# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ns6002a
_database_code_depnum_ccdc_archive 'CCDC 1892887'
loop_
_audit_author_name
_audit_author_address
'Tadeusz Lis'
;Department of Chemistry University of Wroclaw Poland
Poland
;
_audit_update_record             
;
2019-02-13 deposited with the CCDC.	2019-02-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C79 H96 Dy6 N4 O36 Zn4, 4(C H4 O)'
_chemical_formula_sum            'C83 H112 Dy6 N4 O40 Zn4'
_chemical_formula_weight         3042.24

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.591(3)
_cell_length_b                   13.807(3)
_cell_length_c                   14.560(3)
_cell_angle_alpha                80.22(2)
_cell_angle_beta                 69.83(2)
_cell_angle_gamma                77.36(2)
_cell_volume                     2489.2(10)
_cell_formula_units_Z            1
_cell_measurement_temperature    80(2)
_cell_measurement_reflns_used    11517
_cell_measurement_theta_min      2.8
_cell_measurement_theta_max      31

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.030
_exptl_crystal_F_000             1474
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    5.473
_shelx_estimated_absorpt_T_min   0.393
_shelx_estimated_absorpt_T_max   0.771
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.483
_exptl_absorpt_correction_T_max  0.775
_exptl_absorpt_process_details   
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.33.66 (release 28-04-2010 CrysAlis171 .NET)
(compiled Apr 28 2010,14:27:37)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      80(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Xcalibur R with Ruby CCD detector'
_diffrn_measurement_method       /w
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            37200
_diffrn_reflns_av_unetI/netI     0.0586
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.890
_diffrn_reflns_theta_max         30.709
_diffrn_reflns_theta_full        25.500
_diffrn_measured_fraction_theta_max 0.907
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.907
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.907
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             14033
_reflns_number_gt                10607
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisCCD (Agilent)'
_computing_cell_refinement       'CrysAlisRED (Agilent)'
_computing_data_reduction        'CrysAlisRED (Agilent)'
_computing_structure_solution    'SHELXS (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0284P)²+1.0013P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         14033
_refine_ls_number_parameters     634
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0620
_refine_ls_R_factor_gt           0.0368
_refine_ls_wR_factor_ref         0.0735
_refine_ls_wR_factor_gt          0.0662
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.41550(2) 0.59793(2) 0.45996(2) 0.02249(5) Uani 1 1 d . . . . .
Dy2 Dy 0.69414(2) 0.62833(2) 0.37581(2) 0.01721(5) Uani 1 1 d . . . . .
Dy3 Dy 0.36769(2) 0.55021(2) 0.72983(2) 0.01845(5) Uani 1 1 d . . . . .
Zn1 Zn 0.52232(4) 0.69048(4) 0.22861(3) 0.01934(11) Uani 1 1 d . . . . .
Zn2 Zn 0.83625(4) 0.34378(4) 0.34838(4) 0.02132(11) Uani 1 1 d . . . . .
O1 O 0.5838(2) 0.5163(2) 0.41011(19) 0.0179(6) Uani 1 1 d . . . . .
O1W O 0.3878(2) 0.5150(2) 0.8916(2) 0.0267(7) Uani 1 1 d . . . . .
H1W H 0.409483 0.453646 0.902193 0.040 Uiso 1 1 d R U . . .
H2W H 0.328703 0.531637 0.934072 0.040 Uiso 1 1 d R U . . .
O2A O 0.5302(2) 0.6825(2) 0.0901(2) 0.0283(7) Uani 1 1 d . . . . .
C1A C 0.4363(3) 0.8458(3) 0.0577(3) 0.0212(9) Uani 1 1 d . . . . .
C2A C 0.4844(3) 0.7484(4) 0.0342(3) 0.0237(10) Uani 1 1 d . . . . .
C3A C 0.4817(4) 0.7177(4) -0.0537(3) 0.0343(12) Uani 1 1 d . . . . .
H3A H 0.513079 0.651486 -0.069412 0.041 Uiso 1 1 calc R U . . .
C4A C 0.4356(4) 0.7802(5) -0.1147(3) 0.0386(14) Uani 1 1 d . . . . .
H4A H 0.431921 0.756010 -0.170561 0.046 Uiso 1 1 calc R U . . .
C5A C 0.3459(4) 0.9492(5) -0.1638(4) 0.0440(15) Uani 1 1 d . . . . .
H5A H 0.341753 0.925366 -0.219595 0.053 Uiso 1 1 calc R U . . .
C6A C 0.3085(5) 1.0451(5) -0.1488(4) 0.0518(17) Uani 1 1 d . . . . .
H6A H 0.276025 1.088346 -0.192342 0.062 Uiso 1 1 calc R U . . .
C7A C 0.3175(5) 1.0810(5) -0.0689(4) 0.0472(15) Uani 1 1 d . . . . .
H7A H 0.293397 1.149695 -0.059537 0.057 Uiso 1 1 calc R U . . .
C8A C 0.3610(4) 1.0181(4) -0.0030(3) 0.0332(12) Uani 1 1 d . . . . .
H8A H 0.367270 1.044855 0.050274 0.040 Uiso 1 1 calc R U . . .
C9A C 0.3960(3) 0.9161(4) -0.0124(3) 0.0244(10) Uani 1 1 d . . . . .
C10A C 0.3921(4) 0.8818(4) -0.0977(3) 0.0316(12) Uani 1 1 d . . . . .
C11A C 0.4148(3) 0.8785(3) 0.1525(3) 0.0221(9) Uani 1 1 d . . . . .
H11A H 0.375278 0.943879 0.162334 0.026 Uiso 1 1 calc R U . . .
