# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_sq
_database_code_depnum_ccdc_archive 'CCDC 1962830'
loop_
_audit_author_name
_audit_author_address
'Benjamin Gelfand'
;University of Calgary
Canada
;
_audit_update_record             
;
2019-10-31 deposited with the CCDC.	2020-03-12 downloaded from the CCDC.
;
_audit_creation_date             2018-02-15
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C22 H46 La2 N3 O15 P3'
_chemical_formula_sum            'C22 H46 La2 N3 O15 P3'
_chemical_formula_weight         963.35
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.6056(16)
_cell_length_b                   15.424(3)
_cell_length_c                   16.780(3)
_cell_angle_alpha                95.434(7)
_cell_angle_beta                 106.266(7)
_cell_angle_gamma                91.765(9)
_cell_volume                     2371.5(7)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9780
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.37
_cell_measurement_theta_min      2.99
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.928
_exptl_absorpt_correction_T_max  0.9311
_exptl_absorpt_correction_T_min  0.6412
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0901 before and 0.0665 after correction.
The Ratio of minimum to maximum transmission is 0.6886.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.349
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       rod
_exptl_crystal_F_000             956
_exptl_crystal_size_max          0.308
_exptl_crystal_size_mid          0.157
_exptl_crystal_size_min          0.084
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0872
_diffrn_reflns_av_unetI/netI     0.1072
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            32249
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.443
_diffrn_reflns_theta_min         2.587
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8076
_reflns_number_total             11739
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         2.867
_refine_diff_density_min         -1.330
_refine_diff_density_rms         0.186
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     410
_refine_ls_number_reflns         11739
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0768
_refine_ls_R_factor_gt           0.0494
_refine_ls_restrained_S_all      0.968
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0573P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1156
_refine_ls_wR_factor_ref         0.1272
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2.a Rotating group:
 O15(H15A,H15B), O14(H14A,H14B)
2.b Ternary CH refined with riding coordinates:
 N3(H3), C16(H16), N2(H2), N1(H1), C7(H7), C4(H4)
2.c Secondary CH2 refined with riding coordinates:
 C17(H17A,H17B), C12(H12A,H12B), C15(H15C,H15D), C18(H18A,H18B), C9(H9A,H9B),
 C13(H13A,H13B), C10(H10A,H10B), C11(H11A,H11B), C8(H8A,H8B), C14(H14C,H14D),
 C1(H1A,H1B), C6(H6A,H6B), C2(H2A,H2B), C5(H5A,H5B), C3(H3A,H3B)
2.d Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C22(H22A,H22B,H22C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
La2 La 1.28704(3) 0.55640(2) 1.08450(2) 0.01058(8) Uani 1 1 d . . . . .
La1 La -0.11412(3) 0.65801(2) 0.09422(2) 0.01234(9) Uani 1 1 d . . . . .
P3 P 1.49612(15) 0.40347(9) 1.06409(8) 0.0116(3) Uani 1 1 d . . . . .
P2 P 1.02392(15) 0.58141(9) 0.92497(8) 0.0115(3) Uani 1 1 d . . . . .
P1 P 0.22042(16) 0.59295(10) 0.25883(8) 0.0144(3) Uani 1 1 d . . . . .
O8 O 1.5213(4) 0.4827(2) 1.1281(2) 0.0149(8) Uani 1 1 d . . . . .
O11 O 0.0079(5) 0.8123(3) 0.0960(2) 0.0241(10) Uani 1 1 d . . . . .
O6 O 1.0739(4) 0.6441(2) 1.0041(2) 0.0120(8) Uani 1 1 d . . . . .
O10 O -0.1673(4) 0.7680(3) -0.0180(2) 0.0185(8) Uani 1 1 d . . . . .
O9 O 1.6128(4) 0.3919(2) 1.0209(2) 0.0132(8) Uani 1 1 d . . . . .
O3 O 0.3519(4) 0.5540(3) 0.2405(2) 0.0162(8) Uani 1 1 d . . . . .
O15 O 1.4256(5) 0.7051(3) 1.1459(2) 0.0224(9) Uani 1 1 d . . . . .
