# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2019

data_exp_796
_audit_creation_date               2019-04-30
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2016/6'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C15 H21 N O Si'
_chemical_formula_sum              'C15 H21 N O Si'
_chemical_formula_weight           259.42
_chemical_absolute_configuration   ?
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             4
_space_group_name_H-M_alt          'P 1 21 1'
_space_group_name_Hall             'P 2yb'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z'

_cell_length_a                     9.9331(2)
_cell_length_b                     7.24400(10)
_cell_length_c                     10.5483(2)
_cell_angle_alpha                  90
_cell_angle_beta                   108.156(2)
_cell_angle_gamma                  90
_cell_volume                       721.22(2)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      11548
_cell_measurement_temperature      100.00(10)
_cell_measurement_theta_max        74.0820
_cell_measurement_theta_min        5.3220
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      1.334
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.07906
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.32a (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'clear light yellow'
_exptl_crystal_colour_lustre       clear
_exptl_crystal_colour_modifier     light
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.195
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plate
_exptl_crystal_F_000               280
_exptl_crystal_size_max            0.46
_exptl_crystal_size_mid            0.12
_exptl_crystal_size_min            0.09
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0841
_diffrn_reflns_av_unetI/netI       0.0426
_diffrn_reflns_Laue_measured_fraction_full  0.999
_diffrn_reflns_Laue_measured_fraction_max  0.991
_diffrn_reflns_limit_h_max         12
_diffrn_reflns_limit_h_min         -12
_diffrn_reflns_limit_k_max         8
_diffrn_reflns_limit_k_min         -8
_diffrn_reflns_limit_l_max         13
_diffrn_reflns_limit_l_min         -13
_diffrn_reflns_number              13777
_diffrn_reflns_point_group_measured_fraction_full  0.974
_diffrn_reflns_point_group_measured_fraction_max  0.959
_diffrn_reflns_theta_full          67.684
_diffrn_reflns_theta_max           74.386
_diffrn_reflns_theta_min           4.411
_diffrn_ambient_environment        N~2~
_diffrn_ambient_temperature        100.00(10)
_diffrn_detector                   'CCD plate'
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.999
_diffrn_measured_fraction_theta_max  0.991
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω     28.00  78.00   1.00    1.00    --    0.00  38.00 120.00   50
  2  ω    -55.00  -9.00   1.00    1.00    --    0.00 -57.00-180.00   46
  3  ω     -7.00  25.00   1.00    1.00    --    0.00  38.00 -60.00   32
  4  ω    -33.00  -7.00   1.00    1.00    --    0.00 -82.00 -90.00   26
  5  ω    -19.00  28.00   1.00    1.00    --    0.00  38.00 -90.00   47
  6  ω      3.00  31.00   1.00    1.00    --    0.00 -82.00 -90.00   28
  7  ω    -84.00 -59.00   1.00    1.00    --    0.00 -57.00-180.00   25
  8  ω     29.00  88.00   1.00    1.00    --    0.00  38.00 -60.00   59
  9  ω     53.00  87.00   1.00    1.00    --    0.00  38.00  60.00   34
 10  ω    -86.00 -17.00   1.00    1.00    --    0.00 -82.00   0.00   69
 11  ω     -4.00  21.00   1.00    1.00    --    0.00 -57.00-180.00   25
