# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_sfw12s
_database_code_depnum_ccdc_archive 'CCDC 1959154'
loop_
_audit_author_name
_audit_author_address
'Fangwei Shao'
;Zhejiang University
China
;
_audit_update_record             
;
2019-10-14 deposited with the CCDC.	2020-10-27 downloaded from the CCDC.
;
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C51 H34 F12 N10 O P2 Pt2'
_chemical_formula_iupac          ?
_chemical_formula_weight         1483.00

_chemical_melting_point          ?

_space_group_crystal_system      monoclinic
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   6.8545(3)
_cell_length_b                   39.3855(16)
_cell_length_c                   17.3529(7)
_cell_angle_alpha                90
_cell_angle_beta                 98.991(2)
_cell_angle_gamma                90
_cell_volume                     4627.2(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9405
_cell_measurement_theta_min      2.2436
_cell_measurement_theta_max      66.5998
_cell_measurement_temperature    103.(2)

_exptl_crystal_description       needle
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.020
_exptl_crystal_density_diffrn    2.129
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2848

_exptl_absorpt_coefficient_mu    12.723
_exptl_absorpt_correction_type   Multi-Scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
;
_exptl_absorpt_correction_T_min  0.42
_exptl_absorpt_correction_T_max  0.79

_exptl_special_details           
;
;

_diffrn_ambient_temperature      103.(2)

_diffrn_source                   'Incoatec Microfocus Source'
_diffrn_source_type              'Bruker Kappa Duo APEX2'

_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_monochromator  'Multilayer Mirror'

_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'

_diffrn_detector_area_resol_mean 8.3333

_diffrn_reflns_number            50559
_diffrn_reflns_av_R_equivalents  0.0589
_diffrn_reflns_av_unetI/netI     0.0392
_diffrn_reflns_theta_min         2.24
_diffrn_reflns_theta_max         66.69
_diffrn_reflns_theta_full        66.69
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -46
_diffrn_reflns_limit_k_max       46
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20

_refine_special_details          
;
;

_reflns_number_total             8170
_reflns_number_gt                7587
_reflns_threshold_expression     'I > 2σ(I)'

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.0472
_refine_ls_R_factor_gt           0.0438
_refine_ls_wR_factor_gt          0.0999
_refine_ls_wR_factor_ref         0.1014
_refine_ls_goodness_of_fit_ref   1.220
_refine_ls_restrained_S_all      1.215
_refine_ls_number_reflns         8170
_refine_ls_number_parameters     705
_refine_ls_number_restraints     72
_refine_ls_number_constraints    ?
_refine_ls_hydrogen_treatment    constr
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0142P)²+49.1929P] where P=(Fo²+2Fc²)/3'

_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?

_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_diff_density_max         1.000
_refine_diff_density_min         -2.066
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       'APEX3 (Bruker AXS Inc., 2016)'
_computing_cell_refinement       'SAINT V8.37A (Bruker AXS Inc., 2015)'
_computing_data_reduction        'SAINT V8.37A (Bruker AXS Inc., 2015)'
_computing_structure_solution    'XS, VERSION 2013/1'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'XP (Bruker AXS Inc., 2016)'
_computing_publication_material  'APEX3 (Bruker AXS Inc., 2016)'

loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_refinement_flags_posn
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt1 0.14758(4) 0.09271(2) 0.67626(2) 0.01337(9) Uani d . . . 1 . .
Pt Pt2 0.64549(4) 0.12540(2) 0.67097(2) 0.01489(9) Uani d . . . 1 . .
C C1 0.1232(11) 0.17005(19) 0.6437(4) 0.0202(15) Uani d . . . 1 . .
H H1 0.1104 0.1735 0.6968 0.024 Uiso calc U . R 1 . .
C C2 0.1229(12) 0.19855(19) 0.5948(5) 0.0240(16) Uani d . . . 1 . .
H H2 0.1136 0.2207 0.6154 0.029 Uiso calc U . R 1 . .
C C3 0.1361(11) 0.19435(19) 0.5173(5) 0.0242(16) Uani d . . . 1 . .
H H3 0.1365 0.2135 0.4839 0.029 Uiso calc U . R 1 . .
C C4 0.1489(10) 0.16136(18) 0.4880(4) 0.0176(14) Uani d . . . 1 . .
C C5 0.1618(11) 0.1537(2) 0.4081(4) 0.0219(16) Uani d . . . 1 . .
H H5 0.1559 0.1718 0.3717 0.026 Uiso calc U . R 1 . .
C C6 0.1818(12) 0.12163(19) 0.3829(4) 0.0226(16) Uani d . . . 1 . .
H H6 0.1962 0.1175 0.3302 0.027 Uiso calc U . R 1 . .
C C7 0.1811(10) 0.09340(19) 0.4374(4) 0.0185(15) Uani d . . . 1 . .
C C8 0.2003(11) 0.05879(19) 0.4169(4) 0.0200(15) Uani d . . . 1 . .
H H8 0.2133 0.0529 0.3649 0.024 Uiso calc U . R 1 . .
C C9 0.1999(11) 0.03406(19) 0.4720(4) 0.0217(15) Uani d . . . 1 . .
H H9 0.2113 0.011 0.4576 0.026 Uiso calc U . R 1 . .
C C10 0.1829(10) 0.04220(17) 0.5506(4) 0.0169(14) Uani d . . . 1 . .
C C11 0.1637(9) 0.01743(18) 0.6758(4) 0.0154(14) Uani d . . . 1 . .
C C12 0.1624(11) -0.01463(18) 0.7153(4) 0.0204(15) Uani d . . . 1 . .
H H12 0.1711 -0.0349 0.6864 0.025 Uiso calc U . R 1 . .
C C13 0.1490(10) -0.01691(18) 0.7925(5) 0.0206(15) Uani d . . . 1 . .
H H13 0.1459 -0.0385 0.8167 0.025 Uiso calc U . R 1 . .
C C14 0.1398(10) 0.01324(18) 0.8369(4) 0.0185(15) Uani d . . . 1 . .
C C15 0.1332(10) 0.01450(19) 0.9182(4) 0.0206(15) Uani d . . . 1 . .
H H15 0.1327 -0.0061 0.9465 0.025 Uiso calc U . R 1 . .
C C16 0.1277(11) 0.0443(2) 0.9565(4) 0.0214(15) Uani d . . . 1 . .
H H16 0.1261 0.0443 1.0112 0.026 Uiso calc U . R 1 . .
C C17 0.1243(10) 0.07573(19) 0.9157(4) 0.0185(15) Uani d . . . 1 . .
C C18 0.1162(10) 0.1077(2) 0.9516(4) 0.0214(16) Uani d . . . 1 . .
H H18 0.1091 0.1094 1.0057 0.026 Uiso calc U . R 1 . .
C C19 0.1186(11) 0.13638(19) 0.9072(4) 0.0221(16) Uani d . . . 1 . .
H H19 0.1122 0.1581 0.9304 0.027 Uiso calc U . R 1 . .
C C20 0.1305(11) 0.13372(19) 0.8277(4) 0.0198(15) Uani d . . . 1 . .
H H20 0.1353 0.154 0.7984 0.024 Uiso calc U . R 1 . .