H15A H 1.365211 0.743047 1.152820 0.034 Uiso 1 1 d GR . . . .
H15B H 1.463117 0.725049 1.109997 0.034 Uiso 1 1 d GR . . . .
O13 O -0.1079(5) 0.7581(3) 0.2308(2) 0.0277(10) Uani 1 1 d . . . . .
O2 O 0.1394(4) 0.5346(3) 0.2994(2) 0.0194(9) Uani 1 1 d . . . . .
O1 O 0.1279(4) 0.6245(2) 0.1782(2) 0.0143(8) Uani 1 1 d . . . . .
O7 O 1.3440(4) 0.4030(2) 1.0063(2) 0.0153(8) Uani 1 1 d . . . . .
O12 O -0.3069(5) 0.7623(3) 0.1252(2) 0.0252(10) Uani 1 1 d . . . . .
O4 O 0.8617(4) 0.5640(2) 0.8928(2) 0.0139(8) Uani 1 1 d . . . . .
O14 O -0.2309(5) 0.5790(3) 0.1895(2) 0.0213(9) Uani 1 1 d . . . . .
H14A H -0.173149 0.583817 0.238609 0.032 Uiso 1 1 d GR . . . .
H14B H -0.239523 0.524553 0.173977 0.032 Uiso 1 1 d GR . . . .
N3 N 1.4705(5) 0.2247(3) 1.0741(3) 0.0143(9) Uani 1 1 d . . . . .
H3 H 1.387249 0.228118 1.025115 0.017 Uiso 1 1 calc R . . . .
O5 O 1.1066(4) 0.5005(2) 0.9415(2) 0.0125(8) Uani 1 1 d . . . . .
C16 C 1.5219(6) 0.0422(3) 1.0300(3) 0.0169(12) Uani 1 1 d . . . . .
H16 H 1.606101 0.031156 1.075925 0.020 Uiso 1 1 calc R . . . .
N2 N 0.9521(5) 0.6359(3) 0.7667(3) 0.0150(10) Uani 1 1 d . . . . .
H2 H 0.893256 0.580585 0.753362 0.018 Uiso 1 1 calc R . . . .
C17 C 1.3992(7) 0.0689(4) 1.0673(4) 0.0192(12) Uani 1 1 d . . . . .
H17A H 1.311547 0.073305 1.022257 0.023 Uiso 1 1 calc R . . . .
H17B H 1.380066 0.023854 1.100076 0.023 Uiso 1 1 calc R . . . .
N1 N 0.4272(6) 0.6882(3) 0.3904(3) 0.0197(11) Uani 1 1 d . . . . .
H1 H 0.491393 0.656410 0.363275 0.024 Uiso 1 1 calc R . . . .
C19 C -0.0542(6) 0.8168(4) 0.0193(4) 0.0179(12) Uani 1 1 d . . . . .
C12 C 1.0791(6) 0.6274(4) 0.8402(3) 0.0170(12) Uani 1 1 d . . . . .
H12A H 1.128306 0.684348 0.860765 0.020 Uiso 1 1 calc R . . . .
H12B H 1.147072 0.589950 0.822908 0.020 Uiso 1 1 calc R . . . .
C15 C 1.5657(7) 0.1168(4) 0.9868(4) 0.0209(13) Uani 1 1 d . . . . .
H15C H 1.650746 0.102096 0.969135 0.025 Uiso 1 1 calc R . . . .
H15D H 1.487441 0.124308 0.937299 0.025 Uiso 1 1 calc R . . . .
C18 C 1.4346(7) 0.1541(4) 1.1214(3) 0.0201(13) Uani 1 1 d . . . . .
H18A H 1.352187 0.169476 1.141401 0.024 Uiso 1 1 calc R . . . .
H18B H 1.516586 0.148413 1.169488 0.024 Uiso 1 1 calc R . . . .
C9 C 1.0020(6) 0.6529(4) 0.6916(3) 0.0184(12) Uani 1 1 d . . . . .
H9A H 1.063805 0.607511 0.680398 0.022 Uiso 1 1 calc R . . . .
H9B H 1.057403 0.708487 0.702259 0.022 Uiso 1 1 calc R . . . .
