# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2019

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1879132'
loop_
_audit_author_name
_audit_author_address
'Dr Prabusankar Ganesan'
;Indian Institute of Technology Hyderabad
India
;
_audit_update_record             
;
2018-11-15 deposited with the CCDC.	2019-02-18 downloaded from the CCDC.
;
_audit_creation_date             2018-07-11
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.18 svn.r3508 for OlexSys, GUI svn.r5497)
;
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C27 H29 Ag N5, F6 P'
_chemical_formula_sum            'C27 H29 Ag F6 N5 P'
_chemical_formula_weight         676.40
_chemical_oxdiff_formula         'C20 H20 N3 Ag'
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
C 0.01920 0.00962 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.215599998832
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
Ag 0.17563 4.27121 19.28080 16.68850 4.80450 1.04630 0.64460 7.47260 24.66050
99.81560 5.17899990082
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
F 0.07537 0.05506 3.53920 2.64120 1.51700 1.02430 10.28250 4.29440 0.26150
26.14760 0.277599990368
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.0030380000826
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
N 0.03256 0.01839 12.21260 3.13220 2.01250 1.16630 0.00570 9.89330 28.99750
0.58260 -11.5290002823
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'
P 0.30360 0.43703 6.43450 4.17910 1.78000 1.49080 1.90670 27.15700 0.52600
68.16450 1.11489999294
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Henke, Gullikson and Davis, At. Data and Nucl. Data Tables, 1993, 54, 2'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2ybc (x-z,y,z)'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x+1/2,y+1/2,-z+1/2
3 -x,-y,-z
4 x-1/2,-y-1/2,z-1/2

_symmetry_Int_Tables_number      14
_cell_length_a                   7.76382(19)
_cell_length_b                   15.1103(4)
_cell_length_c                   24.2613(6)
_cell_angle_alpha                90
_cell_angle_beta                 97.833(2)
_cell_angle_gamma                90
_cell_volume                     2819.63(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4866
_cell_measurement_temperature    298
_cell_measurement_theta_max      69.7460
_cell_measurement_theta_min      4.6790
_exptl_absorpt_coefficient_mu    6.864
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.55952
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.5933
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1374.3970
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_unetI/netI     0.0325
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            10683
_diffrn_reflns_theta_full        69.8721
_diffrn_reflns_theta_max         69.87
_diffrn_reflns_theta_min         3.45
_diffrn_ambient_temperature      298.0
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1293
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.9830
_diffrn_measured_fraction_theta_max 0.9830
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     13.00  65.00   1.00    1.00    --    0.00  57.00  90.00   52
  2  ω     38.00  64.00   1.00    1.75    --   54.00  57.00   0.00   26
  3  ω     70.00 120.00   1.00    1.75    --   54.00  57.00 -30.00   50
  4  ω     88.00 113.00   1.00    1.75    --   54.00  57.00   0.00   25
  5  ω     82.00 174.00   1.00    1.75    --  108.00  38.00  90.00   92
  6  ω    138.00 175.00   1.00    1.75    --  108.00 111.00  60.00   37
  7  ω    111.00 137.00   1.00    1.75    --  108.00 178.00  90.00   26
  8  ω    107.00 133.00   1.00    1.75    --  108.00 111.00 178.00   26
  9  ω     33.00  64.00   1.00    1.75    --   54.00  57.00 -30.00   31
