# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_FCoP-SiMe3
_database_code_depnum_ccdc_archive 'CCDC 1950759'
loop_
_audit_author_name
_audit_author_address
'Gelun Xu'
;Shaanxi Normal University
China
;
_audit_update_record             
;
2019-09-02 deposited with the CCDC.	2019-09-26 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C64 H44 Co F16 N4 Si4'
_chemical_formula_weight         1344.32

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.176(2)
_cell_length_b                   14.488(2)
_cell_length_c                   23.065(4)
_cell_angle_alpha                90
_cell_angle_beta                 92.255(5)
_cell_angle_gamma                90
_cell_volume                     4065.7(11)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    44209
_cell_measurement_theta_min      2.770
_cell_measurement_theta_max      26.345

_exptl_crystal_description       block
_exptl_crystal_colour            purple
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.098
_exptl_crystal_F_000             1366
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_absorpt_coefficient_mu    0.340
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  bruker
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            42243
_diffrn_reflns_av_unetI/netI     0.0454
_diffrn_reflns_av_R_equivalents  0.0642
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.258
_diffrn_reflns_theta_max         26.472
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measured_fraction_theta_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_point_group_measured_fraction_full 0.991
_reflns_number_total             8305
_reflns_number_gt                5783
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+45.2000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8305
_refine_ls_number_parameters     408
_refine_ls_number_restraints     60
_refine_ls_R_factor_all          0.1584
_refine_ls_R_factor_gt           0.1211
_refine_ls_wR_factor_ref         0.3251
_refine_ls_wR_factor_gt          0.3037
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.057
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.5000 0.0000 0.0000 0.0361(3) Uani 1 2 d S . P . .
Si1 Si 0.4884(3) 0.5895(3) 0.37399(15) 0.1009(13) Uani 1 1 d . . . . .
Si2 Si 1.1527(4) 0.5269(4) -0.21252(18) 0.1258(16) Uani 1 1 d . U . . .
F1 F 0.3004(5) 0.2636(4) 0.1329(2) 0.0830(17) Uani 1 1 d . . . . .
F2 F 0.2910(5) 0.3863(4) 0.2187(2) 0.0889(18) Uani 1 1 d . . . . .
F3 F 0.6581(5) 0.1821(5) 0.1960(2) 0.0844(17) Uani 1 1 d . . . . .
F4 F 0.6494(5) 0.3061(5) 0.2816(3) 0.099(2) Uani 1 1 d . . . . .
F5 F 0.6159(5) 0.2636(5) -0.1632(3) 0.095(2) Uani 1 1 d . . . . .
F6 F 0.7561(6) 0.3801(5) -0.2113(3) 0.107(2) Uani 1 1 d . . . . .
F7 F 0.8980(5) 0.1591(5) -0.0347(3) 0.106(2) Uani 1 1 d . . . . .
F8 F 1.0384(6) 0.2754(6) -0.0852(4) 0.129(3) Uani 1 1 d . . . . .
N1 N 0.4232(4) 0.0022(4) 0.0741(2) 0.0342(11) Uani 1 1 d . . . . .
N2 N 0.5680(5) 0.1207(4) 0.0188(2) 0.0421(13) Uani 1 1 d . . . . .
C1 C 0.6360(6) 0.1719(5) -0.0143(3) 0.0425(16) Uani 1 1 d . . . . .
C2 C 0.6640(7) 0.2589(5) 0.0136(3) 0.054(2) Uani 1 1 d . . . . .
H2 H 0.7108 0.3056 -0.0006 0.064 Uiso 1 1 calc R U . . .
C3 C 0.6113(7) 0.2604(5) 0.0630(3) 0.055(2) Uani 1 1 d . . . . .
H3 H 0.6129 0.3090 0.0907 0.065 Uiso 1 1 calc R U . . .
C4 C 0.5516(7) 0.1753(5) 0.0668(3) 0.0449(17) Uani 1 1 d . . . . .