C13 C 1.4964(6) 0.3116(3) 1.1251(3) 0.0146(11) Uani 1 1 d . . . . .
H13A H 1.589292 0.313140 1.167348 0.018 Uiso 1 1 calc R . . . .
H13B H 1.421738 0.318298 1.153603 0.018 Uiso 1 1 calc R . . . .
C10 C 0.8589(6) 0.7065(4) 0.7842(3) 0.0157(11) Uani 1 1 d . . . . .
H10A H 0.911750 0.762690 0.791829 0.019 Uiso 1 1 calc R . . . .
H10B H 0.833713 0.698450 0.835189 0.019 Uiso 1 1 calc R . . . .
C21 C -0.2304(7) 0.7886(4) 0.1992(4) 0.0284(15) Uani 1 1 d . . . . .
C20 C 0.0059(8) 0.8768(4) -0.0282(4) 0.0285(15) Uani 1 1 d . . . . .
H20A H 0.065344 0.922869 0.009744 0.043 Uiso 1 1 calc GR . . . .
H20B H -0.072347 0.901298 -0.067057 0.043 Uiso 1 1 calc GR . . . .
H20C H 0.063562 0.845274 -0.058079 0.043 Uiso 1 1 calc GR . . . .
C11 C 0.7232(7) 0.7045(4) 0.7129(3) 0.0226(13) Uani 1 1 d . . . . .
H11A H 0.661063 0.749071 0.725405 0.027 Uiso 1 1 calc R . . . .
H11B H 0.670587 0.648254 0.705253 0.027 Uiso 1 1 calc R . . . .
C8 C 0.8678(7) 0.6540(4) 0.6163(3) 0.0187(12) Uani 1 1 d . . . . .
H8A H 0.898798 0.667378 0.568314 0.022 Uiso 1 1 calc R . . . .
H8B H 0.818469 0.596351 0.603112 0.022 Uiso 1 1 calc R . . . .
C14 C 1.5987(6) 0.2014(4) 1.0437(4) 0.0200(12) Uani 1 1 d . . . . .
H14C H 1.681932 0.195517 1.091078 0.024 Uiso 1 1 calc R . . . .
H14D H 1.623065 0.247707 1.013759 0.024 Uiso 1 1 calc R . . . .
C1 C 0.2855(7) 0.6957(4) 0.3255(3) 0.0199(12) Uani 1 1 d . . . . .
H1A H 0.297516 0.740693 0.290861 0.024 Uiso 1 1 calc R . . . .
H1B H 0.213065 0.713442 0.353017 0.024 Uiso 1 1 calc R . . . .
C7 C 0.7612(6) 0.7207(4) 0.6319(3) 0.0196(12) Uani 1 1 d . . . . .
H7 H 0.810875 0.778719 0.640718 0.024 Uiso 1 1 calc R . . . .
C6 C 0.4072(7) 0.6383(4) 0.4581(3) 0.0207(13) Uani 1 1 d . . . . .
H6A H 0.364975 0.580352 0.434599 0.025 Uiso 1 1 calc R . . . .
H6B H 0.340406 0.667255 0.484233 0.025 Uiso 1 1 calc R . . . .
C4 C 0.6219(7) 0.7207(4) 0.5588(3) 0.0221(13) Uani 1 1 d . . . . .
H4 H 0.551946 0.752117 0.581556 0.027 Uiso 1 1 calc R . . . .
C2 C 0.4984(8) 0.7775(4) 0.4244(4) 0.0302(16) Uani 1 1 d . . . . .
H2A H 0.513558 0.807862 0.379206 0.036 Uiso 1 1 calc R . . . .
H2B H 0.435473 0.811091 0.450028 0.036 Uiso 1 1 calc R . . . .
C5 C 0.5496(7) 0.6311(4) 0.5229(3) 0.0222(13) Uani 1 1 d . . . . .
H5A H 0.613542 0.597804 0.497846 0.027 Uiso 1 1 calc R . . . .
H5B H 0.533036 0.600302 0.567489 0.027 Uiso 1 1 calc R . . . .
C3 C 0.6409(8) 0.7702(4) 0.4877(4) 0.0313(16) Uani 1 1 d . . . . .
