63
cis-[(dmpe)2Mn(SiH2Ph)] (cis-2Ph) rotamer 1
  Mn        4.922028    8.504958    3.719699
  P         3.519420   10.115049    4.265286
  P         6.278914    6.838193    3.145529
  P         6.724215    9.566159    4.261283
  P         4.399814    7.663650    5.667257
  Si        4.891878    9.412180    1.560972
  C         3.584155    7.397890   -0.269883
  H         4.003892    7.881255   -1.154567
  H         4.220908   10.731734    1.219054
  C         3.754177    7.995685    0.986567
  H         6.678385    4.403051    3.251192
  H         5.572895    4.944295    4.549387
  C         8.262229    8.518376    3.964418
  H         8.611968    8.767531    2.951410
  H         9.060294    8.799691    4.666616
  C         3.238274    7.308056    2.105981
  H         3.238175    7.785296    3.126478
  H         4.976583    4.805782    2.880033
  C         2.981883    6.454893    5.739322
  H         2.102177    6.896835    5.253392
  H         2.722040    6.183309    6.772415
  C         3.731109    8.985139    6.815610
  H         3.213761    8.527158    7.672076
  H         4.600927    9.532559    7.204148
  C         7.896749    7.041396    4.041883
  H         7.735276    6.728817    5.082825
  H         8.670790    6.391931    3.606827
  H         3.252480    5.546856    5.185952
  C         2.385539    5.534423    0.718699
  H         1.849906    4.590658    0.607702
  H         6.048004    9.438435    0.579945
  C         3.974822   11.907611    4.282026
  H         4.799392   12.083256    4.983028
  H         3.114270   12.519818    4.583612
  H         4.292745   12.203172    3.274775
  C         2.560191    6.093479    1.988024
  H         2.169824    5.587710    2.872224
  C         2.899077    6.185890   -0.405588
  H         2.766441    5.742254   -1.394034
  C         7.072559   10.179194    5.984960
  H         6.308454   10.909918    6.279772
  H         8.059315   10.659381    6.042481
  H         7.040199    9.348158    6.698966
  C         6.885563    6.590879    1.415459
  H         6.032900    6.363763    0.763719
  H         7.609197    5.765770    1.367634
  H         7.348370    7.513587    1.046397
  C         7.280072   11.089316    3.360979
  H         7.274528   10.888589    2.282113
  H         8.295919   11.373042    3.671931
  H         6.601724   11.925698    3.559821
  C         1.926562   10.266052    3.330169
  H         2.138321   10.551499    2.292135
  H         1.274067   11.020743    3.790325
  H         1.409186    9.298522    3.321111
  C         5.520389    6.788236    6.862411
  H         5.837943    5.821526    6.453665
  H         5.004459    6.611204    7.816703
  H         6.418289    7.387837    7.051869
  C         2.822225    9.903130    6.010075
  H         2.675604   10.882236    6.487641
  H         1.828079    9.446670    5.893682
  C         5.844240    5.075203    3.496092

63
cis-[(dmpe)2Mn(SiH2Ph)] (cis-2Ph) rotamer 2
   Mn        4.887122    8.647360    3.848117
   P         3.667692   10.301423    4.609637
   P         6.153745    6.990909    3.111164
   P         6.759024    9.598712    4.276922
   P         4.431689    7.739782    5.769313
   Si        4.441382    9.216892    1.611987
   H         4.718529    5.092670    2.578150
   C         3.006908    6.551934    5.592317
   C         3.222729   10.532438    0.958330
   H         3.734093    7.950974    1.112477
   C         3.621133   11.848133    0.663915
   H         4.670790   12.131438    0.783969
   C         8.232356    8.409329    4.177723
   H         8.796974    8.674211    3.272333
   H         8.901221    8.569028    5.034447
   H         5.321277    4.978349    4.249127
   H         6.391357    4.546334    2.883370
   C         0.951219   11.164134    0.297574
   H        -0.092720   10.883358    0.144995
   C         1.867160   10.216583    0.756763
   H         1.524733    9.196518    0.949296
   C         3.692548    8.937339    7.038464
   H         2.668044    8.599395    7.249350
   H         4.255544    8.860524    7.978397
   C         7.735630    6.971092    4.090496
   H         7.495890    6.577935    5.086116
   H         8.474643    6.300437    3.627687
   C         2.714059   12.804123    0.203908
   H         3.055462   13.816192   -0.021525
   C         1.371526   12.466151    0.022297
   H         0.660706   13.209254   -0.341541
   C         3.937859   12.085086    4.242197
   H         4.970084   12.364762    4.484847
   H         3.252401   12.707142    4.834867
   H         3.762034   12.270391    3.176385
   H         2.193967    7.039196    5.038445
   H         2.626275    6.234359    6.573511
   H         3.319966    5.667475    5.025312
   H         5.582443    9.374151    0.629039
   C         7.165222   10.455653    5.873169
   H         6.559908   11.363902    5.981298
   H         8.226107   10.741034    5.900257
   H         6.949733    9.791575    6.719984
   C         6.866223    6.923031    1.404467
   H         6.059732    6.854969    0.664309
   H         7.535391    6.058391    1.297804
   H         7.422773    7.844717    1.197300
   C         7.365174   10.910321    3.117564
   H         7.341390   10.508405    2.097210
   H         8.387197   11.230396    3.367810
   H         6.695457   11.777940    3.152403
   C         1.839195   10.214863    4.325453
   H         1.631051   10.353740    3.258354
   H         1.317610   10.992994    4.900199
   H         1.458199    9.231779    4.630014
   C         5.489880    6.717288    6.897794
   H         5.833172    5.811705    6.382532
   H         4.929933    6.419866    7.795575
   H         6.370822    7.296809    7.202739
   C         3.694197   10.357075    6.483573
   H         4.616805   10.879909    6.764951
   H         2.850818   10.954658    6.858820
   C         5.599194    5.229886    3.219125

65
cis-[(dmpe)2Mn(SiH2nBu)] (cis-2Bu)
Mn       4.89108535       8.54024141       3.76619858
P       3.55743473      10.19228120       4.37068890
P       6.21181443       6.86913175       3.15228345
P       6.73043036       9.57090991       4.24306292
P       4.41363237       7.71866589       5.73139506
Si       4.75422379       9.44617775       1.61242789
H       1.38921107      11.30231773       4.01620372
H       1.29306393       9.56440124       3.63930603
H       4.18976194      10.83869985       1.36632608
H       3.99210713       7.47231073       0.28254176
H       6.59891751       4.42871787       3.24360574
H       5.51882754       4.97339289       4.56059572
C       8.24667001       8.49586368       3.92655904
H       8.58855992       8.73680272       2.90939052
H       9.05753026       8.76341398       4.61860377
H       6.44601792       7.36589908       7.06869028
H       5.03007962       6.61290544       7.85212780
H       4.89271262       4.82614399       2.90743460
C       2.94709698       6.57230791       5.82019839
H       2.08683624       7.05037775       5.33484896
H       2.68166282       6.31549401       6.85534141
C       3.83645357       9.05285621       6.91289800
H       3.33384647       8.60668950       7.78384280
H       4.74010770       9.56217679       7.27377832
C       7.85297645       7.02928626       4.01112809
H       7.70529987       6.71789091       5.05407095
H       8.59975987       6.36183598       3.55667831
H       3.17303120       5.65143264       5.26821434
C       2.93559785      10.01100746       6.14922974
H       2.85767176      10.99623673       6.62959927
H       5.90586285       9.46693504       0.62206550
C       4.09751275      11.96187762       4.37108833
H       4.97043707      12.09609071       5.01920900
H       3.28603767      12.60877903       4.72950776
H       4.36397881      12.24943373       3.34709280
H       1.91712879       9.60167530       6.08281794
C       5.77137381       5.10338123       3.50285902
C       5.52977346       6.79109380       6.88971730
H       5.81470720       5.82343952       6.46072160
C       7.14520330      10.19450914       5.94881545
H       6.39999692      10.93170868       6.27203995
H       8.13760339      10.66542481       5.96782166
H       7.13284652       9.36393035       6.66426736
C       6.78471335       6.61987596       1.40772251
H       5.92518283       6.36363905       0.77618370
H       7.52783509       5.81346723       1.34345631
H       7.20914311       7.55267695       1.01942080
C       7.29237478      11.06333187       3.29725835
H       7.23381984      10.84445409       2.22372055
H       8.32889727      11.31662245       3.56136565
H       6.65175220      11.92515477       3.50767091
C       1.91591590      10.46168615       3.54491323
H       2.06712215      10.68099955       2.48097243
C       3.46167236       8.18455507       0.93485649
H       3.68502359       7.29775269       2.95278813
H       2.65689039       8.61940358       0.32477162
C       2.88991994       7.43611322       2.15080668
H       2.07669027       8.01109306       2.60670780
H       3.22115994       5.42365189       1.44696412
C       2.39260278       6.01252624       1.87343792
H       2.11603195       5.52575654       2.82209468
H       0.35264240       6.54252709       1.32499679
C       1.20470398       5.98184868       0.91430668
H       1.46448906       6.43159589      -0.05285426
H       0.87143752       4.95224475       0.72824493

59
cis-[(dmpe)2Mn(SiH2Et)] (cis-2Et)
  Mn        4.877321    8.542832    3.766827
  P         3.567678   10.205674    4.385543
  P         6.195626    6.880624    3.130997
  P         6.723169    9.560565    4.236382
  P         4.421542    7.725740    5.738435
  Si        4.699467    9.415986    1.597936
  H         1.397465   11.325193    4.069750
  H         1.278817    9.581819    3.726387
  H         4.089669   10.785682    1.333319
  H         3.983223    7.353552    0.384005
  H         6.521365    4.426409    3.154517
  H         5.426959    4.963200    4.465294
  C         8.236135    8.462362    3.968779
  H         8.621525    8.701565    2.966727
  H         9.024059    8.715126    4.692484
  H         6.464643    7.340838    7.052759
  H         5.047836    6.597786    7.845604
  H         4.834641    4.883078    2.792661
  C         2.940615    6.598924    5.844658
  H         2.077077    7.092076    5.380300
  H         2.692901    6.338100    6.883467
  C         3.878439    9.065669    6.931435
  H         3.374259    8.622698    7.803474
  H         4.794109    9.555184    7.289442
  C         7.818305    6.999542    4.032449
  H         7.643403    6.681248    5.068740
  H         8.565404    6.325764    3.587296
  H         3.142224    5.678712    5.281391
  C         2.988049   10.047729    6.183005
  H         2.951185   11.036647    6.661291
  H         5.838460    9.447853    0.594870
  C         4.114820   11.973234    4.344113
  H         5.008373   12.114991    4.962107
  H         3.316775   12.628935    4.717458
  H         4.350147   12.243473    3.307350
  H         1.956192    9.669004    6.143721
  C         5.707425    5.116593    3.416977
  C         5.539501    6.777791    6.879027
  H         5.807625    5.809871    6.438158
  C         7.130086   10.221788    5.930247
  H         6.384034   10.964601    6.238941
  H         8.122749   10.693067    5.941485
  H         7.117858    9.404188    6.661286
  C         6.826408    6.673311    1.399867
  H         5.989492    6.450424    0.726723
  H         7.559637    5.856984    1.341716
  H         7.281556    7.609415    1.056234
  C         7.302240   11.022001    3.252765
  H         7.251739   10.768862    2.186068
  H         8.336860   11.282456    3.518781
  H         6.659790   11.890708    3.429270
  C         1.905775   10.472614    3.598965
  H         2.029898   10.672678    2.527425
  C         3.433085    8.098618    0.977896
  H         3.640450    7.252289    3.037580
  H         2.626237    8.472930    0.330199
  C         2.855861    7.437608    2.240175
  H         2.047726    8.024162    2.682867
  H         2.465674    6.419456    2.073815

56
cis-[(dmpe)2Mn(SiH2Me)] (cis-2Me) rotamer 1
  Mn        9.804740   -0.909039    4.598924
  P        10.615952   -0.723874    2.574297
  P        11.250782   -2.520080    4.809314
  Si        8.812769    1.182083    4.229610
  H         7.427844    1.474078    4.781166
  H         8.660015   -3.589267    2.243576
  H         7.175276   -4.138010    3.068264
  H         8.774813   -4.408902    3.815810
  C         7.075237   -2.546329    5.606523
  H         6.272745   -1.800069    5.699301
  H         6.597218   -3.525273    5.460495
  C        11.871307   -2.083312    2.150367
  H        11.731851   -2.414895    1.112372
  H        12.867825   -1.623266    2.211119
  C         9.591185   -0.699424    1.038459
  H         9.045845   -1.645234    0.938496
  H        10.226048   -0.558375    0.153507
  H         8.871891    0.125051    1.108344
  C        11.664925    0.766618    2.229917
  H        11.026815    1.658489    2.211620
  H        12.184262    0.669671    1.266548
  H        12.410044    0.885796    3.027108
  C         6.704621   -1.337995    3.069728
  H         6.417746   -0.372190    3.503672
  H         5.833293   -2.008130    3.054427
  H         7.039616   -1.164526    2.041504
  C        11.139149   -4.098954    5.776344
  H        11.054874   -3.886291    6.848646
  H        12.027422   -4.724446    5.610484
  H        10.248553   -4.660984    5.470103
  C        11.756720   -3.227274    3.149316
  H        12.692178   -3.798578    3.242162
  H        10.965412   -3.930453    2.857092
  C        12.914595   -1.942566    5.423842
  H        13.253881   -1.093013    4.817367
  H        13.668393   -2.740780    5.371398
  H        12.825765   -1.601257    6.462461
  H         8.620862    1.699879    2.808612
  H         9.495799    3.543348    4.866694
  H         7.397305   -2.479574    7.775765
  C        10.206532   -1.165762    8.112625
  H        10.893024   -2.004498    7.952632
  H         9.659562   -1.319488    9.053003
  H        10.802308   -0.247665    8.200598
  C         7.919796    0.266936    7.432689
  H         8.432568    1.234868    7.491495
  H         7.607476   -0.038161    8.440547
  H         7.039077    0.405842    6.795989
  C         8.175486   -3.709643    3.220740
  P         9.047429   -0.993856    6.677222
  P         8.076717   -2.063393    4.081085
  C         7.972071   -2.506091    6.838255
  H         8.639027   -3.377808    6.869350
  C         9.920290    2.543066    5.031518
  H        10.017546    2.390337    6.115539
  H        10.934063    2.534637    4.607280

56
cis-[(dmpe)2Mn(SiH2Me)] (cis-2Me) rotamer 2
  Mn        9.976868   -0.877126    4.593115
  P        10.707710   -0.785436    2.519509
  P        11.297528   -2.607564    4.737052
  Si        9.272094    1.310788    4.207467
  H         9.185073    1.815163    2.771997
  H         8.478981   -3.452137    2.316054
  H         6.998666   -3.869758    3.223186
  H         8.607122   -4.281796    3.882133
  C         7.182870   -2.282396    5.758246
  H         6.474417   -1.454727    5.912258
  H         6.591756   -3.201209    5.633980
  C        11.791303   -2.266580    2.039973
  H        11.552003   -2.592288    1.018253
  H        12.829783   -1.905963    2.029357
  C         9.613566   -0.665156    1.035876
  H         8.968670   -1.550446    0.976388
  H        10.214290   -0.599711    0.118584
  H         8.988815    0.231146    1.128590
  C        11.898999    0.578218    2.120291
  H        11.377865    1.542018    2.164838
  H        12.334827    0.436354    1.121374
  H        12.702749    0.585316    2.867875
  C         6.777842   -1.043250    3.237425
  H         6.576876   -0.067813    3.696248
  H         5.859100   -1.647672    3.246585
  H         7.085261   -0.874570    2.199328
  C        11.084550   -4.173000    5.713715
  H        11.072427   -3.968000    6.790432
  H        11.903591   -4.874142    5.499667
  H        10.133501   -4.650525    5.447225
  C        11.629633   -3.381440    3.063653
  H        12.510207   -4.039353    3.112124
  H        10.757870   -4.008392    2.832877
  C        13.046735   -2.206633    5.246339
  H        13.435821   -1.405317    4.604660
  H        13.708074   -3.081498    5.167743
  H        13.055446   -1.841553    6.280888
  H        10.570448    1.992454    4.676118
  H         7.794745    3.323486    4.447061
  H         7.652803   -2.299128    7.902961
  C        10.605815   -1.281522    8.064241
  H        11.223058   -2.154832    7.828423
  H        10.110141   -1.439668    9.032364
  H        11.267483   -0.408882    8.148270
  C         8.435667    0.370974    7.615574
  H         9.044091    1.283214    7.647818
  H         8.197726    0.059392    8.642351
  H         7.509608    0.603219    7.078746
  C         8.039768   -3.530920    3.318940
  P         9.368913   -0.957642    6.720486
  P         8.136123   -1.882875    4.179186
  C         8.158645   -2.361524    6.927898
  H         8.731479   -3.297982    6.899509
  C         7.873933    2.371414    4.989687
  H         6.895697    1.871948    4.921726
  H         8.056564    2.598673    6.046335

63
trans-[(dmpe)2Mn(SiH2Ph)] (trans-2Ph)
  Mn       11.960432    2.263162    4.265364
  P        13.375387    2.391958    5.931649
  H        13.233051   -3.000392    9.007518
  H        14.869760   -2.651435    7.162120
  Si       11.659848    0.004960    4.256456
  H         8.963487    0.575285    2.709616
  H        15.303654    3.557471    1.683959
  H        15.414934    3.575014    3.465214
  H         8.197507    2.145560    3.050863
  C        13.832780    4.156998    6.319896
  C        15.053675    1.643234    6.082390
  C        12.635416    1.846464    7.550661
  H        14.165727    4.543872    2.648406
  H        14.192010   -0.148151    2.416744
  H         8.563806    1.694950    1.363861
  H        11.363371    0.619755    1.114857
  H        14.474289    4.209905    7.210790
  H        14.367082    4.599986    5.470118
  H        12.927959    4.749603    6.502562
  H        14.977570    0.557052    5.962394
  H        15.720804    2.046144    5.310709
  H        15.482691    1.863313    7.069914
  H        12.827062    0.767561    7.614083
  H        13.164794    2.330282    8.384064
  H        12.291546   -0.792727    3.118957
  P        10.464167    2.483790    5.845082
  P        10.585618    2.384111    2.567536
  P        13.536103    2.170156    2.731955
  H        13.463357    1.643475    0.299537
  H        15.326391    0.685664    3.499642
  H        10.823332    2.002817    0.128329
  C        11.133301    2.123417    7.575408
  C         9.868046    4.235808    6.077141
  C         8.816829    1.653245    5.937849
  C        10.171006    4.114989    2.019187
  C         8.913646    1.626972    2.403070
  C        11.393293    1.716107    1.024668
  C        14.721042    3.597093    2.615272
  C        14.746122    0.784255    2.575766
  C        12.828897    2.217163    0.989795
  H        12.857462    3.268249    0.664698
  H        15.428404    0.961429    1.733139
  H        10.586956    1.258155    7.971773
  H        10.890352    2.983862    8.214081
  H         9.225618    4.324594    6.964860
  H         9.296408    4.544641    5.192671
  H        10.721183    4.916942    6.188233
  H         8.922688    0.589671    5.695677
  H         8.135528    2.103616    5.206859
  H         8.385043    1.768709    6.941240
  H         9.640985    4.113776    1.056031
  H         9.531057    4.588501    2.774637
  H        11.085711    4.713859    1.924507
  H        14.197778   -1.438592    5.115447
  H        10.212892   -0.466883    4.130494
  C        12.171569   -1.055656    5.763723
  C        11.261723   -1.301282    6.807808
  C        11.632908   -1.987172    7.964291
  C        12.938220   -2.461304    8.106326
  C        13.854672   -2.259653    7.072442
  C        13.471006   -1.568488    5.921907
  H        10.230017   -0.956191    6.708841
  H        10.899993   -2.161096    8.754709

65
trans-[(dmpe)2Mn(SiH2nBu)] (trans-2Bu)
  Mn       11.998730    2.308199    4.247066
  P        13.383056    2.128516    5.934639
  H        11.912039   -1.932403    2.747397
  H        14.536265   -1.142545    4.141437
  Si       11.676719    0.040136    4.254905
  H         8.871718    0.785810    2.850705
  H        14.757865    4.145203    1.489102
  H        14.794526    4.355393    3.262366
  H         8.235791    2.420143    3.187191
  C        14.320580    3.678610    6.372708
  C        14.740415    0.897679    6.146152
  C        12.459483    1.824937    7.526924
  H        13.334551    4.794685    2.350383
  H        14.975256    0.386566    2.665285
  H         8.473658    1.897475    1.498745
  H        11.146205    0.589783    1.183943
  H        14.821128    3.587970    7.347119
  H        15.077854    3.873366    5.602785
  H        13.636284    4.536280    6.399536
  H        14.310113   -0.108710    6.092455
  H        15.487756    1.000843    5.352728
  H        15.229598    1.031280    7.120735
  H        12.206423    0.754405    7.527834
  H        13.101389    2.027459    8.396865
  H        10.241520   -0.406149    3.978598
  P        10.450953    2.574115    5.790452
  P        10.603470    2.474195    2.577685
  P        13.505485    2.348566    2.663432
  H        13.361224    1.148906    0.504617
  H        15.785189    1.811090    3.363873
  H        10.753344    1.979874    0.150994
  C        11.199927    2.677207    7.509519
  C         9.455499    4.143091    5.786824
  C         9.094151    1.360564    6.105763
  C        10.269692    4.193042    1.930101
  C         8.875550    1.830760    2.518554
  C        11.308247    1.668038    1.047431
  C        14.162207    4.077550    2.410290
  C        15.126403    1.465498    2.558283
  C        12.799394    1.981652    0.948304
  H        12.976434    2.863539    0.316686
  H        15.612362    1.671323    1.594395
  H        10.468226    2.373394    8.271396
  H        11.446558    3.734611    7.689554
  H         8.884184    4.258631    6.718473
  H         8.756073    4.133563    4.941438
  H        10.126241    5.003883    5.669111
  H         9.539270    0.388011    6.349110
  H         8.483942    1.229737    5.206548
  H         8.461145    1.699300    6.936778
  H         9.605244    4.168866    1.054989
  H         9.800136    4.796368    2.717286
  H        11.211230    4.678214    1.645289
  H        11.879673   -0.660267    5.604632
  C        12.637346   -1.173267    3.084901
  H        12.956597   -0.644038    2.171077
  C        13.839889   -1.880906    3.710744
  H        13.494431   -2.485232    4.565695
  H        15.003895   -2.154432    1.914943
  C        14.622804   -2.772713    2.745393
  H        16.352699   -4.112992    2.697766
  H        13.933882   -3.500274    2.286838
  C        15.782399   -3.507001    3.414876
  H        16.480796   -2.798107    3.883879
  H        15.417623   -4.179121    4.204996

59
trans-[(dmpe)2Mn(SiH2Et)] (trans-2Et)
  Mn       12.000888    2.313325    4.243215
  P        13.387017    2.131465    5.926402
  H        11.931484   -1.946751    2.789178
  H        14.654223   -1.168583    4.028639
  Si       11.693357    0.045969    4.246076
  H         8.874273    0.786225    2.845487
  H        14.744122    4.183538    1.490494
  H        14.787483    4.381409    3.265518
  H         8.234322    2.419464    3.185070
  C        14.315276    3.684311    6.379982
  C        14.752038    0.906554    6.122731
  C        12.467300    1.808771    7.519046
  H        13.321628    4.822212    2.362555
  H        14.982950    0.418024    2.629166
  H         8.474700    1.900470    1.495275
  H        11.157449    0.601472    1.178327
  H        14.820737    3.585711    7.351309
  H        15.067650    3.895122    5.608925
  H        13.623702    4.535971    6.420457
  H        14.330479   -0.102337    6.044878
  H        15.503810    1.032713    5.336143
  H        15.234665    1.024048    7.103023
  H        12.222446    0.736136    7.512256
  H        13.109137    2.010605    8.389399
  H        10.262242   -0.402362    3.947417
  P        10.452660    2.562284    5.788862
  P        10.602878    2.479305    2.576175
  P        13.504092    2.372916    2.658593
  H        13.366673    1.185436    0.491097
  H        15.788100    1.835068    3.350730
  H        10.748975    1.990184    0.147942
  C        11.200453    2.651748    7.509397
  C         9.453646    4.129362    5.797805
  C         9.097340    1.342806    6.092086
  C        10.264089    4.200760    1.935175
  C         8.875782    1.832238    2.515819
  C        11.309038    1.681882    1.043105
  C        14.152292    4.107224    2.413786
  C        15.130091    1.499315    2.539913
  C        12.797786    2.010217    0.940916
  H        12.964633    2.898043    0.314480
  H        15.614212    1.722923    1.578852
  H        10.470455    2.333671    8.267750
  H        11.438584    3.709450    7.701591
  H         8.881677    4.235689    6.730715
  H         8.754093    4.125962    4.952025
  H        10.122723    4.993086    5.687992
  H         9.544463    0.368107    6.323989
  H         8.485164    1.221885    5.192594
  H         8.465459    1.671966    6.928434
  H         9.597980    4.177980    1.060834
  H         9.794677    4.800809    2.725333
  H        11.204467    4.688809    1.650128
  H        11.875900   -0.653114    5.600486
  C        12.664254   -1.183956    3.098453
  H        12.969965   -0.675473    2.168859
  C        13.870578   -1.881423    3.734235
  H        13.571820   -2.416769    4.647008
  H        14.336511   -2.613850    3.056414

56
trans-[(dmpe)2Mn(SiH2Me)] (trans-2Me)
  Mn       12.114362    2.302777    4.211976
  P        13.606615    2.366778    5.799884
  H        10.521348   -0.508618    3.898709
  H        13.557447   -1.057925    5.778927
  H        12.305173   -2.193008    5.237660
  H         9.068292    0.585094    2.793993
  H        15.158346    3.896411    1.452995
  H        15.435362    3.823977    3.214142
  H         8.305701    2.114237    3.307211
  C        14.175000    4.093885    6.218282
  C        15.245078    1.518959    5.868712
  C        12.888022    1.871030    7.452463
  H        14.061041    4.756505    2.573795
  H        14.391963    0.086052    2.148793
  H         8.510173    1.771662    1.567338
  H        11.366101    0.728952    1.074904
  H        14.812772    4.100005    7.113408
  H        14.739823    4.510232    5.375193
  H        13.305638    4.739597    6.396580
  H        15.122501    0.456213    5.631076
  H        15.924704    1.965535    5.131988
  H        15.694688    1.618714    6.866333
  H        12.865196    0.773661    7.470198
  H        13.536501    2.212701    8.272320
  H        12.608774   -0.662432    2.919421
  P        10.653697    2.357472    5.848828
  P        10.630409    2.436844    2.612503
  P        13.586231    2.339556    2.577845
  H        13.366395    1.847726    0.145060
  H        15.544143    0.984763    3.157863
  H        10.708083    2.109002    0.154847
  C        11.484578    2.453361    7.537147
  C         9.550624    3.849272    5.972395
  C         9.381038    1.057230    6.169812
  C        10.145568    4.172123    2.137473
  C         8.963291    1.651613    2.561034
  C        11.347117    1.827122    1.005753
  C        14.663998    3.849510    2.433432
  C        14.883080    1.056053    2.287328
  C        12.758219    2.385630    0.884840
  H        12.724599    3.441492    0.577139
  H        15.477051    1.307378    1.398434
  H        10.865241    1.957120    8.298599
  H        11.531778    3.520722    7.801809
  H         9.043177    3.896477    6.947089
  H         8.790836    3.809493    5.181015
  H        10.144409    4.762435    5.833508
  H         9.875073    0.096958    6.357021
  H         8.739202    0.932790    5.291206
  H         8.767653    1.331776    7.039607
  H         9.531712    4.180455    1.225197
  H         9.572686    4.625359    2.955942
  H        11.042225    4.782754    1.970793
  Si       11.938351    0.022528    4.110598
  C        12.489513   -1.150285    5.535146
  H        11.924374   -0.967827    6.461455

63
cis-[(dmpe)2MnH(=SiHPh)] (cis-3Ph,H)
  Mn        9.895930   -0.896876    4.551397
  P        10.542544   -0.891570    2.451527
  P        11.518010   -2.342489    4.793459
  Si        9.623840    1.264986    4.412109
  H         9.931209    2.156003    3.214258
  H         8.375323   -3.404984    2.035565
  H         7.172010   -4.163348    3.107221
  H         8.919533   -4.371515    3.425579
  C         7.359324   -2.864799    5.703972
  H         6.427001   -2.307978    5.873535
  H         7.084886   -3.915166    5.538114
  C        11.343457   -2.517416    1.995478
  H        10.541701   -3.254952    1.867738
  H        11.878764   -2.430683    1.038622
  C         9.432926   -0.608521    1.004333
  H         8.622700   -1.346614    0.994852
  H         9.987467   -0.676509    0.058745
  H         8.989571    0.391167    1.093082
  C        11.925123    0.247041    1.977066
  H        11.597392    1.286670    2.093956
  H        12.245231    0.077035    0.940233
  H        12.772509    0.082976    2.653618
  C         6.673909   -1.310487    3.411983
  H         6.423062   -0.453109    4.047379
  H         5.813115   -1.991321    3.342508
  H         6.918372   -0.927289    2.415078
  C        11.386477   -3.990176    5.645558
  H        11.189438   -3.847599    6.715016
  H        12.317527   -4.563087    5.536266
  H        10.557659   -4.567002    5.216647
  C        12.264681   -2.909380    3.143853
  H        13.235520   -2.403653    3.043749
  H        12.463744   -3.989026    3.172505
  C        13.071014   -1.754524    5.621405
  H        13.405129   -0.839783    5.116804
  H        13.868851   -2.509796    5.581672
  H        12.862467   -1.503457    6.667874
  H        11.014940    0.460625    4.898601
  C         9.511318    2.614612    5.741910
  C         8.373902    4.567866    6.666829
  H         7.592150    5.324850    6.586736
  C         8.522069    3.610672    5.663480
  H         7.848109    3.638009    4.802967
  C        10.364487    2.632148    6.858946
  H        11.150961    1.878629    6.939913
  C         9.228371    4.561673    7.771964
  H         9.117157    5.311263    8.555954
  C        10.231396    3.594715    7.860494
  H        10.912352    3.591876    8.713219
  P         9.195950   -1.062052    6.648470
  P         8.157303   -2.147094    4.144604
  C         8.305950   -2.686804    6.883266
  H         9.063834   -3.479050    6.897591
  H         7.780592   -2.701825    7.849180
  C        10.315077   -1.067512    8.120687
  H        11.072372   -1.853041    8.015194
  H         9.748625   -1.238374    9.046399
  H        10.826266   -0.100112    8.190762
  C         7.875863    0.057757    7.308916
  H         8.263052    1.076758    7.407711
  H         7.514747   -0.292336    8.285784
  H         7.042538    0.083908    6.596486
  C         8.152527   -3.669212    3.076227

65
cis-[(dmpe)2MnH(=SiHnBu)] (cis-3Bu,H)
Mn       9.74109366      -0.86542722       4.47102311
P      10.38651711      -0.91620162       2.36957813
P      11.35715049      -2.30728576       4.75230159
Si       9.51423559       1.31204477       4.30182803
H       9.91755899       2.14567482       3.08607654
H       8.20513842      -3.43705466       2.01373552
H       7.04638412      -4.20045675       3.12990230
H       8.80527219      -4.37416893       3.40187284
C       7.27647546      -2.87949394       5.69994785
H       6.30025327      -2.39771040       5.85033949
H       7.08952272      -3.95321744       5.56606173
C      11.17672455      -2.55975878       1.95735591
H      10.37123661      -3.29555783       1.84646034
H      11.71409248      -2.50059531       0.99954197
C       9.26688263      -0.66900676       0.92371733
H       8.44548603      -1.39431084       0.95062387
H       9.80886058      -0.77853270      -0.02537620
H       8.83878258       0.33940866       0.98340409
C      11.77682827       0.19306716       1.85126146
H      11.46444840       1.23912801       1.94703653
H      12.08135347      -0.00866978       0.81547182
H      12.63027208       0.03323507       2.52130064
C       6.50599451      -1.35722421       3.39981651
H       6.25323119      -0.49008005       4.02090265
H       5.65483502      -2.05250102       3.35946567
H       6.72634280      -0.98976097       2.39107782
C      11.24089056      -3.92580833       5.66203380
H      11.07670161      -3.74427302       6.73136533
H      12.16648677      -4.50632950       5.54660501
H      10.39802682      -4.51378615       5.27789175
C      12.09457774      -2.92895452       3.11629046
H      13.07098291      -2.43719672       3.00117712
H      12.28190426      -4.00951433       3.17483900
C      12.91653654      -1.69411153       5.55073880
H      13.24707452      -0.79442398       5.01769890
H      13.71390784      -2.45063698       5.52814917
H      12.71470814      -1.41232630       6.59084488
H      10.88994384       0.47222180       4.78885482
H      10.95160771       3.95088995       4.51512656
H       7.66463333      -2.57802637       7.83744517
C      10.12584593      -0.77887632       8.02078705
H      10.90877699      -1.54569008       7.98115664
H       9.57043162      -0.88074529       8.96324451
H      10.61116634       0.20484559       7.99138937
C       7.61222912       0.12224837       7.12651970
H       7.90950229       1.17480324       7.14551824
H       7.27225914      -0.17573514       8.12821700
H       6.78250521       0.02582634       6.41608758
C       8.01688530      -3.69015512       3.06388247
P       9.01823588      -0.94671899       6.55068822
P       8.02161940      -2.15422516       4.11281170
C       8.20124141      -2.59338851       6.87781983
H       8.99246157      -3.34852897       6.94491512
C       9.47792572       2.75418566       5.56348078
H       8.60197436       3.38400976       5.32586097
H       9.31783714       2.37468990       6.58333587
C      10.74946685       3.60895626       5.54363385
H      12.31891185       5.93763476       5.54949824
H      11.61192845       2.98018923       5.82442720
C      10.69171103       4.82158864       6.47651411
H       9.88352545       5.49146844       6.14022710
H      10.40621622       4.48508321       7.48671326
C      12.00898564       5.59039661       6.54573569
H      11.93198787       6.47075835       7.19814823
H      12.81508392       4.95333588       6.93819778

