# Electronic Supplementary Material for CrystEngComm
# This journal is (c) The Royal Society of Chemistry 2009

data_global
_journal_name_full               CrystEngComm
_journal_coden_cambridge         1350

_publ_section_title              
;
Metal-directed assembly of two 2-D 4d-4f coordination
polymers based on elliptical triple-decked cylinders hinged by meso-double
helical chains
;
_publ_contact_author_name        'Yue-Peng Cai'
_publ_contact_author_email       YPCAI8@YAHOO.COM
loop_
_publ_author_name
'Yue-Peng Cai'
'Li Chen'
'Hua-Cai Fang'
'Zuo-Jun Hu'
'Cheng-Yong Su'
'Ning Wang'
'Qiong-Yan Yu'
'Qing-Guang Zhan'
'Zheng-Yuan Zhou'

data_ca
_database_code_depnum_ccdc_archive 'CCDC 703239'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H20 Ag2 N4 O10 Sm, N O3, H2 O'
_chemical_formula_sum            'C24 H22 Ag2 N5 O14 Sm'
_chemical_formula_weight         970.56

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.9103(5)
_cell_length_b                   24.7509(7)
_cell_length_c                   6.7730(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.0820(10)
_cell_angle_gamma                90.00
_cell_volume                     2818.85(14)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    8646
_cell_measurement_theta_min      2.75
_cell_measurement_theta_max      31.72

