# Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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#######################################################################

data_mo_dm16164_0m
_database_code_depnum_ccdc_archive 'CCDC 1893731'
loop_
_audit_author_name
_audit_author_address
'Qiong Wu'
;Xuzhou University of Technology
China
;
_audit_update_record             
;
2019-01-26 deposited with the CCDC.	2019-03-11 downloaded from the CCDC.
;
_audit_creation_date             2016-04-01
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C24 H22 Cl N O'
_chemical_formula_sum            'C24 H22 Cl N O'
_chemical_formula_weight         375.87
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   17.424(3)
_cell_length_b                   12.100(2)
_cell_length_c                   19.028(3)
_cell_angle_alpha                90
_cell_angle_beta                 101.189(4)
_cell_angle_gamma                90
_cell_volume                     3935.4(12)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    2944
_cell_measurement_temperature    296
_cell_measurement_theta_max      23.66
_cell_measurement_theta_min      2.182
_shelx_estimated_absorpt_T_max   0.970
_shelx_estimated_absorpt_T_min   0.950
_exptl_absorpt_coefficient_mu    0.207
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6912
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0462 before and 0.0397 after correction.
The Ratio of minimum to maximum transmission is 0.9264.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.269
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             1584
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.15
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_unetI/netI     0.0509
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            19722
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.714
_diffrn_reflns_theta_min         2.062
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2999
_reflns_number_total             6111
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.181
_refine_diff_density_min         -0.307
_refine_diff_density_rms         0.037
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     257
_refine_ls_number_reflns         6111
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1218
_refine_ls_R_factor_gt           0.0478
_refine_ls_restrained_S_all      1.000
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0607P)²+0.5889P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1450
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Others
 Sof(H18)=Sof(O1')=Sof(H1')=1-FVAR(1)
 Sof(H24)=Sof(O1)=Sof(H1A)=FVAR(1)
3.a Ternary CH refined with riding coordinates:
 C12(H12)
3.b Secondary CH2 refined with riding coordinates:
 C10(H10A,H10B)
3.c Aromatic/amide H refined with riding coordinates:
 N1(H1), C4(H4), C7(H7), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18),
 C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
3.d Tetrahedral OH refined with riding coordinates:
 O1'(H1')
3.e Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C11(H11A,H11B,H11C)
3.f Idealised tetrahedral OH refined as rotating group:
 O1(H1A)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
_atom_sites_special_details      
;
The structure was solved using Direct Methods (ShelXS). RE = 0.2, Nqual =  -1, Ralpha = 0.069
;
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.78952(3) 1.10966(5) 0.17271(3) 0.07185(19) Uani 1 1 d . . . . .
N1 N 0.95661(8) 0.84259(12) -0.00296(8) 0.0481(4) Uani 1 1 d . . . . .
H1 H 0.9432 0.8077 -0.0428 0.058 Uiso 1 1 calc R . . . .
C1 C 1.03121(10) 0.84784(15) 0.03715(10) 0.0497(4) Uani 1 1 d . . . . .
C2 C 1.03163(10) 0.90931(15) 0.09682(10) 0.0504(4) Uani 1 1 d . . . . .
C3 C 0.95224(10) 0.94535(14) 0.09420(9) 0.0451(4) Uani 1 1 d . . . . .
C4 C 0.91434(10) 1.01043(15) 0.13755(9) 0.0493(4) Uani 1 1 d . . . . .
H4 H 0.9422 1.0421 0.1793 0.059 Uiso 1 1 calc R . . . .
C5 C 0.83509(10) 1.02683(14) 0.11730(9) 0.0473(4) Uani 1 1 d . . . . .
C6 C 0.78927(9) 0.98165(13) 0.05467(9) 0.0415(4) Uani 1 1 d . . . . .
C7 C 0.82727(10) 0.91871(13) 0.01110(9) 0.0431(4) Uani 1 1 d . . . . .
H7 H 0.7993 0.8881 -0.0310 0.052 Uiso 1 1 calc R . . . .
C8 C 0.90700(10) 0.90168(13) 0.03057(9) 0.0422(4) Uani 1 1 d . . . . .
C9 C 1.09631(12) 0.79013(17) 0.01147(12) 0.0664(6) Uani 1 1 d . . . . .
H9A H 1.0991 0.8159 -0.0357 0.100 Uiso 1 1 calc GR . . . .
H9B H 1.0869 0.7119 0.0100 0.100 Uiso 1 1 calc GR . . . .
H9C H 1.1448 0.8054 0.0435 0.100 Uiso 1 1 calc GR . . . .
