# Supplementary Material (ESI) for ChemComm
# This journal is © The Royal Society of Chemistry 2000
# CCDC Number: 182/1622

data_dycul 
  
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'C41 H46 Cl5 Cu Dy N10 O12' 
_chemical_formula_weight          1274.17 
  
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cl'  'Cl'   0.1484   0.1585 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cu'  'Cu'   0.3201   1.2651 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Dy'  'Dy'  -0.1892   4.4098 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
  
_symmetry_cell_setting            Monoclinic 
_symmetry_space_group_name_H-M    P2(1)/c 
  
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x, -y-1/2, z-1/2' 
  
_cell_length_a                    19.6358(7) 
_cell_length_b                    11.8049(4) 
_cell_length_c                    21.5544(8) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  98.26 
_cell_angle_gamma                 90.00 
_cell_volume                      4944.4(3) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     5247 
_cell_measurement_theta_min       1.05 
_cell_measurement_theta_max       25.05 
  
_exptl_crystal_description        'Prism' 
_exptl_crystal_colour             'Red' 
_exptl_crystal_size_max            .28 
_exptl_crystal_size_mid            .16 
_exptl_crystal_size_min            .06 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.712 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              2552 
_exptl_absorpt_coefficient_mu     2.270 
_exptl_absorpt_correction_type    empirical 
_exptl_absorpt_process_details    'SADABS (Sheldrick, 1996)' 
_exptl_absorpt_correction_T_min    .6743 
_exptl_absorpt_correction_T_max    .9279 
  
_exptl_special_details 
; 
 ? 
; 
  
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'CCD area detector' 
_diffrn_measurement_method        'phi and omega scans' 
_diffrn_detector_area_resol_mean  ? 
_diffrn_standards_number          none 
_diffrn_standards_interval_count  none 
_diffrn_standards_interval_time   none 
_diffrn_standards_decay_%         none 
_diffrn_reflns_number             17965 
_diffrn_reflns_av_R_equivalents   0.0834 
_diffrn_reflns_av_sigmaI/netI     0.1458 
_diffrn_reflns_limit_h_min        -23 
_diffrn_reflns_limit_h_max        12 
_diffrn_reflns_limit_k_min        -10 
_diffrn_reflns_limit_k_max        14 
_diffrn_reflns_limit_l_min        -25 
_diffrn_reflns_limit_l_max        25 
_diffrn_reflns_theta_min          1.05 
_diffrn_reflns_theta_max          25.05 
_reflns_number_total              8693 
_reflns_number_gt                 4533 
_reflns_threshold_expression      >2sigma(I) 
  
_computing_data_collection        'Siemens SMART' 
_computing_cell_refinement        'Siemens SMART & SAINT' 
_computing_data_reduction         'Siemens XPREP' 
_computing_structure_solution     'Siemens SHELXTL' 
_computing_structure_refinement   'Siemens SHELXTL' 
_computing_molecular_graphics     'Bruker SHELXTL' 
_computing_publication_material   'Bruker SHELXTL' 
  
_refine_special_details 
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
  
_refine_ls_structure_factor_coef  Fsqd 
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme     calc 
_refine_ls_weighting_details 
 'calc w=1/[\s^2^(Fo^2^)+(0.0421P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          8693 
_refine_ls_number_parameters      631 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_ref           0.1570 
_refine_ls_R_factor_gt            0.0658 
_refine_ls_wR_factor_ref          0.1450 
_refine_ls_wR_factor_gt           0.1109 
_refine_ls_goodness_of_fit_ref    1.040 
_refine_ls_restrained_S_all       1.040 
_refine_ls_shift/su_max           0.001 
_refine_ls_shift/su_mean          0.000 
  