 12  ω    -17.00  20.00   1.00    1.00    --    0.00  38.00  60.00   37
 13  ω    -37.00   0.00   1.00    1.00    --    0.00 -38.00  90.00   37
 14  ω    -88.00 -54.00   1.00    1.00    --    0.00 -38.00  90.00   34
 15  ω    -17.00  21.00   1.00    1.00    --    0.00  38.00 120.00   38
 16  ω     53.00 128.00   1.00    1.00    --   95.80 -82.00-150.00   75
 17  ω    124.00 163.00   1.00    1.00    --   95.80  45.00  90.00   39
 18  ω    160.00 185.00   1.00    1.00    --   95.80  77.00-150.00   25
 19  ω     76.00 118.00   1.00    1.00    --   95.80  45.00  90.00   42
 20  ω     65.00  91.00   1.00    1.00    --   95.80  77.00-120.00   26
 21  ω     65.00  91.00   1.00    1.00    --   95.80  77.00-150.00   26
 22  ω     76.00 146.00   1.00    1.00    --   95.80  45.00 -60.00   70
 23  ω    126.00 170.00   1.00    1.00    --   95.80  82.00   0.00   44
 24  ω     65.00  91.00   1.00    1.00    --   95.80  77.00 -60.00   26
 25  ω    112.00 181.00   1.00    1.00    --   95.80  77.00 -60.00   69
 26  ω     66.00  91.00   1.00    1.00    --   95.80  77.00 150.00   25
 27  ω     63.00  91.00   1.00    1.00    --   95.80  82.00 -30.00   28
 28  ω    128.00 181.00   1.00    1.00    --   95.80  82.00 -30.00   53
 29  ω     86.00 127.00   1.00    1.00    --   95.80 -82.00 120.00   41
 30  ω     77.00 184.00   1.00    1.00    --   95.80  45.00-150.00  107
 31  ω     64.00  90.00   1.00    1.00    --   95.80  82.00   0.00   26
 32  ω    160.00 185.00   1.00    1.00    --   95.80  82.00  60.00   25
 33  ω     73.00  99.00   1.00    1.00    --   95.80  61.00-180.00   26
 34  ω     66.00  93.00   1.00    1.00    --   95.80  82.00  60.00   27
 35  ω     75.00 168.00   1.00    1.00    --   95.80  45.00 -90.00   93
 36  ω     72.00 154.00   1.00    1.00    --   95.80  61.00 -30.00   82
 37  ω     74.00 100.00   1.00    1.00    --   95.80  61.00 150.00   26
 38  ω     76.00 173.00   1.00    1.00    --   95.80  45.00-180.00   97
 39  ω     65.00  91.00   1.00    1.00    --   95.80  82.00 -90.00   26
 40  ω     65.00  90.00   1.00    1.00    --   95.80  77.00-180.00   25
 41  ω     63.00  89.00   1.00    1.00    --   95.80  82.00-180.00   26
 42  ω     65.00  90.00   1.00    1.00    --   95.80  77.00 120.00   25
 43  ω    120.00 166.00   1.00    1.00    --   95.80  77.00  60.00   46
 44  ω     76.00 103.00   1.00    1.00    --   95.80  45.00 120.00   27
 45  ω     12.00 101.00   1.00    1.00    --   95.80 -61.00 -30.00   89
 46  ω     65.00  91.00   1.00    1.00    --   95.80  77.00  30.00   26
 47  ω     65.00  91.00   1.00    1.00    --   95.80  77.00  60.00   26
 48  ω     75.00 101.00   1.00    1.00    --   95.80  45.00 -30.00   26
 49  ω     76.00 118.00   1.00    1.00    --   95.80  45.00  30.00   42
 50  ω     75.00 123.00   1.00    1.00    --   95.80  45.00 150.00   48
 51  ω     58.00 119.00   1.00    1.00    --   95.80 -82.00  60.00   61
 52  ω     76.00 157.00   1.00    1.00    --   95.80  45.00-120.00   81
 53  ω     65.00  91.00   1.00    1.00    --   95.80  77.00 -90.00   26
 54  ω     74.00 117.00   1.00    1.00    --   95.80  61.00  60.00   43
 55  ω    154.00 179.00   1.00    1.00    --   95.80  45.00 -60.00   25
 56  ω     63.00  88.00   1.00    1.00    --   95.80  82.00  90.00   25
 57  ω     12.00 124.00   1.00    1.00    --   95.80 -82.00 -30.00  112
 58  ω     33.00  63.00   1.00    1.00    --   95.80 -82.00 120.00   30
 59  ω    104.00 180.00   1.00    1.00    --   95.80  78.00  16.81   76
 60  ω     65.00  91.00   1.00    1.00    --   95.80  78.00  16.81   26