_exptl_crystal_description       block
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.287
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1876
_exptl_absorpt_coefficient_mu    3.514
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4619
_exptl_absorpt_correction_T_max  0.5865
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            15991
_diffrn_reflns_av_R_equivalents  0.0243
_diffrn_reflns_av_sigmaI/netI    0.0250
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         2.75
_diffrn_reflns_theta_max         25.50
_reflns_number_total             5241
_reflns_number_gt                4770
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.Two Hydrogen atoms of each
water molecule were restrained in idealized positions and isotropically
refined with the O-H and H...H distances restrained to 0.84(1)Å and
1.43(2Å), respectively, and Uiso values were set equal to 1.5Ueq
(parent atom) for water H atoms.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0180P)²+3.9464P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00080(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         5241
_refine_ls_number_parameters     434
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.0257
_refine_ls_R_factor_gt           0.0222
_refine_ls_wR_factor_ref         0.0494
_refine_ls_wR_factor_gt          0.0480
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_restrained_S_all      1.020
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sm1 Sm 0.230021(8) 0.662845(6) 0.88302(2) 0.01895(6) Uani 1 1 d . . .
Ag1 Ag -0.271295(14) 0.771026(13) 1.00955(5) 0.04507(9) Uani 1 1 d . . .
Ag2 Ag 0.734923(16) 0.509695(14) 1.09832(5) 0.04918(10) Uani 1 1 d . . .
O1 O 0.32652(12) 0.68519(10) 0.6616(3) 0.0317(5) Uani 1 1 d . . .
O2 O 0.31431(13) 0.76980(10) 0.5521(4) 0.0409(6) Uani 1 1 d . . .
O3 O 0.13896(13) 0.73026(10) 0.9546(4) 0.0403(6) Uani 1 1 d . . .
O4 O 0.14713(12) 0.81387(9) 1.0717(3) 0.0280(5) Uani 1 1 d . . .
O5 O 0.08704(13) 0.55764(10) 0.6254(3) 0.0368(6) Uani 1 1 d . . .
O6 O 0.11529(13) 0.60775(9) 0.8977(3) 0.0326(5) Uani 1 1 d . . .
O7 O 0.33362(15) 0.60435(11) 1.0261(4) 0.0441(7) Uani 1 1 d . . .
O8 O 0.34810(14) 0.58444(11) 1.3481(4) 0.0418(6) Uani 1 1 d . . .
O9 O 0.24100(13) 0.58038(9) 0.6658(3) 0.0305(5) Uani 1 1 d D . .
H9A H 0.1937(9) 0.5698(15) 0.638(5) 0.046 Uiso 1 1 d D . .
H9B H 0.2704(14) 0.5782(16) 0.574(4) 0.046 Uiso 1 1 d D . .
O10 O 0.21625(15) 0.64812(12) 1.2354(4) 0.0429(6) Uani 1 1 d D . .
H10A H 0.2574(16) 0.6314(15) 1.281(5) 0.064 Uiso 1 1 d D . .
H10B H 0.193(2) 0.6655(16) 1.318(4) 0.064 Uiso 1 1 d D . .
O11 O 0.70060(18) 0.54847(16) 0.6744(5) 0.0749(11) Uani 1 1 d . . .
O12 O 0.7411(3) 0.62969(17) 0.7003(6) 0.0878(12) Uani 1 1 d . . .
O13 O 0.7588(2) 0.58393(19) 0.4410(5) 0.0920(14) Uani 1 1 d . . .
O1W O 0.7287(2) 0.65691(12) 0.0951(6) 0.0713(10) Uani 1 1 d D . .
H1WA H 0.735(4) 0.6352(16) 0.190(4) 0.107 Uiso 1 1 d D . .
H1WB H 0.727(4) 0.6441(19) -0.020(3) 0.107 Uiso 1 1 d D . .
N1 N 0.60160(15) 0.72802(12) 0.5170(4) 0.0321(7) Uani 1 1 d . . .
N2 N -0.14430(15) 0.77196(12) 1.0002(4) 0.0320(7) Uani 1 1 d . . .
N3 N -0.14873(15) 0.52859(11) 1.0008(4) 0.0318(6) Uani 1 1 d . . .
N4 N 0.61218(15) 0.53665(12) 1.1249(4) 0.0336(7) Uani 1 1 d . . .
N5 N 0.73282(19) 0.58666(18) 0.6024(6) 0.0543(10) Uani 1 1 d . . .
C1 C 0.35210(17) 0.72738(13) 0.5901(5) 0.0237(7) Uani 1 1 d . . .
C2 C 0.43924(17) 0.72748(13) 0.5559(4) 0.0220(6) Uani 1 1 d . . .
C3 C 0.47977(18) 0.77531(13) 0.5418(5) 0.0262(7) Uani 1 1 d . . .
H3 H 0.4530 0.8081 0.5436 0.031 Uiso 1 1 calc R . .
C4 C 0.56078(18) 0.77434(14) 0.5251(5) 0.0298(7) Uani 1 1 d . . .
H4 H 0.5878 0.8069 0.5193 0.036 Uiso 1 1 calc R . .
C5 C 0.56096(19) 0.68153(14) 0.5242(5) 0.0330(8) Uani 1 1 d . . .
H5 H 0.5881 0.6491 0.5150 0.040 Uiso 1 1 calc R . .
C6 C 0.48092(18) 0.67986(14) 0.5446(5) 0.0284(7) Uani 1 1 d . . .
H6 H 0.4551 0.6468 0.5508 0.034 Uiso 1 1 calc R . .
C7 C 0.10956(16) 0.77216(12) 1.0140(4) 0.0207(6) Uani 1 1 d . . .
C8 C 0.01993(16) 0.77289(12) 1.0085(4) 0.0207(6) Uani 1 1 d . . .
C9 C -0.02195(18) 0.82070(13) 1.0110(5) 0.0261(7) Uani 1 1 d . . .
H9 H 0.0045 0.8537 1.0164 0.031 Uiso 1 1 calc R . .
C10 C -0.10360(18) 0.81886(14) 1.0054(5) 0.0324(8) Uani 1 1 d . . .
H10 H -0.1317 0.8512 1.0052 0.039 Uiso 1 1 calc R . .
C11 C -0.10294(19) 0.72586(14) 0.9967(5) 0.0325(8) Uani 1 1 d . . .
H11 H -0.1304 0.6933 0.9923 0.039 Uiso 1 1 calc R . .
C12 C -0.02150(18) 0.72474(13) 0.9993(5) 0.0266(7) Uani 1 1 d . . .
H12 H 0.0053 0.6920 0.9949 0.032 Uiso 1 1 calc R . .
C13 C 0.07153(18) 0.57657(13) 0.7856(5) 0.0256(7) Uani 1 1 d . . .
C14 C -0.00722(17) 0.56155(12) 0.8594(5) 0.0250(7) Uani 1 1 d . . .
C15 C -0.06132(18) 0.52924(14) 0.7453(5) 0.0300(7) Uani 1 1 d . . .
H15 H -0.0513 0.5182 0.6190 0.036 Uiso 1 1 calc R . .
C16 C -0.13011(19) 0.51373(14) 0.8221(6) 0.0352(8) Uani 1 1 d . . .
H16 H -0.1656 0.4916 0.7449 0.042 Uiso 1 1 calc R . .
C17 C -0.09638(19) 0.56006(14) 1.1102(5) 0.0327(8) Uani 1 1 d . . .
H17 H -0.1082 0.5709 1.2352 0.039 Uiso 1 1 calc R . .
C18 C -0.02580(19) 0.57700(13) 1.0453(5) 0.0286(7) Uani 1 1 d . . .
H18 H 0.0090 0.5987 1.1260 0.034 Uiso 1 1 calc R . .
C19 C 0.37240(18) 0.58818(13) 1.1834(5) 0.0274(7) Uani 1 1 d . . .
C20 C 0.45760(18) 0.57168(12) 1.1643(5) 0.0244(7) Uani 1 1 d . . .
C21 C 0.4901(2) 0.57659(14) 0.9857(5) 0.0318(8) Uani 1 1 d . . .
H21 H 0.4604 0.5914 0.8756 0.038 Uiso 1 1 calc R . .
C22 C 0.5671(2) 0.55923(14) 0.9727(5) 0.0353(8) Uani 1 1 d . . .
H22 H 0.5885 0.5635 0.8527 0.042 Uiso 1 1 calc R . .
C23 C 0.58087(19) 0.53228(14) 1.2976(5) 0.0329(8) Uani 1 1 d . . .
H23 H 0.6115 0.5169 1.4052 0.039 Uiso 1 1 calc R . .
C24 C 0.50498(19) 0.54962(13) 1.3225(5) 0.0294(7) Uani 1 1 d . . .
H24 H 0.4858 0.5464 1.4457 0.035 Uiso 1 1 calc R . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sm1 O3 2.356(2) . ?
Sm1 O6 2.382(2) . ?
Sm1 O1 2.395(2) . ?
Sm1 O7 2.397(2) . ?
Sm1 O2 2.403(2) 4_576 ?
Sm1 O10 2.450(2) . ?
Sm1 O4 2.473(2) 4_575 ?
Sm1 O9 2.534(2) . ?
Ag1 N2 2.155(2) . ?
Ag1 N1 2.155(2) 4_476 ?
Ag2 N3 2.191(3) 1_655 ?
Ag2 N4 2.206(3) . ?
O1 C1 1.248(4) . ?
O2 C1 1.242(4) . ?
O2 Sm1 2.403(2) 4_575 ?
O3 C7 1.236(4) . ?
O4 C7 1.253(4) . ?
O4 Sm1 2.473(2) 4_576 ?
O5 C13 1.235(4) . ?
O6 C13 1.265(4) . ?
O7 C19 1.256(4) . ?
O8 C19 1.232(4) . ?
O9 H9A 0.844(10) . ?
O9 H9B 0.840(10) . ?
O10 H10A 0.841(10) . ?
O10 H10B 0.840(10) . ?
O11 N5 1.219(5) . ?
O12 N5 1.254(5) . ?
O13 N5 1.222(5) . ?
O1W H1WA 0.834(10) . ?
O1W H1WB 0.838(10) . ?
N1 C4 1.343(4) . ?
N1 C5 1.344(4) . ?
N1 Ag1 2.155(2) 4_675 ?
N2 C11 1.340(4) . ?
N2 C10 1.348(4) . ?
N3 C16 1.334(5) . ?
N3 C17 1.342(4) . ?
N3 Ag2 2.191(3) 1_455 ?
N4 C22 1.338(4) . ?
N4 C23 1.338(5) . ?
C1 C2 1.516(4) . ?
C2 C3 1.376(4) . ?
C2 C6 1.380(4) . ?
C3 C4 1.387(4) . ?
C3 H3 0.9300 . ?
C4 H4 0.9300 . ?
C5 C6 1.376(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.512(4) . ?
C8 C9 1.380(4) . ?
C8 C12 1.381(4) . ?
C9 C10 1.378(4) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.376(4) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.517(4) . ?
C14 C18 1.383(5) . ?
C14 C15 1.387(4) . ?
C15 C16 1.378(5) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 C18 1.380(4) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.516(4) . ?
C20 C24 1.381(4) . ?
C20 C21 1.386(5) . ?
C21 C22 1.383(5) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.380(4) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Sm1 O6 81.02(8) . . ?
O3 Sm1 O1 117.96(9) . . ?
O6 Sm1 O1 140.38(8) . . ?
O3 Sm1 O7 144.15(9) . . ?
O6 Sm1 O7 101.59(9) . . ?
O1 Sm1 O7 82.83(9) . . ?
O3 Sm1 O2 77.19(8) . 4_576 ?
O6 Sm1 O2 145.26(8) . 4_576 ?
O1 Sm1 O2 74.28(8) . 4_576 ?
O7 Sm1 O2 81.67(9) . 4_576 ?
O3 Sm1 O10 76.89(9) . . ?
O6 Sm1 O10 73.28(9) . . ?
O1 Sm1 O10 141.79(8) . . ?
O7 Sm1 O10 69.95(8) . . ?
O2 Sm1 O10 75.63(10) 4_576 . ?
O3 Sm1 O4 71.74(8) . 4_575 ?
O6 Sm1 O4 77.20(8) . 4_575 ?
O1 Sm1 O4 76.97(7) . 4_575 ?
O7 Sm1 O4 144.03(8) . 4_575 ?
O2 Sm1 O4 119.90(8) 4_576 4_575 ?
O10 Sm1 O4 139.60(8) . 4_575 ?
O3 Sm1 O9 141.23(8) . . ?
O6 Sm1 O9 70.93(7) . . ?
O1 Sm1 O9 74.09(8) . . ?
O7 Sm1 O9 69.68(8) . . ?
O2 Sm1 O9 139.37(8) 4_576 . ?
O10 Sm1 O9 117.78(9) . . ?
O4 Sm1 O9 76.26(7) 4_575 . ?
N2 Ag1 N1 178.71(11) . 4_476 ?
N3 Ag2 N4 147.44(11) 1_655 . ?
C1 O1 Sm1 136.4(2) . . ?
C1 O2 Sm1 162.1(2) . 4_575 ?
C7 O3 Sm1 162.9(2) . . ?
C7 O4 Sm1 132.9(2) . 4_576 ?
C13 O6 Sm1 138.7(2) . . ?
C19 O7 Sm1 146.0(2) . . ?
Sm1 O9 H9A 105(2) . . ?
Sm1 O9 H9B 125(3) . . ?
H9A O9 H9B 115.8(15) . . ?
Sm1 O10 H10A 106(3) . . ?
Sm1 O10 H10B 132(3) . . ?
H10A O10 H10B 116.2(15) . . ?
H1WA O1W H1WB 117.2(16) . . ?
C4 N1 C5 117.6(3) . . ?
C4 N1 Ag1 120.7(2) . 4_675 ?
C5 N1 Ag1 121.7(2) . 4_675 ?
C11 N2 C10 117.9(3) . . ?
C11 N2 Ag1 121.0(2) . . ?
C10 N2 Ag1 121.1(2) . . ?
C16 N3 C17 117.1(3) . . ?
C16 N3 Ag2 121.4(2) . 1_455 ?
C17 N3 Ag2 121.2(2) . 1_455 ?
C22 N4 C23 117.5(3) . . ?
C22 N4 Ag2 121.8(2) . . ?
C23 N4 Ag2 120.7(2) . . ?
O11 N5 O13 122.2(5) . . ?
O11 N5 O12 118.5(4) . . ?
O13 N5 O12 119.3(4) . . ?
O2 C1 O1 126.6(3) . . ?
O2 C1 C2 117.0(3) . . ?
O1 C1 C2 116.3(3) . . ?
C3 C2 C6 118.0(3) . . ?
C3 C2 C1 120.8(3) . . ?
C6 C2 C1 121.2(3) . . ?
C2 C3 C4 119.6(3) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
N1 C4 C3 122.3(3) . . ?
N1 C4 H4 118.8 . . ?
C3 C4 H4 118.8 . . ?
N1 C5 C6 122.8(3) . . ?
N1 C5 H5 118.6 . . ?
C6 C5 H5 118.6 . . ?
C5 C6 C2 119.6(3) . . ?
C5 C6 H6 120.2 . . ?
C2 C6 H6 120.2 . . ?
O3 C7 O4 125.8(3) . . ?
O3 C7 C8 116.0(3) . . ?
O4 C7 C8 118.1(3) . . ?
C9 C8 C12 118.8(3) . . ?
C9 C8 C7 121.6(3) . . ?
C12 C8 C7 119.6(3) . . ?
C10 C9 C8 119.0(3) . . ?
C10 C9 H9 120.5 . . ?
C8 C9 H9 120.5 . . ?
N2 C10 C9 122.4(3) . . ?
N2 C10 H10 118.8 . . ?
C9 C10 H10 118.8 . . ?
N2 C11 C12 122.7(3) . . ?
N2 C11 H11 118.6 . . ?
C12 C11 H11 118.6 . . ?
C11 C12 C8 119.1(3) . . ?
C11 C12 H12 120.5 . . ?
C8 C12 H12 120.5 . . ?
O5 C13 O6 126.4(3) . . ?
O5 C13 C14 118.1(3) . . ?
O6 C13 C14 115.5(3) . . ?
C18 C14 C15 117.8(3) . . ?
C18 C14 C13 121.6(3) . . ?
C15 C14 C13 120.5(3) . . ?
C16 C15 C14 118.9(3) . . ?
C16 C15 H15 120.5 . . ?
C14 C15 H15 120.5 . . ?
N3 C16 C15 123.7(3) . . ?
N3 C16 H16 118.1 . . ?
C15 C16 H16 118.1 . . ?
N3 C17 C18 122.9(3) . . ?
N3 C17 H17 118.6 . . ?
C18 C17 H17 118.6 . . ?
C17 C18 C14 119.6(3) . . ?
C17 C18 H18 120.2 . . ?
C14 C18 H18 120.2 . . ?
O8 C19 O7 126.7(3) . . ?
O8 C19 C20 117.9(3) . . ?
O7 C19 C20 115.4(3) . . ?
C24 C20 C21 117.4(3) . . ?
C24 C20 C19 121.2(3) . . ?
C21 C20 C19 121.3(3) . . ?
C22 C21 C20 119.5(3) . . ?
C22 C21 H21 120.3 . . ?
C20 C21 H21 120.3 . . ?
N4 C22 C21 122.9(3) . . ?
N4 C22 H22 118.5 . . ?
C21 C22 H22 118.5 . . ?
N4 C23 C24 122.7(3) . . ?
N4 C23 H23 118.6 . . ?
C24 C23 H23 118.6 . . ?
C23 C24 C20 119.9(3) . . ?
C23 C24 H24 120.0 . . ?
C20 C24 H24 120.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Sm1 O1 C1 14.1(3) . . . . ?
O6 Sm1 O1 C1 125.5(3) . . . . ?
O7 Sm1 O1 C1 -135.0(3) . . . . ?
O2 Sm1 O1 C1 -51.7(3) 4_576 . . . ?
O10 Sm1 O1 C1 -90.9(3) . . . . ?
O4 Sm1 O1 C1 75.0(3) 4_575 . . . ?
O9 Sm1 O1 C1 154.2(3) . . . . ?
O6 Sm1 O3 C7 153.0(8) . . . . ?
O1 Sm1 O3 C7 -64.0(8) . . . . ?
O7 Sm1 O3 C7 55.6(9) . . . . ?
O2 Sm1 O3 C7 0.2(8) 4_576 . . . ?
O10 Sm1 O3 C7 78.2(8) . . . . ?
O4 Sm1 O3 C7 -127.6(8) 4_575 . . . ?
O9 Sm1 O3 C7 -163.5(8) . . . . ?
O3 Sm1 O6 C13 119.3(3) . . . . ?
O1 Sm1 O6 C13 -4.3(4) . . . . ?
O7 Sm1 O6 C13 -97.0(3) . . . . ?
O2 Sm1 O6 C13 170.9(3) 4_576 . . . ?
O10 Sm1 O6 C13 -161.7(3) . . . . ?
O4 Sm1 O6 C13 46.2(3) 4_575 . . . ?
O9 Sm1 O6 C13 -33.5(3) . . . . ?
O3 Sm1 O7 C19 3.8(5) . . . . ?
O6 Sm1 O7 C19 -86.8(4) . . . . ?
O1 Sm1 O7 C19 133.1(4) . . . . ?
O2 Sm1 O7 C19 58.0(4) 4_576 . . . ?
O10 Sm1 O7 C19 -19.7(4) . . . . ?
O4 Sm1 O7 C19 -171.0(4) 4_575 . . . ?
O9 Sm1 O7 C19 -151.3(5) . . . . ?
N1 Ag1 N2 C11 -164(5) 4_476 . . . ?
N1 Ag1 N2 C10 18(5) 4_476 . . . ?
N3 Ag2 N4 C22 47.3(4) 1_655 . . . ?
N3 Ag2 N4 C23 -130.7(3) 1_655 . . . ?
Sm1 O2 C1 O1 -86.7(8) 4_575 . . . ?
Sm1 O2 C1 C2 96.5(7) 4_575 . . . ?
Sm1 O1 C1 O2 -30.7(5) . . . . ?
Sm1 O1 C1 C2 146.1(2) . . . . ?
O2 C1 C2 C3 18.8(4) . . . . ?
O1 C1 C2 C3 -158.3(3) . . . . ?
O2 C1 C2 C6 -163.4(3) . . . . ?
O1 C1 C2 C6 19.5(4) . . . . ?
C6 C2 C3 C4 -2.6(5) . . . . ?
C1 C2 C3 C4 175.3(3) . . . . ?
C5 N1 C4 C3 0.5(5) . . . . ?
Ag1 N1 C4 C3 -176.1(3) 4_675 . . . ?
C2 C3 C4 N1 1.7(5) . . . . ?
C4 N1 C5 C6 -1.8(5) . . . . ?
Ag1 N1 C5 C6 174.8(3) 4_675 . . . ?
N1 C5 C6 C2 0.9(5) . . . . ?
C3 C2 C6 C5 1.3(5) . . . . ?
C1 C2 C6 C5 -176.5(3) . . . . ?
Sm1 O3 C7 O4 13.1(10) . . . . ?
Sm1 O3 C7 C8 -169.1(7) . . . . ?
Sm1 O4 C7 O3 -76.8(4) 4_576 . . . ?
Sm1 O4 C7 C8 105.5(3) 4_576 . . . ?
O3 C7 C8 C9 -159.8(3) . . . . ?
O4 C7 C8 C9 18.1(4) . . . . ?
O3 C7 C8 C12 19.7(4) . . . . ?
O4 C7 C8 C12 -162.4(3) . . . . ?
C12 C8 C9 C10 0.4(5) . . . . ?
C7 C8 C9 C10 179.9(3) . . . . ?
C11 N2 C10 C9 -1.3(5) . . . . ?
Ag1 N2 C10 C9 176.2(3) . . . . ?
C8 C9 C10 N2 0.9(5) . . . . ?
C10 N2 C11 C12 0.4(5) . . . . ?
Ag1 N2 C11 C12 -177.1(3) . . . . ?
N2 C11 C12 C8 0.9(5) . . . . ?
C9 C8 C12 C11 -1.2(5) . . . . ?
C7 C8 C12 C11 179.2(3) . . . . ?
Sm1 O6 C13 O5 14.2(5) . . . . ?
Sm1 O6 C13 C14 -166.0(2) . . . . ?
O5 C13 C14 C18 174.0(3) . . . . ?
O6 C13 C14 C18 -5.9(4) . . . . ?
O5 C13 C14 C15 -2.6(5) . . . . ?
O6 C13 C14 C15 177.6(3) . . . . ?
C18 C14 C15 C16 -0.6(5) . . . . ?
C13 C14 C15 C16 176.1(3) . . . . ?
C17 N3 C16 C15 -0.6(5) . . . . ?
Ag2 N3 C16 C15 173.1(3) 1_455 . . . ?
C14 C15 C16 N3 0.9(5) . . . . ?
C16 N3 C17 C18 -0.1(5) . . . . ?
Ag2 N3 C17 C18 -173.7(3) 1_455 . . . ?
N3 C17 C18 C14 0.3(5) . . . . ?
C15 C14 C18 C17 0.0(5) . . . . ?
C13 C14 C18 C17 -176.7(3) . . . . ?
Sm1 O7 C19 O8 31.2(7) . . . . ?
Sm1 O7 C19 C20 -149.0(3) . . . . ?
O8 C19 C20 C24 4.4(5) . . . . ?
O7 C19 C20 C24 -175.4(3) . . . . ?
O8 C19 C20 C21 -177.6(3) . . . . ?
O7 C19 C20 C21 2.5(5) . . . . ?
C24 C20 C21 C22 0.4(5) . . . . ?
C19 C20 C21 C22 -177.6(3) . . . . ?
C23 N4 C22 C21 -1.7(5) . . . . ?
Ag2 N4 C22 C21 -179.8(3) . . . . ?
C20 C21 C22 N4 1.3(5) . . . . ?
C22 N4 C23 C24 0.5(5) . . . . ?
Ag2 N4 C23 C24 178.6(3) . . . . ?
N4 C23 C24 C20 1.2(5) . . . . ?
C21 C20 C24 C23 -1.5(5) . . . . ?
C19 C20 C24 C23 176.5(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9A O5 0.844(10) 1.822(11) 2.649(3) 166(3) .
O9 H9B O8 0.840(10) 2.123(11) 2.957(3) 172(4) 1_554
O10 H10A O8 0.841(10) 1.939(11) 2.771(3) 170(4) .
O10 H10B O4 0.840(10) 2.021(18) 2.829(3) 161(4) 4_576
O1W H1WA O13 0.834(10) 2.126(12) 2.959(6) 175(6) .
O1W H1WB O12 0.838(10) 1.969(17) 2.787(6) 165(6) 1_554

