# Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2003


data_global
_journal_coden_Cambridge         182
loop_
_publ_author_name
'Thomas Pechmann'
'Carsten D. Brandt'
'Helmut Werner'

_publ_contact_author             'Prof. Dr. Helmut Werner'
_publ_contact_author_address     
;
Institut fur Anorganische Chemie
Universit\"at Wurzburg
Am Hubland
D-97074 Wurzburg
Deutschland
;
_publ_contact_author_email       helmut.werner@mail.uni-wuerzburg.de
_publ_requested_journal          'Chem. Commun.'

_publ_section_title              
;
The truly symmetrical bridging mode of trimethylphosphine in a dinuclear 
rhodium complex
;

_publ_section_abstract           
;
The dinuclear complex [Rh2I2(µ-CPh2)2(µ-PMe3)] was prepared from the 
Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to 
contain the PMe3 ligand in a truly symmetrical bridging position; 
a new synthetic route to migrate more bulky phosphines such as PPh3 
and PiPr3 from a terminal into a bridging site is also described.
;

data_tp7cb
_database_code_CSD               202931
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C31 H33 I2 O0.67 P Rh2'
_chemical_formula_weight         906.83

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           trigonal
_symmetry_space_group_name_H-M   R-3c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'

_cell_length_a                   22.9416(17)
_cell_length_b                   22.9416(17)
_cell_length_c                   31.230(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_volume                     14235(2)
_cell_formula_units_Z            18
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9283
_cell_measurement_theta_min      2.431
_cell_measurement_theta_max      24.492

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.904
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7836
_exptl_absorpt_coefficient_mu    3.066
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'SADABS2.0 (Sheldrick 2000)'

_exptl_special_details           
; 
The residual electron densities above 1 are less than 1 A away from 
the heavy atoms. The asymmetric unit contains half a molecule. 
Additionally two third of a heavily disordered solvent molecule is found.
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart Apex with D8-Goniometer'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            53384
_diffrn_reflns_av_R_equivalents  0.0787
_diffrn_reflns_av_sigmaI/netI    0.0216
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         1.66
_diffrn_reflns_theta_max         25.14
_reflns_number_total             2817
_reflns_number_gt                2779
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART-NT V5.6'
_computing_cell_refinement       'SAINT-NT V6.0'
_computing_data_reduction        'SAINT-NT V6.0'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'XSHELL in SHELXTL-97'
_computing_publication_material  'XSHELL in SHELXTL-97'