H3A H 0.684705 0.828112 0.510059 0.038 Uiso 1 1 calc R . . . .
H3B H 0.705883 0.739984 0.461061 0.038 Uiso 1 1 calc R . . . .
C22 C -0.2827(9) 0.8591(5) 0.2501(5) 0.053(2) Uani 1 1 d . . . . .
H22A H -0.386872 0.857575 0.232058 0.080 Uiso 1 1 calc GR . . . .
H22B H -0.243837 0.914895 0.242846 0.080 Uiso 1 1 calc GR . . . .
H22C H -0.250651 0.849686 0.308055 0.080 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
La2 P3 3.1998(16) . ?
La2 P2 3.1887(15) . ?
La2 P1 3.1690(14) 1_656 ?
La2 O8 2.506(4) . ?
La2 O6 2.610(4) . ?
La2 O9 2.422(3) 2_867 ?
La2 O3 2.520(3) 1_656 ?
La2 O15 2.586(4) . ?
La2 O1 2.654(3) 1_656 ?
La2 O7 2.741(4) . ?
La2 O4 2.432(4) 2_767 ?
La2 O5 2.587(3) . ?
La1 O11 2.613(4) . ?
La1 O6 2.661(3) 1_454 ?
La1 O10 2.609(4) . ?
La1 O13 2.624(4) . ?
La1 O1 2.456(4) . ?
La1 O7 2.468(4) 2_666 ?
La1 O12 2.618(4) . ?
La1 O14 2.566(4) . ?
La1 O5 2.470(4) 2_666 ?
La1 C19 2.968(6) . ?
La1 C21 2.996(6) . ?
P3 O8 1.515(4) . ?
P3 O9 1.502(4) . ?
P3 O7 1.510(4) . ?
P3 C13 1.824(5) . ?
P2 O6 1.517(4) . ?
P2 O4 1.505(4) . ?
P2 O5 1.506(4) . ?
P2 C12 1.843(5) . ?
P1 O3 1.510(4) . ?
P1 O2 1.500(4) . ?
P1 O1 1.528(4) . ?
P1 C1 1.835(6) . ?
O11 C19 1.268(7) . ?
O10 C19 1.272(7) . ?
O15 H15A 0.8588 . ?
O15 H15B 0.8588 . ?
O13 C21 1.273(8) . ?
O12 C21 1.273(7) . ?
O14 H14A 0.8501 . ?
O14 H14B 0.8500 . ?
N3 H3 0.9800 . ?
N3 C18 1.493(7) . ?
N3 C13 1.495(7) . ?
N3 C14 1.500(7) . ?
C16 C16 1.538(10) 2_857 ?
C16 H16 0.9800 . ?
C16 C17 1.531(8) . ?
C16 C15 1.525(7) . ?
N2 H2 0.9800 . ?
N2 C12 1.491(7) . ?
N2 C9 1.509(6) . ?
N2 C10 1.490(7) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 C18 1.497(7) . ?
N1 H1 0.9800 . ?
N1 C1 1.502(7) . ?
N1 C6 1.483(7) . ?
N1 C2 1.506(7) . ?
C19 C20 1.480(8) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C15 H15C 0.9700 . ?
C15 H15D 0.9700 . ?
C15 C14 1.511(7) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 C8 1.534(8) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 C11 1.500(8) . ?
C21 C22 1.504(9) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C7 1.542(8) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C7 1.530(9) . ?
C14 H14C 0.9700 . ?
C14 H14D 0.9700 . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C7 H7 0.9800 . ?
C7 C4 1.542(8) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C6 C5 1.505(8) . ?
C4 H4 0.9800 . ?
C4 C5 1.518(8) . ?
C4 C3 1.524(8) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C2 C3 1.494(9) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 La2 P3 116.79(4) . . ?
P1 La2 P3 117.82(4) 1_656 . ?
P1 La2 P2 115.29(4) 1_656 . ?
O8 La2 P3 27.51(8) . . ?
O8 La2 P2 142.12(8) . . ?
O8 La2 P1 100.44(8) . 1_656 ?
O8 La2 O6 163.32(11) . . ?
