# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2009

data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Cheuk-Wai So'
_publ_contact_author_email       CWSO@NTU.EDU.SG

_publ_section_title              
;
Synthesis and characterization of
[(PPh2=S)2C=Ge=C(PPh2=S)2]: novel base-stabilized 2-germaallene
;
loop_
_publ_author_name
'Cheuk-Wai So'
'Cechao Foo'
'Kai-Chung Lau'

# Attachment 'scw10o.cif'

data_scw10o
_database_code_depnum_ccdc_archive 'CCDC 735370'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C58 H56 Ge O2 P4 S4'
_chemical_formula_sum            'C58 H56 Ge O2 P4 S4'
_chemical_formula_weight         1109.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   Pccn

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-x, y+1/2, -z+1/2'
'x+1/2, -y, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'x, -y-1/2, z-1/2'
'-x-1/2, y, z-1/2'

_cell_length_a                   23.5445(9)
_cell_length_b                   11.4051(5)
_cell_length_c                   19.7011(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     5290.3(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    8755
_cell_measurement_theta_min      1.98
_cell_measurement_theta_max      30.66

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.38
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.393
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2304
_exptl_absorpt_coefficient_mu    0.901
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7145
_exptl_absorpt_correction_T_max  0.7259
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            74919
_diffrn_reflns_av_R_equivalents  0.0569
_diffrn_reflns_av_sigmaI/netI    0.0471
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.73
_diffrn_reflns_theta_max         33.29
_reflns_number_total             10186
_reflns_number_gt                7243
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0645P)^2^+0.5015P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10186
_refine_ls_number_parameters     358
_refine_ls_number_restraints     10
_refine_ls_R_factor_all          0.0714
_refine_ls_R_factor_gt           0.0379
_refine_ls_wR_factor_ref         0.1260
_refine_ls_wR_factor_gt          0.0978
_refine_ls_goodness_of_fit_ref   1.120
_refine_ls_restrained_S_all      1.120
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C26 C 0.9340(3) 0.2399(10) 0.3281(7) 0.080(3) Uani 0.671(16) 1 d PD A 1
H26A H 0.9628 0.2631 0.2940 0.096 Uiso 0.671(16) 1 calc PR A 1
H26B H 0.9442 0.1615 0.3459 0.096 Uiso 0.671(16) 1 calc PR A 1
C27 C 0.9327(2) 0.3270(5) 0.3845(2) 0.0356(14) Uani 0.671(16) 1 d PD A 1
H27A H 0.9691 0.3699 0.3881 0.043 Uiso 0.671(16) 1 calc PR A 1
H27B H 0.9243 0.2888 0.4285 0.043 Uiso 0.671(16) 1 calc PR A 1
C28 C 0.8852(4) 0.4069(6) 0.3631(6) 0.049(2) Uani 0.671(16) 1 d PD A 1
H28A H 0.8989 0.4687 0.3318 0.058 Uiso 0.671(16) 1 calc PR A 1
H28B H 0.8668 0.4442 0.4028 0.058 Uiso 0.671(16) 1 calc PR A 1
C29 C 0.8455(4) 0.3234(8) 0.3279(6) 0.068(3) Uani 0.671(16) 1 d PD A 1
H29A H 0.8189 0.2878 0.3609 0.082 Uiso 0.671(16) 1 calc PR A 1
H29B H 0.8231 0.3650 0.2928 0.082 Uiso 0.671(16) 1 calc PR A 1
O1 O 0.8797(2) 0.2364(5) 0.2979(5) 0.066(2) Uani 0.671(16) 1 d PD A 1
C26A C 0.9231(6) 0.2097(15) 0.3480(14) 0.081(7) Uani 0.329(16) 1 d PD A 2
H26C H 0.9456 0.1907 0.3070 0.098 Uiso 0.329(16) 1 calc PR A 2
H26D H 0.9306 0.1496 0.3831 0.098 Uiso 0.329(16) 1 calc PR A 2
C27A C 0.9376(7) 0.3259(14) 0.3731(16) 0.144(12) Uani 0.329(16) 1 d PD A 2
H27C H 0.9745 0.3512 0.3540 0.172 Uiso 0.329(16) 1 calc PR A 2
H27D H 0.9409 0.3244 0.4232 0.172 Uiso 0.329(16) 1 calc PR A 2
C28A C 0.8920(7) 0.4091(13) 0.3523(12) 0.050(5) Uani 0.329(16) 1 d PD A 2
H28C H 0.9048 0.4596 0.3144 0.060 Uiso 0.329(16) 1 calc PR A 2
H28D H 0.8802 0.4594 0.3908 0.060 Uiso 0.329(16) 1 calc PR A 2
C29A C 0.8442(4) 0.3297(9) 0.3302(8) 0.027(3) Uani 0.329(16) 1 d PD A 2
H29C H 0.8113 0.3381 0.3612 0.032 Uiso 0.329(16) 1 calc PR A 2
H29D H 0.8319 0.3497 0.2836 0.032 Uiso 0.329(16) 1 calc PR A 2
O1A O 0.8655(5) 0.2138(7) 0.3325(6) 0.054(2) Uani 0.329(16) 1 d PD A 2
Ge1 Ge 0.2500 0.2500 0.429745(12) 0.01514(7) Uani 1 2 d S . .