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Dy Dy 0.32994(2) 0.22499(4) 0.35887(2) 0.04051(17) Uani 1 1 d . . . 
Cu Cu 0.16265(6) 0.21934(9) 0.34355(5) 0.0384(3) Uani 1 1 d . . . 
Cl1 Cl 0.20412(17) -0.3909(2) 0.28177(16) 0.0841(11) Uani 1 1 d . . . 
Cl2 Cl 0.2065(2) 0.5030(3) 0.03919(14) 0.0962(12) Uani 1 1 d . . . 
Cl3 Cl 0.22705(19) 0.4457(3) 0.66244(13) 0.0824(10) Uani 1 1 d . . . 
O1 O 0.2436(3) 0.0917(5) 0.3371(3) 0.0479(18) Uani 1 1 d . . . 
O2 O 0.2458(3) 0.3067(5) 0.2915(3) 0.0459(17) Uani 1 1 d . . . 
O3 O 0.2378(3) 0.2511(4) 0.4146(3) 0.0371(16) Uani 1 1 d . . . 
O4 O 0.3537(4) 0.3957(6) 0.4128(3) 0.056(2) Uani 1 1 d . . . 
N1 N 0.4640(4) 0.2079(7) 0.3831(4) 0.047(2) Uani 1 1 d . . . 
N2 N 0.3731(4) 0.0660(7) 0.3008(4) 0.050(2) Uani 1 1 d . . . 
N3 N 0.3886(4) 0.3508(7) 0.2890(4) 0.049(2) Uani 1 1 d . . . 
N4 N 0.3656(4) 0.1605(6) 0.4663(4) 0.045(2) Uani 1 1 d . . . 
N5 N 0.1168(4) 0.0788(7) 0.3886(3) 0.043(2) Uani 1 1 d . . . 
N6 N 0.1121(4) 0.2019(6) 0.2568(4) 0.048(2) Uani 1 1 d . . . 
N7 N 0.1135(4) 0.3569(6) 0.3761(4) 0.046(2) Uani 1 1 d . . . 
N8 N 0.0009(4) 0.2101(8) 0.3325(4) 0.057(2) Uani 1 1 d . . . 
N9 N 0.3318(6) 0.5618(8) 0.4575(5) 0.079(3) Uani 1 1 d . . . 
C1 C 0.2363(5) -0.0165(8) 0.3276(4) 0.038(2) Uani 1 1 d . . . 
C2 C 0.2853(5) -0.0795(8) 0.3005(4) 0.040(2) Uani 1 1 d . . . 
C3 C 0.2738(5) -0.1939(8) 0.2867(4) 0.050(3) Uani 1 1 d . . . 
H3A H 0.3053 -0.2339 0.2669 0.060 Uiso 1 1 calc R . . 
C4 C 0.2173(6) -0.2482(8) 0.3017(5) 0.055(3) Uani 1 1 d . . . 
C5 C 0.1719(5) -0.1910(8) 0.3323(5) 0.051(3) Uani 1 1 d . . . 
H5A H 0.1348 -0.2298 0.3444 0.061 Uiso 1 1 calc R . . 
C6 C 0.1795(5) -0.0759(8) 0.3459(4) 0.038(2) Uani 1 1 d . . . 
C7 C 0.1293(5) -0.0261(9) 0.3815(4) 0.047(3) Uani 1 1 d . . . 
H7A H 0.1034 -0.0768 0.4014 0.056 Uiso 1 1 calc R . . 
C8 C 0.0609(5) 0.1046(8) 0.4248(5) 0.055(3) Uani 1 1 d . . . 
H8A H 0.0723 0.1717 0.4501 0.066 Uiso 1 1 calc R . . 
H8B H 0.0548 0.0420 0.4526 0.066 Uiso 1 1 calc R . . 
C9 C -0.0053(5) 0.1243(9) 0.3797(5) 0.065(3) Uani 1 1 d . . . 
H9A H -0.0192 0.0535 0.3588 0.077 Uiso 1 1 calc R . . 
H9B H -0.0413 0.1468 0.4036 0.077 Uiso 1 1 calc R . . 
C10 C 0.3491(5) -0.0329(9) 0.2873(4) 0.046(3) Uani 1 1 d . . . 
H10A H 0.3762 -0.0803 0.2666 0.055 Uiso 1 1 calc R . . 
C11 C 0.4417(5) 0.0949(8) 0.2850(5) 0.061(3) Uani 1 1 d . . . 
H11A H 0.4381 0.1601 0.2574 0.073 Uiso 1 1 calc R . . 
H11B H 0.4595 0.0319 0.2634 0.073 Uiso 1 1 calc R . . 
C12 C 0.4902(5) 0.1212(9) 0.3440(6) 0.067(3) Uani 1 1 d . . . 
H12A H 0.4988 0.0522 0.3683 0.080 Uiso 1 1 calc R . . 
H12B H 0.5337 0.1466 0.3326 0.080 Uiso 1 1 calc R . . 
C13 C 0.2376(5) 0.3458(8) 0.2349(5) 0.044(3) Uani 1 1 d . . . 
C14 C 0.2920(6) 0.4040(8) 0.2114(5) 0.049(3) Uani 1 1 d . . . 
C15 C 0.2794(6) 0.4549(8) 0.1504(4) 0.050(3) Uani 1 1 d . . . 
H15A H 0.3140 0.4962 0.1355 0.060 Uiso 1 1 calc R . . 
C16 C 0.2172(7) 0.4431(9) 0.1143(5) 0.066(4) Uani 1 1 d . . . 
C17 C 0.1655(6) 0.3813(8) 0.1348(5) 0.058(3) Uani 1 1 d . . . 
H17A H 0.1237 0.3722 0.1089 0.069 Uiso 1 1 calc R . . 
C18 C 0.1753(6) 0.3328(9) 0.1935(5) 0.053(3) Uani 1 1 d . . . 
C19 C 0.1200(6) 0.2558(9) 0.2065(5) 0.059(3) Uani 1 1 d . . . 
H19A H 0.0852 0.2443 0.1730 0.071 Uiso 1 1 calc R . . 
C20 C 0.0538(5) 0.1220(9) 0.2482(5) 0.060(3) Uani 1 1 d . . . 
H20A H 0.0658 0.0542 0.2728 0.072 Uiso 1 1 calc R . . 
H20B H 0.0439 0.1001 0.2044 0.072 Uiso 1 1 calc R . . 
C21 C -0.0107(5) 0.1770(9) 0.2687(5) 0.064(3) Uani 1 1 d . . . 