 10  ω     47.00 131.00   1.00    1.75    --  108.00 -50.00 -90.00   84
 11  ω     52.00 123.00   1.00    1.75    --  108.00 -50.00   0.00   71
 12  ω     51.00 113.00   1.00    1.75    --  108.00-111.00-120.00   62
 13  ω     49.00  86.00   1.00    1.75    --   54.00 -77.00-180.00   37
 14  ω     -7.00  58.00   1.00    1.75    --   54.00 -77.00  30.00   65
 15  ω     49.00  86.00   1.00    1.75    --  108.00-111.00  60.00   37
 16  ω    -15.00  62.00   1.00    1.75    --   54.00 -77.00 150.00   77
 17  ω    -23.00  20.00   1.00    1.00    --    0.00 -57.00-120.00   43
 18  ω     62.00 147.00   1.00    1.75    --  108.00 178.00-120.00   85
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0329408000
_diffrn_orient_matrix_UB_12      -0.0714695000
_diffrn_orient_matrix_UB_13      -0.0425910000
_diffrn_orient_matrix_UB_21      0.0144846000
_diffrn_orient_matrix_UB_22      -0.0706970000
_diffrn_orient_matrix_UB_23      0.0461788000
_diffrn_orient_matrix_UB_31      -0.1970600000
_diffrn_orient_matrix_UB_32      -0.0170808000
_diffrn_orient_matrix_UB_33      -0.0126404000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              8
_reflns_limit_h_min              -9
_reflns_limit_k_max              18
_reflns_limit_k_min              0
_reflns_limit_l_max              29
_reflns_limit_l_min              -7
_reflns_number_gt                4326
_reflns_number_total             5251
_reflns_odcompleteness_completeness 99.75
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_threshold_expression     I>=2u(I)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine (Bourhis et al., 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         1.0574
_refine_diff_density_min         -0.6643
_refine_diff_density_rms         0.1000
_refine_ls_d_res_high            0.8211
_refine_ls_d_res_low             12.7923
_refine_ls_goodness_of_fit_ref   1.0462
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    48
_refine_ls_number_parameters     365
_refine_ls_number_reflns         5251
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0630
_refine_ls_R_factor_gt           0.0536
_refine_ls_restrained_S_all      1.0462
_refine_ls_shift/su_max          0.0001
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0992P)²+2.2882P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1528
_refine_ls_wR_factor_ref         0.1647
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C22(H22), C25(H25)
2.b Secondary CH2 refined with riding coordinates:
 C21(H21a,H21b), C7(H7a,H7b)
2.c Aromatic/amide H refined with riding coordinates:
 C9(H9), C10(H10), C11(H11), C18(H18), C17(H17), C16(H16), C14(H14), C5(H5),
 C6(H6), C3(H3), C2(H2)
2.d Idealised Me refined as rotating group:
 C23(H23a,H23b,H23c), C24(H24a,H24b,H24c), C26(H26a,H26b,H26c), C27(H27a,H27b,
 H27c)
;
_atom_sites_solution_primary     iterative
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_refinement_flags_posn
Ag1 Ag 0.14889(4) 0.73230(3) 0.562857(14) 0.05591(17) Uani 1.000000 .
N4 N 0.4006(5) 0.8238(3) 0.65404(17) 0.0628(11) Uani 1.000000 .
N1 N 0.0823(5) 0.7078(3) 0.43676(16) 0.0538(9) Uani 1.000000 .
N5 N 0.2959(4) 0.9087(3) 0.50831(15) 0.0494(8) Uani 1.000000 .
C4 C 0.2638(7) 0.7705(3) 0.6415(2) 0.0591(12) Uani 1.000000 .
N3 N 0.2106(7) 0.7495(4) 0.6902(2) 0.0758(14) Uani 1.000000 .
C20 C 0.2046(5) 0.9276(3) 0.4583(2) 0.0518(10) Uani 1.000000 .
C1 C 0.0275(6) 0.6913(3) 0.48585(19) 0.0520(10) Uani 1.000000 .
C12 C 0.2753(6) 1.0639(3) 0.5342(2) 0.0593(12) Uani 1.000000 .
C19 C 0.1716(6) 0.8590(4) 0.4170(2) 0.0573(11) Uani 1.000000 .
C13 C 0.3322(6) 0.9745(3) 0.5453(2) 0.0525(10) Uani 1.000000 .
C11 C 0.3226(8) 1.1307(4) 0.5746(3) 0.0760(16) Uani 1.000000 .
C5 C 0.3133(11) 0.7916(6) 0.7327(3) 0.101(2) Uani 1.000000 .
