# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2032477'
loop_
_audit_author_name
_audit_author_address
'Yuhao Wu'
;South Central University For Nationalities
China
;
_audit_update_record             
;
2020-12-22 deposited with the CCDC.	2021-01-05 downloaded from the CCDC.
;
_audit_creation_date             2020-12-17
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C33 H26 N5 Ru, F6 P,2[CH4O]'
_chemical_formula_sum            'C35 H34 F6 N5 O2 P Ru'
_chemical_formula_weight         802.71
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.5639(4)
_cell_length_b                   12.0236(5)
_cell_length_c                   19.0129(9)
_cell_angle_alpha                99.165(3)
_cell_angle_beta                 93.603(3)
_cell_angle_gamma                91.597(3)
_cell_volume                     1702.43(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9949
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.3645
_cell_measurement_theta_min      2.4823
_shelx_estimated_absorpt_T_max   0.988
_shelx_estimated_absorpt_T_min   0.801
_exptl_absorpt_coefficient_mu    0.581
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'dull blackish black'
_exptl_crystal_colour_lustre     dull
_exptl_crystal_colour_modifier   blackish
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.02
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_av_unetI/netI     0.0866
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            29410
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        24.996
_diffrn_reflns_theta_max         24.996
_diffrn_reflns_theta_min         1.717
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                22141
_reflns_number_total             29410
_reflns_special_details          
;
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.857
_refine_diff_density_min         -0.770
_refine_diff_density_rms         0.117
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     416
_refine_ls_number_reflns         29410
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0889
_refine_ls_R_factor_gt           0.0671
_refine_ls_restrained_S_all      1.090
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1070P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1864
_refine_ls_wR_factor_ref         0.2026
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.656(4)
 0.344(4)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
3.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C7(H7), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C13(H13), C14(H14), C19(H19), C20(H20), C21(H21), C22(H22), C23(H23),
  C24(H24), C25(H25), C26(H26), C28(H28), C31(H31), C32(H32), C33(H33),
 C34(H34), C35(H35)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2354(10) 0.3906(7) 0.2876(4) 0.057(2) Uani 1 1 d . . . . .
H1 H 0.2918 0.4138 0.2501 0.068 Uiso 1 1 calc R . . . .
C2 C 0.1509(12) 0.4698(7) 0.3321(4) 0.068(2) Uani 1 1 d . . . . .
H2 H 0.1469 0.5439 0.3238 0.082 Uiso 1 1 calc R . . . .
C3 C 0.0714(13) 0.4374(7) 0.3897(5) 0.072(3) Uani 1 1 d . . . . .
H3 H 0.0181 0.4899 0.4223 0.087 Uiso 1 1 calc R . . . .
C4 C 0.0734(11) 0.3245(8) 0.3975(4) 0.069(2) Uani 1 1 d . . . . .
H4 H 0.0187 0.3003 0.4352 0.082 Uiso 1 1 calc R . . . .
C5 C 0.1566(9) 0.2479(6) 0.3495(4) 0.0486(18) Uani 1 1 d . . . . .
C6 C 0.1541(9) 0.1265(6) 0.3502(4) 0.0489(18) Uani 1 1 d . . . . .
C7 C 0.0809(11) 0.0763(7) 0.4022(4) 0.060(2) Uani 1 1 d . . . . .
H7 H 0.0346 0.1194 0.4413 0.072 Uiso 1 1 calc R . . . .
C8 C 0.0778(12) -0.0403(8) 0.3948(5) 0.073(3) Uani 1 1 d . . . . .
H8 H 0.0314 -0.0758 0.4300 0.087 Uiso 1 1 calc R . . . .
C9 C 0.1419(12) -0.1037(8) 0.3367(5) 0.070(2) Uani 1 1 d . . . . .
H9 H 0.1347 -0.1821 0.3302 0.084 Uiso 1 1 calc R . . . .
C10 C 0.2186(11) -0.0468(7) 0.2874(4) 0.058(2) Uani 1 1 d . . . . .
H10 H 0.2673 -0.0892 0.2486 0.070 Uiso 1 1 calc R . . . .
C11 C 0.6500(11) 0.3110(7) 0.1873(5) 0.066(2) Uani 1 1 d . . . . .
H11 H 0.7194 0.2883 0.2242 0.079 Uiso 1 1 calc R . . . .