C C21 0.1318(10) 0.07530(18) 0.8357(4) 0.0175(14) Uani d . . . 1 . .
C C22 0.1413(9) 0.04387(17) 0.7964(4) 0.0140(13) Uani d . . . 1 . .
C C23 0.1498(10) 0.13407(18) 0.5409(4) 0.0160(14) Uani d . . . 1 . .
C C24 0.1664(10) 0.10038(17) 0.5150(4) 0.0147(13) Uani d . . . 1 . .
C C25 0.6261(13) 0.2033(2) 0.6416(5) 0.0322(19) Uani d . . . 1 . .
H H25 0.6187 0.2067 0.6953 0.039 Uiso calc U . R 1 . .
C C26 0.6249(14) 0.2319(2) 0.5932(6) 0.037(2) Uani d . . . 1 . .
H H26 0.6183 0.2541 0.6144 0.045 Uiso calc U . R 1 . .
C C27 0.6334(13) 0.2278(2) 0.5156(5) 0.0308(18) Uani d . . . 1 . .
H H27 0.6358 0.2471 0.4829 0.037 Uiso calc U . R 1 . .
C C28 0.6385(11) 0.19520(19) 0.4844(5) 0.0249(17) Uani d . . . 1 . .
C C29 0.6477(12) 0.1883(2) 0.4048(5) 0.0273(17) Uani d . . . 1 . .
H H29 0.643 0.2066 0.3689 0.033 Uiso calc U . R 1 . .
C C30 0.6632(12) 0.1560(2) 0.3789(5) 0.0262(17) Uani d . . . 1 . .
H H30 0.6708 0.152 0.3254 0.031 Uiso calc U . R 1 . .
C C31 0.6681(11) 0.1280(2) 0.4315(4) 0.0218(16) Uani d . . . 1 . .
C C32 0.6845(11) 0.09327(19) 0.4089(4) 0.0240(16) Uani d . . . 1 . .
H H32 0.6928 0.0877 0.3562 0.029 Uiso calc U . R 1 . .
C C33 0.6881(10) 0.06831(19) 0.4636(4) 0.0194(15) Uani d . . . 1 . .
H H33 0.7011 0.0453 0.4484 0.023 Uiso calc U . R 1 . .
C C34 0.6730(11) 0.07573(18) 0.5431(4) 0.0188(15) Uani d . . . 1 . .
C C35 0.6598(10) 0.04981(18) 0.6674(4) 0.0177(14) Uani d . . . 1 . .
C C36 0.6514(10) 0.01791(18) 0.7061(4) 0.0179(14) Uani d . . . 1 . .
H H36 0.6526 -0.0023 0.6763 0.021 Uiso calc U . R 1 . .
C C37 0.6419(10) 0.01528(18) 0.7826(4) 0.0191(15) Uani d . . . 1 . .
H H37 0.6408 -0.0065 0.8063 0.023 Uiso calc U . R 1 . .
C C38 0.6337(9) 0.04500(17) 0.8280(4) 0.0151(14) Uani d . . . 1 . .
C C39 0.6231(10) 0.04552(18) 0.9091(4) 0.0175(14) Uani d . . . 1 . .
H H39 0.6191 0.0246 0.936 0.021 Uiso calc U . R 1 . .
C C40 0.6185(10) 0.07511(19) 0.9494(4) 0.0200(15) Uani d . . . 1 . .
H H40 0.6135 0.0746 1.0038 0.024 Uiso calc U . R 1 . .
C C41 0.6213(10) 0.10713(19) 0.9099(4) 0.0191(15) Uani d . . . 1 . .
C C42 0.6177(12) 0.1385(2) 0.9471(4) 0.0242(16) Uani d . . . 1 . .
H H42 0.6121 0.1397 1.0014 0.029 Uiso calc U . R 1 . .
C C43 0.6223(13) 0.1679(2) 0.9039(5) 0.0305(19) Uani d . . . 1 . .
H H43 0.6222 0.1894 0.9284 0.037 Uiso calc U . R 1 . .
C C44 0.6273(11) 0.16570(19) 0.8242(5) 0.0234(16) Uani d . . . 1 . .
H H44 0.625 0.1862 0.7951 0.028 Uiso calc U . R 1 . .
C C45 0.6299(10) 0.10731(17) 0.8300(4) 0.0160(14) Uani d . . . 1 . .
