# Supplementary Material (ESI) for ChemComm
# This journal is © The Royal Society of Chemistry 2000
# CCDC Number: 182/1840

data_fidi1

_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             ?
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'C33 H48 N2 O5 P2 Si4 W1'
_chemical_formula_weight          910.90

loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P'  'P'   0.1023   0.0942
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'W'  'W'  -0.8490   6.8722
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si'  'Si'   0.0817   0.0704
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting            monoclinic
_symmetry_space_group_name_H-M    P2/n

loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x+1/2, y, -z+1/2'
 '-x, -y, -z'
 'x-1/2, -y, z-1/2'

_cell_length_a                    18.440(3)
_cell_length_b                    9.831(3)
_cell_length_c                    25.145(4)
_cell_angle_alpha                 90.00
_cell_angle_beta                  111.491(10)
_cell_angle_gamma                 90.00
_cell_volume                      4241.3(16)
_cell_formula_units_Z             4
_cell_measurement_temperature     173(2)
_cell_measurement_reflns_used     47
_cell_measurement_theta_min       2.5
_cell_measurement_theta_max       12.5

_exptl_crystal_description        'cut prism'
_exptl_crystal_colour             'pale yellow'
_exptl_crystal_size_max           0.80
_exptl_crystal_size_mid           0.20
_exptl_crystal_size_min           0.15
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.426
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              1840
_exptl_absorpt_coefficient_mu     2.949
_exptl_absorpt_correction_type    Psi-scans
_exptl_absorpt_correction_T_min   0.2557
_exptl_absorpt_correction_T_max   0.3231
_exptl_absorpt_process_details    ?

_exptl_special_details
;
 ?
;

_diffrn_ambient_temperature       173(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   'Siemens P4'
_diffrn_measurement_method        \w-scans
_diffrn_detector_area_resol_mean  ?
_diffrn_standards_number          3
_diffrn_standards_interval_count  247
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         2
_diffrn_reflns_number             12772
_diffrn_reflns_av_R_equivalents   0.1151
_diffrn_reflns_av_sigmaI/netI     0.2268
_diffrn_reflns_limit_h_min        -20
_diffrn_reflns_limit_h_max        21
_diffrn_reflns_limit_k_min        -11
_diffrn_reflns_limit_k_max        11
_diffrn_reflns_limit_l_min        -29
_diffrn_reflns_limit_l_max        10
_diffrn_reflns_theta_min          3.03
_diffrn_reflns_theta_max          24.99
_reflns_number_total              7430
_reflns_number_gt                 3410
_reflns_threshold_expression      >2sigma(I)

_computing_data_collection        'Siemens XSCANS'
_computing_cell_refinement        'Siemens XSCANS'
_computing_data_reduction         'Siemens XSCANS'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics     'Siemens XP'
_computing_publication_material   'SHELXS-97 (Sheldrick, 1990)'

_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F^2^, conventional R-factors R are based
 on F, with F set to zero for negative F^2^. The threshold expression of
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F^2^ are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.

 The methyl groups at Si3 and Si4 are slightly disorderd.

;

_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[\s^2^(Fo^2^)+(0.0001P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      Patterson
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     'all riding'
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          7430
_refine_ls_number_parameters      424
_refine_ls_number_restraints      171
_refine_ls_R_factor_all           0.1494
_refine_ls_R_factor_gt            0.0537
_refine_ls_wR_factor_ref          0.0731
_refine_ls_wR_factor_gt           0.0581
_refine_ls_goodness_of_fit_ref    0.763
_refine_ls_restrained_S_all       0.756
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000

loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
W W 0.78540(3) 0.53286(4) 0.886220(19) 0.03567(11) Uani 1 1 d . . .
Si1 Si 0.65161(17) 1.0055(3) 0.82221(11) 0.0494(9) Uani 1 1 d . . .
Si2 Si 0.54020(17) 0.7419(3) 0.80187(12) 0.0459(8) Uani 1 1 d . . .
Si3 Si 0.74635(19) 0.9421(3) 1.11754(13) 0.0599(10) Uani 1 1 d . . .
Si4 Si 0.85143(19) 0.6644(3) 1.15812(14) 0.0608(10) Uani 1 1 d . . .
P1 P 0.70776(15) 0.7372(2) 0.89480(10) 0.0318(7) Uani 1 1 d U . .
P2 P 0.77772(15) 0.7249(2) 1.02903(11) 0.0346(7) Uani 1 1 d . . .
N1 N 0.6462(4) 0.7216(7) 0.9314(3) 0.036(2) Uani 1 1 d U . .
N2 N 0.7710(4) 0.8604(6) 0.9312(3) 0.0298(19) Uani 1 1 d U . .
O1 O 0.6619(4) 0.4248(7) 0.7695(3) 0.068(2) Uani 1 1 d U . .
O2 O 0.8923(4) 0.2932(7) 0.8747(3) 0.068(2) Uani 1 1 d U . .
O3 O 0.8383(4) 0.7342(8) 0.8083(3) 0.071(2) Uani 1 1 d U . .
O4 O 0.9353(4) 0.6031(7) 0.9953(3) 0.049(2) Uani 1 1 d U . .
O5 O 0.7111(4) 0.3760(6) 0.9644(3) 0.064(2) Uani 1 1 d U . .
C1 C 0.7047(6) 0.4669(12) 0.8137(4) 0.051(3) Uani 1 1 d U . .
C2 C 0.8520(6) 0.3808(9) 0.8788(4) 0.045(3) Uani 1 1 d U . .
C3 C 0.8226(6) 0.6596(11) 0.8378(4) 0.052(3) Uani 1 1 d U . .
C4 C 0.8797(6) 0.5823(10) 0.9573(4) 0.040(3) Uani 1 1 d U . .
C5 C 0.7376(6) 0.4304(10) 0.9354(4) 0.051(3) Uani 1 1 d U . .
C6 C 0.6451(5) 0.8107(8) 0.8285(3) 0.032(2) Uani 1 1 d . . .
H6 H 0.6664 0.7750 0.8000 0.039 Uiso 1 1 calc R . .
C7 C 0.7510(5) 1.0531(9) 0.8264(4) 0.066(3) Uani 1 1 d . . .
H7A H 0.7892 1.0254 0.8635 0.079 Uiso 1 1 calc R . .
H7B H 0.7537 1.1518 0.8221 0.079 Uiso 1 1 calc R . .
H7C H 0.7626 1.0073 0.7958 0.079 Uiso 1 1 calc R . .
C8 C 0.5845(6) 1.0612(9) 0.7503(4) 0.072(4) Uani 1 1 d . . .
H8A H 0.5308 1.0383 0.7455 0.087 Uiso 1 1 calc R . .
H8B H 0.5984 1.0148 0.7208 0.087 Uiso 1 1 calc R . .
H8C H 0.5891 1.1598 0.7466 0.087 Uiso 1 1 calc R . .
C9 C 0.6256(6) 1.0946(8) 0.8800(4) 0.073(4) Uani 1 1 d . . .
H9A H 0.5732 1.0670 0.8771 0.087 Uiso 1 1 calc R . .
H9B H 0.6269 1.1933 0.8750 0.087 Uiso 1 1 calc R . .
H9C H 0.6633 1.0692 0.9177 0.087 Uiso 1 1 calc R . .
C10 C 0.5032(6) 0.7369(10) 0.7216(4) 0.064(3) Uani 1 1 d . . .
H10A H 0.5376 0.6795 0.7092 0.077 Uiso 1 1 calc R . .
H10B H 0.5024 0.8292 0.7067 0.077 Uiso 1 1 calc R . .
H10C H 0.4504 0.6991 0.7069 0.077 Uiso 1 1 calc R . .
C11 C 0.4748(5) 0.8511(9) 0.8262(4) 0.065(3) Uani 1 1 d . . .
H11A H 0.4941 0.8524 0.8680 0.078 Uiso 1 1 calc R . .
H11B H 0.4218 0.8141 0.8113 0.078 Uiso 1 1 calc R . .
H11C H 0.4744 0.9440 0.8119 0.078 Uiso 1 1 calc R . .
C12 C 0.5320(5) 0.5629(9) 0.8247(4) 0.060(3) Uani 1 1 d . . .
H12A H 0.5659 0.5035 0.8127 0.072 Uiso 1 1 calc R . .
H12B H 0.4779 0.5321 0.8069 0.072 Uiso 1 1 calc R . .
H12C H 0.5480 0.5595 0.8664 0.072 Uiso 1 1 calc R . .
C13 C 0.6734(6) 0.7196(8) 0.9861(4) 0.033(2) Uani 1 1 d U . .