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'XtaLAB AFC12 (RINC): Kappa dual home/near'
_diffrn_measurement_method         'ω scans'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        -0.0354644000
_diffrn_orient_matrix_UB_12        -0.0217572000
_diffrn_orient_matrix_UB_13        0.1313431000
_diffrn_orient_matrix_UB_21        0.1504200000
_diffrn_orient_matrix_UB_22        0.0651416000
_diffrn_orient_matrix_UB_23        0.0790202000
_diffrn_orient_matrix_UB_31        -0.0525699000
_diffrn_orient_matrix_UB_32        0.2012647000
_diffrn_orient_matrix_UB_33        -0.0113143000
_diffrn_radiation_monochromator    graphite
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             CuK\a
_diffrn_radiation_wavelength       1.54184
_diffrn_source                     'fine-focus sealed X-ray tube'
_diffrn_source_type                'Enhance (Cu) X-ray Source'
_reflns_Friedel_coverage           0.785
_reflns_Friedel_fraction_full      0.945
_reflns_Friedel_fraction_max       0.920
_reflns_number_gt                  2774
_reflns_number_total               2822
_reflns_odcompleteness_completeness  100.00
_reflns_odcompleteness_iscentric   1
_reflns_odcompleteness_theta       66.97
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_data_collection         'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_data_reduction          'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           0.342
_refine_diff_density_min           -0.398
_refine_diff_density_rms           0.050
_refine_ls_abs_structure_details
;
 Flack x determined using 1192 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack     0.04(2)
_refine_ls_extinction_coef         0.008(2)
_refine_ls_extinction_expression  
 'Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^'
_refine_ls_extinction_method       'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_goodness_of_fit_ref     1.073
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       168
_refine_ls_number_reflns           2822
_refine_ls_number_restraints       1
_refine_ls_R_factor_all            0.0397
_refine_ls_R_factor_gt             0.0394
_refine_ls_restrained_S_all        1.073
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0730P)²+0.0880P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1052
_refine_ls_wR_factor_ref           0.1054
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C12(H12A,H12B), C14(H14A,H14B)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C5(H5), C7(H7), C8(H8)
2.c Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C13(H13A,H13B,H13C), C15(H15A,H15B,
 H15C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Si1 Si 0.58362(6) 0.56141(9) 0.21116(6) 0.0149(2) Uani 1 1 d . . . . .
 O1 O 0.3123(2) 0.5438(3) 0.03396(19) 0.0320(5) Uani 1 1 d . . . . .
 N1 N 0.9646(2) 0.4325(3) 0.6773(2) 0.0201(5) Uani 1 1 d . . . . .
 C1 C 0.6511(3) 0.4312(3) 0.3721(2) 0.0148(5) Uani 1 1 d . . . . .
 C2 C 0.7790(2) 0.4791(4) 0.4650(2) 0.0157(5) Uani 1 1 d . . . . .
 H2 H 0.829285 0.578263 0.446482 0.019 Uiso 1 1 calc R . . . .
 C3 C 0.8368(3) 0.3828(4) 0.5877(3) 0.0177(5) Uani 1 1 d . . . . .
 C4 C 0.7564(3) 0.2332(4) 0.6106(3) 0.0196(5) Uani 1 1 d . . . . .
 H4 H 0.790240 0.164948 0.688738 0.024 Uiso 1 1 calc R . . . .
 C5 C 0.6285(3) 0.1868(4) 0.5188(3) 0.0195(5) Uani 1 1 d . . . . .
 H5 H 0.578455 0.087019 0.537011 0.023 Uiso 1 1 calc R . . . .
 C6 C 0.5705(2) 0.2841(3) 0.3988(2) 0.0161(5) Uani 1 1 d . . . . .
 C7 C 0.4302(3) 0.2335(4) 0.3131(3) 0.0195(5) Uani 1 1 d . . . . .
