# Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2005

data_global
_journal_name_full               Chem.Commun.

#------------------ PROCESSING SUMMARY (JOURNAL OFFICE ONLY) ----------------#

_journal_coden_Cambridge         0182

#------------------ AUDIT DETAILS -------------------------------------------#

_audit_creation_date             2005-09-27
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.2
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_update_record             ?

#------------------ SUBMISSION DETAILS --------------------------------------#

# Name and address of author for correspondence

_publ_contact_author_name        'Bernhard Lippert'
_publ_contact_author_address     
;
Anorganische Chemie
Universit\\\"at Dortmund
Otto-Hahn-Str. 6
44227 Dortmund
Germany
;
_publ_contact_author_email       bernhard.lippert@uni-dortmund.de
_publ_contact_author_fax         '+49 231 755 3797'
_publ_contact_author_phone       '+49 231 755 3840'

_publ_requested_category         metalorganic
_journal_year                    ?
_journal_volume                  ?
_journal_issue                   ?
_journal_page_first              ?

#------------------ TITLE AND AUTHOR LIST------------------------------------#

_publ_section_title              
;
Structural precursor of the hemideprotonated guanine pair
;

loop_
_publ_author_name
_publ_author_address
M.Roitzsch
;
Anorganische Chemie
Universit\\\"at Dortmund
Otto-Hahn-Str. 6
44227 Dortmund
Germany
;
B.Lippert
;
Anorganische Chemie
Universit\\\"at Dortmund
Otto-Hahn-Str. 6
44227 Dortmund
Germany
;

_publ_section_synopsis           
;
# Insert blank lines between paragraphs
?
;
_publ_section_abstract           
;
# Insert blank lines between paragraphs
?
;

_publ_section_comment            
;
# Insert blank lines between paragraphs
?
;

_publ_section_exptl_prep         
;
?
;

_publ_section_exptl_refinement   
;
?
;

_publ_section_references         
;

Farrugia, L. J. (1997) ORTEP-3 for Windows, J. Appl. Cryst. 30, 565.

Farrugia, L. J. (1999) WinGX, J. Appl. Cryst. 32, 837-838.

Sheldrick, G.M. (1997) SHELXL97. Program for crystal structure
refinement. University of G\\\"ottingen, Germany.

Sheldrick, G.M. (1997) SHELXS97. Program for Crystal Structure solution.
University of G\\\"ottingen, Germany.

;
_publ_section_acknowledgements   
;
?
;

data_1900
_database_code_depnum_ccdc_archive 'CCDC 281552'

_audit_creation_date             2005-09-27T18:47:04-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'

#------------------ CHEMICAL INFORMATION ------------------------------------#

_chemical_formula_sum            'C13 H34 Cl4 N14 O16 Pt2'
_chemical_formula_moiety         'C13 H34 Cl4 N14 O16 Pt2'
_chemical_formula_weight         1174.46

#------------------ UNIT CELL INFORMATION -----------------------------------#

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.7260(17)
_cell_length_b                   10.837(2)
_cell_length_c                   19.885(4)
_cell_angle_alpha                89.60(3)
_cell_angle_beta                 84.65(3)
_cell_angle_gamma                75.25(3)
_cell_volume                     1810.3(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5445
_cell_measurement_theta_min      3
_cell_measurement_theta_max      27.5

#------------------ CRYSTAL INFORMATION -------------------------------------#

_exptl_crystal_description       cuboid
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_exptl_crystal_density_diffrn    2.155
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1124
_exptl_absorpt_coefficient_mu    8.096
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2807
_exptl_absorpt_correction_T_max  0.4433
_exptl_absorpt_process_details   'SADABS, Sheldrick, Bruker, 2000'

#------------------ DATA COLLECTION INFORMATION -----------------------------#

_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\\a
_diffrn_reflns_number            15431
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_theta_min         3.03
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_full        27.5
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measured_fraction_theta_full 0.966
_reflns_number_total             8037
_reflns_number_gt                5445
_reflns_threshold_expression     >2sigma(I)

#------------------ COMPUTER PROGRAMS USED ----------------------------------#

_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'

