3) . . ?
O10 N4 Dy1 59.1(3) . . ?
Dy1 O1 Dy1 110.00(13) . 3_665 ?
Dy1 O1 Dy2 109.58(12) . 3_665 ?
Dy1 O1 Dy2 93.58(11) 3_665 3_665 ?
Dy1 O1 H1A 114.0 . . ?
Dy1 O1 H1A 114.0 3_665 . ?
Dy2 O1 H1A 114.0 3_665 . ?
C2 O2 Dy1 128.5(3) . . ?
C2 O2 Dy2 119.3(3) . 3_665 ?
Dy1 O2 Dy2 110.76(13) . 3_665 ?
C13 O3 Dy1 121.5(3) . . ?
C13 O3 Dy2 124.5(3) . . ?
Dy1 O3 Dy2 94.00(12) . . ?
C3 O4 C14 117.2(4) . . ?
C3 O4 Dy2 114.2(3) . 3_665 ?
C14 O4 Dy2 128.5(3) . 3_665 ?
C16 O5 Dy2 137.3(4) . . ?
C27 O6 Dy1 139.7(3) . . ?
C27 O6 Dy2 116.0(3) . . ?
Dy1 O6 Dy2 96.12(13) . . ?
C17 O7 C28 118.5(6) . . ?
C29 O8 Dy2 133.6(4) . . ?
N4 O9 Dy1 97.8(3) . . ?
N4 O10 Dy1 95.1(3) . . ?
C2 C1 C6 118.6(5) . . ?
C2 C1 C7 124.6(5) . . ?
C6 C1 C7 116.7(5) . . ?
O2 C2 C1 123.6(5) . . ?
O2 C2 C3 118.7(5) . . ?
C1 C2 C3 117.7(5) . . ?
C4 C3 O4 123.9(5) . . ?
C4 C3 C2 122.8(5) . . ?
O4 C3 C2 113.3(4) . . ?
C3 C4 C5 119.2(5) . . ?
C3 C4 H4A 120.4 . . ?
C5 C4 H4A 120.4 . . ?
C6 C5 C4 119.6(5) . . ?
C6 C5 H5A 120.2 . . ?
C4 C5 H5A 120.2 . . ?
C5 C6 C1 122.0(5) . . ?
C5 C6 H6A 119.0 . . ?
C1 C6 H6A 119.0 . . ?
N1 C7 C1 127.7(5) . . ?
N1 C7 H7A 116.2 . . ?
C1 C7 H7A 116.2 . . ?
C9 C8 C13 119.0(5) . . ?
C9 C8 N1 124.6(5) . . ?
C13 C8 N1 116.4(5) . . ?
C10 C9 C8 120.9(6) . . ?
C10 C9 H9A 119.5 . . ?
C8 C9 H9A 119.5 . . ?
C11 C10 C9 120.3(6) . . ?
C11 C10 H10A 119.9 . . ?
C9 C10 H10A 119.9 . . ?
C10 C11 C12 120.2(6) . . ?
C10 C11 H11A 119.9 . . ?
C12 C11 H11A 119.9 . . ?
C11 C12 C13 120.7(5) . . ?
C11 C12 H12A 119.6 . . ?
C13 C12 H12A 119.6 . . ?
O3 C13 C12 121.2(5) . . ?
O3 C13 C8 120.0(5) . . ?
C12 C13 C8 118.8(5) . . ?
O4 C14 H14A 109.5 . . ?
O4 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
O4 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C20 C15 C16 119.3(6) . . ?
C20 C15 C21 117.4(6) . . ?
C16 C15 C21 123.3(5) . . ?
O5 C16 C15 122.6(5) . . ?
O5 C16 C17 119.4(6) . . ?
C15 C16 C17 118.0(5) . . ?
O7 C17 C18 125.7(6) . . ?
O7 C17 C16 113.6(5) . . ?
C18 C17 C16 120.7(7) . . ?
C17 C18 C19 120.4(7) . . ?
C17 C18 H18A 119.8 . . ?