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         0.976
_refine_diff_density_min         -1.059
_refine_diff_density_rms         0.086

data_c
_database_code_depnum_ccdc_archive 'CCDC 703240'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H20 Ag2 Eu N4 O10, N O3, H2 O'
_chemical_formula_sum            'C24 H22 Ag2 Eu N5 O14'
_chemical_formula_weight         972.17

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.8877(3)
_cell_length_b                   24.7375(6)
_cell_length_c                   6.77160(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.162(2)
_cell_angle_gamma                90.00
_cell_volume                     2812.56(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3523
_cell_measurement_theta_min      2.56
_cell_measurement_theta_max      30.53

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.296
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1880
_exptl_absorpt_coefficient_mu    3.664
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4493
_exptl_absorpt_correction_T_max  0.5747
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            16532
_diffrn_reflns_av_R_equivalents  0.0231
_diffrn_reflns_av_sigmaI/netI    0.0248
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         2.43
_diffrn_reflns_theta_max         25.50
_reflns_number_total             5232
_reflns_number_gt                4779
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger. Two Hydrogen atoms of each
water molecule were restrained in idealized positions and isotropically
refined with the O-H and H...H distances restrained to 0.84(1)Å and
1.43(2Å), respectively, and Uiso values were set equal to 1.5Ueq
(parent atom) for water H atoms.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0202P)²+3.4651P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00094(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         5232
_refine_ls_number_parameters     434
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.0238
_refine_ls_R_factor_gt           0.0208
_refine_ls_wR_factor_ref         0.0489
_refine_ls_wR_factor_gt          0.0478
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_restrained_S_all      1.011
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.229718(8) 0.662958(6) 0.88333(2) 0.01857(6) Uani 1 1 d . . .
Ag1 Ag -0.271528(15) 0.770907(13) 1.00999(5) 0.04409(9) Uani 1 1 d . . .
Ag2 Ag 0.734820(16) 0.509413(13) 1.09896(5) 0.04829(9) Uani 1 1 d . . .
O1 O 0.32598(12) 0.68536(9) 0.6643(3) 0.0311(5) Uani 1 1 d . . .
O2 O 0.31345(13) 0.76996(10) 0.5536(4) 0.0414(6) Uani 1 1 d . . .
O3 O 0.13905(13) 0.73019(9) 0.9529(4) 0.0405(6) Uani 1 1 d . . .
O4 O 0.14755(12) 0.81379(9) 1.0727(3) 0.0276(5) Uani 1 1 d . . .
O5 O 0.08705(13) 0.55789(10) 0.6255(3) 0.0362(5) Uani 1 1 d . . .
O6 O 0.11534(13) 0.60810(9) 0.8975(3) 0.0318(5) Uani 1 1 d . . .
O7 O 0.33310(14) 0.60473(11) 1.0254(3) 0.0422(6) Uani 1 1 d . . .
O8 O 0.34768(14) 0.58498(10) 1.3483(3) 0.0407(6) Uani 1 1 d . . .
O9 O 0.24105(13) 0.58093(9) 0.6668(3) 0.0300(5) Uani 1 1 d D . .
H9A H 0.1939(8) 0.5715(15) 0.630(4) 0.045 Uiso 1 1 d D . .
H9B H 0.2725(14) 0.5805(15) 0.579(4) 0.045 Uiso 1 1 d D . .
O10 O 0.21542(16) 0.64841(12) 1.2339(3) 0.0427(6) Uani 1 1 d D . .
H10A H 0.2544(17) 0.6306(15) 1.287(5) 0.064 Uiso 1 1 d D . .
H10B H 0.191(2) 0.6672(15) 1.310(4) 0.064 Uiso 1 1 d D . .
O11 O 0.69999(18) 0.54860(16) 0.6754(5) 0.0729(10) Uani 1 1 d . . .
O12 O 0.7412(3) 0.62969(16) 0.7004(6) 0.0868(11) Uani 1 1 d . . .
O13 O 0.7588(2) 0.58357(18) 0.4419(5) 0.0896(13) Uani 1 1 d . . .
O1W O 0.7287(2) 0.65697(12) 0.0966(6) 0.0688(9) Uani 1 1 d D . .
H1WA H 0.728(4) 0.6340(15) 0.187(5) 0.103 Uiso 1 1 d D . .
H1WB H 0.727(4) 0.6453(18) -0.020(3) 0.103 Uiso 1 1 d D . .
N1 N 0.60129(15) 0.72813(11) 0.5180(4) 0.0314(6) Uani 1 1 d . . .
N2 N -0.14445(15) 0.77192(12) 1.0001(4) 0.0329(6) Uani 1 1 d . . .
N3 N -0.14893(15) 0.52864(11) 1.0013(4) 0.0311(6) Uani 1 1 d . . .
N4 N 0.61206(15) 0.53663(11) 1.1252(4) 0.0322(6) Uani 1 1 d . . .
N5 N 0.73260(19) 0.58636(17) 0.6031(6) 0.0534(9) Uani 1 1 d . . .
C1 C 0.35140(17) 0.72763(12) 0.5918(4) 0.0235(6) Uani 1 1 d . . .
C2 C 0.43882(16) 0.72752(12) 0.5565(4) 0.0218(6) Uani 1 1 d . . .
C3 C 0.47950(18) 0.77555(12) 0.5430(4) 0.0249(6) Uani 1 1 d . . .
H3 H 0.4528 0.8084 0.5455 0.030 Uiso 1 1 calc R . .
C4 C 0.56029(19) 0.77442(13) 0.5258(5) 0.0301(7) Uani 1 1 d . . .
H4 H 0.5873 0.8070 0.5193 0.036 Uiso 1 1 calc R . .
C5 C 0.56084(19) 0.68162(14) 0.5251(5) 0.0326(7) Uani 1 1 d . . .
H5 H 0.5882 0.6492 0.5158 0.039 Uiso 1 1 calc R . .
C6 C 0.48081(18) 0.67967(13) 0.5456(5) 0.0267(7) Uani 1 1 d . . .
H6 H 0.4551 0.6466 0.5522 0.032 Uiso 1 1 calc R . .
C7 C 0.11001(17) 0.77231(12) 1.0144(4) 0.0211(6) Uani 1 1 d . . .
C8 C 0.02025(16) 0.77282(12) 1.0084(4) 0.0197(6) Uani 1 1 d . . .
C9 C -0.02186(18) 0.82057(12) 1.0106(4) 0.0257(6) Uani 1 1 d . . .
H9 H 0.0045 0.8536 1.0156 0.031 Uiso 1 1 calc R . .
C10 C -0.10376(18) 0.81860(13) 1.0054(5) 0.0314(7) Uani 1 1 d . . .
H10 H -0.1319 0.8509 1.0056 0.038 Uiso 1 1 calc R . .
C11 C -0.10309(19) 0.72551(13) 0.9972(5) 0.0318(7) Uani 1 1 d . . .
H11 H -0.1306 0.6929 0.9936 0.038 Uiso 1 1 calc R . .
C12 C -0.02150(18) 0.72462(12) 0.9994(4) 0.0263(6) Uani 1 1 d . . .
H12 H 0.0053 0.6919 0.9949 0.032 Uiso 1 1 calc R . .
C13 C 0.07152(18) 0.57691(12) 0.7861(4) 0.0254(6) Uani 1 1 d . . .
C14 C -0.00737(18) 0.56155(12) 0.8596(4) 0.0250(6) Uani 1 1 d . . .
C15 C -0.06142(18) 0.52930(13) 0.7459(5) 0.0301(7) Uani 1 1 d . . .
H15 H -0.0515 0.5184 0.6195 0.036 Uiso 1 1 calc R . .
C16 C -0.13011(19) 0.51347(14) 0.8221(5) 0.0338(7) Uani 1 1 d . . .
H16 H -0.1653 0.4911 0.7452 0.041 Uiso 1 1 calc R . .
C17 C -0.09630(19) 0.56010(13) 1.1104(5) 0.0317(7) Uani 1 1 d . . .
H17 H -0.1081 0.5710 1.2353 0.038 Uiso 1 1 calc R . .
C18 C -0.02577(19) 0.57698(12) 1.0464(5) 0.0283(7) Uani 1 1 d . . .
H18 H 0.0092 0.5985 1.1274 0.034 Uiso 1 1 calc R . .
C19 C 0.37206(18) 0.58835(12) 1.1837(5) 0.0270(7) Uani 1 1 d . . .
C20 C 0.45719(18) 0.57160(12) 1.1646(4) 0.0252(6) Uani 1 1 d . . .
C21 C 0.48930(19) 0.57680(13) 0.9853(5) 0.0306(7) Uani 1 1 d . . .
H21 H 0.4595 0.5918 0.8753 0.037 Uiso 1 1 calc R . .
C22 C 0.5664(2) 0.55922(14) 0.9731(5) 0.0343(7) Uani 1 1 d . . .
H22 H 0.5877 0.5633 0.8529 0.041 Uiso 1 1 calc R . .
C23 C 0.58043(19) 0.53243(14) 1.2987(5) 0.0331(7) Uani 1 1 d . . .
H23 H 0.6110 0.5170 1.4065 0.040 Uiso 1 1 calc R . .
C24 C 0.50479(19) 0.54998(13) 1.3233(5) 0.0299(7) Uani 1 1 d . . .
H24 H 0.4858 0.5473 1.4469 0.036 Uiso 1 1 calc R . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.342(2) . ?
Eu1 O6 2.371(2) . ?
Eu1 O1 2.381(2) . ?
Eu1 O7 2.385(2) . ?
Eu1 O2 2.394(2) 4_576 ?
Eu1 O10 2.439(2) . ?
Eu1 O4 2.461(2) 4_575 ?
Eu1 O9 2.523(2) . ?
Ag1 N2 2.154(3) . ?
Ag1 N1 2.154(2) 4_476 ?
Ag2 N3 2.190(3) 1_655 ?
Ag2 N4 2.205(3) . ?
O1 C1 1.251(4) . ?
O2 C1 1.240(4) . ?
O2 Eu1 2.394(2) 4_575 ?
O3 C7 1.242(4) . ?
O4 C7 1.248(4) . ?
O4 Eu1 2.461(2) 4_576 ?
O5 C13 1.238(4) . ?
O6 C13 1.262(4) . ?
O7 C19 1.263(4) . ?
O8 C19 1.232(4) . ?
O9 H9A 0.841(10) . ?
O9 H9B 0.840(10) . ?
O10 H10A 0.839(10) . ?
O10 H10B 0.839(10) . ?
O11 N5 1.214(4) . ?
O12 N5 1.258(5) . ?
O13 N5 1.223(5) . ?
O1W H1WA 0.835(10) . ?
O1W H1WB 0.839(10) . ?
N1 C5 1.341(4) . ?
N1 C4 1.342(4) . ?
N1 Ag1 2.154(2) 4_675 ?
N2 C10 1.342(4) . ?
N2 C11 1.345(4) . ?
N3 C16 1.341(4) . ?
N3 C17 1.342(4) . ?
N3 Ag2 2.190(2) 1_455 ?
N4 C22 1.340(4) . ?
N4 C23 1.346(4) . ?
C1 C2 1.521(4) . ?
C2 C3 1.380(4) . ?
C2 C6 1.386(4) . ?
C3 C4 1.382(4) . ?
C3 H3 0.9300 . ?
C4 H4 0.9300 . ?
C5 C6 1.374(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.512(4) . ?