C14 C 0.6146(6) 0.6929(10) 1.0140(4) 0.041(3) Uani 1 1 d U . .
C15 C 0.6213(6) 0.5831(9) 1.0494(4) 0.057(3) Uani 1 1 d U . .
H15 H 0.6647 0.5241 1.0570 0.069 Uiso 1 1 calc R . .
C16 C 0.5674(7) 0.5548(11) 1.0743(4) 0.071(4) Uani 1 1 d U . .
H16 H 0.5736 0.4794 1.0992 0.085 Uiso 1 1 calc R . .
C17 C 0.5041(7) 0.6414(12) 1.0614(5) 0.081(4) Uani 1 1 d U . .
H17 H 0.4660 0.6239 1.0777 0.097 Uiso 1 1 calc R . .
C18 C 0.4944(6) 0.7500(11) 1.0263(5) 0.066(3) Uani 1 1 d U . .
H18 H 0.4499 0.8068 1.0181 0.079 Uiso 1 1 calc R . .
C19 C 0.5508(6) 0.7784(10) 1.0021(4) 0.049(3) Uani 1 1 d U . .
H19 H 0.5450 0.8551 0.9779 0.059 Uiso 1 1 calc R . .
C20 C 0.8016(5) 0.8607(8) 0.9853(4) 0.029(2) Uani 1 1 d U . .
C21 C 0.8652(5) 0.9573(11) 1.0151(3) 0.0280(19) Uani 1 1 d U . .
C22 C 0.9376(6) 0.9191(9) 1.0533(4) 0.041(3) Uani 1 1 d U . .
H22 H 0.9469 0.8254 1.0625 0.049 Uiso 1 1 calc R . .
C23 C 0.9958(6) 1.0083(11) 1.0781(4) 0.053(3) Uani 1 1 d U . .
H23 H 1.0450 0.9780 1.1038 0.064 Uiso 1 1 calc R . .
C24 C 0.9819(7) 1.1460(12) 1.0650(4) 0.064(4) Uani 1 1 d U . .
H24 H 1.0211 1.2115 1.0831 0.076 Uiso 1 1 calc R . .
C25 C 0.9105(7) 1.1866(11) 1.0255(4) 0.063(3) Uani 1 1 d U . .
H25 H 0.9019 1.2798 1.0152 0.075 Uiso 1 1 calc R . .
C26 C 0.8532(6) 1.0954(10) 1.0015(4) 0.045(3) Uani 1 1 d U . .
H26 H 0.8043 1.1252 0.9750 0.054 Uiso 1 1 calc R . .
C27 C 0.7972(6) 0.7928(9) 1.1017(4) 0.062(3) Uani 1 1 d . . .
H27 H 0.8448 0.8448 1.1039 0.074 Uiso 1 1 calc R . .
C28 C 0.8199(8) 1.0607(12) 1.1651(5) 0.163(7) Uani 1 1 d . . .
H28A H 0.7934 1.1383 1.1745 0.196 Uiso 1 1 calc R . .
H28B H 0.8539 1.0932 1.1457 0.196 Uiso 1 1 calc R . .
H28C H 0.8512 1.0134 1.2004 0.196 Uiso 1 1 calc R . .
C29 C 0.6780(7) 0.8877(11) 1.1524(4) 0.120(6) Uani 1 1 d . . .
H29A H 0.6394 0.8248 1.1272 0.144 Uiso 1 1 calc R . .
H29B H 0.6514 0.9676 1.1598 0.144 Uiso 1 1 calc R . .
H29C H 0.7072 0.8421 1.1886 0.144 Uiso 1 1 calc R . .
C30 C 0.6918(5) 1.0430(10) 1.0524(3) 0.070(3) Uani 1 1 d . . .
H30A H 0.6523 0.9853 1.0250 0.084 Uiso 1 1 calc R . .
H30B H 0.7281 1.0763 1.0351 0.084 Uiso 1 1 calc R . .
H30C H 0.6664 1.1204 1.0630 0.084 Uiso 1 1 calc R . .
C31 C 0.7961(6) 0.5152(14) 1.1606(6) 0.181(8) Uani 1 1 d . . .
H31A H 0.7795 0.4686 1.1236 0.217 Uiso 1 1 calc R . .
H31B H 0.7502 0.5420 1.1689 0.217 Uiso 1 1 calc R . .
H31C H 0.8286 0.4539 1.1906 0.217 Uiso 1 1 calc R . .
C32 C 0.8786(9) 0.7422(15) 1.2314(5) 0.165(8) Uani 1 1 d . . .
H32A H 0.9098 0.8243 1.2337 0.198 Uiso 1 1 calc R . .
H32B H 0.9091 0.6766 1.2603 0.198 Uiso 1 1 calc R . .
H32C H 0.8311 0.7660 1.2382 0.198 Uiso 1 1 calc R . .
C33 C 0.9444(6) 0.6212(10) 1.1505(5) 0.103(5) Uani 1 1 d . . .
H33A H 0.9729 0.7049 1.1498 0.123 Uiso 1 1 calc R . .
H33B H 0.9340 0.5710 1.1148 0.123 Uiso 1 1 calc R . .
H33C H 0.9758 0.5648 1.1829 0.123 Uiso 1 1 calc R . .

loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
W 0.0383(2) 0.03194(19) 0.0408(2) -0.0016(3) 0.0193(2) 0.0002(3)
Si1 0.054(2) 0.042(3) 0.0362(17) 0.0040(14) -0.0024(16) -0.0062(17)
Si2 0.034(2) 0.060(2) 0.0421(19) -0.0011(16) 0.0123(17) -0.0037(18)
Si3 0.069(3) 0.068(2) 0.0391(18) -0.0082(19) 0.016(2) 0.011(2)
Si4 0.050(2) 0.087(3) 0.050(2) 0.035(2) 0.024(2) 0.019(2)
P1 0.0368(18) 0.0312(16) 0.0302(15) 0.0010(12) 0.0155(14) -0.0006(14)
P2 0.0390(18) 0.0354(16) 0.0346(15) 0.0068(13) 0.0196(15) 0.0021(15)
N1 0.043(6) 0.029(5) 0.039(4) -0.001(4) 0.020(5) -0.004(4)
N2 0.036(5) 0.019(4) 0.035(4) 0.002(4) 0.013(4) -0.002(4)
O1 0.068(6) 0.071(6) 0.057(5) -0.015(4) 0.015(5) -0.007(5)
O2 0.062(6) 0.043(5) 0.095(6) -0.012(5) 0.025(5) 0.006(4)
O3 0.059(6) 0.105(6) 0.059(5) 0.031(5) 0.033(5) -0.003(5)
O4 0.037(5) 0.054(5) 0.059(5) -0.001(4) 0.020(4) 0.009(4)
O5 0.075(6) 0.044(5) 0.088(6) 0.007(4) 0.047(5) -0.007(4)
C1 0.065(8) 0.042(6) 0.050(6) 0.013(7) 0.025(6) 0.003(7)
C2 0.056(9) 0.032(7) 0.045(7) -0.002(6) 0.015(7) -0.015(6)
C3 0.037(7) 0.076(9) 0.044(7) -0.004(6) 0.015(6) -0.001(7)
C4 0.034(7) 0.042(7) 0.056(7) 0.011(6) 0.030(5) -0.002(6)
C5 0.040(7) 0.050(8) 0.068(8) -0.002(6) 0.025(6) 0.011(6)
C6 0.045(7) 0.028(6) 0.030(6) -0.005(4) 0.021(5) -0.004(5)
C7 0.088(9) 0.050(7) 0.049(6) 0.017(6) 0.013(7) -0.029(7)
C8 0.085(9) 0.049(8) 0.071(8) 0.018(7) 0.016(7) -0.009(7)
C9 0.093(10) 0.035(7) 0.076(9) -0.018(6) 0.015(8) -0.001(7)
C10 0.051(8) 0.073(8) 0.051(7) -0.012(6) -0.001(6) -0.033(7)
C11 0.044(8) 0.099(9) 0.048(7) -0.005(7) 0.012(7) -0.002(7)
C12 0.056(8) 0.070(8) 0.064(7) -0.012(6) 0.036(7) -0.029(7)
C13 0.054(7) 0.019(5) 0.039(5) -0.004(5) 0.033(6) 0.001(5)
C14 0.038(6) 0.053(7) 0.040(6) 0.007(5) 0.022(5) -0.004(5)
C15 0.062(8) 0.052(7) 0.065(7) 0.023(5) 0.033(6) 0.005(6)
C16 0.088(9) 0.060(8) 0.089(8) 0.030(7) 0.062(8) 0.006(7)
C17 0.060(9) 0.099(10) 0.100(10) 0.035(7) 0.051(8) 0.006(7)
C18 0.036(7) 0.093(9) 0.075(9) 0.019(6) 0.028(7) 0.007(7)