59
cis-[(dmpe)2MnH(=SiHEt)] (cis-3Et,H)
Mn       9.75159350      -0.87130600       4.47415484
P      10.38730853      -0.91834320       2.37060197
P      11.36174599      -2.32048778       4.74907445
Si       9.53701113       1.30623111       4.31960410
H       9.92276981       2.14837714       3.10396083
H       8.20206415      -3.43552361       2.02198964
H       7.03176381      -4.18657203       3.13444406
H       8.78803414      -4.37400374       3.41491026
C       7.26085342      -2.85479393       5.70232777
H       6.29311266      -2.35547572       5.85055959
H       7.05513866      -3.92535582       5.57031939
C      11.17747545      -2.56169694       1.95477988
H      10.37161620      -3.29784473       1.84736790
H      11.71119264      -2.50261212       0.99487364
C       9.26512583      -0.67007360       0.92683351
H       8.44629746      -1.39830990       0.95102392
H       9.80699729      -0.77399194      -0.02293494
H       8.83375111       0.33673731       0.99043247
C      11.77462949       0.19318648       1.84891899
H      11.45869848       1.23860081       1.94102245
H      12.08010073      -0.01075967       0.81384264
H      12.62835235       0.03888579       2.51985790
C       6.51282282      -1.33935238       3.39418971
H       6.26414967      -0.46821393       4.01137792
H       5.65695819      -2.02890911       3.35444914
H       6.73782206      -0.97768876       2.38446431
C      11.23773834      -3.94308777       5.64979066
H      11.06385060      -3.76569058       6.71833484
H      12.16401445      -4.52376787       5.54025856
H      10.39781937      -4.52890524       5.25610089
C      12.09997525      -2.93106884       3.11014090
H      13.07283313      -2.43208373       2.99545771
H      12.29466037      -4.01066955       3.16293660
C      12.91952361      -1.71369886       5.55476317
H      13.25300890      -0.81284570       5.02553900
H      13.71602588      -2.47113767       5.53297429
H      12.71402659      -1.43434635       6.59479355
H      10.91120983       0.45672357       4.79350411
H      10.58614839       4.19578394       4.38792538
H       7.65271543      -2.55994985       7.83997311
C      10.13960976      -0.80598080       8.02789667
H      10.90663185      -1.58869553       7.98803294
H       9.57909337      -0.90023723       8.96815721
H      10.64504407       0.16761440       8.00475724
C       7.64909185       0.15114034       7.13138236
H       7.97213059       1.19651647       7.14727364
H       7.30327827      -0.13672970       8.13412140
H       6.81695495       0.07188466       6.42152996
C       8.00676107      -3.68440212       3.07190205
P       9.03130570      -0.94743337       6.55504275
P       8.01997553      -2.14492894       4.11573407
C       8.18895171      -2.58175421       6.88020734
H       8.97049490      -3.34747145       6.94656797
C       9.52026293       2.73088164       5.60594240
H       8.53941916       3.23329053       5.55270568
H       9.59171172       2.30438945       6.61754127
C      10.64448329       3.74967495       5.39022531
H      10.60973533       4.56776356       6.12594051
H      11.63157256       3.27179276       5.47264883

56
cis-[(dmpe)2MnH(=SiHMe)] (cis-3Me,H)
  Mn        9.745201   -0.858619    4.478064
  P        10.378639   -0.900118    2.369191
  P        11.372613   -2.294118    4.751284
  Si        9.515394    1.316513    4.327752
  H         9.889357    2.159125    3.111528
  H         8.219211   -3.431617    2.027002
  H         7.042835   -4.188756    3.129944
  H         8.798477   -4.365290    3.426189
  C         7.253091   -2.846340    5.703905
  H         6.291117   -2.337105    5.857303
  H         7.036449   -3.914731    5.570346
  C        11.189407   -2.534553    1.956275
  H        10.391990   -3.281499    1.857438
  H        11.717777   -2.473671    0.993292
  C         9.247727   -0.667921    0.927452
  H         8.441717   -1.410614    0.951798
  H         9.788713   -0.759675   -0.024266
  H         8.798777    0.331126    0.994976
  C        11.748597    0.231872    1.840828
  H        11.415187    1.272462    1.928411
  H        12.056232    0.028431    0.806091
  H        12.605181    0.094698    2.511961
  C         6.506477   -1.342077    3.385172
  H         6.251627   -0.469246    3.997752
  H         5.653583   -2.035546    3.344419
  H         6.734500   -0.984220    2.374615
  C        11.263252   -3.923587    5.642957
  H        11.078748   -3.753332    6.711124
  H        12.197320   -4.492648    5.537330
  H        10.432821   -4.516734    5.239694
  C        12.122943   -2.885677    3.110092
  H        13.083924   -2.363986    2.994533
  H        12.341808   -3.960919    3.161066
  C        12.920343   -1.671160    5.566044
  H        13.243696   -0.763572    5.041789
  H        13.726957   -2.418092    5.544545
  H        12.706318   -1.398712    6.606386
  H        10.895641    0.475411    4.799660
  H        10.229181    3.470493    5.401048
  H         7.659025   -2.572828    7.842872
  C        10.136748   -0.804578    8.036590
  H        10.904806   -1.586452    7.995683
  H         9.576854   -0.899404    8.977331
  H        10.640899    0.169914    8.012945
  C         7.641817    0.147933    7.146455
  H         7.962466    1.193825    7.168974
  H         7.297214   -0.147208    8.147631
  H         6.809437    0.071186    6.436360
  C         8.015646   -3.681103    3.075446
  P         9.027007   -0.945055    6.563388
  P         8.014892   -2.138835    4.116434
  C         8.189343   -2.584224    6.879354
  H         8.972914   -3.349354    6.931650
  C         9.438256    2.735977    5.608795
  H         8.476026    3.265571    5.533805
  H         9.554667    2.389899    6.643605

69
cis-[(dmpe)2MnH(=SiEtPh)] (cis-3Ph,Et)
  Mn        9.731234   -0.843170    4.436563
  P        10.336886   -1.005571    2.330101
  P        11.387076   -2.231730    4.767504
  Si        9.456869    1.313916    4.304360
  H        10.945932    4.016250    3.858600
  H         8.706755   -4.392777    3.603464
  C         7.147348   -2.696353    5.686965
  H         6.272391   -2.053734    5.860113
  H         6.979952   -4.181166    3.191580
  H         6.779487   -3.724244    5.566079
  H         8.244890   -3.550023    2.108798
  C        11.180244   -2.648172    2.021919
  H        10.410373   -3.429470    2.032279
  H        11.663947   -2.659387    1.034072
  C         9.217423   -0.913345    0.859930
  H         8.446746   -1.690346    0.916063
  H         9.782618   -1.043777   -0.072914
  H         8.717791    0.063061    0.845165
  C        11.696610    0.086576    1.691888
  H        11.320693    1.100179    1.526120
  H        12.099200   -0.301706    0.746376
  H        12.499257    0.141151    2.436437
  C         6.496902   -1.323491    3.279631
  H         6.244410   -0.416914    3.841967
  H         5.634195   -2.005267    3.258770
  H         6.748572   -1.023639    2.256508
  C        11.280888   -3.850247    5.679483
  H        11.022622   -3.681419    6.731578
  H        12.238555   -4.386979    5.636763
  H        10.499246   -4.475781    5.230545
  C        12.169787   -2.850501    3.160387
  H        13.073889   -2.248077    2.990675
  H        12.489526   -3.895902    3.266851
  C        12.912218   -1.570754    5.590535
  H        13.233616   -0.674424    5.045952
  H        13.727473   -2.308048    5.598429
  H        12.684036   -1.274067    6.620645
  H        10.846881    0.380514    4.680478
  C         9.591298    2.542894    5.761317
  C         8.724384    4.434130    7.046417
  H         7.969723    5.210843    7.179633
  C         8.645920    3.565959    5.957328
  H         7.818209    3.682192    5.252883
  C        10.638529    2.447615    6.694703
  H        11.396131    1.672033    6.562824
  C         9.768646    4.311615    7.965892
  H         9.833514    4.989888    8.817154
  C        10.732396    3.319075    7.780950
  H        11.560318    3.225086    8.485810
  P         9.063522   -0.952350    6.555220
  P         7.968814   -2.101739    4.094230
  C         8.141838   -2.554952    6.828956
  H         8.874485   -3.371036    6.810168
  H         7.655144   -2.555438    7.815175
  C        10.181959   -0.958978    8.029632
  H        10.937216   -1.747332    7.935549
  H         9.606853   -1.125595    8.950736
  H        10.691722    0.008720    8.101943
  C         7.767725    0.192047    7.226427
  H         8.187511    1.192742    7.365178
  H         7.381998   -0.176935    8.186750
  H         6.947039    0.269398    6.503458
  C         7.971891   -3.710531    3.158157
  C         9.620271    2.590084    2.876933
  H         8.725107    3.229282    2.984420
  H         9.505325    2.093196    1.902606
  C        10.874178    3.473255    2.907244
  H        11.791491    2.875663    2.808330
  H        10.875679    4.215901    2.095587

71
cis-[(dmpe)2MnH(=SiEtnBu)] (cis-3Bu,Et)
  Mn        9.748915   -0.860748    4.470980
  P        10.395212   -0.975451    2.374847
  P        11.399016   -2.268729    4.787254
  Si        9.364157    1.275966    4.293324
  H         9.533097    3.640723    5.100097
  H         8.307041   -3.548266    2.128175
  H         6.977950   -4.145623    3.152327
  H         8.679426   -4.385392    3.648924
  C         7.080841   -2.612927    5.646802
  H         6.269950   -1.891033    5.822166
  H         6.618396   -3.599780    5.507802
  C        11.259082   -2.598313    2.026996
  H        10.487912   -3.378147    1.980729
  H        11.769432   -2.566509    1.052931
  C         9.318690   -0.885765    0.869538
  H         8.605422   -1.718410    0.876210
  H         9.923027   -0.948807   -0.045427
  H         8.749034    0.050186    0.859200
  C        11.769876    0.151795    1.832777
  H        11.441590    1.195178    1.854657
  H        12.118700   -0.097282    0.821230
  H        12.600800    0.048514    2.540785
  C         6.543762   -1.285324    3.194153
  H         6.281226   -0.368350    3.734795
  H         5.673691   -1.956364    3.147955
  H         6.838368   -1.003794    2.177295
  C        11.242579   -3.923968    5.626558
  H        10.925816   -3.806082    6.669050
  H        12.199682   -4.463352    5.611091
  H        10.485816   -4.524265    5.106449
  C        12.214639   -2.849267    3.182330
  H        13.133329   -2.259242    3.054378
  H        12.513902   -3.902648    3.267198
  C        12.919425   -1.666934    5.663575
  H        13.257716   -0.750753    5.164071
  H        13.724840   -2.415069    5.646333
  H        12.684164   -1.413860    6.703150
  H        10.811499    0.403090    4.726563
  H        10.665026    1.572777    7.092326
  H         7.585434   -2.590461    7.782116
  C        10.234965   -1.212185    8.052064
  H        10.898678   -2.074423    7.926843
  H         9.652998   -1.345956    8.974156
  H        10.857064   -0.314773    8.153441
  C         7.922394    0.165922    7.363835
  H         8.439784    1.102732    7.593822
  H         7.502624   -0.243116    8.293235
  H         7.114275    0.387351    6.657138
  C         7.979274   -3.693843    3.164346
  P         9.108694   -1.035293    6.587572
  P         7.973320   -2.069827    4.076770
  C         8.074675   -2.580790    6.797026
  H         8.754428   -3.441416    6.745951
  H         9.368044    1.779112    1.810419
  C         9.469312    2.675315    5.625435
  H         8.526609    2.711899    6.192915
  C        10.658023    2.545307    6.583524
  H        11.610731    2.616204    6.039793
  H        10.655764    3.329991    7.354755
  C         9.325903    2.389610    2.722642
  H         8.076667    3.990062    3.492039
  H        10.211552    3.046990    2.709113
  C         8.048638    3.243622    2.682656
  H         9.283971    5.546152    1.711368
  H         7.167967    2.610489    2.887371
  C         7.822061    3.968483    1.348113
  H         6.912092    4.584203    1.430765
  H         7.617358    3.221302    0.563499
  C         8.994038    4.846098    0.913394
  H         9.877390    4.240608    0.669226
  H         8.740942    5.437159    0.023326

63
trans-[(dmpe)2MnH(=SiHPh)] (trans-3Ph,H)
  Mn        7.910038    6.945102   -0.079280
  P         9.299026    7.259691   -1.762426
  P         6.348133    7.373377   -1.568155
  Si        7.949428    4.775322   -0.048308
  C         7.003168    7.283206   -3.318221
  H         7.021930    6.227152   -3.618601
  H         6.333570    7.817262   -4.008689
  C         5.645292    9.087832   -1.640953
  H         6.472902    9.795121   -1.773766
  H         4.928317    9.195948   -2.466991
  H         5.148864    9.334491   -0.696927
  C         7.908185    3.326166   -1.280753
  H         5.906339    9.426703    1.686836
  H         4.533246    8.410339    1.176541
  C         4.777482    6.412421   -1.730139
  H         4.146426    6.597537   -0.851012
  H         4.217470    6.703444   -2.630211
  H         5.006733    5.340471   -1.766568
  C        10.617236    8.557217   -1.687593
  H        10.173507    9.493886   -1.329059
  H        11.409054    8.254920   -0.990575
  H        11.067832    8.715930   -2.677462
  H         4.968228    8.493952    2.901469
  C         5.357031    5.690865    2.023100
  H        10.786935    4.993653    1.269804
  H         5.935063    4.774985    2.204641
  C        10.319509    5.882340   -2.460418
  H         9.658121    5.077541   -2.803259
  H        10.949986    6.223357   -3.293924
  H        10.957292    5.471341   -1.667567
  C         8.410379    7.859971   -3.300980
  H         8.372970    8.957254   -3.227760
  H         8.990127    7.605839   -4.200006
  H         7.974811    8.523868    0.028374
  H         8.824838    1.920204    0.079880
  C         5.372341    8.488378    1.879376
  H         4.733868    5.912212    2.901630
  H         4.712201    5.513478    1.153696
  C         7.463358    7.177490    3.270838
  H         7.582111    8.247101    3.500020
  H         6.863413    6.730720    4.076543
  P         6.535604    7.068074    1.641349
  P         9.485592    7.044971    1.444258
  C         8.822581    6.514457    3.102837
  H         8.722738    5.419342    3.061231
  H         9.523591    6.768382    3.911689
  C        10.194695    8.693827    1.901303
  H         9.369894    9.369006    2.158708
  H        10.891137    8.616044    2.748105
  H        10.717822    9.124452    1.040440
  C        11.044784    6.055179    1.377204
  H        11.641552    6.354286    0.506028
  H        11.649457    6.194878    2.284234
  H         8.205299    3.903530    1.197630
  C         7.393426    3.468217   -2.583238
  C         7.958206    1.184559   -3.130403
  C         8.473751    1.013761   -1.843551
  C         8.436181    2.067837   -0.930441
  H         6.967903    4.427176   -2.881430
  C         7.408210    2.415646   -3.496687
  H         6.993081    2.552215   -4.496882
  H         7.979354    0.359679   -3.843920
  H         8.900008    0.052516   -1.550938

65
trans-[(dmpe)2MnH(=SiHnBu)] (trans-3Bu,H)
Mn       7.97838953       6.91267071       0.00893144
P       9.44854562       7.12654522      -1.61581407
P       6.49066415       7.11945588      -1.59043554
Si       7.99337491       4.75280949      -0.07189998
C       7.25137703       6.69953191      -3.23858692
H       7.35165787       5.60392738      -3.26349671
H       6.59996833       7.00679507      -4.06984740
C       5.80004171       8.79441403      -1.97426905
H       6.63372618       9.48627743      -2.14149672
H       5.14730561       8.77581121      -2.85809554
H       5.23313813       9.16486926      -1.11310299
H       9.21375812       1.98301613      -0.00803255
H      10.77954907       5.10051274       1.69670619
C       5.26409716       8.48933997       1.64141282
C       4.93142588       6.13245641      -1.68153396
H       4.27309680       6.39653198      -0.84432725
H       4.39400056       6.31562795      -2.62222226
H       5.17951019       5.06653022      -1.60316646
C      10.64404007       8.53740294      -1.66657707
H      10.10659451       9.46749286      -1.44743788
H      11.42087248       8.39520156      -0.90469996
H      11.13041836       8.60950770      -2.64924301
H       5.77572880       9.42920778       1.40295602
H       4.49628553       8.30716729       0.87899609
H       4.77047516       8.57151997       2.61969585
C       5.36722669       5.72782540       2.09968882
C      10.62666057       5.76077867      -2.04014795
H      10.04732914       4.86727207      -2.30645538
H      11.28872568       6.03205075      -2.87452488
H      11.23356959       5.51600799      -1.16018710
C       8.61663247       7.36910606      -3.28057775
H       8.50878987       8.45343963      -3.43088784
H       9.25917843       6.98463091      -4.08516115
H       7.97895140       8.49972034       0.00631009
H       7.95765989       3.85102767      -1.32655151
H       5.96850677       4.86784953       2.41807154
H       4.68352588       6.01452228       2.91125528
H       4.78297203       5.42253339       1.22347453
C       7.32194172       7.44060614       3.28860535
H       7.40955007       8.53234703       3.39069904
H       6.68215643       7.08123161       4.10698140
P       6.50407913       7.11582112       1.63120611
P       9.45721409       7.14910942       1.61260688
C       8.70036669       6.79852167       3.28258876
H       8.62601277       5.70534768       3.37705644
H       9.34540356       7.16737936       4.09364996
C      10.14810773       8.83561739       1.94796739
H       9.31318326       9.52919511       2.10162503
H      10.80558709       8.84202800       2.82841815
H      10.70866268       9.18575371       1.07452174
C      11.01884004       6.16946137       1.75044487
H      11.68669392       6.41504414       0.91521284
H      11.54300742       6.38101367       2.69281104
C       8.08364454       3.34431928       1.23024039
H       8.12468221       3.78995351       2.23577624
H       7.13509859       2.77845326       1.17521569
C       9.25568893       2.37733911       1.01962306
H      10.20966296       2.92930777       1.08964663
H      10.38918149       2.21381735       3.59775455
C       9.29725110       1.20275221       2.00609434
H      10.12223380       0.52984696       1.72255971
H       8.36975606       0.61679336       1.89956356
C       9.47025051       1.62355285       3.46446329
H       8.62777285       2.23812661       3.80938617
H       9.53433598       0.75086504       4.12785757

59
trans-[(dmpe)2MnH(=SiHEt)] (trans-3Et,H)
   Mn        7.977259    6.908694    0.013061
   P         9.448451    7.119374   -1.612274
   P         6.490762    7.112542   -1.587225
   Si        7.998575    4.746986   -0.051406
   C         7.252069    6.694802   -3.235717
   H         7.353474    5.599372   -3.262287
   H         6.600514    7.002777   -4.066603
   C         5.800472    8.787705   -1.971486
   H         6.634435    9.479641   -2.136904
   H         5.149456    8.769352   -2.856565
   H         5.231880    9.158025   -1.111444
   H         9.273797    1.980344   -0.026327
   H        10.783200    5.108603    1.699991
   C         5.266040    8.495127    1.640265
   C         4.931583    6.125696   -1.680632
   H         4.272429    6.389151   -0.843897
   H         4.395162    6.309897   -2.621693
   H         5.179605    5.059745   -1.602959
   C        10.646702    8.527848   -1.662596
   H        10.111194    9.458738   -1.442196
   H        11.424478    8.383723   -0.902090
   H        11.131665    8.599809   -2.645960
   H         5.779017    9.433390    1.398434
   H         4.497798    8.311540    0.878632
   H         4.772711    8.581495    2.618300
   C         5.364677    5.734175    2.104050
   C        10.622793    5.751589   -2.040131
   H        10.040941    4.859647   -2.306006
   H        11.283182    6.022619   -2.875903
   H        11.231536    5.504499   -1.162102
   C         8.616459    7.365993   -3.276255
   H         8.507309    8.450645   -3.423298
   H         9.259387    6.984673   -4.082019
   H         7.977926    8.495320    0.004117
   H         7.968382    3.841144   -1.303778
   H         5.964802    4.873478    2.422961
   H         4.680749    6.022236    2.914949
   H         4.780662    5.429442    1.227475
   C         7.322082    7.447656    3.290490
   H         7.409879    8.539581    3.390335
   H         6.682598    7.089978    4.109800
   P         6.503787    7.119528    1.634074
   P         9.456892    7.154139    1.614930
   C         8.700377    6.805196    3.285051
   H         8.624695    5.712088    3.378805
   H         9.345204    7.173711    4.096411
   C        10.145512    8.842224    1.946295
   H         9.310155    9.535741    2.097567
   H        10.802226    8.851077    2.827278
   H        10.706877    9.190304    1.072575
   C        11.020606    6.177952    1.751890
   H        11.685920    6.423316    0.914572
   H        11.546703    6.391835    2.692608
   C         8.105689    3.324352    1.238386
   H         8.144903    3.737942    2.258263
   H         7.162303    2.754264    1.169257
   C         9.290557    2.379151    0.997863
   H        10.252030    2.898157    1.126042
   H         9.287240    1.524545    1.690467

56
trans-[(dmpe)2MnH(=SiHMe)] (trans-3Me,H)
Mn       7.97280844       6.90893773       0.01294764
P       9.44634435       7.11341083      -1.61209780
P       6.48757033       7.11040625      -1.59086282
Si       7.98277868       4.74743889      -0.03924870
C       7.25560680       6.71310003      -3.24206424
H       7.36136247       5.61844008      -3.27986958
H       6.60485853       7.02660077      -4.07135885
C       5.77485253       8.77904439      -1.96755010
H       6.59902098       9.48576578      -2.11863142
H       5.13326747       8.75757348      -2.85938639
H       5.19086070       9.13313356      -1.11108128
H       9.02139847       2.74364450       1.06110342
H      10.73144076       5.05671205       1.69918516
C       5.25608600       8.50230478       1.63870679
C       4.94261813       6.10224193      -1.69532386
H       4.27833587       6.34905289      -0.85771016
H       4.40534635       6.28537655      -2.63601287
H       5.20746395       5.03983778      -1.62560038
C      10.67594183       8.49546117      -1.65441514
H      10.16348429       9.43690835      -1.42448466
H      11.45334397       8.32683110      -0.89872301
H      11.15847876       8.56447506      -2.63914389
H       5.76396303       9.44149939       1.39018498
H       4.48315032       8.31275719       0.88344612
H       4.76922305       8.59049806       2.61978368
C       5.36208220       5.74260576       2.10552436
C      10.58925413       5.72328188      -2.05380462
H       9.98594411       4.84774280      -2.32650625
H      11.25574013       5.98466085      -2.88772195
H      11.19200702       5.45521254      -1.17780081
C       8.61761671       7.38949106      -3.27178227
H       8.50556133       8.47634083      -3.39887968
H       9.26203371       7.02396781      -4.08369293
H       7.98560725       8.49697723       0.01045008
H       7.89006250       3.83339117      -1.27971359
H       5.96472769       4.88213043       2.41984897
H       4.68143831       6.02827674       2.91984662
H       4.77490182       5.43882194       1.23075705
C       7.31795552       7.46241799       3.28600562
H       7.41637779       8.55414148       3.37713914
H       6.67460890       7.11710757       4.10760369
P       6.49740258       7.12951006       1.63159147
P       9.45392789       7.13296706       1.61447455
C       8.68961794       6.80561787       3.28663790
H       8.60194021       5.71454394       3.38986578
H       9.33735190       7.17323553       4.09591641
C      10.17966729       8.80678992       1.94428787
H       9.35922241       9.51838939       2.09322975
H      10.83425606       8.80228405       2.82682148
H      10.75078702       9.14210158       1.07201170
C      10.99437731       6.12015300       1.75217068
H      11.66494846       6.35119196       0.91497236
H      11.52541348       6.32057294       2.69294436
C       8.13115543       3.35793123       1.27000322
H       8.20739635       3.73724564       2.29759132
H       7.26604486       2.67946396       1.21022404

69
trans-[(dmpe)2MnH(=SiEtPh)] (trans-3Ph,Et)
Mn       7.99937684       6.86216313       0.01311238
P       9.38171911       7.07894604      -1.68439082
P       6.43206530       7.09396803      -1.50580745
Si       7.96479156       4.68299141       0.03112589
C       7.09027500       6.75199999      -3.22032684
H       7.13835757       5.66063364      -3.33618964
H       6.40414886       7.14370340      -3.98554334
C       5.72796451       8.78152568      -1.80729109
H       6.55486654       9.46979446      -2.01809519
H       5.02064777       8.78171783      -2.64817824
H       5.22046976       9.14296690      -0.90704776
H       9.92774012       3.89617711       2.23123081
H       6.05118684       9.48953800       1.51536044
H       4.66261074       8.45538212       1.09597201
C       4.86231814       6.11856844      -1.55597890
H       4.23868729       6.37688921      -0.69097321
H       4.29229661       6.32226566      -2.47307917
H       5.09977084       5.04915081      -1.50303190
C      10.56796563       8.49767312      -1.77516578
H      10.02863703       9.42427455      -1.54576536
H      11.37129768       8.37064004      -1.03913065
H      11.02016777       8.56972396      -2.77397170
H       5.07743731       8.70953861       2.80858203
C       5.40699304       5.83553194       2.24375195
H      11.13413925       5.34042793       1.35884973
H       5.94627055       4.93076057       2.54586788
C      10.54878244       5.72872776      -2.18370640
H       9.96929525       4.83978146      -2.45840614
H      11.18320053       6.02557440      -3.03076198
H      11.18310159       5.46680609      -1.32839435
C       8.47587806       7.37206032      -3.30439202
H       8.39861379       8.46248318      -3.42592912
H       9.06917433       6.98780270      -4.14600787
H       7.96983340       8.44050597      -0.04723434
H       7.74301962       3.94602287      -2.36416644
C       5.49429721       8.58879615       1.79907705
H       4.78451619       6.18661241       3.07848977
H       4.76130961       5.57678019       1.39575472
C       7.54949356       7.38955639       3.34135458
H       7.59833193       8.47530644       3.50788529
H       6.97485633       6.95434844       4.17051780
P       6.62728395       7.12546058       1.72127717
P       9.56211354       7.21588859       1.51447921
C       8.94948399       6.80527394       3.22541557
H       8.92094852       5.71067096       3.30690960
H       9.63427961       7.19423589       3.99360279
C      10.10580143       8.96311926       1.80847797
H       9.22245578       9.57288007       2.03048120
H      10.82290060       9.03332050       2.63829150
H      10.56319133       9.36540755       0.89822542
C      11.23271731       6.42071258       1.51128102
H      11.82715189       6.82563046       0.68238827
H      11.76845821       6.61405590       2.45090545
C       7.95977264       3.41074487       1.47575242
C       6.85573468       2.56061733       1.68425018
C       6.82429993       1.63996288       2.73159047
C       7.91626759       1.52363681       3.59486442
C       9.03156827       2.33835144       3.40009676
C       9.04306133       3.27117224       2.36064253
H       5.99240649       2.62131367       1.01658084
H       5.94800250       1.00510497       2.87241561
H       7.89877164       0.79951069       4.40988532
H       9.89598370       2.24851251       4.05999497
C       7.74827113       3.40694751      -1.40510197
H       9.79518485       2.64113960      -1.55512657
H       6.73308936       2.98274036      -1.29644483
C       8.76873856       2.26211387      -1.44211926
H       8.74084184       1.67874890      -0.51268247
H       8.58070353       1.57185278      -2.27767795

71
trans-[(dmpe)2MnH(=SiEtnBu)] (trans-3Bu,Et)
Mn       7.94400832       6.82703567      -0.00520598
P       9.41723916       7.08227533      -1.62317713
P       6.44331789       7.21875989      -1.55951731
Si       7.84129248       4.65199288      -0.09969529
C       7.16097431       6.85040460      -3.24269499
H       7.18908055       5.75528111      -3.34150025
H       6.52365782       7.25403061      -4.04341104
C       5.90517110       8.96902347      -1.85184082
H       6.79701163       9.59472036      -1.97212696
H       5.26564712       9.05521925      -2.74131421
H       5.35899157       9.34029630      -0.97839545
C       6.31372677       3.46682360      -0.15171223
H       6.33737276       2.82138918       0.74339245
H       5.39777309       4.06415871      -0.06196091
C       4.79545141       6.39702250      -1.72229178
H       4.17157536       6.63114500      -0.85046854
H       4.27520982       6.73804521      -2.62782073
H       4.92737558       5.31057458      -1.76896447
C      10.61496188       8.49537406      -1.61497760
H      10.08946533       9.40807397      -1.31140163
H      11.42129776       8.29935030      -0.89711338
H      11.06364012       8.63552655      -2.60821577
C       6.24635182       2.59137924      -1.41180822
H       5.33541448       1.97531727      -1.43801241
H       6.25165533       3.20178061      -2.32834578
H       7.10428506       1.90872269      -1.47789539
C      10.60720518       5.77367986      -2.18301529
H      10.04998402       4.88490129      -2.50088590
H      11.22215097       6.13668294      -3.01810022
H      11.26577711       5.48089109      -1.35713792
C       8.56446428       7.43660511      -3.26432593
H       8.51401015       8.53108837      -3.36146722
H       9.17353492       7.06041261      -4.09815797
H       8.01758319       8.40618693       0.05990902
C       9.24705263       3.32888731      -0.21619507
H       9.19774173       2.87292990      -1.22227798
H      10.21823820       3.84071861      -0.17554980
C       9.20968342       2.21377315       0.83534895
H      10.38207074       0.80929454      -0.29995580
H       9.21346199       2.65131363       1.85007092
H       8.26323258       1.65505289       0.75854582
P       6.48772516       7.10394411       1.62285187
P       9.46720741       6.96016266       1.57177701
C       8.69583939       6.60077243       3.23412916
H       8.55293959       5.51135506       3.28733447
H       9.36427809       6.90227449       4.05416427
C      10.21245660       8.61489491       1.95239861
H       9.40163910       9.33736085       2.10090237
H      10.84937432       8.57880350       2.84709663
H      10.80774868       8.96073146       1.10097757
C      10.99753911       5.93145716       1.70382777
H      11.65847087       6.12895133       0.85053378
H      11.54304503       6.15686665       2.63048168
H      10.72731482       4.86951816       1.69175306
C       5.38049019       8.58668525       1.68298525
H       5.96839333       9.48061446       1.44492547
H       4.57779403       8.48734642       0.94142947
H       4.92278238       8.69559235       2.67595713
C       5.22244987       5.84105051       2.11817609
H       5.72708029       4.90051803       2.36922493
H       4.63918912       6.18584208       2.98325170
H       4.53915087       5.64441986       1.28386995
C       7.36029380       7.32743585       3.27312709
H       7.52198509       8.40855502       3.39700318
H       6.71360527       6.99384282       4.09685364
C      10.37246627       1.22525395       0.72081413
H      11.32237815       1.77294914       0.83285417
H      11.14981117      -0.60194861       1.63434937
C      10.30385455       0.09053135       1.73982987
H      10.31689853       0.47936027       2.76836468
H       9.37891045      -0.49194997       1.61922244

82
[(dmpe)2MnH(SiH2nBu)2] (4Bu)
Mn       4.40454337      10.08397703      10.15955052
Si       2.63808255       8.61311441       9.52031286
H       3.61007136       6.47868265       8.68335374
C       1.17394130      11.38874455       9.08358411
C       3.08273829      13.31501915       9.08275541
H       4.15493388       7.77253844      13.13941681
H       2.55619835       7.84192515      12.35250937
H       2.77677636       8.52261671      13.99290966
H       4.41435120       8.54061868      10.15450899
H       4.83461386      11.75535905      13.53343754
H       5.69088339      10.19646544      13.66111106
H       4.20927599      10.48591882      14.62085735
H       1.30551050      10.30004941      12.15042160
H       1.96135183      11.20935011      13.53358137
P       5.09811801      10.02431447       8.06250904
P       5.98557408      11.66322305      10.43708720
C       5.56332027       8.41970118       7.28130535
C       4.09712704      10.71704006       6.66836595
C       6.68005985      10.99453499       7.85286092
C       6.60612927      12.21627944       8.75727211
C       7.62738677      11.39153059      11.25827528
C       5.71150315      13.30920247      11.26978179
H       4.65938249       7.81562971       7.13518030
H       6.25144670       7.87270836       7.93642831
H       6.04328187       8.58289111       6.30710954
H       3.96506978      11.79597109       6.80535957
H       3.11108605      10.23691207       6.66249302
H       4.59062579      10.53916993       5.70360359
H       7.49820516      10.33075134       8.16761130
H       6.83949814      11.25772308       6.79770386
H       7.57601955      12.72265552       8.86556205
H       5.88985868      12.94828273       8.35814474
H       8.21015698      12.31970025      11.19583182
H       7.48264494      11.12763048      12.31136577
H       8.18321907      10.57955161      10.77888176
H       5.87377443      13.18231800      12.34657575
H       6.44790011      14.03610909      10.90017191
H       4.70818248      13.71218262      11.12012875
H       1.40359803       8.72203399      10.39921061
H       2.07794140       8.87705242       8.13659269
Si       6.18001590       8.61402709      10.77923596
H       8.06211701       6.23806515      10.29231832
H       1.22847321      12.70267778      11.48563700
H       2.91500682      12.91974779      11.99593915
H       0.58693915      12.31347189       9.15727433
H       1.31537606      11.13541403       8.02750074
H       0.62410409      10.56945375       9.55764761
H       2.91310018      13.19824554       8.00596921
H       2.34812481      14.03748776       9.46440562
H       4.08668109      13.71776653       9.22903357
H       7.41403735       8.75914328       9.90562871
H       6.72675155       8.86414475      12.17047447
P       3.70667010       9.99598963      12.25501854
P       2.81731071      11.66045392       9.90118402
C       3.24888053       8.37790591      13.01195714
C       4.70396222      10.67477964      13.65877891
C       2.12273265      10.96003645      12.47536065
C       2.19784199      12.19390603      11.58734722
C       6.01804579       6.70532834      10.80719172
H       5.27061294       6.41991955      11.56633491
H       5.60988134       6.35213867       9.84796554
C       2.85953144       6.71435317       9.45695010
H       3.29884464       6.36959558      10.40325721
H       3.50231272       4.06423021      10.15671258
C       1.56732958       5.94874159       9.16893468
H       0.88733469       6.05364868      10.03104807
H       1.04328992       6.40989736       8.31582940
C       7.34074735       5.99332977      11.09015654
H       7.78581457       6.38206728      12.02186883
H       9.20583319       3.94670829      10.51120853
C       1.78004393       4.45819390       8.87088010
H       2.36738416       4.36291735       7.94246758
H       0.80361285       3.99136245       8.66511700
C       2.48234983       3.69170666       9.99090046
H       1.93534089       3.78973653      10.94029622
H       2.55532255       2.62123448       9.75655040
C       7.20681466       4.47197558      11.19430547
H       6.53953719       4.22792828      12.03709885
H       6.70101405       4.09485245      10.29031312
C       8.54495655       3.75834084      11.36969097
H       9.06763900       4.11033518      12.27072846
H       8.41739715       2.67111577      11.46028663