_refine_special_details          
; 
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
goodness of fit S are based on F^2^, conventional R-factors R are based 
on F, with F set to zero for negative F^2^. The threshold expression of 
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
not relevant to the choice of reflections for refinement.  R-factors based 
on F^2^ are statistically about twice as large as those based on F, and R- 
factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w==1/[\s^2^(Fo^2^)+(0.0186P)^2^+644.7705P] where P==(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         2817
_refine_ls_number_parameters     201
_refine_ls_number_restraints     30
_refine_ls_R_factor_all          0.0664
_refine_ls_R_factor_gt           0.0658
_refine_ls_wR_factor_ref         0.1375
_refine_ls_wR_factor_gt          0.1372
_refine_ls_goodness_of_fit_ref   1.303
_refine_ls_restrained_S_all      1.306
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3731(4) 0.3595(5) 0.3807(3) 0.031(2) Uani 1 1 d . . .
C2 C 0.3826(4) 0.4291(5) 0.3769(3) 0.030(2) Uani 1 1 d . . .
C3 C 0.4415(5) 0.4844(5) 0.3931(3) 0.040(2) Uani 1 1 d . . .
H3 H 0.4745 0.4768 0.4062 0.048 Uiso 1 1 calc R . .
C4 C 0.4531(5) 0.5494(5) 0.3907(3) 0.041(2) Uani 1 1 d . . .
H4 H 0.4933 0.5857 0.4020 0.049 Uiso 1 1 calc R . .
C5 C 0.4053(6) 0.5610(5) 0.3717(4) 0.047(3) Uani 1 1 d . . .
H5 H 0.4127 0.6054 0.3690 0.057 Uiso 1 1 calc R . .
C6 C 0.3471(6) 0.5069(5) 0.3568(4) 0.054(3) Uani 1 1 d . . .
H6 H 0.3136 0.5147 0.3447 0.065 Uiso 1 1 calc R . .
C7 C 0.3350(5) 0.4414(5) 0.3585(4) 0.043(3) Uani 1 1 d . . .
H7 H 0.2945 0.4055 0.3472 0.052 Uiso 1 1 calc R . .
C8 C 0.4069(5) 0.3439(4) 0.3451(3) 0.032(2) Uani 1 1 d . . .
C9 C 0.3737(5) 0.3179(5) 0.3058(3) 0.041(2) Uani 1 1 d . . .
H9 H 0.3301 0.3122 0.3015 0.049 Uiso 1 1 calc R . .
C10 C 0.4034(6) 0.3003(5) 0.2732(4) 0.048(3) Uani 1 1 d . . .
H10 H 0.3801 0.2828 0.2470 0.058 Uiso 1 1 calc R . .
C11 C 0.4664(6) 0.3085(5) 0.2791(4) 0.047(3) Uani 1 1 d . . .
H11 H 0.4863 0.2955 0.2572 0.057 Uiso 1 1 calc R . .
C12 C 0.5005(6) 0.3354(6) 0.3166(4) 0.049(3) Uani 1 1 d . . .
H12 H 0.5446 0.3421 0.3201 0.059 Uiso 1 1 calc R . .
C13 C 0.4715(5) 0.3531(5) 0.3497(4) 0.044(3) Uani 1 1 d . . .
H13 H 0.4958 0.3715 0.3755 0.053 Uiso 1 1 calc R . .
C14 C 0.3346(14) 0.1828(12) 0.4655(7) 0.048(6) Uani 0.50 1 d P . .
H14A H 0.3412 0.1442 0.4610 0.072 Uiso 0.50 1 calc PR . .
H14B H 0.2917 0.1678 0.4803 0.072 Uiso 0.50 1 calc PR . .
H14C H 0.3715 0.2166 0.4830 0.072 Uiso 0.50 1 calc PR . .
C15 C 0.2415(13) 0.1349(11) 0.3979(8) 0.054(6) Uani 0.50 1 d P . .