C C46 0.6395(10) 0.07599(17) 0.7893(4) 0.0132(13) Uani d . . . 1 . .
C C47 0.6585(11) 0.13426(18) 0.5095(4) 0.0187(15) Uani d . . . 1 . .
C C48 0.6441(10) 0.16774(19) 0.5366(4) 0.0203(15) Uani d . . . 1 . .
C C49 -0.0771(18) 0.1669(3) 0.1793(6) 0.051(3) Uani d . . . 1 . .
H H49A -0.2204 0.1657 0.1778 0.077 Uiso calc U . R 1 . .
H H49B -0.0171 0.1788 0.2267 0.077 Uiso calc U . R 1 . .
H H49C -0.0228 0.1439 0.1792 0.077 Uiso calc U . R 1 . .
C C50 -0.0325(17) 0.1859(3) 0.1088(6) 0.050(3) Uani d . . . 1 . .
C C51 0.182(2) 0.1937(3) 0.1062(7) 0.061(3) Uani d . . . 1 . .
H H51A 0.1935 0.2051 0.057 0.092 Uiso calc U . R 1 . .
H H51B 0.2575 0.1725 0.1098 0.092 Uiso calc U . R 1 . .
H H51C 0.2335 0.2085 0.1501 0.092 Uiso calc U . R 1 . .
F F1 0.5452(7) 0.94332(10) 0.8754(2) 0.0280(10) Uani d U . . 1 . .
F F2 0.8146(7) 0.91300(13) 0.8575(3) 0.0357(11) Uani d U . . 1 . .
F F3 0.5554(7) 0.88651(11) 0.8978(2) 0.0292(10) Uani d U . . 1 . .
F F4 0.6203(7) 0.87751(11) 0.7755(3) 0.0307(10) Uani d U . . 1 . .
F F5 0.3521(7) 0.90797(11) 0.7932(3) 0.0303(10) Uani d U . . 1 . .
F F6 0.6124(8) 0.93424(11) 0.7531(2) 0.0312(11) Uani d U . . 1 . .
F F7 0.2900(8) 0.21840(15) 0.7815(4) 0.0509(15) Uani d U . . 1 . .
F F8 0.2664(11) 0.27196(17) 0.8227(6) 0.095(3) Uani d U . . 1 . .
F F9 -0.0278(10) 0.26160(17) 0.8536(4) 0.0657(19) Uani d U . . 1 . .
F F10 0.0278(11) 0.25051(18) 0.7327(4) 0.0650(18) Uani d U . . 1 . .
F F11 0.2319(14) 0.2289(3) 0.9019(4) 0.096(3) Uani d U . . 1 . .
F F12 -0.0097(9) 0.20789(14) 0.8109(5) 0.0645(19) Uani d U . . 1 . .
N N1 0.1406(8) 0.13862(14) 0.6187(3) 0.0141(11) Uani d . . . 1 . .
N N2 0.1654(8) 0.07572(14) 0.5702(3) 0.0143(12) Uani d . . . 1 . .
N N3 0.1805(9) 0.01555(14) 0.5997(3) 0.0176(12) Uani d . . . 1 . .
N N4 0.1524(8) 0.04563(14) 0.7185(3) 0.0132(11) Uani d . . . 1 . .
N N5 0.1355(8) 0.10398(14) 0.7915(3) 0.0131(11) Uani d . . . 1 . .
N N6 0.6370(9) 0.17186(15) 0.6154(4) 0.0202(13) Uani d . . . 1 . .
N N7 0.6593(8) 0.10931(15) 0.5639(3) 0.0164(12) Uani d . . . 1 . .
N N8 0.6701(8) 0.04899(14) 0.5909(3) 0.0155(12) Uani d . . . 1 . .
N N9 0.6507(8) 0.07841(14) 0.7111(3) 0.0126(11) Uani d . . . 1 . .
N N10 0.6352(8) 0.13612(14) 0.7865(3) 0.0134(11) Uani d . . . 1 . .
O O1 -0.1628(15) 0.1987(2) 0.0620(4) 0.071(3) Uani d . . . 1 . .
P P1 0.5836(3) 0.91034(5) 0.82516(10) 0.0199(4) Uani d . . . 1 . .
P P2 0.1297(3) 0.24003(5) 0.81846(12) 0.0282(4) Uani d . . . 1 . .