 H7 H 0.390278 0.130633 0.340200 0.023 Uiso 1 1 calc R . . . .
 C8 C 0.3493(3) 0.3152(4) 0.1990(3) 0.0210(6) Uani 1 1 d . . . . .
 H8 H 0.259320 0.267243 0.158145 0.025 Uiso 1 1 calc R . . . .
 C9 C 0.3938(3) 0.4730(4) 0.1364(3) 0.0199(5) Uani 1 1 d . . . . .
 C10 C 0.6813(3) 0.4942(4) 0.0937(2) 0.0211(5) Uani 1 1 d . . . . .
 H10A H 0.779447 0.526424 0.131415 0.032 Uiso 1 1 calc GR . . . .
 H10B H 0.641938 0.558126 0.010604 0.032 Uiso 1 1 calc GR . . . .
 H10C H 0.672871 0.363477 0.078439 0.032 Uiso 1 1 calc GR . . . .
 C11 C 0.5884(3) 0.8139(4) 0.2415(3) 0.0241(6) Uani 1 1 d . . . . .
 H11A H 0.524898 0.844195 0.290871 0.036 Uiso 1 1 calc GR . . . .
 H11B H 0.559761 0.877947 0.157653 0.036 Uiso 1 1 calc GR . . . .
 H11C H 0.682923 0.850218 0.291670 0.036 Uiso 1 1 calc GR . . . .
 C12 C 1.0374(3) 0.6004(4) 0.6580(3) 0.0219(6) Uani 1 1 d . . . . .
 H12A H 1.042772 0.600514 0.567711 0.026 Uiso 1 1 calc R . . . .
 H12B H 1.133640 0.597271 0.718455 0.026 Uiso 1 1 calc R . . . .
 C13 C 0.9679(3) 0.7795(4) 0.6805(3) 0.0232(6) Uani 1 1 d . . . . .
 H13A H 0.869543 0.778318 0.628628 0.035 Uiso 1 1 calc GR . . . .
 H13B H 1.013994 0.882159 0.653821 0.035 Uiso 1 1 calc GR . . . .
 H13C H 0.976478 0.791092 0.773386 0.035 Uiso 1 1 calc GR . . . .
 C14 C 1.0116(3) 0.3476(4) 0.8104(3) 0.0240(6) Uani 1 1 d . . . . .
 H14A H 1.111514 0.374106 0.851335 0.029 Uiso 1 1 calc R . . . .
 H14B H 1.001440 0.214768 0.800357 0.029 Uiso 1 1 calc R . . . .
 C15 C 0.9316(4) 0.4125(5) 0.9034(3) 0.0289(6) Uani 1 1 d . . . . .
 H15A H 0.831681 0.398222 0.860357 0.043 Uiso 1 1 calc GR . . . .
 H15B H 0.952743 0.540112 0.925176 0.043 Uiso 1 1 calc GR . . . .
 H15C H 0.959848 0.340100 0.983653 0.043 Uiso 1 1 calc GR . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Si1 C1 1.874(2) . ?
 Si1 C9 1.913(3) . ?
 Si1 C10 1.861(3) . ?
 Si1 C11 1.855(3) . ?
 O1 C9 1.241(3) . ?
 N1 C3 1.373(4) . ?
 N1 C12 1.462(4) . ?
 N1 C14 1.469(3) . ?
 C1 C2 1.385(3) . ?
 C1 C6 1.413(3) . ?
 C2 H2 0.9300 . ?
 C2 C3 1.424(4) . ?
 C3 C4 1.411(4) . ?
 C4 H4 0.9300 . ?
 C4 C5 1.378(4) . ?
 C5 H5 0.9300 . ?
 C5 C6 1.406(4) . ?
 C6 C7 1.451(3) . ?
 C7 H7 0.9300 . ?
 C7 C8 1.357(4) . ?
 C8 H8 0.9300 . ?
 C8 C9 1.457(4) . ?
 C10 H10A 0.9600 . ?