C8 C9 1.380(4) . ?
C8 C12 1.383(4) . ?
C9 C10 1.381(4) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.377(4) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.520(4) . ?
C14 C15 1.383(4) . ?
C14 C18 1.388(4) . ?
C15 C16 1.376(4) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 C18 1.375(4) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.515(4) . ?
C20 C24 1.379(4) . ?
C20 C21 1.388(4) . ?
C21 C22 1.384(5) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.376(4) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O6 81.10(8) . . ?
O3 Eu1 O1 117.70(8) . . ?
O6 Eu1 O1 140.55(8) . . ?
O3 Eu1 O7 144.47(9) . . ?
O6 Eu1 O7 101.67(9) . . ?
O1 Eu1 O7 82.68(8) . . ?
O3 Eu1 O2 77.06(8) . 4_576 ?
O6 Eu1 O2 144.97(8) . 4_576 ?
O1 Eu1 O2 74.41(8) . 4_576 ?
O7 Eu1 O2 81.69(9) . 4_576 ?
O3 Eu1 O10 76.93(9) . . ?
O6 Eu1 O10 73.14(9) . . ?
O1 Eu1 O10 141.86(8) . . ?
O7 Eu1 O10 70.30(8) . . ?
O2 Eu1 O10 75.44(9) 4_576 . ?
O3 Eu1 O4 71.64(8) . 4_575 ?
O6 Eu1 O4 77.36(7) . 4_575 ?
O1 Eu1 O4 76.88(7) . 4_575 ?
O7 Eu1 O4 143.82(7) . 4_575 ?
O2 Eu1 O4 119.96(8) 4_576 4_575 ?
O10 Eu1 O4 139.56(8) . 4_575 ?
O3 Eu1 O9 141.25(8) . . ?
O6 Eu1 O9 71.10(7) . . ?
O1 Eu1 O9 74.07(7) . . ?
O7 Eu1 O9 69.55(8) . . ?
O2 Eu1 O9 139.43(7) 4_576 . ?
O10 Eu1 O9 117.96(8) . . ?
O4 Eu1 O9 76.24(7) 4_575 . ?
N2 Ag1 N1 178.66(11) . 4_476 ?
N3 Ag2 N4 147.04(10) 1_655 . ?
C1 O1 Eu1 136.50(19) . . ?
C1 O2 Eu1 161.9(2) . 4_575 ?
C7 O3 Eu1 162.3(2) . . ?
C7 O4 Eu1 133.12(19) . 4_576 ?
C13 O6 Eu1 138.94(19) . . ?
C19 O7 Eu1 145.9(2) . . ?
Eu1 O9 H9A 105(2) . . ?
Eu1 O9 H9B 121(2) . . ?
H9A O9 H9B 116.1(15) . . ?
Eu1 O10 H10A 110(3) . . ?
Eu1 O10 H10B 129(3) . . ?
H10A O10 H10B 116.5(15) . . ?
H1WA O1W H1WB 116.9(16) . . ?
C5 N1 C4 117.6(3) . . ?
C5 N1 Ag1 121.6(2) . 4_675 ?
C4 N1 Ag1 120.8(2) . 4_675 ?
C10 N2 C11 118.0(3) . . ?
C10 N2 Ag1 121.2(2) . . ?
C11 N2 Ag1 120.7(2) . . ?
C16 N3 C17 116.9(3) . . ?
C16 N3 Ag2 121.3(2) . 1_455 ?
C17 N3 Ag2 121.5(2) . 1_455 ?
C22 N4 C23 117.0(3) . . ?
C22 N4 Ag2 122.2(2) . . ?
C23 N4 Ag2 120.8(2) . . ?
O11 N5 O13 122.7(5) . . ?
O11 N5 O12 118.4(4) . . ?
O13 N5 O12 118.9(4) . . ?
O2 C1 O1 126.6(3) . . ?
O2 C1 C2 117.2(3) . . ?
O1 C1 C2 116.1(3) . . ?
C3 C2 C6 118.1(3) . . ?
C3 C2 C1 120.5(3) . . ?
C6 C2 C1 121.4(3) . . ?
C2 C3 C4 119.4(3) . . ?
C2 C3 H3 120.3 . . ?
C4 C3 H3 120.3 . . ?
N1 C4 C3 122.6(3) . . ?
N1 C4 H4 118.7 . . ?
C3 C4 H4 118.7 . . ?
N1 C5 C6 122.9(3) . . ?
N1 C5 H5 118.5 . . ?
C6 C5 H5 118.5 . . ?
C5 C6 C2 119.3(3) . . ?
C5 C6 H6 120.3 . . ?
C2 C6 H6 120.3 . . ?
O3 C7 O4 126.2(3) . . ?
O3 C7 C8 115.4(3) . . ?
O4 C7 C8 118.4(2) . . ?
C9 C8 C12 118.5(3) . . ?
C9 C8 C7 121.6(3) . . ?
C12 C8 C7 119.9(3) . . ?
C8 C9 C10 119.1(3) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
N2 C10 C9 122.7(3) . . ?
N2 C10 H10 118.7 . . ?
C9 C10 H10 118.7 . . ?
N2 C11 C12 122.3(3) . . ?
N2 C11 H11 118.9 . . ?
C12 C11 H11 118.9 . . ?
C11 C12 C8 119.4(3) . . ?
C11 C12 H12 120.3 . . ?
C8 C12 H12 120.3 . . ?
O5 C13 O6 126.2(3) . . ?
O5 C13 C14 117.9(3) . . ?
O6 C13 C14 115.8(3) . . ?
C15 C14 C18 117.8(3) . . ?
C15 C14 C13 120.8(3) . . ?
C18 C14 C13 121.3(3) . . ?
C16 C15 C14 119.2(3) . . ?
C16 C15 H15 120.4 . . ?
C14 C15 H15 120.4 . . ?
N3 C16 C15 123.4(3) . . ?
N3 C16 H16 118.3 . . ?
C15 C16 H16 118.3 . . ?
N3 C17 C18 123.2(3) . . ?
N3 C17 H17 118.4 . . ?
C18 C17 H17 118.4 . . ?
C17 C18 C14 119.3(3) . . ?
C17 C18 H18 120.3 . . ?
C14 C18 H18 120.3 . . ?
O8 C19 O7 126.6(3) . . ?
O8 C19 C20 118.1(3) . . ?
O7 C19 C20 115.4(3) . . ?
C24 C20 C21 117.9(3) . . ?
C24 C20 C19 121.3(3) . . ?
C21 C20 C19 120.8(3) . . ?
C22 C21 C20 118.8(3) . . ?
C22 C21 H21 120.6 . . ?
C20 C21 H21 120.6 . . ?
N4 C22 C21 123.5(3) . . ?
N4 C22 H22 118.2 . . ?
C21 C22 H22 118.2 . . ?
N4 C23 C24 122.8(3) . . ?
N4 C23 H23 118.6 . . ?
C24 C23 H23 118.6 . . ?
C23 C24 C20 119.9(3) . . ?
C23 C24 H24 120.0 . . ?
C20 C24 H24 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Eu1 O1 C1 13.6(3) . . . . ?
O6 Eu1 O1 C1 124.8(3) . . . . ?
O7 Eu1 O1 C1 -135.7(3) . . . . ?
O2 Eu1 O1 C1 -52.3(3) 4_576 . . . ?
O10 Eu1 O1 C1 -91.2(3) . . . . ?
O4 Eu1 O1 C1 74.4(3) 4_575 . . . ?
O9 Eu1 O1 C1 153.6(3) . . . . ?
O6 Eu1 O3 C7 150.7(8) . . . . ?
O1 Eu1 O3 C7 -66.1(8) . . . . ?
O7 Eu1 O3 C7 53.1(8) . . . . ?
O2 Eu1 O3 C7 -1.7(7) 4_576 . . . ?
O10 Eu1 O3 C7 76.1(8) . . . . ?
O4 Eu1 O3 C7 -129.7(8) 4_575 . . . ?
O9 Eu1 O3 C7 -165.2(7) . . . . ?
O3 Eu1 O6 C13 119.2(3) . . . . ?
O1 Eu1 O6 C13 -4.2(4) . . . . ?
O7 Eu1 O6 C13 -96.8(3) . . . . ?
O2 Eu1 O6 C13 171.0(3) 4_576 . . . ?
O10 Eu1 O6 C13 -161.8(3) . . . . ?
O4 Eu1 O6 C13 46.2(3) 4_575 . . . ?
O9 Eu1 O6 C13 -33.4(3) . . . . ?
O3 Eu1 O7 C19 4.4(5) . . . . ?
O6 Eu1 O7 C19 -86.5(4) . . . . ?
O1 Eu1 O7 C19 133.2(4) . . . . ?
O2 Eu1 O7 C19 58.0(4) 4_576 . . . ?
O10 Eu1 O7 C19 -19.4(4) . . . . ?
O4 Eu1 O7 C19 -171.0(4) 4_575 . . . ?
O9 Eu1 O7 C19 -151.1(4) . . . . ?
N1 Ag1 N2 C10 17(5) 4_476 . . . ?
N1 Ag1 N2 C11 -166(4) 4_476 . . . ?
N3 Ag2 N4 C22 47.6(4) 1_655 . . . ?
N3 Ag2 N4 C23 -130.5(3) 1_655 . . . ?
Eu1 O2 C1 O1 -88.1(7) 4_575 . . . ?
Eu1 O2 C1 C2 95.0(7) 4_575 . . . ?
Eu1 O1 C1 O2 -30.1(5) . . . . ?
Eu1 O1 C1 C2 146.9(2) . . . . ?
O2 C1 C2 C3 19.4(4) . . . . ?
O1 C1 C2 C3 -157.8(3) . . . . ?
O2 C1 C2 C6 -163.4(3) . . . . ?
O1 C1 C2 C6 19.3(4) . . . . ?
C6 C2 C3 C4 -2.1(4) . . . . ?
C1 C2 C3 C4 175.2(3) . . . . ?
C5 N1 C4 C3 0.8(5) . . . . ?
Ag1 N1 C4 C3 -176.1(2) 4_675 . . . ?
C2 C3 C4 N1 1.2(5) . . . . ?
C4 N1 C5 C6 -2.0(5) . . . . ?
Ag1 N1 C5 C6 174.9(2) 4_675 . . . ?
N1 C5 C6 C2 1.1(5) . . . . ?
C3 C2 C6 C5 1.0(4) . . . . ?
C1 C2 C6 C5 -176.2(3) . . . . ?
Eu1 O3 C7 O4 15.4(10) . . . . ?
Eu1 O3 C7 C8 -167.2(6) . . . . ?
Eu1 O4 C7 O3 -77.5(4) 4_576 . . . ?
Eu1 O4 C7 C8 105.1(3) 4_576 . . . ?
O3 C7 C8 C9 -159.2(3) . . . . ?
O4 C7 C8 C9 18.4(4) . . . . ?
O3 C7 C8 C12 20.4(4) . . . . ?
O4 C7 C8 C12 -161.9(3) . . . . ?
C12 C8 C9 C10 0.5(4) . . . . ?
C7 C8 C9 C10 -179.8(3) . . . . ?
C11 N2 C10 C9 -0.9(5) . . . . ?
Ag1 N2 C10 C9 176.3(2) . . . . ?
C8 C9 C10 N2 0.7(5) . . . . ?
C10 N2 C11 C12 0.0(5) . . . . ?
Ag1 N2 C11 C12 -177.2(2) . . . . ?
N2 C11 C12 C8 1.2(5) . . . . ?
C9 C8 C12 C11 -1.4(4) . . . . ?
C7 C8 C12 C11 179.0(3) . . . . ?
Eu1 O6 C13 O5 14.0(5) . . . . ?
Eu1 O6 C13 C14 -166.3(2) . . . . ?
O5 C13 C14 C15 -2.9(4) . . . . ?
O6 C13 C14 C15 177.5(3) . . . . ?
O5 C13 C14 C18 173.8(3) . . . . ?
O6 C13 C14 C18 -5.9(4) . . . . ?
C18 C14 C15 C16 -0.7(5) . . . . ?
C13 C14 C15 C16 176.1(3) . . . . ?
C17 N3 C16 C15 -1.2(5) . . . . ?
Ag2 N3 C16 C15 173.0(3) 1_455 . . . ?
C14 C15 C16 N3 1.5(5) . . . . ?
C16 N3 C17 C18 0.2(5) . . . . ?
Ag2 N3 C17 C18 -174.1(2) 1_455 . . . ?
N3 C17 C18 C14 0.6(5) . . . . ?
C15 C14 C18 C17 -0.3(5) . . . . ?
C13 C14 C18 C17 -177.1(3) . . . . ?
Eu1 O7 C19 O8 30.3(6) . . . . ?
Eu1 O7 C19 C20 -149.5(3) . . . . ?
O8 C19 C20 C24 4.0(5) . . . . ?
O7 C19 C20 C24 -176.1(3) . . . . ?
O8 C19 C20 C21 -177.0(3) . . . . ?
O7 C19 C20 C21 2.8(4) . . . . ?
C24 C20 C21 C22 1.2(5) . . . . ?
C19 C20 C21 C22 -177.8(3) . . . . ?
C23 N4 C22 C21 -1.6(5) . . . . ?
Ag2 N4 C22 C21 -179.8(3) . . . . ?
C20 C21 C22 N4 0.9(5) . . . . ?
C22 N4 C23 C24 0.2(5) . . . . ?
Ag2 N4 C23 C24 178.5(2) . . . . ?
N4 C23 C24 C20 1.9(5) . . . . ?
C21 C20 C24 C23 -2.5(5) . . . . ?
C19 C20 C24 C23 176.5(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9A O5 0.841(10) 1.832(11) 2.648(3) 163(3) .
O9 H9B O8 0.840(10) 2.117(11) 2.956(3) 176(4) 1_554
O10 H10A O8 0.839(10) 1.947(11) 2.771(3) 167(3) .
O10 H10B O4 0.839(10) 2.05(2) 2.831(3) 155(3) 4_576
O1W H1WA O13 0.835(10) 2.147(19) 2.961(5) 165(6) .
O1W H1WB O12 0.839(10) 1.971(15) 2.797(6) 168(6) 1_554