H21A H -0.0236 0.2429 0.2428 0.077 Uiso 1 1 calc R . . 
H21B H -0.0486 0.1236 0.2624 0.077 Uiso 1 1 calc R . . 
C22 C 0.3604(6) 0.4111(8) 0.2429(5) 0.056(3) Uani 1 1 d . . . 
H22A H 0.3881 0.4661 0.2283 0.068 Uiso 1 1 calc R . . 
C23 C 0.4641(5) 0.3653(8) 0.3076(5) 0.057(3) Uani 1 1 d . . . 
H23A H 0.4754 0.4450 0.3054 0.069 Uiso 1 1 calc R . . 
H23B H 0.4881 0.3251 0.2780 0.069 Uiso 1 1 calc R . . 
C24 C 0.4889(5) 0.3229(9) 0.3721(5) 0.053(3) Uani 1 1 d . . . 
H24A H 0.5388 0.3228 0.3787 0.064 Uiso 1 1 calc R . . 
H24B H 0.4736 0.3743 0.4024 0.064 Uiso 1 1 calc R . . 
C25 C 0.2342(5) 0.2935(7) 0.4700(4) 0.039(2) Uani 1 1 d . . . 
C26 C 0.2859(5) 0.2701(8) 0.5216(4) 0.038(2) Uani 1 1 d . . . 
C27 C 0.2811(6) 0.3177(8) 0.5798(4) 0.054(3) Uani 1 1 d . . . 
H27A H 0.3150 0.3018 0.6134 0.065 Uiso 1 1 calc R . . 
C28 C 0.2272(6) 0.3882(8) 0.5890(5) 0.056(3) Uani 1 1 d . . . 
C29 C 0.1779(6) 0.4122(8) 0.5393(5) 0.052(3) Uani 1 1 d . . . 
H29A H 0.1421 0.4607 0.5452 0.063 Uiso 1 1 calc R . . 
C30 C 0.1796(5) 0.3664(8) 0.4804(4) 0.041(2) Uani 1 1 d . . . 
C31 C 0.1248(5) 0.3970(8) 0.4314(5) 0.050(3) Uani 1 1 d . . . 
H31A H 0.0942 0.4521 0.4414 0.060 Uiso 1 1 calc R . . 
C32 C 0.0501(5) 0.4014(8) 0.3380(5) 0.061(3) Uani 1 1 d . . . 
H32A H 0.0559 0.4025 0.2941 0.073 Uiso 1 1 calc R . . 
H32B H 0.0416 0.4783 0.3507 0.073 Uiso 1 1 calc R . . 
C33 C -0.0101(5) 0.3276(9) 0.3469(6) 0.067(3) Uani 1 1 d . . . 
H33A H -0.0186 0.3335 0.3900 0.080 Uiso 1 1 calc R . . 
H33B H -0.0507 0.3548 0.3201 0.080 Uiso 1 1 calc R . . 
C34 C 0.3450(5) 0.1967(8) 0.5161(5) 0.052(3) Uani 1 1 d . . . 
H34A H 0.3706 0.1736 0.5536 0.063 Uiso 1 1 calc R . . 
C35 C 0.4318(5) 0.0998(8) 0.4734(5) 0.057(3) Uani 1 1 d . . . 
H35A H 0.4278 0.0314 0.4482 0.069 Uiso 1 1 calc R . . 
H35B H 0.4459 0.0789 0.5169 0.069 Uiso 1 1 calc R . . 
C36 C 0.4835(5) 0.1801(9) 0.4515(5) 0.056(3) Uani 1 1 d . . . 
H36A H 0.4854 0.2492 0.4760 0.067 Uiso 1 1 calc R . . 
H36B H 0.5288 0.1456 0.4581 0.067 Uiso 1 1 calc R . . 
C37 C 0.3862(8) 0.5483(11) 0.5079(7) 0.131(6) Uani 1 1 d . . . 
H37A H 0.4113 0.4804 0.5018 0.196 Uiso 1 1 calc R . . 
H37B H 0.3675 0.5431 0.5466 0.196 Uiso 1 1 calc R . . 
H37C H 0.4165 0.6123 0.5094 0.196 Uiso 1 1 calc R . . 
C38 C 0.2873(10) 0.6645(12) 0.4580(7) 0.180(10) Uani 1 1 d . . . 
H38A H 0.2533 0.6646 0.4213 0.270 Uiso 1 1 calc R . . 
H38B H 0.3152 0.7313 0.4583 0.270 Uiso 1 1 calc R . . 
H38C H 0.2649 0.6634 0.4947 0.270 Uiso 1 1 calc R . . 
C39 C 0.3200(7) 0.4837(11) 0.4142(5) 0.075(4) Uani 1 1 d . . . 
H39A H 0.2836 0.4953 0.3821 0.090 Uiso 1 1 calc R . . 
Cl4 Cl 0.51691(18) 0.2336(3) 0.13839(15) 0.0749(9) Uani 1 1 d . . . 
O5 O 0.5568(4) 0.1971(8) 0.1937(4) 0.107(3) Uani 1 1 d . . . 
O6 O 0.4650(7) 0.3035(10) 0.1536(5) 0.164(5) Uani 1 1 d . . . 
O7 O 0.5562(6) 0.2999(10) 0.1032(5) 0.156(5) Uani 1 1 d . . . 
O8 O 0.4882(7) 0.1473(9) 0.1010(5) 0.164(5) Uani 1 1 d . . . 
Cl5 Cl 0.03146(19) 0.7054(3) 0.45087(16) 0.0719(9) Uani 1 1 d . . . 
O9 O 0.0070(8) 0.8096(10) 0.4487(7) 0.205(7) Uani 1 1 d . . . 
O10 O 0.0477(7) 0.6779(10) 0.3949(5) 0.170(5) Uani 1 1 d . . . 
O11 O 0.0837(10) 0.6974(17) 0.4870(8) 0.302(13) Uani 1 1 d . . . 
O12 O -0.0128(9) 0.6359(14) 0.4644(11) 0.316(12) Uani 1 1 d . . . 
N N 0.6802(8) 0.2491(12) 0.8698(7) 0.130(5) Uani 1 1 d . . . 
C40 C 0.7400(9) 0.2448(12) 0.8740(7) 0.101(5) Uani 1 1 d . . . 
C41 C 0.8108(7) 0.2405(11) 0.8782(8) 0.103(5) Uani 1 1 d . . . 
  
