File Name : figure s1.tif Caption : 2d-pes matrix of the m/z 56 mass signals. File Name : figure s2.tif Caption : mass selected pepico spectra obtained at 15.5 ev for m/z 54 (red), m/z 27 (black) and m/z 26 (blue). the appearance energies are derived as the first point where the signal increases above the background. this method is less accurate than using recorded spes and hence we give an estimated error of 0.1 ev for the derived appearance energies. File Name : figure s3.png Caption : the spes corresponding to the mke trimer (m/z 168). File Name : figure s4.png Caption : peak evolution of the m/z 56 signal with increasing photon energy. File Name : figure s5.png Caption : total ion yield (tiy) of the m/z 56 signal (black). by employing the same filtering as was done on the m/z 56 spes the signal can be disentangled into the contribution of the ionized mke monomer (red) and that of the c3h3o+ fragments formed by dissociative ionization of the mke dimer.