C5 C 0.4853(6) 0.1505(5) 0.1125(3) 0.0449(16) Uani 1 1 d . . . . .
C6 C 0.4286(6) 0.0696(5) 0.1158(3) 0.0389(15) Uani 1 1 d . . . . .
C7 C 0.3631(6) 0.0440(5) 0.1642(3) 0.0460(17) Uani 1 1 d . . . . .
H7 H 0.3537 0.0792 0.1984 0.055 Uiso 1 1 calc R U . . .
C8 C 0.3191(6) -0.0367(5) 0.1522(3) 0.0453(17) Uani 1 1 d . . . . .
H8 H 0.2718 -0.0710 0.1759 0.054 Uiso 1 1 calc R U . . .
C9 C 0.3567(6) -0.0635(5) 0.0957(3) 0.0391(15) Uani 1 1 d . . . . .
C10 C 0.6730(6) 0.1443(5) -0.0679(3) 0.0412(15) Uani 1 1 d . . . . .
C11 C 0.4795(7) 0.2188(5) 0.1610(3) 0.0490(18) Uani 1 1 d . . . . .
C12 C 0.3870(7) 0.2719(6) 0.1689(3) 0.054(2) Uani 1 1 d . . . . .
C13 C 0.3809(8) 0.3373(6) 0.2138(3) 0.061(2) Uani 1 1 d . . . . .
C14 C 0.4708(7) 0.3502(6) 0.2527(3) 0.059(2) Uani 1 1 d . . . . .
C15 C 0.5592(8) 0.2977(7) 0.2453(3) 0.064(2) Uani 1 1 d . . . . .
C16 C 0.5655(7) 0.2320(6) 0.2006(3) 0.060(2) Uani 1 1 d . . . . .
C17 C 0.4691(8) 0.4216(7) 0.2960(4) 0.073(3) Uani 1 1 d . . . . .
C18 C 0.4723(9) 0.4833(8) 0.3294(4) 0.085(3) Uani 1 1 d . . . . .
C19 C 0.7519(6) 0.2085(5) -0.0971(3) 0.0439(16) Uani 1 1 d . . . . .
C20 C 0.7204(7) 0.2652(6) -0.1423(3) 0.054(2) Uani 1 1 d . . . . .
C21 C 0.7946(8) 0.3259(7) -0.1677(3) 0.064(2) Uani 1 1 d . . . . .
C22 C 0.9006(8) 0.3307(6) -0.1493(3) 0.058(2) Uani 1 1 d . . . . .
C23 C 0.9328(8) 0.2739(8) -0.1048(4) 0.076(3) Uani 1 1 d . . . . .
C24 C 0.8610(8) 0.2117(7) -0.0787(4) 0.065(2) Uani 1 1 d . . . . .
C25 C 0.9772(9) 0.3938(7) -0.1738(4) 0.079(3) Uani 1 1 d . . . . .
C26 C 1.0438(12) 0.4433(11) -0.1924(6) 0.118(3) Uani 1 1 d . U . . .
C53 C 0.4001(9) 0.5819(9) 0.4373(4) 0.096(4) Uani 1 1 d . . . . .
H53A H 0.4253 0.5310 0.4624 0.144 Uiso 1 1 calc R U . . .
H53B H 0.3239 0.5708 0.4238 0.144 Uiso 1 1 calc R U . . .
H53C H 0.4044 0.6400 0.4591 0.144 Uiso 1 1 calc R U . . .
C54 C 0.6361(11) 0.5951(13) 0.3993(6) 0.155(8) Uani 1 1 d . . . . .
H54A H 0.6471 0.5579 0.4345 0.232 Uiso 1 1 calc R U . . .
H54B H 0.6563 0.6593 0.4077 0.232 Uiso 1 1 calc R U . . .
H54C H 0.6823 0.5709 0.3689 0.232 Uiso 1 1 calc R U . . .
C55 C 0.4395(19) 0.6838(12) 0.3237(7) 0.174(9) Uani 1 1 d . . . . .