O8 La2 O3 72.59(12) . 1_656 ?
O8 La2 O15 89.48(13) . . ?
O8 La2 O1 129.06(11) . 1_656 ?
O8 La2 O7 55.61(11) . . ?
O8 La2 O5 117.64(11) . . ?
O6 La2 P3 144.16(8) . . ?
O6 La2 P2 28.13(8) . . ?
O6 La2 P1 94.69(8) . 1_656 ?
O6 La2 O1 65.99(11) . 1_656 ?
O6 La2 O7 118.41(11) . . ?
O9 La2 P3 79.63(9) 2_867 . ?
O9 La2 P2 71.90(9) 2_867 . ?
O9 La2 P1 148.93(9) 2_867 1_656 ?
O9 La2 O8 84.19(12) 2_867 . ?
O9 La2 O6 79.22(12) 2_867 . ?
O9 La2 O3 140.04(12) 2_867 1_656 ?
O9 La2 O15 72.59(12) 2_867 . ?
O9 La2 O1 134.83(12) 2_867 1_656 ?
O9 La2 O7 78.33(11) 2_867 . ?
O9 La2 O4 141.24(12) 2_867 2_767 ?
O9 La2 O5 73.47(12) 2_867 . ?
O3 La2 P3 92.41(9) 1_656 . ?
O3 La2 P2 142.70(9) 1_656 . ?
O3 La2 P1 27.91(9) 1_656 1_656 ?
O3 La2 O6 122.03(11) 1_656 . ?
O3 La2 O15 75.09(12) 1_656 . ?
O3 La2 O1 56.47(12) 1_656 1_656 ?
O3 La2 O7 111.66(12) 1_656 . ?
O3 La2 O5 146.25(12) 1_656 . ?
O15 La2 P3 113.38(10) . . ?
O15 La2 P2 109.87(10) . . ?
O15 La2 P1 76.73(9) . 1_656 ?
O15 La2 O6 87.18(13) . . ?
O15 La2 O1 77.63(12) . 1_656 ?
O15 La2 O7 136.55(12) . . ?
O15 La2 O5 133.42(12) . . ?
O1 La2 P3 144.43(9) 1_656 . ?
O1 La2 P2 87.72(8) 1_656 . ?
O1 La2 P1 28.73(9) 1_656 1_656 ?
O1 La2 O7 143.29(11) 1_656 . ?
O7 La2 P3 28.11(8) . . ?
O7 La2 P2 90.29(9) . . ?
O7 La2 P1 129.58(8) . 1_656 ?
O4 La2 P3 82.13(9) 2_767 . ?
O4 La2 P2 86.60(9) 2_767 . ?
O4 La2 P1 69.45(8) 2_767 1_656 ?
O4 La2 O8 94.94(13) 2_767 . ?
O4 La2 O6 96.93(12) 2_767 . ?
O4 La2 O3 74.32(12) 2_767 1_656 ?
O4 La2 O15 146.14(11) 2_767 . ?
O4 La2 O1 73.59(12) 2_767 1_656 ?
O4 La2 O7 69.70(11) 2_767 . ?
O4 La2 O5 72.81(12) 2_767 . ?
O5 La2 P3 90.55(9) . . ?
O5 La2 P2 27.81(9) . . ?
O5 La2 P1 127.81(8) . 1_656 ?
O5 La2 O6 55.71(11) . . ?
O5 La2 O1 106.14(11) . 1_656 ?
O5 La2 O7 63.05(12) . . ?
O11 La1 La2 136.58(8) . 2_666 ?
O11 La1 O6 71.06(12) . 1_454 ?
O11 La1 O13 68.81(13) . . ?
O11 La1 O12 77.57(13) . . ?
O11 La1 C19 25.25(14) . . ?
O11 La1 C21 70.81(15) . . ?
O6 La1 La2 76.07(8) 1_454 2_666 ?
O6 La1 C19 63.81(13) 1_454 . ?
O6 La1 C21 141.85(14) 1_454 . ?
O10 La1 La2 92.57(8) . 2_666 ?
O10 La1 O11 49.82(12) . . ?
O10 La1 O6 69.74(12) . 1_454 ?