70
[(dmpe)2MnH(SiH2Et)2] (4Et)
  Mn        4.402953   10.064348   10.165585
  Si        2.638994    8.593041    9.528046
  H         3.659435    6.413713    8.815342
  C         1.169841   11.367971    9.093468
  C         3.080965   13.291793    9.078591
  H         4.174517    7.779894   13.167721
  H         2.569999    7.841710   12.391633
  H         2.802244    8.537112   14.024370
  H         4.403433    8.518733   10.168644
  H         4.840717   11.772695   13.521008
  H         5.708147   10.220571   13.657859
  H         4.230338   10.508988   14.623436
  H         1.314736   10.291019   12.165259
  H         1.971309   11.209371   13.542293
  P         5.088490    9.990658    8.065442
  P         5.989032   11.642488   10.422558
  C         5.539430    8.378563    7.292673
  C         4.085771   10.684325    6.672812
  C         6.673002   10.952629    7.843294
  C         6.601240   12.183123    8.735966
  C         7.636582   11.372294   11.232504
  C         5.723599   13.294018   11.247333
  H         4.632657    7.773826    7.167666
  H         6.237255    7.838541    7.943346
  H         6.004078    8.530599    6.309311
  H         3.961737   11.764642    6.806410
  H         3.096528   10.210975    6.672846
  H         4.573876   10.499493    5.706654
  H         7.490193   10.290357    8.163743
  H         6.831548   11.205289    6.785434
  H         7.570753   12.691917    8.835704
  H         5.882069   12.910136    8.332934
  H         8.220393   12.299064   11.159767
  H         7.500342   11.114449   12.288156
  H         8.186664   10.556329   10.753184
  H         5.902707   13.175169   12.322336
  H         6.452104   14.020360   10.861365
  H         4.716833   13.692914   11.110197
  H         1.399764    8.709096   10.399817
  H         2.091800    8.863643    8.140291
  Si        6.168912    8.596066   10.804868
  H         8.134167    6.263567   10.713508
  H         1.231491   12.691085   11.488514
  H         2.919385   12.912645   11.992347
  H         0.584730   12.294063    9.164342
  H         1.307606   11.108963    8.038303
  H         0.620267   10.551892    9.573200
  H         2.906210   13.171074    8.003083
  H         2.349358   14.017002    9.460798
  H         4.086260   13.693226    9.219036
  H         7.407254    8.712197    9.931868
  H         6.716431    8.870084   12.191803
  P         3.716673    9.994606   12.265541
  P         2.816108   11.641006    9.904977
  C         3.267236    8.383588   13.041400
  C         4.718203   10.692483   13.656894
  C         2.130862   10.954947   12.485003
  C         2.201613   12.183820   11.590067
  C         5.999810    6.688871   10.874738
  H         5.154998    6.416552   11.525787
  H         5.732429    6.310863    9.876241
  C         2.811185    6.685969    9.461880
  H         3.074482    6.310246   10.462367
  H         1.621002    4.917284    8.935729
  C         1.529988    6.013447    8.964351
  H         0.676256    6.258989    9.612379
  H         1.271668    6.352733    7.950950
  C         7.284466    6.019249   11.367263
  H         7.548324    6.362056   12.378049
  H         7.194772    4.923092   11.399916

69
[(dmpe)2MnH(PhHSi=CHMe)] (6Ph,H) i
  Mn        5.714886    1.966796   10.293513
  P         5.890857   -0.241653   10.364129
  P         4.166853    1.539258    8.791258
  P         5.256707    4.151275   10.237469
  P         4.588228    2.008003   12.178878
  Si        8.063213    1.991470   10.323213
  C         3.904454    3.717748   12.589512
  H         2.959898    3.634443   13.145152
  H         4.636301    4.194097   13.258563
  C         5.506955    1.740045   13.770862
  C        10.780715    5.184172   10.468296
  H        11.387425    5.743536    9.754412
  H         5.915414    0.725434   13.824545
  H         4.856623    1.911275   14.640436
  C         9.979651    4.129219   10.025247
  H         9.973645    3.875265    8.964147
  H         6.346737    2.445457   13.806211
  C         7.283537    2.098365    8.700175
  C         9.174999    3.402376   10.916623
  H         8.756101    0.728449   10.757295
  C        10.803195    5.524452   11.820875
  H        11.423410    6.351804   12.168034
  C        10.030585    4.797083   12.728492
  H        10.050431    5.052298   13.789393
  H         6.856689    2.222678   11.442376
  H         7.295713    1.163492    8.131875
  C         2.415852    2.146242    8.943606
  H         1.999063    1.860992    9.916406
  H         1.788179    1.723010    8.147307
  H         2.382395    3.239387    8.866385
  C         4.766532    5.138467    8.749399
  H         5.596785    5.197732    8.038607
  H         4.483894    6.155450    9.054998
  H         3.911625    4.674824    8.244415
  C         7.487177    3.288544    7.781071
  H         6.640579    3.445885    7.095187
  H         8.380722    3.162658    7.143903
  H         7.627504    4.227381    8.334834
  C         4.392400    1.933758    6.996514
  H         4.402670    3.016984    6.833855
  H         3.580716    1.492120    6.401642
  H         5.353759    1.528290    6.660385
  C         9.227203    3.751697   12.276194
  H         8.617043    3.201510   12.997458
  C         6.291380   -1.197072   11.893025
  H         7.263901   -0.868978   12.281488
  H         6.335642   -2.273861   11.681552
  H         5.530032   -1.020916   12.661216
  C         4.285109   -1.035229    9.849658
  H         4.421896   -2.114285    9.685205
  H         3.564436   -0.904036   10.666564
  C         7.009415   -1.160871    9.197837
  H         6.757436   -0.913320    8.159683
  H         6.897031   -2.243286    9.344142
  H         8.055226   -0.881251    9.369400
  C         3.827087   -0.305701    8.598044
  H         2.766696   -0.475708    8.364744
  H         4.409753   -0.642306    7.727854
  C         3.099874    0.971220   12.599047
  H         2.326612    1.081687   11.829475
  H         2.679829    1.265211   13.570941
  H         3.380477   -0.088124   12.650048
  C         3.769097    4.518236   11.307841
  H         3.692372    5.600640   11.489508
  H         2.877363    4.208374   10.746832
  C         6.440014    5.370288   10.969622
  H         6.718545    5.051977   11.980668
  H         5.991211    6.372582   11.009404
  H         7.362035    5.409000   10.378650

69
[(dmpe)2MnH(PhHSi=CHMe)] (6Ph,H) ii
  Mn        5.728457    1.896551   10.289043
  P         5.782950   -0.333300   10.324643
  P         4.155709    1.578061    8.782086
  P         5.374993    4.092581   10.287171
  P         4.617068    1.949942   12.182603
  Si        8.081471    2.004232   10.292895
  C        10.058209   -0.698614   12.812102
  H        10.048859   -0.947271   13.874676
  C        10.919466   -1.373606   11.945122
  H        11.582346   -2.151129   12.326834
  H         3.065179    3.625566   13.189592
  H         4.764835    4.105852   13.317263
  C        10.929815   -1.046324   10.588704
  H        11.603860   -1.566710    9.906443
  C         5.537662    1.606617   13.759543
  C         4.013213    3.679734   12.636399
  C         9.206938    0.290749   12.318847
  H         8.533502    0.804834   13.008842
  H         8.798829    3.287039   10.606217
  C         9.193882    0.629763   10.956042
  H         5.901983    0.573997   13.783491
  H         4.903550    1.784109   14.639837
  H         6.406761    2.275497   13.802946
  C         7.293738    1.976620    8.675813
  C        10.078251   -0.052376   10.104013
  H        10.094090    0.197391    9.040524
  C         2.435040    2.256632    8.970321
  H         2.014961    1.960197    9.938444
  H         1.782342    1.885780    8.168102
  H         2.449175    3.352145    8.926517
  C         4.938053    5.144833    8.828021
  H         5.762636    5.162609    8.108349
  H         4.725106    6.171531    9.156848
  H         4.048997    4.747981    8.324691
  C         7.531718    3.147120    7.734939
  H         6.681649    3.355901    7.067628
  H         8.403943    2.966669    7.083191
  H         7.744991    4.077072    8.282902
  C         4.380420    2.010584    6.996566
  H         4.442709    3.095380    6.859172
  H         3.539593    1.623955    6.404010
  H         5.315222    1.564982    6.638105
  H         6.889638    2.081381   11.439528
  H         7.305258    1.022959    8.141448
  C         6.072413   -1.366831   11.828094
  H         7.080256   -1.182169   12.217602
  H         5.977162   -2.432724   11.579890
  H         5.341896   -1.122213   12.607264
  C         4.131632   -1.010107    9.783034
  H         4.202401   -2.093914    9.608767
  H         3.413403   -0.842831   10.595641
  C         6.844807   -1.309676    9.155384
  H         6.674191   -0.983885    8.122503
  H         6.604317   -2.378020    9.238280
  H         7.904034   -1.163314    9.390656
  C         3.732502   -0.239989    8.538044
  H         2.670136   -0.353432    8.280503
  H         4.317736   -0.586061    7.673355
  C         3.085353    0.974694   12.598099
  H         2.309352    1.139571   11.841171
  H         2.691615    1.267736   13.581193
  H         3.314168   -0.097746   12.622873
  C         3.915322    4.516327   11.374660
  H         3.896391    5.596892   11.580673
  H         3.006519    4.266761   10.810837
  C         6.636881    5.216991   11.045697
  H         6.927585    4.829369   12.029981
  H         6.241280    6.236461   11.152708
  H         7.538668    5.242929   10.423614

69
[(dmpe)2MnH(PhHSi=CHMe)] (6Ph,H) iii
  Mn        5.722403    1.901651   10.298107
  P         5.816075   -0.318476   10.433108
  P         4.152969    1.526028    8.795775
  P         5.322406    4.095304   10.233281
  P         4.597291    2.017610   12.184209
  Si        8.071963    2.051737   10.252482
  C         3.917087    3.742185   12.543865
  H         2.963302    3.677251   13.085768
  H         4.640094    4.233325   13.211567
  C         5.524031    1.800985   13.779365
  C        10.644823    5.331571   10.497730
  H        11.168020    5.974896    9.788345
  H         5.930294    0.787968   13.865984
  H         4.880412    2.005597   14.646788
  C         9.842378    4.288220   10.033228
  H         9.738472    4.124129    8.958206
  H         6.365576    2.505311   13.781592
  C         7.263790    2.170042    8.650563
  C         9.152440    3.449461   10.922245
  H         8.853759    0.789145   10.492477
  C        10.776108    5.552308   11.868964
  H        11.398057    6.370055   12.235564
  C        10.110792    4.718839   12.770644
  H        10.214335    4.885423   13.844187
  H         6.905548    2.039122   11.432824
  H         8.192695    1.709692    6.744915
  C         2.388394    2.073305    9.017114
  H         2.004084    1.766099    9.995786
  H         1.750787    1.645846    8.231028
  H         2.326202    3.166524    8.952351
  C         4.959363    5.055994    8.694708
  H         5.761917    4.911588    7.961062
  H         4.873415    6.126861    8.922657
  H         4.017458    4.716445    8.249496
  H         7.138000    3.182434    8.253906
  C         7.633448    1.191382    7.540550
  H         8.283804    0.381284    7.893777
  H         6.776432    0.703031    7.046137
  C         4.287976    2.034564    7.019505
  H         4.219421    3.122917    6.926546
  H         3.474869    1.578510    6.437371
  H         5.249439    1.718986    6.605468
  C         9.310288    3.679271   12.297758
  H         8.787926    3.042091   13.016492
  C         6.050437   -1.218250   12.032488
  H         7.038160   -0.966843   12.440401
  H         5.998698   -2.304258   11.876559
  H         5.289840   -0.931275   12.765581
  C         4.210160   -1.046265    9.825301
  H         4.306724   -2.132497    9.681065
  H         3.441748   -0.870692   10.590157
  C         6.964363   -1.389735    9.439430
  H         6.811599   -1.219253    8.369567
  H         6.779121   -2.448035    9.668579
  H         8.005372   -1.145752    9.679929
  C         3.866914   -0.312686    8.538260
  H         2.838406   -0.499483    8.197452
  H         4.543690   -0.626195    7.728918
  C         3.093179    1.016294   12.639615
  H         2.294377    1.181959   11.907286
  H         2.724148    1.302063   13.634284
  H         3.326477   -0.054865   12.649066
  C         3.806930    4.509479   11.237827
  H         3.731554    5.596483   11.388405
  H         2.926322    4.185289   10.669139
  C         6.491944    5.309450   10.999145
  H         6.793986    4.968182   11.995519
  H         6.019773    6.298763   11.073907
  H         7.401851    5.389952   10.394575

69
[(dmpe)2MnH(PhHSi=CHMe)] (6Ph,H) iv
  Mn        5.724623    1.837303   10.320446
  P         5.710394   -0.401375   10.425153
  P         4.167120    1.554902    8.784084
  P         5.423364    4.040205   10.290209
  P         4.581047    1.968470   12.193471
  Si        8.067867    2.066428   10.331902
  C        10.021990   -0.777407   12.681458
  H         9.973145   -1.097062   13.723888
  C        10.936313   -1.372041   11.810079
  H        11.598511   -2.162419   12.166028
  H         3.008249    3.682283   13.102365
  H         4.705631    4.155784   13.277440
  C        11.003240   -0.943749   10.483755
  H        11.719794   -1.400337    9.798951
  C         5.482661    1.681632   13.792467
  C         3.975573    3.716240   12.582103
  C         9.170573    0.225125   12.217680
  H         8.455504    0.676405   12.910141
  H         8.723547    3.320628   10.827842
  C         9.213541    0.667128   10.884142
  H         5.838667    0.648512   13.863933
  H         4.842813    1.901733   14.658853
  H         6.357204    2.344534   13.813778
  C         7.293699    2.058952    8.704038
  C        10.157331    0.071007   10.031245
  H        10.231917    0.400556    8.993488
  C         2.424535    2.171312    8.998431
  H         2.013425    1.841660    9.958923
  H         1.781098    1.802297    8.187773
  H         2.408658    3.267880    8.977934
  C         5.118090    5.048483    8.769387
  H         5.920467    4.884827    8.039444
  H         5.075228    6.117448    9.018399
  H         4.166525    4.758467    8.309636
  H         7.176452    3.056890    8.266761
  C         7.671269    1.051257    7.629100
  H         8.174602    0.166832    8.033788
  H         6.816831    0.673537    7.040975
  C         4.350114    2.091874    7.020980
  H         4.312168    3.183094    6.944902
  H         3.536763    1.667826    6.415532
  H         5.311036    1.756660    6.620487
  H         6.874827    1.909593   11.480896
  H         8.367593    1.504512    6.903159
  C         5.839467   -1.351920   12.007217
  H         6.850029   -1.227233   12.415635
  H         5.665913   -2.420371   11.820008
  H         5.114411   -1.001970   12.748255
  C         4.076758   -1.024445    9.771889
  H         4.115070   -2.113127    9.618735
  H         3.302997   -0.813194   10.522334
  C         6.805650   -1.536146    9.442728
  H         6.693296   -1.340771    8.371960
  H         6.530830   -2.579684    9.649274
  H         7.854755   -1.381090    9.717302
  C         3.802235   -0.261459    8.486759
  H         2.774994   -0.393752    8.117524
  H         4.484751   -0.595512    7.690561
  C         3.028531    1.029372   12.618693
  H         2.243797    1.247532   11.884815
  H         2.666020    1.311828   13.616720
  H         3.211413   -0.051428   12.607536
  C         3.928137    4.520610   11.295425
  H         3.915098    5.606431   11.470892
  H         3.037528    4.263486   10.707704
  C         6.667526    5.169896   11.074683
  H         6.954136    4.785520   12.061058
  H         6.257342    6.184028   11.176294
  H         7.574178    5.209134   10.459836

71
[(dmpe)2MnH(nBuHSi=CHMe)] (6Bu,H) i
Mn       5.72866044       1.95330484      10.27373240
P       5.85780261      -0.26185453      10.30353870
P       4.12002313       1.58056943       8.82283962
P       5.31107838       4.13681388      10.25929280
P       4.67248884       1.98789935      12.19643203
Si       8.09251719       1.88846059      10.23361771
C       4.02326898       3.70451565      12.64774997
H       3.09289530       3.62683186      13.22687978
H       4.77911602       4.16263717      13.30234708
C       5.64461096       1.68994883      13.75278660
H       3.45666709      -0.09574688      12.70454599
C       3.86319388       4.52251935      11.37907924
H       6.02584725       0.66405155      13.78569236
H       5.03268603       1.87410407      14.64692837
H       2.39018812       1.08382965      11.91528150
H       2.79778283       1.26386801      13.64566450
H       6.50653283       2.36873590      13.75820559
C       7.25520221       2.05982438       8.64287672
H      10.31933682       2.89948628      10.33263578
H       8.71454441       0.57513011      10.63388858
H       3.81011136       5.60387556      11.57336793
H       2.95065858       4.23325928      10.84185943
C       6.54670167       5.32152433      10.97774572
H       6.92467156       4.93049910      11.92936108
H       6.92384378       2.19262262      11.37435064
H       7.20323199       1.14452916       8.04659303
C       2.38922915       2.23322988       9.03222395
H       1.99867816       1.95982125      10.01915015
H       1.72595286       1.82367989       8.25838065
H       2.37963805       3.32640207       8.95249969
C       4.81191747       5.16638061       8.80187729
H       5.61914685       5.19572721       8.06311629
H       4.58393335       6.19099762       9.12613939
H       3.92095166       4.74521084       8.32320998
C       7.51032111       3.26557679       7.75472216
H       6.66661972       3.48578846       7.08150267
H       8.39286187       3.11592393       7.10879465
H       7.70111844       4.18121489       8.33335428
C       4.30761437       1.99343255       7.02585271
H       4.34941175       3.07827504       6.88140643
H       3.46758536       1.58806156       6.44522587
H       5.24711238       1.56468613       6.65918891
H       6.09826718       6.31152754      11.13860520
H       7.39607889       5.42666210      10.29378406
C       6.30345973      -1.24695348      11.80193245
H       7.29878370      -0.94363079      12.14961601
H       6.31457745      -2.32133358      11.57598289
H       5.58102554      -1.06326951      12.60470522
C       4.21179226      -1.01007322       9.84834659
H       4.31556139      -2.08960925       9.66567169
H       3.52995189      -0.87184751      10.69610777
C       6.89691656      -1.19332091       9.07249978
H       6.59702967      -0.92983445       8.05148456
H       6.76600116      -2.27365081       9.21567580
H       7.95567273      -0.93912792       9.19255697
C       3.71972991      -0.25404409       8.62475912
H       2.64569092      -0.39159208       8.43901412
H       4.25229210      -0.59731873       7.72615172
C       3.18455836       0.96588081      12.66160441
C       9.36019486       3.17915436      10.80078619
H       9.10476750       4.17065204      10.40002584
H       9.79429215       4.58550536      14.78591662
C       9.52971134       3.24965079      12.32012062
H       8.56446982       3.51101382      12.78742908
H       9.78395053       2.24910055      12.71027944
C      10.58892247       4.24964955      12.78510454
H      10.32788068       5.24979969      12.40228268
H      11.55445815       3.98987048      12.32181900
C      10.74037026       4.29969750      14.30332610
H      11.03060185       3.31756661      14.70370800
H      11.50475810       5.02520363      14.61236632

71
[(dmpe)2MnH(nBuHSi=CHMe)] (6Bu,H) ii
Mn       5.72927392       1.89570160      10.28562304
P       5.80793493      -0.31887774      10.29481309
P       4.13117667       1.57392924       8.80155110
P       5.37557406       4.09538142      10.27469556
P       4.61746367       1.94786296      12.17233110
Si       8.10054115       2.00634390      10.29129742
H       3.32681905      -0.10055137      12.64049422
C       3.91624621       4.52017054      11.36530263
H       3.90243254       5.60001434      11.57421959
H       3.00680995       4.27634463      10.80091264
H       3.06216682       3.62588600      13.17639132
H       4.76200564       4.10393640      13.30841575
C       6.63975907       5.21739584      11.03636623
H       6.93358730       4.82415256      12.01697366
C       5.52573822       1.60269717      13.75841983
C       4.01123169       3.67999826      12.62560630
H       6.24356057       6.23566045      11.14865735
H       7.53886924       5.24492801      10.41121174
H       8.78750622       3.31308825      10.58276136
H      10.26142140       0.88770199      10.60233667
H       5.86255992       0.56147279      13.79800868
H       4.89092646       1.80588802      14.63222730
H       6.41286669       2.24655566      13.79813950
C       7.29398136       1.97401261       8.67745933
H       2.31894112       1.10454369      11.81426991
H       2.67407674       1.27856810      13.55623655
C       2.42126746       2.28441544       8.98668283
H       2.00776941       2.03551427       9.97046543
H       1.75424004       1.89079841       8.20768430
H       2.45103715       3.37649745       8.89609370
C       4.94349252       5.14737065       8.81504104
H       5.76980163       5.16058201       8.09748214
H       4.73419637       6.17513008       9.14192280
H       4.05455360       4.75315133       8.30991956
C       7.52689098       3.13756289       7.72607650
H       6.67310670       3.33546713       7.05978511
H       8.39669551       2.95305972       7.07243963
H       7.73863320       4.07340725       8.26383610
C       4.34724965       1.97807635       7.00667685
H       4.42357704       3.06058500       6.85904348
H       3.49740150       1.59780151       6.42323791
H       5.27417977       1.51764171       6.64687676
H       6.89050634       2.09918919      11.42213010
H       7.29993678       1.02172112       8.14184026
C       6.16908461      -1.35296762      11.79006739
H       7.16617529      -1.11881527      12.18012609
H       6.12296854      -2.42226099      11.54416252
H       5.43435349      -1.14226379      12.57513193
C       4.15083834      -1.02666462       9.80902741
H       4.23613645      -2.10571820       9.61361073
H       3.46563399      -0.88831316      10.65400982
C       6.83361599      -1.27480828       9.06824114
H       6.52034104      -1.01757973       8.04923287
H       6.69552755      -2.35297741       9.22166381
H       7.89730788      -1.03229033       9.15795276
C       3.67926708      -0.24762270       8.59329150
H       2.60138258      -0.35276403       8.40813169
H       4.19945056      -0.59846812       7.69041193
C       3.08510257       0.96789342      12.58612224
C       9.26601654       0.71179791      11.04452160
H      10.26563984       0.69615483      15.21441729
H       8.98148788      -0.31038783      10.75580921
C       9.34649796       0.80607328      12.57109488
H       9.56982799       1.84403664      12.87282700
H       8.35474070       0.58528151      12.99930960
C      10.37956358      -0.13295419      13.19879031
H      11.39151074       0.23185326      12.96108531
H      10.29697999      -1.12424764      12.72392802
C      10.21577122      -0.27916772      14.70949469
H       9.24038781      -0.72561283      14.95175102
H      10.99330196      -0.92143103      15.14361457

71
[(dmpe)2MnH(nBuHSi=CHMe)] (6Bu,H) iii
Mn       5.73533839       1.88931808      10.26545351
P       5.81035504      -0.33352723      10.34859290
P       4.08648185       1.55307307       8.84152576
P       5.37423822       4.07593548      10.22377388
P       4.68279049       1.99287024      12.19130786
Si       8.11539843       1.94727307      10.19762202
C       4.05399696       3.73159085      12.59936277
H       3.11026417       3.67883946      13.15932000
H       4.80334999       4.18504210      13.26436501
C       5.65795287       1.73808384      13.75437978
C       3.93468021       4.53907751      11.31800339
H       2.37004563       1.13906042      11.98626090
H       6.03628266       0.71287968      13.81942038
H       5.04731498       1.95276041      14.64256581
H       2.84083261       1.31183265      13.69882862
H       3.43349367      -0.06501350      12.73776982
H       6.52150200       2.41401154      13.73851594
C       7.26843080       2.19193562       8.62415181
H      10.34161419       2.87254092      10.54125015
H       8.78320625       0.60623846      10.35529080
H       3.92022549       5.62382169      11.49843786
H       3.01651233       4.27699733      10.77731526
C       6.64889168       5.24552108      10.89757130
H       7.03148876       4.87584551      11.85575725
H       6.94769158       2.01152106      11.36900692
H       8.12904984       1.80231438       6.66755710
C       2.35000776       2.15181037       9.15251981
H       2.00992490       1.86336799      10.15250320
H       1.66080524       1.73599898       8.40512359
H       2.31405715       3.24545997       9.08126609
C       4.94812584       5.05777723       8.71255722
H       5.69729659       4.88539332       7.93049848
H       4.91373305       6.13026696       8.94591818
H       3.96882634       4.75304584       8.32747382
H       7.19875455       3.23126820       8.28531533
C       7.56682412       1.26509938       7.44812505
H       8.18423968       0.40486769       7.73540460
H       6.67409595       0.84879280       6.95275864
C       4.13958991       2.06032377       7.05797941
H       4.08390424       3.14957793       6.96851388
H       3.29219923       1.61746317       6.51644540
H       5.07466797       1.73006615       6.59730008
H       6.22939600       6.25202865      11.03098780
H       7.48748524       5.30518080      10.19424428
C       6.15564965      -1.25926256      11.91293682
H       7.16155833      -0.99604963      12.26450614
H       6.11051669      -2.34327404      11.74401389
H       5.43509860      -0.99297068      12.69284792
C       4.15306609      -1.03042319       9.84973536
H       4.22140761      -2.11614186       9.68897833
H       3.44340570      -0.84960776      10.66725949
C       6.85970047      -1.40025903       9.24320859
H       6.64427295      -1.18260496       8.19272198
H       6.65537125      -2.46030722       9.44503921
H       7.92047745      -1.19656159       9.42440767
C       3.73571554      -0.27842131       8.59523999
H       2.68134788      -0.43710517       8.32846370
H       4.34408965      -0.60194670       7.73755587
C       3.18731853       1.00291224      12.70324503
C       9.36682157       3.14244901      10.98217806
H       9.17345966       4.18005393      10.67866009
H       9.63389994       4.10105224      15.10887671
C       9.44705714       3.04147142      12.50680544
H       8.47381743       3.32217050      12.94482803
H       9.60945634       1.99019045      12.80192082
C      10.53784907       3.90924170      13.13550341
H      10.37117228       4.95897542      12.84359621
H      11.51258121       3.62614780      12.70661105
C      10.58944236       3.79677165      14.65718647
H      10.78634009       2.76118062      14.97011550
H      11.37749741       4.43044326      15.08554627

71
[(dmpe)2MnH(nBuHSi=CHMe)] (6Bu,H) iv
Mn       5.73999942       1.83747449      10.31580243
P       5.73023152      -0.39305942      10.42689595
P       4.16908107       1.54549435       8.79749391
P       5.41968461       4.04298377      10.29894858
P       4.60642392       1.96680914      12.19584351
Si       8.09130561       2.14208101      10.27593283
H       3.29965709      -0.08536445      12.67229405
C       3.89167237       4.49391125      11.26856820
H       3.85039619       5.57995532      11.43606570
H       3.01853618       4.21082475      10.66877060
H       2.96247967       3.63753020      13.06162396
H       4.63904816       4.16705666      13.26987520
C       6.61420988       5.18884970      11.14221363
H       6.90150715       4.77886106      12.11762048
C       5.52538572       1.72824568      13.79440383
C       3.93899257       3.69974640      12.56254087
H       6.16155308       6.18071425      11.27504413
H       7.52599279       5.28666892      10.54341168
H       8.67753782       3.44167908      10.74455762
H      10.33918013       1.14171070      10.34722798
H       5.90915818       0.70613932      13.87759539
H       4.88661048       1.94472718      14.66219047
H       6.38483067       2.41032223      13.79785992
C       7.26942658       2.06275265       8.67235158
H       2.29793127       1.15402396      11.89366649
H       2.70207886       1.29441756      13.62597343
C       2.43151718       2.18982924       8.99210817
H       2.02764547       1.92748693       9.97614291
H       1.77757322       1.77539578       8.21292559
H       2.42518765       3.28245522       8.89904003
C       5.15172316       5.06193858       8.77697655
H       5.98481553       4.92044183       8.07775563
H       5.08097883       6.12705159       9.03452999
H       4.22477218       4.75920607       8.27749042
H       7.08648784       3.03064699       8.19575615
C       7.68282964       1.02651633       7.63612480
H       8.28803653       0.21700206       8.06270993
H       6.83930312       0.53882765       7.11650220
C       4.36694957       2.04404812       7.02405707
H       4.39854504       3.13463501       6.93509251
H       3.52568686       1.66393018       6.42823420
H       5.30360158       1.64451243       6.62483639
H       6.92819637       1.89981982      11.44258573
H       8.29929658       1.49293037       6.85029687
C       5.92818552      -1.33084320      12.01320673
H       6.94476907      -1.17414184      12.39596000
H       5.77530305      -2.40569487      11.84770004
H       5.21951306      -0.98665163      12.77224699
C       4.07674270      -1.02249380       9.82803444
H       4.10490440      -2.11305812       9.68939549
H       3.32203323      -0.79453585      10.59126054
C       6.77640438      -1.55104857       9.40700601
H       6.66219379      -1.33417494       8.34130081
H       6.46973286      -2.58767803       9.60155857
H       7.83516608      -1.44393768       9.66383380
C       3.77940796      -0.27526558       8.53712739
H       2.74337405      -0.40496229       8.19418941
H       4.43978154      -0.62793845       7.73090227
C       3.08198958       0.98818663      12.64189108
C       9.37392948       0.84773802      10.79291162
H      10.94410387       0.56608747      14.73412941
H       9.12946782      -0.13571956      10.36676355
C       9.51708026       0.73562427      12.31378725
H       9.77947747       1.72181015      12.73349936
H       8.53985392       0.47940422      12.75734928
C      10.55383900      -0.29148315      12.77010385
H      11.53466075      -0.02590551      12.34382432
H      10.29490122      -1.27492031      12.34422249
C      10.66051747      -0.39861553      14.28922146
H       9.69874533      -0.69527870      14.73269776
H      11.41126987      -1.14019280      14.59348762

65
[(dmpe)2MnH(EtHSi=CHMe)] (6Et,H) i
  Mn        5.704286    1.982385   10.290665
  P         5.897705   -0.227827   10.358533
  P         4.155698    1.540232    8.793899
  P         5.223137    4.150121   10.226272
  P         4.587159    2.012795   12.177365
  Si        8.069104    1.982085   10.333727
  C         3.873876    3.716059   12.581544
  H         2.927214    3.618938   13.130541
  H         4.593483    4.204813   13.254443
  C         5.522205    1.767420   13.765597
  H         3.417996   -0.099647   12.675647
  C         3.732503    4.512466   11.296787
  H         5.931532    0.753627   13.825234
  H         4.880094    1.947107   14.639199
  H         2.340002    1.041482   11.846513
  H         2.696361    1.249883   13.584928
  H         6.363772    2.470939   13.783733
  C         7.282459    2.106880    8.712372
  H        10.279356    2.987479   10.497039
  H         8.704523    0.690931   10.782981
  H         3.645391    5.594599   11.474226
  H         2.844623    4.192486   10.736042
  C         6.406154    5.373838   10.964263
  H         6.729930    5.021368   11.950241
  H         6.854289    2.286941   11.424070
  H         7.276083    1.182153    8.128756
  C         2.399191    2.138192    8.942359
  H         1.986721    1.859085    9.918708
  H         1.774321    1.701690    8.151502
  H         2.356856    3.229855    8.853674
  C         4.740007    5.142813    8.738347
  H         5.567581    5.183402    8.022935
  H         4.474605    6.165493    9.039527
  H         3.875210    4.689871    8.241033
  C         7.533342    3.306441    7.814542
  H         6.706915    3.491237    7.109879
  H         8.441433    3.173898    7.201078
  H         7.676705    4.236079    8.384444
  C         4.387618    1.938277    6.998595
  H         4.397509    3.022007    6.841024
  H         3.581216    1.497373    6.396604
  H         5.352486    1.537200    6.668319
  H         5.943229    6.365375   11.062698
  H         7.293781    5.459075   10.327968
  C         6.317693   -1.179354   11.885859
  H         7.290601   -0.842297   12.264490
  H         6.368240   -2.255819   11.675712
  H         5.561688   -1.006732   12.659674
  C         4.291598   -1.031688    9.857071
  H         4.433976   -2.110007    9.694362
  H         3.575994   -0.902271   10.678078
  C         7.006101   -1.146433    9.178562
  H         6.735017   -0.907071    8.143693
  H         6.900662   -2.227774    9.334427
  H         8.052366   -0.860320    9.331414
  C         3.821321   -0.307991    8.605668
  H         2.759851   -0.482353    8.382449
  H         4.397668   -0.645306    7.732124
  C         3.117414    0.953406   12.614581
  C         9.307711    3.296280   10.916584
  H         9.082264    4.273940   10.468850
  H        10.241678    4.058877   12.753808
  C         9.411166    3.409822   12.440641
  H         8.488857    3.825086   12.871731
  H         9.569795    2.425076   12.905512

65
[(dmpe)2MnH(EtHSi=CHMe)] (6Et,H) ii
  Mn        5.722816    1.893182   10.283521
  P         5.796255   -0.323060   10.298844
  P         4.131729    1.575949    8.798479
  P         5.379865    4.091967   10.279384
  P         4.608998    1.946463   12.173036
  Si        8.092655    1.981949   10.303295
  H         3.310191   -0.097919   12.633115
  C         3.920372    4.522574   11.366295
  H         3.910315    5.602243   11.576134
  H         3.010938    4.282517   10.800322
  H         3.059778    3.630690   13.175788
  H         4.761544    4.101081   13.310373
  C         6.648021    5.208334   11.040892
  H         6.938984    4.813885   12.021936
  C         5.516764    1.597493   13.757631
  C         4.009803    3.680947   12.626325
  H         6.256766    6.228581   11.152632
  H         7.548066    5.231482   10.416761
  H         8.791795    3.282153   10.598606
  H        10.225558    0.807664   10.566124
  H         5.852960    0.555918   13.794846
  H         4.882795    1.799563   14.632312
  H         6.404072    2.241198   13.797934
  C         7.294023    1.960743    8.685385
  H         2.306796    1.115591   11.813838
  H         2.664990    1.280057   13.556146
  C         2.421302    2.287823    8.980794
  H         2.004300    2.033070    9.961547
  H         1.756427    1.900422    8.196956
  H         2.453422    3.380424    8.897697
  C         4.953946    5.146268    8.817422
  H         5.780013    5.152889    8.099529
  H         4.751994    6.175779    9.143374
  H         4.061969    4.757613    8.313516
  C         7.539614    3.126437    7.739277
  H         6.690459    3.331562    7.069259
  H         8.411765    2.939077    7.089583
  H         7.753870    4.059195    8.281435
  C         4.353339    1.985462    7.004914
  H         4.431365    3.068357    6.860966
  H         3.505254    1.607874    6.417229
  H         5.281130    1.525242    6.647014
  H         6.880545    2.090450   11.430107
  H         7.293511    1.010944    8.145657
  C         6.147417   -1.354159   11.795948
  H         7.140040   -1.115433   12.195170
  H         6.107837   -2.423911   11.550663
  H         5.404714   -1.146005   12.574203
  C         4.140358   -1.026065    9.800972
  H         4.223636   -2.105165    9.605042
  H         3.450547   -0.886278   10.642044
  C         6.828927   -1.280082    9.077627
  H         6.523223   -1.022305    8.056535
  H         6.688248   -2.358083    9.229821
  H         7.892324   -1.038802    9.175074
  C         3.678225   -0.244369    8.583052
  H         2.601648   -0.348031    8.390133
  H         4.204554   -0.594222    7.683360
  C         3.073344    0.971924   12.584030
  C         9.251989    0.686516   11.068059
  H        10.179068    0.223415   13.006267
  H         8.923914   -0.339221   10.853112
  C         9.413952    0.887962   12.579496
  H         9.707948    1.921842   12.812883
  H         8.471049    0.694702   13.110566

