# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1946617'
loop_
_audit_author_name
_audit_author_address
'Meihong Duan'
;Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2019-08-12 deposited with the CCDC.	2019-09-10 downloaded from the CCDC.
;
_audit_creation_date             2019-08-12
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.25(Li8 Na8 O36 P8 Ti4)'
_chemical_formula_sum            'Li2 Na2 O9 P2 Ti'
_chemical_formula_weight         313.70
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ti Ti 0.2776 0.4457 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           57
_space_group_name_H-M_alt        'P b c m'
_space_group_name_Hall           '-P 2c 2b'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x, y-1/2, z'

_cell_length_a                   7.2930(15)
_cell_length_b                   7.0892(14)
_cell_length_c                   14.699(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     760.0(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2385
_cell_measurement_temperature    153.1500
_cell_measurement_theta_max      27.4584
_cell_measurement_theta_min      2.7715
_shelx_estimated_absorpt_T_max   0.983
_shelx_estimated_absorpt_T_min   0.905
_exptl_absorpt_coefficient_mu    1.689
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5301
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2008)'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    2.742
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       ROD
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.01
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0852
_diffrn_reflns_av_unetI/netI     0.0723
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            2640
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.362
_diffrn_reflns_theta_min         2.771
_diffrn_ambient_temperature      153.1500
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                668
_reflns_number_total             808
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.314
_refine_diff_density_min         -0.820
_refine_diff_density_rms         0.198
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.208
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     78
_refine_ls_number_reflns         808
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1016
_refine_ls_R_factor_gt           0.0835
_refine_ls_restrained_S_all      1.208
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0425P)²+10.2824P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1640
_refine_ls_wR_factor_ref         0.1739
_refine_special_details          ?
_olex2_refinement_description    
;
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ti1 Ti 0.0169(3) 0.7875(3) 0.250000 0.0117(5) Uani 1 2 d S T P . .
P1 P 0.2693(3) 0.5096(3) 0.38778(14) 0.0110(5) Uani 1 1 d . . . . .
Na1 Na 0.0171(6) 0.250000 0.500000 0.0152(10) Uani 1 2 d S T P . .
Na2 Na 0.5449(7) 0.7338(6) 0.250000 0.0195(11) Uani 1 2 d S T P . .
O5 O 0.1088(10) 1.0138(10) 0.250000 0.0135(17) Uani 1 2 d S T P . .
O3 O 0.4679(7) 0.4978(7) 0.3603(4) 0.0143(12) Uani 1 1 d . . . . .
O2 O 0.2250(7) 0.5102(8) 0.4888(4) 0.0135(12) Uani 1 1 d . . . . .
O4 O 0.1872(8) 0.6970(7) 0.3465(4) 0.0166(13) Uani 1 1 d . . . . .
O1 O 0.1682(8) 0.3354(7) 0.3453(4) 0.0162(13) Uani 1 1 d . . . . .
Li1 Li 0.288(2) 0.547(3) 0.6089(11) 0.034(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ti1 Na1 3.6927(8) 2_564 ?
Ti1 Na1 3.6927(8) 5_566 ?
Ti1 Na2 3.463(5) 1_455 ?
Ti1 O5 1.739(7) . ?
Ti1 O5 2.146(7) 3_545 ?
Ti1 O4 1.992(6) . ?
Ti1 O4 1.992(6) 6_556 ?
Ti1 O1 1.974(6) 8_565 ?
Ti1 O1 1.974(6) 3 ?
Ti1 Li1 3.099(17) 4_566 ?
Ti1 Li1 3.099(17) 7_575 ?
P1 Na1 3.161(4) 5_566 ?
P1 Na1 3.081(3) . ?
P1 Na2 3.266(4) . ?
P1 Na2 3.124(4) 3_645 ?
P1 O3 1.506(6) . ?
P1 O2 1.520(6) . ?
P1 O4 1.578(6) . ?
P1 O1 1.568(6) . ?
Na1 O2 2.394(6) . ?
Na1 O2 2.456(6) 8 ?
Na1 O2 2.394(6) 4_556 ?
Na1 O2 2.456(6) 5_566 ?
