# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1845686'
_audit_update_record             
;
2018-05-28 deposited with the CCDC.
2018-07-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C27 H30 Ag N7 O3 S3'
_chemical_formula_sum            'C27 H30 Ag N7 O3 S3'
_chemical_formula_weight         704.63

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   19.003(6)
_cell_length_b                   11.340(4)
_cell_length_c                   15.080(5)
_cell_angle_alpha                90
_cell_angle_beta                 102.27(2)
_cell_angle_gamma                90
_cell_volume                     3175.6(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    7182
_cell_measurement_theta_min      2.19
_cell_measurement_theta_max      24.18

_exptl_crystal_description       parallelepiped
_exptl_crystal_colour            white
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.474
_exptl_crystal_F_000             1440
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.11
_exptl_absorpt_coefficient_mu    0.872
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8110
_exptl_absorpt_correction_T_max  0.9093
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'omega scan'
_diffrn_reflns_number            67030
_diffrn_reflns_av_unetI/netI     0.0351
_diffrn_reflns_av_R_equivalents  0.0639
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.104
_diffrn_reflns_theta_max         27.498
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7298
_reflns_number_gt                5045
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0520P)²+3.6977P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7298
_refine_ls_number_parameters     370
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0699
_refine_ls_R_factor_gt           0.0404
_refine_ls_wR_factor_ref         0.1162
_refine_ls_wR_factor_gt          0.0977
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_restrained_S_all      0.989
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.13776(2) 0.85364(2) 0.29764(2) 0.04801(10) Uani 1 1 d . . . . .
S1 S 0.23059(5) 0.62888(7) 0.35831(6) 0.0404(2) Uani 1 1 d . . . . .
S2 S 0.19976(6) 0.06266(8) 0.19869(6) 0.0517(3) Uani 1 1 d . . . . .
S3 S 0.49192(5) 0.51342(8) 0.22852(6) 0.0439(2) Uani 1 1 d . . . . .
N1 N 0.20872(14) 0.8270(2) 0.43685(18) 0.0348(6) Uani 1 1 d . . . . .
N2 N 0.27879(14) 0.6830(2) 0.53472(18) 0.0366(6) Uani 1 1 d . . . . .
N3 N 0.12399(15) -0.1268(2) 0.14648(18) 0.0378(6) Uani 1 1 d . . . . .
N4 N 0.12307(14) 0.0189(2) 0.03027(18) 0.0376(6) Uani 1 1 d . . . . .
N5 N 0.41744(15) 0.4598(3) 0.06075(19) 0.0409(7) Uani 1 1 d . . . . .
N6 N 0.46490(15) 0.6562(2) 0.08937(19) 0.0407(6) Uani 1 1 d . . . . .
N7 N -0.0125(2) 0.8795(3) 0.3307(2) 0.0575(9) Uani 1 1 d . . . . .
O1 O 0.03636(18) 0.9536(4) 0.3503(3) 0.0964(12) Uani 1 1 d . . . . .
O2 O 0.0004(2) 0.7898(3) 0.2909(2) 0.0956(12) Uani 1 1 d . . . . .
O3 O -0.07117(19) 0.8949(4) 0.3510(3) 0.0995(13) Uani 1 1 d . . . . .
C1 C 0.21761(18) 0.9051(3) 0.5072(2) 0.0398(8) Uani 1 1 d . . . . .
C2 C 0.25712(19) 0.8729(3) 0.5921(2) 0.0455(8) Uani 1 1 d . . . . .
H2A H 0.2637 0.9260 0.6402 0.055 Uiso 1 1 calc R U . . .
C3 C 0.28691(18) 0.7601(3) 0.6047(2) 0.0400(8) Uani 1 1 d . . . . .
C4 C 0.24106(16) 0.7205(3) 0.4553(2) 0.0330(7) Uani 1 1 d . . . . .
C5 C 0.3300(2) 0.7183(4) 0.6945(2) 0.0558(10) Uani 1 1 d . . . . .
H5A H 0.3322 0.7798 0.7388 0.084 Uiso 1 1 calc R U . . .
H5B H 0.3074 0.6499 0.7136 0.084 Uiso 1 1 calc R U . . .
H5C H 0.3779 0.6986 0.6884 0.084 Uiso 1 1 calc R U . . .
C6 C 0.1824(2) 1.0244(3) 0.4894(3) 0.0576(10) Uani 1 1 d . . . . .
H6A H 0.1927 1.0705 0.5441 0.086 Uiso 1 1 calc R U . . .
H6B H 0.2007 1.0640 0.4428 0.086 Uiso 1 1 calc R U . . .
H6C H 0.1312 1.0146 0.4701 0.086 Uiso 1 1 calc R U . . .
C7 C 0.2644(2) 0.4855(3) 0.4056(2) 0.0416(8) Uani 1 1 d . . . . .