65
[(dmpe)2MnH(EtHSi=CHMe)] (6Et,H) iii
  Mn        5.709812    1.916538   10.286937
  P         5.832274   -0.304675   10.417050
  P         4.130674    1.518354    8.800227
  P         5.298178    4.093001   10.203847
  P         4.593149    2.025195   12.177146
  Si        8.087701    2.033107   10.284830
  C         3.912506    3.753525   12.540345
  H         2.954313    3.685875   13.073689
  H         4.630582    4.236823   13.218563
  C         5.529372    1.815976   13.770612
  C         3.811208    4.535202   11.241768
  H         2.289010    1.173317   11.932713
  H         5.922953    0.799079   13.866099
  H         4.892239    2.037811   14.638165
  H         2.742787    1.298971   13.653105
  H         3.343960   -0.052784   12.660667
  H         6.381620    2.506300   13.762270
  C         7.277026    2.214821    8.683822
  H        10.285741    2.988728   10.645492
  H         8.781828    0.713259   10.498282
  H         3.760100    5.622146   11.401159
  H         2.918988    4.236689   10.676662
  C         6.523979    5.292621   10.912209
  H         6.876779    4.937891   11.887281
  H         6.887733    2.095247   11.422455
  H         8.166515    1.796370    6.745008
  C         2.358131    2.032698    9.047734
  H         1.985010    1.682043   10.015624
  H         1.723847    1.623020    8.249868
  H         2.277665    3.125996    9.024738
  C         4.901533    5.052998    8.670366
  H         5.674208    4.885080    7.910576
  H         4.844034    6.126912    8.892394
  H         3.937607    4.729390    8.262484
  H         7.189850    3.242351    8.314233
  C         7.623779    1.262037    7.541022
  H         8.276891    0.440240    7.860601
  H         6.753004    0.789273    7.056594
  C         4.230955    2.038341    7.022224
  H         4.078963    3.118388    6.932801
  H         3.454698    1.525034    6.437992
  H         5.214173    1.797921    6.609077
  H         6.083109    6.292973   11.020970
  H         7.387544    5.360178   10.240556
  C         6.103268   -1.197767   12.014958
  H         7.087046   -0.917905   12.413279
  H         6.078443   -2.284883   11.862761
  H         5.341091   -0.926802   12.752267
  C         4.224599   -1.049292    9.830623
  H         4.328259   -2.135162    9.691246
  H         3.461462   -0.873985   10.600260
  C         6.969637   -1.369339    9.399238
  H         6.802771   -1.189828    8.333021
  H         6.786213   -2.428778    9.622847
  H         8.013140   -1.127732    9.627691
  C         3.867926   -0.324274    8.541840
  H         2.841210   -0.524535    8.204104
  H         4.546961   -0.629922    7.731839
  C         3.099365    1.015808   12.653394
  C         9.306363    3.262104   11.071256
  H         9.112769    4.292597   10.748390
  H        10.202699    3.742543   13.019182
  C         9.361092    3.173374   12.599421
  H         8.439822    3.565430   13.053214
  H         9.467262    2.131944   12.937742

65
[(dmpe)2MnH(EtHSi=CHMe)] (6Et,H) iv
  Mn        5.728335    1.826677   10.322352
  P         5.700107   -0.402023   10.424174
  P         4.166469    1.550729    8.791253
  P         5.427132    4.035973   10.298632
  P         4.584465    1.965611   12.195222
  Si        8.083163    2.112481   10.307762
  H         3.232474   -0.062436   12.641997
  C         3.907951    4.503628   11.274307
  H         3.878284    5.590166   11.441102
  H         3.029221    4.228533   10.678592
  H         2.981769    3.666937   13.078842
  H         4.671112    4.163448   13.266898
  C         6.635390    5.180755   11.123716
  H         6.923816    4.780442   12.102731
  C         5.482338    1.697941   13.801013
  C         3.953455    3.709687   12.568269
  H         6.191901    6.178110   11.245706
  H         7.545244    5.263093   10.519501
  H         8.671607    3.404837   10.794295
  H        10.310305    1.086987   10.299247
  H         5.836118    0.665317   13.885860
  H         4.841195    1.930249   14.662926
  H         6.359881    2.356409   13.814190
  C         7.276646    2.049093    8.695748
  H         2.261434    1.204697   11.869054
  H         2.655405    1.319462   13.605507
  C         2.433698    2.211461    8.973234
  H         2.014825    1.937370    9.947711
  H         1.785236    1.816144    8.179630
  H         2.439387    3.305429    8.898331
  C         5.156936    5.047364    8.771671
  H         5.981715    4.890907    8.065833
  H         5.101676    6.114965    9.022489
  H         4.221752    4.752888    8.282828
  H         7.106487    3.021080    8.222615
  C         7.696237    1.016743    7.658076
  H         8.287952    0.198708    8.087384
  H         6.856398    0.540381    7.122150
  C         4.382696    2.046519    7.018968
  H         4.414572    3.136805    6.927382
  H         3.547540    1.664514    6.415773
  H         5.323417    1.646027    6.630363
  H         6.908885    1.860941   11.461232
  H         8.328524    1.483425    6.884970
  C         5.881879   -1.341494   12.010689
  H         6.886880   -1.167482   12.415908
  H         5.750455   -2.418472   11.840786
  H         5.150087   -1.010306   12.753729
  C         4.046925   -1.020286    9.814454
  H         4.069380   -2.110415    9.671313
  H         3.290120   -0.791198   10.575361
  C         6.748160   -1.558973    9.405695
  H         6.637305   -1.338400    8.340290
  H         6.440257   -2.596009    9.596012
  H         7.806359   -1.452787    9.665387
  C         3.759750   -0.265966    8.525475
  H         2.723072   -0.383742    8.180177
  H         4.417781   -0.622809    7.719230
  C         3.036417    1.015612   12.621097
  C         9.375393    0.824752   10.821161
  H        10.424868    0.128259   12.622465
  H         9.100224   -0.177669   10.466585
  C         9.609132    0.807634   12.336361
  H         9.870127    1.809199   12.708891
  H         8.705251    0.489276   12.876068

62
[(dmpe)2MnH(MeHSi=CHMe)] (6Me,H) i
  Mn        5.706740    1.979242   10.292508
  P         5.894267   -0.230958   10.364785
  P         4.164342    1.540897    8.790872
  P         5.224924    4.147465   10.234740
  P         4.588104    2.011171   12.180655
  Si        8.074697    1.987143   10.329387
  C         3.881789    3.714345   12.588390
  H         2.939546    3.620207   13.146190
  H         4.608502    4.203716   13.253806
  C         5.517640    1.761143   13.769949
  H         3.402282   -0.096493   12.662624
  C         3.732775    4.506491   11.302753
  H         5.922772    0.745552   13.832613
  H         4.873817    1.944557   14.642027
  H         2.333624    1.063095   11.846137
  H         2.695018    1.251972   13.585760
  H         6.361157    2.462833   13.790050
  C         7.278793    2.101933    8.713110
  H        10.291557    3.072711   10.498868
  H         8.719767    0.700350   10.769924
  H         3.640601    5.588926   11.477070
  H         2.845225    4.180073   10.744605
  C         6.404906    5.371640   10.978100
  H         6.786426    4.987805   11.931481
  H         6.863974    2.278736   11.421773
  H         7.273479    1.175913    8.131037
  C         2.408170    2.135521    8.935456
  H         1.990435    1.845202    9.906696
  H         1.787159    1.707681    8.136399
  H         2.365247    3.228444    8.859088
  C         4.745133    5.144205    8.749440
  H         5.571621    5.179714    8.032135
  H         4.486472    6.168809    9.051106
  H         3.876262    4.696800    8.253504
  C         7.530983    3.300399    7.814782
  H         6.703087    3.491945    7.113502
  H         8.436331    3.163754    7.197617
  H         7.682365    4.228592    8.385757
  C         4.401036    1.943199    6.998386
  H         4.408959    3.027580    6.843114
  H         3.596718    1.502008    6.393314
  H         5.367727    1.544856    6.669585
  H         5.917685    6.343604   11.138838
  H         7.258046    5.513631   10.305023
  C         6.303983   -1.183355   11.893457
  H         7.276967   -0.850030   12.276201
  H         6.351573   -2.260315   11.683869
  H         5.545704   -1.008023   12.664849
  C         4.289963   -1.030052    9.853059
  H         4.429276   -2.109485    9.693091
  H         3.568153   -0.896683   10.668497
  C         7.008576   -1.149566    9.192690
  H         6.746086   -0.907773    8.155871
  H         6.900976   -2.231540    9.345208
  H         8.054347   -0.864880    9.353704
  C         3.832316   -0.305974    8.597690
  H         2.772926   -0.480421    8.363196
  H         4.417880   -0.642674    7.729662
  C         3.111990    0.960226   12.611817
  C         9.290326    3.327438   10.875221
  H         9.029851    4.321953   10.495341
  H         9.350590    3.387444   11.971496

62
[(dmpe)2MnH(MeHSi=CHMe)] (6Me,H) ii
  Mn        5.722342    1.892486   10.283947
  P         5.789284   -0.322685   10.303772
  P         4.138644    1.576302    8.792768
  P         5.380038    4.091429   10.282136
  P         4.612143    1.948843   12.176473
  Si        8.094336    1.972399   10.305132
  H         3.303176   -0.093023   12.621344
  C         3.924112    4.522650   11.372195
  H         3.913550    5.602811   11.581217
  H         3.012881    4.281551   10.808685
  H         3.068824    3.632783   13.185413
  H         4.771399    4.102401   13.313966
  C         6.649244    5.206616   11.041784
  H         6.934531    4.816279   12.026542
  C         5.527916    1.596825   13.754394
  C         4.017176    3.682248   12.632209
  H         6.261658    6.229288   11.147828
  H         7.552366    5.223751   10.421409
  H         8.801170    3.268235   10.591375
  H        10.228879    0.731363   10.585226
  H         5.862667    0.554548   13.788663
  H         4.900697    1.800410   14.634073
  H         6.416965    2.239201   13.788808
  C         7.291738    1.957943    8.689597
  H         2.302088    1.141332   11.830335
  H         2.678901    1.277018   13.571244
  C         2.425571    2.276470    8.976353
  H         2.004954    2.001172    9.950434
  H         1.765868    1.900416    8.182238
  H         2.452414    3.370914    8.914295
  C         4.950129    5.146145    8.822720
  H         5.775775    5.157297    8.103992
  H         4.744098    6.174578    9.150636
  H         4.058947    4.754978    8.318616
  C         7.540254    3.127730    7.750014
  H         6.691762    3.339675    7.081010
  H         8.412490    2.942457    7.099310
  H         7.756654    4.056879    8.298193
  C         4.363713    1.994707    7.002936
  H         4.434739    3.078771    6.862513
  H         3.520011    1.613247    6.410961
  H         5.295911    1.541899    6.646310
  H         6.885588    2.085870   11.427335
  H         7.290757    1.010274    8.145224
  C         6.122033   -1.347221   11.808647
  H         7.097419   -1.086232   12.236220
  H         6.111526   -2.418149   11.564404
  H         5.353098   -1.154219   12.565742
  C         4.138075   -1.023441    9.791034
  H         4.219604   -2.103769    9.599657
  H         3.438677   -0.878043   10.623829
  C         6.831465   -1.282084    9.093713
  H         6.530983   -1.027881    8.069907
  H         6.692105   -2.360272    9.248026
  H         7.893943   -1.038190    9.194851
  C         3.694114   -0.243209    8.566110
  H         2.621111   -0.349864    8.354017
  H         4.237314   -0.590787    7.675181
  C         3.075513    0.979721   12.590530
  C         9.233423    0.656376   11.045347
  H         9.351080    0.846248   12.122818
  H         8.880331   -0.373530   10.924073

62
[(dmpe)2MnH(MeHSi=CHMe)] (6Me,H) iii
  Mn        5.712360    1.916928   10.289488
  P         5.829319   -0.305422   10.424911
  P         4.141858    1.520143    8.796206
  P         5.289340    4.093081   10.209608
  P         4.596147    2.025273   12.179503
  Si        8.090997    2.044567   10.278941
  C         3.910718    3.749732   12.542432
  H         2.958364    3.680462   13.086451
  H         4.633441    4.241839   13.209858
  C         5.535850    1.820930   13.770251
  C         3.793344    4.519715   11.238839
  H         2.290131    1.186855   11.935305
  H         5.933104    0.805242   13.867164
  H         4.900827    2.042594   14.639953
  H         2.746669    1.298192   13.656128
  H         3.337061   -0.051715   12.653642
  H         6.385018    2.516008   13.756970
  C         7.273039    2.213533    8.681850
  H        10.288159    3.107376   10.619395
  H         8.797517    0.730960   10.475440
  H         3.723926    5.607145   11.389744
  H         2.905485    4.200752   10.677784
  C         6.490850    5.306912   10.936748
  H         6.860989    4.941620   11.901574
  H         6.896461    2.095876   11.418382
  H         8.178146    1.775625    6.755239
  C         2.369139    2.034051    9.034841
  H         1.993862    1.692193   10.005456
  H         1.736523    1.617178    8.239045
  H         2.287727    3.127344    9.001422
  C         4.899317    5.054652    8.676724
  H         5.679562    4.893736    7.922732
  H         4.833141    6.127829    8.901150
  H         3.940849    4.726137    8.259332
  H         7.175982    3.236383    8.301911
  C         7.626007    1.250147    7.551207
  H         8.274611    0.429973    7.885077
  H         6.759092    0.773858    7.062435
  C         4.252724    2.041135    7.020535
  H         4.114410    3.123252    6.931632
  H         3.471780    1.537535    6.433573
  H         5.234150    1.789246    6.609548
  H         6.022648    6.292284   11.068914
  H         7.346838    5.414189   10.260178
  C         6.078206   -1.198052   12.026248
  H         7.062718   -0.930667   12.431967
  H         6.040967   -2.285384   11.875250
  H         5.314189   -0.917539   12.758390
  C         4.225683   -1.046220    9.825935
  H         4.327643   -2.132777    9.688216
  H         3.456587   -0.868839   10.589806
  C         6.974050   -1.376731    9.423912
  H         6.817871   -1.202785    8.354947
  H         6.786284   -2.434910    9.651462
  H         8.016076   -1.136024    9.661257
  C         3.880209   -0.320916    8.534737
  H         2.856094   -0.520770    8.188005
  H         4.566279   -0.626826    7.730286
  C         3.100647    1.018914   12.654072
  C         9.288746    3.297891   11.036588
  H         9.031488    4.342179   10.833330
  H         9.353920    3.167346   12.127163

62
[(dmpe)2MnH(MeHSi=CHMe)] (6Me,H) iv
  Mn        5.719061    1.823804   10.323994
  P         5.689443   -0.405871   10.410663
  P         4.164115    1.551841    8.787387
  P         5.424188    4.032132   10.289923
  P         4.578878    1.966622   12.197621
  Si        8.083661    2.077842   10.351187
  H         3.189754   -0.039395   12.619555
  C         3.930189    4.516516   11.293854
  H         3.915252    5.603340   11.463177
  H         3.037860    4.253057   10.711713
  H         3.024171    3.694184   13.115485
  H         4.726313    4.158924   13.269815
  C         6.663390    5.171813   11.071021
  H         6.959475    4.789985   12.055454
  C         5.476250    1.674041   13.798335
  C         3.986260    3.719267   12.584931
  H         6.243447    6.181782   11.175111
  H         7.566109    5.220515   10.451285
  H         8.693829    3.354500   10.846951
  H        10.236036    0.819945   10.242250
  H         5.805034    0.632719   13.881515
  H         4.844195    1.921161   14.663410
  H         6.369499    2.311668   13.810264
  C         7.291446    2.056180    8.731209
  H         2.235652    1.265503   11.887933
  H         2.655009    1.333623   13.620847
  C         2.427824    2.194671    8.977362
  H         1.998500    1.860838    9.928882
  H         1.792015    1.839967    8.154247
  H         2.424787    3.291287    8.966843
  C         5.124254    5.033535    8.763391
  H         5.929379    4.865167    8.037470
  H         5.083610    6.103684    9.007764
  H         4.173997    4.743801    8.300901
  H         7.152133    3.041879    8.274605
  C         7.714355    1.039927    7.679811
  H         8.279749    0.200556    8.104592
  H         6.877958    0.591914    7.114194
  C         4.382753    2.063811    7.020418
  H         4.348736    3.154207    6.928404
  H         3.582952    1.632922    6.401633
  H         5.353369    1.721564    6.649127
  H         6.890162    1.866160   11.476165
  H         8.374288    1.510234    6.931773
  C         5.857205   -1.355784   11.990992
  H         6.856976   -1.185761   12.411268
  H         5.725058   -2.431906   11.812988
  H         5.115594   -1.027811   12.726553
  C         4.041120   -1.022198    9.790087
  H         4.064712   -2.112051    9.642138
  H         3.279303   -0.796661   10.548103
  C         6.736443   -1.555687    9.382957
  H         6.612437   -1.332806    8.318800
  H         6.434929   -2.595125    9.572928
  H         7.798214   -1.447416    9.626516
  C         3.763156   -0.261422    8.503570
  H         2.729199   -0.377570    8.148322
  H         4.428239   -0.612718    7.700153
  C         3.016955    1.043375   12.624663
  C         9.323164    0.743121   10.850268
  H         9.611177    0.892595   11.901094
  H         8.935343   -0.277203   10.754672

75
[(dmpe)2MnH(PhEtSi=CHMe)] (6Ph,Et) i
   Mn        5.720291    1.917830   10.305337
   P         5.795571   -0.301327   10.307852
   P         4.154701    1.574600    8.791266
   P         5.288186    4.114929   10.252193
   P         4.577077    1.963967   12.176239
   Si        8.119166    1.984958   10.399925
   C         3.937125    3.686261   12.602659
   H         2.998846    3.623820   13.171702
   H         4.689661    4.146153   13.260586
   C         5.471913    1.638758   13.771588
   C        10.821058    5.187586   10.422142
   H        11.469072    5.676348    9.692739
   H         5.832711    0.604844   13.811467
   H         4.824249    1.825700   14.639960
   C        10.001118    4.129197   10.025813
   H        10.023659    3.801513    8.985134
   H         6.343406    2.303521   13.822660
   C         7.337256    2.028815    8.771039
   C         9.142881    3.488511   10.934146
   H        10.017744    1.416734   12.838608
   C        10.814128    5.618439   11.748772
   H        11.454965    6.443809   12.061678
   C         9.985480    4.982530   12.674987
   H         9.980980    5.307674   13.716726
   H         6.880270    2.106385   11.474853
   H         7.376334    1.083240    8.220895
   C         2.432212    2.269129    8.919208
   H         1.987505    1.990693    9.882077
   H         1.803042    1.874922    8.109415
   H         2.438845    3.362466    8.850012
   C         4.815205    5.096529    8.752722
   H         5.663368    5.163293    8.063539
   H         4.519814    6.110898    9.054541
   H         3.977282    4.631705    8.223125
   C         7.541286    3.201629    7.827096
   H         6.703663    3.337430    7.126397
   H         8.445395    3.073973    7.204767
   H         7.664596    4.152605    8.364095
   C         4.424468    1.943136    6.995095
   H         4.493568    3.021851    6.819516
   H         3.599512    1.536553    6.393534
   H         5.368458    1.484123    6.678695
   C         9.161517    3.934636   12.266536
   H         8.508676    3.459527   13.002933
   C         6.151969   -1.348324   11.791770
   H         7.147503   -1.128108   12.192861
   H         6.095316   -2.415561   11.537354
   H         5.412774   -1.136279   12.573349
   C         4.139247   -1.008430    9.824512
   H         4.221469   -2.090781    9.645463
   H         3.446317   -0.854102   10.660124
   C         6.787945   -1.247961    9.043566
   H         6.438066   -0.978576    8.039381
   H         6.650256   -2.327610    9.189921
   H         7.855283   -1.013609    9.091063
   C         3.687822   -0.243773    8.594166
   H         2.610542   -0.337792    8.400042
   H         4.211018   -0.612909    7.700534
   C         3.051694    0.970887   12.575886
   H         2.290677    1.105367   11.797727
   H         2.630198    1.277389   13.543313
   H         3.298571   -0.096634   12.630761
   C         3.800251    4.489451   11.322093
   H         3.731954    5.572064   11.505503
   H         2.903182    4.186165   10.767193
   C         6.446434    5.364488   10.975148
   H         6.717797    5.075741   11.996308
   H         5.973662    6.356290   10.987877
   H         7.373576    5.411748   10.393993
   C         9.185959    0.533565   11.020801
   H        10.140616    0.608595   10.474105
   H         8.744878   -0.424625   10.720229
   C         9.458073    0.524782   12.528865
   H         8.523862    0.510580   13.110115
   H        10.047044   -0.354513   12.828600

75
[(dmpe)2MnH(PhEtSi=CHMe)] (6Ph,Et) ii
   Mn        5.738617    1.929784   10.305129
   P         5.806461   -0.306830   10.332750
   P         4.184705    1.583921    8.776424
   P         5.277166    4.111719   10.279523
   P         4.603748    1.953653   12.183709
   Si        8.131180    2.042279   10.375661
   C        10.016717   -0.784514   12.829361
   H        10.009249   -1.046660   13.888678
   C        10.870359   -1.454304   11.950941
   H        11.529609   -2.241172   12.319372
   H         2.991975    3.574285   13.187712
   H         4.669881    4.136303   13.275828
   C        10.879773   -1.106461   10.599612
   H        11.549799   -1.620139    9.908284
   C         5.524042    1.645398   13.767532
   C         3.927840    3.659639   12.618059
   C         9.174033    0.220355   12.352208
   H         8.512990    0.736111   13.053234
   H        10.915122    2.572741   11.770008
   C         9.155794    0.576994   10.994434
   H         5.920716    0.624401   13.792503
   H         4.880570    1.802527   14.644871
   H         6.371882    2.340769   13.813484
   C         7.350048    2.032455    8.749004
   C        10.034421   -0.099238   10.132626
   H        10.053925    0.169656    9.073700
   C         2.446541    2.232692    8.930551
   H         2.018821    1.933420    9.894825
   H         1.817467    1.834916    8.122571
   H         2.428880    3.326931    8.874393
   C         4.822378    5.120871    8.793551
   H         5.666592    5.168320    8.097427
   H         4.552041    6.140741    9.100440
   H         3.969386    4.676879    8.269263
   C         7.562714    3.198851    7.798553
   H         6.723743    3.351201    7.102770
   H         8.463139    3.058108    7.174952
   H         7.701241    4.150962    8.332288
   C         4.431757    2.000771    6.989090
   H         4.486931    3.083688    6.836725
   H         3.603565    1.598504    6.389069
   H         5.375458    1.557847    6.650524
   H         6.898574    2.130073   11.464853
   H         7.385856    1.078745    8.213743
   C         6.092687   -1.355490   11.826609
   H         7.106707   -1.195850   12.209056
   H         5.972700   -2.416808   11.569393
   H         5.373708   -1.103038   12.614031
   C         4.158492   -0.992307    9.791615
   H         4.234513   -2.077629    9.629497
   H         3.433203   -0.819000   10.595995
   C         6.855128   -1.276043    9.145732
   H         6.684835   -0.929231    8.119625
   H         6.599446   -2.342152    9.210805
   H         7.916237   -1.148967    9.379716
   C         3.769551   -0.236383    8.536632
   H         2.709571   -0.352040    8.270926
   H         4.362316   -0.588549    7.679890
   C         3.097545    0.935813   12.591781
   H         2.322198    1.082458   11.830014
   H         2.691191    1.220854   13.572094
   H         3.351036   -0.130722   12.619351
   C         3.772350    4.457167   11.336493
   H         3.676961    5.538285   11.516130
   H         2.885258    4.129416   10.780228
   C         6.405761    5.362531   11.058826
   H         6.732862    5.008776   12.043328
   H         5.890127    6.326403   11.170446
   H         7.296673    5.507124   10.439610
   C         9.182873    3.559297   10.871423
   H         8.815124    3.957088   11.829083
   H         9.000273    4.348509   10.127175
   C        10.688333    3.291588   10.971587
   H        11.091283    2.869632   10.040162
   H        11.243670    4.216369   11.185773

75
[(dmpe)2MnH(PhEtSi=CHMe)] (6Ph,Et) iii
   Mn        5.739111    1.853881   10.296488
   P         5.715710   -0.380351   10.372533
   P         4.149960    1.560874    8.789480
   P         5.356940    4.060123   10.253068
   P         4.612089    1.971524   12.181922
   Si        8.131021    2.046807   10.313008
   C         3.938468    3.698349   12.549548
   H         2.983151    3.634541   13.088851
   H         4.661528    4.184719   13.220691
   C         5.545738    1.740587   13.771640
   C        10.645860    5.373342   10.431250
   H        11.189345    5.968305    9.695358
   H         5.944604    0.722910   13.846684
   H         4.910811    1.944089   14.645717
   C         9.834187    4.317575   10.013113
   H         9.744638    4.095981    8.946915
   H         6.393984    2.436746   13.772582
   C         7.317640    2.111942    8.705663
   C         9.118540    3.536462   10.934707
   H        10.188948    1.282579   12.571536
   C        10.764679    5.665519   11.790421
   H        11.400010    6.488083   12.121362
   C        10.070842    4.894834   12.725323
   H        10.163465    5.115714   13.790042
   H         6.939887    1.924312   11.440356
   H         8.376489    1.587572    6.882608
   C         2.417455    2.218068    8.984338
   H         2.012216    1.950126    9.967144
   H         1.765779    1.802497    8.203618
   H         2.405279    3.310427    8.893335
   C         5.020926    5.020978    8.707775
   H         5.842505    4.877993    7.994815
   H         4.929035    6.091539    8.934484
   H         4.091739    4.681910    8.237253
   H         7.197419    3.115266    8.282264
   C         7.708615    1.115386    7.622547
   H         8.254375    0.250371    8.020687
   H         6.860746    0.701991    7.049608
   C         4.339703    2.023519    7.005825
   H         4.340504    3.111644    6.886995
   H         3.510809    1.603322    6.418918
   H         5.288091    1.640219    6.618107
   C         9.259765    3.844016   12.297693
   H         8.715929    3.259280   13.043547
   C         5.990076   -1.340526   11.930461
   H         7.022491   -1.189032   12.270110
   H         5.826344   -2.413619   11.761790
   H         5.315517   -1.000884   12.723221
   C         4.028424   -0.984708    9.852709
   H         4.028057   -2.078025    9.733243
   H         3.303007   -0.725281   10.633154
   C         6.657862   -1.541214    9.254294
   H         6.515269   -1.259638    8.206635
   H         6.292358   -2.566003    9.407794
   H         7.731530   -1.521706    9.463354
   C         3.713343   -0.252500    8.559268
   H         2.664920   -0.358301    8.247029
   H         4.340201   -0.634071    7.739860
   C         3.101978    0.983987   12.650912
   H         2.311509    1.124218   11.903512
   H         2.722587    1.305054   13.630831
   H         3.335008   -0.086007   12.703350
   C         3.831558    4.470002   11.246075
   H         3.758869    5.556600   11.399984
   H         2.951308    4.150232   10.676814
   C         6.489539    5.299243   11.036791
   H         6.781228    4.970262   12.039794
   H         5.985739    6.273495   11.100293
   H         7.406704    5.405584   10.448893
   C         9.286020    0.590181   10.706065
   H        10.207749    0.758795   10.124562
   H         8.851304   -0.337724   10.315958
   C         9.636164    0.415425   12.187042
   H         8.733539    0.305936   12.807013
   H        10.261599   -0.473642   12.354763

75
[(dmpe)2MnH(PhEtSi=CHMe)] (6Ph,Et) iv
   Mn        5.733639    1.884826   10.356237
   P         5.740048   -0.367058   10.478547
   P         4.230798    1.559390    8.771178
   P         5.310177    4.072003   10.299239
   P         4.534603    1.982272   12.199502
   Si        8.122787    2.091283   10.427008
   C         9.930428   -0.979495   12.623786
   H         9.847401   -1.378460   13.636251
   C        10.869953   -1.511984   11.739281
   H        11.518202   -2.330698   12.054103
   H         2.881761    3.631015   13.083894
   H         4.552933    4.202017   13.228567
   C        10.982617   -0.981607   10.453701
   H        11.723530   -1.383409    9.760563
   C         5.401448    1.737264   13.823712
   C         3.842159    3.701519   12.554520
   C         9.099670    0.063183   12.212488
   H         8.371231    0.472758   12.916703
   H        10.890757    2.532731   11.856914
   C         9.179492    0.599394   10.917029
   H         5.790767    0.717281   13.911577
   H         4.732524    1.940689   14.672141
   H         6.252655    2.429153   13.861308
   C         7.349848    2.108800    8.795844
   C        10.152150    0.066359   10.054179
   H        10.262780    0.476035    9.048558
   C         2.452197    2.092969    8.925166
   H         2.021668    1.734362    9.866714
   H         1.861516    1.696071    8.088226
   H         2.378478    3.186673    8.907363
   C         5.007948    5.053358    8.757329
   H         5.830015    4.901005    8.047118
   H         4.929381    6.123498    8.991093
   H         4.075292    4.732277    8.280843
   H         7.254010    3.110960    8.360339
   C         7.706574    1.090517    7.722278
   H         8.223728    0.214465    8.128095
   H         6.842353    0.696934    7.160349
   C         4.439448    2.116831    7.014363
   H         4.271081    3.194723    6.930151
   H         3.711462    1.598856    6.374401
   H         5.450916    1.900575    6.660474
   H         6.891394    1.994098   11.530944
   H         8.383225    1.535175    6.972951
   C         5.795692   -1.313210   12.068628
   H         6.797645   -1.225392   12.504820
   H         5.591356   -2.375352   11.876082
   H         5.063566   -0.939656   12.790415
   C         4.139109   -1.005045    9.762252
   H         4.189087   -2.096040    9.630816
   H         3.326676   -0.782898   10.467146
   C         6.862511   -1.519474    9.546390
   H         6.786120   -1.336586    8.470349
   H         6.569577   -2.557291    9.756589
   H         7.903161   -1.372309    9.851027
   C         3.933017   -0.263515    8.453672
   H         2.936148   -0.421417    8.017801
   H         4.675931   -0.585954    7.708579
   C         2.993574    1.004785   12.580906
   H         2.217601    1.238559   11.842112
   H         2.614136    1.259595   13.580159
   H         3.182902   -0.073645   12.543465
   C         3.744172    4.454455   11.240226
   H         3.631891    5.540217   11.375288
   H         2.891198    4.096639   10.651288
   C         6.390279    5.329924   11.139794
   H         6.719477    4.962192   12.117836
   H         5.841298    6.272868   11.268287
   H         7.280708    5.524064   10.533822
   C         9.131550    3.577731   11.081025
   H         8.756656    3.861059   12.076695
   H         8.931793    4.434346   10.422956
   C        10.643361    3.337337   11.152267
   H        11.054772    3.044175   10.176114
   H        11.174343    4.243852   11.477665

77
[(dmpe)2MnH(nBuEtSi=CHMe)] (6Bu,Et) i
  Mn        5.726790    1.930046   10.287178
  P         5.797596   -0.291812   10.280335
  P         4.128262    1.608814    8.805990
  P         5.294674    4.118212   10.306521
  P         4.630556    1.940086   12.188917
  Si        8.138751    1.966167   10.289689
  H         3.383059   -0.143005   12.648180
  C         3.798548    4.457259   11.379186
  H         3.706843    5.536445   11.570259
  H         2.906615    4.136059   10.827946
  H         4.718477    4.112593   13.303936
  C         5.567981    1.609951   13.759901
  C         6.452380    5.328054   11.115961
  H         6.900770    4.882756   12.010940
  C        10.665424    3.315217   10.102251
  H         3.036839    3.558102   13.230468
  C         9.468398    0.662989   12.472029
  H         5.916734    6.247405   11.389181
  C         9.243133    3.473781   10.655393
  C         9.154964    0.506913   10.978513
  H         5.942248    0.580686   13.778643
  H         4.939346    1.778666   14.645503
  H         6.431765    2.285313   13.795258
  C         7.289279    2.004130    8.691657
  H         7.261325    5.590087   10.426274
  C         3.966105    3.646000   12.651064
  C         2.406252    2.299295    8.980404
  H         1.988640    2.035091    9.958890
  H         1.754618    1.896553    8.193402
  H         2.414293    3.391681    8.894878
  C         4.850588    5.172198    8.848207
  H         5.689310    5.211637    8.145282
  H         4.609128    6.191758    9.178598
  H         3.982048    4.759567    8.323636
  C         7.517733    3.183443    7.758349
  H         6.666893    3.374452    7.086797
  H         8.397081    3.026074    7.108976
  H         7.699927    4.119464    8.305986
  C         4.350627    2.020824    7.012052
  H         4.423370    3.103841    6.866895
  H         3.505447    1.638166    6.423572
  H         5.281088    1.564728    6.655690
  H         6.934323    2.148181   11.402047
  H         7.264835    1.067408    8.128812
  C         6.149192   -1.342693   11.766012
  H         7.127438   -1.098193   12.193759
  H         6.129077   -2.408505   11.502137
  H         5.386619   -1.158716   12.531360
  C         4.136228   -0.992272    9.798283
  H         4.218504   -2.071491    9.602725
  H         3.451161   -0.851626   10.642357
  C         6.787985   -1.241437    9.014510
  H         6.416097   -0.994642    8.012728
  H         6.670999   -2.320279    9.180104
  H         7.850895   -0.985480    9.041780
  C         3.670484   -0.210108    8.583636
  H         2.592662   -0.309346    8.396698
  H         4.189824   -0.559738    7.680129
  C         3.124959    0.921891   12.608437
  H         2.348691    1.056144   11.845811
  H         2.719378    1.215121   13.586250
  H        10.091972    0.457387   10.401548
  H         8.654143   -0.451783   10.806236
  H        10.045633   -0.187931   12.861839
  H         8.547395    0.739647   13.068278
  H        10.053795    1.571544   12.669323
  H         9.265767    3.664476   11.739619
  H         8.791196    4.365441   10.202763
  H        10.967720    5.081867   12.329729
  H        10.607152    3.080467    9.027139
  H        11.161931    2.451277   10.573506
  C        11.556611    4.548775   10.293378
  H        11.066795    5.420951    9.829971
  H        12.498385    4.396110    9.742750
  C        11.876229    4.856532   11.755048
  H        12.370065    3.999168   12.236234
  H        12.546853    5.721409   11.845486