C10 C 1.10091(12) 0.93365(19) 0.15505(12) 0.0678(6) Uani 1 1 d . . . . .
H10A H 1.0903 0.9999 0.1802 0.081 Uiso 1 1 calc R . . . .
H10B H 1.1459 0.9485 0.1334 0.081 Uiso 1 1 calc R . . . .
C11 C 1.12091(16) 0.8413(2) 0.20831(14) 0.1011(9) Uani 1 1 d . . . . .
H11A H 1.0777 0.8287 0.2319 0.152 Uiso 1 1 calc GR . . . .
H11B H 1.1664 0.8611 0.2432 0.152 Uiso 1 1 calc GR . . . .
H11C H 1.1314 0.7752 0.1839 0.152 Uiso 1 1 calc GR . . . .
C12 C 0.70069(9) 0.99574(14) 0.03767(9) 0.0434(4) Uani 1 1 d . . . . .
H12 H 0.6895 1.0721 0.0497 0.052 Uiso 1 1 calc R . . . .
C13 C 0.66153(10) 0.92061(14) 0.08458(9) 0.0455(4) Uani 1 1 d . . . . .
C14 C 0.69674(11) 0.82563(15) 0.11657(10) 0.0516(4) Uani 1 1 d . . . . .
H14 H 0.7464 0.8068 0.1095 0.062 Uiso 1 1 calc R . . . .
C15 C 0.66012(14) 0.75804(18) 0.15871(11) 0.0652(6) Uani 1 1 d . . . . .
H15 H 0.6852 0.6948 0.1794 0.078 Uiso 1 1 calc R . . . .
C16 C 0.58719(15) 0.7844(2) 0.16979(11) 0.0733(6) Uani 1 1 d . . . . .
H16 H 0.5625 0.7391 0.1981 0.088 Uiso 1 1 calc R . . . .
C17 C 0.55020(13) 0.8781(2) 0.13892(12) 0.0718(6) Uani 1 1 d . . . . .
H17 H 0.5005 0.8960 0.1463 0.086 Uiso 1 1 calc R . . . .
C18 C 0.58719(11) 0.94578(17) 0.09671(11) 0.0579(5) Uani 1 1 d . . . . .
H18 H 0.5619 1.0090 0.0762 0.069 Uiso 0.329(3) 1 calc R . P A 2
C19 C 0.66848(9) 0.98052(14) -0.04221(9) 0.0443(4) Uani 1 1 d . . . . .
C20 C 0.63097(11) 0.88564(16) -0.07037(10) 0.0553(5) Uani 1 1 d . . . . .
H20 H 0.6213 0.8299 -0.0395 0.066 Uiso 1 1 calc R . . . .
C21 C 0.60722(14) 0.8713(2) -0.14372(12) 0.0720(6) Uani 1 1 d . . . . .
H21 H 0.5818 0.8067 -0.1615 0.086 Uiso 1 1 calc R . . . .
C22 C 0.62124(14) 0.9525(2) -0.19020(12) 0.0793(7) Uani 1 1 d . . . . .
H22 H 0.6062 0.9427 -0.2394 0.095 Uiso 1 1 calc R . . . .
C23 C 0.65775(13) 1.0483(2) -0.16304(12) 0.0740(7) Uani 1 1 d . . . . .
H23 H 0.6670 1.1039 -0.1942 0.089 Uiso 1 1 calc R . . . .
C24 C 0.68096(11) 1.06313(17) -0.08992(11) 0.0562(5) Uani 1 1 d . . . . .
H24 H 0.7051 1.1288 -0.0724 0.067 Uiso 0.671(3) 1 calc R . P A 1
O1 O 0.55428(12) 1.03847(18) 0.06853(14) 0.0735(8) Uani 0.671(3) 1 d . . P A 1
H1A H 0.5117 1.0464 0.0802 0.110 Uiso 0.671(3) 1 calc GR . P A 1
O1' O 0.7150(2) 1.1576(3) -0.0672(2) 0.0645(14) Uani 0.329(3) 1 d . . P A 2
H1' H 0.7369 1.1832 -0.0980 0.097 Uiso 0.329(3) 1 calc R . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C5 1.7525(18) . ?
N1 H1 0.8600 . ?
N1 C1 1.375(2) . ?
N1 C8 1.371(2) . ?
C1 C2 1.356(3) . ?
C1 C9 1.493(3) . ?
C2 C3 1.442(2) . ?
C2 C10 1.501(3) . ?
C3 C4 1.396(2) . ?
C3 C8 1.413(2) . ?
C4 H4 0.9300 . ?
C4 C5 1.374(2) . ?
C5 C6 1.410(2) . ?
C6 C7 1.385(2) . ?