H7A H 0.3050 0.4966 0.4561 0.050 Uiso 1 1 calc R U . . .
H7B H 0.2270 0.4437 0.4276 0.050 Uiso 1 1 calc R U . . .
C8 C 0.28741(18) 0.4150(3) 0.3311(2) 0.0361(7) Uani 1 1 d . . . . .
C9 C 0.35825(18) 0.4217(3) 0.3190(2) 0.0368(7) Uani 1 1 d . . . . .
H9A H 0.3912 0.4690 0.3577 0.044 Uiso 1 1 calc R U . . .
C10 C 0.38076(18) 0.3588(3) 0.2501(2) 0.0356(7) Uani 1 1 d . . . . .
C11 C 0.33055(19) 0.2883(3) 0.1925(2) 0.0383(7) Uani 1 1 d . . . . .
H11A H 0.3449 0.2460 0.1465 0.046 Uiso 1 1 calc R U . . .
C12 C 0.25915(18) 0.2799(3) 0.2025(2) 0.0364(7) Uani 1 1 d . . . . .
C13 C 0.23769(18) 0.3439(3) 0.2720(2) 0.0375(7) Uani 1 1 d . . . . .
H13A H 0.1903 0.3393 0.2790 0.045 Uiso 1 1 calc R U . . .
C14 C 0.2056(2) 0.2021(3) 0.1401(2) 0.0461(9) Uani 1 1 d . . . . .
H14A H 0.2215 0.1883 0.0839 0.055 Uiso 1 1 calc R U . . .
H14B H 0.1588 0.2400 0.1257 0.055 Uiso 1 1 calc R U . . .
C15 C 0.14251(17) -0.0220(3) 0.1145(2) 0.0342(7) Uani 1 1 d . . . . .
C16 C 0.08275(19) -0.1996(3) 0.0853(2) 0.0422(8) Uani 1 1 d . . . . .
C17 C 0.0596(2) -0.1631(3) -0.0038(2) 0.0475(9) Uani 1 1 d . . . . .
H17A H 0.0311 -0.2124 -0.0460 0.057 Uiso 1 1 calc R U . . .
C18 C 0.07931(18) -0.0523(3) -0.0300(2) 0.0399(8) Uani 1 1 d . . . . .
C19 C 0.0621(3) -0.3172(3) 0.1185(3) 0.0630(12) Uani 1 1 d . . . . .
H19A H 0.0332 -0.3598 0.0689 0.094 Uiso 1 1 calc R U . . .
H19B H 0.1049 -0.3616 0.1429 0.094 Uiso 1 1 calc R U . . .
H19C H 0.0352 -0.3052 0.1649 0.094 Uiso 1 1 calc R U . . .
C20 C 0.0547(2) -0.0055(4) -0.1246(2) 0.0545(10) Uani 1 1 d . . . . .
H20A H 0.0243 -0.0628 -0.1611 0.082 Uiso 1 1 calc R U . . .
H20B H 0.0282 0.0662 -0.1230 0.082 Uiso 1 1 calc R U . . .
H20C H 0.0958 0.0098 -0.1505 0.082 Uiso 1 1 calc R U . . .
C21 C 0.45925(19) 0.3644(3) 0.2409(3) 0.0437(8) Uani 1 1 d . . . . .
H21A H 0.4644 0.3182 0.1885 0.052 Uiso 1 1 calc R U . . .
H21B H 0.4892 0.3284 0.2941 0.052 Uiso 1 1 calc R U . . .
C22 C 0.45269(17) 0.5453(3) 0.1134(2) 0.0359(7) Uani 1 1 d . . . . .
C23 C 0.39065(18) 0.4894(4) -0.0266(2) 0.0488(9) Uani 1 1 d . . . . .
C25 C 0.4382(2) 0.6840(3) 0.0015(3) 0.0481(9) Uani 1 1 d . . . . .
C24 C 0.4003(2) 0.6017(4) -0.0579(2) 0.0548(10) Uani 1 1 d . . . . .
H24A H 0.3816 0.6217 -0.1181 0.066 Uiso 1 1 calc R U . . .
C27 C 0.3522(2) 0.3926(5) -0.0874(3) 0.0754(14) Uani 1 1 d . . . . .
H27A H 0.3354 0.4229 -0.1476 0.113 Uiso 1 1 calc R U . . .
H27B H 0.3849 0.3284 -0.0891 0.113 Uiso 1 1 calc R U . . .
H27C H 0.3119 0.3650 -0.0640 0.113 Uiso 1 1 calc R U . . .
C26 C 0.4536(3) 0.8075(4) -0.0267(3) 0.0785(14) Uani 1 1 d . . . . .
H26A H 0.4324 0.8184 -0.0898 0.118 Uiso 1 1 calc R U . . .
H26B H 0.4334 0.8635 0.0087 0.118 Uiso 1 1 calc R U . . .