O10 La1 O13 102.14(13) . . ?
O10 La1 O12 71.93(13) . . ?
O10 La1 C19 25.32(14) . . ?
O10 La1 C21 86.34(16) . . ?
O13 La1 La2 151.74(10) . 2_666 ?
O13 La1 O6 131.62(12) . 1_454 ?
O13 La1 C19 88.49(15) . . ?
O13 La1 C21 25.06(16) . . ?
O1 La1 La2 108.42(8) . 2_666 ?
O1 La1 O11 84.75(13) . . ?
O1 La1 O6 68.00(11) . 1_454 ?
O1 La1 O10 125.69(12) . . ?
O1 La1 O13 82.42(13) . . ?
O1 La1 O7 145.22(13) . 2_666 ?
O1 La1 O12 132.52(12) . . ?
O1 La1 O14 90.12(13) . . ?
O1 La1 O5 76.44(12) . 2_666 ?
O1 La1 C19 103.18(15) . . ?
O1 La1 C21 107.45(15) . . ?
O7 La1 La2 38.44(9) 2_666 2_666 ?
O7 La1 O11 125.28(13) 2_666 . ?
O7 La1 O6 102.74(11) 2_666 1_454 ?
O7 La1 O10 76.46(12) 2_666 . ?
O7 La1 O13 122.16(13) 2_666 . ?
O7 La1 O12 76.53(13) 2_666 . ?
O7 La1 O14 78.92(12) 2_666 . ?
O7 La1 O5 68.79(13) 2_666 2_666 ?
O7 La1 C19 101.78(14) 2_666 . ?
O7 La1 C21 99.77(15) 2_666 . ?
O12 La1 La2 114.72(9) . 2_666 ?
O12 La1 O6 140.60(13) . 1_454 ?
O12 La1 O13 50.12(14) . . ?
O12 La1 C19 77.62(15) . . ?
O12 La1 C21 25.07(16) . . ?
O14 La1 La2 85.33(8) . 2_666 ?
O14 La1 O11 137.06(12) . . ?
O14 La1 O6 144.28(13) . 1_454 ?
O14 La1 O10 142.36(13) . . ?
O14 La1 O13 68.25(13) . . ?
O14 La1 O12 74.95(14) . . ?
O14 La1 C19 151.59(14) . . ?
O14 La1 C21 70.28(16) . . ?
O5 La1 La2 34.64(8) 2_666 2_666 ?
O5 La1 O11 145.65(13) 2_666 . ?
O5 La1 O6 75.29(11) 2_666 1_454 ?
O5 La1 O10 122.75(11) 2_666 . ?
O5 La1 O13 134.72(13) 2_666 . ?
O5 La1 O12 135.76(13) 2_666 . ?
O5 La1 O14 72.20(12) 2_666 . ?
O5 La1 C19 135.01(13) 2_666 . ?
O5 La1 C21 142.25(15) 2_666 . ?
C19 La1 La2 113.11(11) . 2_666 ?
C19 La1 C21 81.74(17) . . ?
C21 La1 La2 136.20(12) . 2_666 ?
O8 P3 La2 49.83(16) . . ?
O8 P3 C13 104.0(2) . . ?
O9 P3 La2 134.38(16) . . ?
O9 P3 O8 114.8(2) . . ?
O9 P3 O7 114.8(2) . . ?
O9 P3 C13 107.8(2) . . ?
O7 P3 La2 58.81(15) . . ?
O7 P3 O8 108.6(2) . . ?
O7 P3 C13 106.0(2) . . ?
C13 P3 La2 117.45(18) . . ?
O6 P2 La2 54.21(15) . . ?
O6 P2 C12 109.7(2) . . ?
O4 P2 La2 140.05(15) . . ?
O4 P2 O6 114.3(2) . . ?
O4 P2 O5 114.0(2) . . ?
O4 P2 C12 105.6(2) . . ?
O5 P2 La2 53.27(13) . . ?
O5 P2 O6 106.9(2) . . ?
O5 P2 C12 106.0(2) . . ?
C12 P2 La2 114.24(18) . . ?
O3 P1 La2 51.37(14) . 1_454 ?