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.50
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         1.002
_refine_diff_density_min         -1.052
_refine_diff_density_rms         0.080


data_compound_3a
_database_code_depnum_ccdc_archive 'CCDC 718430'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C48 H52 Ag4 N8 O26 Sm2, 2(N O3), 4(H2 O)'
_chemical_formula_sum            'C48 H60 Ag4 N10 O36 Sm2'
_chemical_formula_weight         2085.24

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   p-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.5461(15)
_cell_length_b                   13.0618(8)
_cell_length_c                   17.320(5)
_cell_angle_alpha                97.189(13)
_cell_angle_beta                 92.502(15)
_cell_angle_gamma                100.548(12)
_cell_volume                     1661.5(6)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3216
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      22.67

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    2.085
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1018
_exptl_absorpt_coefficient_mu    2.998
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5117
_exptl_absorpt_correction_T_max  0.6011
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detectorr'
_diffrn_measurement_method       'phi and omga scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_reflns_number            9369
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_av_sigmaI/netI    0.0575
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.60
_diffrn_reflns_theta_max         27.54
_reflns_number_total             7628
_reflns_number_gt                5754
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker XSCANS'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2001)'
_computing_publication_material  'SHELXTL (Bruker, 2001)'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger. Two Hydrogen atoms of each
water molecule were restrained in idealized positions and isotropically
refined with the O-H and H...H distances restrained to 0.84(1)Å and
1.43(2Å), respectively, and Uiso values were set equal to 1.5Ueq
(parent atom) for water H atoms.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0584P)²+4.4590P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7628
_refine_ls_number_parameters     493
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0694
_refine_ls_R_factor_gt           0.0428
_refine_ls_wR_factor_ref         0.1252
_refine_ls_wR_factor_gt          0.0998
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sm1 Sm 0.87367(4) 0.79572(2) 0.480077(16) 0.02531(10) Uani 1 1 d . . .
Ag1 Ag 1.20792(9) 0.50579(6) 0.03712(3) 0.06001(19) Uani 1 1 d . . .
Ag2 Ag 1.22846(10) 1.06011(6) 0.02494(3) 0.06035(19) Uani 1 1 d . . .
C1 C 0.9212(9) 0.5502(5) 0.3817(3) 0.0330(13) Uani 1 1 d . . .
C2 C 0.9989(9) 0.5396(4) 0.3029(3) 0.0302(12) Uani 1 1 d . . .
C3 C 1.0731(11) 0.6272(5) 0.2692(4) 0.0433(16) Uani 1 1 d . . .
H3 H 1.0822 0.6944 0.2961 0.052 Uiso 1 1 calc R . .
C4 C 1.1328(11) 0.6130(6) 0.1955(4) 0.0477(17) Uani 1 1 d . . .
H4 H 1.1829 0.6723 0.1736 0.057 Uiso 1 1 calc R . .
C5 C 1.0537(10) 0.4349(5) 0.1872(4) 0.0429(16) Uani 1 1 d . . .
H5 H 1.0468 0.3684 0.1595 0.051 Uiso 1 1 calc R . .
C6 C 0.9923(9) 0.4418(5) 0.2608(3) 0.0349(14) Uani 1 1 d . . .
H6 H 0.9466 0.3813 0.2821 0.042 Uiso 1 1 calc R . .
C7 C 1.5442(9) 0.5522(5) -0.2966(3) 0.0344(13) Uani 1 1 d . . .
C8 C 1.4674(8) 0.5421(5) -0.2170(4) 0.0341(13) Uani 1 1 d . . .
C9 C 1.4620(11) 0.6295(6) -0.1638(4) 0.0512(19) Uani 1 1 d . . .
H9 H 1.5050 0.6966 -0.1758 0.061 Uiso 1 1 calc R . .
C10 C 1.3930(12) 0.6162(7) -0.0933(4) 0.057(2) Uani 1 1 d . . .
H10 H 1.3922 0.6760 -0.0580 0.068 Uiso 1 1 calc R . .
C11 C 1.3249(11) 0.4386(6) -0.1246(4) 0.0503(18) Uani 1 1 d . . .
H11 H 1.2743 0.3727 -0.1123 0.060 Uiso 1 1 calc R . .
C12 C 1.3947(11) 0.4449(6) -0.1963(4) 0.0455(17) Uani 1 1 d . . .
H12 H 1.3931 0.3840 -0.2307 0.055 Uiso 1 1 calc R . .
C13 C 0.9842(8) 0.9956(4) 0.3687(3) 0.0247(11) Uani 1 1 d . . .
C14 C 1.0376(8) 1.0126(4) 0.2876(3) 0.0281(12) Uani 1 1 d . . .
C15 C 1.0917(10) 1.1130(5) 0.2677(4) 0.0390(15) Uani 1 1 d . . .
H15 H 1.0922 1.1721 0.3038 0.047 Uiso 1 1 calc R . .
C16 C 1.1443(11) 1.1231(5) 0.1936(4) 0.0454(17) Uani 1 1 d . . .
H16 H 1.1812 1.1903 0.1806 0.054 Uiso 1 1 calc R . .
C17 C 1.0920(11) 0.9452(6) 0.1587(4) 0.0477(18) Uani 1 1 d . . .
H17 H 1.0904 0.8873 0.1213 0.057 Uiso 1 1 calc R . .
C18 C 1.0392(10) 0.9277(5) 0.2315(3) 0.0379(15) Uani 1 1 d . . .
H18 H 1.0049 0.8594 0.2429 0.046 Uiso 1 1 calc R . .
C19 C 1.5440(9) 1.0548(5) -0.3157(3) 0.0352(14) Uani 1 1 d . . .
C20 C 1.4739(9) 1.0556(5) -0.2340(3) 0.0343(13) Uani 1 1 d . . .
C21 C 1.4726(12) 1.1493(5) -0.1881(4) 0.0494(19) Uani 1 1 d . . .
H21 H 1.5143 1.2127 -0.2064 0.059 Uiso 1 1 calc R . .
C22 C 1.4088(13) 1.1486(6) -0.1144(4) 0.059(2) Uani 1 1 d . . .
H22 H 1.4091 1.2127 -0.0841 0.071 Uiso 1 1 calc R . .
C23 C 1.3462(12) 0.9712(6) -0.1298(4) 0.052(2) Uani 1 1 d . . .
H23 H 1.3022 0.9089 -0.1104 0.062 Uiso 1 1 calc R . .
C24 C 1.4070(11) 0.9651(5) -0.2038(4) 0.0465(18) Uani 1 1 d . . .
H24 H 1.4027 0.9000 -0.2332 0.056 Uiso 1 1 calc R . .
N1 N 1.1226(8) 0.5181(5) 0.1535(3) 0.0433(13) Uani 1 1 d . . .
N2 N 1.3264(9) 0.5226(5) -0.0720(3) 0.0486(15) Uani 1 1 d . . .
N3 N 1.1451(9) 1.0404(5) 0.1390(3) 0.0449(14) Uani 1 1 d . . .
N4 N 1.3472(9) 1.0611(5) -0.0849(3) 0.0483(15) Uani 1 1 d . . .
N5 N 1.0126(13) 0.2530(5) 0.0075(4) 0.0578(19) Uani 1 1 d . . .
O1 O 0.8972(7) 0.6406(3) 0.4071(3) 0.0454(12) Uani 1 1 d . . .
O2 O 0.8871(9) 0.4733(4) 0.4152(3) 0.0579(16) Uani 1 1 d . . .
O3 O 1.5494(8) 0.4693(4) -0.3387(3) 0.0493(13) Uani 1 1 d . . .
O4 O 1.5959(8) 0.6430(4) -0.3106(3) 0.0478(12) Uani 1 1 d . . .
O5 O 0.9408(7) 0.9029(3) 0.3811(2) 0.0378(10) Uani 1 1 d . . .
O6 O 0.9847(7) 1.0748(3) 0.4169(2) 0.0405(11) Uani 1 1 d . . .
O7 O 1.5222(8) 0.9683(4) -0.3576(3) 0.0549(14) Uani 1 1 d . . .
O8 O 1.6201(7) 1.1409(4) -0.3325(3) 0.0413(11) Uani 1 1 d . . .
O9 O 0.9222(13) 0.1732(6) 0.0250(4) 0.099(3) Uani 1 1 d . . .
O10 O 0.9516(15) 0.3145(6) -0.0258(5) 0.116(3) Uani 1 1 d . . .
O11 O 1.1801(12) 0.2734(6) 0.0259(5) 0.091(2) Uani 1 1 d . . .
O12 O 1.2011(7) 0.8098(4) 0.4608(3) 0.0451(12) Uani 1 1 d D . .
H12A H 1.244(11) 0.826(5) 0.419(3) 0.068 Uiso 1 1 d D . .
H12B H 1.230(12) 0.751(4) 0.470(4) 0.068 Uiso 1 1 d D . .
O13 O 0.6179(7) 0.7388(4) 0.3813(3) 0.0419(11) Uani 1 1 d D . .
H13A H 0.545(8) 0.778(4) 0.370(5) 0.063 Uiso 1 1 d D . .
H13B H 0.559(8) 0.675(2) 0.374(5) 0.063 Uiso 1 1 d D . .
O14 O 0.6746(7) 0.9280(4) 0.5013(3) 0.0426(11) Uani 1 1 d D . .
H14A H 0.697(11) 0.986(3) 0.484(4) 0.064 Uiso 1 1 d D . .
H14B H 0.614(10) 0.931(5) 0.541(3) 0.064 Uiso 1 1 d D . .
O15 O 0.6367(7) 0.7064(4) 0.5480(3) 0.0448(12) Uani 1 1 d D . .
H15A H 0.529(5) 0.685(6) 0.528(4) 0.067 Uiso 1 1 d D . .
H15B H 0.655(10) 0.670(6) 0.585(4) 0.067 Uiso 1 1 d D . .
O16 O 1.0033(7) 0.7094(3) 0.5793(3) 0.0383(10) Uani 1 1 d D . .
H16A H 1.111(5) 0.733(5) 0.600(5) 0.057 Uiso 1 1 d D . .
H16B H 0.990(9) 0.6419(17) 0.569(5) 0.057 Uiso 1 1 d D . .
O1W O 0.6767(8) 0.2290(4) 0.3403(4) 0.0543(13) Uani 1 1 d D . .
H1WA H 0.606(9) 0.271(5) 0.334(6) 0.081 Uiso 1 1 d D . .
H1WB H 0.621(9) 0.168(2) 0.339(6) 0.081 Uiso 1 1 d D . .
O2W O 0.3167(7) 0.6097(4) 0.4737(3) 0.0437(11) Uani 1 1 d D . .
H2WA H 0.342(11) 0.574(5) 0.432(3) 0.065 Uiso 1 1 d D . .
H2WB H 0.267(11) 0.567(4) 0.503(3) 0.065 Uiso 1 1 d D . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sm1 O1 2.289(4) . ?
Sm1 O5 2.360(4) . ?
Sm1 O6 2.367(4) 2_776 ?
Sm1 O15 2.389(4) . ?
Sm1 O16 2.434(4) . ?
Sm1 O13 2.464(5) . ?
Sm1 O12 2.484(5) . ?
Sm1 O14 2.492(4) . ?
Ag2 N3 2.130(5) . ?
Ag2 N4 2.138(5) . ?
Ag1 N1 2.138(5) . ?
Ag1 N2 2.145(5) . ?
Ag1 Ag1 3.3086(16) 2_765 ?
C10 N2 1.337(10) . ?
C10 C9 1.366(10) . ?
C10 H10 0.9300 . ?
C9 C8 1.383(10) . ?
C9 H9 0.9300 . ?
C8 C12 1.385(9) . ?
C8 C7 1.529(8) . ?
C12 C11 1.375(9) . ?
C12 H12 0.9300 . ?
C11 N2 1.333(10) . ?
C11 H11 0.9300 . ?
C7 O3 1.235(8) . ?