77
[(dmpe)2MnH(nBuEtSi=CHMe)] (6Bu,Et) ii
Mn       5.71676078       1.94099745      10.29751070
P       5.82613773      -0.27950003      10.28570389
P       4.14936189       1.58893818       8.79004621
P       5.23527938       4.12104564      10.29779240
P       4.59202338       1.93378157      12.18289252
Si       8.13106429       2.01926749      10.34651561
H       3.36419749      -0.16297551      12.62616833
C       3.72315086       4.43138410      11.35659431
H       3.60410999       5.50918383      11.54018922
H       2.84300888       4.08511773      10.80143896
H       4.64741428       4.11362787      13.28380712
C       5.50466433       1.61354132      13.77063003
C       6.35411615       5.37227642      11.10013279
H       6.81626339       4.95088755      11.99951778
C      10.59698690       3.45594933      10.09530697
H       2.97370591       3.53405868      13.21411927
C       9.33924872       0.61463841      12.55229088
H       5.78914838       6.27685220      11.36358389
C       9.20812610       3.53893815      10.74210770
C       9.15127450       0.56327685      11.03191323
H       5.88320084       0.58596693      13.79987340
H       4.85913487       1.78185049      14.64407578
H       6.36467365       2.29270538      13.81982082
C       7.30679340       2.05480236       8.73499200
H       7.15291217       5.65488524      10.40611921
C       3.90175574       3.63165704      12.63423827
C       2.41548632       2.25894019       8.92355791
H       1.97791325       1.98173879       9.88979344
H       1.78959469       1.85108146       8.11852446
H       2.40849401       3.35159672       8.84520240
C       4.78029296       5.15207237       8.82605244
H       5.63043206       5.21629918       8.13881864
H       4.50033043       6.16460819       9.14751213
H       3.93585505       4.71029613       8.28671851
C       7.53088340       3.24615937       7.81600160
H       6.68967110       3.42634985       7.12935226
H       8.42524262       3.11124556       7.18226539
H       7.68501164       4.18048273       8.37535526
C       4.40967690       1.98854553       6.99829079
H       4.47036754       3.07112257       6.84486664
H       3.58604688       1.58773139       6.39170182
H       5.35622573       1.54383488       6.67079913
H       6.90290625       2.18277969      11.43316289
H       7.31218237       1.12212353       8.16468065
C       6.18666239      -1.33508973      11.76558455
H       7.16696390      -1.09299825      12.18884764
H       6.16493852      -2.39975687      11.49708673
H       5.42787734      -1.15388091      12.53546378
C       4.17944569      -1.00713912       9.79431261
H       4.28088430      -2.08538839       9.60239088
H       3.48670053      -0.87558438      10.63339503
C       6.83287388      -1.20573019       9.01519906
H       6.45539416      -0.95968392       8.01530111
H       6.73458255      -2.28735122       9.17490040
H       7.89123859      -0.93223412       9.04130982
C       3.70983654      -0.23597945       8.57444306
H       2.63328411      -0.34509197       8.38625686
H       4.23335018      -0.58619804       7.67376401
C       3.09179145       0.89808360      12.57757480
H       2.32845802       1.01911960      11.79979917
H       2.66394968       1.18891819      13.54659347
H      10.13535430       0.58163724      10.53523450
H       8.70633729      -0.40141874      10.75990797
H      10.74556598       0.31996817      14.97982828
H       8.35496626       0.69424652      13.04439546
H       9.88355117       1.53040488      12.83505907
H       9.30058689       3.65711234      11.83360610
H       8.70087888       4.44230377      10.38735100
H      11.18965171       4.36216816      10.28721429
H      10.51787495       3.33808772       9.00505366
H      11.17664056       2.60291231      10.47333829
C      10.07858839      -0.59868815      13.11936976
H      11.07950103      -0.65604117      12.66203202
H       9.55248273      -1.51602641      12.80628221
C      10.20128519      -0.57304965      14.64068267
H       9.20922876      -0.55447967      15.11521533
H      10.73618575      -1.45411667      15.01980759

77
[(dmpe)2MnH(nBuEtSi=CHMe)] (6Bu,Et) iii
Mn       5.71434578       1.87074872      10.32651018
P       5.71336186      -0.37043578      10.37676510
P       4.19076269       1.60026238       8.75500118
P       5.32684097       4.06397801      10.38524569
P       4.49411514       1.92054411      12.15708659
Si       8.11359298       2.09121754      10.36531501
H       3.30091969      -0.21424176      12.60540792
C       3.68687882       4.41100578      11.20799271
H       3.57250241       5.48971538      11.38757233
H       2.88293099       4.09371731      10.53715227
H       4.26755220       4.09857644      13.26878918
C       5.37068878       1.74119723      13.78766356
C       6.32936820       5.20711962      11.46247301
H       6.61785723       4.69618684      12.38790545
C      10.60756874       3.51801991      10.50404902
H       2.66253433       3.45334611      12.89438932
C       9.40142663       0.67678382      12.48492776
H       5.74271036       6.10255785      11.70789169
C       9.11291985       3.64988426      10.81946863
C       9.18749622       0.64128512      10.96606502
H       5.82948421       0.74993127      13.87238789
H       4.68963910       1.89746414      14.63603023
H       6.17531071       2.48612893      13.82629280
C       7.31281958       2.06548125       8.74762676
H       7.24349885       5.51911552      10.95111084
C       3.67391591       3.59690770      12.49143948
C       2.43603206       2.22099806       8.88486343
H       2.00437625       1.97986926       9.86299138
H       1.81771428       1.76808692       8.09837465
H       2.40904119       3.30902071       8.75236089
C       5.20304599       5.16413553       8.90207625
H       6.11243592       5.07516757       8.29481930
H       5.07218910       6.21261284       9.20127535
H       4.34809608       4.86485541       8.28527500
H       7.19807270       3.06082814       8.30309050
H      13.33487203       3.88896635      11.10679197
H      10.74022216       3.20622455       9.45395167
H      11.05556560       2.71687004      11.11316943
C       4.44769849       2.14232053       7.00182563
H       4.47199027       3.23580883       6.94666364
H       3.63156636       1.77327838       6.36541249
H       5.40191503       1.76373582       6.62540892
H       6.89392940       1.99022898      11.48105745
H       8.33442039       1.52514506       6.91392390
C       5.92347951      -1.33483703      11.94486797
H       6.95578349      -1.21173875      12.29654060
H       5.73341968      -2.40308119      11.77477780
H       5.25256604      -0.97561349      12.73035440
C       4.06307556      -0.97890315       9.74567562
H       4.08406913      -2.06819128       9.59694674
H       3.29015683      -0.74993202      10.48838411
C       6.72231248      -1.53429471       9.31680783
H       6.56787286      -1.31372181       8.25697803
H       6.40174746      -2.56478109       9.52080888
H       7.79313730      -1.45385090       9.52323155
C       3.80964226      -0.21685085       8.45311496
H       2.78469417      -0.34068095       8.07700606
H       4.49334995      -0.56166782       7.66351102
C       3.02199070       0.84382724      12.55446798
H       2.25665090       0.95812047      11.77710322
H       2.58962450       1.13662210      13.52069351
H      10.15687408       0.67409086      10.44481080
H       8.72701293      -0.31236671      10.68484766
H      10.01322704      -0.16649308      12.83654446
H       8.44183331       0.63791853      13.02096195
H       9.90570905       1.60039755      12.80255181
H       8.98013040       3.92914055      11.87679356
H       8.70839428       4.48139350      10.22474813
C       7.70190065       1.04961264       7.68135770
H       8.28687091       0.21399311       8.08497272
H       6.85384228       0.59569439       7.13930625
C      11.39368826       4.80817676      10.74485366
H      11.24017863       5.12889907      11.78835220
H      10.97241594       5.60933240      10.11593616
C      12.88750990       4.66222720      10.46544835
H      13.06811252       4.36926317       9.42116447
H      13.42852066       5.60052613      10.64764316

77
[(dmpe)2MnH(nBuEtSi=CHMe)] (6Bu,Et) iv
  Mn        5.713890    1.887937   10.296196
  P         5.746033   -0.350206   10.357670
  P         4.132394    1.564790    8.791106
  P         5.259592    4.071949   10.280765
  P         4.591941    1.947915   12.186960
  Si        8.127186    2.118156   10.318067
  H         3.364833   -0.145632   12.695205
  C         3.715465    4.417739   11.274627
  H         3.593961    5.499868   11.427103
  H         2.848430    4.056205   10.711547
  H         4.587882    4.160014   13.235833
  C         5.533337    1.719395   13.774789
  C         6.345254    5.332323   11.120536
  H         6.800562    4.914013   12.024472
  C        10.606599    3.531716   10.322638
  H         2.925743    3.555100   13.132109
  C         9.488160    0.616700   12.342514
  H         5.755858    6.221596   11.381720
  C         9.166193    3.625635   10.845248
  C         9.195926    0.633583   10.837893
  H         5.949800    0.708392   13.838821
  H         4.895336    1.901675   14.650981
  H         6.370291    2.428716   13.782303
  C         7.298820    2.138415    8.711874
  H         7.148263    5.640929   10.443535
  C         3.868795    3.651445   12.577103
  C         2.390357    2.207972    8.968994
  H         1.982386    1.951242    9.953413
  H         1.748809    1.772822    8.191161
  H         2.367347    3.298146    8.859388
  C         4.917325    5.074017    8.760781
  H         5.761361    4.986621    8.065201
  H         4.775851    6.131763    9.019817
  H         4.015330    4.713506    8.255101
  H         7.179340    3.141748    8.285992
  H        11.180044    4.440812   10.554206
  H        10.621895    3.400282    9.230803
  H        11.150383    2.683355   10.759552
  C         4.337313    2.031465    7.009354
  H         4.414544    3.118141    6.904033
  H         3.481041    1.674947    6.420354
  H         5.256733    1.589517    6.614453
  H         6.916669    2.053007   11.428866
  H         8.357515    1.637084    6.884606
  C         6.051080   -1.320139   11.907206
  H         7.075805   -1.138209   12.254033
  H         5.923670   -2.395576   11.724666
  H         5.362624   -1.013290   12.700957
  C         4.066004   -0.989041    9.847428
  H         4.090447   -2.080840    9.719341
  H         3.343776   -0.753489   10.637384
  C         6.697576   -1.486570    9.218116
  H         6.500664   -1.223396    8.174719
  H         6.377245   -2.521826    9.397035
  H         7.777064   -1.421840    9.379583
  C         3.715950   -0.256095    8.562309
  H         2.663323   -0.376849    8.271836
  H         4.330800   -0.625825    7.729038
  C         3.104996    0.917897   12.645755
  H         2.314883    1.041623   11.895269
  H         2.714677    1.225458   13.625268
  H        10.140602    0.651752   10.270160
  H         8.700725   -0.305067   10.562857
  H        10.982206    0.224521   14.694305
  H         8.537032    0.659767   12.901170
  H        10.039120    1.526556   12.632331
  H         9.164214    3.738480   11.941454
  H         8.705417    4.533961   10.444145
  C         7.705111    1.148219    7.626856
  H         8.274359    0.297607    8.022124
  H         6.865812    0.714750    7.056560
  C        10.278470   -0.608015   12.806118
  H        11.262597   -0.609899   12.309933
  H         9.763793   -1.519118   12.458428
  C        10.458343   -0.667256   14.321088
  H         9.484342   -0.714319   14.829949
  H        11.037972   -1.548072   14.628220

82
cis-[(dmpe)2Mn(SiH2Ph)(xylylNC)] (cis-7a)
   Mn        5.899224    7.007822    4.355942
   P         6.424842    6.852654    6.501084
   P         3.878034    7.563652    5.082495
   P         5.396118    7.165859    2.204568
   P         5.551680    4.784288    4.035988
   Si        8.142622    6.447332    3.889318
   N         6.696251    9.904488    4.382464
   C         7.277617   11.140050    4.392736
   C         7.897724   11.639272    3.220492
   C         7.239143   11.919181    5.575901
   C         6.411684    8.729316    4.350683
   C         9.443980    7.737943    3.349125
   C         9.830414    8.817732    4.161417
   H         9.359798    8.959762    5.134001
   C        10.084918    7.616485    2.103472
   H         9.823945    6.781449    1.449713
   C         7.883665   13.156249    5.581782
   H         7.866573   13.751470    6.496556
   C         7.880459   10.835464    1.959766
   H         6.849608   10.595059    1.659873
   H         8.409595    9.882482    2.096926
   H         8.361425   11.381414    1.140335
   C        11.053827    8.528991    1.683138
   H        11.531623    8.404951    0.709516
   C        10.801386    9.732332    3.754358
   H        11.068269   10.566007    4.405674
   C         8.525185   12.883567    3.277958
   H         9.019124   13.260529    2.380876
   C         6.709570    7.360362    0.925237
   H         7.402860    6.513445    0.987442
   H         6.274969    7.407123   -0.082580
   H         7.282208    8.272648    1.119527
   C         6.670547    5.239692    7.366699
   H         5.791934    4.595413    7.240836
   H         7.544367    4.738359    6.934143
   H         6.846125    5.401240    8.438835
   C         7.894358    7.726939    7.182204
   H         7.917916    8.754460    6.804681
   H         7.869820    7.740838    8.280239
   H         8.803588    7.213672    6.846670
   C         3.413077    9.351880    5.022715
   H         4.208854    9.951538    5.475680
   H         3.311022    9.677387    3.981406
   H         2.466794    9.529971    5.550587
   C         6.502652   11.433940    6.789088
   H         6.873015   10.460179    7.135715
   H         5.430975   11.305062    6.575901
   H         6.598378   12.149366    7.614371
   C        11.414444    9.594390    2.508574
   H        12.169735   10.311509    2.184001
   C         5.070804    7.597093    7.557233
   H         5.150265    7.248750    8.597228
   H         5.233265    8.685235    7.556012
   C         2.238992    6.882526    4.543535
   H         2.172739    5.814420    4.769536
   H         1.422636    7.401853    5.064315
   H         2.104439    7.017137    3.463191
   C         8.535393   13.638737    4.448663
   H         9.039372   14.604967    4.475303
   C         4.053469    3.894758    4.688451
   H         3.160888    4.223660    4.145652
   H         3.911188    4.110276    5.754755
   H         4.162855    2.809731    4.556310
   C         5.329729    4.443535    2.216239
   H         6.341648    4.358545    1.793073
   H         4.821494    3.478884    2.072242
   C         6.773338    3.455152    4.441141
   H         7.791150    3.759397    4.174684
   H         6.739802    3.227486    5.511480
   H         6.508978    2.547078    3.882171
   C         4.583013    5.609975    1.587001
   H         3.533646    5.627678    1.918235
   H         4.589454    5.572099    0.487740
   C         4.231629    8.459732    1.592860
   H         3.257256    8.359164    2.084593
   H         4.638644    9.449844    1.834041
   H         4.092537    8.385384    0.505892
   C         3.730128    7.262298    6.922123
   H         2.899269    7.843104    7.349214
   H         3.493484    6.195014    7.053857
   H         8.878903    5.744390    5.022452
   H         8.355159    5.424052    2.780773

78
cis-[(dmpe)2Mn(SiH2Et)(xylylNC)] (cis-7b*)
  Mn       11.935973    9.225972   12.531908
  P        13.857165   10.064835   11.811118
  Si       10.832648   10.754537   11.111954
  P         9.907253    8.517990   13.065898
  P        12.149472    7.840260   10.743775
  P        12.654567    7.768982   14.037361
  N        11.709634   11.373851   14.619589
  C        11.836483   10.517903   13.768730
  C        11.970805   12.299813   15.592817
  C        10.877403   12.937475   16.237366
  C        13.300142   12.622050   15.970084
  C        11.135450    8.047623    9.210613
  H        11.224986    9.076564    8.843013
  H        11.474880    7.347389    8.435876
  H        10.078672    7.861478    9.426003
  C        11.133036   13.886649   17.224996
  H        10.287789   14.374729   17.712900
  C        10.296099   12.473338   11.764059
  H         9.552448   12.303255   12.558161
  H        11.142898   12.968674   12.262979
  C        14.055202   11.886169   11.623936
  H        13.306807   12.247533   10.908349
  H        13.877060   12.379659   12.584828
  H        15.059196   12.143258   11.261574
  C        12.436364   14.214678   17.596203
  H        12.617793   14.958377   18.371825
  C        15.482757    9.644041   12.610113
  H        15.452000    9.833482   13.688025
  H        15.682091    8.576894   12.456447
  H        16.303746   10.226010   12.169512
  H        10.490263   13.714761    9.981061
  C        11.277329    6.583917   14.491151
  H        11.505173    6.068364   15.435712
  C        13.502579   13.577036   16.969681
  H        14.527008   13.819728   17.258318
  C        14.078999    6.586746   13.891102
  H        14.117685    6.119860   12.901528
  H        11.222991    5.824618   13.697049
  C         9.984879    7.385802   14.558655
  H         9.987260    8.040052   15.443690
  H         9.089379    6.750833   14.616795
  C         9.470604   12.579703   15.865790
  H         9.242872   11.538952   16.141111
  H         9.308969   12.667809   14.782893
  H         8.753481   13.228726   16.381760
  C        14.248149    9.484977   10.086551
  H        13.637802   10.090529    9.401536
  H        15.307588    9.654696    9.847409
  C        14.480487   11.970111   15.314479
  H        14.193078   11.035841   14.825085
  H        15.268224   11.757193   16.048965
  H        14.923124   12.620897   14.545588
  C         8.622228    9.710770   13.617382
  H         9.054612   10.395573   14.351128
  H         8.281112   10.293277   12.752747
  H         7.764462    9.185286   14.057811
  H        15.014518    7.137429   14.043668
  H        14.009684    5.800582   14.655919
  H        11.569517   11.131114    9.827164
  H         9.522492   10.265074   10.501896
  C        13.069956    8.397529   15.728392
  H        12.258302    9.031118   16.103075
  H        13.245039    7.568031   16.426584
  H        13.975202    9.013797   15.677821
  C         8.837103    7.521572   11.935252
  H         9.334436    6.594427   11.632679
  H         7.891582    7.270466   12.433722
  H         8.620379    8.120229   11.042519
  C        12.052271    5.988796   10.830645
  H        12.652729    5.598725   11.658038
  H        11.014380    5.672288   10.983818
  H        12.410391    5.548141    9.890193
  C        13.853481    8.018751   10.004739
  H        14.535360    7.395981   10.603731
  H        13.862965    7.629821    8.976276
  C         9.708981   13.374216   10.674942
  H         8.960706   12.836961   10.073811
  H         9.220585   14.269628   11.089748

78
cis-[(dmpe)2Mn(SiH2Ph)(tBuNC)] (cis-7c)
   Mn       -2.681317   13.615404    3.496155
   P        -3.056125   11.718199    4.573971
   P        -4.834782   13.998157    3.822196
   P        -2.309285   15.530658    2.463658
   Si       -0.416854   12.961275    3.363964
   H        -0.164785   11.465372    3.504835
   H         0.273245   13.214455    2.028839
   P        -2.800567   12.761078    1.407965
   N        -2.033451   14.924791    6.123642
   C        -2.251988   14.427776    5.049262
   C         1.916876   14.542686    4.068041
   H         1.891304   14.870035    3.027228
   C         0.945582   13.637123    4.529071
   C        -5.298778   15.102599    5.232907
   H        -4.787982   14.763396    6.141030
   H        -6.385104   15.103743    5.394204
   H        -4.963475   16.126553    5.032384
   C        -1.538079   15.894109    7.059362
   C        -4.781277   11.700929    5.306880
   H        -5.104927   10.670335    5.512898
   H        -4.714558   12.227373    6.271301
   C         1.056014   13.221912    5.867463
   H         0.333881   12.513212    6.273019
   C        -2.089499   11.282725    6.078110
   H        -1.087121   10.955088    5.777587
   H        -2.579181   10.470740    6.632752
   H        -2.000455   12.168028    6.719059
   C         2.076147   13.681757    6.701137
   H         2.138785   13.325424    7.731313
   C         3.017180   14.593856    6.221409
   H         3.813678   14.958949    6.871023
   C        -3.032587   10.065408    3.750266
   H        -3.752450   10.043865    2.922654
   H        -3.285799    9.271475    4.465977
   H        -2.027375    9.883183    3.351984
   C         2.932533   15.023006    4.896598
   H         3.668831   15.725728    4.502055
   C        -5.716103   12.441592    4.365035
   H        -6.687138   12.678244    4.824853
   H        -5.910123   11.846976    3.459248
   C        -3.188605   17.077606    2.961466
   H        -4.274628   16.938181    2.925717
   H        -2.913271   17.916779    2.308232
   H        -2.908366   17.325078    3.993496
   C        -4.403457   12.239098    0.619117
   H        -4.949372   11.554204    1.280181
   H        -4.218031   11.734980   -0.339254
   H        -5.031579   13.117395    0.435917
   C        -2.679423   16.859359    7.417443
   H        -3.028434   17.394552    6.524649
   H        -2.331224   17.597974    8.151862
   H        -3.529139   16.313437    7.847020
   C        -1.796692   11.334456    0.788986
   H        -0.761578   11.400764    1.141594
   H        -1.806095   11.336777   -0.309703
   H        -2.228720   10.391262    1.139677
   C        -6.085936   14.624220    2.601635
   H        -5.755352   15.568987    2.153367
   H        -7.052693   14.791211    3.096620
   H        -6.228291   13.894860    1.798246
   C        -0.609699   16.238837    2.358843
   H        -0.204979   16.367725    3.369317
   H        -0.609054   17.204289    1.834624
   H         0.039853   15.533092    1.828012
   C        -1.073716   15.152279    8.321161
   H        -1.905151   14.580613    8.754216
   H        -0.712284   15.867993    9.071304
   H        -0.259594   14.461401    8.074839
   C        -2.731366   15.421768    0.653727
   H        -3.823882   15.517339    0.561399
   H        -2.271689   16.247309    0.090454
   C        -2.265344   14.055080    0.173425
   H        -1.166368   14.010897    0.142709
   H        -2.641220   13.801314   -0.828626
   C        -0.368335   16.668751    6.435671
   H         0.433536   15.985285    6.135771
   H         0.034000   17.388878    7.161134
   H        -0.707742   17.223889    5.551202

74
cis-[(dmpe)2Mn(SiH2Et)(tBuNC)] (cis-7d*)
  Mn        4.803014   17.315403    4.039454
  P         3.999682   17.985953    5.982583
  Si        6.148279   15.854492    5.302720
  H         5.556600   15.349795    6.617133
  H         6.477164   14.506825    4.658423
  P         3.333995   15.630693    3.742210
  P         5.772305   16.518497    2.223535
  P         3.501445   18.853696    3.150163
  N         6.974088   19.357300    4.412271
  C         6.143976   18.507120    4.215355
  C         7.891876   16.408272    5.880904
  H         8.475142   16.707972    4.995595
  H         7.780155   17.324751    6.480266
  H         9.638265   15.678953    7.004205
  H         1.809914   20.407734    4.101922
  H         1.432507   18.702398    4.431949
  C         8.138833   20.169081    4.222967
  C         1.486582   15.822327    3.756507
  H         1.136288   15.965517    4.785224
  H         1.009419   14.918028    3.354398
  C         3.394332   14.079254    4.747981
  H         4.402006   13.649336    4.707890
  H         2.663190   13.348996    4.376233
  H         3.173701   14.309569    5.796096
  C         5.153062   18.572415    7.293940
  H         5.687484   17.710017    7.711358
  H         4.604281   19.079178    8.098824
  H         5.885341   19.257905    6.852809
  C         2.940492   19.521250    5.761020
  H         2.237818   19.637757    6.598447
  H         3.631428   20.377612    5.785738
  C         4.248987   20.487620    2.698529
  H         4.768350   20.904797    3.567954
  H         3.485595   21.195246    2.348496
  H         4.992417   20.338097    1.905904
  H         1.168489   16.686029    3.164838
  C         3.550559   14.911909    2.030951
  H         3.085240   13.916982    1.973813
  H         3.014810   15.573402    1.333665
  C         5.707279   17.453105    0.620253
  H         4.667247   17.546552    0.288700
  H         6.290881   16.953024   -0.164962
  H         6.110832   18.461483    0.777529
  C         7.567637   16.096893    2.184058
  H         8.157403   17.012238    2.302107
  H         7.832530   15.621552    1.230050
  H         7.804800   15.414769    3.008424
  C         2.900131   16.950589    7.047936
  H         1.981723   16.686132    6.512990
  H         2.633628   17.488743    7.967264
  H         3.437105   16.031674    7.312771
  C         8.932578   19.668446    3.005820
  H         9.294891   18.648111    3.179959
  H         9.800093   20.317204    2.826105
  H         8.302109   19.671365    2.107423
  C         2.412034   18.700216    1.650591
  H         3.025998   18.818137    0.749834
  H         1.644032   19.486347    1.648145
  H         1.922317   17.722351    1.601813
  C         7.695000   21.624025    3.994053
  H         7.085005   21.705144    3.085933
  H         8.572165   22.275383    3.886160
  H         7.100172   21.979013    4.845299
  C         9.012976   20.086844    5.485568
  H         8.453863   20.440871    6.360985
  H         9.908514   20.711037    5.367103
  H         9.322858   19.051536    5.670060
  C         5.037178   14.884787    1.710753
  H         5.546764   14.118167    2.312939
  H         5.242317   14.677434    0.650733
  C         2.243766   19.444694    4.409395
  C         8.642972   15.339313    6.676154
  H         8.079243   15.047646    7.573986
  H         8.783554   14.426984    6.078706

82
trans-[(dmpe)2Mn(SiH2Ph)(xylylNC)] (trans-7a)
Mn      12.42012908       2.53821117       4.82116245
P      14.24297712       2.97359248       6.01659287
N      12.09204950       5.45714709       4.20264740
C      12.22471863       4.27827418       4.45115143
H      10.93017955      -1.42135697       7.08716793
H       9.66971940      -0.09538096       4.42526564
H      14.83974250       3.48154813       1.23747351
H      15.64379915       3.41138114       2.82352935
H       8.71158656       1.28924194       5.00386124
C      15.06967040       4.61317146       5.79432009
C      15.76522220       1.93347647       6.07050440
C      13.80958780       3.03316718       7.83157788
H      14.29318458       4.54118647       2.57926671
H      13.96401467      -0.13535926       2.46821974
H       8.54216694       0.74441989       3.31677549
H      11.27747340       0.34512937       2.07330337
H      15.85964701       4.75814567       6.54294045
H      15.51199094       4.66790471       4.79323072
H      14.33409979       5.41948844       5.87349672
H      15.51212006       0.89416184       6.30640077
H      16.25444030       1.95310918       5.08828064
H      16.46506850       2.32355752       6.82166921
H      13.84105753       1.99240648       8.18563643
H      14.56444751       3.60606590       8.38881721
H      13.12433932       0.04215719       6.94264492
P      11.29620663       2.81227106       6.71034852
P      10.58640456       2.04838118       3.65306798
P      13.50872239       2.24147789       2.90685497
H      12.73944047       1.75753877       0.60087688
H      15.37061083       0.66254757       3.17006451
H      10.20468261       1.51151786       1.26842958
C      12.40765646       3.60767205       7.98476365
C       9.84123518       3.94918912       6.75495928
C      10.56959411       1.43822898       7.70778383
C       9.49730466       3.46049341       3.15995699
C       9.25320007       0.87548117       4.14351958
C      11.05161578       1.41511892       1.96306898
C      14.67735205       3.54900459       2.32175603
C      14.55494374       0.78616940       2.44918194
C      12.27864186       2.19070640       1.50029487
H      12.01173374       3.23277514       1.27203107
H      14.97071868       0.93363320       1.44341421
H      12.00041715       3.46009712       8.99542488
H      12.40487700       4.68673445       7.77619877
H       9.61035811       4.25197146       7.78528279
H       8.96553918       3.43185490       6.34320599
H      10.03914771       4.83597697       6.14369793
H      11.36770316       0.76595058       8.04098131
H       9.87560375       0.85899538       7.08754444
H      10.03406613       1.83508879       8.58056261
H       8.68397174       3.11615202       2.50770941
H       9.06791840       3.93080273       4.05128119
H      10.08858442       4.22069311       2.64000833
H      11.09631634       5.62589924       1.49303669
H      12.35413580      -1.43418589       3.02421252
H      10.85094144      -3.31116830       2.49941624
H       9.35631620      -4.25262413       4.25887679
H       9.42605659      -3.30400719       6.56218207
C      10.85474242      -2.88760783       3.50513233
C      10.01979819      -3.41885564       4.49019096
C      10.05783990      -2.88293974       5.77829370
C      10.90873060      -1.81495271       6.06966343
H      14.17758899      -0.30034571       4.91438701
C      11.74112670      -1.24389356       5.09125685
C      11.69979743      -1.82046582       3.80886524
Si      12.87903603       0.25108990       5.45562636
C      12.02266293       6.79356131       3.94801072
C      11.99455273       7.72140856       5.02304501
C      11.93401180       9.08443716       4.73218726
C      11.89564723       9.54714739       3.41836195
C      11.91217585       8.62885960       2.37007754
C      11.97195521       7.25531798       2.60576950
H      12.91619557       6.64999354       6.65932049
H      11.91506436       9.79488993       5.56030358
H      11.85010867      10.61625269       3.21276485
H      11.87746918       8.98098925       1.33779280
C      12.01828603       7.24583682       6.44488755
H      12.00147682       8.09438252       7.13849580
H      11.15521128       6.60388101       6.66875088
C      11.97667627       6.28389532       1.46305856
H      11.96960573       6.81368205       0.50351335
H      12.85862649       5.63064542       1.48805197

78
trans-[(dmpe)2Mn(SiH2Et)(xylylNC)] (trans-7b*)
  Mn       12.068274    2.439020    4.270164
  P        13.592179    2.392271    5.886051
  N        12.095224    5.440160    4.255416
  C        12.095386    4.227722    4.261231
  H        12.422590    6.184414    7.038864
  H         9.451221    0.247487    2.610221
  H        15.447723    3.624574    1.659587
  H        15.756707    3.232915    3.368023
  H         8.421409    1.504119    3.330931
  C        14.489901    3.969138    6.253817
  C        15.051988    1.269248    6.009373
  C        12.775582    2.099235    7.536839
  H        14.631416    4.547903    2.963546
  H        13.890418    0.014983    1.996008
  H         8.603560    1.426787    1.556487
  H        11.478488    0.999716    0.913545
  H        15.124986    3.863262    7.143200
  H        15.115039    4.246719    5.397832
  H        13.770720    4.778926    6.409685
  H        14.745819    0.222827    5.935973
  H        15.749115    1.487683    5.190481
  H        15.574693    1.432518    6.961670
  H        12.614378    1.014548    7.628783
  H        13.432852    2.415555    8.359783
  H        11.880999   -0.483792    2.670024
  P        10.578231    2.451555    5.917654
  P        10.565878    2.429511    2.631882
  P        13.591185    2.349682    2.667101
  H        13.426234    2.371890    0.194115
  H        15.166672    0.536262    3.112643
  H        10.786374    2.461478    0.167288
  C        11.446303    2.842819    7.526378
  C         9.236643    3.722374    5.912381
  C         9.552502    1.021576    6.485210
  C         9.676602    4.005198    2.250505
  C         9.122370    1.287910    2.514504
  C        11.404575    2.093312    0.998374
  C        14.988730    3.559504    2.655486
  C        14.568856    0.838936    2.244800
  C        12.790835    2.723064    1.020013
  H        12.720681    3.818058    0.947682
  H        15.239272    1.034986    1.397257
  H        10.808083    2.582237    8.382783
  H        11.612832    3.929366    7.547806
  H         8.808919    3.857667    6.915036
  H         8.436763    3.393147    5.236631
  H         9.628922    4.676053    5.543807
  H        10.195566    0.186406    6.785341
  H         8.913423    0.662422    5.671346
  H         8.929371    1.331617    7.334860
  H         9.055713    3.897856    1.351371
  H         9.038207    4.281945    3.097255
  H        10.400073    4.813424    2.105161
  H        11.816032    6.158408    1.445744
  H        11.841445    9.493550    6.297491
  H        12.391633   10.689379    4.186025
  H        12.790634    9.386723    2.104180
  C        11.599702    6.833338    6.706446
  H        11.397510    7.556013    7.505449
  H        10.717791    6.188740    6.593610
  C        12.715458    6.707724    1.759269
  H        13.000184    7.381667    0.943044
  H        10.492011   -0.501873    4.492333
  H        13.997105   -1.177378    4.594916
  H        13.511284    5.961615    1.882688
  Si       11.850506    0.042463    4.103378
  C        12.170074    6.799334    4.234990
  C        11.935661    7.537638    5.425698
  C        12.021368    8.929102    5.380994
  C        12.328241    9.601662    4.199448
  C        12.551465    8.869349    3.034808
  C        12.477095    7.476406    3.024623
  C        12.962413   -1.278019    4.957205
  H        12.993643   -1.077866    6.041344
  H        12.438948   -2.925925    3.630915
  C        12.464459   -2.703576    4.707165
  H        13.101176   -3.460625    5.190801
  H        11.440837   -2.834436    5.085208