C1 C 0.17708(7) 0.20801(15) 0.39914(8) 0.0166(3) Uani 1 1 d . . .
C2 C 0.20778(9) 0.1163(2) 0.22902(10) 0.0337(5) Uani 1 1 d . . .
H2 H 0.1780 0.1698 0.2192 0.040 Uiso 1 1 calc R . .
C3 C 0.24970(11) 0.0947(3) 0.18103(11) 0.0424(6) Uani 1 1 d . . .
H3 H 0.2489 0.1351 0.1389 0.051 Uiso 1 1 calc R . .
C4 C 0.29219(10) 0.0156(2) 0.19397(11) 0.0400(5) Uani 1 1 d . . .
H4 H 0.3202 -0.0001 0.1604 0.048 Uiso 1 1 calc R . .
C5 C 0.29429(9) -0.0410(2) 0.25556(12) 0.0381(5) Uani 1 1 d . . .
H5 H 0.3238 -0.0956 0.2647 0.046 Uiso 1 1 calc R . .
C6 C 0.25318(8) -0.0180(2) 0.30454(10) 0.0290(4) Uani 1 1 d . . .
H6 H 0.2552 -0.0560 0.3474 0.035 Uiso 1 1 calc R . .
C7 C 0.20950(7) 0.05956(16) 0.29133(9) 0.0207(3) Uani 1 1 d . . .
C8 C 0.15522(7) -0.04425(16) 0.40456(9) 0.0217(3) Uani 1 1 d . . .
C9 C 0.14457(9) -0.15225(18) 0.37339(11) 0.0318(4) Uani 1 1 d . . .
H9 H 0.1326 -0.1548 0.3274 0.038 Uiso 1 1 calc R . .
C10 C 0.15144(11) -0.25530(18) 0.40936(14) 0.0393(5) Uani 1 1 d . . .
H10 H 0.1449 -0.3286 0.3878 0.047 Uiso 1 1 calc R . .
C11 C 0.16780(12) -0.2515(2) 0.47679(14) 0.0457(6) Uani 1 1 d . . .
H11 H 0.1734 -0.3225 0.5012 0.055 Uiso 1 1 calc R . .
C12 C 0.17600(12) -0.1455(2) 0.50877(12) 0.0436(6) Uani 1 1 d . . .
H12 H 0.1858 -0.1433 0.5555 0.052 Uiso 1 1 calc R . .
C13 C 0.16986(9) -0.04178(18) 0.47266(10) 0.0289(4) Uani 1 1 d . . .
H13 H 0.1757 0.0313 0.4947 0.035 Uiso 1 1 calc R . .
C14 C 0.09211(7) 0.23771(14) 0.51264(9) 0.0202(3) Uani 1 1 d . . .
C15 C 0.04159(8) 0.18408(18) 0.49299(10) 0.0279(4) Uani 1 1 d . . .