C12 C 0.7218(14) 0.3888(8) 0.1514(6) 0.082(3) Uani 1 1 d . . . . .
H12 H 0.8348 0.4206 0.1646 0.099 Uiso 1 1 calc R . . . .
C13 C 0.6221(17) 0.4185(8) 0.0953(6) 0.092(3) Uani 1 1 d . . . . .
H13 H 0.6685 0.4703 0.0693 0.111 Uiso 1 1 calc R . . . .
C14 C 0.4562(14) 0.3730(7) 0.0773(5) 0.073(3) Uani 1 1 d . . . . .
H14 H 0.3892 0.3936 0.0391 0.088 Uiso 1 1 calc R . . . .
C15 C 0.3860(11) 0.2951(6) 0.1165(4) 0.0513(19) Uani 1 1 d . . . . .
C16 C 0.2116(10) 0.2394(6) 0.1011(4) 0.0489(19) Uani 1 1 d . . . . .
C19 C 0.0936(12) 0.2564(8) 0.0455(4) 0.068(2) Uani 1 1 d . . . . .
H19 H 0.1192 0.3104 0.0172 0.081 Uiso 1 1 calc R . . . .
C20 C -0.0621(14) 0.1925(10) 0.0328(5) 0.084(3) Uani 1 1 d . . . . .
H20 H -0.1393 0.2002 -0.0061 0.101 Uiso 1 1 calc R . . . .
C21 C -0.1043(12) 0.1173(8) 0.0770(4) 0.068(2) Uani 1 1 d . . . . .
H21 H -0.2092 0.0735 0.0690 0.082 Uiso 1 1 calc R . . . .
C22 C 0.0137(10) 0.1093(7) 0.1330(4) 0.059(2) Uani 1 1 d . . . . .
H22 H -0.0157 0.0609 0.1644 0.071 Uiso 1 1 calc R . . . .
C23 C 0.4378(10) -0.0315(6) 0.1083(4) 0.057(2) Uani 1 1 d . . . . .
H23 H 0.3406 -0.0066 0.0836 0.069 Uiso 1 1 calc R . . . .
C24 C 0.5255(12) -0.1236(7) 0.0756(5) 0.072(3) Uani 1 1 d . . . . .
H24 H 0.4891 -0.1588 0.0296 0.086 Uiso 1 1 calc R . . . .
C25 C 0.6668(12) -0.1615(7) 0.1125(5) 0.074(3) Uani 1 1 d . . . . .
H25 H 0.7247 -0.2249 0.0924 0.089 Uiso 1 1 calc R . . . .
C26 C 0.7224(11) -0.1056(7) 0.1789(5) 0.067(2) Uani 1 1 d . . . . .
H26 H 0.8197 -0.1298 0.2039 0.080 Uiso 1 1 calc R . . . .
C27 C 0.6306(9) -0.0109(6) 0.2092(4) 0.053(2) Uani 1 1 d . . . . .
C28 C 0.6724(10) 0.0524(7) 0.2794(4) 0.064(2) Uani 1 1 d . . . . .
H28 H 0.7670 0.0342 0.3086 0.077 Uiso 1 1 calc R . . . .
C29 C 0.5693(10) 0.1389(7) 0.3011(4) 0.0536(19) Uani 1 1 d . . . . .
C30 C 0.5949(10) 0.2023(8) 0.3752(4) 0.061(2) Uani 1 1 d . . . . .
C31 C 0.6002(12) 0.1451(10) 0.4317(5) 0.087(3) Uani 1 1 d . . . . .
H31 H 0.5932 0.0667 0.4238 0.104 Uiso 1 1 calc R . . . .
C32 C 0.6160(16) 0.2040(13) 0.5015(6) 0.115(4) Uani 1 1 d . . . . .
H32 H 0.6170 0.1650 0.5400 0.138 Uiso 1 1 calc R . . . .
C33 C 0.6301(15) 0.3210(15) 0.5131(7) 0.126(6) Uani 1 1 d . . . . .
H33 H 0.6414 0.3602 0.5596 0.151 Uiso 1 1 calc R . . . .
C34 C 0.6275(14) 0.3793(10) 0.4566(6) 0.095(3) Uani 1 1 d . . . . .
H34 H 0.6382 0.4576 0.4646 0.114 Uiso 1 1 calc R . . . .