C6 C 0.4315(9) 0.8379(5) 0.7109(2) 0.092(2) Uani 1.000000 .
C10 C 0.4209(8) 1.1121(4) 0.6221(3) 0.0769(16) Uani 1.000000 .
C8 C 0.4363(6) 0.9568(3) 0.5975(2) 0.0563(11) Uani 1.000000 .
N2 N -0.1153(5) 0.6403(3) 0.47348(17) 0.0565(9) Uani 1.000000 .
C15 C 0.1427(6) 1.0153(4) 0.4439(2) 0.0593(12) Uani 1.000000 .
C22 C -0.2166(8) 0.6043(4) 0.5157(3) 0.0733(15) Uani 1.000000 .
C3 C -0.1472(7) 0.6251(4) 0.4174(2) 0.0700(14) Uani 1.000000 .
C14 C 0.1772(7) 1.0811(4) 0.4825(3) 0.0669(14) Uani 1.000000 .
C2 C -0.0223(7) 0.6662(4) 0.3943(2) 0.0689(14) Uani 1.000000 .
C9 C 0.4815(8) 1.0255(4) 0.6339(3) 0.0731(15) Uani 1.000000 .
C18 C 0.0894(7) 0.8805(5) 0.3656(2) 0.0734(15) Uani 1.000000 .
C17 C 0.0251(8) 0.9673(5) 0.3519(3) 0.0820(18) Uani 1.000000 .
C16 C 0.0515(7) 1.0324(5) 0.3901(3) 0.0758(17) Uani 1.000000 .
C23 C -0.3671(11) 0.6626(5) 0.5218(4) 0.115(3) Uani 1.000000 .
C24 C -0.2564(10) 0.5094(5) 0.5074(4) 0.107(3) Uani 1.000000 .
P1 P 0.3866(3) 0.5409(3) 0.31849(10) 0.1310(11) Uani 1.000000 .
F3 F 0.4331(10) 0.5780(8) 0.3760(3) 0.213(4) Uani 1.000000 .
F2 F 0.2787(18) 0.6281(11) 0.3092(4) 0.326(8) Uani 1.000000 .
F4 F 0.5522(8) 0.5676(6) 0.2965(3) 0.173(3) Uani 1.000000 .
F6 F 0.2241(10) 0.5003(9) 0.3440(4) 0.264(6) Uani 1.000000 .
F1 F 0.3136(15) 0.5233(14) 0.2636(5) 0.418(13) Uani 1.000000 .
F5 F 0.476(2) 0.4613(9) 0.3314(11) 0.490(16) Uani 1.000000 .
C21 C 0.2304(7) 0.7663(3) 0.4295(2) 0.0579(12) Uani 1.000000 .
C7 C 0.4975(6) 0.8647(4) 0.6130(2) 0.0600(12) Uani 1.000000 .
H9 H 0.5537(8) 1.0144(4) 0.6670(3) 0.0877(18) Uiso 1.000000 R
H10 H 0.4502(8) 1.1568(4) 0.6481(3) 0.0922(19) Uiso 1.000000 R
H11 H 0.2839(8) 1.1884(4) 0.5676(3) 0.091(2) Uiso 1.000000 R
H18 H 0.0745(7) 0.8368(5) 0.3384(2) 0.0881(19) Uiso 1.000000 R
H17 H -0.0347(8) 0.9789(5) 0.3167(3) 0.098(2) Uiso 1.000000 R
H16 H 0.0097(7) 1.0890(5) 0.3812(3) 0.091(2) Uiso 1.000000 R
H14 H 0.1350(7) 1.1379(4) 0.4743(3) 0.0803(17) Uiso 1.000000 R
H5 H 0.3017(11) 0.7882(6) 0.7703(3) 0.121(3) Uiso 1.000000 R
H6 H 0.5183(9) 0.8730(5) 0.7299(2) 0.110(3) Uiso 1.000000 R
H22 H -0.1397(8) 0.6082(4) 0.5511(3) 0.0880(18) Uiso 1.000000 R