78
trans-[(dmpe)2Mn(SiH2Ph)(tBuNC)] (trans-7c)
Mn      12.40899429       2.52619072       4.72983062
P      14.17932572       3.07412441       5.94141386
N      12.09150304       5.33412488       3.72372853
C      12.21575901       4.22766865       4.20105148
H      14.13524689       7.08103448       3.76237459
H       9.66162802      -0.11896536       4.47175119
H      14.88716590       3.24867547       1.12410078
H      15.56792968       3.50823632       2.74929901
H       8.69125670       1.31128840       4.89885948
C      14.96863424       4.72716516       5.66509992
C      15.72471789       2.07965568       6.10412428
C      13.68953643       3.24711638       7.73557546
H      14.11896529       4.41880451       2.24767854
H      14.16074797      -0.24750391       2.65030393
H       8.57351716       0.62408175       3.25969754
H      11.37202043       0.09700454       2.17122574
H      15.80308437       4.88819231       6.36038025
H      15.33587510       4.79743734       4.63507353
H      14.22027584       5.51391922       5.80674082
H      15.48509709       1.04232707       6.36284760
H      16.25880356       2.07942848       5.14521958
H      16.37926621       2.51179321       6.87297910
H      13.70745518       2.23227344       8.15908700
H      14.42353535       3.85832730       8.28015194
H      13.06304815       0.18131553       7.02613679
P      11.22043555       2.92309418       6.55073253
P      10.61751489       1.94278314       3.54795415
P      13.55801458       2.12449641       2.86845590
H      12.86437596       1.37877873       0.60851493
H      15.49953834       0.68826789       3.31293923
H      10.31072947       1.16115709       1.22094739
C      12.28224690       3.82700964       7.79637372
C       9.75470915       4.04630873       6.47087520
C      10.47565859       1.62099441       7.62917754
C       9.56348684       3.30629282       2.86876860
C       9.25825246       0.82517635       4.09458219
C      11.13770910       1.14662588       1.94584134
C      14.63540504       3.45525197       2.17307309
C      14.69984973       0.70166907       2.56396028
C      12.36718020       1.89175864       1.44426171
H      12.09138052       2.90042627       1.10135706
H      15.13658454       0.78610073       1.55985796
H      11.84188134       3.76178346       8.80188344
H      12.28426560       4.88664582       7.49890317
H       9.47265430       4.40068590       7.47165968
H       8.90290376       3.50338857       6.04239856
H       9.97965704       4.90138690       5.82505871
H      11.26846436       0.97367344       8.01999619
H       9.79293491       1.00015040       7.03731899
H       9.92455871       2.07472409       8.46381317
H       8.77744064       2.90064012       2.21832841
H       9.09726731       3.86134122       3.69079255
H      10.18503813       4.01114194       2.30579699
C      11.97790825       6.76558161       3.78522422
C      10.75576824       7.18942074       2.95410060
H      10.64946473       8.28219213       2.95913994
H      10.86612881       6.85309396       1.91548834
H       9.83968344       6.74574221       3.36420832
C      11.80450150       7.23994230       5.23751435
H      10.89173213       6.82180751       5.67830589
H      11.73206747       8.33512498       5.27077383
H      12.65878819       6.93356667       5.85340788
C      13.25282872       7.38199371       3.18428280
H      13.38619599       7.04551225       2.14836702
H      13.18725427       8.47811030       3.18966771
Si      12.87102363       0.29559578       5.51996006
H      10.82537431      -1.25818545       7.16020406
H      14.19255691      -0.28165102       5.06402160
C      11.75817742      -1.23154249       5.21020095
C      11.79224714      -1.90403915       3.97512022
C      10.96062176      -2.98973981       3.70068592
C      10.06396522      -3.44458071       4.66954935
C      10.02764824      -2.81404832       5.91430255
C      10.86491046      -1.72783562       6.17597297
H      12.49769449      -1.57975459       3.20647201
H      11.01590366      -3.48768073       2.73110032
H       9.41067290      -4.29231226       4.46092744
H       9.34704419      -3.17449048       6.68756733

74
trans-[(dmpe)2Mn(SiH2Et)(tBuNC)] (trans-7d*)
  Mn       12.061452    2.432146    4.239011
  P        13.539636    2.471447    5.883564
  N        12.294385    5.392350    3.819749
  C        12.157478    4.214932    4.079993
  H        14.286725    6.883189    4.842664
  H         9.356000    0.272272    2.727444
  H        15.493087    3.426494    1.612641
  H        15.697431    3.319822    3.378902
  H         8.377332    1.648650    3.281433
  C        14.407332    4.074218    6.227448
  C        15.012101    1.374317    6.084092
  C        12.688569    2.241038    7.528733
  H        14.539622    4.492467    2.698153
  H        13.992632   -0.141108    2.229468
  H         8.608494    1.383330    1.531411
  H        11.498063    0.760614    1.017182
  H        15.091377    3.980692    7.081230
  H        14.971447    4.387876    5.341890
  H        13.665741    4.851483    6.439936
  H        14.727637    0.323142    5.991026
  H        15.746280    1.609734    5.302976
  H        15.482420    1.541882    7.062714
  H        12.521766    1.161305    7.659125
  H        13.327652    2.588303    8.353752
  H        11.950777   -0.591944    2.811321
  P        10.531996    2.538082    5.842406
  P        10.597110    2.374896    2.575034
  P        13.619968    2.234279    2.678697
  H        13.489990    2.028695    0.210823
  H        15.240787    0.517650    3.306324
  H        10.854472    2.162620    0.122925
  C        11.361319    2.986048    7.458586
  C         9.208020    3.824809    5.757764
  C         9.472754    1.144095    6.440586
  C         9.829273    3.965985    2.023203
  C         9.089673    1.313968    2.516270
  C        11.448039    1.858455    0.997019
  C        14.969462    3.491474    2.576023
  C        14.645607    0.720750    2.408301
  C        12.846409    2.460383    0.990749
  H        12.798273    3.547093    0.822141
  H        15.320967    0.857413    1.553056
  H        10.702445    2.760046    8.309234
  H        11.529816    4.073392    7.443090
  H         8.715988    3.963667    6.730158
  H         8.451967    3.514833    5.024905
  H         9.643076    4.772068    5.423711
  H        10.098291    0.311947    6.783442
  H         8.846425    0.763909    5.626405
  H         8.836193    1.491474    7.265527
  H         9.193155    3.809284    1.142079
  H         9.223518    4.384295    2.835874
  H        10.617324    4.690325    1.789183
  C        12.216925    6.787440    4.164775
  C        11.323301    7.494202    3.132504
  H        11.265003    8.569262    3.348479
  H        11.730669    7.361929    2.122203
  H        10.308644    7.076913    3.152650
  C        11.629823    6.977575    5.572458
  H        10.602952    6.596528    5.621302
  H        11.612599    8.043911    5.834327
  H        12.232352    6.449040    6.321322
  C        13.636589    7.377448    4.110176
  H        14.068939    7.234963    3.111753
  H        13.613693    8.452839    4.331327
  Si       11.825855    0.037400    4.197130
  H        13.903742   -1.203112    4.878303
  H        10.436260   -0.473819    4.522575
  C        12.857724   -1.227682    5.222380
  H        12.874837   -0.914275    6.279633
  H        12.295816   -2.985812    4.064036
  C        12.312410   -2.653412    5.111804
  H        12.912103   -3.378429    5.684105
  H        11.278322   -2.707784    5.480092

90
cis-[(dmpe)2MnH{=SiHPh(iPrNHC)}] (cis-8a) i
   Mn       18.512443    5.140722   12.466636
   Si       18.505529    7.344607   11.957677
   N        19.063336    9.170636    9.599825
   N        20.617994    7.686506    9.764519
   C        19.457396    8.097722   10.350642
   C        19.949340    9.406224    8.567407
   H        19.818065   10.211174    7.856700
   C        18.070351    9.704323   13.623568
   H        17.012358    9.452949   13.515890
   C        20.372150    9.306731   13.120195
   H        21.157965    8.733333   12.623742
   C        17.921292   10.059250    9.888254
   H        17.385224    9.554492   10.701870
   C        20.928850    8.470909    8.670047
   H        21.812159    8.306817    8.067748
   C        19.760529   11.206694   14.481887
   H        20.039153   12.092156   15.054503
   C        18.420630   10.834129   14.364111
   H        17.643912   11.433417   14.842693
   C        21.492702    6.600147   10.245155
   H        20.974133    6.203659   11.133420
   C        20.738706   10.438119   13.849571
   H        21.789878   10.723640   13.922287
   C        17.007032   10.160846    8.674108
   H        17.495497   10.675918    7.834445
   H        16.111769   10.737529    8.938506
   H        16.689998    9.166525    8.335189
   C        18.426203   11.411271   10.379317
   H        19.069915   11.289643   11.258747
   H        17.572920   12.039816   10.664301
   H        18.988656   11.938617    9.595034
   C        22.863636    7.149852   10.615665
   H        23.421362    7.498383    9.734166
   H        23.454584    6.359745   11.095610
   H        22.781625    7.986357   11.321060
   C        21.558502    5.479923    9.217490
   H        20.557848    5.066601    9.041958
   H        22.193267    4.670683    9.600441
   H        21.983640    5.820345    8.262250
   C        19.033140    8.900117   12.990154
   P        17.292475    4.772889   10.682050
   P        16.609243    5.329936   13.525663
   C        17.238104    5.943314    9.232656
   H        16.927514    6.937170    9.576328
   H        16.534342    5.591337    8.465640
   H        18.238383    6.027882    8.788715
   C        17.355807    3.235613    9.639917
   H        18.309889    3.190383    9.099497
   H        16.535625    3.236570    8.908041
   H        17.267642    2.340857   10.266991
   C        15.461877    4.725953   11.098623
   H        14.856392    5.004253   10.222773
   H        15.223700    3.678954   11.344435
   C        15.218357    5.618840   12.301910
   H        14.240027    5.441163   12.773368
   H        15.273189    6.680130   12.014995
   C        15.822323    3.942508   14.495262
   H        15.655812    3.076415   13.845239
   H        14.861445    4.254511   14.929601
   H        16.494716    3.635926   15.307847
   C        16.161716    6.657076   14.749451
   H        16.546276    6.397610   15.743131
   H        15.069138    6.759714   14.820754
   H        16.600600    7.616264   14.457209
   P        19.807450    5.472486   14.198883
   P        19.073378    3.041166   12.723479
   C        19.512699    6.627722   15.611986
   H        19.405378    7.657223   15.253445
   H        20.346107    6.578840   16.326842
   H        18.589295    6.342690   16.127679
   C        21.602099    5.871156   13.920188
   H        22.014800    5.164162   13.189971
   H        22.183853    5.820689   14.851803
   H        21.688641    6.882726   13.508371
   C        20.034701    3.893095   15.173781
   H        20.855406    3.984106   15.901830
   H        19.100366    3.731325   15.733206
   C        20.260779    2.785852   14.162121
   H        20.139619    1.776812   14.582213
   H        21.279779    2.850486   13.751371
   C        17.901993    1.637654   13.093324
   H        17.480332    1.772100   14.095589
   H        18.419778    0.668710   13.052127
   H        17.071542    1.628690   12.376041
   C        20.080911    2.171256   11.430845
   H        19.474418    1.934157   10.550995
   H        20.501857    1.237491   11.830884
   H        20.892225    2.840709   11.120986
   H        19.756248    5.020999   11.516592
   H        17.166940    7.961069   11.530709

90
cis-[(dmpe)2MnH{=SiHPh(iPrNHC)}] (cis-8a) ii
   Mn       18.413699    5.136249   12.406845
   Si       18.585507    7.376361   12.006203
   N        19.075141    9.135159    9.456201
   N        20.558430    7.598123    9.733431
   C        19.432280    8.120521   10.307044
   C        19.940284    9.212197    8.380511
   H        19.826975    9.947354    7.595189
   H        18.696851    0.666184   12.977316
   H        17.264945    1.509507   12.319159
   H        17.661455    1.656520   14.041164
   C        18.091743    1.582027   13.036649
   C        18.051618   10.176402    9.671697
   H        17.537232    9.886769   10.588253
   C        20.874752    8.247274    8.557349
   H        21.734442    7.980346    7.957932
   C        20.244792    2.311702   11.428508
   H        19.683446    2.057111   10.523414
   H        20.708355    1.397185   11.825668
   H        21.023748    3.034098   11.159300
   C        21.462660    6.605911   10.341487
   H        20.909429    6.222297   11.212268
   H        19.640078    5.082551   11.439277
   H        15.824740    7.653759   10.690350
   C        17.048487   10.197305    8.527502
   H        17.512005   10.502164    7.578319
   H        16.250947   10.914618    8.757801
   H        16.590319    9.210112    8.390087
   C        18.724615   11.525070    9.906573
   H        19.438710   11.462203   10.737377
   H        17.962839   12.270979   10.166561
   H        19.257688   11.881587    9.013571
   C        22.752549    7.287593   10.779290
   H        23.333252    7.655147    9.920525
   H        23.377279    6.573039   11.329872
   H        22.540091    8.134639   11.443691
   C        21.686846    5.436596    9.395285
   H        20.733042    4.944398    9.168600
   H        22.340281    4.698918    9.877802
   H        22.168559    5.743905    8.456174
   H        19.567513    8.227777   12.822181
   P        17.254470    4.701065   10.610378
   P        16.484770    5.146012   13.456901
   C        17.276556    5.805081    9.107877
   H        17.041765    6.840504    9.374693
   H        16.571047    5.459313    8.338783
   H        18.291940    5.794612    8.688891
   C        17.417776    3.138385    9.610587
   H        18.386133    3.122347    9.094842
   H        16.618356    3.078016    8.858065
   H        17.354140    2.258769   10.261630
   C        15.407388    4.547402   10.960334
   H        14.821108    4.901590   10.098497
   H        15.216402    3.467460   11.054737
   C        15.048236    5.256782   12.253007
   H        14.140652    4.843079   12.717916
   H        14.871313    6.325889   12.087556
   C        15.876456    3.679210   14.438531
   H        15.780636    2.805616   13.784556
   H        14.899348    3.890771   14.896276
   H        16.594345    3.437318   15.233525
   C        15.882231    6.410489   14.681276
   H        16.311730    6.207033   15.669655
   H        14.787478    6.355392   14.769009
   H        16.168228    7.421009   14.374157
   P        19.647915    5.565668   14.159952
   P        19.136297    3.091892   12.695271
   C        19.232479    6.739988   15.526896
   H        19.072153    7.744423   15.116072
   H        20.044031    6.779425   16.266878
   H        18.311729    6.419001   16.024480
   C        21.410131    6.104519   13.916582
   H        21.914086    5.396695   13.246853
   H        21.956476    6.157836   14.868709
   H        21.416534    7.095905   13.447766
   C        19.973497    4.025183   15.164670
   H        20.771920    4.187255   15.904912
   H        19.044840    3.795701   15.709011
   C        20.304951    2.932271   14.165254
   H        20.248232    1.919420   14.589383
   H        21.326538    3.069907   13.779644
   C        17.084010    8.573903   12.190254
   C        17.091369    9.575989   13.178421
   C        15.973763   10.374600   13.428736
   C        14.807933   10.206201   12.680322
   C        14.771954    9.224285   11.688472
   C        15.885933    8.418151   11.465369
   H        18.001040    9.733588   13.762568
   H        16.012176   11.134984   14.210921
   H        13.933939   10.830558   12.869523
   H        13.867692    9.079257   11.094002

86
cis-[(dmpe)2MnH{=SiHEt(iPrNHC)}] (cis-8b*) i
  Mn       18.527073    5.151761   12.461462
  Si       18.598133    7.416781   12.051564
  N        18.995901    9.136098    9.523702
  N        20.616178    7.744979    9.822598
  C        19.451140    8.172962   10.388307
  C        19.851610    9.279409    8.448142
  H        19.671478    9.986520    7.649812
  H        18.276151    0.669421   12.941316
  H        16.960830    1.710062   12.319409
  H        17.421069    1.798749   14.030088
  C        17.808955    1.661723   13.014131
  C        17.785117    9.969834    9.674514
  H        17.346345    9.637410   10.623815
  C        20.873968    8.405149    8.638252
  H        21.751908    8.206810    8.038772
  C        19.981703    2.140066   11.308672
  H        19.361122    1.917490   10.436756
  H        20.386718    1.196542   11.701096
  H        20.805662    2.790366   10.992118
  C        21.514237    6.723524   10.390153
  H        20.971622    6.341541   11.270504
  H        19.787990    5.012296   11.530000
  H        17.277309    8.150017   11.760150
  C        16.798326    9.707551    8.539370
  H        17.200835   10.043917    7.573599
  H        15.873990   10.267852    8.727631
  H        16.548944    8.644490    8.459852
  C        18.158181   11.448418    9.758622
  H        18.892894   11.633433   10.548615
  H        17.258845   12.036281    9.981286
  H        18.566077   11.814183    8.805978
  C        22.842533    7.348460   10.796529
  H        23.407398    7.714520    9.926923
  H        23.457782    6.595885   11.305028
  H        22.688494    8.186232   11.488132
  C        21.661876    5.557118    9.421109
  H        20.679213    5.114641    9.217063
  H        22.287110    4.781511    9.880439
  H        22.133152    5.855930    8.474252
  H        20.323996    8.435161   13.595183
  P        17.305366    4.814448   10.671382
  P        16.629353    5.420658   13.507753
  C        17.175031    6.073388    9.307307
  H        16.853663    7.022490    9.749598
  H        16.456141    5.766836    8.534728
  H        18.159350    6.222072    8.845670
  C        17.405730    3.345720    9.534777
  H        18.372888    3.334966    9.017428
  H        16.603413    3.393532    8.785595
  H        17.301078    2.412955   10.100294
  C        15.486169    4.667642   11.109333
  H        14.853727    4.881607   10.234458
  H        15.316519    3.617470   11.393414
  C        15.211895    5.588651   12.284455
  H        14.246314    5.388003   12.771563
  H        15.215291    6.640290   11.958700
  C        15.888358    4.131445   14.638613
  H        15.717271    3.208521   14.072971
  H        14.936699    4.466277   15.075256
  H        16.594139    3.906440   15.449161
  C        16.189112    6.895738   14.558295
  H        16.769518    6.899412   15.487200
  H        15.119263    6.886680   14.810946
  H        16.414954    7.815109   14.003518
  P        19.811821    5.367054   14.229952
  P        19.029245    3.025059   12.640228
  C        19.488485    6.333901   15.785039
  H        19.404258    7.406611   15.592452
  H        20.300594    6.163795   16.505625
  H        18.549971    5.982178   16.230123
  C        21.604395    5.830830   14.001606
  H        22.046011    5.140737   13.271753
  H        22.170726    5.781789   14.942295
  H        21.679589    6.845671   13.594732
  C        20.075879    3.723519   15.093614
  H        20.919440    3.779431   15.798101
  H        19.161705    3.529429   15.675011
  C        20.264596    2.677006   14.017723
  H        20.151168    1.645406   14.380772
  H        21.267321    2.763072   13.573059
  C        19.311417    8.736595   13.286987
  H        19.969962   10.403227   12.039618
  H        18.684259    8.606361   14.182377
  C        19.312154   10.212461   12.899499
  H        18.302629   10.551367   12.626805
  H        19.659223   10.858082   13.721341

86
cis-[(dmpe)2MnH{=SiHEt(iPrNHC)}] (cis-8b*) ii
  Mn       18.408593    5.208934   12.403138
  Si       18.775882    7.447163   12.049252
  N        19.051228    8.886890    9.286831
  N        20.700156    7.588183    9.766948
  C        19.510255    8.043203   10.261394
  C        19.933056    8.952485    8.222880
  H        19.751003    9.563840    7.349768
  H        18.560987    0.700830   12.478480
  H        17.254691    1.655394   11.722203
  H        17.384036    1.577400   13.489468
  C        17.961145    1.618092   12.560185
  C        17.846259    9.726079    9.368655
  H        17.285961    9.322346   10.212878
  C        20.971323    8.132498    8.527591
  H        21.867429    7.896372    7.970358
  C        20.332857    2.497346   11.382162
  H        19.918652    2.474623   10.367624
  H        20.678353    1.489628   11.653999
  H        21.180569    3.192069   11.386404
  C        21.653489    6.728730   10.492167
  H        21.075179    6.332997   11.337867
  H        19.606490    5.228574   11.384914
  H        18.120161    9.915252   12.254679
  C        16.997262    9.608648    8.106613
  H        17.494828   10.056956    7.235986
  H        16.053921   10.147868    8.258089
  H        16.763114    8.562299    7.880924
  C        18.231831   11.172133    9.674169
  H        18.853995   11.229589   10.574891
  H        17.327280   11.770633    9.840165
  H        18.787216   11.617909    8.837336
  C        22.827371    7.564168   10.989793
  H        23.413432    7.976184   10.155685
  H        23.492860    6.938902   11.597829
  H        22.470482    8.393197   11.613451
  C        22.070633    5.545355    9.629591
  H        21.189762    4.964574    9.330595
  H        22.727352    4.888629   10.213450
  H        22.624423    5.853763    8.732008
  H        20.053315    8.031295   12.676600
  P        17.166783    4.885842   10.638206
  P        16.524288    5.170254   13.512969
  C        16.798657    6.227782    9.401640
  H        16.392665    7.098061    9.930717
  H        16.079175    5.895607    8.639527
  H        17.732098    6.522398    8.908070
  C        17.500464    3.571295    9.367615
  H        18.440600    3.809812    8.853186
  H        16.692056    3.517429    8.624945
  H        17.611194    2.590783    9.842955
  C        15.405642    4.442583   11.107677
  H        14.714460    4.610625   10.268183
  H        15.399111    3.365604   11.335352
  C        15.043863    5.248640   12.347015
  H        14.136808    4.876667   12.846403
  H        14.874119    6.300940   12.080818
  C        15.935070    3.667377   14.467686
  H        15.753028    2.839797   13.773528
  H        15.003235    3.883511   15.009261
  H        16.698776    3.349987   15.188679
  C        15.979172    6.381325   14.828575
  H        16.360988    6.039002   15.799181
  H        14.882272    6.422668   14.892774
  H        16.374343    7.383202   14.638749
  P        19.684410    5.479570   14.156035
  P        19.057209    3.133839   12.575857
  C        19.434580    6.725322   15.503762
  H        19.532276    7.733589   15.081375
  H        20.181821    6.600241   16.299716
  H        18.432112    6.623545   15.930657
  C        21.514222    5.751643   13.940840
  H        21.916123    4.998957   13.251505
  H        22.046736    5.688356   14.899882
  H        21.675577    6.746985   13.511039
  C        19.767595    3.908067   15.167755
  H        20.551351    3.967264   15.937934
  H        18.799013    3.808528   15.677668
  C        19.994241    2.766767   14.186879
  H        19.685617    1.790752   14.585824
  H        21.061902    2.691784   13.934737
  C        17.672107    8.965579   12.587530
  H        15.704462    8.047552   12.741747
  H        17.846186    8.952898   13.677811
  C        16.158945    8.966667   12.358193
  H        15.666332    9.812377   12.861485
  H        15.871803    9.024438   11.297181

84
cis-[(dmpe)2MnH{=SiHPh(MeNHC)}] (cis-8c) i
   Mn       18.501863    5.150289   12.471195
   Si       18.496822    7.353819   11.948227
   N        19.046607    9.159595    9.582943
   N        20.592851    7.677866    9.742163
   C        19.439920    8.091003   10.335282
   C        19.929687    9.404021    8.536006
   H        20.587704   10.533602    6.859373
   C        18.112526    9.680349   13.672686
   H        17.050703    9.439351   13.582156
   C        20.398629    9.297496   13.085274
   H        21.168200    8.748790   12.536198
   H        18.280640   10.926325   10.421722
   H        19.085173    3.776171   15.751951
   C        20.914658    8.461399    8.637861
   H        22.204474    8.990463    7.030457
   C        19.836311   11.118972   14.571992
   H        20.136922   11.966538   15.189279
   C        18.490211   10.766384   14.463934
   H        17.730495   11.344581   14.993329
   H        21.792783    5.995169    9.399286
   H        18.471531    0.672675   13.058662
   C        20.791431   10.384196   13.867721
   H        21.845801   10.660888   13.927997
   H        22.170177    5.859777   14.845742
   H        21.655833    6.935480   13.519852
   C        20.022297    3.937216   15.197063
   H        20.838078    4.040129   15.929032
   C        20.261687    2.820807   14.197702
   H        20.138969    1.815690   14.626383
   H        21.284710    2.885065   13.797274
   C        17.935496    1.632021   13.088805
   C        20.131726    2.213926   11.459524
   H        19.548529    1.996873   10.558959
   H        20.544737    1.272499   11.849621
   H        17.120900    1.608486   12.353955
   H        20.949602    2.891540   11.186052
   H        17.490137    1.759354   14.081745
   H        19.756989    5.015028   11.541940
   H        17.157851    7.977243   11.530723
   C        19.053691    8.900168   12.978622
   P        17.304154    4.774467   10.671406
   P        16.585095    5.324597   13.508128
   C        17.278249    5.933333    9.210281
   H        16.966269    6.933375    9.534712
   H        16.587029    5.575766    8.434407
   H        18.288201    6.005022    8.786027
   C        17.385284    3.230269    9.638510
   H        18.343650    3.193765    9.105222
   H        16.570304    3.220006    8.900807
   H        17.302369    2.337970   10.269586
   C        15.465956    4.732556   11.061480
   H        14.875322    5.021537   10.178983
   H        15.219660    3.684545   11.294065
   C        15.206659    5.616443   12.268982
   H        14.222975    5.433264   12.727052
   H        15.262692    6.679905   11.990583
   C        15.800282    3.921084   14.457463
   H        15.655702    3.058097   13.797985
   H        14.829153    4.216138   14.880683
   H        16.466199    3.617462   15.276353
   C        16.113953    6.640848   14.735126
   H        16.515572    6.393609   15.725156
   H        15.019975    6.717841   14.816773
   H        16.527039    7.609112   14.434887
   P        19.790247    5.507620   14.207073
   P        19.087888    3.058027   12.742119
   C        19.488428    6.672991   15.611715
   H        19.385779    7.700541   15.247114
   H        20.317858    6.626666   16.331359
   H        18.561297    6.393157   16.123680
   C        21.581489    5.917763   13.918858
   H        21.992387    5.223697   13.175795
   C        21.458988    6.620477   10.235738
   H        22.336223    7.052107   10.736914
   H        20.874665    6.005062   10.941821
   C        22.123761    8.225001    7.810157
   H        23.042649    8.260139    8.413325
   H        22.095311    7.243978    7.312981
   C        17.926854   10.035215    9.886048
   H        17.431158   10.335562    8.956576
   H        17.229462    9.489888   10.529695
   C        19.742630   10.503556    7.556331
   H        18.826483   10.372149    6.961317
   H        19.679334   11.484294    8.049511

84
cis-[(dmpe)2MnH{=SiHPh(MeNHC)}] (cis-8c) ii
Mn       7.27796843       4.57619238      12.30026810
P       6.54275660       4.22679305      14.32576974
P       9.39420825       4.05691219      12.31268325
Si       5.39655968       5.17440453      11.22931011
P       8.00716798       6.57614888      12.79560945
P       6.69311721       2.46429805      11.99364185
N       4.29873545       7.97235178      11.46057336
N       5.59915420       7.75906491       9.75945149
C       5.05021989       7.05526633      10.78741787
C       7.56169549       4.51498583      15.86572380
H       8.51070357       3.97080560      15.78289499
H       7.03048831       4.17750355      16.76677804
H       7.79149443       5.58196842      15.97661190
C       4.98355411       4.52220017       9.45108732
C       4.37834754       9.23107830      10.86710970
C       6.49706205       7.18531046       8.76905445
H       7.06068620       6.37249023       9.23935763
H       7.19502259       7.95599828       8.42729851
H       5.93209762       6.78540880       7.91849059
C       5.20070482       9.09354440       9.78182909
C       3.68937402       4.65382455       8.92194688
H       2.91455889       5.13083782       9.52793380
C       5.94370435       3.88799001       8.64816084
H       6.95658674       3.78062704       9.04519361
C       5.65466393      10.08776166       8.77730006
H       6.74409667      10.23696853       8.81270273
H       5.18076820      11.05717493       8.96556425
H       5.39550405       9.78005681       7.75425962
C       3.66493293      10.41589949      11.40590794
H       2.57372201      10.27695432      11.39790737
H       3.89158371      11.30105270      10.80188790
H       3.96151685      10.63257638      12.44255689
C       4.97700468       5.01550143      14.95786719
H       5.10452562       6.10200125      15.03136729
H       4.68819550       4.62106567      15.94281375
H       4.17740462       4.81028170      14.23482258
C      10.17607421       2.69383168      13.32131172
H       9.92535016       2.83249366      14.38034804
H      11.26926971       2.69291454      13.20808794
H       9.79332119       1.71540256      13.00741707
C       3.50832419       7.68538124      12.64343929
H       2.49586602       8.08824576      12.52281365
H       3.96881916       8.12698877      13.53670620
H       3.45871829       6.59852720      12.75894943
C       7.58557012       1.25349079      10.90733673
H       7.51506680       1.58280004       9.86351065
H       7.13966119       0.25300208      10.99357094
H       8.64418508       1.19379867      11.18250424
C      10.50542351       5.48563581      12.87370613
H      11.36492744       5.10169892      13.44022831
H      10.89872261       5.96176549      11.96337190
C       6.76346782       1.55105557      13.62713459
H       6.31100692       0.55243476      13.53449593
H       7.82056250       1.42553981      13.89362395
C      10.25415300       3.68660022      10.70741916
H       9.84174406       2.77824393      10.25459369
H      11.33850574       3.56322912      10.84159063
H      10.05837232       4.52107685      10.02312948
C       7.17037992       7.82235783      13.89121700
H       6.24390967       8.15724665      13.40995192
H       7.81591584       8.69530305      14.06307952
H       6.91669410       7.37301519      14.85772131
C       5.63348126       3.40568901       7.37518710
H       6.40105976       2.91347406       6.77496563
C       9.66597483       6.47555269      13.66445306
H      10.13573558       7.46785793      13.74104906
H       9.48277121       6.10520057      14.68135016
C       6.05178267       2.42793237      14.64420772
H       6.26995864       2.14597518      15.68373110
H       4.96243102       2.36186148      14.50648209
C       4.97110097       1.93866675      11.51652014
H       4.23325810       2.50200583      12.10107123
H       4.83450571       0.86337947      11.69516365
H       4.79042289       2.15197673      10.45793117
C       3.36521805       4.17785812       7.64935158
H       2.34938021       4.28945279       7.26577240
C       8.51305576       7.78455353      11.46688647
H       9.05306055       7.25024344      10.67696588
H       9.15146733       8.57986686      11.87648493
H       7.62132536       8.24571628      11.03070789
C       4.33951669       3.54987039       6.87003799
H       4.09015990       3.17135971       5.87790214
H       3.97536507       4.99773604      11.79578268
H       7.57705703       4.83104172      10.76045910

80
cis-[(dmpe)2MnH{=SiHEt(MeNHC)}] (cis-8d*) i
  Mn       18.525322    5.157150   12.453611
  Si       18.582787    7.408552   12.046428
  N        18.937469    9.004528    9.467118
  N        20.649149    7.785800    9.893782
  C        19.423288    8.115321   10.378791
  C        19.835468    9.216844    8.427407
  H        20.404517   10.166819    6.609185
  H        18.296110    0.673730   12.927242
  H        16.980995    1.709144   12.295653
  H        17.428293    1.799716   14.009593
  C        17.824197    1.664218   12.996511
  H        17.814220   10.773519    9.608193
  H        18.733995    8.724065   14.123599
  C        20.927959    8.442332    8.700896
  H        22.226812    8.924059    7.085685
  C        20.005568    2.157513   11.303803
  H        19.388489    1.939930   10.427760
  H        20.412578    1.212391   11.690990
  H        20.827712    2.814152   10.995103
  H        22.132338    6.309920    9.825328
  P        19.041127    3.032496   12.632547
  H        19.777017    5.064408   11.493706
  H        17.250421    8.125398   11.773799
  C        20.076011    3.746848   15.091033
  H        20.918454    3.806624   15.796535
  H        19.160585    3.556628   15.671660
  C        20.267112    2.692766   14.021612
  H        20.149032    1.663924   14.391323
  H        21.272782    2.773064   13.582521
  C        19.314246    8.803548   13.191031
  H        19.850487   10.394395   11.783057
  H        20.308789    6.247628   16.464861
  H        18.559714    6.019775   16.213479
  C        21.604118    5.856192   13.990679
  H        22.052010    5.188343   13.244426
  H        19.375287    7.442788   15.524183
  C        19.485737    6.378079   15.748482
  H        22.168921    5.787799   14.930985
  H        21.669903    6.882526   13.611366
  H        20.350490    8.554868   13.468945
  P        17.292068    4.826854   10.666957
  P        16.633606    5.419110   13.512501
  C        17.142122    6.077205    9.290788
  H        16.798949    7.031156    9.706546
  H        16.431947    5.741903    8.522457
  H        18.126704    6.228703    8.830810
  C        17.400414    3.357406    9.531507
  H        18.366020    3.360532    9.011301
  H        16.594059    3.393286    8.785900
  H        17.311388    2.424584   10.099412
  C        15.476302    4.670617   11.117131
  H        14.836930    4.887439   10.247963
  H        15.311861    3.618568   11.397171
  C        15.207618    5.585508   12.298436
  H        14.246605    5.379303   12.792313
  H        15.204204    6.638448   11.977007
  C        15.899877    4.130376   14.649283
  H        15.723756    3.207521   14.084942
  H        14.951787    4.466049   15.093276
  H        16.611668    3.905053   15.454473
  C        16.198542    6.894161   14.564759
  H        16.765446    6.885123   15.501739
  H        15.125222    6.896480   14.802666
  H        16.443293    7.814289   14.019259
  P        19.813631    5.383769   14.213295
  C        21.590652    6.903760   10.568679
  H        22.306350    7.487570   11.161340
  H        21.005546    6.226448   11.213565
  C        22.198535    8.255868    7.952855
  H        23.074789    8.476446    8.578461
  H        22.307212    7.225454    7.584317
  C        17.655660    9.690926    9.534956
  H        17.062161    9.468165    8.640263
  H        17.132472    9.337350   10.427974
  C        19.556351   10.145936    7.301300
  H        18.665699    9.843840    6.731903
  H        19.387056   11.173091    7.655923
  C        19.242664   10.246121   12.688063
  H        18.208769   10.524434   12.437148
  H        19.601227   10.967341   13.438838