loop_ 
 _atom_site_aniso_label 
 _atom_site_aniso_U_11 
 _atom_site_aniso_U_22 
 _atom_site_aniso_U_33 
 _atom_site_aniso_U_23 
 _atom_site_aniso_U_13 
 _atom_site_aniso_U_12 
Dy 0.0355(3) 0.0474(3) 0.0391(3) -0.0012(3) 0.0072(2) -0.0003(3) 
Cu 0.0354(7) 0.0403(7) 0.0402(7) -0.0047(6) 0.0078(5) 0.0021(6) 
Cl1 0.085(2) 0.0430(19) 0.124(3) -0.0260(18) 0.014(2) -0.0002(15) 
Cl2 0.141(3) 0.093(3) 0.050(2) 0.0251(18) -0.002(2) 0.006(2) 
Cl3 0.127(3) 0.082(2) 0.0418(18) -0.0170(15) 0.0239(18) -0.0071(19) 
O1 0.045(4) 0.037(4) 0.065(5) -0.019(3) 0.019(4) -0.011(3) 
O2 0.040(4) 0.058(5) 0.039(4) 0.007(3) 0.004(3) 0.000(3) 
O3 0.032(4) 0.048(4) 0.030(4) -0.008(3) -0.001(3) 0.004(3) 
O4 0.066(5) 0.047(5) 0.057(5) -0.009(4) 0.010(4) 0.001(4) 
N1 0.036(5) 0.044(6) 0.059(6) -0.003(5) 0.000(4) 0.001(4) 
N2 0.038(5) 0.061(6) 0.051(6) -0.013(5) 0.014(4) -0.003(4) 
N3 0.034(5) 0.057(6) 0.056(6) 0.000(5) 0.005(4) -0.012(4) 
N4 0.030(5) 0.048(5) 0.055(6) 0.010(4) 0.003(4) 0.008(4) 
N5 0.048(6) 0.038(5) 0.044(5) -0.008(4) 0.011(4) 0.004(4) 
N6 0.041(5) 0.052(6) 0.048(6) -0.004(4) -0.001(4) 0.005(4) 
N7 0.039(5) 0.050(6) 0.047(6) 0.002(4) 0.003(4) 0.003(4) 
N8 0.036(5) 0.070(7) 0.063(6) 0.003(6) 0.000(4) 0.006(5) 
N9 0.110(9) 0.071(8) 0.055(7) -0.005(6) 0.007(7) -0.007(6) 
C1 0.031(6) 0.048(7) 0.031(6) -0.010(5) -0.003(5) 0.006(5) 
C2 0.039(6) 0.037(6) 0.043(6) -0.001(5) 0.001(5) -0.007(5) 
C3 0.052(7) 0.046(7) 0.052(7) -0.012(5) 0.010(6) 0.013(5) 
C4 0.052(7) 0.045(8) 0.068(8) -0.008(5) 0.006(6) 0.003(5) 
C5 0.036(6) 0.049(8) 0.068(8) -0.008(5) 0.007(6) 0.000(5) 
C6 0.034(6) 0.030(6) 0.050(6) 0.001(5) 0.006(5) -0.001(5) 
C7 0.033(6) 0.054(7) 0.056(7) 0.006(6) 0.012(5) 0.000(5) 
C8 0.052(8) 0.063(7) 0.054(7) 0.005(6) 0.023(6) 0.004(6) 
C9 0.037(7) 0.078(9) 0.081(9) -0.013(7) 0.015(6) 0.002(6) 
C10 0.045(7) 0.053(7) 0.040(6) -0.021(5) 0.008(5) 0.004(5) 
C11 0.053(8) 0.062(8) 0.073(8) -0.020(6) 0.030(7) -0.005(6) 
C12 0.042(7) 0.060(8) 0.103(10) -0.001(7) 0.028(7) -0.007(6) 
C13 0.062(8) 0.032(6) 0.036(6) -0.009(5) 0.005(6) 0.005(5) 
C14 0.056(8) 0.043(7) 0.046(7) -0.007(5) 0.001(6) 0.000(5) 
C15 0.084(9) 0.043(7) 0.029(6) 0.004(5) 0.028(6) -0.002(6) 
C16 0.100(11) 0.049(8) 0.041(7) 0.000(6) -0.012(7) 0.016(7) 