Na1 O4 2.730(6) 5_566 ?
Na1 O4 2.730(6) 8 ?
Na1 O1 2.599(6) 4_556 ?
Na1 O1 2.599(6) . ?
Na1 Li1 3.098(17) 8 ?
Na1 Li1 3.098(17) 5_566 ?
Na2 O5 2.968(9) 3_645 ?
Na2 O3 2.478(6) 8_665 ?
Na2 O3 2.478(6) 3_655 ?
Na2 O3 2.396(6) . ?
Na2 O3 2.396(6) 6_556 ?
Na2 O4 2.981(7) 6_556 ?
Na2 O4 2.981(7) . ?
Na2 O1 2.619(7) 3_655 ?
Na2 O1 2.619(7) 8_665 ?
Na2 Li1 3.120(18) 2_664 ?
Na2 Li1 3.120(18) 5_666 ?
O5 Li1 2.490(18) 4_566 ?
O5 Li1 2.490(18) 7_575 ?
O3 Li1 1.862(17) 5_666 ?
O2 Li1 1.842(17) . ?
O4 Li1 2.068(18) 4_566 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Na1 Ti1 Na1 168.70(11) 2_564 5_566 ?
Na2 Ti1 Na1 85.72(8) 1_455 2_564 ?
Na2 Ti1 Na1 85.72(8) 1_455 5_566 ?
O5 Ti1 Na1 95.30(4) . 5_566 ?
O5 Ti1 Na1 84.62(4) 3_545 5_566 ?
O5 Ti1 Na1 95.30(4) . 2_564 ?
O5 Ti1 Na1 84.62(4) 3_545 2_564 ?
O5 Ti1 Na2 58.4(2) 3_545 1_455 ?
O5 Ti1 Na2 119.0(3) . 1_455 ?
O5 Ti1 O5 177.4(2) . 3_545 ?
O5 Ti1 O4 93.3(2) . . ?
O5 Ti1 O4 93.3(2) . 6_556 ?
O5 Ti1 O1 96.0(2) . 8_565 ?
O5 Ti1 O1 96.0(2) . 3 ?
O5 Ti1 Li1 128.0(4) 3_545 4_566 ?
O5 Ti1 Li1 53.4(4) . 7_575 ?
O5 Ti1 Li1 53.4(4) . 4_566 ?
O5 Ti1 Li1 128.0(4) 3_545 7_575 ?
O4 Ti1 Na1 46.36(18) 6_556 2_564 ?
O4 Ti1 Na1 136.68(19) 6_556 5_566 ?
O4 Ti1 Na1 46.36(18) . 5_566 ?
O4 Ti1 Na1 136.68(19) . 2_564 ?
O4 Ti1 Na2 125.75(18) . 1_455 ?
O4 Ti1 Na2 125.75(18) 6_556 1_455 ?
O4 Ti1 O5 88.6(2) 6_556 3_545 ?
O4 Ti1 O5 88.6(2) . 3_545 ?
O4 Ti1 O4 90.8(3) 6_556 . ?
O4 Ti1 Li1 41.2(4) . 4_566 ?
O4 Ti1 Li1 101.6(3) . 7_575 ?
O4 Ti1 Li1 101.6(4) 6_556 4_566 ?
O4 Ti1 Li1 41.2(4) 6_556 7_575 ?
O1 Ti1 Na1 132.25(19) 8_565 2_564 ?
O1 Ti1 Na1 42.32(18) 8_565 5_566 ?
O1 Ti1 Na1 42.32(18) 3 2_564 ?
O1 Ti1 Na1 132.25(19) 3 5_566 ?
O1 Ti1 Na2 48.66(17) 8_565 1_455 ?
O1 Ti1 Na2 48.66(17) 3 1_455 ?
O1 Ti1 O5 82.2(2) 3 3_545 ?
O1 Ti1 O5 82.2(2) 8_565 3_545 ?
O1 Ti1 O4 88.7(2) 3 6_556 ?
O1 Ti1 O4 170.7(2) 8_565 6_556 ?
O1 Ti1 O4 170.7(2) 3 . ?