H26C H 0.5047 0.8191 -0.0167 0.118 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N3 2.250(3) 1_565 ?
Ag N1 2.261(3) . ?
Ag O1 2.506(3) . ?
S1 C4 1.771(3) . ?
S1 C7 1.837(3) . ?
S2 C15 1.769(3) . ?
S2 C14 1.827(4) . ?
S3 C22 1.774(3) . ?
S3 C21 1.824(4) . ?
N1 C4 1.357(4) . ?
N1 C1 1.365(4) . ?
N2 C4 1.328(4) . ?
N2 C3 1.354(4) . ?
N3 C15 1.356(4) . ?
N3 C16 1.357(4) . ?
N3 Ag 2.250(3) 1_545 ?
N4 C15 1.329(4) . ?
N4 C18 1.359(4) . ?
N5 C22 1.339(4) . ?
N5 C23 1.350(5) . ?
N6 C22 1.343(4) . ?
N6 C25 1.351(5) . ?
N7 O3 1.230(5) . ?
N7 O2 1.232(5) . ?
N7 O1 1.241(5) . ?
C1 C2 1.389(5) . ?
C1 C6 1.508(5) . ?
C2 C3 1.396(5) . ?
C3 C5 1.503(5) . ?
C7 C8 1.517(4) . ?
C8 C9 1.398(5) . ?
C8 C13 1.406(5) . ?
C9 C10 1.401(4) . ?
C10 C11 1.397(5) . ?
C10 C21 1.528(5) . ?
C11 C12 1.400(5) . ?
C12 C13 1.405(5) . ?
C12 C14 1.514(4) . ?
C16 C17 1.386(5) . ?
C16 C19 1.504(5) . ?
C17 C18 1.392(5) . ?
C18 C20 1.502(5) . ?
C23 C24 1.384(6) . ?
C23 C27 1.515(5) . ?
C25 C24 1.385(6) . ?
C25 C26 1.510(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Ag N1 150.68(10) 1_565 . ?
N3 Ag O1 110.17(13) 1_565 . ?
N1 Ag O1 96.50(12) . . ?
C4 S1 C7 103.29(15) . . ?
C15 S2 C14 102.37(15) . . ?
C22 S3 C21 101.96(17) . . ?
C4 N1 C1 116.2(3) . . ?
C4 N1 Ag 117.7(2) . . ?
C1 N1 Ag 125.9(2) . . ?
C4 N2 C3 116.5(3) . . ?
C15 N3 C16 116.6(3) . . ?
C15 N3 Ag 117.6(2) . 1_545 ?
C16 N3 Ag 123.7(2) . 1_545 ?
C15 N4 C18 116.0(3) . . ?
C22 N5 C23 115.9(3) . . ?
C22 N6 C25 115.7(3) . . ?
O3 N7 O2 121.6(4) . . ?
O3 N7 O1 121.1(4) . . ?
O2 N7 O1 117.3(4) . . ?
N7 O1 Ag 101.9(3) . . ?
N1 C1 C2 120.0(3) . . ?
N1 C1 C6 117.9(3) . . ?
C2 C1 C6 122.2(3) . . ?
C1 C2 C3 119.3(3) . . ?
N2 C3 C2 120.7(3) . . ?
N2 C3 C5 116.7(3) . . ?
C2 C3 C5 122.6(3) . . ?
N2 C4 N1 127.2(3) . . ?
N2 C4 S1 120.1(2) . . ?
N1 C4 S1 112.7(2) . . ?
C8 C7 S1 108.1(2) . . ?
C9 C8 C13 119.0(3) . . ?
C9 C8 C7 120.3(3) . . ?
C13 C8 C7 120.7(3) . . ?
C8 C9 C10 121.5(3) . . ?
C11 C10 C9 118.5(3) . . ?
C11 C10 C21 121.2(3) . . ?
C9 C10 C21 120.3(3) . . ?
C10 C11 C12 121.4(3) . . ?
C11 C12 C13 119.2(3) . . ?
C11 C12 C14 120.7(3) . . ?
C13 C12 C14 120.1(3) . . ?
C12 C13 C8 120.4(3) . . ?
C12 C14 S2 107.8(2) . . ?
N4 C15 N3 127.2(3) . . ?
N4 C15 S2 120.0(2) . . ?
N3 C15 S2 112.7(2) . . ?
N3 C16 C17 119.7(3) . . ?
N3 C16 C19 117.9(3) . . ?
C17 C16 C19 122.4(3) . . ?
C16 C17 C18 119.8(3) . . ?
N4 C18 C17 120.6(3) . . ?
N4 C18 C20 116.7(3) . . ?
C17 C18 C20 122.7(3) . . ?
C10 C21 S3 114.0(2) . . ?
N5 C22 N6 127.7(3) . . ?
N5 C22 S3 119.1(3) . . ?
N6 C22 S3 113.2(2) . . ?