N1A N 0.4432(3) 0.8289(3) 0.2261(2) 0.0177(7) Uani 1 1 d . . . . .
C12A C 0.4033(3) 0.8713(4) 0.3216(3) 0.0241(10) Uani 1 1 d . . . . .
C13A C 0.3918(4) 0.9855(4) 0.3127(4) 0.0334(11) Uani 1 1 d . . . . .
H13A H 0.453299 1.006751 0.260110 0.050 Uiso 1 1 calc R U . . .
H13B H 0.388375 1.006056 0.375095 0.050 Uiso 1 1 calc R U . . .
H13C H 0.326501 1.016462 0.297261 0.050 Uiso 1 1 calc R U . . .
C14A C 0.4857(4) 0.8250(3) 0.3745(3) 0.0260(10) Uani 1 1 d . . . . .
H14A H 0.549782 0.856498 0.343104 0.031 Uiso 1 1 calc R U . . .
H14B H 0.455629 0.840315 0.443766 0.031 Uiso 1 1 calc R U . . .
O14A O 0.5163(2) 0.7206(2) 0.37277(19) 0.0190(6) Uani 1 1 d . . . . .
C15A C 0.2930(4) 0.8453(4) 0.3784(3) 0.0306(11) Uani 1 1 d . . . . .
H15B H 0.264192 0.876445 0.440944 0.037 Uiso 1 1 calc R U . . .
H15C H 0.244525 0.873038 0.339341 0.037 Uiso 1 1 calc R U . . .
O15A O 0.2965(2) 0.7403(3) 0.3993(2) 0.0322(8) Uani 1 1 d . . . . .
H15A H 0.234923 0.729440 0.431872 0.048 Uiso 1 1 d R U . . .
O2B O 0.7113(2) 0.7834(2) 0.3844(2) 0.0226(7) Uani 1 1 d . . . . .
C1B C 0.8810(3) 0.8205(3) 0.2796(3) 0.0187(8) Uani 1 1 d . . . . .
C2B C 0.7845(3) 0.8380(3) 0.3583(3) 0.0204(9) Uani 1 1 d . . . . .
C3B C 0.7652(4) 0.9244(4) 0.4083(3) 0.0314(11) Uani 1 1 d . . . . .
H3B H 0.698880 0.940298 0.458040 0.038 Uiso 1 1 calc R U . . .
C4B C 0.8386(4) 0.9843(4) 0.3867(4) 0.0344(12) Uani 1 1 d . . . . .
H4B H 0.823468 1.039400 0.423542 0.041 Uiso 1 1 calc R U . . .
C5B C 1.0130(4) 1.0307(4) 0.2877(4) 0.0320(11) Uani 1 1 d . . . . .
H5B H 0.997403 1.086187 0.324140 0.038 Uiso 1 1 calc R U . . .
C6B C 1.1072(4) 1.0143(4) 0.2150(4) 0.0408(13) Uani 1 1 d . . . . .
H6B H 1.157961 1.056785 0.201463 0.049 Uiso 1 1 calc R U . . .
C7B C 1.1287(4) 0.9345(4) 0.1605(5) 0.0538(17) Uani 1 1 d . . . . .
H7B H 1.193931 0.923671 0.108194 0.065 Uiso 1 1 calc R U . . .
C8B C 1.0571(4) 0.8710(4) 0.1809(4) 0.0418(14) Uani 1 1 d . . . . .
H8B H 1.074687 0.816126 0.143296 0.050 Uiso 1 1 calc R U . . .
C9B C 0.9584(3) 0.8852(3) 0.2562(3) 0.0236(9) Uani 1 1 d . . . . .
C10B C 0.9374(4) 0.9672(4) 0.3106(3) 0.0255(10) Uani 1 1 d . . . . .
C11B C 0.8977(3) 0.7451(3) 0.2160(3) 0.0233(9) Uani 1 1 d . . . . .
H11B H 0.955726 0.746131 0.156418 0.028 Uiso 1 1 calc R U . . .
N1B N 0.8413(3) 0.6763(3) 0.2322(2) 0.0198(7) Uani 1 1 d . . . . .
C12B C 0.8611(3) 0.6098(3) 0.1549(3) 0.0198(9) Uani 1 1 d . . . . .
C13B C 0.9481(3) 0.6284(4) 0.0575(3) 0.0268(10) Uani 1 1 d . . . . .
H13D H 0.934262 0.698285 0.030889 0.040 Uiso 1 1 calc R U . . .
H13E H 0.948514 0.584867 0.010664 0.040 Uiso 1 1 calc R U . . .
H13F H 1.017377 0.613956 0.068271 0.040 Uiso 1 1 calc R U . . .
C14B C 0.8862(3) 0.5028(3) 0.2006(3) 0.0225(9) Uani 1 1 d . . . . .
H14C H 0.898299 0.455713 0.152031 0.027 Uiso 1 1 calc R U . . .
H14D H 0.952219 0.494463 0.217702 0.027 Uiso 1 1 calc R U . . .
O14B O 0.7998(2) 0.4796(2) 0.28837(19) 0.0200(6) Uani 1 1 d . . . . .
C15B C 0.7565(3) 0.6261(4) 0.1322(3) 0.0233(10) Uani 1 1 d . . . . .
H15D H 0.745611 0.692948 0.096118 0.028 Uiso 1 1 calc R U . . .
H15E H 0.760885 0.575781 0.089267 0.028 Uiso 1 1 calc R U . . .
O15B O 0.6679(2) 0.6184(2) 0.21956(19) 0.0188(6) Uani 1 1 d . . . . .
O1C O 0.8945(2) 0.2473(3) 0.4517(2) 0.0309(8) Uani 1 1 d . . . . .