C19 0.039(7) 0.068(8) 0.050(7) 0.020(6) 0.026(6) 0.013(5)
C20 0.032(6) 0.023(5) 0.027(5) -0.002(4) 0.007(5) 0.007(4)
C21 0.029(5) 0.032(5) 0.026(5) 0.000(5) 0.015(4) -0.001(5)
C22 0.044(6) 0.045(6) 0.025(6) -0.004(4) 0.002(5) -0.004(5)
C23 0.040(6) 0.082(9) 0.029(5) -0.003(5) 0.002(5) -0.007(5)
C24 0.066(8) 0.083(7) 0.035(7) 0.002(6) 0.011(6) -0.041(7)
C25 0.088(9) 0.044(6) 0.040(7) 0.013(5) 0.005(6) -0.025(6)
C26 0.063(7) 0.037(5) 0.024(6) 0.000(5) 0.005(5) -0.015(5)
C27 0.093(10) 0.062(8) 0.033(6) 0.015(6) 0.026(7) 0.024(7)
C28 0.224(18) 0.081(12) 0.095(11) -0.038(9) -0.047(11) -0.012(13)
C29 0.113(12) 0.202(15) 0.062(9) 0.045(9) 0.053(9) 0.114(11)
C30 0.082(9) 0.062(7) 0.051(7) 0.006(7) 0.007(7) 0.041(8)
C31 0.068(11) 0.177(17) 0.234(17) 0.165(15) -0.020(11) -0.019(12)
C32 0.23(2) 0.202(17) 0.053(10) 0.040(10) 0.039(12) 0.106(16)
C33 0.070(10) 0.129(12) 0.111(11) 0.061(9) 0.037(9) 0.052(9)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
W C2 1.986(10) . ?
W C1 1.993(11) . ?
W C3 2.029(10) . ?
W C5 2.030(10) . ?
W C4 2.044(11) . ?
W P1 2.521(2) . ?
Si1 C7 1.857(9) . ?
Si1 C8 1.861(9) . ?
Si1 C9 1.903(8) . ?
Si1 C6 1.929(8) . ?
Si2 C12 1.874(9) . ?
Si2 C11 1.876(8) . ?
Si2 C10 1.880(8) . ?
Si2 C6 1.923(9) . ?
Si3 C28 1.855(12) . ?
Si3 C29 1.858(10) . ?
Si3 C27 1.861(9) . ?
Si3 C30 1.862(9) . ?
Si4 C31 1.800(12) . ?
Si4 C33 1.843(10) . ?
Si4 C32 1.885(12) . ?
Si4 C27 1.889(9) . ?
P1 N2 1.698(7) . ?
P1 N1 1.710(7) . ?
P1 C6 1.796(8) . ?
P2 C13 1.829(10) . ?
P2 C27 1.852(9) . ?
P2 C20 1.882(9) . ?
N1 C13 1.280(9) . ?
N2 C20 1.267(9) . ?
O1 C1 1.177(10) . ?
O2 C2 1.167(10) . ?
O3 C3 1.153(10) . ?
O4 C4 1.135(10) . ?
O5 C5 1.148(9) . ?
C13 C14 1.514(11) . ?
C14 C15 1.375(11) . ?
C14 C19 1.388(12) . ?
C15 C16 1.384(11) . ?
C16 C17 1.383(14) . ?
C17 C18 1.355(13) . ?
C18 C19 1.413(10) . ?
C20 C21 1.482(12) . ?
C21 C22 1.379(11) . ?
C21 C26 1.398(10) . ?
C22 C23 1.349(11) . ?
C23 C24 1.394(12) . ?
C24 C25 1.386(14) . ?
C25 C26 1.348(12) . ?

loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
C2 W C1 87.1(4) . . ?
C2 W C3 92.9(4) . . ?
C1 W C3 87.4(4) . . ?
C2 W C5 96.0(4) . . ?
C1 W C5 92.9(4) . . ?
C3 W C5 171.1(4) . . ?
C2 W C4 84.5(4) . . ?
C1 W C4 171.2(4) . . ?
C3 W C4 90.7(4) . . ?
C5 W C4 90.3(4) . . ?
C2 W P1 176.0(3) . . ?
C1 W P1 94.6(3) . . ?
C3 W P1 83.7(3) . . ?
C5 W P1 87.5(3) . . ?
C4 W P1 93.7(3) . . ?
C7 Si1 C8 105.8(4) . . ?
C7 Si1 C9 111.1(5) . . ?
C8 Si1 C9 110.1(5) . . ?
C7 Si1 C6 109.6(4) . . ?
C8 Si1 C6 109.4(4) . . ?
C9 Si1 C6 110.7(4) . . ?
C12 Si2 C11 107.7(4) . . ?
C12 Si2 C10 105.4(4) . . ?
C11 Si2 C10 110.0(4) . . ?
C12 Si2 C6 114.0(4) . . ?
C11 Si2 C6 111.7(4) . . ?
C10 Si2 C6 107.8(4) . . ?
C28 Si3 C29 109.8(5) . . ?
C28 Si3 C27 109.1(6) . . ?
C29 Si3 C27 110.9(5) . . ?
C28 Si3 C30 105.3(5) . . ?
C29 Si3 C30 109.1(4) . . ?
C27 Si3 C30 112.6(4) . . ?
C31 Si4 C33 112.1(6) . . ?
C31 Si4 C32 104.4(7) . . ?
C33 Si4 C32 105.7(6) . . ?
C31 Si4 C27 114.8(5) . . ?
C33 Si4 C27 109.4(5) . . ?
C32 Si4 C27 110.0(5) . . ?
N2 P1 N1 103.6(3) . . ?
N2 P1 C6 107.1(4) . . ?
N1 P1 C6 102.0(4) . . ?
N2 P1 W 108.4(3) . . ?
N1 P1 W 119.0(2) . . ?
C6 P1 W 115.7(3) . . ?
C13 P2 C27 112.0(4) . . ?
C13 P2 C20 95.5(4) . . ?
C27 P2 C20 108.6(4) . . ?
C13 N1 P1 120.2(7) . . ?
C20 N2 P1 121.9(6) . . ?
O1 C1 W 174.6(9) . . ?
O2 C2 W 178.7(9) . . ?
O3 C3 W 175.1(10) . . ?
O4 C4 W 174.8(9) . . ?
O5 C5 W 177.8(9) . . ?
P1 C6 Si2 113.9(4) . . ?
P1 C6 Si1 115.9(5) . . ?
Si2 C6 Si1 113.9(5) . . ?
N1 C13 C14 115.8(9) . . ?
N1 C13 P2 123.2(7) . . ?
C14 C13 P2 120.5(7) . . ?
C15 C14 C19 118.9(9) . . ?
C15 C14 C13 121.8(9) . . ?
C19 C14 C13 119.3(8) . . ?
C14 C15 C16 122.9(10) . . ?
C17 C16 C15 117.0(10) . . ?
C18 C17 C16 122.5(11) . . ?
C17 C18 C19 119.6(11) . . ?
C14 C19 C18 119.2(10) . . ?
N2 C20 C21 120.3(8) . . ?
N2 C20 P2 121.2(7) . . ?
C21 C20 P2 118.0(6) . . ?
C22 C21 C26 117.4(10) . . ?
C22 C21 C20 124.2(10) . . ?
C26 C21 C20 118.2(9) . . ?
C23 C22 C21 123.2(10) . . ?
C22 C23 C24 118.4(10) . . ?
C25 C24 C23 119.5(11) . . ?
C26 C25 C24 120.8(11) . . ?
C25 C26 C21 120.5(11) . . ?
P2 C27 Si3 124.4(5) . . ?
P2 C27 Si4 111.0(5) . . ?
Si3 C27 Si4 122.4(5) . . ?

_diffrn_measured_fraction_theta_max    0.995
_diffrn_reflns_theta_full              24.99
_diffrn_measured_fraction_theta_full   0.995
_refine_diff_density_max    1.162
_refine_diff_density_min   -0.712
_refine_diff_density_rms    0.132