H55A H 0.4287 0.7405 0.3459 0.261 Uiso 1 1 calc R U . . .
H55B H 0.3699 0.6655 0.3043 0.261 Uiso 1 1 calc R U . . .
H55C H 0.4945 0.6947 0.2946 0.261 Uiso 1 1 calc R U . . .
C56 C 1.1663(14) 0.6136(11) -0.1548(7) 0.141(4) Uani 1 1 d . U . . .
H56A H 1.0999 0.6135 -0.1322 0.211 Uiso 1 1 calc R U . . .
H56B H 1.1761 0.6747 -0.1720 0.211 Uiso 1 1 calc R U . . .
H56C H 1.2302 0.5989 -0.1293 0.211 Uiso 1 1 calc R U . . .
C57 C 1.1214(14) 0.5645(13) -0.2846(7) 0.151(4) Uani 1 1 d . U . . .
H57A H 1.0976 0.5126 -0.3093 0.182 Uiso 1 1 d R U . . .
H57B H 1.0611 0.6089 -0.2821 0.182 Uiso 1 1 d R U . . .
H57C H 1.1848 0.5948 -0.3014 0.182 Uiso 1 1 d R U . . .
C58 C 1.2903(13) 0.4615(13) -0.2165(7) 0.149(4) Uani 1 1 d . U . . .
H58A H 1.2996 0.4399 -0.2563 0.223 Uiso 1 1 calc R U . . .
H58B H 1.2901 0.4084 -0.1901 0.223 Uiso 1 1 calc R U . . .
H58C H 1.3510 0.5029 -0.2051 0.223 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N2 1.976(6) . ?
Co1 N2 1.976(6) 3_655 ?
Co1 N1 1.980(4) 3_655 ?
Co1 N1 1.980(4) . ?
Si1 C54 1.870(14) . ?
Si1 C53 1.850(10) . ?
Si1 C18 1.857(10) . ?
Si1 C55 1.874(19) . ?
Si2 C56 1.833(16) . ?
Si2 C57 1.778(15) . ?
Si2 C58 1.930(19) . ?
Si2 C26 1.868(12) . ?
F1 C12 1.322(10) . ?
F2 C13 1.313(10) . ?
F3 C16 1.347(10) . ?
F4 C15 1.360(10) . ?
F5 C20 1.343(10) . ?
F6 C21 1.345(10) . ?
F7 C24 1.334(10) . ?
F8 C23 1.346(11) . ?
N1 C9 1.357(8) . ?
N1 C6 1.371(8) . ?
N2 C1 1.367(8) . ?
N2 C4 1.380(8) . ?
C1 C10 1.390(8) . ?
C1 C2 1.450(10) . ?
C2 C3 1.329(9) . ?
C2 H2 0.9500 . ?
C3 C4 1.437(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.399(9) . ?
C5 C6 1.364(10) . ?
C5 C11 1.499(9) . ?
C6 C7 1.445(8) . ?
C7 C8 1.311(10) . ?
C7 H7 0.9500 . ?
C8 C9 1.451(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.377(10) 3_655 ?
C10 C9 1.377(10) 3_655 ?
C10 C19 1.514(9) . ?
C11 C16 1.375(12) . ?
C11 C12 1.382(11) . ?
C12 C13 1.407(10) . ?
C13 C14 1.400(13) . ?
C14 C15 1.335(13) . ?
C14 C17 1.440(10) . ?
C15 C16 1.407(11) . ?
C17 C18 1.179(12) . ?
C19 C20 1.369(10) . ?
C19 C24 1.379(11) . ?
C20 C21 1.406(10) . ?
C21 C22 1.344(12) . ?
C22 C23 1.361(13) . ?
C22 C25 1.437(11) . ?
C23 C24 1.408(13) . ?
C25 C26 1.176(13) . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 H57A 0.9801 . ?
C57 H57B 0.9794 . ?
C57 H57C 0.9805 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Co1 N2 180.0 . 3_655 ?