H3 H -0.2387(7) 0.5923(4) 0.3989(2) 0.0840(17) Uiso 1.000000 R
H2 H -0.0089(7) 0.6665(4) 0.3568(2) 0.0827(17) Uiso 1.000000 R
H23a H -0.3257(11) 0.7196(17) 0.535(3) 0.172(5) Uiso 1.000000 GR
H23b H -0.438(5) 0.669(4) 0.4864(8) 0.172(5) Uiso 1.000000 GR
H23c H -0.435(6) 0.637(3) 0.548(2) 0.172(5) Uiso 1.000000 GR
H24a H -0.311(7) 0.4998(7) 0.4700(9) 0.160(4) Uiso 1.000000 GR
H24b H -0.1506(13) 0.4758(6) 0.514(3) 0.160(4) Uiso 1.000000 GR
H24c H -0.333(7) 0.4908(11) 0.5331(18) 0.160(4) Uiso 1.000000 GR
H21a H 0.3134(7) 0.7656(3) 0.4633(2) 0.0695(14) Uiso 1.000000 R
H21b H 0.2885(7) 0.7442(3) 0.3994(2) 0.0695(14) Uiso 1.000000 R
H7a H 0.6199(6) 0.8665(4) 0.6279(2) 0.0720(14) Uiso 1.000000 R
H7b H 0.4853(6) 0.8283(4) 0.5797(2) 0.0720(14) Uiso 1.000000 R
C25 C 0.0677(9) 0.6875(6) 0.6972(3) 0.097(2) Uani 1.000000 .
C26 C 0.1325(13) 0.6058(7) 0.7192(6) 0.158(5) Uani 1.000000 .
C27 C -0.0893(14) 0.7297(7) 0.7045(9) 0.242(11) Uani 1.000000 .
H25 H 0.0375(9) 0.6696(6) 0.6583(3) 0.117(3) Uiso 1.000000 R
H26a H 0.192(11) 0.576(3) 0.6923(16) 0.237(7) Uiso 1.000000 GR
H26b H 0.212(10) 0.6160(8) 0.753(2) 0.237(7) Uiso 1.000000 GR
H26c H 0.0377(19) 0.570(3) 0.728(4) 0.237(7) Uiso 1.000000 GR
H27a H -0.073(7) 0.7927(8) 0.704(8) 0.363(16) Uiso 1.000000 GR
H27b H -0.178(6) 0.713(10) 0.675(4) 0.363(16) Uiso 1.000000 GR
H27c H -0.124(13) 0.712(10) 0.739(4) 0.363(16) Uiso 1.000000 GR


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C4 2.074(5) . ?
Ag1 C1 2.069(5) . ?
N4 C4 1.335(7) . ?
N4 C6 1.383(7) . ?
N4 C7 1.464(6) . ?
N1 C1 1.341(6) . ?
N1 C2 1.375(6) . ?
N1 C21 1.480(7) . ?
N5 C20 1.349(6) . ?
N5 C13 1.343(6) . ?
C4 N3 1.343(7) . ?
N3 C5 1.371(9) . ?
N3 C25 1.480(9) . ?
C20 C19 1.440(7) . ?
C20 C15 1.437(7) . ?
C1 N2 1.350(6) . ?
C12 C13 1.435(7) . ?
C12 C11 1.421(8) . ?
C12 C14 1.401(8) . ?
C19 C18 1.360(7) . ?
C19 C21 1.492(7) . ?
C13 C8 1.433(7) . ?
C11 C10 1.323(9) . ?
C5 C6 1.321(9) . ?
C10 C9 1.407(9) . ?
C8 C9 1.376(8) . ?
C8 C7 1.501(8) . ?
N2 C22 1.477(7) . ?
N2 C3 1.368(7) . ?
C15 C14 1.366(8) . ?
C15 C16 1.422(8) . ?
C22 C23 1.487(9) . ?
C22 C24 1.475(10) . ?
C3 C2 1.338(8) . ?
C18 C17 1.428(9) . ?
C17 C16 1.348(10) . ?