_geom_special_details            
;

All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pt1 N2 . 1.981(6) ?
Pt1 N4 . 1.992(5) ?
Pt1 N5 . 2.062(5) ?
Pt1 N1 . 2.062(5) ?
Pt2 N9 . 1.976(5) ?
Pt2 N7 . 1.979(6) ?
Pt2 N10 . 2.060(6) ?
Pt2 N6 . 2.065(6) ?
C1 N1 . 1.323(9) ?
C1 C2 . 1.407(10) ?
C2 C3 . 1.372(11) ?
C3 C4 . 1.402(11) ?
C4 C23 . 1.413(10) ?
C4 C5 . 1.436(10) ?
C5 C6 . 1.349(11) ?
C6 C7 . 1.460(10) ?
C7 C24 . 1.392(10) ?
C7 C8 . 1.420(10) ?
C8 C9 . 1.366(11) ?
C9 C10 . 1.424(10) ?
C10 N3 . 1.354(9) ?
C10 N2 . 1.373(9) ?
C11 N4 . 1.343(9) ?
C11 N3 . 1.346(9) ?
C11 C12 . 1.437(10) ?
C12 C13 . 1.361(11) ?
C13 C14 . 1.422(11) ?
C14 C22 . 1.397(10) ?
C14 C15 . 1.420(10) ?
C15 C16 . 1.354(11) ?
C16 C17 . 1.423(10) ?
C17 C21 . 1.399(10) ?
C17 C18 . 1.411(11) ?
C18 C19 . 1.368(11) ?
C19 C20 . 1.397(10) ?
C20 N5 . 1.333(9) ?
C21 N5 . 1.368(9) ?
C21 C22 . 1.420(10) ?
C22 N4 . 1.367(9) ?
C23 N1 . 1.373(9) ?
C23 C24 . 1.412(10) ?
C24 N2 . 1.365(9) ?
C25 N6 . 1.327(10) ?
C25 C26 . 1.404(12) ?
C26 C27 . 1.367(13) ?
C27 C28 . 1.397(12) ?
C28 C48 . 1.407(10) ?
C28 C29 . 1.419(12) ?
C29 C30 . 1.357(12) ?
C30 C31 . 1.430(10) ?
C31 C47 . 1.388(11) ?
C31 C32 . 1.432(11) ?
C32 C33 . 1.364(11) ?
C33 C34 . 1.430(10) ?
C34 N8 . 1.343(9) ?
C34 N7 . 1.378(9) ?
C35 N8 . 1.341(9) ?
C35 N9 . 1.364(9) ?
C35 C36 . 1.430(10) ?
C36 C37 . 1.345(10) ?
C37 C38 . 1.416(10) ?
C38 C46 . 1.397(9) ?
C38 C39 . 1.420(10) ?
C39 C40 . 1.363(11) ?
C40 C41 . 1.438(11) ?
C41 C42 . 1.397(11) ?
C41 C45 . 1.397(10) ?
C42 C43 . 1.381(12) ?
C43 C44 . 1.391(11) ?
C44 N10 . 1.342(9) ?
C45 N10 . 1.366(9) ?
C45 C46 . 1.428(9) ?
C46 N9 . 1.375(9) ?
C47 N7 . 1.362(9) ?
C47 C48 . 1.409(11) ?
C48 N6 . 1.385(10) ?
C49 C50 . 1.503(15) ?
C50 O1 . 1.219(12) ?
C50 C51 . 1.508(18) ?
F1 P1 . 1.609(4) ?
F2 P1 . 1.598(5) ?
F3 P1 . 1.607(4) ?
F4 P1 . 1.595(4) ?
F5 P1 . 1.599(5) ?
F6 P1 . 1.601(4) ?
F7 P2 . 1.602(5) ?
F8 P2 . 1.563(7) ?
F9 P2 . 1.570(6) ?
F10 P2 . 1.596(6) ?
F11 P2 . 1.569(7) ?
F12 P2 . 1.579(6) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N2 Pt1 N4 . . 91.6(2) ?