H15 H 0.0307 0.1835 0.4465 0.034 Uiso 1 1 calc R . .
C16 C 0.00715(9) 0.13148(18) 0.54133(11) 0.0335(5) Uani 1 1 d . . .
H16 H -0.0274 0.0953 0.5278 0.040 Uiso 1 1 calc R . .
C17 C 0.02269(10) 0.13128(19) 0.60882(12) 0.0382(5) Uani 1 1 d . . .
H17 H -0.0010 0.0946 0.6416 0.046 Uiso 1 1 calc R . .
C18 C 0.07281(10) 0.1846(2) 0.62861(11) 0.0393(5) Uani 1 1 d . . .
H18 H 0.0836 0.1847 0.6751 0.047 Uiso 1 1 calc R . .
C19 C 0.10728(9) 0.23778(18) 0.58077(10) 0.0305(4) Uani 1 1 d . . .
H19 H 0.1416 0.2746 0.5946 0.037 Uiso 1 1 calc R . .
C20 C 0.09369(7) 0.40675(14) 0.40397(9) 0.0188(3) Uani 1 1 d . . .
C21 C 0.06129(8) 0.48640(16) 0.44094(9) 0.0239(4) Uani 1 1 d . . .
H21 H 0.0609 0.4830 0.4891 0.029 Uiso 1 1 calc R . .
C22 C 0.02965(8) 0.57051(17) 0.40735(11) 0.0289(4) Uani 1 1 d . . .
H22 H 0.0079 0.6256 0.4325 0.035 Uiso 1 1 calc R . .
C23 C 0.02963(9) 0.57456(18) 0.33735(11) 0.0305(4) Uani 1 1 d . . .
H23 H 0.0074 0.6317 0.3144 0.037 Uiso 1 1 calc R . .
C24 C 0.06184(10) 0.4958(2) 0.30044(11) 0.0353(5) Uani 1 1 d . . .
H24 H 0.0617 0.4990 0.2523 0.042 Uiso 1 1 calc R . .
C25 C 0.09424(9) 0.41249(18) 0.33358(10) 0.0278(4) Uani 1 1 d . . .
H25 H 0.1169 0.3592 0.3082 0.033 Uiso 1 1 calc R . .
P1 P 0.153461(18) 0.08707(4) 0.35264(2) 0.01743(10) Uani 1 1 d . . .
P2 P 0.137357(18) 0.30236(4) 0.44827(2) 0.01634(9) Uani 1 1 d . . .
S1 S 0.078545(19) 0.10801(5) 0.31048(3) 0.02914(12) Uani 1 1 d . . .
S2 S 0.203243(18) 0.39118(4) 0.49398(2) 0.02161(10) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C26 0.038(3) 0.084(6) 0.120(7) -0.060(5) -0.030(4) 0.017(4)
C27 0.032(2) 0.043(3) 0.032(2) -0.0073(18) -0.0053(16) -0.009(2)
C28 0.071(4) 0.034(3) 0.040(3) 0.001(3) 0.012(3) 0.011(3)
C29 0.054(6) 0.076(8) 0.073(8) 0.022(6) -0.012(5) 0.013(5)
O1 0.047(2) 0.058(3) 0.092(5) -0.036(3) -0.028(3) 0.0058(18)
C26A 0.048(7) 0.057(8) 0.139(16) -0.050(9) 0.017(8) -0.012(6)
C27A 0.040(9) 0.048(11) 0.34(4) 0.021(15) -0.043(13) -0.010(7)
C28A 0.054(7) 0.046(8) 0.050(9) 0.017(6) -0.020(7) -0.029(6)
C29A 0.019(6) 0.027(6) 0.035(7) 0.014(5) -0.011(5) -0.007(5)
O1A 0.062(5) 0.052(4) 0.047(5) -0.004(3) -0.011(4) -0.019(4)
Ge1 0.01213(11) 0.01609(13) 0.01720(12) 0.000 0.000 -0.00016(8)
C1 0.0125(7) 0.0175(7) 0.0199(8) -0.0034(6) 0.0004(6) 0.0006(6)
C2 0.0375(11) 0.0360(11) 0.0276(10) 0.0014(9) 0.0038(8) 0.0062(9)
C3 0.0526(15) 0.0510(16) 0.0236(10) 0.0012(10) 0.0121(10) -0.0019(11)