#------------------ REFINEMENT INFORMATION ----------------------------------#

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\\s^2^(Fo^2^)+(0.0473P)^2^+4.6981P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_number_reflns         8037
_refine_ls_number_parameters     449
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0446
_refine_ls_wR_factor_ref         0.1117
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          3.592
_refine_diff_density_max         1.196
_refine_diff_density_min         -0.789

#------------------ ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS --------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
_atom_site_disorder_assembly
Pt2 Pt 0.71331(4) 0.08400(3) 0.169699(17) 0.04205(11) Uani 1 d . . .
Pt1 Pt 0.55522(4) -0.42239(3) 0.285734(16) 0.03947(11) Uani 1 d . . .
N7G N 0.4412(7) -0.4712(7) 0.3710(3) 0.0413(16) Uani 1 d . . .
N1A N 0.6615(8) -0.3584(7) 0.2021(3) 0.0451(17) Uani 1 d . . .
N9G N 0.2955(8) -0.5554(7) 0.4437(4) 0.0461(17) Uani 1 d . . .
C4G C 0.3062(9) -0.4443(8) 0.4728(4) 0.0391(19) Uani 1 d . . .
N3G N 0.2364(8) -0.3961(8) 0.5343(3) 0.0488(18) Uani 1 d . . .
N12 N 0.7588(8) -0.4403(9) 0.3333(4) 0.061(2) Uani 1 d . . .
H12A H 0.843 -0.4794 0.3057 0.091 Uiso 1 calc R . .
H12B H 0.7538 -0.486 0.3705 0.091 Uiso 1 calc R . .
H12C H 0.7678 -0.3632 0.3445 0.091 Uiso 1 calc R . .
C6A C 0.6670(9) -0.2342(8) 0.2002(4) 0.0383(18) Uani 1 d . . .
N6A N 0.6063(8) -0.1572(7) 0.2528(3) 0.0470(18) Uani 1 d . . .
H6A1 H 0.5635 -0.1858 0.2882 0.056 Uiso 1 calc R . .
H6A2 H 0.6099 -0.0786 0.2515 0.056 Uiso 1 calc R . .
N9A N 0.8386(9) -0.2245(8) 0.0340(3) 0.0506(19) Uani 1 d . . .
O6G O 0.5094(8) -0.2139(6) 0.4072(3) 0.0630(18) Uani 1 d . . .
N11 N 0.3522(9) -0.4012(9) 0.2387(4) 0.065(2) Uani 1 d . . .
H11A H 0.3495 -0.3435 0.2065 0.098 Uiso 1 calc R . .
H11B H 0.2679 -0.3752 0.2688 0.098 Uiso 1 calc R . .
H11C H 0.3507 -0.4756 0.2205 0.098 Uiso 1 calc R . .
N1G N 0.3578(9) -0.2274(8) 0.5058(4) 0.055(2) Uani 1 d . . .
H1G H 0.3731 -0.1568 0.5196 0.066 Uiso 1 calc R . .