N2 Pt1 N5 . . 172.6(2) ?
N4 Pt1 N5 . . 81.1(2) ?
N2 Pt1 N1 . . 81.2(2) ?
N4 Pt1 N1 . . 172.7(2) ?
N5 Pt1 N1 . . 106.2(2) ?
N9 Pt2 N7 . . 91.7(2) ?
N9 Pt2 N10 . . 81.4(2) ?
N7 Pt2 N10 . . 173.1(2) ?
N9 Pt2 N6 . . 172.9(2) ?
N7 Pt2 N6 . . 81.2(2) ?
N10 Pt2 N6 . . 105.7(2) ?
N1 C1 C2 . . 122.8(7) ?
C3 C2 C1 . . 120.1(7) ?
C2 C3 C4 . . 118.9(7) ?
C3 C4 C23 . . 117.7(7) ?
C3 C4 C5 . . 124.2(7) ?
C23 C4 C5 . . 118.2(7) ?
C6 C5 C4 . . 122.4(7) ?
C5 C6 C7 . . 119.4(7) ?
C24 C7 C8 . . 117.1(6) ?
C24 C7 C6 . . 118.9(7) ?
C8 C7 C6 . . 123.9(6) ?
C9 C8 C7 . . 119.9(6) ?
C8 C9 C10 . . 121.3(7) ?
N3 C10 N2 . . 125.5(6) ?
N3 C10 C9 . . 116.1(6) ?
N2 C10 C9 . . 118.5(6) ?
N4 C11 N3 . . 127.4(6) ?
N4 C11 C12 . . 117.3(6) ?
N3 C11 C12 . . 115.3(6) ?
C13 C12 C11 . . 122.2(7) ?
C12 C13 C14 . . 119.6(6) ?
C22 C14 C15 . . 118.3(7) ?
C22 C14 C13 . . 116.4(6) ?
C15 C14 C13 . . 125.3(7) ?
C16 C15 C14 . . 121.8(7) ?
C15 C16 C17 . . 120.6(7) ?
C21 C17 C18 . . 117.3(7) ?
C21 C17 C16 . . 118.9(7) ?
C18 C17 C16 . . 123.7(6) ?
C19 C18 C17 . . 118.9(6) ?
C18 C19 C20 . . 120.1(7) ?
N5 C20 C19 . . 122.8(7) ?
N5 C21 C17 . . 123.7(6) ?
N5 C21 C22 . . 116.4(6) ?
C17 C21 C22 . . 119.9(6) ?
N4 C22 C14 . . 123.2(6) ?
N4 C22 C21 . . 116.4(6) ?
C14 C22 C21 . . 120.5(6) ?
N1 C23 C24 . . 117.1(6) ?
N1 C23 C4 . . 122.9(6) ?
C24 C23 C4 . . 120.0(6) ?
N2 C24 C7 . . 123.1(6) ?
N2 C24 C23 . . 115.8(6) ?
C7 C24 C23 . . 121.1(6) ?
N6 C25 C26 . . 122.7(8) ?
C27 C26 C25 . . 119.8(8) ?
C26 C27 C28 . . 119.9(7) ?
C27 C28 C48 . . 117.2(7) ?
C27 C28 C29 . . 124.2(7) ?
C48 C28 C29 . . 118.5(7) ?
C30 C29 C28 . . 121.4(7) ?
C29 C30 C31 . . 120.4(7) ?
C47 C31 C30 . . 119.0(7) ?
C47 C31 C32 . . 117.1(7) ?
C30 C31 C32 . . 123.8(7) ?
C33 C32 C31 . . 119.4(7) ?
C32 C33 C34 . . 121.9(7) ?
N8 C34 N7 . . 125.6(6) ?
N8 C34 C33 . . 116.5(6) ?
N7 C34 C33 . . 117.8(6) ?
N8 C35 N9 . . 125.7(6) ?
N8 C35 C36 . . 117.1(6) ?
N9 C35 C36 . . 117.2(6) ?
C37 C36 C35 . . 122.9(7) ?
C36 C37 C38 . . 119.8(7) ?
C46 C38 C37 . . 116.7(6) ?
C46 C38 C39 . . 118.2(6) ?
C37 C38 C39 . . 125.1(6) ?