H15A H 0.2440 0.0936 0.4004 0.080 Uiso 0.50 1 calc PR . .
H15B H 0.2319 0.1408 0.3682 0.080 Uiso 0.50 1 calc PR . .
H15C H 0.2055 0.1315 0.4165 0.080 Uiso 0.50 1 calc PR . .
C16 C 0.3796(15) 0.2036(12) 0.3812(7) 0.051(6) Uani 0.50 1 d P . .
H16A H 0.3723 0.1581 0.3852 0.077 Uiso 0.50 1 calc PR . .
H16B H 0.4273 0.2366 0.3855 0.077 Uiso 0.50 1 calc PR . .
H16C H 0.3662 0.2081 0.3521 0.077 Uiso 0.50 1 calc PR . .
I1 I 0.49132(4) 0.39739(4) 0.48738(3) 0.0566(3) Uani 1 1 d . . .
P P 0.3333 0.21745(17) 0.4167 0.0552(13) Uani 1 2 d S . .
Rh1 Rh 0.38501(4) 0.33315(4) 0.43961(2) 0.0310(2) Uani 1 1 d . . .
C20 C 0.6667 0.3333 0.3730(13) 0.213(17) Uani 1 3 d SDU . .
H20A H 0.6338 0.3407 0.3575 0.320 Uiso 0.33 1 calc PR . .
H20B H 0.6675 0.2944 0.3609 0.320 Uiso 0.33 1 calc PR . .
H20C H 0.7114 0.3733 0.3704 0.320 Uiso 0.33 1 calc PR . .
C21 C 0.648(3) 0.321(2) 0.4185(13) 0.179(15) Uani 0.33 1 d PDU . .
C22 C 0.674(5) 0.306(5) 0.4587(17) 0.177(17) Uani 0.33 1 d PDU . .
H22A H 0.6439 0.3009 0.4826 0.265 Uiso 0.33 1 calc PR . .
H22B H 0.7191 0.3430 0.4647 0.265 Uiso 0.33 1 calc PR . .
H22C H 0.6749 0.2641 0.4550 0.265 Uiso 0.33 1 calc PR . .
O O 0.593(3) 0.324(3) 0.4194(14) 0.179(15) Uani 0.33 1 d PDU . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.021(4) 0.030(5) 0.035(5) 0.006(4) -0.001(4) 0.009(4)
C2 0.028(5) 0.031(5) 0.029(5) 0.008(4) 0.007(4) 0.013(4)
C3 0.034(5) 0.035(5) 0.046(6) -0.001(5) -0.012(5) 0.014(4)
C4 0.037(5) 0.031(5) 0.037(6) 0.001(4) 0.005(4) 0.004(4)
C5 0.048(6) 0.033(5) 0.060(7) 0.012(5) 0.017(5) 0.019(5)
C6 0.041(6) 0.039(6) 0.087(9) 0.012(6) -0.007(6) 0.023(5)
C7 0.026(5) 0.039(6) 0.059(7) 0.005(5) 0.003(5) 0.012(4)
C8 0.029(5) 0.022(4) 0.042(6) 0.005(4) 0.000(4) 0.010(4)
C9 0.039(6) 0.041(6) 0.044(6) 0.010(5) 0.004(5) 0.021(5)
C10 0.070(8) 0.040(6) 0.035(6) -0.003(5) 0.001(6) 0.028(6)
C11 0.065(8) 0.036(6) 0.044(6) 0.000(5) 0.017(6) 0.027(6)
C12 0.044(6) 0.053(7) 0.052(7) -0.001(6) 0.008(5) 0.026(6)
C13 0.037(6) 0.041(6) 0.049(7) -0.002(5) 0.002(5) 0.016(5)
C14 0.064(16) 0.046(14) 0.040(13) 0.000(11) -0.009(12) 0.032(13)
C15 0.071(16) 0.037(12) 0.054(15) 0.002(11) -0.005(12) 0.028(12)
C16 0.080(19) 0.051(14) 0.038(13) 0.005(11) 0.013(13) 0.044(14)
I1 0.0365(4) 0.0504(5) 0.0702(6) 0.0087(4) -0.0204(4) 0.0123(3)
P 0.097(4) 0.0420(15) 0.045(2) 0.0140(12) 0.028(2) 0.0483(18)
Rh1 0.0260(4) 0.0311(4) 0.0370(4) 0.0012(3) -0.0017(3) 0.0152(3)
C20 0.25(2) 0.25(2) 0.15(3) 0.000 0.000 0.123(12)
C21 0.23(3) 0.21(3) 0.14(2) -0.014(16) -0.011(12) 0.14(2)
C22 0.23(3) 0.20(3) 0.15(3) -0.01(2) -0.01(2) 0.15(3)
O 0.24(3) 0.19(3) 0.16(3) -0.02(2) -0.023(15) 0.15(2)