O3 P1 O1 107.5(2) . . ?
O3 P1 C1 106.5(3) . . ?
O2 P1 La2 128.39(16) . 1_454 ?
O2 P1 O3 114.1(2) . . ?
O2 P1 O1 114.6(2) . . ?
O2 P1 C1 110.8(2) . . ?
O1 P1 La2 56.58(14) . 1_454 ?
O1 P1 C1 102.3(2) . . ?
C1 P1 La2 120.77(19) . 1_454 ?
P3 O8 La2 102.66(19) . . ?
C19 O11 La1 93.2(3) . . ?
La2 O6 La1 107.23(12) . 1_656 ?
P2 O6 La2 97.66(18) . . ?
P2 O6 La1 114.95(19) . 1_656 ?
C19 O10 La1 93.3(3) . . ?
P3 O9 La2 144.7(2) . 2_867 ?
P1 O3 La2 100.72(19) . 1_454 ?
La2 O15 H15A 109.7 . . ?
La2 O15 H15B 109.7 . . ?
H15A O15 H15B 104.1 . . ?
C21 O13 La1 94.1(3) . . ?
La1 O1 La2 112.22(12) . 1_454 ?
P1 O1 La2 94.69(18) . 1_454 ?
P1 O1 La1 147.7(2) . . ?
La1 O7 La2 107.54(15) 2_666 . ?
P3 O7 La2 93.07(17) . . ?
P3 O7 La1 157.8(2) . 2_666 ?
C21 O12 La1 94.3(4) . . ?
P2 O4 La2 128.5(2) . 2_767 ?
La1 O14 H14A 109.4 . . ?
La1 O14 H14B 109.3 . . ?
H14A O14 H14B 104.5 . . ?
C18 N3 H3 107.9 . . ?
C18 N3 C13 111.8(4) . . ?
C18 N3 C14 109.5(4) . . ?
C13 N3 H3 107.9 . . ?
C13 N3 C14 111.6(4) . . ?
C14 N3 H3 107.9 . . ?
La1 O5 La2 112.50(14) 2_666 . ?
P2 O5 La2 98.92(16) . . ?
P2 O5 La1 147.2(2) . 2_666 ?
C16 C16 H16 108.1 2_857 . ?
C17 C16 C16 111.2(6) . 2_857 ?
C17 C16 H16 108.1 . . ?
C15 C16 C16 111.5(5) . 2_857 ?
C15 C16 H16 108.1 . . ?
C15 C16 C17 109.8(5) . . ?
C12 N2 H2 108.2 . . ?
C12 N2 C9 110.6(4) . . ?
C9 N2 H2 108.2 . . ?
C10 N2 H2 108.2 . . ?
C10 N2 C12 112.0(4) . . ?
C10 N2 C9 109.6(4) . . ?
C16 C17 H17A 109.1 . . ?
C16 C17 H17B 109.1 . . ?
H17A C17 H17B 107.8 . . ?
C18 C17 C16 112.6(5) . . ?
C18 C17 H17A 109.1 . . ?
C18 C17 H17B 109.1 . . ?
C1 N1 H1 108.0 . . ?
C1 N1 C2 110.1(5) . . ?
C6 N1 H1 108.0 . . ?
C6 N1 C1 111.4(5) . . ?
C6 N1 C2 111.3(4) . . ?
C2 N1 H1 108.0 . . ?
O11 C19 La1 61.5(3) . . ?
O11 C19 O10 120.0(5) . . ?
O11 C19 C20 120.6(5) . . ?
O10 C19 La1 61.4(3) . . ?
O10 C19 C20 119.4(5) . . ?
C20 C19 La1 161.6(4) . . ?
P2 C12 H12A 109.2 . . ?
P2 C12 H12B 109.2 . . ?
N2 C12 P2 111.9(4) . . ?
N2 C12 H12A 109.2 . . ?
N2 C12 H12B 109.2 . . ?
H12A C12 H12B 107.9 . . ?
C16 C15 H15C 109.3 . . ?
C16 C15 H15D 109.3 . . ?
H15C C15 H15D 107.9 . . ?
C14 C15 C16 111.7(4) . . ?
C14 C15 H15C 109.3 . . ?