C4 0.0343(11) 0.0527(15) 0.0329(11) -0.0162(10) 0.0137(9) -0.0044(10)
C5 0.0247(10) 0.0498(14) 0.0399(12) -0.0131(10) 0.0043(8) 0.0089(9)
C6 0.0227(9) 0.0378(12) 0.0265(9) -0.0048(8) 0.0009(7) 0.0057(8)
C7 0.0192(8) 0.0234(9) 0.0195(8) -0.0074(7) 0.0008(6) -0.0017(6)
C8 0.0199(8) 0.0206(8) 0.0245(8) -0.0025(7) 0.0040(6) -0.0049(6)
C9 0.0348(10) 0.0254(10) 0.0352(10) -0.0059(9) 0.0051(8) -0.0076(8)
C10 0.0455(13) 0.0219(10) 0.0505(14) -0.0045(9) 0.0134(11) -0.0091(9)
C11 0.0651(17) 0.0241(11) 0.0480(14) 0.0113(10) 0.0107(13) -0.0015(11)
C12 0.0646(16) 0.0331(12) 0.0330(11) 0.0084(10) 0.0010(11) -0.0075(12)
C13 0.0366(10) 0.0238(10) 0.0263(9) 0.0009(8) 0.0031(8) -0.0043(8)
C14 0.0179(7) 0.0174(8) 0.0255(8) 0.0010(7) 0.0058(6) 0.0026(6)
C15 0.0255(9) 0.0274(10) 0.0310(10) -0.0059(8) 0.0074(7) -0.0054(7)
C16 0.0278(10) 0.0254(10) 0.0473(12) -0.0067(9) 0.0156(9) -0.0066(8)
C17 0.0407(12) 0.0281(11) 0.0459(13) 0.0128(10) 0.0209(10) 0.0028(9)
C18 0.0376(12) 0.0506(14) 0.0298(11) 0.0169(10) 0.0065(9) 0.0028(10)
C19 0.0250(9) 0.0383(12) 0.0283(10) 0.0106(8) 0.0015(7) 0.0009(8)
C20 0.0153(7) 0.0175(8) 0.0236(8) -0.0012(6) 0.0022(6) 0.0011(6)
C21 0.0245(9) 0.0213(9) 0.0258(9) -0.0010(7) 0.0053(7) 0.0029(7)
C22 0.0281(9) 0.0210(9) 0.0376(10) 0.0003(8) 0.0069(8) 0.0073(7)
C23 0.0306(10) 0.0242(10) 0.0366(11) 0.0049(8) -0.0040(8) 0.0064(8)
C24 0.0474(13) 0.0320(11) 0.0264(9) 0.0019(9) -0.0041(9) 0.0120(10)
C25 0.0340(10) 0.0255(10) 0.0240(9) -0.0023(7) 0.0018(8) 0.0092(8)
P1 0.01439(18) 0.0189(2) 0.0190(2) -0.00365(16) -0.00038(15) -0.00066(15)
P2 0.01354(18) 0.0168(2) 0.0187(2) -0.00112(16) 0.00222(14) 0.00095(15)
S1 0.0173(2) 0.0357(3) 0.0345(3) -0.0054(2) -0.00735(17) -0.00066(18)
S2 0.01875(19) 0.0221(2) 0.0240(2) -0.00803(17) 0.00147(15) -0.00179(16)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C26 O1 1.411(6) . ?
C26 C27 1.491(8) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.504(7) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 C29 1.505(9) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 O1 1.409(9) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C26A O1A 1.389(13) . ?
C26A C27A 1.455(14) . ?
C26A H26C 0.9900 . ?
C26A H26D 0.9900 . ?
C27A C28A 1.491(13) . ?
C27A H27C 0.9900 . ?
C27A H27D 0.9900 . ?
C28A C29A 1.509(11) . ?
C28A H28C 0.9900 . ?
C28A H28D 0.9900 . ?
C29A O1A 1.415(11) . ?