N2 Co1 N1 89.7(2) . 3_655 ?
N2 Co1 N1 90.3(2) 3_655 3_655 ?
N2 Co1 N1 90.3(2) . . ?
N2 Co1 N1 89.7(2) 3_655 . ?
N1 Co1 N1 180.0 3_655 . ?
C54 Si1 C53 109.8(6) . . ?
C54 Si1 C18 106.8(6) . . ?
C53 Si1 C18 109.6(5) . . ?
C54 Si1 C55 116.1(9) . . ?
C53 Si1 C55 110.5(7) . . ?
C18 Si1 C55 103.7(7) . . ?
C56 Si2 C57 118.7(9) . . ?
C56 Si2 C58 108.5(8) . . ?
C57 Si2 C58 105.1(9) . . ?
C56 Si2 C26 108.0(7) . . ?
C57 Si2 C26 107.6(7) . . ?
C58 Si2 C26 108.6(8) . . ?
C9 N1 C6 104.7(5) . . ?
C9 N1 Co1 128.0(4) . . ?
C6 N1 Co1 127.3(4) . . ?
C1 N2 C4 104.4(6) . . ?
C1 N2 Co1 127.9(4) . . ?
C4 N2 Co1 127.6(4) . . ?
N2 C1 C10 124.5(6) . . ?
N2 C1 C2 111.1(5) . . ?
C10 C1 C2 124.4(6) . . ?
C3 C2 C1 106.4(6) . . ?
C3 C2 H2 126.8 . . ?
C1 C2 H2 126.8 . . ?
C2 C3 C4 107.5(6) . . ?
C2 C3 H3 126.2 . . ?
C4 C3 H3 126.2 . . ?
N2 C4 C5 124.2(6) . . ?
N2 C4 C3 110.6(5) . . ?
C5 C4 C3 125.1(6) . . ?
C6 C5 C4 124.9(6) . . ?
C6 C5 C11 119.1(6) . . ?
C4 C5 C11 116.0(6) . . ?
C5 C6 N1 125.6(5) . . ?
C5 C6 C7 124.1(6) . . ?
N1 C6 C7 110.3(6) . . ?
C8 C7 C6 107.4(6) . . ?
C8 C7 H7 126.3 . . ?
C6 C7 H7 126.3 . . ?
C7 C8 C9 106.7(6) . . ?
C7 C8 H8 126.6 . . ?
C9 C8 H8 126.6 . . ?
N1 C9 C10 125.1(5) . 3_655 ?
N1 C9 C8 110.9(6) . . ?
C10 C9 C8 124.0(6) 3_655 . ?
C1 C10 C9 124.7(6) . 3_655 ?
C1 C10 C19 116.9(6) . . ?
C9 C10 C19 118.3(5) 3_655 . ?
C16 C11 C12 116.0(7) . . ?
C16 C11 C5 122.1(7) . . ?
C12 C11 C5 121.9(7) . . ?
F1 C12 C11 120.0(6) . . ?
F1 C12 C13 117.4(8) . . ?
C11 C12 C13 122.6(8) . . ?
F2 C13 C14 120.3(7) . . ?
F2 C13 C12 119.8(8) . . ?
C14 C13 C12 119.9(8) . . ?
C15 C14 C13 117.2(7) . . ?
C15 C14 C17 122.1(9) . . ?
C13 C14 C17 120.6(9) . . ?
F4 C15 C14 120.4(7) . . ?
F4 C15 C16 116.4(8) . . ?
C14 C15 C16 123.1(8) . . ?
F3 C16 C11 119.3(7) . . ?
F3 C16 C15 119.4(8) . . ?
C11 C16 C15 121.2(8) . . ?
C18 C17 C14 175.8(10) . . ?
C17 C18 Si1 171.7(9) . . ?
C20 C19 C24 116.8(7) . . ?
C20 C19 C10 122.9(7) . . ?
C24 C19 C10 120.3(7) . . ?
F5 C20 C19 119.7(7) . . ?