N5 C23 C24 120.7(3) . . ?
N5 C23 C27 116.4(4) . . ?
C24 C23 C27 122.9(4) . . ?
N6 C25 C24 120.8(4) . . ?
N6 C25 C26 116.0(4) . . ?
C24 C25 C26 123.2(4) . . ?
C23 C24 C25 119.2(3) . . ?

_refine_diff_density_max         0.346
_refine_diff_density_min         -0.722
_refine_diff_density_rms         0.074

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_5
_database_code_depnum_ccdc_archive 'CCDC 1845687'
_audit_update_record             
;
2018-07-09 deposited with the CCDC.
2018-07-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C29 H30 Ag F3 N6 O2 S3, 0.5(H2 O)'
_chemical_formula_sum            'C29 H31 Ag F3 N6 O2.50 S3'
_chemical_formula_weight         764.65

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   20.058(4)
_cell_length_b                   11.420(2)
_cell_length_c                   15.067(3)
_cell_angle_alpha                90
_cell_angle_beta                 100.308(14)
_cell_angle_gamma                90
_cell_volume                     3395.7(12)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    9506
_cell_measurement_theta_min      2.25
_cell_measurement_theta_max      22.59

_exptl_crystal_description       parallelepiped
_exptl_crystal_colour            white
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.496
_exptl_crystal_F_000             1556
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.09
_exptl_absorpt_coefficient_mu    0.832
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8560
_exptl_absorpt_correction_T_max  0.9593
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'omega scan'
_diffrn_reflns_number            55350
_diffrn_reflns_av_unetI/netI     0.0562
_diffrn_reflns_av_R_equivalents  0.1010
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.060
_diffrn_reflns_theta_max         24.121
_diffrn_reflns_theta_full        24.121
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             5383
_reflns_number_gt                3329
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0156P)²+14.0959P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5383
_refine_ls_number_parameters     469
_refine_ls_number_restraints     115
_refine_ls_R_factor_all          0.1108
_refine_ls_R_factor_gt           0.0552
_refine_ls_wR_factor_ref         0.1221
_refine_ls_wR_factor_gt          0.0993
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_restrained_S_all      1.070
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.16593(3) 1.14171(5) 0.81786(4) 0.0623(2) Uani 1 1 d . . . . .
S1 S 0.23147(10) 0.93248(16) 0.71990(12) 0.0626(5) Uani 1 1 d . . . . .
S2 S 0.24591(10) 0.37467(15) 0.87786(11) 0.0565(5) Uani 1 1 d . . . . .
S3 S 0.49622(9) 0.47277(15) 0.73521(11) 0.0535(5) Uani 1 1 d . . . . .
N1 N 0.1526(3) 1.1110(5) 0.6712(4) 0.0544(15) Uani 1 1 d . . . . .
N2 N 0.1529(3) 0.9633(5) 0.5587(4) 0.0572(15) Uani 1 1 d . . . . .
N4 N 0.2926(3) 0.3182(5) 1.0509(3) 0.0490(14) Uani 1 1 d . . . . .
N3 N 0.2287(3) 0.1759(4) 0.9539(3) 0.0453(13) Uani 1 1 d . . . . .
N5 N 0.4651(3) 0.3470(4) 0.5898(3) 0.0472(13) Uani 1 1 d . . . . .
N6 N 0.4267(3) 0.5459(4) 0.5770(3) 0.0460(13) Uani 1 1 d . . . . .
C1 C 0.1099(4) 1.1781(7) 0.6104(6) 0.067(2) Uani 1 1 d . . . . .
C2 C 0.0876(4) 1.1358(8) 0.5259(5) 0.075(2) Uani 1 1 d . . . . .
H2 H 0.0585 1.1809 0.4845 0.090 Uiso 1 1 calc R U . . .
C3 C 0.1074(4) 1.0275(8) 0.5009(5) 0.065(2) Uani 1 1 d . . . . .
C4 C 0.1718(3) 1.0082(6) 0.6401(4) 0.0485(17) Uani 1 1 d . . . . .
C5 C 0.0894(5) 1.2941(7) 0.6430(6) 0.101(3) Uani 1 1 d . . . . .
H5A H 0.1112 1.3057 0.7044 0.151 Uiso 1 1 calc R U . . .
H5B H 0.1026 1.3553 0.6060 0.151 Uiso 1 1 calc R U . . .
H5C H 0.0411 1.2959 0.6393 0.151 Uiso 1 1 calc R U . . .
C6 C 0.0817(4) 0.9738(9) 0.4107(5) 0.102(3) Uani 1 1 d . . . . .
H6A H 0.0500 1.0261 0.3755 0.152 Uiso 1 1 calc R U . . .
H6B H 0.1190 0.9598 0.3801 0.152 Uiso 1 1 calc R U . . .
H6C H 0.0596 0.9010 0.4187 0.152 Uiso 1 1 calc R U . . .