_geom_special_details            
; 
All esds (except the esd in the dihedral angle between two l.s. planes) 
are estimated using the full covariance matrix.  The cell esds are taken 
into account individually in the estimation of esds in distances, angles 
and torsion angles; correlations between esds in cell parameters are only 
used when they are defined by crystal symmetry.  An approximate (isotropic) 
treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C8 1.497(14) . ?
C1 C2 1.503(13) . ?
C1 Rh1 1.999(9) . ?
C1 Rh1 2.004(9) 12 ?
C2 C7 1.384(14) . ?
C2 C3 1.406(13) . ?
C3 C4 1.379(14) . ?
C4 C5 1.385(15) . ?
C5 C6 1.372(16) . ?
C6 C7 1.384(15) . ?
C8 C13 1.395(14) . ?
C8 C9 1.411(14) . ?
C9 C10 1.390(15) . ?
C10 C11 1.374(17) . ?
C11 C12 1.373(16) . ?
C12 C13 1.395(15) . ?
C14 P 1.73(2) . ?
C15 P 2.09(2) . ?
C16 P 1.67(2) . ?
I1 Rh1 2.5983(10) . ?
P C16 1.67(2) 12 ?
P C14 1.73(2) 12 ?
P C15 2.09(2) 12 ?
P Rh1 2.412(3) . ?
P Rh1 2.412(3) 12 ?
Rh1 C1 2.004(9) 12 ?
Rh1 Rh1 2.5040(14) 12 ?
C20 C21 1.47(2) . ?
C21 O 1.30(2) . ?
C21 C22 1.498(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 C1 C2 112.2(7) . . ?
C8 C1 Rh1 116.5(6) . . ?
C2 C1 Rh1 115.0(7) . . ?
C8 C1 Rh1 112.0(6) . 12 ?
C2 C1 Rh1 119.7(6) . 12 ?
Rh1 C1 Rh1 77.4(3) . 12 ?
C7 C2 C3 117.7(9) . . ?
C7 C2 C1 122.6(9) . . ?
C3 C2 C1 119.7(8) . . ?
C4 C3 C2 122.4(10) . . ?
C3 C4 C5 119.2(10) . . ?
C6 C5 C4 118.5(10) . . ?
C5 C6 C7 123.0(11) . . ?
C2 C7 C6 119.2(10) . . ?
C13 C8 C9 117.5(10) . . ?
C13 C8 C1 121.7(9) . . ?
C9 C8 C1 120.8(8) . . ?
C10 C9 C8 121.3(10) . . ?
C11 C10 C9 119.8(11) . . ?
C10 C11 C12 120.0(10) . . ?
C11 C12 C13 121.0(11) . . ?
C12 C13 C8 120.3(11) . . ?
C16 P C16 119.0(16) 12 . ?
C16 P C14 35.3(11) 12 . ?
C16 P C14 109.9(11) . . ?
C16 P C14 109.9(11) 12 12 ?
C16 P C14 35.3(11) . 12 ?
C14 P C14 124.1(16) . 12 ?
C16 P C15 60.1(11) 12 . ?
C16 P C15 95.2(12) . . ?
C14 P C15 94.1(11) . . ?
C14 P C15 63.4(11) 12 . ?
C16 P C15 95.2(12) 12 12 ?
C16 P C15 60.1(11) . 12 ?
C14 P C15 63.4(11) . 12 ?
C14 P C15 94.1(11) 12 12 ?
C15 P C15 132.6(13) . 12 ?
C16 P Rh1 118.1(8) 12 . ?
C16 P Rh1 113.4(9) . . ?
C14 P Rh1 97.6(8) . . ?
C14 P Rh1 132.0(8) 12 . ?
C15 P Rh1 142.9(7) . . ?
C15 P Rh1 83.6(6) 12 . ?
C16 P Rh1 113.4(9) 12 12 ?
C16 P Rh1 118.1(8) . 12 ?
C14 P Rh1 132.0(8) . 12 ?
C14 P Rh1 97.6(8) 12 12 ?
C15 P Rh1 83.6(6) . 12 ?
C15 P Rh1 142.9(7) 12 12 ?
Rh1 P Rh1 62.54(10) . 12 ?
C1 Rh1 C1 86.7(4) . 12 ?
C1 Rh1 P 89.6(3) . . ?
C1 Rh1 P 89.5(3) 12 . ?
C1 Rh1 Rh1 51.4(2) . 12 ?
C1 Rh1 Rh1 51.2(3) 12 12 ?
P Rh1 Rh1 58.73(5) . 12 ?
C1 Rh1 I1 126.1(3) . . ?