C5A C 0.7344(9) -0.1976(8) 0.1398(4) 0.0375(18) Uani 1 d . . .
C4A C 0.7839(10) -0.2865(8) 0.0883(4) 0.043(2) Uani 1 d . . .
C5G C 0.3978(9) -0.3908(8) 0.4274(4) 0.0381(18) Uani 1 d . . .
C6G C 0.4287(10) -0.2740(9) 0.4422(4) 0.046(2) Uani 1 d . . .
C8A C 0.8198(10) -0.1036(9) 0.0540(4) 0.050(2) Uani 1 d . . .
H8A H 0.8475 -0.0419 0.0262 0.06 Uiso 1 calc R . .
C8G C 0.3781(10) -0.5667(9) 0.3831(4) 0.044(2) Uani 1 d . . .
H8G H 0.3893 -0.6346 0.3531 0.052 Uiso 1 calc R . .
C2A C 0.7171(12) -0.4387(10) 0.1482(5) 0.064(3) Uani 1 d . . .
H2A H 0.7108 -0.5227 0.1533 0.077 Uiso 1 calc R . .
C9G C 0.2051(12) -0.6434(10) 0.4720(5) 0.063(3) Uani 1 d . . .
H9G1 H 0.0955 -0.5981 0.4821 0.094 Uiso 1 calc R . .
H9G2 H 0.248 -0.6791 0.5126 0.094 Uiso 1 calc R . .
H9G3 H 0.2124 -0.7108 0.4398 0.094 Uiso 1 calc R . .
N3A N 0.7796(11) -0.4084(8) 0.0889(4) 0.065(2) Uani 1 d . . .
Cl1 Cl 0.6644(3) 0.2702(3) 0.22974(15) 0.0707(7) Uani 1 d . . .
N7A N 0.7576(7) -0.0808(7) 0.1174(3) 0.0392(16) Uani 1 d . . .
N21 N 0.5002(9) 0.1453(9) 0.1306(5) 0.074(3) Uani 1 d . . .
H21A H 0.5005 0.0998 0.0934 0.111 Uiso 1 calc R . .
H21B H 0.4842 0.2273 0.1203 0.111 Uiso 1 calc R . .
H21C H 0.4226 0.1354 0.1609 0.111 Uiso 1 calc R . .
N22 N 0.9288(9) 0.0275(9) 0.2077(4) 0.065(2) Uani 1 d . . .
H22A H 0.9198 -0.018 0.2447 0.097 Uiso 1 calc R . .
H22B H 0.9612 0.0959 0.2182 0.097 Uiso 1 calc R . .
H22C H 0.9994 -0.0201 0.177 0.097 Uiso 1 calc R . .
Cl10 Cl 0.1200(3) 0.3260(3) 0.24458(16) 0.0771(9) Uani 1 d . . .
Cl20 Cl 0.3121(3) -0.1455(4) 0.08763(18) 0.0824(9) Uani 1 d . . .
C9A1 C 0.9040(15) -0.2786(13) -0.0339(5) 0.083(4) Uani 1 d . . .
H9A1 H 0.914 -0.3698 -0.033 0.1 Uiso 1 calc R . .
H9A2 H 0.8277 -0.2424 -0.0657 0.1 Uiso 1 calc R . .
O21 O 0.1561(10) -0.0979(11) 0.0749(5) 0.118(4) Uani 1 d . . .
N2G N 0.2080(12) -0.2218(10) 0.6055(5) 0.089(3) Uani 1 d . . .
H2G1 H 0.1499 -0.2528 0.6349 0.107 Uiso 1 calc R . .
H2G2 H 0.2285 -0.1501 0.6134 0.107 Uiso 1 calc R . .
C2G C 0.2664(11) -0.2853(10) 0.5475(4) 0.051(2) Uani 1 d . . .
O23 O 0.4127(13) -0.0971(15) 0.0420(6) 0.170(6) Uani 1 d . . .
