Corrigendum
X-Ray structure of bridged 2,2'-bi(adamant-2-ylidene) chloronium cation and comparison of its reactivity with a singly-bonded chlorarenium cation
T. Mori, R. Rathore, S. V. Lindeman and J. K. Kochi
Chem. Commun., 1998, 927.
Please note that Table 1 was omitted from this article in error. It is reproduced below in full:
Table 1 A comparison of electrophilic (transfer) chlorination of aromatic donors with 1-Cl+ and 2-Cl+ in CH2Cl2a |
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1-Cl+ SbCl6- | 2-Cl+ SbCl6- | ||||||
Donor | Productsb | Yield (%)c | t/h | Yield (%)d | t/h | ||
1 | 98 | 1.0 | <1 | 6.0 | |||
2 | 100 | 0.2 | <1 | 3.0 | |||
3 | 98 | 0.2 | <1 | 3.0 | |||
4 | 93 | 0.2 | ~2 | 3.0 | |||
5 | 99 | 0.2 | ~3 | 3.0 | |||
a In CH2Cl2 solution of 0.015-0.02 M 1-Cl+ or 2-Cl+ SbCl6- and 3 equiv. of aromatic donor at 25 °C. b Products were characterised by GC-MS comparison of authentic samples and quantified by GC using internal standard method (isomer distribution in parentheses). c Excess aromatic donor and 1 recovered quantitatively. d Unreacted aromatic donors recovered quantitatively. A mixture of 2 (20-30%), rearranged spiroketone (50-70%) and several unidentified products were produced. |
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