C7 C 0.2381(4) 0.7955(5) 0.6631(4) 0.0578(19) Uani 1 1 d . . . . .
H7A H 0.1938 0.7594 0.6478 0.069 Uiso 1 1 calc R U . . .
H7B H 0.2552 0.8090 0.6076 0.069 Uiso 1 1 calc R U . . .
C8 C 0.2858(4) 0.7149(5) 0.7241(4) 0.0468(17) Uani 1 1 d . . . . .
C9 C 0.3522(3) 0.7035(5) 0.7136(4) 0.0445(16) Uani 1 1 d . . . . .
H9 H 0.3674 0.7454 0.6683 0.053 Uiso 1 1 calc R U . . .
C10 C 0.3971(3) 0.6305(5) 0.7695(4) 0.0428(15) Uani 1 1 d . . . . .
C11 C 0.3732(4) 0.5703(5) 0.8375(4) 0.0475(17) Uani 1 1 d . . . . .
H11 H 0.4027 0.5217 0.8756 0.057 Uiso 1 1 calc R U . . .
C12 C 0.3064(4) 0.5806(5) 0.8504(4) 0.0449(16) Uani 1 1 d . . . . .
C13 C 0.2631(3) 0.6534(5) 0.7926(4) 0.0481(16) Uani 1 1 d . . . . .
H13 H 0.2182 0.6610 0.7999 0.058 Uiso 1 1 calc R U . . .
C14 C 0.2825(4) 0.5131(5) 0.9244(4) 0.0559(19) Uani 1 1 d . . . . .
H14A H 0.2487 0.5581 0.9483 0.067 Uiso 1 1 calc R U . . .
H14B H 0.3202 0.4981 0.9730 0.067 Uiso 1 1 calc R U . . .
C15 C 0.2572(3) 0.2814(5) 0.9723(4) 0.0447(16) Uani 1 1 d . . . . .
C16 C 0.2364(3) 0.0984(5) 1.0219(5) 0.0512(18) Uani 1 1 d . . . . .
C17 C 0.2727(4) 0.1286(7) 1.1059(5) 0.061(2) Uani 1 1 d . . . . .
H17 H 0.2782 0.0750 1.1532 0.074 Uiso 1 1 calc R U . . .
C18 C 0.3003(3) 0.2392(6) 1.1187(4) 0.0518(18) Uani 1 1 d . . . . .
C19 C 0.2036(4) -0.0195(6) 1.0027(5) 0.082(3) Uani 1 1 d . . . . .
H19A H 0.2126 -0.0669 1.0561 0.123 Uiso 1 1 calc R U . . .
H19B H 0.1556 -0.0098 0.9844 0.123 Uiso 1 1 calc R U . . .
H19C H 0.2218 -0.0571 0.9552 0.123 Uiso 1 1 calc R U . . .
C20 C 0.3405(4) 0.2794(7) 1.2074(4) 0.072(2) Uani 1 1 d . . . . .
H20A H 0.3430 0.2172 1.2507 0.108 Uiso 1 1 calc R U . . .
H20B H 0.3854 0.3005 1.1996 0.108 Uiso 1 1 calc R U . . .
H20C H 0.3188 0.3461 1.2285 0.108 Uiso 1 1 calc R U . . .
C21 C 0.4700(3) 0.6202(5) 0.7589(4) 0.0544(18) Uani 1 1 d . . . . .
H21A H 0.4984 0.6477 0.8138 0.065 Uiso 1 1 calc R U . . .
H21B H 0.4775 0.6714 0.7102 0.065 Uiso 1 1 calc R U . . .
C22 C 0.4577(3) 0.4548(6) 0.6212(4) 0.0416(15) Uani 1 1 d . . . . .
C23 C 0.4380(4) 0.3294(6) 0.5029(5) 0.0553(19) Uani 1 1 d . . . . .
C24 C 0.4039(4) 0.4195(7) 0.4505(4) 0.0581(19) Uani 1 1 d . . . . .
H24 H 0.3846 0.4068 0.3904 0.070 Uiso 1 1 calc R U . . .
C25 C 0.3997(3) 0.5264(6) 0.4894(5) 0.0533(18) Uani 1 1 d . . . . .
C26 C 0.4486(4) 0.2108(6) 0.4652(5) 0.076(2) Uani 1 1 d . . . . .
H26A H 0.4272 0.2079 0.4029 0.114 Uiso 1 1 calc R U . . .
H26B H 0.4962 0.1963 0.4701 0.114 Uiso 1 1 calc R U . . .
H26C H 0.4291 0.1522 0.4985 0.114 Uiso 1 1 calc R U . . .
C27 C 0.3654(4) 0.6296(7) 0.4384(5) 0.081(2) Uani 1 1 d . . . . .
H27A H 0.3480 0.6070 0.3773 0.121 Uiso 1 1 calc R U . . .