O2C O 0.9985(2) 0.3483(3) 0.3536(2) 0.0304(7) Uani 1 1 d . . . . .
C1C C 0.9826(3) 0.2787(4) 0.4219(3) 0.0266(10) Uani 1 1 d . . . . .
C2C C 1.0665(4) 0.2304(4) 0.4684(4) 0.0401(13) Uani 1 1 d . . . . .
H2C1 H 1.119540 0.182767 0.425746 0.060 Uiso 1 1 calc R U . . .
H2C2 H 1.033523 0.195163 0.532483 0.060 Uiso 1 1 calc R U . . .
H2C3 H 1.101172 0.281642 0.477372 0.060 Uiso 1 1 calc R U . . .
O1D O 0.8923(2) 0.2611(3) 0.2344(2) 0.0297(8) Uani 1 1 d . . . . .
O2D O 0.7604(2) 0.3322(2) 0.1737(2) 0.0267(7) Uani 1 1 d . . . . .
C1D C 0.8406(3) 0.2666(3) 0.1761(3) 0.0251(10) Uani 1 1 d . . . . .
C2D C 0.8779(4) 0.1867(4) 0.1066(3) 0.0305(11) Uani 1 1 d . . . . .
H2D1 H 0.953691 0.184518 0.069982 0.046 Uiso 1 1 calc R U . . .
H2D2 H 0.837158 0.201744 0.060380 0.046 Uiso 1 1 calc R U . . .
H2D3 H 0.866874 0.121805 0.144292 0.046 Uiso 1 1 calc R U . . .
O1E O 0.5779(2) 0.6321(2) 0.5461(2) 0.0277(7) Uani 1 1 d . . . . .
O2E O 0.4853(2) 0.6586(2) 0.6998(2) 0.0266(7) Uani 1 1 d . . . . .
C1E C 0.5626(3) 0.6711(3) 0.6227(3) 0.0218(9) Uani 1 1 d . . . . .
C2E C 0.6392(4) 0.7329(4) 0.6270(3) 0.0291(11) Uani 1 1 d . . . . .
H2E1 H 0.684413 0.751221 0.560187 0.044 Uiso 1 1 calc R U . . .
H2E2 H 0.683767 0.694192 0.665653 0.044 Uiso 1 1 calc R U . . .
H2E3 H 0.599253 0.793581 0.658036 0.044 Uiso 1 1 calc R U . . .
O1F O 0.8240(2) 0.5823(3) 0.4615(2) 0.0290(7) Uani 1 1 d . . . . .
O2F O 0.7506(2) 0.4454(3) 0.5055(2) 0.0317(8) Uani 1 1 d . . . . .
C1F C 0.8138(3) 0.5002(4) 0.5107(3) 0.0267(10) Uani 1 1 d . . . . .
C2F C 0.8789(4) 0.4596(4) 0.5796(4) 0.0349(12) Uani 1 1 d . . . . .
H2F1 H 0.953138 0.437226 0.541006 0.052 Uiso 1 1 calc R U . . .
H2F2 H 0.850154 0.403208 0.623610 0.052 Uiso 1 1 calc R U . . .
H2F3 H 0.875508 0.512179 0.618717 0.052 Uiso 1 1 calc R U . . .
O1M O 0.4597(2) 0.5657(2) 0.2934(2) 0.0216(6) Uani 1 1 d . . . . .
C1M C 0.3786(4) 0.5515(4) 0.2558(4) 0.0327(11) Uani 1 1 d . . . . .
H1M1 H 0.327367 0.613691 0.255928 0.049 Uiso 1 1 calc R U . . .
H1M2 H 0.341704 0.498327 0.297638 0.049 Uiso 1 1 calc R U . . .
H1M3 H 0.411978 0.532956 0.188498 0.049 Uiso 1 1 calc R U . . .
O2 O 0.6819(2) 0.3236(2) 0.3944(2) 0.0229(7) Uani 0.5 1 d . . P A 1
H2 H 0.672225 0.265587 0.394326 0.034 Uiso 0.5 1 calc R U P A 1
O2M O 0.6819(2) 0.3236(2) 0.3944(2) 0.0229(7) Uani 0.5 1 d . . P A 2
C2M C 0.6769(7) 0.2214(7) 0.3797(7) 0.030(2) Uani 0.5 1 d . . P A 2
H2M1 H 0.680349 0.219778 0.311607 0.045 Uiso 0.5 1 calc R U P A 2
H2M2 H 0.610044 0.202210 0.424622 0.045 Uiso 0.5 1 calc R U P A 2
H2M3 H 0.737055 0.174517 0.393119 0.045 Uiso 0.5 1 calc R U P A 2
O3M O 1.1849(3) 0.3757(3) 0.2043(3) 0.0504(10) Uani 1 1 d . . . . .
H3M H 1.128486 0.374232 0.251992 0.076 Uiso 1 1 calc R U . . .
C3M C 1.2131(5) 0.2864(5) 0.1597(4) 0.0543(16) Uani 1 1 d . . . . .
H3M1 H 1.239422 0.231706 0.202418 0.081 Uiso 1 1 calc R U . . .
H3M2 H 1.268901 0.293787 0.096162 0.081 Uiso 1 1 calc R U . . .
H3M3 H 1.150493 0.271547 0.149600 0.081 Uiso 1 1 calc R U . . .
O4M O 0.7759(5) 0.4652(4) -0.0641(3) 0.0781(16) Uani 1 1 d . . . . .
H4M H 0.774260 0.514350 -0.106689 0.117 Uiso 1 1 calc R U . . .
C4M C 0.7904(5) 0.3755(5) -0.1073(5) 0.0640(19) Uani 1 1 d . . . . .