P1 F3 1.501(8) . ?
P1 F2 1.562(13) . ?
P1 F4 1.512(6) . ?
P1 F6 1.601(8) . ?
P1 F1 1.399(9) . ?
P1 F5 1.403(11) . ?
C25 C26 1.410(12) . ?
C25 C27 1.408(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 C4 177.80(19) . . ?
C6 N4 C4 110.2(5) . . ?
C7 N4 C4 124.4(4) . . ?
C7 N4 C6 125.3(5) . . ?
C2 N1 C1 110.7(4) . . ?
C21 N1 C1 124.2(4) . . ?
C21 N1 C2 125.0(4) . . ?
C13 N5 C20 118.7(4) . . ?
N4 C4 Ag1 127.4(4) . . ?
N3 C4 Ag1 126.8(4) . . ?
N3 C4 N4 105.8(5) . . ?
C5 N3 C4 109.6(5) . . ?
C25 N3 C4 125.2(6) . . ?
C25 N3 C5 125.2(6) . . ?
C19 C20 N5 119.6(4) . . ?
C15 C20 N5 122.1(5) . . ?
C15 C20 C19 118.2(4) . . ?
N1 C1 Ag1 125.8(3) . . ?
N2 C1 Ag1 129.1(3) . . ?
N2 C1 N1 105.0(4) . . ?
C11 C12 C13 119.7(5) . . ?
C14 C12 C13 117.3(5) . . ?
C14 C12 C11 123.0(5) . . ?
C18 C19 C20 118.9(5) . . ?
C21 C19 C20 120.9(4) . . ?
C21 C19 C18 120.1(5) . . ?
C12 C13 N5 122.7(5) . . ?
C8 C13 N5 119.6(4) . . ?
C8 C13 C12 117.6(5) . . ?
C10 C11 C12 120.9(6) . . ?
C6 C5 N3 108.0(6) . . ?
C5 C6 N4 106.4(6) . . ?
C9 C10 C11 120.8(6) . . ?
C9 C8 C13 119.4(5) . . ?
C7 C8 C13 121.0(4) . . ?
C7 C8 C9 119.7(5) . . ?
C22 N2 C1 123.7(4) . . ?
C3 N2 C1 110.4(4) . . ?
C3 N2 C22 125.8(5) . . ?
C14 C15 C20 118.5(5) . . ?
C16 C15 C20 119.9(6) . . ?
C16 C15 C14 121.6(5) . . ?
C23 C22 N2 110.6(5) . . ?
C24 C22 N2 112.7(5) . . ?
C24 C22 C23 115.8(6) . . ?
C2 C3 N2 107.2(5) . . ?
C15 C14 C12 120.7(5) . . ?
C3 C2 N1 106.6(5) . . ?
C8 C9 C10 121.5(6) . . ?
C17 C18 C19 122.6(6) . . ?
C16 C17 C18 119.6(5) . . ?
C17 C16 C15 120.6(6) . . ?
F2 P1 F3 82.8(6) . . ?
F4 P1 F3 96.9(4) . . ?
F4 P1 F2 100.9(7) . . ?
F6 P1 F3 83.5(4) . . ?
F6 P1 F2 86.8(7) . . ?
F6 P1 F4 172.3(7) . . ?
F1 P1 F3 165.8(9) . . ?
F1 P1 F2 83.3(9) . . ?
F1 P1 F4 88.2(6) . . ?
F1 P1 F6 93.2(7) . . ?
F5 P1 F3 93.6(11) . . ?
F5 P1 F2 174.6(8) . . ?
F5 P1 F4 83.6(5) . . ?
F5 P1 F6 88.8(7) . . ?
F5 P1 F1 100.1(13) . . ?
C19 C21 N1 111.4(4) . . ?
C8 C7 N4 112.7(4) . . ?
C26 C25 N3 111.3(7) . . ?
C27 C25 N3 113.7(8) . . ?
C27 C25 C26 128.3(9) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.772
_oxdiff_exptl_absorpt_empirical_full_min 0.690