C35 C 0.6091(11) 0.3217(8) 0.3888(5) 0.074(3) Uani 1 1 d . . . . .
H35 H 0.6058 0.3614 0.3506 0.089 Uiso 1 1 calc R . . . .
N1 N 0.2418(7) 0.2815(5) 0.2950(3) 0.0429(14) Uani 1 1 d . . . . .
N2 N 0.2262(7) 0.0651(5) 0.2928(3) 0.0447(14) Uani 1 1 d . . . . .
N3 N 0.4851(8) 0.2649(5) 0.1727(3) 0.0480(15) Uani 1 1 d . . . . .
N4 N 0.1695(8) 0.1672(5) 0.1456(3) 0.0442(14) Uani 1 1 d . . . . .
N5 N 0.4878(7) 0.0239(5) 0.1748(3) 0.0470(15) Uani 1 1 d . . . . .
F1 F 0.0114(12) 0.6613(7) 0.2112(4) 0.170(4) Uani 1 1 d . . . . .
F2 F 0.1394(9) 0.5121(4) 0.1529(3) 0.108(2) Uani 1 1 d . . . . .
F3 F 0.2439(11) 0.6241(6) 0.0804(4) 0.153(3) Uani 1 1 d . . . . .
F4 F 0.1132(9) 0.7697(5) 0.1372(3) 0.1068(19) Uani 1 1 d . . . . .
F5 F -0.0399(10) 0.6127(6) 0.0950(4) 0.144(3) Uani 1 1 d . . . . .
F6 F 0.2942(11) 0.6715(7) 0.1999(5) 0.179(4) Uani 1 1 d . . . . .
P1 P 0.1333(3) 0.64079(19) 0.14601(12) 0.0654(6) Uani 1 1 d . . . . .
Ru1 Ru 0.36288(7) 0.15785(5) 0.23043(3) 0.0433(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 H1 0.9300 . ?
C1 C2 1.370(10) . ?
C1 N1 1.344(9) . ?
C2 H2 0.9300 . ?
C2 C3 1.384(12) . ?
C3 H3 0.9300 . ?
C3 C4 1.390(12) . ?
C4 H4 0.9300 . ?
C4 C5 1.383(10) . ?
C5 C6 1.463(10) . ?
C5 N1 1.362(9) . ?
C6 C7 1.375(10) . ?
C6 N2 1.369(9) . ?
C7 H7 0.9300 . ?
C7 C8 1.386(12) . ?
C8 H8 0.9300 . ?
C8 C9 1.363(11) . ?
C9 H9 0.9300 . ?
C9 C10 1.390(11) . ?
C10 H10 0.9300 . ?
C10 N2 1.333(9) . ?
C11 H11 0.9300 . ?
C11 C12 1.363(12) . ?
C11 N3 1.345(10) . ?
C12 H12 0.9300 . ?
C12 C13 1.367(14) . ?
C13 H13 0.9300 . ?
C13 C14 1.356(13) . ?
C14 H14 0.9300 . ?
C14 C15 1.400(11) . ?
C15 C16 1.454(10) . ?
C15 N3 1.368(9) . ?
C16 C19 1.384(10) . ?
C16 N4 1.351(9) . ?
C19 H19 0.9300 . ?
C19 C20 1.375(12) . ?
C20 H20 0.9300 . ?
C20 C21 1.374(13) . ?
C21 H21 0.9300 . ?
C21 C22 1.363(10) . ?
C22 H22 0.9300 . ?
C22 N4 1.340(9) . ?
C23 H23 0.9300 . ?
C23 C24 1.388(10) . ?
C23 N5 1.358(9) . ?
C24 H24 0.9300 . ?
C24 C25 1.370(11) . ?
C25 H25 0.9300 . ?
C25 C26 1.368(11) . ?
C26 H26 0.9300 . ?
C26 C27 1.413(10) . ?
C27 C28 1.438(10) . ?
C27 N5 1.340(8) . ?
C28 H28 0.9300 . ?
C28 C29 1.345(10) . ?
C29 C30 1.490(10) . ?
C29 Ru1 2.037(7) . y
C30 C31 1.364(12) . ?
C30 C35 1.417(12) . ?
C31 H31 0.9300 . ?
C31 C32 1.397(14) . ?