80
cis-[(dmpe)2MnH{=SiHEt(MeNHC)}] (cis-8d*) ii
  Mn       18.442722    5.183502   12.425104
  Si       18.661632    7.441628   12.091538
  N        18.987215    8.952112    9.366485
  N        20.671798    7.745493    9.925131
  C        19.433904    8.124964   10.359009
  C        19.919968    9.078965    8.338739
  H        20.535304    9.839766    6.451005
  H        18.619485    0.678559   12.744290
  H        17.224551    1.584949   12.092108
  H        17.573366    1.633755   13.829497
  C        18.030642    1.601668   12.835002
  H        17.834520   10.673844    9.067647
  C        19.694672    9.935028    7.146091
  C        20.991587    8.312404    8.696342
  H        22.333498    8.655357    7.082623
  C        20.214137    2.388110   11.287223
  H        19.647094    2.228246   10.364202
  H        20.646457    1.430770   11.610601
  H        21.015677    3.106908   11.077899
  H        22.210250    6.337316    9.989469
  P        19.115168    3.109466   12.601791
  H        19.616316    5.168146   11.373830
  H        18.336474   10.593033   11.844586
  C        19.976620    3.906379   15.116828
  H        20.775485    3.998496   15.867966
  H        19.031249    3.706596   15.643594
  C        20.260674    2.832564   14.079020
  H        20.145209    1.810807   14.467439
  H        21.293159    2.928808   13.710127
  H        19.801091    8.169293   12.827019
  H        18.779318    9.656999    6.604245
  H        20.231659    6.646566   16.290064
  H        18.477567    6.396667   16.066509
  C        21.537336    5.941816   13.944101
  H        22.002040    5.265608   13.217141
  H        19.310489    7.686651   15.166247
  C        19.409433    6.667126   15.561025
  H        22.079464    5.880405   14.897788
  H        21.603044    6.968271   13.564946
  H        19.606868   10.998039    7.417071
  P        17.186440    4.888511   10.663447
  P        16.558757    5.209696   13.533427
  C        17.070950    6.138462    9.284212
  H        16.709094    7.086242    9.698546
  H        16.382067    5.805442    8.495598
  H        18.066218    6.299717    8.852804
  C        17.301571    3.412691    9.535054
  H        18.253833    3.449692    8.991659
  H        16.477479    3.406225    8.808226
  H        17.270655    2.483952   10.115714
  C        15.361676    4.776106   11.102653
  H        14.734060    5.101965   10.259872
  H        15.145068    3.711263   11.281348
  C        15.126373    5.578174   12.372514
  H        14.163221    5.341908   12.850184
  H        15.148711    6.658368   12.165980
  C        15.826325    3.675448   14.318643
  H        15.696833    2.889987   13.566891
  H        14.854213    3.892318   14.784479
  H        16.511605    3.301072   15.090090
  C        16.070343    6.309749   14.964787
  H        16.408587    5.849030   15.901752
  H        14.976078    6.408733   15.011032
  H        16.519221    7.304715   14.893922
  P        19.740615    5.498455   14.163111
  C        21.588140    6.913588   10.682493
  H        22.227471    7.532008   11.324985
  H        20.987604    6.218014   11.287890
  C        22.276153    8.057190    7.999470
  H        23.140935    8.317900    8.625669
  H        22.382448    7.000092    7.714043
  C        17.694526    9.607998    9.286925
  H        17.087781    9.154828    8.492404
  H        17.178003    9.505905   10.237273
  C        17.281795    8.755045   12.445526
  H        16.466461    8.674578   11.706231
  H        16.810859    8.386730   13.367358
  C        17.718485   10.206497   12.667925
  H        16.864779   10.892819   12.795418
  H        18.336228   10.275080   13.571759

90
trans-[(dmpe)2MnH{=SiHPh(iPrNHC)}] (trans-8a)
Mn       4.75752871      18.96980093       4.12339109
P       4.73625334      20.71320020       2.79062129
P       4.87882756      17.78486134       2.29292323
P       5.16968635      17.30277436       5.47391815
P       5.54859379      20.15123559       5.77858367
H       6.27164437      18.93228700       3.72006747
H       2.26053062      19.05507191       6.94030903
C       0.09617871      16.53871035       6.61343738
Si       2.46692033      19.06707873       4.17901384
H       2.58874900      18.34848453       9.26334090
H       1.74460328      18.90267641       2.83161612
C       0.26549427      16.55491143       3.00713634
H      -0.07508625      20.31904496       3.11564012
H      -0.43644931      18.83277974       8.41466504
C       1.20329086      17.74222197       5.03567258
H       1.05580516      17.15216598       2.54390341
N       0.46373992      16.74749278       4.45401209
H      -1.20415593      17.04986713       1.50123519
H       1.37432436      14.68269336       3.00034362
C      -0.21606444      16.00689693       5.40368758
H      -0.85386026      15.17222176       5.14710868
C       0.35116209      19.40671788       7.90620031
H       0.75466824      20.13717503       8.61843809
H      -0.08884798      19.95654536       7.06830503
H      -0.21663263      16.25471759       7.60871425
C       2.06075889      17.67134719       8.58106173
H       1.28074590      17.16049204       9.16171534
C       6.36012407      21.56244439       2.47512571
H       6.68616417      22.08388774       3.38365639
H       6.28564443      22.29401179       1.65829088
H       7.11572900      20.80590678       2.23438095
C       3.68531742      22.23132166       2.90861701
H       2.62592531      21.95815882       2.85866204
H       3.92319814      22.92466343       2.08999748
H       3.85258096      22.73642830       3.86638091
C       4.31927204      20.19441532       1.04716906
H       3.22956204      20.03909042       1.02613127
H       4.56891194      20.98590850       0.32515463
C       5.05662982      18.89358128       0.78165124
H       6.13269332      19.08309544       0.65205806
H       4.70070594      18.36949663      -0.11722216
C       6.30912808      16.65580052       1.94277483
H       7.23459058      17.11398740       2.30871536
H       6.38691429      16.47157089       0.86207393
H       6.16921947      15.69118868       2.44464873
C       3.55954422      16.64582160       1.63588440
H       3.29567453      15.91345481       2.40837277
H       3.88917937      16.11525084       0.73162717
H       2.67068693      17.24069408       1.39690375
C       6.73628379      16.30560034       5.30438634
H       6.67590978      15.63959225       4.43797255
H       6.91426395      15.69720971       6.20252132
H       7.58017297      16.98847570       5.14997537
C       4.05161890      15.83435421       5.71739177
H       3.04182265      16.15930900       5.98340630
H       4.43524848      15.15112285       6.48878459
H       3.99057076      15.29111333       4.76489349
C       5.46462383      17.85754314       7.27627780
H       4.86407114      17.24274733       7.95858361
H       6.51723170      17.63865347       7.50115824
C       5.20591217      19.35021023       7.43659460
H       5.82836601      19.79605687       8.22726312
H       4.15558373      19.55930757       7.67804288
C       5.28614193      21.94435880       6.20293536
H       5.77517195      22.56538194       5.44150276
H       5.73888463      22.17692391       7.17710229
H       4.22611637      22.21116743       6.22150482
C       7.40656647      20.21687215       5.89694189
H       7.80416483      19.19566817       5.89993216
H       7.74919066      20.74881783       6.79631985
H       7.79845517      20.71810473       5.00423187
N       0.95982511      17.58941620       6.37274238
H       2.77398673      16.92373889       8.21934895
C       1.46482386      18.47743502       7.43094589
C       1.36330310      20.58655946       4.70057891
C       1.71635152      21.43380342       5.76013711
C       0.98239579      22.57752575       6.07660463
C      -0.14467145      22.91026027       5.32290557
C      -0.52542631      22.08436635       4.26290184
C       0.22029709      20.94221022       3.96339983
H       2.59996149      21.18726646       6.35014963
H       1.29210971      23.21546725       6.90663735
H      -0.71775862      23.80868719       5.55454991
H      -1.40080450      22.33830033       3.66210321
C       0.42961922      15.08994445       2.62134238
H      -0.39543252      14.46967406       2.99834275
H       0.43516174      15.00290047       1.52814389
C      -1.08486046      17.13142138       2.58904197
H      -1.91466786      16.59100581       3.06551322
H      -1.15169718      18.19011533       2.86711273

86
trans-[(dmpe)2MnH{=SiHEt(iPrNHC)}] (trans-8b*)
  Mn        4.806703   18.873463    4.197692
  P         4.871352   20.494744    2.744631
  P         4.864605   17.653146    2.390115
  P         5.380356   17.251891    5.536125
  P         5.291666   20.217518    5.843274
  H         6.372143   18.869183    4.049341
  H         2.487382   19.401747    6.939119
  C         0.495507   16.756174    7.261777
  Si        2.512437   18.872396    4.206405
  H         1.544777   20.954882    5.325632
  H         1.790064   18.345419    2.949607
  C         0.599072   15.957644    3.740496
  C         1.355500   20.431209    4.375877
  H         1.726190   21.120329    3.601254
  H        -0.566893   19.502059    4.883485
  H         1.251466   16.578294    3.116423
  N         0.771031   16.513639    5.092823
  H        -0.942319   15.794866    2.238363
  H         2.069215   14.392794    4.079646
  C         0.211126   15.936610    6.217013
  H        -0.331405   15.001542    6.185910
  C         1.051184   14.503321    3.688458
  H         0.382588   13.844456    4.259886
  H         1.047949   14.157884    2.647511
  H         0.248214   16.667254    8.310362
  C        -0.837924   16.157777    3.268705
  H        -1.549648   15.605466    3.897935
  C         6.514688   20.899625    1.968066
  H         7.218005   21.205664    2.751153
  H         6.431551   21.696890    1.215616
  H         6.921027   19.998591    1.494974
  C         4.316955   22.253809    2.967600
  H         3.314530   22.299050    3.405002
  H         4.317726   22.780473    2.002920
  H         5.011804   22.771380    3.641426
  C         3.920710   20.038274    1.202918
  H         2.855989   20.135680    1.457843
  H         4.140200   20.733955    0.379443
  C         4.260937   18.593076    0.850026
  H         5.059352   18.551645    0.097011
  H         3.394706   18.059731    0.436664
  C         6.503443   17.053828    1.739318
  H         7.226368   17.876672    1.763516
  H         6.408992   16.670838    0.713218
  H         6.886522   16.252762    2.380557
  C         3.952850   16.054750    2.127611
  H         4.215632   15.343419    2.920739
  H         4.193111   15.608702    1.152294
  H         2.877916   16.251426    2.171584
  C         6.695759   16.027592    5.072746
  H         6.306425   15.312772    4.336767
  H         7.036195   15.466737    5.954647
  H         7.541404   16.564432    4.628329
  C         4.221385   16.001118    6.292436
  H         3.435782   16.508155    6.860163
  H         4.747540   15.294343    6.949966
  H         3.734847   15.442265    5.482691
  C         6.214893   17.928340    7.083391
  H         6.154691   17.202675    7.908270
  H         7.276695   18.041416    6.818607
  C         5.618816   19.280897    7.436718
  H         6.264682   19.867128    8.107489
  H         4.649375   19.159149    7.935563
  C         4.274041   21.616647    6.534805
  H         4.132428   22.382656    5.764005
  H         4.767903   22.074716    7.403894
  H         3.280875   21.262958    6.832468
  C         6.888345   21.166661    5.731307
  H         7.693890   20.464462    5.487283
  H         7.120444   21.696417    6.665933
  H         6.825623   21.900416    4.918031
  N         1.227118   17.811343    6.749764
  H        -1.101785   17.222158    3.288995
  C         1.705200   18.941997    7.560655
  H         2.784996   19.305811    9.385479
  H        -0.204974   19.476553    8.443306
  C         1.412149   17.683268    5.398881
  C         0.574594   19.935709    7.818882
  H         0.963428   20.811639    8.353716
  H         0.117512   20.274894    6.884516
  C         2.320786   18.456287    8.870288
  H         1.558670   18.043952    9.545371
  H         3.090117   17.693972    8.703394
  C        -0.141715   20.211664    4.156904
  H        -0.725224   21.143480    4.230536
  H        -0.323009   19.785707    3.159516

84
trans-[(dmpe)2MnH{=SiHPh(MeNHC)}] (trans-8c)
Mn       4.75951163      18.92266935       4.11896863
P       4.79701069      20.51758753       2.62347670
P       4.75156887      17.58242277       2.41211450
P       5.21115039      17.35561061       5.56712071
P       5.42404532      20.24401982       5.71862242
H       6.29086085      18.90964691       3.80174545
H       2.58972592      18.33444740       6.74858533
C       0.24380091      16.10179919       5.94257086
Si       2.49022691      19.13879244       4.12394094
H       1.86236645      17.11277281       7.83764181
H       1.80990116      19.28179318       2.75246796
C       0.38559402      16.88306963       2.42386112
H       0.01359532      20.59375874       3.25776799
H       0.98120649      18.63328797       7.46837691
C       1.27124253      17.66275768       4.63250866
H       0.91295656      17.77884293       2.08241494
N       0.54912330      16.79591262       3.86417567
H      -0.67895475      16.96838167       2.17215362
H       0.80351458      15.99604208       1.93191966
C      -0.08334206      15.82642764       4.64350051
C      -0.92183301      14.75107676       4.05705586
H      -1.78078614      15.15664969       3.50248139
H      -1.31265575      14.10204258       4.84813386
H      -0.34846743      14.12179255       3.36065293
C      -0.12852966      15.41830580       7.20646847
H       0.75048831      15.00182256       7.72042651
H      -0.81479913      14.58993229       7.00012130
C       6.34475562      21.51139643       2.38224118
H       6.50278611      22.17477420       3.24167747
H       6.29005395      22.12521401       1.47219994
H       7.19526753      20.82220255       2.31793116
C       3.58939590      21.92498223       2.55700358
H       2.57331137      21.53035457       2.43737766
H       3.81489179      22.60428863       1.72305544
H       3.62249248      22.48460731       3.49886005
C       4.61768508      19.84310724       0.86362516
H       4.00581259      20.53149549       0.26446495
H       5.62562138      19.83391509       0.42439377
C       4.04616280      18.43245247       0.90184871
H       4.26952309      17.86180000      -0.01195716
H       2.95602827      18.46378885       1.03589427
C       6.38144839      17.05364107       1.69263904
H       6.96392620      17.94995653       1.44924139
H       6.25437066      16.43841376       0.79024187
H       6.94762325      16.48875734       2.44199946
C       3.90668025      15.92832979       2.29887228
H       4.53780337      15.17021879       2.77998301
H       3.74589807      15.62977613       1.25305250
H       2.95077379      15.95886996       2.83113186
C       6.85549550      16.49171184       5.43635975
H       6.86169351      15.86119245       4.53842554
H       7.05890116      15.85864516       6.31218305
H       7.64583725      17.24309273       5.32660074
C       4.23329075      15.79569793       5.87505352
H       3.16906489      16.01529029       5.99195108
H       4.60135873      15.26846507       6.76672910
H       4.34218608      15.13291359       5.00867652
C       5.37768017      18.00615528       7.35210108
H       4.70576379      17.43285328       8.00551650
H       6.40256169      17.78874636       7.68259213
C       5.10369456      19.50604336       7.41463405
H       5.71888164      20.00882115       8.17577956
H       4.05256327      19.71096709       7.65799367
C       4.94007416      22.01201592       6.01093266
H       5.41781923      22.63974047       5.24766423
H       5.27850755      22.35544113       6.99891493
H       3.85640737      22.14017625       5.92995060
C       7.25982722      20.49430480       5.88334239
H       7.74495334      19.51707845       5.99238980
H       7.51589485      21.12957276       6.74342210
H       7.64288335      20.95123310       4.96377816
N       1.06873998      17.22223602       5.90536787
H      -0.62866464      16.10290169       7.90652332
C       1.65080941      17.86251072       7.06854856
C       1.34876982      20.48953295       4.94874838
C       1.58975156      21.03576936       6.21918423
C       0.76780330      22.01881496       6.77571015
C      -0.33125959      22.49508358       6.06011802
C      -0.59614028      21.97406382       4.79188342
C       0.23129938      20.98697371       4.25395541
H       2.45278529      20.69193020       6.79013258
H       0.99213755      22.42158668       7.76523412
H      -0.97175112      23.26964485       6.48353695
H      -1.44904240      22.34258149       4.21875656

80
trans-[(dmpe)2MnH{=SiHEt(MeNHC)}] (trans-8d*)
  Mn        4.803376   18.937464    3.957158
  P         4.906373   20.467334    2.419910
  P         5.060657   17.585225    2.265594
  P         5.346645   17.424430    5.453604
  P         5.098271   20.389818    5.568847
  H         6.376750   18.976428    3.977874
  H         2.248355   17.988506    1.736441
  C         0.167853   20.580890    1.404295
  Si        2.542062   18.779990    4.351906
  H         1.588160   16.564439    3.478250
  H         1.985323   19.335539    5.679227
  C         0.687615   21.745209    4.776936
  C         1.420696   17.180351    4.374905
  H         1.813879   16.577392    5.204602
  H        -0.544837   17.932178    3.748423
  H         1.035860   21.037204    5.534768
  N         0.682631   21.054258    3.502210
  H        -0.327585   22.079053    5.020594
  H         1.359356   22.612682    4.752538
  C         0.004855   21.527045    2.377656
  C        -0.717546   22.823621    2.363676
  H        -1.545235   22.840728    3.088321
  H        -1.142214   23.009072    1.371125
  H        -0.050677   23.663805    2.605690
  C        -0.323217   20.528883    0.004435
  H         0.505527   20.516284   -0.719145
  H        -0.939756   21.407949   -0.212166
  C         6.585604   21.063465    1.882752
  H         7.112723   21.504297    2.735828
  H         6.525519   21.799415    1.067982
  H         7.169669   20.197291    1.548915
  C         4.058324   22.122615    2.438957
  H         2.995863   21.985749    2.670264
  H         4.157230   22.630980    1.469036
  H         4.505530   22.760028    3.212000
  C         4.285073   19.856935    0.758384
  H         3.196011   19.982745    0.786330
  H         4.667774   20.498144   -0.049580
  C         4.687610   18.398372    0.578666
  H         5.602715   18.324041   -0.023710
  H         3.921053   17.808453    0.057585
  C         6.774142   16.986015    1.836414
  H         7.445965   17.852229    1.807167
  H         6.786131   16.475707    0.862741
  H         7.144955   16.297215    2.601024
  C         4.220328   15.936120    2.045199
  H         4.531792   15.274202    2.864006
  H         4.486976   15.464392    1.088645
  H         3.131778   16.042994    2.108558
  C         6.710652   16.198370    5.181348
  H         6.393715   15.415530    4.481237
  H         6.987112   15.721215    6.131802
  H         7.581736   16.716351    4.764693
  C         4.180119   16.245311    6.299706
  H         3.372839   16.810955    6.781554
  H         4.700964   15.642680    7.057131
  H         3.730474   15.576022    5.556224
  C         6.061419   18.249643    6.979767
  H         6.034158   17.562722    7.838040
  H         7.115735   18.467242    6.751980
  C         5.293148   19.535553    7.220877
  H         5.774317   20.196984    7.956475
  H         4.273449   19.316938    7.574624
  C         3.937384   21.728881    6.119964
  H         3.745638   22.429036    5.299095
  H         4.355342   22.282425    6.972229
  H         2.991674   21.266692    6.421006
  C         6.643425   21.422197    5.559006
  H         7.502181   20.778178    5.337987
  H         6.793816   21.936235    6.518704
  H         6.573239   22.178373    4.766572
  N         0.948430   19.575465    1.968511
  H        -0.937384   19.635511   -0.179749
  C         1.302890   18.336117    1.306416
  H         1.436200   18.509176    0.234107
  H         0.528559   17.573951    1.463226
  C         1.285685   19.854293    3.260485
  C        -0.076453   17.405572    4.594292
  H        -0.629427   16.463332    4.735205
  H        -0.247788   18.026382    5.486281

69
[(dmpe)2Mn(CH2CH2SiH2Ph)] (DPh)
Mn       4.99627074       8.60784473       3.54659218
P       3.58955612      10.15822404       4.24259779
P       6.53779989       7.08609415       3.07799105
P       6.68042242       9.66801367       4.40583505
P       4.17676940       7.45120043       5.20383505
C       5.03232996       9.42572815       1.65333647
H       5.46206085       5.02467081       2.29777225
C       3.10241280       5.97662090       4.83544076
H       2.27179944      10.51906947       6.31178058
H       3.85874806       7.73067371       2.60334961
H       4.72431958      10.46767066       1.50798766
H       4.15972553       4.20789001       0.27330678
C       8.27303271       8.64787559       4.48244307
H       8.91177122       8.98312510       3.65297844
H       8.81428301       8.85680246       5.41506537
H       5.87981589       4.92195177       4.01807340
H       7.15377637       4.70975631       2.78568134
H       5.11497260       6.60818310      -0.16378164
Si       3.79330878       7.17966655       0.23612361
H       5.88393940       9.19688753       1.00365513
C       6.23665098       5.25949863       3.03789220
C       2.91973246       8.42116040       6.23993958
H       1.92258591       8.13629696       5.87330361
H       2.97569081       8.12366714       7.29605919
C       7.92388196       7.17691887       4.31997994
H       7.55243707       6.75585503       5.26209713
H       8.78011150       6.57093721       3.98890601
H       3.20350314       7.87108183      -0.95470083
C       3.90933178       8.44412455       1.62744887
C       3.14694867       9.91182393       6.03682715
H       2.92498775       8.93214025       1.64275132
C       3.90389549      11.98299191       4.19892758
H       4.79173429      12.23809597       4.78740492
H       3.04515189      12.54173812       4.59508598
H       4.08110061      12.29240785       3.16098958
H       2.30998364       6.27925164       4.13960675
H       2.64449693       5.56830080       5.74782942
H       3.68572488       5.18889710       4.34516489
H       4.00025413      10.26101625       6.63267636
C       6.72758072      10.38226490       6.12553991
H       5.97235131      11.16794872       6.24259271
H       7.71469151      10.81362778       6.34181338
H       6.51427893       9.59222480       6.85606077
C       7.57541000       7.21885020       1.53763403
H       6.96384242       7.05114001       0.64505011
H       8.38981676       6.48214865       1.55585745
H       8.00180437       8.22714440       1.46925927
C       7.35052676      11.14113272       3.49674221
H       7.54548657      10.84392745       2.45940983
H       8.27902527      11.51021166       3.95484045
H       6.61152337      11.94945233       3.47996134
C       1.87120298      10.21986327       3.52047239
H       1.90933422      10.58162862       2.48497502
H       1.23151584      10.89928620       4.09931651
H       1.42682180       9.21675428       3.52049463
C       5.16182210       6.67371465       6.58286666
H       5.80250080       5.87808512       6.18303214
H       4.50135484       6.23713351       7.34493427
H       5.80578619       7.42694010       7.05313568
C       2.70906663       5.73512785       0.76246087
C       1.43180744       5.95744765       1.30636219
C       0.64942358       4.89940690       1.76742122
C       1.13226684       3.59107456       1.69553742
C       2.39540362       3.34803853       1.15589975
C       3.17293143       4.41160395       0.69448307
H       1.03909237       6.97483138       1.37477293
H      -0.33865033       5.09378294       2.18632675
H       0.52347946       2.76257945       2.05862014
H       2.77661068       2.32797958       1.09445048

71
[(dmpe)2Mn(CH2CH2SiH2nBu)] (DBu)
Mn       4.91928001       8.65500194       3.54413482
P       3.68409848      10.30288722       4.33542900
P       6.31709621       7.04120961       2.94824112
P       6.73427430       9.58557946       4.27819747
P       4.15199306       7.56125534       5.26216262
C       4.86013498       9.46754554       1.65086687
H       5.09925564       5.07412261       2.13951082
C       2.93988253       6.17288419       4.98027208
H       2.55248289      10.75306275       6.49514972
H       3.64637654       7.86784398       2.70077459
H       4.61011389      10.52744063       1.52467518
Si       3.37757516       7.28278586       0.36064808
C       8.24559138       8.44419579       4.26561029
H       8.87047849       8.74283462       3.41213645
H       8.84266378       8.59654384       5.17473713
H       5.51807828       4.90931375       3.86044197
H       6.76325715       4.63226740       2.61078511
H       4.62955699       6.55600750      -0.02096337
H       2.88650993       7.99370053      -0.86508431
H       5.64330662       9.18545109       0.93927679
C       5.88902339       5.23953152       2.88306695
C       3.05386449       8.61725620       6.39211110
H       2.01233681       8.40056529       6.11250652
H       3.17783683       8.31882603       7.44213901
C       7.77887190       7.00571125       4.10273002
H       7.43688027       6.59370665       5.05958913
H       8.56645586       6.34654690       3.70875424
H       2.46923671       5.50140664       1.80504601
C       3.67564881       8.56244620       1.70963608
C       3.36300426      10.08911102       6.15993877
H       2.72904603       9.11483737       1.79087050
C       4.12664557      12.09919614       4.25499069
H       5.07461276      12.28998378       4.76920910
H       3.34477283      12.72001295       4.71306325
H       4.24295966      12.39231315       3.20378145
H       2.12599104       6.54011877       4.34162058
H       2.51521539       5.79979889       5.92329788
H       3.42995745       5.34248390       4.45831756
H       4.27938237      10.38298924       6.68778494
C       6.95087102      10.30562734       5.98227961
H       6.27336861      11.15290583       6.13829993
H       7.98254265      10.65391843       6.12890890
H       6.72085677       9.54105108       6.73459197
C       7.26750465       7.14293237       1.35074939
H       6.59305567       7.04436209       0.49395626
H       8.02557990       6.34970107       1.30133390
H       7.76178653       8.11969254       1.28163006
C       7.45171599      10.99705812       3.30923927
H       7.55720943      10.67797887       2.26542168
H       8.43193878      11.30179980       3.70225186
H       6.77259035      11.85639619       3.32854864
C       1.92585495      10.48810254       3.74460880
H       1.91220745      10.84069513       2.70543597
H       1.38388920      11.21580568       4.36317147
H       1.40942212       9.52124071       3.78755934
C       5.17340662       6.69437507       6.55912586
H       5.70926541       5.84956903       6.10867443
H       4.54226901       6.31100889       7.37296170
H       5.91551308       7.38709678       6.97466750
C       2.09133787       6.01085120       0.90249759
H       1.18559240       6.55378336       1.22256596
H       2.63834620       4.44274513      -0.49032919
C       1.72941844       4.97998583      -0.17104994
H       1.06102483       3.43313124       1.17484766
H       1.35741962       5.49845752      -1.07043944
C       0.68328026       3.96104909       0.28413116
H      -0.22110609       4.49981312       0.61069684
H       1.20130550       2.38080685      -1.12385873
C       0.31849471       2.95097648      -0.80063332
H      -0.43281693       2.23183834      -0.44821824
H      -0.09150227       3.45510008      -1.68755855

65
[(dmpe)2Mn(CH2CH2SiH2Et)] (DEt)
Mn       4.91757740       8.65093540       3.54716855
P       3.67712149      10.29842098       4.33014535
P       6.32225630       7.04090879       2.95775303
P       6.72945812       9.59477267       4.27141878
P       4.16165191       7.56587190       5.27530277
C       4.84687324       9.45044521       1.64919688
H       5.11191539       5.06354727       2.16233884
C       2.95471338       6.17043644       5.00606285
H       2.54861610      10.75821858       6.48944394
H       3.64679975       7.84859079       2.71136353
H       4.58923764      10.50770504       1.51592039
Si       3.38109904       7.25258359       0.37088447
C       8.24582354       8.45975271       4.26548903
H       8.86974003       8.75639632       3.41061892
H       8.84188965       8.61979484       5.17394289
H       5.53572545       4.91036599       3.88307575
H       6.77916231       4.63241618       2.63191152
H       4.63886895       6.53084064      -0.00165994
H       2.89419689       7.95704906      -0.86039138
H       5.62941898       9.16889552       0.93657768
C       5.90268242       5.23697545       2.90296402
C       3.06214527       8.62462446       6.40153611
H       2.02075502       8.39998594       6.12776716
H       3.19188732       8.33493990       7.45330909
C       7.78559577       7.01831078       4.11056871
H       7.44689518       6.60950170       5.06993141
H       8.57572582       6.36085178       3.71886264
H       2.46236124       5.48697715       1.82401133
C       3.66782809       8.53783075       1.71696223
C       3.36206249      10.09642909       6.15709932
H       2.71803897       9.08472277       1.79747612
C       4.11206134      12.09594216       4.23567640
H       5.06078887      12.29432332       4.74557620
H       3.32902539      12.71675109       4.69175367
H       4.22396362      12.38207217       3.18206585
H       2.13699212       6.53074179       4.36829211
H       2.53483721       5.80089779       5.95262641
H       3.44673411       5.33925883       4.48716119
H       4.27805851      10.39971501       6.68025275
C       6.94641419      10.32898660       5.96941250
H       6.26599465      11.17478951       6.12048357
H       7.97703987      10.68242246       6.11096944
H       6.72121222       9.56931060       6.72812474
C       7.27099122       7.13948462       1.35904668
H       6.59674742       7.03336808       0.50305096
H       8.03308131       6.34990134       1.31309050
H       7.76026552       8.11841605       1.28501212
C       7.43947691      11.00153420       3.29009436
H       7.54410640      10.67468089       2.24858877
H       8.41931762      11.31310548       3.67869247
H       6.75709820      11.85839494       3.30402967
C       1.91675032      10.47236821       3.74254845
H       1.89920935      10.81676072       2.70068058
H       1.37362329      11.20285837       4.35678653
H       1.40405014       9.50395751       3.79440738
C       5.19021991       6.71171629       6.57508877
H       5.72733792       5.86539417       6.12899986
H       4.56284755       6.33212408       7.39357670
H       5.93136679       7.40973198       6.98342887
C       2.10047642       5.96887475       0.90138042
H       1.17813770       6.50203542       1.18363184
H       2.70617198       4.35655200      -0.44497955
C       1.80026342       4.91514982      -0.17048648
H       1.05275277       4.18509952       0.17053812
H       1.41418726       5.37897970      -1.08888299

75
[(dmpe)2Mn(CH2CH2SiHEtPh)] (DPh,Et)
Mn       4.86279761       8.67584574       3.57765960
P       3.54483762      10.18424509       4.49849837
P       6.33728689       7.18472403       2.86196184
P       6.63436883       9.68415029       4.31390821
P       4.20769471       7.42531272       5.23953755
C       4.70702227       9.59275722       1.73961318
H       5.17559826       5.17527433       2.07586272
C       3.09884551       5.96997740       4.89876849
H       2.43837635      10.42436299       6.70484780
H       3.63510057       7.84725654       2.71263957
H       4.38963647      10.64128151       1.68665440
H       2.15002586       2.58940090       1.25527411
C       8.22024783       8.66074801       4.16559064
H       8.77294735       9.04406064       3.29608922
H       8.85559048       8.81393315       5.04843106
H       5.76873087       4.96776529       3.73496039
H       6.90652359       4.83043277       2.36598049
H       4.55163133       6.79382832      -0.15703795
H      -0.73899594       5.46788592       2.63833226
H       5.48611088       9.40445687       0.99343244
C       6.02385449       5.36361968       2.74494962
C       3.06139193       8.33329703       6.44597895
H       2.03231392       8.07159808       6.15879195
H       3.21497825       7.97343779       7.47261141
C       7.84689433       7.20207344       3.95367780
H       7.57307798       6.72568854       4.90297149
H       8.66005036       6.61667622       3.49957732
H       0.00781671       3.10447435       2.41325917
C       3.58429580       8.61106392       1.77536437
C       3.27809107       9.83321524       6.31017783
H       2.60973865       9.09812901       1.92608546
C       3.86709051      12.00828481       4.53177574
H       4.81108479      12.22639577       5.04260002
H       3.05637787      12.54416605       5.04387908
H       3.94260679      12.37865746       3.50138753
H       2.24182887       6.30692237       4.30236433
H       2.73322498       5.51042262       5.82825515
H       3.62937607       5.21249373       4.31068276
H       4.18841896      10.14532212       6.83866136
C       6.86553125      10.29846253       6.05734421
H       6.12812536      11.07244473       6.29945311
H       7.87084681      10.72070354       6.19293063
H       6.72918565       9.46627267       6.75891648
C       7.20436991       7.41107165       1.22982259
H       6.49691790       7.30192638       0.40122642
H       8.00808810       6.67163320       1.11312605
H       7.63155500       8.42011002       1.17932712
C       7.21621166      11.20704927       3.42535440
H       7.30039078      10.96949027       2.35809324
H       8.18961936      11.54945935       3.80415193
H       6.48429426      12.01506112       3.53163762
C       1.76378842      10.29390846       3.95404752
H       1.70392268      10.71657574       2.94281239
H       1.18992979      10.93965604       4.63199273
H       1.31291477       9.29382003       3.93827459
C       5.32308374       6.57670145       6.46928401
H       5.92016675       5.80759797       5.96384400
H       4.74094533       6.09532575       7.26741271
H       6.01131770       7.30557235       6.91450785
Si       3.28462702       7.41371664       0.34908486
H       4.20711179       9.15488471      -2.04250593
H       3.53777290       4.42120572       0.33782528
C       2.43329965       8.34019843      -1.05809858
H       2.19177060       7.60846637      -1.84502732
H       1.46314384       8.70144059      -0.67866657
C       2.20345729       6.00150168       0.96662791
C       0.98714791       6.26813562       1.62013862
C       0.20061495       5.23786959       2.13439975
C       0.61857946       3.91160944       2.00787497
C       1.81979514       3.62372343       1.35946965
C       2.60016580       4.66024547       0.84444994
H       0.64681037       7.30021525       1.73608315
C       3.24943162       9.50447651      -1.63209055
H       2.71014636      10.01674051      -2.44134176
H       3.48331206      10.24735131      -0.85811367