C19 C18 H18A 119.8 . . ?
C20 C19 C18 120.4(6) . . ?
C20 C19 H19A 119.8 . . ?
C18 C19 H19A 119.8 . . ?
C19 C20 C15 121.1(7) . . ?
C19 C20 H20A 119.5 . . ?
C15 C20 H20A 119.5 . . ?
N2 C21 C15 127.1(6) . . ?
N2 C21 H21A 116.5 . . ?
C15 C21 H21A 116.5 . . ?
C23 C22 C27 119.6(5) . . ?
C23 C22 N2 125.7(5) . . ?
C27 C22 N2 114.7(5) . . ?
C24 C23 C22 120.9(6) . . ?
C24 C23 H23A 119.6 . . ?
C22 C23 H23A 119.6 . . ?
C23 C24 C25 119.7(6) . . ?
C23 C24 H24A 120.2 . . ?
C25 C24 H24A 120.2 . . ?
C24 C25 C26 120.3(6) . . ?
C24 C25 H25A 119.8 . . ?
C26 C25 H25A 119.8 . . ?
C27 C26 C25 120.6(6) . . ?
C27 C26 H26A 119.7 . . ?
C25 C26 H26A 119.7 . . ?
O6 C27 C26 123.2(5) . . ?
O6 C27 C22 118.1(5) . . ?
C26 C27 C22 118.7(5) . . ?
O7 C28 H28A 109.5 . . ?
O7 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
O7 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
O8 C29 N3 125.5(6) . . ?
O8 C29 H29A 117.2 . . ?
N3 C29 H29A 117.2 . . ?
N3 C30 H30A 109.5 . . ?
N3 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
N3 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N3 C31 H31A 109.5 . . ?
N3 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
N3 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O11 N4 O9 Dy1 -179.9(5) . . . . ?
O10 N4 O9 Dy1 1.4(5) . . . . ?
O11 N4 O10 Dy1 179.9(5) . . . . ?
O9 N4 O10 Dy1 -1.4(5) . . . . ?
Dy1 O2 C2 C1 40.8(7) . . . . ?
Dy2 O2 C2 C1 -154.3(4) 3_665 . . . ?
Dy1 O2 C2 C3 -138.8(4) . . . . ?
Dy2 O2 C2 C3 26.1(6) 3_665 . . . ?
C6 C1 C2 O2 177.4(5) . . . . ?
C7 C1 C2 O2 -2.8(9) . . . . ?
C6 C1 C2 C3 -3.1(8) . . . . ?
C7 C1 C2 C3 176.7(5) . . . . ?
C14 O4 C3 C4 -24.5(8) . . . . ?
Dy2 O4 C3 C4 152.0(5) 3_665 . . . ?
C14 O4 C3 C2 158.3(5) . . . . ?
Dy2 O4 C3 C2 -25.2(5) 3_665 . . . ?
O2 C2 C3 C4 -175.9(5) . . . . ?
C1 C2 C3 C4 4.5(8) . . . . ?
O2 C2 C3 O4 1.3(7) . . . . ?
C1 C2 C3 O4 -178.2(5) . . . . ?
O4 C3 C4 C5 179.9(5) . . . . ?
C2 C3 C4 C5 -3.2(9) . . . . ?
C3 C4 C5 C6 0.3(10) . . . . ?
C4 C5 C6 C1 1.0(10) . . . . ?
C2 C1 C6 C5 0.4(9) . . . . ?
C7 C1 C6 C5 -179.4(6) . . . . ?
C8 N1 C7 C1 179.7(5) . . . . ?
Dy1 N1 C7 C1 -17.0(8) . . . . ?
C2 C1 C7 N1 -7.3(10) . . . . ?
C6 C1 C7 N1 172.5(6) . . . . ?
C7 N1 C8 C9 -20.8(8) . . . . ?
Dy1 N1 C8 C9 174.3(5) . . . . ?
C7 N1 C8 C13 159.9(5) . . . . ?
Dy1 N1 C8 C13 -5.0(6) . . . . ?