O24 O 0.3666(17) -0.2739(13) 0.0942(8) 0.168(5) Uani 1 d . . .
O22 O 0.3351(17) -0.0975(19) 0.1524(7) 0.187(7) Uani 1 d . . .
C9A2 C 1.0512(18) -0.2590(17) -0.0580(8) 0.148(8) Uani 1 d . . .
H9A3 H 1.039 -0.1703 -0.0678 0.222 Uiso 1 calc R . .
H9A4 H 1.091 -0.3092 -0.0985 0.222 Uiso 1 calc R . .
H9A5 H 1.1249 -0.284 -0.0245 0.222 Uiso 1 calc R . .
O1W O 0.4197(19) -0.0370(13) 0.5878(9) 0.206(7) Uani 1 d . . .
O2W O 0.452(3) 0.410(3) 0.0534(14) 0.333(14) Uani 1 d . . .
O3W O 0.696(4) -0.054(2) 0.641(3) 0.64(4) Uani 1 d . . .
Cl30 Cl 1.0120(4) -0.1972(4) 0.3588(2) 0.0986(11) Uani 1 d . . .
O31 O 0.8814(19) -0.129(3) 0.3435(9) 0.310(15) Uani 1 d . . .
O32 O 1.033(3) -0.307(3) 0.328(2) 0.57(4) Uani 1 d . . .
O34 O 1.1488(16) -0.1724(14) 0.3348(8) 0.181(6) Uani 1 d . . .
O33 O 1.017(3) -0.219(4) 0.4167(17) 0.49(3) Uani 1 d . . .
O11 O 0.2740(12) 0.3341(14) 0.2425(7) 0.113(5) Uani 0.790(18) d P . .
O14 O 0.1272(18) 0.2156(15) 0.2047(8) 0.138(7) Uani 0.790(18) d P . .
O12 O 0.0145(15) 0.4319(16) 0.2170(8) 0.142(7) Uani 0.790(18) d P . .
O13 O 0.0586(16) 0.3176(17) 0.3103(6) 0.147(7) Uani 0.790(18) d P . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt2 0.0469(2) 0.0352(2) 0.0459(2) 0.00145(15) 0.00274(14) -0.01647(15)
Pt1 0.0498(2) 0.0330(2) 0.03537(19) 0.00165(14) 0.00678(13) -0.01403(15)
N7G 0.043(4) 0.045(4) 0.036(4) 0.003(3) 0.006(3) -0.016(3)
N1A 0.059(4) 0.037(4) 0.038(4) -0.003(3) 0.013(3) -0.015(3)
N9G 0.049(4) 0.048(5) 0.044(4) 0.005(4) 0.002(3) -0.020(3)
C4G 0.039(4) 0.041(5) 0.035(5) 0.009(4) -0.003(3) -0.006(4)
N3G 0.050(4) 0.052(5) 0.037(4) -0.003(4) 0.007(3) -0.004(4)
N12 0.052(4) 0.084(7) 0.049(5) 0.018(4) -0.005(3) -0.023(4)
C6A 0.042(4) 0.032(5) 0.040(5) -0.005(4) 0.006(3) -0.010(4)
N6A 0.070(5) 0.036(4) 0.034(4) -0.004(3) 0.015(3) -0.018(4)
N9A 0.070(5) 0.056(5) 0.030(4) -0.005(4) 0.010(3) -0.029(4)
O6G 0.079(4) 0.049(4) 0.065(4) -0.010(3) 0.017(3) -0.032(4)
N11 0.076(5) 0.077(7) 0.051(5) 0.013(5) -0.005(4) -0.034(5)
N1G 0.067(5) 0.051(5) 0.047(5) -0.005(4) 0.007(4) -0.023(4)
C5A 0.041(4) 0.039(5) 0.033(4) 0.001(4) 0.003(3) -0.013(4)