C40 C39 C38 . . 122.1(6) ?
C39 C40 C41 . . 120.1(6) ?
C42 C41 C45 . . 117.5(7) ?
C42 C41 C40 . . 123.6(7) ?
C45 C41 C40 . . 119.0(7) ?
C43 C42 C41 . . 119.1(7) ?
C42 C43 C44 . . 119.7(7) ?
N10 C44 C43 . . 123.2(7) ?
N10 C45 C41 . . 124.1(6) ?
N10 C45 C46 . . 115.9(6) ?
C41 C45 C46 . . 119.9(6) ?
N9 C46 C38 . . 123.0(6) ?
N9 C46 C45 . . 116.3(6) ?
C38 C46 C45 . . 120.7(6) ?
N7 C47 C31 . . 123.5(7) ?
N7 C47 C48 . . 115.9(7) ?
C31 C47 C48 . . 120.6(7) ?
N6 C48 C28 . . 122.9(7) ?
N6 C48 C47 . . 117.0(6) ?
C28 C48 C47 . . 120.0(7) ?
O1 C50 C49 . . 121.8(12) ?
O1 C50 C51 . . 120.7(11) ?
C49 C50 C51 . . 116.6(9) ?
C1 N1 C23 . . 117.6(6) ?
C1 N1 Pt1 . . 131.2(5) ?
C23 N1 Pt1 . . 111.1(4) ?
C24 N2 C10 . . 120.1(6) ?
C24 N2 Pt1 . . 114.8(4) ?
C10 N2 Pt1 . . 125.1(5) ?
C11 N3 C10 . . 125.9(6) ?
C11 N4 C22 . . 121.3(6) ?
C11 N4 Pt1 . . 124.5(5) ?
C22 N4 Pt1 . . 114.2(4) ?
C20 N5 C21 . . 117.2(6) ?
C20 N5 Pt1 . . 130.9(5) ?
C21 N5 Pt1 . . 111.9(4) ?
C25 N6 C48 . . 117.4(7) ?
C25 N6 Pt2 . . 131.8(6) ?
C48 N6 Pt2 . . 110.8(5) ?
C47 N7 C34 . . 120.3(6) ?
C47 N7 Pt2 . . 115.1(5) ?
C34 N7 Pt2 . . 124.6(5) ?
C35 N8 C34 . . 126.9(6) ?
C35 N9 C46 . . 120.4(6) ?
C35 N9 Pt2 . . 125.3(5) ?
C46 N9 Pt2 . . 114.3(4) ?
C44 N10 C45 . . 116.4(6) ?
C44 N10 Pt2 . . 131.5(5) ?
C45 N10 Pt2 . . 112.0(4) ?
F4 P1 F2 . . 90.7(3) ?
F4 P1 F5 . . 89.8(3) ?
F2 P1 F5 . . 179.5(3) ?
F4 P1 F6 . . 90.4(2) ?
F2 P1 F6 . . 90.0(3) ?
F5 P1 F6 . . 90.0(3) ?
F4 P1 F3 . . 89.9(2) ?
F2 P1 F3 . . 89.8(3) ?
F5 P1 F3 . . 90.2(3) ?
F6 P1 F3 . . 179.7(3) ?
F4 P1 F1 . . 179.6(3) ?
F2 P1 F1 . . 89.6(3) ?
F5 P1 F1 . . 89.8(3) ?
F6 P1 F1 . . 89.9(2) ?
F3 P1 F1 . . 89.8(2) ?
F8 P2 F11 . . 90.2(6) ?
F8 P2 F9 . . 89.4(4) ?
F11 P2 F9 . . 91.6(4) ?
F8 P2 F12 . . 177.9(5) ?
F11 P2 F12 . . 91.7(5) ?
F9 P2 F12 . . 91.3(4) ?
F8 P2 F10 . . 90.4(5) ?
F11 P2 F10 . . 178.6(4) ?
F9 P2 F10 . . 89.7(4) ?
F12 P2 F10 . . 87.6(4) ?
F8 P2 F7 . . 90.2(4) ?
F11 P2 F7 . . 89.2(4) ?
F9 P2 F7 . . 179.1(4) ?
F12 P2 F7 . . 89.1(3) ?
F10 P2 F7 . . 89.5(4) ?


_exptl_crystal_preparation       Luminescent