O1 Ti1 O4 88.7(2) 8_565 . ?
O1 Ti1 O1 90.4(3) 3 8_565 ?
O1 Ti1 Li1 147.8(4) 3 4_566 ?
O1 Ti1 Li1 84.1(3) 8_565 4_566 ?
O1 Ti1 Li1 147.8(4) 8_565 7_575 ?
O1 Ti1 Li1 84.1(3) 3 7_575 ?
Li1 Ti1 Na1 53.4(3) 7_575 2_564 ?
Li1 Ti1 Na1 137.4(3) 4_566 2_564 ?
Li1 Ti1 Na1 53.4(3) 4_566 5_566 ?
Li1 Ti1 Na1 137.4(3) 7_575 5_566 ?
Li1 Ti1 Na2 132.6(3) 4_566 1_455 ?
Li1 Ti1 Na2 132.6(3) 7_575 1_455 ?
Li1 Ti1 Li1 84.0(6) 4_566 7_575 ?
Na1 P1 Na1 69.39(4) . 5_566 ?
Na1 P1 Na2 117.90(10) 5_566 . ?
Na1 P1 Na2 171.94(10) . . ?
Na1 P1 Na2 103.43(10) . 3_645 ?
Na2 P1 Na1 164.25(13) 3_645 5_566 ?
Na2 P1 Na2 68.63(5) 3_645 . ?
O3 P1 Na1 133.2(2) . . ?
O3 P1 Na1 143.7(2) . 5_566 ?
O3 P1 Na2 51.3(2) . 3_645 ?
O3 P1 Na2 43.0(2) . . ?
O3 P1 O2 117.8(3) . . ?
O3 P1 O4 108.0(3) . . ?
O3 P1 O1 107.6(3) . . ?
O2 P1 Na1 49.6(2) . . ?
O2 P1 Na1 49.3(2) . 5_566 ?
O2 P1 Na2 137.3(2) . . ?
O2 P1 Na2 136.7(2) . 3_645 ?
O2 P1 O4 107.0(3) . . ?
O2 P1 O1 107.0(3) . . ?
O4 P1 Na1 118.8(2) . . ?
O4 P1 Na1 59.7(2) . 5_566 ?
O4 P1 Na2 65.5(2) . . ?
O4 P1 Na2 116.2(2) . 3_645 ?
O1 P1 Na1 57.5(2) . . ?
O1 P1 Na1 108.8(2) . 5_566 ?
O1 P1 Na2 115.2(2) . . ?
O1 P1 Na2 56.8(2) . 3_645 ?
O1 P1 O4 109.3(3) . . ?
P1 Na1 P1 106.68(16) . 4_556 ?
P1 Na1 Li1 82.8(4) . 5_566 ?
P1 Na1 Li1 169.7(4) 4_556 5_566 ?
P1 Na1 Li1 82.8(4) 4_556 8 ?
P1 Na1 Li1 169.7(4) . 8 ?
O2 Na1 P1 28.92(14) . . ?
O2 Na1 P1 92.96(13) 5_566 . ?
O2 Na1 P1 143.79(14) 8 . ?
O2 Na1 P1 92.96(13) 8 4_556 ?
O2 Na1 P1 143.79(14) 5_566 4_556 ?
O2 Na1 P1 28.92(14) 4_556 4_556 ?
O2 Na1 P1 96.82(19) . 4_556 ?
O2 Na1 P1 96.82(19) 4_556 . ?
O2 Na1 O2 85.79(19) . 5_566 ?
O2 Na1 O2 169.8(2) 4_556 5_566 ?
O2 Na1 O2 85.79(19) 4_556 8 ?
O2 Na1 O2 169.8(2) . 8 ?
O2 Na1 O2 88.1(3) 8 5_566 ?
O2 Na1 O2 101.4(3) 4_556 . ?
O2 Na1 O4 76.0(2) 8 5_566 ?
O2 Na1 O4 107.23(18) 4_556 8 ?
O2 Na1 O4 57.12(18) 5_566 5_566 ?
O2 Na1 O4 57.12(18) 8 8 ?
O2 Na1 O4 76.0(2) 5_566 8 ?