C4A 0.054(5) 0.041(5) 0.035(5) -0.003(4) 0.010(4) -0.022(4)
C5G 0.038(4) 0.045(5) 0.029(4) -0.002(4) 0.004(3) -0.009(4)
C6G 0.046(5) 0.044(5) 0.046(5) -0.008(4) 0.003(4) -0.011(4)
C8A 0.064(6) 0.054(6) 0.039(5) 0.001(4) 0.006(4) -0.030(5)
C8G 0.055(5) 0.041(5) 0.037(5) 0.001(4) 0.003(4) -0.017(4)
C2A 0.096(7) 0.045(6) 0.049(6) -0.025(5) 0.033(5) -0.029(5)
C9G 0.077(7) 0.060(7) 0.058(6) 0.008(5) 0.007(5) -0.034(5)
N3A 0.100(6) 0.049(5) 0.047(5) -0.008(4) 0.023(4) -0.034(5)
Cl1 0.0847(17) 0.0446(15) 0.0825(19) -0.0159(13) 0.0075(14) -0.0211(13)
N7A 0.041(4) 0.046(4) 0.035(4) 0.001(3) 0.002(3) -0.021(3)
N21 0.048(5) 0.068(6) 0.103(7) -0.005(5) -0.017(4) -0.004(4)
N22 0.068(5) 0.065(6) 0.067(6) -0.001(5) -0.024(4) -0.020(4)
Cl10 0.0563(16) 0.098(2) 0.084(2) -0.0229(18) 0.0073(13) -0.0364(16)
Cl20 0.0668(18) 0.086(2) 0.096(2) 0.0259(19) -0.0228(15) -0.0168(16)
C9A1 0.121(10) 0.096(10) 0.040(6) -0.025(6) 0.033(6) -0.054(8)
O21 0.065(5) 0.154(10) 0.134(8) 0.022(7) -0.025(5) -0.018(6)
N2G 0.124(8) 0.072(7) 0.067(6) -0.019(5) 0.034(6) -0.033(6)
C2G 0.061(6) 0.052(6) 0.036(5) -0.009(4) 0.006(4) -0.008(5)
O23 0.112(8) 0.255(17) 0.146(11) 0.108(11) -0.015(7) -0.054(9)
O24 0.185(12) 0.107(10) 0.196(14) 0.047(10) -0.001(10) -0.015(9)
O22 0.162(12) 0.28(2) 0.116(10) -0.015(11) -0.041(9) -0.046(12)
C9A2 0.149(14) 0.172(19) 0.134(15) -0.095(14) 0.076(12) -0.090(14)
O1W 0.220(14) 0.119(11) 0.288(19) -0.103(12) 0.042(13) -0.080(10)
O2W 0.40(3) 0.33(3) 0.35(3) 0.10(3) -0.16(3) -0.19(3)
O3W 0.61(5) 0.120(17) 1.22(10) -0.06(3) -0.68(7) 0.06(2)
Cl30 0.069(2) 0.115(3) 0.114(3) 0.019(3) -0.0115(19) -0.029(2)
O31 0.126(12) 0.53(4) 0.195(17) 0.04(2) -0.045(11) 0.069(18)
O32 0.22(2) 0.54(5) 0.99(9) -0.62(6) 0.29(4) -0.27(3)
O34 0.143(10) 0.168(14) 0.239(16) 0.014(12) 0.028(10) -0.071(9)
O33 0.22(2) 0.76(7) 0.41(4) 0.47(5) -0.02(2) -0.01(3)
O11 0.061(7) 0.146(12) 0.140(11) -0.044(9) 0.008(6) -0.046(7)
O14 0.155(13) 0.141(13) 0.141(12) -0.073(10) 0.028(9) -0.092(10)
O12 0.096(9) 0.151(14) 0.145(13) 0.053(11) 0.003(8) 0.028(9)
O13 0.128(10) 0.213(18) 0.065(8) 0.021(9) 0.038(7) 0.003(10)