C17 0.062(8) 0.048(7) 0.058(8) 0.000(6) -0.007(6) -0.002(6) 
C18 0.068(8) 0.048(7) 0.040(7) -0.009(6) -0.003(6) 0.013(6) 
C19 0.061(8) 0.059(8) 0.051(7) -0.010(6) -0.016(6) -0.005(6) 
C20 0.049(7) 0.080(8) 0.049(7) -0.016(6) 0.000(6) -0.026(6) 
C21 0.030(7) 0.095(9) 0.063(8) -0.012(7) -0.006(6) -0.010(6) 
C22 0.076(9) 0.036(7) 0.061(8) -0.004(6) 0.022(7) -0.005(6) 
C23 0.058(8) 0.059(8) 0.054(8) -0.006(6) 0.008(6) -0.017(6) 
C24 0.037(6) 0.069(8) 0.055(7) -0.013(6) 0.012(6) -0.008(6) 
C25 0.048(6) 0.030(6) 0.038(6) -0.003(5) 0.007(5) -0.009(5) 
C26 0.037(6) 0.048(6) 0.029(5) 0.009(5) 0.003(4) -0.005(5) 
C27 0.069(8) 0.061(8) 0.029(6) 0.003(5) -0.005(6) -0.012(6) 
C28 0.082(9) 0.045(7) 0.042(7) -0.009(5) 0.017(7) 0.003(6) 
C29 0.067(8) 0.046(7) 0.048(7) -0.006(5) 0.022(6) 0.001(6) 
C30 0.039(6) 0.047(7) 0.039(6) -0.004(5) 0.010(5) 0.003(5) 
C31 0.045(7) 0.041(7) 0.066(8) -0.003(6) 0.016(6) 0.003(5) 
C32 0.049(7) 0.062(8) 0.068(8) 0.001(6) -0.004(6) 0.015(6) 
C33 0.042(7) 0.062(8) 0.096(10) -0.008(7) 0.010(7) 0.006(6) 
C34 0.049(7) 0.063(8) 0.042(7) 0.009(6) -0.003(6) -0.005(6) 
C35 0.053(8) 0.058(7) 0.063(8) 0.018(6) 0.014(6) 0.003(6) 
C36 0.036(7) 0.076(8) 0.054(7) 0.004(6) 0.001(5) 0.006(5) 
C37 0.150(16) 0.132(14) 0.099(13) -0.043(10) -0.019(12) -0.029(11) 
C38 0.30(3) 0.105(13) 0.126(15) -0.035(11) -0.016(15) 0.124(15) 
C39 0.104(11) 0.065(9) 0.052(8) -0.013(7) -0.005(7) -0.003(8) 
Cl4 0.071(2) 0.101(3) 0.0520(19) -0.003(2) 0.0040(17) -0.006(2) 
O5 0.072(6) 0.153(9) 0.089(7) 0.031(6) -0.009(5) -0.018(5) 
O6 0.179(13) 0.218(13) 0.091(8) -0.031(8) 0.006(8) 0.073(10) 
O7 0.142(11) 0.222(13) 0.105(9) 0.050(8) 0.021(8) -0.059(9) 
O8 0.215(14) 0.110(8) 0.148(11) -0.037(7) -0.039(9) -0.041(8) 
Cl5 0.081(2) 0.075(3) 0.064(2) -0.0014(18) 0.0231(19) 0.0025(19) 
O9 0.230(16) 0.100(10) 0.310(19) 0.008(10) 0.125(14) 0.048(10) 
O10 0.240(15) 0.176(11) 0.114(9) -0.056(8) 0.091(10) -0.045(10) 
O11 0.25(2) 0.42(3) 0.179(16) -0.068(16) -0.137(16) 0.137(19) 
O12 0.23(2) 0.245(18) 0.52(3) 0.101(19) 0.20(2) -0.093(15) 
N 0.097(11) 0.161(13) 0.133(12) 0.029(9) 0.020(10) -0.011(10) 
C40 0.115(15) 0.105(13) 0.079(10) 0.007(8) -0.002(11) -0.016(12) 
C41 0.044(8) 0.112(12) 0.147(14) -0.012(9) -0.008(9) 0.003(7) 
  