C7 O4 1.237(7) . ?
C4 N1 1.344(9) . ?
C4 C3 1.374(10) . ?
C4 H4 0.9300 . ?
C3 C2 1.387(8) . ?
C3 H3 0.9300 . ?
C2 C6 1.380(8) . ?
C2 C1 1.509(8) . ?
C6 C5 1.372(9) . ?
C6 H6 0.9300 . ?
C5 N1 1.332(9) . ?
C5 H5 0.9300 . ?
C1 O2 1.214(7) . ?
C1 O1 1.256(7) . ?
C22 N4 1.325(10) . ?
C22 C21 1.384(10) . ?
C22 H22 0.9300 . ?
C21 C20 1.375(9) . ?
C21 H21 0.9300 . ?
C20 C24 1.373(9) . ?
C20 C19 1.530(8) . ?
C24 C23 1.378(9) . ?
C24 H24 0.9300 . ?
C23 N4 1.323(9) . ?
C23 H23 0.9300 . ?
C19 O8 1.240(7) . ?
C19 O7 1.244(8) . ?
C16 N3 1.344(9) . ?
C16 C15 1.374(9) . ?
C16 H16 0.9300 . ?
C15 C14 1.392(8) . ?
C15 H15 0.9300 . ?
C14 C18 1.382(8) . ?
C14 C13 1.510(7) . ?
C18 C17 1.371(9) . ?
C18 H18 0.9300 . ?
C17 N3 1.327(9) . ?
C17 H17 0.9300 . ?
C13 O5 1.243(6) . ?
C13 O6 1.245(7) . ?
N5 O10 1.191(10) . ?
N5 O9 1.217(9) . ?
N5 O11 1.261(11) . ?
O6 Sm1 2.367(4) 2_776 ?
O12 H12A 0.84(2) . ?
O12 H12B 0.86(2) . ?
O15 H15A 0.85(2) . ?
O15 H15B 0.86(2) . ?
O13 H13A 0.85(2) . ?
O13 H13B 0.87(2) . ?
O16 H16A 0.86(2) . ?
O16 H16B 0.86(2) . ?
O14 H14A 0.84(2) . ?
O14 H14B 0.84(2) . ?
O1w H1WA 0.85(2) . ?
O1W H1WB 0.83(2) . ?
O2W H2WA 0.86(2) . ?
O2W H2WB 0.86(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Sm1 O5 96.50(16) . . ?
O1 Sm1 O6 144.00(19) . 2_776 ?
O5 Sm1 O6 95.02(15) . 2_776 ?
O1 Sm1 O15 90.61(19) . . ?
O5 Sm1 O15 144.75(18) . . ?
O6 Sm1 O15 99.25(17) 2_776 . ?
O1 Sm1 O16 79.84(17) . . ?
O5 Sm1 O16 144.60(17) . . ?
O6 Sm1 O16 71.20(15) 2_776 . ?
O15 Sm1 O16 70.63(17) . . ?
O1 Sm1 O13 69.36(18) . . ?
O5 Sm1 O13 74.95(16) . . ?
O6 Sm1 O13 146.63(17) 2_776 . ?
O15 Sm1 O13 75.46(17) . . ?
O16 Sm1 O13 133.38(15) . . ?
O1 Sm1 O12 74.92(18) . . ?
O5 Sm1 O12 72.95(17) . . ?
O6 Sm1 O12 76.13(18) 2_776 . ?
O15 Sm1 O12 141.84(17) . . ?
O16 Sm1 O12 72.12(16) . . ?
O13 Sm1 O12 128.02(17) . . ?
O1 Sm1 O14 143.05(19) . . ?
O5 Sm1 O14 75.82(16) . . ?
O6 Sm1 O14 72.92(17) 2_776 . ?
O15 Sm1 O14 77.87(18) . . ?
O16 Sm1 O14 126.73(16) . . ?
O13 Sm1 O14 73.76(17) . . ?
O12 Sm1 O14 133.27(17) . . ?
N3 Ag2 N4 169.1(2) . . ?
N1 Ag1 N2 168.8(2) . . ?
N1 Ag1 Ag1 91.77(17) . 2_765 ?
N2 Ag1 Ag1 93.77(18) . 2_765 ?
N2 C10 C9 124.0(7) . . ?
N2 C10 H10 118.0 . . ?
C9 C10 H10 118.0 . . ?
C10 C9 C8 119.3(7) . . ?
C10 C9 H9 120.3 . . ?
C8 C9 H9 120.3 . . ?
C9 C8 C12 117.1(6) . . ?
C9 C8 C7 121.6(6) . . ?
C12 C8 C7 121.3(6) . . ?
C11 C12 C8 119.9(7) . . ?
C11 C12 H12 120.1 . . ?
C8 C12 H12 120.1 . . ?
N2 C11 C12 123.0(7) . . ?
N2 C11 H11 118.5 . . ?
C12 C11 H11 118.5 . . ?
O3 C7 O4 127.7(6) . . ?
O3 C7 C8 116.6(5) . . ?
O4 C7 C8 115.7(6) . . ?
N1 C4 C3 123.4(6) . . ?
N1 C4 H4 118.3 . . ?
C3 C4 H4 118.3 . . ?
C4 C3 C2 118.9(6) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 H3 120.5 . . ?
C6 C2 C3 117.8(6) . . ?
C6 C2 C1 120.7(5) . . ?
C3 C2 C1 121.4(5) . . ?
C5 C6 C2 119.4(6) . . ?
C5 C6 H6 120.3 . . ?
C2 C6 H6 120.3 . . ?
N1 C5 C6 123.6(6) . . ?
N1 C5 H5 118.2 . . ?
C6 C5 H5 118.2 . . ?
O2 C1 O1 125.4(6) . . ?
O2 C1 C2 119.2(5) . . ?
O1 C1 C2 115.4(5) . . ?
N4 C22 C21 123.3(7) . . ?
N4 C22 H22 118.4 . . ?
C21 C22 H22 118.4 . . ?
C20 C21 C22 119.5(6) . . ?
C20 C21 H21 120.3 . . ?
C22 C21 H21 120.3 . . ?
C24 C20 C21 117.1(6) . . ?
C24 C20 C19 122.6(6) . . ?
C21 C20 C19 120.3(6) . . ?
C20 C24 C23 119.8(6) . . ?
C20 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?
N4 C23 C24 123.4(6) . . ?
N4 C23 H23 118.3 . . ?
C24 C23 H23 118.3 . . ?
O8 C19 O7 126.7(6) . . ?
O8 C19 C20 116.2(5) . . ?
O7 C19 C20 117.1(6) . . ?
N3 C16 C15 123.1(6) . . ?
N3 C16 H16 118.4 . . ?
C15 C16 H16 118.4 . . ?
C16 C15 C14 118.7(6) . . ?
C16 C15 H15 120.7 . . ?
C14 C15 H15 120.7 . . ?
C18 C14 C15 118.1(5) . . ?
C18 C14 C13 120.4(5) . . ?
C15 C14 C13 121.5(5) . . ?
C17 C18 C14 119.2(6) . . ?
C17 C18 H18 120.4 . . ?
C14 C18 H18 120.4 . . ?
N3 C17 C18 123.4(6) . . ?
N3 C17 H17 118.3 . . ?
C18 C17 H17 118.3 . . ?
O5 C13 O6 125.6(5) . . ?
O5 C13 C14 116.7(5) . . ?
O6 C13 C14 117.6(5) . . ?
C11 N2 C10 116.7(6) . . ?
C11 N2 Ag1 120.5(5) . . ?
C10 N2 Ag1 122.7(5) . . ?
C5 N1 C4 116.8(6) . . ?
C5 N1 Ag1 123.0(5) . . ?
C4 N1 Ag1 120.2(5) . . ?
C23 N4 C22 116.9(6) . . ?
C23 N4 Ag2 119.7(5) . . ?
C22 N4 Ag2 123.1(5) . . ?
C17 N3 C16 117.4(6) . . ?
C17 N3 Ag2 120.8(5) . . ?
C16 N3 Ag2 121.7(4) . . ?
O10 N5 O9 123.6(11) . . ?
O10 N5 O11 117.3(9) . . ?
O9 N5 O11 119.1(9) . . ?
C1 O1 Sm1 167.0(5) . . ?
C13 O6 Sm1 151.6(5) . 2_776 ?
C13 O5 Sm1 143.6(4) . . ?
Sm1 O12 H12A 121(6) . . ?
Sm1 O12 H12B 107(6) . . ?
H12A O12 H12B 109(3) . . ?
Sm1 O15 H15A 124(5) . . ?
Sm1 O15 H15B 123(5) . . ?
H15A O15 H15B 109(3) . . ?
Sm1 O13 H13A 123(5) . . ?
Sm1 O13 H13B 121(5) . . ?
H13A O13 H13B 108(3) . . ?
Sm1 O16 H16A 121(5) . . ?
Sm1 O16 H16B 116(5) . . ?
H16A O16 H16B 108(3) . . ?
Sm1 O14 H14A 122(5) . . ?
Sm1 O14 H14B 120(5) . . ?
H14A O14 H14B 112(3) . . ?
H1WA O1W H1WB 112(3) . . ?
H2WA O2W H2WB 108(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C10 C9 C8 -0.9(14) . . . . ?
C10 C9 C8 C12 2.4(12) . . . . ?
C10 C9 C8 C7 -179.7(7) . . . . ?
C9 C8 C12 C11 -1.3(11) . . . . ?
C7 C8 C12 C11 -179.3(7) . . . . ?
C8 C12 C11 N2 -1.4(13) . . . . ?
C9 C8 C7 O3 177.2(7) . . . . ?
C12 C8 C7 O3 -5.0(10) . . . . ?
C9 C8 C7 O4 -1.8(10) . . . . ?
C12 C8 C7 O4 176.0(7) . . . . ?
N1 C4 C3 C2 0.4(12) . . . . ?
C4 C3 C2 C6 1.3(11) . . . . ?
C4 C3 C2 C1 -176.5(7) . . . . ?
C3 C2 C6 C5 -1.8(10) . . . . ?
C1 C2 C6 C5 175.9(6) . . . . ?
C2 C6 C5 N1 0.8(11) . . . . ?
C6 C2 C1 O2 15.3(10) . . . . ?
C3 C2 C1 O2 -167.1(7) . . . . ?
C6 C2 C1 O1 -164.7(6) . . . . ?
C3 C2 C1 O1 13.0(9) . . . . ?
N4 C22 C21 C20 -0.1(15) . . . . ?
C22 C21 C20 C24 1.3(12) . . . . ?
C22 C21 C20 C19 -180.0(8) . . . . ?
C21 C20 C24 C23 -1.4(12) . . . . ?
C19 C20 C24 C23 179.9(7) . . . . ?
C20 C24 C23 N4 0.4(14) . . . . ?
C24 C20 C19 O8 -171.9(7) . . . . ?
C21 C20 C19 O8 9.4(10) . . . . ?
C24 C20 C19 O7 6.8(10) . . . . ?
C21 C20 C19 O7 -171.9(7) . . . . ?
N3 C16 C15 C14 0.4(12) . . . . ?
C16 C15 C14 C18 -0.1(10) . . . . ?
C16 C15 C14 C13 177.9(6) . . . . ?
C15 C14 C18 C17 -0.6(10) . . . . ?
C13 C14 C18 C17 -178.6(7) . . . . ?
C14 C18 C17 N3 1.1(12) . . . . ?
C18 C14 C13 O5 -0.8(9) . . . . ?
C15 C14 C13 O5 -178.8(6) . . . . ?
C18 C14 C13 O6 -179.8(6) . . . . ?
C15 C14 C13 O6 2.2(9) . . . . ?
C12 C11 N2 C10 2.9(12) . . . . ?
C12 C11 N2 Ag1 178.3(6) . . . . ?
C9 C10 N2 C11 -1.7(13) . . . . ?
C9 C10 N2 Ag1 -177.0(7) . . . . ?
N1 Ag1 N2 C11 159.1(11) . . . . ?
Ag1 Ag1 N2 C11 -81.3(6) 2_765 . . . ?
N1 Ag1 N2 C10 -25.8(17) . . . . ?
Ag1 Ag1 N2 C10 93.8(7) 2_765 . . . ?
C6 C5 N1 C4 0.8(11) . . . . ?
C6 C5 N1 Ag1 -177.5(6) . . . . ?
C3 C4 N1 C5 -1.4(11) . . . . ?
C3 C4 N1 Ag1 177.0(6) . . . . ?
N2 Ag1 N1 C5 -156.0(11) . . . . ?
Ag1 Ag1 N1 C5 84.3(6) 2_765 . . . ?
N2 Ag1 N1 C4 25.8(16) . . . . ?
Ag1 Ag1 N1 C4 -94.0(6) 2_765 . . . ?
C24 C23 N4 C22 0.8(13) . . . . ?
C24 C23 N4 Ag2 174.8(7) . . . . ?
C21 C22 N4 C23 -0.9(14) . . . . ?
C21 C22 N4 Ag2 -174.7(7) . . . . ?
N3 Ag2 N4 C23 57.0(16) . . . . ?
N3 Ag2 N4 C22 -129.4(13) . . . . ?
C18 C17 N3 C16 -0.8(12) . . . . ?
C18 C17 N3 Ag2 179.1(6) . . . . ?
C15 C16 N3 C17 0.1(12) . . . . ?
C15 C16 N3 Ag2 -179.9(6) . . . . ?
N4 Ag2 N3 C17 -55.0(16) . . . . ?
N4 Ag2 N3 C16 124.9(13) . . . . ?
O2 C1 O1 Sm1 37(3) . . . . ?
C2 C1 O1 Sm1 -142.8(19) . . . . ?
O5 Sm1 O1 C1 150(2) . . . . ?
O6 Sm1 O1 C1 42(2) 2_776 . . . ?
O15 Sm1 O1 C1 -65(2) . . . . ?
O16 Sm1 O1 C1 5(2) . . . . ?
O13 Sm1 O1 C1 -139(2) . . . . ?
O12 Sm1 O1 C1 79(2) . . . . ?
O14 Sm1 O1 C1 -135(2) . . . . ?
O5 C13 O6 Sm1 86.3(10) . . . 2_776 ?
C14 C13 O6 Sm1 -94.8(8) . . . 2_776 ?
O6 C13 O5 Sm1 -10.6(12) . . . . ?
C14 C13 O5 Sm1 170.5(5) . . . . ?
O1 Sm1 O5 C13 -165.3(7) . . . . ?
O6 Sm1 O5 C13 -19.4(7) 2_776 . . . ?
O15 Sm1 O5 C13 94.4(8) . . . . ?
O16 Sm1 O5 C13 -83.7(8) . . . . ?
O13 Sm1 O5 C13 128.2(7) . . . . ?
O12 Sm1 O5 C13 -93.3(7) . . . . ?
O14 Sm1 O5 C13 51.5(7) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.54
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.367
_refine_diff_density_min         -1.854
_refine_diff_density_rms         0.175
#======================================