#------------------ MOLECULAR GEOMETRY --------------------------------------#

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt2 N7A 2.005(7) . ?
Pt2 N21 2.034(7) . ?
Pt2 N22 2.038(7) . ?
Pt2 Cl1 2.276(3) . ?
Pt1 N7G 2.021(6) . ?
Pt1 N1A 2.032(6) . ?
Pt1 N11 2.040(8) . ?
Pt1 N12 2.056(7) . ?
N7G C8G 1.302(10) . ?
N7G C5G 1.390(10) . ?
N1A C2A 1.357(11) . ?
N1A C6A 1.359(10) . ?
N9G C8G 1.336(10) . ?
N9G C4G 1.368(11) . ?
N9G C9G 1.463(11) . ?
C4G N3G 1.359(10) . ?
C4G C5G 1.373(10) . ?
N3G C2G 1.326(12) . ?
C6A N6A 1.324(10) . ?
C6A C5A 1.388(10) . ?
N9A C8A 1.336(12) . ?
N9A C4A 1.379(10) . ?
N9A C9A1 1.480(11) . ?
O6G C6G 1.241(10) . ?
N1G C2G 1.358(11) . ?
N1G C6G 1.394(11) . ?
C5A C4A 1.372(11) . ?
C5A N7A 1.396(10) . ?
C4A N3A 1.331(11) . ?
C5G C6G 1.397(12) . ?
C8A N7A 1.324(10) . ?
C2A N3A 1.328(11) . ?
Cl10 O11 1.366(10) . ?
Cl10 O13 1.377(11) . ?
Cl10 O12 1.419(12) . ?
Cl10 O14 1.426(13) . ?
Cl20 O24 1.360(13) . ?
Cl20 O21 1.374(8) . ?
Cl20 O23 1.396(11) . ?
Cl20 O22 1.442(14) . ?
C9A1 C9A2 1.396(15) . ?
N2G C2G 1.336(12) . ?
Cl30 O33 1.18(3) . ?
Cl30 O31 1.254(15) . ?
Cl30 O32 1.310(19) . ?
Cl30 O34 1.334(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N7A Pt2 N21 90.4(3) . . ?
N7A Pt2 N22 90.6(3) . . ?
N21 Pt2 N22 178.2(4) . . ?
N7A Pt2 Cl1 179.5(2) . . ?
N21 Pt2 Cl1 90.0(3) . . ?
N22 Pt2 Cl1 89.0(3) . . ?
N7G Pt1 N1A 175.4(3) . . ?
N7G Pt1 N11 89.3(3) . . ?
N1A Pt1 N11 90.0(3) . . ?
N7G Pt1 N12 90.9(3) . . ?
N1A Pt1 N12 89.7(3) . . ?
N11 Pt1 N12 179.0(4) . . ?
C8G N7G C5G 106.7(6) . . ?
C8G N7G Pt1 130.7(6) . . ?
C5G N7G Pt1 122.1(5) . . ?
C2A N1A C6A 121.6(7) . . ?
C2A N1A Pt1 119.2(6) . . ?
C6A N1A Pt1 119.1(5) . . ?
C8G N9G C4G 107.2(7) . . ?
C8G N9G C9G 126.0(8) . . ?
C4G N9G C9G 126.7(8) . . ?
N3G C4G N9G 126.1(7) . . ?
N3G C4G C5G 127.1(8) . . ?
N9G C4G C5G 106.7(7) . . ?
C2G N3G C4G 111.7(7) . . ?
N6A C6A N1A 120.1(7) . . ?
N6A C6A C5A 124.9(8) . . ?
N1A C6A C5A 114.9(7) . . ?
C8A N9A C4A 106.7(7) . . ?
C8A N9A C9A1 125.8(8) . . ?
C4A N9A C9A1 127.5(8) . . ?
C2G N1G C6G 124.7(8) . . ?
C4A C5A C6A 118.3(8) . . ?
C4A C5A N7A 109.2(7) . . ?
C6A C5A N7A 132.4(8) . . ?
N3A C4A C5A 127.9(7) . . ?
N3A C4A N9A 125.7(8) . . ?
C5A C4A N9A 106.4(7) . . ?
C4G C5G N7G 107.5(7) . . ?
C4G C5G C6G 120.6(8) . . ?
N7G C5G C6G 131.9(7) . . ?
O6G C6G N1G 120.3(8) . . ?
O6G C6G C5G 128.5(8) . . ?
N1G C6G C5G 111.2(7) . . ?
N7A C8A N9A 113.2(7) . . ?
N7G C8G N9G 111.8(8) . . ?
N3A C2A N1A 126.1(9) . . ?
C2A N3A C4A 111.2(8) . . ?
C8A N7A C5A 104.5(7) . . ?
C8A N7A Pt2 127.4(6) . . ?
C5A N7A Pt2 128.1(5) . . ?
O11 Cl10 O13 110.5(9) . . ?
O11 Cl10 O12 114.6(10) . . ?
O13 Cl10 O12 106.0(8) . . ?
O11 Cl10 O14 104.7(8) . . ?
O13 Cl10 O14 112.9(10) . . ?
O12 Cl10 O14 108.2(11) . . ?
O24 Cl20 O21 118.1(8) . . ?
O24 Cl20 O23 111.6(9) . . ?
O21 Cl20 O23 110.4(6) . . ?
O24 Cl20 O22 102.4(10) . . ?
O21 Cl20 O22 109.1(8) . . ?
O23 Cl20 O22 104.0(9) . . ?
C9A2 C9A1 N9A 116.1(10) . . ?
N3G C2G N2G 121.0(9) . . ?
N3G C2G N1G 124.6(8) . . ?
N2G C2G N1G 114.3(9) . . ?
O33 Cl30 O31 114.6(15) . . ?
O33 Cl30 O32 106(3) . . ?
O31 Cl30 O32 107(2) . . ?
O33 Cl30 O34 108.6(16) . . ?
O31 Cl30 O34 120.7(15) . . ?
O32 Cl30 O34 97.8(11) . . ?