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
  
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Dy O2 2.254(6) . ? 
Dy O1 2.311(6) . ? 
Dy O3 2.331(6) . ? 
Dy O4 2.340(7) . ? 
Dy N4 2.443(8) . ? 
Dy N2 2.473(8) . ? 
Dy N3 2.509(8) . ? 
Dy N1 2.617(7) . ? 
Dy Cu 3.2545(12) . ? 
Cu N6 1.997(8) . ? 
Cu O3 2.003(5) . ? 
Cu N7 2.063(8) . ? 
Cu N5 2.182(8) . ? 
Cu O1 2.208(6) . ? 
Cu O2 2.349(6) . ? 
Cl1 C4 1.748(10) . ? 
Cl2 C16 1.750(11) . ? 
Cl3 C28 1.722(10) . ? 
O1 C1 1.299(9) . ? 
O2 C13 1.293(10) . ? 
O3 C25 1.307(10) . ? 
O4 C39 1.234(12) . ? 
N1 C12 1.465(12) . ? 
N1 C24 1.473(11) . ? 
N1 C36 1.506(11) . ? 
N2 C10 1.276(10) . ? 
N2 C11 1.476(12) . ? 
N3 C22 1.282(11) . ? 
N3 C23 1.489(11) . ? 
N4 C34 1.274(11) . ? 
N4 C35 1.473(11) . ? 
N5 C7 1.276(10) . ? 
N5 C8 1.466(11) . ? 
N6 C19 1.285(12) . ? 
N6 C20 1.476(11) . ? 
N7 C31 1.272(11) . ? 
N7 C32 1.486(11) . ? 
N8 C21 1.415(12) . ? 
N8 C33 1.443(12) . ? 
N8 C9 1.452(12) . ? 
N9 C39 1.309(13) . ? 
N9 C37 1.419(14) . ? 
N9 C38 1.495(14) . ? 
C1 C2 1.408(12) . ? 
C1 C6 1.421(12) . ? 
C2 C3 1.395(11) . ? 
C2 C10 1.433(13) . ? 
C3 C4 1.360(13) . ? 
C4 C5 1.362(13) . ? 
C5 C6 1.393(11) . ? 
C6 C7 1.456(12) . ? 
C8 C9 1.526(13) . ? 
C11 C12 1.506(13) . ? 
C13 C18 1.414(13) . ? 
C13 C14 1.423(14) . ? 
C14 C22 1.418(14) . ? 
C14 C15 1.435(12) . ? 
C15 C16 1.357(14) . ? 
C16 C17 1.373(15) . ? 
C17 C18 1.378(13) . ? 
C18 C19 1.474(15) . ? 
C20 C21 1.543(13) . ? 
C23 C24 1.491(12) . ? 
C25 C30 1.417(12) . ? 
C25 C26 1.421(12) . ? 
C26 C27 1.389(12) . ? 
C26 C34 1.467(13) . ? 
C27 C28 1.382(13) . ? 
C28 C29 1.367(13) . ? 
C29 C30 1.385(12) . ? 
C30 C31 1.442(13) . ? 
C32 C33 1.502(13) . ? 
C35 C36 1.513(12) . ? 
Cl4 O8 1.369(9) . ? 
Cl4 O6 1.387(11) . ? 
Cl4 O7 1.396(10) . ? 
Cl4 O5 1.397(8) . ? 
Cl5 O11 1.200(13) . ? 
Cl5 O12 1.260(12) . ? 
Cl5 O9 1.318(11) . ? 
Cl5 O10 1.332(10) . ? 
N C40 1.164(18) . ? 
C40 C41 1.38(2) . ? 
  