H4M1 H 0.799053 0.317797 -0.059504 0.096 Uiso 1 1 calc R U . . .
H4M2 H 0.853994 0.372003 -0.165622 0.096 Uiso 1 1 calc R U . . .
H4M3 H 0.728006 0.375217 -0.126407 0.096 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.243(3) . ?
Dy1 O1 2.249(3) 2_666 ?
Dy1 O2F 2.326(3) 2_666 ?
Dy1 O14A 2.333(3) . ?
Dy1 O2 2.375(3) 2_666 ?
Dy1 O1M 2.384(3) . ?
Dy1 O15A 2.502(3) . ?
Dy2 O2B 2.232(3) . ?
Dy2 O1 2.265(3) . ?
Dy2 O1F 2.416(3) . ?
Dy2 O1E 2.439(3) . ?
Dy2 O15B 2.451(3) . ?
Dy2 N1B 2.456(3) . ?
Dy2 O14A 2.484(3) . ?
Dy2 O14B 2.497(3) . ?
Dy3 O1 2.208(3) 2_666 ?
Dy3 O2E 2.309(3) . ?
Dy3 O2D 2.344(3) 2_666 ?
Dy3 O1W 2.420(3) . ?
Dy3 O15B 2.421(3) 2_666 ?
Dy3 O2 2.453(3) 2_666 ?
Dy3 O1M 2.484(3) 2_666 ?
Dy3 O14B 2.506(3) 2_666 ?
Zn1 N1A 1.979(4) . ?
Zn1 O15B 1.981(3) . ?
Zn1 O2A 2.003(3) . ?
Zn1 O1M 2.030(3) . ?
Zn1 O14A 2.179(3) . ?
Zn2 O14B 1.965(3) . ?
Zn2 O1D 2.008(3) . ?
Zn2 O2M 2.037(3) . ?
Zn2 O2 2.037(3) . ?
Zn2 O1C 2.084(3) . ?
Zn2 O2C 2.248(3) . ?
O2A C2A 1.315(5) . ?
C1A C2A 1.403(6) . ?
C1A C11A 1.439(6) . ?
C1A C9A 1.449(6) . ?
C2A C3A 1.430(6) . ?
C3A C4A 1.347(7) . ?
C4A C10A 1.426(8) . ?
C5A C6A 1.336(9) . ?
C5A C10A 1.430(7) . ?
C6A C7A 1.391(8) . ?
C7A C8A 1.382(7) . ?
C8A C9A 1.398(7) . ?
C9A C10A 1.423(6) . ?
C11A N1A 1.298(5) . ?
N1A C12A 1.479(5) . ?
C12A C15A 1.529(6) . ?
C12A C13A 1.538(6) . ?
C12A C14A 1.540(6) . ?
C14A O14A 1.412(5) . ?
C15A O15A 1.424(6) . ?
O2B C2B 1.293(5) . ?
C1B C2B 1.418(5) . ?
C1B C11B 1.440(6) . ?
C1B C9B 1.443(6) . ?
C2B C3B 1.432(6) . ?
C3B C4B 1.355(7) . ?
C4B C10B 1.418(6) . ?
C5B C6B 1.353(7) . ?
C5B C10B 1.413(6) . ?
C6B C7B 1.387(7) . ?
C7B C8B 1.375(7) . ?
C8B C9B 1.408(6) . ?
C9B C10B 1.413(6) . ?
C11B N1B 1.290(5) . ?
N1B C12B 1.489(5) . ?
C12B C13B 1.526(5) . ?
C12B C15B 1.530(6) . ?
C12B C14B 1.530(6) . ?
C14B O14B 1.451(4) . ?
C15B O15B 1.426(4) . ?
O1C C1C 1.270(5) . ?
O2C C1C 1.256(6) . ?
C1C C2C 1.500(6) . ?
O1D C1D 1.259(5) . ?
O2D C1D 1.261(5) . ?
C1D C2D 1.511(6) . ?
O1E C1E 1.254(5) . ?
O2E C1E 1.263(5) . ?
C1E C2E 1.506(6) . ?
O1F C1F 1.242(6) . ?
O2F C1F 1.291(5) . ?
C1F C2F 1.519(6) . ?
O1M C1M 1.448(5) . ?
O2M C2M 1.483(9) . ?
O3M C3M 1.408(7) . ?
O4M C4M 1.428(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O1 79.06(10) . 2_666 ?
O1 Dy1 O2F 134.49(11) . 2_666 ?
O1 Dy1 O2F 80.62(11) 2_666 2_666 ?
O1 Dy1 O14A 75.10(10) . . ?
O1 Dy1 O14A 135.67(10) 2_666 . ?
O2F Dy1 O14A 141.74(11) 2_666 . ?
O1 Dy1 O2 130.45(10) . 2_666 ?
O1 Dy1 O2 71.75(10) 2_666 2_666 ?
O2F Dy1 O2 79.10(10) 2_666 2_666 ?
O14A Dy1 O2 99.14(10) . 2_666 ?
O1 Dy1 O1M 71.22(10) . . ?
O1 Dy1 O1M 126.59(10) 2_666 . ?
O2F Dy1 O1M 89.68(10) 2_666 . ?
O14A Dy1 O1M 77.27(10) . . ?
O2 Dy1 O1M 156.92(10) 2_666 . ?
O1 Dy1 O15A 139.29(10) . . ?
O1 Dy1 O15A 141.65(9) 2_666 . ?
O2F Dy1 O15A 70.58(12) 2_666 . ?
O14A Dy1 O15A 71.67(10) . . ?
O2 Dy1 O15A 78.24(10) 2_666 . ?
O1M Dy1 O15A 79.02(10) . . ?