C29A H29C 0.9900 . ?
C29A H29D 0.9900 . ?
Ge1 C1 1.8817(16) . ?
Ge1 C1 1.8817(16) 2 ?
Ge1 S2 2.3251(4) 2 ?
Ge1 S2 2.3251(4) . ?
Ge1 P2 2.7429(4) 2 ?
Ge1 P2 2.7429(4) . ?
C1 P2 1.7232(16) . ?
C1 P1 1.7467(17) . ?
C2 C7 1.388(3) . ?
C2 C3 1.389(3) . ?
C2 H2 0.9500 . ?
C3 C4 1.371(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.375(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.392(3) . ?
C5 H5 0.9500 . ?
C6 C7 1.381(3) . ?
C6 H6 0.9500 . ?
C7 P1 1.8161(17) . ?
C8 C13 1.386(3) . ?
C8 C9 1.399(3) . ?
C8 P1 1.8141(19) . ?
C9 C10 1.382(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.384(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.377(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.388(3) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C19 1.389(3) . ?
C14 C15 1.392(3) . ?
C14 P2 1.8129(18) . ?
C15 C16 1.387(3) . ?
C15 H15 0.9500 . ?
C16 C17 1.379(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.384(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.384(3) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C25 1.388(3) . ?
C20 C21 1.392(2) . ?
C20 P2 1.7990(17) . ?
C21 C22 1.383(3) . ?
C21 H21 0.9500 . ?
C22 C23 1.380(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.382(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.383(3) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
P1 S1 1.9642(6) . ?
P2 S2 2.0600(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C26 C27 108.3(5) . . ?
O1 C26 H26A 110.0 . . ?
C27 C26 H26A 110.0 . . ?
O1 C26 H26B 110.0 . . ?
C27 C26 H26B 110.0 . . ?
H26A C26 H26B 108.4 . . ?
C26 C27 C28 102.1(5) . . ?
C26 C27 H27A 111.3 . . ?
C28 C27 H27A 111.3 . . ?
C26 C27 H27B 111.3 . . ?
C28 C27 H27B 111.3 . . ?
H27A C27 H27B 109.2 . . ?
C27 C28 C29 102.0(5) . . ?
C27 C28 H28A 111.4 . . ?
C29 C28 H28A 111.4 . . ?
C27 C28 H28B 111.4 . . ?
C29 C28 H28B 111.4 . . ?
H28A C28 H28B 109.2 . . ?
O1 C29 C28 106.5(6) . . ?
O1 C29 H29A 110.4 . . ?
C28 C29 H29A 110.4 . . ?
O1 C29 H29B 110.4 . . ?
C28 C29 H29B 110.4 . . ?
H29A C29 H29B 108.6 . . ?
C29 O1 C26 108.8(5) . . ?
O1A C26A C27A 105.9(11) . . ?
O1A C26A H26C 110.6 . . ?
C27A C26A H26C 110.6 . . ?
O1A C26A H26D 110.6 . . ?
C27A C26A H26D 110.6 . . ?
H26C C26A H26D 108.7 . . ?
C26A C27A C28A 108.4(12) . . ?
C26A C27A H27C 110.0 . . ?
C28A C27A H27C 110.0 . . ?
C26A C27A H27D 110.0 . . ?
C28A C27A H27D 110.0 . . ?
H27C C27A H27D 108.4 . . ?
C27A C28A C29A 103.6(10) . . ?
C27A C28A H28C 111.0 . . ?
C29A C28A H28C 111.0 . . ?
C27A C28A H28D 111.0 . . ?
C29A C28A H28D 111.0 . . ?
H28C C28A H28D 109.0 . . ?
O1A C29A C28A 106.6(9) . . ?
O1A C29A H29C 110.4 . . ?
C28A C29A H29C 110.4 . . ?
O1A C29A H29D 110.4 . . ?
C28A C29A H29D 110.4 . . ?
H29C C29A H29D 108.6 . . ?
C26A O1A C29A 112.6(9) . . ?
C1 Ge1 C1 142.62(10) . 2 ?
C1 Ge1 S2 115.48(5) . 2 ?