F5 C20 C21 118.4(7) . . ?
C19 C20 C21 121.8(8) . . ?
F6 C21 C22 120.5(8) . . ?
F6 C21 C20 117.8(8) . . ?
C22 C21 C20 121.7(8) . . ?
C23 C22 C21 116.8(8) . . ?
C23 C22 C25 120.6(9) . . ?
C21 C22 C25 122.6(9) . . ?
F8 C23 C22 119.2(9) . . ?
F8 C23 C24 117.8(10) . . ?
C22 C23 C24 123.0(9) . . ?
F7 C24 C19 120.5(8) . . ?
F7 C24 C23 119.6(9) . . ?
C19 C24 C23 119.8(8) . . ?
C26 C25 C22 176.9(15) . . ?
C25 C26 Si2 172.8(12) . . ?
Si1 C53 H53A 109.5 . . ?
Si1 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
Si1 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
Si1 C54 H54A 109.5 . . ?
Si1 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
Si1 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
Si1 C55 H55A 109.5 . . ?
Si1 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
Si1 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
Si2 C56 H56A 109.5 . . ?
Si2 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
Si2 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
Si2 C57 H57A 110.9 . . ?
Si2 C57 H57B 106.2 . . ?
H57A C57 H57B 109.5 . . ?
Si2 C57 H57C 111.3 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
Si2 C58 H58A 109.5 . . ?
Si2 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
Si2 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 N2 C1 C10 -178.7(7) . . . . ?
Co1 N2 C1 C10 -2.6(11) . . . . ?
C4 N2 C1 C2 0.9(8) . . . . ?
Co1 N2 C1 C2 177.1(5) . . . . ?
N2 C1 C2 C3 -1.0(10) . . . . ?
C10 C1 C2 C3 178.7(8) . . . . ?
C1 C2 C3 C4 0.6(10) . . . . ?
C1 N2 C4 C5 179.2(7) . . . . ?
Co1 N2 C4 C5 3.1(11) . . . . ?
C1 N2 C4 C3 -0.5(9) . . . . ?
Co1 N2 C4 C3 -176.7(5) . . . . ?
C2 C3 C4 N2 -0.1(10) . . . . ?
C2 C3 C4 C5 -179.8(8) . . . . ?
N2 C4 C5 C6 0.1(13) . . . . ?
C3 C4 C5 C6 179.9(8) . . . . ?
N2 C4 C5 C11 179.1(7) . . . . ?
C3 C4 C5 C11 -1.2(12) . . . . ?
C4 C5 C6 N1 -3.3(12) . . . . ?
C11 C5 C6 N1 177.7(7) . . . . ?
C4 C5 C6 C7 178.1(7) . . . . ?
C11 C5 C6 C7 -0.9(11) . . . . ?
C9 N1 C6 C5 -178.9(7) . . . . ?
Co1 N1 C6 C5 3.0(10) . . . . ?
C9 N1 C6 C7 -0.1(7) . . . . ?
Co1 N1 C6 C7 -178.2(5) . . . . ?
C5 C6 C7 C8 178.8(7) . . . . ?
N1 C6 C7 C8 0.0(9) . . . . ?
C6 C7 C8 C9 0.1(8) . . . . ?
C6 N1 C9 C10 179.4(7) . . . 3_655 ?
Co1 N1 C9 C10 -2.5(10) . . . 3_655 ?
C6 N1 C9 C8 0.2(7) . . . . ?
Co1 N1 C9 C8 178.3(5) . . . . ?
C7 C8 C9 N1 -0.2(8) . . . . ?
C7 C8 C9 C10 -179.4(7) . . . 3_655 ?
N2 C1 C10 C9 2.3(12) . . . 3_655 ?
C2 C1 C10 C9 -177.3(7) . . . 3_655 ?
N2 C1 C10 C19 -177.5(7) . . . . ?
C2 C1 C10 C19 2.9(11) . . . . ?
C6 C5 C11 C16 105.5(9) . . . . ?