C32 H32 0.9300 . ?
C32 C33 1.389(18) . ?
C33 H33 0.9300 . ?
C33 C34 1.373(17) . ?
C34 H34 0.9300 . ?
C34 C35 1.359(13) . ?
C35 H35 0.9300 . ?
N1 Ru1 2.047(5) . y
N2 Ru1 2.056(6) . y
N3 Ru1 2.056(6) . y
N4 Ru1 2.127(5) . y
N5 Ru1 2.067(5) . y
F1 P1 1.583(7) . ?
F2 P1 1.575(5) . ?
F3 P1 1.535(6) . ?
F4 P1 1.596(6) . ?
F5 P1 1.575(7) . ?
F6 P1 1.538(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1 118.0 . . y
N1 C1 H1 118.0 . . y
N1 C1 C2 123.9(7) . . y
C1 C2 H2 120.6 . . y
C1 C2 C3 118.7(8) . . y
C3 C2 H2 120.6 . . y
C2 C3 H3 120.9 . . y
C2 C3 C4 118.2(8) . . y
C4 C3 H3 120.9 . . y
C3 C4 H4 119.9 . . y
C5 C4 C3 120.2(8) . . y
C5 C4 H4 119.9 . . y
C4 C5 C6 124.1(7) . . y
N1 C5 C4 121.2(7) . . y
N1 C5 C6 114.7(6) . . y
C7 C6 C5 123.7(7) . . y
N2 C6 C5 114.2(6) . . y
N2 C6 C7 122.1(7) . . y
C6 C7 H7 120.9 . . y
C6 C7 C8 118.2(8) . . y
C8 C7 H7 120.9 . . y
C7 C8 H8 119.6 . . y
C9 C8 C7 120.9(8) . . y
C9 C8 H8 119.6 . . y
C8 C9 H9 121.3 . . y
C8 C9 C10 117.5(8) . . y
C10 C9 H9 121.3 . . y
C9 C10 H10 118.2 . . y
N2 C10 C9 123.6(8) . . y
N2 C10 H10 118.2 . . y
C12 C11 H11 117.9 . . y
N3 C11 H11 117.9 . . y
N3 C11 C12 124.1(9) . . y
C11 C12 H12 121.1 . . y
C11 C12 C13 117.8(10) . . y
C13 C12 H12 121.1 . . y
C12 C13 H13 119.7 . . y
C14 C13 C12 120.6(10) . . y
C14 C13 H13 119.7 . . y
C13 C14 H14 120.1 . . y
C13 C14 C15 119.8(9) . . y
C15 C14 H14 120.1 . . y
C14 C15 C16 124.5(8) . . y
N3 C15 C14 119.9(8) . . y
N3 C15 C16 115.6(6) . . y
C19 C16 C15 124.3(7) . . y
N4 C16 C15 115.0(6) . . y
N4 C16 C19 120.7(8) . . y
C16 C19 H19 120.5 . . y
C20 C19 C16 119.0(8) . . y
C20 C19 H19 120.5 . . y
C19 C20 H20 119.8 . . y
C21 C20 C19 120.4(8) . . y
C21 C20 H20 119.8 . . y
C20 C21 H21 121.3 . . y
C22 C21 C20 117.3(9) . . y
C22 C21 H21 121.3 . . y
C21 C22 H22 118.0 . . y
N4 C22 C21 123.9(8) . . y
N4 C22 H22 118.0 . . y
C24 C23 H23 118.6 . . y
N5 C23 H23 118.6 . . y
N5 C23 C24 122.9(7) . . y
C23 C24 H24 120.7 . . y
C25 C24 C23 118.6(8) . . y
C25 C24 H24 120.7 . . y
C24 C25 H25 120.2 . . y
C26 C25 C24 119.6(7) . . y
C26 C25 H25 120.2 . . y
C25 C26 H26 120.3 . . y
C25 C26 C27 119.5(7) . . y
C27 C26 H26 120.3 . . y
C26 C27 C28 124.7(7) . . y
N5 C27 C26 121.3(7) . . y
N5 C27 C28 114.0(6) . . y
C27 C28 H28 121.3 . . y
C29 C28 C27 117.3(7) . . y
