# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_r19_MTG_GeEt3_1_0m_a
_database_code_depnum_ccdc_archive 'CCDC 1983059'
loop_
_audit_author_name
_audit_author_address
'Simon Rachor'
;Humboldt Universitaet zu Berlin
Germany
;
_audit_update_record             
;
2020-02-18 deposited with the CCDC.	2020-03-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H19 B F20 Ge O2'
_chemical_formula_sum            'C30 H19 B F20 Ge O2'
_chemical_formula_weight         874.85

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   14.3032(13)
_cell_length_b                   17.5925(15)
_cell_length_c                   24.968(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     6282.8(10)
_cell_formula_units_Z            8
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9716
_cell_measurement_theta_min      2.46
_cell_measurement_theta_max      25.04

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_F_000             3456
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.355
_exptl_crystal_size_min          0.24
_exptl_absorpt_coefficient_mu    1.125
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5653
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_process_details   SADABS-2016/2
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            75256
_diffrn_reflns_av_unetI/netI     0.0134
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         2.165
_diffrn_reflns_theta_max         25.082
_diffrn_reflns_theta_full        25.082
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             5570
_reflns_number_gt                5100
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5570
_refine_ls_number_parameters     504
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0312
_refine_ls_R_factor_gt           0.0276
_refine_ls_wR_factor_ref         0.1112
_refine_ls_wR_factor_gt          0.1051
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.45189(7) 0.73032(5) 0.34321(4) 0.0202(3) Uani 1 1 d . . . . .
F2 F 0.61283(7) 0.73593(6) 0.39438(4) 0.0219(3) Uani 1 1 d . . . . .
F3 F 0.72386(8) 0.61044(7) 0.40262(4) 0.0252(3) Uani 1 1 d . . . . .
F4 F 0.66534(7) 0.47658(6) 0.35871(5) 0.0197(3) Uani 1 1 d . . . . .
F5 F 0.49840(7) 0.46708(5) 0.31225(4) 0.0159(2) Uani 1 1 d . . . . .
F6 F 0.38435(7) 0.50789(6) 0.40654(4) 0.0164(2) Uani 1 1 d . . . . .
F7 F 0.26490(8) 0.41278(6) 0.44989(4) 0.0210(3) Uani 1 1 d . . . . .
F8 F 0.11113(8) 0.36447(7) 0.39512(5) 0.0256(3) Uani 1 1 d . . . . .
F9 F 0.07787(7) 0.42014(6) 0.29471(4) 0.0221(3) Uani 1 1 d . . . . .
F10 F 0.18960(7) 0.52501(6) 0.25296(4) 0.0177(2) Uani 1 1 d . . . . .
F11 F 0.33307(7) 0.43473(6) 0.23131(4) 0.0179(2) Uani 1 1 d . . . . .
F12 F 0.38974(8) 0.41026(6) 0.13280(4) 0.0233(3) Uani 1 1 d . . . . .
F13 F 0.49078(8) 0.51618(7) 0.07874(4) 0.0267(3) Uani 1 1 d . . . . .
F14 F 0.53217(8) 0.65129(7) 0.12767(4) 0.0251(3) Uani 1 1 d . . . . .
F15 F 0.46813(8) 0.68152(6) 0.22557(4) 0.0184(2) Uani 1 1 d . . . . .
F16 F 0.26895(8) 0.67368(6) 0.20282(4) 0.0181(3) Uani 1 1 d . . . . .
F17 F 0.14194(8) 0.77957(6) 0.21438(4) 0.0225(3) Uani 1 1 d . . . . .
F18 F 0.09036(8) 0.82913(6) 0.31403(5) 0.0240(3) Uani 1 1 d . . . . .
F19 F 0.17300(7) 0.76810(6) 0.40186(4) 0.0209(3) Uani 1 1 d . . . . .
F20 F 0.30051(8) 0.65855(6) 0.39180(4) 0.0166(2) Uani 1 1 d . . . . .
O1 O 0.78881(11) 0.81137(9) 0.38647(6) 0.0246(3) Uani 1 1 d . . . . .
H1 H 0.735(2) 0.8067(15) 0.3864(2) 0.037 Uiso 1 1 calc R U . . .
O2 O 0.87877(11) 0.82725(9) 0.30171(6) 0.0247(3) Uani 1 1 d D . . . .
C1 C 0.82016(14) 0.73668(11) 0.49208(8) 0.0238(4) Uani 1 1 d . . . . .
H1A H 0.831237 0.742735 0.530982 0.029 Uiso 1 1 calc R U . . .