C4 C5 C11 C16 -73.6(10) . . . . ?
C6 C5 C11 C12 -74.1(10) . . . . ?
C4 C5 C11 C12 106.9(9) . . . . ?
C16 C11 C12 F1 -179.9(8) . . . . ?
C5 C11 C12 F1 -0.3(12) . . . . ?
C16 C11 C12 C13 1.4(12) . . . . ?
C5 C11 C12 C13 -179.0(7) . . . . ?
F1 C12 C13 F2 0.7(12) . . . . ?
C11 C12 C13 F2 179.4(8) . . . . ?
F1 C12 C13 C14 -179.0(8) . . . . ?
C11 C12 C13 C14 -0.3(13) . . . . ?
F2 C13 C14 C15 179.7(8) . . . . ?
C12 C13 C14 C15 -0.7(12) . . . . ?
F2 C13 C14 C17 -4.4(13) . . . . ?
C12 C13 C14 C17 175.2(8) . . . . ?
C13 C14 C15 F4 -179.6(8) . . . . ?
C17 C14 C15 F4 4.6(13) . . . . ?
C13 C14 C15 C16 0.4(13) . . . . ?
C17 C14 C15 C16 -175.4(8) . . . . ?
C12 C11 C16 F3 179.4(7) . . . . ?
C5 C11 C16 F3 -0.1(12) . . . . ?
C12 C11 C16 C15 -1.7(12) . . . . ?
C5 C11 C16 C15 178.7(7) . . . . ?
F4 C15 C16 F3 -0.3(12) . . . . ?
C14 C15 C16 F3 179.7(8) . . . . ?
F4 C15 C16 C11 -179.1(8) . . . . ?
C14 C15 C16 C11 0.8(14) . . . . ?
C1 C10 C19 C20 -102.9(9) . . . . ?
C9 C10 C19 C20 77.3(9) 3_655 . . . ?
C1 C10 C19 C24 77.3(9) . . . . ?
C9 C10 C19 C24 -102.5(9) 3_655 . . . ?
C24 C19 C20 F5 178.2(8) . . . . ?
C10 C19 C20 F5 -1.5(12) . . . . ?
C24 C19 C20 C21 -1.9(12) . . . . ?
C10 C19 C20 C21 178.3(7) . . . . ?
F5 C20 C21 F6 1.0(13) . . . . ?
C19 C20 C21 F6 -178.9(8) . . . . ?
F5 C20 C21 C22 -179.5(8) . . . . ?
C19 C20 C21 C22 0.6(13) . . . . ?
F6 C21 C22 C23 179.6(9) . . . . ?
C20 C21 C22 C23 0.1(13) . . . . ?
F6 C21 C22 C25 1.1(14) . . . . ?
C20 C21 C22 C25 -178.5(8) . . . . ?
C21 C22 C23 F8 179.3(9) . . . . ?
C25 C22 C23 F8 -2.1(15) . . . . ?
C21 C22 C23 C24 0.6(15) . . . . ?
C25 C22 C23 C24 179.2(9) . . . . ?
C20 C19 C24 F7 179.5(8) . . . . ?
C10 C19 C24 F7 -0.7(12) . . . . ?
C20 C19 C24 C23 2.4(13) . . . . ?
C10 C19 C24 C23 -177.8(8) . . . . ?
F8 C23 C24 F7 2.3(15) . . . . ?
C22 C23 C24 F7 -179.0(9) . . . . ?
F8 C23 C24 C19 179.4(9) . . . . ?
C22 C23 C24 C19 -1.9(15) . . . . ?

_refine_diff_density_max         1.426
_refine_diff_density_min         -0.725
_refine_diff_density_rms         0.133


_vrf_PLAT602_FCoP-SiMe3          
;
PROBLEM: ALERT: VERY LARGE Solvent Accessible VOID(S) in Structure . ! Info
RESPONSE: Solvent accessible void in structure is caused by severely
disordered of guest dichloromethane molecules which cannot be detected.
;