C14 C15 H15D 109.3 . . ?
N3 C18 C17 110.8(4) . . ?
N3 C18 H18A 109.5 . . ?
N3 C18 H18B 109.5 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 108.1 . . ?
N2 C9 H9A 110.0 . . ?
N2 C9 H9B 110.0 . . ?
N2 C9 C8 108.6(4) . . ?
H9A C9 H9B 108.3 . . ?
C8 C9 H9A 110.0 . . ?
C8 C9 H9B 110.0 . . ?
P3 C13 H13A 108.8 . . ?
P3 C13 H13B 108.8 . . ?
N3 C13 P3 113.8(3) . . ?
N3 C13 H13A 108.8 . . ?
N3 C13 H13B 108.8 . . ?
H13A C13 H13B 107.7 . . ?
N2 C10 H10A 109.7 . . ?
N2 C10 H10B 109.7 . . ?
N2 C10 C11 109.8(4) . . ?
H10A C10 H10B 108.2 . . ?
C11 C10 H10A 109.7 . . ?
C11 C10 H10B 109.7 . . ?
O13 C21 La1 60.8(3) . . ?
O13 C21 O12 121.4(6) . . ?
O13 C21 C22 118.7(6) . . ?
O12 C21 La1 60.6(3) . . ?
O12 C21 C22 119.9(6) . . ?
C22 C21 La1 176.0(5) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C10 C11 H11A 109.6 . . ?
C10 C11 H11B 109.6 . . ?
C10 C11 C7 110.3(5) . . ?
H11A C11 H11B 108.1 . . ?
C7 C11 H11A 109.6 . . ?
C7 C11 H11B 109.6 . . ?
C9 C8 H8A 109.1 . . ?
C9 C8 H8B 109.1 . . ?
H8A C8 H8B 107.8 . . ?
C7 C8 C9 112.6(4) . . ?
C7 C8 H8A 109.1 . . ?
C7 C8 H8B 109.1 . . ?
N3 C14 C15 110.7(5) . . ?
N3 C14 H14C 109.5 . . ?
N3 C14 H14D 109.5 . . ?
C15 C14 H14C 109.5 . . ?
C15 C14 H14D 109.5 . . ?
H14C C14 H14D 108.1 . . ?
P1 C1 H1A 109.1 . . ?
P1 C1 H1B 109.1 . . ?
N1 C1 P1 112.5(4) . . ?
N1 C1 H1A 109.1 . . ?
N1 C1 H1B 109.1 . . ?
H1A C1 H1B 107.8 . . ?
C11 C7 H7 107.7 . . ?
C8 C7 C11 109.0(5) . . ?
C8 C7 H7 107.7 . . ?
C8 C7 C4 114.0(5) . . ?
C4 C7 C11 110.5(5) . . ?
C4 C7 H7 107.7 . . ?
N1 C6 H6A 109.4 . . ?
N1 C6 H6B 109.4 . . ?
N1 C6 C5 111.1(5) . . ?
H6A C6 H6B 108.0 . . ?
C5 C6 H6A 109.4 . . ?
C5 C6 H6B 109.4 . . ?
C7 C4 H4 106.1 . . ?
C5 C4 C7 114.9(5) . . ?
C5 C4 H4 106.1 . . ?
C5 C4 C3 109.0(5) . . ?
C3 C4 C7 114.0(5) . . ?
C3 C4 H4 106.1 . . ?
N1 C2 H2A 109.6 . . ?
N1 C2 H2B 109.6 . . ?
H2A C2 H2B 108.1 . . ?
C3 C2 N1 110.2(5) . . ?
C3 C2 H2A 109.6 . . ?
C3 C2 H2B 109.6 . . ?
C6 C5 C4 110.9(5) . . ?
C6 C5 H5A 109.5 . . ?
C6 C5 H5B 109.5 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 108.0 . . ?
C4 C3 H3A 109.4 . . ?
C4 C3 H3B 109.4 . . ?
C2 C3 C4 111.1(6) . . ?
C2 C3 H3A 109.4 . . ?
C2 C3 H3B 109.4 . . ?
H3A C3 H3B 108.0 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