H1AB H 0.755721 0.717313 0.487256 0.029 Uiso 1 1 calc R U . . .
C2 C 0.88901(16) 0.67836(13) 0.46989(10) 0.0290(5) Uani 1 1 d . . . . .
H2A H 0.879040 0.672543 0.431274 0.044 Uiso 1 1 calc R U . . .
H2B H 0.879108 0.629365 0.487688 0.044 Uiso 1 1 calc R U . . .
H2C H 0.953101 0.695711 0.476458 0.044 Uiso 1 1 calc R U . . .
C3 C 0.74437(14) 0.91273(11) 0.48110(9) 0.0258(5) Uani 1 1 d . . . . .
H3A H 0.772170 0.939917 0.511953 0.031 Uiso 1 1 calc R U . . .
H3AB H 0.736469 0.949984 0.451733 0.031 Uiso 1 1 calc R U . . .
C4 C 0.64836(16) 0.88316(13) 0.49733(9) 0.0323(5) Uani 1 1 d . . . . .
H4A H 0.608412 0.925960 0.507684 0.048 Uiso 1 1 calc R U . . .
H4B H 0.654925 0.848248 0.527683 0.048 Uiso 1 1 calc R U . . .
H4C H 0.619983 0.856235 0.467056 0.048 Uiso 1 1 calc R U . . .
C5 C 0.95775(14) 0.86672(13) 0.44489(8) 0.0273(5) Uani 1 1 d . . . . .
H5A H 0.989140 0.829698 0.421055 0.033 Uiso 1 1 calc R U . . .
H5AB H 0.957872 0.916848 0.426867 0.033 Uiso 1 1 calc R U . . .
C6 C 1.01090(15) 0.87219(14) 0.49801(9) 0.0346(5) Uani 1 1 d . . . . .
H6A H 1.074925 0.889513 0.491209 0.052 Uiso 1 1 calc R U . . .
H6B H 1.012503 0.822099 0.515149 0.052 Uiso 1 1 calc R U . . .
H6C H 0.979263 0.908467 0.521649 0.052 Uiso 1 1 calc R U . . .
C7 C 0.46353(12) 0.59719(10) 0.32667(7) 0.0126(4) Uani 1 1 d . . . . .
C8 C 0.49915(13) 0.66406(9) 0.34715(8) 0.0145(4) Uani 1 1 d . . . . .
C9 C 0.58448(14) 0.66916(10) 0.37326(7) 0.0160(4) Uani 1 1 d . . . . .
C10 C 0.64054(12) 0.60622(11) 0.37792(7) 0.0177(4) Uani 1 1 d . . . . .
C11 C 0.61071(12) 0.53887(10) 0.35593(7) 0.0151(4) Uani 1 1 d . . . . .
C12 C 0.52438(12) 0.53608(9) 0.33169(7) 0.0124(4) Uani 1 1 d . . . . .
C13 C 0.29707(12) 0.51948(9) 0.32545(7) 0.0126(4) Uani 1 1 d . . . . .
C14 C 0.30958(12) 0.48878(10) 0.37585(7) 0.0139(4) Uani 1 1 d . . . . .
C15 C 0.24874(13) 0.43839(10) 0.39980(7) 0.0147(4) Uani 1 1 d . . . . .
C16 C 0.16999(12) 0.41433(10) 0.37291(8) 0.0168(4) Uani 1 1 d . . . . .
C17 C 0.15356(12) 0.44356(10) 0.32268(7) 0.0167(4) Uani 1 1 d . . . . .
C18 C 0.21403(12) 0.49591(10) 0.30127(7) 0.0137(4) Uani 1 1 d . . . . .
C19 C 0.39389(11) 0.56097(10) 0.23398(7) 0.0127(4) Uani 1 1 d . . . . .
C20 C 0.37834(12) 0.49304(10) 0.20732(7) 0.0141(4) Uani 1 1 d . . . . .
C21 C 0.40824(12) 0.47810(10) 0.15565(7) 0.0174(4) Uani 1 1 d . . . . .
C22 C 0.45967(13) 0.53039(11) 0.12847(7) 0.0189(4) Uani 1 1 d . . . . .
C23 C 0.48045(12) 0.59845(11) 0.15337(7) 0.0174(4) Uani 1 1 d . . . . .
C24 C 0.44728(12) 0.61149(10) 0.20410(7) 0.0148(4) Uani 1 1 d . . . . .
C25 C 0.29362(13) 0.65998(9) 0.29701(7) 0.0131(4) Uani 1 1 d . . . . .
C26 C 0.24951(12) 0.69456(10) 0.25394(7) 0.0148(4) Uani 1 1 d . . . . .