O2B Dy2 O1 147.35(10) . . ?
O2B Dy2 O1F 83.39(11) . . ?
O1 Dy2 O1F 113.20(11) . . ?
O2B Dy2 O1E 86.30(10) . . ?
O1 Dy2 O1E 70.52(10) . . ?
O1F Dy2 O1E 79.39(10) . . ?
O2B Dy2 O15B 109.93(10) . . ?
O1 Dy2 O15B 74.55(9) . . ?
O1F Dy2 O15B 142.65(10) . . ?
O1E Dy2 O15B 134.40(9) . . ?
O2B Dy2 N1B 71.23(11) . . ?
O1 Dy2 N1B 134.96(10) . . ?
O1F Dy2 N1B 85.82(11) . . ?
O1E Dy2 N1B 154.40(10) . . ?
O15B Dy2 N1B 67.33(10) . . ?
O2B Dy2 O14A 79.69(10) . . ?
O1 Dy2 O14A 71.78(10) . . ?
O1F Dy2 O14A 148.09(9) . . ?
O1E Dy2 O14A 72.72(10) . . ?
O15B Dy2 O14A 69.10(9) . . ?
N1B Dy2 O14A 113.53(11) . . ?
O2B Dy2 O14B 138.89(9) . . ?
O1 Dy2 O14B 73.12(9) . . ?
O1F Dy2 O14B 82.36(10) . . ?
O1E Dy2 O14B 128.12(10) . . ?
O15B Dy2 O14B 64.49(10) . . ?
N1B Dy2 O14B 69.43(10) . . ?
O14A Dy2 O14B 127.34(9) . . ?
O2B Dy2 Dy1 141.02(7) . 2_666 ?
O1 Dy2 Dy1 31.61(7) . 2_666 ?
O1F Dy2 Dy1 82.37(8) . 2_666 ?
O1E Dy2 Dy1 55.46(8) . 2_666 ?
O15B Dy2 Dy1 103.30(7) . 2_666 ?
N1B Dy2 Dy1 142.97(8) . 2_666 ?
O14A Dy2 Dy1 94.06(7) . 2_666 ?
O14B Dy2 Dy1 74.27(7) . 2_666 ?
O1 Dy3 O2E 103.70(10) 2_666 . ?
O1 Dy3 O2D 143.45(10) 2_666 2_666 ?
O2E Dy3 O2D 86.78(11) . 2_666 ?
O1 Dy3 O1W 141.02(11) 2_666 . ?
O2E Dy3 O1W 84.94(11) . . ?
O2D Dy3 O1W 73.86(11) 2_666 . ?
O1 Dy3 O15B 76.18(10) 2_666 2_666 ?
O2E Dy3 O15B 147.47(11) . 2_666 ?
O2D Dy3 O15B 113.01(10) 2_666 2_666 ?
O1W Dy3 O15B 76.85(10) . 2_666 ?
O1 Dy3 O2 70.93(10) 2_666 2_666 ?
O2E Dy3 O2 77.53(11) . 2_666 ?
O2D Dy3 O2 77.59(10) 2_666 2_666 ?
O1W Dy3 O2 147.16(10) . 2_666 ?
O15B Dy3 O2 130.29(9) 2_666 2_666 ?
O1 Dy3 O1M 69.88(10) 2_666 2_666 ?
O2E Dy3 O1M 77.87(11) . 2_666 ?
O2D Dy3 O1M 146.43(10) 2_666 2_666 ?
O1W Dy3 O1M 75.18(10) . 2_666 ?
O15B Dy3 O1M 71.57(10) 2_666 2_666 ?
O2 Dy3 O1M 126.43(9) 2_666 2_666 ?
O1 Dy3 O14B 73.88(9) 2_666 2_666 ?
O2E Dy3 O14B 147.28(11) . 2_666 ?
O2D Dy3 O14B 78.65(10) 2_666 2_666 ?
O1W Dy3 O14B 117.97(9) . 2_666 ?
O15B Dy3 O14B 64.78(10) 2_666 2_666 ?
O2 Dy3 O14B 70.83(10) 2_666 2_666 ?
O1M Dy3 O14B 128.29(10) 2_666 2_666 ?
O1 Dy3 Dy2 39.14(7) 2_666 2_666 ?
O2E Dy3 Dy2 142.75(7) . 2_666 ?
O2D Dy3 Dy2 123.76(8) 2_666 2_666 ?
O1W Dy3 Dy2 121.31(8) . 2_666 ?
O15B Dy3 Dy2 44.47(6) 2_666 2_666 ?
O2 Dy3 Dy2 88.12(7) 2_666 2_666 ?
O1M Dy3 Dy2 83.82(7) 2_666 2_666 ?
O14B Dy3 Dy2 45.54(7) 2_666 2_666 ?
O1 Dy3 Dy1 32.54(7) 2_666 2_666 ?
O2E Dy3 Dy1 86.12(7) . 2_666 ?
O2D Dy3 Dy1 169.40(8) 2_666 2_666 ?
O1W Dy3 Dy1 113.29(7) . 2_666 ?
O15B Dy3 Dy1 76.91(6) 2_666 2_666 ?
O2 Dy3 Dy1 93.18(7) 2_666 2_666 ?
O1M Dy3 Dy1 38.39(7) 2_666 2_666 ?
O14B Dy3 Dy1 103.45(6) 2_666 2_666 ?
Dy2 Dy3 Dy1 60.256(19) 2_666 2_666 ?
N1A Zn1 O15B 139.40(13) . . ?
N1A Zn1 O2A 91.28(13) . . ?
O15B Zn1 O2A 97.54(12) . . ?
N1A Zn1 O1M 126.44(13) . . ?