C1 Ge1 S2 85.33(5) 2 2 ?
C1 Ge1 S2 85.33(5) . . ?
C1 Ge1 S2 115.48(5) 2 . ?
S2 Ge1 S2 114.05(3) 2 . ?
C1 Ge1 P2 150.40(5) . 2 ?
C1 Ge1 P2 38.35(5) 2 2 ?
S2 Ge1 P2 47.079(14) 2 2 ?
S2 Ge1 P2 122.422(16) . 2 ?
C1 Ge1 P2 38.35(5) . . ?
C1 Ge1 P2 150.40(5) 2 . ?
S2 Ge1 P2 122.422(16) 2 . ?
S2 Ge1 P2 47.079(14) . . ?
P2 Ge1 P2 164.71(2) 2 . ?
P2 C1 P1 127.95(9) . . ?
P2 C1 Ge1 98.99(8) . . ?
P1 C1 Ge1 131.26(9) . . ?
C7 C2 C3 119.9(2) . . ?
C7 C2 H2 120.0 . . ?
C3 C2 H2 120.0 . . ?
C4 C3 C2 120.6(2) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C3 C4 C5 119.93(19) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 119.9(2) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C7 C6 C5 120.5(2) . . ?
C7 C6 H6 119.7 . . ?
C5 C6 H6 119.7 . . ?
C6 C7 C2 119.13(17) . . ?
C6 C7 P1 121.75(15) . . ?
C2 C7 P1 119.11(14) . . ?
C13 C8 C9 119.18(18) . . ?
C13 C8 P1 122.34(14) . . ?
C9 C8 P1 118.38(15) . . ?
C10 C9 C8 120.2(2) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 119.9(2) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 H10 120.1 . . ?
C12 C11 C10 120.4(2) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C11 C12 C13 120.0(2) . . ?
C11 C12 H12 120.0 . . ?
C13 C12 H12 120.0 . . ?
C8 C13 C12 120.33(19) . . ?
C8 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C19 C14 C15 119.25(17) . . ?
C19 C14 P2 121.64(15) . . ?
C15 C14 P2 119.09(14) . . ?
C16 C15 C14 119.90(19) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C17 C16 C15 120.50(19) . . ?
C17 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
C16 C17 C18 119.81(19) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C17 C18 C19 120.1(2) . . ?
C17 C18 H18 120.0 . . ?
C19 C18 H18 120.0 . . ?
C18 C19 C14 120.5(2) . . ?
C18 C19 H19 119.8 . . ?
C14 C19 H19 119.8 . . ?
C25 C20 C21 119.81(16) . . ?
C25 C20 P2 120.69(13) . . ?
C21 C20 P2 119.42(14) . . ?
C22 C21 C20 119.83(17) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?
C23 C22 C21 120.11(17) . . ?
C23 C22 H22 119.9 . . ?
C21 C22 H22 119.9 . . ?
C22 C23 C24 120.25(18) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 H23 119.9 . . ?
C23 C24 C25 120.07(19) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C24 C25 C20 119.93(18) . . ?
C24 C25 H25 120.0 . . ?
C20 C25 H25 120.0 . . ?
C1 P1 C8 110.42(8) . . ?
C1 P1 C7 104.71(8) . . ?
C8 P1 C7 102.46(8) . . ?
C1 P1 S1 114.31(6) . . ?
C8 P1 S1 111.05(6) . . ?
C7 P1 S1 113.09(6) . . ?
C1 P2 C20 116.81(8) . . ?
C1 P2 C14 117.25(8) . . ?
C20 P2 C14 105.82(8) . . ?
C1 P2 S2 98.28(6) . . ?
C20 P2 S2 108.48(6) . . ?
C14 P2 S2 109.68(6) . . ?
C1 P2 Ge1 42.65(5) . . ?
C20 P2 Ge1 129.21(6) . . ?
C14 P2 Ge1 124.94(6) . . ?
S2 P2 Ge1 55.744(16) . . ?
P2 S2 Ge1 77.177(18) . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        33.29
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         0.643
_refine_diff_density_min         -0.905
_refine_diff_density_rms         0.201