C27 C 0.18263(12) 0.75083(10) 0.25853(8) 0.0157(4) Uani 1 1 d . . . . .
C28 C 0.15672(12) 0.77633(10) 0.30813(8) 0.0174(4) Uani 1 1 d . . . . .
C29 C 0.19883(13) 0.74459(10) 0.35269(7) 0.0155(4) Uani 1 1 d . . . . .
C30 C 0.26407(12) 0.68853(10) 0.34613(7) 0.0142(4) Uani 1 1 d . . . . .
B1 B 0.36272(14) 0.58457(11) 0.29546(8) 0.0127(4) Uani 1 1 d . . . . .
Ge1 Ge 0.83053(2) 0.83481(2) 0.45788(2) 0.01770(11) Uani 1 1 d . . . . .
H2 H 0.903(5) 0.787(3) 0.284(3) 0.27(4) Uiso 1 1 d D . . . .
H3 H 0.9035(18) 0.8628(17) 0.2954(11) 0.033(8) Uiso 1 1 d . . . . .
H4 H 0.825(2) 0.8141(18) 0.3550(14) 0.062(10) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C8 1.351(2) . ?
F2 C9 1.350(2) . ?
F3 C10 1.344(2) . ?
F4 C11 1.348(2) . ?
F5 C12 1.3592(19) . ?
F6 C14 1.358(2) . ?
F7 C15 1.349(2) . ?
F8 C16 1.336(2) . ?
F9 C17 1.353(2) . ?
F10 C18 1.356(2) . ?
F11 C20 1.353(2) . ?
F12 C21 1.349(2) . ?
F13 C22 1.343(2) . ?
F14 C23 1.350(2) . ?
F15 C24 1.376(2) . ?
F16 C26 1.357(2) . ?
F17 C27 1.345(2) . ?
F18 C28 1.336(2) . ?
F19 C29 1.347(2) . ?
F20 C30 1.360(2) . ?
O1 Ge1 1.9247(14) . ?
O1 H1 0.77(3) . ?
O1 H4 0.94(4) . ?
O2 H2 0.91(2) . ?
O2 H3 0.74(3) . ?
C1 C2 1.526(3) . ?
C1 Ge1 1.932(2) . ?
C1 H1A 0.9900 . ?
C1 H1AB 0.9900 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.523(3) . ?
C3 Ge1 1.9324(19) . ?
C3 H3A 0.9900 . ?
C3 H3AB 0.9900 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 C6 1.532(3) . ?
C5 Ge1 1.932(2) . ?
C5 H5A 0.9900 . ?
C5 H5AB 0.9900 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.380(2) . ?
C7 C12 1.389(2) . ?
C7 B1 1.654(3) . ?
C8 C9 1.387(3) . ?
C9 C10 1.372(3) . ?
C10 C11 1.374(3) . ?
C11 C12 1.376(2) . ?
C13 C14 1.381(2) . ?
C13 C18 1.395(2) . ?
C13 B1 1.659(3) . ?
C14 C15 1.379(3) . ?
C15 C16 1.378(3) . ?
C16 C17 1.376(3) . ?
C17 C18 1.372(3) . ?
C19 C20 1.386(3) . ?
C19 C24 1.389(2) . ?
C19 B1 1.652(3) . ?
C20 C21 1.384(3) . ?
C21 C22 1.359(3) . ?
C22 C23 1.381(3) . ?
C23 C24 1.372(3) . ?
C25 C26 1.387(3) . ?
C25 C30 1.391(3) . ?
C25 B1 1.655(2) . ?
C26 C27 1.381(3) . ?
C27 C28 1.368(3) . ?
C28 C29 1.383(3) . ?
C29 C30 1.368(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge1 O1 H1 109.5 . . ?
Ge1 O1 H4 126.6(19) . . ?
H1 O1 H4 123.0 . . ?
H2 O2 H3 112(6) . . ?
C2 C1 Ge1 113.00(14) . . ?
C2 C1 H1A 109.0 . . ?
Ge1 C1 H1A 109.0 . . ?
C2 C1 H1AB 109.0 . . ?
Ge1 C1 H1AB 109.0 . . ?
H1A C1 H1AB 107.8 . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C4 C3 Ge1 114.36(14) . . ?
C4 C3 H3A 108.7 . . ?
Ge1 C3 H3A 108.7 . . ?
C4 C3 H3AB 108.7 . . ?
Ge1 C3 H3AB 108.7 . . ?
H3A C3 H3AB 107.6 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C6 C5 Ge1 109.90(14) . . ?