H27B H 0.3287 0.6557 0.4666 0.121 Uiso 1 1 calc R U . . .
H27C H 0.3975 0.6920 0.4388 0.121 Uiso 1 1 calc R U . . .
F1 F -0.0733(9) 1.2416(18) 0.7935(16) 0.213(9) Uani 0.5 1 d D U P A 1
F2 F -0.0946(13) 1.071(2) 0.8276(19) 0.164(14) Uani 0.5 1 d D U P A 1
F3 F -0.0558(12) 1.182(2) 0.9282(14) 0.137(9) Uani 0.5 1 d D U P A 1
O1 O 0.0661(7) 1.1794(17) 0.8701(12) 0.113(7) Uani 0.5 1 d D U P A 1
O2 O 0.0242(8) 1.0332(14) 0.7891(11) 0.132(6) Uani 0.5 1 d D U P A 1
C28 C 0.0205(9) 1.1210(16) 0.8343(12) 0.070(8) Uani 0.5 1 d D U P A 1
C29 C -0.0514(10) 1.1562(16) 0.8464(12) 0.091(7) Uani 0.5 1 d D U P A 1
F1A F -0.0953(8) 1.086(2) 0.8196(16) 0.143(13) Uani 0.5 1 d D U P A 2
F2A F -0.0365(7) 1.0462(14) 0.9563(9) 0.146(5) Uani 0.5 1 d D U P A 2
F3A F -0.0597(13) 1.232(2) 0.9068(19) 0.190(15) Uani 0.5 1 d D U P A 2
O1A O 0.0640(10) 1.0496(19) 0.8704(15) 0.172(7) Uani 0.5 1 d D U P A 2
O2A O 0.0352(13) 1.210(2) 0.8111(17) 0.207(13) Uani 0.5 1 d D U P A 2
C28A C 0.0232(13) 1.1269(17) 0.8520(14) 0.104(10) Uani 0.5 1 d D U P A 2
C29A C -0.0443(13) 1.1212(16) 0.8861(13) 0.115(10) Uani 0.5 1 d D U P A 2
O0AA O -0.0926(10) 1.3173(19) 0.6949(19) 0.261(13) Uani 0.5 1 d D . P B 2
H0AA H -0.0504 1.3133 0.6942 0.391 Uiso 0.5 1 d DR U P B 2
H0AB H -0.1027 1.3887 0.6837 0.391 Uiso 0.5 1 d R U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N1 2.206(5) . ?
Ag N3 2.239(5) 1_565 ?
Ag O1 2.318(14) . ?
Ag O1A 2.55(2) . ?
S1 C4 1.764(7) . ?
S1 C7 1.800(6) . ?
S2 C15 1.759(6) . ?
S2 C14 1.829(6) . ?
S3 C22 1.765(6) . ?
S3 C21 1.819(6) . ?
N1 C4 1.345(8) . ?
N1 C1 1.372(9) . ?
N2 C4 1.321(8) . ?
N2 C3 1.359(9) . ?
N4 C15 1.335(8) . ?
N4 C18 1.351(8) . ?
N3 C15 1.341(8) . ?
N3 C16 1.342(7) . ?
N3 Ag 2.239(5) 1_545 ?
N5 C22 1.337(7) . ?
N5 C23 1.340(8) . ?
N6 C22 1.328(7) . ?
N6 C25 1.352(8) . ?
C1 C2 1.360(10) . ?
C1 C5 1.496(10) . ?
C2 C3 1.372(10) . ?
C3 C6 1.495(10) . ?
C7 C8 1.514(8) . ?
C8 C9 1.374(8) . ?
C8 C13 1.391(8) . ?
C9 C10 1.394(8) . ?
C10 C11 1.388(8) . ?
C10 C21 1.503(8) . ?
C11 C12 1.393(8) . ?
C12 C13 1.391(8) . ?
C12 C14 1.503(8) . ?
C16 C17 1.387(9) . ?
C16 C19 1.503(9) . ?
C17 C18 1.379(9) . ?
C18 C20 1.504(9) . ?
C23 C24 1.399(9) . ?
C23 C26 1.499(9) . ?
C24 C25 1.363(9) . ?
C25 C27 1.505(9) . ?
F1 C29 1.286(18) . ?
F2 C29 1.301(19) . ?
F3 C29 1.288(18) . ?
O1 C28 1.182(15) . ?
O2 C28 1.222(16) . ?
C28 C29 1.539(17) . ?
F1A C29A 1.358(18) . ?
F2A C29A 1.348(17) . ?
F3A C29A 1.355(19) . ?
O1A C28A 1.202(17) . ?
O2A C28A 1.179(17) . ?
C28A C29A 1.533(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag N3 153.12(19) . 1_565 ?
N1 Ag O1 114.3(4) . . ?
N3 Ag O1 92.0(4) 1_565 . ?