C29 C28 H28 121.3 . . y
C28 C29 C30 120.4(7) . . y
C28 C29 Ru1 114.4(6) . . y
C30 C29 Ru1 124.6(5) . . y
C31 C30 C29 119.7(8) . . y
C31 C30 C35 118.7(8) . . y
C35 C30 C29 121.5(8) . . y
C30 C31 H31 119.9 . . y
C30 C31 C32 120.1(11) . . y
C32 C31 H31 119.9 . . y
C31 C32 H32 120.1 . . y
C33 C32 C31 119.8(12) . . y
C33 C32 H32 120.1 . . y
C32 C33 H33 119.8 . . y
C34 C33 C32 120.5(11) . . y
C34 C33 H33 119.8 . . y
C33 C34 H34 120.3 . . y
C35 C34 C33 119.5(11) . . y
C35 C34 H34 120.3 . . y
C30 C35 H35 119.3 . . y
C34 C35 C30 121.3(10) . . y
C34 C35 H35 119.3 . . y
C1 N1 C5 117.6(6) . . y
C1 N1 Ru1 126.4(5) . . y
C5 N1 Ru1 116.0(5) . . y
C6 N2 Ru1 115.4(5) . . y
C10 N2 C6 117.6(7) . . y
C10 N2 Ru1 126.6(5) . . y
C11 N3 C15 117.7(7) . . y
C11 N3 Ru1 125.7(5) . . y
C15 N3 Ru1 116.5(5) . . y
C16 N4 Ru1 115.2(5) . . y
C22 N4 C16 118.4(6) . . y
C22 N4 Ru1 126.4(5) . . y
C23 N5 Ru1 126.4(5) . . y
C27 N5 C23 118.0(6) . . y
C27 N5 Ru1 115.5(5) . . y
F1 P1 F4 88.7(4) . . y
F2 P1 F1 90.0(4) . . y
F2 P1 F4 176.1(4) . . y
F2 P1 F5 88.6(4) . . y
F3 P1 F1 176.8(5) . . y
F3 P1 F2 91.9(4) . . y
F3 P1 F4 89.2(4) . . y
F3 P1 F5 89.3(5) . . y
F3 P1 F6 94.5(6) . . y
F5 P1 F1 88.3(5) . . y
F5 P1 F4 87.7(4) . . y
F6 P1 F1 87.9(6) . . y
F6 P1 F2 92.3(4) . . y
F6 P1 F4 91.3(4) . . y
F6 P1 F5 176.1(5) . . y
C29 Ru1 N1 97.0(3) . . y
C29 Ru1 N2 82.8(3) . . y
C29 Ru1 N3 99.1(3) . . y
C29 Ru1 N4 172.1(2) . . y
C29 Ru1 N5 78.7(3) . . y
N1 Ru1 N2 78.4(2) . . y
N1 Ru1 N3 95.6(2) . . y
N1 Ru1 N4 90.4(2) . . y
N1 Ru1 N5 173.7(2) . . y
N2 Ru1 N3 174.0(2) . . y
N2 Ru1 N4 101.5(2) . . y
N2 Ru1 N5 96.4(2) . . y
N3 Ru1 N4 77.4(2) . . y
N3 Ru1 N5 89.6(2) . . y
N5 Ru1 N4 94.2(2) . . y

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 -3.2(13) . . . . ?
C2 C1 N1 C5 1.0(11) . . . . ?
C2 C1 N1 Ru1 179.4(6) . . . . ?
C2 C3 C4 C5 1.4(13) . . . . ?
C3 C4 C5 C6 -175.2(8) . . . . ?
C3 C4 C5 N1 1.8(12) . . . . ?
C4 C5 C6 C7 -5.4(11) . . . . ?
C4 C5 C6 N2 172.4(7) . . . . ?
C4 C5 N1 C1 -2.9(10) . . . . ?
C4 C5 N1 Ru1 178.5(5) . . . . ?
C5 C6 C7 C8 176.4(7) . . . . ?
C5 C6 N2 C10 -175.9(6) . . . . ?
C5 C6 N2 Ru1 11.4(7) . . . . ?
C6 C5 N1 C1 174.3(6) . . . . ?
C6 C5 N1 Ru1 -4.3(7) . . . . ?
C6 C7 C8 C9 -1.5(13) . . . . ?
C7 C6 N2 C10 2.0(10) . . . . ?
C7 C6 N2 Ru1 -170.7(6) . . . . ?