C1 Rh1 I1 125.7(3) 12 . ?
P Rh1 I1 126.89(6) . . ?
Rh1 Rh1 I1 174.37(2) 12 . ?
O C21 C20 102(3) . . ?
O C21 C22 120(3) . . ?
C20 C21 C22 138(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C1 C2 C7 96.8(11) . . . . ?
Rh1 C1 C2 C7 -126.9(9) . . . . ?
Rh1 C1 C2 C7 -37.5(12) 12 . . . ?
C8 C1 C2 C3 -84.0(11) . . . . ?
Rh1 C1 C2 C3 52.2(11) . . . . ?
Rh1 C1 C2 C3 141.7(8) 12 . . . ?
C7 C2 C3 C4 -0.7(16) . . . . ?
C1 C2 C3 C4 -179.9(9) . . . . ?
C2 C3 C4 C5 -0.1(16) . . . . ?
C3 C4 C5 C6 1.6(16) . . . . ?
C4 C5 C6 C7 -2.4(19) . . . . ?
C3 C2 C7 C6 0.0(16) . . . . ?
C1 C2 C7 C6 179.2(10) . . . . ?
C5 C6 C7 C2 1.6(19) . . . . ?
C2 C1 C8 C13 95.0(11) . . . . ?
Rh1 C1 C8 C13 -40.6(11) . . . . ?
Rh1 C1 C8 C13 -127.1(8) 12 . . . ?
C2 C1 C8 C9 -86.4(10) . . . . ?
Rh1 C1 C8 C9 138.0(8) . . . . ?
Rh1 C1 C8 C9 51.5(10) 12 . . . ?
C13 C8 C9 C10 1.6(15) . . . . ?
C1 C8 C9 C10 -177.0(9) . . . . ?
C8 C9 C10 C11 -0.2(16) . . . . ?
C9 C10 C11 C12 -1.6(17) . . . . ?
C10 C11 C12 C13 1.8(18) . . . . ?
C11 C12 C13 C8 -0.2(17) . . . . ?
C9 C8 C13 C12 -1.4(15) . . . . ?
C1 C8 C13 C12 177.2(9) . . . . ?
C8 C1 Rh1 C1 -149.2(7) . . . 12 ?
C2 C1 Rh1 C1 76.5(6) . . . 12 ?
Rh1 C1 Rh1 C1 -40.7(4) 12 . . 12 ?
C8 C1 Rh1 P -59.7(6) . . . . ?
C2 C1 Rh1 P 165.9(6) . . . . ?
Rh1 C1 Rh1 P 48.8(2) 12 . . . ?
C8 C1 Rh1 Rh1 -108.5(7) . . . 12 ?
C2 C1 Rh1 Rh1 117.2(7) . . . 12 ?
C8 C1 Rh1 I1 77.8(7) . . . . ?
C2 C1 Rh1 I1 -56.5(7) . . . . ?
Rh1 C1 Rh1 I1 -173.68(5) 12 . . . ?
C16 P Rh1 C1 -146.7(11) 12 . . . ?
C16 P Rh1 C1 67.3(10) . . . . ?
C14 P Rh1 C1 -177.2(9) . . . . ?
C14 P Rh1 C1 31.1(12) 12 . . . ?
C15 P Rh1 C1 -70.0(11) . . . . ?
C15 P Rh1 C1 120.8(7) 12 . . . ?
Rh1 P Rh1 C1 -43.4(3) 12 . . . ?
C16 P Rh1 C1 -60.0(11) 12 . . 12 ?
C16 P Rh1 C1 154.0(10) . . . 12 ?
C14 P Rh1 C1 -90.4(9) . . . 12 ?
C14 P Rh1 C1 117.8(12) 12 . . 12 ?
C15 P Rh1 C1 16.7(11) . . . 12 ?
C15 P Rh1 C1 -152.4(7) 12 . . 12 ?
Rh1 P Rh1 C1 43.3(3) 12 . . 12 ?
C16 P Rh1 Rh1 -103.3(11) 12 . . 12 ?
C16 P Rh1 Rh1 110.7(10) . . . 12 ?
C14 P Rh1 Rh1 -133.7(9) . . . 12 ?
C14 P Rh1 Rh1 74.5(12) 12 . . 12 ?
C15 P Rh1 Rh1 -26.5(11) . . . 12 ?
C15 P Rh1 Rh1 164.3(7) 12 . . 12 ?
C16 P Rh1 I1 76.3(11) 12 . . . ?
C16 P Rh1 I1 -69.7(10) . . . . ?
C14 P Rh1 I1 45.8(9) . . . . ?
C14 P Rh1 I1 -105.9(12) 12 . . . ?
C15 P Rh1 I1 153.0(11) . . . . ?
C15 P Rh1 I1 -16.1(7) 12 . . . ?
Rh1 P Rh1 I1 179.59(7) 12 . . . ?

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        25.14
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         1.389
_refine_diff_density_min         -1.044
_refine_diff_density_rms         0.157