data_compound_3b
_database_code_depnum_ccdc_archive 'CCDC 718431'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C48 H52 Ag4 Eu2 N8 O26, 2(N O3), 4(H2 O)'
_chemical_formula_sum            'C48 H60 Ag4 Eu2 N10 O36'
_chemical_formula_weight         2088.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   p-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.5268(8)
_cell_length_b                   13.047(3)
_cell_length_c                   17.351(4)
_cell_angle_alpha                97.295(16)
_cell_angle_beta                 92.252(15)
_cell_angle_gamma                100.496(10)
_cell_volume                     1658.5(5)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3258
_cell_measurement_theta_min      2.13
_cell_measurement_theta_max      22.78

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      0
_exptl_crystal_density_diffrn    2.093
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1020
_exptl_absorpt_coefficient_mu    3.126
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5147
_exptl_absorpt_correction_T_max  0.6997
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omga scan'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_reflns_number            9298
_diffrn_reflns_av_R_equivalents  0.0234
_diffrn_reflns_av_sigmaI/netI    0.0391
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       1
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.60
_diffrn_reflns_theta_max         27.52
_reflns_number_total             7569
_reflns_number_gt                6551
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F² against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger. Two Hydrogen atoms of each
water molecule were restrained in idealized positions and isotropically
refined with the O-H and H...H distances restrained to 0.84(1)Å and
1.43(2Å), respectively, and Uiso values were set equal to 1.5Ueq
(parent atom) for water H atoms.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0584P)²+4.4590P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7569
_refine_ls_number_parameters     493
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0435
_refine_ls_R_factor_gt           0.0337
_refine_ls_wR_factor_ref         0.1039
_refine_ls_wR_factor_gt          0.0900
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_restrained_S_all      0.974
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.87385(3) 0.795961(15) 0.480158(11) 0.02467(7) Uani 1 1 d . . .
Ag1 Ag 1.20819(7) 0.50612(5) 0.03724(3) 0.06045(14) Uani 1 1 d . . .
Ag2 Ag 1.22848(8) 1.05914(4) 0.02509(3) 0.06101(15) Uani 1 1 d . . .
C1 C 0.9227(6) 0.5514(3) 0.3824(3) 0.0323(9) Uani 1 1 d . . .
C2 C 1.0001(6) 0.5402(3) 0.3033(2) 0.0296(9) Uani 1 1 d . . .
C3 C 1.0740(8) 0.6272(4) 0.2691(3) 0.0422(11) Uani 1 1 d . . .
H3 H 1.0832 0.6946 0.2958 0.051 Uiso 1 1 calc R . .
C4 C 1.1332(8) 0.6134(5) 0.1957(3) 0.0483(13) Uani 1 1 d . . .
H4 H 1.1828 0.6729 0.1738 0.058 Uiso 1 1 calc R . .
C5 C 1.0568(8) 0.4356(4) 0.1873(3) 0.0423(11) Uani 1 1 d . . .
H5 H 1.0519 0.3691 0.1595 0.051 Uiso 1 1 calc R . .
C6 C 0.9941(7) 0.4420(4) 0.2613(3) 0.0372(10) Uani 1 1 d . . .
H6 H 0.9486 0.3812 0.2825 0.045 Uiso 1 1 calc R . .
C7 C 1.5418(6) 0.5520(4) -0.2971(3) 0.0340(9) Uani 1 1 d . . .
C8 C 1.4652(6) 0.5417(4) -0.2172(3) 0.0341(9) Uani 1 1 d . . .
C9 C 1.4626(8) 0.6295(5) -0.1638(3) 0.0496(13) Uani 1 1 d . . .
H9 H 1.5090 0.6964 -0.1755 0.059 Uiso 1 1 calc R . .
C10 C 1.3915(9) 0.6173(5) -0.0934(4) 0.0580(16) Uani 1 1 d . . .
H10 H 1.3892 0.6773 -0.0585 0.070 Uiso 1 1 calc R . .
C11 C 1.3248(9) 0.4384(5) -0.1246(4) 0.0546(15) Uani 1 1 d . . .
H11 H 1.2757 0.3723 -0.1120 0.066 Uiso 1 1 calc R . .
C12 C 1.3944(8) 0.4449(4) -0.1965(3) 0.0470(13) Uani 1 1 d . . .
H12 H 1.3934 0.3840 -0.2309 0.056 Uiso 1 1 calc R . .
C13 C 0.9855(6) 0.9958(3) 0.3690(2) 0.0272(8) Uani 1 1 d . . .
C14 C 1.0383(6) 1.0126(3) 0.2879(2) 0.0260(8) Uani 1 1 d . . .
C15 C 1.0933(7) 1.1129(4) 0.2683(3) 0.0373(10) Uani 1 1 d . . .
H15 H 1.0961 1.1721 0.3046 0.045 Uiso 1 1 calc R . .
C16 C 1.1437(8) 1.1225(4) 0.1936(3) 0.0453(12) Uani 1 1 d . . .
H16 H 1.1793 1.1897 0.1802 0.054 Uiso 1 1 calc R . .
C17 C 1.0916(8) 0.9434(4) 0.1591(3) 0.0445(12) Uani 1 1 d . . .
H17 H 1.0926 0.8852 0.1222 0.053 Uiso 1 1 calc R . .
C18 C 1.0369(7) 0.9274(4) 0.2317(3) 0.0365(10) Uani 1 1 d . . .
H18 H 0.9988 0.8594 0.2431 0.044 Uiso 1 1 calc R . .
C19 C 1.5440(6) 1.0541(4) -0.3159(3) 0.0333(9) Uani 1 1 d . . .
C20 C 1.4738(6) 1.0553(4) -0.2344(3) 0.0336(9) Uani 1 1 d . . .
C21 C 1.4734(9) 1.1488(4) -0.1878(3) 0.0505(14) Uani 1 1 d . . .
H21 H 1.5161 1.2124 -0.2059 0.061 Uiso 1 1 calc R . .
C22 C 1.4097(9) 1.1484(5) -0.1141(3) 0.0563(15) Uani 1 1 d . . .
H22 H 1.4114 1.2126 -0.0835 0.068 Uiso 1 1 calc R . .
C23 C 1.3456(9) 0.9694(5) -0.1300(3) 0.0518(14) Uani 1 1 d . . .
H23 H 1.3020 0.9068 -0.1107 0.062 Uiso 1 1 calc R . .
C24 C 1.4064(9) 0.9638(4) -0.2037(3) 0.0485(13) Uani 1 1 d . . .
H24 H 1.4025 0.8985 -0.2331 0.058 Uiso 1 1 calc R . .
N1 N 1.1237(6) 0.5189(4) 0.1537(3) 0.0444(10) Uani 1 1 d . . .
N2 N 1.3247(7) 0.5227(4) -0.0722(3) 0.0497(11) Uani 1 1 d . . .
N3 N 1.1438(7) 1.0395(4) 0.1394(2) 0.0443(10) Uani 1 1 d . . .
N4 N 1.3459(7) 1.0599(4) -0.0849(3) 0.0488(11) Uani 1 1 d . . .
N5 N 1.0139(9) 0.2529(4) 0.0077(3) 0.0537(13) Uani 1 1 d . . .
O1 O 0.8975(6) 0.6410(3) 0.4079(2) 0.0463(9) Uani 1 1 d . . .
O2 O 0.8876(7) 0.4738(3) 0.4152(2) 0.0588(12) Uani 1 1 d . . .
O3 O 1.5468(6) 0.4689(3) -0.3395(2) 0.0490(9) Uani 1 1 d . . .
O4 O 1.5939(6) 0.6433(3) -0.3112(2) 0.0484(9) Uani 1 1 d . . .
O5 O 0.9431(5) 0.9029(2) 0.38188(19) 0.0397(8) Uani 1 1 d . . .
O6 O 0.9875(5) 1.0752(3) 0.41756(19) 0.0400(8) Uani 1 1 d . . .
O7 O 1.5224(6) 0.9681(3) -0.3578(2) 0.0560(11) Uani 1 1 d . . .
O8 O 1.6190(5) 1.1408(3) -0.3329(2) 0.0414(8) Uani 1 1 d . . .
O9 O 0.9228(9) 0.1734(4) 0.0249(3) 0.0919(19) Uani 1 1 d . . .
O10 O 0.9512(12) 0.3137(5) -0.0271(4) 0.111(2) Uani 1 1 d . . .
O11 O 1.1807(9) 0.2730(5) 0.0261(4) 0.0920(18) Uani 1 1 d . . .
O12 O 0.6212(5) 0.7395(3) 0.3821(2) 0.0411(8) Uani 1 1 d D . .
H12A H 0.544(6) 0.776(3) 0.370(4) 0.062 Uiso 1 1 d D . .
H12B H 0.575(7) 0.6740(16) 0.370(4) 0.062 Uiso 1 1 d D . .
O13 O 1.2004(5) 0.8107(3) 0.4615(2) 0.0449(9) Uani 1 1 d D . .
H13A H 1.260(8) 0.831(5) 0.424(3) 0.067 Uiso 1 1 d D . .
H13B H 1.244(8) 0.763(4) 0.480(3) 0.067 Uiso 1 1 d D . .
O14 O 0.6746(5) 0.9272(3) 0.5009(2) 0.0439(8) Uani 1 1 d D . .
H14A H 0.679(9) 0.974(4) 0.471(3) 0.066 Uiso 1 1 d D . .
H14B H 0.605(8) 0.936(5) 0.537(3) 0.066 Uiso 1 1 d D . .
O15 O 0.6369(5) 0.7083(3) 0.5483(2) 0.0454(9) Uani 1 1 d D . .
H15A H 0.542(6) 0.676(5) 0.520(3) 0.068 Uiso 1 1 d D . .
H15B H 0.634(8) 0.683(5) 0.592(2) 0.068 Uiso 1 1 d D . .
O16 O 1.0007(5) 0.7092(3) 0.5782(2) 0.0378(7) Uani 1 1 d D . .
H16A H 1.100(5) 0.737(4) 0.603(3) 0.057 Uiso 1 1 d D . .
H16B H 0.992(8) 0.6418(15) 0.572(4) 0.057 Uiso 1 1 d D . .
O1W O 0.6775(6) 0.2288(3) 0.3410(3) 0.0550(10) Uani 1 1 d D . .
H1WA H 0.614(8) 0.276(4) 0.335(5) 0.082 Uiso 1 1 d D . .
H1WB H 0.608(7) 0.173(3) 0.350(5) 0.082 Uiso 1 1 d D . .
O2W O 0.3177(5) 0.6100(3) 0.4736(2) 0.0445(8) Uani 1 1 d D . .
H2WA H 0.370(8) 0.566(4) 0.445(3) 0.067 Uiso 1 1 d D . .
H2WB H 0.259(8) 0.575(4) 0.507(3) 0.067 Uiso 1 1 d D . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.278(3) . ?
Eu1 O5 2.351(3) . ?
Eu1 O6 2.349(3) 2_776 ?
Eu1 O15 2.376(3) . ?
Eu1 O16 2.416(3) . ?
Eu1 O12 2.444(4) . ?
Eu1 O13 2.467(4) . ?
Eu1 O14 2.475(3) . ?
Ag2 N3 2.137(4) . ?
Ag2 N4 2.134(4) . ?
Ag1 N1 2.136(4) . ?
Ag1 N2 2.141(4) . ?
Ag1 Ag1 3.3121(11) 2_765 ?
C10 N2 1.346(8) . ?
C10 C9 1.367(8) . ?
C10 H10 0.9300 . ?
C9 C8 1.382(7) . ?
C9 H9 0.9300 . ?
C8 C12 1.376(7) . ?
C8 C7 1.533(6) . ?
C12 C11 1.378(7) . ?
C12 H12 0.9300 . ?
C11 N2 1.334(8) . ?
C11 H11 0.9300 . ?
C7 O3 1.237(6) . ?
C7 O4 1.243(6) . ?
C4 N1 1.338(7) . ?
C4 C3 1.366(7) . ?
C4 H4 0.9300 . ?
C3 C2 1.384(6) . ?