O2 Na1 O4 113.29(18) 4_556 5_566 ?
O2 Na1 O4 107.23(18) . 5_566 ?
O2 Na1 O4 113.29(18) . 8 ?
O2 Na1 O1 101.65(18) 8 4_556 ?
O2 Na1 O1 88.3(2) . 4_556 ?
O2 Na1 O1 59.47(19) 4_556 4_556 ?
O2 Na1 O1 101.65(18) 5_566 . ?
O2 Na1 O1 88.3(2) 4_556 . ?
O2 Na1 O1 59.47(19) . . ?
O2 Na1 O1 114.05(18) 5_566 4_556 ?
O2 Na1 O1 114.05(18) 8 . ?
O2 Na1 Li1 93.5(4) . 5_566 ?
O2 Na1 Li1 93.5(4) 4_556 8 ?
O2 Na1 Li1 76.8(4) 5_566 8 ?
O2 Na1 Li1 148.1(3) 4_556 5_566 ?
O2 Na1 Li1 148.1(3) . 8 ?
O2 Na1 Li1 36.5(3) 5_566 5_566 ?
O2 Na1 Li1 36.5(3) 8 8 ?
O2 Na1 Li1 76.8(4) 8 5_566 ?
O4 Na1 P1 88.03(12) 8 . ?
O4 Na1 P1 133.33(12) 8 4_556 ?
O4 Na1 P1 133.33(12) 5_566 . ?
O4 Na1 P1 88.03(12) 5_566 4_556 ?
O4 Na1 O4 113.8(3) 8 5_566 ?
O4 Na1 Li1 88.3(4) 5_566 5_566 ?
O4 Na1 Li1 41.0(3) 8 5_566 ?
O4 Na1 Li1 41.0(3) 5_566 8 ?
O4 Na1 Li1 88.3(4) 8 8 ?
O1 Na1 P1 30.58(12) 4_556 4_556 ?
O1 Na1 P1 110.77(19) . 4_556 ?
O1 Na1 P1 110.77(19) 4_556 . ?
O1 Na1 P1 30.58(12) . . ?
O1 Na1 O4 157.32(18) . 5_566 ?
O1 Na1 O4 62.62(17) . 8 ?
O1 Na1 O4 157.32(18) 4_556 8 ?
O1 Na1 O4 62.62(17) 4_556 5_566 ?
O1 Na1 O1 129.8(3) . 4_556 ?
O1 Na1 Li1 75.2(4) 4_556 8 ?
O1 Na1 Li1 149.9(3) 4_556 5_566 ?
O1 Na1 Li1 75.2(4) . 5_566 ?
O1 Na1 Li1 149.9(3) . 8 ?
Li1 Na1 Li1 88.1(7) 5_566 8 ?
O5 Na2 P1 87.69(16) 3_645 8_665 ?
O5 Na2 O4 134.32(19) 3_645 . ?
O5 Na2 O4 134.32(19) 3_645 6_556 ?
O5 Na2 Li1 48.2(3) 3_645 2_664 ?
O5 Na2 Li1 48.2(3) 3_645 5_666 ?
O3 Na2 P1 28.30(13) 8_665 8_665 ?
O3 Na2 P1 167.7(2) 6_556 8_665 ?
O3 Na2 P1 95.74(14) . 8_665 ?
O3 Na2 P1 88.15(18) 3_655 8_665 ?
O3 Na2 O5 80.4(2) 6_556 3_645 ?
O3 Na2 O5 115.4(2) 8_665 3_645 ?
O3 Na2 O5 115.4(2) 3_655 3_645 ?
O3 Na2 O5 80.4(2) . 3_645 ?
O3 Na2 O3 85.2(3) 6_556 . ?
O3 Na2 O3 81.7(3) 8_665 3_655 ?
O3 Na2 O3 94.35(19) 6_556 3_655 ?
O3 Na2 O3 94.35(19) . 8_665 ?
O3 Na2 O3 164.0(2) 6_556 8_665 ?
O3 Na2 O3 164.0(2) . 3_655 ?
O3 Na2 O4 73.85(19) 3_655 6_556 ?