O15B Zn1 O1M 91.32(12) . . ?
O2A Zn1 O1M 98.83(12) . . ?
N1A Zn1 O14A 82.36(12) . . ?
O15B Zn1 O14A 84.44(11) . . ?
O2A Zn1 O14A 172.11(12) . . ?
O1M Zn1 O14A 88.74(11) . . ?
N1A Zn1 Dy3 170.95(10) . 2_666 ?
O15B Zn1 Dy3 44.94(9) . 2_666 ?
O2A Zn1 Dy3 95.90(10) . 2_666 ?
O1M Zn1 Dy3 46.96(8) . 2_666 ?
O14A Zn1 Dy3 90.89(8) . 2_666 ?
O14B Zn2 O1D 103.74(13) . . ?
O14B Zn2 O2M 91.81(12) . . ?
O1D Zn2 O2M 98.29(12) . . ?
O14B Zn2 O2 91.81(12) . . ?
O1D Zn2 O2 98.29(12) . . ?
O14B Zn2 O1C 150.22(13) . . ?
O1D Zn2 O1C 100.57(13) . . ?
O2M Zn2 O1C 101.51(12) . . ?
O2 Zn2 O1C 101.51(12) . . ?
O14B Zn2 O2C 100.54(12) . . ?
O1D Zn2 O2C 94.24(12) . . ?
O2M Zn2 O2C 159.82(12) . . ?
O2 Zn2 O2C 159.82(12) . . ?
O1C Zn2 O2C 60.45(12) . . ?
O14B Zn2 Dy3 48.99(8) . 2_666 ?
O1D Zn2 Dy3 88.79(9) . 2_666 ?
O2 Zn2 Dy3 47.63(9) . 2_666 ?
O1C Zn2 Dy3 149.00(9) . 2_666 ?
O2C Zn2 Dy3 148.93(9) . 2_666 ?
Dy3 O1 Dy1 115.50(12) 2_666 . ?
Dy3 O1 Dy1 113.20(12) 2_666 2_666 ?
Dy1 O1 Dy1 100.94(10) . 2_666 ?
Dy3 O1 Dy2 102.90(11) 2_666 . ?
Dy1 O1 Dy2 108.22(12) . . ?
Dy1 O1 Dy2 116.53(12) 2_666 . ?
C2A O2A Zn1 127.9(3) . . ?
C2A C1A C11A 123.5(4) . . ?
C2A C1A C9A 119.6(4) . . ?
C11A C1A C9A 116.6(4) . . ?
O2A C2A C1A 123.5(4) . . ?
O2A C2A C3A 117.7(4) . . ?
C1A C2A C3A 118.8(4) . . ?
C4A C3A C2A 121.6(5) . . ?
C3A C4A C10A 121.7(4) . . ?
C6A C5A C10A 121.4(5) . . ?
C5A C6A C7A 119.5(5) . . ?
C8A C7A C6A 120.8(6) . . ?
C7A C8A C9A 121.9(5) . . ?
C8A C9A C10A 116.4(4) . . ?
C8A C9A C1A 124.2(4) . . ?
C10A C9A C1A 119.4(4) . . ?
C9A C10A C4A 118.4(4) . . ?
C9A C10A C5A 119.8(5) . . ?
C4A C10A C5A 121.8(5) . . ?
N1A C11A C1A 127.4(4) . . ?
C11A N1A C12A 119.3(4) . . ?
C11A N1A Zn1 125.5(3) . . ?
C12A N1A Zn1 114.7(3) . . ?
N1A C12A C15A 108.8(4) . . ?
N1A C12A C13A 114.1(4) . . ?
C15A C12A C13A 107.1(4) . . ?
N1A C12A C14A 106.0(3) . . ?
C15A C12A C14A 112.6(4) . . ?
C13A C12A C14A 108.3(4) . . ?
O14A C14A C12A 113.6(4) . . ?
C14A O14A Zn1 105.7(2) . . ?
C14A O14A Dy1 127.5(2) . . ?
Zn1 O14A Dy1 94.93(11) . . ?
C14A O14A Dy2 123.6(2) . . ?
Zn1 O14A Dy2 99.64(10) . . ?
Dy1 O14A Dy2 98.57(11) . . ?
O15A C15A C12A 111.7(4) . . ?
C15A O15A Dy1 135.2(3) . . ?
C2B O2B Dy2 139.4(3) . . ?
C2B C1B C11B 120.3(4) . . ?
C2B C1B C9B 120.1(4) . . ?
C11B C1B C9B 119.2(4) . . ?
O2B C2B C1B 124.1(4) . . ?
O2B C2B C3B 118.3(4) . . ?
C1B C2B C3B 117.5(4) . . ?
C4B C3B C2B 122.0(4) . . ?
C3B C4B C10B 121.9(4) . . ?
C6B C5B C10B 121.5(5) . . ?
C5B C6B C7B 119.1(5) . . ?
C8B C7B C6B 121.0(5) . . ?
C7B C8B C9B 121.7(5) . . ?
C8B C9B C10B 116.6(4) . . ?
C8B C9B C1B 123.3(4) . . ?
C10B C9B C1B 120.0(4) . . ?
C5B C10B C9B 120.1(4) . . ?
C5B C10B C4B 121.5(4) . . ?
C9B C10B C4B 118.3(4) . . ?
N1B C11B C1B 126.1(4) . . ?
C11B N1B C12B 120.1(3) . . ?
C11B N1B Dy2 131.6(3) . . ?
C12B N1B Dy2 108.3(2) . . ?
N1B C12B C13B 117.2(3) . . ?
N1B C12B C15B 105.6(3) . . ?
C13B C12B C15B 107.0(3) . . ?