C7 C8 C9 C10 3.4(13) . . . . ?
C8 C9 C10 N2 -2.7(12) . . . . ?
C9 C10 N2 C6 0.0(11) . . . . ?
C9 C10 N2 Ru1 171.8(6) . . . . ?
C11 C12 C13 C14 1.2(15) . . . . ?
C12 C11 N3 C15 2.6(11) . . . . ?
C12 C11 N3 Ru1 -174.4(6) . . . . ?
C12 C13 C14 C15 0.1(14) . . . . ?
C13 C14 C15 C16 -178.6(8) . . . . ?
C13 C14 C15 N3 -0.1(12) . . . . ?
C14 C15 C16 C19 0.2(11) . . . . ?
C14 C15 C16 N4 -179.9(7) . . . . ?
C14 C15 N3 C11 -1.2(10) . . . . ?
C14 C15 N3 Ru1 176.1(5) . . . . ?
C15 C16 C19 C20 175.0(7) . . . . ?
C15 C16 N4 C22 -177.4(6) . . . . ?
C15 C16 N4 Ru1 2.7(7) . . . . ?
C16 C15 N3 C11 177.5(6) . . . . ?
C16 C15 N3 Ru1 -5.2(7) . . . . ?
C16 C19 C20 C21 3.6(13) . . . . ?
C19 C16 N4 C22 2.5(10) . . . . ?
C19 C16 N4 Ru1 -177.4(5) . . . . ?
C19 C20 C21 C22 -0.1(13) . . . . ?
C20 C21 C22 N4 -2.5(13) . . . . ?
C21 C22 N4 C16 1.2(11) . . . . ?
C21 C22 N4 Ru1 -178.9(6) . . . . ?
C23 C24 C25 C26 -2.6(14) . . . . ?
C24 C23 N5 C27 1.6(12) . . . . ?
C24 C23 N5 Ru1 -177.6(6) . . . . ?
C24 C25 C26 C27 1.4(14) . . . . ?
C25 C26 C27 C28 177.8(9) . . . . ?
C25 C26 C27 N5 1.5(13) . . . . ?
C26 C27 C28 C29 -178.4(8) . . . . ?
C26 C27 N5 C23 -2.9(11) . . . . ?
C26 C27 N5 Ru1 176.4(6) . . . . ?
C27 C28 C29 C30 174.9(8) . . . . ?
C27 C28 C29 Ru1 3.0(10) . . . . ?
C28 C27 N5 C23 -179.6(7) . . . . ?
C28 C27 N5 Ru1 -0.3(9) . . . . ?
C28 C29 C30 C31 -51.2(12) . . . . ?
C28 C29 C30 C35 130.6(9) . . . . ?
C29 C30 C31 C32 -177.1(9) . . . . ?
C29 C30 C35 C34 178.2(8) . . . . ?
C30 C31 C32 C33 -1.4(17) . . . . ?
C31 C30 C35 C34 -0.1(13) . . . . ?
C31 C32 C33 C34 0.4(19) . . . . ?
C32 C33 C34 C35 0.7(18) . . . . ?
C33 C34 C35 C30 -0.8(15) . . . . ?
C35 C30 C31 C32 1.2(14) . . . . ?
N1 C1 C2 C3 2.1(13) . . . . ?
N1 C5 C6 C7 177.4(6) . . . . ?
N1 C5 C6 N2 -4.7(9) . . . . ?
N2 C6 C7 C8 -1.3(11) . . . . ?
N3 C11 C12 C13 -2.7(14) . . . . ?
N3 C15 C16 C19 -178.4(6) . . . . ?
N3 C15 C16 N4 1.5(9) . . . . ?
N4 C16 C19 C20 -4.9(12) . . . . ?
N5 C23 C24 C25 1.1(13) . . . . ?
N5 C27 C28 C29 -1.8(12) . . . . ?
Ru1 C29 C30 C31 119.9(8) . . . . ?
Ru1 C29 C30 C35 -58.4(10) . . . . ?

_platon_squeeze_special_details  
;
A solvent mask was calculated and 72 electrons were 
found in a volume of 238Å³ in 1 void per unit cell. 
This is consistent with the presence of 2[CH4O] per
Formula Unit which account for 72 electrons per unit cell.
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.656(4)
2 0.344(4)