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
O2 Dy O1 73.3(2) . . ? 
O2 Dy O3 74.0(2) . . ? 
O1 Dy O3 66.0(2) . . ? 
O2 Dy O4 91.5(2) . . ? 
O1 Dy O4 140.8(2) . . ? 
O3 Dy O4 75.2(2) . . ? 
O2 Dy N4 145.9(3) . . ? 
O1 Dy N4 94.7(2) . . ? 
O3 Dy N4 72.0(2) . . ? 
O4 Dy N4 77.8(2) . . ? 
O2 Dy N2 105.7(2) . . ? 
O1 Dy N2 71.1(2) . . ? 
O3 Dy N2 135.1(2) . . ? 
O4 Dy N2 147.9(3) . . ? 
N4 Dy N2 99.9(3) . . ? 
O2 Dy N3 73.6(2) . . ? 
O1 Dy N3 131.9(2) . . ? 
O3 Dy N3 133.5(2) . . ? 
O4 Dy N3 73.3(2) . . ? 
N4 Dy N3 131.3(3) . . ? 
N2 Dy N3 85.7(3) . . ? 
O2 Dy N1 141.7(2) . . ? 
O1 Dy N1 132.5(2) . . ? 
O3 Dy N1 137.8(2) . . ? 
O4 Dy N1 81.0(2) . . ? 
N4 Dy N1 69.1(3) . . ? 
N2 Dy N1 68.6(3) . . ? 
N3 Dy N1 68.3(3) . . ? 
O2 Dy Cu 46.19(16) . . ? 
O1 Dy Cu 42.70(16) . . ? 
O3 Dy Cu 37.65(13) . . ? 
O4 Dy Cu 101.22(18) . . ? 
N4 Dy Cu 103.74(19) . . ? 
N2 Dy Cu 110.32(19) . . ? 
N3 Dy Cu 119.65(19) . . ? 
N1 Dy Cu 172.05(18) . . ? 
N6 Cu O3 161.2(3) . . ? 
N6 Cu N7 101.9(3) . . ? 
O3 Cu N7 85.5(3) . . ? 
N6 Cu N5 99.1(3) . . ? 
O3 Cu N5 96.2(3) . . ? 
N7 Cu N5 101.7(3) . . ? 
N6 Cu O1 97.8(3) . . ? 
O3 Cu O1 73.6(2) . . ? 
N7 Cu O1 159.1(3) . . ? 
N5 Cu O1 81.7(3) . . ? 
N6 Cu O2 83.3(3) . . ? 
O3 Cu O2 78.3(2) . . ? 
N7 Cu O2 102.0(3) . . ? 
N5 Cu O2 155.0(3) . . ? 
O1 Cu O2 73.3(2) . . ? 
N6 Cu Dy 117.1(2) . . ? 
O3 Cu Dy 45.30(17) . . ? 
N7 Cu Dy 117.7(2) . . ? 
N5 Cu Dy 116.5(2) . . ? 
O1 Cu Dy 45.20(15) . . ? 
O2 Cu Dy 43.83(15) . . ? 
C1 O1 Cu 128.1(5) . . ? 
C1 O1 Dy 139.7(5) . . ? 
Cu O1 Dy 92.1(2) . . ? 
C13 O2 Dy 137.9(6) . . ? 
C13 O2 Cu 127.4(6) . . ? 
Dy O2 Cu 90.0(2) . . ? 
C25 O3 Cu 129.8(6) . . ? 
C25 O3 Dy 132.0(5) . . ? 
Cu O3 Dy 97.1(2) . . ? 
C39 O4 Dy 131.9(8) . . ? 
C12 N1 C24 113.6(8) . . ? 
C12 N1 C36 110.5(8) . . ? 
C24 N1 C36 108.4(7) . . ? 
C12 N1 Dy 111.4(6) . . ? 
C24 N1 Dy 104.1(5) . . ? 
C36 N1 Dy 108.6(6) . . ? 
C10 N2 C11 118.6(8) . . ? 
C10 N2 Dy 131.8(7) . . ? 
C11 N2 Dy 109.4(6) . . ? 
C22 N3 C23 116.6(9) . . ? 
C22 N3 Dy 127.6(7) . . ? 
C23 N3 Dy 115.5(6) . . ? 
C34 N4 C35 117.3(9) . . ? 
C34 N4 Dy 127.7(7) . . ? 
C35 N4 Dy 112.2(6) . . ? 
C7 N5 C8 116.0(8) . . ? 
C7 N5 Cu 125.8(7) . . ? 
C8 N5 Cu 117.9(6) . . ? 
C19 N6 C20 113.3(8) . . ? 
C19 N6 Cu 129.5(7) . . ? 
C20 N6 Cu 117.1(7) . . ? 
C31 N7 C32 113.9(9) . . ? 
C31 N7 Cu 125.8(7) . . ? 
C32 N7 Cu 119.0(6) . . ? 
C21 N8 C33 117.7(9) . . ? 
C21 N8 C9 118.0(9) . . ? 
C33 N8 C9 119.3(9) . . ? 
C39 N9 C37 120.2(11) . . ? 
C39 N9 C38 122.2(12) . . ? 
C37 N9 C38 117.5(11) . . ? 
O1 C1 C2 121.2(9) . . ? 
O1 C1 C6 121.0(8) . . ? 
C2 C1 C6 117.8(9) . . ? 
C3 C2 C1 119.9(9) . . ? 