O3 Na2 O4 53.98(18) . . ?
O3 Na2 O4 110.2(2) 3_655 . ?
O3 Na2 O4 53.98(18) 6_556 6_556 ?
O3 Na2 O4 93.2(2) 6_556 . ?
O3 Na2 O4 93.2(2) . 6_556 ?
O3 Na2 O4 110.2(2) 8_665 6_556 ?
O3 Na2 O4 73.85(19) 8_665 . ?
O3 Na2 O1 137.8(3) . 3_655 ?
O3 Na2 O1 91.00(19) . 8_665 ?
O3 Na2 O1 137.8(3) 6_556 8_665 ?
O3 Na2 O1 91.00(19) 6_556 3_655 ?
O3 Na2 O1 99.9(2) 8_665 3_655 ?
O3 Na2 O1 58.16(18) 8_665 8_665 ?
O3 Na2 O1 99.9(2) 3_655 8_665 ?
O3 Na2 O1 58.17(18) 3_655 3_655 ?
O3 Na2 Li1 36.6(4) 6_556 2_664 ?
O3 Na2 Li1 93.5(3) 3_655 2_664 ?
O3 Na2 Li1 158.6(4) 8_665 2_664 ?
O3 Na2 Li1 95.5(3) . 2_664 ?
O3 Na2 Li1 93.5(3) 8_665 5_666 ?
O3 Na2 Li1 158.6(4) 3_655 5_666 ?
O3 Na2 Li1 95.5(3) 6_556 5_666 ?
O3 Na2 Li1 36.6(4) . 5_666 ?
O4 Na2 P1 137.97(19) 6_556 8_665 ?
O4 Na2 P1 97.23(13) . 8_665 ?
O4 Na2 O4 56.8(2) . 6_556 ?
O4 Na2 Li1 88.2(3) 6_556 2_664 ?
O4 Na2 Li1 127.0(4) . 2_664 ?
O4 Na2 Li1 88.2(3) . 5_666 ?
O4 Na2 Li1 127.0(4) 6_556 5_666 ?
O1 Na2 P1 80.09(17) 3_655 8_665 ?
O1 Na2 P1 30.08(13) 8_665 8_665 ?
O1 Na2 O5 57.63(18) 8_665 3_645 ?
O1 Na2 O5 57.63(18) 3_655 3_645 ?
O1 Na2 O4 117.96(16) 3_655 6_556 ?
O1 Na2 O4 167.9(2) 3_655 . ?
O1 Na2 O4 167.9(2) 8_665 6_556 ?
O1 Na2 O4 117.96(16) 8_665 . ?
O1 Na2 O1 64.6(3) 8_665 3_655 ?
O1 Na2 Li1 102.6(4) 8_665 2_664 ?
O1 Na2 Li1 60.5(4) 3_655 2_664 ?
O1 Na2 Li1 102.6(4) 3_655 5_666 ?
O1 Na2 Li1 60.5(4) 8_665 5_666 ?
Li1 Na2 P1 131.3(4) 2_664 8_665 ?
Li1 Na2 P1 78.4(3) 5_666 8_665 ?
Li1 Na2 Li1 83.3(6) 2_664 5_666 ?
Ti1 O5 Ti1 132.0(4) . 3 ?
Ti1 O5 Na2 144.4(4) . 3_655 ?
Ti1 O5 Na2 83.6(2) 3 3_655 ?
Ti1 O5 Li1 92.5(5) . 4_566 ?
Ti1 O5 Li1 112.3(5) 3 7_575 ?
Ti1 O5 Li1 92.5(5) . 7_575 ?
Ti1 O5 Li1 112.3(5) 3 4_566 ?
Li1 O5 Na2 69.1(4) 4_566 3_655 ?
Li1 O5 Na2 69.1(4) 7_575 3_655 ?
Li1 O5 Li1 112.9(8) 4_566 7_575 ?
P1 O3 Na2 111.6(3) . . ?
P1 O3 Na2 100.4(3) . 3_645 ?
P1 O3 Li1 149.6(6) . 5_666 ?
Na2 O3 Na2 95.37(19) . 3_645 ?