C13 C8 C9 C10 -3.1(9) . . . . ?
N1 C8 C9 C10 177.6(6) . . . . ?
C8 C9 C10 C11 -0.3(10) . . . . ?
C9 C10 C11 C12 1.6(10) . . . . ?
C10 C11 C12 C13 0.6(9) . . . . ?
Dy1 O3 C13 C12 179.1(4) . . . . ?
Dy2 O3 C13 C12 -59.6(6) . . . . ?
Dy1 O3 C13 C8 0.5(6) . . . . ?
Dy2 O3 C13 C8 121.8(4) . . . . ?
C11 C12 C13 O3 177.3(5) . . . . ?
C11 C12 C13 C8 -4.0(8) . . . . ?
C9 C8 C13 O3 -176.1(5) . . . . ?
N1 C8 C13 O3 3.2(7) . . . . ?
C9 C8 C13 C12 5.2(8) . . . . ?
N1 C8 C13 C12 -175.4(5) . . . . ?
Dy2 O5 C16 C15 -30.7(8) . . . . ?
Dy2 O5 C16 C17 150.0(4) . . . . ?
C20 C15 C16 O5 -178.4(5) . . . . ?
C21 C15 C16 O5 0.0(9) . . . . ?
C20 C15 C16 C17 1.0(8) . . . . ?
C21 C15 C16 C17 179.4(5) . . . . ?
C28 O7 C17 C18 -24.7(10) . . . . ?
C28 O7 C17 C16 157.7(6) . . . . ?
O5 C16 C17 O7 -1.6(8) . . . . ?
C15 C16 C17 O7 179.0(5) . . . . ?
O5 C16 C17 C18 -179.3(6) . . . . ?
C15 C16 C17 C18 1.3(9) . . . . ?
O7 C17 C18 C19 -179.7(6) . . . . ?
C16 C17 C18 C19 -2.3(10) . . . . ?
C17 C18 C19 C20 0.9(11) . . . . ?
C18 C19 C20 C15 1.4(11) . . . . ?
C16 C15 C20 C19 -2.4(10) . . . . ?
C21 C15 C20 C19 179.1(6) . . . . ?
C22 N2 C21 C15 -175.2(5) . . . . ?
Dy2 N2 C21 C15 3.3(9) . . . . ?
C20 C15 C21 N2 -170.7(6) . . . . ?
C16 C15 C21 N2 10.8(10) . . . . ?
C21 N2 C22 C23 -30.8(9) . . . . ?
Dy2 N2 C22 C23 150.4(5) . . . . ?
C21 N2 C22 C27 150.8(5) . . . . ?
Dy2 N2 C22 C27 -28.0(6) . . . . ?
C27 C22 C23 C24 -3.2(10) . . . . ?
N2 C22 C23 C24 178.5(6) . . . . ?
C22 C23 C24 C25 0.7(11) . . . . ?
C23 C24 C25 C26 0.1(11) . . . . ?
C24 C25 C26 C27 1.6(10) . . . . ?
Dy1 O6 C27 C26 -14.1(8) . . . . ?
Dy2 O6 C27 C26 -153.6(4) . . . . ?
Dy1 O6 C27 C22 167.9(4) . . . . ?
Dy2 O6 C27 C22 28.4(6) . . . . ?
C25 C26 C27 O6 177.9(5) . . . . ?
C25 C26 C27 C22 -4.1(9) . . . . ?
C23 C22 C27 O6 -177.1(5) . . . . ?
N2 C22 C27 O6 1.4(7) . . . . ?
C23 C22 C27 C26 4.9(8) . . . . ?
N2 C22 C27 C26 -176.6(5) . . . . ?
Dy2 O8 C29 N3 -160.6(4) . . . . ?
C30 N3 C29 O8 1.8(10) . . . . ?
C31 N3 C29 O8 175.0(6) . . . . ?

_refine_diff_density_max         1.066
_refine_diff_density_min         -0.604
_refine_diff_density_rms         0.123