C3 C2 C10 116.8(9) . . ? 
C1 C2 C10 123.3(9) . . ? 
C4 C3 C2 121.3(9) . . ? 
C3 C4 C5 119.6(9) . . ? 
C3 C4 Cl1 119.5(8) . . ? 
C5 C4 Cl1 120.9(9) . . ? 
C4 C5 C6 121.9(10) . . ? 
C5 C6 C1 119.2(9) . . ? 
C5 C6 C7 116.4(9) . . ? 
C1 C6 C7 124.3(9) . . ? 
N5 C7 C6 127.8(9) . . ? 
N5 C8 C9 109.1(8) . . ? 
N8 C9 C8 113.8(9) . . ? 
N2 C10 C2 127.6(9) . . ? 
N2 C11 C12 109.9(9) . . ? 
N1 C12 C11 113.4(9) . . ? 
O2 C13 C18 122.4(10) . . ? 
O2 C13 C14 120.7(9) . . ? 
C18 C13 C14 117.0(10) . . ? 
C22 C14 C13 124.5(10) . . ? 
C22 C14 C15 116.1(10) . . ? 
C13 C14 C15 119.3(10) . . ? 
C16 C15 C14 120.3(10) . . ? 
C15 C16 C17 121.0(10) . . ? 
C15 C16 Cl2 117.9(10) . . ? 
C17 C16 Cl2 121.0(10) . . ? 
C16 C17 C18 120.4(11) . . ? 
C17 C18 C13 121.8(11) . . ? 
C17 C18 C19 114.9(10) . . ? 
C13 C18 C19 122.8(10) . . ? 
N6 C19 C18 130.2(10) . . ? 
N6 C20 C21 110.4(8) . . ? 
N8 C21 C20 111.8(8) . . ? 
N3 C22 C14 127.7(10) . . ? 
N3 C23 C24 113.1(9) . . ? 
N1 C24 C23 112.8(8) . . ? 
O3 C25 C30 121.2(8) . . ? 
O3 C25 C26 121.0(8) . . ? 
C30 C25 C26 117.8(8) . . ? 
C27 C26 C25 119.6(9) . . ? 
C27 C26 C34 118.0(9) . . ? 
C25 C26 C34 122.3(8) . . ? 
C28 C27 C26 121.7(9) . . ? 
C29 C28 C27 118.9(9) . . ? 
C29 C28 Cl3 122.9(9) . . ? 
C27 C28 Cl3 118.2(9) . . ? 
C28 C29 C30 122.0(10) . . ? 
C29 C30 C25 120.0(9) . . ? 
C29 C30 C31 117.3(9) . . ? 
C25 C30 C31 122.6(9) . . ? 
N7 C31 C30 127.1(9) . . ? 
N7 C32 C33 109.7(8) . . ? 
N8 C33 C32 112.7(9) . . ? 
N4 C34 C26 128.2(9) . . ? 
N4 C35 C36 106.5(8) . . ? 
N1 C36 C35 110.8(8) . . ? 
O4 C39 N9 124.8(12) . . ? 
O8 Cl4 O6 109.1(8) . . ? 
O8 Cl4 O7 108.1(8) . . ? 
O6 Cl4 O7 106.2(8) . . ? 
O8 Cl4 O5 113.9(7) . . ? 
O6 Cl4 O5 108.8(6) . . ? 
O7 Cl4 O5 110.5(6) . . ? 
O11 Cl5 O12 110.7(14) . . ? 
O11 Cl5 O9 111.7(11) . . ? 
O12 Cl5 O9 110.9(11) . . ? 
O11 Cl5 O10 106.0(12) . . ? 
O12 Cl5 O10 108.3(12) . . ? 
O9 Cl5 O10 109.2(9) . . ? 
N C40 C41 179(2) . . ? 
  
_diffrn_measured_fraction_theta_max    0.993 
_diffrn_reflns_theta_full              25.05 
_diffrn_measured_fraction_theta_full   0.993 
_refine_diff_density_max    1.490 
_refine_diff_density_min   -0.766 
_refine_diff_density_rms    0.126 
  
_publ_section_references 
; 
 Sheldrick G.M.(1996), SADABS, Absorption Correction Program, University of 
 Goeltingen, German 
 Siemens(1994), SAINT Software Reference Manual, Siemens Energy & 
 Automation Inc., Madison, Wisconsin, USA 
 Siemens(1996), SMART Software Reference Manual, Siemens Energy & 
 Automation Inc., Madison, Wisconsin, USA 
 Siemens(1994), SHELXTL^TM^ Version 5 Reference Manual, Siemens Energy & 
 Automation Inc., Madison, Wisconsin, USA 
;