C6 C5 H5A 109.7 . . ?
Ge1 C5 H5A 109.7 . . ?
C6 C5 H5AB 109.7 . . ?
Ge1 C5 H5AB 109.7 . . ?
H5A C5 H5AB 108.2 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 C12 113.27(15) . . ?
C8 C7 B1 127.63(15) . . ?
C12 C7 B1 119.01(15) . . ?
F1 C8 C7 121.59(17) . . ?
F1 C8 C9 114.76(15) . . ?
C7 C8 C9 123.66(16) . . ?
F2 C9 C10 119.58(17) . . ?
F2 C9 C8 120.29(16) . . ?
C10 C9 C8 120.13(16) . . ?
F3 C10 C9 120.83(17) . . ?
F3 C10 C11 120.43(17) . . ?
C9 C10 C11 118.73(16) . . ?
F4 C11 C10 120.04(16) . . ?
F4 C11 C12 120.93(16) . . ?
C10 C11 C12 119.02(17) . . ?
F5 C12 C11 115.73(15) . . ?
F5 C12 C7 119.20(15) . . ?
C11 C12 C7 125.06(16) . . ?
C14 C13 C18 112.84(16) . . ?
C14 C13 B1 127.43(16) . . ?
C18 C13 B1 119.44(15) . . ?
F6 C14 C15 114.31(16) . . ?
F6 C14 C13 121.29(16) . . ?
C15 C14 C13 124.39(17) . . ?
F7 C15 C16 119.28(16) . . ?
F7 C15 C14 120.57(16) . . ?
C16 C15 C14 120.15(17) . . ?
F8 C16 C17 121.07(16) . . ?
F8 C16 C15 120.96(17) . . ?
C17 C16 C15 117.97(17) . . ?
F9 C17 C18 120.54(17) . . ?
F9 C17 C16 119.57(16) . . ?
C18 C17 C16 119.90(17) . . ?
F10 C18 C17 115.94(16) . . ?
F10 C18 C13 119.47(15) . . ?
C17 C18 C13 124.58(17) . . ?
C20 C19 C24 112.46(16) . . ?
C20 C19 B1 128.30(15) . . ?
C24 C19 B1 119.13(15) . . ?
F11 C20 C21 114.62(15) . . ?
F11 C20 C19 121.20(15) . . ?
C21 C20 C19 124.17(16) . . ?
F12 C21 C22 119.60(16) . . ?
F12 C21 C20 120.09(16) . . ?
C22 C21 C20 120.26(16) . . ?
F13 C22 C21 120.99(16) . . ?
F13 C22 C23 120.42(17) . . ?
C21 C22 C23 118.58(17) . . ?
F14 C23 C24 120.87(16) . . ?
F14 C23 C22 120.05(16) . . ?
C24 C23 C22 119.08(16) . . ?
C23 C24 F15 115.74(15) . . ?
C23 C24 C19 125.38(16) . . ?
F15 C24 C19 118.86(15) . . ?
C26 C25 C30 112.76(16) . . ?
C26 C25 B1 127.23(16) . . ?
C30 C25 B1 119.45(15) . . ?
F16 C26 C27 114.46(15) . . ?
F16 C26 C25 121.15(15) . . ?
C27 C26 C25 124.39(17) . . ?
F17 C27 C28 120.09(16) . . ?
F17 C27 C26 120.06(17) . . ?
C28 C27 C26 119.84(17) . . ?
F18 C28 C27 121.34(17) . . ?
F18 C28 C29 120.09(17) . . ?
C27 C28 C29 118.55(16) . . ?
F19 C29 C30 121.17(16) . . ?
F19 C29 C28 119.33(16) . . ?
C30 C29 C28 119.47(17) . . ?
F20 C30 C29 116.14(16) . . ?
F20 C30 C25 118.86(15) . . ?
C29 C30 C25 124.98(17) . . ?
C19 B1 C7 103.66(13) . . ?
C19 B1 C25 112.61(14) . . ?
C7 B1 C25 113.71(14) . . ?
C19 B1 C13 113.50(14) . . ?
C7 B1 C13 111.92(14) . . ?
C25 B1 C13 101.82(14) . . ?
O1 Ge1 C5 101.47(8) . . ?
O1 Ge1 C1 101.20(8) . . ?
C5 Ge1 C1 113.97(9) . . ?
O1 Ge1 C3 103.43(8) . . ?
C5 Ge1 C3 116.42(9) . . ?
C1 Ge1 C3 116.89(9) . . ?

_refine_diff_density_max         0.359
_refine_diff_density_min         -0.711
_refine_diff_density_rms         0.062