N1B C12B C14B 106.6(3) . . ?
C13B C12B C14B 109.9(3) . . ?
C15B C12B C14B 110.4(3) . . ?
O14B C14B C12B 111.2(3) . . ?
C14B O14B Zn2 110.4(2) . . ?
C14B O14B Dy2 113.7(2) . . ?
Zn2 O14B Dy2 127.01(12) . . ?
C14B O14B Dy3 119.0(2) . 2_666 ?
Zn2 O14B Dy3 94.74(11) . 2_666 ?
Dy2 O14B Dy3 88.71(9) . 2_666 ?
O15B C15B C12B 111.8(3) . . ?
C15B O15B Zn1 122.5(3) . . ?
C15B O15B Dy3 113.1(2) . 2_666 ?
Zn1 O15B Dy3 99.76(11) . 2_666 ?
C15B O15B Dy2 117.3(2) . . ?
Zn1 O15B Dy2 106.75(11) . . ?
Dy3 O15B Dy2 91.76(10) 2_666 . ?
C1C O1C Zn2 93.4(3) . . ?
C1C O2C Zn2 86.3(3) . . ?
O2C C1C O1C 119.8(4) . . ?
O2C C1C C2C 121.2(4) . . ?
O1C C1C C2C 119.0(4) . . ?
C1D O1D Zn2 120.9(3) . . ?
C1D O2D Dy3 140.6(3) . 2_666 ?
O1D C1D O2D 124.7(4) . . ?
O1D C1D C2D 116.2(4) . . ?
O2D C1D C2D 119.1(4) . . ?
C1E O1E Dy2 141.2(3) . . ?
C1E O2E Dy3 127.1(3) . . ?
O1E C1E O2E 122.4(4) . . ?
O1E C1E C2E 120.6(4) . . ?
O2E C1E C2E 117.0(4) . . ?
C1F O1F Dy2 109.7(3) . . ?
C1F O2F Dy1 153.7(3) . 2_666 ?
O1F C1F O2F 123.0(4) . . ?
O1F C1F C2F 119.8(4) . . ?
O2F C1F C2F 117.2(4) . . ?
C1M O1M Zn1 112.8(3) . . ?
C1M O1M Dy1 120.7(2) . . ?
Zn1 O1M Dy1 97.48(12) . . ?
C1M O1M Dy3 122.9(3) . 2_666 ?
Zn1 O1M Dy3 96.37(11) . 2_666 ?
Dy1 O1M Dy3 101.27(11) . 2_666 ?
Zn2 O2 Dy1 110.11(13) . 2_666 ?
Zn2 O2 Dy3 94.53(11) . 2_666 ?
Dy1 O2 Dy3 100.80(11) 2_666 2_666 ?
C2M O2M Zn2 110.0(4) . . ?
Zn2 O2M Dy1 110.11(13) . 2_666 ?
Zn2 O2M Dy3 94.53(11) . 2_666 ?
Dy1 O2M Dy3 100.80(11) 2_666 2_666 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Zn1 O2A C2A C1A 11.9(6) . . . . ?
Zn1 O2A C2A C3A -166.4(3) . . . . ?
C11A C1A C2A O2A -11.5(6) . . . . ?
C9A C1A C2A O2A 174.6(4) . . . . ?
C11A C1A C2A C3A 166.8(4) . . . . ?
C9A C1A C2A C3A -7.1(6) . . . . ?
O2A C2A C3A C4A 179.4(4) . . . . ?
C1A C2A C3A C4A 1.0(7) . . . . ?
C2A C3A C4A C10A 3.4(7) . . . . ?
C10A C5A C6A C7A 2.0(8) . . . . ?
C5A C6A C7A C8A -2.4(8) . . . . ?
C6A C7A C8A C9A -1.1(8) . . . . ?
C7A C8A C9A C10A 4.7(7) . . . . ?
C7A C8A C9A C1A -176.1(4) . . . . ?
C2A C1A C9A C8A -170.3(4) . . . . ?
C11A C1A C9A C8A 15.4(6) . . . . ?
C2A C1A C9A C10A 8.9(6) . . . . ?
C11A C1A C9A C10A -165.4(4) . . . . ?
C8A C9A C10A C4A 174.7(4) . . . . ?
C1A C9A C10A C4A -4.5(6) . . . . ?
C8A C9A C10A C5A -5.0(6) . . . . ?
C1A C9A C10A C5A 175.8(4) . . . . ?
C3A C4A C10A C9A -1.5(7) . . . . ?
C3A C4A C10A C5A 178.1(5) . . . . ?
C6A C5A C10A C9A 1.8(7) . . . . ?
C6A C5A C10A C4A -177.8(5) . . . . ?
C2A C1A C11A N1A 6.3(7) . . . . ?
C9A C1A C11A N1A -179.6(4) . . . . ?
C1A C11A N1A C12A -173.3(4) . . . . ?
C1A C11A N1A Zn1 -1.7(6) . . . . ?
C11A N1A C12A C15A 84.1(5) . . . . ?
Zn1 N1A C12A C15A -88.4(4) . . . . ?
C11A N1A C12A C13A -35.5(5) . . . . ?
Zn1 N1A C12A C13A 152.0(3) . . . . ?
C11A N1A C12A C14A -154.6(4) . . . . ?
Zn1 N1A C12A C14A 32.9(4) . . . . ?
N1A C12A C14A O14A -47.3(5) . . . . ?
C15A C12A C14A O14A 71.6(5) . . . . ?
C13A C12A C14A O14A -170.1(4) . . . . ?
C12A C14A O14A Zn1 37.3(4) . . . . ?
C12A C14A O14A Dy1 -71.9(4) . . . . ?