C3 H3 0.9300 . ?
C2 C6 1.383(6) . ?
C2 C1 1.512(6) . ?
C6 C5 1.383(7) . ?
C6 H6 0.9300 . ?
C5 N1 1.326(7) . ?
C5 H5 0.9300 . ?
C1 O2 1.215(6) . ?
C1 O1 1.246(5) . ?
C22 N4 1.336(7) . ?
C22 C21 1.384(8) . ?
C22 H22 0.9300 . ?
C21 C20 1.375(7) . ?
C21 H21 0.9300 . ?
C20 C24 1.388(7) . ?
C20 C19 1.527(6) . ?
C24 C23 1.372(7) . ?
C24 H24 0.9300 . ?
C23 N4 1.330(8) . ?
C23 H23 0.9300 . ?
C19 O8 1.244(6) . ?
C19 O7 1.238(6) . ?
C16 N3 1.341(7) . ?
C16 C15 1.377(7) . ?
C16 H16 0.9300 . ?
C15 C14 1.387(6) . ?
C15 H15 0.9300 . ?
C14 C18 1.379(6) . ?
C14 C13 1.508(5) . ?
C18 C17 1.368(7) . ?
C18 H18 0.9300 . ?
C17 N3 1.335(7) . ?
C17 H17 0.9300 . ?
C13 O5 1.246(5) . ?
C13 O6 1.247(5) . ?
N5 O10 1.205(8) . ?
N5 O9 1.213(7) . ?
N5 O11 1.255(8) . ?
O6 Eu1 2.349(3) 2_776 ?
O13 H13A 0.848(19) . ?
O13 H13B 0.848(19) . ?
O15 H15A 0.86(2) . ?
O15 H15B 0.865(19) . ?
O12 H12A 0.848(19) . ?
O12 H12B 0.858(19) . ?
O16 H16A 0.848(19) . ?
O16 H16B 0.862(19) . ?
O14 H14A 0.839(19) . ?
O14 H14B 0.841(19) . ?
O1W H1WA 0.86(2) . ?
O1W H1WB 0.85(2) . ?
O2W H2WA 0.865(19) . ?
O2W H2WB 0.868(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O5 96.63(13) . . ?
O1 Eu1 O6 144.20(14) . 2_776 ?
O5 Eu1 O6 94.99(12) . 2_776 ?
O1 Eu1 O15 90.85(15) . . ?
O5 Eu1 O15 144.95(14) . . ?
O6 Eu1 O15 98.69(13) 2_776 . ?
O1 Eu1 O16 79.51(13) . . ?
O5 Eu1 O16 144.57(13) . . ?
O6 Eu1 O16 71.57(12) 2_776 . ?
O15 Eu1 O16 70.46(13) . . ?
O1 Eu1 O12 69.27(14) . . ?
O5 Eu1 O12 75.04(13) . . ?
O6 Eu1 O12 146.53(13) 2_776 . ?
O15 Eu1 O12 75.81(13) . . ?
O16 Eu1 O12 133.11(12) . . ?
O1 Eu1 O13 75.36(14) . . ?
O5 Eu1 O13 72.68(13) . . ?
O6 Eu1 O13 76.07(14) 2_776 . ?
O15 Eu1 O13 142.03(13) . . ?
O16 Eu1 O13 72.29(12) . . ?
O13 Eu1 O13 128.10(13) . . ?
O1 Eu1 O14 142.83(15) . . ?
O5 Eu1 O14 76.00(12) . . ?
O6 Eu1 O14 72.92(14) 2_776 . ?
O15 Eu1 O14 77.47(14) . . ?
O16 Eu1 O14 126.92(12) . . ?
O12 Eu1 O14 73.66(13) . . ?
O13 Eu1 O14 133.16(13) . . ?
N3 Ag2 N4 169.52(19) . . ?
N1 Ag1 N2 168.9(2) . . ?
N1 Ag1 Ag1 92.29(13) . 2_765 ?
N2 Ag1 Ag1 92.99(14) . 2_765 ?
N2 C10 C9 123.3(6) . . ?
N2 C10 H10 118.4 . . ?
C9 C10 H10 118.4 . . ?
C10 C9 C8 119.5(5) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C9 C8 C12 117.6(5) . . ?
C9 C8 C7 121.2(4) . . ?
C12 C8 C7 121.2(5) . . ?
C11 C12 C8 119.8(5) . . ?
C11 C12 H12 120.1 . . ?
C8 C12 H12 120.1 . . ?
N2 C11 C12 122.9(5) . . ?
N2 C11 H11 118.5 . . ?
C12 C11 H11 118.5 . . ?
O3 C7 O4 127.6(4) . . ?
O3 C7 C8 116.6(4) . . ?
O4 C7 C8 115.8(4) . . ?
N1 C4 C3 123.5(5) . . ?
N1 C4 H4 118.2 . . ?
C3 C4 H4 118.2 . . ?
C4 C3 C2 119.6(5) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C6 C2 C3 117.5(4) . . ?
C6 C2 C1 120.9(4) . . ?
C3 C2 C1 121.6(4) . . ?
C5 C6 C2 118.9(4) . . ?
C5 C6 H6 120.5 . . ?
C2 C6 H6 120.5 . . ?
N1 C5 C6 123.6(5) . . ?
N1 C5 H5 118.2 . . ?
C6 C5 H5 118.2 . . ?
O2 C1 O1 125.5(5) . . ?
O2 C1 C2 118.5(4) . . ?
O1 C1 C2 116.0(4) . . ?
N4 C22 C21 122.9(5) . . ?
N4 C22 H22 118.6 . . ?
C21 C22 H22 118.6 . . ?
C20 C21 C22 120.1(5) . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C24 C20 C21 116.6(5) . . ?
C24 C20 C19 122.5(4) . . ?
C21 C20 C19 120.9(4) . . ?
C20 C24 C23 120.2(5) . . ?
C20 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
N4 C23 C24 123.2(5) . . ?
N4 C23 H23 118.4 . . ?
C24 C23 H23 118.4 . . ?
O8 C19 O7 126.7(4) . . ?
O8 C19 C20 115.9(4) . . ?
O7 C19 C20 117.4(4) . . ?
N3 C16 C15 123.1(5) . . ?
N3 C16 H16 118.5 . . ?
C15 C16 H16 118.5 . . ?
C16 C15 C14 118.4(4) . . ?
C16 C15 H15 120.8 . . ?
C14 C15 H15 120.8 . . ?
C18 C14 C15 118.4(4) . . ?
C18 C14 C13 120.2(4) . . ?
C15 C14 C13 121.4(4) . . ?
C17 C18 C14 119.8(4) . . ?
C17 C18 H18 120.1 . . ?
C14 C18 H18 120.1 . . ?
N3 C17 C18 122.4(5) . . ?
N3 C17 H17 118.8 . . ?
C18 C17 H17 118.8 . . ?
O5 C13 O6 125.3(4) . . ?
O5 C13 C14 116.9(4) . . ?
O6 C13 C14 117.9(4) . . ?
C11 N2 C10 116.9(5) . . ?
C11 N2 Ag1 120.6(4) . . ?
C10 N2 Ag1 122.4(4) . . ?
C5 N1 C4 116.8(4) . . ?
C5 N1 Ag1 122.6(4) . . ?
C4 N1 Ag1 120.6(3) . . ?
C23 N4 C22 117.2(5) . . ?
C23 N4 Ag2 119.8(4) . . ?
C22 N4 Ag2 122.9(4) . . ?
C17 N3 C16 117.9(4) . . ?
C17 N3 Ag2 120.6(4) . . ?
C16 N3 Ag2 121.5(3) . . ?
O10 N5 O9 122.6(8) . . ?
O10 N5 O11 118.2(7) . . ?
O9 N5 O11 119.1(7) . . ?
C1 O1 Eu1 167.3(4) . . ?
C13 O6 Eu1 152.6(3) . 2_776 ?
C13 O5 Eu1 143.9(3) . . ?
Eu1 O13 H13A 129(4) . . ?
Eu1 O13 H13B 112(4) . . ?
H13A O13 H13B 110(3) . . ?
Eu1 O15 H15A 115(4) . . ?
Eu1 O15 H15B 134(4) . . ?
H15A O15 H15B 107(2) . . ?
Eu1 O12 H12A 126(4) . . ?
Eu1 O12 H12B 121(4) . . ?
H12A O12 H12B 109(3) . . ?
Eu1 O16 H16A 121(4) . . ?
Eu1 O16 H16B 121(4) . . ?
H16A O16 H16B 109(2) . . ?
Eu1 O14 H14A 119(4) . . ?
Eu1 O14 H14B 129(4) . . ?
H14A O14 H14B 112(3) . . ?
H1WA O6W H1WB 109(3) . . ?
H2WA O2W H2WB 107(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C10 C9 C8 1.0(10) . . . . ?
C10 C9 C8 C12 0.2(9) . . . . ?
C10 C9 C8 C7 179.3(5) . . . . ?
C9 C8 C12 C11 -0.1(8) . . . . ?
C7 C8 C12 C11 -179.3(5) . . . . ?
C8 C12 C11 N2 -1.0(10) . . . . ?
C9 C8 C7 O3 176.5(5) . . . . ?
C12 C8 C7 O3 -4.4(7) . . . . ?
C9 C8 C7 O4 -2.6(7) . . . . ?
C12 C8 C7 O4 176.5(5) . . . . ?
N1 C4 C3 C2 0.2(9) . . . . ?
C4 C3 C2 C6 1.6(8) . . . . ?
C4 C3 C2 C1 -176.4(5) . . . . ?
C3 C2 C6 C5 -1.7(7) . . . . ?
C1 C2 C6 C5 176.2(5) . . . . ?
C2 C6 C5 N1 0.1(9) . . . . ?
C6 C2 C1 O2 14.2(7) . . . . ?
C3 C2 C1 O2 -167.9(5) . . . . ?
C6 C2 C1 O1 -164.6(5) . . . . ?
C3 C2 C1 O1 13.3(7) . . . . ?
N4 C22 C21 C20 -0.3(11) . . . . ?
C22 C21 C20 C24 0.6(9) . . . . ?
C22 C21 C20 C19 -179.8(6) . . . . ?
C21 C20 C24 C23 -0.7(9) . . . . ?
C19 C20 C24 C23 179.8(5) . . . . ?
C20 C24 C23 N4 0.5(10) . . . . ?
C24 C20 C19 O8 -172.2(5) . . . . ?
C21 C20 C19 O8 8.2(7) . . . . ?
C24 C20 C19 O7 7.2(8) . . . . ?
C21 C20 C19 O7 -172.3(5) . . . . ?
N3 C16 C15 C14 -0.7(9) . . . . ?
C16 C15 C14 C18 0.0(7) . . . . ?
C16 C15 C14 C13 178.5(5) . . . . ?
C15 C14 C18 C17 1.0(7) . . . . ?
C13 C14 C18 C17 -177.5(5) . . . . ?
C14 C18 C17 N3 -1.5(9) . . . . ?
C18 C14 C13 O5 0.6(6) . . . . ?
C15 C14 C13 O5 -177.9(5) . . . . ?
C18 C14 C13 O6 -179.5(4) . . . . ?
C15 C14 C13 O6 2.1(7) . . . . ?
C12 C11 N2 C10 2.1(10) . . . . ?
C12 C11 N2 Ag1 178.6(5) . . . . ?
C9 C10 N2 C11 -2.1(10) . . . . ?
C9 C10 N2 Ag1 -178.5(5) . . . . ?
N1 Ag1 N2 C11 159.6(8) . . . . ?
Ag1 Ag1 N2 C11 -82.0(5) 2_765 . . . ?
N1 Ag1 N2 C10 -24.1(13) . . . . ?
Ag1 Ag1 N2 C10 94.3(5) 2_765 . . . ?
C6 C5 N1 C4 1.6(8) . . . . ?
C6 C5 N1 Ag1 -177.1(4) . . . . ?
C3 C4 N1 C5 -1.8(9) . . . . ?
C3 C4 N1 Ag1 177.0(5) . . . . ?
N2 Ag1 N1 C5 -156.8(9) . . . . ?
Ag1 Ag1 N1 C5 84.8(4) 2_765 . . . ?
N2 Ag1 N1 C4 24.5(12) . . . . ?
Ag1 Ag1 N1 C4 -93.9(4) 2_765 . . . ?
C24 C23 N4 C22 -0.2(10) . . . . ?
C24 C23 N4 Ag2 175.1(5) . . . . ?
C21 C22 N4 C23 0.1(10) . . . . ?
C21 C22 N4 Ag2 -175.0(5) . . . . ?
N3 Ag2 N4 C23 55.0(13) . . . . ?
N3 Ag2 N4 C22 -130.0(10) . . . . ?
C18 C17 N3 C16 0.8(9) . . . . ?
C18 C17 N3 Ag2 179.9(4) . . . . ?
C15 C16 N3 C17 0.3(9) . . . . ?
C15 C16 N3 Ag2 -178.8(4) . . . . ?
N4 Ag2 N3 C17 -52.8(13) . . . . ?
N4 Ag2 N3 C16 126.2(10) . . . . ?
O2 C1 O1 Eu1 40(2) . . . . ?
C2 C1 O1 Eu1 -141.0(15) . . . . ?
O5 Eu1 O1 C1 147.0(17) . . . . ?
O6 Eu1 O1 C1 38.8(18) 2_776 . . . ?
O15 Eu1 O1 C1 -67.3(17) . . . . ?
O16 Eu1 O1 C1 2.6(17) . . . . ?
O12 Eu1 O1 C1 -141.8(17) . . . . ?
O13 Eu1 O1 C1 76.9(17) . . . . ?
O14 Eu1 O1 C1 -137.5(16) . . . . ?
O5 C13 O6 Eu1 84.9(8) . . . 2_776 ?
C14 C13 O6 Eu1 -95.0(7) . . . 2_776 ?
O6 C13 O5 Eu1 -8.1(9) . . . . ?
C14 C13 O5 Eu1 171.8(4) . . . . ?
O1 Eu1 O5 C13 -166.5(6) . . . . ?
O6 Eu1 O5 C13 -20.4(6) 2_776 . . . ?
O15 Eu1 O5 C13 92.5(6) . . . . ?
O16 Eu1 O5 C13 -85.2(6) . . . . ?
O12 Eu1 O5 C13 127.1(6) . . . . ?
O13 Eu1 O5 C13 -94.1(6) . . . . ?
O14 Eu1 O5 C13 50.6(6) . . . . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        27.52
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         1.452
_refine_diff_density_min         -1.364
_refine_diff_density_rms         0.131