Li1 O3 Na2 93.4(6) 5_666 . ?
Li1 O3 Na2 93.9(6) 5_666 3_645 ?
P1 O2 Na1 102.7(3) . 5_566 ?
P1 O2 Na1 101.5(3) . . ?
P1 O2 Li1 152.1(7) . . ?
Na1 O2 Na1 94.20(19) . 5_566 ?
Li1 O2 Na1 91.1(6) . 5_566 ?
Li1 O2 Na1 101.6(7) . . ?
Ti1 O4 Na1 101.8(2) . 5_566 ?
Ti1 O4 Na2 100.3(2) . . ?
Ti1 O4 Li1 99.5(6) . 4_566 ?
P1 O4 Ti1 141.4(3) . . ?
P1 O4 Na1 90.3(3) . 5_566 ?
P1 O4 Na2 85.7(3) . . ?
P1 O4 Li1 118.9(6) . 4_566 ?
Na1 O4 Na2 149.2(2) 5_566 . ?
Li1 O4 Na1 79.1(5) 4_566 5_566 ?
Li1 O4 Na2 76.2(5) 4_566 . ?
Ti1 O1 Na1 106.9(2) 3_545 . ?
Ti1 O1 Na2 96.9(2) 3_545 3_645 ?
P1 O1 Ti1 137.7(3) . 3_545 ?
P1 O1 Na1 92.0(3) . . ?
P1 O1 Na2 93.1(3) . 3_645 ?
Na1 O1 Na2 138.0(2) . 3_645 ?
Ti1 Li1 Na1 100.6(5) 7_576 . ?
Ti1 Li1 Na2 92.6(5) 7_576 5_666 ?
Ti1 Li1 Na2 75.8(4) 7_576 7_576 ?
Na1 Li1 Ti1 73.2(4) 5_566 7_576 ?
Na1 Li1 Na1 67.4(3) 5_566 . ?
Na1 Li1 Na2 157.0(7) 5_566 5_666 ?
Na1 Li1 Na2 121.9(6) 5_566 7_576 ?
Na2 Li1 Na1 98.6(5) 5_666 . ?
Na2 Li1 Na1 167.2(7) 7_576 . ?
Na2 Li1 Na2 69.6(3) 5_666 7_576 ?
O5 Li1 Ti1 34.1(3) 7_576 7_576 ?
O5 Li1 Na1 88.8(6) 7_576 . ?
O5 Li1 Na1 97.6(5) 7_576 5_566 ?
O5 Li1 Na2 81.4(5) 7_576 7_576 ?
O5 Li1 Na2 62.7(4) 7_576 5_666 ?
O3 Li1 Ti1 120.7(7) 5_666 7_576 ?
O3 Li1 Na1 153.0(10) 5_666 5_566 ?
O3 Li1 Na1 125.6(8) 5_666 . ?
O3 Li1 Na2 50.6(4) 5_666 7_576 ?
O3 Li1 Na2 50.1(5) 5_666 5_666 ?
O3 Li1 O5 105.7(8) 5_666 7_576 ?
O3 Li1 O4 114.3(9) 5_666 4_566 ?
O2 Li1 Ti1 122.3(7) . 7_576 ?
O2 Li1 Na1 52.4(4) . 5_566 ?
O2 Li1 Na1 45.3(4) . . ?
O2 Li1 Na2 130.2(8) . 5_666 ?
O2 Li1 Na2 146.7(9) . 7_576 ?
O2 Li1 O5 130.0(9) . 7_576 ?
O2 Li1 O3 116.6(9) . 5_666 ?
O2 Li1 O4 109.7(9) . 4_566 ?
O4 Li1 Ti1 39.3(3) 4_566 7_576 ?
O4 Li1 Na1 59.9(4) 4_566 5_566 ?
O4 Li1 Na1 120.0(7) 4_566 . ?
O4 Li1 Na2 64.8(5) 4_566 7_576 ?
O4 Li1 Na2 119.2(7) 4_566 5_666 ?
O4 Li1 O5 72.5(5) 4_566 7_576 ?

_olex2_submission_special_instructions 'No special instructions were received'