C12A C14A O14A Dy2 150.6(3) . . . . ?
N1A C12A C15A O15A 61.9(5) . . . . ?
C13A C12A C15A O15A -174.2(3) . . . . ?
C14A C12A C15A O15A -55.3(5) . . . . ?
C12A C15A O15A Dy1 44.1(5) . . . . ?
Dy2 O2B C2B C1B 24.2(7) . . . . ?
Dy2 O2B C2B C3B -159.1(3) . . . . ?
C11B C1B C2B O2B 7.1(7) . . . . ?
C9B C1B C2B O2B -179.6(4) . . . . ?
C11B C1B C2B C3B -169.7(4) . . . . ?
C9B C1B C2B C3B 3.7(6) . . . . ?
O2B C2B C3B C4B 178.6(5) . . . . ?
C1B C2B C3B C4B -4.5(7) . . . . ?
C2B C3B C4B C10B 2.5(8) . . . . ?
C10B C5B C6B C7B 1.5(9) . . . . ?
C5B C6B C7B C8B -1.7(10) . . . . ?
C6B C7B C8B C9B 1.4(10) . . . . ?
C7B C8B C9B C10B -0.9(8) . . . . ?
C7B C8B C9B C1B 179.7(5) . . . . ?
C2B C1B C9B C8B 178.3(5) . . . . ?
C11B C1B C9B C8B -8.3(7) . . . . ?
C2B C1B C9B C10B -1.1(7) . . . . ?
C11B C1B C9B C10B 172.3(4) . . . . ?
C6B C5B C10B C9B -1.1(8) . . . . ?
C6B C5B C10B C4B -179.9(5) . . . . ?
C8B C9B C10B C5B 0.7(7) . . . . ?
C1B C9B C10B C5B -179.9(4) . . . . ?
C8B C9B C10B C4B 179.6(5) . . . . ?
C1B C9B C10B C4B -1.0(7) . . . . ?
C3B C4B C10B C5B 179.2(5) . . . . ?
C3B C4B C10B C9B 0.3(8) . . . . ?
C2B C1B C11B N1B -13.6(7) . . . . ?
C9B C1B C11B N1B 173.0(4) . . . . ?
C1B C11B N1B C12B 173.6(4) . . . . ?
C1B C11B N1B Dy2 -5.7(7) . . . . ?
C11B N1B C12B C13B -1.1(6) . . . . ?
Dy2 N1B C12B C13B 178.4(3) . . . . ?
C11B N1B C12B C15B -120.1(4) . . . . ?
Dy2 N1B C12B C15B 59.4(3) . . . . ?
C11B N1B C12B C14B 122.5(4) . . . . ?
Dy2 N1B C12B C14B -58.0(3) . . . . ?
N1B C12B C14B O14B 57.8(4) . . . . ?
C13B C12B C14B O14B -174.3(3) . . . . ?
C15B C12B C14B O14B -56.4(4) . . . . ?
C12B C14B O14B Zn2 -177.8(3) . . . . ?
C12B C14B O14B Dy2 -28.1(4) . . . . ?
C12B C14B O14B Dy3 74.3(4) . . . 2_666 ?
N1B C12B C15B O15B -49.7(4) . . . . ?
C13B C12B C15B O15B -175.3(3) . . . . ?
C14B C12B C15B O15B 65.1(4) . . . . ?
C12B C15B O15B Zn1 151.8(3) . . . . ?
C12B C15B O15B Dy3 -88.8(3) . . . 2_666 ?
C12B C15B O15B Dy2 16.2(4) . . . . ?
Zn2 O2C C1C O1C -2.0(4) . . . . ?
Zn2 O2C C1C C2C 177.1(4) . . . . ?
Zn2 O1C C1C O2C 2.2(4) . . . . ?
Zn2 O1C C1C C2C -176.9(4) . . . . ?
Zn2 O1D C1D O2D 11.0(6) . . . . ?
Zn2 O1D C1D C2D -167.6(3) . . . . ?
Dy3 O2D C1D O1D -17.6(8) 2_666 . . . ?
Dy3 O2D C1D C2D 160.9(3) 2_666 . . . ?
Dy2 O1E C1E O2E 175.3(3) . . . . ?
Dy2 O1E C1E C2E -6.7(8) . . . . ?
Dy3 O2E C1E O1E 8.3(7) . . . . ?
Dy3 O2E C1E C2E -169.7(3) . . . . ?
Dy2 O1F C1F O2F 7.3(5) . . . . ?
Dy2 O1F C1F C2F -173.8(3) . . . . ?
Dy1 O2F C1F O1F -77.5(8) 2_666 . . . ?
Dy1 O2F C1F C2F 103.5(7) 2_666 . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O1W H1W O2A 0.84 1.88 2.715(5) 172.9 2_666 yes
O1W H2W O4M 0.84 1.94 2.729(5) 156.7 2_666 yes
C14A H14A O2B 0.99 2.44 3.043(5) 119.1 . yes
O15A H15A O1C 0.84 1.99 2.743(4) 149.1 2_666 yes
C15B H15E O1W 0.99 2.52 3.183(5) 124.4 2_666 yes
C2E H2E1 O2B 0.98 2.43 3.316(5) 149.7 . yes
C1M H1M3 O1W 0.98 2.55 3.197(6) 123.8 2_666 yes
C2M^b H2M1^b O2D 0.98 2.41 3.079(10) 125.2 . yes
O3M H3M O2C 0.84 1.93 2.762(5) 169.5 . yes
O4M H4M O3M 0.84 1.93 2.742(6) 162.2 2_765 yes

_refine_diff_density_max         1.693
_refine_diff_density_min         -0.990
_refine_diff_density_rms         0.172