N1 Ag O1A 106.6(6) . . ?
N3 Ag O1A 98.0(5) 1_565 . ?
C4 S1 C7 101.6(3) . . ?
C15 S2 C14 103.2(3) . . ?
C22 S3 C21 101.9(3) . . ?
C4 N1 C1 116.0(6) . . ?
C4 N1 Ag 119.8(4) . . ?
C1 N1 Ag 122.0(5) . . ?
C4 N2 C3 115.7(6) . . ?
C15 N4 C18 115.5(6) . . ?
C15 N3 C16 116.6(6) . . ?
C15 N3 Ag 119.7(4) . 1_545 ?
C16 N3 Ag 123.6(5) . 1_545 ?
C22 N5 C23 115.6(6) . . ?
C22 N6 C25 115.5(6) . . ?
C2 C1 N1 119.2(7) . . ?
C2 C1 C5 124.0(8) . . ?
N1 C1 C5 116.9(7) . . ?
C1 C2 C3 121.0(7) . . ?
N2 C3 C2 120.3(7) . . ?
N2 C3 C6 116.3(8) . . ?
C2 C3 C6 123.4(8) . . ?
N2 C4 N1 127.6(6) . . ?
N2 C4 S1 119.3(5) . . ?
N1 C4 S1 113.1(5) . . ?
C8 C7 S1 109.4(4) . . ?
C9 C8 C13 119.3(6) . . ?
C9 C8 C7 120.5(6) . . ?
C13 C8 C7 120.2(6) . . ?
C8 C9 C10 121.5(6) . . ?
C11 C10 C9 118.1(6) . . ?
C11 C10 C21 120.6(6) . . ?
C9 C10 C21 121.2(6) . . ?
C10 C11 C12 121.9(6) . . ?
C13 C12 C11 118.2(6) . . ?
C13 C12 C14 121.6(6) . . ?
C11 C12 C14 120.2(6) . . ?
C12 C13 C8 121.0(6) . . ?
C12 C14 S2 108.6(4) . . ?
N4 C15 N3 127.3(6) . . ?
N4 C15 S2 119.8(5) . . ?
N3 C15 S2 112.8(5) . . ?
N3 C16 C17 120.2(6) . . ?
N3 C16 C19 117.2(6) . . ?
C17 C16 C19 122.6(6) . . ?
C18 C17 C16 119.1(6) . . ?
N4 C18 C17 121.2(7) . . ?
N4 C18 C20 116.0(6) . . ?
C17 C18 C20 122.8(6) . . ?
C10 C21 S3 114.5(4) . . ?
N6 C22 N5 128.1(6) . . ?
N6 C22 S3 118.8(5) . . ?
N5 C22 S3 113.2(5) . . ?
N5 C23 C24 120.9(6) . . ?
N5 C23 C26 116.5(7) . . ?
C24 C23 C26 122.6(7) . . ?
C25 C24 C23 118.5(6) . . ?
N6 C25 C24 121.5(6) . . ?
N6 C25 C27 115.9(7) . . ?
C24 C25 C27 122.7(7) . . ?
C28 O1 Ag 112.7(12) . . ?
O1 C28 O2 126.7(19) . . ?
O1 C28 C29 117.7(17) . . ?
O2 C28 C29 115.6(15) . . ?
F1 C29 F3 110.0(19) . . ?
F1 C29 F2 107.0(19) . . ?
F3 C29 F2 103.0(19) . . ?
F1 C29 C28 110.4(14) . . ?
F3 C29 C28 113.6(17) . . ?
F2 C29 C28 112.4(18) . . ?
C28A O1A Ag 100.2(17) . . ?
O2A C28A O1A 121(2) . . ?
O2A C28A C29A 119.0(19) . . ?
O1A C28A C29A 120(2) . . ?
F2A C29A F3A 114(2) . . ?
F2A C29A F1A 110.9(18) . . ?
F3A C29A F1A 105.9(19) . . ?
F2A C29A C28A 107.7(17) . . ?
F3A C29A C28A 106.7(18) . . ?
F1A C29A C28A 111.1(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 N1 C1 C2 2.9(10) . . . . ?
Ag N1 C1 C2 -160.1(6) . . . . ?
C4 N1 C1 C5 -178.4(7) . . . . ?
Ag N1 C1 C5 18.5(9) . . . . ?
N1 C1 C2 C3 -0.2(12) . . . . ?
C5 C1 C2 C3 -178.7(8) . . . . ?
C4 N2 C3 C2 4.8(10) . . . . ?
C4 N2 C3 C6 -175.7(6) . . . . ?
C1 C2 C3 N2 -3.9(12) . . . . ?
C1 C2 C3 C6 176.6(7) . . . . ?
C3 N2 C4 N1 -1.9(10) . . . . ?
C3 N2 C4 S1 -179.3(5) . . . . ?
C1 N1 C4 N2 -2.0(10) . . . . ?