 C10 H10B 0.9600 . ?
 C10 H10C 0.9600 . ?
 C11 H11A 0.9600 . ?
 C11 H11B 0.9600 . ?
 C11 H11C 0.9600 . ?
 C12 H12A 0.9700 . ?
 C12 H12B 0.9700 . ?
 C12 C13 1.523(4) . ?
 C13 H13A 0.9600 . ?
 C13 H13B 0.9600 . ?
 C13 H13C 0.9600 . ?
 C14 H14A 0.9700 . ?
 C14 H14B 0.9700 . ?
 C14 C15 1.517(4) . ?
 C15 H15A 0.9600 . ?
 C15 H15B 0.9600 . ?
 C15 H15C 0.9600 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C1 Si1 C9 103.49(11) . . ?
 C10 Si1 C1 110.99(11) . . ?
 C10 Si1 C9 106.82(11) . . ?
 C11 Si1 C1 110.93(12) . . ?
 C11 Si1 C9 111.72(12) . . ?
 C11 Si1 C10 112.47(13) . . ?
 C3 N1 C12 120.9(2) . . ?
 C3 N1 C14 119.9(2) . . ?
 C12 N1 C14 117.2(2) . . ?
 C2 C1 Si1 120.35(19) . . ?
 C2 C1 C6 120.0(2) . . ?
 C6 C1 Si1 119.66(19) . . ?
 C1 C2 H2 118.6 . . ?
 C1 C2 C3 122.8(2) . . ?
 C3 C2 H2 118.6 . . ?
 N1 C3 C2 121.4(2) . . ?
 N1 C3 C4 122.3(2) . . ?
 C4 C3 C2 116.2(2) . . ?
 C3 C4 H4 119.5 . . ?
 C5 C4 C3 121.0(2) . . ?
 C5 C4 H4 119.5 . . ?
 C4 C5 H5 118.7 . . ?
 C4 C5 C6 122.6(2) . . ?
 C6 C5 H5 118.7 . . ?
 C1 C6 C7 124.1(2) . . ?
 C5 C6 C1 117.3(2) . . ?
 C5 C6 C7 118.6(2) . . ?
 C6 C7 H7 115.5 . . ?
 C8 C7 C6 129.1(2) . . ?
 C8 C7 H7 115.5 . . ?
 C7 C8 H8 117.8 . . ?
 C7 C8 C9 124.4(2) . . ?
 C9 C8 H8 117.8 . . ?
 O1 C9 Si1 120.8(2) . . ?
 O1 C9 C8 120.7(2) . . ?
 C8 C9 Si1 118.39(19) . . ?
 Si1 C10 H10A 109.5 . . ?
 Si1 C10 H10B 109.5 . . ?
 Si1 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 Si1 C11 H11A 109.5 . . ?
 Si1 C11 H11B 109.5 . . ?
 Si1 C11 H11C 109.5 . . ?
 H11A C11 H11B 109.5 . . ?
 H11A C11 H11C 109.5 . . ?
 H11B C11 H11C 109.5 . . ?
 N1 C12 H12A 108.6 . . ?
 N1 C12 H12B 108.6 . . ?
 N1 C12 C13 114.78(19) . . ?
 H12A C12 H12B 107.5 . . ?
 C13 C12 H12A 108.6 . . ?
 C13 C12 H12B 108.6 . . ?
 C12 C13 H13A 109.5 . . ?
 C12 C13 H13B 109.5 . . ?
 C12 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 N1 C14 H14A 108.6 . . ?
 N1 C14 H14B 108.6 . . ?
 N1 C14 C15 114.5(2) . . ?
 H14A C14 H14B 107.6 . . ?
 C15 C14 H14A 108.6 . . ?
 C15 C14 H14B 108.6 . . ?
 C14 C15 H15A 109.5 . . ?
 C14 C15 H15B 109.5 . . ?
 C14 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  10.907
_oxdiff_exptl_absorpt_empirical_full_min  0.281