C6 C12 1.524(2) . ?
C7 H7 0.9300 . ?
C7 C8 1.382(2) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 C11 1.503(3) . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12 0.9800 . ?
C12 C13 1.525(2) . ?
C12 C19 1.526(2) . ?
C13 C14 1.387(2) . ?
C13 C18 1.393(3) . ?
C14 H14 0.9300 . ?
C14 C15 1.385(3) . ?
C15 H15 0.9300 . ?
C15 C16 1.366(3) . ?
C16 H16 0.9300 . ?
C16 C17 1.378(3) . ?
C17 H17 0.9300 . ?
C17 C18 1.390(3) . ?
C18 H18 0.9300 . ?
C18 O1 1.325(3) . ?
C19 C20 1.377(2) . ?
C19 C24 1.396(2) . ?
C20 H20 0.9300 . ?
C20 C21 1.387(3) . ?
C21 H21 0.9300 . ?
C21 C22 1.375(3) . ?
C22 H22 0.9300 . ?
C22 C23 1.374(3) . ?
C23 H23 0.9300 . ?
C23 C24 1.383(3) . ?
C24 H24 0.9300 . ?
C24 O1' 1.321(4) . ?
O1 H1A 0.8200 . ?
O1' H1' 0.8200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 H1 125.3 . . ?
C8 N1 H1 125.3 . . ?
C8 N1 C1 109.34(15) . . ?
N1 C1 C9 119.56(18) . . ?
C2 C1 N1 109.93(15) . . ?
C2 C1 C9 130.51(18) . . ?
C1 C2 C3 106.71(15) . . ?
C1 C2 C10 126.78(18) . . ?
C3 C2 C10 126.50(18) . . ?
C4 C3 C2 135.31(16) . . ?
C4 C3 C8 117.91(15) . . ?
C8 C3 C2 106.77(15) . . ?
C3 C4 H4 120.6 . . ?
C5 C4 C3 118.74(16) . . ?
C5 C4 H4 120.6 . . ?
C4 C5 Cl1 117.51(13) . . ?
C4 C5 C6 123.67(16) . . ?
C6 C5 Cl1 118.81(13) . . ?
C5 C6 C12 121.35(15) . . ?
C7 C6 C5 117.46(15) . . ?
C7 C6 C12 121.10(14) . . ?
C6 C7 H7 120.2 . . ?
C8 C7 C6 119.60(15) . . ?
C8 C7 H7 120.2 . . ?
N1 C8 C3 107.24(15) . . ?
N1 C8 C7 130.16(16) . . ?
C7 C8 C3 122.60(16) . . ?
C1 C9 H9A 109.5 . . ?
C1 C9 H9B 109.5 . . ?
C1 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C2 C10 H10A 108.9 . . ?
C2 C10 H10B 108.9 . . ?
C2 C10 C11 113.57(19) . . ?
H10A C10 H10B 107.7 . . ?
C11 C10 H10A 108.9 . . ?
C11 C10 H10B 108.9 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C6 C12 H12 107.1 . . ?
C6 C12 C13 111.04(13) . . ?
C6 C12 C19 111.08(13) . . ?
C13 C12 H12 107.1 . . ?
C13 C12 C19 113.03(14) . . ?
C19 C12 H12 107.1 . . ?
C14 C13 C12 122.75(16) . . ?
C14 C13 C18 117.06(17) . . ?
C18 C13 C12 120.19(16) . . ?
C13 C14 H14 119.0 . . ?
C15 C14 C13 121.97(19) . . ?
C15 C14 H14 119.0 . . ?
C14 C15 H15 120.0 . . ?
C16 C15 C14 119.9(2) . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.1 . . ?
C15 C16 C17 119.9(2) . . ?
C17 C16 H16 120.1 . . ?
C16 C17 H17 120.0 . . ?
C16 C17 C18 120.0(2) . . ?
C18 C17 H17 120.0 . . ?
C13 C18 H18 119.4 . . ?
C17 C18 C13 121.2(2) . . ?
C17 C18 H18 119.4 . . ?
O1 C18 C13 117.5(2) . . ?
O1 C18 C17 121.3(2) . . ?
C20 C19 C12 122.91(15) . . ?
C20 C19 C24 117.78(17) . . ?
C24 C19 C12 119.21(16) . . ?
C19 C20 H20 119.3 . . ?
C19 C20 C21 121.47(19) . . ?
C21 C20 H20 119.3 . . ?
C20 C21 H21 119.9 . . ?
C22 C21 C20 120.1(2) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 H22 120.4 . . ?
C23 C22 C21 119.2(2) . . ?