77
[(dmpe)2Mn(CH2CH2SiHEtnBu)] (DBu,Et)
Mn       4.88966158       8.67221562       3.58705977
P       3.66365282      10.28537422       4.45580966
P       6.28742581       7.10405377       2.88532036
P       6.71995644       9.62195341       4.25155877
P       4.22023647       7.53899242       5.31869823
C       4.69271929       9.51185202       1.71431419
H       5.06559802       5.14294082       2.07421597
C       3.02051955       6.13430656       5.06432913
H       2.61016587      10.68013672       6.66623740
H       3.62652769       7.82507766       2.77978356
H       4.39543685      10.56354129       1.62190157
C       2.01811842       5.98865695       1.02249671
C       8.24894654       8.50746844       4.14945489
H       8.83452791       8.83829037       3.28011501
H       8.87879669       8.64803301       5.03814138
H       5.55878697       4.93669619       3.77134589
H       6.75375846       4.71264442       2.46269101
H       4.45275730       6.66980477      -0.04815023
C       1.14293090       9.02522027      -0.67517860
H       5.44236798       9.27329860       0.95172692
C       5.88353175       5.29882911       2.78880617
C       3.15119926       8.55693646       6.51072380
H       2.10325426       8.32248484       6.27224531
H       3.32574102       8.24628948       7.55001413
C       7.80146140       7.06493411       3.96835725
H       7.51042163       6.62078183       4.92787698
H       8.58178464       6.43160192       3.52109124
H       1.27303516      10.50869668      -2.23303783
C       3.54974354       8.55750960       1.82527011
C       3.41969299      10.03833060       6.28812213
H       2.59303183       9.06886466       1.99785647
C       4.08021280      12.08881559       4.38822669
H       5.04610093      12.28369717       4.86618434
H       3.31020786      12.69162409       4.88850935
H       4.14932906      12.40063953       3.33822945
H       2.17656837       6.49636636       4.46275368
H       2.63891417       5.74135214       6.01765299
H       3.50335056       5.31946322       4.51193362
H       4.35084002      10.34427813       6.78247705
C       7.00447086      10.31759080       5.95604385
H       6.31801166      11.14728952       6.16012324
H       8.03476663      10.68484371       6.06023287
H       6.82608841       9.53490682       6.70376854
C       7.15141763       7.26684186       1.24496158
H       6.43198045       7.17573240       0.42441570
H       7.92137861       6.49150153       1.13304222
H       7.62100901       8.25576021       1.17625983
C       7.36949445      11.06107969       3.27388190
H       7.42653755      10.76076829       2.22068012
H       8.36407780      11.37359813       3.62240518
H       6.68045624      11.90993582       3.34199313
C       1.88151537      10.46245943       3.93553876
H       1.82589993      10.82041403       2.89928273
H       1.36013757      11.18408750       4.57841983
H       1.37175800       9.49282541       3.99306302
C       5.31089366       6.66859395       6.55496105
H       5.84143351       5.84251481       6.06495439
H       4.72262152       6.25870030       7.38783963
H       6.05805560       7.36730145       6.95093195
Si       3.19867531       7.34249456       0.42784969
H       3.20178812       9.02871032      -1.36560045
H       2.49284168       5.47634229       1.87482732
H       1.11590103       6.47044733       1.43393068
H       0.40030830       8.30152284      -0.29796201
H       2.52062591       4.48130892      -0.47919823
C       2.44993839       8.30162350      -1.01774573
H       2.28794166       7.60643435      -1.85814996
H       1.31808381       9.73346916       0.15187361
C       1.63203068       4.97436809      -0.05969055
H       0.97152914       4.18696006       0.33008516
H       1.10650390       5.45909319      -0.89448228
C       0.53120685       9.78951711      -1.85011315
H       0.33670325       9.08452136      -2.67457227
H      -0.57699488      11.25526537      -0.68031010
C      -0.75612049      10.52154592      -1.47964075
H      -1.17844371      11.06036128      -2.33816056
H      -1.52062015       9.81916739      -1.11701672

79
[(dmpe)2Mn(CH2CH2SiHPh2)] (DPh2)
Mn       4.91482652       8.67487096       3.61410736
P       3.54369708      10.13538621       4.54113180
P       6.43643995       7.22833424       2.90483363
P       6.64861877       9.72136315       4.38814258
P       4.26418607       7.38150719       5.24508709
C       4.75716183       9.62298265       1.79173496
H       5.33640127       5.18633715       2.11075735
C       3.19908173       5.90558327       4.85606291
H       2.39825330      10.30886234       6.73300822
H       3.73167698       7.81995714       2.70778281
H       4.41725576      10.66530492       1.76083640
H       3.94178057       4.52575707       0.21807144
C       8.26495291       8.75019897       4.23213263
H       8.80390060       9.15668592       3.36447905
H       8.89647178       8.91681662       5.11533032
H       5.93066316       4.99282527       3.77043164
H       7.07629549       4.89402991       2.40531791
C       2.56612014       9.83051124      -1.09369977
Si       3.39540628       7.47684998       0.32086554
H       5.54563375       9.46636556       1.04741005
C       6.17659154       5.39927479       2.78242016
C       3.07374437       8.23802680       6.44541272
H       2.05673837       7.95809294       6.13354025
H       3.21642018       7.86222727       7.46788526
C       7.93584069       7.28290308       4.00941537
H       7.66712239       6.79380124       4.95392829
H       8.76916930       6.72316934       3.55954910
H       1.33085798       6.71697286      -1.70161984
C       3.65682174       8.61457993       1.80103324
C       3.25764858       9.74473274       6.34133239
H       2.66975775       9.07059673       1.95805840
C       3.82252618      11.96531843       4.61358407
H       4.75220509      12.19604292       5.14460656
H       2.99056241      12.47145920       5.12176096
H       3.90554682      12.35755300       3.59192319
H       2.34599956       6.23360408       4.24887953
H       2.82609566       5.42029320       5.76938784
H       3.75932799       5.17210257       4.26525748
H       4.15211402      10.06754100       6.89017897
C       6.84386710      10.30325509       6.14672251
H       6.07795886      11.04550251       6.39943339
H       7.83284808      10.75622683       6.30185898
H       6.72978985       9.45077576       6.82758075
C       7.30506382       7.48051629       1.27812130
H       6.60506672       7.34707357       0.44638129
H       8.13344322       6.76805617       1.16623590
H       7.69844097       8.50313537       1.22680799
C       7.19321461      11.27838423       3.53653101
H       7.29598399      11.06434498       2.46592129
H       8.15232788      11.64072545       3.93275240
H       6.43763797      12.06308509       3.65044154
C       1.76989401      10.21363841       3.97000516
H       1.71384740      10.65130259       2.96494946
H       1.17184210      10.83446246       4.65025073
H       1.34148051       9.20442272       3.93065168
C       5.37970148       6.54261675       6.48089084
H       6.01405885       5.80501716       5.97410482
H       4.79673824       6.02582962       7.25593214
H       6.03260986       7.28481882       6.95632100
H       4.68688308       6.99190605      -0.26156744
C       1.82542699      10.54924412      -2.03246763
C       0.91255919       9.88945261      -2.85687489
C       0.74298570       8.50929005      -2.73758599
C       1.48285651       7.79395245      -1.79542651
H       3.27595945      10.35593758      -0.45187747
C       2.40810103       8.44022905      -0.95896018
H       1.95913122      11.62828474      -2.12023025
H       0.33189112      10.45071000      -3.58981489
H       0.02853047       7.98956379      -3.37723654
C       2.43641948       5.94577105       0.84257703
C       1.17794571       6.07368735       1.45669526
C       0.48486108       4.95670275       1.92077006
C       1.03951572       3.68269108       1.77904737
C       2.28323451       3.53273726       1.16556199
C       2.97124236       4.65564001       0.70170846
H       0.72917174       7.06336640       1.57067360
H      -0.49027912       5.07741023       2.39420604
H       0.50002129       2.80800760       2.14341310
H       2.71778638       2.53943785       1.04666048

71
[(dmpe)2Mn(CH2CH2SiHEt2)] (DEt2)
  Mn        4.891680    8.679446    3.583595
  P         3.674791   10.300858    4.450048
  P         6.284008    7.102930    2.887904
  P         6.724958    9.614316    4.262243
  P         4.202869    7.546847    5.308108
  C         4.710670    9.524053    1.711467
  H         5.063892    5.149524    2.054843
  C         2.995436    6.151027    5.042356
  H         2.610575   10.697331    6.655055
  H         3.623013    7.846438    2.768967
  H         4.423143   10.578413    1.619392
  C         2.083627    5.970001    0.999250
  C         8.246528    8.489334    4.167844
  H         8.839247    8.816448    3.301954
  H         8.872410    8.624708    5.060120
  H         5.529217    4.937992    3.759066
  H         6.743327    4.709865    2.468833
  H         4.482099    6.741729   -0.093977
  C         1.033808    8.898364   -0.673165
  H         5.462426    9.280014    0.952661
  C         5.871243    5.300120    2.782411
  C         3.132681    8.569772    6.494598
  H         2.084829    8.345826    6.245752
  H         3.295022    8.253668    7.534227
  C         7.789115    7.050525    3.982969
  H         7.487368    6.608383    4.940079
  H         8.567635    6.411200    3.541120
  H         0.601471    9.447498   -1.521283
  C         3.558659    8.579051    1.813925
  C         3.416576   10.049409    6.279843
  H         2.605023    9.098591    1.979964
  C         4.107873   12.100737    4.391480
  H         5.072205   12.285658    4.876416
  H         3.339878   12.708541    4.888787
  H         4.186578   12.415506    3.343044
  H         2.159370    6.519169    4.433550
  H         2.602873    5.760298    5.992131
  H         3.477154    5.333000    4.493727
  H         4.347205   10.344554    6.781685
  C         7.003628   10.302658    5.970751
  H         6.321614   11.136155    6.174035
  H         8.035748   10.662596    6.082115
  H         6.815855    9.518495    6.714617
  C         7.163639    7.263975    1.255689
  H         6.451254    7.175802    0.428734
  H         7.932098    6.486185    1.150480
  H         7.636959    8.251400    1.191558
  C         7.391795   11.051113    3.292822
  H         7.453689   10.753101    2.239242
  H         8.386399   11.354950    3.648892
  H         6.708970   11.905129    3.358502
  C         1.897776   10.496137    3.919343
  H         1.852625   10.858981    2.884324
  H         1.379021   11.220036    4.561777
  H         1.378751    9.531048    3.969778
  C         5.278573    6.666314    6.550303
  H         5.807224    5.837885    6.062233
  H         4.681384    6.258376    7.377783
  H         6.027385    7.359060    6.953566
  Si        3.215321    7.367672    0.410967
  H         3.104680    9.124760   -1.304015
  H         2.585768    5.452634    1.832342
  H         1.175468    6.417227    1.435833
  H         0.320607    8.108315   -0.397815
  H         2.602715    4.514215   -0.547405
  C         2.412954    8.319112   -1.012186
  H         2.341747    7.650188   -1.884104
  H         1.087131    9.597555    0.173379
  C         1.707796    4.969871   -0.099879
  H         1.078747    4.153703    0.282598
  H         1.152483    5.457748   -0.913283

69
[(dmpe)2Mn{CH(Me)(SiH2Ph)}] (FPh)
Mn       4.85377967      17.25314700       4.23056476
P       3.84316780      18.10190581       6.04137817
C       6.54206403      16.55201430       5.28668710
H       7.14224867      15.85121465       4.69023918
H       7.02641144      14.47582152       6.96755067
P       3.69666986      15.41139750       4.18589766
P       5.84263212      16.43345066       2.40992100
P       3.51306070      18.57624939       3.13743817
H       5.87483816      14.17153296       1.38081390
C       2.09266633      19.18742271       4.19431882
C       6.81345691      17.97468076       4.94790380
H       5.95520910      18.54216441       4.29550663
H       6.90513593      18.64959702       5.80612929
H       7.67642624      18.13429797       4.28831234
H       1.61125264      20.06372268       3.73534023
H       1.35208462      18.37443435       4.22907880
H       3.13558942      18.32066729       0.70580328
C       1.84743631      15.30028065       4.07105492
H       1.38177440      15.67786956       4.98825498
H       1.52795655      14.25941216       3.92135096
C       3.95850967      14.14711819       5.51764660
H       5.01602401      13.85715981       5.52813178
H       3.33802019      13.25597690       5.34967383
H       3.71893843      14.57272169       6.49736183
C       4.79948720      19.04741132       7.32400600
H       5.49668050      18.40235262       7.87083460
H       4.10582310      19.50086226       8.04509596
H       5.37349244      19.84677393       6.83967447
C       2.65038784      19.47540560       5.57403782
H       1.87397195      19.58644119       6.34410220
H       3.23620678      20.40665800       5.55994258
C       4.18993557      20.21611236       2.56947651
H       4.60512947      20.75281896       3.43187497
H       3.42749910      20.84218272       2.08440567
H       5.01020802      20.03680759       1.86247056
H       1.48854846      15.90777619       3.23241743
C       4.12434422      14.34422671       2.70030745
H       3.90303726      13.28740373       2.90745343
H       3.47592416      14.66245034       1.86972282
C       5.37479521      16.83171677       0.65931019
H       4.34202818      16.52627687       0.46422691
H       6.03893369      16.30535878      -0.03921755
H       5.45749462      17.91089852       0.48134810
C       7.67883478      16.54704560       2.15273594
H       7.94268617      17.57490185       1.87260861
H       7.98542451      15.87402971       1.34144219
H       8.23107977      16.27917254       3.06041532
C       2.75185773      17.15146274       7.20404835
H       1.92823215      16.68430144       6.65369176
H       2.33243335      17.82327020       7.96502068
H       3.33087458      16.36813587       7.70442129
H       1.67094839      18.89325800       1.53373639
H       2.14037424      17.17330931       1.62816008
C       5.58701204      14.58706197       2.35752518
H       6.24393128      14.14729183       3.12270605
C       2.52121773      18.20087296       1.60331617
Si       6.63921615      15.92750462       7.02482171
H       9.28820081      17.21776575       6.47564994
H       5.38337750      15.96649518       7.84490019
C       7.90047517      16.84984872       8.09284185
C       7.67330460      17.05931450       9.46288533
C       8.60052564      17.73674828      10.25629083
C       9.77822564      18.22514806       9.68861693
C      10.02142012      18.03298795       8.32716993
C       9.08993262      17.35435432       7.54101999
H       6.75180665      16.68759929       9.91731196
H       8.40323534      17.88711899      11.31865132
H      10.50348307      18.75784247      10.30469082
H      10.93881870      18.41618698       7.87795459

71
[(dmpe)2Mn{CH(Me)(SiH2nBu)}] (FBu)
Mn       4.75163578      17.15899262       4.10324754
P       3.86611745      17.84931704       6.03673928
C       6.25136738      15.98595649       5.00678780
H       6.73196571      15.30628597       4.28715684
H       8.70205871      15.03926816       6.97236564
P       3.27811704      15.59773509       3.75721009
P       5.61782927      16.48737438       2.16361736
P       3.69803939      18.87023114       3.26577127
H       5.26663237      14.45614870       0.77474293
C       2.36257948      19.51573271       4.41008195
C       6.79319175      17.36951971       4.92114062
H       6.07573696      18.18807440       4.37301400
H       6.97576707      17.86461589       5.88163454
H       7.69181137      17.47644734       4.29965516
H       2.05194774      20.52953288       4.11676686
H       1.49604020      18.84885788       4.28977651
H       3.36923439      19.11650690       0.82602852
C       1.44515299      15.86219029       3.63014875
H       1.03622881      16.18660363       4.59385877
H       0.93607800      14.93585828       3.32911666
C       3.25815161      14.10611499       4.85897162
H       4.23826676      13.61776494       4.81048556
H       2.47895471      13.39445006       4.55257914
H       3.08610162      14.40288820       5.89851994
C       4.94694355      18.41138243       7.44261018
H       5.50262820      17.57051943       7.87320651
H       4.32827434      18.86073275       8.23135081
H       5.66001130      19.16349260       7.08353387
C       2.90724870      19.45253432       5.82316409
H       2.12902873      19.53831144       6.59458154
H       3.62568465      20.26932270       5.98872952
C       4.66158065      20.44363531       3.00835491
H       5.13466711      20.73528945       3.95461032
H       4.03353855      21.26987202       2.64567842
H       5.46136700      20.25433636       2.28068869
H       1.23176734      16.64293357       2.89114161
C       3.54315709      14.72693761       2.11358745
H       3.13061400      13.70835820       2.14518006
H       2.98369801      15.28823815       1.34971403
C       5.27270157      17.24776538       0.50683734
H       4.20649668      17.17660353       0.27032841
H       5.84556715      16.72959694      -0.27382950
H       5.55775369      18.30696623       0.51092628
C       7.45012164      16.30670740       1.91474519
H       7.90002532      17.30192681       1.80663743
H       7.64882308      15.73205153       1.00070462
H       7.92542691      15.79837705       2.76104930
C       2.64046656      16.89809149       7.05688418
H       1.76816071      16.62717869       6.45245527
H       2.30573206      17.50224240       7.91094421
H       3.10693514      15.98127728       7.43331844
H       1.99933298      19.78950824       1.73677835
H       2.15495742      18.02349643       1.52476380
C       5.03398623      14.75243435       1.80800724
H       5.58131588      14.08192125       2.48721077
C       2.71138076      18.95426054       1.68530028
Si       6.26011050      15.03808764       6.59787102
H       5.12061314      15.31317420       7.53857672
H       6.15493427      13.57411770       6.26950114
C       7.84095684      15.26698901       7.62323213
H       7.94121608      16.33362068       7.88827287
H      10.04399602      14.32708390       9.04119607
C       7.89516886      14.40625863       8.88825375
H       7.03620223      14.64776055       9.53715183
H       7.77271380      13.34431183       8.61598572
C       9.18709213      14.56473161       9.69249740
H       9.30596383      15.62311118       9.97653882
H      10.16718749      13.81641140      11.49736187
C       9.22944291      13.68632110      10.94054498
H       8.40007379      13.92606108      11.62159712
H       9.14211038      12.62231906      10.67706148

65
[(dmpe)2Mn{CH(Me)(SiH2Et)}] (FEt)
Mn       4.75544003      17.15467891       4.10274779
P       3.87115333      17.84400912       6.03749219
C       6.25650024      15.97987748       5.00407926
H       6.73489831      15.29950176       4.28391645
H       8.70011214      15.02809044       7.01605591
P       3.27923136      15.59595789       3.75783160
P       5.61850455      16.48203134       2.16182084
P       3.70328613      18.86825587       3.26846832
H       5.26214116      14.45185165       0.77282829
C       2.36529273      19.50993610       4.41186932
C       6.79853857      17.36331692       4.91710767
H       6.08068111      18.18237072       4.37031517
H       6.98297330      17.85855966       5.87721137
H       7.69612658      17.46980308       4.29404822
H       2.05368130      20.52380136       4.11982985
H       1.49987222      18.84208563       4.28923427
H       3.38012874      19.12201049       0.82876204
C       1.44680768      15.86454546       3.63241499
H       1.03995567      16.19426129       4.59520702
H       0.93457326      14.93861776       3.33555329
C       3.25841120      14.10436234       4.85962315
H       4.23830201      13.61547464       4.81085326
H       2.47876767      13.39311491       4.55339509
H       3.08680330      14.40122751       5.89918408
C       4.95387139      18.40868059       7.44078187
H       5.51120500      17.56899898       7.87153482
H       4.33641526      18.85857476       8.23015689
H       5.66558831      19.16089652       7.07918913
C       2.90825907      19.44524758       5.82551708
H       2.12871756      19.52700274       6.59600911
H       3.62391453      20.26385564       5.99391875
C       4.66747202      20.44263576       3.01960993
H       5.13858127      20.73012958       3.96813228
H       4.04021017      21.27052300       2.65935173
H       5.46875265      20.25646602       2.29278680
H       1.23512427      16.64302017       2.89046048
C       3.54070179      14.72513919       2.11374276
H       3.12641807      13.70727477       2.14549193
H       2.98132430      15.28769176       1.35072929
C       5.27300438      17.24353223       0.50564293
H       4.20622461      17.17593221       0.27074756
H       5.84301488      16.72356360      -0.27592107
H       5.56157423      18.30178781       0.50945208
C       7.45013422      16.29796125       1.91041274
H       7.90173794      17.29230355       1.80136107
H       7.64634637      15.72274582       0.99618073
H       7.92580708      15.78890444       2.75605789
C       2.64866453      16.89156624       7.06048527
H       1.77597749      16.61815766       6.45772332
H       2.31409969      17.49648110       7.91406100
H       3.11729966      15.97623438       7.43772753
H       2.00914166      19.79412719       1.73861307
H       2.16300076      18.02849066       1.52191042
C       5.03120166      14.74820447       1.80645350
H       5.57817325      14.07655101       2.48480981
C       2.72024544      18.95814104       1.68616994
Si       6.26365805      15.03680962       6.59798993
H       5.11659360      15.30610675       7.53141663
H       6.17100767      13.57031747       6.27601872
C       7.83036891      15.28599477       7.64138808
H       7.93254323      16.36057627       7.86575913
H       8.75267768      14.63601725       9.52667053
C       7.83860829      14.47011582       8.93820006
H       6.98262437      14.73021892       9.57732055
H       7.77067809      13.39283265       8.73036097

75
[(dmpe)2Mn{CH(Me)(SiHEtPh)}] (FPh,Et)
Mn       4.74478434      17.14031196       4.09271190
P       3.87755235      17.81193382       6.03619460
C       6.22683742      15.93691554       4.98430201
H       6.67296384      15.25350327       4.24717441
H       8.70959738      15.08795116       6.91228384
P       3.21441843      15.63654996       3.72262378
P       5.58748627      16.45705854       2.14550597
P       3.73967964      18.89476850       3.28976378
H       5.18014269      14.44377827       0.74678170
C       2.40111123      19.53333884       4.43507720
C       6.79992677      17.30839801       4.89341550
H       6.09200159      18.14197694       4.36374451
H       7.00687845      17.79432767       5.85378095
H       7.69211289      17.39868734       4.26018030
H       2.11243003      20.56003321       4.16510838
H       1.52449131      18.88627176       4.28592286
H       3.46035476      19.21652091       0.85391841
C       1.39652023      15.98685810       3.58519632
H       0.99762542      16.32581738       4.54843341
H       0.84751108      15.08606525       3.27711645
C       3.12103755      14.13290795       4.79978889
H       4.06256060      13.57950561       4.71592758
H       2.28927227      13.48068085       4.49977171
H       2.99638159      14.41624052       5.84932225
C       4.97585484      18.34415427       7.43987299
H       5.52615137      17.49136086       7.85376513
H       4.36976976      18.78904990       8.24082788
H       5.69431118      19.09297351       7.08469450
C       2.92522457      19.42441999       5.85368901
H       2.13563345      19.48988572       6.61539069
H       3.64277353      20.23380288       6.05493485
C       4.74088567      20.45413769       3.09829322
H       5.20770731      20.70382657       4.05956561
H       4.13543229      21.30569668       2.75637737
H       5.54539672      20.27185429       2.37401784
H       1.22328069      16.77981481       2.84874474
C       3.45621033      14.77168483       2.07261275
H       3.00748853      13.76840067       2.09523906
H       2.92335038      15.35793170       1.30857133
C       5.26304402      17.24297521       0.49678996
H       4.19324502      17.21933915       0.26732415
H       5.80862121      16.70816335      -0.29223177
H       5.59240961      18.28924867       0.50848758
C       7.41332197      16.22261628       1.88833751
H       7.89192472      17.20401565       1.77734652
H       7.59051896      15.64192753       0.97369257
H       7.87885635      15.70174564       2.73251824
C       2.66101896      16.84980517       7.05706938
H       1.78818626      16.57229067       6.45631561
H       2.32626647      17.44900823       7.91459051
H       3.13757770      15.93586370       7.42821828
H       2.09444735      19.90591097       1.75947668
H       2.20204234      18.14231882       1.50169136
C       4.94961646      14.74437921       1.77935339
H       5.46554069      14.05212549       2.46171695
C       2.78248123      19.05149718       1.69711046
Si       6.27156969      14.97937987       6.56781070
H       5.13316763      15.20310318       7.52637768
H       8.87583242      14.70159356       9.41802546
H       7.52616438      13.20684232       4.47582881
C       7.85257729      15.30406028       7.57118249
H       7.91006823      16.38285233       7.79153983
C       7.95067679      14.48825315       8.86343351
H       7.10654573      14.70271722       9.53480953
H       7.93059486      13.40998297       8.65277548
C       6.19777924      13.12894288       6.18510894
C       5.42805741      12.26197887       6.97865148
C       5.36223972      10.89442212       6.70980793
C       6.06873381      10.36082246       5.63089593
C       6.84613022      11.20111449       4.83218014
C       6.91008093      12.56699617       5.11187320
H       4.85861835      12.66920893       7.81684408
H       4.75378352      10.24353915       7.33929507
H       6.01418263       9.29363668       5.41328497
H       7.40386652      10.79025977       3.98940446

77
[(dmpe)2Mn{CH(Me)(SiHEtnBu)}] (FBu,Et)
Mn       4.83013519      17.13273480       3.98775429
P       4.08850733      17.72972590       5.98572806
C       6.33984691      16.12356875       5.07924384
H       6.11674541      16.12739744       6.15759299
H       9.34278038      15.25570106       3.89115666
P       3.32474949      15.59391300       3.69557583
P       5.55632058      16.48827921       1.97689539
P       3.65916014      18.83930370       3.32128067
H       4.83038497      14.75242349       0.36282120
C       2.28651531      19.27126700       4.53080056
C       6.92907147      17.41766503       4.64333908
H       6.17316460      18.17415024       4.06345098
H       7.24687524      18.07954636       5.45993370
H       7.74803385      17.34090055       3.91952598
H       1.91782230      20.28990527       4.34051092
H       1.46264504      18.57698196       4.32110409
H       3.27304873      19.27423957       0.91813419
C       1.49462560      15.84236935       3.89059420
H       1.24742362      16.13593869       4.91785932
H       0.94783197      14.92100607       3.64668807
C       3.46658735      13.97866243       4.60126406
H       4.42678429      13.51613812       4.34496220
H       2.65100233      13.29354916       4.33141719
H       3.44995200      14.15048704       5.68254278
C       5.26893615      18.50790993       7.19531604
H       6.05890256      17.80185621       7.48028687
H       4.73292223      18.81823993       8.10193668
H       5.73482892      19.38949282       6.73805441
C       2.79740291      19.09641526       5.95162850
H       1.99631973      18.88303914       6.67260049
H       3.30196485      20.01170813       6.29174618
C       4.51148164      20.49338304       3.23190657
H       4.99322433      20.70201064       4.19585707
H       3.82066236      21.31281457       2.98698686
H       5.29860191      20.44666291       2.46819554
H       1.15888824      16.64058163       3.21784209
C       3.31064154      14.93414602       1.94051147
H       2.81576540      13.95296801       1.89845056
H       2.71464412      15.63521278       1.33656531
C       5.26788206      17.48421465       0.43429443
H       4.19863409      17.51179113       0.20295280
H       5.80208922      17.03980321      -0.41629202
H       5.61970754      18.51331719       0.57910208
C       7.33615703      16.09881758       1.62011533
H       7.93142982      17.02059375       1.64195580
H       7.42595960      15.64899632       0.62226568
H       7.74241071      15.39747548       2.35480505
C       3.33648065      16.51526446       7.16739703
H       2.44474167      16.05375956       6.72907513
H       3.05800257      17.00247654       8.11155047
H       4.06597372      15.72334270       7.37875166
H       1.90151938      19.83105389       1.90417315
H       2.10576426      18.09129057       1.55318683
C       4.74940985      14.89162887       1.45071866
H       5.30392476      14.07944669       1.94184996
C       2.63733515      19.02530107       1.77351600
Si       7.16340439      14.47959671       4.83305838
H       8.49729231      13.66600763       7.54595122
H       6.71505741      13.71259386       3.61245981
C       9.05969999      14.57034892       4.70527393
H       9.43223034      15.04371126       5.62831933
H      10.81700241      13.28127023       4.41757868
C       9.72301815      13.20440183       4.49841377
H       9.50384351      12.52213591       5.33225850
H       9.35704185      12.71964802       3.58185458
C       6.72864630      13.39881608       6.33307239
H       5.63457389      13.43231692       6.44743727
H       6.97602253      12.34682433       6.11740386
C       7.41311939      13.83704051       7.63381025
H       7.29367399      14.92601473       7.77272826
H       7.56205280      13.37495892       9.73796774
C       6.89858277      13.12929291       8.89373835
H       5.37197736      14.58482185       9.43265117
H       6.97294628      12.03904774       8.74980664
C       5.46396210      13.50139239       9.26438768
H       4.75433479      13.22634730       8.47194547
H       5.14211257      12.99324640      10.18305253

79
[(dmpe)2Mn{CH(Me)(SiHPh2)}] (FPh2)
Mn       4.76994784      17.12256666       4.07664815
P       3.98273986      17.83149283       6.04559147
C       6.23490040      15.86478208       4.92275892
H       6.62800863      15.16302578       4.17482369
C      10.11498238      15.78292536       7.81463964
P       3.18339170      15.66879565       3.74922773
P       5.53556813      16.41727666       2.10521571
P       3.80593108      18.91176530       3.29796884
H       5.02012778      14.42539312       0.71229322
C       2.53653219      19.61010677       4.48529968
C       6.85159993      17.21537648       4.82196398
H       6.15643005      18.07818194       4.32656951
H       7.11137529      17.67746127       5.78106496
H       7.72535188      17.27779390       4.16046821
H       2.27883005      20.64576026       4.21816655
H       1.62996697      18.99727572       4.37388928
H       3.45278015      19.23487343       0.87177678
C       1.37267124      16.06838384       3.66769306
H       1.01057687      16.41187711       4.64356653
H       0.79077495      15.18476904       3.37040401
C       3.08440800      14.16781678       4.83074258
H       4.01622995      13.59903708       4.73483229
H       2.23843415      13.52722256       4.54574815
H       2.97826727      14.45758984       5.88077874
C       5.14068291      18.30527796       7.41933027
H       5.68664625      17.43723964       7.80607380
H       4.57569286      18.75876231       8.24516193
H       5.86979331      19.03623611       7.04899941
C       3.10925422      19.48866598       5.88380035
H       2.35430205      19.60122500       6.67455530
H       3.87465408      20.26167154       6.04807678
C       4.86278114      20.42736408       3.06246005
H       5.37055296      20.66347194       4.00621104
H       4.28116477      21.30070975       2.73449732
H       5.63523009      20.20857811       2.31387994
H       1.20039043      16.87027504       2.94068843
C       3.34885372      14.80173797       2.09128118
H       2.86861681      13.81342311       2.12403779
H       2.81228094      15.40808709       1.34568589
C       5.19306763      17.21849927       0.46776150
H       4.11736869      17.22787493       0.26646494
H       5.70103016      16.66966222      -0.33652484
H       5.55435191      18.25422662       0.47294799
C       7.34461090      16.12013465       1.79892060
H       7.85529292      17.08427481       1.68021091
H       7.47714277      15.53826292       0.87751553
H       7.81254905      15.57808055       2.62830971
C       2.73400409      16.93545651       7.08762121
H       1.83170366      16.72096254       6.50492296
H       2.45760828      17.54675015       7.95725201
H       3.15746482      15.98911500       7.44080807
H       2.14742362      19.97833547       1.82223306
H       2.17874340      18.21113130       1.56917632
C       4.83094464      14.72788547       1.75262228
H       5.34512026      14.01571709       2.41553606
C       2.79990885      19.09821320       1.73932777
Si       6.23165810      14.92178421       6.51160712
H       5.05884800      15.10036127       7.43290715
C       9.00329366      15.48403357       7.02790638
H       6.61532770      15.43553596       9.44719468
H       9.13124321      15.35651053       5.95036660
H       8.58398610      15.97952086      10.84904989
H       4.92438588      12.55470933       7.75109498
H      10.83455410      16.19958738       9.80903042
H      11.09961853      15.87937982       7.35481626
C       7.72437991      15.34780636       7.59421309
C       7.59839584      15.53178351       8.98008966
C       8.70539114      15.83757012       9.77421016
C       9.96733769      15.96186165       9.19205316
C       6.25737386      13.07061697       6.13043664
C       7.00851331      12.54116374       5.06790859
C       7.01905946      11.17192836       4.79840776
C       6.27670687      10.29820418       5.59438696
C       5.52885557      10.80171036       6.65994546
C       5.52179459      12.17215480       6.92071681
H       7.59844348      13.20784523       4.43509752
H       7.60858138      10.78471079       3.96618592
H       6.28161778       9.22798336       5.38518067
H       4.94709626      10.12429001       7.28655793

71
[(dmpe)2Mn{CH(Me)(SiHEt2)}] (FEt2)
Mn       4.81376160      17.13730158       3.98094377
P       4.03865696      17.73309898       5.96624132
C       6.29325399      16.10740575       5.09782554
H       6.04861205      16.10312845       6.17161932
H       9.30477558      15.29679711       3.95797887
P       3.30886915      15.60568628       3.65202630
P       5.57389935      16.50291664       1.97884711
P       3.66167935      18.85030008       3.29678449
H       4.87207785      14.77835057       0.34193383
C       2.27178054      19.28746687       4.48456386
C       6.89921053      17.40110716       4.68318721
H       6.16107690      18.16801494       4.09233067
H       7.20468327      18.05554002       5.51030815
H       7.73232309      17.32382326       3.97572836
H       1.91011512      20.30754796       4.28858848
H       1.44868792      18.59623651       4.26179760
H       3.31046927      19.29264434       0.88887255
C       1.47615821      15.85884225       3.81420446
H       1.21034188      16.14542498       4.83877843
H       0.93119652      14.94113672       3.55296084
C       3.43139036      13.98644052       4.55230109
H       4.39218607      13.52049152       4.30445074
H       2.61575079      13.30635013       4.27020699
H       3.40423941      14.15356466       5.63405725
C       5.20080285      18.49771211       7.20166585
H       5.97972767      17.78500616       7.50000574
H       4.64933342      18.80960551       8.09843183
H       5.68220468      19.37709274       6.75638662
C       2.75981105      19.11027030       5.91285390
H       1.94657998      18.90508562       6.62255364
H       3.26773690      20.02153027       6.25884634
C       4.52106785      20.50121267       3.21912195
H       4.98837459      20.70916263       4.19028162
H       3.83722453      21.32283015       2.96219446
H       5.31999996      20.45056160       2.46803213
H       1.15565336      16.66324000       3.14142231
C       3.32529634      14.95437400       1.89368383
H       2.82971456      13.97419213       1.83847277
H       2.74108691      15.65895984       1.28238072
C       5.31306005      17.50813956       0.43722772
H       4.24832382      17.53630584       0.18626159
H       5.86303974      17.06861864      -0.40577993
H       5.66165766      18.53655497       0.59398345
C       7.35888649      16.11350535       1.64886158
H       7.95507207      17.03400345       1.69137615
H       7.46504132      15.67482606       0.64767397
H       7.75122585      15.40323405       2.38236890
C       3.25377364      16.51956844       7.12777582
H       2.36758819      16.06688004       6.66949647
H       2.96098098      17.00427665       8.06880318
H       3.97394162      15.72098035       7.34745828
H       1.92400952      19.84382955       1.85668620
H       2.13589175      18.10574871       1.50263802
C       4.77245014      14.91136761       1.42904821
H       5.31629586      14.09493381       1.92492919
C       2.66288820      19.03964751       1.73403165
Si       7.12224214      14.46715822       4.84252185
H       8.42439858      13.71830934       7.58660780
H       6.69498727      13.72007540       3.60217752
C       9.01967247      14.57566384       4.73978984
H       9.37850229      15.01523614       5.68479010
H      10.79360990      13.31836605       4.41789112
C       9.69980779      13.22642850       4.48428557
H       9.48035256      12.50794010       5.28686744
H       9.34821856      12.77622920       3.54473189
C       6.68917156      13.33626957       6.30770301
H       5.59342535      13.30935507       6.40792471
H       6.98918378      12.30719906       6.05480539
C       7.32724052      13.75895409       7.63632550
H       7.05574435      14.79045117       7.90504228
H       7.01367585      13.11115785       8.46754220