Ag N1 C4 N2 161.5(5) . . . . ?
C1 N1 C4 S1 175.6(5) . . . . ?
Ag N1 C4 S1 -20.9(6) . . . . ?
C7 S1 C4 N2 -8.7(6) . . . . ?
C7 S1 C4 N1 173.5(5) . . . . ?
C4 S1 C7 C8 -177.5(5) . . . . ?
S1 C7 C8 C9 -98.8(6) . . . . ?
S1 C7 C8 C13 79.9(7) . . . . ?
C13 C8 C9 C10 0.8(9) . . . . ?
C7 C8 C9 C10 179.5(5) . . . . ?
C8 C9 C10 C11 -1.0(9) . . . . ?
C8 C9 C10 C21 -178.8(6) . . . . ?
C9 C10 C11 C12 0.4(9) . . . . ?
C21 C10 C11 C12 178.3(5) . . . . ?
C10 C11 C12 C13 0.2(9) . . . . ?
C10 C11 C12 C14 179.5(6) . . . . ?
C11 C12 C13 C8 -0.4(9) . . . . ?
C14 C12 C13 C8 -179.6(6) . . . . ?
C9 C8 C13 C12 -0.1(9) . . . . ?
C7 C8 C13 C12 -178.8(6) . . . . ?
C13 C12 C14 S2 86.2(6) . . . . ?
C11 C12 C14 S2 -93.0(6) . . . . ?
C15 S2 C14 C12 153.5(5) . . . . ?
C18 N4 C15 N3 0.1(9) . . . . ?
C18 N4 C15 S2 -178.0(4) . . . . ?
C16 N3 C15 N4 0.3(9) . . . . ?
Ag N3 C15 N4 176.0(5) 1_545 . . . ?
C16 N3 C15 S2 178.4(4) . . . . ?
Ag N3 C15 S2 -5.9(6) 1_545 . . . ?
C14 S2 C15 N4 -6.4(6) . . . . ?
C14 S2 C15 N3 175.3(4) . . . . ?
C15 N3 C16 C17 -0.4(9) . . . . ?
Ag N3 C16 C17 -175.9(5) 1_545 . . . ?
C15 N3 C16 C19 178.8(6) . . . . ?
Ag N3 C16 C19 3.3(8) 1_545 . . . ?
N3 C16 C17 C18 0.2(10) . . . . ?
C19 C16 C17 C18 -179.0(6) . . . . ?
C15 N4 C18 C17 -0.3(9) . . . . ?
C15 N4 C18 C20 179.7(6) . . . . ?
C16 C17 C18 N4 0.2(10) . . . . ?
C16 C17 C18 C20 -179.8(6) . . . . ?
C11 C10 C21 S3 61.4(7) . . . . ?
C9 C10 C21 S3 -120.9(6) . . . . ?
C22 S3 C21 C10 74.5(5) . . . . ?
C25 N6 C22 N5 -0.3(9) . . . . ?
C25 N6 C22 S3 178.6(4) . . . . ?
C23 N5 C22 N6 0.3(9) . . . . ?
C23 N5 C22 S3 -178.6(4) . . . . ?
C21 S3 C22 N6 6.3(6) . . . . ?
C21 S3 C22 N5 -174.6(4) . . . . ?
C22 N5 C23 C24 -0.6(9) . . . . ?
C22 N5 C23 C26 177.2(6) . . . . ?
N5 C23 C24 C25 0.9(10) . . . . ?
C26 C23 C24 C25 -176.7(6) . . . . ?
C22 N6 C25 C24 0.7(9) . . . . ?
C22 N6 C25 C27 -179.1(6) . . . . ?
C23 C24 C25 N6 -0.9(10) . . . . ?
C23 C24 C25 C27 178.8(6) . . . . ?
Ag O1 C28 O2 15(2) . . . . ?
Ag O1 C28 C29 -166.3(12) . . . . ?
O1 C28 C29 F1 79(2) . . . . ?
O2 C28 C29 F1 -102(2) . . . . ?
O1 C28 C29 F3 -45(2) . . . . ?
O2 C28 C29 F3 134(2) . . . . ?
O1 C28 C29 F2 -161(2) . . . . ?
O2 C28 C29 F2 18(2) . . . . ?
Ag O1A C28A O2A 7(2) . . . . ?
Ag O1A C28A C29A -169.6(13) . . . . ?
O2A C28A C29A F2A -157(2) . . . . ?
O1A C28A C29A F2A 20(2) . . . . ?
O2A C28A C29A F3A -34(3) . . . . ?
O1A C28A C29A F3A 143(2) . . . . ?
O2A C28A C29A F1A 81(3) . . . . ?
O1A C28A C29A F1A -102(2) . . . . ?

_refine_diff_density_max         0.668
_refine_diff_density_min         -0.565
_refine_diff_density_rms         0.079