C23 C22 H22 120.4 . . ?
C22 C23 H23 119.6 . . ?
C22 C23 C24 120.7(2) . . ?
C24 C23 H23 119.6 . . ?
C19 C24 H24 119.7 . . ?
C23 C24 C19 120.6(2) . . ?
C23 C24 H24 119.7 . . ?
O1' C24 C19 121.5(3) . . ?
O1' C24 C23 117.8(3) . . ?
C18 O1 H1A 109.5 . . ?
C24 O1' H1' 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 C5 C6 C7 178.51(12) . . . . ?
Cl1 C5 C6 C12 -5.0(2) . . . . ?
N1 C1 C2 C3 -0.1(2) . . . . ?
N1 C1 C2 C10 178.94(17) . . . . ?
C1 N1 C8 C3 -0.16(19) . . . . ?
C1 N1 C8 C7 -179.10(17) . . . . ?
C1 C2 C3 C4 -178.96(19) . . . . ?
C1 C2 C3 C8 -0.01(19) . . . . ?
C1 C2 C10 C11 -80.6(3) . . . . ?
C2 C3 C4 C5 -179.70(18) . . . . ?
C2 C3 C8 N1 0.10(18) . . . . ?
C2 C3 C8 C7 179.14(15) . . . . ?
C3 C2 C10 C11 98.2(3) . . . . ?
C3 C4 C5 Cl1 -179.63(13) . . . . ?
C3 C4 C5 C6 -0.1(3) . . . . ?
C4 C3 C8 N1 179.27(15) . . . . ?
C4 C3 C8 C7 -1.7(2) . . . . ?
C4 C5 C6 C7 -1.0(3) . . . . ?
C4 C5 C6 C12 175.53(16) . . . . ?
C5 C6 C7 C8 0.7(2) . . . . ?
C5 C6 C12 C13 -75.02(19) . . . . ?
C5 C6 C12 C19 158.29(15) . . . . ?
C6 C7 C8 N1 179.38(16) . . . . ?
C6 C7 C8 C3 0.6(2) . . . . ?
C6 C12 C13 C14 -22.8(2) . . . . ?
C6 C12 C13 C18 157.43(16) . . . . ?
C6 C12 C19 C20 103.18(19) . . . . ?
C6 C12 C19 C24 -73.11(19) . . . . ?
C7 C6 C12 C13 101.35(18) . . . . ?
C7 C6 C12 C19 -25.3(2) . . . . ?
C8 N1 C1 C2 0.2(2) . . . . ?
C8 N1 C1 C9 -179.66(15) . . . . ?
C8 C3 C4 C5 1.4(2) . . . . ?
C9 C1 C2 C3 179.70(18) . . . . ?
C9 C1 C2 C10 -1.3(3) . . . . ?
C10 C2 C3 C4 2.0(3) . . . . ?
C10 C2 C3 C8 -179.04(18) . . . . ?
C12 C6 C7 C8 -175.78(15) . . . . ?
C12 C13 C14 C15 -179.65(17) . . . . ?
C12 C13 C18 C17 179.59(18) . . . . ?
C12 C13 C18 O1 -2.6(3) . . . . ?
C12 C19 C20 C21 -175.42(18) . . . . ?
C12 C19 C24 C23 175.09(17) . . . . ?
C12 C19 C24 O1' -5.0(3) . . . . ?
C13 C12 C19 C20 -22.4(2) . . . . ?
C13 C12 C19 C24 161.30(15) . . . . ?
C13 C14 C15 C16 -0.1(3) . . . . ?
C14 C13 C18 C17 -0.2(3) . . . . ?
C14 C13 C18 O1 177.58(19) . . . . ?
C14 C15 C16 C17 0.1(3) . . . . ?
C15 C16 C17 C18 -0.1(3) . . . . ?
C16 C17 C18 C13 0.2(3) . . . . ?
C16 C17 C18 O1 -177.5(2) . . . . ?
C18 C13 C14 C15 0.1(3) . . . . ?
C19 C12 C13 C14 102.81(18) . . . . ?
C19 C12 C13 C18 -77.0(2) . . . . ?
C19 C20 C21 C22 0.3(3) . . . . ?
C20 C19 C24 C23 -1.4(3) . . . . ?
C20 C19 C24 O1' 178.5(3) . . . . ?
C20 C21 C22 C23 -1.1(4) . . . . ?
C21 C22 C23 C24 0.6(4) . . . . ?
C22 C23 C24 C19 0.6(3) . . . . ?
C22 C23 C24 O1' -179.3(3) . . . . ?
C24 C19 C20 C21 0.9(3) . . . . ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
